903R81006
U.S. EPA Region III
Regional Center for Environmental
Information
1650 Arch Street (3PM52)
Philadelphia^ 10103
ASSESSMENT AND UPDATING OF PARTICULATE EMISSIONS DATA
FOR THE SOUTHWEST PENNSYLVANIA INTRASTATE AIR
QUALITY CONTROL REGION
VOLUME II
APPENDIX D
DETAILS OF THE HI-VOL FILTER ANALYSIS PROGRAM
H. E. Cramer, H. V. Geary and S". F. Saterlie
Prepared for
U. S. ENVIRONMENTAL PROTECTION AGENCY
Region III
Philadelphia, Pennsylvania 19106
Contract No. 68-02-1387
Task Order No. 3
H. E. Cramer company, inc.
UNIVERSITY OF UTAH RESEARCH PARK
POST OFFICE BOX 8049
SALT LAKE CITY, UTAH 84108
-------
U.S. EPA Region III
Regional Center for Environmental
Information
1650 Arch Street (3PM52)
Philadelphia, PA 19103
903R81006
TR-81-104-01
January 1981
ASSESSMENT AND UPDATING OF PARTICULATE EMISSIONS DATA
FOR THE SOUTHWEST PENNSYLVANIA INTRASTATE AIR
QUALITY CONTROL REGION
VOLUME II
APPENDIX D
DETAILS OF THE HI-VOL FILTER ANALYSIS PROGRAM
H. E. Cramer, H. V. Geary and S. F. Sarerlie
Prepared for
U. S. ENVIRONMENTAL PROTECTION AGENCY
Region III
Philadelphia, Pennsylvania 19106
Contract No. 68-02-1387
Task Order No. 3
Regional ( enter for HiMronmenMI Infnrnwtion
US H'A Region III
1650 Arch St
Philadelphia. PA 1910^
H. G. Cramer company, inc.
UNIVERSITY OF UTAH RESEARCH PARK
POST OFFICE BOX 8049
SALT LAKE CITY, UTAH 84108
-------
TABLE OF CONTENTS
VOLUME II
Appendix Title Page
LIST OF TABLES iii
LIST OF FIGURES v
D ADDITIONAL DETAILS OF THE HI-VOL FILTER
ANALYSIS PROGRAM D-l
D.I Description of the Sampler Locations D-l
D.2 Meteorological Conditions on
Sampling Days D-14
D.3 Observer's Log for The Sampling Days D-26
D.4 Filter Analysis Results D-39
-------
TABLE OF CONTENTS
VOLUME I
Section
Title
Page
1
2
ACKNOWLEDGEMENTS
EXECUTIVE SUMMARY
INTRODUCTION
DESCRIPTION OF THE PHASE II PARTICULATE
SAMPLING PROGRAM
EMISSIONS FROM INDUSTRIAL SOURCES AND
SOURCE COMPLEXES
RESULTS OF THE OPTICAL AND SEM/EDAX
ANALYSES OF THE HI-VOL FILTER SAMPLES
REVISION OF THE PHASE I EMISSIONS
INVENTORY
RESULTS OF THE PHASE II DIFFUSION MODEL
CALCULATION FOR PARTICULATE EMISSIONS FROM
INDUSTRIAL SOURCES
COMPARISON OF CALCULATED AND OBSERVED
PARTICULATE CONCENTRATIONS
REFERENCES
i
ii
1-1
2-1
3-1
4-1
5-1
6-1
7-1
8-1
Appendix
A
R
MATHEMATICAL MODELS USED TO CALCULATE
GROUND-LEVEL CONCENTRATIONS
SEASONAL AND ANNUAL FREQUENCY DISTRIBUTIONS
OF WIND SPEED AND WIND DIRECTION
INDUSTRIAL PARTICULATE EMISSIONS INVENTORY
A-l
B-l
C-l
11
-------
LIST OF TABLES
Table
Number
D-l
D-2
through
D-8
D-8
D-9
D-10
through
D-15
D-16
through
D-88
Title
List of Hi-Vol Monitoring Sites
Hourly Surface Weather Observations at the
Greater Pittsburgh Airport on the Sample
Days
Mean Wind Speed and Precipitation Data
for Sample Days
Mixing Depths and Potential Temperature
Gradients Measured at the Greater Pitts-
burgh Airport before, during and after
Sample Days
Observer's Logs for the Sample Days
Results of Optical Particle Counts
Page
D-2
D-15
through
D-20
D-21
D-22
D-27
through
D-38
D-44
D-89
through
D-167
D-l 68
through
D-170
D-171
through
D-216
Results of SEM Particle Counts
Summary of EDAX Elemental Analysis
Particle Analysis of Selected Filters
D-45
D-46
D-47
D-217
through
D-224
Analysis of Selected Large Particles
D-48
D-225
and
D-226
EDAX Elemental Analysis of Five Selected
Large Particles
D-49
iii
-------
LIST OF TABLES (Continued)
Table
Number
D-227A
through
D-229B
Title
EDAX Elemental Analysis of Large Sla|
Particles
D-50
D-230
through
D-236
Optical Microscopy Analysis by McCrone
Associates
D-51
IV
-------
LIST OF FIGURES
Figure
Number
D-l
D-2
through
D-5
D-6
through
D-19
Title
Locations of hi-vol monitoring sites.
Topographic maps of the areas surrounding
the monitoring sites.
Cumulative Mass Distributions from the
Optical and SEM Analyses
Page
D-3
D-5
through
D-8
D-52
D-20
through
D-30
SEM Photographs of Selected Filters
D-53
D-31
through
D-86
Photomicrographs of Selected Large Particles
Found on Hi-Vol Filter Samples
D-54
D-87
through
D-91
Photomicrographs of Five Very Large Particles
Found on Hi-Vol Filter Samples
D-55
D-92
through
D-101
D-102
through
D-112
D-113
and
D-114
Photomicrographs of Large Particles Contained
in Slag Samples from Electric Arc Furnaces
and of Smaller Particles found on the Surface
of these Particles
Photomicrographs of Small Particles Contained
in Slag Samples from Electric Arc Furnaces
and of Smaller Particles Found on the Surface
of these Particles
Photomicrographs of Large Particles Contained
in Slag Samples from Blast Furnaces and of
Smaller Particles Found on the Surface of
these Particles
D-56
D-57
D-58
D-115
and
D-116
Photomicrographs of Large Particles Contained
in Slag Samples from Basic Oxygen Furnaces and
of Smaller Particles Found on the Surface of
these Particles
D-59
v
-------
APPENDIX D
ADDITIONAL DETAILS OF THE HI-VOL FILTER ANALYSIS PROGRAM
D.I DESCRIPTION OF THE SAMPLER LOCATIONS
The fifteen hi-vol monitoring sites selected for the particulate
sampling program are listed in Table D-l. The locations of the moni-
toring sites are shown in Figure D-l. The site selection was made
jointly by the H. E. Cramer Company and the EPA Project Officer after
consultation with the Pennsylvania DER and the Allegheny County BAPC.
The criteria used in site selection included, in addition to logistical
factors, the need for obtaining particulate samples representative of
industrial, urban, suburban and rural areas. The only sites con-
sidered were those currently operated by DER and BAPC as part of
their regular monitoring programs for which a minimum of several years'
records of particulate measurements are available. Logistical factors
included:
• Availability of electrical power required to operate two
hi-vols simultaneously (one hi-vol was required for the
regular DER or BAPC filter sample and a second hi-vol was used
for the special sampling program)
• The requirement that each site be accessible to operating
personnel and observers on a 24-hour basis
• Availability of meteorological observations (the COPAMS and TM
monitoring sites in Table D-l have meteorological measurement
capabilities)
• The requirement that the sites be grouped geographically so
that all monitors could be serviced and periodic activity
observations could be made at each site during each 24-hour
sampling period
D-l
-------
TABLE D-l
LIST OF HI-VOL MONITORING SITES
Site Number
I
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Name
Baden (COPAMS)*
Beaver Falls (COPAMS)*
Koppel
Brighton Township
Midland
Elco
Downtown
Central Lab
Hazelwood**
North Braddock (TM)***
Duquesne II
Liberty Boro (TM)***
Clairton
Greater Pittsburgh Airport
South Fayette
Agency
DER
DER
DER
DER
DER
DER
BACP
BACP
BACP
BACP
BACP
BACP
BACP
BACP
BACP
Classification
Industrial
Suburban
Industrial
Suburban
Industrial
Rural
Urban
Urban
Industrial
Industrial
Industrial
Industrial
Industrial
Rural
Rural
*COPAMS - Commonwealth of Pennsylvania Air Monitoring System (DER telemetered
data site)
**Hazelwood T, a TM site, is located approximately 0. 5 kilometers south of the selec- .
ted Hazelwood hi-vol site.
***TM - Allegheny County Bureau of Air Pollution telemetered site
D-2
-------
LAWRENCE CO.
BUTLER CO
ARMSTRONG CO.
INDIANA CO
BEAVER CO.
ALLEGHENY CO.
©15
WESTMORELAND CO.
WASHINGTON CO.
FAYETTE CO.
GREENE CO.
50 5 10 15 20 KILOMETERS
FIGURE D-l. Locations of hi-vol monitoring sites. The numbers refer
to site names and other details given in Table D-l.
D-3
-------
The site classifications given in Table D-l are admittedly qualitative
and are intended principally to serve as a basis for grouping the monitor
locations according to the proximity of major industrial sources, popula-
tion density and traffic density.
Figures D-2 through D-5 present 2-kilometer by 2-kilometer topographic
maps showing the major roads, railroads and buildings in the areas surround-
ing the individual monitoring sites. The location of the monitor is shown
by the ® symbol at the center of each map. Terrain elevations in
Figures D-2 through D-5 are in feet above mean sea level, and the contour
interval is 100 feet (30.5 meters). A brief description of each monitor
site is given below.
Site No. 1 - Baden (PER, COPAMS)
The Baden monitor is located on the north side of the Ohio River,
immediately adjacent to the Ohio River Boulevard, on a slight rise approxi-
mately 6 meters above the level of the Boulevard. Vehicle traffic compris-
ing passenger cards and trucks is typically moderate-to-heavy. Directly
across the Ohio River Boulevard from the monitor site there are multiple
railroad tracks leading to a switching yard complex and railroad car
humping stations. Rail traffic is typically heavy and at low speed with
much idle operation of the diesel svitching engines. The Jones and Laughlin
(J&L) Aliquippa Works is located on the south side of the Ohio River directly
west of the Baden monitor site. Heavy particulate emissions are associated
with the operation of the coke ovens and the new EOF shop which are the
facilities closest to the monitor.
Site No. 2 - B,eayer Falls (PER, COPAMS)
The Beaver Falls monitor is located near ground level immediately
adjacent to a hard-packed earth parking lot and loading area for an
industrial warehouse. Observations during the study showed that diesel
D-4
-------
SITE NO I BADEN
SITE NO. 2 BEAVER FALLS
SITE NO 3 KOPPEL
SITE NO 4 BRIGHTON TOWNSHIP
FIGURE D-2. Topographic maps of the areas surrounding the Baden, Beaver
Falls, Koppel and Brighton Township monitoring sites.
D-5
-------
SITE NO. 5 MIDLAND
SITE NO. 6 ELCO
SITE NO 7 DOWNTOWN
SITE NO 8 CENTRAL LAB
FIGURE D-3. Topographic maps of the areas surrounding the Midland, Elco,
Downtown and Central Lab monitoring sites.
D-6
-------
SITE NO 9 HAZELWOOD
SITE NO. 10 NORTH BRADDOCK
SITE NO II DUQUESNE
SITE NO 12 LIBERTY BOROUGH
FIGURE D-4. Topographic maps of the areas surrounding the Hazelwood, North
Braddock, Duquesne II and Liberty Borough monitoring sites.
D-7
-------
SITE NO. 13 CLAIRTON
SITE NO 14 GREATER PITTSBURGH AIRPORT
SITE NO. 15 SOUTH FAYETTE
FIGURE D-5. Topographic maps of the areas surrounding the Clairton,
Greater Pittsburgh Airport and South Fayette monitoring
sites.
D-8
-------
tractor-trailer traffic was continuous during the five-day work week and
daylight hours. Only one loading dock was observed to be in use, and
only one truck was in the yard at any one time. Trucks usually did not
idle during loading operations. There is a railroad track on the far
side of the loading yard.. During,each observation period, at least one
diesel train passed by at slow speed, suggesting fairly continuous rail
traffic. Except for the truck-loading and rail operations, the area
surrounding the monitor appears to be typical of a suburban community.
Site No. 3 - Koppel (PER)
The Koppel monitor is on the roof of the municipal fire station,
approximately 10 meters above street level. The Babcock and Wilcox
(B & W) Koppel Plant is located approximately 0.5'kilometers east of the
monitor. On Pennsylvania Route 351, used by diesel trucks hauling scrap
to and products from the B & W Plant, the bumping of the trucks as they
cross the tracks produces visible dust clouds. During the observation
periods, the use of torches to cut the scrap was frequently noticed at
the B & W Plant. According to the technician servicing the DER hi-vol
at the Koppel site, this is a common occurrence. A small charcoal grill
was noted on the roof of the fire station about 7 meters north of the
hi-vol sampler. There was no evidence that the grill was used during
any of the sampling days.
Site No. 4 -Brighton Township (PER)
The Brighton Township monitor site is in a grass field adjacent to
the overflow parking lot for the Beaver County Hospital. The parking
lot was vacant at the times the observers visited the site. The only partic-
ulate emissions noted'were infrequent'visible plumes .from a 'small hospital
incinerator stack located 200 meters north and 30 meters above the
sampler.
D-9
-------
Site No. 5 - Midland (PER)
The Midland hi-vol monitor is at an elevation of approximately 10
meters above street level on the roof of the Midland Post Office, which is
directly across Midland's main downtown street (Pennsylvania Route 68)
from the Crucible Steel Plant complex. While stack and fugitive emissions
from Crucible Steel were dominant, the monitor was also impacted by
emissions from heavy vehicle traffic on all days of the week except
Sunday. The most noticeable emissions from Crucible Steel typically
were from the vicinity of the strip mill and scarfer with south winds.
All of the monitoring equipment as well as the roof of the building on
which the monitor was located were coated with a rust-colored dust that
appeared to adhere to the surfaces.
Site No. 6 - Elco (DER)
The Elco monitor is located on a hillside lawn of a private resi-
dence on Washington County Route 88 overlooking the Monongahela River,
which is about 100 meters below the elevation of the monitor. Light
vehicle traffic was observed on Route 88 on all sample days.
Site No. 7 - Downtown (BAPC)
The Downtown monitor is on the roof of the multistory County Office
Building located in downtown Pittsburgh at an elevation of approximately
30 meters above ground level. Heavy car and truck traffic moving at slow
speeds or idling was observed on all days except Sunday when the traffic
was light. The industrial source complex most likely to affect this
sampler is the Jones and Laughlin integrated steel plant located about 3
kilometers to the east.
D-10
-------
Site No. 8 - Central Lab (BAPC)
The Central Lab monitor is located on a roof approximately 15
meters above ground level in the Oakland section of Pittsburgh. The
traffic patterns are similar to those at the downtown monitor site.
The Jones and Laughlin plant is only 1 kilometer from this monitor,
and odors from the plant were frequently noted during the visits to
the monitor.
Site No. 9 - Hazelwood (BAPC)
The Hazelwood monitor is located on the roof of an apartment
building, approximately 15 meters above street level, on the main
thoroughfare of the Hazelwood district. The hi-vol is abut 500 meters
south of the ACBAPC Hazelwood TM station and 200 meters east of the
newest Jones and Laughlin coke batteries. Coking process emissions were
typically present during observations, as were emissions from the trucks
and cars on the heavily-traveled street below the monitor. Traffic
patterns were typically heavy and slow moving on all days except Sunday.
Site No. 10 - North Braddock (BAPC)
The North Braddock monitor is situated on the roof of the North
Braddock municipal building complex, approximately 5 meters above the
level of the parking lot. It is some distance away from the heaviest
downtown Braddock vehicle traffic, but is only 1 kilometer northwest of
the United States Steel Edgar Thompson Plant.
D-ll
-------
Site No. 11 - Duquesne II (BAPC)
The Duquesne II monitor is located on the roof of a shopping center
building, 5 meters above the level of the parking lot. Vehicle
traffic in the lot consists principally of passenger cars. Allegheny
County Route 837, the main riverside thoroughfare, is 100 meters to the
east. The United States Steel Duquesne Plant is located directly across
Route 837. Vehicle traffic in the shopping center and along the county
route was heavy on all days except Sunday. Visible stack or fugitive
emissions from the Duquesne Plant were generally not prominent.
Site No. 12 - Liberty Boro (BAPC)
The Liberty Boro monitor is located on a school roof approximately
10 meters above the ground. The school is 2.5 kilometers north-northeast
of the United States Steel Clairton Works at a terrain elevation approxi-
mately 150 meters above the terrain elevation of the coke works. The
school was in session only on the last sampling day and vehicle traffic
was very light. Odors were typically present at the site and emissions
from the Clairton Works were generally visible below the hills to the
south-southeast.
Site No. 13 - Clairton (BAPC)
The Clairton monitor is mounted on the roof of the Clairton water
treatment plant, approximately 10 meters above ground level, and only
300 meters southwest of the nearest coke battery of the United States
Steel Clairton Works. Typical activity near the monitor included
diesel truck traffic hauling slag to a nearby dump and heavy vehicle
traffic on County Route 837, 100 meters to the northeast.
-------
Site No. 14 - Greater Pittsburgh Airport
The Greater Pittsburgh Airport monitor is located on the airport
terminal roof, approximately 20 meters above the ramp and loading areas.
In addition to the aircraft operations, there was heavy vehicle traffic
along the roadway leading to the airport and in the airport parking lots.
Site No. 15 - South Fayette (BAPC)
The South Fayette monitor is located on the roof of the South
Fayette Township High School, approximately 10 meters above ground
level. Vehicle traffic was very light except on the last sampling day
which coincided with the opening of school.
D-13
-------
D.2 METEOROLOGICAL CONDITIONS ON SAMPLING DAYS
Tables D-2 through D-7 give the hourly observations of wind speed,
wind direction, ambient air temperature, Pasquill stability category
(following the Turner (1964) definitions of the Pasquill stability cate-
gories) and "weather" at the Greater Pittsburgh Airport on the six sampling
days (10, 16, 22 and 28 August 1976; 3 and 9 September 1976). The term
"weather" is used to refer to observations of fog, haze, smoke and pre-
cipitation; the absence of an entry in the'"weather" column for a given
hour indicates that none of these conditions was reported. Table D-8 gives
the 24-hour average wind speeds and precipitation data for the sampling days,
and Table D-9 Lists the mixing depths and vertical potential temperature
gradients obtained from the twice-daily upper-air soundings made at the
Greater Pittsburgh Airport before, during and after each sampling day. The
mixing depths in Table D-9 were estimated using the procedures outlined in
Section 3.3 of Cramer, e_t^ al_. (1975); the potential temperature gradients
are the average values for the surface mixing layer. Meteorological con-
ditions on the individual sampling days are discussed below.
10 August 1976
A slow-moving surface high pressure system passed over the Pittsburgh
area during the period 9-11 August 1976. Early morning ground fog cleared
at the Greater Pittsburgh Airport by about 1200 EST on 10 August 1976, but .
broken middle clouds remained until about 1700 EST. Light-to-moderate
northwest winds persisted throughout most of the day, with the wind be-
coming calm after about 2100 EST. Rawinsonde data for the Greater Pitts-
burgh Airport show relatively deep mixing depths at 0700 and 1900 EST, with
a slightly stable potential temperature gradient at 0700 EST and an adia-
batic potential temperature gradient at 1900 EST. However, the 0700 EST
sounding on 11 August 1976 shows that, with clear skies, a strong surface-
based inversion formed during the night of 10 - 11 August 1976.
D-14
-------
TABLE D-2
HOURLY SURFACE WEATH ER OBSERVATIONS
AT THE GREATER PITTSBURGH
AIRPORT ON 10 AUGUST 1970
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(cleg)
330
300
330
300
250
280
300
320
320
330
330
030
320
330
330
320
340
330
300
220
Calm
Calm
Calm
Calm
Wind
Speed
(m/sec)
3. Oi)
3. 09
3. 09
2. 06
2. 06
2. 06
2.57
3. 09
3.60
4. 12
5. 14
2.57
4. 12
3. 09
1.54
2.57
3. 09
2. 06
2.57
1.54
0.00
0. 00
0.00
0.00
Ambient Air
Temperature'*
(°K)
288 (59)
288 (59)
288 (59)
288 (59)
288 (59)
288 (59)
288 (58)
289 (61)
290 (63)
291 (65)
294 (69)
295 (72)
296 (73)
297 (75)
297 (75)
297 (75)
297 (75)
297 (75)
296 (73)
294 (69)
291 (64)
290 (63)
290 (62)
289 (60)
"Weather"
Ground fog
Ground fog
Ground log
Ground fog
Ground fog
Ground fog
Ground fog
Ground fog
Fog-
Fog
Fog
Pasquill Stability
Category
E
D
E
E
D
D
D
D
U
D
D
D
D
D
C
D
C
D
E
E
E
E
E
E
*Temperatures in degrees Fahrenheit are enclosed by parentheses.
D-15
-------
TABLE D-3
HOURLY SURFACE WEATHER OBSERVATIONS
AT THE GREATER PITTSBURGH
AIRPORT ON 10AUGUST
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(deg)
310
310
320
350
280
280
310
010
010
3 GO
350
350
340
320
340
340
340
340
340
340
300
350
010
350
Wind
Speed
(m/sec)
2. 06
2. Of5
2. 57
2. 06
2.06
2.06
2. OG
3. 09
3.09
3.60
4.63
5.66
5.14
5. 14
6. 17
4. 12
5. 14
4.12
4. 12
5. 14
4.12
2. 06
1 . 5 \
2.57
Ambient Air
Temperature*
(°K)
286 (56)
285 (54)
285 (53)
285 (54)
285 (53)
284 (51)
285 (53)
288 (58)
289 (61)
291 (61)
292 (66)
293 (67)
293 (68)
293 (68)
294 (69)
294 (69)
291 (69)
293 (68)
292 (66)
290 (62)
289 (60)
287 (57)
286 (55)
286 (55)
"Weather"
Fos,
Fog
FOR
Haze
Pasquill Stability
Category
E
E
E
E
E
D
C
C
13
B
D
D
I)
D
D
U
D
D
E
E
E
E
E
E
^Temperatures in degrees Fahrenheit are enclosed by parentheses.
D-16
-------
TAHU-: D-4
HOURLY SURFACE WEATHER OBSERVATIONS
AT THE GREATER PFTTSFHJRGII
AIRPORT ON 22 AUGUST 1976
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(deg)
Calm
Calm
Calm
320
Calm
Calm
Calm
140
180
130
360
320
320
360
360
260
280
320
310
320
300
270
310
Calm
Wind
Speed
(m/sec)
0.00
0. 00
0.00
1.54
0.00
0.00
0. 00
1.54
1.54
1.54
1.54
4. 12
2. 57
2.57
2.57
4. 63
4.12
4.12
2.57
3. 09
2.06
1.51
2. 06
0. 00
Ambient Air
Temperature *
(°K)
288 (58)
287 (57)
286 (55)
286 (55)
286 (55)
285 (51)
286 (56)
290 (62)
293 (68)
296 (73)
298 (77)
299 (78)
300 (80)
300 (81)
300 (81)
300 (81)
300 (81)
300 (80)
298 (77)
296 (73)
294 (70)
291 (65)
291 (64)
290 (62)
"Weather"
'laze £ Smoke
Haze fr Smoke
laze £ Smoke
:Iaze £ Smoke
la/c £ Smoke
Haze & Smoke
:Iaze & Smoke
flaze £ Smoke
Haze £ Smoke
Haze
Haze
Flaze
Haze
Haze
Haze
IF a 7,0
Haze
Pasquill Stability
Category
E
E
E
E
E
C
B
B
B
B
B
B
B
B
B
C
C
D
E
E
E
E
E
E
*Temperatures in degrees Fahrenheit arc enclosed by parentheses.
D-17
-------
TABLE D-5
HOURLY SURFACE WEATHER OBSERVATIONS
AT THE GREATER PITTSBURGH
AIRPORT ON 28 AUGUST 1976
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(deg)
200
230
220
170
160
240
200
200
200
170
200
170
200
220
210
230
220
190
220
230
210
210
270
300
Wind
Speed
(m/sec)
2.57
2.57
2.06
1.54
2. 06
2.57
3.09
2.57
2.57
2.57
3.60
4.12
4.63
6. 69
6.17
5. 14
5. 66
4.12
5. 14
1.63
4. 12
4.12
3. GO
3.60
Ambient Air
Temperature*
(°K)
292 (66)
292 (66)
292 (66)
290 (63)
290 (63)
291 (65)
291 (65)
291 (65)
293 (67)
294 (69)
295 (71)
295 (71)
297 (75)
298 (77)
299 (79)
299 (79)
298 (76)
296 (74)
296 (73)
295 (72)
294 (70)
294 (70)
29 1 (70)
294 (69)
"Weather"
Haze
Haze
Haze
Ground fog
Fog
Fog-
Fog
Fog-
Fog
Haze
Haze
Haze
Haze
Haze
Haze
Haze
Haze
Haze
I faze
1 1 a ze
Light Shower;
Haze
[laze
1 1 a/o
Pasquill Stability
Category
E
E
E
E
D
I)
D
D
D
D
D
D
D
I)
D
D
D
D
D
D
D
D
D
D
*Temperatures in degrees Fahrenheit are enelosed by parentheses.
D-18
-------
TABU-; D-6
HOURLY SURFACE WEATHER OBSERVATIONS AT THE
GREATER PITTSBURGH AIHPORT ON
3 SEPTEMBER 197(5
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(cleg)
Calm
Calm
Calm
040
Calm
Calm
130
080
090
190
150
150
160
130
190
170
180
210
200
1GO
200
160
140
150
Wind
Speed
(m/sec)
0. 00
0. 00
0.00
2. 06
0. 00
0.00
2.06
2. 06
2. 06
2. 06
2. 06
3.60
3. GO
4.12
5. 14
4.12
4.63
3. 09
2. 57
2.57
2. 06
1.5-1
1 . 54
1.51
Ambient Air
Temperature*
(°K)
284 (51)
283 (50)
282 (48)
281 (47)
280 (45)
280 (44)
280 (45)
282 (48)
283 (50)
288 (58)
291 (65)
293 (68)
294 (74)
295 (72)
296 (74)
296 (74)
296 (74)
295 (72)
293 (67)
290 (63)
289 (61)
288 (59)
288 (58)
288 (59)
"Weather"
Ground fog'
Fog
Dense fog
Dense fog
Dense fog
Dense fog
Dense fog
Fog
Haze
Haze
Ha 7.c
II a/A1
Haze
Ilaz.o
Pasquill Stability
Category
E
E
D
D
D
D
D
D
D
B
B
B
B
C
C
C
C
D
E
E
E
E
E
E
*Temperatures in degrees Fahrenheit arc enclosed bv parentheses.
D-19
-------
TABLE D-7
HOURLY SURF AC1!-: WEATHER OBSERVATIONS AT THE
GREATER PITTSBURGH AIRPORT ON
9 SEPTEMBER 1976
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(dog)
Calm
Calm
Calm
Calm
Calm
150
Calm
180
220
230
240
200
220
230
230
210
220
230
190
210
230
190
190
300
Wind
Speed
(m/see)
0. 00
0. 00
0. 00
0.00
0.00
1.54
0.00
2.06
4.12
5. 14
4. 63
5.14
6. G9
6. 17
5.G6
7. 72
•LI 2
4. 12
3.09
3.09
3. 09
4. 12
5. 66
10.29
Ainbient Air
Temperature*
289 (61)
289 (60)
288 (59)
287 (57)
286 (56)
286 (55)
286 (56)
289 (61)
295 (71)
297 (75)
298 (77)
300 (81)
300 (81)
301 (82)
301 (82)
300 (81)
299 (79)
298 (76)
296 (74)
295 (72)
294 (69)
292 (66)
291 (65)
291 (64)
"We at her"
Haze
Haze
Haze
Haze
Haze
Haze
Haze .
Haze
Haze
Haze
Haze
Haze
Haze
Light Showers,
Haze
Haze
Light Showers,
O '
Haze
Light Showers,
Haze
Light Showers,
Fog
Light Showers,
o
Fog
Pasquill Stability
Category
E
E
E
E
E
C
C
C
C
C
C
C
D
D
C
D
D
D
D
E
D
D
D
D
*Temperatures in degrees Fahrenheit are enelosed by parentheses.
D-20
-------
TABLE D-8
MEAN WIND SPEED AND PRECIPITATION
DATA FOR SAMPLE DAYS
Sample Date
10 August 197G
16 August 1976
22 August 197G
28 August 1976
3 September 1976
9 September 1976
Mean Wind Speed
(m/sec)
2.4
3.5
1.8
3.7
2.2
3.6
Precipitation (inches)
Sample Day
0.00
0. 00
0. 00
Trace
0. 00
0.28
Prior Day
NA*
0.48
0.00
Trace
0.00
0. 00
*NA = not available.
D-21
-------
TAB Li; D-9
MIXING DEPTHS AND POTENTIAL TEMPERATURE
GRADIENTS MEASURED AT THE GREATER
PITTSBURGH AIRPORT BEFORE,
DURING AND AFTER
SAMPLE DAYS
Date
9 August 197G
10 August 1976
10 August 197G
11 August 197G
15 August 1976
16 August 1976
16 August 1976
17 August 1976
21 August 1976
22 August 1976
22 August 1976
23 August 1976
27 August 1976
28 August 1976
28 August 1976
29 August 1976
2 September 1976
3 September 1976
3 September 1976
4 September 1976
8 September 1976
9 September 1976
9 September 1976
10 September 1976
Time (EST)
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
Mixing Depth (m)
NA*
660
1450
125
1150
125
1500
125
1160
125
1100
125
>3000
340
700
1540
1650
200
980
125
1170
125
1250
1500
Potential Temperature
Gradient (°K/m)
NA*
0.004
0.000
0.059
0. 000
0.024
0. 000
0.058
0.001
0.069
0.002
0. 040
0.001
0. 006
0. 001
0.005
0.001
0. 009
0. 000
0.021
0.001
0. 056
0.000
0.004
*NA - not available.
D-22
-------
16 August 1976
A weak frontal system passed over the Pittsburgh area on the morning
of 15 August 1976, with 12.2 millimeters (0.48 inches) of precipitation
recorded at the Greater Pittsburgh Airport for the 24-hour period ending
at midnight on 15 August. A surface high pressure system followed the
front and remained over Pittsburgh on 16 August. Fog or haze was observed
during the period 0500 to 0800 EST on 16 August, and broken middle clouds
were observed during the period 1100 to 1600 EST. Winds were light-to-
moderate and from the west-northwest through north. Upper-air soundings
at the Greater [jttsburgh Airport indicate that:
• A shallow mixing layer with a moderate surface-based
inversion developed during the night of 15 - 16 August
• A relatively deep mixing layer with an adiabatic lapse
rate developed during the daylight hours on 16 August
• A strong surface-based inversion with a corresponding
shallow mixing depth formed during the night of 16 -
17 August
22 August 1976
A surface high pressure system was approximately centered over the
Pittsburgh area on 22 August 1976. With the exception of scattered to
broken high cirrus clouds after 0800 EST, skies were clear in the Pitts-
burth area on 22 August. At the Greater Pittsburgh Airport, haze and
smoke were observed during the period 0100 to 0900 EST and haze was reported
after 1700 EST. During the period 1200 to 2100 EST, light-to-moderate north-
west and north winds were observed. The wind was calm or light and varia-
ble during the remaining hours of 22 August. Upper-air data for the
Greater Pittsburgh Airport show that strong surface-based inversions devel-
D-23
-------
oped during the nights of 21 - 22 August and 22 - 23 August. The 1900 EST
sounding on 23 August shows a relatively deep mixing layer with a slightly
stable lapse rate.
28August 1976
A trace of precipitation was reported at the Greater Pittsburgh Air-
port on 27 August 1976 as a short-wave trough at 500 millibars passed over
the Pittsburgh area. Similarly, a trace of precipitation was measured on
28 August as an advancing frontal system induced light rain showers at about
2100 EST. Broken to overcast low clouds covered the Pittsburgh area after
0500 EST on 28 August, and haze or ground fog was reported throughout the
day. Upper-air soundings made at the Greater Pittsburgh Airport on 28
August indicate that the mixing depth varied from about 350 meters in the
early morning hours to about 700 meters in the afternoon. The vertical
potential temperature gradient within the surface mixing layer was approx-
imately equal to the moist-adiabatic value during the period. Light-to-
moderate south or southwest xvinds persisted from 0100 EST until about mid-
night when the wind shifted to the northwest, probably indicating a frontal
passage.
3 September 1976
A surface, high pressure system, centered over the Great Lakes on the
morning of 2 September 1976, moved across the Pittsburgh area on 3 Sept-
ember. Calm winds and dense fog (visibility at or near zero) were ob-
served at the Greater Pittsburgh Airport during the period 0100 to 0900
EST on 3 September. After the fog cleared, light-to-moderate surface wind
speeds were measured, with the wind direction ranging from east through
south-southwest. Rawinsonde measurements at the Greater Pittsburgh Airport
show a shallow mixing layer with a slightly stable lapse rate at 1900 EST.
D-24
-------
A surface-based inversion of moderate strength developed during the night
of 3 - 4 September 1976.
' 9 September 1976
A weak cold front passed over the Greater Pittsburgh Airport at about
midnight on 9 September 1976. The storm resulted in 7.1 millimeters (0.28
inches) of precipitation at the airport for the 24-hour period ending at
midnight on 9 September. This precipitation occurred in the form of light
rain showers during the period 1900 to 2400 EST. Skies were clear on 9
September until clouds in advance of the front moved into the Pittsburgh
area at about 1600 EST. Haze was reported from 0600 EST until 2300 EST,
when fog replaced haze as the major restriction to visibility. Winds
were calm until moderate southwest winds developed at about 0900 EST.
After the frontal passage at about 2400 EST, the wind direction shifted
from southwest to northwest and the wind speed increased to over 10 meters
per second. According to the 0700 EST upper-air sounding at the Greater-
Pittsburgh Airport, a strong-surface based inversion formed during the
night of 8 - 9 September. Hcwever, a relatively deep surface mixing layer
with an adiabatic lapse rate developed by 1900 EST on 9 September and con-
tinued throughout the night of 9 - 10 September.
D- 25
-------
D.3 OBSERVER'S LOGS FOR THE SAMPLING DAYS
The Observer's Logs for the six special sampling days are given in
Tables D-10 through D-15. The logs include filter numbers, filter
weights, air flows through the hi-vol samplers during the sampling
period and 24-hour average particulate concentrations. The sampling
sites were visited several times during each 24-hour sampling period, and
the logs also contain notes by the observers of industrial or other
activities in the vicinity of the sampling sites that could have affected
the observed particulate concentrations. Some of the remarks, such as
those referring to noticeable odors from a particular source, are sub-
jective.
D-26
-------
H
W
t)
O
I
a
w
p
U3
w
H
O
O
1-1
w
w
PQ
O
co
I,
0)
erf
CO
(_,
0)
t.
01
o
I
4-1 d o-T
doe
0) -H ~-~
U 4J 60
d a
o ^— -
U
^
O m
rH U
P-I cd
-U
60 60
-H B
0) ^
(U
CO M
V4 n)
Q) CX
XI CO
s
3
Z
S-l T3
01 0)
1 i , — (
rH t— 1
•H cd
CO
c
M
a)
•H
CO
tn
Q)
•H
•H
60
3
60
d
•H
H
-d
d
cfl
a)
tH
•H
a.
CD
rJ iH
o cd
l__ j j^
u3 O
>-> 2:
CN CN
• .
i — i vO
LO OO
, — i
i — 1 - — 1
O\ 0\
O O
- — l - — l
i — f i — )
i — l i — l
OO -fr
t-H r— t
0 0
r— 1 l— t
l — 1 i — 1
T-H t-H
>H
c a> w
cu > H
*"O rd i — (
nj cu cd
pA jV^ r-f .
1 O
3
o 6
o
cd •— i
j-i
a 60
en d
•H
o a
V-) 'H
q ( cy
p;
en
CD ^->
>
p.) V-j
!-l
d O d
•H -d O
V-l rH
•H , T3 0)
rH 4-) 6D
3 ft -H
cfl 3 ^H
O
CJ>
CM
•
r^
*^f
-1
i — i
CN
O
r-H
i
r-H
O
CM
O
,— l
i — l
r— 1
T3
rd
rH
S
1
*H •
cn 4J
•H cn
> 3
cn
d d
O O
•H -H
cn 4-J
cn o
•H 3
t3 a) w
a) cn
I — J i-d d
T-H 4J O
cd S-< CJ
4-1 Cd V-l
cn o) i — i o
d ^ cri ^3
•H O O
d o
0) rH P, -H
B * ^
4J M f_i -H i — 1
d
o cd
4-1 !H
o d 4->
W Q U _q
1
00 &
d 4J
•H I-J
d o
C C
CO
tj i Cj
o
CO !M
0) U-(
3 -a
rH d
a, -H
3
4-1
d
cd •
T — 1 cn
CU rM
o
O OT
o
(-J -U
hJ cd cn
^ G is
^1
CD
i — f
o
•
ST
r^>
CN
r— t
O
CN
i-H
0
r-H
T)
O
O
S
H
N
«d
EC
D-27
-------
CU
a
n
•H
o
CJ
o
rH
I
I-I
pq
tn
(y]
j_j
cfl
g
0)
CO
J_J
0)
5-1
0)
cn
,£>
O
cfl
4J d co
COB
CU -H ~^
O 4-1 60
a 3-
o •— '
O
s ^
O 14-1
rH O
fx< cfl
-U
60 60
•H 6
£
CD
cn V-J
5-1 CO
cu ex
,d C/5
S
2; .
H T3
01 CU
4-1 1 — 1
1 — t 1 — 1
•H Cfl
frj 4J
CO
C
M
CU
[ i
CO
^
a
cfl
4J
cn
j_i
cfl
CU
d
60
a
p*
a
cfl
IM
CU
6
3
r-i
a.
H
w
1
cn
CO
^
MO
00
o
•
cr>
CN
r-
i — i
in
CM
a\
o
i — i
i — i
i — i
^
CM
o°*
o
rH
I — 1
, — f
^
4-J
V4
o
2;
•
}_f
o
o
CU
r-i
rQ
ct)
0)
o
-H
4J
O
^
O
o
-d
cfl
£_|
P3
CO
4J
cn
2
^j
t-t
OJ
j>
CU
, — 1
15
o
CU
c
cn
Q)
^
a*
3
Q
1
CO
CO
13
T-H
ro
i — i
O
•
m
o
O
i — I
• — 1
rH
VO
CN
CTi
O
r— (
i — 1
, — 1
CU
c
cn
a)
3
a*
3
Q
•
p,
O
to
PM
O
W
6
o
M-<
M
rH
4J
CO rH
3 CU
T3 ^>
CU
60 rH
a
•H JS
rH O
r-l rH
•H
vj a
•d -H
^5
4-1 S-l
C M
a) i
B co
cu to •
J> | — 1 rrj
cfl 3
a, o
• , — j
rH CU O
0 0
O S-i 4-1
& 3 cn
a o 3
co cn T3
VD
ro
i — i
O
"
CM
^f-
co
, — 1
ro
CTi
0
i — i
i — i
i — i
O
ro
o**
o
1 — f
, — I
!>,
4J
S-l
CU O
,£> J-l
-H 0
r-J CO
1
60 CU
d j: o
•H O -H
cn n 4J
5-1 CU O
cu 3 is
a. tr
CO
•H "X^ •
T3 C rH
Cfl CU
CO >
CU 4-1 CU
6 CO rH
3 3
rH O *d
a, cj
3
C • 0
O cn 5-j
4-1 ^ 60 •
5-1 O 5-1
•H cfl 4-> O
cfl 4J cfl T)
i— l cn o
c_> g
1 5-i cfl CU
C/3 Cfl CU rH
CO OJ 4-1 ,13
ED d cn cfl
in
m
o
•
01
m
co
CO
, — i
m
ro
CT>
0
i — i
rH
. 1
^.
CO
cr>
o
j-j
i — i
i — i
d
o
4-1
yj
•H
cfl
U
•
01
rH
a,
e
cfl
CO
a)
rH
cfl
a
o
•H
4-1
cn
cu
3
O-
• •
r—4 , — (
cr3 cd
S G
M M
O O
s: ;s
^ CxJ
r~^ I—H
o o
• •
CT> CM
~H >— (
t-H i — 1
v£)
-------
H
1/3
o
t=>
w
I
H
O
fa
O
O
Ct!
W
s
w
w
CO
O
CO
r^
5-1
^d
6
0)
(%
0)
•-
M
J-l
0)
en
,0
o
1
n)
tl (3 ro^
(3 O B
QJ -H ~-~
CJ 4-J 60
C 3.
O >-'
^_^
O u-i
rH a
fa cO
-LJ
rf~^ s \
CO &0
•H e
QJ ^
0)
in j-i
J-i O
QJ a
a ^
3
z
OJ QJ
AJ rH
t— 1 rH
•H m
[•T | 1
CO
c
1 — i
OJ
-U
•1-1
CO
60
a
•H
OT
•H
(3
•rH
s
•H
TJ
#1
13
•H
rO
J-i
J-i
QJ •
4-> >~i
cO
4-J *CJ
QJ
£ 60
" -rH
60 M
O 3
fa T3
00
^O
vO
^J-
vO
, — I
O
CN
CN
rv-j
CTi
0
"~"
, — 1
CN
co
(3^
0
, — i
(3
QJ
cS
pq
60
a
•H
r1,
V)
•H
C
•H
0
•H
•n
#,
a
•H
CO
J-i
01
4J
4-1
OJ
*,
60
O
fa
00
CN
co
^-j-
CN
LO
i — 1
CN
CN
CO
as
0
""*
iH
CM
CN
CO
CTi
O
, — 1
£_J
QJ
>
cfl
0)
pq
•
£•*">
cd
•n
60
(3
•H
JH
3
TJ
in
rH
rH
crj
fa
60
C
•H (3
W
•H in
(3 ^ Q
CO iH
4-J T3 CU
QJ 43
S 60
C3 >,
• -H
\o
^
if}
00
, — 1
CN
CN
CO
C7"i
0
1-^
CN
CN
CO
a>
o
i — i
, — {
QJ
a.
o.
o
60
(3
•H
lf~^
in
•H
(3
•H
E
-H
13
*.
0
-H
(tf
M
M
0) •
4-J t>^
cO
4-J TX3"
QJ
pj
" -H
60 JH
0 3
fa Tj
2
o
m
-o-
i — i
i — i
CN
CN
on
O"\
o
I— 1
^
CN
CN
ro
CTi
O
.-H
C3
O
4J
43
60
•H a
W H
a)
4-1 rH
CO ,Q
•H
bO O
tl 3
•H J-I
•0 U
•H in
3 • OJ
QJ O
4-1 rH e
C Cu en
QJ 6
O CO »
n) on in
•r-, JrJ
T3 in in
co crj 3
T3-
60 ' — 1
C QJ rH
•rH £> CU
4-1 QJ >
O ' — !
Jw Q)
1 S S
0) CO O
rt in F-)
CO
as
CO
-^j-
, — i
CO
CN
CN
CO
C7">
0
«— i
CN
CN
CO
O^
O
rH
T3
c
ca
rH
T3
SI
ct)
60
{3
•H
^
CO
4-1
in
0)
e
rH
Pu
•
U 60
•H f3
M-t -H
q_j 43
CO O
J-I 0
4-J • Q)
rH 3
1 i (rj rj*
4-* t*
60 JJ fJ
•H 0 <#
<-l 5Z, >->
\O O^ O
i ( i i
O O O
LO O O
in in in
r~- --5
O
CO
0
^
m
0
CO
, — 1
CN
0
CN
ro
O^
0
1-1
o
CN
CO
CT»
O
, — 1
T)
0
O
£5
rH
0)
N
CO
B
p>^
v-i
OJ
>
M
O
T3
Q
•
4J
t3
OJ
'O
•H
^>
QJ
QJ
^
O
e
in
•
K*-l
rH
a
o
(3
3
J-i
J-l
3
O
X!
j
in
i — t
•
Q)
rH
43
cO
QJ
O
•H
4-1
O
C
D- 29
-------
TJ
CU
d
•H
4->
d
o
u
i
Q
W
nJ
pq
CU
cn
0)
0
3
d.
T-f
rd ^
0 0
O 4J
2; co
o m
r — •
ro
i — i
CO
, — 1
o
i—i
CN
ro
cn
O
t-H
CTv
0
CN|
ro
CTl
O
! 1
£">
4J
M
CU
n
•H
^
4J
d
0)
0
CU
J>
cd
a,
, — i
o
o
o
cn
d
o
^
^i
o
4-> >^
d -*-1
cd co
•H 3
P, *~£j
O
o
pq
o
cn
0) rH -T3
4-1 cd d
•H cd
43 «CO
13 rH d CU
1 CU O ^
43 > -H 0
CO CU CO Q
•H rH cn cn
3 -H
i — 1 *T3 0 15
43 d OJ O
3 rH
T3 O bO rH
C VJ d CU
rd bO -H !>,
r~\
^) J-4 CO "
cd cd 3 cu
M CU P-( rH
bO d 43
cd
•> W • CU
^ cu cn a •
0 S 4J -H ^
cfl 3 CO 4-1 O
rH rH 3 O T3
pq a,Tj d O
CN
u-l
m
CN
i — I
CN
r-l
CN
ro
O
r-l
r— <
1 — 1
CN
ro
cn
O
. — i
d
o
4-1
^
•H
cd
rH
U
.
*;*
<£
0)
J_J
3
4J
CO
•H
O
•V
CU
N
cd
rC
vO
f^^
O
oo
^D
O
O
LO
0
-------
CN
,—1
I
Q
H
H
in
O
CN
CN
O
J3
O
o
I-J
to
W
W
to
cq
O
*5
r-&
M
s
cy
CM
cn
*-
^
CLJ
P*
V*
CD
tn
o
" i
CO
t-l /-s
•IJ ti CO
COB
0) -H ~~v
CJ 4-1 bO
C ;l
O N— '
0
3 1?
O <4-l
rH O
pL< 03
4-)
M) 60
•H g
QJ > — '
CD
01 M
V-l CO
0) P,
,O (SI
e
S-i T3
0) 0)
4-J I — 1
rH rH
•H rt
C^H - 4J
01
C
M
CT1 rH
""O 3
ti O
Cfl rH
60 P4
C O
-H pq
0 -
O X
nJ Cfl
•Ji 0)
>-> 42
V?
, — i
oo
^
"*
00
CN
vO
CN
CTi
O
i — i
n
vO
CN
CTi
O
1 — 1
£j
0)
T3
cO
•
r~]
4-1
3
O
cn
0)
r^
4-1
O
4J
toO
O
S-I
tn
0
TJ
O
4-)
r^
60
Ai -H
CJ iJ
3
VJ
4J
g
O P-i
ti
•H
•
-d >-<
0) Q)
cn -H •
O N CJ
rH Cfl -H
o fd u-4
0) CO
CO . M
3 O 1 *
0 -H
42 4-1 C
0) IH -H
J-t nj cO
cO S-i S-i
54-14-1
0
, — 1
oo
1 — I
~*
o
00
, — 1
CN
vD
CN
ro
cn
o
, — I
, — 1
vO
CN
CO
cn
o
i — i
i-i
(U cn
> rH
CO rH
0) Cfl
pq rri
o o
c a
4J
3 •
CM
4J
ti G
cu -H
ti
•H S-l
> 0)
0) -H
N •
rH CO U
rH X -H
0) 4-4
B 4-J
co • cfl
CO S-)
4J 0) 4J
rH rH
CO 43 44
42 -H O
a. cn 3
to -H S-J
< > w
CN
CN
, — 1
< — 1
o
in
0
CN
CO
CN
co
o
• — 1
CO
CN
CTi
o
t — 1
rH
0)
a,
p.
o
rH
cd
4-1
•H
p.
CO
0
B
0
il
QJ
y
o
B
CO
^
o
cfl
rH
43
a)
cn
C
0)
Q
r--
CN
, — [
m
m
~*
in
CO
CM
CO
cn
O
1 — 1
,_]
^
vO
co
cn
0
i— i
, — r
r-H
O
4-1
r;
60
•H
VJ
pq
•
^
^
cfl
13
-*
.
O
•H
4J
CO
4-1
cn
CN
O
CN
co
cn
o
• — i
i — i
CO
CN
CO
cn
0
ti
CO
rH
T3
•H
S
W
ti r-l
O CO
•H CD
CO C
CO
•H 0)
e -^
0) O
s
rH W
Q)
£> *z
0) 0 •
rH rH T3
rH ti
5 -i S
rH
4-1
CD • CO
rH 4-1 QJ
43 ti &
•H OJ
CJ T3
3 -H -
S^ h-* fn
c_> co pq
c^
i— 1
cn
CM
~*
cn
S
ro
cn
o
1 — 1
1 — 1
CN
CO
cn
o
i — i
r-l
. — 1
C
cfl
rH
•r-l
S
rH
CO
g
O
&
, — (
00
o
^J
m
oo
t — 1
CN
in
CN
CO
cn
o
i — i
, — i
m
CN
cn
o
i— i
o
CJ
rH
W
rH
CO
e
0
&
o
CN
m
cn
"*
•o-
0)
0)
O
s
cn
T3
aj
M
r-J
^3
»-)
00
1 '
O
00
-*
cn
co
0
vO
CN
co
cn
o
^H
cn
in
CN
cn
0
H
C3
^-4
4-1
c
a)
u
•
cij
rH
43
CD
CJ
•H
4-1
0
C
o
CO
v-J
D-31
-------
13
CU
d
•H
4-J
C
O
U
I
p
w
CO
t-^
J-i
flj
e
QJ
P^
CO
~
r-l
QJ
K*
(-1
cu
CO
o
i -
CO
r-l ^N
4J dco
doe
O 4-J &C
d 3-
o -^
o
, -s
Q "-H
rH O
P-i cO
4J
60 00
•H 0
QJ --^
QJ
Cf) M
J-i CO
QJ D-
JD CO
e
D
j-i -a
01 CU
4-1 rH
i — t i — 1
•H cd
fj^, 4J
CO
C
r— 1
ai
4-1
•H
CO
^
o
CTl i — 1
rH QJ
n £>
QJ
- rH
TJ
QJ ^
r-l O
rH
W >i
d >
o cd
•H QJ
CO PC
CO
•H
6 •
QJ CO
CU •
>, r!*3 CO
> o d
cfl 0 0
QJ CO -H
rC CO
>> CO
rJ CTJ -H
<# M 0
>n oo a)
C3>
VD
CN
0
LO
LO
CN
O
OO
LO
CN
CO
CT.
O
• — i
r--
LO
CN
CO
CT*
O
1-1
0
o
s
QJ
N
Cfl
W
d
£;
0
J_l
,0
M
aj
j_i
a
•
rH
Cfl
£j
O
d
H
w
1
CO
CO
^
^
r-^
CM
0
LO
"*
OO
o
LO
-d-
CO
CTi
O
, — I
CO
^j-
CN
CO
Ol
O
i — I
r~!
t j
M
O
^
QJ
rH
o
•H
CO
•H
>
CO
QJ
B
3
rH
a,
QJ
60
a
crj
!-i
o
i
d
o
r-l
r)
T3
C
rfl
O'
O
•a
-rj
cd
J_J
W
•V
QJ
4J
•H
l r;
£2
rH
Cfl
£4
O
a
QJ
d
CO
QJ
3
a*
Q
I
CO
CO
tD
^0
QJ
^
0
6
CO
^
o
rH
rH
QJ
><
CU
rH
cfl
o.
*\
r^i
cfl
r-l
60
M
M
bO
d
•H
r^
a
d
0)
3
0*
M
60
d
•H
\j
O
o
d
o
4J
J-l
•H
cfl
rH
rj
1
CO
CO
^
CM
r^~
CM
O
f
CTi
co
CO
00
CM
(3^
0
i — i
r^.
^j-
CN
CO
CTi
O
r- 4
|>^
4-1
S-l
QJ
,Q
•H
^
.
60
d
o
1-1
4-1
CO
CO
r-l
O
-a
o
o
!-i
0
pq
•
w
d
o
•H
W
en
•H
6
cu
00
d
•H
y
O
o
rH
cfl
e
rJ
O
^
CM
O
, — i
0
o
vD
O
CN
O
LO
CN
CO
0-s
o
, — 1
CJ\
-J-
CN
O^
o
, — 1
d
o
4J
M
•H
cd
rH
o
rH
cfl
£j
o
•z,
CM
VD
1 — '
o
1^
sr
o
1 — t
oo
CO
CN
CO
CTi
o
1 — 1
f\
CO
CN
CO
CTl
0
4J
J^j
O
r-l
•H
^
d
o
rH
O
O
u
CO
4-1
cd
a
•H
\\ |
cO
r-l
4-1
QJ
rH
O
•H
QJ
£>
O
^,-
LO
1 — 1
o
CTi
00
o
CO
CO
CN
CTi
O
. — 1
LO
CO
CN
CO
CTv
O
, — 1
rj
4-1
0
to
rA
cfl
T3
d
3
CO
QJ
4-1
4-1
QJ
cfl
PL,
D- 32
-------
W
,-J
FP
H
CO
O
00
CN
o
H
O
O
erf
w
CO
PQ
O
en
r*i
Vl
cd
6
01
erf
en
••
M
11)
£>
Vl
> o o
> g -H
Cfl 4H
Q) 4-4
rC • tO
w v-i
bO G 4-J
G a)
•H Td a
pG -H -H
0 > CO
G QJ M
0) 4-J
d en
cr H ^ •
0) > O!
rJ > Cfl N
i3 3) CU n)
I-, rH rG 43
on
o
CN
CN
in
•o-
Pi
en
01
on
Q^
O
1 — f
o
Q-V
01
on
On
0
r-l
G
rrj
CO
V^
a
^3
^
4-1
O
G
Td
0)
en
O
rH
o
cu
en
3
O
("^
01
Vi
cO
13
^O
T i
•
, |
~*
£
00
CN
on
@\
0
i — i
00
oo
OJ.
on
a\
o
i — i
j_i
d)
>
CO
Q}
w
(U
N
CO
pa
•
o
•H
4-1
4-1
tfl
}_j
^
CO
, — [
rH
cd
•
cu
N
cd
PC
•
O
•r-(
4-1
4-1
03
4J
t V,
O
3
-U
^2
t^j
CQ
O
on
on
, — i
OJ
,
i\
^
VD
m
00
CN
on
a\
o
r— 1
VO
00
CN
on
CTv
o
r-(
rH
0)
CL,
rl«
O
^
<^
a;
o
e
en
^_j
o
4-1
cO
Vi
0)
G •
•H 01
CJ N
G tO
•H PC
rH
cO •
4-1 g
•H PH
P.
en Td
0 C
ON
1 — {
,
01
OO
in
CN
m
OO
CN
on
on
0
, — i
^j-
00
01
on
CTi
0
"
G
0
4-J
r?
bO
•H P,
V( i5
m H
i
en Vi
•H 01
Td i — i
p.
en g
rH CO
0) en
j>
a) x)
i — 1 Vi
cO
IS E!
O O
rH 4->
** K^
W rH
01 4-1
6 o
-3 a)
rH Vl
P. -rl
Td
01
rH Ml
rd G
•H -H •
O en Ol
3 Vi N
Vi O) CO
u p, pi!
00
CN
en
•
on
~*
S
on
oo
OJ
on
Oi
o
rH
CN
00
CN
ro
cr\
0
1 — 1
Td
C
tO
rH
T)
•H
S
•
01
N
cO
•
a
•H
4-1
4H
tO
Vi
4J
rH
cO t>»
gj>
cO
O 01
Z !ti
••* 0
, — i
O O
. •
CN r^
m on
o en
rH O
" ^
G
J5
O
4-J
o G
o ps
rH O
W Q
en
rH
O)
£>
0)
rH
[5
O
rH
*\
cn
0)
o
e
en
>,
tO
Vl
60
Td
G
cO
Td
01
erf
CTi
i — i
1 '
O
•
oo
on
on
CN
in
04
on
cr\
o
i — i
on
i~n
Osl
on
er>
o
i — i
rH
CO
M
4J
G
0)
CJ
•
JiJ
0
o
rH
£*1
N
cO
0)
,1
<-3
f-)
0)
>
•H
60
o
CO
r5^
CO
60
Td
G
co
G
O
o
A
^
CJ
tO
^Q
j "j|
<*$
*~>
i — i
r-
O
•
CN
m
i — i
m
i — i
CTi
0
on
VD
o
1 — 1
1 — 1
oo
o
on
\X)
o
* — i
i — i
o
o
^
rH
0)
N
cO
PC
0)
N
CO
PC
•
en
rH
cu
>
01
rH
0
rH
C
£j
o
J-1
rQ
•
en
cu
Ai
O
E
en
D-33
-------
CU
a
•H
4-1
C
O
u
1
p
w
t-l
CQ
CO
AS
r-l
CO
0
0)
PM
in
~
r-l
cJ
P*
"
(U
CO
,0
O
1
ro
4-J C C^T
0> -H ---
O 4-1 60
G 3.
O v^
o
s Is
Q MH
rH O
fl-l CO
4-1
60 60
•H e
QJ s /
13
C/}
6
3
25
>-i 13
0) 01
4-J i — 1
r— 1 rH
•H CO
P-. 4-1
CO
C
M
0)
4J
•H
CO
CO
£j
0
•H
co G
05 CO
•H .G
CU
M
rH 0)
CU -H
> >
CU CO
rH 0)
s
o ft cu
rH O N
rG CO
T) cn W
Q)
M p 1
0 •
H m rH
W CO
CO O &
co !H o
£3 14H C
ro
in
, — i
iy~)
^O
^j-
CJ~i
OO
CN
cn
CTi
CN
ro
crv
0
CO
CN
ro
CTv
o
rH
A!
a
o
4J 13
0 Vi
Z PQ
•
cu
rH
a.
6
§
cn
o
•H
4J
cO
4J
cn
I^>
CO
TJ
CN
i
1
O
•H
1 i
cO
cn
00
^
, — I
o
CO
VO
o
, — i
, — i
o
o
ro
vD
O
, — i
, — I
C
cn
OJ
3
rr
3 M
Q M
,
<",
O
a
CU
3
0*
13
C
cO
60
a
•H
AJ
O
O
C
O
4-1
M
•H
CO
rH
U
1
CO
CO
to
o
CO
1 — 1
o
CTi
ro
r-
o
CN
ro
O
ro
O
. — i
, — i
CM
O
ro
vO
O
, — i
i— i
j>^
4J
M
CU
O
•H
rJ
0)
N
cfl
33
•
4,1
c
G
•H
0
O
r-l
d,
>.
S-4
Q)
>
cn
SH
o
13
O
60
G
•H
O
r-l
0
pq
60
G
•H
cn
cn
•H
C*
M
CU
4J
rH
•H
MH
U-f
O
v/
0)
G
M
O
O
i — 1
rH
CO
6
CO
&
o
rH
> a)
CO 60
CU G
(~) rrj
>1 O
rH 1
rH J3
cO co
3 -H
cn c
3 &
C 0
cq
o
4J •
r-l 05
•H G
CO O
rH -H
u cn
I cn
CO -H
co E
to a)
i — i
*vO
0
CTl
LO
1 — I
UO
o
ro
VD
O
, — 1
rH
^j-
o
CO
O
, — 1
. — 1
G
0
4-J
M
•H
cfl
rH
U
CU
|CJ
4_)
01
60
0
4J
4-1
G
0)
13
•H
CU
CO
G
0
•H
CO
cn
•H
6
cu
rH
0)
£>
CU
rH
•
0)
N
CO
|~r)
.
to
Q)
e
rH
a.
^
u
cfl
4J
CO
r
N
CO
W
rH
CO
B
Vl
O
0
, — I
r — 1
0
r^
^r)-
0
. — 1
CN
rH
00
CM
ro
CJ^
O
i — i
O
oo
CM
CO
(y\
O
4J
5-1
0
^_|
•H
<;
•
0)
N
cfl
rti
a
•H
MH
MH
CO
!H
1 1
CU
rH
O
•H
CU
£>
O
t — i
CT^
O
r-
v-f-
1 — 1
r~^
CM
ro
CT*
0
rH
OO
!—-
CN
CO
C7*»
O
. — i
f~j
4J
3
O
CO
0)
4J
4-1
CU
rS
CO
^
D-34
-------
a
w
w
w
H
W
I
O
ffi
O
o
00
p^
w
>
en
w
CO
pq
O
cn
r^i
r*
rd
s
0)
PM
cn
•~
V4
QJ
r>
M
OJ
cn
XI
o
CO
4-1 GCO^
G 0 E
U 4-1 60
C 3.
O v~'
0
s "9"
O C4H
rH U
fe Cfl
,jd f — N
00 60
•H E
-i ci)
0) ft
_a CO
B
3
Z
^ XJ
Ol OJ
4-1 rH
rH rH
•H CO
fr| 4_J
cn
C
M
01
4-1
•H
CO
4J (U 1
1 ft ^> cn
rl 0) CJ -H
3 W CO 6
cn a)
o) co V4
cfl -r( « ,
O O O £
rH 4J CO rH CO
rH
60 Cfl OJ 0) 4-1
G ,C JS 60 4H •
-H ft 4J »H -H 0)
.id cn cfl M N
Vl Cfl O rH *T3 Cfl
CO 4-1 ffi
pf tr] t "] 4J
-u cn ^ 3
4J -H V-l 1-3 JD •
G S OJ rl
(!) 4J "CD
CJ T3 CU • W rH
CO 0) 0 cfl G CU
•r-> U 0) O 6
-d to O S-i -H cfl
•zQ UH in co cn cn
^D
00
m
CF>
^
'
t — 1
CM
^j-
CO
^O
o
T-H
1 1
, 1
^J-
CO
O
, — i
. — i
G
0)
cd
pq
•
a
•rl
14H
m
CO
^
4-1
G
•rl
Cfl
rl
4-1
'rj
G
cfl
^
O
3
M
4J
K^l
"T!J
cd
01
4-1
CO
VO
CM
i — i
.
CN
-d-
CM
^J-
CO
VD
O
-H
i — 1
CO
^J-
CO
MD
O
. — l
• — 1
J_j
o) cn
> H
Cfl rH
Q) Cfl
CQ fTi
.
4-1
Ol
O •
CO O
1 -H
£**> 4-1
X M-i
0 cfl
rG 4-1
4J
•H r^I
Is a
3
ofl M
G 4-1
•H
4-1 >>
4-1 T3
3 co
cj 0)
4-1
ft W
CO
t-l
CJ .
cn ,G
U
i-<3 O
m 4-i
^
00
1— 1
.
1 — 1
m
m
i — i
00
^J-
m
^o
o
1— 1
1 — 1
p^.
^J-
co
l^Q
o
, — 1
rH
, — |
01
ft
a.
o
X
^5
O
rH rH
rH r-H
0) -H
^ B
rH ft
O) -H
t> M
0) 4-1
rH K)
> 4J
0 0
OJ B
60 O
rl rl •
cO MH !H
rH 01
cn MH
0) Ol !-i
rH > Cfl
rH 43 -H CJ
cfl -H 4J CO
0CJ -r-l
3 60 T3
0 rl 3 G
13 U MH CO
CT^ 00
00 CM
in
0)
rH
0
00
CM
O
rH
m
m
'^D
CM
O
^J-
CO
MD
O
, — I
, — 1
cn
rO
CO
MD
O
, — 1
1 — 1
G
£3
O
4J
(^
O
Q
^
O
•
01
rH
•H
cn
•H
J>
W
0)
e
rH
CU
60
a
CO
o
»^j
>~>
co
CM
0
1 — 1
in
m
CM
CO
CO
vO
0
, — 1
, — (
CO
CO
CO
v£>
O
. — i
i — i
rH
Cfl
4-J
C
OJ
U
•
Q)
N
Cfl
f"1
rH
0)
>
0)
rH
CO
^
D-35
-------
T)
CU
G
•rl
4-J
G
O
O
I
P
w
CO
u
cj
CU
CO
,,
cu
i.
CU
w
J3
o
1
CO
4-1 C CO
COS
0) -H -^
CJ 4-1 OC
C 3.
0 ^
CJ)
5 g
O u-j
rH U
P-J tO
4J
to to
•H 6
cu -^
CO M
s-j m
cu a,
,T> CO
B
3
S-i T3
OJ O)
i 1 , — 1
rt
fe 4J
CO
H
QJ
4—1
CO
•
£*1
, — 1
rH
tO
a
•H
4-J
S-(
0)
£>
bO
£
•H
CO
•H
^
M
0)
B •
H O
CX TJ
o
<-3 O
>-l fs;
o>
CM
i — (
m
O
m
in
CM
CM
CO
0
1 — 1
f— i
m
CM
CO
o
! 1
. — 1
X)
o
0
rH
0)
N
tO
f\
w
4-J
to
3
13
, — 1
CU
£>
0)
r—|
[5
o
, — (
CU
G
CO
CU
3
CT1
3
a
0) 1
N CO
CO CO
33 £>
O O
*o
Cxi CM
•-0 CM
^-l CM
CO CO
o o
1 — 1 1—)
m r-t
rH CM
CO CO
v£) v£)
O O
. — 1 i — 1
r— * l — )
rM CU
a G
O CO
JZ T3 CU
M CO cr1
O S-i 3
Z FQ Q
•
0)
N
CO
w
•
J_)
O
TJ
O
M
cu
MH
! — |
3
CO
1 1
M
•
cu
, — {
^Q
•H
CO
•rf
J>
CO
a)
B
r— 4
CX
G
O
4J
(-1
•H
tO
rH
O
1
CO
CO
!=>
CO
p^
o
o
~*
1 — 1
, — 1
0
CO
CO
o
'
a-i
CM
CO
vD
o
• — i
i — i
K^
4_)
rJ
a) o
•H 0
CO
CO Ai
C a
0 3
•H M U-(
CO HO
CO T3
•H M . _a
6 co cu 4-i
CU > rH 3
O J3 O
rH 4-> CO CO
cu cu
> 4J O Cl)
CU CO -H rH
rH CU 4-1 -H
S o a,
3 G
O 0) 60
rH J^ M CO
4J O iH
G Tt CO
O O O
4J 4J 0
M 4-f
•H 60 •
CO G rJ M J-!
rH -H (D G O rH
O 4J rH -H 4J CO
1 LH o, > -H B
en -H 6 -H G C
co l-i co S-i o O
p T3 CO T3 g ^
O r~~
C^ 00
in in
\£> 00
m --)
M O
•H Cu
tO M
rH -H
CJ
r^-.
O
.—i
in
o
i — i
CO
CO
CO
0
I— 1
1 —
CO
CO
o
""*
CU
4J
rG 4-J
4-J CU
3 >>
O CO
CO fn
D-36
-------
vD
r~-
cr>
I
o
w
pq
w
m w
W
rJ
PQ
<
H
erf
o
O
O
rJ
CO
PL]
w
pa
o
CO
1^
cfl
6
QJ
erf
CO
(_i
Q)
S-i
QJ
Cfl
O
1
cfl
S-l /-N
4-1 Gen
cog
QJ -H \
CJ 4-1 DC
C 3-
o ^
0
S E
O U-l
rH CJ
PM Cfl
u
bO &0
•H e
0) N-'
QJ
C/) S-4
QJ P,
E
3J Q)
i-J i — (
i — t rH
pM 4->
CO
(3
H
QJ
j i
C.O
•
CO
G
o
•H
CO
cn
•H
B
Q)
p<_j
o
pq
i — |
QJ
QJ
rH
J5
O
rH •
Q)
i-J N
i-3 cfl
*~3 ffi
p^
O
r-»
m
-a-
CO
cn
(N
r-^
CM
cn
cn
o
. — i
i — i
t~~^
CM
cn
cn
o
i — i
G
QJ
""0
cfl
pq
•
QJ
N
Cfl
ffi
CM
CN
cn
0
•
vD
CM
cn
cn
o
SH
01 CO
> rH
Cfl rH
0) Cfl
pT) fij
o
4J
CO •
!-! QJ
0) N
) 1 (rj
QJ rc
6
o •
0 S-i
.—l OJ
rH
oo a,
G e
•H cfl
G M
S_j
^3 UH
43 O •
i — i
r£ X Cfl
cn -u S
Cfl S-I M
S-i O O
H G tt
VD 00
LO r^-
i — i • — i
cn vo
in vo
^i" •<}"
vD 00
CT> cn
CN cn
oo a\
vO CM
CN CTl
cn o
Oi ^-1
O ^-l
i — i i — i
r-. oo
vD CN
CN C3%
cn o
cn ^i
O --I
i — i . — i
G
0
rH 4-1
QJ 42
p, tjQ
PH -HO,
O S-i 13
w pq H
0 1
i — I O
4-1
T3 pl-l
G pq 60
cfl G
" -H
^ oo s
O G O
CO -H rH
4_> ^ 43
tO O
... a -d
V G
' — • « *H
^ C/} fe
w C
i O • ^ •
•H -H 60 M
2 to G 0 M
S-i Q) -d cfl
O rH O I?
-j-
o
-<)•
m
o
•*3*
VD
VD
cn
cn
CN
cn
o
,—i
CN
cn
CN
cn
cn
o
i — i
G
cfl
rH
rrj
•H
s
OJ 1
rH 6
43 cfl
•H CO
CO
•H S
> O
(-1
QJ UH
S
3 >,
rH CO
cfl
rH
Cfl 00
a c
-H -H •
S to Q)
Q) S-i N
.a QJ cfl
u a, re
to
""0 *rH
Q) TJ •
•H S-l
rH 4J QJ
rH D rH
<£ 43 p(
cfl
CN
1
u
•rH
4J
cfl
4J
to
CN
cn
VO
o
• — t
1 — 1
cn
CN
cn
o
T—l
. 1
O
4-1
C
0
Q
Q)
4-1
•H
rj
jj
rrj
G
CD
Q)
&o •
G Q)
Cfl rH
S-l 43
O -H
to
" -r)
cfl
S-l U)
GO 0)
B
<*3 i — 1
>-J P<
CT>
, — i
CM
0
OO
<*•
CN
~3"
00
CM
cn
vO
0
i — i
i — i
CM
rn
vD
O
"^
rH
cfl
S-i
4-J
G 43
QJ rfl
U rJ
.
Q)
N
i
r^-.
cn
, — i
O
o
in
0
00
CN
-------
tt)
c
•H
4-1
f2
O
Q
W
cf
•-£
J-l
CO
6
d
P^
CO
"•
J-
CL
K*
J-l
a
CO
43
O
1
cd
M
4-J C
C 0
0) -H
0 4-1
C
o
u
•s
o
rH
p-l
u
42
bO
•H
CU
CO
J-l
0)
43
E
3
Z
J-i
CU
4-J
rH
• H
r£-l
C
, — s
CO
e
£0
^L
x-^
,-v
U-l
u
0)
•• — '
60
6
01
j-i
cd
p.
co
TJ
CU
rH
rH
CO
4-J
CO
G
0)
4-1
H
/>
1
s
0
O
0)
rH
o
-H
CO
-H
>
0)
e
3
i — 1
P.
G
O
4-1
J_l
•H
cO
rH rH
CO • U
e
*•£> ^D
O O O
•— 1 i—4 .—I
i — 1 i — 1 i — 1
^D on oo
OO CO OO
on on on
vD vD vO
O O O
1 1 1 1 T— 1
1 — 1 1 — 1 . — 1
£6 CU
O C >.
C CO 4-1
42 T3 CU J^
4-J T) 3 CU
^4 Cd U~* , O
O >-J 3 H -H
!3 pq Q M ,-J
•
j-i
O
T3
0
tiO
G
O
J-i
4-1
OO
•
, — 1
1 — I
•H
(~{
J-)
CU
>
0
60
G
•H
O
j^
O
•
c
o
•H
CO
w
CU
CO
c
•H
rH
O
0
O
CO
•
d)
N
CO
M
•
CO
0)
42
CO
rj
p,
c
cu
cu
J_l
60
G
o
4-1
J-l
•H
CO
rH
O
CO
CO
^
r-
CM
, — I
in
,
vO
LO
cn
CTi
CM
CM
OO
on
*>Q
0
f— i
r-H
i—(
CO
CO
vD
o
t-H
. — 1
C
o
4-1
J_)
•H
cd
rH
CJ
rH 3
rH
cfl T)
QJ
Cfl 4-J
^ r2
o cu
CO -H
4-J J-i
CO o
- W
60 CU
c e
-H 3
42 rH
O p^
C
cu
3 •
cr
- -H
60 4J
G 0
•H CO
60
M >>
CO rJ
42 CU
0 >
Cfl
J-l
0)
T3
cd
^
O
•
4-1
CO
cO
cu
r°t
J-)
J-l
O
G
O
4-1
rH
rH
•H
r;
M
0)
O
CO
0)
J-i
cd
4J
J-l
•H
TJ
G
•H
60
G
•H
^
j-j
0
CO
J-l
CU
N
O
T3
T3
G
cO
•
J-i
O
4-1
•H
G
O
0
MH
0
42
4_i
^_l
O
0
4J
CO
J-l
0)
4-1
CU
6
o
U~l
4-)
CO
3
T3
rH
CU
>
CD
rH
5
O
rH
U-l
o
CO
"0
3
O
rH
O
CU
60
Jj
cd
J
•
0)
N
n3
33
•
e
o
4-1
0)
lJ
0)
r)
4J
4J
rH
3
w
01
•
CU
rH
43
CO
C
O
•H
4J
W
0)
3
0*
A
£g
o
rH
J-l
3
O
42
LT^
.
0
. — 1
r-
0
CM
0
00
P--
1 — 1
LT)
CTi
CM
on
CTi
o
^J-
CTi
CN
on
o
i — i
4-1
^
O
p,
J-l
•H
<
.
G
0
•H
CO
CO
cu
CO
G
•H
rH
o
o
O
CO
U~]
~^f
i — i
O
J-^
-d-
00
r~-
CM
• — I
, — I
on
VD
O
> — l
. — i
O
.—1
on
o
, — i
—i
42
4J
3
O
CO
01
4-1
4J
CU
K^I
CO
PM
D-38
-------
D.4 FILTER ANALYSIS RESULTS
This section presents the results of the optical microscopy, scan-
ning electron microscopy (SEM) and energy-dispersive X-ray (EDAX)
analyses of the hi-vol filter samples from the fifteen monitor locations
described in Section D.I. Although filter samples were collected on six
days, three of the sampling days were determined to be unsuitable for de-
tailed analyses because of the frequent occurrance of calm or light and
variable winds during the 24-hour sampling period. The three sample
days selected for hi-vol filter analysis are 16 August, 28 August and
9 September 1976. (SEM results are also given for the Liberty Boro
monitor on 22 August 1976.)
Tables D-16 through D-88 give the results of the particle count
analyses performed by optical microscopy. Each table lists, for the
primary filter alone, the cover filter alone or the primary and cover
filters in combination, the filter number(s), the monitor location,
the sample day, the particulate loading on the filter(s) as determined
by the Coors Spectro-Cheraical Laboratory and the 24-hour average part-
iculate concentration. Each table also gives the concurrent filter
particulate loading and 24-hour average particulate concentration for
the colocated monitor operator by the Pennsylvania Department of Envi-
ronmental Resources (DER) or the Allegheny County Bureau of Air Pollu-
tion Control (BAPC). In the optical microscopy analysis, the particu-
lates were classified according to six generic categories: (1) flyash,
(2) iron oxide, (3) magnetic iron oxide, (4) quartz, (5) biologicals and
(6) CaCo,.. The particle counts in the tables refer to a filter segment
with an area of 0.00968 square centimeters. As explained in Section 3.6,
the particle counts in each generic category and size range were used
with the particle densities assigned to each generic category to calcu-
late the particulate mass on this filter segment. Under the assumption
of uniform particulate loading on the filter, the total particulate mass
on the entire filter was obtained by multiplying the mass of the filter
D-39
-------
segment by the ratio of the total filter area to the area of the filter
segment. Both the calculated mass and the total measured mass deter-
mined by the filter weight are entered at the top right of each table.
Tables D-89 through D-167 give the results of the SEN filter
analyses. The format for Tables D-89 through D-167 is the same as
for Tables D-16 through D-88 except that, in the SEM analysis, the
particles were classified according to the following three generic
categories: (1) spheres,(2) irregularly-shaped particles, and (3)
agglomerates. The particle counts in Tables D-89 through D-167 refer
to a filter segment with an area of 0.02053 square centimeters. As a
consistency check, two separate SEM filter analyses were performed on
the filter from the Central Laboratory monitor for 9 September 1976,
the North Braddock monitor for 9 September 1976 and the Liberty Boro
monitor for 28 August 1976. The results of both analyses are included
in the tables (for example, see Tables D-148 and D-149).
The results of both the optical microscopy and SEM analyses were
used to estimate the distributions of mass by particle diameter. For
each filter and for each particle size category, the combined mass of
particles in the six (optical microscopy) or three (SEM) generic par-
ticle categories was calculated using the procedures outlined in
Section 3.6. These results were then combined to form the cumulative
mass distributions by particle diameter shown in Figures D-6 through
D-ll. (The contributions of biological particles are removed from the
optical microscopy results in Figures D-6 through D-8.) Each figure
contains fifteen cumulative mass distributions, corresponding to the
fifteen ^articulate monitoring sites. The mass distributions in each
figure are identified by the monitor site number given in Table D-l.
On the basis of the hourly wind speeds and wind directions for
the sampling days as well as the monitor locations, the filters were
assigned to one of three categories: (1) industrial, (2) urban, or
D- 40
-------
(3) rural. The industrial filters were Baden, Midland, Hazelwood and
Clairton on 16 August 1976 and Baden, Midland, North Braddock and Liberty
Boro on both 28 August and 9 September 1976. The Downtown and Central
Laboratory filters were placed in the urban classification on all three
sampling days. Similarly, the Brighton Township, Elco, Greater Pittsburgh
Airport and South Fayette filters were placed in the rural classification
on all three sampling days.
Figure D-12 shows the cumulative mass distribution by particle diameter
for all of the filters analyzed by optical microscopy which have a calculated
filter loading greater than or equal to 100 milligrams. The industrial,
urban and rural cumulative mass distributions derived from these filters
are plotted respectively in Figures D-13, D-14 and D-15. Similarly,
Figure D-15 shows the cumulative mass distribution by particle diameter
for all of the filters analyzed by SEM techniques which have a calculated
filter loading greater than or equal to 100 milligrams. The corresponding
industrial, urban and rural cumulative mass distributions are plotted
respectively in Figures D-17, D-18 and D-19.
Energy-dispersive X-ray (EDAX) analyses were performed on a number of
filters. The surface of each SEM filter stub analyzed by EDAX scan was
made of the entire surface. The height of each integral energy peak record-
ed during the EDAX scan was divided by the height of the integral energy
peak of gold to obtain a ratio which was essentially free of the effects
of any discrepancies between filters in counting rates, beam intensities,
etc. With the exception of copper, mercury, arsenic and lead, the thres-
hold energy ratio for elements present in larger than trace quantities
was arbitrarily set at 0.10, and the elements were ranked according to
descending magnitude of the energy ratio. The threshold ratio for the
trace elements of copper, mercury, arsenic and lead was set equal to 0.03.
The results of the EDAX analyses for 16 August, 18 August and 9 September
1976 are given respectively in Tables D-168, D-169 and D-170. Elements
with an energy peak much larger than the normal peaks are underlined in the
tables.
D-41
-------
For a selected subset of the filters, an SEM-EDAX analysis was
perfomed for twelve to twenty particles on each filter. Tables D-171
through D-216 summarize the results of these analyses. For each particle,
the elements which comprise the particle are listed in descending order
of the ratio of the integral energy peak of the element to the integral
energy peak of gold. Elements with energy peaks much larger than the
usual peaks, are underlined in the tables. Tables D-171 through D-216
also give, for each particle, the particle diameter in microns (micro-
meters), the particle description (spherical, irregularly-shaped or
agglomerate) and a tentative identification of the particle type or
origin. We point out that all of the particles considered in Tables
D-171 through D-216 had diameters larger than 5 micrometers. SEM
photographs of some of the selected filters are shown in Figures D-20
through D-30.
A number of large particles with diameters greater than 40 micro-
meters observed on the filters were analyzed using the SEM-EDAX tech-
niques described above. The results of these analyses of selected large
particles are presented in Tables D-217 through D-224, and photomicro-
graphs containing these particles are shown in Figures D-31 through D-86.
Five very large particles with diameters greater than 100 micrometers
were also analyzed. The elemental analysis of these particles is pre-
sented in Table D-225, the descriptions and possible identifications
are given in Table D-226, and photomicrographs are shown in Figures
D-87 through D-91.
Slag produced by the steel industry is found throughout southwest
Pennsylvania in slag dumps and has been extensively used in road and
building construction. Therefore, slag particles are likely to be a
primary constituent of non-traditional fugitive emissions. We there-
fore performed an analysis of samples of the different types of slag
found in the area to determine the correlation between the elemental
compositions of these slag samples and the compositions of some of the
particles found on the hi-vol filters.
D-42
-------
Tables D-227 through D-229 give the results of the elemental analyses
of the slag samples. The particles from the samples were divided into
two groups, one containing large particles (diameters of the order of
100 micrometers) and one containing small particles (diameters of the
order of 10 micrometers). Table D-227A gives the results of the analysis
of large particles contained in slag samples from an electric arc fur-
nace and Table D-227B gives the results of the analysis of some of the
small particles found on the surface of these large slag particles
Photomicrographs of these samples are shown in Figures D-92 through D-101.
Similarly, Table D-227C gives the results of the analysis of the small
particulates contained in slag samples from an electric arc furance and
Table D-227D gives the results of the analysis of some of the smaller
particles found on the surface of these small slag particles. Photomicro-
graphs of these samples are shown in Figures D-102 through D-112. The
analyses of large particles from a blast furnace and the small particles
found on their surfaces are summarized in Tables D-228A and D-229B.
The photomicrographs of these particles are shown in Figures D-113 and
D-114. The elemental analyses of large slag particles from a basic
oxygen furnace and the smaller particles found on their surfaces are
summarized in Tables D-229A and D-229B. Figures D-115 and D-116 show
the corresponding photomicrographs.
Walter C. McCrone Associates, Inc. used optical microscopy to
analyze six selected filters as a check on the validity of the SEM and
Coors optical microscopy analyses. Tables D-230 through D-236 summarize
the results of the McCrone analyses. These tables give the percent by
number of particles within various size ranges for three general particle
categories: (1) combustion products, (2) minerals, and (3) biological
materials.
D-43
-------
TABLE D-16 through D-88 - RESULTS OF OPTICAL PARTICLE COUNTS
D-44
-------
TABLE D-16
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093219 Total Mass of Particulates (mg) :
Coors: 164 Agency: 139
Monitor Location: Baden Calculated Mass (mg): 261
Date of Sample: 8/16/76 Air Concentration (yg/m3) :
Coors: 86 Agency: 67
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75|j
>75y
Totals
Magnetic
Iron
5-10y
10-2 On
20-50y
50-75y
>75y
Totals
Particle
Count
300
78
23
3
4
408
34
11
0
0
0
45
31
10
3
0
0
44
Percent By
Number
52.3
13.6
4.0
0.5
0.7
71.1
5.9
1.9
0
0
0
7.8
5.4
1.7
0.5
0
0
7.7
Percent By Mass
All
Categories
1.8
3.8
15.3
10.0
35.9
66.9
0.7
1.8
0
0
0
2.4
0.6
1.6
6.5
0
0
8.8
Within
Category
2.8
5.7
22.9
14.9
53.6
100
27.9
72.1
0
0
0
100
7.1
18.4
74.5
0
0
100
-------
TABLE D-16
RESULTS OF OFF!CM, PARTICLE COUNTS
(Conlinued)
Filter Number: 1093219 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75u
Totals
CaC00
1 O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
15
1
9
1
0
26
11
10
3
0
0
24
18
6
3
0
0
27
574
(All Categories)
i
Percent By
Number
2.6
0.2
1.6
0.2
0
4.5
1.9
1.7
0.5
0
0
4.2
3.1
1.0
0.5
0
0
4.7
100
Percent By Mass
All
Categories
0.2
0.08
10.0
5.6
0
15.8
0.04
0.3
1.3
0
0
1.7
0.2
0.5
3.6
0
0
4.3
100
Within
Category
1.0
0.5
63.3
35.2
0
100
2.6
19.2
78.1
0
0
100
4.6
12.3
83.1
0
0
100
-------
TABLE D-17
RESULTS OF OPTICAL PARTICLE (DIM'S
Filter Number: 1093221 Total Mass of Particulates (nig):
Coors: 152 Agency: 12?
Monitor Location: Beaver Falls Calculated Mass (mg): 246
3
Date of Sairple: 8/16/76 Air Concentration (yg/m ):
Coors: 86 Agency: 61
Category
Flyash
5-10y
10-20u
20-50y
50-75u
>75p
Totals
Iron Oxide
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
278
47
13
1
6
345
10
1
0
0
0
11
8
1
0
0
0
9
Percent By
Number
64.8
11.0
3.0
0.2
1.4
80.4
2.3
0.2
0
0
0
2.6
1.9
0.2
0
0
0
2.1
Percent By Mass
All
Categories
1.8
2.5
9.2
3.5
57.2
74.2
0.2
0.2
0
0
0
0.4
0.2
0.2
0
0
0
0.4
Within
Category
2.4
3.3
12.4
4.8
77.1
100
55.6
44.4
0
0
0
100
50.0
50.0
0
0
0
100
-------
TABLE D-17
RESULTS OF 01T1CAL PARTICLE COUNTS
(Continued)
Quartz
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10n
10-20y
20-50y
50-75y
>75y
Totals
CaCCX,
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TarALS
(All CatrfTori
Filter Number
Particle
Count
15
4
3
0
0
22
8
6
3
0
3
20
22
0
0
0
0
22
429
rs)
' : 1093221
Percent By
Number
3.5
0.9
0.7
0
0
5.1
1.9
1.4
0.7
0
0.7
4.7
5.1
0
0
0
0
5.1
100
(Continued)
Percent
All
Categories
0.2
0.3
3.5
0
0
4.0
0.03
0.2
1.4
0
19.1
20.7
0.2
0
0
0
0
0.2
100
By Mass
Within
Category
4.0
8.6
87.3
0
0
100
0.2
1.0
6.8
0
92.0
100
100
0
0
0
0
100
-------
TABLE D-18
RESULTS OF OPTICAL PAOTICLE COUNTS
Filter Number: 1093223
Monitor Location: Koppel
Date of Sarrple: 8/16/76
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20)i
20-50y
50-75y
>75y
Totals
Particle
Count
240
56
26
6
6
334
32
0
0
0
0
32
0
0
0
0
0
0
Total Moss oT Particulates (mg) :
Coors: 189 Agency: 161
Calculated Mass (mg): 277
3
Air Concentration (yg/nf):
Coors: 90 Agency: 86
Percent By
Number
53
12
5
1
1
.1
.4
.8
.3
.3
73.9
7.1
0
0
0
0
7.1
0
0
0
0
0
0
Percent By Mass
AJ1
Categories
1.4
2.6
16.3
18.9
50.8
90.0
0.6
0
0
0
0
0.6
0
0
0
0
0
0
Within
Category
1.5
2.9
18.2
21.0
56.4
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-18
RESULT OF OPTICAL PARTICLE COUNTS
(Continued)
Quartz
5-10y
10-20y
20-5'Oy
50-75y
>75fj
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO3
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
F: 1 ter Number
Particle
Count
11
6
2
0
0
19
10
14
0
0
1
25
40
2
0
0
0
42
452
OS)
• : 1093223
Percent By
Number
2.4
1.3
0.4
0
0
4.2
2.2
3.1
0
0
0.2
5.5
8.8
0.4
0
0
0
9.3
100
(Continued)
Percent
All
Categories
0.1
0.5
2.1
0
0
2.7
0.04
0.4
0
0
5.6
6.1
0.4
0.2
0
0
0
0.6
100
By Mass
Within
Category
4.0
17.4
78.6
0
0
100
0.6
7.1
0
0
92.3
100
71.4
28.6
0
0
0
100
-------
TABLE D-19
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093225 Total Mass of Particulates (mg):
Coors: 119 Agency: 162
Monitor Location: Brighton Calculated Mass (mg): 79
Township
3
Date of Sample: 8/16/76 Air Concentration (]Jg/m ):
Coors : 65 Agency : 87
Category
Flyash
5-10i i
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20M
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50p
50-75y
>75{j
Totals
Particle
Count
190
40
14
1
1
246
34
2
0
0
0
36
0
0
0
0
0
0
Percent By
Number
48.8
10.3
3.6
0.2
0.2
63.2
8.7
0.5
0
0
0
9.2
0
0
0
0
0
0
Percent By Mass
All
Categories
3.8
6.5
30.7
11.0
29.6
81.7
2.2
1.1
0
0
0
3.3
0
0
0
0
0
0
Within
Category
4.7
8.0
37.6
13.4
36.2
100
68.0
32.0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-19
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093225 (Continued)
Category
Quartz
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75y
Totals
CaC00
o
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
19
6
2
0
0
27
28
17
1
0
0
46
32
2
0
0
0
34
389
(All Categories)
Percent By
Number
4.9
1.5
0.5
0
0
6.9
7.2
4.4
0.2
0
0
11.8
8.2
0.5
0
0
0
8.7
100
Percent By Mass
All
Categories
0.6
1.6
7.3
0
0
9.6
0.4
1.8
1.5
0
0
3.7
1.2
0.6
0
0
0
1.8
100
Within
Category
6.7
16.9
76.4
0
0
100
10.3
50.0
39.7
0
0
100
66.7
33.3
0
0
0
100
-------
TABLE U-20
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093227 Total Mass of Particulates (mg):
Coors: 149 Agency: 166
Monitor Location: Midland Calculated Mass (ing): 306
3
Date of Sample: 8/16/76 Air Concentration (pg/m ):
Coors: 83 Agency: 80
Category
Flyash
5-10y
10-20p
20-50p
50-75y
>75y
Totals
Iron Oxide
5-10u
10-20p
20-50y
50-75p
>75y
Totals
Magnetic
Iron
5-10p
10-20p
20-50p
50-75p
>75y
Totals
Particle
Count
259
62
16
2
2
341
15
10
0
0
0
25
0
0
0
0
0
0
Percent By
Number
55.7
13.3
3.4
0.4
0.4
73.3
3.2
2.2
0
0
0
5.4
0
0
0
0
0
0
Percent By Mass
All
Categories
1.4
2.6
9.1
5.7
15.3
34.1
0.2
1.4
0
0
0
1.6
0
0
0
0
0
0
Within
Category
4.0
7.6
26.7
16.7
45.0
100
15.8
84.2
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-20
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093227 (Continued)
Category
Quartz
5-10y
10-20u
20-50u
50-75]j
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOo
O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
19
15
12
2
0
48
19
2
1
3
7
32
18
1
0
0
0
19
465
-6S)
Percent By
Number
4.1
3.2
2.6
0.4
0
10.3
4.1
0.4
0.2
0.6
1.5
6.9
3.9
0.2
0
0
0
4.1
100
Percent By Mass
All
Categories
0.2
1.0
11.4
9.5
0
22.1
0.07
0.06
0.4
5.7
35.8
42.0
0.2
0.08
0
0
0
0.2
100
Within
Category
0.8
4.8
51.5
43.0
0
100
0.2
0.1
0.9
13.6
85.2
100
69.2
30.8
0
0
0
100
-------
TABLE D-21
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093228 Total Mass of Participates (mg):
(Cover Filter) „ .
v Coors: — Agency:
Monitor Location: Midland Calculated Mass (rng): 166
3
Date of Sample: 8/16/76 Air Concentration (ug/m ):
(Cover Filter for 1093227) Coors: — Agency:
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75,j
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
108
43
10
1
2
164
5
14
0
0
0
19
0
0
0
0
0
0
Percent By
Number
42.8
17.1
4.0
0.4
0.8
65.1
2.0
5.6
0
0
0
7.5
0
0
0
0
0
0
Percent By Mass
All
Categories
1.0
3.3
10.5
5.2
28.2
48.3
0.2
3.5
0
0
0
3.7
0
0
0
0
0
0
Within
Category
2.2
6.9
21.7
10.8
58.4
100
4.3
95.7
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-21
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: (Cover Filter\Continued)
1093228
Category
Quartz
5-10(j
10-20y
20-50n
50-75)j
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75u
>75y
Totals
CaCO0
O
5-lOy
10-20y
20-50u
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
16
8
7
0
0
31
10
10
3
1
3
27
11
0
0
0
0
11
252
.es)
I
Percent By
Number
6.3
3.2
2.8
0
0
12.3
4.0
4.0
1.2
0.4
1,2
10.7
4.4
0
0
0
0
4.4
100
Percent By Mass
All
Categories
0.2
1.0
12.2
0
0
13.5
0.06
0.5
2.1
3.5
28.2
34.4
0.2
0
0
0
0
0.2
100
Within
Category
1.9
7.6
90.4
0
0
100
0.2
1.5
6.1
10.2
82.1
100
100
0
0
0
0
100
-------
TABLE D-22
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093213 Total Mass of Particulates (mg):
Coors: 147 Agency: 100
Monitor Location: Elco Calculated Mass (mg) : 143
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors: 66 Agency: 46
Category
F_lyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75p
>75y
Totals
Magnetic
Iron
5-lOy
10~20y
20-50y
50-75y
>75y
Totals
Particle
Count
186
36
18
4
1
245
5
3
0
0
0
8
0
0
0
0
0
0
Percent By
Number
57.0
11.0
5.5
1.2
0.3
75.2
1.5
0.9
0
0
0
2.4
0
0
0
0
0
0
Percent By Mass
All
Categories
2.1
3.2
21.9
24.4
16.4
68.0
0.2
0.9
0
0
0
1.1
0
0
0
0
0
0
Within
Category
3.1
4.8
32.2
35.8
24.1
100
17.2
82.8
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-22
RESULTS OF OFHCAL PARTICLE COUNTS
(G niLinued)
Filter Number: 1093213 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Biological
5-10jj
10-20y
20-50u
50-75p
>75]j
Totals
CaCOQ
O
5-10p
. 10-20y
20-50y
50-75}j
>75p
Totals
TOT'ALS
(All Category
Particle
Count
11
4
1
0
0
16
35
18
1
1
2
57
0
0
0
0
0
0
326
ics)
Percent By
Number
3.4
1.2
0.3
0
0
4.9
10.7
5.5
0.3
0.3
0.6
17.5
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.2
0.6
2.0
0
0
2.8
0.3
1.1
0,8
4.1
21.9
28.1
0
0
0
0
0
0
100
Within
Category
7.3
21.2
71.6
0
0
100
0.9
3.8
2.9
14.5
77.9
100
0
0
0
0
0
0
-------
TABLE D-23
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093215
Monitor Location: Downtown
Date of Sample: 8/16/76
Category
Flyash
5-lOu
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20u
20-50y
50~75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
333
83
22
1
0
439
21
0
0
0
0
21
24
8
0
0
0
32
Total Mass of Particulates (nig):
Coors: 284 Agency: 241
Calculated Mass (mg): 222
3
Air Concentration (yg/m ) :
Coors: 139 Agency: 110
Percent By
Number
57
14
3
0
75
.2
.3
.8
.2
0
.4
3.6
0
0
0
0
3.6
4.1
1.4
0
0
0
5.5
Percent By Mass
All
Categories
2.4
4.8
17.3
3.9
0
28.4
0.5
0
0
0
0
0.5
0.6
1.5
0
0
0
2.1
Within
Category
8.5
16.9
60.7
13.8
0
100
100
0
0
0
0
100
27.2
72.7
0
0
0
100
-------
TABLE D-23
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093215 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75u
>75y
Totals
Biological
5-10n
10-20y
20-50u
50-75y
>75y
Totals
CaCO0
>j
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
17
26
11
2
2
58
10
21
0
1
0
32
0
0
0
0
0
0
582
(All Categories)
I
Percent By
Number
2.9
4.5
1.9
0.3
0.3
10.0
1.7
3.6
0
0.2
0
5.5
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.2
2.5
14.4
13.1
35.3
65.5
0.05
0.8
0
2.6
0
3.5
0
0
0
0
0
0
100
Within
Category
0.3
3.8
22.0
20.0
53.8
100
1.4
23.4
0
75.2
0
100
0
0
0
0
0
0
-------
TABLE D-24
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1Q93241
Monitor Location: Central Lab
Date of Sample: 8/16/76
Category
Flyash
5-10u
10-20u
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75}j
Totals
Particle
Count
229
81
26
1
1
338
42
6
0
0
0
48
15
14
1
0
0
30
Total Mass of Particulates (mg):
Coors : 234 Agency : 202
Calculated Mass (mg): 155
3
Air Concentration (yg/m ):
Coors : HO Agency : 9?
Percent By
Number
46.
16.
5.
0.
0.
68.
8.
1.
3
4
2
2
2
3
5
2
0
0
0
9.
3
2
0
7
0
8
2
0
0
6
1
Percent By Mass
All
Categories
2.4
6.7
29.1
5.6
15.1
^ 58.9
1.4
1.6
0
0
0
3.0
0.5
3.8
3.7
0
0
8.0
Within
Category7
4.0
11.4
49.4
9.5
25.6
100
46.7
53.3
0
0
0
100
6.4
47.6
46.0
0
0
100
-------
TABLE D-24
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093241 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75u
>75y
Totals
Biological
5-10y
10-20y
20-50jj
50-75y
>75y
Totals
CaCOg
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
15
5
4
1
0
25
2
7
5
1
0
15
25
13
1
0
0
39
495
(All Categories)
i
Percent By
Number
3.0
1.0
0.8
0.2
0
5.0
0.4
1.4
1.0
0.2
0
3.0
5.0
2.6
0.2
0
0
7.9
100
Percent By Mass
All
Categories
0.2
0.7
7.5
9.3
0
17.8
0.1
0.4
3.7
3.7
0
7.9
0.5
1.9
2.0
0
0
4.4
100
Within
Category
1.5
3.9
42.0
52.6
0
100
0.2
4.9
47.4
47.5
0
100
10.5
43.8
45.6
0
0
100
-------
TABLE D-25
RESULTS OF OPTICAL PAHT1CLE COUNTS
Filter Number: 1093201 Total Mass of Particulates (mg) :
Coors: igo Agency: 191
Monitor Location: Hazelwood Calculated Mass (mg): 218
3
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors: 131 Agency: 105
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75p
>75M
Totals
Magnetic
Iron
5-K)n
10-20y
20-50y
50-75y
>75p
Totals
Particle
Count
480
78
15
6
4
583
29
9
1
0
0
39
0
0
0
0
0
0
Percent By
Number
72.6
11.8
2.3
0.9
0.6
88.2
4.4
1.4
0.2
0
0
5.9
0
0
0
0
0
0
Percent By Mass
All
Categories
3.5
4.6
12.0
23.9
43.0
87.0
0.7
1.7
2.6
0
0
5.0
0
0
0
0
0
0
Within
Category
4.1
5.3
13.7
27.5
49.4
100
13.9
34.4
51.7
0
0
100
0
0
0
0
0
0
-------
TABLE D-25
RESULTS OF OPHCAL PARTICLE COUNTS
(ConLJnued)
Filter Number: 1Q93201 (Continued)
Category
Quartz
5-10u
10-20u
20-50u
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50u
50-75y
>75y
Totals
CaCOQ
• o
5-10y
10-20y
20-50y
50-75u
>75y
Totals
1DTALS
(All Categor]
Particle
Count
14
7
0
1
0
22
3
4
0
0
0
7
8
2
0
0
0
10
661
_es)
1
Percent By
Number
2.1
1.0
0
0.2
0
3.3
0.4
0.6
0
0
0
1.0
1.2
0.3
0
0
0
1.5
100
Percent By Mass
All
Categories
0.2
0.7
0
6.6
0
7.5
0.01
0.2
0
0
0
0.2
0.1
0.2
0
0
0
0.3
100
Within
Category
2.3
9.2
0
88.5
0
100
8.6
91.4
0
0
0
100
33.3
66.7
0
0
0
100
-------
TABLE D-26
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093203 Total Mass of Particulates (mg) :
Coors: 155 Agency: 126
Monitor Location: North Braddock Calculated Mass (mg): 317
3
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors : 79 Agency : 63
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
229
40
15
9
2
295
26
2
0
0
0
28
0
0
0
0
0
0
Percent By
Number
53.9
9.4
3.5
2.1
0.5
69.4
6.1
0.5
0
0
0
6.6
0
0
0
0
0
0
Percent By Mass
All
Categories
1.2
1.6
8.2
24.7
14.8
50.6
0.4
0.3
0
0
0
0.7
0
0
0
0
0
0
Within
Category
2.3
3.2
16.3
48.9
29.3
100
61.9
38.1
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-26
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093203 (Continued)
Category
Quartz
5-10jj
10-2 Oy
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75)j
>75y
Totals
CaOO,
5-10y
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
(All Categora
Particle
Count
16
2
2
0
0
20
15
27
14
6
6
68
14
0
0
0
0
14
425
es)
Percent By
Number
3.8
0.5
0.5
0
0
4.7
3.5
6.4
3.3
1.4
1.4
16.0
3.3
0
0
0
0
3.3
100
Percent By Mass
All
Categories
0.1
0.1
1.8
0
0
2.1
0.05
0.07
5.1
11.0
29.6
46.5
0.1
0
0
0
0
0.1
100
Within
Category
6.4
6.4
87.1
0
0
100
0.1
1.6
11.0
23.6
63.6
100
100
0
0
0
0
100
-------
TABLE D-27
RESULTS OF OPTICAL PAHTICLE COUNTS
Filter Number: 1093205 Tot.al Mass of Particulates (mg) :
Coors: 231 Agency: 211
Monitor Location: Duquesne II Calculated Ntiss (mg): 157
3
Date of Sample: 8/16/76 Air Concentration (ug/m ):
Coors: 145 Agency: 107
Category
Flyash
5-lOu
10-20^
20-50y
50-75u
>75jj
Totals
Iron Oxide
5-10p
10-20y
20-50)j
50-75u
>75u
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75(J
>75y
Totals
Particle
Count
248
75
19
2
1
345
56
5
0
0
0
61
24
9
6
0
0
39
Percent By
Number
48.8
14.8
3.7
0.4
0.2
67.9
11.0
1.0
0
0
0
12.0
4.7
1.8
1.2
0
0
7.7
Percent By Mass
All
Categories
2.5
6.2
21.1
11.1
14.9
55.8
1.9
1.3
0
0
0
3.2
0.8
2.4
21.7
0
0
25.0
Within
Category
4.6
11.0
37.8
19.9
26.8
100
58.5
41.5
0
0
0
100
3.2
9.7
86.9
0
0
100
-------
TABLE D-27
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093205 (Continued)
Category
Quartz
5-1%
10-20y
20-50M
50-75y
>75y
Totals
Biological
5-lOp
10~20y
20-50y
50-75)j
>75y
Totals
CaC00
" " O
5-10u
10-20u
20-50y
50-75y
>75p
Totals
TOTALS
(AH Category
Particle
Count
16
5
2
0
0
23
21
3
1
0
1
26
13
1
0
0
0
14
508
OS)
Percent By
Number
3.1
1.0
0.4
0
0
4.5
4.1
0.6
0.2
0
0.2
5.1
2.6
0.2
0
0
0
2.8
100
Percent By Mass
All
Categories
0.3
0.7
3.7
0
0
4.6
0.1
0.2
0.7
0
10.0
11.0
0.2
0.1
0
0
0
0.4
100
Within
Category
5.9
14.7
79.4
0
0
100
1.3
1.5
6.7
0
90.5
100
61.9
38.1
0
0
0
100
-------
TABLE D-28
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093209 Total Mass of Particulates (mg) :
C°°"rs: 181 Agency:
Monitor Location: Liberty Boro Calculated Mass (mg): 251
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors : 114 Agency :
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50|j
50-75y
>75y
Totals
Particle
Count
447
187
37
5
2
678
11
0
0
0
0
11
0
0
0
0
0
0
Percent By
Number
59.0
24.7
48.9
0.7
0.3
89.6
1.4
0
0
0
0
f 1.4
0
0
0
0
0
0
Percent By Mass
All
Categories
2.9
9.6
25.7
17.4
18.7
74.2
0.2
0
0
0
0
0.2
0
0
0
0
0
0
Within
Category
3.9
12.9
34.6
23.4
25.2
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-28
RESULTS OF OPTICAL PARTICLE OOUNrrS
(Continued)
Filter Number: 1093209 (Continued)
Category
Quartz
5-10u
10-20p
20-50y
50-75U
>75y
Totals
Biological
5-10u
10-20jj
20-50n
50-75y
>75y
Totals
CaCOQ
5-10p
10-20y
20-50u
50-75n
>75y
Totals
TOTALS
(All Categori
Particle
Count
9
9
2
0
0
20
4
7
1
0
3
15
15
17
1
0
0
33
757
.es)
!
Percent By
Number
1.2
1.2
0.3
0
0
2.6
0.5
0.9
0.1
0
0.4
2.0
2.0
2.2
0.1
0
0
4.4
100
Percent By Mass
All
Categories
0.1
0.8
2.3
0
0
3.2
0.02
0.2
0.5
0
18.7
19.4
0.2
1.6
1.2
0
0
3.0
100
Within
Category
3.0
24.2
72.8
0
0
100
0.09
1.2
2.4
0
96.3
100
5.8
52.5
41.7
0
0
100
-------
TABLE D-29
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093211 Total Mass of Participates (mg) :
Coors: 125 Agency: 150
Monitor Location: Clairton Calculated Mass (mg) : 182
3
Date of Sample: 8/16/76 Air Concentration (yg/ni ):
Coors: 52 Agency: 76
Category
Fly ash
5-lOy
10-20y
20-50M
50-75 u
>75u
Totals
Iron Oxide
5-10y
10-20y
20-50p
50-75M
>75y
Totals
Magnetic
Iron
5-10n
10-20n
20-50u
50-75n
>75y
Totals
Particle
Count
199
62
18
5
3
287
34
1
0
0
0
35
0
0
0
0
0
0
Percent By
Number
54.7
17.0
4.9
1.4
0.8
78.8
9.3
0.3
0
0
0
9.6
0
0
0
0
0
0
Percent By Mass
All
Categori es
1.8
4.4
17.2
23.9
38.7
86.0
1.0
0.2
0
0
0
1.2
0
0
0
0
0
0
Within
Category
2.0
5.1
20.0
27.8
45.0
100
81.0
19.0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-29
RESULTS OF OPTJCAL PARTI CIJ] COUNTS
(Continued)
Filter Number: 1093211 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
1 O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categon
Particle
Count
9
1
1
0
0
11
11
3
3
0
1
18
13
0
0
0
0
13
364
es)
Percent By
Number
2.5
0.3
0.3
0
0
3.0
3.0
0.8
0.8
0
0.3
4.9
3.6
0
0
0
0
3.6
100
Percent By Mass
Al 1
Citegories
0.1
0.1
1.6
0
0
1.8
0.06
0.1
1.9
0
8.6
10.7
0.2
0
0
0
0
0.2
100
Within
Category
7.2
6.4
86.4
0
0
100
0.6
1.3
17.9
0
80.2
100
100
0
0
0
0
100
-------
TABLE D-30
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093229 Total Mass of Participates (mg) :
Coors: 149 Agency: 151
Monitor Location: Airport Calculated Mass (mg): 130
3
Date of Sarrple: 8/16/76 Air Concentration (yg/m ):
Coors: 76 Agency: 72
Category
Flyash
5-10|i
10-20y
20-50y
50-75M
>75y
Totals
Iron Oxide
5-10y
10-20M
20-50y
50-75u
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Particle
Count
186
41
8
4
0
239
14
0
0
0
0
14
9
2
0
0
0
11
Percent By
Number
55.7
12.3
2.4
1.2
0
71.6
4.2
0
0
0
0
4.2
2.7
0.6
0
0
0
3.3
Percent By Mass
Ail
Categories
2.3
4.0
10.7
26.8
0
43.8
0.6
0
0
0
0
0.6
0.4
0.6
0
0
0
1.0
Within
Category
5.2
9.2
24.4
61.1
0
100
100
0
0
0
0
100
36.0
64.0
0
0
0
100
-------
TABLE D-30
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093229 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75U
>75y
Totals
Biological
5-10u
10-20u
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75y
>75u
Totals
TOTALS
Particle
Count
22
9
4
2
0
37
11
1
5
1
1
19
14
0
0
0
0
14
334
(All Categories)
Percent By
Number
6.6
2.7
1.2
0.6
0
11.1
3.3
0.3
1.5
0.3
0.3
5.7
4.2
0
0
0
0
4.2
100
Percent By Mass
AIL
Gitegories
0.4
1.5
8.9
22.3
0
33.2
0.09
0.06
4.4
4.5
12.0
21.1
0.3
0
0
0
0
0.3
100
Within
Category
1.4
4.5
26.9
67.3
0
100
0.4
0.3
21.1
21.2
57.0
100
100
0
0
0
0
100
-------
TABLE D-31
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (C^61* Filter) Total Mass of Participates (rag):
1093230 r, .
Coors: — Agency:
Monitor Location: Airport Calculated Mass (mg): 64
3
Date of Sample: 8/16/76 Air Concentration (ug/m ):
(Cover Filter for 1093229) Coors: — Agency:
Category
Flyash
5-10u
10-20y
20-50U
50-75y
>75y
Totals
Iron Oxide
5-10u
10-20U
20-50u
50-75y
>75u
Totals
Magnetic
Iron
5-10y
10-20jj
20-50u
50-75(j
>75y
Totals
Particle
Count
161
44
9
0
0
214
16
0
0
0
0
16
0
0
0
0
0
0
Percent By
Number
51.4
14.0
2.9
0
0
68.4
5.1
0
0
0
0
5.1
0
0
0
0
0
0
Percent By Mass
All
Categories
4.1
8.9
24.6
0
0
37.5
1.3
0
0
0
0
1.3
0
0
0
0
0
0
Within
Category
10.8
23.7
65.5
0
0
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-31
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: (9°v^ Filter(b^ntinuecl)
Category
Quartz
5-10u
10-20p
20-50y
50-75^
>75u
Totals
Biological
5-lOp
10-20}j
20-50p
50-75p
>75y
Totals
CaC00
5-10y
10-20jj
20-50u
50-75u
>75u
Totals
TOTALS
Particle
Count
22
4
5
0
0
31
16
10
5
0
1
32
20
0
0
0
0
20
313
(All Categories)
Percent By
Number
7.0.
1.3
1.6
0
0
9.9
5.1
3.2
1.6
0
0.3
10.2
6.4
0
0
0
0
6.4
100
Percent By Mass
All
Categories
0.9
1.3
22.7
0
0
25.0
0.3
1.3
9.1
0
24.5
35.2
0.9
0
0
0
0
0.9
100
Within
Category
3.7
5.4
90.9
0
0
100
0.8
3.8
25.8
0
69.6
100
100
0
0
0
0
100
-------
TABLE D-32
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093239 Total Mass of Particulates (mg) :
Coors: 140 Agency: 90
Monitor Location: South Fayette Calculated toss (mg): 33
Date of Sample: 8/16/76 Air Concentration (yg/rrT):
Coors : 69 Agency : 41
Category
Flyash
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
126
22
10
0
0
158
8
2
0
0
0
10
9
0
0
0
0
9
Percent By
Number
55.5
9.7
4.4
0
0
69.6
3.5
0.9
0
0
0
4.4
4.0
0
0
0
0
4.0
Percent By Mass
All
Categories
6.1
8.5
52.1
0
0
66.6
1.2
2.5
0
0
0
3.7
1.4
0
0
0
0
1.4
Within
Category
9.1
12.7
78.2
0
0
100
33.3
66.7
0
0
0
100
100
0
0
0
0
100
-------
TABLE D-32
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093239 (Continued)
Category
Quartz
5-lOy
10-20p
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50u
50-75p
>75y
Totals
CaC00
1 " O
10-20y
20-50M
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
12
6
2
0
0
20
11
0
1
0
0
12
17
1
0
0
0
18
227
es)
1
Percent By
Number
5.3
2.6
0.9
0
0
8.8
4.8
0
0.4
0
0
5.3
7.5
0.4
0
0
0
7.9
100
Percent By t\5ass
All
Categories
1.0
3.8
17.4
0
0
22.2
0.4
0
3.5
0
0
3.8
1.5
0.7
0
0
0
2.2
100
Within
Category
4.3
17.4
78.3
0
0
100
9.2
0
90.8
0
0
100
68.0
32.0
0
0
0
100
-------
TABLE D-33
RESULTS OF OPTICAL PARTICLE COUNTS
( C^r\\ 7OY* TP"i T "t* OT* ^
Filter Number: t">ver inter)
1093240
Monitor Location: South Fayette
Date of Sample: 8/16/76
(Cover Filter for 1093239)
Category
Flyash
5-lOu
10-20y
20-50p
50-75U
>75u
Totals
Ir-on Oxide
5-10u
10-20u
20-50u
50-75y
>75u
Totals
Magnetic
Iron
5-lOu
10-20y
20-50u
50-75u
>75y
Totals
Particle
Count
128
36
3
0
0
167
8
0
0
0
0
8
8
3
0
0
0
11
Total Mass of Particulates (mg) :
Coors: — Agency: —
Calculated Mass (mg): 37
3
Air Concentration (ug/m ):
Coors : — Agency :
Percent By
Number
53.8
15.1
1.3
0
0
70.2
3.4
0
0
0
0
3.4
3.4
1.3
0
0
0
4.6
Percent By Mass
All
Categories
5.6
12.6
14.2
0
0
32.4
1.1
0
0
0
0
1.1
1.1
3.4
0
0
0
4.5
Within
Category
17.3
38.9
43.8
0
0
100
100
0
0
0
0
100
25.0
75.0
0
0
0
100
-------
TABLE D-33
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: (Jgg||4^ilter\/'oontinued)
Category
Quartz
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75y
Totals
CaC00
1 O
5-10y
10-20y
20-50p
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
7
3
1
0
0
11
10
22
1
0
1
34
7
0
0
0
0
7
238
es)
Percent By
Number
2.9
1.3
0.4
0
0
4.6
4.2
9.2
0.4
0
0.4
14.3
2.9
0
0
0
0
2.9
100
Percent By Mass
All
Categories
0.5
1.8
7.9
0
0
10.2
0.3
5.1
3.2
0
42.5
51.1
0.6
0
0
0
0
0.6
100
Within
Category
5.0
17.2
77.7
0
0
100
0.6
10.0
6.2
0
83.2
100
100
0
0
0
0
100
-------
TABLE D-34
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093290
Monitor Location: Baden
Date of Sample: 8/28/76
Category
Flyash
5-10u
10-20y
20~50n
50-75p
>75M
Totals
Iron Oxide
5-10u
10-20M
20-50|j
50-75u
>75y
Totals
Magnetic
Iron
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
375
71
12
2
0
460
13
I
0
0
0
14
12
1
0
0
0
13
Total Mass of Particulates (mg) :
Coors: 374 Agency: 351
Calculated Mass (mg): 66
3
Air Concentration (yg/m ):
Coors: 203 Agency: 183
Percent By
Number
68
13
2
0
.8
.0
.2
.4
0
84
2
0
.4
.4
.2
0
0
0
2
2
0
.6
.2
.2
0
0
0
2
.4
Percent By Mass
All
Categories
9.2
13.9
31.7
26.4
0
81.2
1.0
0.6
0
0
0
1.6
1.0
0.6
0
0
0
1.6
Within
Category
11.3
17.1
39.0
32.6
0
100
61.9
38.1
0
0
0
100
60.0
40.0
0
0
0
100
-------
TABLE D-34
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093290 (Continued)
Category
Quartz
5-10y
10-2 Oy
20-50M
50-75y
>75p
Totals
Biological
5-lOp
10-20^
20-50p
50-75n
>75M
Totals
CaC00
5-10y
10-20p
20-50u
50-75vi
>75y
Totals
TOTALS
(All Categori
Particle
Count
11
2
2
0
0
15
19
9
2
0
0
30
13
0
0
0
0
13
545
es)
1
Percent By
Number
2.0
0.4
0.4
0
0
2.8
3.5
1.6
0.4
0
0
5.5
2.4
0
0
0
0
2.4
100
Percent By Mass
All
Categories
0.4
0.7
8.8
0
0
9.9
0.3
1.2
3.5
0
0
5.0
0.6
0
0
0
0
0.6
100
Within
Category
4.5
6.6
88.9
0
0
100
6.2
23.4
70.4
0
0
100
100
0
0
0
0
100
-------
TABLE D-35
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1093291 Coors: — Agency:
Monitor Location: Baden Calculated Mass (mg) : 192
Date of Sample: 8/28/76 Air Concentration (ug/m ):
(Cover Filter for 1093290) Coors: — Agency:
Category
Flyash
5-lOu
10-20y
20-50p
50-75^
>75y
Totals
Iron Oxide
5-10y
10-20n
20-50p
50-75U
>75M
Totals
Magnetic
Iron
5-10y
10-20)j
20-50u
50-75y
>75y
Totals
Particle
Count
198
76
28
4
2
308
30
9
0
0
0
39
14
8
0
0
0
22
Percent By
Number
46.0
17.7
6.5
0.9
0.5
71.6
7.0
2.1
0
0
0
9.1
3.2
1.9
0
0
0
5.1
Percent By Mass
All
Categories
1.6
5.1
25.3
18.1
24.4
74.6
0.8
2.0
0
0
0
2.8
0.4
1.7
0
0
0
2.1
Within
Category
2.2
6.8
34.0
24.3
32.7
100
29.4
70.6
0
0
0
100
17.9
82.0
0
0
0
100
-------
TABLE D-35
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: ^C^^^lter')( Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75)j
>75y
Totals
CaCOQ
*J
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
11
5
5
0
0
21
14
10
4
3
0
31
8
1
0
0
0
9
430
es)
1
Percent By
Number
2.6
1.2
1.2
0
0
4.9
3.2
2.3
0.9
0.7
0
7.2
1.9
0.2
0
0
0
2.1
100
Percent By Mass
All
Categori es
0.2
0.6
7.5
0
0
8.2
0.08
0.4
2.4
9.0
0
12.0
0.1
0.1
0
0
0
0.2
100
Within
Category
1.8
6.8
91.4
0
0
100
0.6
3.7
20.1
75.5
0
100
50.0
50.0
0
0
0
100
-------
TABLE D-36
RESULTS OF OPTICAL PARTICLE COUiYfS
Filter Number: 1093288 Total Mass of Particulates (mg) :
Coors: 277 Agency: 266
Monitor Location: Beaver Falls Calculated Mass (mg): 182.
3
Date of Sample: 8/28/76 Air Concenti-ation (yg/m ):
Coors : 164 Agency : 137
Category
Flyash
5-lOu
10-20u
20-50p
50-75U
>75M
Totals
Iron Oxide
5-10M
10-20y
20-50p
50-75y
>75,
Totals
Magnetic
Iron
5-lOy
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
352
57
17
4
1
431
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
62.8
10.2
3.0
0.7
0.2
77.0
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
3.1
4.0
16.2
19.1
12.9
55.4
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
5.6
7.3
29.3
34.5
23.2
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-36
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093288 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75M
>75p
Totals
Biological
5-10u
10-20y
20-50u
50-75u
>75y
Totals
CaC00
«_>
5-10u
10-20p
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
12
0
1
0
0
13
38
47
25
5
1
116
0
0
0
0
0
0
560
es)
Percent By
Number
2.1
0
0.2
0
0
2.3
6.8
8.4
4.5
0.9
0.2
20.7
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.2
0
1.6
0
0
1.8
0.2
2.2
15.9
15.9
8.6
42.9
0
0
0
0
0
0
100
Within
Category
10.0
0
90.0
0
0
100
0.5
5.2
37.1
37.2
20.0
100
0
0
0
0
0
0
-------
TABLE D-37
RESULTS OF OPTICAL, PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1093289 Coors: — Agency:
Monitor Location: Beaver Falls Calculated Mass (mg) : 132
3
Date of Sanple: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1093288) Coors: — Agency:
Category
Flyash
5-10u
10-20p
20-50p
50-75M
>75p
Totals
Iron Oxide
5-10p
10-20y
20-50)j
50-75u
>75y
Totals
Magnetic
1 1X311
5-10u
10-20u
20-50u
50-75^
>75n
Totals
Particle
Count
92
39
4
2
2
139
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
42.0
17.8
1.8
0.9
0.9
63.5
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
1.1
3.8
5.3
13.2
35.6
59.0
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
1.9
6.4
9.0
22.4
60.3
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-37
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: (C?QQo2Qglter^Continued)
Category
Quartz
5-10u
10-20y
20-50y
50-75y
>75p
Totals
Biological
5-10p
10-20u
20-50]j
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75u
>75]i
Totals
TOTALS
(All Categor]
Particle
Count
2
6
4
0
0
12
10
38
19
0
1
68
0
0
0
0
0
0
219
es)
Percent By
Number
0.9
2.7
1.8
0
0
5.5
4.6
17.4
8.7
0
0.4
31.0
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.04
1.0
8.8
0
0
9.8
0.08
2.5
16.7
0
11.9
31.2
0
0
0
0
0
0
100
Within
Category
0.4
9.9
89.6
0
0
100
0.3
7.9
53.7
0
38.1
100
0
0
0
0
0
0
-------
TABLE D-38
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093286
Monitor Location: Koppel
Date of Sample: 8/28/76
Category
Flyash
5-1 Oy
10-20u
20-50U
50-75y
>75p
Totals
Iron Oxide
5-10y
10-20M
20-50)j
50-75y
>75|j
Totals
Magnetic
Iron
5-10p
10-20^
20-50u
50-75u
>75M
Totals
Particle
Count
260
72
16
8
7
363
20
5
1
0
0
26
0
0
0
0
0
0
Total Mass of Particulates (mg):
Coors: 256 Agency:
Calculated Mass (mg): 340
3
Air Concentration (yg/m ) :
Coors : 133 Agency :
Percent By
Number
56.6
15.7
3.5
1.7
1.5
79.1
4.4
1.1
0.2
0
0
5.7
0
0
0
0
0
0
Percent By Mass
All
Categories
1.2
2.7
8.2
20.5
48.4
81.0
0.3
0.6
1.7
0
0
2.6
0
0
0
0
0
0
Within
Category
1.5
3.4
10.1
25.3
59.7
100
11.9
23.8
64.3
0
0
100
0
0
0
0
0
0
-------
TABLE D-38
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093286 (Continued)
Category
Quartz
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75p
>75M
Totals
CaOOQ
o
5-10n
10-20M
20-50y
50-75y
>75pi
Totals
TOTALS
(All Categora
Particle
Count
23
8
7
0
0
38
5
15
0
0
2
22
10
0
0
0
0
10
459
es)
Percent By
Number
5.0
1.7
1.5
0
0
8.3
1.1
3.3
0
0
0.4
4.8
2.2
0
0
0
0
2.2
100
Percent By Mass
All
Categories
0.2
0.5
6.0
0
0
6.7
0.02
0.4
0
0
9.2
9.6
0.08
0
0
0
0
0.08
100
Within
Category
2.7
7.6
89.7
0
0
100
0.2
3.9
0
0
95.9
100
100
0
0
0
0
100
-------
TABLE D-39
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number:
Monitor Location: Brighton
Township
Date of Sample: 8/28/76
Category
Fly ash
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Particle
Count
196
56
4
3
1
260
19
10
0
0
0
29
3
3
0
0
0
6
Total Mass of Particulates (mg) :
Coors: 258 Agency: 274
Calculated Mass (mg) : 125
3
Air Concentration (yg/m ):
Coors : 149 Agency : 151
Percent By
Number
46.
13.
0.
0.
0.
61
4
2
2
2
9
7
2
3
5
4
0
0
0
6
0
0
9
.7
7
0
0
0
1
.4
Percent By Mass
All
Categories
2.5
5.8
5.6
20.9
18.8
53.5
0.8
3.4
0
0
0
4.2
0.1
1.0
0
0
0
1.1
Within
Category
4.7
10.8
10.4
39.0
35.0
100
19.2
80.8
0
0
0
100
11.6
88.4
0
0
0
100
-------
TABLE D-39
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093284 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Biological
5-10u
10-20u
20-50y
50-75y
>75y
Totals
CaC00
1 3
5-10y
10-20u
20-50u
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
53
39
13
0
0
105
1
12
2
0
0
15
7
2
0
0
0
9
424
_es)
1
Percent By
Number
12.5
9.2
3.1
0
0
24.8
0.2
2.8
0.5
0
0
3.5
1.6
0.5
0
0
0
2.1
100
Percent By Mass
All
Categories
1.1
6.7
30.2
0
0
38.0
0.008
0.8
1.8
0
0
2.7
0.2
0.4
0
0
0
0.5
100
Within
Category
3.0
17.6
79.4
0
0
100
0.3
30.6
69.0
0
0
100
30.4
69.6
0
0
0
100
-------
TABLE D-40
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093282
Monitor Location : Midland
Date of Sample: 8/28/76
Category
Fly ash
5-10y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
208
97
38
6
6
355
56
29
2
0
0
87
21
17
0
0
0
38
Total Mass oi Particulates (mg) :
Coors: 479 Agency: 501
Calculated Mass (mg): 338
3
Air Concentration (yg/m ):
Coors: 268 Agency: 248
Percent By
Number
37.
17.
6.
1
1
63
10
5
0
3
4
8
1
1
6
0
2
4
0
0
15
3
3
6
8
.0
0
0
0
6
.8
Percent By Mass
All
Categories
1.0
3.7
19.6
15.5
41.7
81.5
0.9
3.6
3.4
0
0
7.9
0.3
2.1
0
0
0
2.4
Within
Category
1.2
4.5
24.0
19.0
51.2
100
11.1
46.0
42.6
0
0
100
13.4
86.6
0
0
0
100
-------
TABLE D-40
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093282 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorn
Particle
Count
23
9
7
0
0
39
6
2
2
0
0
10
22
7
0
0
0
29
558
es)
1
Percent By
Number
4.1
1.6
1.2
0
0
69.9
1.1
0.4
0.4
0
0
1.8
3.9
1.2
0
0
0
5.2
100
Percent By Mass
All
Categories
0.2
0.6
6.0
0
0
6.8
0.02
0.05
0.7
0
0
0.8
0.2
0.5
0
0
0
0.7
100
Within
Category
2.7
8.4
88.8
0
0
100
2.5
6.7
90.8
0
0
100
28.2
71.8
0
0
0
100
-------
TABLE D-41
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106306
Monitor Location: Elco
Date of Sample: 8/28/76
Category
Fly ash
5-10p
10-20y
20-50^
50-75M
>75p
Totals
Iron Oxide
5-10y
10-20y
20-50p
50-75u
>75y
Totals
Magnetic
Iron
5-10y
10-20u
20-50u
50-75p
>75y
Totals
Particle
Count
136
52
25
0
0
213
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors : 91 Agency : 98
Calculated Mass (mg) : 107
3
Air Concentration (ug/m ):
Coors : ^3 Agency : ^0
Percent By
Number
26.
10.
5.
9
3
0
0
0
42.
2
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
2.0
6.2
40.5
0
0
48.8
0
0
0
0
0
0
0
0
0
0
0 •
0
Within
Category
4.2
12.8
83.0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-41
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106306 (Continued)
Category
Quartz
5-10y
10-20u
20-50|j
50-75y
>75U
Totals
Biological
5-10u
10-20y
20-50y
50-75p
>75y
Totals
CaCOQ
5-10y
10-20u
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
68
20
8
0
0
96
112
68
16
0
0
196
0
0
0
0
0
0
505
(All Categories)
1
Percent By
Number
13.5
4.0
1.6
0
0
19.0
22.2
13.5
3.2
0
0
38.8
0
0
0
0
0
0
100
Percent By Mass
All
Categories
1.7
4.0
21.6
0
0
27.3
1.1
5.4
17.2
0
0
23.8
0
0
0
0
0
0
100
Within
Category
16.2
14.6
79.1
0
0
• 100
4.7
22.8
72.5
0
0
100
0
0
0
0
0
0
-------
TABLE D-42
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093296 Total Mass of Participates (mg) :
Coors: 193 Agency: 149
'Monitor Location: Downtown Calculated Mass (mg): 246
3
Date of Sample: 8/28/76 ^r Concentration (ug/m ):
Coors : 101 Agency : 70
Category
Flyash
5-lOy
10-20u
20-50y
50-75U
>75M
Totals
Iron Oxide
5-10y
10-20y
20~50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
153
15
9
8
3
188
4
0
0
0
0
4
0
0
0
0
0
0
Percent By
Number
42.7
4.2
2.5
2.2
0.8
52.5
1.1
0
0
0
0
1.1
0
0
0
0
0
0
Percent By Ivkss
All
Categories
1.0
0.8
6.4
28.3
28.6
65.0
0.08
0
0
0
0
0.08
0
0
0
0
0
0
Within
Category
1.5
1.2
9.8
43.5
43.9
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-42
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093296 (Continued)
Category
Quartz
5-10y
10-20p
20-50y
50-75p
>75p
Totals
Biological
5-lOy
10-20y
20-50y
50-75u
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
13
16
3
0
0
32
121
5
3
1
4
134
0
0
0
0
0
0
358
es)
1
Percent By
Number
3.6
4.5
0.8
0
0
8.9
33.8
1.4
0.8
0.3
1.1
37.4
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.1
1.4
3.5
0
0
5.1
0.5
0.2
1.4
2.4
25.4
29.8
0
0
0
0
0
0
100
Within
Category
2.8
27.5
69.7
0
0
100
1.8
0.6
4.7
7.9
85.0
100
0
0
0
0
0
0
-------
TABLE D-43
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093253 Total Mass of Particulates (mg) :
Coors: 233 Agency:
Monitor Location: Central Lab Calculated Mass (ing): 156
Date of Sample: 8/28/76 Air Concentration (ug/m3):
Coors : 119 Agency : —
Category
Fly-ash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75u
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
262
73
18
2
3
358
44
5
0
0
0
49
0
0
0
0
0
0
Percent By
Number
49.3
13.7
3.4
0.4
0.6
67.4
8.3
0.9
0
0
0
9.2
0
0
0
0
0
0
Percent By Mass
All
Categories
2.7
6.0
20.1
11.2
45.2
85.2
1.5
1.3
0
0
0
2.8
0
0
0
0
0
0
Within
Category
3.2
7.1
23.6
13.1
53.0
100
52.4
47.6
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-43
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093253 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categor:
Particle
Count
26
19
3
0
0
48
40
11
2
0
0
53
19
4
0
0
0
23
531
es)
1
Percent By
Number
4.9
3.6
0.6
0
0
9.0
7.5
2.1
0.4
0
0
10.0
3.6
0.8
0
0
0
4.3
100
Percent By Mass
All
Categories
0.4
2.6
5.6
0
0
8.6
0.3
0.6
1.5
0
0
2.4
0.4
0.6
0
0
0
0.9
100
Within
Category
5.2
30.2
64.6
0
0
100
11.6
25.6
62.8
0
0
100
37.2
62.7
0
0
0
100
-------
TABLE D-44
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106308 Total Mass of Participates (mg) :
Coors: 151 Agency: 143
Monitor Location: Hazelwood Calculated Mass (mg) : 87
Date of Sample: 8/28/76 Air Concentration (yg/m3):
Coors: 71 Agency: 76
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
191
48
9
2
0
250
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
47.0
11.8
2.2
0.5
0
61.6
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
3.5
7.1
18.0
20.0
0
48.6
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
7.3
14.6
37.0
41.1
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-44
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106308 (Continued)
Category
Quartz
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20n
20-50u
50-75p
>75y
Totals
CaCOQ
111 O
5-10y
10-20jj
20-50p
50-75)j
>75|j
Totals
TOTALS
(All Category
Particle
Count
7
1
0
0
0
8
94
24
8
0
2
128
19
1
0
0
0
20
406
.es)
Percent By
Number
1.7
0.2
0
0
0
2.0
23.2
5.9
2.0
0
0.5
31.5
4.7
0.2
0
0
0 '
4.9
100
Percent By Mass
All
Categories
0.2
0.2
0
0
0
0.5
1.2
'2.4
10.6
0
35.9
50.0
0.6
0.3
0
0
0
0.9
100
Within
Category
46.7
53.3
0
0
0
100
2.3
4.7
21.3
0
71.7
100
70.4
29.6
0
0
0
100
-------
TABLE D-45
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106309 Coors: Agency:
Monitor Location: Hazelwood Calculated Mass (mg): 70
T
Date of Sanple: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1106308 Coors: — Agency:
Category
Flyash
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
77
21
18
1
0
117
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
38.9
10.6
9.1
0.5
0
59.1
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
1.8
3.8
44.7
12.4
0
62.8
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
2.8
6.1
71.2
19.8
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-45
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number : (gj|J0|ilter ^Continued)
Category
Quartz
5-10M
10-20p
20-50p
50~75M
>75M
Totals
Biological
5-10u
10-20y
20-50)j
50-75u
>75y
Totals
CaCCL
5-10u
10-20y
20-50p
50-75y
>75y
Totals
TOTA15
Particle
Count
6
10
2
0
0
18
36
9
4
2
0
51
11
1
0
0
0
12
198
(All Categories)
Percent By
Number
3.0
5.1
1.0
0
0
9.1
18.2
4.5
2.0
2.0
0
26.7
5.6
0.5
0
0
0
6.1
100
Percent By Mass
All
Categories
0.2
3.1
8.3
0
0
11.6
0.6
1.1
6.6
16.6
0
24.8
0.5
0.3
0
0
0
0.8
100
Within
Category
2.0
26.5
71.6
0
0
100
2.2
4.4
26.6
66.7
0
100
57.9
42.1
0
0
0
100
-------
TABLE D-46
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093298 Total Mass of Particulates (mg) :
Coors: 289 Agency: 214
Monitor Location: North Braddock Calculated Mass (mg): 113
Date of Sample: 8/28/76 Air Concentration (yg/m ):
Coors: 153 Agency: 108
Category
Flyash
51 Oi i
-i- \J J.J
10-20y
20-50y
50-75y
>75p
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
283
50
15
0
1
349
51
7
0
0
0
58
22
4
0
0
o
26
Percent By
Number
56.6
10.0
3.0
0
0.2
69.8
10.2
1.4
0
0
0
11.6
4.4
0.8
0
0
0
5.2
Percent By Miss
All
Categories
4.0
5.7
23.1
0
20.8
53.6
2.4
2.6
0
0
0
5.0
1.0
1.5
0
0
0
2.5
Within
Category
7.5
10.6
43.1
0
38.7
100
47.7
52.3
0
0
0
100
40.8
59.3
0
0
0
100
-------
TABLE D-46
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093298 (Continued)
Category
Quartz
5-1 Oy
10-20y
20-50|j
50-75y
>75M
Totals
Biological
5-lOu
10-20u
20-50)j
50-75y
>75u
Totals
CaCO0
11 O
5-10y
10-20u
20-50p
50-75ji
>75u
Totals
TOTALS
(All Categor:
Particle
Count
6
11
4
0
0
21
8
0
6
1
1
16
28
2
0
0
0
30
500
.es)
Percent By
Nujnber
1.2
2.2
0.8
0
0
4.2
1.6
0
1.2
0.2
0.2
3.2
5.6
0.4
0
0
0
6.0
100
Percent By Mass
All
Categories
0.1
2.1
10.3
0
0
12.5
0.08
0
6.2
5.1
13.8
25.2
0.7
0.4
0
0
0
1.1
100
Within
Category
1.1
16.7
82.2
0
0
100
0.3
0
24.4
20.4
54.9
100
63.6
36.4
0
0
0
100
-------
TABLE D-47
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Participates (mg) :
1093299 Coors : Agency : —
Monitor Location: North Braddock Calculated Mass (mg): 292
3
Date of Sample: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1093298) Coors: — Agency:
Category
Flyash
5-lOu
10-20y
20-50U
50-75M
>75U
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
279
67
13
6
3
368
35
6
0
0
0
41
24
23
2
0
0
49
Percent By
Number
52.7
12.7
2.4
1.1
0.6
69.6
6.6
1.1
0
0
0
7.7
4.5
4.3
0.4
0
0
9.3
Percent By Mass
All
Categories
1.5
3.0
7.8
17.9
24.1
54.3
0.6
0.9
0
0
0
1.5
0.4
3.3
3.9
0
0
7.6
Within
Category
2.8
5.4
14.3
33.0
44.4
100
42.2
57.8
0
0
0
100
5.7
43.4
51.1
0
0
100
-------
TABLE D-47
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: ^Cover Fllter )( Continued)
1093299
Category
Quartz
5-10u
10-20y
20-50U
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75jj
Totals
CaCO3
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
9
3
6
1
1
20
12
15
0
0
2
29
15
7
0
0
0
22
529
(All Categories)
Percent By
Number
1.7
0.6
1.1
0.2
0.2
3.8
2.3
2.8
0
0
0.4
5.5
2.8
1.3
0
0
0
4.2
100
Percent By Mass
All
Categories
0.08
0.2
6.0
5.0
13.4
24.6
0.04
0.4
0
0
10.7
11.2
0.1
0.6
0
0
0
0.7
100
Within
Category
0.3
0.9
24.2
20.2
54.4
100
0.4
3.9
0
0
95.7
100
21.1
78.9
0
0
0
100
-------
TABLE D-48
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106300 Total Mass o£ Particulates (mg) :
Coors: 68 Agency:
Monitor Location: Duquesne II Calculated Mass (mg): 10
Date of Sample: 8/28/76 Air Concentration (yg/m3):
Coors : — Agency :
Category
Flyash
5-lOy
10-20p
20-50p
50-75y
>75M
Totals
Iron Oxide
5-10p
10-20y
20-50u
50-75^
>75U
Totals
Magnetic
Iron
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Particle
Count
18
3
1
0
0
22
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
43.9
7.3
2.4
0
0
53.6
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
2.8
3.7
16.6
0
0
23.0
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
12.0
16.0
72.0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-48
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106300 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOQ
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
3
1
0
0
0
4
4
9
1
1
0
15
0
0
0
0
0
0
41
(All Categories)
Pore lent By
Number
7.3
2.4
0
0
0
9.8
9.8
22.0
2.4
2.4
0
36.6
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.8
2.0
0
0
0
2.8
0.4
7.4
11.0
55.3
0
74.2
0
0
0
0
0
0
100
Within
Category
27.3
72.7
0
0
0
100
0.6
9.9
14.9
74.6
0
100
0
0
0
0
0
0
-------
TABLE D-49
RESULTS OF CPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (ing).:
1106301 Coors: Agency:
Monitor Location: Duquesne II Calculated Muss (ing): 30
3
Date of Sample: 8/28/76 Air Concentration (ug/m ):
(Cover Filter for 1106300) Coors: ~ Agency:
Category
Flyash
5-lOu
10-20U
20-50y
50-75y
>75u
Totals
Iron Oxide
5-10u
10-20u
20-50y
50-75u
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75u
>75y
Totals
Particle
Count
3
5
0
0
1
9
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
11.5
19.2
0
0
3.8
34.6
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
0.2
2.2
0
0
79.1
81.5
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
0.2
2.7
0
0
97.1
97.1
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-49
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: (Cover Filter ^Continued)
nnfism
Category
Quartz
5-10u
10-20y
20-50p
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50p
50-75y
>75y
Totals
CaCO,,
O
5-10u
10-20y
20-50y
50-75p
>75y
Totals
TOl^ALS
(All Categori
Particle
Count
2
0
0
0
0
2
2
9
4
0
0
15
0
0
0
0
0
0
26
es)
Percent By
Number
7.7
0
0
0
0
7.7
7.7
34.6
15.4
0
0
57.7
0
0
0
0
0
0
100
Percent By Mass
AVJ
Categories
0.2
0
0
0
0
0.2
0.07
2.6
15.7
0
0
18.3
0
0
0
0
0
0
100
Within
Category
100
0
0
0
0
100
0.4
14.2
85.4
0
0
100
0
0
0
0
0
0
-------
TABLE D-50
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106302 Total Mass of Particulates (mg) :
Coors : 207 Agency : 271
Monitor Location: Liberty Boro Calculated Mass (mg) : 209
3
Date of Sample: 8/28/76 Air Concentration (yg/m ) :
Coors : 130 Agency : 136
Category
Fly ash
5-lOu
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-lOp
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-lOy
10-20tj
20-50u
50-75p
>75p
Totals
Particle
Count
276
118
20
3
5
422
12
5
0
0
0
17
0
0
0
0
0
0
Percent By
Number
57.0
24.4
4.1
0.6
1.0
87.2
2.5
1.0
0
0
0
3.5
0
0
0
0
0
0
Percent By Mass
Ail
Categories
2.1
7.3
16.6
12.5
56.1
94.6
0.3
1.0
0
0
0
1.3
0
0
0
0
0
0
Within
Category
2.2
7.7
17.6
13.2
59.3
100
23.1
76.9
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-50
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106302 (Continued)
Category
Quartz
5-10y
10-20p
20-50y
50-75U
>75U
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Ca000
O
5-10n
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
9
5
1
0
0
15
5
14
2
0
0
21
7
2
0
0
0
9
484
es)
Percent By
Number
1.8
1.0
0.2
0
0
3.1
1.0
2.9
0.4
0
0
4.3
1.4
0.4
0
0
0
1.8
100
Percent By Mass
All
Categories
0.1
0.5
1.4
0
0
2.0
0.02
0.6
1.1
0
0
1.7
0.1
0.2
0
0
0
0.3
100
Within
Category
5.7
25.4
68.8
0
0
100
1.5
33.6
64.9
0
0
100
30.4
69.6
0
0
0
100
-------
TABLE D-51
RESULTS OF OPTICAL PARTICLE COURTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106303 Coors: — Agency: —
Monitor Location: Liberty Boro Calculated Mass (mg): 17
Date of Sample: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1106302) Coors: — Agency.
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10M
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
191
70
2
0
0
263
12
0
0
0
0
12
0
0
0
0
0
0
Percent By
Number
61.0
22.4
0.6
0
0
84.0
3.8
0
0
0
0
3.8
0
0
0
0
0
0
Percent By t^kss
All
Categories
17.6
51.7
20.0
0
0
89.3
3.6
0
0
0
0
3.6
0
0
0
0
0
0
Within
Category
19.7
57.9
22.4
0
0
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-51
RESULTS OF OPTICAL PARTICLE OOUNTS
(Continued)
Filter Number: ^Cover Fllter \Continued)
1106303
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOo
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOrALS
(All Categori
Particle
Count
11
1
0
0
0
12
14
4
0
0
0
18
8
0
0
0
0
8
313
OS)
Percent By
Number
3.5
0.3
0
0
0
3.8
4.5
1.3
0
0
0
5.8
2.6
0
0
0
0
2.6
100
Percent By Mass
All
Categories
1.7
1.2
0
0
0
2.9
0.9
2.0
0
0
0
2.8
1.3
0
0
0
0
1.3
100
Within
Category
57.9
42.1
0
0
0
100
30.4
69.6
0
0
0
100
100
0
0
0
0
100
-------
TABLE D-52
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106304 Total Mass of Participates (mg) :
Coors: 147 Agency: 215
Monitor Location: Clairton Calculated Mass (mg) : 126
3
Date of Sample: 8/28/76 Air Concentration (yg/m ):
Coors : 61 Agency : 115
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75|j
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75]j
Totals
Particle
Count
183
44
12
1
1
241
16
0
0
0
0
16
0
0
0
0
0
0
Percent By
Number
52.4
12.6
3.4
0.3
0.3
69.0
4.6
0
0
0
0
4.6
0
0
0
0
0
0
Percent By Mass
All
Categories
2.3
4.5
16.6
6.9
18.6
49.0
0.7
0
0
0
0
0.7
0
0
0
0
0
0
Within
Category
4.8
9.2
33.9
14.1
38.0
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-52
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106304 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO0
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
9
17
5
0
0
31
20
24
3
4
1
52
9
0
0
0
0
9
349
es)
Percent By
Number
2.6
4.9
1.4
0
0
8.9
5.7
6.9
0.8
1.1
0.3
14.9
2.6
0
0
0
0
2.6
100
Percent By Mass
All
Categories
0.2
2.9
11.5
0
0
14.6
0.2
1.6
2.8
18.5
12.4
35.5
0.2
0
0
0
0
0.2
100
Within
Category
1.3
19.8
78.8
0
0
100
0.5
4.6
7.8
52.0
35.0
100
100
0
0
0
0
100
-------
TABLE D-53
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093280 Total Mass ol Particulates (mg) :
Coors: 210 Agency: 202
Monitor Location: Airport Calculated Mass (mg): 168
3
Date of Sample: 8/28/76 Air Concentration (ug/m ):
Coors: 110 Agency: 97
Category
Flyash
5-lOy
10-20y
20-50)j
50-75M
>75M
Totals
Iron Oxide
5-10p
10-20u
20-50u
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20||
20-50u
50-75u
>75jj
Totals
Particle
Count
145
47
12
0
0
204
24
4
0
0
0
28
0
0
0
0
0
0
Percent By
Number
36.6
11.9
3.0
0
0
51.5
6.1
1.0
0
0
0
7.1
0
0
0
0
0
0
Percent By Mass
All
Categories
1.4
3.6
12.4
0
0
17.4
0.8
1.0
0
0
0
1.8
0
0
0
0
0
0
Within
Category
8.0
20.7
71.4
0
0
100
42.8
57.1
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-53
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093280 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-lOp
10-20y
20-50p
50-75U
>75y
Totals
CaOOQ
5-10y
10-20^
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
46
18
13
3
0
80
10
30
40
0
0
80
3
1
0
0
0
4
396
es)
1
Percent By
Number
11.6
4.5
3.3
0.8
0
20.2
2.5
7.6
10.1
0
0
20.2
0.8
0.2
0
0
0
1.0
100
Percent By Mass
All
Categories
0.7
2.3
22.4
25.9
0
51.4
0.06
1.5
27.6
0
0
29.2
0.05
0.1
0
0
0
0.2
100
Within
Category
1.4
4.5
43.7
50.4
0
100
0.2
5.2
94.5
0
0
100
27.3
72.7
0
0
0
100
-------
TABLE D-54
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093278 Total Mass of Particulates (mg) :
Coors: 174 Agency: 120
Monitor Location: South Fayette Calculated Mass (mg): 80
3
Date of Sample: 8/28/76 Air Concentration (yg/rrf ):
Coors: 91 Agency: 59
Category
Flyash
5-10y
10-20y
20-50p
50-75p
>75p
Totals
Iron Oxide
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
83
23
4
0
0
110
21
0
0
0
0
21
0
0
0
0
0
0
Percent By
Number
27.1
7.5
1.3
0
0
35.9
6.9
0
0
0
0
6.9
0
0
0
0
0
0
Percent By Mass
All
Categories
1.7
3.7
8.7
0
0
14.1
1.4
0
0
0
0
1.4
0
0
0
0
0
0
Within
Category
11.9
26.3
61.8
0
0
100
100
0
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-54
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093278 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
' G
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
10
10
12
0
0
32
41
74
4
3
0
122
18
3
0
0
0
21
306
es)
Percent By
Number
3.3
3.3
3.9
0
0
10.4
13.4
24.2
1.3
1.0
0
39.9
5.9
1.0
0
0
0
6.9
100
Percent By Mass
All
Categories
0.3
2.7
43.7
0
0
46.7
0.6
8.0
5.8
21.9
0
36.2
0.6
0.9
0
0
0
1.5
100
Within
Category
0.7
5.7
93.5
0
0
100
1.5
22.0
16.1
60.4
0
100
42.8
57.1
0
0
0
100
-------
TABLE D-55
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093271 Total Mass of Particulates (mg) :
Coors: 335 Agency: 355
Monitor Location: Baden Calculated Mass (mg) : 561
3
Date of Sample: 9/9/76 Air Concentration (jjg/m ):
Coors: 207 Agency: 185
Category
Flyash
5-lOu
10-20u
20-50p
50-75p
>75y
Totals
Iron Oxide
5-10u
10-20^
20-50u
50-75y
>75M
Totals
Magnetic
Iron
5-10p
10-20M
20-50|j
50-75y
>75p
Totals
Particle
Count
281
121
26
6
5
439
37
16
0
0
0
53
0
0
0
0
0
0
Percent By
Number
46.8
20.2
4.3
1.0
0.8
73.2
6.2
2.7
0
0
0
8.8
0
0
0
0
0
0
Percent By Mass
All
Categories
0.8
2.8
8.1
9.3
20.9
41.9
0.3
1.2
0
0
0
1.5
0
0
0
0
0
0
Within
Category
1.9
6.6
19.3
22.2
49.9
100
22.4
77.6
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-55
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093271 (Continued)
Category
Quartz
5-lOy
10-20^
20-50p
50-75M
>75y
Totals
Biological
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
29
14
2
0
0
45
5
29
2
1
19
56
7
0
0
0
0
7
600
es)
Percent By
Number
4.8
2.3
0.3
0
0
7.5
0.8
4.8
0.3
0.2
3.2
9.3
1.2
0
0
0
0
1.2
100
Percent By Mass
All
Categories
0.1
0.5
1.0
0
0
1.7
0.01
0.4
0.4
1.0
52.9
54.8
0.04
0
0
0
0
0.04
100
Within
Category
8.1
31.3
60.5
0
0
100
0.2
0.8
0.8
1.9
96.5
100
100
0
0
0
0
100
-------
TABLE D-56
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093269 Total Mass of Particulates (mg) :
Coors: 387 Agency: 339
Monitor Location: Beaver Falls Calculated Mass (mg): 271
T
Date of Sample: 9/9/76 Air Concentration (ug/nf ):
Coors: 232 Agency: 168
Category
Flyash
5-10u
10-20y
20-50p
50-75p
>75y
Totals
Iron Oxide
5-10u
10-20u
20-50p
50-75p
>75\i
Totals
Magnetic
Iron
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Particle
Count
277
65
17
6
3
368
21
10
0
0
0
31
1
12
1
0
0
14
Percent By
Number
54.1
12.7
3.3
1.2
0.6
71.9
4.1
2.0
0
0
0
6.0
0.2
2.3
0.2
0
0
2.7
Percent By Mass
All
Categories
1.6
3.1
10.9
19.3
26.0
61.0
0.4
1.6
0
, 0
0
2.0
0.02
1.9
2.1
0
0
4.0
Within
Category
2.7
5.1
17.9
31.7
42.6
100
20.8
79.2
0
0
0
100
0.5
46.8
52.8
0
0
100
-------
TABLE D-56
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093269 (Continued)
Category
Quartz
5-10p
10-20p
20-50y
50-75U
>75y
Totals
Biological
5-lOy
10-20y
20-50y
50-75p
>75y
Totals
CaOO,3
\j
5-lOp
10-20u
20-50y
50-75y
>75jj
Totals
TOTALS
(All Category
Particle
Count
14
16
2
1
0
33
10
27
7
6
1
51
11
3
1
0
0
15
512
_es)
Percent By
Number
2.7
3.1
0.4
0.2
0
6.4
2.0
5.3
1.4
1.2
0.2
10.0
2.1
0.6
0.2
0
0
2.9
100
Percent By Mass
All
Categories
0.1
1.3
2.1
5.4
0
8.9
0.04
0.8
3.0
12.9
5.8
22.6
0.1
0.2
1.2
0
0
1.5
100
Within
Category
1.6
14.2
24.0
60.2
0
100
0.2
3.8
13.3
57.1
25.6
100
7.7
16.8
75.6
0
0
100
-------
TABLE D-57
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093267 Total Mass of Particulates (mg) :
Coors: 296 Agency: 330
Monitor Location: Koppel Calculated Mass (nig): 239
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors : 156 Agency : 174
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
292
71
21
7
3
394
15
1
0
0
0
16
0
0
0
0
0
0
Percent By
Number
59.8
14.5
4.3
1.4
0.6
80.7
3.1
0.2
0
0
0
3.3
0
0
0
0
0
0
Percent By Mass
All
Categories
2.0
3.8
15.3
25.5
.29.5
76.1
0.3
0.2
0
0
0
0.5
0
0
0
0
0
0
Within
Category
2.6
5.0
20.1
33.6
38.7
100
65.2
34.8
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-57
RESULTS OF OPTICAL PARTICLE COUNTS
(C< .11 tinned)
Filter Number: 1093267 (Continued)
Category
Quartz
5-10p
10-20p
20-50p
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Ca000
11 " O
5-lOy
10-20y
20-50y
50-75y
>75p
Totals
TOFALS
(All Category
Particle
Count
25
14
6
1
0
46
18
5
3
0
1
27
3
2
0
0
0
5
488
es)
1
Percent By
Number
5.1
2.9
1.2
0.2
0
9.4
3.7
1.0
0.6
0
0.2
5.5
0.6
0.4
0
0
0
1.0
100
Percent By Mass
All
Categories
0.3
1.2
7.3
6.1
0
14.9
0.08
0.2
1.4
0
6.5
8.3
0.04
0.2
0
0
0
0.2
100
Within
Category
1.9
8.4
48.9
40.8
0
100
1.0
2.2
17.6
0
79.2
100
15.8
84.2
0
0
0
100
-------
TABLE D-58
RESULTS OF OPrlCAL PARTICLE COUNTS
Filter Number: mo928 Total Mass of Particulates (mg) :
Coors: 333 Agency: 287
Monitor Location: , . Calculated Mass (mg): 341
Township fe °
2
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 178 Agency: 160
Category
Fly ash
5-lQii
10-20y
20-50|j
50-75y
>75y
Totals
Iron Oxide
5-lOy
10-20n
20-50n
50-75u
>75M
Totals
Magnetic
Iron
5-10y
10-20(j
20-50|j
50-75u
>75(j
Totals
Particle
Count
0
0
55
2
0
57
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
0
0
49.1
1.8
0
50.9
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
28.1
5.1
0
33.2
0
0
0
0
0
0
0
0
0
0
0
0
Wi thin
Category
0
0
84.6
15.4
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-58
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1110928 (Continued)
Category
Quartz
5-10y
10-20n
20-50p
50-75)j
>75y
Totals
Biological
5-10u
10-20n
20-50u
50-75U
>75y
Totals
CaC00
o
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
0
0
47
6
0
53
0
0
1
0
0
1
0
0
1
0
0
1
112
_os)
1
Percent By
Number
0
0
42.0
5.4
0
47.3
0
0
0.9
0
0
0.9
0
0
0.9
0
0
0.9
100
Percent By Mass
All
Categories
0
0
40.0
25.6
0
65.5
0
0
0.3
0
0
0.3
0
0
0.9
0
0
0.9
100
Within
Category
0
0
61.0
39.0
0
100
0
0
100
0
0
100
0
0
100
0
0
100
-------
TABLE D-59
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter)
1110929
Monitor Location: Brighton
Township
Date of Sample: 9/9/76
(Cover Filter to 1110928)
Category
Flyash
5-lO[j
10-20)j
20-50p
50-75p
>75M
Totals
Iron Oxide
5-10y
10-20u
20-50y
50-75U
>75M
Totals
Magnetic
Iron
5-10y
10-20M
20-50M
50-75y
>75y
Totals
Particle
Count
0
0
14
2
1
17
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Participates (ing) :
Coors : — Agency :
Calculated Mass (mg): 180
Air Concentration (vig/rrT ):
Coors : — Agency : —
Percent By
Number
0
0
36.
5.
2.
44.
8
3
6
7
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
13.5
9.6
13.0
36.2
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
0
0
37.4
26.7
35.9
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-59
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
(Cover Filter)
Filter Number: 1110929 (Continued)
Category
Quartz
5-10y
10-20y
20-50M
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOQ
o
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
0
0
15
2
1
18
0
0
3
0
0
3
0
0
0
0
0
0
38
(All Categories)
Percent By
Number
0
0
39.5
5.3
2.6
47.4
0
0
7.9
0
0
7.9
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
24.1
16.1
21.7
61.9
0
0
1.9
0
0
1.9
0
0
0
0
0
0
100
Within
Category
0
0
39.0
26.0
35.0
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-60
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093292 Total Mass of Participates (mg):
Coors: 667 Agency: 688
Monitor Location: Midland Calculated Mass (mg): 473
3
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 404 Agency: 341
Category
Flyash
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20^
20-50y
50-75u
>75y
Totals
*
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
0
0
56
4
5
65
0
0
10
3
0
13
0
0
0
0
0
0
Percent By
Number
0
0
55.4
4.0
5.0
64.4
0
0
9.9
3.0
0
12.9
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
20.6
7.4
24.8
52.8
0
0
12.0
18.1
0
30.1
0
0
0
0
0
0
Within
Category
0
0
39.0
14.0
47.0
100
0
0
40.0
60.0
0
100
0
0
0
0
0
0
-------
TABLE D-60
RESULTS OF OPTICAL PARTICLE COUNTS
(Gonlinued)
Filter Number: 1093292 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75y
Totals
CaOCL
5-1 Op
10-20p
20-50p
50-7 5y
>75y
Totals
TOTALS
(All Categor]
Particle
Count
0
0
15
1
0
16
0
0
6
0
1
7
0
0
0
0
0
0
101
es)
Percent By
Number
0
0
14.8
1.0
0
15.8
0
0
5.9
0
1.0
6.9
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
9.2
3.1
0
12.3
0
0
1.5
0
3.3
4.8
0
0
0
0
0
0
100
Within
Category
0
0
75.0
25.0
0
100
0
0
30.8
0
69.2
100
0
0
0
0
0
0
-------
TABLE D-61
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter)
1093293
Monitor Location: Midland
Date of Sanple: 9/9/76
(Cover Filter to 1093292)
Category
Flyash
5-J.On
10-20y
20-50^
50-75M
>75y
Totals
Iron Oxide
5-10|j
10-20y
20-50y
50-75y
>75)j
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
0
0
42
2
0
44
0
0
0
0
0
0
0
0
0
0
0
0
Perc
Nur
Total Mass of Particulates (mg) :
Coors : — Agency :
Calculated toss (mg): 328
3
Air Concentration (yg/m ):
Coors : — Agency :
Bnt By
Tiber
0
0
61.
2.
8
9
0
64.
7
0
0
0
0
0
0
0
0
0
0
0
0
Pe;rcent By Mass
AIL
Categories
0
0
22.3
5.3
0
27.6
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
0
0
80.8
19.2
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-61
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
„.,, M . (Cover Filter),
Filter Number: 1093293 t Continued)
Category
Quartz
5-10u
10-20u
20-50u
50-75M
>75y
Totals
Biological
5-10M
10-20u
20-50y
50-75u
>75y
Totals
CaC00
5-lOn
10-20u
20-50p
50-75p
>75y
Totals
TOTALS
(All Categori
Particle
Count
0
0
7
0
1
8
0
0
5
0
11
16
0
0
0
0
0
0
68
es)
Percent By
Number
0
0
10.3
0
1.5
11.8
0
0
7.4
0
16.2
23.5
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
6.2
0
11.9
18.1
0
0
1.8
0
52.5
54.2
0
0
0
0
0
0
100
Within
Category
0
0
34.2
0
65.8
100
0
0
3.3
0
96.7
100
0
0
0
0
0
0
-------
TABLE D-62
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106379
Monitor Location: Elco
Date of Sample: 9/9/76
Category
Flyash
5-1 On
10-20y
20-50^
50-75p
>75U
Totals
Iron Oxide
5-10M
10-20M
20-50p
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20u
20-50y
50-75y
>75p
Totals
Particle
Count
0
0
25
5
0
30
0
0
3
0
0
3
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors : 137 Agency : —
Calculated Mass (ing): 229
3
Air Concentration (yg/m ):
Coors : 84 Agency :
Percent By
Number
0
0
39.1
7.8
0
46.9
0
0
4.7
0
0
4.7
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
19.0
19.0
0
38.0
0
0
7.4
0
0
7.4
0
0
0
0
0
0
Within
Category
0
0
50.0
50.0
0
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-62
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106379 (Continued)
Category
Quartz
5-1 Oy
10-20y
20-50ij
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOO.D
5-10p
10-20u
20-50y
50-75y
>75M
Totals
TOTALS
(All Categon
Particle
Count
0
0
14
2
0
16
0
0
9
5
1
15
0
0
0
0
0
0
64
OS)
Percent By
Number
0
0
21.9
3.1
0
25.0
0
0
14.1
7.8
1.6
23.4
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
17.7
12.7
0
30.4
0
0
4.6
12.7
6.8
24.1
0
0
0
0
0
0
100
Within
Category
0
0
58.3
41.7
0
100
0
0
19.0
52.7
28.4
100
0
0
0
0
0
0
-------
TABLE D-63
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106323 Total Ntuss ol' ParLiculates (nig):
Coors: 5-7 Agency: 337
Monitor Location: Downtown Calculated Mass (mg): 23.7
Date of Sample: 9/9/76 Air Concentration (ug/m3):
Coors : — Agency : 159
Category
Fly ash
5-10p
10-20y
2Q-50y
50-75 y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75M
>75y
Totals
Magnetic
Iron
5-10y
10-20]j
20-50y
50-75y
>75y
Totals
Particle
Count
17
3
2
1
0
23
0
1
0
0
0
1
0
0
0
0
0
0
Percent By
Number
43.6
7.7
5.1
2.6
0
59.0
0
2.6
0
0
0
2.6
0
0
0
0
0
0
Percent By Mass
All
Categories
1.2
1.6
14.7
36.7
0
54.2
0
1.8
0
0
0
1.8
0
0
0
0
0
0
Within
Category
2.1
3.0
27.1
67.8
0
100
0
100
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-63
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106323 (Continued)
Category
Quartz
5-10u
10-20p
20-50n
50-75y
>75y
Totals
Biological
5-10p
10-20y
20-50y
50-75p
>75y
Totals
CaC00
' O
5-10y
10-20u
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
6
2
1
0
0
9
0
0
6
0
0
6
0
0
0
0
0
0
39
es)
Percent By
Number
15.4
5.1
2.6
0
0
23.1
0
0
15.4
0
0
15.4
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.7
1.8
12.2
0
0
14.7
0
0
29.3
0
0
29.3
0
0
0
0
0
0
100
Within
Category
4.6
12.3
83.1
0
0
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-64
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106327 Total Mass of Particulates (mg) :
Coors: 429 Agency: 428
Monitor Location: Central Lab Calculated Mass (mg): 203
Date of Sample: 9/9/76 Air Concentration (yg/m ) :
Coors : 219 Agency : 235
Category
Flyash
5-1 Ou
10-20y
20-50p
50-75)j
>75M
Totals
Iron Oxide
5-10y
10-20y
20-50u
50-75U
>75M
Totals
Magnetic
11X511
5-10u
10-20n
20-50u
50-75|j
>75y
Totals
Particle
Count
326
107
21
4
3
461
23
7
0
0
0
30
0
0
0
0
0
0
Percent By
Number
58.1
19.1
3.7
0.7
0.5
82.2
4.1
1.2
0
0
0
5.3
0
0
0
0
0
0
Percent By Mass
All
Categories
2.6
6.8
18.0
17.2
34.7
79.2
0.6
1.4
0
0
0
2.0
0
0
0
0
0
0
Within
Category
3.3
8.6
22.7
21.7
43.8
100
29.1
70.9
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-64
RESULTS OF OPTICAL PARTICLE
(Continued)
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
1 " \J
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTAIS
(All Categor:
Filter Number
Particle
Count
13
12
9
0
0
34
0
12
6
0
0
18
16
2
0
0
0
18
561
.es)
i
' : 1106327
Percent By
Number
2.3
2.1
1.6
0
0
6.1
0
2.1
1.1
0
0
3.2
2.8
0.4
0
0
0
3.2
100
(Continued)
Percent
All
Categories
0.2
1.3
12.9
0
0
14.3
0
0.5
3.4
0
0
3.9
0.2
0.2
0
0
0
3.9
100
By Mass
Within
Category
1.2
8.9
89.9
0
0
100
0
12.9
87.1
0
0
100
50.0
50.0
0
0
0
100
-------
TABLE D-65
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter)
1106328
Monitor Location: Central Lab
Date of Sample: 9/9/76
(Cover Filter for 1106327
Category
Flyash
5-10ii
10-20p
20-50M
50-75U
>75p
Totals
Iron Oxide
5-10p
10-20M
20-50p
50-75y
>75^i
Totals
Magnetic
Iron
5-10u
10-20u
20-50)j
50-75y
>75p
Totals
Part icle
Count
264
76
25
6
7
378
12
15
0
0
0
27
0
0
0
0
0
0
Total Mass of Porticulates (mg) :
Coors : Agency :
Calculated Mass (mg): 357
3
Air Concentration (pg/m ):
Coors : — Agency :
Percent By
Number
56.5
16.3
5.4
1.3
1.5
80.9
2.6
3.2
0
0
0
5.8
0
0
0
0
0
0.
Percent By Mass
All
Categories
1.2
2.7
12.2
14.6
46.0
76.8
0.2
1.8
0
0
0
1.9
0
0
0
0
0
0
Within
Category
1.6
3.6
15.9
19.1
59.9
100
9.1
90.9
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-65
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: ^i^32glte?i>ntlnued)
Category
Quartz
5-10M
10-20y
20-50u
50-75U
>75y
Totals
Biological
5-lOjj
10-20y
20-50y
50-75y
>75y
Totals
CaOCL
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
21
6
4
0
1
32
1
8
4
3
0
16
14
0
0
0
0
14
467
es)
Percent By
Number
4.5
1.3
0.8
0
0.2
6.8
0.2
1.7
0.8
0.6
0
3.4
3.0
0
0
0
0
3.0
100
Percent By Mass
All
Categories
0.2
0.4
3.2
0
11.0
14.7
0.003
0.2
1.3
4.9
0
6.4
0.1
0
0
0
0
0.1
100
Within
Category
1.1
2.4
22.1
0
74.4
100
0.05
3.0
20.4
76.5
0
100
100
0
0
0
0
100
-------
TABLE D-66
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106353 Total Muss of Participates (mg) :
Coors: 280 Agency: 238
Monitor Location: Hazelwood Calculated Mass (mg): 232
Date of Sample: 9/9/76 Air Concentration (yg/m ) :
Coors: 137 Agency: 140
Category
Flyash
5-10u
10-20y
20-50jj
50-75y
>75y
Totals
Iron Oxide
5-10p
10-20n
20-50y
50-75p
>75y
Totals
Magnetic
Iron
5-lOy
10-20y
20-50y
50-75M
>75M
Totals
Particle
Count
424
128
14
2
4
572
52
14
3
0
0
69
0
0
0
0
0
0
Percent By
Number
55.8
16.8
1.8
0.3
0.5
75.3
6.8
1.8
0.4
0
0
9.1
0
0
0
0
0
0
Percent By Miss
All
Categories
2.9
7.1
10.5
7.5
40.5
68.6
1.2
2.5
7.4
0
0
11.1
0
0
0
0
0
0
Within
Category
4.3
10.4
15.3
11.0
59.0
100
10.6
22.9
66.4
0
0
100
0
0
0
0
0
0
-------
TABLE D-66
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106353 (Continued)
Category
Quartz
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOO
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
56
14
2
2
0
74
16
6
0
1
0
23
20
2
0
0
0
22
760
(All Categories)
Percent By
Number
7.4
1.8
0.3
0.3
0
9.7
2.1
0.8
0
0.1
0
3.0
2.6
0.3
0
0
0
2.9
100
Percent By Mass
All
Categories
0.6
1.3
2.5
12.5
0
17.0
0.07
0.2
0
2.5
0
2.8
0.2
0.4
0
0
0
0.4
100
Within
Category
3.8
7.6
14.7
73.8
0
100
2.6
7.9
0
89.4
0
100
55.6
44.4
0
0
0
100
-------
TABLE D-67
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6386
Monitor Location: North Braddock
Date of Sample: 9/9/76
Category
Flyash
5-1 Op
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75)j
>75y
Totals
Particle
Count
349
70
15
5
8
447
79
8
0
0
0
87
9
2
0
0
0
11
Total Mass oi.' Participates (mg) :
Coors: 474 Agency: 532
Calculated Mass (mg): 304
3
Air Concentration (yg/m ):
Coors: 248 Agency: 272
Percent By
Number
54.0
10.8
2.3
0.8
1.2
69.2
12.2
1.2
0
0
0
13.5
1.4
0.3
0
0
0
1.7
Percent By Mass
All
Categories
1.8
3.0
8.6
14.3
61.6
89.4
1.4
1.1
0
0
0
2.5
0.2
0.3
0
0
0
0.4
Within
Category
2.1
3.3
9.6
16.0
69.0
100
55.2
44.7
0
0
0
100
36.0
64.0
0
0
0
100
-------
( TABLE D-67
RESULTS OF OPTICAL PARTICLE COUNTS
(Gmtinued)
rVl t" £* ( YC) T*\7
Quartz
5-lOy
10-20y
20-50U
50-75M
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO0
\J
5-10y
10-20y
20-50p
50-75y
>75y
Totals
TOTALS
(All Categon
Filter Number
Particle
Count
40
15
6
0
0
61
7
0
0
0
0
7
29
4
0
0
0
33
646
1
' : 1106386
Percent By
Number
6.2
2.3
0.9
0
0
9.4
1.1
0
0
0
0
1.1
4.5
0.6
0
0
0
5.1
100
(Continued)
Percent
All
Categories
0.4
1.0
5.7
0
0
7.1
0.02
0
0
0
0
0.02
0.3
0.3
0
0
0
0.6
100
By Mass
Within
Category
4.9
14.8
80.2
0
0
100
100
0
0
0
0
100
47.5
52.4
0
0
0
100
-------
TABLE D-68
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: H06383 Total Muss of Particulates (mg) :
Coors: 423 Agency: 524
Monitor Location: Duquesne II Calculated Mass (mg): 195
3
Date ol Sample: 9/9/76 Air Concentration (ug/m ):
Coors: 242 Agency: 260
Category
Flyash
5-lOiJ
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75p
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
312
93
35
1
2
443
66
12
0
0
0
78
0
0
0
0
0
0
Percent By
Number
52.3
15.6
5.9
0.2
0.3
74.2
11.0
2.0
0
0
0
13.1
0
0
0
0
0
0
Percent By Mass
All
Categories
2.6
6.2
31.3
4.5
24.1
68.6
1.8
2.6
0
0
0
4.4
0
0
0
0
0
0
Within
Category
3.8
9.0
45.6
6.5
35.1
100
40.7
59.2
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-68
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106383 (Continued)
Category
Quartz
5-10u
10-20p
2O-50u
50-75y
>75p
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10p
10-20M
20-50n
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
30
17
0
0
0
47
0
7
0
0
3
19
19
0
0
0
0
19
597
es)
Percent By
Number
5.0
2.8
0
0
0
2.9
0
1.2
0
0
0.5
1.7
3.2
0
0
0
0
3.2
100
Percent By Mass
All
Gitegories
0.4
1.9
0
0
0
2.3
0
,0.3
0
0
24.1
24.4
0.3
0
0
0
0
0.3
100
Within
Category
18.1
81.9
0
0
0
100
0
1.3
0
0
98.7
100
100
0
0
0
0
100
-------
TABLE D-69
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6388
Monitor Location: Liberty Boro
Date of Sample: 9/9/76
Category
Fly ash
5-lOu
10-20y
20-50y
50-75y
>75M
Totals
Iron Oxide
5-10u
lO20n
20-50M
50-75y
>75(j
Totals
Magnetic
Iron
5-10M
10-20p
20-50U
50-75u
>75y
Totals
Particle
Count
0
0
84
17
12
113
0
0
5
0
0
5
0
0
0
0
0
0
Total Moss of Participates (mg) :
Coors : 470 Agency : 582
Calculated Mass (mg): 607
3
Air Concentration (ug/m ):
Ccxn-s: 289 Agency: 315
Percent By
Number
0
0
70.
14.
10.
94.
0
2
0
2
0
0
4.
2
0
0
4.
2
0
0
0
0
0
0
Percent By Miss
AIL
Categories
0
0
24.1
24.4
46.4
94.9
0
0
4.7
0
0
4.7
0
0
0
0
0
0
Within
Category
0
0
25.4
25.7
48.9
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-69
RESULTS OF OFI'ICAL PARTI CUE COUNTS
(Continued)
Filter Number: 1106388 (Continued)
Category
Quartz
5-10u
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50p
50-75y
>75M
Totals
CaC03
5-1 Oy
10-20y
20-50ij
50-75u
>75p
Totals
TOTALS
(All Categori
Particle
Count
0
0
0
0.
0
0
0
0
2
0
0
2
0
0
0
0
0
0
120
es)
1
Percent By
Number
0
0
0
0
0
0
0
0
1.7
0
0
1.7
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
0
0
0
0
0
0
0.4
0
0
0.4
0
0
0
0
0
0
100
Wi thin
Category
0
0
0
0
0
0
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-70
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
(Filter Redone) 1106387 ^^ __ ^^ __
Monitor Location: Liberty Boro Calculated Mass (mg): 246
3
Date of Sample: 9/9/76 Air Concentration (ug/m ):
(Cover Filter for 1106388) Coors: — Agency:
Category
Fly ash
5-10u
10-20y
20-50p
50-75p
>75y
Totals
Iron Oxide
5-10M
10-20jj
20-50u
50-75p
>75M
Totals
Magnetic
Iron
5-10y
10-20)j
20-50y
50-75u
>75y
Total's
Particle
Count
239
78
16
1
5
339
53
10
2
0
0
65
14
7
0
0
0
21
Percent By
Number
46.0
15.0
3.1
0.2
1.0
65.3
10.2
1.9
0.4
0
0
12.5
2.7
1.3
0
0
0
4.0
Percent By Mass
All
Categories
1.6
4.1
11.3
3.5
47.6
68.2
1.1
1.7
4.6
0
0
7.5
0.3
1.2
0
0
0
1.5
Within
Category
2.3
6.0
16.6
5.2
69.9
100
15.2
22.9
61.9
0
0
100
20.0
80.0
0
0
0
100
-------
TABLE D-70
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
(Cover Filter)
Fi Iter Number : H06387 (Continued)
Category
Quartz
5-10y
10-20M
20-50y
50-75M
>75p
Totals
Biological
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50n
50-75)j
>75M
Totals
TOTALS
Particle
Count
20
6
7
0
0
33
3
4
0
0
2
9
47
5
0
0
0
52
519
(All Categories)
1
Percent By
Number
3.8
1.2
1.3
0
0
6.4
0.6
0.8
0
0
0.4
1.7
9.0
1.0
0
0
0
10.0
100
Percent By Mass
All
Categories
0.2
0.5
8.2
0
0
9.0
0.01
0.1
0
0
12.7
12.9
0.6
0.5
0
0
0
1.0
100
Within
Category
2.4
5.8
91.8
0
0
100
0.1
1.1
0
0
98.8
100
54.0
46.0
0
0
0
100
-------
TABLE D-71
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106381 Total Mass of Particulates (mg) :
Coors: 293 Agency: 330
Monitor Location: Clairton Calculated Muss (mg): 295
3
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 127 Agency: 178
Category
Fly ash
5-10d
10-20y
20-50|j
50-75p
>75U
Totals
Iron Oxide
5-10y
10-20y
20-50p
50-75p
>75M
Totals
Magnetic
Iron
5-10u
10-20u
20-50jj
50-75n
>75p
Totals
Particle
Count
0
0
66
6
2
74
0
0
3
0
0
3
0
0
0
0
0
0
Percent By
Number
0
0
72.5
6.6
2.2
81.3
0
0
3.3
0
0
3.3
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
38.9
17.7
15.9
72.6
0
0
5.8
0
0
5.8
0
0
0
0
0
0
Within
Category
0
0
53.7
24.4
21.9
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-71
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1106381 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-lOu
10-20u
20-50p
50-75y
>75y
Totals
CaCO,
O
5-lOp
10-20^
20-50(j
50-75y
>75M
Totals
TOTALS
(All Categori
Particle
Count
0
0
9
1
0
10
0
0
0
4
0
4
0
0
0
0
0
0
91
OS)
Per i1, en t By
Number
0
0
9.9
1.1
0
11.0
0
0
0
4.4
0
4.4
0
0
0
0
0
0
100
Percent By Muss
Al 1
Categories
0
0
8.8
4.9
0
13.8
0
0
0
7.9
0
7.9
0
0
0
0
0
0
100
Wi thin
Category
0
0
64.3
35.7
0
100
0
0
0
100
0
100
0
0
0
0
0
0
-------
TABLE D-72
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Participates (mg) :
1106382 Coors: Agency:
Monitor Location: Clairton Calculated Mass (mg): 175
3
Date of Sample: 9/9/76 Air Concentration (yg/nf):
(Cover Filter to 1106381) Coors: — Agency:
Category
Flyash
5-10iJ
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
0
0
19
2
2
23
0
0
2
0
0
2
0
0
0
0
0
0
Percent By
Number
0
0
48.7
5.1
5.1
59.0
0
0
5.1
0
0
5.1
0
0
0
0
0
0
Percent By Mass
• All
Categories
0
0
18.9
10.0
26.8
55.7
0
0
6.5
0
0
6.5
0
0
0
0
0
0
Within
Category
0
0
34.0
17.9
48.2
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-72
RESULTS OF OPHCAL PARTICLE COUNTS
(G)iitinued)
Filter Number: (C°ver Filter(>Continued)
1106382
Category7
Quartz
5-10u
10-20p
20-50n
50-75M
>75p
Totals
Biological
5-10p
10-20y
20-50u
50-75y
>75y
Totals
CaOOQ
O
5-10(j
10-20u
20-50M
50-75y
>75y
Totals
TOTALS
(All Categor]
Particle
Count
0
0
5
2
0
7
0
0
6
0
1
7
0
0
0
0
0
0
39
.es)
I
Percent By
Number
0
0
12.8
5.1
0
17.9
0
0
15.4
0
2.6
17.9
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
8.3
16.6
0
24.9
0
0
4.0
0
8.9
12.9
0
0
0
0
0
0
100
Within
Category
0
0
33.3
66.7
0
100
0
0
30.8
0
69.2
100
0
0
0
0
0
0
-------
TABLE D-73
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093294 Total Mass of Particulates (mg) :
Coors: 177 Agency: 294
Monitor Location: Airport Calculated Mass (mg): 213
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 207 Agency: 147
Category
(
Flyash
5-10)1
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
I ron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
403
61
25
2
1
492
27
10
0
0
0
37
0
0
0
0
0
0
Percent By
Number
65.8
10.0
4.1
0.3
0.2
80.4
4.4
1.6
0
0
0
6.0
0
0
0
0
0
0
Percent By Mass
All
Categories
3.0
3.7
20.4
8.2
11.0
46.4
0.7
2.0
0
0
0
2.6
0
0
0
0
0
0
Within
Category
6.6
8.0
44.1
17.6
23.8
100
25.2
74.8
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-73
RESULTS OF OPTICAL PARTICLE COUiYrS
(C'diit inued)
Filter Number: 1093294 (Continued)
Category
Quartz
5-10y
10-20u
20-50u
50-75p
>75M
Totals
Biological
5-10p
10-20y
20-50p
50-75u
>75y
Totals
CaCOQ
5-10u
10-20u
20-50|j
50-75p
>75)j
Totals
TOTALS
Particle
Count
21
1
3
0
0
25
12
4
11
12
1
40
18
0
0
0
0
18
612
(All Categories)
I
Percent By
Number
3.4
0.2
0.5
0
0
4.1
2.0
0.6
1.8
2.0
0.2
6.5
2.9
0
0
0
0
2.9
100
Percent By Mass
All
Categories
0.2
0.1
4.1
0
0
4.4
0.06
0.2
6.0
32.7
7.3
46.3
0.2
0
0
0
0
0.2
100
Wi thin
Category
5.9
2.3
91.8
0
0
100
0.1
0.3
13.0
70.7
15.9
100
100
0
0
0
0
100
-------
TABLE D-74
RESULTS OF OPTICAL PARTICLE CX)UNTS
Filter Number: 1106310 Total Mass of Particulates (mg) :
Coors: 278 Agency: 214
Monitor Location: South Fayette Calculated Mass (mg): 571
3
Date of Sample: 9/9/76 Air Concentration (ug/m ):
Coors: 145 Agency: 107
Category
Fly ash
5-lOu
10-20y
20-50p
50-75p
>75M
Totals
Iron Oxide
5-10u
10-20M
20-50n
50-75y
>75M
Totals
Magnetic
I inn
5-lOp
10-20jj
20-50,j
50-75p
>75u
Totals
Particle
Count
139
30
16
7
2
194
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
34.1
7.4
3.9
1.7
0.5
47.5
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
AJ]
Categories
0.4
0.7
4.9
10.7
8.2
24.8
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
1.6
2.7
19.6
43.0
33.1
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-74
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Quartz
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO^
vJ
5-10y
10-20 y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Filter Number
Particle
Count
8
3
1
0
0
12
138
14
16
13
21
202
0
0
0
0
0
0
408
OS)
1 : 1106310
Percent By
Number
2.0
0.7
0.2
0
0
2.9
33.8
3.4
3.9
3.2
5.1
49.5
0
0
0
0
0
0
100
(Continued)
Percent
Al 1
Categories
0.04
0.1
0.5
0
0
0.6
0.2
0.2
3.2
13.2
57.5
74.5
0
0
0
0
0
0
100
By Mass
Within
Category
5.7
17.1
77.2
0
0
100
0.3
0.3
4.4
17.8
77.2
100
0
0
0
0
0
0
-------
TABLE D-75
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093227 & 1093228 Total Mass of Participates (mg) :
(combined cover & primary filters) Coors: 149 Agency: 166
Monitor Location: Midland Calculated Mass (mg): 473
3
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors : 83 Agency : 80
Category
Flyash
5-lQii
10-20y
20-50U
50-75p
>75y
Totals
Iron Oxide
5-10y
10-20p
2Q-50U
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20u
20-50p
50-75(j
>75y
Totals
Particle
Count
367
105
26
3
4
505
20
24
0
0
0
44
0
0
0
0
0
0
Percent By
Number
51.2
14.6
3.6
0.4
0.6
70.4
2.8
3.3
0
0
0
6.1
0
0
0
0
0
0
Percent By Mass
All
Categories
1.2
2.9
9.6
5.5
19.8
39.1
0.2
2.1
0
0
0
2.4
0
0
0
0
0
0
Within
Category
3.2
7.3
24.5
14.2
50.8
100
9.4
90.6
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-75
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: ?"??:??! & (Continued)
l(J9o^o
Category
Quartz
5-10y
10-20y
20-50M
50-75U
>75M
Totals
Biological
5-10y
10-20u
20-50y
50-75y
>75y
Totals
CaOO,
O
5-10y
10-20y
20-50n
50-75y
>75p
Totals
TOTA1S
(All Categori
Particle
Count
35
23
19
2
0
79
29
12
4
4
10
59
29
1
0
0
0
30
717
.es)
Percent By
Number
4.9
3.2
2.6
0.3
0
11.0
4.0
1.7
0.6
0.6
1.4
8.2
4.0
0.1
0
0
0
4.2
100
Percent By Mass
All
Categories
0.2
1.0
11.7
6.1
0
19.0
0.06
0.2
1.0
4.9
33.1
39.3
0.2
0.05
0
0
0
0.2
100
Within
Category
1.0
5.5
61.2
32.2
0
100
0.2
0.6
2.5
12.5
84.2
100
78.4
21.6
0
0
0
100
-------
TABLE D-76
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: i093229 & 1093230
'combined cover & primary filters)
Monitor Location: Airport
Date of Sample: 8/16/76
Category
Flyash
5-10p
10-20y
20-50p
50-75y
>75y
Totals
Iron Oxide
5-10u
10-20y
20-50y
50— 75p
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50— 75y
>75p
Totals
Particle
Count
347
85
17
4
0
453
30
0
0
0
0
30
9
2
0
0
0
11
Total Mass of Particulates (mg) :
Coors: 149 Agency: 151
Calculated Mass (mg) : 194
3
Air Concentration (yg/rrf ):
Coors : 76 Agency : 72
Percent By
Number
53.
13.
2.
0.
6
1
6
6
0
70.
4.
0
6
0
0
0
0
4
1
0
6
4
3
0
0
0
1
7
Percent By Mass
All
Categories
2.9
5.6
15.3
18.0
0
41.8
0.8
0
0
0
0
0.8
0.2
0.4
0
0
0
0.6
Within
Category
6.9
13.5
36.6
43.0
0
100
100
0
0
0
0
100
36.0
64.0
0
0
0
100
-------
TABLE D-76
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
„.-,, M , 1093229 & ,„ . ,,
r liter Number: -,^o^™ (Continued)
1093230
Category
Quartz
5-10y
10-20y
20-50u
50-75M
>75y
Totals
Biological
5-10p
10-20y
20-50y
50-75y
>75y
Totals
CaC00
5-lOp
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
Particle
Co imt
44
13
9
2
0
68
27
11
10
1
2
51
34
0
0
0
0
34
647
(All Categories)
Percent By
Number
6.8
2.0
1.4
0.3
0
10.5
4.2
1.7
1.5
0.2
0.3
7.9
5.2
0
0
0
0
5.2
100
Percent By Mass
All
Categories
0.6
1.4
13.5
15.0
0
30.5
0.1
0.5
6.0
3.0
16.1
25.7
0.5
0
0
0
0
0.5
100
Within
Category
2.0
4.7
44.2
49.1
0
100
0.6
1.9
23.2
11.6
62.6
100
100
0
0
0
0
100
-------
TABLE D-77
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093239 & 1093240 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 140 Agency: 90
Monitor Location: South Fayette Calculated Mass (mg): 70
3
. Date of Sample: 8/16/76 Air Concentration (ug/m ):
Coors : 69 Agency : 41
Category
Flyash
5-lOp
10-20^
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20u
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
20-50u
50-75y
Totals
Particle
Count
254
58
13
0
0
325
16
2
0
0
0
18
17
3
0
0
0
20
Percent By
Number
53.5
12.2
2.7
0
0
68.4
3.3
0.4
0
0
0
3.8
3.6
0.6
0
0
0
4.2
Percent By Mass
All
Categories
5.8
10.6
32.1
0
0
48.5
1.2
1.2
0
0
0
2.4
1.3
1.8
0
0
0
3.1
Within
Category
12.0
21.8
66.2
0
0
100
50.0
50.0
0
0
0
100
41.5
58.5
0
0
0
100
-------
TABLE D-77
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1Q93240 & (Contlnued)
Category
Quartz
5-10vi
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCOQ
5-1 Oy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
19
9
3
0
0
31
21
22
2
0
1
46
34
1
0
0
0
35
465
es)
Percent By
Number
4.0
1.9
0.6
0
0
6.5
4.4
4.6
0.4
0
0.2
9.7
7.2
0.2
0
0
0
7.4
100
Percent By Mass
All
Categories
0.7
2.7
12.4
0
0
15.8
0.3
2.7
3.3
0
22.2
28.5
1.4
0.3
0
0
0
1.7
100
Within
Category
4.6
17.3
78.1
0
0
100
1.1
9.4
11.6
0
77.9
100
81.0
19.0
0
0
0
100
-------
TABLE D-78
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093290 & 1093291 Total Muss of Particulates (mg) :
(combined cover & primary filters) Coors: 374 Agency: 351
Monitor Location: Baden Calculated Mass (mg): 258
3
Date of Sample: 8/28/76 Air Concentration (yg/nf):
Coors: 203 Agency: 183
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
1 1X511
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
573
147
40
6
2
768
43
10
0
0
0
53
26
9
0
0
0
35
Percent By
Number
58.8
15.1
4.1
0.6
0.2
78.8
4.4
1.0
0
0
0
5.4
2.7
0.9
0
0
0
3.6
Percent By Mass
All
Categories
3.6
7.3
27.0
20.2
18.2
76.3
0.9
1.6
0
0
0
2.5
0.5
1.5
0
0
0
2.0
Within
Category
4.7
9.6
35.4
26.5
23.8
100
35.0
65.0
0
0
0
100
26.5
73.5
0
0
0
100
-------
TABLE D-78
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
T--H MI 1093290 & ._ _
Filter Number: 1O93291 (Continued)
Category
Quartz
5-10y
10-20u
20-50u
50-75y
>75y
Totals
Biological
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
CaC00
v3
5-10y
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
22
7
7
0
0
36
33
19
6
3
0
61
21
1
0
0
0
22
975
es)
Percent By
Number
2.2
0.7
0.7
0
0
3.7
3.4
1.9
0.6
0.3
0
6.2
2.2
0.1
0
0
0
2.2
100
Percent By Mass
All
Categories
0.2
0.6
7. .9
0
0
8.7
0.1
0.6
2/7
6.7
0
10.2
0.2
0.09
0
0
0
0.3
100
Within
Category
2.6
6.7
90.6
0
0
100
1.3
6.2
26.4
66.1
0
100
72.4
27.6
0
0
0
100
-------
TABLE D-79
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093288 & 1093289
(combined cover & primary filters)
Monitor Location: Beaver Falls
Date of Sample: 8/28/76
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20ji
20-50y
50-75y
>75y
Totals
Particle
Count
444
96
21
6
3
570
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Particulates (nig) :
Coors: 277 Agency: 266
Calculated Mass (mg): 314
3
Air Concentration (yg/m ):
Coors: 164 Agency: 137
Percent By
Number
57.0
12.3
2.7
0.8
0.4
73.2
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
2.3
3.9
11.6
16.6
22.4
56.9
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
4.0
6.9
20.4
29.2
39.4
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-79
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1Q93289 & (Continued)
Category
Quartz
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75M
Totals
Ca003
5-10u
10-20^
20-50n
50-75u
>75y
Totals
TOTAI-S
Particle
Count
14
6
5
0
0
25
48
85
44
5
2
184
0
0
0
0
0
0
779
(All Categories)
Percent By
Number
1.8
0.8
0.6
0
0
3.2
6.2
10.9
5.6
0.6
0.2
23.6
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.1
0.4
4.6
0
0
5.1
0.2
2.3
16.2
9.2
10.0
38.0
0
0
0
0
0
0
100
Within
Category
2.3
8.0
89.7
0
0
100
0.4
6.1
42.8
24.4
26.2
100
0
0
0
0
0
0
-------
TABLE D-80
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106308 & 1106309
(combined cover & primary filters)
Monitor Location: Hazelwood
Date of Sample: 8/28/76
Category
Fly ash
5-10u
10-20y
20-50U
50-75u
>75U
Totals
Iron Oxide
5-10vi
10-20U
20-50^
50-75p
>75U
Totals
Magnetic
Iron
5-lOn
10-20p
20-50]j
50-75u
>75y
Totals
Particle
Count
268
69
27
3
0
367
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors : 151 Agency : 143
Calculated Mass (mg): 157
3
Air Concentration (yg/m ):
Coors : 71 Agency : 76
Percent By
Number
44.
11.
4.
0.
4
4
5
5
0
60.
8
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
2.7
5.6
29.9
16.6
0
54.9
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
5.0
10.3
54.4
30.3
0
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-80
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
1106308 & ,
Filter Number: nn6309 (Continued)
Category
Quartz
5-10u
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50u
50-75p
>75y
Totals
CaC00
O
5-10u
10-20M
20-50yj
50-75p
>75y
Totals
TOTALS
Particle
Count
13
11
2
0
0
26
130
33
12
2
2
179
30
2
0
0
0
32
604
(All Categories)
Percent By
Number
2.2
1.8
0.3
0
0
4.3
21.5
5.5
2.0
0.3
0.3
29.6
5.0
0.3
0
0
0
5.3
100
Percent By Mass
All
Categories
0.2
1.5
3.7
0
0
5.4
0.9
1.8
8.8
7.4
19.9
38.8
0.6
0.3
0
0
0
0.8
100
Within
Category
4.1
27.7
68.2
0
0
100
2.3
4.6
22.8
19.0
51.2
100
65.3
34.8
0
0
0
100
-------
TABLE D-81
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093298 & 1093299
(combined cover & primary filters)
Monitor Location: North Braddock
Date of Sample: 8/28/76
Category
Flyash
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
562
117
28
6
4
717
86
13
0
0
0
99
46
27
2
0
0
75
Total Mass of Particulates (mg) :
Coors: 289 Agency: 214
Calculated Mass (mg): 405
Air Concentration (yg/m ):
Coors: 153 Agency: 108
Percent By
Number
54
11
2
0
0
69
8
1
6
4
7
6
4
7
3
3
0
0
0
9
4
2
0
6
5
6
.2
0
0
7
3
Percent By Mass
All
Categories
2.2
3.7
12.0
12.9
23.2
54.1
1.1
1.4
0
0
0
2.5
0.6
2.8
2.8
0
0
6.2
Within
Category
4.1
6.9
22.3
23.9
42.8
100
7.6
92.4
0
0
0
100
9.6
45.2
45.2
0
0
100
-------
TABLE D-81
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093298 & (Continued)
1093299
Category
Quartz
5-10y
10-20^
20-50p
50-75p
>75y
Totals
Biological
5-10p
10-20y
20-50p
50-75y
>75y
Totals
CaC00
5-lOy
10-20u
20-50p
50-75y
>75p
Totals
TOTALS
(All Categon
Particle
Count
15
14
10
1
1
41
20
15
6
1
3
45
43
9
0
0
0
52
1029
_es)
I
Percent By
Number
1.4
1.4
1.0
0.1
0.1
4.0
1.9
1.4
0.6
0.1
0.3
4.4
4.2
0.9
0
0
0
5.0
100
Percent By Mass
All
Categories
0.1
0.7
7.2
3.6
9.7
21.3
0.05
0.3
1.7
1.4
11.6
15.1
0.3
0.5
0
0
0
0.8
100
Within
Category
0.5
3.5
33.7
16.9
45.4
100
0.4
2.1
11.4
9.5
76.7
100
37.4
62.6
0
0
0
100
-------
TABLE D-82
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106300 & 1106301 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 68 Agency: —
Monitor Location : Duquesne II Calculated Mass (mg) : 40
Date of Sample: 8/28/76 Air Concentration (yg/m3):
Coors : — Agency :
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
21
8
1
0
1
31
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
31.3
11.9
1.5
0
1.5
46.3
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
0.8
2.6
4.3
0
58.4
66.2
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
1.3
3.9
6.6
0
88.3
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-82
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 110630° & (Continued)
1106301
Category
Quartz
5-10y
10-20p
20-50p
50-75p
>75M
Totals
Biological
5-lOy
10-20ij
20-50p
50-75y
>75y
Totals
CaCO0
5-10y
10-20y
20-50M
50-75y
>75y
Totals
TOTALS
Particle
Count
5
1
0
0
0
6
6
18
5
1
0
30
0
0
0
0
0
0
67
(All Categories)
1
Percent By
Number
7.5
1.5
0
0
0
9.0
9.0
26.9
7.5
1.5
0
44.8
0
0
0
0
0
0
100
Percent By Mass
All
Gitegories
0.3
0.5
0
0
0
0.9
0.2
3.8
14.4
14.5
0
32.9
0
0
0
0
0
0
100
Within
Category
38.5
61.5
0
0
0
100
0.5
11.7
43.9
43.9
0
100
0
0
0
0
0
0
-------
TABLE D-83
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6302 & H06303 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 207 Agency: 271
Monitor Location: Liberty Boro Calculated Mass (mg): 227
*^j
Date of Sample: 8/28/76 ^Y Concentration (ug/m ):
Coors : 130 Agency : 136
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
467
188
22
3
5
685
24
5
0
0
0
29
0
0
0
0
0
0
Percent By
Number
58.6
23.6
2.8
0.4
0.6
85.9
3.0
0.6
0
0
0
3.6
0
0
0
0
0
0
Percent By Mass
All
Categories
3.3
10.7
16.9
11.5
51.8
94.2
0.6
0.9
0
0
0
1.5
0
0
0
0
0
0
Within
Category
3.5
11.3
17.9
12.2
54.9
100
37.5
62.5
0
0
0
100
0
0
0
0
0
0
-------
TABLE D-83
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 11-06302 & (Continued)
1106303
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
20
6
1
0
0
27
19
18
2
0
0
39
15
2
0
0
0
17
797
(An Categories)
Percent By
Number
2.5
0.8
0.1
0
0
3.4
2.4
2.2
0.2
0
0
4.9
1.9
0.2
0
0
0
2.1
100
Percent By Mass
Al]
Categories
0.2
0.6
1.3
0
0
2.1
0.09
0.7
1.0
0
0
1.8
0.2
0.2
0
0
0
0.4
100
Within
Category
11.4
27.2
61.4
0
0
100
5.0
38.0
57.0
0
0
100
48.4
51.6
0
0
0
100
-------
TABLE D-84
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1110928 & 1110929 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 338 Agency: 287
Monitor Location: „ , . Calculated toss (mg): 522
3
Date of Sample: 9/9/76 Air Concentration (yg/nf ):
Coors: 178 Agency: 160
Category
Flyash
5-lQii
10-20y
20-50p
50-75)j
>75M
Totals
Iron Oxide
5-10y
10-20y
20~50u
50-75M
>75p
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Particle
Count
0
0
69
4
1
74
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
0
0
46.0
2.7
0.7
49.3
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
23.0
6.7
4.5
34.2
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
0
0
67.3
19.5
13.1
100
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE D-84
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: }I"|^QOQ ^ (Continued)
Category
Quartz
5-10y
10-20y
20-50ui
50-75y
>75u
Totals
Biqlogical
5-10M
10~20y
20-50y
50~75y
>75y
Totals
CaOOQ
5-lOy
10-20M
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
0
0
62
8
1
71
0
0
4
0
0
4
0
0
1
0
0
1
150
(All Categories)
Percent By
Number
0
0
41.3
5.3
0.7
47.3
0
0
2.7
0
0
2.7
0
0
0.7
0
0
0.7
100
Percent By Mass
All
Categories
0
0
34.5
22.3
7.5
64.3
0
0
0.9
0
0
0.9
0
0
0.6
0
0
0.6
100
Within
Category
0
0
53.7
34.6
11.7
100
0
0
100
0
0
100
0
0
100
0
0
100
-------
TABLE IT-85
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093292 & 1093293
(combined cover & primary filters)
Monitor Location: Midland
Date of Sample: 9/9/76
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
0
0
98
6
5
109
0
0
10
3
0
13
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors: 667 Agency: 688
Calculated Mass (mg): 801
3
Air Concentration (ug/m ):
Coors: 404 Agency: 341
Percent By
Number
0
0
58.0
3.6
3.0
64.5
0
0
5.9
1.8
0
7.7
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
21.3
6.5
14.6
42.5
0
0
7.1
10.7
0
17.8
0
0
0
0
0
0
Within
Category
0
0
50.2
15.4
34.5
100
0
0
40.0
60.0
0
100
0
0
0
0
0
0
-------
TABLE D-85
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: 1093292 & (Continued)
1 nQ-39Q1
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75)j
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categor]
Particle
Count
0
0
22
1
1
24
0
0
11
0
12
23
0
0
0
0
0
0
169
^es)
1
Percent By
Number
0
0
13.0
0.6
0.6
14.2
0
0
6.5
0
7.1
13.6
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
8.0
1.8
4.9
14.7
0
0
1.6
0
23.4
25.0
0
0
0
0
0
0
100
Within
Category
0
0
54.4
12.4
33.3
100
0
0
6.4
0
93.6
100
0
0
0
0
0
0
-------
TABLE D-86
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1105327 & 1106328 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 429 Agency: 428
Monitor Location: Central Lab Calculated Mass (mg): 560
o
Date of Sample: 9/9/76 Air Concentration (ug/m ):
Coors: 219 Agency: 235
Category
Flyash
5-lOu
10-20u
20-50u
50— 75u
>75p
Totals
Iron Oxide
5-lOu
10-20u
20-50[j
50-75u
>75u
Totals
Magnetic
Iron
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
590
183
46
10
10
839
35
22
0
0
0
57
0
0
0
0
0
0
Percent By
Number
57.4
17.8
4.5
1.0
1.0
81.6
3.4
2.1
0
0
0
5.5
0
0
0
0
0
0
Percent By Mass
All
Categories
1.7
4.2
14.3
15.6
41.9
77.7
0.3
1.6
0
0
0
2.0
0
0
0
0
0
0
Within
Category
2.2
5.4
18.4
20.0
53.9
100
16.6
83.4
0
0
0
100
0
0
0
0
. 0
0
-------
TABLE D-86
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: -t-ingooo (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC03
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorj
Particle
Count
34
18
13
0
1
66
1
20
10
3
0
34
30
2
0
0
0
32
1028
-es)
Percent By
Number
3.3
1.8
1.3
0
0.1
6.4
0.1
1.9
1.0
0.3
0
3.3
2.9
0.2
0
0
0
3.1
100
Percent By Mass
All
Categories
0.2
0.7
6.7
0
7.0
14.6
0.002
0.3
2.1
3,1
0
5.5
0.2
0.08
0
0
0
0.2
100
Within
Category
1.1
4.7
46.2
0
47.9
100
0.03
5.6
37.7
56.6
0
100
65.2
34.8 '
0
0
0
100
-------
TABLE D-87
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6388 & 1106387 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 470 Agency: 582
Monitor Location: Liberty Boro Calculated Mass (mg): 853
o
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 289 Agency: 315
Category
Flyash
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20u
20-50y
50-75y •
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
239
78
100
18
17
452
53
10
7
0
0
70
14
7
0
0
0
21
Percent By
Number
37.4
12.2
15.6
2.8
2.7
70.7
8.3
1.6
1.1
0
0
11.0
2.2
1.1
0
0
0
3.2
Percent By Mass
All
Categories
0.4
1.2
20.4
18.4
46.8
87.2
0.3
0.5
4.7
0
0
5.5
0.09
0.3
0
0
0
0.4
Within
Category
0.5
1.4
23.4
21.1
53.6
100
6.0
9.0
85.1
0
0
100
20.0
80.0
0
0
0
100
-------
TABLE D-87
RESULTS OF OPTICAL PARTICLE COUNTS
(Continued)
Filter Number: -1-1^/2007 (Continued)
Category
Quartz
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10p
10-20y
20-50y
50-75y
>75M
Totals
CaOO,
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
20
6
7
0
0
33
3
4
2
0
2
11
47
5
0
0
0
52
639
(All Categories)
i
Percent By
Number
3.1
0.9
1.1
0
0
5.2
0.5
0.6
0.3
0
0.3
1.7
7.4
0.8
0
0
0
1.7
100
Percent By Mass
AH
Categories
0.06
0.2
2.4
0
0
2.6
0.004
0.04
0.3
0
3.7
4.0
0.2
0.1
0
0
0
0.3
100
Within
Category
2.4
5.8
91.8
0
0
100
0.09
1.0
6.8
0
92.1
100
54.0
46.0
0
0
0
100
-------
TABLE D-88
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106381 & 1106382
(combined cover & primary filters)
Monitor Location: Clairton
Date of Sample: 9/9/76
Category
Flyash
5-lOu
10-20y
20-50|j
50-75y
>75y
Totals
Iron Oxide
5-10n
10-20y
20-50y
50-75p
>75M
Totals
Magnetic
Iron
5-10u
10-20y
20-50jj
50-75y
>75y
Totals
Particle
Count
0
0
85
8
4
97
0
0
5
0
0
5
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors: 293 Agency: 330
Calculated Mass (mg): 470
3
Air Concentration (yg/m ):
Coors : 127 Agency : 178
Percent By
Number
65
6
3
74
0
0
.4
.2
.1
.6
0
0
3.8
0
0
3.8
0
0
0
0
0
0
Percent By Mass
All
Categories
0
0
31.5
14.8
20.0
66.3'
0
0
6.0
0
0
6.0
0 ,
0
0
0
0
0
Within
Category
0
0
47.5
22.4
30.1
100
0
0
100
0
0
100
0
0
0
0
0
0
-------
TABLE D-
KESULTS OF OPTICAL PARTICUE COUNTS
(Continued)
Quartz
5-10y
10-20y
20-50y
50-75p
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75u
>75p
Totals
CaC00
5-lOp
10-20y
20-50y
50-75y
>75y'
Totals
TOTALS
(All Category
Filter Number
Particle
Count
0
0
14
3
0
17
0
0
6
4
1
11
0
0
0
0
0
0
130
.es)
1
,. 1106381 &
1106382
Percent By
Nmnber
0
0
10.8
2.3
0
13.1
0
0
4.6
3.1
0.8
8.5
0
0
0
0
0
0
100
(Continued)
Percent
All
Categories
0
0
8.6
9.3
0
17.9
0
0
1.5
4.9
3.3
9.8
0
0
0
0
0
0
100
By Mass
Within
Category
0
0
48.2
51.7
0
100
0
0
15.2
50.7
34.1
100
0
0
0
0
0
0
-------
TABLE D-89 THROUGH D-167 - RESULTS OF SEM PARTICLE COUNTS
-------
TABLE D-89
RESULTS OF SEM PARTICLE COOTS
Filter Number: 1093219 Total Mass of Particulates (mg) :
Coors: 164 Agency: 139
Monitor Location: Baden Calculated Mass (mg) : 193
3
Date of Sample: 8/16/76 ^r conccnt.ration (Mg/ni ):
Coors : 86 Agency : 67
Category
Sphere
5-10^
10-20y
20-50(j
50-75 p
>75y
Totals
Irregular
5-lOy
10-20y
20-50p
50-75y
>75y
Totals
Aggl omer ate
5-lOy
10-20y
20-50p
50-75y
>75p
Totals
TOTAI^
Particle
Count
225
75
0
0
0
300
1075
300
60
0
0
1435
825
275
24
10
0
1125
2860
(All Categories)
Percent By
Number
7.9
2.6
0
0
0
10.5
37.6
10.5
2.1
0
0
50.2
28.8
9.6
0.8
0.03
0
39.3
100
Percent By Mass
All
Categories
1.4
3.8
0
0
0
5.2
7.6
17.0
46.0
0
0
70.6
3.2
8.6
10.2
2.1
0
24.2
100
Within
Category
27.3
72.7
0
0
0
100
10.8
24.1
65.1
0
0
100
13.4
35.7
42.1
8.8
0
100
-------
TABLE D-90
RESULTS OF SEM PARTICLE COUNTS
Filter Number: inci^99i
Monitor Location: Beaver Falls
Date of Sample: 8/16/76
Category
Sphere
5-10|j
10-20y
20-50y
50-75ja
>75y
Totals
Irregular
5-10n
10-20y
20-50y
50-75M
>75U
Totals
Agglomerate
5-lOp
10-20u
20-SOia
50-7 5y
>75y
Totals
TOTALS
Particle
Count
50
25
0
0
0
75
275
150
24
0
0
449
425
125
24
3
2
579
1103
(All Categories)
Total Miss of Particulates (mg) :
Coors: 152 Agency: 127
Calculated Mass (mg) : 124
3
Air concentration (ug/m ):
Coors: 86 Agency: 61
Percent By
Number
4.5
2.3
0
0
0
6.8
24.9
13.6
2.2
0
0
40.
38.
11.
2.
0.
0.
52.
7
5
3
2
3
2
5
100
Percent By Mass
All
Categories
0.5
2.0
0
0
0
2.4
3.0
13.3
28.7
0
0
45.0
2.6
6.1
15.9
10.0
17.9
52.6
100
Within
Category
20
80
0
0
0
100
6.8
29.5
63.8
0
0
100
5.0
11.7
30.3
19.0
34.0
100
-------
TABLE D-91
RESULTS OF SEM PARTICLE COUNTS
Filter Number: inq-^9?^ Total Mass of Particulates (mg) :
Coors: 189 Agency: 161
Monitor Location: Koppel Calculated Mass (mg) : 86
Date of Sample: 8/16/76 Air concentration (yg/m ):
Coors: 90 Agency: 86
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
50
0
0
0
0
50
325
175
8
0
0
508
600
200
40
0
0
840
1398
(All Categories)
Percent By
Number
3.6
0
0
0
0
3.6
23.2
12.5
0.6
0
0
36.3
42.9
14.3
2.9
0
0
60.1
100
Percent By Mass
All
Categories
0.7
0
0
0
0
0.7
5.2
22.4
13.8
0
0
41.4
5.3
14.2
38.4
0
0
57.9
100
Within
Category
100
0
0
0
0
100
12.5
54.0
33.4
0
0
100
9.2
24.5
66.3
0
0
100
-------
TABLE D-92
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093225
Monitor Location: Brighton
Township
Date of Sample: 8/16/76
Cat ego ly
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-7 5y
>75M
Totals
TOTALS
(All Categoric
Particle
Count
125
25
0
0
0
150
575
50
24
0
0
649
400
125
4
0
0
529
1328
s)
Total Mass of Particulates (ing) :
Coors: 119 Agency: 162
Calculated Mass (mg) : 67
3
Air concentration (yg/m ):
Coors: 65 Agency: 87
Percent By
Number
9.4
1.9
0
0
0
11.3
43.3
3.
3
1.8
0
0
48.9
30.0
9.4
0.
0
0
39.
3
8
100
Percent By Mass
All
Categories
2.3
3.6
0
0
0
5.9
11.8
8.2
53.2
0
0
73.2
4,6
11.4
4.9
0
0
20.9
100
Within
Category
38.5
61.5
0
0
0
100
16.1
11.2
72.7
0
0
100
21.8
54.6
23.6
0
0
100
-------
TABLE D-93
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093227
Monitor Location: Midland
Date of Sample: 8/16/76
Categoiy
Sphere
5-10y
10-20(j
20-50u
50-75^
>75\i
Totals
Irregular
5-10u
10-20y
20-50p
50-75u
>75y
Totals
Agglomerate
5-10y
10-2 On
20-50y
50-75y
>75)j
Totals
TOTALS
Particle
Count
225
75
4
0
0
304
1300
225
28
1
0
1554
1250
100
24
2
0
1376
3234
(All Categories)
Total Mass of Particulates (mg) :
Coors : 149 Agency : 166
Calculated Mass (mg) : 150
3
Air concentration (yg/nf):
Coors: 83 Agency: 80
Percent By
Number
7.0
2.3
0.1
0
0
9.4
40.2
7.0
0.
0.
0
48.
38.
3.
0.
0.
9
03
0
6
1
7
06
0
42.
5
100
Percent By Mass
All
Categories
1.8
4.9
3.5
0
0
10.2
11.8
16.4
27.6
4.9
0
60.8
6.3
4.0
13.1
5.5
0
29.0
100
Within
Category
17.9
47.7
34.4
0
0
100
19.5
27.0
45.4
8.1
0
100
21.8
14.0
45.3
18.9
0
100
-------
TABLE D-94
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter)
1093228
Monitor Location: Midland
Date of Sample: 8/16/76
(Cover Filter for 1093227)
Category
Sphere
5-lOy
10-20^
20-50u
50-75jj
>75M
Totals
Irregular
5-10u
10-20u
20-50y
50-75p
>75u
Totals
Agglomerate
5-10y
10-2Qu
20-50y
50-75u
>75p
Totals
TOTALS
Particle
Count
275
25
4
0
0
304
875
125
16
2
0
1018
600
75
4
1
0
680
2002
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency :
Calculated Mass (mg) : 91-6
3
Air concent ration ( pg/m ) :
Coors : — Agency : —
Percent By
Number
13
1
0
15
.7
.2
.2
0
0
.2
43.7
6.2
0.8
0.1
0
50.8
30.0
3.7
0.2
0.05
0
34.0
100
Percent By Mass
All
Categories
3.6
2.6
5.7
0
0
12.0
13.0
14.9
25.8
16.1
0
69.9
5.0
5.0
3.6
4.5
0
18.0
100
Within
Category
30.3
22.0
47.7
0
0
100
18.7
21.3
36.9
23.1
0
100
27.6
27.6
19.9
24.9
0
100
-------
-------
-------
TABLE D-95
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093213 Total Mass of Particulates (mg) :
Coors : 147 Agency : 100
Monitor Location: Elco Calculated Mass (mg) : 126
Date of Sample: 8/16/76 Air concentration (ug/m ):
Coors : 66 Agency : 46
Category
Sphere
5-10u
10-20y
20-50y
50-75M
>75M
Totals
Irregular
5-10y
10-20p
20-50y
50-75jj
>75y
Totals
Agglomerate
5-lOp
10-20p
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count
100
50
0
0
0
150
675
200
12
0
0
887
450
100
56
1
1
608
1645
(All Categories)
Percent By
Number
6.1
3.0
0
0
0
9.1
41.0
12.2
0.7
0
0
53.9
27.4
6.1
3.4
0.06
0.06
37.0
100
Percent By Mass
Al 1
Categories
1.0
3.9
0
0
0
4.8
7.3
17.4
14.1
0
0
38.9
2.7
4.8
36.6
3.3
8.8
56.3
100
Within
Category
20
80
0
0
0
100
18.9
44.8
36.3
0
0
100
4.8
8.6
65.1
5.8
15.7
100
-------
TABLE D-96
RESULTS OF SEM PARTICLE COUNTS
Filter Number: Total Mass of Particulates (mg) :
Coors: 284 Agency: 241
Monitor Location: Downtown Calculated Mass (mg) : 139
3
Date of Sample: o/-,-./^ Air concentration (pg/m ):
o/lb/ /b
Coors: 139 Agency: I10
Category
Sphere
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
75
25
0
0
0
100
525
125
28
0
0
678
1675
300
52
0
0
2027
2805
3S)
Percent By
Number
2.7
0.9
0
0
0
3.6
18.7
4.4
1.0
0
0
24.2
59.7
10.7
1.8
0
0
72.3
100
Percent By Mass
All
Categories
0.6
1.7
0
0
0
2.4
5.2
9.8
29.7
0
0
44.7
9.1
13.1
30.7
0
0
52.9
100
Within
Category
27.3
72.7
0
0
0
100
11.5
22.0
66.5
0
0
100
17.3
24.7
58.0
0
0
100
-------
TABLE D-97
RESULTS OF SEM PARTICLE COUNTS
Filter Number:
1093241
Afonitor Location: Central Lab
Date of Sample: 8/16/76
Category
Sphere
5-lOp
10-20y
20-50y
50-7 5y
>75M
Totals
Irregular
5-10vi
10-20U
20-50y
50-75u
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categorie
Particle -
Count
50
0
0
0
0
50
700
150
16
0
0
866
500
25
16
1
0
542
1458
>s)
Total Mass of Particulates (ing) :
Coors: 224 Agency: 202
Calculated Miss (mg) : 73
3
Air concentration (ug/m ):
Coors: 110 Agency: 97
Percent By
Number
3.4
0
0
0
0
3.4
48.0
10.3
I.
0
0
1
59.4
34.
1.
1.
0.
0
37.
3
7
1
07
2
100
Percent By Mass
All
Categories
0.8
0
0
0
0
0.8
13.1
22.5
32.5
0
0
68.2
5.2
2.1
18.0
5.6
0 '
31.0
100
Within
Category
100
0
0
0
0
100
19.3
33.0
47.7
0
0
100
16.8
6.7
58.2
18.2
0
100
-------
TABLE D-98
RESULTS OF SEM PARTICLE GODOT'S
filter Number: 1093201 Total Mass of Participates (mg) :
Coors : 180 Agency :
Monitor Location: Hazelwood Calculated Mass (mg) : 307
'3
Date of Sample: 8/16/76 Air concentration (ijg/nf):
Coors: 131 Agency: !05
Category
Sphere
5-10|j
10-20y
20-50u
50-7 5y
>75M
Totals
Irregular
5-10y
10-20u
20-50p
50-75y
>75p
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count
75
25
4
0
0
104
1975
350
44
0
1
2370
3600
700
96
0
0
4396
6870
(All Categories)
Percent By
Number
1.1
0.4
0.06
0
0
1.5
28.7
5.1
0.6
0
0.01
34.5
52.4
10.2
1.4
0
0
64.0
100
Percent By Mass
All
Categories
0.3
0.8
1.7
0
0
2.8
8.8
12.4
21.2
0
6.5
48.8
8.9
13.8
25.6
0
0
48.4
100
Within
Category
10.6
28.3
61.1
0
0
100
18.0
25.5
43.3
0
13.2
100
18.4
28.6
53.0
0
0
100
-------
TABLE D-99
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093203 Total Mass of Particulates (mg) :
Coors: 155 Agency: 126
Monitor Location: North Braddock Calculated Mass (mg): 157
2
Date of Sample: 8/16/76 Air concentration (pg/m ):
Coors : 79 Agency : 63
Category
Sphere
5-10n
10-20U
20-50u
50-75y
>75y
Totals
Irregular
5-10p
10-20u
20-50p
50-75p
>75p
Totals
Agglomerate
5-10p
10-20y
20-50y
50-7 5p
>75p
Totals
TOTALS
Particle
Count
200
0
4
0
0
204
750
225
48
1
0
1024
1025
75
24
1
0
1125
2353
(All Categories)
Percent By
Number
8.5
0
0.2
0
0
8.7
31.9
9.6
2.0
0.04
0
43.5
43.6
3.2
1.0
0.04
0
47.8
100
Percent By Mass
All
Categories
1.5
0
3.3
0
0
4. .9
6.5
15.7
45.2
4.7
0
72.1
5.0
2.9
12.6
2.6
0
23.0
100
Within
Category
31.6
0
68.4
0
0
100
9.0
21.7
62.7
6.5
0
100
21.5
12.6
54.5
11.4
0
100
-------
TABLE D-100
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093205 Total Mass of Particulates (nag):
Coors: 231 Agency: 211
Monitor Location: Duquesne II Calculated Mass (mg) : 270
3
Date of Sample: 8/16/76 Air concentration (pg/m ):
Coors: 145 Agency: 107
Category
Sphere
5-lOy
10-20u
20-50u
50-75p
>75p
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Agglomerate
5-10u
10-2 Op
20-50y
50-75)j
>75y
Totals
TOTALS
Particle
Count
175
25
0
0
0
200
1825
500
40
1
0
2366
2050
300
84
4
0
2438
5004
(All Categories)
Percent By
Number
3.5
0.5
0
0
0
4.0
36.5
10.0
0.8
0.02
0
47.3
41.0
6.0
1.7
0.08
0
48.7
100
Percent By Mass
All
Categories
0.8
0.9
0
0
0
1.7
9.2
20.2
21.9
2.7
0
54.1
5.8
6.8
25.6
6.1
0
. 44.2
100
Within
Category
46.7
53.3
0
0
0
100
17.1
37.4
40.5
5.1
0
100
13.0
15.3
57.9
13.8
0
100
-------
TABLE D-101
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093209 Total Mass of Particulates (mg) :
Coors : 181 Agency :
Monitor Location: Liberty Boro Calculated Mass (mg) : 150
Date of Sample: 8/16/76 Air concentration (ug/m ):
Coors : 114 Agency :
Category
Sphere
5-10y
10-20U
20-50u
50-75U
>75U
Totals
Irregular
5-10y
10-20p
20-50p
50-75y
>75y
Totals
Agglaiierato
5-lOp
10-20y
20-50y
50-75p
>75M
Totals
TOTALS
(All Categoric
Particle
Count
75
0
4
0
0
79
650
150
12
1
1
814
1725
325
44
1
0
2095
2988
3S)
Percent By
Number .
2.5
0
0.1
0
0
2.6
21.8
5.0
0.4
0.03
0.03
27.2
57.7
10.9
1.5
0.03
0
70.1
100
Percent By Mass
• All
Categories
0.6
0
3.5
0
0
4.1
5.9
11.0
11.8
4.9
13.3
47.0
8.8
13.2
24.2
2.7
0
48.8
100
Within
Category
14.8
0
85.2
0
0
100
12.6
23.3
25.2
10.5
28.3
100
17.9
27.0
49.4
5.6
0
100
-------
TABLE D-102
RESULTS OF Sill PARTI CLE COUNTS
Filter Number: 1093211 Total Mass of Participates (mg) :
Coors: 125 Agency: 150
Monitor Location: Clairton Calculated Mass (mg) : 106
3
Date of Sample: 8/16/76 Air concentration (yg/m ):
Coors : 52 Agency : 76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
AggLaiierate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
50
25
0
0
0
75
550
75
28
0
1
654
300
75
24
0
0
399
1128
(All Categories)
Percent By
Number
4.4
2.2
0
0
0
6.6
48.8
6.6
2.5
0
0.09
58.0
26.6
6.6
2.1
0
0
35.4
100
Percent By Mass
All
Categories
0.6
2.3
0
0
0
2.8
7.0
7.7
38.8
0
18.7
72.2
2.1
4.3
18.5
0
0
24.9
100
Within
Category
20
80
0
0
0
100
9.8
10.6
53.7
0
25.8
100
8.6
17.2
74.2
0
0
100
-------
TABLE D-103
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093229 Total Mass of Particulates (mg) :
Coors : 149 Agency : 151
Monitor Location: Airport Calculated Mass (mg): 97
Date of Sample: 8/16/76 Air concentration ( ug/rn" ) :
Coors: 76 Agency: 72
Category
Sphere
5-lOu
10-20y
20-50M
50-75M
>75M
Totals
Irregular
5-10y
10-20u
20-50y
50-75y
>75p
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75y
>75p
Totals
TOT/\LS
Particle
Count
50
0
0
0
1
51
750
200
8
1
0
959
1375
275
0
0
0
1650
2660
(All Categories)
Percent By
Number
1.9
0
0
0
0.04
1.9
28.2
7.5
0.3
0.04
0
36.0 '
51.7
10.3
0
0
0
62.0
100
Percent By Mass
All
Categories
0.6
0
0
0
18.3
18.9
10.6
22.6
12.2
7.6
0
53.0 1
10.8
17.2
0
0
0
28.0
100
Within
Category
3.3
0
0
0
96.7
100
20.0
42.6
23.0
14.4
0
100
38.5
61.5
0
0
0
100
-------
TABLE D-104
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (nig):
1093230 Coors: — Agency:
Monitor Location: Airport Calculated Mass (ing): 140
Date of Sample: 8/16/76 Air concentration (yg/m ):
(Cover Filter for 1093229) ^ .
v Coors: — Agency:
Category
Sphere
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
TOTALS
Particle
Count
100
0
4
0
0
104
975
150
24
2
0
1151
750
175
36
2
0
963
2218
(All Categories)
Percent By
Number
4.5
0
0.2
0
0
4.7
44.0
6.8
1.1
0.09
0
51.9
33.8
7.9
1.6
0.09
0
43.4
100
Percent By Mass
All
Categories
0.8
0
3.7
0
0
4.6
9.5
11.7
25.2
10.5
0
56.9
4.0
7.6
21.0
5.8
0
38.5
100
Within
Category
18.8
0
81.2
0
0
100
16.6
20.5
44.3
18.5
0
100
10.5
19.6
54.6
15.2
0
100
-------
TABLE D-105
RESULTS OF SEM PARTICLE COUNTS
Filter Number: incnoqa Total Mass of Particulates (nig):
Coors: 140 Agency: 90
Monitor Location: South Fayette Calculated Mass (mg) : 49
Date of Sample: 8/16/76 Air concentration (pg/m ):
Coors: 69 Agency: 41
Category
Sphere
5-lOp
10-20p
20-50p
50-75p
>75p
Totals
Irregular
5-10p
10-20p
20-50p
50-75p
>75p
Totals
Agglomerate
5-10y
10-2 Op
20-5 Op
50-7 5p
>75p
Totals
TOTALS
(All Categoric
Particle
Count
125
25
0
0
0
150
775
125
4
0
0
904
575
125
4
0
0
704
1758
iS)
Percent By
Number
7.1
1.4
0
0
0
8.5
44.1
7.1
0.2
0
0
51.4
32.7
7.1
0.2
0
0
40.0
100
Percent By Mass
All
Categories
3.1
4.9
0
0
0
8.0
21.4
27.7
12.0
0
0
61.1
8.8
15.4
6.6
0
0
30.9
100
Within
Category
38.5
61.5
0
0
0
100
35.1
45.3
19.6
0
0
100
28.6
49.8
21.5
0
0
100
-------
TABLE D-106
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093247
Monitor Location: Liberty Boro
Date of Sample: 8/22/76
Category
Sphere
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
250
0
0
0
0
250
2200
725
148
7
0
3080
2650
1050
324
38
3
4065
7395
(All Categories)
Total Mass of Particulates (nig) :
Coors: 433 Agency:
Calculated Mass (mg) : 922
Air concentration (yg/m ):
Coors: 272 Agency:
Percent By
Number
3.4
0
0
0
0
3.4
29.7
9.8
2.
0
0.09
0
41.6 n
35.
14.
8
2
4.4
0.
0.
55.
5
04
0
100
Percent By Mass
All
Categories
0.3
0
0
0
0
0.3
3.3
8.6
23.7
5.6
0
41.2
2.2
6.9
28.8
16.9
3.6
58.5
100
Within
Category
100
0
0
0
0
100
7.9
20.9
57.6
13.6
0
100
3.7
11.8
49.3
29.0
6.2
100
-------
TABLE D-107
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1093248 Coors: __ Agency; __
Monitor Location: Liberty Boro Calculated Mass (ing): 104
3
Date of Sample: 8/22/76 Air concentration (yg/rn ):
(Cover Filter for 1093247) Coors: — Agency:
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20(j
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-5 Oy
50-7 5y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
25
0
0
0
0
25
350
150
20
1
0
521
550
175
32
1
0
758
1304
;s)
Percent By
Number
1.9
0
0
0
0
1.9
26.8
11.5
1.5
0.08
0
40.0
42.2
13.4
2.4
0.08
0
58.1
100
Percent By Mass
All
Categories
0.3
0
0
0
0
0.3
4.6
15.8
28.5
7.1
0
56.1
4.0
10.2
25.4
4.0
0
43.6
100
Within
Category
100
0
0
0
0
100
8.2
28.2
50.8
12.7
0
100
9.2
23.5
58.1
9.1
0
100
-------
TABLE D-108
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093290
Monitor Location: Baden
Date of Sample: 8/28/76
Category
Sphere
5-10n
10-20y '
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75p
>75u
Totals
TOTALS
(All Categoric
Particle
Count
275
100
0
0
0
375
1275
450
40
5
1
1771
1050
650
60
40
3
1803
3949
yl
Perce
Total Muss of Particulates (mg) :
Coors: 374 Agency: 351
Calculated Mass (mg): 490
3
Air concentration (yg/irf):
Coors: 203 Agency: 183
nt By
Number
7.
2.
0
5
0
0
0
9.
32.
11.
1.
0.
0.
44.
26.
16.
1.
1.
0.
45.
5
3
4
0
1
02
8
6
4
5
0
08
6
100
Percent By Mass
All
Categories
0.7
2.0
0
0
0
2.7
3.6
10.0
12.1
7.5
4.1
37.3
1.6
8.0
10.0
33.5
6.8
60.0
100
Within
Category
25.6
74.4
0
0
0
100
9.5
26.9
32.4
20.2
10.9
100
2.7
13.4
16.7
55.8
11.3
100
-------
TABLE D-109
RESULTS OF SKM PARTICLE COUNTS
Filter Number: (Cover Filter)
1093291
Monitor Location: Baden
Date of Sample: 8/28/76
(Cover Filter For 1093290)
Category
Sphere
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Irregular
5-10y
10-20M
20-50M
50-75y
>75M
Totals
Agglomerate
5-10M
10-2 Oy
20-50M
50-75p
>75}j
Totals
'TOTALS
Particle
Count
275
125
20
0
0
420
1000
350
112
0
0
1462
1200
550
188
25
2
1965
3847
(All Categories)
Perec.
Total Mass of Particulates (mg) :
Coors : — Agency : —
Calculated Mass (mg) : 581
3
Air concentration (ug/m ):
Coors : — Agency :
nt By
Number
7.
3.
0.
1
2
5
0
0
10.
26.
9.
2.
9
0
1
9
0
0
38.
31.
14.
4.
0.
0.
51.
0
2
3
9
6
05
1
100
Percent By Mass
Al]
Categories
0.6
2.1
4.5
0
0
7.2
2.4
6.6
28.5
0
0
37.4
1.6
5.7
26.6
17.7
3.8
55.4
100
Within
Category
8.0
29.1
62.9
0
0
100
6.3
17.6
76.1
0
0
100
2.8
10.4
48.0
31.9
6.9
100
-------
TABLE D-110
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093288
Monitor Location: Beaver Falls
Date of Sample: 8/28/76
Category
Sphere
5-lOp
10-20jj
20-50p
50-75y
>75M
Totals
Irregular
5-lOu
10-20y
20-50y
50-75p
>75y
Totals
Agglomerate
5-10y
10-20jj
20-50y
50-75p
>75n
Totals
TOTALS
(All Categoric
Particle
Count
750
100
4
0
0
854
1750
325
32
4
0
2111
2150
375
116
1
2
2644
5609
s)
Total Mass of Particulates (mg) :
Coors: 277 Agency: 266
Gilculated Mass (mg) : 321
3
Air concentration (ug/rrf):
Coors: 164 Agency: 137
Percent By
Number
13.
1.
0.
4
8
07
0
0
15.
31.
5.
0.
0.
2
2
8
6
07
0
37.
38.
6.
2.
0.
0.
47.
6
3
7
1
02
04
1
100
Percent By Mass
A1J
Categories
2.8
3.0
1.6
0
0
7.5
7.4
11.1
14.7
9.2
0
42.5
5.1
7.1
29.7
1.3
6.9
50.0
100
Within
Category
37.8
40.4
21.8
0
0
100
17.5
26.1
34.7
21.7
0
100
10.2
14.2
59.3
2.6
13.8
100
-------
TABLE D-lll
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093286 Total Mass of Particulates (nig):
Coors : 256 Agency : —
Monitor Location: Koppel Calculated Mass (mg) : -^6
3
Date of Sample: 8/28/76 Air concentration (ug/iri~):
Coors : 133 Agency :
Category
Sphere
5-10u
10-20y
20-50p
50-75p
>75U
Totals
Irregular
5-lOn
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOu
10-20ij
20-50y
50-75y
>75(j
Totals
TOTALS
Particle
Count
100
0
0
0
0
100
800
175
36
3
1
1015
850
75
24
2
0
951
2066
(All Categories)
Percent By
Number
4.8
0
0
0
0
4.8
38.7
8.5
1.7
0.1
0.05
49.1
41.1
3.6
1.2
0.1
0
46.0
100
Percent By Mass
All
Categories
0.7
0
0
0
0
0.7
6.6
11.6
32.1
13.4
12.0
75.7
3.9
2.8
11.9
5.0
0
23.5
100
Within
Category
100
0
0
0
0
100
8.7
15.2
42.4
17.7
15.9
100
16.6
11.7
50.6
21.1
0
100
-------
TABLE D-112
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93284
.. . , T , . Brighton
Monitor Location: Township
Date of Sample: 8/28/76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
150
50
8
0
0
208
900
225
12
3
0
1140
475
225
0
4
2
706
2054
(All Categories)
Total Mass of Particulates (rug) :
COOTS: 258 Agency: 274
Calculated Mass (mg) : 15°
3
Air concentration ( ug/m ) :
Coors : 149 Agency : 151
Percent By
Number
7
2
0
.3
.4
.4
0
0
10
43
11
.1
.8
.0
0.6
0.1
0
55.5
23.1
11.0
0
0.2
0.1
34.4
100
Percent By Mass
All
Categories
1.2
3.2
7.0
0
0
11.5
8.2
16.4
11.8
14.8
0
51.3
2.4
9.1
0
11.0
14.8
37.3
100
Within
Category
10.6
28.3
61.1
0
0
100
16.0
32.0
23.1
28.9
0
100
6.4
24.5
0
29.4
39.6
100
-------
TABLE D-113
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093282 Total Mass of Particulates (mg) :
Coors: 479 Agency: 501
Monitor Location: Midland Calculated Mass (mg) : 238
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors: 268 Agency: 248
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Irregular
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
400
125
0
0
0
525
475
175
4
0
0
654
1600
625
64
13
3
2305
N 3484
3S)
Percent By
Number
11.5
3.6
0
0
0
15.1
13.6
5.0
0.1
0
0
18.8
45.9
17.9
1.8
0.4
0.09
66.2
100
Percent By Mass
All
Categories
2.0
5.1
0
0
0
7.2
2.7
8.0
2.5
0
0
13.3
5.1
16.0
22.1
22.5
14.0
79.6
100
Within
Category
28.6
71.4
0
0
0
100
20.6
60.7
18.7
0
0
100
6.4
20.0
27.8
28.2
17.5
100
-------
TABLE D-114
RESULTS OF SKM PARTICLE COUNTS
Filter Number: HQ6306
Monitor Location: Elco
Date of Sample: 8/28/76
Category
Sphere
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
225
100
0
0
0
325
250
125
28
4
1
408
350
275
36
1
0
662
1395
«)
Total Mass of Particulates (mg) :
Coors: 91 Agency: 98
Calculated Mass (mg) : 173 .
3
Air concentration ( yg/m ) :
Coors : 43 Agency : 40
Percent By
Number
16
7
.1
.2
0
0
0
23
17
9
2
0
0
29
25
19
2
0
.3
.9
.0
.0
.3
.07
.2
.1
.7
.6
.07
0
47
.4
100
Percent By Mass
All
Categories
1.6
5.6
0
0
0
7.2
2.0
7.9
23.9
17.0
11.4
62.2
1.5
9.6
17.0
2.4
0
30.6
100
Within
Category
22.0
78.0
0
0
0
100
3.2
12.6
38.3
27.4
18.4
100
5.0
31.5
55.7
7.7
0
100
-------
TABLE D-115
RESULTS OF SEM PARTICLE CDUNTS
Filter Number: 1093296 Total Mass of Particulates (mg) :
Coors: 193 Agency: 149
Monitor Location: Downtown Calculated Mass (rug): 92
3
Date of Sample: 8/28/77 Air Concentration (ug/m ):
Coors : 101 Agency : 70
Category
Sphere
5-lOy
10-2Qy
20-50y
50-75 u
>75y
Totals
Irregular
5-lOu
10-20M
20-50y
50-75M
>75y
Totals
Agglomerate
5-10y
10-20M
20-50y
50-75 y
>75y
Totals
TOTALS
(All Categories
Particle
Count
450
0
4
0
0
454
675
175
4
1
0
855
450
175
8
2
1
636
1945
3)
Percent By
Number
23.1
0
0.2
0
0
23.3
34.7
9.0
0.2
0.05
0
44.0
23.1
9.0
0.4
0.1
0.05
32.7
100
Percent By Mass
All
Categories
5.9
0
5.7
0
0
11.6
10.0
20.7
6.4
8.0
0
45.1
3.7
11.5
7.1
8.9
12.0
43.2
100
Within
Category
51.0
0
49.0
0
0
100
22.1
45.9
14.2
17.8
0
100
8.6
26.6
16.5
20.6
27.7
100
-------
TABLE D-116
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093253
Monitor Location: Central Lab
Date of Sample: s 7 28 7 76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20M
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categories
Particle
Count
325
25
0
0
0
350
975
200
4
2
0
1181
375
250
24
0
1
650
2181
s)
Total Mass of Particulates (mg) :
Coors: 233 Agency: —
Calculated Mass (mg): 111
3
Air Concentration ( yg/m ) :
Coors: 119 Agency: —
Percent By
Number
14.
1.
0
0
0
16.
44.
9.
0.
0.
0
54.
9
1
0
7
2
2
1
1
17.2
11.
1.
0
5
1
0.04
29.8
100
Percent By Mass
All
Categories
3.6
2.2
0
0
0
5.7
12.0
19.7
5.3
13.3
0
50.3
2.6
13.7
17.7
0
10.0
43.9
100
Within
Category
61.9
38.1
0
0
0
100
23.8
39.1
10.6
26.5
0
100
5.8
31.1
40.4
0
22.7
100
-------
TABLE D-117
RESULTS OF SEM PARTICLE OOUMS
Filter Number:
1106308
Monitor Location: Hazelwood
Date of Sample: 8/28/76
Category
Sphere
5-10y
10-20M
20-50y
50-75y
>75y
Totals
Irregular
5-10u
10-20y
20-50y
50-75u
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
(All Categoric
Particle
Count
150
0
4
0
0
154
550
125
12
0
0
687
425
25
0
0
0
450
1291
s)
Total Mass of Particulates (mg) :
Coors : 151 Agency : 143
Calculated Mass (mg): 50-7
3
Air concentration (pg/m ):
Coors : 71 Agency : 76
Percent By
Number
11
.6
0
0
.3
0
11
42
9
0
.9
.6
.7
0.9
0
0
53.2
32.9
1.9
0
0
0
34.8
100
Percent By Mass
All
Categories
3.6
0
10.4
0
0
13.9
14.8
26.9
35.0
0
0
76.7
6.4
3.0
0
0
0
9.4
100
Within
Category
25.7
0
74.2
0
0
100
19.3
35.1
45.6
0
0
100
68.0
32.0
0
0
0
100
-------
TABLE D-118
RESULTS OF SEM PARTICLE COLMS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106309 Coors: __ Agency:
Monitor Location: Hazelwood Calculated Mass (mg) : 30.2
•^
Date of Sample: 8/28/76 Air concentration (yg/nf):
(Cover Filter For 1106308) Coors: ~ Agency: —
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorif
Particle
Count
75
0
0
0
0
75
250
150
4
0
0
404
275
25
0
0
0
300
779
•s)
Percent By
Number
9.6
0
0
0
0
9.6
32.1
19.2
0.5
0
0
51.9
35.3
3.2
0
0
0
38.5
100
Percent By Mass
All
Categories
3.0
0
0
0
0
3.0
11.3
54.2
19.5
0
0
85.1
6.9
5.0
0
0
0
11.9
100
Within
Category
100
0
0
0
0
100
13.3
63.7
23.0
0
0
100
57.9
42.1
0
0
0
100
-------
TABLE D-119
RESULTS OF SEM PARTICLE COUNTS
Filter Number:
1093298
Monitor Location: North Braddock
Date of Sample: 8/28/76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75)i
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
200
100
4
0
0
304
900
100
16
9
1
1026
1025
175
32
7
2
1241
2571
*>
Total Mass of Particulates (mg) :
Coors: 289 Agency: 214
Calculated Mass (mg) : 246
3
Air concentration (ug/m ):
Coors: 153 Agency: 108
Percent By
Number
7
3
0
.8
.9
.2
0
0
11
35
3
0
0
0
39
39
6
1
0
.8
.0
.9
.6
.4
.04
.9
.9
.8
.2
.3
0.08
48
.3
100
Percent By Mass
All
Categories
1.0
3.9
2.1
0
0
7.1
5.0
4.4
9.6
27.0
8.1
54.1
3.2
4.3
10.7
11.7
9.0
38.8
100
Within
Category
14.0
55.8
30.2
0
0
100
9.2
8.2
17.7
49.9
14.9
100
8.1
11.1
27.5
30.1
23.2
100
-------
TABLE D-120
RESULTS OF SIM PARnCLE COUNTS
Filter Number: (Cover Filter)
1093299
Monitor Location: North Braddock
Date of Sample: 8/28/76
(Cover Filter for 1093298)
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
350
25
4
0
0
379
725
300
8
0
0
1033
950
175
48
4
0
1177
2589
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency : —
Calculated Mass (mg): 140
3
Air concentration (yg/nV):
Coors: — Agency:
Percent By
Number
13
1
0
.5
.0
.2
0
0
14
28
11
0
.6
.0
.6
.3
0
0
39
36
6
1
0
.9
.7
.8
.8
.2
0
45
.5
100
Percent By Mass
All
Categories
3.0
1.7
3.7
0
0
8.5
7.1
23.4
8.4
0
0
38.9
5.1
7.6
28.1
11.7
0
52.6
100
Within
Category
35.6
20.4
44.0
0
0
100
18.2
60.1
21.7
0
0
100
9.8
14.4
53.5
22.3
0
100
-------
TABLE D-121
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106300
Monitor Location: Duquesne II
Date of Sample: ' 8/28/76
Category
Sphere
5-10y
10-20vi
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
0
0
0
0
0
0
200
50
24
0
0
274
200
250
4
1
0
230
504
*)
Total Mass of Particulates (mg) :
Coors : 68 Agency :
Calculated Mass (mg): 54.1
3
Air concentration (yg/m ):
Coors : — Agency :
Percent By
Number
0
0
0
0
0
0
39.7
9.9
4.J
3
0
0
54.4
39.7
5.0
0.8
0.2
0
45.6
100
Percent By -Mass
All
Categories
0
0
0
0
0
0
5.0
10.1
65.6
0
0
80.7 1
2.8
2.8
6.1
7.6
0
19.3
100
Within
Category
0
0
0
0
0
0
6.2
12.5
81.2
0
0
100
14.6
14.6
31.5
39.4
0
100
-------
TABLE D-122
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106301 Coors: — Agency:
Monitor Location: Duquesne II Calculated Mass (mg) : 4.2
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
(Cover Filter for 1106300) Coors: — Agency:
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
0
0
0
0
0
0
250
0
0
0
0
250
100
0
0
0
0
100
350
3S)
Percent By
Number
0
0
0
0
0
0
71.4
0
0
0
0
71.4
28.6
0
0
0
0
28.6
100
Percent By Mass
All
Categories
0
0
0
0
0
0
81.8
0
0
0
0
81.8
18.2
0
0
0
0
18.2
100
Within
Category
0
0
0
0
0
0
100
0
0
0
0
100
100
0
0
0
0
100
-------
TABLE D-123
RESULT OF SEM PARTICLE COUNTS
Filter Number: HQ6302
Monitor Location: Liberty Boro
Date of Sample: 8/28/76
Category
Sphere
5-10u
10-20M
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
775
0
0
0
0
775
1100
250
24
1
1
1376
2625
650
44
1
0
3320
5471
(All Categories)
Total Mass of Particulates (rug) :
Coors: 207 Agency: 271
Calculated Mass (mg) : 214
Air concentration (ug/m ):
Coors: 130 Agency: 136
Percent By
Number
14
2
0
0
0
0
14
20
4
0
0
0
25
48
11
0
0
2
.1
.6
.4
.02
.02
.2
.0
.9
.8
.02
0
60
.7
100
Percent By Mass
All
Categories
4.4
0
0
0
0
4.4
7.0
12.8
16.6
3.4
9.3
49.1
9.3
18.4
16.9
1.9
0
46.5
100
Within
Category
100
0
0
0
0
100
14.3
26.0
33.7
7.0
18.9
100
20.0
39.6
36.2
4.1
0
100
-------
TABLE D-124
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106303 Coors: — Agency:
Monitor Location: Liberty Boro Calculated Mass (mg) : 110
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
(Cover Filter for 1106302) Coors: — Agency:
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
TOTALS
Particle
Count
150
50
0
0
0
200
600
75
28
0
0
703
550
175
28
2
0
755
1658
(All Categories)
Percent By
Number
9.0
3.0
0
0
0
12.1
36.2
4.5
1.7
0
0
42.4
33.2
10.6
1.7
0.1
0
45.5
100
Percent By Mass
All
Categories
1.6
4.4
0
0
0
6.0
7.4
7.4
37.4
0
0
52.3
3.8
9.6
20-8
7.4
0
41.6
100
Within
Category
27.3
72.7
0
0
0
100
14.2
14.2
71.6
0
0
100
9.1
23.1
50.0
17.8
0
100
-------
TABLE D-125
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106304 Total Mass of Participates (mg) :
Coors: 147 Agency: 215
Monitor Location: Clairton Calculated Mass (mg): 79
3
Date of Sample: August 28, 1976 Air Concentration (yg/m ):
Coors : 61 Agency : 115
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50 y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50M
50-75M
>75y
Totals
TOTALS
(All Categorie.
Particle
Count
525
50
4
0
0
579
700
250
4
0
0
954
300
125
12
0
0
437
1970
5)
Percent By
Number
26.6
25.4
0.2
0
0
29.4
35.5
12.7
0.2
0
0
48.4
15.2
6.3
0.6
0
0
22.2
100
Percent By Mass
All
Categories
8.1
6.1
6.6
0
0
20.9
12.1
34.6
7.5
0
0
54.2
2.9
9.6
12.5
0
0
25.0
100
Within
Category
38.7
29.5
31.9
0
0
100
22.3
63.8
13.8
0
0
100
11.5
38.5
50.0
0
0
100
-------
TABLE D-126
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093280 Total Mass of Particulates (mg) :
Coors: 211 Agency: 202
Monitor Location: Airport Calculated Mass (mg) : 120
3
Date of Sanple: 8/28/76 Air concentration (yg/m ):
Coors: 110 Agency: 97
Category
Sphere
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75p
>75y
Totals
TOTALS
Particle
Count
225
0
0
0
0
225
600
175
4
3
1
784
800
325
20
0
0
1145
2154
(All Categories)
Percent By
Number
10.4
0
0
0
0
10.4
27.9
8.1
0.2
0.1
0.05
36.4
37.2
15.1
0.9
0
0
53.2
100
Percent By Mass
All
Categories
2.3
0
0
0
0
2.3
6.8
15.9
4.9
18.4
16.6
62.6
5.0
16.4
13.6
0
0
35.1
100
Within
Category
100
0
0
0
0
100
10.9
25.4
7.8
29.4
26.4
100
14.4
46.7
38.9
0
0
100
-------
TABLE D-127
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093278
Monitor Location: South Fayette
Date of Sample: 8/28/76
Category
Sphere
5-lOp
10-20,j
20-50y
50-75M
>75y
Totals
Irregular
5-10p
10-20p
20-50y
50-75y
>75u
Totals
Agglomerate
5-lOp
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categoric
Particle
Count
1050
0
0
0
0
1050
1350
600
16
2
0
1968
400
100
16
2
0
518
3536
5S)
Total Mass of Particulates (mg) :
Coors: 174 Agency: 120
Calculated Mass (mg): 166
3
Air concentration (yg/m ):
Coors : 91 Agency : 59
Percent By
Number
29
0
0
0
0
29
38
17
0
0
0
55
11
2
0
0
0
14
.7
.7
.2
.0
.4
06
.6
.3
.8
.4
06
.6
100
Percent By Mass
All
Categories
7.7
0
0
0
0
7.7
11.1
39.6
14.3
8.9
0
73.9
1.8
3.7
7.9
5.0
0
18.4
100
Within
Category
100
0
0
0
0
100
15.1
53.6
19.3
12.1
0
100
10.0
19.9
43.1
27.0
0
100
-------
TABLE D-128
RESULTS OF 81-AI PARTICLE COUNTS
Filter Number: 1106351 Total Mass of Particulates (mg) :
Coors: 226 Agency: 254
Monitor Location: Midland Calculated Mass (mg) : 205
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors: 128 Agency: 127
Category
Sphere
5-lOy
10-20y
20-50y
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20iJ
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorie
Particle
Count
175
0
0
0
0
175
525
125
12
1
0
663
2525
950
88
2
0
3565
4403
;s)
Percent By
Number
4.0
0
0
0
0
4.0
11.9
2.8
0.3
0.02
0
15.0
57.3
21.6
2.0
0.04
0
81.0
100
Percent By Mass
All
Categories
1.0
0
0
0
0
1.0
3.5
6.6
8.6
3.6
0
22.4
9.3
28.1
35.2
4.0
0
76.6
100
Within
Category
100
0
0
0
0
100
15.6
29.7
38.6
16.1
0
100
12.2
36.7
45.9
5.2
0
100
-------
TABLE D-129
RESULTS OF SFA1 PARTICLE GODOT'S
Filter Number: 1093265 Total Mass of Particulates (mg) :
Coors: 114 Agency: 136
Monitor Location: Elco Calculated Mass (mg) : 108
3
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors: 54 Agency: 59
Category
Sphere
5-lOy
10-20y
20-50jj
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
50
0
8
0
0
58
250
175
20
0
0
445
275
225
36
0
0
536
1039
(All Categories)
Percent By
Number
4.8
0
0.8
0
0
5.6
24.1
16.8
1.9
0
0
42.8
26.5
21.6
3.5
0
0
51.6
100
Percent By Mass
All
Categories
0.6
0
9.7
0 •
0
10.2
3.1
17.6
27.2
0
0
48.0
1.9
12.6
27.2
0
0
41.7
100
Within
Category
5.5
0
94.5
0
0
100
6.6
36.7
56.7
0
0
100
4.6
30.2
65.2
0
0
100
-------
TABLE D-130
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1106333
Monitor Location: Central Lab
Date of Sample: 9/3/76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
200
0
0
0
0
200
175
125
32
2
0
335
1150
425
40
1
0
1616
2151
(All Categories)
Total Mass ol Particulates (mg) :
Coors: 256 Agency: 248
Calculated Mass (mg) : 152
3
Air concentration (yg/m ):
Coors: 123 Agency: 132
Percent By
Number
9.
3
0
0
0
0
9.
8.
5.
1.
0.
3
1
8
5
09
0
15.
53.
19.
1.
0.
5
5
8
9
05
0
75.
2
100
Percent By Mass
All
Categories
1.6
0
0
0
0
1.6
1.6
9.0
31.1
9.7
0
51.4
5.7
17.0
21.6
2.7
0
47.0
100
Within
Category
100
0
0
0
0 .
100
3.1
17.5
60.5
18.9
0
100
12.2
36.1
45.9
5.7
0
100
-------
TABLE D-131
RESULTS OF SFM PARTICLE COUNTS
Filter Number: 1106325 Total Mass of Particulates (mg) :
Coors: 265 Agency: 234
Monitor Location: Hazelwood Calculated Mass (mg) : 151
3
Date of Sample: 9/3/76 Air concentration (Mg/m ):
Coors: 129 Agency: 134
Category
Sphere
5-1 Op
10-20y
20-50y
50-75M
>75y
Totals
Irregular
5-10p
10-20y
20-50y
50-75p
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75u
>75M
Totals
TOTALS
Particle
Count
100
0
0
0
0
100
400
250
20
1
0
671
1200
225
60
2
0
1487
2258
(All Categories)
Percent By
Number
4.4
0
0
0
0
4.4
17.7
11.1
0.9
0.04
0
29.7
53.1
10.0
2.6
0.09
0
65.8
100
Percent By Mass
All
Categories
0.8
0
0
0
0
0.8
3.6
18.1
19.5
4.9
0
46.1
6.0
9.0
32.6
5.4
0
53.1
100
Within
Category
100
0
0
0
0
100
7.8
39.2
42.4
10.6
0
100
11.4
17.0
61.4
10.2
0
100
-------
TABLE D-132
RESULTS OF SKAI PARTICLE COUNTS
Filter Number: 1106315 Total Mass of Participates (mg) :
Coors: 289 Agency: 308
Monitor Location: North Braddock Calculated Mass (mg) : 115
3
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors: 140 Agency: 148
' Category
Sphere
5-10u
10-20y
20-5 Oy
50-7 5|j
>75y
Totals
Irregular
5-10y
10-20y
20-5 Oy
50-7 5y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-7 5y
>75y
Totals
TOTALS
Particle
Count
325
25
0
0
0
350
375
100
12
0
0
487
1375
500
36
1
0
1912
2749
(All Categories)
Percent By
Number
11.8
0.9
0
0
0
12.7
13.6
3.6
0.4
0
0
17.7
50.0
18.2
1.3
0.04
0
69.6
100
Percent By Mass
All
Categories
3.4
2.1
0
0
0
5.6
4.5
9.5
15.5
0
0
29.5
9.1
26.5
25.8
3.6
0
65.0
100
Within
Category
61.9
38.1
0
0
0
100
15.2
32.4
52.5
0
0
100
14.0
40.8
39.7
5.5
0
100
-------
TABLE D-133
RESULTS OF SKM PARTICLE COUNTS
Filter Number: HQ6321
Monitor Location: Duquesne II
Date of Sample: 9/3/76
Category
Sphere
5-10u
10-20y
20-50p
50-7 5y
>75p
Totals
Irregular
5-10u
10-20M
20-50n
50-75)j
>75y
Totals
Agglomerate
5-10u
10-20u
20-50p
50-75p
>75u
Totals
TOTALS
(All Categoric
Particle
Count
75
0
0
0
0
75
225
125
16
1
0
367
1100
575
32
2
0
1709
2151
|S)
Total Mass of Particulates (mg) :
Coors: 263 Agency: 319
Calculated Mass (mg) : 126
3
Air concentration (ug/m ):
Coors: 150 Agency: 157
Percent By
Number
3
.5
0
0
0
0
3
10
5
0
0
.5
.5
.8
.7
.05
0
17
51
26
1
0
.1
.1
.7
.5
.09
0
79
.4
100
Percent By Mass
All
Categories
0.7
0
0
0
0
0.7
2.4
10.8
18.7
5.8
0
37.8
6.6
27.6
20.8
6.5
0
61.5
100
Within
Category
100
0
0
0
0
100
6.4
28.6
49.5
15.5
0
100
10.7
44.9
23.8
10.6
0
100
-------
TABLE D-134
RESULTS OF SB1 PARTICLE COUNTS
Filter Number: 1106329 Total Mass of Particulates (mg) :
Coors: 119 Agency: 123
Monitor Location: Liberty Boro Calculated Mass (mg) : 152
3
Date of Sample: 9/3/76 Air concentration (ug/nf ):
Coors: 73 Agency: 60
Category
Sphere
5-10M
10-20M
20-50y
50-75y
>75y
Totals
Irregular
5-10n
10-20y
20-50y
50-75y
>75M
Totals
Agglomerate
5-10p
10-20y
20-50n
50-75y
>75M
Totals
TOTALS
Particle
Count
125
0
0
0
0
125
550
200
12
2
0
764
825
525
56
1
0
1407
2296
(All Categories)
Percent By
Number
5.4
0
0
0
0
5.4
24.0
8.7
0.5
0.09
0
33.3
35.9
22.9
2.4
0.04
0
61.3
100
Percent By Mass
All
Categories
1.0
0
0
0
0
1.0
5.0
14.4
11.7
9.8
0
40.8
4.1
21.0
30.3
2.7
0
58.2
100
Within
Category
100
0
0
0
0
100
12.1
35.3
28.6
23.9
0
100
7.1
36.1
52.1
4.6
0
100
-------
TABLE D-135
RESULTS OF SF.M PARTICLE COUNTS
Filter Number: 1106331 Total Mass of Particulates (mg) :
Coors: 207 Agency: 224
Monitor Location: Clairton Calculated Mass (mg) : 245
3
Date of Sample: 9/3/76 Air concentration (yg/m ):
Coors: 90 Agency: 115
Category
Sphere
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75p
>75y
Totals
TOTALS
(All Categoric
Particle
Count
375
25
0
0
0
400
350
200
44
0
0
594
1075
775
96
3
0
1949
2943
*0
Percent By
Number
12.7
0.8
0
0
0
13.6
11.9
6.8
1.5
0
0
20.2
36.5
26.3
3.3
0.1
0
66.2
100
Percent By Mass
All
Categories
1.8
1.0
0
0
0
2.8
2.0
8.9
26.5
0
0
37.4
3.3
19.2
32.2
5,0
0
59.7
100
Within
Category
65.2
34.8
0
0
0
100
5.2
23.8
70.9
0
0
100
5.6
32.2
53.8
8.4
0
100
-------
TABLE D-136
RESULTS OF SFAI PARTICLE COUNTS
Filter Number: 1106337 Total Mass of Particulates (mg) :
Coors: 164 Agency: 134
Monitor Location: South Fayette Calculated Mass (mg) : 153
3
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors : 79 Agency : 65
Category
Sphere
5-10y
10-20y
20-50p
50-75M
>75p
Totals
Irregular
5-10u
10-20p
20-50M
50-75y
>75p
Totals
Agglomerate
5-lOy
10— 2 Op
20— 50p
50-75U
>75u
Totals
TOTALS
Particle
Count
150
0
4
0
0
154
525
175
16
2
0
718
800
300
44
5
0
1149
2021
(All Categories)
Percent By
Number
7.4
0
0.2
0
0
7.6
26.0
8.6
0.8
0.1
0
35.5
39.6
14.8
2.2
0.2
0
56.8
100
Percent By Mass
All
Categories
1.2
0
3.4
0
0
4.6
4.7
12.5
15.5
9.7
0
42.4
4.0
11.9
23.6
13.4
0
53.0
100
Within
Category
25.7
0
74.2
0
0
100
11.1
29.5
36.5
22.8
0
100
7.5
22.5
44.6
25.4
0
100
-------
TABLE D-137
RESULTS OF SKM PARTICLE OOUN1S
Filter Nun±>er: 1093271
Monitor Location: Baden
Date of Sample: 9/9/76
Category
Sphere
5-10u
10-20y
20-50y
50-75M
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Agglomerate
5-10p
10-20y
20-50vi
50-75y
>75u
Totals
TOTALS
(All Categoric
Particle
Count
750
50
4
0
0
804
550
400
44
2
0
996
600
575
104
3
0
1282
3082
>s)
Total Mass of Particulates (rug) :
Coors: 386 Agency: 355
Calculated Mass (nig): 287
3
Air concentration (ug/m ):
Coors: 207 Agency: 185
Percent By
Number
24
1
0
26
17
13
1
0
.3
.6
.1
0
0
.1
.8
.0
.4
.06
0
32
19
18
3
0
41
.3
.5
.6
.4
.1
0
.6
100
Percent By Mass
All
Categories
3.2
1.7
1.8
0
0
6.7
2.6
15.2
22.6
5.1
0
45.6
1.6
12.1
29.7
4.3
0
47.7
100
Within
Category
47.4
25.3
27.3
0
0
100
5.7
33.4
49.6
11.3
0
100
3.3
25.4
62.2
9.0
0
100
-------
TABLE D-138
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093269 Total Mass of Particulates (mg):
Coors: 387 Agency: 339
Monitor Location: Beaver Falls Qilculated Mass (mg) : 160
3
Date of Sample: 9/9/76 Air concentration (ug/m ):
Coors: 232 Agency: 168
Category
Sphere
5-10y
10-20y
20-50|j
50-7 5y
>75y
Totals
Irregular
5-10y
10-20u
20-50p
50-75y
>75y
Totals
Agglomerate
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
50
0
0
0
0
50
375
250
28
4
0
657
750
325
32
1
0
1108
1815
(All Categories)
Percent By
Number
2.8
0
0
0
0
2.8
20.7
13.8
1.5
0.2
0
36.2
41.3
17.9
1.8
0.06
0
61.0
100
Percent By Mass
All
Categories
0.4
0
0
0
0
0.4
3.2
17.1
25.9
18.5
0
64.7
3.6
12.3
16.4
2.6
0
34.9
100
Within
Category
100
0
0
0
0
100
5.0
26.4
40.0
28.6
0
100
10.2
35.4
47.1
7.4
0
100
-------
TABLE D-139
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093267
Monitor Location: Koppel
Date of Sample: 9/9/76
Category
Sphere
5-10u
10-20M
20-50p
50-75M
>75U
Totals
Irregular
5-10p
10-20y
20-50y
50-75u
>75M
Totals
Agglomerate
5-10y
10-20p
20-50y
50-75y
>75M
Totals
TOTALS
Particle
Count
200
25
0
0
0
225
500
300
28
0
1
829
1025
550
48
6
0
1629
2683
(All Categories)
Total Mass of Particulates (mg) :
Coors: 296 Agency: 330
Calculated Mass (mg) : 211
3
Air concentration ( ug/m ) :
Coors : 156 Agency : 174
Percent By
Number
7.4
0.
0
0
9
0
8.
18.
11.
1.
4
6
2
0
0
0.
30.
38.
20.
1.
0.
04
9
2
5
8
2
0
60.
7
100
Percent By Mass
All
Categories
1.2
1.2
0
0
0
2.3
3.2
15.5
19.6
0
9.4
47.8
3.7
15.8
18.7
11.7
0
49.9
100
Within
Category
50.0
50.0
0
0
0
100
6.8
32.5
41.0
0
19.7
100
7.4
31.7
37.4
23.4
0
100
-------
TABLE D-140
RESULTS OF SF,M PAKTICIE COUNTS
Filter Number: 1110928 Total Mass of Particulates (mg) :
Coors: 338 Agency: 287
Monitor Location: Brlghton Calculated Mass (mg) : 114
Date of Sample: 9/9/76 Air concentration (ug/rrf ):
Coors: 178 Agency: 160
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
200
0
0
0
0
200
325
200
24
0
0
549
525
250
32
1
0
808
1557
(All Categories)
Percent By
Number
12.8
0
0
0
0
12.8
20.9
12.8
1.5
0
0
35.3
33.7
16.0
2.0
0.06
0
51.9
100
Percent By Mass
All
Categories
2.1
0
0
0
0
2.1
3.9
19.2
31.1
0
0
54.3
3.5
13.3
23.1
3.6
0
43.6
100
Within
Category
100
0
0
0
0
100
7.2
35.4
57.4
0
0
100
8.0
30.6
53.0
8.3
0
100
-------
TABLE D-141
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093292 Total Mass of Particulates (mg) :
Coors : 667 Agency : 688
Monitor Location: Midland Calculated Mass (mg) : 185
3
Date of Sample: 9/9/76 Air concentration (ug/nT):
Coors: 404 Agency: 341
Category
Sphere
5-10M
10-20M
20-50u
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
100
0
0
0
0
100
225
150
20
0
1
396
600
725
56
5
0
1386
1882
?s)
Percent By
Number
5.3
0
0
0
0
5.3
12.0
8.0
1.1
0
0.05
21.0
31.9
38.5
3.0
0.3
0
73.6
100
Percent By Mass
All
Categories
0.7
0
0
0
0
0.7
1.6
8.8
16.0
0
10.7
37.2
2.4
23.8
24.8
11.1
0
62.1
100
Within
Category
100
0
0
0
0
100
4.6
23.8
42.9
0
28.9
100
4.0
38.2
39.9
17.8
0
100
-------
TABLE D-142
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106379 Total Mass of Particulates (mg) :
Coors : 187 Agency :
Monitor Location: Elco Calculated Mass (mg) : 132
Date of Sample: 9/9/76 Air concentration (pg/m'):
Coors : 84 Agency :
Category
Sphere
5-10M
10-20U
20-5 Op
50-7 5p
>75)j
Totals
Irregular
5-10p
10-20y
20-50u
50-75y
>75p
Totals
Agglomerate -•
5-lOu
10-20y
20-50y
50-75)j
>75y
Totals
TOTALS
Particle
Count
300
25
0
0
0
325
900
375
8
0
0
1283
775
275
32
3
0
1085
2693
(All Categories)
Percent By
Number
11.1
0.9
0
0
0
12.1
33.4
13.9
0.3
0
0
47.6
28.8
10.2
1.2
0.1
0
40.3
100
Percent By Mass
All
Categories
2.8
1.8
0
0
0
4.6
9.3
31.0
8.9
0
0
49.2
4.4
12.6
19.8
9.3
0
46.2
100
Within
Category
60.0
40.0
0
0
0
100
18.9
63.0
18.2
0
0
100
9.6
27.3
42.9
20.1
0
100
-------
TABLE D-143
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106323 Total Mass of Particulates (mg) :
Coors: 5.7 Agency: 337
Monitor Location: Downtown Calculated Mass (mg): 15.2
3
Date of Sample: 9/9/76 Air concentration (yg/m ):
Coors : — Agency : 159
Category
Sphere
5-lOy
10-20p
20-50jj
50-75)j
>75y
Totals
Irregular
5-10u
10-20y
20-5 Oy
50-75y
>75y
Totals
Agglomerate
5-10y
10-20u
20-50jj
50-75y
>75y
Totals
TOTALS
Particle
Count
25
0
4
0
0
29
150
0
0
1
0
151
25
0
0
0
0
25
205
(All Categories)
Percent By
Number
12.2
0
2.0
0
0
14.1
73.2
0
0
0.5
0
73.6
12.2
0
0
0
0
12.2
100
Percent By Mass
All
Categories
2.0
0
34.6
0
0
36.6
13.5
0
0
48.7
0
62.2
1.2
0
0
0
0
1.2
100
Within
Category
5.5
0
94.5
0
0
100
21.7
0
0
78.3
0
100
100
0
0
0
0
100
-------
TABLE D-144
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106327
Monitor Location: Central Lab
Date of Sample: 9/9/76
(First Fjxamination)
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
500
75
0
0
0
575
2050
625
36
0
0
2711
2950
900
188
6
0
4044
7330
(All Categories)
Total Mass of Particulates (mg) :
Coors : 429 Agency : 428
Calculated Mass (mg): 419
3
Air concentration (yg/m ):
Coors: 219 Agency: 235
Percent By
Number
6
1
.8
.0
0
0
0
7
28
8
0
37
.8
.0
.5
.5
0
0
.0
40.2
12.3
2.6
0.08
0
55.2
100
Percent By Mass
All
Categories
1.4
1.7
0
0
0
3.2
6.7
16.3
12.7
0
0
35.7
5.3
13.0
36.8
5.9
0
61.1
100
Within
Category
45.4
54.5
0
0
0
100
18.7
45.7
35.6
0
0
100
8.7
21.3
60.3
9.6
0
100
-------
TABLE D-145
RESULT OF SEM PARTICLE COUOTS
Filter Number: 1106327
Monitor Location: Central Lab
Date of Sample: 9/9/76
(Second Examination)
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
75
0
0
0
0
75
950
250
28
1
0
1229
1050
300
96
6
1
1453
2757
(All Categories)
Total Mass of Particulates (mg) :
Coors: 42g Agency: 428
Calculated Mass (mg) : 231
3
Air concentration ( ug/m ) :
Coors: 219 Agency: 235
Percent By
Number
2
.7
0
0
0
0
2
34
9
1
0
.7
.4
.1
.0
.04
0
44
38
10
3
0
0
52
.6
.1
.9
.5
.2
.04
.7
100
Percent By Mass
All
Categories
0.4
0
0
0
0
0.4
5.6
11.8
17.9
3.2
0
38.6
3.4
7.9
34.2
10.7
4.8
61.0
100
Within
Category
100
0
0
0
0
100
14.6
30.7
46.4
8.3
0
100
5.7
12.9
56.0
17.5
7.9
100
-------
TABLE D-146
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter)
1106328
Monitor Location: Central Lab
Date of Sample: 9/9/76
(Cover Filter for 1106327)
Category
Sphere
5-10u
10-20y
20-50y
50-75)j
>75U
Totals
Irregular
5-10u
10-20U
20-50y
50-75y
>75y
Totals
Agglanerate
5-10y
10-20y
20-50y
50-75p
>75y
Totals
TOTALS
Particle
Count
100
0
0
0
0
100
825
300
32
1
0
1158
1175
325
60
2
3
1565
2823
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency :
Calculated Mass (mg) : 219
3
Air concentration ( yg/m ) :
Coors : — Agency :
Percent By
Number
3.
5
0
0
0
0
3
29
10
1
0
5
2
6
1
04
0
41
41
11
2
0
0
55
0
6
5
1
.07
1
.4
100
Percent By Mass
All
Categories
0.6
0
0
0
0
0.6
5.1
15.0
21.6
3.4
0
45.0
4.1
9.0
22.5
3.7
15.1
54.4
100
Within
Category
100
0
0
0
0
100
11.4
33.2
47.9
7.5
0
100
7.5
16.5
41.3
6.9
27.8
100
-------
TAfiLE D-147
RESULT OF SKM PARTICLE COUNTS
Filter Number: 1106353
Monitor Location: Hazelwood
Date of Sample: 9/9/76
Category
Sphere
5-10y
10-20y
20-50y
50— 75y
>75y
Totals
Irregular
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
625
25
0
0
0
650
250
100
12
1
0
363
1275
675
64
2
0
2016
3029
(All Categories)
Total Mass of Particulates (mg) :
Coors: 280 Agency: 238
Calculated Mass (mg) : 161
3
Air concentration ( yg/m ) :
Coors: 137 Agency: 140
Percent By
Number
20.6
0.8
0
0
0
21.4
8.2
3.3
0.4
0.3
0
12.0
42.1
22.2
2.1
0.07
0
66.6
100
Percent By Mass
All
Categories
4.7
1.5
0
0
0
6.2
2.1
6.8
11.0
4.6
0
24.5
6.0
25.5
32.6
5.1
0
69.2
100
Within
Category
75.8
24.2
0
0
0
100
8.6
27.7
44.9
18.7
0
100
8.7
36.8
47.2
7.4
0
100
-------
TABLE D-148
RESULTS OF SEM PARTICLE COUNTS
Filter Number: UQ6386
Monitor Location: North Braddock
Date of Sample: 9/9/76
(First examination of stub)
Category
Sphere
5-lOy
10-20y
20-50y
50-7 5y
>75y
Totals
Irregular
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
725
100
8
0
0
833
375
200
36
0
1
612
1125
750
72
4
0
1951
3396
(All Categories)
Total Mass of Particulates (mg) :
Coors : 474 Agency : 532
Calculated .Mass (mg): 259
3
Air concentration (ug/m ):
Coors: 248 Agency: 272
Percent By
Number
21
2
.3
.9
0.2
24
11
0
0
.5
.0
5.9
1
.1
0
0.03
18.0
33
.1
22.1
2.1
0.1
0
57.4
100
Percent By Mass
A1J
Categories
3.4
3.8
4.1
0
0
11.2
2.0
8.4
20.6
0
7.7
38.7
3.3
17.6
22.8
6.4
0
50.1
100
Within
Category
30.3
33.5
36.2
0
0
100
5.1
21.8
53.1
0
19.9
100
6.6
35.1
45.6
12.7
0
100
-------
TABLE D-149
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106386
Monitor Location: North Braddock
Date of Sample: 9/9/76
(Second examination of stub)
Category
Sphere
5-10y
10-20y
20-50p
50-75y
>75M
Totals
Irregular
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count
275
75
4
0
0
354
1850
775
80
1
0
2706
2175
1125
236
11
0
3547
6607
(All Categories)
Total Mass of Particulates (mg) :
Coors : 474 Agency : 532
Calculated Mass (mg) : 575
3
Air concentration (ug/m ):
Coors: 248 Agency: 272
Percent By
Number
4.
1.
0.
2
1
06
0
0
5.
28.
11.
1.
0.
4
0
7
2
02
0
41.
32.
17.
3.
0.
0
9
0
6
2
0
53
7
100
Percent By Mass
All
Categories
0.6
1.3
0.9
0
0
2.8
4.4
14.7
20.6
1.3
0
41.0
2.9
11.9
33.7
7.8
0
56.3
100
Within
Category
21.0
45.9
33.1
0
0
100
10.7
36.0
50.2
3.1
0
100
5.1
21.1
59.8
14.0
0
100
-------
TABLE D-150
RESULTS OF SI-..M PARTICLE COUNTS
Filter Number: (Cover Filter)
1106385
Monitor Location: North Braddock
Date of Sample: 9/9/76
(Cover Filter for 1106386)
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20]J
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
350
100
4
0
0
454
1650
475
44
2
0
2171
1325
925
148
9
0
2407
5032
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency : —
Calculated Mass (mg) : 398
3
Air concentration (yg/m ):
Coors : — Agency :
Percent By
Number
7.0
2.
0.
0
0
9.
32.
9.
0.
0.
0
43.
26.
18.
2.
0.
0
08
0
8
4
9
04
1
3
4
9
2
0
47.
8
100
Percent By Mass
All
Categories
1.1
2.4
1.3
0
0
4.8
5.7
13.0
16.3
3.7
0
38.7
2.5
14.1
30.5
9.3
0
56.4
100
Within
Category
22.1
50.5
27.3
0
0
100
14.6
33.6
42.1
9.6
0
100
4.5
25.0
54.1
16.4
0
100
-------
TABLE D-151
RESULTS OF SEM PARTICLE OOUOTS
Filter Number: 1106383
Monitor Location: Duquesne II
Date of Sample: 9/9/76
Category
Sphere
5-10M
10-20y
20-50y
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
TOTALS
Particle
Count
475
25
0
0
0
500
375
400
16
2
0
793
1025
625
52
5
0
1707
3000
(All Categories)
Total Mass of Particulates (mg) :
Coors : 423 Agency : 524
Calculated Mass (mg) : 204
3
Air concentration (pg/m ):
Coors: 242 Agency: 260
Percent By
Number
15
0
16
.8
.8
0
0
0
.7
12.5
13.3
0.5
0.07
0
26.4
34.2
20.8
1.7
0.2
0
56.9
100
Percent By Mass
Al]
Categories
2.8
1.2
0
0
0
4.0
2.5
21.4
11.6
7.2
0
42.7
3.8
18.6
20.9
10.0
0
53.3
100
Within
Category
70.4
29.6
0
0
0
100
5.9
50.1
27.1
16.9
0
100
7.1
34.8
39.2
18.8
0
100
-------
TABLE D-152
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1106388
Monitor Location: Liberty Boro
Date of Sample: 9/9/76
Category
Sphere
5-lOp
10-20y
20-50p
50-75y
>75)j
Totals
Irregular
5-lOy
10-20p
20-50u
50-75y
>75y
Totals
Agglomerate
5-10y
10-20p
20-50y
50-75y
>75M
Totals
TOTALS
Particle
Count
725
100
0
0
0
825
600
175
16
2
0
793
1825
900
88
12
0
2825
4443
(All Categories)
Total Mass of Particulates (mg) :
Coors : 471 Agency : 582
Calculated Mass (mg): 274
3
Air concentration (ug/m ):
Coors: 289 Agency: 315
Percent By
Number
16.
2.
3
2
0
0
0
18.
13.
3.
0.
0.
6
5
9
4
04
0
17.
41
20
2
0
8
1
2
0
3
0
63
6
100
Percent By Mass
All
Categories
3.2
3.5
0
0
0
6.8
3.0
7.0
8.6
5.4
0
24.0
5.0
19.9
26.3
18.0
0
69.3
100
Within
Category
47.5
52.4
0
0
0
100
12.5
29.1
36.0
22.5
0
100
7.3
28.8
38.0
25.9
0
100
-------
TABLE D-153
RESULTS OF SB! PARTICLE COUNTS
Filter Number: 1106381
Monitor Location: Clairton
Date of Sample: 9/9/76
Category
Sphere
5-10y
10-20y
20-50y
50-75M
>75u
Totals
Irregular
5-lOy
10-20y
20-50p
50-75M
>75y
Totals
Agglomerate
5-10u
10-20p
20-50y
50-75jj
>75p
Totals
TOTALS
Particle
Count
400
25
0
0
0
425
400
300
20
3
0
723
575
500
56
2
0
1133
2281
(All Categories)
Total Mass of Particulates (mg) :
Coors: 293 Agency: 330
Calculated Mass (mg): 186
3
Air concentration (pg/m ):
Coors: 127 Agency: 178
Percent By
Number
17
1
18
17
13
.5
.1
0
0
0
.6
.5
.2
0.9
0.1
31
0
.7
25.2
21
2
.9
.4
0.09
0
49.7
100
Percent By Mass
All
Categories
2.6
1.3
0
0
0
3.9
2.9
17.6
15.9
11.9
0
48.3
2.3
16.3
24.7
4.4
0
47.8
100
Within
Category
66.7
33.3
0
0
0
100
6.1
36.4
32.8
24.6
0
100
4.9
34.1
51.7
9.2
0
100
-------
TABLE D-154
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093294
Monitor Location: Airport
Date ol Sample: 9/9/76
Category
Sphere
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
Agglomerate
5-10u
10-20u
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
75
0
0
0
0
75
550
150
8
1
0
709
800
125
8
7
1
941
1725
(All Categories)
Total Mass of Particulates (mg) :
Coors : 177 Agency : 294
Calculated Mass (mg) : 104
Air concentration (yg/m ):
Coors: 207 Agency: 147
Percent By
Number
4.
3
0
0
0
0
4
31
8
0
0
3
9
7
5
06
0
41
46
7
0
0
0
54
1
.4
.2
.5
.4
.06
.6
100
Percent By Mass
All
Categories
0.9
0
0
0
0
0.9
7.2
15.8
11.4
7.1
0
41.4
5.8
7.3
6.3
27.6
10.6
57.7
100
Within
Category
100
0
0
0
0
100
17.4
38.0
27.4
17.1
0
100
10.1
12.6
10.9
47.9
18.4
100
-------
TABLE D-155
RESULT OF SEiM PARTICLE COUNTS
Filter Number: (Cover Filter)
1093295
Monitor Location: Airport
Date of Sample: 9/9/76
(Cover Filter for 1093294
Category
Sphere
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-lOp
10-20y
20-50p
50-75ij
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75u
Totals
TOTALS
Particle
Count
25
0
0
0
0
25
575
150
4
0
0
729
550
200
12
0
0
762
1516
(All Categories)
Total Mass of Particulates (mg) :
Coors : Agency :
Calculated ,\kss (mg): 56.6
3
Air concentration (ug/m ):
Coors : — Agency :
Percent By
Number
1.
6
0
0
0
0
1.
37.
9
0
6
9
9
3
0
0
48
36
13
0
1
.3
.2
8
0
0
50
.3
100
Percent By Mass
All
Categories
0.5
0
0
0
0
0.5
13.9
28.9
10.4
0
0
53.2
7.4
21.4
17.4
0
0
46.2
100
Within
Category
100
0
0
0
0
100
26.0
54.4
19.6
0
0
100
16.0
46.4
37.6
0
0
100
-------
TABLE D-156
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106310 Total Mass of Particulates (mg) :
Coors: 278 Agency: 214
Monitor Location: South Fayette Calculated Mass (mg): 230
3
Date of Sample: 9/9/76 Air concentration ( pg/m ):
Coors: 145 Agency: 107
Category
Sphere
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
575
100
8
0
0
683
1150
350
40
0
0
1540
1050
400
40
6
0
1496
3719
(All Categories)
Percent By
Number
15.5
2.7
0.2
0
0
18.4
30.9
9.4
1.1
0
0
41.4
28.2
10.8
1.1
0.2
0
40.2
100
Percent By Mass
All
Categories
3.0
4.2
4.6
0
0
11.8
6.8
16.6
25.7
0
0
49.2
3.5
10.6
14.3
10.7
0
39.0
100
Within
Category
25.7
35.7
38.6
0
0
100
13.9
33.8
52.3
0
0
100
8.9
27.1
36.6
27.5
0
100
-------
TABLE D- 157
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93227 & 1093228
(combined cover & primary filters)
Monitor Location: Midland
Date of Sample: 8/16/76
Category
Sphere
5-10y
10-20y
20-50vi
50~75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10u
10~20y
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count
500
100
4
0
0
604
2175
350
44
3
0
2572
1850
175
28
3
0
2056
5232
(All Categories)
Total Mass of Particulates (mg) :
Coors: 149 Agency: 166
Calculated Mass (mg) : 236
3
Air concentration (ug/m ):
Coors: 83 Agency: 80
Percent By
Number
9
1
0
6
9
08
0
0
11
41
6
0
0
5
.6
.7
8
06
0
49
35
3
0
0
.2
.4
.3
.5
.06
0
39
.3
100
Percent By Mass
Ail
Categories
2.6
4.1
2/2
0
0
8.9
12.6
16.2
27.5
9.4
0
65.7
5.9
4.5
9.7
5.2
0
25.4
100
Within
Category
28.8
46.2
25.0
0
0
100
19.2
24.6
41.9
14.3
0
100
23.4
17.7
38.3
20.5
0
100
-------
TABLE D-158
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93229 & 1093230
(combined cover & primary filters)
Monitor Location: Airport
Date of Sample: 8/16/76
Category
Sphere
5-lOu
10-20y
20-50y
50-75y
>75u
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
150
0
4
0
1
155
1725
350
32
3
0
2110
2125
450
36
2
0
2613
4878
(All Categories)
Total Mass of Particulates (mg) :
Coors : 149 Agency : 151
Calculated Nkss (mg) : 237
3
Air concentration (yg/m ):
Coors : 76 Agency : 72
Percent By
Number
3.1
0
0.08
0
0.02
3.2
35.4
7.2
0.6
0.06
0
43.
43.
9.
0.
0.
0
53.
2
6
2
7
04
6
100
Percent By Mass
All
Categories
0.8
0
2.2
0
7.4
10.4
9.9
16.1
19.9
9.3
0
55.3
6.8
11.5
12.4
3.5
0
34.2
100
Within
Category
7.4
0
21.2
0
71.4
100
18.0
29.1
36.0
16.9
0
100
19.8
33.6
36.4
10.1
0
100
-------
TABLE D-159
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93290 & 1093291
(combined cover & primary filters)
Monitor Location: Baden
Date of Sample: 8/28/76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
— — — — — _
Totals
TOTALS
Particle
Count
550
225
20
0
0
795
2275
800
152
5
1
3233
2250
1200
248
65
5
3768
7796
(All Categories)
Total Miss of Particulates (mg) :
Coors: 374 Agency: 351
Calculated Mass (mg) : !071
3
Air concentration (yg/m ):
Coors: 203 Agency: 183
Percent By
Number
7.0
2.9
0.2
0
0
10.2
29.
10.
1.
0.
0.
41.
28.
15.
3.
0.
0.
48".
2
3
9
06
01
5
9
4
2
8
06
T
100
Percent By Mass
. All
Categories
0.6
2.0
2.4
0
0
5.1
2.9
8.2
21.0
3.4
1.8
37.4
1.6
6.8
19.0
24.9
5.2
~~5T.^
100
Within
Category
12.2
39.9
47.9
0
0
100
7.8
21.8
56.2
9.2
5.0
100
2.8
11.8
33.0
43.4
9.0
100
-------
TABLE D- 160
RESULTS OF SEM PARTI CLE OOUMS
Filter Number: ^093247 & 1093248 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 433 Agency:
Monitor Location: Liberty Boro Calculated Mass (mg) : 1026
3
Date of Sample: 8/22/76 Air concentration (yg/m"):
Coors: 272 Agency:
Category
Sphere
5-10y
10-20y
20-50)j
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorit
Particle
Count
275
0
0
0
0
275
2550
875
168
8
0
3601
3200
1225
356
39
3
4823
8699
)S)
Percent By
Number
3.2
0
0
0
0
3.2
29.3
10.0
1.9
0.09
0
41.4
36.8
14.1
4.1
0.4
0.03
55.4
100
Percent By Mass
All
Categories
0.3
0
0
0
0
0.3
3.4
9.3
24.2
5.8
0
42.7
2.4
7.2
28.5
15.6
3.2
57.0
100
Within
Category
100
0
0
0
0
100
8.0
21.8
56.7
13.5
0
100
4.2
12.7
50.0
27.4
5.7
100
-------
TABLE D- 161
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 11 05398 & 1106309 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 151 Agency: 143
Monitor Location: Hazelwood Calculated Mass (mg) : 81
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors : 71 Agency : 76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count
225
0
4
0
0
229
800
275
16
0
0
1091
700
50
0
0
0
750
2070
(All Categories)
Percent By
Number
10.9
0
0.2
0
0
11.1
38.6
13.3
0.8
0
0
52.7
33.8
24.2
0
0
0
36.2
100
Percent By Mass
All
Categories
3.4
0
6.5
0
0
9.9
13.5
37.1
29.2
0
0
79.8
6.6
3.7
0
0
0
10.3
100
Within
Category
34.2
0
65.8
0
0
100
16.9
46.5
36.6
0
0
100
63.6
36.4
0
0
0
100
-------
TABLE D-162
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093298 & 1093299 Total Mass of Particulates (mg) :
(confined cover & primary filters) Coors: 289 A&W- 214
Monitor Location: North Braddock Calculated Mass (mg) : 386
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors: 153 Agency: 108
Category
Sphere
5-10u
10-20y
20-50)j
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75M
>75y
Totals
TOTALS
Particle
Count
550
125
8
0
0
683
1625
400
24
9
1
2059
1975
350
80
11
2
2418
5160
(All Categories)
Percent By
Number
10.6
2.4
0.2
0
0
13.2
31.5
7.8
0.5
0.2
0.02
39.9
38.3
6.8
1.6
0.2
0.04
46.9
100
Percent By Mass
All
Categories
1.7
3.1
2.7
0
0
7.6
5.7
11.3
9.2
17.2
5.2
48.6
3.9
5.5
17.0
11.7
5.7
43.8
100
Within
Category
22.8
41.4
35.8
0
0
100
11.8
23.3
18.9
35.4
10.6
100
8.8
12.6
38.8
26.7
13.1
100
-------
TABLE D-163
RESULTS OF SEM PARTICLE OOUOTS
Filter Number: 1105300 & 1106301 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 68 Agency: —
Monitor Location: Duquesne II Calculated Mass (mg) : 72
3
Date of Sample: 8/28/76 Air concentration (ug/m ):
Coors : — Agency :
Category
Sphere
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
0
0
0
0
0
0
450
50
24
0
0
524
300
250
4
1
0
555
1079
|S)
Percent By
Number
0
0
0
0
0
0
41.7
4.6
2.2
0
0
48.6
27.8
23.2
0.4
0.09
0
51.4
100
Percent By Mass
All
Categories
0
0
0
0
0
0
8.5
7.6
49.3
0
0
65.5
3.2
21.1
4.6
5.7
0
34.5
100
Within
Category
0
0
0
0
0
0
13.0
11.6
75.3
0
0
100
9.2
61.1
13.2
16.5
0
100
-------
TABLE D-164
RESULTS OF SEM PARTICLE COUNTS
Filter Number: HQ6302 & 1106303 Total Mass oC Particulates (mg) :
(combined cover & primary filters) Coors: 207 Agency: 271
Monitor Location: Liberty Boro Calculated Mass (mg) : 325
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors: 130 Agency: 136
Category
Sphere
5-lOy
10-20y
20-50y
50-75y
>75jj
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
925
50
0
0
0
975
1700
325
52
1
1
2079
3175
825
72
3
0
4075
7129
(All Categories)
Percent By
Number
13.0
0.7
0
0
0
13.7
23.8
4.6
0.7
0.01
0.01
29.2
44.5
11.6
1.0
0.04
0
57.2
100
Percent By Mass
All
Categories
3.5
1.5
0
0
0
5.0
7.2
10.9
23.7
2.3
6.1
50.2
7.4
15.4
18.2
3.8
0
44.9
100
Within
Category
69.8
30.2
0
0
0
100
14.2
21.8
47.2
4.5
12.2
100
16.5
34.4
40.6
8.5
0
100
-------
TABLE D- 165
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106327 & 1106328
(combined cover & primary filters)
Monitor Location: Central Lab
Date of Sample: 9/9/76
(second examination)
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
175
0
0
0
0
175
1775
550
60
2
0
2387
2225
625
156
8
4
3018
5580
(All Categories)
Total Mass of Particulates (mg) :
Coors: 429 Agency: 428
Calculated Mass (mg): 450
Air concentration (yg/m ):
Ccors: 219 Agency: 235
Percent By
Number
3.
1
0
0
0
0
3.
31
9
1
0
1
8
8
1
04
0
42
39
11
2
0
0
54
8
9
.2
8
.1
.07
.1
100
Percent By Mass
All
Categories
0.5
0
0
0
0
0.5
5.4
13.4
19.7
3.3
0
41.7
3.8
8.4
28.5
7.3
9.8
57.8
100
Within
Category
100
0
0
0
0
100
12.9
32.0
47.2
7.9
0
100
6.5
14.6
49.2
12.6
17.0
100
-------
TABLE D-166
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106386 & 1106385
(combined cover & primary filters)
Monitor Location: North Braddock
Date of Sample: 9/9/76
(first examination)
Category
Sphere
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50)J
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count
1075
200
12
0
0
1287
2025
675
80
2
1
2783
2450
1675
220
13
0
4358
8428
(All Categories)
Total Mass of Particulates (mg) :
Coors: 474 Agency: 532
Calculated Mass (mg) : 657
3
Air concentration (ug/m ):
Coors: 248 Agency: 272
Percent By
Number
12.
2.
0
8
4
1
0
0
15
24
8
0
0
0
33
29
19
2
0
3
0
0
9
02
01
0
1
.9
.6
.2
0
51
.7
100
Percent By Mass
All
Categories
2.0
3.0
2.4
0
0
7.3
4.2
11.2
18.0
2.2
3.0
38.7
2.8
15.5
27.5
8.1
0
53.9
100
Within
Category
27.0
40.3
32.7
0
0
100
10.9
29.0
46.5
5.8
7.8
100
5.2
28.7
51.0
15.1
0
100
-------
TABLE D-167
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093294 & 1093295
(combined cover & primary filters)
Monitor Location: Airport
Date of Sample: 9/9/76
Category
Sphere
5-lOu
10-20y
20-50y
50-75p
>75y
Totals
Irregular
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Agglomerate
5-10jj
10-20y
20-50y
50-75y
>75y
Total s
TOTALS
Particle
Count
100
0
0
0
0
100
1125
300
12
1
0
1438
1350
325
20
7
1
1703
3241
(All Categories)
Total Mass of Particulates (mg) :
Coors : 278 Agency : 274
Calculated Mass (mg) : 161
3
Air concentration ( yg/m ) :
Coors: 207 Agency: 147
Percent By
Number
3
1
0
0
0
0
3
34
9
0
0
1
.7
2
.4
03
0
44
41
10
0
0
0
52
.4
.6
.0
.6
.2
.03
.5
100
Percent By Mass
All
Categories
0.8
0
0
0
0
0.8
9.6
20.4
11.0
4.6
0
45.6
6.4
12.3
10.2
17.9
6.9
53.6
100
Within
Category
100
0
0
0
0
100
21.0
44.7
24.2
10.1
0
100
11.9
22.9
19.0
33.4
12.8
100
-------
TABLE D-168 through TABLE D-170 - SUMMARY OF EDAX ELEMENTAL ANALYSIS
D-A6
-------
TABLE D- 168
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter-
Baden
1093219
0.00
0.00
0.00
1.48
1.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
0.02
0.00
0. 00
0. 00
0.00
0.00
0.00
0.00
Si
Beaver Falls
1093221
0.00
0.00
0.00
1. 75
1.00
0.16
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
SuS
Koppel
1093223
0.00
0.00
0.02
2.13
1.00
0. 14
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
Si, S
Brighton Twp
1093225
0.14
0.00
0.46
6.76
1.00
0.00
0.00
0.00
0.10
0.89
0.00
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca, Al,
Na, K
Midland
1093227
0.25
0.10
0.45
4.04
1.00
0.23
0.03
0.02
0.18
0.54
0.03
0.03
0.01
0.43
0.00
0.00
0.00
0.00
0.00
0.00
0.00
_Si, Ca, Al,
Fe, Na, S,
K, Mg
-------
TABLE D- 168 (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
Midland
1093228
Cover Filter
0.33
0. 11
0.47
5.23
1.00
0.15
0.07
0.03
0.22
0. 67
0.05
0.04
0.01
0.45
0.01
0.00
0.00
0. 03
0.00
0.00
0.00
Si, Ca, Al,
Fe, Na, K,
S, Mg, Cu
Elco
1093213
0.00
0.00
0.00
1.43
1.00
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
Si
Downtown
1093215
0.00
0.00
0.00
1.64
1.00
0.01
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si
Central Lab
1093241
0.11
0.00
0.37
5.96
1.00
0.22
0. 00
0. 00
0. 11
0.75
0.00
0.00
0.00
0.04
0.00.
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca, Al,
S, Na, K
Hazelwood
1093201
0.00
0.00
0.08
1.50
1.00
0.08
0.00
0.00
0.04
0.22
0.00
0.00
0.00
0.05
0.00
0.00
0.00
0.01
0.00
0.00
0.00
Si, Ca
-------
TABLE D-168 (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
No. Braddock
1093203
0. 11
0.09
0.24
1. 70
1.00
0.24
0.09
0.08
0. 13
0.31
0,07
0.08
0.06
0. 10-
0.06
0.05
0. 04
0.06
0.04
0.03
0.04
Si, Ca, Al,
S, K, Na,
Fe, Cu, Hg,
Pb, As, Cl,
Cd, Cr, Ti
Duquesne II
1093205
0.00
0.00
0.07
1. 17
1.00
0. 12
0.00
0.00
0,04
0.26
0.00
0.00
0.00
0. 13
0.00
0.00
0.00
0.01
0.00
0.00
0.00
Si, Ca, Fe,
S
Liberty Boro
1093209
0.00
0.00
0. 07
1.61
1.00
0.09
0.00
0.00
0.05
0.28
0.00
0.00
0.00
0. 05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca
Clairton
1093211
0.00
0.00
0.00
0.32
1.00
0.00
0.00
0.00
0.00
0.04
0.00
0.00
0.00
0.19
0.00
0.00
0.00
0.00
o.oo
0.00
0.00
Si, Fe
Airport
1093229
0.24
0.03
0.32
3.56
1.00
0.26
0.06
0.05
0.17
0.51
0.06
0.02
0.01
0.45
0.01
0.00
0.00
0.04
0.00
0.00
0.00
jSi, Ca, Fe,
Al, S, Na,
K, Cu
-------
TABLE D-168 (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
Airport
1093230
Cover Filter
0. 14
0.07
0.46
3.59
1.00
0. 15
0.01
0.01
0. 11
0.55
0.04
0.05
0.02
0.27
0.00
0.00
0.00
0.00
0.00
0.00
0. 00
Si, Ca, Al.Fe
S, Na, K
So. Fayette
1093239
0.00
0.00
0. 13
3.79
1.00
0.03
0.00
0. 00
0.00
0.48
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
Si, Ca, Al
-------
TABLE D-169
' SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 28 AUGUST 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
Brighton Twp
1093284
0.08
0.00
0.36
5.36
1.00
0.37
0.00
0.00
0.06
0. 58
0.00
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca, S,
Al
Hazelvvood
1106308
0.22
0. 10
0.39
3.58
1.00
0.45
0.02
0.01
0. 15
0.49
0.04
0.02
0.00
0.08
0.00
0. 00
0. 00
0.01
0.00
0.00
0.00
Si, Ca, S,A1,
Na, K, Mg
Hazelwood
1106309
Cover I- liter
0.24
0.10
0.45
4. 71
1.00
0. 15
0.02
0. 02
0. 16
0. 64
0.04
0.01
0.01
0. 12
0.00
0.00
0.00
0.01
0.00
0. 00
0.00
Si, Ca, Al,
Na, K, S, Fe,
Mg
No. Braddock
1093298
0.20
0.06
0.38
3. 32
1.00
0. 54
0.03
0.07
0. 17
0. 77
0.01
0.02
0.03
0. 35
0.02
0.01
0.01
0.01
0.00
0.00
0.00
_Si, Ca, S, Al,
Fe, Na, K
No. Braddock
1093299
Cover Filter
0.18
0.09
0.45
3.83
1.00
0.15
0.03
0.02
0.16
0.66
0.05
0.02
0.01
0.20
0.00
0.00
0.00
0.02
0.00
0.00
0.00
Si, Ca, Al,
Fe, Na, K, S
-------
TABLE D-169 (Continued)
SUMRTARY OF EDAX ELEMENTAL ANALYSIS FOR 28 AUGUST 1976 FILTER
SAMPLES. ENTRIES ARE RATK )S OF INTEGRAL ENERGY PEAKS
rI'O THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fa
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Runic
Order
Filter
Duquesne II
1106300
0.27
0.15
0.58
6.35
1.00
0.12
0.10
0.08
0.30
0.87
0.07
0.06
0.05
0.08
0.03
0.02
0.01
0.03
0.01
0.00
0.00
Sij Ca, Al,
K, Na, Mg,
S, Cl, Cd, Ti,
Cu
Duquesne II
1106301
Cover Filter
0.24
0.10
0.48
5. 19
1.00
0.08
0.04
0. 00
0.20
0.60
0.04
0. 03
0.01
0. 14
0.00
0.00
0.00
0.01
0.00
0.00
0.00
Si, Ca, Al,
Na, K, Fe,
Mg
Liberty Boro
1106302
0. 10
0.04
0.44
3.65
1.00
0.45
0.02
0.03
0. 19
0. 53
0.06
0.04
0.03
0. 14
0.01
0.00
0.00
0.03
0.00
0.00
0.00
Si, Ca, S, Al,
K, Fe, Na,
Cu
Liberty Boro
1106303
Cover Filter
0.25
0.06
0.41
4.48
1.00
0.13
0.05
0.03
0. 18
0.59
0.05
0.02
0.02
0.43
0.02
0.00
0.01
0.01
0.00
0.00
0.00
Si, Ca, Fe,
Al, Na, K,
S
So. Fayette
1093278
0.06
0.02
0.37
2.55
1.00
0.43
0.01
0. 00
0. 14
0.34
0.03
0. 01
0.01
0. 19
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, S, Al,
Ca, Fe, K
-------
TABLE D-170
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 9 SEPTEMBER 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Filter
Downtown
1106323
0.04
0.00
0.32
5. 66
1.00
0.00
0.00
0.00
0.02
0.62
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0. 00
Sij Ca, Al
Central Lab
1106327
0. 11
0.08
0.41
3.64
1.00
0.67
0.06
0.09
0.23
0.87
0.10
0.02
0.08
0.35
0. 04
0.03
0.01
0.04
0.02
0.00
0.00
Si, Ca, S,
Al, Fe, K,
Na, Ti, Cd,
Cu
Central Lab
1106328
Cover Filter
0.13
0.08
0.47
4.43
1.00
0.27
0.07
0.05
0.22
1.00
0.07
0. 07
0.07
0.24
0. 04
0.05
0.03
0.02
0.00
0.00
0.00
J3i, Ca, Al,
S, Fe, K,
Na
Airport
1093294
0.16
0.04
0.35
4.36
1.00
0.28
0.00
0.21
0.70
0.06
0.00
0.06
0.05
0. 17
0.01
0.00
0.01
0.05
0.00
0.00
0.00
Si, K, Al,
S, Cd, Fe,
Na, Cu
Airport
1093295
Cover Filter
0.21
0.08
0.44
5.41
1.00
0.16
0.13
0.00
0.26
0.90
0.11
0.06
0.05
0.16
0.04
0.00
0.02
0.02
0.00
0.00
0.00
Si, Ca, Al,
K, Na, S, Fe
Cl, Ti
-------
TABLE D-170 (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 9 SEPTEMBER 1976 FILTER
SAMPLES. ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
hnportunt
Elements
In Rank
Order
Filter
So. Fayette
1106310
0. 31
0.44
0.85
2.36
1.00
0.67
0.81
0.64
0.71
0.59
0.49
0.31
0025
0.41
0.23
0. 11
0. 15
0. 19
0.09
0.07
0.09
Si, Al, CL, K,
S, Cd, Ca, Ti
Mg, Fe, Na,
Cr, Mn, Co,
Cu, Zn, Ni,
Hg, Pb, As
-------
TABLE D-171 THROUGH D-216 - PARTICLE ANALYSIS OF SELECTED FILTERS
D-47
-------
TABLE D-171
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Baden Date of Sample: 16 August 1976
Filter Number: 1093219 Photomicrograph Stub Number: 45
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Fe, S, Mn
(low level)
Si, S, Ca
(low level)
Si, Ca
(low level)
Fe, Ca, Si
Si, Ca, Al, S
S, Si, Cl, Ca
(low level)
Ca, S
(low level)
Si, Ca, S
(low level)
Si, Ca
(low level)
S, Si, Ca
(low level)
Si, Zn, Ca, S
(low level)
Si, Fe, Ca, Al, S
(low level)
Dimension &
Description
40 microns
irregular
12 microns
irregular
15 microns
irregular
10 microns
irregular
10 microns
irregular
15 microns
irregular
50 microns
irregular
20 microns
irregular
12 microns
irregular
7 microns
irregular
10 microns
irregular
10 microns
irregular
Probable
Identification
organic - coal
organic - coal
organic - coal
organic - coal
organic - coal
organic - coal
organic - rubber
mineral
organic
organic
organic - coal
organic - coal
See Figure D-20
-------
TABLE D- 172
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Beaver Falls Date of Sample: 16 August 1977
Filter Number: 1093221 Photomicrograph Stub Number: 47
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca (low level)
Si, S, Ca (low level)
Si, Ca, S, Al (low
level)
S, Si, Ca, (low level)
Si, Al, S, Ca (low
level)
Fe, S, Si, Ca, Cl, K,
Al
Si, S, Ca (low level)
Si, S, Ca Fe
S, Si, Ca (low level)
S, Si, Ca, (low level)
Si, Al, S, Ca
Si, S, Ca, Cl, Fe
Dimension &
Description
55 microns
agglomerate
15 microns
irregular
25 microns
irregular
20 microns
irregular
15 microns
irregular
15 microns
agglomerate
60 microns
irregular
15 microns
agglomerate
12 microns
irregular
12 microns
irregular
15 microns
irregular
20 microns
irregular
Probable
Identification
organic -industrial
particle
organic
organic -industrial
particle
insect part
organic
iron-oxide
organic-coal
industrial particle
sulfate
organic
soil dust
soil dust
-------
TABLE D- 173
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Koppel * Date of Sample: 16 August 1977
Filter Number: 1093223 Photomicrograph Stub Number: 48
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Al (low level)
S, Ca, Si, Fe
S, Ca
S, Ca, Si, Al, Fe
Si, Al, S, Ca
S, Ca, Si (low level)
Si, Ca, S
S, Si, Ca, K
Si, S, Ca, Cl, Fe
Si, S, Ca
S, Ca, Si, Fe
Si, Ca, S, K, Cl, Al,
Fe
Dimension &
Description
45 microns
irregular
15 microns
irregular
25 microns
agglomerate
40 microns
agglomerate
30 microns
agglomerate
15 microns
irregular
20 microns
irregular
15 microns
irregular
20 microns
agglomerate
30 microns
irregular
15 microns
irregular
8 microns
irregular
Probable
Identification
organic
industrial particle
organic "industrial
particle
industrial particle
industrial particle
industrial particle
organic-coal
industrial particle
industrial particle
organic-coal
industrial particle
mineral
*Note: Observer noted that 20 meters to the north there was an hibachi grill at the
same level as the monitor which could be a source of coal particulates.
-------
TABLE D-174
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Brighton Twp Date of Sample: 16 August 1977
Filter Number: 1093225 Photomicrograph Stub Number: 49
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Ca, Al, K
Si, Ca, Al, Fe, S,
Ti, Cl
Si, S, Al, Cl, Ca, K
Si, Ca, Al, S, K
K, Si, Al, Fe, Ca, S,
Ti
Si, K, Al, S, Cl
Si, Ca, K, Al, S
Si, Al, Cl, Ca, S
Si, Ca, S, Al, Fe
Fe, Si, Ca, Ti, Al, K,
Mn, S, Zn
Si, Fe, Ca, K, S, Al
Si, Ca, Al, Fe, S, K
Dimension &
Description
20 microns
spherical
15 microns
irregular
15 microns
irregular
15 microns
irregular
8 microns
spherical
20 microns
irregular
10 microns
irregular
15 microns
irregular
12 microns
irregular
15 microns
irregular
6 microns
irregular
8 microns
spherical
Probable
Identification
fly ash
mineral
soil dust
industrial particle
industrial particle
industrial particle
soil dust
industrial particle
soil dust
industrial particle
(iron-oxide)
mineral
flyash
-------
TABLE D-175
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Midland Date of Sample: 16 August 1977
Filter Number: 1093227 Photomicrograph Stub Number: 50
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, AL, K, Fe, Ca, S
Si, Al, Ca, Fe, Ti, Mg
Si, Al, Fe, Ca, K
Si, Fe, Al, S, Ca
Si, Fe, Al
Si, Al, Fe, K, S
Si, Al, Fe, Ca,K, S,
Mg
Si, Fe, Al, S, Ca, K
Si, Al, Ca, Fe, K, S
Si, Fe, S (low level)
Si, Ca, S, Mg, Fe,
Al, K
Ca, Si, Fe, Mg, S,
K, Al, Cl
Dimension &
Description
40 microns
irregular
10 microns
spherical
15 microns
agglomerate
10 microns
irregular
15 microns
irregular
10 microns
spherical
10 microns
spherical
20 microns
irregular
15 microns
irregular
20 microns
spherical
5 microns
agglomerate
7 microns
irregular
Probable
Identification
soil dust
fly ash
industrial particle
soil dust
soil dust
fly ash
fly ash
soil dust
soil dust
organic-coal
industrial particle
industrial particle
See Figure D-21
-------
TABLE D-176
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Midland (Cover Filter) Date of Sample: 16 August 1977
Filter Number: 1093228 Photomicrograph Stub Number: 50C
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, K, Fe, Ca, Al, S,
Cl, Mg
Ca, Si, Fe. K, S, Al,
Cl, Mg, Ti, Mn, Zn
Si, Al, Fe, K, Ca
Si, Ca, Mg, Al, Fe,
Ti, K, S
Fe, Si, S
Si, Al, Fe, K, Ca,
Ti, S
Si, Fe, Al, Ca, Mg,
K, S
Si, Al, Fe, Ca, K
Si, Al, Fe, Ca, K,
S, Na
Si, S, Fe, Al, Ca
Si, Ca, Al, Fe, S
Si, Fe, Ca, Al
Dimension &
Description
30 x 18 microns
irregular
20 microns
irregular
5 microns
spherical
8 microns
irregular
8 microns
spherical
5 microns
spherical
20 microns
irregular
5 microns
spherical
12 microns
irregular
10 microns
irregular
20 microns
irregular
15 microns
irregular
Probable
Identification
industrial particle
industrial particle
( limestone )
fly ash
industrial particle
flyash - iron
oxide
flyash
soil dust
flyash
mineral
soil dust
soil dust
soil dust
-------
TABLE D-177
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Elco Date of Sample: 16 August 1977
Filter Number: 1093213 Photomicrograph Stub Number: 44
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Fe, Ca, Si, Mn, Zn,
Ti
Cl, Si, Ca, S, Ti,
K, Al, Mg
Si, Ca, Cl, S
S, Si, Ca
Si, AI, Fe, Ca, S
Sjj K, Al, Cl, Ca.
Mg, S, Ti, Fe, Mn
Si, S, Ca
Ca, Cl, Si
Ca ( low level)
Si, Al, Fe, Ca, K
organic
Si, Al, S, Fe, Ca
Dimension &
Description
40 microns
irregular
8 microns
agglomerate
25 microns
agglomerate
20 microns
agglomerate
35 microns
agglomerate
8 microns
agglomerate
12 microns
spherical
20 microns
irreg. , square
15 microns
irregular
10 microns
spherical
15 microns
irregular
5 microns
irregular
Probable
Identification
industrial particle
industrial particle
industrial particle
sulfate (?)
industrial particle
industrial particle
organic
CaCl2
organic
industrial particle
organic
industrial particle
* See Figure D-22
-------
TABLE D-178
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Downtown Date of Sample: 16 August 1976
Filter Number: 1093215 Photomicrograph Stub Number: 45
Particle Number-
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca, Al
Si, Ca, S, Al
Si, Ca, S, Al
S, Ca, Si
S, K, Ca, Si
Si, Ca
Si, Ca
Si, Ca (low level)
S, Si, Ca, Fe
Si, Ca, S
Si, S, Ca, Fe
Si, Cl, Ca, S, Al, Fe
Dimension &
Description
30 microns
agglomerate
35 microns
agglomerate
22 microns
agglomerate
15 microns
agglomerate
30 microns
agglomerate
15 microns
irregular
20 microns
irregular
8 microns
spherical
12 microns
agglomerate
20 microns
irregular
25 microns
agglomerate
25 microns
agglomerate
Probable
Identification
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
organic
soil dust
fly ash
industrial particle
organic-coal
industrial particle
industrial particle
-------
TABLE D-179
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Central Lab Date of Sample: 16 August 1977
Filter Number: 1093241 Photomicrograph Stub Number: 21
Particle Number
on Photomicrograph5'
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca (low level)
Si, Al, Ti, Ca, Fe,
K
Si, Ca, Mg, Al, S, K,
Cl, Mn, Ti, Zn
Si, Al, S, Ca, le, K
Si, Al, S, Ca, Cl, Fe
Si, Al, K, Ca, TI,
Fe, Cl, S, Mn, Zn
Si, Ca, S, Al, K
Si, Ca, S, K
Si, Fe, Ca, K, Al,
Ti, Mn
Si, Ca, Fe, Al, S
Sij Ca, S, Al
Sij Al, Ca, Fe, S, K,
Ti
Dimension &
Description
15 microns
irregular
7 microns
agglomerate
5 microns
irregular
15 microns
agglomerate
7 microns
irregular
10 microns
irregular
20 microns
irregular
10 microns
agglomerate
25 microns
irregular
20 microns
agglomerate
15 microns
agglomerate
10 microns
agglomerate
Probable
Identification
organic-coal
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
mineral (indus-
trial origin)
industrial particle
soil dust
industrial particle
industrial particle
industrial particle
* See Figure D~23a and 2J-b
-------
TABLE D-180
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood Date of Sample: 16 August 1977
Filter Number: 1093201 Photomicrograph Stub Number: 39
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
organic
Si, Ca, S, Al
Si, Ca, Fe, S
organic
Si (low level)
Si, S
organic
Si, Fe, Al
Si (low level)
Ca, Si
Si, Al, Mg, Fe
Al, Si
Dimension &
Description
55 microns
irregular
60 microns
agglomerate
35 microns
agglomerate
15 microns
agglomerate
20 microns
agglomerate
25 microns
irregular
50 microns
irregular
25 microns
agglomerate
15 microns
irregular
35 microns
irregular
25 microns
irregular
30 microns
irregular
Probable
Identification
organic-coal
industrial particle
industrial particle
organic - rubber
organic
industrial particle
organic - rubber
industrial particle
soil dust
soil dust
industrial particle
soil dust
See Figure D-24a and 24-b
-------
TABLE D-181
PAimCLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock Date of Sample: 16 August 1977
Filter Number: 1093203 Photomicrograph Stub Number: 40
Particle Number-
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Al, Ca
low level peaks
Si (low level)
Si, Ca, (low level)
low level peaks
Si, Ca
low level peaks
Ca, Si, S, Fe
Si, S
Cl
Si, Ca, S
Ca
Dimension &
Description
35 microns
irregular
25 microns
irregular
20 microns
agglomerate
25 microns
agglomerate
20 microns
agglomerate
30 microns
irregular
25 microns
spherical
15 microns
irregular
15 microns
agglomerate
20 microns
agglomerate
25 microns
irregular
40 microns
irregular
Probable
Identification
soil dust
organic-coal
industrial particle
industrial particle
organic -
industrial particle
industrial particle
organic
soil dust
soil dust
industrial particle
soil dust
industrial particle
-------
TABLE D-182
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Duquesne II Date of Sample: 16 August 1977
Filter Number: 1093205 Photomicrograph Stub Number: 41
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Si, S, Al
Ca, Fe, S, Mn, Cl
S, Si, Ca
.Si, Mg, Ca
Ca, Fe, S, Si
Si, Ca, S (low level)
Si, Ca
Si, Ca, S
Ca, Fe, Si
Si, S, Ca (low level)
Si, Ca, Fe, S, Al, K
Si^ Al, Ca
Dimension &
Description
35 microns
agglomerate
20 microns
agglomerate
25 microns
agglomerate
15 microns
irregular
20 microns
irregular
10 microns
spherical
25 microns
agglomerate
6 microns
spherical
25 microns
agglomerate
15 microns
irregular
12 microns
irregular
20 microns
irregular
Probable
Identification
industrial particle
industrial particle
industrial particle
soil dust
industrial particle
fly ash
industrial particle
fly ash
industrial particle
organic-coal
industrial particle
soil dust
-------
TABLE D-183
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro Date of Sample: 16 August 1977
Filter Number: 1093209 Photomicrograph Stub Number: 42
Particle Number-
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Mg, Ca
Si, Ca
Si, Ca
Ca, S (low level)
Si, Ca
Si, Ca
Si, Al, Mg, Ca
Si, Ca
Fe, Si, Ca, Mn
Si, Ca
Si, Al, Ti, Ca
Si, Ca
Dimension &
Description
55 microns
irregular
18 microns
agglomerate
8 microns
irregular
10 microns
agglomerate
15 microns
irregular
20 microns
irregular
50 microns
irregular
35 microns
irregular
10 microns
agglomerate
20 microns
spherical
30 microns
irregular
15 microns
agglomerate
Probable
Identification
soil dust
industrial particle
industrial particle
coal or coke
soil dust
industrial particle
soil dust
coal or coke
industrial particle
(iron oxide)
flyash
industrial particle
industrial particle
-------
TABLE D-184
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Clairton Date of Sample: 16 August 1976
Filter Number: 1093211 Photomicrograph Stub Number: 43
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Fe, Ca, S (low
level)
Si, Fe, Ca (low
level)
Si, Ca, Fe
Fe, Si, Ca, K, Al,
Pb
Si, Fe, Ca (low
level)
Si, Fe, Ca (low
level)
Si, Mg, Ca (low
level)
S, Si, Cl, Ca, Al,
Na, K, Zn
Al, Si, Ca
Al, Si, S, Ca (low
level)
Al, Ca (low level)
Si
Dimension &
Description
15 microns
irregular (long)
12 microns
irregular
20 microns
irregular
20 microns
irregular
25 microns
agglomerate
20 microns
irregular
15 microns
irregular
15 microns
irregular
20 microns
irregular (long)
15 microns
irregular
25 microns
irregular
8 microns
irregular
Probable
Identification
organic
organic-coal
mineral
iron oxide
industrial particle
organic-coal
organic-coal
industrial particle
(sulfate?)
industrial particle
organic-coal
organic-coal
organic-coal
-------
TABLE D-1S5
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport
Filter Number: 1093229
Date of Sample: 16 August 1976
Photomicrograph Stub Number: 51
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
10
11
12
Ca, Si, Fe, S, A], K,
Cl, Zn, Mn, Ti, Mg
Si, Al, K, Fe, Mg,
Ca, Ti, Cl, S, Mn,Zn
Si, Al, Fe, K, S, Ca
Si, Al, Ca, S, Fe,
K, Mg
Si, Ca, S, Fe, Al
Si, Ca, Fe, K, S, Al,
Ti, Mn, Cl, Zn
Ca, S, Si, Fe
Si, S, Mn, Ca, Cl,
Fe, Al, K, Zn
Si, Fe, Al, Ca, S, K,
Cl
Si, Al, Fe, K, Ca,
S
Si, Al, Fe, S, Ca, K
Si, S, Fe, Ca, Al,
Zn, K
25 microns
irregular
10 microns
spherical
15 microns
irregular
15 microns
agglomerate
6 microns
irregular
50 microns
irregular
15 microns
irregular
5 microns
irregular
6 microns
irregular
30 microns
irregular
10 microns
irregular
15 microns
irregular
industrial particle
flyash
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
soil dust
soil dust
industrial particle
-------
TABLE D-186
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport (Cover Filter) Date of Sample: 16 August 1976
Filter Number: 1093230 Photomicrograph Stub Number: 51C
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order oi'
Spectral Height
Si, Al, Ca, S, Fe,
Mgj K, Cd, Cl, Ti,
Co, Na, Cr, Zn, Cu
Si, Ca, S, Fe, Al
Ca,_S, Si, Fe, Al
Ca, S, Si, Al, Fe
Si, S, Fe
Si, Al, K, Fe, Ca
Si, S, Fe, Ca, Al
Si, Al, K, Ca, Fe, S,
Mg
Si, Fe, Al, S, Ca, K
Si, Ca, AJ., _S, Fe,
Mg, Cl, Ti , Mn
Si, Ca, Al, Fe, S,
K, Na
Si, Al, Ca, K, Fe
Dimension &
Description
30 microns
irregular
20 microns
agglomerate
30 microns
agglomerate
20 microns
spherical
20 microns
irregular
40 microns
agglomerate
25 microns
agglomerate
10 microns
irregular
25 microns
agglomerate
25 microns
agglomerate
15 microns
irregular
25 microns
irregular
Probable
Identification
industrial particle
industrial partid e
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
soil dust
industrial particle
industrial particle
soil dust
industrial particle
-------
TABLE D-187
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: So. Fayette Date of Sample: 16 August 1976
Filter Number: 1093239 Photomicrograph Stub Number: 52
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Ca, Al, K, S
Si, Ca, K
Si, Al, K
Si, Ca, Al, S, Fe, K
Si, K, S, Ca
Ca, Si, Al, K
Si, Al, K, Ca
Si, Ca, S
Si, S
Si, Al, Ca, S, K, Fe
Si, Ca, S, K
Si, Ca, Al, S
Dimension &
Description
20 microns
agglomerate
15 microns
spherical
8 microns
spherical
10 microns
irregular
15 microns
irregular
20 microns
agglomerate
10 microns
irregular
12 microns
agglomerate
12 microns
irregular
20 microns
agglomerate
10 microns
agglomerate
12 microns
agglomerate
Probable
Identification
industrial particle
fly ash
flyash
soil dust
industrial particle
industrial particle
soil dust
industrial particle
coal or coke
industrial particle
industrial particle
industrial particle
-------
TABLE D- 188
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Koppel
Filter Number: 1093286
Date of Sample: 28 August 1976
Photomicrograph Stub Number: 19
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
S, K
S, Si, Ca, Al, Fe
Si
S, Si, Ca, Al, Fe
20 microns
irregular
35 microns
agglomerate
12 microns
irregular
25 microns
agglomerate
industrial particle
industrial particle
soil dust
industrial particle
-------
TABLE D- 189
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Brighton Twp
Filter Number: 1093284
Date of Sample: 28 August 1976
Photomicrograph Stub Number: 16
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
10
11
Si, Al, Ca, Fe, K,
Ti, S, Mn, Zn, Cl
SL Ca, Mg
S, _Zn, Si, K, Fe, Ca,
Al, Ti, Mn
Si, Al, Fe, S, Ca, K
S, Si, Zn
Si, S, Ca, Al, K, Ti,
Fe, Mg
Si, Ca, S, K, Al, Ti,
Cl, Fe, Mg, Mn, Zn
Si, Mg, S, Ca
Si, Al, Mg, Ca, S,
K, Fe, Mn, Cl, Ti,
Zn
Si, S, Ca, Al
Si, Al, K, Fe, Ti,
Ca, S
12 microns
irregular
30 microns
irregular
15 microns
agglomerate
20 microns
irregular
20 microns
irregular
20 microns
agglomerate
10 microns
agglomerate
10 microns
spherical
45 microns
irregular
10 microns
irregular
10 microns
irregular
industrial particle
soil dust
industrial particle
(sulfate)
industrial particle
industrial particle
(sulfate)
industrial particle
industrial particle
flyash
industrial particle
industrial particle
soil dust
-------
TABLE D-190
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Midland Date of Sample: 28 August 1976
Filter Number: 1093282 Photomicrograph Stub Number: 12
Particle Number-
on Photomicrograph
1
2
3
4
5
Elements in Order of
Spectral Height
Si, Fe, Al, S, K, Ca ,
Na
Si, Al, Fe, Ca, Na
Fe, Si, S, Al, Ni,
Cr, Na, Cl, K, Ca
S, Ca, Si, Fe, Al ,
Mg
Fe (very large Fe
peak)
Dimension &
Description
50 microns
agglomerate
25 microns
agglomerate
25 microns
irregular
30 microns
agglomerate
15 microns
spherical
Probable
Identification
industrial particle
industrial particle
industrial particle
(iron oxide)
industrial particle
(sulfate)
flyash
(iron oxide)
steel-making
process
-------
TABLE D-191
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Elco
Filter Number: 1106306
Date of Sample: 28 August 1976
Photomicrograph Stub Number: 18
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
Si, Fe, Al
Si, Fe
Si, Al, Fe, Ca
Si, Ti, Fe
30 microns
fused irreg-
ular
15 microns
irregular
20x6i> microns
irregular
30 microns
agglomerate
soil dust
soil dust
soil dust
industrial particle
-------
TABLE D- 192
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood Date of Sample: 28 August 1976
Filter Number: 1106308 Photomicrograph Stub Number: 58
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ti, Al, Si, S, Ca
Si, Ca, Al, Na, K,
Cl, Mg, S, Fe
Si, Al, K, Fe, S
Si, S, Ca, Al
Si, Al, S, Cl, K, Ca,
Mg, Na, Ti, Fe, Mn
Si, Ca, Al, S, Mg,
Fe
S, Ca, Si, Al, K, Fe
Si, Al, K, Fe, S, Ca,
Mg
Ca, Si, S, Al, K, Cd
Fe, S, Si, Ca
Si, S, Al
Si, Ca, Al, S, Fe, K
Dimension &
Description
22 microns
spherical
12 microns
irregular
40 microns
irregular
20 microns
irregular
20 microns
irregular
30 microns
irregular
10 microns
irregular
15 microns
irregular
15 microns
irregular
20 microns
irregular
25 microns
irregular
20 microns
irregular
Probable
Identification
flyash (titanium
oxide)
mineral (salt)
industrial particle
soil dust
mineral (salt)
industrial particle
industrial particle
soil dust
industrial particle
iron oxide
coal or coke
industrial particle
-------
TABLE D-193
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood (Cover Filter) Date of Sample: 28 August 1976
Filter Number: 1106309 Photomicrograph Stub Number: 58C
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Si, S, Al, Fe, K
Si, Ca, S, Al, Fe, K
K, Ca, Si, S, Al
Si, Al, Ca, Na, K,
Fe, S, Mg
Si, Ca, S (low peaks)
Al, Fe, Si, Ca, Zn
Si, Al, K, Fe, Ca,
S, Mg, Na
Si, S
Si, Al, Ca, K
Sij Ca, Al, K, S, Fe,
Na, Cl, Mg
Ca, Mg, Si, S, Fe,
Al, K, Cd
Si, S, Ca
Dimension &
Description
85x30 microns
irregular
10 microns
irregular
15 microns
irregular
22 microns
agglomerate
20 microns
irregular
30 microns
agglomerate
15 microns
irregular
15 microns
agglomerate
15 microns
irregular
35 microns
irregular
15 microns
agglomerate
30 microns
agglomerate
Probable
Identification
industrial particle
soil particle
industrial particle
industrial particle
organic
(biological)
industrial particle
soil dust
coal or coke
soil dust
soil dust
industrial particle
coal or coke
-------
TABLE D- 194
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock Date of Sample: 28 August 1976
Filter Number: 1093298 Photomicrograph Stub Number: 57
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Al, _K, Fe, Ca,
Ti, S
Si, Ca, Fe, Cl, S
Si, Al, Fe, K, Ca, Ti
Si, K, S, Ca, Al,
Fe, Cl
Si, Al, Fe, S, K
.Si, Ca, Al, Fe, S,
Mg, K, Cl
Si, Al, Ca, K, Fe,
S
Si, Ca, S, Fe, Al
.Si, Al, Fe, K, Ca,
Ti, S
Si, Al, Fe, S, Ca, K
Si, Ca, S, Al, Fe, K
Si, Ca, S, Fe, Al
( low level)
Dimension &
Description
10 microns
irregular
15 microns
irregular
25 microns
irregular
12 microns
spherical
30 microns
agglomerate
35 microns
irregular
10 microns
irregular
15 microns
spherical
5 microns
spherical
12 microns
irregular
30 microns
agglomerate
55 microns
irregular
Probable
Identification
industrial particle
industrial particle
industrial particle
fly ash
industrial particle
soil dust
industrial particle
flyash
fly ash
industrial particle
industrial particle
organic - rubber
* See Figure D-25
-------
TABLE D-195
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock (Cover Filter) Date ctf Sample: 28 Aug 1976
Filter Number: 1093299 Photomicrograph Stub Number: 57C
Particle Number
on Photomicrograph*
1
2
3
4
5
G
7
8
9
10
11
12
13
Elements in Order of
Spectral Height ^
JTe, S, Ca
Ca, Si, Fe, S, Al
Cl
Ca, _§, Si, Al
Ca, S, Si, Al
Si, Al, Ca, S, Fe, K,
Mg
Si, Ca, Ti, Al, K
Mn, Fe, S, Cl, Zn
Sij Al, K, Fe, Ca
Si, Fe, Ca, Al, K,
S, Ti
S (low level)
S, Si, Al, Fe, Ca
(low level)
Ca, S, Si, Fe, Al
Sij Al, Fe, S, Ca,
K
organic
Dimension &
Description
20 microns
spherical
20 microns
irregular
15 microns
irregular
50 microns
agglomerate
30 microns
irregular
15 microns
spherical
10 microns
irregular
20 microns
agglomerate
45 microns
irregular
20 microns
agglomerate
30 microns
agglomerate
40 microns
agglomerate
15 microns
spherical
Probable
Identification
flyash (iron
oxide)
soil dust -
limestone
industrial particle
industrial particle
flyash
flyash
flyash
industrial particle
organic - rubber
industrial particle
industrial particle
industrial particle
pollen
* See Figure 0-26
-------
TABLE D-196
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Duquesne II
Filter Number: 1106300
Date of Sample: 28 August 1976
Photomicrograph Stub Number: 59
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height]
Dimension &
Description
Probable
Identification
ij Ca, Al, K, Mg, S
Si, Ca, Al, K
S, Si, Al
Ca, S, Si, Fe, Al, K
Si, Cl, K, S
(low level)
Si, S, Al
Si, Ca, Al, K, S
60 microns
spherical with
elongated end
20 microns
irregular
15 microns
irregular
25 microns
irregular
50 microns
irregular
35 microns
agglomerate
25 microns
irregular
industrial particle
soil dust
coal or coke
industrial particle
coal or coke
industrial particle
( coke)
industrial particle
-------
TABLE D-197
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Duquesne II (Cover Filter) Date of Sample: 28 Aug 1976
Filter Number: 1106301 Photomicrograph Stub Number: 59C
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height]
Dimension £
Description
Probable
Identification
Si, Fe, Al, S, Ca
Si, Al, Ca, Fe
Si, Ca, Al
Sij Ca, Al, K, Fe,
Mg, Ti, S, Cl, Mn,
Zn
Si, Al, Cl, Ca, K
Si, Ca, Al, Mg, S,
Fe, K, Cl
60 microns
irregular
(broken sphere)
15 microns
irregular
5 microns
spherical
25 microns
irregular
20 microns
irregular
6 microns
irregular
industrial particle
soil dust
fly ash
industrial particle
mineral
industrial particle
-------
TABLE D-198
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro Date of Sample: 28 August 1976
Filter Number: 1106302 Photomicrograph Stub Number: 60
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
SL S, Ca, Al, Fe
Si, S, Fe, Ca
Si, S (low level)
Si, Al, Ca, S
Si, Al, K, Fe, Ca,
S, Ti
Si, S, Al
Si, S, Al
Si, S, Al, K, Fe, Ca
Sij S, Al, Ca
Si_, S, Al, K
SL Fe, S, Ca, Al
Si, Al, S
Dimension &
Description
20 microns
agglomerate
25 microns
agglomerate
30 microns
irregular
15 microns
spherical
15 microns
spherical
20 microns
agglomerate
15 microns
irregular
25 microns
agglomerate
25 microns
agglomerate
20 microns
agglomerate
15 microns
irregular
30 microns
agglomerate
Probable
Identification
industrial particle
industrial particle
organic-coal
fly ash
fly ash
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
* See Figure D-27
-------
TABLE D-198 (Continued)
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro (continued) Date of Sample: 28 August 1976
Filter Number: 1106302 Photomicrograph Stub Number: 60
Particle Number
on Photomicrograph*
13
14
15
16
17
18
19
20
Elements in Order of
Spectral Height '
Si, AL, Ca, K, Fe,
S
Sij S, Al, K, Ca, Fe
Si, Al, Ca, K, Fe,
S, Ti
Si, Al, S, Fe, K
Si, S (low level)
Si, Al, K, Fe, Ca,
S
S, Si, Al, Ca, Fe,
(low level)
Sij S, Al, Fe, K, Ca
Dimension &
Description
35 microns
agglomerate
10 microns
agglomerate
10 microns
irregular
10 microns
irregular
20 microns
irregular
5 microns
agglomerate
15 microns
irregular
7 microns
agglomerate
Probable
Identification
industrial particle
industrial particle
industrial particle
industrial particle
organic - coal
industrial particle
organic
industrial particle
See Figure D-27
-------
TABLE D-199
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro (Cover Date of Sample: 28 August 1976
Filter Number: 1106303 Filter) Photomicrograph Stub Number: 60C
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Fe, Si, S (low level)
Si, Fe, S, Al
Si, Fe, Al, Ca, S,
K, Cl, Na
Si, Ca, Fe, Cl, Ti,
S
Si, Al, Fe, S, Ca
Si, Al, Ca, Fe, K,
Mg, S
Si, Fe, Ca, Al, S
Si, Fe, Ca, Al, S
Si, S, Ca, Fe, Al, K
Cl, Si, Na, Fe, S,
Al, Ca, K
Si, S, Al, Fe, Ca
Si, Al, Fe, Ca, K,
Ti, S, Mn, Mg, Cl
Dimension &
Description
50 microns
irregular
30 microns
agglomerate
20 microns
irregular
15 microns
irregular
15 microns
irregular
10 microns
spherical
40 microns
irregular
60 microns
irregular
15 microns
irregular
20 microns
irregular
(square)
20 microns
agglomerate
10 microns
agglomerate
Probable
Identification
organic-coal
industrial particle
soil dust
industrial particle
industrial particle
fly ash
probable organic
insect part
probable organic
insect part
mineral
salt particle
industrial particle
industrial particle
* See Figure D-28a and 28b
-------
TABLE D-199 (Continued)
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro (Cover Date of Sample: 28 August 1976
Filter Number: 1106303 Filter) Photomicrograph Stub Number: 60C
(Continued)
Particle Number
on Photomicrograph*
13
14
15
16
17
18
19
20
Elements in Order of
Spectral Height
Si, Fe, Ca, K, Al,
S, Ti, Mn
Si, Al, S
Si, Ca, Fe, S, Al,
Na
Sij Al, Fe, S, Ca,
K
Si, Al, Fe, S, K,
Ti
Sij Al, Fe, Ca,
K, S
Si, Fe, Al, S, Ca
Sij Fe, S, Ca, K, Al
[Dimension &
Description
10 microns
irregular
25 microns
irregular
25 microns
agglomerate
30 microns
irregular
20 microns
irregular
10 microns
irregular
15 microns
agglomerate
10 microns
agglomerate
Probable
Identification
industrial particle
soil dust
industrial particle
industrial particle
soil dust
soil dust
industrial particle
industrial particle
* See Figure D-28a and 28b
-------
TABLE D-200
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport Date of Sample: 28 August 1976
Filter Number: 1093280 Photomicrograph Stub Number: 10
Particle Number
on Photomicrograph
1
2
3
4
Elements in Order of
Spectral Height
Si, Ca, Fe, Al , Mg
Si, Fe, Al, Cl, Mg,
Na, Ca, K
Si, S, Ca, Al, Fe,
Cu
Si, Fe, Al, Ca, Mg,
(low level)
Dimension &
Description
25 microns
agglomerate
20 microns
irregular
25 microns
agglomerate
30 microns
irregular
Probable
Identification
industrial particle
mineral
industrial particle
industrial particle
-------
TABLE D- 201
PARTICLE ANALYSTS OF SELECTED FILTERS
Monitor Site: South Fayette Date of Sample: 28 August 1976
Filter Number: 1093278 Photomicrograph Stub Number: 14
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca, Fe, Al
Si, S, Fe, Ca
_Si, Al, Fe, K, S
Si, Al, Fe, K
Si, S, Al, Fe
Si, Al, K, Fe, Ca,
Ti, S
S, Si, Ca
Si, Al, Fe, S, K
S, Si, Al, Fe, K
Si, Fe, Al, S, Ca
Si, Al, K, Fe, S,
Ca
Si, Al, S, K, Fe
Dimension &
Description
65 microns
irregular
30 microns
irregular
8 microns
spherical
5 microns
spherical
16 microns
irregular
10 microns
irregular
20 microns
agglomerate
6 microns
spherical
10 microns
irregular
25 microns
irregular
3 microns
agglomerate
12 microns
irregular
Probable
Identification
soil dust
soil dust
f lyash
f lyash
industrial particle
industrial particle
industrial particle
f lyash
industrial particle
soil dust
industrial particle
soil dust
-------
TABLE D-202
PARTICLE ANALYSES OF SELECTED FILTERS
Monitor Site: Midland Date of Sample: 3 September 1976
Filter Number: 1106351 Photomicrograph Stub Number: i
Particle Number
on Photomicrograph
1
2
Elements in Order of
Spectral Height
Si, Ca, S
S, Si, Ca, Fe, K
Dimension &
Description
35x15 microns
irregular
20 microns
irregular
Probable
Identification
soil dust
industrial particle
-------
TABLE D-203
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Central Lab
Filter Number: 1106333
Date of Sample: 3 September 1976
Photomicrograph Stub Number: 5
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
S, Si, Fe, Ca
Si
Ca, Si, S, Fe
Fe
Si, Fe, S, Mn
35 microns
agglomerate
30 microns
spherical
45 microns
agglomerate
55 microns
irregular
45x15 microns
irregular
industrial particle
industrial particle
industrial particle
(limestone)
iron oxide
soil dust
-------
TABLE D- 204
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood
Filter Number: 1106325
Date of Sample: 3 September 1976
Photomicrograph Stub Number: 17
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
S, Si, Ca, Fe
Fe, Ca, S, Si
Si, S, Fe, Al
Si, Al, S, K, Fe
18 microns
spherical
20 microns
irregular
20 microns
agglomerate
30 microns
irregular
industrial particle
iron oxide
industrial particle
soil dust
-------
TABLE D-205
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock Date of Sample: 3 September 1977
Filter Number: 1106315 Photomicrograph Stub Number: 15
Particle Number
on Photomicrograph
1
2
3
4
Elements in Order of
Spectral Height
Fe, Si, Al
Si, Fe, Ca, S, K, Al
Ca, Si, Fe
Ca, Si, Fe, Al , Mg
Dimension &
Description
30 microns
fused irreg-
ular
40 microns
agglomerate
20 microns
spherical
20 microns
agglomerate
Probable
Identification
industrial particle
industrial particle
industrial particle
(limestone)
industrial particle
-------
TABLE D-206
PARTICLE ANALYSTS OF SELECTED FILTERS
Monitor Site: Duquesne II
Filter Number: 1106321
Date of Sample: 3 September 1976
Photomicrograph Stub Number: ,13
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
Si, S, Ca, K, Fe
Si, S, Ca, K
Zn, S, Na
Mn, S, Si, Al, Ca,
Fe
Fe, S, Si, Ca, Al
25 microns
spherical
30 microns
irregular
20 microns
agglomerate
30 microns
agglomerate
15 microns
irregular
flyash
soil dust
industrial particle
industrial partical
iron oxide
-------
TABLE D- 207
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro
Filter Number: 1106329
Date of Sample: 3 September 1976
Photomicrograph Stub Number: 9
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
Cl, S, Si, K, Ca, Al
Si
Si, S, Ca, Mg
Si, Al, S, Fe, Ca
S, Si, Al, Fe
40 microns
agglomerate
40 microns
Irregular
25 microns
irregular
20 microns
agglomerate
45 x20 microns
irregular
industrial particle
soil dust
soil dust
industrial particle
industrial particle
-------
TABLE D-208
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Clairton
Filter Number: 1106331
Date of Sample: 3 September 1976
Photomicrograph Stub Number: H
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
Si, Ca, Fe, Mg, Na
S, Ca, Si, Fe, Al
S_, S_i, Fe, Al, Ca,
K, Mg
Si, Fe, K, Al, Cl,
Ca, Mg, Na
20 microns
irregular
20 microns
agglomerate
40 microns
agglomerate
10 microns
spherical
industrial particle
industrial particle
(sulfate)
industrial particle
(sulfate)
flyash
-------
TABLE D-209
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: South Fayette Date of Sample: 3 September 1976
Filter Number: 1106337 Photomicrograph Stub Number: 7
Particle Number
on Photomicrograph
1
2
3
4
5
6
Elements in Order of
Spectral Height
Si, S
Si, S, Ca, Fe
Si, Ca, S
Si, Al, S, K, Fe
Fe
S
Dimension &
Description
45 microns
agglomerate
25 microns
spherical
50 microns
irregular
8 microns
spherical
45 microns
irregular
40 microns
irregular
Probable
Identification
industrial particle
f lyash
soil dust
f lyash
iron oxide
industrial particle
(sulf ate )
-------
TABLE D-210
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Brighton Township Date of Sample: 9 September 1976
Filter Number: 1110928 Photomicrograph Stub Number: 23
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
S, Ca, Si, Zn, Fe
S, Zn, Si
S, Si, Ca, Zn, Fe
Si, K, Fe
Fe, S, Si
40 microns
agglomerate
30 microns
irregular
25 microns
agglomerate
20 microns
agglomerate
10 microns
spherical
industrial particle
industrial particle
industrial particle
industrial particle
flyash
(iron oxide)
-------
TABLE D-211
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Downtown Date of Sample: 9 September 1976
Filter Number: 1106323 Photomicrograph Stub Number: 55
Particle Number
on Photomicrograph
1
2
Elements in Order of
Spectral Height '
low level peaks
Si, Al, Ca, K, Fe,
M£, _S, Cl, Ti, Mn,
Zn
Dimension &
Description
20 microns
spherical
30 microns
agglomerate
Probable
Identification
organic - flyash
industrial particle
-------
TABLE D-212
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Central Lab
Filter Number: 1106327
Date of Sample: 9 September 1976
Photomicrograph Stub Number: 55
Particle Number
on Photomicrograph
Elements in Order of
Spectral Height
Dimension &
Description
Probable
Identification
10
11
12
Si, S, Al, Fe, Ca, K
Si, Fe, TL, Ca_, _S,
Al, K, Mn, Zn, Mg,
Cl
Ca, Si, Fe, S, Al, K
Si, Ca, S, Al, Fe, K
Si, Ca, S, Al, Fe,
K, Ti, Cl
Si, S, Ca, Al, Fe, K
Si., Al, K, Ca, S, Fe
Cl
Si, S, Ca, Al
Si, S, Ca, Fe, Al,
K
Si., Al, Fe, Ti, K,
S
Si., Al, K, S, Fe,
Ca, Ti
Si, S, Al, Cl, Ca,
Fe, K (low level)
35 microns
irregular
25 microns
irregular
25 microns
agglomerate
20 microns
agglomerate
20 microns
agglomerate
40 microns
agglomerate
20 microns
irregular
40 microns
agglomerate
30 microns
agglomerate
60x25 microns
agglomerate
45 microns
agglomerate
22 microns
irregular
industrial particle
industrial particle
industrial particle
(limestone)
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
organic - coal
-------
TABLE D-213
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: ^ntralT,Lft> , Date of Sample: 9 September 1976
(Cover Filter)
Filter Number: 1106328 Photomicrograph Stub Number: 5^^
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Si, S, Fe, K,
Al, Cl
Si, Al, Fe, K, Ca,
S
Si, Al, Ca, K, S,
Fe, Mg
Si, Ca, S, Al, K,
Fe, Mg, Cl
Si, Ca, S, Al, Fe, K
Ca, Si, Al, Mn, S,
Fe, K, Ti, Cl, Zn
Si, Al, K, Ca, S,
Fe
Si, S, Ca, Al, Fe
Si, Al, K, Ca, Fe,
S, Ti, Mg, Cl, Mn,
Zn
Si, Al, Fe, K, Ca, S
Si, Ca, S, Al, K, Fe
Si, Ca, Al, S, Fe, K
Dimension &
Description
70 microns
agglomerate
6 microns
irregular
6 microns
spherical
15 microns
agglomerate
8 microns
irregular
15 microns
irregular
30x10 microns
irregular
8 microns
irregular
30 microns
agglomerate
15 microns
irregular
10 microns
irregular
35 microns
agglomerate
Probable
Identification
industrial particle
( limestone)
soil dust
f lyash
industrial particle
soil dust
industrial particle
mineral
soil dust
industrial particle
soil dust
soil dust
industrial particle
-------
TABLE D-214
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport Date of Sample: 9 September 1976
Filter Number: 1093294 Photomicrograph Stub Number: 53
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
13
Elements in Order of
Spectral Height
Si, S, Ca, Al
Si, Ca, Al, Fe, S, K
Si, Al, S, Ca, Fe, K
Si, Ca, Al, K, Mg
Ca, Fe, S, Si, K, Mn
Si, Al, Fe, Ca, K, Ti
Si, S, Al
Si, Al, S, Ca, Fe, K
Ca, S, Fe, Si, K, Al,
Mg, Cl, Mn, Ti, Na,
Zn
Ca, S, Si, Al, K, Fe
Fe, Si, Ca, S, Al , Ti
Si, Ca, Al, Fe
Si, Ca, Al, S
Dimension &
Description
15 microns
irregular
10 microns
agglomerate
10 microns
agglomerate
15 microns
irregular
15 microns
agglomerate
8 microns
spherical
10 microns
irregular
12 microns
agglomerate
5 microns
irregular
10 microns
irregular
10 microns
irregular
7 microns
spherical
10 microns
agglomerate
Probable
Identification
soil dust -
limestone
industrial particle
industrial particle
soil dust
industrial particle
f lyash
soil dust
industrial particle
industrial particle
soil dust
(sulfate?)
industrial particle
(iron oxide)
f lyash
industrial particle
See Figure D-29a and 29b
-------
TABLE D-215
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: ,-,irporr,..1 , Date of Sample: 9 September 1976
(Cover Filter)
Filter Number: 1093295 Photomicrograph Stub Number: cor.
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
13
Elements in Order of
Spectral Height
Si, Al, Ti, pe, K,
Ca, S, Cl, Mg, Na
Si, Ca, Al, Mg, S,
Fe, K
Si, Al, Ca, S, K,
Fe, Mg, Cl, Ti, Na,
Mn, Zn
Ca, Fe, S_, Si, Al, K,
Mg, Ti, Mn, Zn
Si, Al, Ca, K, Fe,
S, Mg, Na, Ti
^i., Al, Ca, S
Si, Al, K, Fe, Ca,
S, Ti, Mg
Si, Al, Fe, K, Ca,
S, Mg
Si, Ca, Al, S, K
Si, Ca, S, Al, K,
Fe, Mg
Si, Ca, S^ Al, K, Fe
Si. Al, Ca, S, Fe,
K, Mg, Ti, Cl, Zn
Ca, J3, Si, Al, Ti
Dimension &
Description
25 microns
irregular
18x6 microns
irregular
12 microns
irregular
14 microns
irregular
8 microns
agglomerate
6 microns
irregular
8 microns
irregular
12 microns
irregular
10 microns
irregular
10 microns
agglomerate
8 microns
irregular
12 microns
agglomerate
8 microns
irregular
Probable
Identification
industrial particle
soil dust
industrial particle
industrial particle
Industrial particle
soil dust
mineral
mineral
soil dust
industrial particle
industrial particle
industrial particle
soil dust
-------
TABLE D-215 (Continued)
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Si to: /^irP°r^.i N Date of Sample: 9 September 1976
(Cover Filter) '
Filter Number: 1093295 Photomicrograph Stub Number: ^c
Continued")
Particle Number
on Photomicrograph
14
15
Elements in Order of
Spectral Height
Fe, Si, S, Ca, K,
Al, Ti
Si, Al, Ca, K, Fe,
Mg, S, Ti
Dimension &
Description
8 microns
irregular
8 microns
agglomerate
Probable
Identification
industrial particle
(iron oxide)
industrial particle
-------
TABLE D- 216
PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: South Fayette Date of Sample: 9 September 1976
Filter Number: 1106310 Photomicrograph Stub Number: 54
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
S_, Ca, Si, Fe, Ti,
K, Al
Ca, S, Si, Al
Si., Al, Fe
Ca, Si, S, Mg, Fe,
Al, K
SI, _S, Al, Ca, K, Fe
Si, S, Al, Ca
Si, S, Al, Fe
(low level)
Si, Al, Fe, K, Ca,
Mn, S, Ti
Si, Al, S, Fe, K,
Ca
_Si, Al, K S, Fe,
Ca, Ti
S, Si, Al
E^i, Al, S, Fe
Dimension &
Description
25 microns
irregular
20 microns
agglomerate
20 microns
irregular
15 microns
irregular
12 microns
agglomerate
15 microns
agglomerate
10 microns
irregular
20 microns
irregular
10 microns
spherical
3 microns
agglomerate
15 microns
irregular
15 microns
spherical
Probable
Identification
industrial particle
industrial particle
soil dust
soil dust -
limestone
industrial particle
industrial particle
organic
soil dust
f lyash
industrial particle
organic
pollen
See Figure D-30
-------
TABLE D-217 THROUGH D-224 - ANALYSIS OF SELECTED LARGE PARTICLES
D-48
-------
TABLE D- 21 7
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
Filter Number: 1110916
Particle Number
(see Figure)
1 ' (Fig.D-31a)
2 (Fig.D-31a)
3 (Fig.D-31a)
4 (Fig.D-31a)
5 (Fig.D-31a)
7 (Fig.I)-31b)
8 (Fig.D-31b)
1 (Fig.D-32)
2 (Fig.D-33)
4 (Flg.D-34)
5 (Fig.D-35)
Elements in Order of
Spectral Height
S (low level peaks)
Si, S (low level
peaks)
j3i, Zn, _S, Na, Fe
Si, Ti, Cl, Al, Fe,
Ca
S_, Cl, K, Zn
Si, S_, Al, Fe, Zn,
K, Ca
Ca, S_, Si
S, Fe, Zn, Al, Si,
K
jFe, Si, Cl, S
Si_, Al, Ti, Fe
Si, Fe, Zn, Al, S, K,
Ca
Dimensions &
Description
100x30
microns
irregular
75x20 microns
irregular
35 microns
irregular
40 microns
elongated
agglomerate
35 microns
irregular
70 microns
rough semi-
spherical
50 microns
agglomerate
40x20 micror
agglomerate
15 microns
fused
25x15 micror
irregular
45x25 micror
agglomerate
Probable
Identification
organic - coal
organic - coal
industrial
particle
industrial
particle
industrial
particle
industrial
particle
industrial
particle
industrial
particle
iron oxide
soil dust
industrial
particle
-------
TABLE D-218
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
(Cover Filter)
Filter Number: 1110917
Particle Number
(see Figure)
1 (Fig.D-36)
la (Fig.D-36)
Ib (Fig.D-36)
Ic (Fig.D-36)
Id (Fig.D-36)
le (Fig.D-36)
Elements in Order of
Spectra] Height
The entire particle
was not analyzed by
EDAX but the follow-
ing individual parts
of it were
Cl, Si, K, Fe
!Si, Fe, S_, Al, Ca,
K, Cl
_C1_, Si, K, Fe, Al,
Ca
Cl, K, Si, Fe, Al
Si, Al, Fe, K, Ti
Dimensions &
Description
100 microns
with
particles
attached
agglomerate
10 microns
spVierical
protrusion
from main
particle
15 microns
fluffy
irregular
attached to
main
particle
20 microns
angular
piece of
main
particle
Area on
right side
of main
particle
5 microns
sphere
attached
to main
particle
Probable
Identif ication
industrial
particle
-------
TABLE D-218
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
(Cover Filter)
Filter Number: 1110917 (Continued)
Particle Number
(see Figure)
1 (Fig.D-37)
2 (Fig.D-37)
3 (Fig.D-38)
1 (Fig.D-39)
1 (Fig.D-40)
2 (Fig.D-40)
3 (Fig.D-41)
4 (Fig.D-42)
5 (Fig.D-43)
6 (Fig.D-44)
Elements in Order of
Spectral Height
Fe, Si + small peaks
Si, Cl, K, Fe, Zn,
Al , Na + low peaks
Fe, Si, S, K, Ca +
low peaks
Al, S±_, Fe
Fe
Si., Al, K, Fe
S_, Si, Cl, Ca, Fe,
Na + low peaks
Si, Ca, Al, Fe, S,
K
Cl, K, J3, Si, Fe
Ca, S
Dimensions &
Description
45 microns
sphere
35x1 5 microns
curved and
flat
35x25microB
agglomerate
65x45micron£
agglomerate
32 microns
sphere with
rough sur-
face
35 microns
fused
150 microns
like crum-
pled paper
65 microns
fused, rough
150 microns
flaky
25 microns
agglomerate
Probable
Identification
plastic
industrial
particle
industrial
particle
industrial
particle
iron oxide
fused ash
ash
industrial
particle
industrial
particle
limestone
-------
TABLE D-218
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
(Cover Filter) (Continued)
Filter Number: 1110917
Particle Number
(see Figures)
7 (Fig.D-45)
8a (Fig.D-46)
8b (Fig.D-46)
9 (Fig.D-47)
Elements in Order of
Spectral Height
Mn, Fe, Si, Ca, K +
low peaks
Fe
Ca, Si, S_, Fe, Al +
small peaks
K, Fe, Si
Dimensions &
Description
25 microns
sphere with
many small
attached
particles
25 microns
agglomerate
15 microns
irregular
35 microns
agglomerate
Probable
Identification
f lyash
iron oxide
soil dust
industrial
particle
-------
TABLE D-219
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Central Lab Date of Sample: 10 August 1976
Filter Number: 1110908
Particle Number
(see Figure)
1 (Fig.D-48)
2 (Fig.D-48)
3 (Fig.D-48)
4 (Fig.D-48)
Elements in Order of
Spectral Height
Ca
Ca, IS, Si, K
Fe
Si,, Fe, Al
Dimensions &
Description
50 microns
agglomerate
50 microns
irregular
40 microns
irregular
40 microns
irregular
Probable
Identification
limestone
industrial
particle
iron oxide
industrial
particle
-------
TABLE D-220
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Central Lab Date of Sample: 10 August 1976
(Cover Filter)
Filter Number: 1110909
Particle Number
(see Figure)
1 (Fig.D-49)
2 (Fig.D-49)
3 (Fig.D-.49)
4 (Fig.D-49)
1 (Fig.l)-50)
1 (Fig.D-51)
2 (Fig.D-52)
1 (Fig.D-53)
2 (Fig.D-53)
3 (Fig.D-53)
1 (Fig.D-54)
2 (Fig.D-54)
Elements in Order of
Spectral Height
Si, Ca, Cl
S±, Al, Ca, Fe, K
Si, S, Cl, Ca, K, Ti,
Na, Fe
Si, S, Mn
S, Fe small peaks, ma)
be organic
Ca, Si, S, Al, K, Cl
Si, S, Cl, Ca, K, Fe.
Al
Ca, Si, S
S_i, Ca
Ca, Ti, S
Si, S, Ca
_S, Ca, Si, K, Fe
Dimensions &
Description
30 microns
irregular
15 microns
spherical
40 microns
irregular
25 microns
irregular
95 microns
irregular,
flat
40 microns
agglomerate
250x60 mic-
rons angulai
agglomerate
40 microns
agglomerate
20 microns
irregular
70 microns
agglomerate
30 microns
agglomerate
30 microns
agglomerate
Probable
Identification
soil dust
fly ash
industrial
particle
industrial
particle
organic
industrial
particle
industrial
particle
industrial par-
ticle, limestone
industrial
particle
industrial
particle
soil dust
industrial
particle
-------
TABLE D-220 (Continued)
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Central Lab
(Cover Filter)
Filter Number 1110909
Date of Sample: 10 August 1976
(Continued)
Particle Number
(see Figure)
3 (Fig.D-54)
9 (Fig.D-55)
10 (Fig.D-55)
11 (Fig.D-55)
12 (Fig.D-55)
14 (Fig.D-56)
15 (Fig.D-56)
16 (Fig.D-56)
17 (Fig.D-56)
18 (Fig.D-56)
19 (Fig.D-56)
Elements in Order of
Spectral Height
SI' Ca, Al, Fe, S,
K, Cl
Si, Ca, S, Cl, Fe
^, Fe,low peaks
Si, Ca, Al, Fe, K
Si, S, Ca, Fe
Ca, Si
Si, Al, Ca
low peaks
Si, Ca, S, Fe
Ca, S
Fe, Si, Ca, Mn
Dimensions&
Description
15 microns
almost
spherical
75x30microni
irregular
70 microns
irregular
120 microns
agglomerate
40 microns
irregular
50 microns
irregular
100 microns
fluffy
agglomerate
70 microns
irregular
50 microns
agglomerate
50 microns
irregular
50 microns
spherical
Probable
Identification
industrial
particle
indvistrial
particle
organic - coal
industrial
particle
soil dust
industrial
particle
industrial
particle
organic - coal
industrial
particle
gypsum
industrial
particle
-------
TABLE D-221
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Duquesne II Date of Sample: 10 August 1976
Filter Number: 1110926
Particle Number
(see Figure)
1 (Fig.D-57)
2 (Fig.D-58)
3a (Fig.I)-59)
3b (Fig.D-59)
4 (Fig.D-60)
5 (Fig.D-61)
1 (Fig.D-62)
2 (Fig.D-62
3 (Fig.D-62)
5 (Fig.D-62)
Elements in Order of
Spectral Height
Si, Al, Ca, Fe, K,
Ti
Si, Al, K, Fe
Si, S + small peaks,
may be organic
_S_i, Ca, Fe, S, K
spectra may come
from attached parti-
cles
Fe
Zn, Cl, Si, Na, Fe
Al
Si, Ca, Fe, + small
peaks
Si, Fe + small peaks
SI., Al, Fe, K
Dimensions &
Description
40x20 microns
agglomerate
with
particles on
surface
40 microns
agglomerate
25 microns
crumpled
40 microns
irregular
with
particles
attached
25 microns
sphere
32 microns
agglomerate
80 microns
irregular
50 microns
irregular
100x20microns
angular
30 microns
irregular
Probable
Identification
industrial
particle
industrial
particle
ash
ash
iron oxide
zinc chloride
industrial par-
ticle (alumi-
num oxide)
coal
coal
soil dust
-------
TABLE D-221 (Continued)
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Duquesne II Date of Sample: 10 August 1976
Filter Number: 1110926 (Continued)
Particle Number
(see Figure)
6 (Fig.D-62)
1 (Fig.n-63)
2 (Fig.D-63)
3 (Flg.D-63)
4 (Fig.D-63)
5 (Fig.D-63)
6 (FLg.D-63)
Elements in Order of
Spectral Height
Al, Mg, Si, Fe, Ca
Si, Ca (particles 1,
2 and 6 may be joined
into a single parti-
cle)
Si, Ca, Fe + small
peaks
Si, S, Ca, Fe
Fe, Si
Si, Ca, Fe
Ca
Dimension3 &
Description
60 microns
irregular
55x30 micron:
irregular
particles
on surface
45 microns
agglomerate,
particles
on surface
20 microns
spherical
with parti-
cles on its
surface
6 microns
spherical
20 microns
particles on
surface
12x17 micron:
triangular
with parti-
cles on the
surface
Probable
Identification
industrial
particle
industrial
particle
industrial
particle
industrial
particle
iron oxide
industrial
particle
limestone
-------
TABLE D-222
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Duquesne II Date of Sample: 10 August 1976
Filter Number: (Cover Filter)
1110927
Particle Number
(see Figure)
2 (Fig.D-64)
3 (Fig.D-65)
4a (Fig.D-66)
4b (Fig.D-66)
1 (Fig.D-67)
2 (Fig.D-67)
3 (Fig.D-67)
4 (Fig.D-67)
Elements in Order of
Spectral Height
organic
SJ,, Al, Ca, Fe
Fe + low peaks
Ca, _S
S_i, K, Cl, S, Al
^i, Al
Fe, Cr, Si, Cu, Al
^i, Ca, S, Al, Fe,
Mn
Dimensions&
Description
35x15 micron
lumpy
20 microns
irregular
like
backbone
25 microns
irregular
20 microns
irregular
45 microns
irregular
25 microns
egg-shaped
35 microns
irregular
30 microns
agglomerate
Probable
Identification
organic
(rubber)
industrial
particle
iron oxide
industrial par-
ticle (gypsum)
industrial
particle
soil dust
industrial par-
ticle (iron
oxide)
soil dust
-------
TABLE D-223
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Central Laboratory Date of Sample: 16 August 1976
Filter Number: 1093241
Particle Number
(see Figure)
Elements in Order of
Spectral Height
Dimensions &
Description
Probable
Identification
14 (Fig.D-68)
Fe
15 (Fig.D-69)
16 (Fig.D-70)
17 (Fig.D-71)
18 (Fig.D-72)
19 (Fig.D-73)
S, Fe small peaks
S, Fe, Si
small peaks
Si, Al, K, Fe
Si, Al, S, Ca, Fe
230 microns
cluster,
angular
agglomerate
160 microns
angular,
frothy
130 microns
frothy
170 microns
flake
125 microns
angular
70 microns
hollow
fused
iron oxide
coke
coke
organic coal
fused clay
fused clay
-------
TABLE D-224
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 9 September 1976
Filter Number: 1110928
Particle Number
(see Figure)
1 (Fig.D-74a
& Fig.D-74b)
la (Fig.D-74b)
Ib (Fig.D-74b)
lc (Fig.D-74b)
2 (Fig.D-74a)
& Fig.D-75)
3 (Fig.D-74a
& Fig.D-76)
4 (Fig.D-74a
& Fig.D-77)
5 (Fig.D-78)
Elements in Order of
Spectral Height
The entire particle
was not analyzed by
EDAX but the follow-
ing parts of it were
Si, Fe, Ca, K, Al,
Cl
Si, Ca, Fe, Al, K,
Cl
Only small peaks
Fe, Ca, S
Si, S, Al, Fe, Zn,
Ti
_S, Ca, Fe, Zn, Si
Si., Al, Fe, K, Ca
Dimensions &
Description
370x160
microns
angular
flake
central 25%
of particle
participates
on particle
central area
of main
particle
(smaller than
25%)
80 microns
rough
surface
230 microns
fused
agglomerate
200x30
microns
irregular
rough
60 microns
hollow
sphere
Probable
Identification
organic
iron oxide
industrial par-
ticle possibly
coke
industrial par-
ticle of gypsum
f lyash
hollow
-------
TABLE D-224 (Continued)
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 9 September 1976
Filter Number: 1110928 (Continued)
Particle Number
(see Figure)
(Fig.D-79)
7 (Fig.D-80)
8 (Fig.D-81)
9 (Fig.D-82)
10 (Fig.D-83)
11 (Fig.D-84)
12
13 (Fig.D-86)
Elements in Order of
Spectral Height
Si, Al, Fe, Ca, K,
Zn
Si, Al, Fe, Zn + low
peaks
Ve_, Si, Zn + low
peaks
_S_i, S_, Al, Fe, Zn,
Ca
Ti, Si, Al, Fe, Cl
Si, Al
Si, Ca, Fe, Al, Zn
The entire particle
was not analyzed by
EDAX but the follow-
ing parts of it were
Dimensions&
Description
55 microns
agglomerate
made up of
many spheres
70 microns
porous flake
95 microns
flaky
agglomerate
65 microns
agglomerate
30 microns
irregular ,
rough
surface
70 microns
lacy open
structure
75x40 microns
irregular
flake with
attached
particles
35 microns
rough sphere
with parti-
cles attachdd
Probable
Identification
flyash
cluster
coke
coke
industrial par-
ticle with
flyash sphere
rutile
silicate
ash
industrial par-
ticle mixed
chloride
-------
TABLE D-224 (Continued)
ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 9 September 1976
Filter Number: 1110928 (Continued)
Particle Number
(see Figure)
13a (Fig.D-86)
13b (Fig.D-86)
13c (Fig.D-86)
13d (Fig.D-86)
Elements in Order of
Spectral Height
_S, Cl, Zn, Fe
S_, Zn, Cl, Fe
Si, S, Al, Cl, Zn,
Fe
Cl, Zn, Fe, Al
Dimensions &
Description
central area
particle in
center
attached
sphere
particle
surface
Probable
Identification
-------
TABLE D-225 and D-226 - ELEMENTAL ANALYSIS OF FIVE SELECTED LARGE
PARTICLES
D-49
-------
TABLE D-225
ELEMENTAL ANALYSIS OF FIVE SELECTED LARGE PARTICLES
ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS TO
THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Rig
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
iAIn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Hunk
Order
Particle Number
1
0.00
0.00
0.01
0.10
1.00
0.18
0.03
0.00
0.01
0.11
0.01
0.00
0.02
0. 19
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, $ Ca,
Si
2
0.00
0.00
0.00
0.12
1.00
0.05
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.13
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, Si
3
0.00
0.00
0.03
0.00
1.00
0.06
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0. 12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe
4
0.00
0. 00
0.00
0.01
1.00
0. 12
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0. 16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, S
5
0.00
0.00
0.00
0.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe
-------
TABLE D-226
RESULTS OF ELEMENTAL ANALYSIS OF FIVE SELECTED
LARGE PARTICLES
Particle Number
(See Figure)
1 (Fig.D-87)
2 (Fig.D-88)
3 (Fig.D-89)
4 (Fig.D-90)
5 (Fig.D-91)
Elements in Order of
Spectral Height
Fe, S, Ca, Si
Fe, Si (low level
peaks)
Fe (low level peaks)
Fe, S, (low level
peaks)
Fe (low level peaks)
Dimension &
Description
100 microns
lacy, agglo-
merate
110 microns
flat, irregular
160 microns
flat, irregular
140 microns
agglomerate
150 microns
angular, irreg-
ular
Probable
Identification
plant particle
industrial
particle
organic, ash
plant particle
(soot)
organic, coal
-------
TABLE D-227A THROUGH D-229B - EDAX ELEMENTAL ANALYSIS OF LARGE
SLAG PARTICLES
D-50
-------
TABLE D-227A
EDAX ELEMENTAL ANALYSIS OF LARGE PARTICLES WHICH WERE TAKEN
FROM SLAG SAMPLES PRODUCED BY AN ELECTRIC ARC FURNACE.
ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-92
and D-93)
A
0.01
0.67
0.02
0.26
1.00
0.12
0.00
0.00
0.00
0.35
0.05
0.08
0.34
1.12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, Mg, Ca,
Mn, Si, S,
Cr, Ti
(Fig. D-96
and D-97)
B
0.00
0.00
0.03
0.99
1.00
0.06
0.04
0.00
0.05
3.19
0.01
0.01
0.07
0.51
0.00
0.00
0.11
0.04
0.00
0.00
0.00
Ca, Si, Fe,
Zn, Mn, Cu
(Fig.D-100)
C
0.00
0.07
0.17
0.82
1.00
0.04
0.01
0.00
0.08
1.21
0.02
0.00
0.00
0.46
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Ca, Si, , Fe,
Al, K, Mg
(Fig.D-101)
D
0.02
0. 07
0. 18
1.31
1.00
0. 14
0.05
0. 00
0.07
3.41
0.02
0.03
0. 06
0. 73
0.00
0.00
0. 02
0.00
0.00
0.00
0.00
Ca, Si, Fe,
Al, S, Mg,
K, Mn, Cl
-------
TABLE D- 227B
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
ON THE LARGE PARTICLES WHICH WERE TAKEN FROM SLAG
SAMPLES PRODUCED BY AN ELECTRIC ARC FURNACE
ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Cu
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-94)
A-l
0.00
0.00
0.00
0.35
1.00
0.02
0.04
0.00
0.00
1.57
0.00
0.01
0.00
0.42
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Ca, Fe, Si
(Fig.D-95)
A- 2
0.09
0.07
0.07
2.25
1.00
0.18
0.19
0.00
0.31
7.55
0.14
0.13
0.31
1.28
0.00
0.00
0.11
0.04
0.00
0.00
0.00
Ca, Si, Fe,
Mn, K, Cl,
S, Ti, Cr,
Zn, Na, Mg,
Al, Cu
(FLt;.D-98)
B-l
0.09
0.12
0.12
1.68
1.00
0.05
0.11
0.00
0.13
4.02
0.06
0.02
0.09
0.56
0.00
0.00
0.01
- 0.02
0.00
0.00
0.00
Ca, Si, ,Fe,K,
Mg, Al, Cl,
Mn, Na, Ti
(Fig.D-99)
B-2
0. 06
0.00
0.07
1.04
1.00
0.08
0. 10
0.00
0.07
3.68
0.05
0.07
0.08
1.05
0.00
0.00
0.05
0.05
0.00
0.00
0.00
Ca, Fe, Si,
Cl, Mn, S,
Cr.Al, K, Na,
Cu, Zn, Ti
-------
TABLE D- 227C
EDAX ELEMENTAL ANALYSIS OF SMALL PARTICLES WHICH WERE TAKEN
FROM SLAG SAMPLES PRODUCED BY AN ELECTRIC ARC FURNACE.
ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-102
and D-103)
E
0.02
0.06
0.15
1.14
1.00
0.13
0.06
0.00
0.11
4.18
0.07
0.21
0.09
0.26
0.00
0.00
0.04
0.06
0.00
0.00
0.00
Ca, Si, Fe,
Cr, Al, K, Mn
Ti, Cu, Mg
(Fig.D-106
and D-107)
F
0.00
0.02
0.07
0.86
1.00
0.10
0.03
0.00
0.10
3.80
0.09
0.26
0.33
1.04
0.00
0.00
0.24
0.19
0.00
0.00
0.00
Ca, Fe, Si, Mn
Cr, Zn, Cu,
S, K
(Fig.D-111)
G
0.10
0.34
4.45
1.15
1.00
0.24
0.33
0.00
0.46
19.76
0.46
0.74
0.72
2.62
0.00
0.00
0.61
0.68
0.00
0.00
0.00
Ca, Al, Fe.Si^
Cr, Mn, Cu,
Zn, Ti, K.Mg,
Cl, S, Na
(Fig.D-111)
H
0.00
0. 32
3.81
1.73
1.00
0.18
0. 15
0.00
0.31
5.20
0.08
0.19
0.26
1.08
0.00
0.00
0.24
0.29
0.00
0.00
0.00
Ca, Al,Si,
Fe, Mg, K, Ci
Mn, Zn, Cr,
S, Cl, Ti
(Fig.D-112)
I
0.00
0.21
0.55
1.26
1.00
0.10
0.01
0.00
0.04
2.27
0.07
0.06
0.05
0.10
0.00
0.00
0.00
0.02
0.00
0.00
0.00
Ca, Si, Al,
Mg, Fe, S,
Ti, Cr, Mn
-------
TABLE D-227D
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
ON THE SMALL PARTICLES WHICH WERE TAKEN FROM SLAG SAMPLES
PRODUCED BY AN ELECTRIC ARC FURNACE. ENTRIES ARE
RATIOS OF INTEGRAL ENERGY PEAKS TO THE
INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-104)
E-l
0.03
0.10
0.38
1.14
1.00
0.18
0.16
0.00
0.25
4.98
0.46
0.21
0.44
0.98
0.00
0.00
0.12
0.23
0.00
0.00
0.00
Ca, Si, Fe.Ti,
Mn, Al, K,.Cu
Cr, S, Cl, Zn,
Mg
(Fig.D-105)
E-2
0.00
0.03
0. 16
0.94
1.00
0.17
0.01
0.00
0.07
2.51
0.07
0.08
0. 13
0.25
0.00
0.00
0. 00
0.04
0.00
0. 00
0.00
Ca, Si, Fe, S,
Al, Mn, Cr, Ti
K, Cu
(Fig.D-108)
F-l
0.00
0.30
0. 58
1.53
1.00
0.28
0.18
0.00
0.28
7.30
0.12
0.30
0. 60
2.89
0.00
0.00
0. 53
0. 67
0. 00
0.00
0.00
Ca, Fe,,Si,
Cu, Mu, Al,
Zn, Mg, Cr, S
K, Cl, Ti
(Fig.D-109)
F-2
0. 15
0.42
0.46
3.02
1.00
0. 14
0.10
0.00
0. 13
4.21
0.09
0. 12
0. 10
0.24
0.00
0.00
0.03
0.03
0.00
0.00
0.00
Ca, Si, Al, Mg
Fe, Na, S, K,
Cr, Mn, Cl.Ti
(Fig.D-110)
F-3
0.05
0.00
0.57
1.67
1.00
0.09
0.01
0.00
0.25
0.77
0.05
0.11
0.10
0.49
0.00
0.00
0.04
0.07
0.00
0.00
0.00
Si, Ca, Al,
Fe, K, Cr,
Mn, S, Cu
-------
TABLE D-228A
EDAX ELEMENTAL ANALYSIS OF LARGE PARTICLES WHICH WERE TAKEN
FROM SLAG SAMPLES PRODUCED BY A BLAST FURNACE.
ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Jig
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig. D-113)
A
0.01
0.2G
0.37
1.67
1.00
0.14
0.08
0.00
0.38
3.20
0.14
0.08
0.11
0.61
0.00
0.00
0.07
0.08
0.00
0.00
0.00
Ca, Si, Fe, K,
Al, Mg, Ti.Mr
Cu, Cr, Cl, Zn
(Fig. D-113)
B
0.02
0.22
0. 11
1.17
1.00
0.13
0. 04
0.00
0.11
1.91
0.07
0.06
0.06
0.35
0. 00
0.00
0.04
0.01
0.00
0.00
0.00
Ca.Si, Fe,
Mg, S.A1, Ti
Cr, Mn
(Fig. D-113)
C
0.05
0.19
0.28
1.29
1.00
0. 19
0.04
0.00
0.21
2.54
0.09
0.04
0.08
0.30
0.00
0.00
0. 03
0. 05
0.00
0.00
0.00
Ca, Si, Fe.Al,
K, Mg,S, Ti,
Mn, Na, Cu
-------
TABLE D-228B
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
ON THE LARGE PARTICLES WHICH WERE TAKEN FROM SLAG SAM-
PLES PRODUCED BY A BLAST FURNACE. ENTRIES ARE
RATIOS OF INTEGRAL ENERGY PEAKS TO THE
INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In R a nls:
Order
Particle
(Fig.D-114)
A-l
0.02
0.07
0.28
0.97
1.00
0.09
0.05
0.00
0.05
1.87
0.02
0.01
0.01
0.11
0.00
0.00
0.01
0.01
0.00
0.00
0.00
Ca, Si, Al, Fe
S, Mg
(Fig.D-114)
A-2
0.01
0.22
0.32
1.80
1.00
0.08
0.04
0.00
0.06
2.36
0.06
0.01
0.02
0.10
0.00
0.00
0.01
0.01
0.00
0.00
0.00
Ca, Si, Al,
Mg, Fe, S
(Fig.D-114)
A-3
0.01
0.02
0.15
2.13
1.00
0.12
0.09
0.00
0.18
6.14
0.07
0.05
0.06
0.33
0.00
0.00
0.04
0.03
0.00
0.00
0.00
Ca, Si, Fe,
K, Al, S, Cl
(Fig. D-114)
A-4
0.00
0.11
0.40
1.18
1.00
0.12
0.01
0.00
0.10
2.78
0.04
0.10
0.05
0.30
0.00
0.00
0.02
0.02
0.00
0.00
0.00
Ca, Si, Al,
Fe, S, Mg,
Cr, K, Mn
(Fig. D-114)
A-5
0.04
0.00
0.27
0.77
1.00
0.08
0.01
0.00
0.20
2.40
0. 14
0.03
0.01
0.28
0.00
0.00
0.02
0.01
0.00
0.00
0.00
Ca, Si, Fe,
Al, K, Ti,
S
-------
TABLE D-229A
EDAX ELEMENTAL ANALYSIS OF LARGE PARTICLES WHICH WERE TAKEN
FROM SLAG SAMPLES PRODUCED BY A BASIC OXYGEN FURNACE.
ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Ranis
Order
Particle
(Fig. D-115)
A
0.10
0.09
0.15
1.25
1.00
0.20
0.07
0.00
0.17
6.19
0.18
0.16
0.24
1.20
0.00
0.00
0.12
0.14
0.00
0.00
0.00
Ca, Si, Fe,Mn,
S, Ti.K, Cr,
Al, Cu, Zn, Mg:
Cl
(Fig. D-115)
B
0.00
0.13
0.07
0.97
1.00
0.09
0.05
0.00
0.05
3.60
0.11
0.09
0.27
0.80
0.00
0.00
0.05
0.04
0.00
0.00
0.00
Ca.Si, Fe, Mn
Mg, Ti, Cr, S,
Al
-------
TABLE D-229B
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
ON THE LARGE PARTICLES WHICH WERE FROM SLAG PRODUCED BY
A BASIC OXYGEN FURNACE. ENTRIES ARE RATIOS OF
INTEGRAL ENERGY PEAKS TO THE INTEGRAL
ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig. D-116)
A-l
0.21
0.45
0.91
7.54
1.00
0.97
0.50
0.00
0.71
29.20
0.38
0.24
0.71
2.38
0.00
0.00
0.16
0.25
0.00
0.00
0.00
Ca.SJjFe.S,
AI.Mn, K, Cl,
Mg, Ti, Cu, Ci
Nu.Zn
(Fig. D-116)
A-2
0.00
0.30
0.29
2.64
1.00
0.36
0.26
0.00
0.41
12.50
0.23
0.23
0.93
2.45
0.00
0.00
0.23
0.23
0.00
0.00
0.00
Ca, Si^Fe,
Mh.K.S, Mg,
Al, Cl,Ti, Cu,
Cr.Zn
(Fig. D-116)
A-3
0.00
0.30
0.77
2.76
1.00
0.37
0.17
0.00
0.34
0.78
0.14
0.08
0.11
0.67
0.00
0.00
0.06
0.09
0.00
0.00
0.00
Sij Ca, AJ.Fe,
S,K,Mg,Cl,
Ti, Mn, Cu, Cr,
Zn
(Fig. D-116)
A-4
0.03
0.02
0.34
1.33
1.00
0.21
0.07
0.00
0.22
3.87
0.09
0.07
0.08
0.51
0.00
0.00
0.01
0.04
0.00
0.00
0.00
Ca, Si, Fe.Al,
K, S, Ti, Mn,
Cr, Cl
(Fig. D-116)
A-5
0.11
0.23
0.36
1.03
1.00
0.23
0. 17
0.00
0.20
10.23
0.69
0. 65
2.34
6.72
0.00
0.00
0.33
0. 31
0.00
0.00
0.00
Ca, Fe, Mn,
Si, Ti, Cr, Al,
Zn, Cu, Mg, S
K, Cl, Na
-------
TABLE D-229B (Continued)
Elements
Na
Mg
Al
Si
An
s
Cl
Cd
K
Cu
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Particle
(Flg.D-116)
A-6
0.00
0.91
0.24
0.58
1.00
0.13
0.05
0.00
0.20
1.94
0.14
0.51
1.87
4.70
0.00
0.00
0.14
0.17
0.00
0.00
0.00
Fe, Ca, Mn,
Mg.Si.Cr.Al,
K, Cu, Zn.Ti,
S
-------
TABLE D-230 THROUGH D-236 - OPTICAL MICROSCOPY ANALYSIS BY
MeCRONE ASSOCIATES
D-51
-------
TABLE D-230
OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
ON FILTER NUMBER 1093225
Location: Brighton Township
Date:
16 August 1976
Component
Percent By Number
Size Range (ym)
Combustion Products
fused ash (glassy spheres)
unfused ash
magnetite spheres
oil soot
coked coal
Total Combustion Products
Minerals
iron oxide
quartz
calcite
Total Minerals
Biological Materials
18
30
2
2
li
83
6
7
_3
16
Not Detected
10-40
20-100
20-40
30-40
20-100
10-100
20-60
10-50
-------
TABLE D-231
OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
ON FILTER NUMBER 1093227
Location:
Midland
Date:
16 August 1976
Component
Percent By Number
Size Range (ym)
Combustion Products
oil soot
unfused ash
fused ash (glassy spheres)
coked coal
Total Combustion Products
Minerals
iron oxide
quartz
calcite
feldspars
Total Minerals
Biological Materials
spores
bark
diatoms
miscellaneous plant tissue
Total Biological Materials
20
10
5
70
5
15
8
trace
28
trace
trace
trace
trace
30-100
30-50
4-12
30-100
10-100
10-50
5-60
50
-------
TABLE D-232
OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
ON FILTER NUMBER 1093205
Location: Duquesne II Date: 16 August 1976
Component
Combustion Products
fused ash (glassy spheres)
unfushed ash
magnetite spheres
coked coal
Total Combustion Products
Minerals
clay
iron oxide
quartz
feldspars
calcite
mica
carborundum
Total Minerals
Biological Materials
starch
pollen
spores
bark
Total Biological Materials
Percent By Number
4
37
1
25_
67
8
5
7
1
3
2
-------
TABLE D- 233
OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
ON FILTER NUMBER 1093209
Location: Liberty Boro Date: 16 August 1976
Component
Combustion Products
coked coal
oil soot
fused ash (glassy spheres)
unfused ash
magnetite spheres
coal (unburned)
Total Combustion Products
Minerals
feldspars
clay
quartz
calcite
iron oxide
Total Minerals
Biological Materials
pollen
spores
miscellaneous plant tissue
Total Biological Materials
Percent By Number
23
13
5
24
<1
_4
70
4
8
4
8
_2
26
<1
trace
<±
<2
Size Range (urn)
10-100
4-40
4-40
20-50
10-40
30-40
10-60
16-30
5-20
3-40
10-20
18-28
-
-
-------
TABLE D-234
OPTICAL MICROSCOPY ANALYSIS BY MeCRONE ASSOCIATES
ON FILTER NUMBER 1093239
Location:
South Fayette
Date:
16 August 1976
Component
Percent By Number
Size Range (urn)
Combustion Products
fused ash (glassy spheres)
unfused ash
magnetite spheres
coked coal
oil soot
Total Combustion Products
Minerals
iron oxide
quartz
calcite
Total Minerals
Biological Materials
2
35
1
11
62
30
5
_2
37
Not Detected
5-20
10-50
30-40
20-90
20-90
10-50
6-15
3-5
-------
TABLE D-235
OPTICAL MICROSCOPY ANALYSIS BY MeCRONE ASSOCIATES
ON FILTER NUMBER 1093284
Location:
Brighton Township
Date: 16 August 1976
Component
Percent By Number
Size Range (ym)
Combustion Products
fused ash (glassy spheres)
unfused ash
coked coal
unburned coal
magnetite spheres
oil soot
Total Combustion Products
Minerals
iron oxide
mica
quartz
feldspars
calcite
Total Minerals
Biological Materials
pollen
spores
bark
miscellaneous plant tissue
Total Biological Materials
28
2
48
4
1
89
trace
8-40
10-50
20-100
20-40
15-20
20-40
5-30
30-80
10-20
40-50
15-20
18-25
18-30
90
-------
TABLE D-236
OPTICAL MICROSCOPY ANALYSIS DONE BY McCRONE ASSOCIATES
ON FILTER NUMBER 1093284
Location:
Brighton Township
Date: August 28, 1976
Component
Percent by Number
Size Range (ym)
Combustion Products
fused ash (glassy spheres)
unfused ash
coked coal
unburned coal
magnetite spheres
oil soot
Total Combustion Products
Minerals
iron oxide
mica
quartz
feldspars
calcite
Total Minerals
Biological Materials
pollen
spores
bark
miscellaneous plant tissue
Total Biological Materials
28
2
48
4
1
89
2
1
2
1
trace
8-40
10-50
20-100
20-40
15-20
20-40
5-30
30-80
10-20
40-50
15-20
18-25
18-30
90
-------
FIGURE D-6 THROUGH D-19 - CUMULATIVE MASS DISTRIBUTIONS FROM THE
OPTICAL AND SEM ANALYSES
D-52
-------
CO
3
oo
c
o
•rl
•H
S-i
CO
•H
a)
N
•H
CO
T3
0)
O
•H
o
•H
I
P
(ujrl)
-------
en
en
cri
en
cri
en
CO
cri
O)
10
cri
CD
en
en
CO
en
IO
en ^
c
0)
O 2
cn »
CO
O CO
CO <
2
O UJ
s§
Si
o
ro
O
CM
O
O
CO
O
O
O
ro
O
CM
O
4J
cn
CO
CN
O
M-l
C
O
•H
4-1
3
.Q
•H
cn
•H
(1)
N
CO
3
cfl
o
•H
oo
o
rH
O
•H
pq
P
w
rt
P
o
(uirt)
-------
0)
•U
ex
CO
CT\
S-i
o
fi
o
•H
•H
Vi
w
•H
01
N
•H
0)
4-1
W
cfl
a
M
o
o
•H
OO
p
w
&
o
-------
ON
rH
r~ 3
S-l
o
W-l
c
o
•H
4J
3
,0
w
•H
0)
N
w
CO
a
CD
O
H
In
-------
O
(X)
o
o
m
o
o
ro
O
CJ
CD
&>.
OS
CD
CD
CD
00
CD
CD
to
CD
CD
CD
CD
CO
CD
lO
CD -^
, c
0)
o e
CO
O CO ^
00 8
in 2
d
o
•H
4J
•H
id
o;
•H
M
o
•—!
I
w
Pi
t3
o
(ujrl)
-------
r>
Ch
0)
4-1
CX
-------
o
o
CM
OO O O O
o en oo r*-
o o
O
ro
O
CJ
c.
a.
CO
CO
_ O LLJ
O
ID
O
T'.'S
O 3
2 §
C n, 01
to £ a
MS
4_1
tfl
0)
M
en
en
to
m
0
en
•H
4J
tO
i-l
3
3
O
C
prese
0)
^
0)
c
•H
1
.
0)
en
to
w
O>
H
.
tfl
4-1
tO
TD
£*%
cx
o
CJ
en
O
Vt
o
•H
B
1 — 1
tO
O
•H
4J
CX
O
01
XI
4-1
A~
en
C
o
•H
3
•H
!-i
4-J
C
O
a
, — |
to
o
•H
O
, — 1
o
•H
•°
01
4J
M
0)
4-1
M-l
tO
C
o
•H
4-1
3
•H
4J
en
•H
-a
en
en
n)
.
en
^
0)
4-1
rH
•H
0)
4-1
O
t-l
-------
o
o
CM
oo o o
O CD 00 N-
o
(£>
o
ID
o
O
ro
O
CO
O
Cfl
I 0)
.H -H 4J
CO i-> rH
U 4-J -H
•H W M-l
4J -H
p. T3 0)
O rC
W 4J
0) W
rTj CO £3
4J e o
M QJ tw
•H ID
4-1 (1)
CO >
•H
!-<
4J
W
3
T3
C
•H
O
•H
4-1
3
•H
M
4-1
en
•H
TD
tn
w
>
•H
4J
ca
3 e
B 0)
3 M
U
OJ Q)
X 0)
4J (t)
c ,c
0)
w q
0) O
(-1 -H
ft 4->
0) 3
0) S-i
•H C
•H O
O
•> 4-1
CXM-,
O cfl
CJ
w c
o o
i-i -H
CJ 4-1
•H 3
6 ^
Q
o
-------
I
w
o
r-l C
O O
•H -H
£ 4-1 •
3 M
rH ,0 J-i
03, -H 0)
O1 r-l 4-1
•H 4-J rH
4-1 U) -H
P. -H M-l
O TD
MH
•H
CO 4-1 T3
0)
3 I
0)
Q)
4-J
•H
t-l CJ
tn
C 4J T3
n)1 C 01
^ 03 0)
•H 4-1 f,
4-1 03 4-1
03 no
rH S-l
3 >^ 0)
6 P. 4J
3 O M-i
U O 03
Q
O
o
3~10lldVd
-------
c
CD
O
i_
OJ
Q.
CO
<
5
LJ
>
<
_J
_|0 O
o
o
CM
oo o o
O en oo h-
(ujri)
O
O
m
o
o
ro
O
c\J
O
co
o
M
o
•H
6
M-l
o
c
o
•H
c
o
•H
4->
3
XI
•H
CO
CD
4-1
4-J rH
CO -H
•H M-l
T3
0)
w ^c
CO 4-1
Cfl
e e
o
0) !-i
> LH
•H
4-J Td
a) a)
iH >
3 o
3 0)
O M
QJ c
j: a)
4-J 0)
^2
CO
4-J T3
C nj
01 ,C
CO
0) C
t-i O
P. -H
0) 4J
>-l 3
rJS
a) -H
C M
•H 4-)
,0
•H
S-i
4-1
CO
•H
CO
W
fO
0)
>
•H
4-1
n)
t—I
3
3
U
O
T3 O
0)
rC I-H
co ca
n) a
T3 -H
&c
cu o
^ rH
H O
•H
&
CO 0)
•U 4=
nj 4-1
13
S-i
>-. a)
CX 4J
O U-l
O Cfl
p
w
C4
p
o
M
En
-------
O
O
CM
oo o o o
O CT) CO Is- (D
o o
o
ro
O
C\J
O
60
O
O
C
0)
tfl
0)
en
en
o
w
•H
3
e
3
U
o
M
-------
o
o
CO
oo o
o en oo
o o
o
LO
o
o
ro
O
C\J
O
-------
o
o
CM
oo o
O CD CO
o
N-
o
CO
o o
o
ro
O
CM
O
-------
o
o
CM
oo o o
O en co f^-
O
to
o
to
o
o
ro
o
CM
- CM
O
OJ
.c
0)
4-J
•H
rH
n)
M
3
S-i
M-i
O
a
o
•H
•U
3
,a
•H
>-l
4-1
tn
•H
-a
en
cfl
e
0)
>
•H
4J
ca
r-t
3
0
a\
•—t
I
O
-------
FIGURES D-20 THROUGH D-116 - PHOTOMICROGRAPHS
D-53
-------
FIGURE D-20: Stub Number 46 which shows a magni-
fied portion of the filter taken from the
Baden Monitor on 8/16/76. (Refer to Table
D-171)
FIGURE D-21: Stub Number 46 which shows a magni-
fied portion of the filter taken from the
Midland Monitor on 8/16/76. (Refer to Table
D-175)
-------
FIGURE D-22: Stub Number 44 which shows a magni-
fied portion of the filter taken from the
Elco monitor on 8/16/76. (Refer to Table
D-177)
-------
HuJTT '"*& *i-'
g^Sfe* ' -SP *" .' „-
FIGURE D-23a: Stub Number 21 which shows a magni-
fied portion of the filter taken from the
Central Lab Monitor on 8/16/76. (Refer to
Table D-179)
FIGURE D-23b: Stub Number 21 which shows a magni-
fied portion of the filter taken from the
Central Lab Monitor on 8/16/76. (Refer to
Table D-179)
-------
FIGURE D-24a: Stub Number 39 which shows a magni-
fied portion of the filter taken from the Hazel-
wood Monitor on 8/16/76. (Refer to Table D-180)
FIGURE D-24b: Stub Number 39 which shows a magni-
fied portion of the filter taken from the Hazel-
wood monitor on 8/16/76. (Refer to Table D-180)
-------
FIGURE D-25: Stub Number 57 which shows a magni-
fied portion of the filter taken from the No.
Braddock Monitor on 8/28/76. (Refer to Table
D-194)
FIGURE D-26: Stub Number 57C which shows a magni-
fied portion of the cover filter taken from
the No. Braddock Monitor on 8/28/76. (Refer
to Table D-195)
-------
FIGURE D-27: Stub Number 60 which shows a magni-
fied portion of the filter taken from the
Liberty Boro Monitor on 8/28/76. (Refer to
Table D-198)
-------
FIGURE D-28a: Stub Number 60C which shows a magni-
fied portion of the cover filter taken from
the Liberty Boro Monitor on 8/28/76. (Refer
to Table D-199)
FIGURE D-28b: Stub Number 60C which shows a magni-
fied portion of the cover filter taken from
the Liberty Boro Monitor on 8/28/76. (Refer
to Table D-199)
-------
FIGURE D-29a: Stub Number 53 which shows a magni-
fied portion of the filter taken from the
Airport Monitor on 9/9/76. (Refer to Table
D-214)
FIGURE D-29b: Stub Number 53 which shows a magni-
fied portion of the filter taken from the
Airport Monitor on 9/9/76. (Refer to Table
D-214)
-------
FIGURE D-30: Stub Number 54 which shows a magni-
fied portion of the filter taken from the
So. Fayette Monitor on 9/9/76. (Refer to
Table D-21b)
-------
FIGURE D-31a: Selected large particles taken from
the Brighton Twp filter which was exposed on
8/10/76. (Refer to Table D-217)
11-17-76
FIGURE D-31b: Se"icted large particles taken from
the Brighton Twp filter which was exposed on
8/10/76. (Refer to Table D-217)
-------
FIGURE D-32: Selected large particles taken from
the Brighton Twp filter which was exposed on
8/10/76. (Refer to Table D-217)
FIGURE D-33: Selected large particles taken from
the Brighton Twp filter which was exposed on
8/10/76. (Refer to Table D-217)
-------
FIGURE D-34: Selected large particles taken from
the Brighton Twp filter which was exposed on
8/10/76. (Refer to Table D-217)
FIGURE D-35: Selected large particles taken from
the Brighton Twp filter which was exposed on
8/10/76. (Refer to Table D-217)
-------
FIGURE D-36: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
FIGURE D-37: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
-------
FIGURE D-38: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
FIGURE D-39: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
-------
FIGURE D-40: Selected large particle taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
FIGURE D-41: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
-------
FIGURE D-42: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
FIGURE D-43: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
-------
FIGURE D-44: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
FIGURE D-45: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
-------
FIGURE D-46: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
FIGURE D-47: Selected large particles taken from
the Brighton Twp cover filter which was ex-
posed on 8/10/76. (Refer to Table D-218)
-------
FIGURE D-48: Selected large particles taken from
the Central Lab filter which was exposed on
8/10/76. (Refer to Table D-219)
-------
FIGURE D-49: Selected large particles taken from
the Central Lab cover filter which was ex-
posed on 8/10/76. (Refer to Table D-220)
FIGURE D-50: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
-------
1100X
H-17-76
FIGURE D-51: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
FIGURE D-52: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
-------
FIGURE D-53: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
FIGURE D-54: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
-------
FIGURE D-55: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
FIGURE D-56: Selected large particles taken from
the Central Lab cover filter which was exposed
on 8/10/76. (Refer to Table D-220)
-------
FIGURE D-57: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
^"N|t_
11-16-76
FIGURE D-58: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
-------
FIGURE D-59: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
FIGURE D-60: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
-------
FIGURE D-61: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
FIGURE D-62: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
-------
FIGURE D-63: Selected large particles taken from
the Duquesne II filter which was exposed on
8/10/76. (Refer to Table D-221)
-------
_,_ c-jfj-'-j
• ! "
FIGURE D-64: Selected large particles taken from
the Duquesne II cover filter which was exposed
on 8/10/76. (Refer to Table D-222)
FIGURE D-65: Selected large particles taken from
the Duquesne II cover filter which was exposed
on 8/10/76. (Refer to Table D-222)
-------
FIGURE D-66: Selected large particles taken from
the Duquesne II cover filter which was exposed
on 8/10/76. (Refer to Table D-222)
FIGURE D-67: Selected large particles taken from
the Duquesne II cover filter which was exposed
on 8/10/76. (Refer to Table D-222)
-------
FIGURE D-68: Selected large particles taken from
the Central Lab filter which was exposed on
8/16/76. (Refer to Table B-223)
FIGURE D-69: Selected large particles taken from
the Central Lab filter which was exposed on
8/16/76. (Refer to Table D-223)
-------
FIGURE D-70: Selected large particles taken from
the Central Lab filter which was exposed on
8/16/76. (Refer to Table D-223)
FIGURE D-71: Selected large particles taken from
the Central Lab filter which was exposed on
8/16/76. (Refer to Table D-223)
-------
FIGURE D-72: Selected large particles taken from
the Central Lab filter which was exposed on
8/16/76. (Refer to Table D-223)
FIGURE D-73: Selected large particles taken from
the Central Lab filter which was exposed on
8/16/76. (Refer to Table D-223)
-------
FIGURE D-74a: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-74b: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-75: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-76: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-77: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-78: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-79: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-80: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-81: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-82: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-83: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-84: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-85: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
FIGURE D-86: Selected large particles taken from
the Brighton Twp filter which was exposed on
9/9/76. (Refer to Table D-224)
-------
FIGURE D-87: Selected large particle Number 1,
(Refer to Table D-226)
FIGURE D-88: Selected large particle Number 2.
(Refer to Table D-226)
-------
FIGURE D-89: Selected large particle Number 3.
(Refer to Table D-226)
FIGURE D-90: Selected large particle Number 4.
(Refer to Table D-226)
-------
FIGURE D-91: Selected large particle Number 5.
(Refer to Table D-226)
-------
FIGURE D-92: Large particle A from an electric
arc furnace slag sample. (Refer to Table
D-227A)
FIGURE D-93: Closeup of large particle A from an
electric arc furnace slag sample. (Refer to
Table D-227A)
-------
FIGURE D-94: Surface particle A-l which had adher-
ed to large particle A from an electric arc
furnace slag sample. (Refer to Figure D-92 and
Table D-227B)
FIGURE D-95: Surface particle A-2 which had adher-
ed to large particle A from an electric arc
furnace slag sample. (Refer to Figure D-92 and
Table D-227B)
-------
FIGURE D-96: Large particle B from an electric
arc furnace slag sample. (Refer to Table
D-227A)
FIGURE D-97: Closeup of large particle B from an
electric arc furnace slag sample. (Refer to
Table D-227A)
-------
^p%fKlppr'™ _J J
FIGURE D-98: Surface particle B-l which had adher-
ed to large particle B from an electric arc
furnace slag sample. (Refer to Figure D-96 and
Table D-227B)
FIGURE D-99: Surface particle B-2 which had adher-
ed to large particle B from an electric arc
furnace slag sample. (Refer to Figure D-96
and Table D-227B)
-------
FIGURE D-100: Large particle C from an electric
arc furnace slag sample. (Refer to Table
D-227A)
FIGURE D-101: Large particle D from an electric
arc furnace slag sample. (Refer to Table
D-227A)
-------
FIGURE D-102: Small particle E from an electric
arc furnace slag sample (Refer to Table
D-227C)
FIGURE D-103: Closeup of small particle E from an
electric arc furnace slag sample. (Refer to
Table D-227C)
-------
FIGURE D-104: Surface particle E-l which had
adhered to large particle E from an electric
arc furnace slag sample. (Refer to Figure
D-102 and Table D-227D)
FIGURE D-105: Surface particle E-2 which had
adhered to large particle E from an electric
arc furnace slag sample. (Refer to Figure
D-102 and Table D-227D)
-------
FIGURE D-106: Small particle F from an electric
arc furnace slag sample. (Refer to Table
D-227C)
isajtow ' ™
"iP%
FIGURE D-107: Closeup of small particle F from
an electric arc furnace slag sample. (Refer
to Table D-227C)
-------
FIGURE D-108: Surface particle F-l which had
adhered to large particle F from an electric
arc furnace slag sample. (Refer to Figure
D-106 and Table D-227D)
FIGURE D-109: Surface particle F-2 which had
adhered to large particle F from an electric
arc furnace slag sample. (Refer to Figure
D-106 and Table D-227D)
-------
FIGURE D-110: Surface particle F-3 which had
adhered to large particle F from an electric
arc furnace slag sample. (Refer to Figure
D-106 and Table D-227D)
-------
FIGURE D-lll: Small particles G and H from an
electric arc furnace slag sample. (Refer to
Table D-227C)
FIGURE D-112: Small particle I from an electric
arc furnace slag sample. (Refer to Table
D-227C)
-------
FIGURE D-113: Large particles A, B and C from a
blast furnace slag sample. (Refer to Table
D-228A)
FIGURE D-114: Surface particles A-l, A-2, A-3,
A-4 and A-5 which had adhered to large parti-
cle A from a blast furnace slag sample. (Refer
to Table D-228B)
-------
FIGURE D-115: Large particles A and B from a basic
oxygen furnace slag sample. (Refer to Table
D-229A)
jjl ,.
?M 80S SA 910X
09-20-7?
FIGURE D-116: Surface particles A-l, A-2, A-3,
A-4, A-5 and A-6 which had adhered to large
particle A from a basic oxygen furnace slag
sample. (Refer to Table D-229B)
------- |