US.  ENVIRONMENTAL  PROTECTION  AGENCY
                                   ounriMf\i
                             NUTRIENT TRANSPORT AND ACCOUNTABILITY
                                         IN THE
                                LOWER SUSQUEHANNA RIVER BASIN
                                      October 1974


                                     Technical Report 60
                                   Annapolis Field Office
                                        Region III
                                Environmental Protection Agency
MIDDLE ATLANTIC REGION-III  6th and Walnut Streets, Philadelphia, Pennsylvania 19106

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            EPA-903/9-74-014
                   Annapolis Field Office
                         Region III
               Environmental Protection Agency
                   SUMMARY AND CONCLUSIONS

            NUTRIENT TRANSPORT AND ACCOUNTABILITY
                           IN THE
                LOWER SUSQUEHANNA RIVER BASIN
                     Technical Report 60

                        October 1974
                        Leo J. Clark
                        Victor Guide
                     Thomas H. Pheiffer
                Annapolis Field Office Staff

Maryann L. Bonning                         Si grid R. Kayser
Tangie L. Brown                            Donald W. Lear, Jr.
Gerard W. Crutchley                        Evelyn P. McPherson
Daniel K. Donnelly                         James W. Marks
Gerard R. Donovan, Jr.                     Margaret S. Mason
Bettina B. Fletcher                        Margaret B. Munro
Margaret E. Flohr                          Marria L. O'Malley
Norman E. Fritsche                         Susan K. Smith
George H. Houghton                         Earl  C. Staton
Patricia A. Johnson                        William M.  Thomas, Jr.
Ronald Jones                               Robert L. Vallandingfiam
                     Orterio Villa, Jr,

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     This report has been reviewed by EPA and approved for
publication.   Approval does not signify that the contents
necessarily reflect the views and policies of the Environmental
Protection Agency, nor does the mention of trade names or
commercial products constitute endorsement or recommendation
for use.

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                                           ABSTRACT



                     Identification  of  the  Susquehanna  River  as  the primary


 I              contributor  of  nutrients  to the  upper Chesapeake Bay and  recognition


                of  the  need  to  develop  a  nutrient management  program for  their mutual


 •              protection,  prompted the  Annapolis  Field Office, EPA, to  conduct a


 *              one-year  comprehensive  nutrient  survey  in  the lower Susquehanna River


 ™              Basin between Northumberland,  Pa. and Conowingo, Md.  Three distinct


 •              hydrologic seasons were represented during  the study period which


                provided  the foundation for an in-depth evaluation of all water quality


                data obtained during this survey.   Its  principal  objectives were:


 A              (1) quantitative  identification  of  average  nitrogen and phosphorus


 *              loadings  and determination  of  seasonal  variations in nutrient loadings


 •              from every major  sub-basin  (2) delineation  of point source and


                non-point source  nutrient contributions to  establish effectiveness of


 jj              controllability measures  (3) seasonal mass  balance of nutrient


«                loadings  in  the main stem and  (4) determination  of the fate of nutrients


                in  impounded areas.   The  report  enumerates  the important  findings


 •T             and conclusions which evolved  during the intensive data analysis and
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interpretation and presents recommendations for future studies.


Hopefully, the material  presented in this report can assist in the


implementation of a workable nutrient management program.

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                           Introduction



     Possibly the most serious pollution problem currently plaguing


the upper Chesapeake Bay is one of progressive eutrophication

stemming from the uncontrolled discharge of nitrogen and phosphorus

in both the tidal and non-tidal areas of the major tributary

watersheds.  Consequently, during 1969 the Annapolis Field Office


(AFO) embarked on a one-year monitoring study to (1) delineate


significant nutrient inputs to the Chesapeake Bay, (2) quantify

nutrient loadings and establish their seasonal trends, and

(3) determine the relative importance of each watershed's nutrient


load in affecting current biological conditions in the Bay.  The

obvious conclusion from this study was the primary significance of


the Susquehanna River as a contributor of nitrogen and phosphorus to


the Chesapeake Bay, accounting for 50, 60 and 66 percent of the total


phosphorus, TKN and nitrate loadings, respectively, entering the Bay

on an annual basis.

     Recognizing the dramatic effect of the Susquehanna  River on the

water quality of the upper Chesapeake Bay and the need to develop a

nutrient management program for their mutual protection, AFO

initiated a comprehensive nutrient study in the lower Susquehanna


Basin between Northumberland, Pa., and Conowingo, Md.  The study


was limited to this particular area since preliminary data analysis


revealed this lower reach to be the significant nutrient contributor


to the Bay.  This twelve month study (June 1971 - May 1972), which

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 comprised weekly or bi-weekly sampling at 37 stream stations and
 monthly sampling of 25 major sewage treatment plant effluents, had
 the following principal objectives:
           a)  quantitative identification of average nitrogen and
 phosphorus loadings from every significant sub-basin in the lower
 Susquehanna,
           b)  determination of seasonal  variations in nutrient
 loadings for individual sub-basins and their dependency on stream
 flow,
           c)  delineation of point source and non-point source
 nutrient contributions and determination of typical loading rates
 from agricultural, forested and urban areas, especially the urban
 Harrisburg metro area, in order to establish the potential
 controllability of nutrients on a seasonal basis,
           d)  seasonal mass balance of nutrient loadings in the
Susquehanna River from the West Branch confluence to Conowingo, Md.,  and
           e)  determination of the fate of nutrients in impounded
areas along the lower Susquehanna River.
      This report contains an enumeration of the important findings
which evolved during the course of data analysis and interpretation.
In addition, the report contains the most important conclusions
which can be drawn from the information presented followed by a
framework of recommendations for future studies.  Graphical
supportive material is included in the Appendix.

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p                    It  should  be noted  that  Item  28 of the Summary and  Item 23 of
                 §the  Conclusion  Sections  of  the  report state the need for point source
                 control  of  phosphorus  to protect the upper Chesapeake Bay from
ft               excessive eutrophication.   Conclusion 24 questions the effectiveness
                 of nitrogen control  at point  sources in the lower Susquehanna River
•               Basin  in the absence of  an  accompanying reduction of the existing
                 nitrogen load from agricultural runoff.  These findings and conclusions
                 were  specifically developed in  AFO Technical Report 56.  Utilizing
ft               a mathematical  model and the  data  from Technical Report 60, the
                 combined impact of nutrient loadings from the Susquehanna River and
•               Baltimore,  Maryland  on the  eutrophic condition of the upper Chesapeake
^               Bay was evaluated.   Technical Report 56, "Nutrient Enrichment and
W               Control  Requirements in  the Upper  Chesapeake Bay, Summary and
ft               Conclusions", should be  read  jointly with this report.
                     Technical  Report  56 concluded that phosphorus could be made the
•               rate  limiting nutrient in the upper Chesapeake Bay to control
A               eutrophication  or, specifically, the level of algal standing crop as
P               measured by chlorophyll  a_.  For Susquehanna River flows less than or
A               equal  to 30,000 cubic  feet  per  second (cfs), a reduction of 70 percent
                 in the existing point  source  phosphorus load from both the lower
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Susquehanna River and the Baltimore Metropolitan Area is required.   At
higher river flows the phosphorus reduction at point sources increases
substantially.   Point source control of nitrogen may not be a viable
alternative to phosphorus control during any flow condition at this
time without a substantial reduction in non-point sources of nitrogen.

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                     The  Commonwealth  of Pennsylvania  has  an  adopted  phosphorus
g              policy for the  lower Susquehanna  Basin which  requires  at  least 80
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percent removal of phosphorus from all new or modified wastewater


treatment facilities.  Maryland places phosphorus limitations on


wastewater treatment facilities on a case by case basis in accordance


with receiving water characteristics.  Even with the introduction of


point source phosphorus control in Maryland and Pennsylvania, the


impact from expected population growth in the study area will eventually
™              require serious  consideration  of non-point  source  control  of  nutrients
as a supplemental measure to high degrees of phosphorus and nitrogen

removal at point sources.  Technological  and cost considerations of

phosphorus removal and the relative magnitude of non-point source

nitrogen loads may make this consideration imperative.   The delineation

and quantification of point source and non-point source nutrient

contributions for the lower Susquehanna Basin set forth in the
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                report  is  substantial.   It  is  hoped  that  management  agencies  will
utilize this body of data and expand upon it where necessary to develop

land-use management programs in conjunction with point source control


of nutrients to allow for the accomodation of future population

growth while at the same time maintaining permissable nutrient levels

in the lower Susquehanna Basin and the upper Chesapeake Bay.

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                                               Summary
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           1)  The Susquehanna River between Sunbury, Pennsylvania
and Conowingo, Maryland, drains an area of approximately 9,000
square miles in south central  Pennsylvania and contains a resident
population (1970 census) of approximately 875,000 (25% of the Basin's
total population).
           2)  In the lower Susquehanna River basin approximately 5%,
40%, 50% and 5% represents urban, agricultural, forested and other
areas, respectively.
           3)  Daily flows were monitored at Conowingo Dam during the
entire survey and ranged from about 4,200 cfs (Aug. 1971) to 319,000
cfs (Mar. 1972).
           4)  For purposes of data evaluation, the study period was
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                separated  into  three  distinct seasons, each characterized by a
different but relatively uniform flow condition.  The mean flows and
mean water temperatures for each season are shown in the table below:

      Period
 -
 *             June  - Oct.,  1971
Mean Flow
(cfs x 1000's)
11
37
88
Mean Water
Temperature
°C
23.5
3.6
12.5
Nov., 1971 - Feb., 1972
March - May, 1972

           5)  The average seasonal  concentration of nutrients
measured near the mouths of the fourteen major tributaries of the
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                lower  Susquehanna  River are presented as follows:
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                     The data  shown  in the preceeding tables indicate that Shamokin,
I               Conoy,  Codorus  and Conestoga Creeks had the highest phosphorus
                 concentrations  during each season.  During low  flow periods these
                 concentrations  exceeded  1.0 mg/1 .  Both total and inorganic
_               phosphorus  concentrations usually decreased when stream flows
™               increased,  indicating that excessive runoff was having a diluting
1|               effect  on point source discharges.
                     Maximum TKN  concentrations  (1.0 - 3.0 mg/1) were also measured
                in Shamokin, Conoy, Codorus and Conestoga Creeks during the low
—              flow season and probably reflected the sizeable waste loadings

™              received by these streams.  In general, TKN behaved similar to

•              phosphorus in that higher stream flows resulted in further dilution.

                     Oxidized inorganic nitrogen (N02 + N03) appeared to be the

•              most prevalent nutrient monitored.  Because of the importance of

                agricultural runoff, most streams did not experience the diluting

™              effect observed for other forms of nutrients during high flow

•              periods.  Pequea Creek, a predominately agricultural watershed

                having no significant point source discharges exhibited a high

•              NOp + NOg concentration but a relatively low TKN concentration for
                each season.  Stony Creek, a predominately forested watershed, on
•              the other hand, contained relatively low nutrient concentrations

•              regardless of season.

                     Except for Shamokin Creek, a highly acidic stream where

•              nitrification is probably inhibited, ammonia levels were quite low,

                especially during the warmer periods when the nitrification reaction

•
                 should  be most  pronounced.
 I

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I
I
                         6)  The average seasonal nutrient concentrations measured
I             at the ten main stem Susquehanna stations are presented in the tables
               on the following pages.
|                  Since the volume of flow in the Susquehanna is extremely
M             large in comparison to the tributary flows, the river was not very
               responsive to a given nutrient input in terms of a concentration
•             increase.  The considerable amount of dilution present is illustrated
               in the comparatively low phosphorus and nitrogen concentrations
l|             shown in the following tables.  Phosphorus concentrations were
M             generally higher during the low flow periods but did not exceed 0.3
*             mg/1.  Moreover, concentrations were consistently greater in the reach
4             from Harrisburg to Conowingo than they were in the upper reach,
               probably the result of several large tributary inputs.  The fairly high
•             phosphorus concentrations observed in the vicinity of Harrisburg during
               the high flow period may be partially due to combined sewer overflows.
               It is also important to recognize the dramatic decrease in phosphorus
•             during lower flow periods in the area of Conowingo and to a lesser extent
               at Safe Harbor.  These impoundments appeared to represent a significant
•             "sink" for phosphorus when detention times were long.
                    The maximum TKN and N09 + NOo concentrations (0.82 mg/1 and
•                                        2
•             1.3 mg/1, respectively) were measured in the Susquehanna River between
•             Safe Harbor and Conowingo Dams.  While TKN was always greatest during
               low flow periods because of minimal dilution of tributary inflows,
I             NOo + NOg levels were greater during the higher flow-lower temperature
               periods.  This  latter  relationship  reflected  the effects of runoff
I

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™               from agricultural  land and reduced  biological  utilization  rates.
•               The Susquehanna River water appeared  to  be  highly  nitrified  during
                 high temperature periods  as evidenced by the  extremely  low NH~
•               concentrations.  During low temperature  periods, however,  NFL was
                 generally more abundant because  of  reduced  nitrification and
™               biological  utilization rates.
•                         7)   In an  attempt to establish  statistically  valid relation-
                 ships  between  both nutrient concentrations  and nutrient loadings
•               versus  stream  flow,  a series of  regression  analyses utilizing the
                 appropriate  sampling data  were performed  at each station and for
•               each parameter.   These regression analyses  were made  using both
•               linear and  log transforms  with the  latter yielding the  best  correlation,
                      A summary of  the regression data for nutrient concentrations
•               versus  stream  flow is presented  in  the following table.  As  can be
                 seen,  numerous regressions  resulted in poor correlation based upon
•               non-significant "t"  statistics at the 5  percent level.  However,
•               several  interesting  conclusions  can be drawn  from  the remaining
                 data.   In the  case of total  phosphorus,  negative slopes ranging
•               from about 0.2 to  0.6 were  detected excepting  for  Pequea Creek.
                 This would  corroborate the  previous discussion wherein  a diluting
I               effect was  shown to  occur  at higher flow  conditions.  Moreover,
•               these  negative slopes would imply that the  majority of  phosphorus
                 was  contributed by wastewater discharges.   Pequea  Creek, on  the
•               other hand, had  a  large positive slope (0.97)  indicating that land
 I
 I
                runoff may be the primary source of phosphorus in that watershed.

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                  The relatively large negative slopes  of the  TKN  regression
•           equations indicated that Shamokin, Codorus and  Conestoga  Creeks  all
             received major TKN loads from wastewater discharges.   Shamokin
9           Creek, an acid stream receiving a considerable  quantity of  untreated
•           sewage, exhibited a particularly large  negative slope  (-0.92).   At
             the other end of the spectrum were streams having relatively  minor
•           point source contributions,  i.e. Pequea and Yellow Breeches Creeks,
             which showed highly positive slopes (0.78  and 0.67).   The remainder
             of the streams appeared to be influenced by a combination of  point
•           and non-point sources insofar as TKN  was concerned.
                  All of the sub-basin sampling stations where statistical
•           validity was realized had a  positive  relationship between
             N00 + NO, and stream flow.  The slopes  varied from about  0.2  to  over
               12     3
             1.0.  The consistency of this relationship indicated  the  significant
u           overall effect of agricultural  runoff as a contributor of nitrate
             nitrogen especially during periods of intense runoff.
•                     8)  The main stem  Susquehanna River sampling results should
             theoretically reflect the accumulative  effect of  all  tributary
|           inputs.  Regression data obtained for a nutrient  concentration versus
•           stream flow relationship for the Susquehanna, which are summarized
             in the following table, basically substantiated this  contention.
 flj           In the case of phosphorus and TKN, the  slope terms were very
             similar for every station where statistically valid data  were
I
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•             realized.  The  range  for  phosphorus  (-0.20  to +0.12) was  somewhat
•             lower than the  values  recorded  for the  tributary  stations  since the
               effects  of land runoff, including drainage  along  the river itself,
I             were  more pronounced  in comparison to point  source  discharges.  A
               similar  situation  was  indicated by the  generally  greater  positive
•             relationship  between  nitrate  nitrogen and stream  flow  for  the
•             Susquehanna River.  The range in slopes  for  TKN  (-0.32  to  -0.05)
               suggested a net diluting  effect when compared to  all of the tributary
I             data  presented  previously.  The negative relationships  for
               phosphorus and  TKN concentrations versus stream flow and  the
I             positive relationships for  nitrate nitrogen  versus  stream  flow
•             determined for  the main stem  Susquehanna River were essentially in
               agreement with  those  reported for the Potomac River.*
I                      9)  Regression  analyses proved much more  statistically
               reliable when nutrient loadings and  stream flow relationships were
W             investigated.   The average  nutrient  loadings computed  for  the various
•j             tributaries to  the Susquehanna  River from regression data  are presented
               in  the following tables for each of  the  three hydrologic  seasons.   It
•             should be noted that  average  stream  flows for the entire  season were
               used,  when available,  rather  than flows  corresponding  to  individual
|             sampling days.
•                  The watersheds contributing the greatest phosphorus  loads
               regardless of season  were Conestoga  and  Codorus Creeks  and the Juniata
•             River.   The major  nitrogen  contributing watersheds  were Conestoga and
               Swatara  Creeks  and the Juniata  River.  The Juniata  River was a
*             * Nutrients in  the Upper  Potomac River  Basin, Jaworski , CTSL Technical
                 Report 15,  August,  1969.

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I
I
_
™
                                                                             19
             significant contributor of nutrients  due to its  relatively  large
             flow whereas the other streams  contained considerably  greater
I           nutrient concentrations because of sizeable inputs  from wastewater
             effluents and land runoff.
•                    10)  Average seasonal  nutrient loadings  computed  at each  of
•           the main stem Susquehanna River stations from regression analysis  and
             average stream flow data are shown in the following tables.   A
•           graphical mass balance analysis of these loadings will  be  presented
             and discussed in a subsequent section of this report.
I                Both nitrogen and phosphorus  loadings  throughout  the  lower
•           Susquehanna River varied drastically from one season to the  next
             because of differences in stream flow.   The loadings also  showed a
•           gradual but steady increase in  the downstream direction which reflected
             substantial inputs from several tributary watersheds.   It  is important
I           to note that generally about 30-40 percent of the total  phosphorus
M           load was inorganic, regardless  of  spatial  or temporal  position.  In-
             organic nitrogen accounted  for  about 50, 65 and 80  percent of the
•           total nitrogen load during  low, mean and high flow  periods,
             respectively.  This upward  shift was partly due to  relatively greater
P           increases in nitrate rather than organic nitrogen loadings from major
             tributary watersheds during periods of excessive  runoff.
                  The nitrogen-phosphorus ratio (by atoms) throughout the lower
B           Susquehanna River averaged  about 34:1 during the  summer season, 46:1
             in the winter and 43:1 in the spring.  These values are considerably
•           greater than the elemental  ratios  comprising algal  cellular  material
_           (15-20:1) reported in the literature.

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•                    11)  The following table shows the average daily phosphorus
             and nitrogen loads currently discharged by each of the major wastewater
I           treatment facilities in the lower Susquehanna Basin.  Also shown are
             the average per capita loadings based upon the present population
|           served.  The three areas  responsible for approximately one half of the
_           total measured phosphorus and nitrogen load from municipal point source
™           discharges were Harrisburg, Lancaster and York.
•                Utilizing the average per capita loadings (0.024 Ibs/day TPO, and
             0.018 Ibs/day TKN) and the entire lower basin population served by
              sewerage  facilities  (850,000), the estimated total phosphorus and

 _            nitrogen  contributions from wastewater effluents were computed to be

 '            20,400  Ibs/day and 15,300 Ibs/day, respectively.

 •                     12)  The average daily phosphorus and nitrogen loadings

              discharged by the major water using industries in the lower Susquehanna

 •            River Basin are presented following the municipal wastewater table.

              These data were contained in the industries' NPDES permit applications

 ^            and  reflect the best currently available information on loading rates.

 •            While the list is probably not complete, it is believed that the

              industries shown in the following table constitute the bulk of the

 •            industrial nutrient contribution based upon a comprehensive compilation

              of industrial discharges throughout the Susquehanna Basin.

 •                As can be seen, the total phosphorus and nitrogen loads from

 •            industrial point-source discharges were estimated to be 1,355 Ibs/day

              and  4,800 Ibs/day, respectively.  Of the total nitrogen load

 •            approximately 40 percent was in the form of TKN and 80 percent was as

              inorganic nitrogen (NH3 + N0? + NO-J.

-------

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                        13)  To assist in the annual nutrient budget evaluation, it


 •             was necessary to ascertain a breakdown of land usage for the entire


               lower Basin.  Presented in the table on the following page is a


 |             delineation of  land  usage for the various tributary watersheds of the


               Susquehanna River for the three major land use categories, namely


               agricultural  (cropland and pasture), forested and urban.


 V                      14)  In order to estimate typical nutrient yields from the


               two major  land  use areas within the Susquehanna River Basin  (i.e.

 I'
               agricultural  and forested), analyses of survey data from


 _             representative  watersheds were performed.  Using the Pequea  Creek water-


 *             shed as primarily agricultural and the Stony Creek watershed as


 tf             forested,  the effect of land use on both nutrient concentrations  and


               loadings in these surface waters could be evaluated.  These  data were


               then extrapolated to develop estimates of the nitrogen and phosphorus


               yields  (lbs/day/mi2) for application to other agricultural and


               forested areas  within the Susquehanna Basin.


 •                  Total phosphorus, total Kjeldahl nitrogen and nitrite-nitrate

               nitrogen contributions measured in these selected watersheds during each

 •             season  are presented in the following tables.  As can be  seen, a


               considerable  difference existed between the concentration and loading


 •             rates of all  three parameters.  Excepting for TKN, the agricultural


 •             runoff  rates  were at least an order of magnitude greater  than


               corresponding rates  for forested areas.  The extremely high  N0? + NCU


 •             concentrations  (4.0  - 5.7 mg/1) characterizing the Pequea Creek water-


               shed revealed the high mobility of the N0q ion, especially during

 I
 w             periods having  excessive runoff.
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                                                                                35
         15)  The City of Harrisburg has been reported to have over
20 combined sewer outfalls which discharge large quantities of sanitary
waste and street surface runoff directly to the Susquehanna River
during periods of heavy rainfall.  The effects of these discharges
coupled with other urban runoff from the Harrisburg metro area were
estimated from an examination of the measured nutrient loads in the
Susquehanna River at both the Route 15 and the 1-83 Bridge stations.
•
             As will be shown in a later section of this report (mass balance
              analysis),  considerable  increases  in  the  total  phosphorus and
              nitrogen  loads were  observed  in  the vicinity  of Harrisburg during the
              high  flow season.  Since  the  Susquehanna  River  received no major
              wastewater effluents  from the  confluence  of Conodoguinet Creek to the
             1-83 Bridge it was assumed that these differences in loading could be
              attributable  to  the  collective  effects of  urban  runoff  (point source
              and  non-point source).
                  Allowing for the possibility of nutrient re-introduction into
             the water column through the scouring of bottom sediment and the
             innundation of shoreline weeds and other sources which are apparent
             during the high flow periods, it appeared that approximately
             6,000 Ibs/day of total phosphorus and 14,000 Ibs/day of total nitrogen
             (approximately 2/3 of which was T.KN) were contributed by the entire
             Harrisburg urban area during the maximum flow period of March-May 1972.
             These figures completely overshadowed the average contributions from
             the area's wastewater facilities.

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                 During the mean flow period (Nov.  1971  - Feb.  1972)  respective
•          phosphorus and nitrogen contributions from the Harrisburg metro area
            exclusive of wastewater effluents were  estimated to be 800 Ibs/day
9          and 3,700 Ibs/day (approximately 2/3 of which was TKN).   During the
A          low flow period no measurable contribution was detected.
                     16)  In view of the fact that  nutrient loads in  the
•          Susquehanna River above and below the Harrisburg area indicated an
            extremely large urban input, the magnitude of which may be somewhat
•          questionable and probably not applicable to other urban areas in the
jg          Basin, the decision was made to utilize relevant literature material
            to provide independent estimates of typical  area! nutrient loading
•          rates exclusive of untreated sanitary sewage contributions.  These
            estimated rates were intended to serve  as a basis for developing a
            total urban effect on the nutrient balance in the lower Susquehanna
«          Basin.
                 A summary of the relevant literature data which was  used as
I          a basis for estimating the nutrient loading rates for the urban and
            suburban portions of the Susquehanna River Basin are presented in
            the following table.
I
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—                     17)   Based  on  a  review  of the  aforementioned  nutrient
•            data  summary  for  storm  water,  the  decision  was  made  to use  the
              following  loading rates applicable to city  and  suburban areas of
•            the Susquehanna Basin for the  high flow season.   It  may be  noted
              that  maximum  importance was  attached to the recent estimates of
•            urban contributions  such  as  the  data presented  in EPA's "Water
•            Pollution  Aspects of Street  Surface Contaminants", and AFO's
              Technical  Report  No. 35.
I

B                                 Areal  Nutrient Loads
_                              Urban  Runoff  (Storm  Water)
*                                      (Ibs/mi2/day)

1                              T.POu            TKN          N0.3
•            City                 20               30          15
              Suburbs              10               15          10


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40
Utilizing the above nutrient loading rates for the major
cities and suburban areas of the lower Susquehanna Basin, the
total non-point source urban runoff nutrient contributions to the
Susquehanna River for the high flow season were determined and
are contained in the table below:

Urban Runoff Contributions
Lower Susquehanna River Basin
(High Flow Season: Mar. 1972 - May 1972)

Urban
Location Land T.PO. TKN N02+N03
Area
(mi2) Ib/mi2/day Ib/day Ib/mi2/day Ib/day Ib/mi2/day
Harrisburg 7.6 20 152 30 228 15
Lancaster 7.2 20 144 30 216 15

Lebanon 4.6 20 92 30 138 15
York 5.3 20 106 30 159 15
Urban Area
exclusive
of Major
Cities 425.3 10 4253 15 6380 10


Total
Urban
Area 450 4750 7120
Applying the measured percentage increase in phosphorus and

nitrogen urban loadings between the Rt. 15 and Rt. 83 Bridge stations
during the middle and high flow periods (see statement #15), an
















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41

estimated urban runoff nutrient contribution for the middle flow
period was determined.
The non-point source urban nutrient loadings (Ibs/day) and
average urban nutrient loading rates (Ibs/mi2/day) for the lower
Susquehanna River Basin during the middle flow season are presented

as follows:
Urban Runoff Contributions
Lower Susquehanna River Basin
(Middle Flow Period: November 1971 - February 1972)
Urban
Location Land Area T.P04 TKN N02 +
mi2 lb/day/mi2 Ib/day lb/day/mi2 Ib/day lb/day/mi2

Harrisburg 7.6 2.6 20 7.8 60 3.9
Lancaster 7.2 2.6 19 7.8 56 3.9
Lebanon 4.6 2.6 12 7.8 36 3.9
York 5.3 2.6 14 7.8 41 3.9
Urban Areas
exclusive
of Major
Cities 425.3 1.3 553 3.9 1659 2.6

Total 450 608 1852
It was assumed that urban runoff contributions for the low flow
season were negligible and consequently were not considered in the
mass balance analyses.















N03
Ib/day

30
28
18
21



1106

1203






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                                                                                42

*                      18)  Utilizing the nutrient loading rates for urban runoff
flj             presented in statement 16 and typical population densities for
               large metropolitan areas in the Susquehanna Basin, i.e. Harrisburg,
|             York and Lancaster, as well as outlying suburban areas (see table
H             in Appendix), an attempt was made to estimate total nitrogen and
™             phosphorus contributions assuming various percentages of sanitary
I             sewage overflows.  The graphs in the Appendix depict these
               contributions which should be applicable to a variety of situations
J             where combined sewer overflows are a problem.  The component
_             representing sanitary sewage  (see  table  below) was derived from  the
™             per capita loading rates presented in statement 11.
I                                   Areal Nutrient Loads
™                                      Sanitary Sewage
•                                       (Ibs/mi2/day)


               City                225             162               0
|             Suburbs              75              54               0
«                  Unfortunately, the actual quantities of untreated sanitary
*             sewage which are bypassed during different storm intensities have
•             not been defined for either Harrisburg, York or Lancaster.  However,
               based upon the measured increased in nitrogen and phosphorus loadings
p             in the Susquehanna River at Harrisburg, it would appear that a
«             relatively large fraction of the wastewater generated in the area is
*             transported through the combined sewer system, especially during the
M             high flow season.

I
T.P04            TKN

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I

                        19)  Applying the nutrient loading rates developed in
•             statement #14 for agricultural and forested land to the total
                                    22
               agricultural (3600 mi ) and forested (4500 mi ) areas of the lower
|             Susquehanna River Basin, relative contributions of T.PO., TKN and
               |N09 + N07 in pounds per day were determined.  Inclusion of the total
                 2     6
               urban nutrient contributions as developed in statement #17 results
fl             in the following tables which show the estimated seasonal nutrient
               loadings in the Susquehanna River Basin for every major land-use
J§             category.
                    Although the total forested area exceeds the agricultural area
               in the Basin, the latter represented the principal land use
•             contributor of T.PO., TKN and NO., (especially during the high flow
               season).  In addition, the urban contribution of nutrients is
£             significant during the high flow season in comparison with other
—             land uses even though the urban area comprises only about 5% of the
™             entire basin.
•                  The key non-point source nutrient input to the lower
               Susquehanna River Basin is definitely from agricultural runoff with
•             significant periodic augmentation by urban stormwater runoff and
^             combined sewer overflows from the major metropolitan areas.


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                                                                                47
I                      20)  The average seasonal nutrient loadings attributed to
_             land runoff (non-point sources) and the average annual nutrient
•             loadings attributed to municipal  and industrial wastewater
               discharges  (point sources) are summarized as follows:
I
                                         NUTRIENT LOADINGS
I                                              IN THE
                                    LOWER SUSQUEHANNA RIVER BASIN
I
I
             Point Source*  ,  Non_Point source Contributions ,  Total (Point + Non-Point Sources
             Contributions
             (Municipal     ; -
  Parameter  Wastewater &    June 1971  Nov. 1971  Mar. 1971   June 1971   Nov. 1971   Mar.  1972
             Industrial         to         to         to          to         to         to
             Discharges)     Oct. 1971  Feb. 1972  May 1972    Oct. 1971   Feb. 1972   May 1972
I             Ibs/day      j
                            i
 - » -
  IT.POij as
     PO^         21,800         8,400    20,000      31,300     30,000      42,000     53,000

JTKN as N       17,400        14,000    35,000      54,000     31,500      53,500     71,500

     as N        20,100       106,000   198,000     264,000    126,000     218,000    284,000
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                * Average  annual  load  applicable  to  each  season
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                                                                   48
            a)  Of tKe total phosphorus and nitrogen loadings from
   the  lower Susquehanna River Basin the percentages attributable
   to point source and non-point source discharges are as follows:
1
Parameter

June 1971 - Oct. 1971
; Point Source Source"1

Nov. 1971 - Feb. 19
Point Source N°^

72 JMar. 1972 - May 1972
^nt:! Point Source |N^nt
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TKN as N

TN as N
PO
                         72
55
            16
                                      28
45
                                      84
                          52
                                      33
                          48
67
                                       91
            41
                                                                            24
59

76

93
       As can be seen, non-point source contributions of T.P04 and
  TKN predominate when flows increase.  Total  nitrogen contributions
  from non-point sources are most significant in every season.  These
  differences in percentage signify the increased importance of the
  collective load from non-point sources when runoff rates are high.
       During the high flow period (March - May 1972) approximately
  93 percent of the estimated 284,000 Ibs/day of total nitrogen
  (N02 + N03 and TKN) entering the surface waters of the lower basin
  was from land runoff (non-point sources) with the remaining 7 percent
  from municipal wastewater and industrial discharges (point sources).

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                                                                                  49
•
•
                  Of  the  264,000  Ibs/day of  total nitrogen from land runoff,
                  approximately 229,000 Ibs/day, or 87%, was from agricultural land
                  areas which  comprise only  42% of the total drainage area in the
I                lower basin.
                           b)  The average annual yield, Ibs/day/sq. mile, for
                 each season based on 8,550 square miles in the lower Susquehanna
                 River Basin (3600 mi2 - agriculture, 4500 mi2 - forest and 450 mi2
B               urban) is as follows:

I

m                                              Average Annual Nutrient Yield
                                                 (Point + Non-Point Sources)
•                                                    Ibs/day/sq.  mile
            Parameter         '   June - Oct. 1971 ;Nov. 1971  - Feb.  1972 !Mar.  1972 - May 1972
            T.PO,, as P04               3.5        |          4.9                    6.2

            TKN as N                   3.7                  6.3         :           8.4

            N02N03 as N               11.1                 19.3                   24.9
            TN as N                   14.7                 25.5                   33.2
I
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•                    Thus, the average annual  yield was directly related to the
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                 runoff rates.

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                         21)   An attempt was made to mass  balance the  average
I              seasonal  phosphorus and nitrogen loads (TPO.,  TKN and  NCL+NO.,)
                in each of the tributary basins.  The method employed  for this
H              analysis  was  to compare measured loads with expected loads in
                accordance with the following equation (Total  Phosphorus):
                                                                                50
 I
                          Pt = Pw * Pa * Pf + Pu t Ps
                     Where:
                          P.  = total  measured phosphorus in watershed
                          P  = phosphorus in wastewater discharges
                          P  = phosphorus from agricultural land
                           a
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                          Pf  =  phosphorus  from  forested  land
•                        P   =  phosphorus  from  urban  runoff
                          P   =  phosphorus  lost  or  released in  the  stream channel
I                             through  biological  utilization,  deposition, scouring, etc,
                     Of  particular  importance in this  analysis  is  the magnitude and
I              sign  of  the P  term.  The  following tables, which  delineate the
_              various  components  of the  mass  balance equations,  permit several
™              conclusions to  be drawn regarding  P   (or TKN   and  NO  depending on
                                                  j        o       o
                the parameter).
                     The  negative signs shown for  most of the  P terms, regardless
•              of flow,  indicate that  phosphorus  was  being retained in the stream
                channels,  bound there by sediments and/or aquatic  plants.  The
•              apparent  loss of nitrogen  fractions which prevailed during the low
•              flow  period might be temporary, however, as indicated by the
                increased  number of positive TKN   and  NO terms during flood flow
I

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51
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               conditions when  a  considerable  tonnage  of  sediment  is  known  to  be
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               greatly  during periods of  high  streamflow  and  extensive scouring
 •             within these tributary basins may  be due to the  high solubility of
               nitrogen  - especially the  nitrate  form.
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                           22)   A seasonal mass balance analysis for the main stem
 •               Susquehanna River between Northumberland, Pa., and Conowingo Dam,
 •               Md. was performed based upon all of the regression data previously
                  presented.  The graphs in the Appendix vividly depict the relative
 •               effects of each tributary's load and the Harrisburg metro area on
                  the phosphorus and nitrogen balances in the river.  In addition,
                  changes in mass between tributary confluences resulting from
 m               various physical, chemical and biological reactions occurring
                  within the stream channel are illustrated.   The following
 •                observations are noteworthy:
                            a)  The impoundments along the lower Susquehanna,
                  especially Conowingo Dam, had a profound effect on the phosphorus
 M                load in the river during the low flow periods.  As can be seen,
                  the load decreased from about 17,000 Ibs/day to 9,000 Ibs/day
                  between Columbia and Conowingo.  During high flow-low temperature
                  periods this decrease diminished because of the reduced rates of
                  biological utilization and shorter retention times in the impoundments,
                            §b)  During the high flow period a considerable increase
                  in phosphorus (20,000 Ibs/day) was detected between Penns Creek
V                and the Juniata River.  Since this area is  primarily undeveloped
                  with the total phosphorus contribution from existing land usage
                  estimated to be less than 2,000 Ibs/day, it was assumed that scouring
                  of the bottom sediment and inundation of shoreline marsh and weeds
                  played an important role in the phosphorus  balance.  The Susquehanna
                  channel is very unique in that its width undergoes a much greater
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                                                                                62
                increase than its depth when flows  rise.   It is  also a  known  fact
                that aquatic weeds and other sources of nutrients  are prevalent
                along the river's shore.
•                   Allowing for contributions from land runoff,  it was  estimated
                that about 500 Ibs/day/mile of total phosphorus  (as  PO.)  was
J              introduced into this reach of the Susquehanna River  during the
•              maximum flow period.  During the mean flow period  (Nov.,  1971  -
                Feb., 1972)  this overall  scouring rate was computed  to  be
•              approximately 70 Ibs/day/mile.
                          c)  A comparison of wastewater effluents and  other  urban
9              contributions of phosphorus in the  Harrisburg metro  area  revealed
•              the significance of the sewage treatment plants  during  low-flow
                periods and  the over-shadowing of this load by non-point  source
•              loads  during high  flow  periods.
                          d)  Total nitrogen behaved much more conservatively  in
y              the Susquehanna River than phosphorus, particularly  in  the area
                §of major impoundments.   While the phosphorus load  was reduced
                radically through the impoundments, nitrogen remained essentially
V              unchanged regardless of flow.
                          e)  The relative importance of point source and non-
P              point source contributions of total nitrogen from  the Harrisburg
                §area for various flow conditions closely paralleled  the findings
                presented in the above statement for phosphorus.
M                       f)   Due  to excessive stratification  it was  not possible
                to adequately balance the summation of the North  Branch and West
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 •                                                                                63

 ™               Branch nitrogen load with the measured load at Sunbury.  This
 •               problem became especially acute during the high flow period when
                 about 25,000  Ibs/day of TKN could not be accounted f0r\
 I                         g)  The effects of scouring and inundation of shoreline
                 vegetation were not restricted to phosphorus.  A review of the
 •               nitrogen data between Penns Creek and the Juniata River indicated
 •               a significant increase in load during high flow periods (60,000
                 Ibs/day) which corresponded closely to the phosphorus profile and
 •               which could not be attributable to normal runoff from the area.
                 Deducting the appropriate agricultural and forested runoff loads
 m               from this observed increase yielded a scouring rate of 1,200
 •               Ibs/day/mile.  A rate of about 100 Ibs/day/mile was computed for
                 the mean flow condition.  During low flow - high temperature periods
 •               both nitrogen and phosphorus loadings were reduced in this stream
                 reach probably because of a physical deposition process.
 |                         h)  The mass balance analysis of the nitrogen fractions
 H               (TKN and NO.,) generally corroborated the pertinent findings for
                 total nitrogen.  During the low flow period the ratio of TKN to NO.,
 IT               varied from about 2:1 in the extreme upper reach of the Susquehanna
                 River to about 1:1 near Conowingo.  This increased abundance of nitrate
£               nitrogen may be partly due to nitrification and, more importantly,
I                 to the relatively greater nitrate loadings contributed by the
                 various sub-basins.  A similar pattern was evidenced during the
I               mean flow condition when nitrification was minimal.
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 *                                                                                65

 I
                  transported by the Susquehanna River, it has been estimated that
 P                only about 2 million tons actually enters the Chesapeake Bay
 _                because much sediment is trapped behind the power dams along the
 *                lower Susquehanna.
 •                         25)   A summary of annual sediment yields and computed
                  nutrient yields for a comparable time period are presented in the
 •                following table for eight stations throughout the lower
                  Susquehanna River Basin.  Except for Conestoga Creek, the data
 •                revealed a definite relationship between the tons per square mile
 •                of sediment yield and the phosphorus yield (lbs/mi2)  on an annual
                  basis.  The annual TKN yield also appeared to be strongly influenced
 •                by sediment load.  The leaching and general mobility  characteristics
                  of the NCu ion in soil are such that a reliable correlation between
 I
 V                sediment and NCL yields could not be made with existing data.

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67

26) Regression analyses performed separately with 1969
(Chesapeake Bay Nutrient Input Study, TR #47) and
nitrogen and phosphorus data at the Conowingo Dam
distinct increases in loading for both parameters

year period. A comparison of these Susquehanna 1
follows:
Flow Total Phosphorus
(cfs) (Ibs/day)
1969 1971
10,000 6,500 8,500 75
50,000 60,000 75,000 370
100,000 150,000 190,000 750

27) The data presented in the following
1971 total
station revealed
during the two

oadings is as

Total Nitrogen
(Ibs/day)
1969 1971
,000 82,000
,000 420,000
,000 850,000

table, which were
derived from a mass balance analysis, depict the effects of
different reductions at all continuous point source discharges on


the river loadings at Conowingo Dam and reveal the extent of
nitrogen and phosphorus controllability during di
and flow conditions.





fferent seasons








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                                                                                 64
                           i)  As  the  flows  increased,  differences in the TKN and
                 NCL  loadings  became less  pronounced.   Moreover, at times of excessive
                 stream  flow these loadings  approached  their maximum level much
                 farther upstream.
                          23)  The effects of  sediments on  the  concentration of
•               nutrients  in  surface  waters as  summarized  by Jaworski in AFO
•               Technical  Report  #15  are  as follows:   (1)  sediments contain nutrients
                 and  act as transport  mechanisms  (2) due to the adsorption phenomena
•               sediments  when  deposited  in the  stream channel also trap nutrients
                 (3)  more  than 99% of  the  soluble nitrogen  is in the form of nitrates
m               which leach at  a  more rapid rate than  the  other forms of nitrogen, and
tt               (4)  in  contrast to the high mobility of nitrate nitrogen, phosphorus
                 compounds  react vigorously with  soil and have  a very low mobility.
•                        24)  Sediment yields calculated by USGS at over 40 sites
                 throughout the  Susquehanna  Basin generally indicated that the
•               seasonal  distribution of  sediment discharge is quite similar to that
•               of water  discharge.   Moreover,  the long-term data showed the annual
                 sediment  discharge rates  to the  extremely  variable but strongly
•               related to a  particular year's  hydrograph.  On the average, the
                 Susquehanna River transports  approximately 3 million tons of
•               sediment  annually which equates  to 110 tons per square mile.  Extreme
•               sediment yields vary  from 20  tons per  square mile in established
                 forest  land to  800 tons per square mile in denuded areas and areas
•               disturbed  by  strip mining.  Of  the three million tons of sediment
I
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                                                                                  69
•                        28)  In order to protect the upper Chesapeake Bay from

                 excessive eutrophication, a combination of mathematical modeling

I               studies and mass balance analyses have indicated that during

                 relatively low-flow conditions  (<_ 30,000 cfs), 70-75 percent of

I               the total phosphorus load from  point source discharges in the lower

_               Susquehanna Basin must be eliminated.  For a river flow of 50,000

•               cfs, a 90 percent reduction of  the point source contribution must

•               be realized.

                          29)  Based on the extensive body of data previously

•               presented in this report nitrogen is largely uncontrollable in the

                 Susquehanna Basin, especially during periods when flows and runoff

V               rates are high.  In order for the management of nitrogen to be a

                 viable alternative during extremely low-flow periods (_< 10,000 cfs)

                 about 90 percent of the point source loading will have to be

fl               eliminated.  In view of the importance of agricultural runoff as

                 a contributor of nitrogen, and  to a lesser extent phosphorus, it

•               is recommended that methods be  devised and seriously considered to

                 maximize control of this once regarded non-controllable source of

                 nutrients.

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                                                                                  70
                                             Conclusions


•                     1)   The  tributary  streams  of  the  lower  Susquehanna  River

                  which  had the highest phosphorus concentrations  on  both  an  annual

•                and  seasonal  basis  were:

•                                           Shamokin  Creek

                                             Conoy Creek

V                                           Codorus Creek

                                             Conestoga Creek

g                     2)   The  greatest total  nitrogen concentrations  both  seasonally

_                and  annually, were  measured  in  the following  tributaries:

*                                           Conoy Creek

fl                                           Chickies  Creek

                                             Conestoga Creek

•                                           Pequea  Creek

                       3)   Maximum  nitrogen  and phosphorus concentrations  in  the

M                tributary streams occurred during  the  low flow period with  the

m                exception of  oxidized inorganic nitrogen, the most  abundant nutrient

                  fraction  in the study area.  Higher  stream flows  appeared to have

ff                a  "diluting"  effect on  the TKN  and phosphorus concentrations but

                  not  on  the oxidized nitrogen fraction.

J|                     4)   In general, all seasonal  concentrations  of  every nitrogen

_                and  phosphorus fraction in the  Susquehanna River were dramatically

™                higher  in the reach from Harrisburg  to Conowingo  Dam than in the

                  reach  upstream of Harrisburg.
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                                                                                   71
0                     5)  The major impoundments along the lower Susquehanna River,
M                i.e. Conowingo and Safe Harbor, represented a significant "sink"
                  for phosphorus, particularly during low flow periods when
•                detention times were long.
                       6)  Phosphorus concentrations in the Susquehanna River were
•                not significantly influenced by variations in stream flow as were
                  the nitrogen fractions.  While TKN concentrations throughout the
I                Susquehanna River were at a maximum during the low flow - high
•                temperature season, NOp+NO^ levels increased during higher flow -
                  lower temperature periods due to amplified effects of agricultural
I                runoff and reduced biological activity.
                       7)  The major phosphorus contributing streams, in terms of
|                daily loads to the Susquehanna River, were as follows:
                                             Conestoga Creek
                                             Codorus Creek
                                             Juniata River
                       8)  Streams providing the major daily loads of nitrogen were
I                as follows:
                                             Conestoga Creek
0                                           Swatara Creek
•                                           Juniata River
                       9)  Nitrogen-phosphorus ratios (by atoms) in the lower
I                Susquehanna River varied from about 34:1 to 46:1.  Approximately
                  30-40 percent of the total  phosphorus load represented the inorganic
I

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                                                                                   72
                    fraction, whereas approximately 50-80 percent of the total nitrogen
                    load represented the inorganic fraction.
•                      10)  The total nitrogen and phosphorus contributions from
                    municipal wastewater effluents were estimated to be about 15,000
I                  Ibs/day  (5 to 25 percent of the maximum measured load in the
                    Susquehanna River) and 20,000 Ibs/day (40 to 200 percent of the
•                  maximum measured load in the river), respectively.
•                      11)  Approximately 50 percent of the total measured phosphorus
                    and nitrogen load from municipal wastewater effluents was contributed
•                  from three areas - Harrisburg, Lancaster and York.
                        12)  The total nitrogen and phosphorus contributions from major
|                  industrial dischargers in the lower Susquehanna River Basin were
'—                  estimated to be approximately 4800 Ibs/day (30% of the municipal
™                  wastewater load) and 1350 Ibs/day (7% of the municipal wastewater
•                  load), respectively.
                        13)  Runoff from agricultural land  (42 percent of the study
•                  area), accounted for 75-85 percent of the non-point source phosphorus
                    contribution, 60-70 percent of the TKN contribution, and more than
•                  90 percent of the nitrate nitrogen contribution from all non-point
jl                  sources.
                        14)  Runoff from forested land (53 percent of the study area),
 I                  accounted for 10-15 percent of the non-point source phosphorus
                    load, 25-30 percent of the TKN load, and about 5 percent of the
 •                  nitrate nitrogen load from all non-point sources.

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                                                                                73
                     15)   During  the high  flow period, it has been estimated that

•               urban  storm water  from a  450 square mile area accounted for about

                 15  percent of the  non-point source phosphorus load, 13 percent of

•               the  TKN  load, and  a negligible percentage of the nitrate nitrogen

                 load from all non-point sources.

|                   16)   Although  the nutrient contribution from the numerous combined

_               sewer  outfalls in  Harrisburg was not accurately quantified, it

•               appeared, from a comparison of sampling data obtained above and

•               below  the majority of these sewers, that this source was quite

                 significant, actually surpassing the measured nitrogen and

I               phosphorus load  from the  Harrisburg S.T.P. during the peak flow

                 season.

                     17)   During  the low flow season, wastewater effluents alone

                 accounted for 16 and 72 percent of the total nitrogen and

                 phosphorus contribution from both point and non-point sources,

I               respectively.  During the high flow condition, these percentages

                 decreased to about 7 and  40 percent, respectively.

•                   18)   A mass balance analysis of the data collected in the

                 tributary watersheds indicated that a significant quantity of

•               phosphorus was retained in the stream channels through a deposition

•               or  biological utilization process during every flow season.  While

                 nitrogen  showed similar loses during the low flow season, its

•               recoverability during the higher flow periods, when scouring of

                 the  bottom sediment prevails, appeared to be greater and more

                 widespread than phosphorus.
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                                                                                  74
                     19)   A mass balance analysis  of the  main stem Susquehanna  River
                 data, besides underscoring the importance of major impoundments  as  a
                 sink for phosphorus, depicted a substantial  introduction  of both
                 because of scouring of the bottom sediments and innundation of
                 shoreline vegetation.   Any apparent difference in scouring characteristics
                 of the main stem Susquehanna River and the tributary streams as  related
                 to phosphorus may be the result of higher stream velocities in the  river,
                 longer duration of high flows, sediment content and its  adsorption
                 potential, or some other complex physical  behavior.  During the  low
                 flow period deposition of nutrients and biological  utilization by
                 aquatic plants were significant in-stream processes implied by mass
                 balance data.
                                                                        2
                     20)  The areal yields of phosphorus and TKN (Ibs/mi  )  appeared
                                                                      2
                 to be markedly influenced by sediment yields (tons/mi  )  based upon
                 nitrogen and phosphorus into the water column during high  flow periods
I

I

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                 average annual  data collected by USGS at eight stations  in the lower
I               Susquehanna Basin.   Such a relationship could not be established  for  NO.,.
                     21)  A regression analysis utilizing 1969 and 1971 nutrient data
|               collected at Conowingo Dam revealed that distinct increases in both
_               phosphorus and  nitrogen loadings for comparable stream-flows  have
™               occurred during this two year period.
•                   22)  Phosphorus is considerably more manageable  than nitrogen  in
                 the lower Susquehanna River Basin during all  flow conditions.
•                   23)  In order to protect the biological  integrity of the  upper
                 Chesapeake Bay,  a sizeable reduction (70-90  percent)  in the existing


I

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75
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                 point source contribution of phosphorus must be realized.
I                   24)  The effectiveness of nitrogen control  at point sources  is
                 questionable unless attention is given towards  reducing the existing
•               load from agricultural  runoff.
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                                                                  76
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                                      RECOMMENDED  FUTURE STUDIES
™                      1.   Select  a  primarily  agricultural watershed to study  fertilizer
application practices.  This study should include but not be limited
to the following:  determination of the present rate of application
(Ibs/acre) and types of fertilizer applied (quick vs. slow release);
quantification of seasonal application practices (fall, summer and
spring); identification of the state of the plant growth that
fertilizers are applied.  Study results would be compared to recommended
Federal and State fertilizer application programs to determine if the
existing practices of the farmers within the watershed are sound, both
in terms of conservation and economics.  Should it be found that
excessive amounts of fertilizer are being applied, economic
considerations should dictate reassessment of current practices.
Subsequent to the implementation of any modified fertilization program
water quality monitoring of the watershed would allow for data
comparison with previous studies (Technical Report 60) to show possible
nutrient reductions in the watershed.
     2.  Technical Report 60 concluded that the area! yields of
                          2
phosphorus and TKN (Ibs/mi ) appeared  to be markedly influenced by
                        2
sediment yields (tons/mi ) based upon  average annual  data collected by
the USGS at eight stations in the lower Susquehanna Basin.  Actual
nutrient loadings associated with sediment yields, however, were
not determined.  It is recommended that a study be undertaken to

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                 contrast a watershed farmed with a high degree of conservation measures
g               employed versus a watershed in which conservation practices are
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                minimal.  Area! sediment yields from the two watersheds would be
                determined on a seasonal basis.  The phosphorus content of the
                sediment would be determined in order to establish  the relative
I
                 contribution of phosphorus from the erosion of farmland under the two
                contrasting situations.  The selection of phosphorus for this study
                seems appropriate because of its correlation with sediment yields
                (Technical Report 60) and its known adsorption to sediment particles.
•              In addition, reduction of non-point source phosphorus input by erosion
                control measures in conjunction with direct point source control  of
•              phosphorus should enhance the possibilities of making phosphorus  the
                rate limiting nutrient to control eutrophication in impoundments  in
J              the lower Susquehanna Basin and the upper Chesapeake Bay.
_                   3.  The significance of the construction industry as  a non-point
•              source of pollutants in the lower Susquehanna Basin should be examined.
•              The scope of Technical Report 60 did not include the assessment of
                nutrient contributions from specific land uses.  The impact of sediment
•              loading from activities including, but not limited to, housing
                construction, commercial building, road construction, and  water
I              resources projects should be evaluated for the purpose of  developing
•              guidelines for erosion and sediment control for use by the various
                management agencies.
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                                                                  78
     4.   Although the nutrient contribution from the numerous  combined

sewer outfalls in the City of Harrisburg was not accurately quantified

in Technical  Report 60,  the significance of the combined sewer system as

a major source of nitrogen and phosphorus was established.  Studies

should be carried out to determine the sources  of nitrogen and

phosphorus in the urban  runoff.   The relative contribution from

diffuse  sources such as  street debris, rainfall, snow melt,  lawn

fertilizer, vegetative decay, and fallout from  particulate matter

should be included in a  study of this nature.  The object of the

study would be to develop guidelines for reducing the water quality

impact of urban runoff.


     5.   Major impoundments exert considerable  influence in  regulating

phosphorus and, to a lesser extent, nitrogen in the lower Susquehanna

River.  In addition, these impoundments are highly susceptable to  the

proliferation of aquatic plant growths because  of their quiescent

nature and reduced silt  content.   It is therefore suggested that a

detailed study be undertaken in  at least one of these impoundments

to address the following key areas:  the lateral, longitudinal and

vertical distribution of nutrients on a seasonal basis;  exchange

rates at the  mud-water interface including characterization  of the

bottom sediment;  existing algal  growth conditions and species

diversity; growth potential through a series of bioassay analyses;

and development of nutrient-algal relationships for inclusion  in a

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                 predictive model.  The literature is abundant in material dealing
•               with lake eutrophi cation and it is quite conceivable that much of
79
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                 it would be applicable to and assist in the design of such an
                 impoundment study.

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                                                                 80

                         Acknowledgements



     The authors wish to acknowledge and express their gratitude to

the following governmental and institutional agencies for having

extended the assistance and cooperation that facilitated the collection,

analysis and evaluation of the data presented in this report:


               Pennsylvania Department of Environmental
                Resources
               Susquehanna River Basin Commission
               City of Harrisburg
               City of York
               City of Lancaster
               City of Lebanon
               Borough of Selinsgrove
               City of Sunbury
               Township of East Pennsboro
               Borough of Mechanicsburg
               Borough of Shippensburg
               Borough of Carlisle
               Township of Lower Allen
               Borough of New Cumberland
               Borough of Camp Hill
               Borough of Middletown
               Borough of Palmyra
               Hershey Sewage Company
               Borough of Hanover
               Borough of Elizabeth
               Borough of Red Lion
               Township of Penn
               Borough of Manheim
               Borough of Lemoyne
               Borough of Lititz
               Borough of Ephrata
               Borough of Columbia
               U. S. Geological Survey, Department of Interior
               Philadelphia Power & Light Company
               Pennsylvania Power & Light Company

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APPENDIX

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SUSQUEHANNA  RIVER  NUTRIENT SURVEY
        SAMPLING NETWORK

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1
I Land area figures (acres and square miles) were determined for
Ithe following sub-divisions within the lower Susquehanna River Basin:

SUB-DIVISION
1
I Major cities of
greater than
125,000 inhibitants




AREA

Harrisburg
Lancaster
Lebanon
York



LAND AREA

mi
7.6
7.2
4.6
5.3


2 acres
4,864
4,608
2,944
3,392


POPULATION

67,880
57,589
28,572
50,335


POPULATION

pop/mi2
8,931
7,998
6,211
9,497


DENSITY

pop/acre
13.45
12.50
9.70
14.84


• Major Urbanized
Areas
1


1

1
Counties
1



1
1
Harrisburg
Lancaster
York

Adams
Cumberland
Dauphin
Juniata
Lancaster
Lebanon
Northumberland

Perry
Snyder
York
78
39
37

526
555
518
386
946
363
453

551
327
909
49,920
24,960
23,680

336,640
355,200
331,520
247,040
605,440
232,320
289,920

352,640
209,280
581,760
240,751
117,097
123,106

56,937
158,177
223,834
16,712
319,693
99,665
99,190

28,615
29,269
272,603
3,086
3,002
3,327

108
285
432
43
338
275
219

52
90
300
4.82
4.69
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