United States
Environmental Protection
Agency
Air and Energy Engineering
Research Laboratory
Research Triangle Park NC 27711
Research and Development
EPA/600/S 7-87/026  Feb. 1988
Project  Summary
The  Northeast Cooperative
Woodstove  Study
Paul Burnet
  This report gives results of a 2-year
study in Vermont and  New York,
monitoring  woodstove performance.
The objective  of the study  was to
determine the effectiveness of catalytic
and non-catalytic low-emissions wood-
stove technology in reducing wood use,
creosote accumulation, and paniculate
emissions.  Wood  use and  creosote
accumulation in chimney systems were
measured  in 68 houses over two
heating seasons. Of these houses, 42
were instrumented to measure partic-
ulate emissions and directly measured
wood use. Catalytic woodstoves, cata-
lytic add-on/retrofit devices, and non-
catalytic  low-emission  stoves  were
provided by various woodstove manu-
facturers   for  use  by  volunteer
homeowners during the study period.
Conventional technology  stoves were
also included to provide baseline data.
  Averaged results  indicate  that the
low-emission non-catalytic stoves and
catalytic  stoves had  lower  creosote
accumulation, wood use,  and  particu-
late emissions than conventional tech-
nology stoves, but the range of values
was quite large. Particulate emissions
reductions by the catalytic  and low-
emission stoves were not as great as
could be expected based on laboratory
tests.  The  many variables  affecting
stove performance in real world con-
ditions make it difficult to  identify
causative factors. Additional analysis
of data and further tests are currently
planned.
  This Project Summary was devel-
oped by EPA's Air and Energy Engi-
neering Research Laboratory. Research
Triangle Park.  NC.  to announce key
findings of the research project that is
fully documented  in two  separate
volumes of the same title (see Project
Report ordering information at back).

Introduction
  Woodstove  performance was studied
during the 1985-86 and 1986-87 heating
seasons in the Northeast. In the Water-
bury, VT, and  Glens Falls, NY, areas, 68
homeowners were provided  with
selected "advanced technology" stoves
or asked to use their existing (conven-
tional) stoves for the study. The stoves
were monitored for wood use, creosote
accumulation in  the  chimney  system,
and  paniculate emissions. Three
advanced  technology stove categories
(catalytic stoves, add-on/retrofit devices,
and low-emission, non-catalytic stoves)
were compared with conventional  tech-
nology stoves. Objectives of the  study
were to evaluate the performance of the
advanced  technology stoves for safety
factors (creosote), efficiency (wood use),
and environmental  impacts (particulate
emissions). The effectiveness of catalytic
combustors was emphasized.
  Creosote and woodpile volumes were
measured on all 68 houses.  Creosote
accumulation was measured by period-
ically sweeping the chimney system and
weighing  the collected material. Wood
use was  monitored by measuring  wood
piles during  the heating  season and
normalizing for moisture content and fuel
species.
  Additionally, 34 houses were routinely
sampled  for particulate emissions over
1 -week periods. These houses had data
logging systems to record stove temper-
atures, flue gas oxygen concentrations,
and wood weights.  Particulate samples
consisted of integrated samples collected
every half hour during each week-long
sampling period. Fl ue gas flow rates were

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\
    calculated based on combustion stoichi-
    ometry: burn rates, fuel species, flue gas
    oxygen measurements, and  estimated
    CO/C02 levels.
      Note that many variables were found
    in field  stove installations:  chimney
    systems, fuel characteristics, user prac-
    tices, stove maintenance, etc. The range
    of values recorded in all categories was
    quite large. Reported data, while repres-
    enting the values  recorded during this
    study, may not be representative of other
    climates, fuel  woods, stove or catalytic
    combustor models, chimney systems, or
    stove use patterns. Great care should be
    used in extrapolating these  findings to
    other circumstances.
      Due to the high variability and large
    range of data, averages from advanced
    technology stove groups, in most cases,
    were not statistically different from the
    conventional stove group.  "Student's t"
    tests showed that only the low-emission
    non-catalytic stove group had a mean
particulate emission rate with a greater
than 90% probability of being different
and  hence lower than those from  the
conventional stove group.  Emissions
from individual  stove models, however,
often were statistically different from the
mean of  the conventional stoves.  All
advanced  technology devices (catalytic,
add-on/retrofit, and low-emission non-
catalytic) showed lower average partic-
ulate emission rates,  wood  use,  and
creosote accumulation than the conven-
tional technology. Figure 1 summarizes
averaged results from the stove technol-
ogy groups.
  The  stove technology group data
represent  averages, and reflect a wide
range of  values.  In general, all stove
categories,   including conventional
stoves, had models and specific instal-
lations with low (and high)  particulate
emissions. It  is therefore most  approp-
riate to  evaluate stove performance on
a model-by-model basis, recognizing that
(due to the relatively few  installations
and  stove  models)  values  may  not  be
representative   of "typical"  stove
performance.
  Although  the  number  of samples is
high, the wide range of values and the
many variables make it difficult to identify
causative factors. Results given  in this
report are from a number of stove types
and  models in different installations, in
which  homeowners used different fuels
and  operating procedures.  A thorough
review of stove burn rates, fuel loading
practices, catalyst operation times, and
frequencies of alternate heating systems
did not identify a single factor responsible
for emission patterns. This indicates that,
while many factors can  affect particulate
emission rates, no single factor appears
to be  dominant  in all stove  types  or
models. In  general, however, it appears
that stoves with  smaller fireboxes,
regardless  of technology type, tend to
have lower emission rates.


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                                 Particulate Emissions, g/hr

                                 Wood Use, kg/HDD

                                 Creosote Accumulation, kg/1000/HDD
                                                       (HDD = Heating
                                                       Degree Days)
    Figure  1.   Performance comparison by stove technology.

                                        2

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Conclusions
  General conclusions are listed below
by category: Advanced Technology Per-
formance, Catalyst Performance, Oper-
ator Practices, Technology Factors, and
Other Findings.

Advanced Technology
Performance
  1.  Most stoves in the advanced tech-
     nology categories (catalytic,  add-
     on/retrofit,  low-emission non-
     catalytic)  episodically  demon-
     strated lower emissions than the
     baseline conventional stoves under
     field use conditions. Good perfor-
     mance in at least one installation
     for most  of the stove models indi-
     cates that  factors, such as stove
     maintenance andfueling practices,
     may  be  as important as  stove
     technology features  in achieving
     low emission rates. Stove firebox
     size, regardless of technology
     group, was a prime factor in deter-
     mining emission  rates;  smaller
     stoves had  lower emissions.
  2.  In  general, performance  of  the
     stove technology groups appeared
     to be consistently ranked in terms
     of particulate emission rates, wood
     use, and creosote accumulation;
     low-emission non-catalytic stoves
     had the  lowest particulate emis-
     sion rate, wood use, and creosote
     accumulation, while  conventional
     stoves had the highest. Note that
     only  low-emission non-catalytic
     stoves showed a mean emission
     rate which  was statistically differ-
     ent from  that of conventional
     stoves. Also note that creosote
     accumulation is strongly  influ-
     enced by flue system type, and
     wood use appears to be influenced
     by burning patterns and  firebox
     size.
  3.  All advanced technology  stove
     groups averaged lower wood  use
     and creosote  accumulation rates
     when  households switched  from
     conventional  stoves  between
     heating  seasons. Average reduc-
     tions by  stove group ranged from
     about  10 to 35% for creosote, and
     from about 15 to 30% for wood use.
  4. The low-emission stoves, as a
     group,  had the  lowest  average
     emissions.  Each  model had differ-
     ent burning characteristics;  most
     showed  relatively good  perfor-
     mance. Average  results from this
     technology  group  are  strongly
     influenced by the  good perfor-
     mance of two stoves (M and  N)
     which  may  be   EPA   1990-
     certifiable. Furthermore, excluding
     one  high-emission  house  (V18,
     using non-EPA-certifiable Stove K)
     would reduce average emissions in
     this category from 13.4 to 10.0 g/
     hr, and reduce the standard devi-
     ation (a) from 10.2 to 5.7.
  5.  User  satisfaction was generally
     high with the advanced technology
     stoves provided to study houses. In
     particular, homeowners with cata-
     lytic and low-emission stove mod-
     els were frequently  pleased with
     the units. (In some cases, user
     satisfaction remained high even
     though the catalytic combustor had
     deteriorated.) Some add-on devices
     also  received positive comments.
     The add-on with  the lowest aver-
     age particulate emission  rate also
     received  homeowner  complaints
     about smoke spillage.

Catalyst Performance
  1.  Catalytic  stoves  showed variable
     performance. Most individual mod-
     els performed well in some houses.
     Other installations had relatively
     high  emissions.  Overall, perfor-
     mance of these  stoves did not
     match the expectations  created
     under ideal laboratory conditions,
     although  only one of the catalytic
     models  may be  EPA  1990-
     certifiable. The  mean emission
     rates  of existing catalytic  stoves
     and  new  catalytic  stoves  were
     virtually identical  User education
     and  further  technology refine-
     ments remain possible  factors
     which could  help  improve the
     performance of catalytic stoves.

  2.  Add-on/retrofit  devices did not
     perform  well overall,  but two
     devices reduced emissions consid-
     erably. The stoves on which these
     devices were mounted are a major
     factor in measured emission rates.
     Retrofit F, which consistently had
     high emissions, is no longer being
     produced.

  3.  Catalyst durability was quite var-
     iable. Rapid  deterioration was
     noted in some combustors, all  of
     which were cordierite-based, with
     corresponding  increases  in  emis-
     sions. In one stove model (which
     apparently accelerated combustor
     deterioration),  replacement with
     second generation, non-cordiente
     combustors appeared to virtually
     eliminate the deterioration trend.
     Emissions from this stove model
     were  reduced  by about 30% by
     using second generation combus-
     tors  during  the second  year,
     although it is not clear whether this
     was from  improved  catalytic per-
     formance or reduced degradation.

 4.  Overall, there did not appear to be
     a consistent increase in particulate
     emissions  from catalytic  devices
     over the 2-year testing period. No
     clear  trend of long-term  loss of
     effectiveness was noted. However,
     a   number   of   combustors
     (cordierite-based) were discovered
     to be deteriorating. These combus-
     tors  were  replaced;  emission
     values reported in this study reflect
     relatively frequent catalyst inspec-
     tions and  replacement  when
     necessary. Note, however, that not
     all cordierite-based combustors m
     the study indicated signs of dete-
     rioration  of the  substrate.  A
     cordierite-based combustor from
     an existing stove with an estimated
     6000  hours  of use  showed rela-
     tively  low emissions m  laboratory
     retestmg. All combustors retested
     m  the laboratory had  reduced
     performance  relative  to  new
     combustors.

 5.  Condensation of moisture and
     organic material in  flue systems
     and subsequent drainage or leach-
     ing of condensate was a problem
     in  some houses during very cold
     « 20°C) weather  Only catalytic
     stoves experienced this problem.
     This  appears  to be related to
     inappropriate installation and is not
     necessarily a technology limitation

 6.  Catalyst AT  (temperature change
     across the combustor) and percent
     operation time are not  good indi-
     cators of  stove particulate  emis-
     sions  Factors such as  fueling
     cyclesflong burn-down "tails") and
     measurement difficulties may pre-
     clude the use of these parameters
     for predicting emission rates.

Operator Practices
 1.  Operator practices, in combination
     with  other parameters,  appear to

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    be a significant  factor in stove
    performance. Specific  practices
    which may  result in lower emis-
    sions from all stoves have not been
    identified from  available data.
    However,  routine maintenance
    inspections of  the combustor,
    gasketing, and overall stove system
    can help identify deteriorated com-
    ponents  in need of  repair  or
    replacement.

2.   Burn rates did not demonstrate a
    strong correlation with emission
    rates for any of the stove technol-
    ogy groups,  although general
    trends were observed. Often,  as
    with conventional stoves, the trend
    was  opposite  that which was
    expected; emissions  increased
    with burn  rate. This may be related
    to field conditions, in which lower
    burn rates may include  longer
    "charcoal phase" burning periods.

3.   Mean fuel  loading frequencies
    were identical for the low-emission
    and conventional stove groups,
    although the average low-emission
    stove fuel load was 56% that of the
    average  conventional  stove fuel
    load. This indicates that  smaller
    firebox capacity  (typically asso-
    ciated with low-emission  stoves)
    does not necessarily require more
    frequent fueling of the stove. User
    satisfaction  was  generally high
    with the low-emission stoves.

4.   Average emission factors (g/kg) for
    all the stove categories were quite
    similar.  Differences  in average
    emission  rates (g/hr) were there-
    fore driven by burn rates. The low
    average  burn  rate of the low-
    emission  stoves, and resulting low
    average emission rate, may be due
    to more frequent "charcoal phase"
    burning periods.
5.   Fuel  loading frequencies  did  not
    correlate well  with particulate
    emissions.  However, loading fre-
    quencies  did increase with smaller
    fuel loads for all technology groups,
    as was expected.
6.   Fuel  loading frequencies  were
    significantly different between
    houses, even those using the same
    stove model.
7.   The lack  of strong correlations
    between particulate emissions and
    other variables indicated that many
    parameters  have significant, if
     unquantified, effects  on stove
     performance. Fueling and burning
     cycles are thought to be areas for
     further investigation.

Technology Factors
  1.  Firebox  size is a major factor  in
     determining particulate  emissions
     from woodstoves; emission rates
     increased with  firebox volume,
     regardless of stove technology.
  2.  Preliminary results  from stove
     inspections  conducted  after the
     second heating season (September
     1987)  indicate  that significant
     leakage of smoke around combus-
     tors may be a cause of high emis-
     sions in some stoves. (A separate
     report on this work will be issued.)
     Stove  inspections showed  that
     gasketing, especially around the
     bypass  damper  and combustor,
     was the most frequent component
     in need of maintenance and the
     apparent cause of leakage. Leak-
     age rates and particulate emissions
     do not  appear  to correlate  well
     overall, but show some correlation
     for individual stove models.
  3.  Using a qualitative measurement
     methodology,  insulated  metal
     chimney systems accumulated the
     least amount of creosote. Masonry
     chimneys located on outside walls
     accumulated the most.
Other Findings
  1.  This study did  not show that one
     stove  model is necessarily better
     than another. As stated previously,
     a wide range  of  results  were
    recorded. For a given stove model,
    the most emission samples was 19;
    the fewest was 1. The most instal-
    lations for a given stove model was
    four; the fewest was one. The high
    degree of variability in performance
    and the  relatively  small  sample
    populations  make  comparisons
    inappropriate.

2.   Conventional stoves in this study
    may be cleaner-burning  heaters
    than are "typical." Four of the six
    conventional stoves had relatively
    small fireboxes ( < 2.4 ft3), and two
    of these had small  effective fire-
    boxes (  < 1.5 ft3). Emissions from
    these stoves therefore may not be
    typical of existing stove technology.
    Additionally,  the cold Northeast
    climate  and  commensurately
    higher burn rates preclude direct
    comparison to stove performance
    in milder climates.
3.   Alternate heating system  use did
    not correlate well with particulate
    emission  rates  or burn  rates,
    although  heating system use was
    monitored only in the room with the
    stove. In general, most houses in
    the study used their  alternative
    heating system less than 3.5% of
    the time (while the stove  was
    operating). This amounts  to less
    than 1  hour per day. Many of the
    houses used no backup heat at all.
4.   Polycyclic organic material (POM]
    emissions were variable and  non-
    conclusive. Testing method and
    analytical method limitations, and
    a very  limited database, preclude
    any ranking of POM emissions by
    stove type.
                                 4

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                                                                               —_    \OH\O,
      Paul Burnet is with OMNI Environmental Services, Inc., Beaverton, OR 97005.
      Robert C. McCrillis is the EPA Project Officer (see below).
      The complete report consists  of two volumes,  entitled "The Northeast
        Cooperative Woodstove Study:"
        "Volume I," (Order No. PB 88-140 769/AS; Cost: $32.95)
        "Vo/umell. TechnicalAppendix,"(OrderNo. PB88-140 777'/AS; Cost: $19.95)
      The above reports will be available only from: (costs subject to change)
             National Technical Information Service
             5285 Port Royal Road
             Springfield, VA 22161
             Telephone: 703-487-4650
      The EPA Project Officer can be contacted at:
             Air and Energy Engineering Research Laboratory
             U.S. Environmental Protection Agency
             Research  Triangle Park, NC 27711
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
Penalty for Private Use S300

EPA/600/S7-87/026
                              ps

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