HEAT TRANSFER  IN  FLUIDIZED BEDS
                    by

             .Anthony Bright
             Kenneth A.  Smith
               FINAL  REPORT

              October, 1970
Prepared under Contract No. CPA-22-&3-44  for

National Air Pollution Control Administration

Division of Process Control Engineering
              Chi...  .-u ••        .  ~;   .,.;-v.;

     Department of Chemical Engineering
   Massachusetts Institute of Technology
         Cambridge, Massachusetts

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   Synopsis




         This  report  contains:                                         *.




           (a)  A  summary of  the  state of  the  art  for heat  transfer  to surfaces  in




               contact with  fluidized beds, including  a  compilation of published




               investigations; with  a listing  and discussion of  the various  theo-




               retical, empirical/ and  semi-empirical  expressions for predicting




               heat  transfer coefficients  in  fluidized beds.




           (b)  A  summary of  the  study carried  out here,  with a discussion relat-




               ing these investigations to the general picture proposed above.




           (c)  A  general discussion  of  the important factors to be  considered in




               the design of fluidized-bed heat transfer units with recommenda-




               tions for future  research.






   I.  THE STATE OF THE ART




         Appendix  IIIA presents a compilation,  in  tabular form, of the  major  ex-




   perimental  investigations  carried  out in the field of  heat transfer to surfaces




   in contact with fluidized beds.  It has been found helpful to separate them




   into two groups; heat transfer in  the dense  phase region i.e., up to the point




   where  there is  a net movement  of the.  solids  bed relative to the walls of the




   confining vessel (low bed voidage  of  the order  of magnitude 50-70  percent);




   heat transfer in the dilute phase  region (bed voidage  usually in  excess of 90




   percent).  Although many investigations overlap into both regions,  the various




   studies have been divided according to the region containing the  majority  of




   the data points.  The reason for the division is that  no one particular dense-




   phase  heat-transfer correlation can be extended into the dilute zone, and  vice




   versa.  The first group has been further divided into  heat transfer  to the con-




   fining wall, and heat transfer to bodies immersed in the fluidized  bed.
i

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r
             From the extensive amount of experimental data  that have been  collected

                                ;

       by various investigators, a number of  theoretical,  empirical  and  semi-empiric.



       correlations have been advanced.  These  are  listed  in Appendix IIIB.   Each  co.



       relation is valid only within the limits of  the experimental  data used by  the



       author.



             Appendix IIIC lists the two generalized empirical correlations  for heat



       transfer in fluidized beds, the Wen-Leva (38) and the Wender-Cooper  (3^) cor-



       relations.  These two correlations are held  to be the most useful  in  predictir



       heat transfer coefficients at surfaces in  fluidized beds, and cover  a wide



       range of conditions.  Zenz  (40), Kunii and Levenspiel (4_1J , and Zabrodsky  (4_2^



       all cite these generalized correlations  in their books; Zabrodsky  also con-



       siders the correlation of Vreedenburg  (28) for horizontal tubes to be generall



       applicable .



             Appendix HID shows by means of  a  power function equation,  the  predicted



       effect of the many parameters which could  affect the  heat transfer in fluidize



       beds.  The values in the columns under each  parameter are the exponents in a



       standard power function equation of the  type:
  a*

C    etc.
 g
g    s


etc., are the exponents listed, and the power equation is
                  had    o    C
                       p


       where ai , aj, aj, an



       derived  from the empirical or theoretical correlation of the investigator.  Th



       value of such an analysis is questionable, since many of the parameters are



       interrelated, but it has been suggested  (Mickley (21) ) that the effect of the



       thermal properties of the bed k , k , C  , C  on heat transfer can be separated



       from the effect of bed dynamics, which includes those properties related to th



       state of fluidization of the bed e.g., d , p , u etc.  Bearing in mind the



       interrelationships of many of the parameters, it is possible to discuss the



       general effect of significant properties on the heat transfer process.

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'.[ ected

^pirical

:ach cor-

by the
m
^r
T heat

) cor-

ndicting
*

j de


>.y (4_2)
con-
^
e^nerally


edicted

ftiidized

in a


*
t ion is
or. The
• re

of the
parated
^ to the
the
the


3

Effect of Variables (Empirical Models)

(a) Particle Diameter d
P
The majority of investigations show an inverse relationship between

the heat transfer coefficient h and the particle diameter d , the most notable
exception being the correlation of Leva (6) . The latter investigator, however,

included a fluidization efficiency factor of which makes allowance for the

inverse effect of the particle diameter d on h. There is a wide variation in
P
the precise dependence of h on d , as can be seen from Appendix HID e.g.,
P
-0 23
Dow (5) had
- P
Miller (24) had ~ฐ'96
P
(b) Medium Thermal Conductivity k
9
All investigators showed a direct proportionality between h and k ,
ranging as follows:
0 33
Mickley (22) h a k
— g
Leva (6.) h a k1'0

This variation in exponents is discussed later when the proposed mechanisms of
heat transfer in fluidized beds are considered.
(c) Solids Heat Capacity C
Most investigators showed a direct proportionality between h and C
_ ,_. . _ 0 . 25
Dow (5) h a C
""" S
Wender (39) h a C ฐ'8
— s
(d) Other Solid and Gas Properties
Because of the wide disparities between the various investigators as
to the precise effects of properties such as bed-porosity e,.; bed geometry D.
and H ; superficial gas velocity u; gas density and viscosity p and u ; caused
by the complex nature of the fluidized state of the bed, a more detailed dis-
cussion will have to await developments in the understanding of the physical
I '

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nature of the complex behaviour of  f.luidized  beds.   However,  for engineerir



design purposes, Mickley  (21') suggested  the use  of  a stirring factor S  whic



accoun'ts for bed motion and geometry  to  include  the effects of those proper



which modify bed dynamics.  The present  study attempted  to relate these prc



ties with a simplified model of gas bubble behaviour in  fluidized beds.



       (e)  Gas Velocity u



           A qualitative understanding of the overall  picture of heat trans



in  fluidized systems can be obtained  by  considering the  way in which the he



transfer coefficient h varies with  gas velocity.  Up to  the point of initia



fluidization, the value of h is essentially the  same as  for heat transfer t



packed bed.  At the point of minimum  f luidization,  gas velocity u _,  the he



transfer coefficient increases abruptly  and continues  to increase with  gas



velocity until a maximum value h    is reached.   At higher gas velocities,
                                fflclX


heat transfer coefficient decreases slowly as the bed  becomes "diluted" of



solid particles.  This general trend  is  borne out by all the  investigations



covered.  Baerg (13), Kharchenko  (20) and Varygin (27) have attempted to co



relate their data to predict the value of h    ,  the maximum heat transfer c
                                           max


efficient to surfaces in contact with fluidized beds.  Leva (ฃ3_)  suggested



another reason for the variation in the  predictions might  be  that individua



investigators have studied different portions of  the heat  transfer -  veloci


                                         0 8
curve.  For example, Dow  (5_) gives h a u * ,  whereas Van Heerden (11) gives


     0 45
h a u     which suggests that the latter author's data refer  to a region  cl



to the maximum on the h vs u curve.





Theoretical Models                                                  {



      Of the various models which have been presented  to suggest  the  physic-



mechanism of heat transfer between fluidized  beds and  contacting  surfaces,



general classes can be distinguished:

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Bering

"which
         I
         i
>;-operties

;e proper-
 transfer

 >^e heat

 nitial

 fer  to a

 he heat
 •
  gas

 ies,  the

 " of
 i o  cor-

 f'er co-

 |jฃed that

 vidual

 elocity

 gives
 •
 on  closer
       (a)  The resistance to heat transfer  lies within  a  relatively  thin  region


at the wall [ง.ปง./I/ill •

       (b)  The resistance to hea't transfer,  lies within  a  relatively  thick  emul-
                                                                           \
sion layer which is being frequently replaced by  fresh  emulsion  from the main


core of the fluidized bed []JL'U.'I1'11'1P_'1ง.'1ZJ •

      Botterill  (44) suggests that the thermal conductivity of the fluidizing

medium is the limiting factor in the heat transfer process.  Mickley (2JJ , pro-

posing the contacting emulsion-packet mechanism of type  (b) above, found that

the heat transfer coefficient should vary as the  square-root of  the  quiescent
                                   I
bed conductivity, i.e., the gas conductivity raised to  the one-third power

since the relationship between gas conductivity and quiescent bed conductivity

                                            2/3
has been found to be approximated by k  a k
 *
 hysical
          i
 ces,  two  •*
                                                   Alternatively,  if  a gas  film

were controlling the heat transfer process,  (type  (a)}  as proposed by Leva (ฃ),

the heat transfer .coefficient should vary as  the first  power  of  the  gas  con-

ductivity.  As shown previously, the exponent power  on  the  gas conductivity

varies from 0.33 to 1.0 in the various correlations  proposed, giving an  indica-

tion of the type of mechanism operating in each case.


II.  THE PRESENT STUDY

      The overall purpose of the study was to investigate the heat transfer

characteristics between fluidized beds and contacting surfaces in order  to

develop heat-transfer correlations for use in large-scale fluidized  bed  design.

The general approach was to consider the basic mechanics of fluidized bed  heat

transfer in order to provide a foundation for a better  understanding of  the

many different correlations proposed in this  field.  To do  this, generalized

serai-empirical correlations were selected from the literature representing the

two major theoretical models, and ware tested using  available data.

      As previously mentioned, the physical picture  of  the  heat  transfer

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 process  has been  debated  by  several  groups of investigators,  the outcome of



 which  has been the division  of  opinion into two broad categories, the extremes



 of  which are best represented by  the theories of Leva (6_)  and Mickley (21) .



 Leva  (6) assumes  that  the chief resistance to heat exchange is in the laminar



 gas film at the boundary  of  the surface in contact with the fluidized bed.



 Heat  flow through the  film is by  conduction.   Further he suggests that the  ver



 tical  motion of the particles along  the surface considerably  lessens the ther-




 mal resistance of the  laminar layer, causing the high heat-transfer coeffi-



 cients observed in fluidized beds.   The theory depends upon an understanding o



 the pattern of this particle motion  and the velocities of  the particles.



 Mickley  (21) assumes that the controlling mechanism may be considered to be  an



 unsteady-state diffusion  of  heat  into mobile  elements of quiescent bed materia



 "emulsion packets", in contact  with  the surface, which are constantly being



 renewed  by fresh.emulsion from  the main core  of the bed.



       Neither of  the theories can be tested directly since quantitative  values



'for parameters such as Leva's interparticle friction factor 6, or Mickley"s



 emulsion packet contact frequency <}>, are not  well known.   However, it was de-



 cided  to represent the two theories  by the generalized correlations of Wen  and



 Leva  (38) for the "thin-film"model and Wender and Cooper (39)  for the "emulsioi



 market"  model.  The basis for this assumption came from the following observa-



 tions:



       (a)  The Wen-Leva (38) correlation was  developed directly from the Leva



 (6_) 'thin-film1 model.



       (b)  The Wender-Cooper (39) correlation for heat transfer to immersed



 surfaces was developed from  the data of Mickley (21)  and when  tested indepen-



 dently gave a close alignment to the data of  Pratt and Richards (45) ,  Fairbanks



 (46),  and Hawthorn (47) which were the source data of Mickley's (2_2_)  theoret-



 ical correlation.

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 ปof


 y's


 as de-

 *
 •Jen  and


 2mulsion


 Dserva-


 •


 3 Leva





 Mod


 2epen-


 lirbanks


:o ret-
       to)  The Wen-Leva, (38) correlation  is  based  largely  on  data pertaining to


heat-transfer between fluidized beds and  the confining  vessel wall  [5,6,10,11] .


The Wender-Cooper  (3_9_) correlation used was  based  entirely on data  from inves-


tigations with surfaces immersed in the fluidized  bed  [K^, 1J3,21^ 2_3_, 3j>_] .   Toomey


(10) reported simultaneous bed-exterior wall and bed-interior calrod  heat-


transfer coefficients and found large differences  between  the coefficients  at


the two surfaces although at high fluid mass velocities the coefficients  ap-


proach each other.  It was deduced that the  differences might be  due  to dif-


ferent mechanisms operating and that the  Wen-Leva  correlation  (bed-wall)%rep-


resents the 'thin-film1 mechanism and the Wender-Cooper correlation  (bed-


internal surface) represents the 'emulsion-contact' mechanism.  Further it


seems likely that in a bubbling bed, surfaces immersed  in  the bed will be con-


tacted frequently with rising bubbles which  allow  fresh emulsion  packets  to


sweep up to the surface, while the frequency of bubbles near  the  wall will be


much Tower with solids descending along the  wall surface and  the  development of


a thin gas film layer at the wall.


      In order to test the Wen-Leva and the  Wender-Cooper  correlations, and  the


theoretical models that they were chosen  to  represent, the data of Van Heerden


(13J and Dow and Jacob (5)  for heat transfer from  the bed  to  external surfaces


and the data of Fairbanks (4jy , Hawthorn  (47) and  Baerg (13)  for  heat transfer


to surfaces immersed in the bed were employed.  The comprehensive data of


Fairbanks and Hawthorn were available at  M.I.T.  The data  of  Van  Heerden  and


Baerg are generally considered to be the  most systematic and  representative


data on heat transfer between fluidized beds  and contacting surfaces  [cf  Leva


(4J[) , Kunii and Levenspiel (41), Zenz (40)].  Of the other data sources listed


in Appendix IIIA only Dow and Jacob gave  information on bed voidage at dif-


ferent fluidization conditions which was  necessary for application to the gen-
                 i                                  .
oralized correlations.  An attempt to. predict bed  voidage  from the  'M-plot1  of

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                                                                             8






Leva  (4JO was made, but the results did not prove  very  satisfactory.   Thus me



of the investigations in this study wore based on  the five  data sources men-



tioned above which gave sufficient details to apply  to  the  Wen-Leva and Wendc



Cooper correlations.



      Appendix IV, Graphs 1 and 2, shows the results of the data-testing.   As



might be expected, the bed-to-external surface heat  transfer data  of  VanH^erc'



 (1^), and Dow and Jacob (5_) (which had been employed  by  Wen  and  Leva,  along wi



other data, to develop their correlation) aligned  closest to the Wen-Leva  coi



relation for bed-to-external surface transfer; also, the vertical  immersed sv



face transfer data of Fairbanks (ฃ6_) (used by Wender  and Cooper  to  help  develc



their relationship) and Hawthorn  (47)  aligned closest to the Wender-Cooper cc



relation for transfer to vertical immersed tubes.  The  data of  Baerg  (13),  ho.



ever, showed a tendency under certain conditions to  follow  the  Wen-Leva cor-



relation whereas it would be expected to be in line with Wender-Cooper  for in



mersed heat transfer surfaces.



      In order to explain the anomalous results of Baerg, it was thought that



not only the location of the heat transfer surface  (external wall  or  internal



immersed) but the geometry and size of that surface might be a  governing fad



as to which correlation, and which corresponding mechanism,  might  be  valid ii



any circumstance.  Baerg"s internally heated tube was much  larger  than  the



internal cylindrical heaters of Fairbanks and Hawthorn, and  the following  hy-



pothesis was therefore proposed:



         1)  Heat transfer coefficients to the containing walls of  the  fluid



ized bed can be predicted by the Wen-Leva (thin-film) correlation.



         2)  For surfaces immersed in the fluidized bed:



             (a)   If the dimensions of the surface  (tube diameter)  are  smalL



than some characteristic dimension for the fluidized system,  then  the Wender



Cooper (emulsiom-contact)  correlation should predict the heat-exchange  rates

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 ?h.us mos-
           (b)   If  the dimensions  of  the  surface  are large compared to this
  men-   Characteristic  dimension then the Wen-Leva (thin-film)  correlation will apply.



 1 Wender-       For the characteristic dimension,  the b,ubble diameter was chosen based on



          the  physical picture  that only when  the  bubbles are of sufficient size, in cora-



     As   parison with the  size of the immersed  surface,  to be able to sweep packets of



        nemulsion  to the immersed surface  will  the  conditions for the 'contacting emul-



 long with sion packet1 mechanism be favorable.   Estimations of the bubble diameter for
 ^a cor- 'different  fluidizing  gas  rates were'attempted "in  order to deduce values of


 rsed sur-Hawthorn's emulsion-packet  contact  frequency,  ,.   Assuming that the unsteady
 develop  state behaviour  of  the  emulsion  packets  is  caused by the passage of the low
 Doer cor-density bubbles,  it was  proposed  that  the  contact  frequency of the emulsion


 91       I
 13), how-packets can be equated to  the  frequency  of bubbles past the surface.   Values of


 a cor-   'bubble frequency  were determined  theoretically  from Davidson's (43)  simplified


  for im-  model.  It was found that  these values were from two to ten times higher than
ht that
nternal
the emulsion contact frequencies measured by Hawthorn, which  implies  that  the


theoretically derived values of bubble diameter over-estimated  the  actual  bub-


hie size.  Nonetheless, it was hoped that these estimates would serve as a corn-
   factorparative guide  for assessing  the  characteristic  dimension proposed above.
a lid in
 the
      Graphs 3 and 4 in Appendix IV show the results of  Baerg  (13)  and
H/reedenburg  (28) in the form of a plot of h
             — — .
                                              /h   ,  versus  the  ratio  of  pseudo
                                                C 61 -L C
Ing hy-  "bubble diameter to  internal tube diameter d, /d  .   It  was  hoped to observe  a


         •transition  from the  'thin-film' mechanism to  the  "emulsion-contact1  mechanism
 fluid-  'as d,/d  increased.  The general  scatter of  the  data  points  do not show a clear


         .transition; although the data of  Vreedenburg indicate an  agreement with the


         above hypothesis  i.e.  at a  certain d  /d  ratio  (approx. 1.5)  and greater the


 smaller wender-Cooper correlation gave  a  better fit  to  the  experimental results, whilst


Kender-  pelow this value, the  Wen-Leva  correlation gave  the closer fit.  Vreedenburg


•rates.  himself found it  necessary  to propose two correlations of his own to represent

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                                                                           ir



his experimental results, noticing a transition at a Reynolds  Group No.  ( p "c
                                                                          ~V(>"
of 2050, evidence of a change in nature of the fluidized bed and  the


mechanism controlling heat transfer.


      For large-scale systems, the data of Highley  (18) for transfer to  im-


mersed horizontal tubes in a 3-ft. diameter bed were applied to the correla-


tions.  Appendix V shows the coefficients predicted by the correlations  com-


pared with an average observed value of the heat-transfer coefficient  from


individual horizontal tubes in a multiple bank of tubes.  The  Wender-Cooper


correlation gives the closer approximation, although neither of the correla-


tions takes account of factors such as tube position in the bundle or  the


change in heat transfer coefficient around the circumference of the tube.


      A large part of the investigation was centred on gaining physical  insii


as to the internal workings of a bubbling fluidized bed by investigating pro


posed mechanisms for gas-particle motion and endeavouring to build a simplif


model relating fluidized bed dynamics with easily measured physical properti*


of the system.  Davidson's (48)  bubbling-bed model has already been mentione


in connection with bubble diameter and bubble frequency calculations.  Howev


the complex nature of the gas-particle interactions in most of the experimen


systems studies make it unlikely that Davidson's simplifying assumptions appli


in these cases.  The Davidson model, therefore,  is of limited  quantitative u


although it serves as an order-of-magnitude analytical tool for most fluidiz


situations, and is readily amenable to design work since only  well-known phy


ical properties of the system under study are required for its application.


other physically-based model has been found which combines simplicity  in dat


requirements with quantitative accuracy.  This scarcity of viable theoretica


models for the purely mechanical behaviour of fluidized beds is the largest


obstacle to useful advance in understanding their heat transfer properties.

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      10
   ,d Go
   (  P  ฃ
 i  im-



 •ela


 ;  com



 : rom
 rtela-
 L  insight



 ig pro-



 i-nplif ie



 flerties



 itioned



 However
 applied



^ive use



1 uidized

•

.in phys-



tion.  Nc



in data



rcitical



rgest



ties .
                                                                            11





Overall Conclusions                         ,



      The lack of theoretical understanding of mechanism and of general  correla-



tion work has left open the problem of predicting heat  transfer coefficients



between fluidized beds and the surfaces in contact with them.   The  reported



empirical correlations of various individual  investigators  are  valid  only



within the limits of their own experiment and do not  appear to  be able to en-



compass the data of other investigators.



      Two generalized correlations, Wen-Leva  (38) and Wender-Cooper  (3JU cover



more extensive ranges of conditions and data  and may  be expected to be extended
                                                                     •


for use in large-scale design work after modification by the effect of such



factors as:



           (i)  Tube spacing and arrangement  in multiple tube banks



          (ii)  Position around tube circumference



         (iii)  Bed diameter (changing the flow properties  of the fluidized



                solids)



          (iv)  Particle size distribution



           (v)  Gas entry configuration (distributor)



          (vi)  Baffles



      However, it is important to note that even these  correlations.ordinarily



require estimates of the void fraction; and in this regard,  our present  pre-



dictive abilities are very poor.



      It is suggested, albeit very tentatively, that  the choice of correlation



is based on the hypothesis outlined previously which  proposes that for surfaces



immersed in a fluidized bed, the heat exchange rates  will depend upon the phys-



ical state of the fluidized bed,  either vigorously bubbling  with the  surfaces



often swept clean of emulsion ('emulsion-packet model")  or fairly smooth  fluid-

• •                               ซ
ization with particles descending near the surface "scouring" the gas film



formed there  ("thin-film model").  That there mi^ht be  a transition from one

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mechanism to the other with change in fluidization conditions  is  at  least  th




retically possible.  Furthermore, transition would be -expected to depend on




relative sizes of the immersed element 'and a characteristic  dimension of the




bubbling bed (e.g., bubble diameter), and the choice of design correlation




would depend on the physical mechanism operating i.e., Wen-Leva (38) for the




'thin-film' model and Wender-Cooper  (390 for the 'emulsion-packet' model.






III.  FUTURE RESEARCH REQUIRED




      It is to be expected that future research in this field  will be concer




trated mainly on bridging the gap between laboratory and industrial  fluidizc




bed design with the emphasis on gaining information about the  effects of pa:




meters such as those outlined in the conclusions.




      Until the mechanics of gas-particle motion in a fluidized bed  and its




relation to the physical properties of the bed is better understood, no the'




retical equation describing the heat transfer properties of  fluidized beds




suitable for use as a design correlation can be formulated.  For  example, p




diction of bed voidage at any fluidized conditions with any  degree of accur




is difficult with existing correlations, yet knowledge of this  important pa




meter is essential for specifying the state of fluidization  of  a  bed.




      The problem of scaling-up laboratory experimentation into full-scale




units is to maintain the quality of fluidization.  As more data are made a\




able from large-scale units, general design trends will become  apparent.  F




example, Volk (49) used vertical surfaces in the form of tubes  to modify tf




'equivalent1 diameter of his large-scale bed to conform with the  diameter c




his small-scale unit and Petrie (31)  found that finned surfaces on the flu.




ized bed side of heat exchanger tubes increased heat transfer  rates twofoli




Nonetheless, a sound interpretation of heat transfer in fluidized beds mus'




await future developments in our understanding of bed mechanics.

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    12  :
                                                                                   13
   the o-l
3 on th;-  nomenclature
f the
ion
         C
                                           APPENDIX  I
T the
1.
ft
oncen-
i dized
j" para-
[ its
> theo-
||ds and
.o, pre-
i::curacy
it  para-
                           d *p p g
                           JE__1_3_ฃ.
:ale
3e avail
?.  For
fy the
ter of
ftfluid-
cfold.
 must
      Avogadro  No.

      heat capacity  of fluidizing  gas
      heat capacity  of solid particles
      correlation  factor for non-axial location of internal tube
      particle  diameter
      bubble diameter
      external  diameter of immersed object (tube,  sphere)
      diameter  of  containing vessel
      superficial  mass velocity  of fluidizing gas
      superficial  mass velocity  of fluidizing gas  at minimum fluidization
      heat transfer  coefficient
      heat transfer  coefficient  measured  by  investigator
i   ..   heat transfer  coefficient  calculated according to one of the generalized
ca Xc
      correlations
      height of heat transfer surface exposed to fluidized bed
      emulsion  thermal conductivity
      thermal conductivity of fluidizing  gas
      thermal conductivity of solid particles
      length of immersed tube
      height of bubbling fluidized bed
         mf
        h
         exp
         mf
              bed height at minimum fluidizing conditions
                          hd
                        *  ซ
         >r
              Nusselt No.
              Prandtl No. r-—
                           g

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R

Re

T
 B
 mf
lmf
u
pc
oฃ
Pn
*.:
expansion ratio, Lf/L
             Gd
Reynolds No. —*-
mf
bed temperature
superficial velocity of fluidizing gas
superficial velocity of fluidizing gas  at minimum  fluidizing conditions
void fraction in fluidized bed
void fraction in fluidized bed at minimum fluidizing  conditions
fluidization efficiency (defined by Leva  (6_) )
viscosity of fluidizing gas
density of fluidizing gas
density of solid particles
bulk density of fluidized bed at minimum fluidization
emulsion-packet contact frequency (Mickley  (21))
kinematic viscosity

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                                                                                       15
renditions
ป
                                  APPENDIX II

Reference^

  1.   Agarwal,  O.P.,  and J.A.  Storrow,  "Heat Tr-ansfer in Fluidized Beds," Chem.

      {. Ind.,  321 (1951) .

  2.   Ciborowski, J.,  and  J.  Roszak,  "An Investigation of Heat Transfer Between

      a Heated  Surface and a  Fluidized  Bed," in "Hydrodynamics and Heat Trans-

      fer in  Fluidized Beds,"  S.S.  Zabrodsky, loc. cit.  pp 268-270.

  3.   Ibid.,  pp 242-243.

  4.   Drinkenburg,  A.A.M.,  N.J.J.  Huige, and K. Rietama, Proc. 3rd Internation-

      al Heat Transfer Conf.,  4_,  271, Chicago (1966).

  5.   Dow, W.M.,  and  M.  Jakob,  "Heat Transfer Between a  Vertical Tube  and a

      Fluidized Air-Solid  Flow,"  Chem.  Eng.  Progr.,  47,  637 (1951).

  6.   Leva., M. ,  M.  Weintraub  and  M. Grummer,  "Heat Transmission through Fluid-

      ized Beds of  Fine  Particles," Chem.  Eng.  Progr.,  4_5_, 563 (1949).

  7.   Levenspiel, O.,  and  J.  S. Walton, "Bed Wall  Heat Transfer in Fluidized

      Systems,"  Chem.  Eng.  Progr.  Symp. Ser., 50,  No. 9, 1, (1954).

  8.   Matsuyama,  T, Kagaku  Kogaku,  18,  406 (1954), in "Fluidization Engineer-

      ing," D.  Kunii  and O. Levenspiel, loc.  cit.  p 269.

  9.   Massimilla, L.,  S. Bracale  and A. Cabella, "Solido-Gas  Fluidizzati," in

      "Hydrodynamics  and Heat Transfer  in  Fluidized  Beds," S.  S.  Zabrodsky,

      loc. cit.  p 261.

 10.   Toomey, R., and  Johnstone H., "Heat  Transfer Between Beds of Fluidized

      Solids and  the Walls  of the  Container," Chem.  Eng. Progr.  Symp.  Ser. 49 ,

      No. 5, 51  (1953).

 11.   Van Heerden,  C., A.P. Nobel,  and  D.  Van Krevelen,  "Mechanism of  Heat

      Transfer  in Fluidized Beds,"  Ind. Eng.  Chem.,  45,  1237  (1953).

-------
(' I
                                                                                     16 ;



           12.   Ainshtein,  V.G.,  "An  Investigation, of Heat Transfer Processes Between

                Fluidized Beds  and  Single  Tubes Submerged in the Beds," in  "Hydrodynamic

                and  Heat Transfer in  Fluidized Beds," S.S. Zabrodsky, Ic5c_.  cit. pp 270-

                272.                                                                     i"

           13.   Baerg, A.,  J. Klassen,  and P.E. Gishler, "Heat Transfer in  a Fluidized
                                                                                        \
                Solids Bed," CajT^^J^Re^earch^^ F2_8, 287 (1950).                        |

           14.   Bondareva,  A.K.,  "Measurement of the Thermal Conductivity of Suspended  *

                Beds," from S.S. Zabrodsky,  loc.  cit. p 267.

           15.   Campbell, J.R., and F.  Rumford, "The Influence of Solid Properties on

                Heat Transfer from  a  Fluidized Solid Medium," J. Soc. Chem. Ind. ^ 6_9_, 37ซ
                                                                                        I
                (1950).                                                                  |
                                                                                        s
           16.   Chechetkin, A.V., "High Temperature and Heat Transfer Agents," from
                                                                                        0
                S.S. Zabrodsky, loc.  cit.  p  262.                                         ]
                                                                                        <
           17.   Ernst, R. ,  "Heat Transfer  Mechanism in Fluidized Beds," Chem.  Ing. Tcchr.,

                3_1, No. 3,  166  (1959) .                                                   j

           18.   Highley, J., 'Heat  Transfer  Between Horizontal Tubes and a Fluidized Bed

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                Combustion  Section  Report  No. _20^ (1969) .

           19.   Jacob, A.,  G.L. Osberg,  "Effect of  Gas Thermal Conductivity on Local Heat

                Transfer in Fluidized Bed,"  Can.  J.  Chem.  Eng.,  3J[,  5 (1957).

           20.   Kharchenko, N.V., and K.E. Makhorin,  "The  Rate of Heat Transfer Between

                a Fluidized Bed and an  Immersed Body at High Temperatures," Intern.  Chem.

                Eng., 4_, 650 (1364)  .

           21.   Mickley, H.S.,  and  D.F.  Fairbanks,  "Mechanism of Heat Transfer to Fluid-

                ized Beds,1' A.I.Ch.E. J.,  I,  374  (1955).                         '

           22.   Mickley, H.S.,  D.F.  Fairbanks,  and  R.D.  Hawthorn, "Heat Transfer  Coef-

                ficients in Fluidized Beds,"  Chem.  Eng.  P rog r.  Symp ^ งe_r_ie_s_ 57 ,  32,  51

                (1961).  ,

-------
     .
Dynamic;'
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 6_9, 37]


•om


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 Coef-

32,  51

I
                                                                           17


23.  Olin, H.L., and O.C. Dean, Petrol. Eng. 25, C-23  (1953)  in  "Fluidization•

     Engineering," D. Kunii and O. Levenspiel, loc_. cit. p  268.

24.  Miller, C.O., and A.K. Logwinuk,  "Fluidization Studies of Solid  Particles1,'

     Ind. Eng. Chem. , 4_3, No. 5, 1220  (1951).

25.  Sarkits, V.B.,  "Heat Transfer from Suspended Beds of Granular Materials

     and Walls," from S.S. Zabrodsky,  log, c it. p 275.

26.  Shirai, T., and H. Yoshitome, "Heat and Mass Transfer on the Surface  of

     Solid Spheres Fixed within Fluidized Beds," Kagaku Kogaku  (English

     edition) ฃ, 162 (1966) .

27.  Varygin, N.N., and I.G.  Martyushin, "Calculation of Heat Transfer Area in

     Fluidized Bed Equipment," from S.S. Zabrodsky, loc. cit_. p  272.

28.  Vreedenburg, H., "Heat Transfer Between a Fluidized Bed and a Horizontal

     Tube," Chem. Eng.  Sci. ,  9, 52 (1958).

29.  Vreedenburg, H". , "Heat Transfer Between a Fluidized Bed and a Vertical

     Tube," Chem. Eng.  Sci.,11, 274 (1960).

30.  Ziegler, F.N., and W.T.  Brazelton, "Mechanism of Heat Transfer to a Fixed

     Surface in a Fluidized Bed," Ind. Eng. Chem. Fundamentals,  3_, 94  (1964).

31.  Petrie, J.C., W.A. Freeby and J.A. Buckham,  "In-Bed Heat Exchangers,"

     Chem. Eng. Prog.,  64, 45 (1968).

32.  Bartholomew, R.N., and D.L. Katz, "Heat Transfer from the Wall of a Tube

     to a Fluidized Bed," Chem. Eng.  Progr. Symp. Ser. 48, No. 4, 3 (1952).

33.  Brazelton, W.T., Ph.D. Thesis Northwestern University  (1951) in  "Fluid-

     ization," M. Leva, loc.  cit. p 218.

34.  Trense, R.V., "Heat Transfer in Gas-Solid Fluidized Beds," Piss. Abstrs.,

     15_, 1814 (1955) .

35.  Mickley, U.S., and C. Trilling,  "Heat Transfer Characteristics of Fluid-

     ized Beds," Ind. Eng. Chem., 4_1^,  1135 (1949).

36.  Urie, R.W., "Heat  Transmission in Fluidized Systems," M.S. Thesis, M.I.T.
     (1948).

-------
                                                                          18





37.  Wicke, E., and F. Fetting,  "Heat Transfer  in  Fluidized Beds,"  Che in.  Ing.



     Tech. , 26_, 301 (1954).    '                                               '„:

                                                                              i-

38.  Wen, C.Y., and M. Leva, "Fluidixed Bed  Heat Transfer;  A Generalized  Dens


                                                                              I
     Correlation," A.I.Ch.E. J._, 2, 482  (1956).                               I



39.  Wender, L., and G.T. Cooper,  "Heat Transfer Between  Fluidized  Solids Bed;'



     and Boundary Surfaces - Correlation of  Data,"  A.I.Ch.E.  J.,  4_,  15 (1958).<



40.  Zenz, F.A., and D.F. Othmer,  "Fluidization and Fluid-Particle  Systems,"



     Reinhold Publish. Corp., New York  (I960).



41.  Kunii, D., and O. Levenspiel, "Fluidization Engineering,"  Wiley,  New YorV



     (1969) .



42.  Zabrodsky, S.S.,  "Hydrodynamics and Heat Transfer  in Fluidized  Beds,"



     M.I.T. Press (1966).



43.  Leva, M., "Fluidization," McGraw-Hill,  New York  (1959).



44.  Botterill, J.S.,  and J.R. Williams, "The Mechanism of  Heat Transfer  to



     Fluidized Beds,"  Inst. Chem. Engrs. (London),  41,  217  (1963).



45.  Pratt, S.W.', and J. Richards, "Heat Transfer to a  Fluidized  Bed," M.S.



     Thesis, M.I.T.  (1951).



46.  Fairbanks, D.F.,  "Heat Transfer to Fluidized Beds,"  Sc.D. Thesis, M.I.T.



     (1953).



47.  Hawthorn, R.D., "Heat Transfer to Fluidized Beds," Sc.D. Thesis,  M.I.T.



     (1956) .



48.  Davidson, J.F., and D. Harrison,  "Fluidized Particles,"  Cambridge Univ.



     Press, Cambridge, England (1963).



49.  Volk,  W., A. Johnson, and H. Stotler,  "Effect  of Reactor Internals on



     Quality of Fluidization," Chem.  Eng.  Prog., 58, 44 (1962).

-------
     IS
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                                                 22
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                                                               23
                      APPENDIX HID




SUMMARY  OF THEORKTICAL  AND
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                                                                                           27
                                             APPENDIX II1C
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1 !
                                              APPENDIX  HID
                      EFFECT OF INDIVIDUAL BCD PROPERTIES  ON HEAT TRANSFER COEFFICIENT
                                                                                               28
                        VALUES LISTED ARE  EXPONENTS TO  WHICH EACH PROPERTY  IS RAISED

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-------
                                                              29
         "  exp

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 BTU

hr ft2ฐF
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                  APPENDIX TSL  GRAPH  1

                  COMPARISON  OF MEASURED AND  CALCULATED

                  HEAT -TRANSFER  COEFFICIENTS .

-------
30
   "exp
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hr ft2ฐF
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75
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                                 DATA SOURCES
                                 • FAIRBANKS
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          APPENDIX  EZ1   GRAPH   2
          COMPARISON OF MEASURED AND  CALCULATED
          HEAT  TRANSFER  COEFFICIENTS

-------
                                          31
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internal tube diameter
APPENDIX  W.  GRAPH 3
DATA OF BAERG (13)
INTERNAL VERTICAL  HEATED  TUBE   dt  = 1.25'

-------
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       APPENDIX  IZ   GRAPH 4
       DATA OF VREEDENBURG (28)
       SINGLE  HORIZONTAL TUBES  dt =0.66"and 1.35

-------
                                  APPENDIX V

Calculation of Heat Transfer Coefficients in a Large  Diameter  Bed  Compared •,.

the Data of Highley (18)

Vessel Diameter - 3 ft.
 avg
 w-c
 w-1
u
   Average value of heat transfer coefficient  from measurements  to  ir-.-
                                                              2
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   Heat transfer coefficient calculated from the correlation of  Wendซ:
                             2
   and Cooper (3_9_) , Btu/hr-ft -ฐF.

- ' Heat transfer coefficient calculated from the correlation of  Wen ar
                       2
   Leva (3ฃ) , Btu/hr-ft -ฐF.

   Superficial gas  velocity, ft/sec.
U li 11
avg w-c
0
1
2
3
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.94
33
38
41
43
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31
30
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27
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w-1
42
64
77
86
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.6
.7

-------