903R81006
 U.S. EPA Region III
Regional Center for Environmental
  Information
1650 Arch Street (3PM52)
Philadelphia^ 10103
 ASSESSMENT AND UPDATING OF PARTICULATE EMISSIONS DATA
     FOR THE SOUTHWEST PENNSYLVANIA INTRASTATE AIR
               QUALITY CONTROL REGION

                      VOLUME  II

                     APPENDIX D
     DETAILS OF THE HI-VOL FILTER ANALYSIS PROGRAM
    H. E. Cramer, H.  V.  Geary and S".  F.  Saterlie
                    Prepared  for

        U.  S. ENVIRONMENTAL PROTECTION AGENCY
                     Region III
           Philadelphia,  Pennsylvania  19106
               Contract No.  68-02-1387
                   Task Order No. 3
       H. E.  Cramer company, inc.
         UNIVERSITY OF UTAH RESEARCH PARK
               POST OFFICE BOX 8049
             SALT LAKE CITY, UTAH 84108

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 U.S. EPA Region III
 Regional Center for Environmental
   Information
 1650 Arch Street (3PM52)
 Philadelphia, PA 19103
903R81006
                                                TR-81-104-01
                                                January 1981
ASSESSMENT AND UPDATING  OF PARTICULATE EMISSIONS DATA
    FOR THE SOUTHWEST  PENNSYLVANIA INTRASTATE AIR
               QUALITY CONTROL REGION

                      VOLUME II

                    APPENDIX D
    DETAILS OF THE HI-VOL FILTER ANALYSIS PROGRAM
   H.  E.  Cramer, H. V. Geary and S. F. Sarerlie
                    Prepared  for

       U. S.  ENVIRONMENTAL  PROTECTION AGENCY
                     Region III
          Philadelphia,  Pennsylvania  19106
               Contract  No.  68-02-1387
                   Task  Order  No. 3
                                                 Regional ( enter for HiMronmenMI Infnrnwtion
                                                       US H'A Region III
                                                        1650 Arch St
                                                      Philadelphia. PA 1910^
      H. G. Cramer company, inc.
         UNIVERSITY OF UTAH RESEARCH PARK
               POST OFFICE BOX 8049
             SALT LAKE  CITY, UTAH 84108

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                             TABLE OF CONTENTS
                                VOLUME II

Appendix                           Title                               Page
                  LIST OF TABLES                                       iii
                  LIST OF FIGURES                                       v
   D              ADDITIONAL DETAILS OF THE HI-VOL FILTER
                  ANALYSIS PROGRAM                                     D-l
                  D.I   Description of the Sampler Locations           D-l
                  D.2   Meteorological Conditions on
                        Sampling Days                                  D-14
                  D.3   Observer's Log for The Sampling Days           D-26
                  D.4   Filter Analysis Results                        D-39

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                              TABLE OF CONTENTS

                                 VOLUME I
Section
                 Title
Page
   1

   2
ACKNOWLEDGEMENTS

EXECUTIVE SUMMARY

INTRODUCTION

DESCRIPTION OF THE PHASE II PARTICULATE
SAMPLING PROGRAM

EMISSIONS FROM INDUSTRIAL SOURCES AND
SOURCE COMPLEXES

RESULTS OF THE OPTICAL AND SEM/EDAX
ANALYSES OF THE HI-VOL FILTER SAMPLES

REVISION OF THE PHASE I EMISSIONS
INVENTORY

RESULTS OF THE PHASE II DIFFUSION MODEL
CALCULATION FOR PARTICULATE EMISSIONS FROM
INDUSTRIAL SOURCES

COMPARISON OF CALCULATED AND OBSERVED
PARTICULATE CONCENTRATIONS

REFERENCES
   i

  ii

 1-1


 2-1


 3-1


 4-1


 5-1



 6-1


 7-1

 8-1
Appendix

   A


   R
MATHEMATICAL MODELS USED TO CALCULATE
GROUND-LEVEL CONCENTRATIONS

SEASONAL AND ANNUAL FREQUENCY DISTRIBUTIONS
OF WIND SPEED AND WIND DIRECTION

INDUSTRIAL PARTICULATE EMISSIONS INVENTORY
 A-l


 B-l

 C-l
                                      11

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                              LIST OF TABLES
Table
Number

 D-l

 D-2
through
 D-8

 D-8
 D-9
 D-10
through
 D-15

 D-16
through
 D-88
                 Title

List of Hi-Vol Monitoring Sites

Hourly Surface Weather Observations at the
Greater Pittsburgh Airport on the Sample
Days

Mean Wind Speed and Precipitation Data
for Sample Days

Mixing Depths and Potential Temperature
Gradients Measured at the Greater Pitts-
burgh Airport before, during and after
Sample Days


Observer's Logs for the Sample Days
Results of Optical Particle Counts
 Page

 D-2

 D-15
through
 D-20


 D-21
 D-22

 D-27
through
 D-38
 D-44
 D-89
through
 D-167

 D-l 68
through
 D-170

 D-171
through
 D-216
Results of SEM Particle Counts
Summary of EDAX Elemental Analysis
Particle Analysis of Selected Filters
 D-45
 D-46
 D-47
 D-217
through
 D-224
Analysis of Selected Large Particles
 D-48
 D-225
  and
 D-226
EDAX Elemental Analysis of Five Selected
Large Particles
 D-49
                                    iii

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                       LIST OF TABLES (Continued)
Table
Number

D-227A
through
D-229B
                 Title
EDAX Elemental Analysis of Large Sla|
Particles
D-50
D-230
through
D-236
Optical Microscopy Analysis by McCrone
Associates
D-51
                                    IV

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                              LIST OF FIGURES
Figure
Number

  D-l

  D-2
 through
  D-5

  D-6
 through
  D-19
                 Title

Locations of hi-vol monitoring sites.


Topographic maps of the areas surrounding
the monitoring sites.
Cumulative Mass Distributions from the
Optical and SEM Analyses
   Page

  D-3

  D-5
through
  D-8


  D-52
  D-20
 through
  D-30
SEM Photographs of Selected Filters
  D-53
  D-31
 through
  D-86
Photomicrographs of Selected Large Particles
Found on Hi-Vol Filter Samples
  D-54
  D-87
 through
  D-91
Photomicrographs of Five Very Large Particles
Found on Hi-Vol Filter Samples
  D-55
  D-92
 through
  D-101
  D-102
 through
  D-112
  D-113
   and
  D-114
Photomicrographs of Large Particles Contained
in Slag Samples from Electric Arc Furnaces
and of Smaller Particles found on the Surface
of these Particles

Photomicrographs of Small Particles Contained
in Slag Samples from Electric Arc Furnaces
and of Smaller Particles Found on the Surface
of these Particles

Photomicrographs of Large Particles Contained
in Slag Samples from Blast Furnaces and of
Smaller Particles Found on the Surface of
these Particles
                                                                       D-56
                                                                       D-57
                                                                       D-58
  D-115
   and
  D-116
Photomicrographs of Large Particles Contained
in Slag Samples from Basic Oxygen Furnaces and
of Smaller Particles Found on the Surface of
these Particles
                                                                       D-59
                                      v

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                              APPENDIX D
       ADDITIONAL DETAILS OF THE HI-VOL FILTER ANALYSIS PROGRAM

D.I  DESCRIPTION OF THE SAMPLER LOCATIONS

     The fifteen hi-vol monitoring sites selected for the particulate
sampling program are listed in Table D-l.  The locations of the moni-
toring sites are shown in Figure D-l.  The site selection was made
jointly by the H. E. Cramer Company and the EPA Project Officer after
consultation with the Pennsylvania DER and the Allegheny County BAPC.
The criteria used in site selection included,  in addition to logistical
factors, the need for obtaining particulate samples representative of
industrial, urban, suburban and rural areas.  The only sites con-
sidered were those currently operated by DER and BAPC as part of
their regular monitoring programs for which a minimum of several years'
records of particulate measurements are available.   Logistical factors
included:

     •    Availability of electrical power required to operate two
          hi-vols simultaneously (one hi-vol was required for the
          regular DER or BAPC filter sample and a second hi-vol was used
          for the special sampling program)

     •    The requirement that each site be accessible to operating
          personnel and observers on a 24-hour basis

     •    Availability of meteorological observations (the COPAMS and TM
          monitoring sites in Table D-l have meteorological measurement
          capabilities)

     •    The requirement that the sites be grouped geographically so
          that all monitors could be serviced and periodic activity
          observations could be made at each site during each 24-hour
          sampling period
                                 D-l

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                                    TABLE D-l

                      LIST OF HI-VOL MONITORING SITES
Site Number
I
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Name
Baden (COPAMS)*
Beaver Falls (COPAMS)*
Koppel
Brighton Township
Midland
Elco
Downtown
Central Lab
Hazelwood**
North Braddock (TM)***
Duquesne II
Liberty Boro (TM)***
Clairton
Greater Pittsburgh Airport
South Fayette
Agency
DER
DER
DER
DER
DER
DER
BACP
BACP
BACP
BACP
BACP
BACP
BACP
BACP
BACP
Classification
Industrial
Suburban
Industrial
Suburban
Industrial
Rural
Urban
Urban
Industrial
Industrial
Industrial
Industrial
Industrial
Rural
Rural
  *COPAMS  -  Commonwealth of Pennsylvania Air Monitoring System (DER telemetered
               data site)

 **Hazelwood T, a TM site, is located approximately 0. 5 kilometers south of the selec- .
   ted Hazelwood hi-vol site.

***TM  -  Allegheny County Bureau of Air Pollution telemetered site
                                      D-2

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LAWRENCE CO.
                 BUTLER CO
                                ARMSTRONG CO.
                                               INDIANA CO
BEAVER CO.
        ALLEGHENY CO.
            ©15
                                 WESTMORELAND  CO.
  WASHINGTON CO.
                        FAYETTE CO.
   GREENE CO.
50 5 10 15 20 KILOMETERS
FIGURE D-l.  Locations of hi-vol monitoring sites.  The numbers refer
           to site names and other details given in Table D-l.
                              D-3

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The site classifications given in Table D-l are admittedly qualitative
and are intended principally to serve as a basis for grouping the monitor
locations according to the proximity of major industrial sources, popula-
tion density and traffic density.

     Figures D-2 through D-5 present 2-kilometer by 2-kilometer topographic
maps showing the major roads, railroads and buildings in the areas surround-
ing the individual monitoring sites.  The location of the monitor is shown
by the  ®  symbol at the center of each map.  Terrain elevations in
Figures D-2 through D-5 are in feet above mean sea level, and the contour
interval is 100 feet (30.5 meters).  A brief description of each monitor
site is given below.

                     Site No. 1 - Baden (PER, COPAMS)

     The Baden monitor is located on the north side of the Ohio River,
immediately adjacent to the Ohio River Boulevard, on a slight rise approxi-
mately 6 meters above the level of the Boulevard.  Vehicle traffic compris-
ing passenger cards and trucks is typically moderate-to-heavy.   Directly
across the Ohio River Boulevard from the monitor site there are multiple
railroad tracks leading to a switching yard complex and railroad car
humping stations.  Rail traffic is typically heavy and at low speed with
much idle operation of the diesel svitching engines.  The Jones and Laughlin
(J&L) Aliquippa Works is located on the south side of the Ohio River directly
west of the Baden monitor site.  Heavy particulate emissions are associated
with the operation of the coke ovens and the new EOF shop which are the
facilities closest to the monitor.

                 Site No. 2  - B,eayer Falls (PER, COPAMS)

     The Beaver Falls monitor is located near ground level immediately
adjacent to a hard-packed earth parking lot and loading area for an
industrial warehouse.  Observations during the study showed that diesel
                                   D-4

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        SITE NO I  BADEN
  SITE NO. 2  BEAVER FALLS
        SITE NO 3 KOPPEL
SITE NO 4  BRIGHTON TOWNSHIP
FIGURE D-2.  Topographic maps of the areas  surrounding the Baden,  Beaver
             Falls,  Koppel and Brighton  Township monitoring sites.
                                   D-5

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        SITE NO. 5  MIDLAND
   SITE NO. 6 ELCO
        SITE NO 7  DOWNTOWN
SITE NO 8  CENTRAL LAB
FIGURE D-3.  Topographic maps of the areas surrounding the Midland, Elco,
             Downtown  and Central Lab monitoring  sites.
                                   D-6

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       SITE NO 9 HAZELWOOD
SITE NO. 10 NORTH BRADDOCK
       SITE NO II  DUQUESNE
SITE NO 12 LIBERTY BOROUGH
FIGURE D-4.  Topographic maps of the areas  surrounding the Hazelwood,  North
             Braddock,  Duquesne II and Liberty Borough monitoring  sites.
                                  D-7

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       SITE NO. 13 CLAIRTON
SITE NO 14 GREATER PITTSBURGH AIRPORT
     SITE NO. 15 SOUTH FAYETTE
FIGURE D-5.   Topographic maps of  the  areas surrounding  the  Clairton,
              Greater Pittsburgh Airport and South Fayette monitoring
              sites.
                                   D-8

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tractor-trailer traffic was continuous during the five-day work week and
daylight hours.  Only one loading dock was observed to be in use, and
only one truck was in the yard at any one time.   Trucks usually did not
idle during loading operations.  There is a railroad track on the far
side of the loading yard.. During,each observation period, at least one
diesel train passed by at slow speed, suggesting fairly continuous rail
traffic.  Except for the truck-loading and rail operations, the area
surrounding the monitor appears to be typical of a suburban community.
                       Site No.  3 - Koppel (PER)

     The Koppel monitor is on the roof of the municipal fire station,
approximately 10 meters above street level.   The  Babcock and Wilcox
(B & W) Koppel Plant is located approximately 0.5'kilometers east of the
monitor.  On Pennsylvania Route 351, used by diesel trucks hauling scrap
to and products from the B & W Plant,  the bumping of the trucks as they
cross the tracks produces visible dust clouds.  During the observation
periods, the use of torches to cut the scrap was  frequently noticed at
the B & W Plant.  According to the technician servicing the DER hi-vol
at the Koppel site, this is a common occurrence.   A small charcoal grill
was noted on the roof of the fire station about 7 meters north of the
hi-vol sampler.   There was no evidence that the  grill was used during
any of the sampling days.
                 Site No. 4 -Brighton Township (PER)

     The Brighton Township monitor site is in a grass field adjacent to
the overflow parking lot for the Beaver County Hospital.  The parking
lot was vacant at the times the observers visited the site.  The only partic-
ulate emissions noted'were infrequent'visible plumes .from a 'small hospital
incinerator stack located 200 meters north and 30 meters above the
sampler.
                                 D-9

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                         Site No. 5 - Midland (PER)

     The Midland hi-vol monitor is at an elevation of approximately 10
meters above street level on the roof of the Midland Post Office, which is
directly across Midland's main downtown street (Pennsylvania Route 68)
from the Crucible Steel Plant complex.  While stack and fugitive emissions
from Crucible Steel were dominant, the monitor was also impacted by
emissions from heavy vehicle traffic on all days of the week except
Sunday.  The most noticeable emissions from Crucible Steel typically
were from the vicinity of the strip mill and scarfer with south winds.
All of the monitoring equipment as well as the roof of the building on
which the monitor was located were coated with a rust-colored dust that
appeared to adhere to the surfaces.
                           Site No. 6 - Elco (DER)
     The Elco monitor is located on a hillside lawn of a private resi-
dence on Washington County Route 88 overlooking the Monongahela River,
which is about 100 meters below the elevation of the monitor.  Light
vehicle traffic was observed on Route 88 on all sample days.

                        Site No. 7 - Downtown (BAPC)

     The Downtown monitor is on the roof of the multistory County Office
Building located in downtown Pittsburgh at an elevation of approximately
30 meters above ground level.  Heavy car and truck traffic moving at slow
speeds or idling was observed on all days except Sunday when the traffic
was light.  The industrial source complex most likely to affect this
sampler is the Jones and Laughlin integrated steel plant located about 3
kilometers to the east.
                                    D-10

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                    Site No. 8 - Central Lab (BAPC)

     The Central Lab monitor is located on a roof approximately 15
meters above ground level in the Oakland section of Pittsburgh.  The
traffic patterns are similar to those at the downtown monitor site.
The Jones and Laughlin plant is only 1 kilometer from this monitor,
and odors from the plant were frequently noted during the visits to
the monitor.
                     Site No. 9 - Hazelwood (BAPC)
     The Hazelwood monitor is located on the roof of an apartment
building, approximately 15 meters above street level, on the main
thoroughfare of the Hazelwood district.  The hi-vol is abut 500 meters
south of the ACBAPC Hazelwood TM station and 200 meters east of the
newest Jones and Laughlin coke batteries.   Coking process emissions were
typically present during observations, as  were emissions from the trucks
and cars on the heavily-traveled street below the monitor.  Traffic
patterns were typically heavy and slow moving on all days except Sunday.
                  Site No. 10 - North Braddock (BAPC)

     The North Braddock monitor is situated on the roof of the North
Braddock municipal building complex, approximately 5 meters above the
level of the parking lot.  It is some distance away from the heaviest
downtown Braddock vehicle traffic, but is only 1 kilometer northwest of
the United States Steel Edgar Thompson Plant.
                                 D-ll

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                   Site No. 11 - Duquesne II (BAPC)

     The Duquesne II monitor is located on the roof of a shopping center
building, 5 meters above the level of the parking lot.  Vehicle
traffic in the lot consists principally of passenger cars.  Allegheny
County Route 837, the main riverside thoroughfare,  is 100 meters to the
east.  The United States Steel Duquesne Plant is located directly across
Route 837.  Vehicle traffic in the shopping center and along the county
route was heavy on all days except Sunday.  Visible stack or fugitive
emissions from the Duquesne Plant were generally not prominent.
                   Site No. 12 - Liberty Boro (BAPC)

     The Liberty Boro monitor is located on a school roof approximately
10 meters above the ground.  The school is 2.5 kilometers north-northeast
of the United States Steel Clairton Works at a terrain elevation approxi-
mately 150 meters above the terrain elevation of the coke works.  The
school was in session only on the last sampling day and vehicle traffic
was very light.  Odors were typically present at the site and emissions
from the Clairton Works were generally visible below the hills to the
south-southeast.
                     Site No. 13 - Clairton (BAPC)
     The Clairton monitor is mounted on the roof of the Clairton water
treatment plant, approximately 10 meters above ground level, and only
300 meters southwest of the nearest coke battery of the United States
Steel Clairton Works.  Typical activity near the monitor included
diesel truck traffic hauling slag to a nearby dump and heavy vehicle
traffic on County Route 837, 100 meters to the northeast.

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               Site No. 14 - Greater Pittsburgh Airport

     The Greater Pittsburgh Airport monitor is located on the airport
terminal roof, approximately 20 meters above the ramp and loading areas.
In addition to the aircraft operations, there was heavy vehicle traffic
along the roadway leading to the airport and in the airport parking lots.
                  Site No. 15 - South Fayette (BAPC)

     The South Fayette monitor is located on the roof of the South
Fayette Township High School, approximately 10 meters above ground
level.  Vehicle traffic was very light except on the last sampling day
which coincided with the opening of school.
                                 D-13

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D.2       METEOROLOGICAL CONDITIONS ON SAMPLING DAYS

     Tables D-2 through D-7 give the hourly observations of wind speed,
wind direction, ambient air temperature, Pasquill stability category
(following the Turner (1964) definitions of the Pasquill stability cate-
gories) and "weather" at the Greater Pittsburgh Airport on the six sampling
days (10, 16, 22 and 28 August 1976; 3 and 9 September 1976).   The term
"weather" is used to refer to observations of fog, haze, smoke and pre-
cipitation; the absence of an entry in the'"weather" column for a given
hour indicates that none of these conditions was  reported.  Table D-8  gives
the 24-hour average wind speeds and precipitation data for the sampling days,
and Table D-9  Lists the mixing depths and vertical potential  temperature
gradients obtained  from the twice-daily upper-air soundings made at the
Greater Pittsburgh Airport before,  during and after each sampling day.   The
mixing depths  in Table D-9 were estimated using the procedures outlined in
Section 3.3 of Cramer, e_t^ al_.  (1975); the potential temperature gradients
are the average values for the surface mixing  layer.  Meteorological con-
ditions on  the individual sampling  days are  discussed below.
                             10 August  1976

     A  slow-moving surface high pressure system passed over the Pittsburgh
 area during  the  period  9-11 August 1976.  Early morning ground  fog cleared
 at  the  Greater Pittsburgh Airport by about 1200 EST on 10 August  1976, but  .
 broken  middle clouds remained until about 1700 EST.  Light-to-moderate
 northwest winds  persisted throughout most of the day, with the wind be-
 coming  calm  after about  2100 EST.  Rawinsonde data for the Greater Pitts-
 burgh Airport show relatively deep mixing depths at 0700 and  1900 EST, with
 a slightly stable potential  temperature gradient at 0700 EST  and  an adia-
 batic potential  temperature  gradient at 1900 EST.  However, the 0700 EST
 sounding on  11 August  1976 shows that, with clear skies, a strong surface-
 based inversion  formed  during the night of 10 - 11 August 1976.
                                 D-14

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                               TABLE D-2

                 HOURLY SURFACE WEATH ER OBSERVATIONS
                     AT THE GREATER PITTSBURGH
                      AIRPORT ON 10 AUGUST 1970
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(cleg)
330
300
330
300
250
280
300
320
320
330
330
030
320
330
330
320
340
330
300
220
Calm
Calm
Calm
Calm
Wind
Speed
(m/sec)
3. Oi)
3. 09
3. 09
2. 06
2. 06
2. 06
2.57
3. 09
3.60
4. 12
5. 14
2.57
4. 12
3. 09
1.54
2.57
3. 09
2. 06
2.57
1.54
0.00
0. 00
0.00
0.00
Ambient Air
Temperature'*
(°K)
288 (59)
288 (59)
288 (59)
288 (59)
288 (59)
288 (59)
288 (58)
289 (61)
290 (63)
291 (65)
294 (69)
295 (72)
296 (73)
297 (75)
297 (75)
297 (75)
297 (75)
297 (75)
296 (73)
294 (69)
291 (64)
290 (63)
290 (62)
289 (60)
"Weather"
Ground fog
Ground fog
Ground log
Ground fog
Ground fog
Ground fog
Ground fog
Ground fog
Fog-
Fog
Fog













Pasquill Stability
Category
E
D
E
E
D
D
D
D
U
D
D
D
D
D
C
D
C
D
E
E
E
E
E
E
*Temperatures in degrees Fahrenheit are enclosed by parentheses.
                                  D-15

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                           TABLE D-3

             HOURLY SURFACE WEATHER OBSERVATIONS
                  AT THE GREATER PITTSBURGH
                   AIRPORT ON 10AUGUST
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(deg)
310
310
320
350
280
280
310
010
010
3 GO
350
350
340
320
340
340
340
340
340
340
300
350
010
350
Wind
Speed
(m/sec)
2. 06
2. Of5
2. 57
2. 06
2.06
2.06
2. OG
3. 09
3.09
3.60
4.63
5.66
5.14
5. 14
6. 17
4. 12
5. 14
4.12
4. 12
5. 14
4.12
2. 06
1 . 5 \
2.57
Ambient Air
Temperature*
(°K)
286 (56)
285 (54)
285 (53)
285 (54)
285 (53)
284 (51)
285 (53)
288 (58)
289 (61)
291 (61)
292 (66)
293 (67)
293 (68)
293 (68)
294 (69)
294 (69)
291 (69)
293 (68)
292 (66)
290 (62)
289 (60)
287 (57)
286 (55)
286 (55)
"Weather"




Fos,
Fog
FOR
Haze
















Pasquill Stability
Category
E
E
E
E
E
D
C
C
13
B
D
D
I)
D
D
U
D
D
E
E
E
E
E
E
^Temperatures in degrees Fahrenheit are enclosed by parentheses.
                              D-16

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                               TAHU-: D-4

               HOURLY SURFACE WEATHER OBSERVATIONS
                     AT THE GREATER PFTTSFHJRGII
                      AIRPORT ON 22 AUGUST 1976
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(deg)
Calm
Calm
Calm
320
Calm
Calm
Calm
140
180
130
360
320
320
360
360
260
280
320
310
320
300
270
310
Calm
Wind
Speed
(m/sec)
0.00
0. 00
0.00
1.54
0.00
0.00
0. 00
1.54
1.54
1.54
1.54
4. 12
2. 57
2.57
2.57
4. 63
4.12
4.12
2.57
3. 09
2.06
1.51
2. 06
0. 00
Ambient Air
Temperature *
(°K)
288 (58)
287 (57)
286 (55)
286 (55)
286 (55)
285 (51)
286 (56)
290 (62)
293 (68)
296 (73)
298 (77)
299 (78)
300 (80)
300 (81)
300 (81)
300 (81)
300 (81)
300 (80)
298 (77)
296 (73)
294 (70)
291 (65)
291 (64)
290 (62)
"Weather"
'laze £ Smoke
Haze fr Smoke
laze £ Smoke
:Iaze £ Smoke
la/c £ Smoke
Haze & Smoke
:Iaze & Smoke
flaze £ Smoke
Haze £ Smoke







Haze
Haze
Flaze
Haze
Haze
Haze
IF a 7,0
Haze
Pasquill Stability
Category
E
E
E
E
E
C
B
B
B
B
B
B
B
B
B
C
C
D
E
E
E
E
E
E
*Temperatures in degrees Fahrenheit arc enclosed by parentheses.
                                 D-17

-------
                              TABLE D-5

              HOURLY SURFACE WEATHER OBSERVATIONS
                    AT THE GREATER PITTSBURGH
                      AIRPORT ON 28 AUGUST 1976
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(deg)
200
230
220
170
160
240
200
200
200
170
200
170
200
220
210
230
220
190
220
230
210
210
270
300
Wind
Speed
(m/sec)
2.57
2.57
2.06
1.54
2. 06
2.57
3.09
2.57
2.57
2.57
3.60
4.12
4.63
6. 69
6.17
5. 14
5. 66
4.12
5. 14
1.63
4. 12
4.12
3. GO
3.60
Ambient Air
Temperature*
(°K)
292 (66)
292 (66)
292 (66)
290 (63)
290 (63)
291 (65)
291 (65)
291 (65)
293 (67)
294 (69)
295 (71)
295 (71)
297 (75)
298 (77)
299 (79)
299 (79)
298 (76)
296 (74)
296 (73)
295 (72)
294 (70)
294 (70)
29 1 (70)
294 (69)
"Weather"
Haze
Haze
Haze
Ground fog
Fog
Fog-
Fog
Fog-
Fog
Haze
Haze
Haze
Haze
Haze
Haze
Haze
Haze
Haze
I faze
1 1 a ze
Light Shower;
Haze
[laze
1 1 a/o

Pasquill Stability
Category
E
E
E
E
D
I)
D
D
D
D
D
D
D
I)
D
D
D
D
D
D
D
D
D
D
*Temperatures in degrees Fahrenheit are enelosed by parentheses.
                                 D-18

-------
                              TABU-; D-6

          HOURLY SURFACE WEATHER OBSERVATIONS AT THE
                  GREATER PITTSBURGH AIHPORT ON
                          3 SEPTEMBER 197(5
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Wind
Direction
(cleg)
Calm
Calm
Calm
040
Calm
Calm
130
080
090
190
150
150
160
130
190
170
180
210
200
1GO
200
160
140
150
Wind
Speed
(m/sec)
0. 00
0. 00
0.00
2. 06
0. 00
0.00
2.06
2. 06
2. 06
2. 06
2. 06
3.60
3. GO
4.12
5. 14
4.12
4.63
3. 09
2. 57
2.57
2. 06
1.5-1
1 . 54
1.51
Ambient Air
Temperature*
(°K)
284 (51)
283 (50)
282 (48)
281 (47)
280 (45)
280 (44)
280 (45)
282 (48)
283 (50)
288 (58)
291 (65)
293 (68)
294 (74)
295 (72)
296 (74)
296 (74)
296 (74)
295 (72)
293 (67)
290 (63)
289 (61)
288 (59)
288 (58)
288 (59)
"Weather"

Ground fog'
Fog
Dense fog
Dense fog
Dense fog
Dense fog
Dense fog
Fog









Haze
Haze
Ha 7.c
II a/A1
Haze
Ilaz.o
Pasquill Stability
Category
E
E
D
D
D
D
D
D
D
B
B
B
B
C
C
C
C
D
E
E
E
E
E
E
*Temperatures in degrees Fahrenheit arc enclosed bv parentheses.
                                D-19

-------
                               TABLE D-7

          HOURLY SURF AC1!-: WEATHER OBSERVATIONS AT THE
                   GREATER PITTSBURGH AIRPORT ON
                           9 SEPTEMBER 1976
Time
(EST)
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000

2100
2200
2300

2400
Wind
Direction
(dog)
Calm
Calm
Calm
Calm
Calm
150
Calm
180
220
230
240
200
220
230
230
210
220
230
190
210

230
190
190

300
Wind
Speed
(m/see)
0. 00
0. 00
0. 00
0.00
0.00
1.54
0.00
2.06
4.12
5. 14
4. 63
5.14
6. G9
6. 17
5.G6
7. 72
•LI 2
4. 12
3.09
3.09

3. 09
4. 12
5. 66

10.29
Ainbient Air
Temperature*
289 (61)
289 (60)
288 (59)
287 (57)
286 (56)
286 (55)
286 (56)
289 (61)
295 (71)
297 (75)
298 (77)
300 (81)
300 (81)
301 (82)
301 (82)
300 (81)
299 (79)
298 (76)
296 (74)
295 (72)

294 (69)
292 (66)
291 (65)

291 (64)
"We at her"





Haze
Haze
Haze
Haze
Haze
Haze
Haze .
Haze
Haze
Haze
Haze
Haze
Haze
Light Showers,
Haze
Haze
Light Showers,
O '
Haze
Light Showers,
Haze
Light Showers,
Fog
Light Showers,
o
Fog
Pasquill Stability
Category
E
E
E
E
E
C
C
C
C
C
C
C
D
D
C
D
D
D
D
E

D
D
D

D
*Temperatures in degrees Fahrenheit are enelosed by parentheses.
                                 D-20

-------
                         TABLE D-8
           MEAN WIND SPEED AND PRECIPITATION
                  DATA FOR SAMPLE DAYS
Sample Date
10 August 197G
16 August 1976
22 August 197G
28 August 1976
3 September 1976
9 September 1976
Mean Wind Speed
(m/sec)
2.4
3.5
1.8
3.7
2.2
3.6
Precipitation (inches)
Sample Day
0.00
0. 00
0. 00
Trace
0. 00
0.28
Prior Day
NA*
0.48
0.00
Trace
0.00
0. 00
*NA  = not available.
                           D-21

-------
                              TAB Li; D-9

            MIXING DEPTHS AND POTENTIAL TEMPERATURE
               GRADIENTS MEASURED AT THE GREATER
                   PITTSBURGH AIRPORT BEFORE,
                         DURING AND AFTER
                            SAMPLE DAYS
Date
9 August 197G
10 August 1976
10 August 197G
11 August 197G
15 August 1976
16 August 1976
16 August 1976
17 August 1976
21 August 1976
22 August 1976
22 August 1976
23 August 1976
27 August 1976
28 August 1976
28 August 1976
29 August 1976
2 September 1976
3 September 1976
3 September 1976
4 September 1976
8 September 1976
9 September 1976
9 September 1976
10 September 1976
Time (EST)
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
1900
0700
Mixing Depth (m)
NA*
660
1450
125
1150
125
1500
125
1160
125
1100
125
>3000
340
700
1540
1650
200
980
125
1170
125
1250
1500
Potential Temperature
Gradient (°K/m)
NA*
0.004
0.000
0.059
0. 000
0.024
0. 000
0.058
0.001
0.069
0.002
0. 040
0.001
0. 006
0. 001
0.005
0.001
0. 009
0. 000
0.021
0.001
0. 056
0.000
0.004
*NA  - not available.
                                D-22

-------
                            16 August 1976

     A weak frontal system passed over the Pittsburgh area on the morning
of 15 August 1976, with 12.2 millimeters (0.48 inches) of precipitation
recorded at the Greater Pittsburgh Airport for the 24-hour period ending
at midnight on 15 August.  A surface high pressure system followed the
front and remained over Pittsburgh on 16 August.   Fog or haze was observed
during the period 0500 to 0800 EST on 16 August,  and broken middle clouds
were observed during the period 1100 to 1600 EST.   Winds were light-to-
moderate and from the west-northwest through north.  Upper-air soundings
at the Greater [jttsburgh Airport indicate that:

     •    A shallow mixing layer with a moderate  surface-based
          inversion developed during the night of  15 - 16 August

     •    A relatively deep mixing layer with an  adiabatic lapse
          rate developed during the daylight hours on 16 August

     •    A strong surface-based inversion with a  corresponding
          shallow mixing depth formed during the  night of 16 -
          17 August
                            22 August 1976

     A surface high pressure system was approximately centered over the
Pittsburgh area on 22 August 1976.   With the exception of scattered to
broken high cirrus clouds after 0800 EST,  skies were clear in the Pitts-
burth area on 22 August.  At the Greater Pittsburgh Airport,  haze and
smoke were observed during the period 0100 to 0900 EST and haze was reported
after 1700 EST.  During the period 1200 to 2100 EST, light-to-moderate north-
west and north winds were observed.  The wind was calm or light and varia-
ble during the remaining hours of 22 August.  Upper-air data  for the
Greater Pittsburgh Airport show that strong surface-based inversions devel-
                                 D-23

-------
oped during the nights of 21 - 22 August and 22 - 23 August.   The 1900 EST
sounding on 23 August shows a relatively deep mixing layer with a slightly
stable lapse rate.
                            28August 1976

     A trace of precipitation was reported at the Greater Pittsburgh Air-
port on 27 August 1976 as a short-wave trough at 500 millibars passed over
the Pittsburgh area.   Similarly, a trace of precipitation was measured on
28 August as an advancing frontal system induced light rain showers at about
2100 EST.  Broken to  overcast low clouds covered the Pittsburgh area after
0500 EST on 28 August, and haze or ground fog was reported throughout the
day.  Upper-air soundings made at the Greater Pittsburgh Airport on 28
August indicate that  the mixing depth varied from about 350 meters in the
early morning hours to about 700 meters in the afternoon.  The vertical
potential temperature gradient within the surface mixing layer was approx-
imately equal to the  moist-adiabatic value during the period.  Light-to-
moderate south or southwest xvinds persisted from 0100 EST until about mid-
night when the wind shifted to the northwest, probably indicating a frontal
passage.
                           3 September 1976

     A surface, high pressure system, centered over the Great Lakes on the
morning of 2 September 1976, moved across the Pittsburgh area on 3 Sept-
ember.  Calm winds and dense fog (visibility at or near zero) were ob-
served at the Greater Pittsburgh Airport during the period 0100 to 0900
EST on 3 September.  After the fog cleared, light-to-moderate surface wind
speeds were measured, with the wind direction ranging from east through
south-southwest.  Rawinsonde measurements at the Greater Pittsburgh Airport
show a shallow mixing layer with a slightly stable lapse rate at 1900 EST.
                                 D-24

-------
A surface-based inversion of moderate strength developed during the night
of 3 - 4 September 1976.
                         '  9 September 1976

     A weak cold front passed over the Greater Pittsburgh Airport at about
midnight on 9 September 1976.  The storm resulted in 7.1 millimeters (0.28
inches) of precipitation at the airport for the 24-hour period ending at
midnight on 9 September.  This precipitation occurred in the form of light
rain showers during the period 1900 to 2400 EST.  Skies were clear on 9
September until clouds in advance of the front moved into the Pittsburgh
area at about 1600 EST.  Haze was reported from 0600 EST until 2300 EST,
when fog replaced haze as the major restriction to visibility.  Winds
were calm until moderate southwest winds developed at about 0900 EST.
After  the frontal passage at about 2400 EST, the wind direction shifted
from southwest to northwest and the wind speed increased to over 10 meters
per second.  According to the 0700 EST upper-air sounding at the Greater-
Pittsburgh Airport, a strong-surface based inversion formed during the
night  of 8 - 9 September.  Hcwever, a relatively deep surface mixing layer
with an adiabatic lapse rate developed by 1900 EST on 9 September and con-
tinued throughout the night of 9 - 10 September.
                                D- 25

-------
D.3       OBSERVER'S LOGS FOR THE SAMPLING DAYS

     The Observer's Logs for the six special sampling days are given in
Tables D-10 through D-15.  The logs include filter numbers, filter
weights, air flows through the hi-vol samplers during the sampling
period and 24-hour average particulate concentrations.  The sampling
sites were visited several times during each 24-hour sampling period, and
the logs also contain notes by the observers of industrial or other
activities in the vicinity of the sampling sites that could have affected
the observed particulate concentrations.  Some of the remarks, such as
those referring to noticeable odors from a particular source, are sub-
jective.
                                D-26

-------
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D.4       FILTER ANALYSIS RESULTS

     This section presents the results of the optical microscopy, scan-
ning electron microscopy (SEM) and energy-dispersive X-ray (EDAX)
analyses of the hi-vol filter samples from the fifteen monitor locations
described in Section D.I.  Although filter samples were collected on six
days, three of the sampling days were determined to be unsuitable for de-
tailed analyses because of the frequent occurrance of calm or light and
variable winds during the 24-hour sampling period.  The three sample
days selected for hi-vol filter analysis are 16 August, 28 August and
9 September 1976.  (SEM results are also given for the Liberty Boro
monitor on 22 August 1976.)

     Tables D-16 through D-88 give the results of the particle count
analyses performed by optical microscopy.  Each table lists, for the
primary filter alone, the cover filter alone or the primary and cover
filters in combination, the filter number(s), the monitor location,
the sample day, the particulate loading on the filter(s) as determined
by the Coors Spectro-Cheraical Laboratory and the 24-hour average part-
iculate concentration.  Each table also gives the concurrent filter
particulate loading and 24-hour average particulate concentration for
the colocated monitor operator by the Pennsylvania Department of Envi-
ronmental Resources  (DER) or the Allegheny County Bureau of Air Pollu-
tion Control (BAPC).  In the optical microscopy analysis, the particu-
lates were classified according to six generic categories:  (1) flyash,
(2) iron oxide,  (3) magnetic iron oxide, (4) quartz, (5) biologicals and
(6) CaCo,..  The particle counts in the tables refer to a filter segment
with an area of 0.00968 square centimeters.  As explained in Section 3.6,
the particle counts in each generic category and size range were used
with the particle densities assigned to each generic category to calcu-
late the particulate mass on this filter segment.  Under the assumption
of uniform particulate loading on the filter, the total particulate mass
on the entire filter was obtained by multiplying the mass of the filter
                                D-39

-------
 segment by  the ratio of  the  total filter area  to the area of  the filter
 segment.  Both the calculated mass and the total measured mass deter-
 mined by the filter weight are entered at the  top right of each table.

     Tables D-89 through D-167 give the results of the SEN filter
 analyses.   The format for Tables D-89 through  D-167 is the same as
 for Tables  D-16 through D-88 except that, in the SEM analysis, the
 particles were classified according to the following three generic
 categories:  (1) spheres,(2) irregularly-shaped particles, and (3)
 agglomerates.  The particle  counts in Tables D-89 through D-167 refer
 to a filter segment with an  area of 0.02053 square centimeters.  As a
 consistency check, two separate SEM filter analyses were performed on
 the filter  from the Central  Laboratory monitor for 9 September 1976,
 the North Braddock monitor for 9 September 1976 and the Liberty Boro
 monitor for 28 August 1976.  The results of both analyses are included
 in the tables  (for example,  see Tables D-148 and D-149).

     The results of both the optical microscopy and SEM analyses were
 used to estimate the distributions of mass by  particle diameter.  For
 each filter and for each particle size category, the combined mass of
 particles in the six (optical microscopy) or three (SEM) generic par-
 ticle categories was calculated using the procedures outlined in
 Section 3.6.  These results were then combined to form the cumulative
 mass distributions by particle diameter shown  in Figures D-6  through
 D-ll.  (The contributions of biological particles are removed from the
 optical microscopy results in Figures D-6 through D-8.)  Each figure
 contains fifteen cumulative mass distributions, corresponding to the
 fifteen ^articulate monitoring sites.  The mass distributions in each
 figure are  identified by the monitor site number given in Table D-l.

     On the basis of the hourly wind speeds and wind directions for
the  sampling days  as  well as  the  monitor  locations,  the  filters were
 assigned to one of three categories:  (1) industrial, (2) urban, or
                                D- 40

-------
(3) rural.  The industrial filters were Baden,  Midland,  Hazelwood and
Clairton on 16 August 1976 and Baden,  Midland,  North Braddock and Liberty
Boro on both 28 August and 9 September 1976.   The Downtown and Central
Laboratory filters were placed in the  urban classification on all three
sampling days.  Similarly, the Brighton Township, Elco,  Greater Pittsburgh
Airport and South Fayette filters were placed in the rural classification
on all three sampling days.

     Figure D-12 shows the cumulative  mass distribution by particle diameter
for all of the filters analyzed by optical microscopy which have a calculated
filter loading greater than or equal to 100 milligrams.   The industrial,
urban and rural cumulative mass distributions derived from these filters
are plotted respectively in Figures D-13,  D-14  and D-15.  Similarly,
Figure D-15 shows the cumulative mass  distribution by particle diameter
for all of the filters analyzed by SEM techniques which have a calculated
filter loading greater than or equal to 100 milligrams.   The corresponding
industrial, urban and rural cumulative mass distributions are plotted
respectively in Figures D-17, D-18 and D-19.

     Energy-dispersive X-ray (EDAX) analyses were performed on a number of
filters.  The surface of each SEM filter stub analyzed by EDAX scan was
made of the entire surface.  The height of each integral energy peak record-
ed during the EDAX scan was divided by the height of the integral energy
peak of gold to obtain a ratio which was essentially free of the effects
of any discrepancies between filters in counting rates,  beam intensities,
etc.  With the exception of copper, mercury,  arsenic and lead, the thres-
hold energy ratio for elements present in larger than trace quantities
was arbitrarily set at 0.10, and the elements were ranked according to
descending magnitude of the energy ratio.   The  threshold ratio for the
trace elements of copper, mercury, arsenic and  lead was set equal to 0.03.
The results of the EDAX analyses for 16 August, 18 August and 9 September
1976 are given respectively in Tables  D-168,  D-169 and D-170.  Elements
with an energy peak much larger than the normal peaks are underlined in the
tables.
                                  D-41

-------
     For a selected subset of the filters, an SEM-EDAX analysis was
perfomed for twelve to twenty particles on each filter.   Tables D-171
through D-216 summarize the results of these analyses.  For each particle,
the elements which comprise the particle are listed in descending order
of the ratio of the integral energy peak of the element  to the integral
energy peak of gold.  Elements with energy peaks much larger than the
usual peaks, are underlined in the tables.  Tables D-171 through D-216
also give, for each particle, the particle diameter in microns (micro-
meters), the particle description (spherical, irregularly-shaped or
agglomerate) and a tentative identification of the particle type or
origin.  We point out that all of the particles considered in Tables
D-171 through D-216 had diameters larger than 5 micrometers.  SEM
photographs of some of the selected filters are shown in Figures D-20
through D-30.

     A number of large particles with diameters greater  than 40 micro-
meters observed on the filters were analyzed using the SEM-EDAX tech-
niques described above.  The results of these analyses of selected large
particles are presented in Tables D-217 through D-224, and photomicro-
graphs containing these particles are shown in Figures D-31 through D-86.
Five very large particles with diameters greater than 100 micrometers
were also analyzed.  The elemental analysis of these particles is pre-
sented in Table D-225, the descriptions and possible identifications
are given in Table D-226, and photomicrographs are shown in Figures
D-87 through D-91.

     Slag produced by the steel industry is found throughout southwest
Pennsylvania in slag dumps and has been extensively used in road and
building construction.  Therefore, slag particles are likely to be a
primary constituent  of non-traditional fugitive emissions.  We there-
fore performed an analysis of samples of the different types of slag
found in the area to determine the correlation between the elemental
compositions of these slag samples and the compositions  of some of the
particles found on the hi-vol filters.
                                D-42

-------
     Tables D-227 through D-229 give the results of the elemental analyses
of the slag samples.  The particles from the samples were divided into
two groups, one containing large particles (diameters of the order of
100 micrometers) and one containing small particles (diameters of the
order of 10 micrometers).  Table D-227A gives the results of the analysis
of large particles contained in slag samples from an electric arc fur-
nace and Table D-227B gives the results of the analysis of some of the
small particles found on the surface of these large slag particles
Photomicrographs of these samples are shown in Figures D-92 through D-101.
Similarly, Table D-227C gives the results of the analysis of the small
particulates contained in slag samples from an electric arc furance and
Table D-227D gives the results of the analysis of some of the smaller
particles found on the surface of these small slag particles.  Photomicro-
graphs of these samples are shown in Figures D-102 through D-112.  The
analyses of large particles from a blast furnace and the small particles
found on their surfaces are summarized in Tables D-228A and D-229B.
The photomicrographs of these particles are shown in Figures D-113 and
D-114.  The elemental analyses of large slag particles from a basic
oxygen furnace and the smaller particles found on their surfaces are
summarized in Tables D-229A and D-229B.  Figures D-115 and D-116 show
the corresponding photomicrographs.

     Walter C. McCrone Associates, Inc. used optical microscopy to
analyze six selected filters as a check on the validity of the SEM and
Coors optical microscopy analyses.  Tables D-230 through D-236 summarize
the results of the McCrone analyses.  These tables give the percent by
number of particles within various size ranges for three general particle
categories: (1) combustion products, (2) minerals, and (3) biological
materials.
                                 D-43

-------
TABLE D-16 through D-88  - RESULTS OF OPTICAL PARTICLE  COUNTS
                           D-44

-------
           TABLE D-16




RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093219 Total Mass of Particulates (mg) :
Coors: 164 Agency: 139
Monitor Location: Baden Calculated Mass (mg): 261
Date of Sample: 8/16/76 Air Concentration (yg/m3) :
Coors: 86 Agency: 67
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75|j
>75y
Totals
Magnetic
Iron
5-10y
10-2 On
20-50y
50-75y
>75y
Totals
Particle
Count

300
78
23
3
4
408
34
11
0
0
0
45
31
10
3
0
0
44
Percent By
Number

52.3
13.6
4.0
0.5
0.7
71.1
5.9
1.9
0
0
0
7.8
5.4
1.7
0.5
0
0
7.7
Percent By Mass
All
Categories

1.8
3.8
15.3
10.0
35.9
66.9
0.7
1.8
0
0
0
2.4
0.6
1.6
6.5
0
0
8.8
Within
Category

2.8
5.7
22.9
14.9
53.6
100
27.9
72.1
0
0
0
100
7.1
18.4
74.5
0
0
100

-------
          TABLE D-16
RESULTS OF OFF!CM, PARTICLE COUNTS
            (Conlinued)
Filter Number: 1093219 (Continued)
Category

Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75u
Totals
CaC00
1 O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count

15
1
9
1
0
26
11
10
3
0
0
24
18
6
3
0
0
27
574
(All Categories)
i
Percent By
Number

2.6
0.2
1.6
0.2
0
4.5
1.9
1.7
0.5
0
0
4.2
3.1
1.0
0.5
0
0
4.7
100

Percent By Mass
All
Categories
0.2
0.08
10.0
5.6
0
15.8
0.04
0.3
1.3
0
0
1.7
0.2
0.5
3.6
0
0
4.3
100

Within
Category
1.0
0.5
63.3
35.2
0
100
2.6
19.2
78.1
0
0
100
4.6
12.3
83.1
0
0
100



-------
           TABLE  D-17



RESULTS OF OPTICAL PARTICLE  (DIM'S
Filter Number: 1093221 Total Mass of Particulates (nig):
Coors: 152 Agency: 12?
Monitor Location: Beaver Falls Calculated Mass (mg): 246
3
Date of Sairple: 8/16/76 Air Concentration (yg/m ):
Coors: 86 Agency: 61
Category
Flyash
5-10y
10-20u
20-50y
50-75u
>75p
Totals
Iron Oxide
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

278
47
13
1
6
345
10
1
0
0
0
11
8
1
0
0
0
9
Percent By
Number

64.8
11.0
3.0
0.2
1.4
80.4
2.3
0.2
0
0
0
2.6
1.9
0.2
0
0
0
2.1
Percent By Mass
All
Categories

1.8
2.5
9.2
3.5
57.2
74.2
0.2
0.2
0
0
0
0.4
0.2
0.2
0
0
0
0.4
Within
Category

2.4
3.3
12.4
4.8
77.1
100
55.6
44.4
0
0
0
100
50.0
50.0
0
0
0
100

-------
            TABLE D-17
RESULTS OF 01T1CAL PARTICLE COUNTS
            (Continued)



Quartz
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10n
10-20y
20-50y
50-75y
>75y
Totals
CaCCX,
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TarALS
(All CatrfTori
Filter Number
Particle
Count

15
4
3
0
0
22

8
6
3
0
3
20

22
0
0
0
0
22
429
rs)
' : 1093221
Percent By
Number

3.5
0.9
0.7
0
0
5.1

1.9
1.4
0.7
0
0.7
4.7

5.1
0
0
0
0
5.1
100
(Continued)
Percent
All
Categories

0.2
0.3
3.5
0
0
4.0

0.03
0.2
1.4
0
19.1
20.7

0.2
0
0
0
0
0.2
100

By Mass
Within
Category

4.0
8.6
87.3
0
0
100

0.2
1.0
6.8
0
92.0
100

100
0
0
0
0
100


-------
             TABLE D-18
RESULTS OF OPTICAL PAOTICLE COUNTS
Filter Number: 1093223

Monitor Location: Koppel
Date of Sarrple: 8/16/76

Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20)i
20-50y
50-75y
>75y
Totals
Particle
Count
240
56
26
6
6
334
32
0
0
0
0
32
0
0
0
0
0
0
Total Moss oT Particulates (mg) :
Coors: 189 Agency: 161
Calculated Mass (mg): 277
3
Air Concentration (yg/nf):
Coors: 90 Agency: 86
Percent By
Number
53
12
5
1
1
.1
.4
.8
.3
.3
73.9
7.1




0
0
0
0
7.1





0
0
0
0
0
0
Percent By Mass
AJ1
Categories
1.4
2.6
16.3
18.9
50.8
90.0
0.6
0
0
0
0
0.6
0
0
0
0
0
0
Within
Category
1.5
2.9
18.2
21.0
56.4
100
100
0
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-18
RESULT OF OPTICAL PARTICLE COUNTS
            (Continued)



Quartz
5-10y
10-20y
20-5'Oy
50-75y
>75fj
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO3
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
F: 1 ter Number
Particle
Count

11
6
2
0
0
19

10
14
0
0
1
25

40
2
0
0
0
42
452
OS)
• : 1093223
Percent By
Number

2.4
1.3
0.4
0
0
4.2

2.2
3.1
0
0
0.2
5.5

8.8
0.4
0
0
0
9.3
100
(Continued)
Percent
All
Categories

0.1
0.5
2.1
0
0
2.7

0.04
0.4
0
0
5.6
6.1

0.4
0.2
0
0
0
0.6
100

By Mass
Within
Category

4.0
17.4
78.6
0
0
100

0.6
7.1
0
0
92.3
100

71.4
28.6
0
0
0
100


-------
             TABLE D-19
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093225 Total Mass of Particulates (mg):
Coors: 119 Agency: 162
Monitor Location: Brighton Calculated Mass (mg): 79
Township
3
Date of Sample: 8/16/76 Air Concentration (]Jg/m ):
Coors : 65 Agency : 87
Category

Flyash
5-10i i
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20M
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50p
50-75y
>75{j
Totals
Particle
Count


190
40
14
1
1
246

34
2
0
0
0
36


0
0
0
0
0
0
Percent By
Number


48.8
10.3
3.6
0.2
0.2
63.2

8.7
0.5
0
0
0
9.2


0
0
0
0
0
0
Percent By Mass
All
Categories

3.8
6.5
30.7
11.0
29.6
81.7

2.2
1.1
0
0
0
3.3


0
0
0
0
0
0
Within
Category

4.7
8.0
37.6
13.4
36.2
100

68.0
32.0
0
0
0
100


0
0
0
0
0
0

-------
            TABLE D-19
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093225 (Continued)
Category

Quartz
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75y
Totals
CaC00
	 o
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


19
6
2
0
0
27

28
17
1
0
0
46

32
2
0
0
0
34
389
(All Categories)
Percent By
Number


4.9
1.5
0.5
0
0
6.9

7.2
4.4
0.2
0
0
11.8

8.2
0.5
0
0
0
8.7
100

Percent By Mass
All
Categories

0.6
1.6
7.3
0
0
9.6

0.4
1.8
1.5
0
0
3.7

1.2
0.6
0
0
0
1.8
100

Within
Category

6.7
16.9
76.4
0
0
100

10.3
50.0
39.7
0
0
100

66.7
33.3
0
0
0
100



-------
             TABLE U-20
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093227 Total Mass of Particulates (mg):
Coors: 149 Agency: 166
Monitor Location: Midland Calculated Mass (ing): 306
3
Date of Sample: 8/16/76 Air Concentration (pg/m ):
Coors: 83 Agency: 80
Category
Flyash
5-10y
10-20p
20-50p
50-75y
>75y
Totals
Iron Oxide
5-10u
10-20p
20-50y
50-75p
>75y
Totals
Magnetic
Iron
5-10p
10-20p
20-50p
50-75p
>75y
Totals
Particle
Count

259
62
16
2
2
341
15
10
0
0
0
25
0
0
0
0
0
0
Percent By
Number

55.7
13.3
3.4
0.4
0.4
73.3
3.2
2.2
0
0
0
5.4
0
0
0
0
0
0
Percent By Mass
All
Categories

1.4
2.6
9.1
5.7
15.3
34.1
0.2
1.4
0
0
0
1.6
0
0
0
0
0
0
Within
Category

4.0
7.6
26.7
16.7
45.0
100
15.8
84.2
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-20
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093227 (Continued)
Category
Quartz
5-10y
10-20u
20-50u
50-75]j
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOo
O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
19
15
12
2
0
48

19
2
1
3
7
32
18
1
0
0
0
19
465
-6S)
Percent By
Number
4.1
3.2
2.6
0.4
0
10.3

4.1
0.4
0.2
0.6
1.5
6.9
3.9
0.2
0
0
0
4.1
100
Percent By Mass
All
Categories
0.2
1.0
11.4
9.5
0
22.1

0.07
0.06
0.4
5.7
35.8
42.0
0.2
0.08
0
0
0
0.2
100
Within
Category
0.8
4.8
51.5
43.0
0
100

0.2
0.1
0.9
13.6
85.2
100
69.2
30.8
0
0
0
100


-------
             TABLE D-21
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093228 Total Mass of Participates (mg):
(Cover Filter) „ .
v Coors: — Agency:
Monitor Location: Midland Calculated Mass (rng): 166
3
Date of Sample: 8/16/76 Air Concentration (ug/m ):
(Cover Filter for 1093227) Coors: — Agency:
Category

Flyash
5-lOu
10-20y
20-50y
50-75y
>75,j
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


108
43
10
1
2
164

5
14
0
0
0
19


0
0
0
0
0
0
Percent By
Number


42.8
17.1
4.0
0.4
0.8
65.1

2.0
5.6
0
0
0
7.5


0
0
0
0
0
0
Percent By Mass
All
Categories

1.0
3.3
10.5
5.2
28.2
48.3

0.2
3.5
0
0
0
3.7


0
0
0
0
0
0
Within
Category

2.2
6.9
21.7
10.8
58.4
100

4.3
95.7
0
0
0
100


0
0
0
0
0
0

-------
             TABLE D-21
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: (Cover Filter\Continued)
1093228
Category
Quartz
5-10(j
10-20y
20-50n
50-75)j
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75u
>75y
Totals
CaCO0
O
5-lOy
10-20y
20-50u
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
16
8
7
0
0
31

10
10
3
1
3
27
11
0
0
0
0
11
252
.es)
I
Percent By
Number
6.3
3.2
2.8
0
0
12.3

4.0
4.0
1.2
0.4
1,2
10.7
4.4
0
0
0
0
4.4
100
Percent By Mass
All
Categories
0.2
1.0
12.2
0
0
13.5

0.06
0.5
2.1
3.5
28.2
34.4
0.2
0
0
0
0
0.2
100
Within
Category
1.9
7.6
90.4
0
0
100

0.2
1.5
6.1
10.2
82.1
100
100
0
0
0
0
100


-------
             TABLE D-22
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093213 Total Mass of Particulates (mg):
Coors: 147 Agency: 100
Monitor Location: Elco Calculated Mass (mg) : 143
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors: 66 Agency: 46
Category
F_lyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75p
>75y
Totals
Magnetic
Iron
5-lOy
10~20y
20-50y
50-75y
>75y
Totals
Particle
Count

186
36
18
4
1
245
5
3
0
0
0
8
0
0
0
0
0
0
Percent By
Number

57.0
11.0
5.5
1.2
0.3
75.2
1.5
0.9
0
0
0
2.4
0
0
0
0
0
0
Percent By Mass
All
Categories

2.1
3.2
21.9
24.4
16.4
68.0
0.2
0.9
0
0
0
1.1
0
0
0
0
0
0
Within
Category

3.1
4.8
32.2
35.8
24.1
100
17.2
82.8
0
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-22
RESULTS OF OFHCAL PARTICLE COUNTS
            (G niLinued)
Filter Number: 1093213 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Biological
5-10jj
10-20y
20-50u
50-75p
>75]j
Totals
CaCOQ
O
5-10p
. 10-20y
20-50y
50-75}j
>75p
Totals
TOT'ALS
(All Category
Particle
Count
11
4
1
0
0
16
35
18
1
1
2
57
0
0
0
0
0
0
326
ics)
Percent By
Number
3.4
1.2
0.3
0
0
4.9
10.7
5.5
0.3
0.3
0.6
17.5
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.2
0.6
2.0
0
0
2.8
0.3
1.1
0,8
4.1
21.9
28.1
0
0
0
0
0
0
100
Within
Category
7.3
21.2
71.6
0
0
100
0.9
3.8
2.9
14.5
77.9
100
0
0
0
0
0
0


-------
             TABLE D-23
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093215

Monitor Location: Downtown
Date of Sample: 8/16/76

Category
Flyash
5-lOu
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20u
20-50y
50~75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
333
83
22
1
0
439
21
0
0
0
0
21
24
8
0
0
0
32
Total Mass of Particulates (nig):
Coors: 284 Agency: 241
Calculated Mass (mg): 222
3
Air Concentration (yg/m ) :
Coors: 139 Agency: 110
Percent By
Number
57
14
3
0

75
.2
.3
.8
.2
0
.4
3.6




0
0
0
0
3.6
4.1
1.4



0
0
0
5.5
Percent By Mass
All
Categories
2.4
4.8
17.3
3.9
0
28.4
0.5
0
0
0
0
0.5
0.6
1.5
0
0
0
2.1
Within
Category
8.5
16.9
60.7
13.8
0
100
100
0
0
0
0
100
27.2
72.7
0
0
0
100

-------
            TABLE D-23
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093215 (Continued)
Category

Quartz
5-10y
10-20y
20-50y
50-75u
>75y
Totals
Biological
5-10n
10-20y
20-50u
50-75y
>75y
Totals
CaCO0
>j
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count

17
26
11
2
2
58

10
21
0
1
0
32
0
0
0
0
0
0
582
(All Categories)
I
Percent By
Number

2.9
4.5
1.9
0.3
0.3
10.0

1.7
3.6
0
0.2
0
5.5
0
0
0
0
0
0
100

Percent By Mass
All
Categories
0.2
2.5
14.4
13.1
35.3
65.5

0.05
0.8
0
2.6
0
3.5
0
0
0
0
0
0
100

Within
Category
0.3
3.8
22.0
20.0
53.8
100

1.4
23.4
0
75.2
0
100
0
0
0
0
0
0



-------
             TABLE D-24
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1Q93241
Monitor Location: Central Lab
Date of Sample: 8/16/76

Category
Flyash
5-10u
10-20u
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75}j
Totals
Particle
Count
229
81
26
1
1
338
42
6
0
0
0
48
15
14
1
0
0
30
Total Mass of Particulates (mg):
Coors : 234 Agency : 202
Calculated Mass (mg): 155
3
Air Concentration (yg/m ):
Coors : HO Agency : 9?
Percent By
Number
46.
16.
5.
0.
0.
68.
8.
1.
3
4
2
2
2
3
5
2
0
0
0
9.
3
2
0
7
0
8
2
0
0
6
1
Percent By Mass
All
Categories
2.4
6.7
29.1
5.6
15.1
^ 58.9
1.4
1.6
0
0
0
3.0
0.5
3.8
3.7
0
0
8.0
Within
Category7
4.0
11.4
49.4
9.5
25.6
100
46.7
53.3
0
0
0
100
6.4
47.6
46.0
0
0
100

-------
            TABLE D-24
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093241 (Continued)
Category

Quartz
5-10y
10-20y
20-50y
50-75u
>75y
Totals
Biological
5-10y
10-20y
20-50jj
50-75y
>75y
Totals
CaCOg
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


15
5
4
1
0
25

2
7
5
1
0
15

25
13
1
0
0
39
495
(All Categories)
i
Percent By
Number


3.0
1.0
0.8
0.2
0
5.0

0.4
1.4
1.0
0.2
0
3.0

5.0
2.6
0.2
0
0
7.9
100

Percent By Mass
All
Categories

0.2
0.7
7.5
9.3
0
17.8

0.1
0.4
3.7
3.7
0
7.9

0.5
1.9
2.0
0
0
4.4
100

Within
Category

1.5
3.9
42.0
52.6
0
100

0.2
4.9
47.4
47.5
0
100

10.5
43.8
45.6
0
0
100



-------
             TABLE  D-25
RESULTS OF OPTICAL PAHT1CLE COUNTS
Filter Number: 1093201 Total Mass of Particulates (mg) :
Coors: igo Agency: 191
Monitor Location: Hazelwood Calculated Mass (mg): 218
3
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors: 131 Agency: 105
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75p
>75M
Totals
Magnetic
Iron
5-K)n
10-20y
20-50y
50-75y
>75p
Totals
Particle
Count

480
78
15
6
4
583
29
9
1
0
0
39

0
0
0
0
0
0
Percent By
Number

72.6
11.8
2.3
0.9
0.6
88.2
4.4
1.4
0.2
0
0
5.9

0
0
0
0
0
0
Percent By Mass
All
Categories

3.5
4.6
12.0
23.9
43.0
87.0
0.7
1.7
2.6
0
0
5.0

0
0
0
0
0
0
Within
Category

4.1
5.3
13.7
27.5
49.4
100
13.9
34.4
51.7
0
0
100

0
0
0
0
0
0

-------
             TABLE  D-25
RESULTS OF OPHCAL PARTICLE COUNTS
            (ConLJnued)
Filter Number: 1Q93201 (Continued)
Category
Quartz
5-10u
10-20u
20-50u
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50u
50-75y
>75y
Totals
CaCOQ
• o
5-10y
10-20y
20-50y
50-75u
>75y
Totals
1DTALS
(All Categor]
Particle
Count
14
7
0
1
0
22
3
4
0
0
0
7
8
2
0
0
0
10
661
_es)
1
Percent By
Number
2.1
1.0
0
0.2
0
3.3
0.4
0.6
0
0
0
1.0
1.2
0.3
0
0
0
1.5
100
Percent By Mass
All
Categories
0.2
0.7
0
6.6
0
7.5
0.01
0.2
0
0
0
0.2
0.1
0.2
0
0
0
0.3
100
Within
Category
2.3
9.2
0
88.5
0
100
8.6
91.4
0
0
0
100
33.3
66.7
0
0
0
100


-------
             TABLE D-26
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093203 Total Mass of Particulates (mg) :
Coors: 155 Agency: 126
Monitor Location: North Braddock Calculated Mass (mg): 317
3
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors : 79 Agency : 63
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

229
40
15
9
2
295
26
2
0
0
0
28
0
0
0
0
0
0
Percent By
Number

53.9
9.4
3.5
2.1
0.5
69.4
6.1
0.5
0
0
0
6.6
0
0
0
0
0
0
Percent By Mass
All
Categories

1.2
1.6
8.2
24.7
14.8
50.6
0.4
0.3
0
0
0
0.7
0
0
0
0
0
0
Within
Category

2.3
3.2
16.3
48.9
29.3
100
61.9
38.1
0
0
0
100
0
0
0
0
0
0

-------
            TABLE D-26
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093203 (Continued)
Category
Quartz
5-10jj
10-2 Oy
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75)j
>75y
Totals
CaOO,
5-10y
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
(All Categora
Particle
Count

16
2
2
0
0
20

15
27
14
6
6
68
14
0
0
0
0
14
425
es)
Percent By
Number

3.8
0.5
0.5
0
0
4.7

3.5
6.4
3.3
1.4
1.4
16.0
3.3
0
0
0
0
3.3
100
Percent By Mass
All
Categories

0.1
0.1
1.8
0
0
2.1

0.05
0.07
5.1
11.0
29.6
46.5
0.1
0
0
0
0
0.1
100
Within
Category

6.4
6.4
87.1
0
0
100

0.1
1.6
11.0
23.6
63.6
100
100
0
0
0
0
100


-------
             TABLE D-27



RESULTS OF OPTICAL PAHTICLE COUNTS
Filter Number: 1093205 Tot.al Mass of Particulates (mg) :
Coors: 231 Agency: 211
Monitor Location: Duquesne II Calculated Ntiss (mg): 157
3
Date of Sample: 8/16/76 Air Concentration (ug/m ):
Coors: 145 Agency: 107
Category
Flyash
5-lOu
10-20^
20-50y
50-75u
>75jj
Totals
Iron Oxide
5-10p
10-20y
20-50)j
50-75u
>75u
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75(J
>75y
Totals
Particle
Count

248
75
19
2
1
345
56
5
0
0
0
61
24
9
6
0
0
39
Percent By
Number

48.8
14.8
3.7
0.4
0.2
67.9
11.0
1.0
0
0
0
12.0
4.7
1.8
1.2
0
0
7.7
Percent By Mass
All
Categories

2.5
6.2
21.1
11.1
14.9
55.8
1.9
1.3
0
0
0
3.2
0.8
2.4
21.7
0
0
25.0
Within
Category

4.6
11.0
37.8
19.9
26.8
100
58.5
41.5
0
0
0
100
3.2
9.7
86.9
0
0
100

-------
             TABLE D-27
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093205 (Continued)
Category
Quartz
5-1%
10-20y
20-50M
50-75y
>75y
Totals
Biological
5-lOp
10~20y
20-50y
50-75)j
>75y
Totals
CaC00
" " O
5-10u
10-20u
20-50y
50-75y
>75p
Totals
TOTALS
(AH Category
Particle
Count
16
5
2
0
0
23

21
3
1
0
1
26
13
1
0
0
0
14
508
OS)
Percent By
Number
3.1
1.0
0.4
0
0
4.5

4.1
0.6
0.2
0
0.2
5.1
2.6
0.2
0
0
0
2.8
100
Percent By Mass
All
Categories
0.3
0.7
3.7
0
0
4.6

0.1
0.2
0.7
0
10.0
11.0
0.2
0.1
0
0
0
0.4
100
Within
Category
5.9
14.7
79.4
0
0
100

1.3
1.5
6.7
0
90.5
100
61.9
38.1
0
0
0
100


-------
             TABLE D-28
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093209 Total Mass of Particulates (mg) :
C°°"rs: 181 Agency:
Monitor Location: Liberty Boro Calculated Mass (mg): 251
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors : 114 Agency :
Category

Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50|j
50-75y
>75y
Totals
Particle
Count


447
187
37
5
2
678

11
0
0
0
0
11


0
0
0
0
0
0
Percent By
Number


59.0
24.7
48.9
0.7
0.3
89.6

1.4
0
0
0
0
f 1.4


0
0
0
0
0
0
Percent By Mass
All
Categories

2.9
9.6
25.7
17.4
18.7
74.2

0.2
0
0
0
0
0.2


0
0
0
0
0
0
Within
Category

3.9
12.9
34.6
23.4
25.2
100

100
0
0
0
0
100


0
0
0
0
0
0

-------
             TABLE D-28
RESULTS OF OPTICAL PARTICLE OOUNrrS
            (Continued)
Filter Number: 1093209 (Continued)
Category
Quartz
5-10u
10-20p
20-50y
50-75U
>75y
Totals
Biological
5-10u
10-20jj
20-50n
50-75y
>75y
Totals
CaCOQ
5-10p
10-20y
20-50u
50-75n
>75y
Totals
TOTALS
(All Categori
Particle
Count
9
9
2
0
0
20

4
7
1
0
3
15
15
17
1
0
0
33
757
.es)
!
Percent By
Number
1.2
1.2
0.3
0
0
2.6

0.5
0.9
0.1
0
0.4
2.0
2.0
2.2
0.1
0
0
4.4
100
Percent By Mass
All
Categories
0.1
0.8
2.3
0
0
3.2

0.02
0.2
0.5
0
18.7
19.4
0.2
1.6
1.2
0
0
3.0
100
Within
Category
3.0
24.2
72.8
0
0
100

0.09
1.2
2.4
0
96.3
100
5.8
52.5
41.7
0
0
100


-------
             TABLE  D-29
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093211 Total Mass of Participates (mg) :
Coors: 125 Agency: 150
Monitor Location: Clairton Calculated Mass (mg) : 182
3
Date of Sample: 8/16/76 Air Concentration (yg/ni ):
Coors: 52 Agency: 76
Category
Fly ash
5-lOy
10-20y
20-50M
50-75 u
>75u
Totals
Iron Oxide
5-10y
10-20y
20-50p
50-75M
>75y
Totals
Magnetic
Iron
5-10n
10-20n
20-50u
50-75n
>75y
Totals
Particle
Count

199
62
18
5
3
287
34
1
0
0
0
35
0
0
0
0
0
0
Percent By
Number

54.7
17.0
4.9
1.4
0.8
78.8
9.3
0.3
0
0
0
9.6
0
0
0
0
0
0
Percent By Mass
All
Categori es

1.8
4.4
17.2
23.9
38.7
86.0
1.0
0.2
0
0
0
1.2
0
0
0
0
0
0
Within
Category

2.0
5.1
20.0
27.8
45.0
100
81.0
19.0
0
0
0
100
0
0
0
0
0
0

-------
            TABLE  D-29
RESULTS OF OPTJCAL PARTI CIJ] COUNTS
            (Continued)
Filter Number: 1093211 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
1 O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categon
Particle
Count
9
1
1
0
0
11

11
3
3
0
1
18
13
0
0
0
0
13
364
es)
Percent By
Number
2.5
0.3
0.3
0
0
3.0

3.0
0.8
0.8
0
0.3
4.9
3.6
0
0
0
0
3.6
100
Percent By Mass
Al 1
Citegories
0.1
0.1
1.6
0
0
1.8

0.06
0.1
1.9
0
8.6
10.7
0.2
0
0
0
0
0.2
100
Within
Category
7.2
6.4
86.4
0
0
100

0.6
1.3
17.9
0
80.2
100
100
0
0
0
0
100


-------
             TABLE D-30



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093229 Total Mass of Participates (mg) :
Coors: 149 Agency: 151
Monitor Location: Airport Calculated Mass (mg): 130
3
Date of Sarrple: 8/16/76 Air Concentration (yg/m ):
Coors: 76 Agency: 72
Category

Flyash
5-10|i
10-20y
20-50y
50-75M
>75y
Totals
Iron Oxide
5-10y
10-20M
20-50y
50-75u
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Particle
Count


186
41
8
4
0
239

14
0
0
0
0
14


9
2
0
0
0
11
Percent By
Number


55.7
12.3
2.4
1.2
0
71.6

4.2
0
0
0
0
4.2


2.7
0.6
0
0
0
3.3
Percent By Mass
Ail
Categories

2.3
4.0
10.7
26.8
0
43.8

0.6
0
0
0
0
0.6


0.4
0.6
0
0
0
1.0
Within
Category

5.2
9.2
24.4
61.1
0
100

100
0
0
0
0
100


36.0
64.0
0
0
0
100

-------
             TABLE D-30
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093229 (Continued)
Category

Quartz
5-10y
10-20y
20-50u
50-75U
>75y
Totals
Biological
5-10u
10-20u
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75y
>75u
Totals
TOTALS
Particle
Count


22
9
4
2
0
37

11
1
5
1
1
19

14
0
0
0
0
14
334
(All Categories)
Percent By
Number


6.6
2.7
1.2
0.6
0
11.1

3.3
0.3
1.5
0.3
0.3
5.7

4.2
0
0
0
0
4.2
100

Percent By Mass
AIL
Gitegories

0.4
1.5
8.9
22.3
0
33.2

0.09
0.06
4.4
4.5
12.0
21.1

0.3
0
0
0
0
0.3
100

Within
Category

1.4
4.5
26.9
67.3
0
100

0.4
0.3
21.1
21.2
57.0
100

100
0
0
0
0
100



-------
             TABLE D-31
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (C^61* Filter) Total Mass of Participates (rag):
1093230 r, .
Coors: — Agency:
Monitor Location: Airport Calculated Mass (mg): 64
3
Date of Sample: 8/16/76 Air Concentration (ug/m ):
(Cover Filter for 1093229) Coors: — Agency:
Category
Flyash
5-10u
10-20y
20-50U
50-75y
>75y
Totals
Iron Oxide
5-10u
10-20U
20-50u
50-75y
>75u
Totals
Magnetic
Iron
5-10y
10-20jj
20-50u
50-75(j
>75y
Totals
Particle
Count

161
44
9
0
0
214
16
0
0
0
0
16
0
0
0
0
0
0
Percent By
Number

51.4
14.0
2.9
0
0
68.4
5.1
0
0
0
0
5.1
0
0
0
0
0
0
Percent By Mass
All
Categories

4.1
8.9
24.6
0
0
37.5
1.3
0
0
0
0
1.3
0
0
0
0
0
0
Within
Category

10.8
23.7
65.5
0
0
100
100
0
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-31
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: (9°v^ Filter(b^ntinuecl)
Category

Quartz
5-10u
10-20p
20-50y
50-75^
>75u
Totals
Biological
5-lOp
10-20}j
20-50p
50-75p
>75y
Totals
CaC00

5-10y
10-20jj
20-50u
50-75u
>75u
Totals
TOTALS
Particle
Count


22
4
5
0
0
31

16
10
5
0
1
32

20
0
0
0
0
20
313
(All Categories)
Percent By
Number


7.0.
1.3
1.6
0
0
9.9

5.1
3.2
1.6
0
0.3
10.2

6.4
0
0
0
0
6.4
100

Percent By Mass
All
Categories

0.9
1.3
22.7
0
0
25.0

0.3
1.3
9.1
0
24.5
35.2

0.9
0
0
0
0
0.9
100

Within
Category

3.7
5.4
90.9
0
0
100

0.8
3.8
25.8
0
69.6
100

100
0
0
0
0
100



-------
             TABLE D-32



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093239 Total Mass of Particulates (mg) :
Coors: 140 Agency: 90
Monitor Location: South Fayette Calculated toss (mg): 33
Date of Sample: 8/16/76 Air Concentration (yg/rrT):
Coors : 69 Agency : 41
Category

Flyash
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


126
22
10
0
0
158

8
2
0
0
0
10


9
0
0
0
0
9
Percent By
Number


55.5
9.7
4.4
0
0
69.6

3.5
0.9
0
0
0
4.4


4.0
0
0
0
0
4.0
Percent By Mass
All
Categories

6.1
8.5
52.1
0
0
66.6

1.2
2.5
0
0
0
3.7


1.4
0
0
0
0
1.4
Within
Category

9.1
12.7
78.2
0
0
100

33.3
66.7
0
0
0
100


100
0
0
0
0
100

-------
             TABLE  D-32
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093239 (Continued)
Category
Quartz
5-lOy
10-20p
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50u
50-75p
>75y
Totals
CaC00
1 " O
10-20y
20-50M
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
12
6
2
0
0
20

11
0
1
0
0
12
17
1
0
0
0
18
227
es)
1
Percent By
Number
5.3
2.6
0.9
0
0
8.8

4.8
0
0.4
0
0
5.3
7.5
0.4
0
0
0
7.9
100
Percent By t\5ass
All
Categories
1.0
3.8
17.4
0
0
22.2

0.4
0
3.5
0
0
3.8
1.5
0.7
0
0
0
2.2
100
Within
Category
4.3
17.4
78.3
0
0
100

9.2
0
90.8
0
0
100
68.0
32.0
0
0
0
100


-------
             TABLE D-33
RESULTS OF OPTICAL PARTICLE COUNTS
( C^r\\ 7OY* TP"i T "t* OT* ^
Filter Number: t">ver inter)
1093240
Monitor Location: South Fayette
Date of Sample: 8/16/76
(Cover Filter for 1093239)
Category
Flyash
5-lOu
10-20y
20-50p
50-75U
>75u
Totals
Ir-on Oxide
5-10u
10-20u
20-50u
50-75y
>75u
Totals
Magnetic
Iron
5-lOu
10-20y
20-50u
50-75u
>75y
Totals
Particle
Count

128
36
3
0
0
167
8
0
0
0
0
8
8
3
0
0
0
11
Total Mass of Particulates (mg) :
Coors: — Agency: —
Calculated Mass (mg): 37
3
Air Concentration (ug/m ):
Coors : — Agency :
Percent By
Number


53.8
15.1
1.3


0
0
70.2
3.4




0
0
0
0
3.4
3.4
1.3



0
0
0
4.6
Percent By Mass
All
Categories

5.6
12.6
14.2
0
0
32.4
1.1
0
0
0
0
1.1
1.1
3.4
0
0
0
4.5
Within
Category

17.3
38.9
43.8
0
0
100
100
0
0
0
0
100
25.0
75.0
0
0
0
100

-------
             TABLE D-33
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: (Jgg||4^ilter\/'oontinued)
Category
Quartz
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75y
Totals
CaC00
1 O
5-10y
10-20y
20-50p
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
7
3
1
0
0
11

10
22
1
0
1
34
7
0
0
0
0
7
238
es)
Percent By
Number
2.9
1.3
0.4
0
0
4.6

4.2
9.2
0.4
0
0.4
14.3
2.9
0
0
0
0
2.9
100
Percent By Mass
All
Categories
0.5
1.8
7.9
0
0
10.2

0.3
5.1
3.2
0
42.5
51.1
0.6
0
0
0
0
0.6
100
Within
Category
5.0
17.2
77.7
0
0
100

0.6
10.0
6.2
0
83.2
100
100
0
0
0
0
100


-------
             TABLE D-34
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093290

Monitor Location: Baden
Date of Sample: 8/28/76

Category
Flyash
5-10u
10-20y
20~50n
50-75p
>75M
Totals
Iron Oxide
5-10u
10-20M
20-50|j
50-75u
>75y
Totals
Magnetic
Iron
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count

375
71
12
2
0
460
13
I
0
0
0
14
12
1
0
0
0
13
Total Mass of Particulates (mg) :
Coors: 374 Agency: 351
Calculated Mass (mg): 66
3
Air Concentration (yg/m ):
Coors: 203 Agency: 183
Percent By
Number

68
13
2
0

.8
.0
.2
.4
0
84
2
0
.4
.4
.2
0
0
0
2
2
0
.6
.2
.2
0
0
0
2
.4
Percent By Mass
All
Categories

9.2
13.9
31.7
26.4
0
81.2
1.0
0.6
0
0
0
1.6
1.0
0.6
0
0
0
1.6
Within
Category

11.3
17.1
39.0
32.6
0
100
61.9
38.1
0
0
0
100
60.0
40.0
0
0
0
100

-------
             TABLE  D-34
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093290 (Continued)
Category
Quartz
5-10y
10-2 Oy
20-50M
50-75y
>75p
Totals
Biological
5-lOp
10-20^
20-50p
50-75n
>75M
Totals
CaC00
5-10y
10-20p
20-50u
50-75vi
>75y
Totals
TOTALS
(All Categori
Particle
Count
11
2
2
0
0
15

19
9
2
0
0
30
13
0
0
0
0
13
545
es)
1
Percent By
Number
2.0
0.4
0.4
0
0
2.8

3.5
1.6
0.4
0
0
5.5
2.4
0
0
0
0
2.4
100
Percent By Mass
All
Categories
0.4
0.7
8.8
0
0
9.9

0.3
1.2
3.5
0
0
5.0
0.6
0
0
0
0
0.6
100
Within
Category
4.5
6.6
88.9
0
0
100

6.2
23.4
70.4
0
0
100
100
0
0
0
0
100


-------
             TABLE D-35
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1093291 Coors: — Agency:
Monitor Location: Baden Calculated Mass (mg) : 192
Date of Sample: 8/28/76 Air Concentration (ug/m ):
(Cover Filter for 1093290) Coors: — Agency:
Category
Flyash
5-lOu
10-20y
20-50p
50-75^
>75y
Totals
Iron Oxide
5-10y
10-20n
20-50p
50-75U
>75M
Totals
Magnetic
Iron
5-10y
10-20)j
20-50u
50-75y
>75y
Totals
Particle
Count

198
76
28
4
2
308
30
9
0
0
0
39
14
8
0
0
0
22
Percent By
Number

46.0
17.7
6.5
0.9
0.5
71.6
7.0
2.1
0
0
0
9.1
3.2
1.9
0
0
0
5.1
Percent By Mass
All
Categories

1.6
5.1
25.3
18.1
24.4
74.6
0.8
2.0
0
0
0
2.8
0.4
1.7
0
0
0
2.1
Within
Category

2.2
6.8
34.0
24.3
32.7
100
29.4
70.6
0
0
0
100
17.9
82.0
0
0
0
100

-------
             TABLE D-35
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: ^C^^^lter')( Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75)j
>75y
Totals
CaCOQ
*J
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count

11
5
5
0
0
21
14
10
4
3
0
31
8
1
0
0
0
9
430
es)
1
Percent By
Number

2.6
1.2
1.2
0
0
4.9
3.2
2.3
0.9
0.7
0
7.2
1.9
0.2
0
0
0
2.1
100
Percent By Mass
All
Categori es

0.2
0.6
7.5
0
0
8.2
0.08
0.4
2.4
9.0
0
12.0
0.1
0.1
0
0
0
0.2
100
Within
Category

1.8
6.8
91.4
0
0
100
0.6
3.7
20.1
75.5
0
100
50.0
50.0
0
0
0
100


-------
             TABLE  D-36



RESULTS OF OPTICAL PARTICLE COUiYfS
Filter Number: 1093288 Total Mass of Particulates (mg) :
Coors: 277 Agency: 266
Monitor Location: Beaver Falls Calculated Mass (mg): 182.
3
Date of Sample: 8/28/76 Air Concenti-ation (yg/m ):
Coors : 164 Agency : 137
Category

Flyash
5-lOu
10-20u
20-50p
50-75U
>75M
Totals
Iron Oxide
5-10M
10-20y
20-50p
50-75y
>75,
Totals
Magnetic
Iron
5-lOy
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count


352
57
17
4
1
431

0
0
0
0
0
0


0
0
0
0
0
0
Percent By
Number


62.8
10.2
3.0
0.7
0.2
77.0

0
0
0
0
0
0


0
0
0
0
0
0
Percent By Mass
All
Categories

3.1
4.0
16.2
19.1
12.9
55.4

0
0
0
0
0
0


0
0
0
0
0
0
Within
Category

5.6
7.3
29.3
34.5
23.2
100

0
0
0
0
0
0


0
0
0
0
0
0

-------
             TABLE D-36
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093288 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75M
>75p
Totals
Biological
5-10u
10-20y
20-50u
50-75u
>75y
Totals
CaC00
«_>
5-10u
10-20p
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
12
0
1
0
0
13
38
47
25
5
1
116
0
0
0
0
0
0
560
es)
Percent By
Number
2.1
0
0.2
0
0
2.3
6.8
8.4
4.5
0.9
0.2
20.7
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.2
0
1.6
0
0
1.8
0.2
2.2
15.9
15.9
8.6
42.9
0
0
0
0
0
0
100
Within
Category
10.0
0
90.0
0
0
100
0.5
5.2
37.1
37.2
20.0
100
0
0
0
0
0
0


-------
              TABLE  D-37
RESULTS OF OPTICAL, PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1093289 Coors: — Agency:
Monitor Location: Beaver Falls Calculated Mass (mg) : 132
3
Date of Sanple: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1093288) Coors: — Agency:
Category
Flyash
5-10u
10-20p
20-50p
50-75M
>75p
Totals
Iron Oxide
5-10p
10-20y
20-50)j
50-75u
>75y
Totals
Magnetic
1 1X311
5-10u
10-20u
20-50u
50-75^
>75n
Totals
Particle
Count

92
39
4
2
2
139
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number

42.0
17.8
1.8
0.9
0.9
63.5
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories

1.1
3.8
5.3
13.2
35.6
59.0
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category

1.9
6.4
9.0
22.4
60.3
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
            TABLE D-37
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: (C?QQo2Qglter^Continued)
Category
Quartz
5-10u
10-20y
20-50y
50-75y
>75p
Totals
Biological
5-10p
10-20u
20-50]j
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75u
>75]i
Totals
TOTALS
(All Categor]
Particle
Count
2
6
4
0
0
12
10
38
19
0
1
68
0
0
0
0
0
0
219
es)
Percent By
Number
0.9
2.7
1.8
0
0
5.5
4.6
17.4
8.7
0
0.4
31.0
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.04
1.0
8.8
0
0
9.8
0.08
2.5
16.7
0
11.9
31.2
0
0
0
0
0
0
100
Within
Category
0.4
9.9
89.6
0
0
100
0.3
7.9
53.7
0
38.1
100
0
0
0
0
0
0


-------
             TABLE D-38
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093286

Monitor Location: Koppel
Date of Sample: 8/28/76

Category
Flyash
5-1 Oy
10-20u
20-50U
50-75y
>75p
Totals
Iron Oxide
5-10y
10-20M
20-50)j
50-75y
>75|j
Totals
Magnetic
Iron
5-10p
10-20^
20-50u
50-75u
>75M
Totals
Particle
Count

260
72
16
8
7
363
20
5
1
0
0
26

0
0
0
0
0
0
Total Mass of Particulates (mg):
Coors: 256 Agency:
Calculated Mass (mg): 340
3
Air Concentration (yg/m ) :
Coors : 133 Agency :
Percent By
Number


56.6
15.7
3.5
1.7
1.5
79.1
4.4
1.1
0.2


0
0
5.7







0
0
0
0
0
0
Percent By Mass
All
Categories

1.2
2.7
8.2
20.5
48.4
81.0
0.3
0.6
1.7
0
0
2.6

0
0
0
0
0
0
Within
Category

1.5
3.4
10.1
25.3
59.7
100
11.9
23.8
64.3
0
0
100

0
0
0
0
0
0

-------
             TABLE D-38
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093286 (Continued)
Category
Quartz
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75p
>75M
Totals
CaOOQ
o
5-10n
10-20M
20-50y
50-75y
>75pi
Totals
TOTALS
(All Categora
Particle
Count
23
8
7
0
0
38

5
15
0
0
2
22
10
0
0
0
0
10
459
es)
Percent By
Number
5.0
1.7
1.5
0
0
8.3

1.1
3.3
0
0
0.4
4.8
2.2
0
0
0
0
2.2
100
Percent By Mass
All
Categories
0.2
0.5
6.0
0
0
6.7

0.02
0.4
0
0
9.2
9.6
0.08
0
0
0
0
0.08
100
Within
Category
2.7
7.6
89.7
0
0
100

0.2
3.9
0
0
95.9
100
100
0
0
0
0
100


-------
             TABLE D-39
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number:

Monitor Location: Brighton
Township
Date of Sample: 8/28/76

Category

Fly ash
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Particle
Count


196
56
4
3
1
260

19
10
0
0
0
29


3
3
0
0
0
6
Total Mass of Particulates (mg) :
Coors: 258 Agency: 274
Calculated Mass (mg) : 125
3
Air Concentration (yg/m ):
Coors : 149 Agency : 151
Percent By
Number


46.
13.
0.
0.
0.
61

4
2


2
2
9
7
2
3

5
4
0
0
0
6


0
0
9


.7
7
0
0
0
1
.4
Percent By Mass
All
Categories

2.5
5.8
5.6
20.9
18.8
53.5

0.8
3.4
0
0
0
4.2


0.1
1.0
0
0
0
1.1
Within
Category

4.7
10.8
10.4
39.0
35.0
100

19.2
80.8
0
0
0
100


11.6
88.4
0
0
0
100

-------
             TABLE D-39
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093284 (Continued)
Category
Quartz
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Biological
5-10u
10-20u
20-50y
50-75y
>75y
Totals
CaC00
1 3
5-10y
10-20u
20-50u
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
53
39
13
0
0
105

1
12
2
0
0
15
7
2
0
0
0
9
424
_es)
1
Percent By
Number
12.5
9.2
3.1
0
0
24.8

0.2
2.8
0.5
0
0
3.5
1.6
0.5
0
0
0
2.1
100
Percent By Mass
All
Categories
1.1
6.7
30.2
0
0
38.0

0.008
0.8
1.8
0
0
2.7
0.2
0.4
0
0
0
0.5
100
Within
Category
3.0
17.6
79.4
0
0
100

0.3
30.6
69.0
0
0
100
30.4
69.6
0
0
0
100


-------
             TABLE D-40
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093282

Monitor Location : Midland
Date of Sample: 8/28/76
Category
Fly ash
5-10y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
208
97
38
6
6
355
56
29
2
0
0
87
21
17
0
0
0
38
Total Mass oi Particulates (mg) :
Coors: 479 Agency: 501
Calculated Mass (mg): 338
3
Air Concentration (yg/m ):
Coors: 268 Agency: 248
Percent By
Number
37.
17.
6.
1
1
63
10
5
0
3
4
8
1
1
6
0
2
4
0
0
15
3
3
6
8
.0
0
0
0
6
.8
Percent By Mass
All
Categories
1.0
3.7
19.6
15.5
41.7
81.5
0.9
3.6
3.4
0
0
7.9
0.3
2.1
0
0
0
2.4
Within
Category
1.2
4.5
24.0
19.0
51.2
100
11.1
46.0
42.6
0
0
100
13.4
86.6
0
0
0
100

-------
            TABLE D-40
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093282 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorn
Particle
Count
23
9
7
0
0
39
6
2
2
0
0
10
22
7
0
0
0
29
558
es)
1
Percent By
Number
4.1
1.6
1.2
0
0
69.9
1.1
0.4
0.4
0
0
1.8
3.9
1.2
0
0
0
5.2
100
Percent By Mass
All
Categories
0.2
0.6
6.0
0
0
6.8
0.02
0.05
0.7
0
0
0.8
0.2
0.5
0
0
0
0.7
100
Within
Category
2.7
8.4
88.8
0
0
100
2.5
6.7
90.8
0
0
100
28.2
71.8
0
0
0
100


-------
             TABLE D-41
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106306

Monitor Location: Elco
Date of Sample: 8/28/76

Category

Fly ash
5-10p
10-20y
20-50^
50-75M
>75p
Totals
Iron Oxide
5-10y
10-20y
20-50p
50-75u
>75y
Totals
Magnetic
Iron
5-10y
10-20u
20-50u
50-75p
>75y
Totals
Particle
Count


136
52
25
0
0
213

0
0
0
0
0
0


0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors : 91 Agency : 98
Calculated Mass (mg) : 107
3
Air Concentration (ug/m ):
Coors : ^3 Agency : ^0
Percent By
Number


26.
10.
5.


9
3
0
0
0
42.

2

0
0
0
0
0
0




0
0
0
0
0
0
Percent By Mass
All
Categories

2.0
6.2
40.5
0
0
48.8

0
0
0
0
0
0


0
0
0
0
0 •
0
Within
Category

4.2
12.8
83.0
0
0
100

0
0
0
0
0
0


0
0
0
0
0
0

-------
             TABLE  D-41
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106306 (Continued)
Category

Quartz
5-10y
10-20u
20-50|j
50-75y
>75U
Totals
Biological
5-10u
10-20y
20-50y
50-75p
>75y
Totals
CaCOQ
5-10y
10-20u
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count

68
20
8
0
0
96
112
68
16
0
0
196
0
0
0
0
0
0
505
(All Categories)
1
Percent By
Number

13.5
4.0
1.6
0
0
19.0
22.2
13.5
3.2
0
0
38.8
0
0
0
0
0
0
100

Percent By Mass
All
Categories
1.7
4.0
21.6
0
0
27.3
1.1
5.4
17.2
0
0
23.8
0
0
0
0
0
0
100

Within
Category
16.2
14.6
79.1
0
0
• 100
4.7
22.8
72.5
0
0
100
0
0
0
0
0
0



-------
             TABLE D-42
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093296 Total Mass of Participates (mg) :
Coors: 193 Agency: 149
'Monitor Location: Downtown Calculated Mass (mg): 246
3
Date of Sample: 8/28/76 ^r Concentration (ug/m ):
Coors : 101 Agency : 70
Category
Flyash
5-lOy
10-20u
20-50y
50-75U
>75M
Totals
Iron Oxide
5-10y
10-20y
20~50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

153
15
9
8
3
188
4
0
0
0
0
4
0
0
0
0
0
0
Percent By
Number

42.7
4.2
2.5
2.2
0.8
52.5
1.1
0
0
0
0
1.1
0
0
0
0
0
0
Percent By Ivkss
All
Categories

1.0
0.8
6.4
28.3
28.6
65.0
0.08
0
0
0
0
0.08
0
0
0
0
0
0
Within
Category

1.5
1.2
9.8
43.5
43.9
100
100
0
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-42
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093296 (Continued)
Category
Quartz
5-10y
10-20p
20-50y
50-75p
>75p
Totals
Biological
5-lOy
10-20y
20-50y
50-75u
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
13
16
3
0
0
32

121
5
3
1
4
134
0
0
0
0
0
0
358
es)
1
Percent By
Number
3.6
4.5
0.8
0
0
8.9

33.8
1.4
0.8
0.3
1.1
37.4
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.1
1.4
3.5
0
0
5.1

0.5
0.2
1.4
2.4
25.4
29.8
0
0
0
0
0
0
100
Within
Category
2.8
27.5
69.7
0
0
100

1.8
0.6
4.7
7.9
85.0
100
0
0
0
0
0
0


-------
             TABLE D-43
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093253 Total Mass of Particulates (mg) :
Coors: 233 Agency:
Monitor Location: Central Lab Calculated Mass (ing): 156
Date of Sample: 8/28/76 Air Concentration (ug/m3):
Coors : 119 Agency : —
Category
Fly-ash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75u
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

262
73
18
2
3
358
44
5
0
0
0
49
0
0
0
0
0
0
Percent By
Number

49.3
13.7
3.4
0.4
0.6
67.4
8.3
0.9
0
0
0
9.2
0
0
0
0
0
0
Percent By Mass
All
Categories

2.7
6.0
20.1
11.2
45.2
85.2
1.5
1.3
0
0
0
2.8
0
0
0
0
0
0
Within
Category

3.2
7.1
23.6
13.1
53.0
100
52.4
47.6
0
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-43
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093253 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categor:
Particle
Count
26
19
3
0
0
48

40
11
2
0
0
53
19
4
0
0
0
23
531
es)
1
Percent By
Number
4.9
3.6
0.6
0
0
9.0

7.5
2.1
0.4
0
0
10.0
3.6
0.8
0
0
0
4.3
100
Percent By Mass
All
Categories
0.4
2.6
5.6
0
0
8.6

0.3
0.6
1.5
0
0
2.4
0.4
0.6
0
0
0
0.9
100
Within
Category
5.2
30.2
64.6
0
0
100

11.6
25.6
62.8
0
0
100
37.2
62.7
0
0
0
100


-------
             TABLE D-44
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106308 Total Mass of Participates (mg) :
Coors: 151 Agency: 143
Monitor Location: Hazelwood Calculated Mass (mg) : 87
Date of Sample: 8/28/76 Air Concentration (yg/m3):
Coors: 71 Agency: 76
Category

Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


191
48
9
2
0
250

0
0
0
0
0
0


0
0
0
0
0
0
Percent By
Number


47.0
11.8
2.2
0.5
0
61.6

0
0
0
0
0
0


0
0
0
0
0
0
Percent By Mass
All
Categories

3.5
7.1
18.0
20.0
0
48.6

0
0
0
0
0
0


0
0
0
0
0
0
Within
Category

7.3
14.6
37.0
41.1
0
100

0
0
0
0
0
0


0
0
0
0
0
0

-------
             TABLE D-44
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106308 (Continued)
Category
Quartz
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20n
20-50u
50-75p
>75y
Totals
CaCOQ
111 O
5-10y
10-20jj
20-50p
50-75)j
>75|j
Totals
TOTALS
(All Category
Particle
Count
7
1
0
0
0
8

94
24
8
0
2
128
19
1
0
0
0
20
406
.es)
Percent By
Number
1.7
0.2
0
0
0
2.0

23.2
5.9
2.0
0
0.5
31.5
4.7
0.2
0
0
0 '
4.9
100
Percent By Mass
All
Categories
0.2
0.2
0
0
0
0.5

1.2
'2.4
10.6
0
35.9
50.0
0.6
0.3
0
0
0
0.9
100
Within
Category
46.7
53.3
0
0
0
100

2.3
4.7
21.3
0
71.7
100
70.4
29.6
0
0
0
100


-------
             TABLE D-45



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106309 Coors: 	 Agency:
Monitor Location: Hazelwood Calculated Mass (mg): 70
T
Date of Sanple: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1106308 Coors: — Agency:
Category
Flyash
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count
77
21
18
1
0
117
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number
38.9
10.6
9.1
0.5
0
59.1
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
1.8
3.8
44.7
12.4
0
62.8
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
2.8
6.1
71.2
19.8
0
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
             TABLE D-45
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number : (gj|J0|ilter ^Continued)
Category

Quartz
5-10M
10-20p
20-50p
50~75M
>75M
Totals
Biological
5-10u
10-20y
20-50)j
50-75u
>75y
Totals
CaCCL

5-10u
10-20y
20-50p
50-75y
>75y
Totals
TOTA15
Particle
Count


6
10
2
0
0
18

36
9
4
2
0
51

11
1
0
0
0
12
198
(All Categories)
Percent By
Number


3.0
5.1
1.0
0
0
9.1

18.2
4.5
2.0
2.0
0
26.7

5.6
0.5
0
0
0
6.1
100

Percent By Mass
All
Categories

0.2
3.1
8.3
0
0
11.6

0.6
1.1
6.6
16.6
0
24.8

0.5
0.3
0
0
0
0.8
100

Within
Category

2.0
26.5
71.6
0
0
100

2.2
4.4
26.6
66.7
0
100

57.9
42.1
0
0
0
100



-------
             TABLE D-46



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093298 Total Mass of Particulates (mg) :
Coors: 289 Agency: 214
Monitor Location: North Braddock Calculated Mass (mg): 113
Date of Sample: 8/28/76 Air Concentration (yg/m ):
Coors: 153 Agency: 108
Category

Flyash
51 Oi i
-i- \J J.J
10-20y
20-50y
50-75y
>75p
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75y

>75y
Totals
Particle
Count


283
50
15
0
1
349

51
7
0
0
0
58


22
4
0
0
o

26
Percent By
Number


56.6
10.0
3.0
0
0.2
69.8

10.2
1.4
0
0
0
11.6


4.4
0.8
0
0
0

5.2
Percent By Miss
All
Categories

4.0
5.7
23.1
0
20.8
53.6

2.4
2.6
0
0
0
5.0


1.0
1.5
0
0
0

2.5
Within
Category

7.5
10.6
43.1
0
38.7
100

47.7
52.3
0
0
0
100


40.8
59.3
0
0
0

100

-------
             TABLE D-46
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093298 (Continued)
Category
Quartz
5-1 Oy
10-20y
20-50|j
50-75y
>75M
Totals
Biological
5-lOu
10-20u
20-50)j
50-75y
>75u
Totals
CaCO0
11 O
5-10y
10-20u
20-50p
50-75ji
>75u
Totals
TOTALS
(All Categor:
Particle
Count

6
11
4
0
0
21

8
0
6
1
1
16
28
2
0
0
0
30
500
.es)
Percent By
Nujnber

1.2
2.2
0.8
0
0
4.2

1.6
0
1.2
0.2
0.2
3.2
5.6
0.4
0
0
0
6.0
100
Percent By Mass
All
Categories

0.1
2.1
10.3
0
0
12.5

0.08
0
6.2
5.1
13.8
25.2
0.7
0.4
0
0
0
1.1
100
Within
Category

1.1
16.7
82.2
0
0
100

0.3
0
24.4
20.4
54.9
100
63.6
36.4
0
0
0
100


-------
             TABLE D-47
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Participates (mg) :
1093299 Coors : 	 Agency : —
Monitor Location: North Braddock Calculated Mass (mg): 292
3
Date of Sample: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1093298) Coors: — Agency:
Category
Flyash
5-lOu
10-20y
20-50U
50-75M
>75U
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count
279
67
13
6
3
368
35
6
0
0
0
41
24
23
2
0
0
49
Percent By
Number
52.7
12.7
2.4
1.1
0.6
69.6
6.6
1.1
0
0
0
7.7
4.5
4.3
0.4
0
0
9.3
Percent By Mass
All
Categories
1.5
3.0
7.8
17.9
24.1
54.3
0.6
0.9
0
0
0
1.5
0.4
3.3
3.9
0
0
7.6
Within
Category
2.8
5.4
14.3
33.0
44.4
100
42.2
57.8
0
0
0
100
5.7
43.4
51.1
0
0
100

-------
             TABLE  D-47
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: ^Cover Fllter )( Continued)
1093299
Category

Quartz
5-10u
10-20y
20-50U
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75jj
Totals
CaCO3
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


9
3
6
1
1
20

12
15
0
0
2
29

15
7
0
0
0
22
529
(All Categories)
Percent By
Number


1.7
0.6
1.1
0.2
0.2
3.8

2.3
2.8
0
0
0.4
5.5

2.8
1.3
0
0
0
4.2
100

Percent By Mass
All
Categories

0.08
0.2
6.0
5.0
13.4
24.6

0.04
0.4
0
0
10.7
11.2

0.1
0.6
0
0
0
0.7
100

Within
Category

0.3
0.9
24.2
20.2
54.4
100

0.4
3.9
0
0
95.7
100

21.1
78.9
0
0
0
100



-------
             TABLE D-48



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106300 Total Mass o£ Particulates (mg) :
Coors: 68 Agency:
Monitor Location: Duquesne II Calculated Mass (mg): 10
Date of Sample: 8/28/76 Air Concentration (yg/m3):
Coors : — Agency :
Category
Flyash
5-lOy
10-20p
20-50p
50-75y
>75M
Totals
Iron Oxide
5-10p
10-20y
20-50u
50-75^
>75U
Totals
Magnetic
Iron
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Particle
Count

18
3
1
0
0
22
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number

43.9
7.3
2.4
0
0
53.6
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories

2.8
3.7
16.6
0
0
23.0
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category

12.0
16.0
72.0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
            TABLE D-48
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106300 (Continued)
Category

Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOQ

5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


3
1
0
0
0
4

4
9
1
1
0
15

0
0
0
0
0
0
41
(All Categories)
Pore lent By
Number


7.3
2.4
0
0
0
9.8

9.8
22.0
2.4
2.4
0
36.6

0
0
0
0
0
0
100

Percent By Mass
All
Categories

0.8
2.0
0
0
0
2.8

0.4
7.4
11.0
55.3
0
74.2

0
0
0
0
0
0
100

Within
Category

27.3
72.7
0
0
0
100

0.6
9.9
14.9
74.6
0
100

0
0
0
0
0
0



-------
             TABLE D-49
RESULTS OF CPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (ing).:
1106301 Coors: 	 Agency:
Monitor Location: Duquesne II Calculated Muss (ing): 30
3
Date of Sample: 8/28/76 Air Concentration (ug/m ):
(Cover Filter for 1106300) Coors: ~ Agency:
Category

Flyash
5-lOu
10-20U
20-50y
50-75y
>75u
Totals
Iron Oxide
5-10u
10-20u
20-50y
50-75u
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75u
>75y
Totals
Particle
Count


3
5
0
0
1
9

0
0
0
0
0
0


0
0
0
0
0
0
Percent By
Number


11.5
19.2
0
0
3.8
34.6

0
0
0
0
0
0


0
0
0
0
0
0
Percent By Mass
All
Categories

0.2
2.2
0
0
79.1
81.5

0
0
0
0
0
0


0
0
0
0
0
0
Within
Category

0.2
2.7
0
0
97.1
97.1

0
0
0
0
0
0


0
0
0
0
0
0

-------
             TABLE D-49
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: (Cover Filter ^Continued)
nnfism
Category
Quartz
5-10u
10-20y
20-50p
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50p
50-75y
>75y
Totals
CaCO,,
O
5-10u
10-20y
20-50y
50-75p
>75y
Totals
TOl^ALS
(All Categori
Particle
Count

2
0
0
0
0
2

2
9
4
0
0
15
0
0
0
0
0
0
26
es)
Percent By
Number

7.7
0
0
0
0
7.7

7.7
34.6
15.4
0
0
57.7
0
0
0
0
0
0
100
Percent By Mass
AVJ
Categories

0.2
0
0
0
0
0.2

0.07
2.6
15.7
0
0
18.3
0
0
0
0
0
0
100
Within
Category

100
0
0
0
0
100

0.4
14.2
85.4
0
0
100
0
0
0
0
0
0


-------
             TABLE D-50



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106302 Total Mass of Particulates (mg) :
Coors : 207 Agency : 271
Monitor Location: Liberty Boro Calculated Mass (mg) : 209
3
Date of Sample: 8/28/76 Air Concentration (yg/m ) :
Coors : 130 Agency : 136
Category
Fly ash
5-lOu
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-lOp
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-lOy
10-20tj
20-50u
50-75p
>75p
Totals
Particle
Count

276
118
20
3
5
422
12
5
0
0
0
17
0
0
0
0
0
0
Percent By
Number

57.0
24.4
4.1
0.6
1.0
87.2
2.5
1.0
0
0
0
3.5
0
0
0
0
0
0
Percent By Mass
Ail
Categories

2.1
7.3
16.6
12.5
56.1
94.6
0.3
1.0
0
0
0
1.3
0
0
0
0
0
0
Within
Category

2.2
7.7
17.6
13.2
59.3
100
23.1
76.9
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-50
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106302 (Continued)
Category
Quartz
5-10y
10-20p
20-50y
50-75U
>75U
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Ca000
O
5-10n
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
9
5
1
0
0
15

5
14
2
0
0
21
7
2
0
0
0
9
484
es)
Percent By
Number
1.8
1.0
0.2
0
0
3.1

1.0
2.9
0.4
0
0
4.3
1.4
0.4
0
0
0
1.8
100
Percent By Mass
All
Categories
0.1
0.5
1.4
0
0
2.0

0.02
0.6
1.1
0
0
1.7
0.1
0.2
0
0
0
0.3
100
Within
Category
5.7
25.4
68.8
0
0
100

1.5
33.6
64.9
0
0
100
30.4
69.6
0
0
0
100


-------
             TABLE D-51



RESULTS OF OPTICAL PARTICLE COURTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106303 Coors: — Agency: —
Monitor Location: Liberty Boro Calculated Mass (mg): 17
Date of Sample: 8/28/76 Air Concentration (yg/m ):
(Cover Filter for 1106302) Coors: — Agency.
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10M
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

191
70
2
0
0
263
12
0
0
0
0
12
0
0
0
0
0
0
Percent By
Number

61.0
22.4
0.6
0
0
84.0
3.8
0
0
0
0
3.8
0
0
0
0
0
0
Percent By t^kss
All
Categories

17.6
51.7
20.0
0
0
89.3
3.6
0
0
0
0
3.6
0
0
0
0
0
0
Within
Category

19.7
57.9
22.4
0
0
100
100
0
0
0
0
100
0
0
0
0
0
0

-------
            TABLE  D-51
RESULTS OF OPTICAL PARTICLE OOUNTS
            (Continued)
Filter Number: ^Cover Fllter \Continued)
1106303
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOo
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOrALS
(All Categori
Particle
Count
11
1
0
0
0
12

14
4
0
0
0
18
8
0
0
0
0
8
313
OS)
Percent By
Number
3.5
0.3
0
0
0
3.8

4.5
1.3
0
0
0
5.8
2.6
0
0
0
0
2.6
100
Percent By Mass
All
Categories
1.7
1.2
0
0
0
2.9

0.9
2.0
0
0
0
2.8
1.3
0
0
0
0
1.3
100
Within
Category
57.9
42.1
0
0
0
100

30.4
69.6
0
0
0
100
100
0
0
0
0
100


-------
             TABLE D-52
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106304 Total Mass of Participates (mg) :
Coors: 147 Agency: 215
Monitor Location: Clairton Calculated Mass (mg) : 126
3
Date of Sample: 8/28/76 Air Concentration (yg/m ):
Coors : 61 Agency : 115
Category
Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75|j
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75]j
Totals
Particle
Count
183
44
12
1
1
241
16
0
0
0
0
16
0
0
0
0
0
0
Percent By
Number
52.4
12.6
3.4
0.3
0.3
69.0
4.6
0
0
0
0
4.6
0
0
0
0
0
0
Percent By Mass
All
Categories
2.3
4.5
16.6
6.9
18.6
49.0
0.7
0
0
0
0
0.7
0
0
0
0
0
0
Within
Category
4.8
9.2
33.9
14.1
38.0
100
100
0
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-52
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106304 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO0
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
9
17
5
0
0
31

20
24
3
4
1
52
9
0
0
0
0
9
349
es)
Percent By
Number
2.6
4.9
1.4
0
0
8.9

5.7
6.9
0.8
1.1
0.3
14.9
2.6
0
0
0
0
2.6
100
Percent By Mass
All
Categories
0.2
2.9
11.5
0
0
14.6

0.2
1.6
2.8
18.5
12.4
35.5
0.2
0
0
0
0
0.2
100
Within
Category
1.3
19.8
78.8
0
0
100

0.5
4.6
7.8
52.0
35.0
100
100
0
0
0
0
100


-------
             TABLE D-53
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093280 Total Mass ol Particulates (mg) :
Coors: 210 Agency: 202
Monitor Location: Airport Calculated Mass (mg): 168
3
Date of Sample: 8/28/76 Air Concentration (ug/m ):
Coors: 110 Agency: 97
Category
Flyash
5-lOy
10-20y
20-50)j
50-75M
>75M
Totals
Iron Oxide
5-10p
10-20u
20-50u
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20||
20-50u
50-75u
>75jj
Totals
Particle
Count
145
47
12
0
0
204
24
4
0
0
0
28
0
0
0
0
0
0
Percent By
Number
36.6
11.9
3.0
0
0
51.5
6.1
1.0
0
0
0
7.1
0
0
0
0
0
0
Percent By Mass
All
Categories
1.4
3.6
12.4
0
0
17.4
0.8
1.0
0
0
0
1.8
0
0
0
0
0
0
Within
Category
8.0
20.7
71.4
0
0
100
42.8
57.1
0
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-53
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093280 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-lOp
10-20y
20-50p
50-75U
>75y
Totals
CaOOQ
5-10y
10-20^
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
46
18
13
3
0
80
10
30
40
0
0
80
3
1
0
0
0
4
396
es)
1
Percent By
Number
11.6
4.5
3.3
0.8
0
20.2
2.5
7.6
10.1
0
0
20.2
0.8
0.2
0
0
0
1.0
100
Percent By Mass
All
Categories
0.7
2.3
22.4
25.9
0
51.4
0.06
1.5
27.6
0
0
29.2
0.05
0.1
0
0
0
0.2
100
Within
Category
1.4
4.5
43.7
50.4
0
100
0.2
5.2
94.5
0
0
100
27.3
72.7
0
0
0
100


-------
             TABLE D-54
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093278 Total Mass of Particulates (mg) :
Coors: 174 Agency: 120
Monitor Location: South Fayette Calculated Mass (mg): 80
3
Date of Sample: 8/28/76 Air Concentration (yg/rrf ):
Coors: 91 Agency: 59
Category

Flyash
5-10y
10-20y
20-50p
50-75p
>75p
Totals
Iron Oxide
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


83
23
4
0
0
110

21
0
0
0
0
21


0
0
0
0
0
0
Percent By
Number


27.1
7.5
1.3
0
0
35.9

6.9
0
0
0
0
6.9


0
0
0
0
0
0
Percent By Mass
All
Categories

1.7
3.7
8.7
0
0
14.1

1.4
0
0
0
0
1.4


0
0
0
0
0
0
Within
Category

11.9
26.3
61.8
0
0
100

100
0
0
0
0
100


0
0
0
0
0
0

-------
             TABLE  D-54
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093278 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
' G
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
10
10
12
0
0
32

41
74
4
3
0
122
18
3
0
0
0
21
306
es)
Percent By
Number
3.3
3.3
3.9
0
0
10.4

13.4
24.2
1.3
1.0
0
39.9
5.9
1.0
0
0
0
6.9
100
Percent By Mass
All
Categories
0.3
2.7
43.7
0
0
46.7

0.6
8.0
5.8
21.9
0
36.2
0.6
0.9
0
0
0
1.5
100
Within
Category
0.7
5.7
93.5
0
0
100

1.5
22.0
16.1
60.4
0
100
42.8
57.1
0
0
0
100


-------
             TABLE D-55



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093271 Total Mass of Particulates (mg) :
Coors: 335 Agency: 355
Monitor Location: Baden Calculated Mass (mg) : 561
3
Date of Sample: 9/9/76 Air Concentration (jjg/m ):
Coors: 207 Agency: 185
Category
Flyash
5-lOu
10-20u
20-50p
50-75p
>75y
Totals
Iron Oxide
5-10u
10-20^
20-50u
50-75y
>75M
Totals
Magnetic
Iron
5-10p
10-20M
20-50|j
50-75y
>75p
Totals
Particle
Count
281
121
26
6
5
439
37
16
0
0
0
53
0
0
0
0
0
0
Percent By
Number
46.8
20.2
4.3
1.0
0.8
73.2
6.2
2.7
0
0
0
8.8
0
0
0
0
0
0
Percent By Mass
All
Categories
0.8
2.8
8.1
9.3
20.9
41.9
0.3
1.2
0
0
0
1.5
0
0
0
0
0
0
Within
Category
1.9
6.6
19.3
22.2
49.9
100
22.4
77.6
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-55
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093271 (Continued)
Category
Quartz
5-lOy
10-20^
20-50p
50-75M
>75y
Totals
Biological
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
29
14
2
0
0
45

5
29
2
1
19
56
7
0
0
0
0
7
600
es)
Percent By
Number
4.8
2.3
0.3
0
0
7.5

0.8
4.8
0.3
0.2
3.2
9.3
1.2
0
0
0
0
1.2
100
Percent By Mass
All
Categories
0.1
0.5
1.0
0
0
1.7

0.01
0.4
0.4
1.0
52.9
54.8
0.04
0
0
0
0
0.04
100
Within
Category
8.1
31.3
60.5
0
0
100

0.2
0.8
0.8
1.9
96.5
100
100
0
0
0
0
100


-------
             TABLE D-56
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093269 Total Mass of Particulates (mg) :
Coors: 387 Agency: 339
Monitor Location: Beaver Falls Calculated Mass (mg): 271
T
Date of Sample: 9/9/76 Air Concentration (ug/nf ):
Coors: 232 Agency: 168
Category
Flyash
5-10u
10-20y
20-50p
50-75p
>75y
Totals
Iron Oxide
5-10u
10-20u
20-50p
50-75p
>75\i
Totals
Magnetic
Iron
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Particle
Count

277
65
17
6
3
368
21
10
0
0
0
31
1
12
1
0
0
14
Percent By
Number

54.1
12.7
3.3
1.2
0.6
71.9
4.1
2.0
0
0
0
6.0
0.2
2.3
0.2
0
0
2.7
Percent By Mass
All
Categories

1.6
3.1
10.9
19.3
26.0
61.0
0.4
1.6
0
, 0
0
2.0
0.02
1.9
2.1
0
0
4.0
Within
Category

2.7
5.1
17.9
31.7
42.6
100
20.8
79.2
0
0
0
100
0.5
46.8
52.8
0
0
100

-------
             TABLE D-56
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093269 (Continued)
Category
Quartz
5-10p
10-20p
20-50y
50-75U
>75y
Totals
Biological
5-lOy
10-20y
20-50y
50-75p
>75y
Totals
CaOO,3
\j
5-lOp
10-20u
20-50y
50-75y
>75jj
Totals
TOTALS
(All Category
Particle
Count
14
16
2
1
0
33

10
27
7
6
1
51
11
3
1
0
0
15
512
_es)
Percent By
Number
2.7
3.1
0.4
0.2
0
6.4

2.0
5.3
1.4
1.2
0.2
10.0
2.1
0.6
0.2
0
0
2.9
100
Percent By Mass
All
Categories
0.1
1.3
2.1
5.4
0
8.9

0.04
0.8
3.0
12.9
5.8
22.6
0.1
0.2
1.2
0
0
1.5
100
Within
Category
1.6
14.2
24.0
60.2
0
100

0.2
3.8
13.3
57.1
25.6
100
7.7
16.8
75.6
0
0
100


-------
             TABLE D-57



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093267 Total Mass of Particulates (mg) :
Coors: 296 Agency: 330
Monitor Location: Koppel Calculated Mass (nig): 239
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors : 156 Agency : 174
Category

Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


292
71
21
7
3
394

15
1
0
0
0
16


0
0
0
0
0
0
Percent By
Number


59.8
14.5
4.3
1.4
0.6
80.7

3.1
0.2
0
0
0
3.3


0
0
0
0
0
0
Percent By Mass
All
Categories

2.0
3.8
15.3
25.5
.29.5
76.1

0.3
0.2
0
0
0
0.5


0
0
0
0
0
0
Within
Category

2.6
5.0
20.1
33.6
38.7
100

65.2
34.8
0
0
0
100


0
0
0
0
0
0

-------
             TABLE D-57
RESULTS OF OPTICAL PARTICLE COUNTS
            (C< .11 tinned)
Filter Number: 1093267 (Continued)
Category
Quartz
5-10p
10-20p
20-50p
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Ca000
11 " O
5-lOy
10-20y
20-50y
50-75y
>75p
Totals
TOFALS
(All Category
Particle
Count

25
14
6
1
0
46

18
5
3
0
1
27
3
2
0
0
0
5
488
es)
1
Percent By
Number

5.1
2.9
1.2
0.2
0
9.4

3.7
1.0
0.6
0
0.2
5.5
0.6
0.4
0
0
0
1.0
100
Percent By Mass
All
Categories

0.3
1.2
7.3
6.1
0
14.9

0.08
0.2
1.4
0
6.5
8.3
0.04
0.2
0
0
0
0.2
100
Within
Category

1.9
8.4
48.9
40.8
0
100

1.0
2.2
17.6
0
79.2
100
15.8
84.2
0
0
0
100


-------
             TABLE D-58
RESULTS OF OPrlCAL PARTICLE COUNTS
Filter Number: mo928 Total Mass of Particulates (mg) :
Coors: 333 Agency: 287
Monitor Location: , . Calculated Mass (mg): 341
Township fe °
2
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 178 Agency: 160
Category
Fly ash
5-lQii
10-20y
20-50|j
50-75y
>75y
Totals
Iron Oxide
5-lOy
10-20n
20-50n
50-75u
>75M
Totals
Magnetic
Iron
5-10y
10-20(j
20-50|j
50-75u
>75(j
Totals
Particle
Count

0
0
55
2
0
57
0
0
0
0
0
0
0
0
0
0
0
0
Percent By
Number

0
0
49.1
1.8
0
50.9
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
28.1
5.1
0
33.2
0
0
0
0
0
0
0
0
0
0
0
0
Wi thin
Category

0
0
84.6
15.4
0
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
            TABLE D-58
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1110928 (Continued)
Category
Quartz
5-10y
10-20n
20-50p
50-75)j
>75y
Totals
Biological
5-10u
10-20n
20-50u
50-75U
>75y
Totals
CaC00
o
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Category
Particle
Count
0
0
47
6
0
53

0
0
1
0
0
1
0
0
1
0
0
1
112
_os)
1
Percent By
Number
0
0
42.0
5.4
0
47.3

0
0
0.9
0
0
0.9
0
0
0.9
0
0
0.9
100
Percent By Mass
All
Categories
0
0
40.0
25.6
0
65.5

0
0
0.3
0
0
0.3
0
0
0.9
0
0
0.9
100
Within
Category
0
0
61.0
39.0
0
100

0
0
100
0
0
100
0
0
100
0
0
100


-------
             TABLE  D-59
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter)
1110929
Monitor Location: Brighton
Township
Date of Sample: 9/9/76
(Cover Filter to 1110928)
Category
Flyash
5-lO[j
10-20)j
20-50p
50-75p
>75M
Totals
Iron Oxide
5-10y
10-20u
20-50y
50-75U
>75M
Totals
Magnetic
Iron
5-10y
10-20M
20-50M
50-75y
>75y
Totals
Particle
Count

0
0
14
2
1
17
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Participates (ing) :
Coors : — Agency :
Calculated Mass (mg): 180
Air Concentration (vig/rrT ):
Coors : — Agency : —
Percent By
Number


0
0
36.
5.
2.
44.
8
3
6
7
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
13.5
9.6
13.0
36.2
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category

0
0
37.4
26.7
35.9
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
            TABLE D-59
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
(Cover Filter)
Filter Number: 1110929 (Continued)
Category

Quartz
5-10y
10-20y
20-50M
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOOQ
o
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


0
0
15
2
1
18

0
0
3
0
0
3

0
0
0
0
0
0
38
(All Categories)
Percent By
Number


0
0
39.5
5.3
2.6
47.4

0
0
7.9
0
0
7.9

0
0
0
0
0
0
100

Percent By Mass
All
Categories

0
0
24.1
16.1
21.7
61.9

0
0
1.9
0
0
1.9

0
0
0
0
0
0
100

Within
Category

0
0
39.0
26.0
35.0
100

0
0
100
0
0
100

0
0
0
0
0
0



-------
             TABLE  D-60



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093292 Total Mass of Participates (mg):
Coors: 667 Agency: 688
Monitor Location: Midland Calculated Mass (mg): 473
3
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 404 Agency: 341
Category
Flyash
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20^
20-50y
50-75u
>75y
Totals
*
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

0
0
56
4
5
65
0
0
10
3
0
13
0
0
0
0
0
0
Percent By
Number

0
0
55.4
4.0
5.0
64.4
0
0
9.9
3.0
0
12.9
0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
20.6
7.4
24.8
52.8
0
0
12.0
18.1
0
30.1
0
0
0
0
0
0
Within
Category

0
0
39.0
14.0
47.0
100
0
0
40.0
60.0
0
100
0
0
0
0
0
0

-------
             TABLE  D-60
RESULTS OF OPTICAL PARTICLE COUNTS
            (Gonlinued)
Filter Number: 1093292 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75y
Totals
CaOCL
5-1 Op
10-20p
20-50p
50-7 5y
>75y
Totals
TOTALS
(All Categor]
Particle
Count

0
0
15
1
0
16

0
0
6
0
1
7
0
0
0
0
0
0
101
es)
Percent By
Number

0
0
14.8
1.0
0
15.8

0
0
5.9
0
1.0
6.9
0
0
0
0
0
0
100
Percent By Mass
All
Categories

0
0
9.2
3.1
0
12.3

0
0
1.5
0
3.3
4.8
0
0
0
0
0
0
100
Within
Category

0
0
75.0
25.0
0
100

0
0
30.8
0
69.2
100
0
0
0
0
0
0


-------
             TABLE D-61
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter)
1093293
Monitor Location: Midland
Date of Sanple: 9/9/76
(Cover Filter to 1093292)
Category
Flyash
5-J.On
10-20y
20-50^
50-75M
>75y
Totals
Iron Oxide
5-10|j
10-20y
20-50y
50-75y
>75)j
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

0
0
42
2
0
44
0
0
0
0
0
0
0
0
0
0
0
0
Perc
Nur

Total Mass of Particulates (mg) :
Coors : — Agency :
Calculated toss (mg): 328
3
Air Concentration (yg/m ):
Coors : — Agency :
Bnt By
Tiber

0
0
61.
2.
8
9
0
64.
7
0
0
0
0
0
0
0
0
0
0
0
0
Pe;rcent By Mass
AIL
Categories

0
0
22.3
5.3
0
27.6
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category

0
0
80.8
19.2
0
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
            TABLE D-61

RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
„.,, M . (Cover Filter),
Filter Number: 1093293 t Continued)
Category
Quartz
5-10u
10-20u
20-50u
50-75M
>75y
Totals
Biological
5-10M
10-20u
20-50y
50-75u
>75y
Totals
CaC00
5-lOn
10-20u
20-50p
50-75p
>75y
Totals
TOTALS
(All Categori
Particle
Count

0
0
7
0
1
8
0
0
5
0
11
16
0
0
0
0
0
0
68
es)
Percent By
Number

0
0
10.3
0
1.5
11.8
0
0
7.4
0
16.2
23.5
0
0
0
0
0
0
100
Percent By Mass
All
Categories

0
0
6.2
0
11.9
18.1
0
0
1.8
0
52.5
54.2
0
0
0
0
0
0
100
Within
Category

0
0
34.2
0
65.8
100
0
0
3.3
0
96.7
100
0
0
0
0
0
0


-------
             TABLE  D-62



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106379

Monitor Location: Elco
Date of Sample: 9/9/76

Category
Flyash
5-1 On
10-20y
20-50^
50-75p
>75U
Totals
Iron Oxide
5-10M
10-20M
20-50p
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20u
20-50y
50-75y
>75p
Totals
Particle
Count
0
0
25
5
0
30
0
0
3
0
0
3
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors : 137 Agency : —
Calculated Mass (ing): 229
3
Air Concentration (yg/m ):
Coors : 84 Agency :
Percent By
Number
0
0


39.1
7.8
0

46.9
0
0


4.7
0
0


4.7
0
0
0
0
0





0
Percent By Mass
All
Categories
0
0
19.0
19.0
0
38.0
0
0
7.4
0
0
7.4
0
0
0
0
0
0
Within
Category
0
0
50.0
50.0
0
100
0
0
100
0
0
100
0
0
0
0
0
0

-------
             TABLE D-62
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106379 (Continued)
Category
Quartz
5-1 Oy
10-20y
20-50ij
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOO.D
5-10p
10-20u
20-50y
50-75y
>75M
Totals
TOTALS
(All Categon
Particle
Count
0
0
14
2
0
16
0
0
9
5
1
15
0
0
0
0
0
0
64
OS)
Percent By
Number
0
0
21.9
3.1
0
25.0
0
0
14.1
7.8
1.6
23.4
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
17.7
12.7
0
30.4
0
0
4.6
12.7
6.8
24.1
0
0
0
0
0
0
100
Within
Category
0
0
58.3
41.7
0
100
0
0
19.0
52.7
28.4
100
0
0
0
0
0
0


-------
             TABLE D-63
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106323 Total Ntuss ol' ParLiculates (nig):
Coors: 5-7 Agency: 337
Monitor Location: Downtown Calculated Mass (mg): 23.7
Date of Sample: 9/9/76 Air Concentration (ug/m3):
Coors : — Agency : 159
Category
Fly ash
5-10p
10-20y
2Q-50y
50-75 y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75M
>75y
Totals
Magnetic
Iron
5-10y
10-20]j
20-50y
50-75y
>75y
Totals
Particle
Count

17
3
2
1
0
23
0
1
0
0
0
1
0
0
0
0
0
0
Percent By
Number

43.6
7.7
5.1
2.6
0
59.0
0
2.6
0
0
0
2.6
0
0
0
0
0
0
Percent By Mass
All
Categories

1.2
1.6
14.7
36.7
0
54.2
0
1.8
0
0
0
1.8
0
0
0
0
0
0
Within
Category

2.1
3.0
27.1
67.8
0
100
0
100
0
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-63
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106323 (Continued)
Category
Quartz
5-10u
10-20p
20-50n
50-75y
>75y
Totals
Biological
5-10p
10-20y
20-50y
50-75p
>75y
Totals
CaC00
' O
5-10y
10-20u
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
6
2
1
0
0
9

0
0
6
0
0
6
0
0
0
0
0
0
39
es)
Percent By
Number
15.4
5.1
2.6
0
0
23.1

0
0
15.4
0
0
15.4
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0.7
1.8
12.2
0
0
14.7

0
0
29.3
0
0
29.3
0
0
0
0
0
0
100
Within
Category
4.6
12.3
83.1
0
0
100

0
0
100
0
0
100
0
0
0
0
0
0


-------
             TABLE D-64
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106327 Total Mass of Particulates (mg) :
Coors: 429 Agency: 428
Monitor Location: Central Lab Calculated Mass (mg): 203
Date of Sample: 9/9/76 Air Concentration (yg/m ) :
Coors : 219 Agency : 235
Category
Flyash
5-1 Ou
10-20y
20-50p
50-75)j
>75M
Totals
Iron Oxide
5-10y
10-20y
20-50u
50-75U
>75M
Totals
Magnetic
11X511
5-10u
10-20n
20-50u
50-75|j
>75y
Totals
Particle
Count

326
107
21
4
3
461
23
7
0
0
0
30
0
0
0
0
0
0
Percent By
Number

58.1
19.1
3.7
0.7
0.5
82.2
4.1
1.2
0
0
0
5.3
0
0
0
0
0
0
Percent By Mass
All
Categories

2.6
6.8
18.0
17.2
34.7
79.2
0.6
1.4
0
0
0
2.0
0
0
0
0
0
0
Within
Category

3.3
8.6
22.7
21.7
43.8
100
29.1
70.9
0
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-64
RESULTS OF OPTICAL PARTICLE
            (Continued)



Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
1 " \J
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTAIS
(All Categor:
Filter Number
Particle
Count

13
12
9
0
0
34

0
12
6
0
0
18

16
2
0
0
0
18
561
.es)
i
' : 1106327
Percent By
Number

2.3
2.1
1.6
0
0
6.1

0
2.1
1.1
0
0
3.2

2.8
0.4
0
0
0
3.2
100
(Continued)
Percent
All
Categories

0.2
1.3
12.9
0
0
14.3

0
0.5
3.4
0
0
3.9

0.2
0.2
0
0
0
3.9
100

By Mass
Within
Category

1.2
8.9
89.9
0
0
100

0
12.9
87.1
0
0
100

50.0
50.0
0
0
0
100


-------
             TABLE  D-65
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter)
1106328
Monitor Location: Central Lab
Date of Sample: 9/9/76
(Cover Filter for 1106327
Category
Flyash
5-10ii
10-20p
20-50M
50-75U
>75p
Totals
Iron Oxide
5-10p
10-20M
20-50p
50-75y
>75^i
Totals
Magnetic
Iron
5-10u
10-20u
20-50)j
50-75y
>75p
Totals
Part icle
Count

264
76
25
6
7
378
12
15
0
0
0
27
0
0
0
0
0
0
Total Mass of Porticulates (mg) :
Coors : 	 Agency :
Calculated Mass (mg): 357
3
Air Concentration (pg/m ):
Coors : — Agency :
Percent By
Number


56.5
16.3
5.4
1.3
1.5
80.9
2.6
3.2



0
0
0
5.8





0
0
0
0
0
0.
Percent By Mass
All
Categories

1.2
2.7
12.2
14.6
46.0
76.8
0.2
1.8
0
0
0
1.9
0
0
0
0
0
0
Within
Category

1.6
3.6
15.9
19.1
59.9
100
9.1
90.9
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-65
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: ^i^32glte?i>ntlnued)
Category
Quartz
5-10M
10-20y
20-50u
50-75U
>75y
Totals
Biological
5-lOjj
10-20y
20-50y
50-75y
>75y
Totals
CaOCL
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
21
6
4
0
1
32
1
8
4
3
0
16
14
0
0
0
0
14
467
es)
Percent By
Number
4.5
1.3
0.8
0
0.2
6.8
0.2
1.7
0.8
0.6
0
3.4
3.0
0
0
0
0
3.0
100
Percent By Mass
All
Categories
0.2
0.4
3.2
0
11.0
14.7
0.003
0.2
1.3
4.9
0
6.4
0.1
0
0
0
0
0.1
100
Within
Category
1.1
2.4
22.1
0
74.4
100
0.05
3.0
20.4
76.5
0
100
100
0
0
0
0
100


-------
             TABLE D-66
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106353 Total Muss of Participates (mg) :
Coors: 280 Agency: 238
Monitor Location: Hazelwood Calculated Mass (mg): 232
Date of Sample: 9/9/76 Air Concentration (yg/m ) :
Coors: 137 Agency: 140
Category

Flyash
5-10u
10-20y
20-50jj
50-75y
>75y
Totals
Iron Oxide
5-10p
10-20n
20-50y
50-75p
>75y
Totals
Magnetic
Iron
5-lOy
10-20y
20-50y
50-75M
>75M
Totals
Particle
Count


424
128
14
2
4
572

52
14
3
0
0
69


0
0
0
0
0
0
Percent By
Number


55.8
16.8
1.8
0.3
0.5
75.3

6.8
1.8
0.4
0
0
9.1


0
0
0
0
0
0
Percent By Miss
All
Categories

2.9
7.1
10.5
7.5
40.5
68.6

1.2
2.5
7.4
0
0
11.1


0
0
0
0
0
0
Within
Category

4.3
10.4
15.3
11.0
59.0
100

10.6
22.9
66.4
0
0
100


0
0
0
0
0
0

-------
             TABLE  D-66
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106353 (Continued)
Category

Quartz
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaOO
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


56
14
2
2
0
74

16
6
0
1
0
23
20
2
0
0
0
22
760
(All Categories)
Percent By
Number


7.4
1.8
0.3
0.3
0
9.7

2.1
0.8
0
0.1
0
3.0
2.6
0.3
0
0
0
2.9
100

Percent By Mass
All
Categories

0.6
1.3
2.5
12.5
0
17.0

0.07
0.2
0
2.5
0
2.8
0.2
0.4
0
0
0
0.4
100

Within
Category

3.8
7.6
14.7
73.8
0
100

2.6
7.9
0
89.4
0
100
55.6
44.4
0
0
0
100



-------
             TABLE D-67
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6386

Monitor Location: North Braddock
Date of Sample: 9/9/76

Category
Flyash
5-1 Op
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75)j
>75y
Totals
Particle
Count
349
70
15
5
8
447
79
8
0
0
0
87
9
2
0
0
0
11
Total Mass oi.' Participates (mg) :
Coors: 474 Agency: 532
Calculated Mass (mg): 304
3
Air Concentration (yg/m ):
Coors: 248 Agency: 272
Percent By
Number
54.0
10.8
2.3
0.8
1.2
69.2
12.2
1.2



0
0
0
13.5
1.4
0.3



0
0
0
1.7
Percent By Mass
All
Categories
1.8
3.0
8.6
14.3
61.6
89.4
1.4
1.1
0
0
0
2.5
0.2
0.3
0
0
0
0.4
Within
Category
2.1
3.3
9.6
16.0
69.0
100
55.2
44.7
0
0
0
100
36.0
64.0
0
0
0
100

-------
           (  TABLE D-67
RESULTS OF OPTICAL PARTICLE COUNTS
            (Gmtinued)

rVl t" £* ( YC) T*\7

Quartz
5-lOy
10-20y
20-50U
50-75M
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO0
\J
5-10y
10-20y
20-50p
50-75y
>75y
Totals
TOTALS
(All Categon
Filter Number
Particle
Count

40
15
6
0
0
61

7
0
0
0
0
7

29
4
0
0
0
33
646
1
' : 1106386
Percent By
Number

6.2
2.3
0.9
0
0
9.4

1.1
0
0
0
0
1.1

4.5
0.6
0
0
0
5.1
100
(Continued)
Percent
All
Categories

0.4
1.0
5.7
0
0
7.1

0.02
0
0
0
0
0.02

0.3
0.3
0
0
0
0.6
100

By Mass
Within
Category

4.9
14.8
80.2
0
0
100

100
0
0
0
0
100

47.5
52.4
0
0
0
100


-------
             TABLE D-68



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: H06383 Total Muss of Particulates (mg) :
Coors: 423 Agency: 524
Monitor Location: Duquesne II Calculated Mass (mg): 195
3
Date ol Sample: 9/9/76 Air Concentration (ug/m ):
Coors: 242 Agency: 260
Category
Flyash
5-lOiJ
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75p
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

312
93
35
1
2
443
66
12
0
0
0
78
0
0
0
0
0
0
Percent By
Number

52.3
15.6
5.9
0.2
0.3
74.2
11.0
2.0
0
0
0
13.1
0
0
0
0
0
0
Percent By Mass
All
Categories

2.6
6.2
31.3
4.5
24.1
68.6
1.8
2.6
0
0
0
4.4
0
0
0
0
0
0
Within
Category

3.8
9.0
45.6
6.5
35.1
100
40.7
59.2
0
0
0
100
0
0
0
0
0
0

-------
            TABLE D-68
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106383 (Continued)
Category
Quartz
5-10u
10-20p
2O-50u
50-75y
>75p
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10p
10-20M
20-50n
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
30
17
0
0
0
47

0
7
0
0
3
19
19
0
0
0
0
19
597
es)
Percent By
Number
5.0
2.8
0
0
0
2.9

0
1.2
0
0
0.5
1.7
3.2
0
0
0
0
3.2
100
Percent By Mass
All
Gitegories
0.4
1.9
0
0
0
2.3

0
,0.3
0
0
24.1
24.4
0.3
0
0
0
0
0.3
100
Within
Category
18.1
81.9
0
0
0
100

0
1.3
0
0
98.7
100
100
0
0
0
0
100


-------
             TABLE D-69



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6388

Monitor Location: Liberty Boro
Date of Sample: 9/9/76

Category
Fly ash
5-lOu
10-20y
20-50y
50-75y
>75M
Totals
Iron Oxide
5-10u
lO20n
20-50M
50-75y
>75(j
Totals
Magnetic
Iron
5-10M
10-20p
20-50U
50-75u
>75y
Totals
Particle
Count

0
0
84
17
12
113
0
0
5
0
0
5
0
0
0
0
0
0
Total Moss of Participates (mg) :
Coors : 470 Agency : 582
Calculated Mass (mg): 607
3
Air Concentration (ug/m ):
Ccxn-s: 289 Agency: 315
Percent By
Number


0
0
70.
14.
10.
94.
0
2
0
2
0
0
4.
2
0
0
4.
2
0
0
0
0
0
0
Percent By Miss
AIL
Categories

0
0
24.1
24.4
46.4
94.9
0
0
4.7
0
0
4.7
0
0
0
0
0
0
Within
Category

0
0
25.4
25.7
48.9
100
0
0
100
0
0
100
0
0
0
0
0
0

-------
             TABLE D-69
RESULTS OF OFI'ICAL PARTI CUE COUNTS
            (Continued)
Filter Number: 1106388 (Continued)
Category

Quartz
5-10u
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50p
50-75y
>75M
Totals
CaC03
5-1 Oy
10-20y
20-50ij
50-75u
>75p
Totals
TOTALS
(All Categori
Particle
Count

0
0
0
0.
0
0

0
0
2
0
0
2
0
0
0
0
0
0
120
es)
1
Percent By
Number

0
0
0
0
0
0

0
0
1.7
0
0
1.7
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
0
0
0
0

0
0
0.4
0
0
0.4
0
0
0
0
0
0
100
Wi thin
Category
0
0
0
0
0
0

0
0
100
0
0
100
0
0
0
0
0
0


-------
             TABLE D-70



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
(Filter Redone) 1106387 ^^ __ ^^ __
Monitor Location: Liberty Boro Calculated Mass (mg): 246
3
Date of Sample: 9/9/76 Air Concentration (ug/m ):
(Cover Filter for 1106388) Coors: — Agency:
Category

Fly ash
5-10u
10-20y
20-50p
50-75p
>75y
Totals
Iron Oxide
5-10M
10-20jj
20-50u
50-75p
>75M
Totals
Magnetic
Iron
5-10y
10-20)j
20-50y
50-75u
>75y
Total's
Particle
Count


239
78
16
1
5
339

53
10
2
0
0
65


14
7
0
0
0
21
Percent By
Number


46.0
15.0
3.1
0.2
1.0
65.3

10.2
1.9
0.4
0
0
12.5


2.7
1.3
0
0
0
4.0
Percent By Mass
All
Categories

1.6
4.1
11.3
3.5
47.6
68.2

1.1
1.7
4.6
0
0
7.5


0.3
1.2
0
0
0
1.5
Within
Category

2.3
6.0
16.6
5.2
69.9
100

15.2
22.9
61.9
0
0
100


20.0
80.0
0
0
0
100

-------
            TABLE D-70
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
(Cover Filter)
Fi Iter Number : H06387 (Continued)
Category

Quartz
5-10y
10-20M
20-50y
50-75M
>75p
Totals
Biological
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
CaC00
O
5-10y
10-20y
20-50n
50-75)j
>75M
Totals
TOTALS
Particle
Count

20
6
7
0
0
33

3
4
0
0
2
9
47
5
0
0
0
52
519
(All Categories)
1
Percent By
Number

3.8
1.2
1.3
0
0
6.4

0.6
0.8
0
0
0.4
1.7
9.0
1.0
0
0
0
10.0
100

Percent By Mass
All
Categories
0.2
0.5
8.2
0
0
9.0

0.01
0.1
0
0
12.7
12.9
0.6
0.5
0
0
0
1.0
100

Within
Category
2.4
5.8
91.8
0
0
100

0.1
1.1
0
0
98.8
100
54.0
46.0
0
0
0
100



-------
             TABLE  D-71
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106381 Total Mass of Particulates (mg) :
Coors: 293 Agency: 330
Monitor Location: Clairton Calculated Muss (mg): 295
3
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 127 Agency: 178
Category

Fly ash
5-10d
10-20y
20-50|j
50-75p
>75U
Totals
Iron Oxide
5-10y
10-20y
20-50p
50-75p
>75M
Totals
Magnetic
Iron
5-10u
10-20u
20-50jj
50-75n
>75p
Totals
Particle
Count


0
0
66
6
2
74

0
0
3
0
0
3


0
0
0
0
0
0
Percent By
Number


0
0
72.5
6.6
2.2
81.3

0
0
3.3
0
0
3.3


0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
38.9
17.7
15.9
72.6

0
0
5.8
0
0
5.8


0
0
0
0
0
0
Within
Category

0
0
53.7
24.4
21.9
100

0
0
100
0
0
100


0
0
0
0
0
0

-------
             TABLE  D-71
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1106381 (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-lOu
10-20u
20-50p
50-75y
>75y
Totals
CaCO,
O
5-lOp
10-20^
20-50(j
50-75y
>75M
Totals
TOTALS
(All Categori
Particle
Count

0
0
9
1
0
10
0
0
0
4
0
4
0
0
0
0
0
0
91
OS)
Per i1, en t By
Number

0
0
9.9
1.1
0
11.0
0
0
0
4.4
0
4.4
0
0
0
0
0
0
100
Percent By Muss
Al 1
Categories

0
0
8.8
4.9
0
13.8
0
0
0
7.9
0
7.9
0
0
0
0
0
0
100
Wi thin
Category

0
0
64.3
35.7
0
100
0
0
0
100
0
100
0
0
0
0
0
0


-------
             TABLE  D-72



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Participates (mg) :
1106382 Coors: 	 Agency:
Monitor Location: Clairton Calculated Mass (mg): 175
3
Date of Sample: 9/9/76 Air Concentration (yg/nf):
(Cover Filter to 1106381) Coors: — Agency:
Category
Flyash
5-10iJ
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

0
0
19
2
2
23
0
0
2
0
0
2
0
0
0
0
0
0
Percent By
Number

0
0
48.7
5.1
5.1
59.0
0
0
5.1
0
0
5.1
0
0
0
0
0
0
Percent By Mass
• All
Categories

0
0
18.9
10.0
26.8
55.7
0
0
6.5
0
0
6.5
0
0
0
0
0
0
Within
Category

0
0
34.0
17.9
48.2
100
0
0
100
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-72
RESULTS OF OPHCAL PARTICLE COUNTS
            (G)iitinued)
Filter Number: (C°ver Filter(>Continued)
1106382
Category7
Quartz
5-10u
10-20p
20-50n
50-75M
>75p
Totals
Biological
5-10p
10-20y
20-50u
50-75y
>75y
Totals
CaOOQ
O
5-10(j
10-20u
20-50M
50-75y
>75y
Totals
TOTALS
(All Categor]
Particle
Count
0
0
5
2
0
7

0
0
6
0
1
7
0
0
0
0
0
0
39
.es)
I
Percent By
Number
0
0
12.8
5.1
0
17.9

0
0
15.4
0
2.6
17.9
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
8.3
16.6
0
24.9

0
0
4.0
0
8.9
12.9
0
0
0
0
0
0
100
Within
Category
0
0
33.3
66.7
0
100

0
0
30.8
0
69.2
100
0
0
0
0
0
0


-------
             TABLE  D-73
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093294 Total Mass of Particulates (mg) :
Coors: 177 Agency: 294
Monitor Location: Airport Calculated Mass (mg): 213
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 207 Agency: 147
Category
(
Flyash
5-10)1
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
I ron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

403
61
25
2
1
492
27
10
0
0
0
37
0
0
0
0
0
0
Percent By
Number

65.8
10.0
4.1
0.3
0.2
80.4
4.4
1.6
0
0
0
6.0
0
0
0
0
0
0
Percent By Mass
All
Categories

3.0
3.7
20.4
8.2
11.0
46.4
0.7
2.0
0
0
0
2.6
0
0
0
0
0
0
Within
Category

6.6
8.0
44.1
17.6
23.8
100
25.2
74.8
0
0
0
100
0
0
0
0
0
0

-------
             TABLE D-73
RESULTS OF OPTICAL PARTICLE COUiYrS
             (C'diit inued)
Filter Number: 1093294 (Continued)
Category

Quartz
5-10y
10-20u
20-50u
50-75p
>75M
Totals
Biological
5-10p
10-20y
20-50p
50-75u
>75y
Totals
CaCOQ

5-10u
10-20u
20-50|j
50-75p
>75)j
Totals
TOTALS
Particle
Count


21
1
3
0
0
25

12
4
11
12
1
40

18
0
0
0
0
18
612
(All Categories)
I
Percent By
Number


3.4
0.2
0.5
0
0
4.1

2.0
0.6
1.8
2.0
0.2
6.5

2.9
0
0
0
0
2.9
100

Percent By Mass
All
Categories

0.2
0.1
4.1
0
0
4.4

0.06
0.2
6.0
32.7
7.3
46.3

0.2
0
0
0
0
0.2
100

Wi thin
Category

5.9
2.3
91.8
0
0
100

0.1
0.3
13.0
70.7
15.9
100

100
0
0
0
0
100



-------
            TABLE  D-74
RESULTS OF OPTICAL PARTICLE CX)UNTS
Filter Number: 1106310 Total Mass of Particulates (mg) :
Coors: 278 Agency: 214
Monitor Location: South Fayette Calculated Mass (mg): 571
3
Date of Sample: 9/9/76 Air Concentration (ug/m ):
Coors: 145 Agency: 107
Category

Fly ash
5-lOu
10-20y
20-50p
50-75p
>75M
Totals
Iron Oxide
5-10u
10-20M
20-50n
50-75y
>75M
Totals
Magnetic
I inn
5-lOp
10-20jj
20-50,j
50-75p
>75u
Totals
Particle
Count


139
30
16
7
2
194

0
0
0
0
0
0


0
0
0
0
0
0
Percent By
Number


34.1
7.4
3.9
1.7
0.5
47.5

0
0
0
0
0
0


0
0
0
0
0
0
Percent By Mass
AJ]
Categories

0.4
0.7
4.9
10.7
8.2
24.8

0
0
0
0
0
0


0
0
0
0
0
0
Within
Category

1.6
2.7
19.6
43.0
33.1
100

0
0
0
0
0
0


0
0
0
0
0
0

-------
            TABLE D-74
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)




Quartz
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCO^
vJ
5-10y
10-20 y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Filter Number
Particle
Count


8
3
1
0
0
12

138
14
16
13
21
202


0
0
0
0
0
0
408
OS)
1 : 1106310
Percent By
Number


2.0
0.7
0.2
0
0
2.9

33.8
3.4
3.9
3.2
5.1
49.5


0
0
0
0
0
0
100

(Continued)
Percent
Al 1
Categories

0.04
0.1
0.5
0
0
0.6

0.2
0.2
3.2
13.2
57.5
74.5


0
0
0
0
0
0
100


By Mass
Within
Category

5.7
17.1
77.2
0
0
100

0.3
0.3
4.4
17.8
77.2
100


0
0
0
0
0
0



-------
             TABLE D-75



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093227 & 1093228 Total Mass of Participates (mg) :
(combined cover & primary filters) Coors: 149 Agency: 166
Monitor Location: Midland Calculated Mass (mg): 473
3
Date of Sample: 8/16/76 Air Concentration (yg/m ):
Coors : 83 Agency : 80
Category
Flyash
5-lQii
10-20y
20-50U
50-75p
>75y
Totals
Iron Oxide
5-10y
10-20p
2Q-50U
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20u
20-50p
50-75(j
>75y
Totals
Particle
Count
367
105
26
3
4
505
20
24
0
0
0
44
0
0
0
0
0
0
Percent By
Number
51.2
14.6
3.6
0.4
0.6
70.4
2.8
3.3
0
0
0
6.1
0
0
0
0
0
0
Percent By Mass
All
Categories
1.2
2.9
9.6
5.5
19.8
39.1
0.2
2.1
0
0
0
2.4
0
0
0
0
0
0
Within
Category
3.2
7.3
24.5
14.2
50.8
100
9.4
90.6
0
0
0
100
0
0
0
0
0
0

-------
             TABLE  D-75
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: ?"??:??! & (Continued)
l(J9o^o
Category
Quartz
5-10y
10-20y
20-50M
50-75U
>75M
Totals
Biological
5-10y
10-20u
20-50y
50-75y
>75y
Totals
CaOO,
O
5-10y
10-20y
20-50n
50-75y
>75p
Totals
TOTA1S
(All Categori
Particle
Count
35
23
19
2
0
79

29
12
4
4
10
59
29
1
0
0
0
30
717
.es)
Percent By
Number
4.9
3.2
2.6
0.3
0
11.0

4.0
1.7
0.6
0.6
1.4
8.2
4.0
0.1
0
0
0
4.2
100
Percent By Mass
All
Categories
0.2
1.0
11.7
6.1
0
19.0

0.06
0.2
1.0
4.9
33.1
39.3
0.2
0.05
0
0
0
0.2
100
Within
Category
1.0
5.5
61.2
32.2
0
100

0.2
0.6
2.5
12.5
84.2
100
78.4
21.6
0
0
0
100


-------
             TABLE  D-76
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: i093229 & 1093230
'combined cover & primary filters)
Monitor Location: Airport
Date of Sample: 8/16/76

Category
Flyash
5-10p
10-20y
20-50p
50-75y
>75y
Totals
Iron Oxide
5-10u
10-20y
20-50y
50— 75p
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50— 75y
>75p
Totals
Particle
Count

347
85
17
4
0
453
30
0
0
0
0
30
9
2
0
0
0
11
Total Mass of Particulates (mg) :
Coors: 149 Agency: 151
Calculated Mass (mg) : 194
3
Air Concentration (yg/rrf ):
Coors : 76 Agency : 72
Percent By
Number

53.
13.
2.
0.

6
1
6
6
0
70.
4.
0
6
0
0
0
0
4
1
0
6
4
3
0
0
0
1
7
Percent By Mass
All
Categories

2.9
5.6
15.3
18.0
0
41.8
0.8
0
0
0
0
0.8
0.2
0.4
0
0
0
0.6
Within
Category

6.9
13.5
36.6
43.0
0
100
100
0
0
0
0
100
36.0
64.0
0
0
0
100

-------
             TABLE D-76
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
„.-,, M , 1093229 & ,„ . ,,
r liter Number: -,^o^™ (Continued)
1093230
Category

Quartz
5-10y
10-20y
20-50u
50-75M
>75y
Totals
Biological
5-10p
10-20y
20-50y
50-75y
>75y
Totals
CaC00
5-lOp
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
Particle
Co imt


44
13
9
2
0
68

27
11
10
1
2
51

34
0
0
0
0
34
647
(All Categories)
Percent By
Number


6.8
2.0
1.4
0.3
0
10.5

4.2
1.7
1.5
0.2
0.3
7.9

5.2
0
0
0
0
5.2
100

Percent By Mass
All
Categories

0.6
1.4
13.5
15.0
0
30.5

0.1
0.5
6.0
3.0
16.1
25.7

0.5
0
0
0
0
0.5
100

Within
Category

2.0
4.7
44.2
49.1
0
100

0.6
1.9
23.2
11.6
62.6
100

100
0
0
0
0
100



-------
             TABLE D-77
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093239 & 1093240 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 140 Agency: 90
Monitor Location: South Fayette Calculated Mass (mg): 70
3
. Date of Sample: 8/16/76 Air Concentration (ug/m ):
Coors : 69 Agency : 41
Category
Flyash
5-lOp
10-20^
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20u
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
20-50u
50-75y
Totals
Particle
Count

254
58
13
0
0
325
16
2
0
0
0
18
17
3
0
0
0
20
Percent By
Number

53.5
12.2
2.7
0
0
68.4
3.3
0.4
0
0
0
3.8
3.6
0.6
0
0
0
4.2
Percent By Mass
All
Categories

5.8
10.6
32.1
0
0
48.5
1.2
1.2
0
0
0
2.4
1.3
1.8
0
0
0
3.1
Within
Category

12.0
21.8
66.2
0
0
100
50.0
50.0
0
0
0
100
41.5
58.5
0
0
0
100

-------
             TABLE D-77
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1Q93240 & (Contlnued)
Category
Quartz
5-10vi
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaCOQ
5-1 Oy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categori
Particle
Count
19
9
3
0
0
31

21
22
2
0
1
46
34
1
0
0
0
35
465
es)
Percent By
Number
4.0
1.9
0.6
0
0
6.5

4.4
4.6
0.4
0
0.2
9.7
7.2
0.2
0
0
0
7.4
100
Percent By Mass
All
Categories
0.7
2.7
12.4
0
0
15.8

0.3
2.7
3.3
0
22.2
28.5
1.4
0.3
0
0
0
1.7
100
Within
Category
4.6
17.3
78.1
0
0
100

1.1
9.4
11.6
0
77.9
100
81.0
19.0
0
0
0
100


-------
             TABLE D-78
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093290 & 1093291 Total Muss of Particulates (mg) :
(combined cover & primary filters) Coors: 374 Agency: 351
Monitor Location: Baden Calculated Mass (mg): 258
3
Date of Sample: 8/28/76 Air Concentration (yg/nf):
Coors: 203 Agency: 183
Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
1 1X511
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

573
147
40
6
2
768
43
10
0
0
0
53
26
9
0
0
0
35
Percent By
Number

58.8
15.1
4.1
0.6
0.2
78.8
4.4
1.0
0
0
0
5.4
2.7
0.9
0
0
0
3.6
Percent By Mass
All
Categories

3.6
7.3
27.0
20.2
18.2
76.3
0.9
1.6
0
0
0
2.5
0.5
1.5
0
0
0
2.0
Within
Category

4.7
9.6
35.4
26.5
23.8
100
35.0
65.0
0
0
0
100
26.5
73.5
0
0
0
100

-------
             TABLE D-78
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
T--H MI 1093290 & ._ _
Filter Number: 1O93291 (Continued)
Category
Quartz
5-10y
10-20u
20-50u
50-75y
>75y
Totals
Biological
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
CaC00
v3
5-10y
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categori
Particle
Count
22
7
7
0
0
36

33
19
6
3
0
61
21
1
0
0
0
22
975
es)
Percent By
Number
2.2
0.7
0.7
0
0
3.7

3.4
1.9
0.6
0.3
0
6.2
2.2
0.1
0
0
0
2.2
100
Percent By Mass
All
Categories
0.2
0.6
7. .9
0
0
8.7

0.1
0.6
2/7
6.7
0
10.2
0.2
0.09
0
0
0
0.3
100
Within
Category
2.6
6.7
90.6
0
0
100

1.3
6.2
26.4
66.1
0
100
72.4
27.6
0
0
0
100


-------
             TABLE D-79
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093288 & 1093289
(combined cover & primary filters)
Monitor Location: Beaver Falls
Date of Sample: 8/28/76

Category
Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20ji
20-50y
50-75y
>75y
Totals
Particle
Count
444
96
21
6
3
570
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Particulates (nig) :
Coors: 277 Agency: 266
Calculated Mass (mg): 314
3
Air Concentration (yg/m ):
Coors: 164 Agency: 137
Percent By
Number
57.0
12.3
2.7
0.8
0.4
73.2
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories
2.3
3.9
11.6
16.6
22.4
56.9
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category
4.0
6.9
20.4
29.2
39.4
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
             TABLE  D-79
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1Q93289 & (Continued)
Category

Quartz
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10u
10-20y
20-50y
50-75y
>75M
Totals
Ca003
5-10u
10-20^
20-50n
50-75u
>75y
Totals
TOTAI-S
Particle
Count


14
6
5
0
0
25

48
85
44
5
2
184

0
0
0
0
0
0
779
(All Categories)
Percent By
Number


1.8
0.8
0.6
0
0
3.2

6.2
10.9
5.6
0.6
0.2
23.6

0
0
0
0
0
0
100

Percent By Mass
All
Categories

0.1
0.4
4.6
0
0
5.1

0.2
2.3
16.2
9.2
10.0
38.0

0
0
0
0
0
0
100

Within
Category

2.3
8.0
89.7
0
0
100

0.4
6.1
42.8
24.4
26.2
100

0
0
0
0
0
0



-------
             TABLE D-80
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106308 & 1106309
(combined cover & primary filters)
Monitor Location: Hazelwood
Date of Sample: 8/28/76

Category
Fly ash
5-10u
10-20y
20-50U
50-75u
>75U
Totals
Iron Oxide
5-10vi
10-20U
20-50^
50-75p
>75U
Totals
Magnetic
Iron
5-lOn
10-20p
20-50]j
50-75u
>75y
Totals
Particle
Count

268
69
27
3
0
367
0
0
0
0
0
0
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors : 151 Agency : 143
Calculated Mass (mg): 157
3
Air Concentration (yg/m ):
Coors : 71 Agency : 76
Percent By
Number

44.
11.
4.
0.

4
4
5
5
0
60.
8
0
0
0
0
0
0
0
0
0
0
0
0
Percent By Mass
All
Categories

2.7
5.6
29.9
16.6
0
54.9
0
0
0
0
0
0
0
0
0
0
0
0
Within
Category

5.0
10.3
54.4
30.3
0
100
0
0
0
0
0
0
0
0
0
0
0
0

-------
             TABLE D-80
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
1106308 & ,
Filter Number: nn6309 (Continued)
Category

Quartz
5-10u
10-20u
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50u
50-75p
>75y
Totals
CaC00
O
5-10u
10-20M
20-50yj
50-75p
>75y
Totals
TOTALS
Particle
Count


13
11
2
0
0
26

130
33
12
2
2
179

30
2
0
0
0
32
604
(All Categories)
Percent By
Number


2.2
1.8
0.3
0
0
4.3

21.5
5.5
2.0
0.3
0.3
29.6

5.0
0.3
0
0
0
5.3
100

Percent By Mass
All
Categories

0.2
1.5
3.7
0
0
5.4

0.9
1.8
8.8
7.4
19.9
38.8

0.6
0.3
0
0
0
0.8
100

Within
Category

4.1
27.7
68.2
0
0
100

2.3
4.6
22.8
19.0
51.2
100

65.3
34.8
0
0
0
100



-------
             TABLE D-81
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093298 & 1093299
(combined cover & primary filters)
Monitor Location: North Braddock
Date of Sample: 8/28/76

Category
Flyash
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count

562
117
28
6
4
717
86
13
0
0
0
99
46
27
2
0
0
75
Total Mass of Particulates (mg) :
Coors: 289 Agency: 214
Calculated Mass (mg): 405
Air Concentration (yg/m ):
Coors: 153 Agency: 108
Percent By
Number

54
11
2
0
0
69
8
1

6
4
7
6
4
7
3
3
0
0
0
9
4
2
0
6
5
6
.2
0
0
7
3
Percent By Mass
All
Categories

2.2
3.7
12.0
12.9
23.2
54.1
1.1
1.4
0
0
0
2.5
0.6
2.8
2.8
0
0
6.2
Within
Category

4.1
6.9
22.3
23.9
42.8
100
7.6
92.4
0
0
0
100
9.6
45.2
45.2
0
0
100

-------
             TABLE D-81
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093298 & (Continued)
1093299
Category
Quartz
5-10y
10-20^
20-50p
50-75p
>75y
Totals
Biological
5-10p
10-20y
20-50p
50-75y
>75y
Totals
CaC00
5-lOy
10-20u
20-50p
50-75y
>75p
Totals
TOTALS
(All Categon
Particle
Count
15
14
10
1
1
41

20
15
6
1
3
45
43
9
0
0
0
52
1029
_es)
I
Percent By
Number
1.4
1.4
1.0
0.1
0.1
4.0

1.9
1.4
0.6
0.1
0.3
4.4
4.2
0.9
0
0
0
5.0
100
Percent By Mass
All
Categories
0.1
0.7
7.2
3.6
9.7
21.3

0.05
0.3
1.7
1.4
11.6
15.1
0.3
0.5
0
0
0
0.8
100
Within
Category
0.5
3.5
33.7
16.9
45.4
100

0.4
2.1
11.4
9.5
76.7
100
37.4
62.6
0
0
0
100


-------
             TABLE  D-82
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106300 & 1106301 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 68 Agency: —
Monitor Location : Duquesne II Calculated Mass (mg) : 40
Date of Sample: 8/28/76 Air Concentration (yg/m3):
Coors : — Agency :
Category

Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


21
8
1
0
1
31

0
0
0
0
0
0


0
0
0
0
0
0
Percent By
Number


31.3
11.9
1.5
0
1.5
46.3

0
0
0
0
0
0


0
0
0
0
0
0
Percent By Mass
All
Categories

0.8
2.6
4.3
0
58.4
66.2

0
0
0
0
0
0


0
0
0
0
0
0
Within
Category

1.3
3.9
6.6
0
88.3
100

0
0
0
0
0
0


0
0
0
0
0
0

-------
             TABLE D-82
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 110630° & (Continued)
1106301
Category

Quartz
5-10y
10-20p
20-50p
50-75p
>75M
Totals
Biological
5-lOy
10-20ij
20-50p
50-75y
>75y
Totals
CaCO0

5-10y
10-20y
20-50M
50-75y
>75y
Totals
TOTALS
Particle
Count


5
1
0
0
0
6

6
18
5
1
0
30

0
0
0
0
0
0
67
(All Categories)
1
Percent By
Number


7.5
1.5
0
0
0
9.0

9.0
26.9
7.5
1.5
0
44.8

0
0
0
0
0
0
100

Percent By Mass
All
Gitegories

0.3
0.5
0
0
0
0.9

0.2
3.8
14.4
14.5
0
32.9

0
0
0
0
0
0
100

Within
Category

38.5
61.5
0
0
0
100

0.5
11.7
43.9
43.9
0
100

0
0
0
0
0
0



-------
             TABLE D-83
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6302 & H06303 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 207 Agency: 271
Monitor Location: Liberty Boro Calculated Mass (mg): 227
*^j
Date of Sample: 8/28/76 ^Y Concentration (ug/m ):
Coors : 130 Agency : 136
Category

Flyash
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


467
188
22
3
5
685

24
5
0
0
0
29


0
0
0
0
0
0
Percent By
Number


58.6
23.6
2.8
0.4
0.6
85.9

3.0
0.6
0
0
0
3.6


0
0
0
0
0
0
Percent By Mass
All
Categories

3.3
10.7
16.9
11.5
51.8
94.2

0.6
0.9
0
0
0
1.5


0
0
0
0
0
0
Within
Category

3.5
11.3
17.9
12.2
54.9
100

37.5
62.5
0
0
0
100


0
0
0
0
0
0

-------
             TABLE D-83
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 11-06302 & (Continued)
1106303
Category

Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


20
6
1
0
0
27

19
18
2
0
0
39

15
2
0
0
0
17
797
(An Categories)
Percent By
Number


2.5
0.8
0.1
0
0
3.4

2.4
2.2
0.2
0
0
4.9

1.9
0.2
0
0
0
2.1
100

Percent By Mass
Al]
Categories

0.2
0.6
1.3
0
0
2.1

0.09
0.7
1.0
0
0
1.8

0.2
0.2
0
0
0
0.4
100

Within
Category

11.4
27.2
61.4
0
0
100

5.0
38.0
57.0
0
0
100

48.4
51.6
0
0
0
100



-------
             TABLE D-84
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1110928 & 1110929 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 338 Agency: 287
Monitor Location: „ , . Calculated toss (mg): 522
3
Date of Sample: 9/9/76 Air Concentration (yg/nf ):
Coors: 178 Agency: 160
Category

Flyash
5-lQii
10-20y
20-50p
50-75)j
>75M
Totals
Iron Oxide
5-10y
10-20y
20~50u
50-75M
>75p
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Particle
Count


0
0
69
4
1
74

0
0
0
0
0
0


0
0
0
0
0
0
Percent By
Number


0
0
46.0
2.7
0.7
49.3

0
0
0
0
0
0


0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
23.0
6.7
4.5
34.2

0
0
0
0
0
0


0
0
0
0
0
0
Within
Category

0
0
67.3
19.5
13.1
100

0
0
0
0
0
0


0
0
0
0
0
0

-------
            TABLE D-84
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: }I"|^QOQ ^ (Continued)
Category

Quartz
5-10y
10-20y
20-50ui
50-75y
>75u
Totals
Biqlogical
5-10M
10~20y
20-50y
50~75y
>75y
Totals
CaOOQ
5-lOy
10-20M
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


0
0
62
8
1
71

0
0
4
0
0
4

0
0
1
0
0
1
150
(All Categories)
Percent By
Number


0
0
41.3
5.3
0.7
47.3

0
0
2.7
0
0
2.7

0
0
0.7
0
0
0.7
100

Percent By Mass
All
Categories

0
0
34.5
22.3
7.5
64.3

0
0
0.9
0
0
0.9

0
0
0.6
0
0
0.6
100

Within
Category

0
0
53.7
34.6
11.7
100

0
0
100
0
0
100

0
0
100
0
0
100



-------
              TABLE  IT-85
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1093292 & 1093293
(combined cover & primary filters)
Monitor Location: Midland
Date of Sample: 9/9/76

Category

Flyash
5-lOu
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count


0
0
98
6
5
109

0
0
10
3
0
13


0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors: 667 Agency: 688
Calculated Mass (mg): 801
3
Air Concentration (ug/m ):
Coors: 404 Agency: 341
Percent By
Number






0
0
58.0
3.6
3.0
64.5




0
0
5.9
1.8

0
7.7









0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
21.3
6.5
14.6
42.5

0
0
7.1
10.7
0
17.8


0
0
0
0
0
0
Within
Category

0
0
50.2
15.4
34.5
100

0
0
40.0
60.0
0
100


0
0
0
0
0
0

-------
             TABLE D-85
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: 1093292 & (Continued)
1 nQ-39Q1
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75)j
>75y
Totals
CaC00
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categor]
Particle
Count
0
0
22
1
1
24

0
0
11
0
12
23
0
0
0
0
0
0
169
^es)
1
Percent By
Number
0
0
13.0
0.6
0.6
14.2

0
0
6.5
0
7.1
13.6
0
0
0
0
0
0
100
Percent By Mass
All
Categories
0
0
8.0
1.8
4.9
14.7

0
0
1.6
0
23.4
25.0
0
0
0
0
0
0
100
Within
Category
0
0
54.4
12.4
33.3
100

0
0
6.4
0
93.6
100
0
0
0
0
0
0


-------
             TABLE D-86
RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1105327 & 1106328 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 429 Agency: 428
Monitor Location: Central Lab Calculated Mass (mg): 560
o
Date of Sample: 9/9/76 Air Concentration (ug/m ):
Coors: 219 Agency: 235
Category

Flyash
5-lOu
10-20u
20-50u
50— 75u
>75p
Totals
Iron Oxide
5-lOu
10-20u
20-50[j
50-75u
>75u
Totals
Magnetic
Iron
5-10u
10-20y
20-50u
50-75y
>75y
Totals
Particle
Count


590
183
46
10
10
839

35
22
0
0
0
57


0
0
0
0
0
0
Percent By
Number


57.4
17.8
4.5
1.0
1.0
81.6

3.4
2.1
0
0
0
5.5


0
0
0
0
0
0
Percent By Mass
All
Categories

1.7
4.2
14.3
15.6
41.9
77.7

0.3
1.6
0
0
0
2.0


0
0
0
0
0
0
Within
Category

2.2
5.4
18.4
20.0
53.9
100

16.6
83.4
0
0
0
100


0
0
0
0
. 0
0

-------
             TABLE D-86
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: -t-ingooo (Continued)
Category
Quartz
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75y
>75y
Totals
CaC03
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorj
Particle
Count
34
18
13
0
1
66

1
20
10
3
0
34

30
2
0
0
0
32
1028
-es)
Percent By
Number
3.3
1.8
1.3
0
0.1
6.4

0.1
1.9
1.0
0.3
0
3.3

2.9
0.2
0
0
0
3.1
100
Percent By Mass
All
Categories
0.2
0.7
6.7
0
7.0
14.6

0.002
0.3
2.1
3,1
0
5.5

0.2
0.08
0
0
0
0.2
100
Within
Category
1.1
4.7
46.2
0
47.9
100

0.03
5.6
37.7
56.6
0
100

65.2
34.8 '
0
0
0
100


-------
              TABLE  D-87



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: HQ6388 & 1106387 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 470 Agency: 582
Monitor Location: Liberty Boro Calculated Mass (mg): 853
o
Date of Sample: 9/9/76 Air Concentration (yg/m ):
Coors: 289 Agency: 315
Category
Flyash
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Iron Oxide
5-10y
10-20u
20-50y
50-75y •
>75M
Totals
Magnetic
Iron
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Particle
Count

239
78
100
18
17
452
53
10
7
0
0
70
14
7
0
0
0
21
Percent By
Number

37.4
12.2
15.6
2.8
2.7
70.7
8.3
1.6
1.1
0
0
11.0
2.2
1.1
0
0
0
3.2
Percent By Mass
All
Categories

0.4
1.2
20.4
18.4
46.8
87.2
0.3
0.5
4.7
0
0
5.5
0.09
0.3
0
0
0
0.4
Within
Category

0.5
1.4
23.4
21.1
53.6
100
6.0
9.0
85.1
0
0
100
20.0
80.0
0
0
0
100

-------
             TABLE D-87
RESULTS OF OPTICAL PARTICLE COUNTS
            (Continued)
Filter Number: -1-1^/2007 (Continued)
Category

Quartz
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Biological
5-10p
10-20y
20-50y
50-75y
>75M
Totals
CaOO,
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count

20
6
7
0
0
33

3
4
2
0
2
11
47
5
0
0
0
52
639
(All Categories)
i
Percent By
Number

3.1
0.9
1.1
0
0
5.2

0.5
0.6
0.3
0
0.3
1.7
7.4
0.8
0
0
0
1.7
100

Percent By Mass
AH
Categories
0.06
0.2
2.4
0
0
2.6

0.004
0.04
0.3
0
3.7
4.0
0.2
0.1
0
0
0
0.3
100

Within
Category
2.4
5.8
91.8
0
0
100

0.09
1.0
6.8
0
92.1
100
54.0
46.0
0
0
0
100



-------
             TABLE D-88



RESULTS OF OPTICAL PARTICLE COUNTS
Filter Number: 1106381 & 1106382
(combined cover & primary filters)
Monitor Location: Clairton
Date of Sample: 9/9/76

Category
Flyash
5-lOu
10-20y
20-50|j
50-75y
>75y
Totals
Iron Oxide
5-10n
10-20y
20-50y
50-75p
>75M
Totals
Magnetic
Iron
5-10u
10-20y
20-50jj
50-75y
>75y
Totals
Particle
Count

0
0
85
8
4
97
0
0
5
0
0
5
0
0
0
0
0
0
Total Mass of Particulates (mg) :
Coors: 293 Agency: 330
Calculated Mass (mg): 470
3
Air Concentration (yg/m ):
Coors : 127 Agency : 178
Percent By
Number



65
6
3
74



0
0
.4
.2
.1
.6
0
0
3.8


0
0
3.8





0
0
0
0
0
0
Percent By Mass
All
Categories

0
0
31.5
14.8
20.0
66.3'
0
0
6.0
0
0
6.0
0 ,
0
0
0
0
0
Within
Category

0
0
47.5
22.4
30.1
100
0
0
100
0
0
100
0
0
0
0
0
0

-------
             TABLE D-
KESULTS OF OPTICAL PARTICUE COUNTS
            (Continued)



Quartz
5-10y
10-20y
20-50y
50-75p
>75y
Totals
Biological
5-10y
10-20y
20-50y
50-75u
>75p
Totals
CaC00
5-lOp
10-20y
20-50y
50-75y
>75y'
Totals
TOTALS
(All Category
Filter Number
Particle
Count

0
0
14
3
0
17

0
0
6
4
1
11

0
0
0
0
0
0
130
.es)
1
,. 1106381 &
1106382
Percent By
Nmnber

0
0
10.8
2.3
0
13.1

0
0
4.6
3.1
0.8
8.5

0
0
0
0
0
0
100
(Continued)
Percent
All
Categories

0
0
8.6
9.3
0
17.9

0
0
1.5
4.9
3.3
9.8

0
0
0
0
0
0
100

By Mass
Within
Category

0
0
48.2
51.7
0
100

0
0
15.2
50.7
34.1
100

0
0
0
0
0
0


-------
TABLE D-89 THROUGH D-167 - RESULTS OF SEM PARTICLE COUNTS

-------
          TABLE D-89
RESULTS OF SEM PARTICLE COOTS
Filter Number: 1093219 Total Mass of Particulates (mg) :
Coors: 164 Agency: 139
Monitor Location: Baden Calculated Mass (mg) : 193
3
Date of Sample: 8/16/76 ^r conccnt.ration (Mg/ni ):
Coors : 86 Agency : 67
Category

Sphere
5-10^
10-20y
20-50(j
50-75 p
>75y
Totals
Irregular
5-lOy
10-20y
20-50p
50-75y
>75y
Totals
Aggl omer ate
5-lOy
10-20y
20-50p
50-75y
>75p
Totals
TOTAI^
Particle
Count


225
75
0
0
0
300

1075
300
60
0
0
1435

825
275
24
10
0
1125
2860
(All Categories)
Percent By
Number


7.9
2.6
0
0
0
10.5

37.6
10.5
2.1
0
0
50.2

28.8
9.6
0.8
0.03
0
39.3
100

Percent By Mass
All
Categories

1.4
3.8
0
0
0
5.2

7.6
17.0
46.0
0
0
70.6

3.2
8.6
10.2
2.1
0
24.2
100

Within
Category

27.3
72.7
0
0
0
100

10.8
24.1
65.1
0
0
100

13.4
35.7
42.1
8.8
0
100



-------
           TABLE D-90




RESULTS OF SEM PARTICLE COUNTS
Filter Number: inci^99i

Monitor Location: Beaver Falls
Date of Sample: 8/16/76

Category

Sphere
5-10|j
10-20y
20-50y
50-75ja
>75y
Totals
Irregular
5-10n
10-20y
20-50y
50-75M
>75U
Totals
Agglomerate
5-lOp
10-20u
20-SOia
50-7 5y
>75y
Totals
TOTALS
Particle
Count


50
25
0
0
0
75

275
150
24
0
0
449

425
125
24
3
2
579
1103
(All Categories)
Total Miss of Particulates (mg) :
Coors: 152 Agency: 127
Calculated Mass (mg) : 124
3
Air concentration (ug/m ):
Coors: 86 Agency: 61
Percent By
Number




4.5
2.3
0
0
0



6.8


24.9
13.6
2.2
0
0
40.

38.
11.
2.
0.
0.
52.


7

5
3
2
3
2
5
100


Percent By Mass
All
Categories

0.5
2.0
0
0
0
2.4

3.0
13.3
28.7
0
0
45.0

2.6
6.1
15.9
10.0
17.9
52.6
100

Within
Category

20
80
0
0
0
100

6.8
29.5
63.8
0
0
100

5.0
11.7
30.3
19.0
34.0
100



-------
          TABLE D-91
RESULTS OF SEM PARTICLE COUNTS
Filter Number: inq-^9?^ Total Mass of Particulates (mg) :
Coors: 189 Agency: 161
Monitor Location: Koppel Calculated Mass (mg) : 86
Date of Sample: 8/16/76 Air concentration (yg/m ):
Coors: 90 Agency: 86
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


50
0
0
0
0
50

325
175
8
0
0
508

600
200
40
0
0
840
1398
(All Categories)
Percent By
Number


3.6
0
0
0
0
3.6

23.2
12.5
0.6
0
0
36.3

42.9
14.3
2.9
0
0
60.1
100

Percent By Mass
All
Categories

0.7
0
0
0
0
0.7

5.2
22.4
13.8
0
0
41.4

5.3
14.2
38.4
0
0
57.9
100

Within
Category

100
0
0
0
0
100

12.5
54.0
33.4
0
0
100

9.2
24.5
66.3
0
0
100



-------
          TABLE D-92
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093225

Monitor Location: Brighton
Township
Date of Sample: 8/16/76

Cat ego ly
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-7 5y
>75M
Totals
TOTALS
(All Categoric
Particle
Count
125
25
0
0
0
150
575
50
24
0
0
649
400
125
4
0
0
529
1328
s)
Total Mass of Particulates (ing) :
Coors: 119 Agency: 162
Calculated Mass (mg) : 67
3
Air concentration (yg/m ):
Coors: 65 Agency: 87
Percent By
Number
9.4
1.9
0
0
0



11.3
43.3
3.
3
1.8
0
0


48.9
30.0
9.4
0.
0
0
39.
3


8
100
Percent By Mass
All
Categories
2.3
3.6
0
0
0
5.9
11.8
8.2
53.2
0
0
73.2
4,6
11.4
4.9
0
0
20.9
100
Within
Category
38.5
61.5
0
0
0
100
16.1
11.2
72.7
0
0
100
21.8
54.6
23.6
0
0
100


-------
           TABLE  D-93



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093227

Monitor Location: Midland
Date of Sample: 8/16/76

Categoiy

Sphere
5-10y
10-20(j
20-50u
50-75^
>75\i
Totals
Irregular
5-10u
10-20y
20-50p
50-75u
>75y
Totals
Agglomerate
5-10y
10-2 On
20-50y
50-75y
>75)j
Totals
TOTALS
Particle
Count


225
75
4
0
0
304

1300
225
28
1
0
1554

1250
100
24
2
0
1376
3234
(All Categories)
Total Mass of Particulates (mg) :
Coors : 149 Agency : 166
Calculated Mass (mg) : 150
3
Air concentration (yg/nf):
Coors: 83 Agency: 80
Percent By
Number




7.0
2.3
0.1
0
0


9.4


40.2
7.0
0.
0.
0
48.

38.
3.
0.
0.
9
03

0

6
1
7
06
0
42.
5
100


Percent By Mass
All
Categories

1.8
4.9
3.5
0
0
10.2

11.8
16.4
27.6
4.9
0
60.8

6.3
4.0
13.1
5.5
0
29.0
100

Within
Category

17.9
47.7
34.4
0
0
100

19.5
27.0
45.4
8.1
0
100

21.8
14.0
45.3
18.9
0
100



-------
           TABLE D-94
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter)
1093228
Monitor Location: Midland
Date of Sample: 8/16/76
(Cover Filter for 1093227)
Category

Sphere
5-lOy
10-20^
20-50u
50-75jj
>75M
Totals
Irregular
5-10u
10-20u
20-50y
50-75p
>75u
Totals
Agglomerate
5-10y
10-2Qu
20-50y
50-75u
>75p
Totals
TOTALS
Particle
Count


275
25
4
0
0
304

875
125
16
2
0
1018

600
75
4
1
0
680
2002
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency :
Calculated Mass (mg) : 91-6
3
Air concent ration ( pg/m ) :
Coors : — Agency : —
Percent By
Number


13
1
0


15



.7
.2
.2
0
0
.2

43.7
6.2
0.8
0.1

0
50.8


30.0
3.7
0.2
0.05

0
34.0
100


Percent By Mass
All
Categories

3.6
2.6
5.7
0
0
12.0

13.0
14.9
25.8
16.1
0
69.9

5.0
5.0
3.6
4.5
0
18.0
100

Within
Category

30.3
22.0
47.7
0
0
100

18.7
21.3
36.9
23.1
0
100

27.6
27.6
19.9
24.9
0
100



-------

-------

-------
           TABLE  D-95
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093213 Total Mass of Particulates (mg) :
Coors : 147 Agency : 100
Monitor Location: Elco Calculated Mass (mg) : 126
Date of Sample: 8/16/76 Air concentration (ug/m ):
Coors : 66 Agency : 46
Category

Sphere
5-10u
10-20y
20-50y
50-75M
>75M
Totals
Irregular
5-10y
10-20p
20-50y
50-75jj
>75y
Totals
Agglomerate
5-lOp
10-20p
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count


100
50
0
0
0
150

675
200
12
0
0
887

450
100
56
1
1
608
1645
(All Categories)
Percent By
Number


6.1
3.0
0
0
0
9.1

41.0
12.2
0.7
0
0
53.9

27.4
6.1
3.4
0.06
0.06
37.0
100

Percent By Mass
Al 1
Categories

1.0
3.9
0
0
0
4.8

7.3
17.4
14.1
0
0
38.9

2.7
4.8
36.6
3.3
8.8
56.3
100

Within
Category

20
80
0
0
0
100

18.9
44.8
36.3
0
0
100

4.8
8.6
65.1
5.8
15.7
100



-------
           TABLE D-96
RESULTS OF SEM PARTICLE COUNTS
Filter Number: Total Mass of Particulates (mg) :
Coors: 284 Agency: 241
Monitor Location: Downtown Calculated Mass (mg) : 139
3
Date of Sample: o/-,-./^ Air concentration (pg/m ):
o/lb/ /b
Coors: 139 Agency: I10
Category
Sphere
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
75
25
0
0
0
100
525
125
28
0
0
678
1675
300
52
0
0
2027
2805
3S)
Percent By
Number
2.7
0.9
0
0
0
3.6
18.7
4.4
1.0
0
0
24.2
59.7
10.7
1.8
0
0
72.3
100
Percent By Mass
All
Categories
0.6
1.7
0
0
0
2.4
5.2
9.8
29.7
0
0
44.7
9.1
13.1
30.7
0
0
52.9
100
Within
Category
27.3
72.7
0
0
0
100
11.5
22.0
66.5
0
0
100
17.3
24.7
58.0
0
0
100


-------
           TABLE D-97



RESULTS OF SEM PARTICLE COUNTS
Filter Number:
1093241
Afonitor Location: Central Lab
Date of Sample: 8/16/76

Category
Sphere
5-lOp
10-20y
20-50y
50-7 5y
>75M
Totals
Irregular
5-10vi
10-20U
20-50y
50-75u
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categorie
Particle -
Count
50
0
0
0
0
50
700
150
16
0
0
866
500
25
16
1
0
542
1458
>s)
Total Mass of Particulates (ing) :
Coors: 224 Agency: 202
Calculated Miss (mg) : 73
3
Air concentration (ug/m ):
Coors: 110 Agency: 97
Percent By
Number
3.4
0
0
0
0




3.4
48.0
10.3
I.
0
0
1


59.4
34.
1.
1.
0.
0
37.
3
7
1
07

2
100
Percent By Mass
All
Categories
0.8
0
0
0
0
0.8
13.1
22.5
32.5
0
0
68.2
5.2
2.1
18.0
5.6
0 '
31.0
100
Within
Category
100
0
0
0
0
100
19.3
33.0
47.7
0
0
100
16.8
6.7
58.2
18.2
0
100


-------
           TABLE D-98
RESULTS OF SEM PARTICLE GODOT'S
filter Number: 1093201 Total Mass of Participates (mg) :
Coors : 180 Agency :
Monitor Location: Hazelwood Calculated Mass (mg) : 307
'3
Date of Sample: 8/16/76 Air concentration (ijg/nf):
Coors: 131 Agency: !05
Category

Sphere
5-10|j
10-20y
20-50u
50-7 5y
>75M
Totals
Irregular
5-10y
10-20u
20-50p
50-75y
>75p
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count


75
25
4
0
0
104

1975
350
44
0
1
2370

3600
700
96
0
0
4396
6870
(All Categories)
Percent By
Number


1.1
0.4
0.06
0
0
1.5

28.7
5.1
0.6
0
0.01
34.5

52.4
10.2
1.4
0
0
64.0
100

Percent By Mass
All
Categories

0.3
0.8
1.7
0
0
2.8

8.8
12.4
21.2
0
6.5
48.8

8.9
13.8
25.6
0
0
48.4
100

Within
Category

10.6
28.3
61.1
0
0
100

18.0
25.5
43.3
0
13.2
100

18.4
28.6
53.0
0
0
100



-------
          TABLE D-99



RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093203 Total Mass of Particulates (mg) :
Coors: 155 Agency: 126
Monitor Location: North Braddock Calculated Mass (mg): 157
2
Date of Sample: 8/16/76 Air concentration (pg/m ):
Coors : 79 Agency : 63
Category

Sphere
5-10n
10-20U
20-50u
50-75y
>75y
Totals
Irregular
5-10p
10-20u
20-50p
50-75p
>75p
Totals
Agglomerate
5-10p
10-20y
20-50y
50-7 5p
>75p
Totals
TOTALS
Particle
Count


200
0
4
0
0
204

750
225
48
1
0
1024

1025
75
24
1
0
1125
2353
(All Categories)
Percent By
Number


8.5
0
0.2
0
0
8.7

31.9
9.6
2.0
0.04
0
43.5

43.6
3.2
1.0
0.04
0
47.8
100

Percent By Mass
All
Categories

1.5
0
3.3
0
0
4. .9

6.5
15.7
45.2
4.7
0
72.1

5.0
2.9
12.6
2.6
0
23.0
100

Within
Category

31.6
0
68.4
0
0
100

9.0
21.7
62.7
6.5
0
100

21.5
12.6
54.5
11.4
0
100



-------
           TABLE  D-100



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093205 Total Mass of Particulates (nag):
Coors: 231 Agency: 211
Monitor Location: Duquesne II Calculated Mass (mg) : 270
3
Date of Sample: 8/16/76 Air concentration (pg/m ):
Coors: 145 Agency: 107
Category

Sphere
5-lOy
10-20u
20-50u
50-75p
>75p
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Agglomerate
5-10u
10-2 Op
20-50y
50-75)j
>75y
Totals
TOTALS
Particle
Count


175
25
0
0
0
200

1825
500
40
1
0
2366

2050
300
84
4
0
2438
5004
(All Categories)
Percent By
Number


3.5
0.5
0
0
0
4.0

36.5
10.0
0.8
0.02
0
47.3

41.0
6.0
1.7
0.08
0
48.7
100

Percent By Mass
All
Categories

0.8
0.9
0
0
0
1.7

9.2
20.2
21.9
2.7
0
54.1

5.8
6.8
25.6
6.1
0
. 44.2
100

Within
Category

46.7
53.3
0
0
0
100

17.1
37.4
40.5
5.1
0
100

13.0
15.3
57.9
13.8
0
100



-------
           TABLE D-101
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093209 Total Mass of Particulates (mg) :
Coors : 181 Agency :
Monitor Location: Liberty Boro Calculated Mass (mg) : 150
Date of Sample: 8/16/76 Air concentration (ug/m ):
Coors : 114 Agency :
Category
Sphere
5-10y
10-20U
20-50u
50-75U
>75U
Totals
Irregular
5-10y
10-20p
20-50p
50-75y
>75y
Totals
Agglaiierato
5-lOp
10-20y
20-50y
50-75p
>75M
Totals
TOTALS
(All Categoric
Particle
Count
75
0
4
0
0
79
650
150
12
1
1
814
1725
325
44
1
0
2095
2988
3S)
Percent By
Number .
2.5
0
0.1
0
0
2.6
21.8
5.0
0.4
0.03
0.03
27.2
57.7
10.9
1.5
0.03
0
70.1
100
Percent By Mass
• All
Categories
0.6
0
3.5
0
0
4.1
5.9
11.0
11.8
4.9
13.3
47.0
8.8
13.2
24.2
2.7
0
48.8
100
Within
Category
14.8
0
85.2
0
0
100
12.6
23.3
25.2
10.5
28.3
100
17.9
27.0
49.4
5.6
0
100


-------
           TABLE D-102
RESULTS OF Sill PARTI CLE  COUNTS
Filter Number: 1093211 Total Mass of Participates (mg) :
Coors: 125 Agency: 150
Monitor Location: Clairton Calculated Mass (mg) : 106
3
Date of Sample: 8/16/76 Air concentration (yg/m ):
Coors : 52 Agency : 76
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
AggLaiierate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


50
25
0
0
0
75

550
75
28
0
1
654

300
75
24
0
0
399
1128
(All Categories)
Percent By
Number


4.4
2.2
0
0
0
6.6

48.8
6.6
2.5
0
0.09
58.0

26.6
6.6
2.1
0
0
35.4
100

Percent By Mass
All
Categories

0.6
2.3
0
0
0
2.8

7.0
7.7
38.8
0
18.7
72.2

2.1
4.3
18.5
0
0
24.9
100

Within
Category

20
80
0
0
0
100

9.8
10.6
53.7
0
25.8
100

8.6
17.2
74.2
0
0
100



-------
           TABLE  D-103



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093229 Total Mass of Particulates (mg) :
Coors : 149 Agency : 151
Monitor Location: Airport Calculated Mass (mg): 97
Date of Sample: 8/16/76 Air concentration ( ug/rn" ) :
Coors: 76 Agency: 72
Category

Sphere
5-lOu
10-20y
20-50M
50-75M
>75M
Totals
Irregular
5-10y
10-20u
20-50y
50-75y
>75p
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75y
>75p
Totals
TOT/\LS
Particle
Count


50
0
0
0
1
51

750
200
8
1
0
959

1375
275
0
0
0
1650
2660
(All Categories)
Percent By
Number


1.9
0
0
0
0.04
1.9

28.2
7.5
0.3
0.04
0
36.0 '

51.7
10.3
0
0
0
62.0
100

Percent By Mass
All
Categories

0.6
0
0
0
18.3
18.9

10.6
22.6
12.2
7.6
0
53.0 1

10.8
17.2
0
0
0
28.0
100

Within
Category

3.3
0
0
0
96.7
100

20.0
42.6
23.0
14.4
0
100

38.5
61.5
0
0
0
100



-------
           TABLE D-104
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (nig):
1093230 Coors: — Agency:
Monitor Location: Airport Calculated Mass (ing): 140
Date of Sample: 8/16/76 Air concentration (yg/m ):
(Cover Filter for 1093229) ^ .
v Coors: — Agency:
Category

Sphere
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
TOTALS
Particle
Count

100
0
4
0
0
104
975
150
24
2
0
1151
750
175
36
2
0
963
2218
(All Categories)
Percent By
Number

4.5
0
0.2
0
0
4.7
44.0
6.8
1.1
0.09
0
51.9
33.8
7.9
1.6
0.09
0
43.4
100

Percent By Mass
All
Categories
0.8
0
3.7
0
0
4.6
9.5
11.7
25.2
10.5
0
56.9
4.0
7.6
21.0
5.8
0
38.5
100

Within
Category
18.8
0
81.2
0
0
100
16.6
20.5
44.3
18.5
0
100
10.5
19.6
54.6
15.2
0
100



-------
          TABLE D-105



RESULTS OF SEM PARTICLE COUNTS
Filter Number: incnoqa Total Mass of Particulates (nig):
Coors: 140 Agency: 90
Monitor Location: South Fayette Calculated Mass (mg) : 49
Date of Sample: 8/16/76 Air concentration (pg/m ):
Coors: 69 Agency: 41
Category
Sphere
5-lOp
10-20p
20-50p
50-75p
>75p
Totals
Irregular
5-10p
10-20p
20-50p
50-75p
>75p
Totals
Agglomerate
5-10y
10-2 Op
20-5 Op
50-7 5p
>75p
Totals
TOTALS
(All Categoric
Particle
Count
125
25
0
0
0
150
775
125
4
0
0
904

575
125
4
0
0
704
1758
iS)
Percent By
Number
7.1
1.4
0
0
0
8.5
44.1
7.1
0.2
0
0
51.4

32.7
7.1
0.2
0
0
40.0
100
Percent By Mass
All
Categories
3.1
4.9
0
0
0
8.0
21.4
27.7
12.0
0
0
61.1

8.8
15.4
6.6
0
0
30.9
100
Within
Category
38.5
61.5
0
0
0
100
35.1
45.3
19.6
0
0
100

28.6
49.8
21.5
0
0
100


-------
           TABLE D-106



RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093247

Monitor Location: Liberty Boro
Date of Sample: 8/22/76

Category

Sphere
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


250
0
0
0
0
250

2200
725
148
7
0
3080

2650
1050
324
38
3
4065
7395
(All Categories)
Total Mass of Particulates (nig) :
Coors: 433 Agency:
Calculated Mass (mg) : 922
Air concentration (yg/m ):
Coors: 272 Agency:
Percent By
Number




3.4
0
0
0
0




3.4


29.7
9.8
2.
0
0.09
0

41.6 n

35.
14.

8
2
4.4
0.
0.
55.
5
04
0
100


Percent By Mass
All
Categories

0.3
0
0
0
0
0.3

3.3
8.6
23.7
5.6
0
41.2

2.2
6.9
28.8
16.9
3.6
58.5
100

Within
Category

100
0
0
0
0
100

7.9
20.9
57.6
13.6
0
100

3.7
11.8
49.3
29.0
6.2
100



-------
           TABLE D-107



RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1093248 Coors: __ Agency; __
Monitor Location: Liberty Boro Calculated Mass (ing): 104
3
Date of Sample: 8/22/76 Air concentration (yg/rn ):
(Cover Filter for 1093247) Coors: — Agency:
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20(j
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-5 Oy
50-7 5y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
25
0
0
0
0
25
350
150
20
1
0
521
550
175
32
1
0
758
1304
;s)
Percent By
Number
1.9
0
0
0
0
1.9
26.8
11.5
1.5
0.08
0
40.0
42.2
13.4
2.4
0.08
0
58.1
100
Percent By Mass
All
Categories
0.3
0
0
0
0
0.3
4.6
15.8
28.5
7.1
0
56.1
4.0
10.2
25.4
4.0
0
43.6
100
Within
Category
100
0
0
0
0
100
8.2
28.2
50.8
12.7
0
100
9.2
23.5
58.1
9.1
0
100


-------
           TABLE D-108



RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093290

Monitor Location: Baden
Date of Sample: 8/28/76

Category
Sphere
5-10n
10-20y '
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75p
>75u
Totals
TOTALS
(All Categoric
Particle
Count
275
100
0
0
0
375
1275
450
40
5
1
1771
1050
650
60
40
3
1803
3949
yl 	
Perce
Total Muss of Particulates (mg) :
Coors: 374 Agency: 351
Calculated Mass (mg): 490
3
Air concentration (yg/irf):
Coors: 203 Agency: 183
nt By
Number
7.
2.
0
5
0
0
0
9.
32.
11.
1.
0.
0.
44.
26.
16.
1.
1.
0.
45.
5
3
4
0
1
02
8
6
4
5
0
08
6
100
Percent By Mass
All
Categories
0.7
2.0
0
0
0
2.7
3.6
10.0
12.1
7.5
4.1
37.3
1.6
8.0
10.0
33.5
6.8
60.0
100
Within
Category
25.6
74.4
0
0
0
100
9.5
26.9
32.4
20.2
10.9
100
2.7
13.4
16.7
55.8
11.3
100


-------
           TABLE D-109



RESULTS OF SKM PARTICLE COUNTS
Filter Number: (Cover Filter)
1093291
Monitor Location: Baden
Date of Sample: 8/28/76
(Cover Filter For 1093290)
Category

Sphere
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Irregular
5-10y
10-20M
20-50M
50-75y
>75M
Totals
Agglomerate
5-10M
10-2 Oy
20-50M
50-75p
>75}j
Totals
'TOTALS
Particle
Count


275
125
20
0
0
420

1000
350
112
0
0
1462

1200
550
188
25
2
1965
3847
(All Categories)
Perec.
Total Mass of Particulates (mg) :
Coors : — Agency : —
Calculated Mass (mg) : 581
3
Air concentration (ug/m ):
Coors : — Agency :
nt By
Number


7.
3.
0.


1
2
5
0
0
10.

26.
9.
2.
9

0
1
9
0
0
38.

31.
14.
4.
0.
0.
51.
0

2
3
9
6
05
1
100


Percent By Mass
Al]
Categories

0.6
2.1
4.5
0
0
7.2

2.4
6.6
28.5
0
0
37.4

1.6
5.7
26.6
17.7
3.8
55.4
100

Within
Category

8.0
29.1
62.9
0
0
100

6.3
17.6
76.1
0
0
100

2.8
10.4
48.0
31.9
6.9
100



-------
          TABLE  D-110



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093288

Monitor Location: Beaver Falls
Date of Sample: 8/28/76

Category
Sphere
5-lOp
10-20jj
20-50p
50-75y
>75M
Totals
Irregular
5-lOu
10-20y
20-50y
50-75p
>75y
Totals
Agglomerate
5-10y
10-20jj
20-50y
50-75p
>75n
Totals
TOTALS
(All Categoric
Particle
Count
750
100
4
0
0
854
1750
325
32
4
0
2111
2150
375
116
1
2
2644
5609
s)
Total Mass of Particulates (mg) :
Coors: 277 Agency: 266
Gilculated Mass (mg) : 321
3
Air concentration (ug/rrf):
Coors: 164 Agency: 137
Percent By
Number
13.
1.
0.
4
8
07
0
0
15.
31.
5.
0.
0.
2
2
8
6
07
0
37.
38.
6.
2.
0.
0.
47.
6
3
7
1
02
04
1
100
Percent By Mass
A1J
Categories
2.8
3.0
1.6
0
0
7.5
7.4
11.1
14.7
9.2
0
42.5
5.1
7.1
29.7
1.3
6.9
50.0
100
Within
Category
37.8
40.4
21.8
0
0
100
17.5
26.1
34.7
21.7
0
100
10.2
14.2
59.3
2.6
13.8
100


-------
           TABLE D-lll



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093286 Total Mass of Particulates (nig):
Coors : 256 Agency : —
Monitor Location: Koppel Calculated Mass (mg) : -^6
3
Date of Sample: 8/28/76 Air concentration (ug/iri~):
Coors : 133 Agency :
Category

Sphere
5-10u
10-20y
20-50p
50-75p
>75U
Totals
Irregular
5-lOn
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOu
10-20ij
20-50y
50-75y
>75(j
Totals
TOTALS
Particle
Count


100
0
0
0
0
100

800
175
36
3
1
1015

850
75
24
2
0
951
2066
(All Categories)
Percent By
Number


4.8
0
0
0
0
4.8

38.7
8.5
1.7
0.1
0.05
49.1

41.1
3.6
1.2
0.1
0
46.0
100

Percent By Mass
All
Categories

0.7
0
0
0
0
0.7

6.6
11.6
32.1
13.4
12.0
75.7

3.9
2.8
11.9
5.0
0
23.5
100

Within
Category

100
0
0
0
0
100

8.7
15.2
42.4
17.7
15.9
100

16.6
11.7
50.6
21.1
0
100



-------
           TABLE D-112
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93284

.. . , T , . Brighton
Monitor Location: Township
Date of Sample: 8/28/76

Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


150
50
8
0
0
208

900
225
12
3
0
1140

475
225
0
4
2
706
2054
(All Categories)
Total Mass of Particulates (rug) :
COOTS: 258 Agency: 274
Calculated Mass (mg) : 15°
3
Air concentration ( ug/m ) :
Coors : 149 Agency : 151
Percent By
Number


7
2
0


.3
.4
.4
0
0
10

43
11
.1

.8
.0
0.6
0.1

0
55.5


23.1
11.0

0
0.2
0.1
34.4
100


Percent By Mass
All
Categories

1.2
3.2
7.0
0
0
11.5

8.2
16.4
11.8
14.8
0
51.3

2.4
9.1
0
11.0
14.8
37.3
100

Within
Category

10.6
28.3
61.1
0
0
100

16.0
32.0
23.1
28.9
0
100

6.4
24.5
0
29.4
39.6
100



-------
           TABLE D-113
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093282 Total Mass of Particulates (mg) :
Coors: 479 Agency: 501
Monitor Location: Midland Calculated Mass (mg) : 238
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors: 268 Agency: 248
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Irregular
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
400
125
0
0
0
525
475
175
4
0
0
654
1600
625
64
13
3
2305
N 3484
3S)
Percent By
Number
11.5
3.6
0
0
0
15.1
13.6
5.0
0.1
0
0
18.8
45.9
17.9
1.8
0.4
0.09
66.2
100
Percent By Mass
All
Categories
2.0
5.1
0
0
0
7.2
2.7
8.0
2.5
0
0
13.3
5.1
16.0
22.1
22.5
14.0
79.6
100
Within
Category
28.6
71.4
0
0
0
100
20.6
60.7
18.7
0
0
100
6.4
20.0
27.8
28.2
17.5
100


-------
           TABLE D-114
RESULTS OF SKM PARTICLE COUNTS
Filter Number: HQ6306

Monitor Location: Elco
Date of Sample: 8/28/76

Category
Sphere
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75p
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
225
100
0
0
0
325
250
125
28
4
1
408
350
275
36
1
0
662
1395
«)
Total Mass of Particulates (mg) :
Coors: 91 Agency: 98
Calculated Mass (mg) : 173 .
3
Air concentration ( yg/m ) :
Coors : 43 Agency : 40
Percent By
Number
16
7
.1
.2
0
0
0
23
17
9
2
0
0
29
25
19
2
0
.3
.9
.0
.0
.3
.07
.2
.1
.7
.6
.07
0
47
.4
100
Percent By Mass
All
Categories
1.6
5.6
0
0
0
7.2
2.0
7.9
23.9
17.0
11.4
62.2
1.5
9.6
17.0
2.4
0
30.6
100
Within
Category
22.0
78.0
0
0
0
100
3.2
12.6
38.3
27.4
18.4
100
5.0
31.5
55.7
7.7
0
100


-------
           TABLE D-115
RESULTS OF SEM PARTICLE CDUNTS
Filter Number: 1093296 Total Mass of Particulates (mg) :
Coors: 193 Agency: 149
Monitor Location: Downtown Calculated Mass (rug): 92
3
Date of Sample: 8/28/77 Air Concentration (ug/m ):
Coors : 101 Agency : 70
Category
Sphere
5-lOy
10-2Qy
20-50y
50-75 u
>75y
Totals
Irregular
5-lOu
10-20M
20-50y
50-75M
>75y
Totals
Agglomerate
5-10y
10-20M
20-50y
50-75 y
>75y
Totals
TOTALS
(All Categories
Particle
Count

450
0
4
0
0
454

675
175
4
1
0
855

450
175
8
2
1
636
1945
3)
Percent By
Number

23.1
0
0.2
0
0
23.3

34.7
9.0
0.2
0.05
0
44.0

23.1
9.0
0.4
0.1
0.05
32.7
100
Percent By Mass
All
Categories

5.9
0
5.7
0
0
11.6

10.0
20.7
6.4
8.0
0
45.1

3.7
11.5
7.1
8.9
12.0
43.2
100
Within
Category

51.0
0
49.0
0
0
100

22.1
45.9
14.2
17.8
0
100

8.6
26.6
16.5
20.6
27.7
100


-------
            TABLE  D-116
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093253

Monitor Location: Central Lab
Date of Sample: s 7 28 7 76
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20M
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categories
Particle
Count

325
25
0
0
0
350

975
200
4
2
0
1181

375
250
24
0
1
650
2181
s)
Total Mass of Particulates (mg) :
Coors: 233 Agency: —
Calculated Mass (mg): 111
3
Air Concentration ( yg/m ) :
Coors: 119 Agency: —
Percent By
Number

14.
1.
0
0
0
16.

44.
9.
0.
0.
0
54.


9
1



0

7
2
2
1

1

17.2
11.
1.
0
5
1

0.04
29.8
100
Percent By Mass
All
Categories

3.6
2.2
0
0
0
5.7

12.0
19.7
5.3
13.3
0
50.3

2.6
13.7
17.7
0
10.0
43.9
100
Within
Category

61.9
38.1
0
0
0
100

23.8
39.1
10.6
26.5
0
100

5.8
31.1
40.4
0
22.7
100


-------
           TABLE D-117
RESULTS OF SEM PARTICLE OOUMS
Filter Number:
1106308
Monitor Location: Hazelwood
Date of Sample: 8/28/76

Category
Sphere
5-10y
10-20M
20-50y
50-75y
>75y
Totals
Irregular
5-10u
10-20y
20-50y
50-75u
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
(All Categoric
Particle
Count
150
0
4
0
0
154
550
125
12
0
0
687
425
25
0
0
0
450
1291
s)
Total Mass of Particulates (mg) :
Coors : 151 Agency : 143
Calculated Mass (mg): 50-7
3
Air concentration (pg/m ):
Coors : 71 Agency : 76
Percent By
Number
11
.6
0
0
.3
0

11
42
9
0
.9
.6
.7
0.9


0
0
53.2
32.9
1.9



0
0
0
34.8
100
Percent By Mass
All
Categories
3.6
0
10.4
0
0
13.9
14.8
26.9
35.0
0
0
76.7
6.4
3.0
0
0
0
9.4
100
Within
Category
25.7
0
74.2
0
0
100
19.3
35.1
45.6
0
0
100
68.0
32.0
0
0
0
100


-------
           TABLE D-118
RESULTS OF SEM PARTICLE COLMS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106309 Coors: __ Agency:
Monitor Location: Hazelwood Calculated Mass (mg) : 30.2
•^
Date of Sample: 8/28/76 Air concentration (yg/nf):
(Cover Filter For 1106308) Coors: ~ Agency: —
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorif
Particle
Count
75
0
0
0
0
75
250
150
4
0
0
404
275
25
0
0
0
300
779
•s)
Percent By
Number
9.6
0
0
0
0
9.6
32.1
19.2
0.5
0
0
51.9
35.3
3.2
0
0
0
38.5
100
Percent By Mass
All
Categories
3.0
0
0
0
0
3.0
11.3
54.2
19.5
0
0
85.1
6.9
5.0
0
0
0
11.9
100
Within
Category
100
0
0
0
0
100
13.3
63.7
23.0
0
0
100
57.9
42.1
0
0
0
100


-------
           TABLE  D-119
RESULTS OF SEM PARTICLE COUNTS
Filter Number:
1093298
Monitor Location: North Braddock
Date of Sample: 8/28/76

Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75)i
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
200
100
4
0
0
304
900
100
16
9
1
1026
1025
175
32
7
2
1241
2571
*>
Total Mass of Particulates (mg) :
Coors: 289 Agency: 214
Calculated Mass (mg) : 246
3
Air concentration (ug/m ):
Coors: 153 Agency: 108
Percent By
Number
7
3
0
.8
.9
.2
0
0
11
35
3
0
0
0
39
39
6
1
0
.8
.0
.9
.6
.4
.04
.9
.9
.8
.2
.3
0.08
48
.3
100
Percent By Mass
All
Categories
1.0
3.9
2.1
0
0
7.1
5.0
4.4
9.6
27.0
8.1
54.1
3.2
4.3
10.7
11.7
9.0
38.8
100
Within
Category
14.0
55.8
30.2
0
0
100
9.2
8.2
17.7
49.9
14.9
100
8.1
11.1
27.5
30.1
23.2
100


-------
          TABLE D-120



RESULTS OF SIM PARnCLE COUNTS
Filter Number: (Cover Filter)
1093299
Monitor Location: North Braddock
Date of Sample: 8/28/76
(Cover Filter for 1093298)
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


350
25
4
0
0
379

725
300
8
0
0
1033

950
175
48
4
0
1177
2589
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency : —
Calculated Mass (mg): 140
3
Air concentration (yg/nV):
Coors: — Agency:
Percent By
Number


13
1
0


.5
.0
.2
0
0
14

28
11
0
.6

.0
.6
.3
0
0
39

36
6
1
0
.9

.7
.8
.8
.2
0
45
.5
100


Percent By Mass
All
Categories

3.0
1.7
3.7
0
0
8.5

7.1
23.4
8.4
0
0
38.9

5.1
7.6
28.1
11.7
0
52.6
100

Within
Category

35.6
20.4
44.0
0
0
100

18.2
60.1
21.7
0
0
100

9.8
14.4
53.5
22.3
0
100



-------
          TABLE D-121
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106300

Monitor Location: Duquesne II
Date of Sample: ' 8/28/76

Category
Sphere
5-10y
10-20vi
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
0
0
0
0
0
0
200
50
24
0
0
274
200
250
4
1
0
230
504
*)
Total Mass of Particulates (mg) :
Coors : 68 Agency :
Calculated Mass (mg): 54.1
3
Air concentration (yg/m ):
Coors : — Agency :
Percent By
Number
0
0
0
0
0
0
39.7
9.9
4.J
3
0
0
54.4
39.7
5.0
0.8
0.2
0
45.6
100
Percent By -Mass
All
Categories
0
0
0
0
0
0
5.0
10.1
65.6
0
0
80.7 1
2.8
2.8
6.1
7.6
0
19.3
100
Within
Category
0
0
0
0
0
0
6.2
12.5
81.2
0
0
100
14.6
14.6
31.5
39.4
0
100


-------
           TABLE D-122
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106301 Coors: — Agency:
Monitor Location: Duquesne II Calculated Mass (mg) : 4.2
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
(Cover Filter for 1106300) Coors: — Agency:
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
0
0
0
0
0
0
250
0
0
0
0
250
100
0
0
0
0
100
350
3S)
Percent By
Number
0
0
0
0
0
0
71.4
0
0
0
0
71.4
28.6
0
0
0
0
28.6
100
Percent By Mass
All
Categories
0
0
0
0
0
0
81.8
0
0
0
0
81.8
18.2
0
0
0
0
18.2
100
Within
Category
0
0
0
0
0
0
100
0
0
0
0
100
100
0
0
0
0
100


-------
           TABLE D-123
RESULT OF SEM PARTICLE COUNTS
Filter Number: HQ6302

Monitor Location: Liberty Boro
Date of Sample: 8/28/76

Category

Sphere
5-10u
10-20M
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


775
0
0
0
0
775

1100
250
24
1
1
1376

2625
650
44
1
0
3320
5471
(All Categories)
Total Mass of Particulates (rug) :
Coors: 207 Agency: 271
Calculated Mass (mg) : 214
Air concentration (ug/m ):
Coors: 130 Agency: 136
Percent By
Number


14


2
0
0
0
0
14

20
4
0
0
0
25

48
11
0
0
2

.1
.6
.4
.02
.02
.2

.0
.9
.8
.02
0
60
.7
100


Percent By Mass
All
Categories

4.4
0
0
0
0
4.4

7.0
12.8
16.6
3.4
9.3
49.1

9.3
18.4
16.9
1.9
0
46.5
100

Within
Category

100
0
0
0
0
100

14.3
26.0
33.7
7.0
18.9
100

20.0
39.6
36.2
4.1
0
100



-------
           TABLE D-124



RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter) Total Mass of Particulates (mg) :
1106303 Coors: — Agency:
Monitor Location: Liberty Boro Calculated Mass (mg) : 110
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
(Cover Filter for 1106302) Coors: — Agency:
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
TOTALS
Particle
Count


150
50
0
0
0
200

600
75
28
0
0
703

550
175
28
2
0
755
1658
(All Categories)
Percent By
Number


9.0
3.0
0
0
0
12.1

36.2
4.5
1.7
0
0
42.4

33.2
10.6
1.7
0.1
0
45.5
100

Percent By Mass
All
Categories

1.6
4.4
0
0
0
6.0

7.4
7.4
37.4
0
0
52.3

3.8
9.6
20-8
7.4
0
41.6
100

Within
Category

27.3
72.7
0
0
0
100

14.2
14.2
71.6
0
0
100

9.1
23.1
50.0
17.8
0
100



-------
           TABLE D-125
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106304 Total Mass of Participates (mg) :
Coors: 147 Agency: 215
Monitor Location: Clairton Calculated Mass (mg): 79
3
Date of Sample: August 28, 1976 Air Concentration (yg/m ):
Coors : 61 Agency : 115
Category
Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50 y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50M
50-75M
>75y
Totals
TOTALS
(All Categorie.
Particle
Count

525
50
4
0
0
579

700
250
4
0
0
954

300
125
12
0
0
437
1970
5)
Percent By
Number

26.6
25.4
0.2
0
0
29.4

35.5
12.7
0.2
0
0
48.4

15.2
6.3
0.6
0
0
22.2
100
Percent By Mass
All
Categories

8.1
6.1
6.6
0
0
20.9

12.1
34.6
7.5
0
0
54.2

2.9
9.6
12.5
0
0
25.0
100
Within
Category

38.7
29.5
31.9
0
0
100

22.3
63.8
13.8
0
0
100

11.5
38.5
50.0
0
0
100


-------
           TABLE D-126
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093280 Total Mass of Particulates (mg) :
Coors: 211 Agency: 202
Monitor Location: Airport Calculated Mass (mg) : 120
3
Date of Sanple: 8/28/76 Air concentration (yg/m ):
Coors: 110 Agency: 97
Category

Sphere
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20u
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75p
>75y
Totals
TOTALS
Particle
Count


225
0
0
0
0
225

600
175
4
3
1
784

800
325
20
0
0
1145
2154
(All Categories)
Percent By
Number


10.4
0
0
0
0
10.4

27.9
8.1
0.2
0.1
0.05
36.4

37.2
15.1
0.9
0
0
53.2
100

Percent By Mass
All
Categories

2.3
0
0
0
0
2.3

6.8
15.9
4.9
18.4
16.6
62.6

5.0
16.4
13.6
0
0
35.1
100

Within
Category

100
0
0
0
0
100

10.9
25.4
7.8
29.4
26.4
100

14.4
46.7
38.9
0
0
100



-------
          TABLE D-127
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093278

Monitor Location: South Fayette
Date of Sample: 8/28/76

Category
Sphere
5-lOp
10-20,j
20-50y
50-75M
>75y
Totals
Irregular
5-10p
10-20p
20-50y
50-75y
>75u
Totals
Agglomerate
5-lOp
10-20y
20-50y
50-75u
>75y
Totals
TOTALS
(All Categoric
Particle
Count
1050
0
0
0
0
1050
1350
600
16
2
0
1968
400
100
16
2
0
518
3536
5S)
Total Mass of Particulates (mg) :
Coors: 174 Agency: 120
Calculated Mass (mg): 166
3
Air concentration (yg/m ):
Coors : 91 Agency : 59
Percent By
Number
29
0
0
0
0
29
38
17
0
0
0
55
11
2
0
0
0
14
.7




.7
.2
.0
.4
06

.6
.3
.8
.4
06

.6
100
Percent By Mass
All
Categories
7.7
0
0
0
0
7.7
11.1
39.6
14.3
8.9
0
73.9
1.8
3.7
7.9
5.0
0
18.4
100
Within
Category
100
0
0
0
0
100
15.1
53.6
19.3
12.1
0
100
10.0
19.9
43.1
27.0
0
100


-------
           TABLE D-128



RESULTS OF 81-AI PARTICLE COUNTS
Filter Number: 1106351 Total Mass of Particulates (mg) :
Coors: 226 Agency: 254
Monitor Location: Midland Calculated Mass (mg) : 205
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors: 128 Agency: 127
Category
Sphere
5-lOy
10-20y
20-50y
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20iJ
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorie
Particle
Count
175
0
0
0
0
175
525
125
12
1
0
663
2525
950
88
2
0
3565
4403
;s)
Percent By
Number
4.0
0
0
0
0
4.0
11.9
2.8
0.3
0.02
0
15.0
57.3
21.6
2.0
0.04
0
81.0
100
Percent By Mass
All
Categories
1.0
0
0
0
0
1.0
3.5
6.6
8.6
3.6
0
22.4
9.3
28.1
35.2
4.0
0
76.6
100
Within
Category
100
0
0
0
0
100
15.6
29.7
38.6
16.1
0
100
12.2
36.7
45.9
5.2
0
100


-------
           TABLE D-129
RESULTS OF SFA1 PARTICLE GODOT'S
Filter Number: 1093265 Total Mass of Particulates (mg) :
Coors: 114 Agency: 136
Monitor Location: Elco Calculated Mass (mg) : 108
3
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors: 54 Agency: 59
Category

Sphere
5-lOy
10-20y
20-50jj
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


50
0
8
0
0
58

250
175
20
0
0
445

275
225
36
0
0
536
1039
(All Categories)
Percent By
Number


4.8
0
0.8
0
0
5.6

24.1
16.8
1.9
0
0
42.8

26.5
21.6
3.5
0
0
51.6
100

Percent By Mass
All
Categories

0.6
0
9.7
0 •
0
10.2

3.1
17.6
27.2
0
0
48.0

1.9
12.6
27.2
0
0
41.7
100

Within
Category

5.5
0
94.5
0
0
100

6.6
36.7
56.7
0
0
100

4.6
30.2
65.2
0
0
100



-------
           TABLE D-130
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1106333

Monitor Location: Central Lab
Date of Sample: 9/3/76

Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


200
0
0
0
0
200

175
125
32
2
0
335

1150
425
40
1
0
1616
2151
(All Categories)
Total Mass ol Particulates (mg) :
Coors: 256 Agency: 248
Calculated Mass (mg) : 152
3
Air concentration (yg/m ):
Coors: 123 Agency: 132
Percent By
Number


9.


3
0
0
0
0
9.

8.
5.
1.
0.
3

1
8
5
09
0
15.

53.
19.
1.
0.
5

5
8
9
05
0
75.
2
100


Percent By Mass
All
Categories

1.6
0
0
0
0
1.6

1.6
9.0
31.1
9.7
0
51.4

5.7
17.0
21.6
2.7
0
47.0
100

Within
Category

100
0
0
0
0 .
100

3.1
17.5
60.5
18.9
0
100

12.2
36.1
45.9
5.7
0
100



-------
          TABLE  D-131
RESULTS OF SFM PARTICLE COUNTS
Filter Number: 1106325 Total Mass of Particulates (mg) :
Coors: 265 Agency: 234
Monitor Location: Hazelwood Calculated Mass (mg) : 151
3
Date of Sample: 9/3/76 Air concentration (Mg/m ):
Coors: 129 Agency: 134
Category

Sphere
5-1 Op
10-20y
20-50y
50-75M
>75y
Totals
Irregular
5-10p
10-20y
20-50y
50-75p
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75u
>75M
Totals
TOTALS
Particle
Count


100
0
0
0
0
100

400
250
20
1
0
671

1200
225
60
2
0
1487
2258
(All Categories)
Percent By
Number


4.4
0
0
0
0
4.4

17.7
11.1
0.9
0.04
0
29.7

53.1
10.0
2.6
0.09
0
65.8
100

Percent By Mass
All
Categories

0.8
0
0
0
0
0.8

3.6
18.1
19.5
4.9
0
46.1

6.0
9.0
32.6
5.4
0
53.1
100

Within
Category

100
0
0
0
0
100

7.8
39.2
42.4
10.6
0
100

11.4
17.0
61.4
10.2
0
100



-------
           TABLE D-132
RESULTS OF SKAI PARTICLE COUNTS
Filter Number: 1106315 Total Mass of Participates (mg) :
Coors: 289 Agency: 308
Monitor Location: North Braddock Calculated Mass (mg) : 115
3
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors: 140 Agency: 148
' Category

Sphere
5-10u
10-20y
20-5 Oy
50-7 5|j
>75y
Totals
Irregular
5-10y
10-20y
20-5 Oy
50-7 5y
>75y
Totals
Agglomerate
5-10y
10-2 Oy
20-50y
50-7 5y
>75y
Totals
TOTALS
Particle
Count


325
25
0
0
0
350

375
100
12
0
0
487

1375
500
36
1
0
1912
2749
(All Categories)
Percent By
Number


11.8
0.9
0
0
0
12.7

13.6
3.6
0.4
0
0
17.7

50.0
18.2
1.3
0.04
0
69.6
100

Percent By Mass
All
Categories

3.4
2.1
0
0
0
5.6

4.5
9.5
15.5
0
0
29.5

9.1
26.5
25.8
3.6
0
65.0
100

Within
Category

61.9
38.1
0
0
0
100

15.2
32.4
52.5
0
0
100

14.0
40.8
39.7
5.5
0
100



-------
           TABLE D-133
RESULTS OF SKM PARTICLE COUNTS
Filter Number: HQ6321

Monitor Location: Duquesne II
Date of Sample: 9/3/76

Category
Sphere
5-10u
10-20y
20-50p
50-7 5y
>75p
Totals
Irregular
5-10u
10-20M
20-50n
50-75)j
>75y
Totals
Agglomerate
5-10u
10-20u
20-50p
50-75p
>75u
Totals
TOTALS
(All Categoric
Particle
Count
75
0
0
0
0
75
225
125
16
1
0
367
1100
575
32
2
0
1709
2151
|S)
Total Mass of Particulates (mg) :
Coors: 263 Agency: 319
Calculated Mass (mg) : 126
3
Air concentration (ug/m ):
Coors: 150 Agency: 157
Percent By
Number
3
.5
0
0
0
0
3
10
5
0
0
.5
.5
.8
.7
.05
0
17
51
26
1
0
.1
.1
.7
.5
.09
0
79
.4
100
Percent By Mass
All
Categories
0.7
0
0
0
0
0.7
2.4
10.8
18.7
5.8
0
37.8
6.6
27.6
20.8
6.5
0
61.5
100
Within
Category
100
0
0
0
0
100
6.4
28.6
49.5
15.5
0
100
10.7
44.9
23.8
10.6
0
100


-------
           TABLE D-134
RESULTS OF SB1 PARTICLE COUNTS
Filter Number: 1106329 Total Mass of Particulates (mg) :
Coors: 119 Agency: 123
Monitor Location: Liberty Boro Calculated Mass (mg) : 152
3
Date of Sample: 9/3/76 Air concentration (ug/nf ):
Coors: 73 Agency: 60
Category

Sphere
5-10M
10-20M
20-50y
50-75y
>75y
Totals
Irregular
5-10n
10-20y
20-50y
50-75y
>75M
Totals
Agglomerate
5-10p
10-20y
20-50n
50-75y
>75M
Totals
TOTALS
Particle
Count


125
0
0
0
0
125

550
200
12
2
0
764

825
525
56
1
0
1407
2296
(All Categories)
Percent By
Number


5.4
0
0
0
0
5.4

24.0
8.7
0.5
0.09
0
33.3

35.9
22.9
2.4
0.04
0
61.3
100

Percent By Mass
All
Categories

1.0
0
0
0
0
1.0

5.0
14.4
11.7
9.8
0
40.8

4.1
21.0
30.3
2.7
0
58.2
100

Within
Category

100
0
0
0
0
100

12.1
35.3
28.6
23.9
0
100

7.1
36.1
52.1
4.6
0
100



-------
           TABLE D-135
RESULTS OF SF.M PARTICLE COUNTS
Filter Number: 1106331 Total Mass of Particulates (mg) :
Coors: 207 Agency: 224
Monitor Location: Clairton Calculated Mass (mg) : 245
3
Date of Sample: 9/3/76 Air concentration (yg/m ):
Coors: 90 Agency: 115
Category
Sphere
5-10u
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10p
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75p
>75y
Totals
TOTALS
(All Categoric
Particle
Count
375
25
0
0
0
400
350
200
44
0
0
594
1075
775
96
3
0
1949
2943
*0
Percent By
Number
12.7
0.8
0
0
0
13.6
11.9
6.8
1.5
0
0
20.2
36.5
26.3
3.3
0.1
0
66.2
100
Percent By Mass
All
Categories
1.8
1.0
0
0
0
2.8
2.0
8.9
26.5
0
0
37.4
3.3
19.2
32.2
5,0
0
59.7
100
Within
Category
65.2
34.8
0
0
0
100
5.2
23.8
70.9
0
0
100
5.6
32.2
53.8
8.4
0
100


-------
           TABLE D-136
RESULTS OF SFAI PARTICLE COUNTS
Filter Number: 1106337 Total Mass of Particulates (mg) :
Coors: 164 Agency: 134
Monitor Location: South Fayette Calculated Mass (mg) : 153
3
Date of Sample: 9/3/76 Air concentration (ug/m ):
Coors : 79 Agency : 65
Category

Sphere
5-10y
10-20y
20-50p
50-75M
>75p
Totals
Irregular
5-10u
10-20p
20-50M
50-75y
>75p
Totals
Agglomerate
5-lOy
10— 2 Op
20— 50p
50-75U
>75u
Totals
TOTALS
Particle
Count


150
0
4
0
0
154

525
175
16
2
0
718

800
300
44
5
0
1149
2021
(All Categories)
Percent By
Number


7.4
0
0.2
0
0
7.6

26.0
8.6
0.8
0.1
0
35.5

39.6
14.8
2.2
0.2
0
56.8
100

Percent By Mass
All
Categories

1.2
0
3.4
0
0
4.6

4.7
12.5
15.5
9.7
0
42.4

4.0
11.9
23.6
13.4
0
53.0
100

Within
Category

25.7
0
74.2
0
0
100

11.1
29.5
36.5
22.8
0
100

7.5
22.5
44.6
25.4
0
100



-------
           TABLE D-137
RESULTS OF SKM PARTICLE OOUN1S
Filter Nun±>er: 1093271

Monitor Location: Baden
Date of Sample: 9/9/76

Category
Sphere
5-10u
10-20y
20-50y
50-75M
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75U
>75y
Totals
Agglomerate
5-10p
10-20y
20-50vi
50-75y
>75u
Totals
TOTALS
(All Categoric
Particle
Count
750
50
4
0
0
804
550
400
44
2
0
996
600
575
104
3
0
1282
3082
>s)
Total Mass of Particulates (rug) :
Coors: 386 Agency: 355
Calculated Mass (nig): 287
3
Air concentration (ug/m ):
Coors: 207 Agency: 185
Percent By
Number
24
1
0


26
17
13
1
0
.3
.6
.1
0
0
.1
.8
.0
.4
.06
0
32
19
18
3
0

41
.3
.5
.6
.4
.1
0
.6
100
Percent By Mass
All
Categories
3.2
1.7
1.8
0
0
6.7
2.6
15.2
22.6
5.1
0
45.6
1.6
12.1
29.7
4.3
0
47.7
100
Within
Category
47.4
25.3
27.3
0
0
100
5.7
33.4
49.6
11.3
0
100
3.3
25.4
62.2
9.0
0
100


-------
          TABLE D-138
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093269 Total Mass of Particulates (mg):
Coors: 387 Agency: 339
Monitor Location: Beaver Falls Qilculated Mass (mg) : 160
3
Date of Sample: 9/9/76 Air concentration (ug/m ):
Coors: 232 Agency: 168
Category

Sphere
5-10y
10-20y
20-50|j
50-7 5y
>75y
Totals
Irregular
5-10y
10-20u
20-50p
50-75y
>75y
Totals
Agglomerate
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count

50
0
0
0
0
50
375
250
28
4
0
657
750
325
32
1
0
1108
1815
(All Categories)
Percent By
Number

2.8
0
0
0
0
2.8
20.7
13.8
1.5
0.2
0
36.2
41.3
17.9
1.8
0.06
0
61.0
100

Percent By Mass
All
Categories
0.4
0
0
0
0
0.4
3.2
17.1
25.9
18.5
0
64.7
3.6
12.3
16.4
2.6
0
34.9
100

Within
Category
100
0
0
0
0
100
5.0
26.4
40.0
28.6
0
100
10.2
35.4
47.1
7.4
0
100



-------
           TABLE D-139
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093267

Monitor Location: Koppel
Date of Sample: 9/9/76

Category

Sphere
5-10u
10-20M
20-50p
50-75M
>75U
Totals
Irregular
5-10p
10-20y
20-50y
50-75u
>75M
Totals
Agglomerate
5-10y
10-20p
20-50y
50-75y
>75M
Totals
TOTALS
Particle
Count


200
25
0
0
0
225

500
300
28
0
1
829

1025
550
48
6
0
1629
2683
(All Categories)
Total Mass of Particulates (mg) :
Coors: 296 Agency: 330
Calculated Mass (mg) : 211
3
Air concentration ( ug/m ) :
Coors : 156 Agency : 174
Percent By
Number




7.4
0.
0
0
9


0
8.

18.
11.
1.
4

6
2
0
0
0.
30.

38.
20.
1.
0.
04
9

2
5
8
2
0
60.
7
100


Percent By Mass
All
Categories

1.2
1.2
0
0
0
2.3

3.2
15.5
19.6
0
9.4
47.8

3.7
15.8
18.7
11.7
0
49.9
100

Within
Category

50.0
50.0
0
0
0
100

6.8
32.5
41.0
0
19.7
100

7.4
31.7
37.4
23.4
0
100



-------
            TABLE  D-140
RESULTS OF  SF,M PAKTICIE COUNTS
Filter Number: 1110928 Total Mass of Particulates (mg) :
Coors: 338 Agency: 287
Monitor Location: Brlghton Calculated Mass (mg) : 114
Date of Sample: 9/9/76 Air concentration (ug/rrf ):
Coors: 178 Agency: 160
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


200
0
0
0
0
200

325
200
24
0
0
549

525
250
32
1
0
808
1557
(All Categories)
Percent By
Number


12.8
0
0
0
0
12.8

20.9
12.8
1.5
0
0
35.3

33.7
16.0
2.0
0.06
0
51.9
100

Percent By Mass
All
Categories

2.1
0
0
0
0
2.1

3.9
19.2
31.1
0
0
54.3

3.5
13.3
23.1
3.6
0
43.6
100

Within
Category

100
0
0
0
0
100

7.2
35.4
57.4
0
0
100

8.0
30.6
53.0
8.3
0
100



-------
           TABLE D-141
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1093292 Total Mass of Particulates (mg) :
Coors : 667 Agency : 688
Monitor Location: Midland Calculated Mass (mg) : 185
3
Date of Sample: 9/9/76 Air concentration (ug/nT):
Coors: 404 Agency: 341
Category
Sphere
5-10M
10-20M
20-50u
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
100
0
0
0
0
100
225
150
20
0
1
396
600
725
56
5
0
1386
1882
?s)
Percent By
Number
5.3
0
0
0
0
5.3
12.0
8.0
1.1
0
0.05
21.0
31.9
38.5
3.0
0.3
0
73.6
100
Percent By Mass
All
Categories
0.7
0
0
0
0
0.7
1.6
8.8
16.0
0
10.7
37.2
2.4
23.8
24.8
11.1
0
62.1
100
Within
Category
100
0
0
0
0
100
4.6
23.8
42.9
0
28.9
100
4.0
38.2
39.9
17.8
0
100


-------
           TABLE D-142
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106379 Total Mass of Particulates (mg) :
Coors : 187 Agency :
Monitor Location: Elco Calculated Mass (mg) : 132
Date of Sample: 9/9/76 Air concentration (pg/m'):
Coors : 84 Agency :
Category

Sphere
5-10M
10-20U
20-5 Op
50-7 5p
>75)j
Totals
Irregular
5-10p
10-20y
20-50u
50-75y
>75p
Totals
Agglomerate -•
5-lOu
10-20y
20-50y
50-75)j
>75y
Totals
TOTALS
Particle
Count


300
25
0
0
0
325

900
375
8
0
0
1283

775
275
32
3
0
1085
2693
(All Categories)
Percent By
Number


11.1
0.9
0
0
0
12.1

33.4
13.9
0.3
0
0
47.6

28.8
10.2
1.2
0.1
0
40.3
100

Percent By Mass
All
Categories

2.8
1.8
0
0
0
4.6

9.3
31.0
8.9
0
0
49.2

4.4
12.6
19.8
9.3
0
46.2
100

Within
Category

60.0
40.0
0
0
0
100

18.9
63.0
18.2
0
0
100

9.6
27.3
42.9
20.1
0
100



-------
           TABLE  D-143
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106323 Total Mass of Particulates (mg) :
Coors: 5.7 Agency: 337
Monitor Location: Downtown Calculated Mass (mg): 15.2
3
Date of Sample: 9/9/76 Air concentration (yg/m ):
Coors : — Agency : 159
Category

Sphere
5-lOy
10-20p
20-50jj
50-75)j
>75y
Totals
Irregular
5-10u
10-20y
20-5 Oy
50-75y
>75y
Totals
Agglomerate
5-10y
10-20u
20-50jj
50-75y
>75y
Totals
TOTALS
Particle
Count


25
0
4
0
0
29

150
0
0
1
0
151

25
0
0
0
0
25
205
(All Categories)
Percent By
Number


12.2
0
2.0
0
0
14.1

73.2
0
0
0.5
0
73.6

12.2
0
0
0
0
12.2
100

Percent By Mass
All
Categories

2.0
0
34.6
0
0
36.6

13.5
0
0
48.7
0
62.2

1.2
0
0
0
0
1.2
100

Within
Category

5.5
0
94.5
0
0
100

21.7
0
0
78.3
0
100

100
0
0
0
0
100



-------
           TABLE D-144
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106327

Monitor Location: Central Lab
Date of Sample: 9/9/76
(First Fjxamination)
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


500
75
0
0
0
575

2050
625
36
0
0
2711

2950
900
188
6
0
4044
7330
(All Categories)
Total Mass of Particulates (mg) :
Coors : 429 Agency : 428
Calculated Mass (mg): 419
3
Air concentration (yg/m ):
Coors: 219 Agency: 235
Percent By
Number


6
1


.8
.0
0
0
0
7

28
8
0


37

.8

.0
.5
.5
0
0
.0

40.2
12.3
2.6
0.08

0
55.2
100


Percent By Mass
All
Categories

1.4
1.7
0
0
0
3.2

6.7
16.3
12.7
0
0
35.7

5.3
13.0
36.8
5.9
0
61.1
100

Within
Category

45.4
54.5
0
0
0
100

18.7
45.7
35.6
0
0
100

8.7
21.3
60.3
9.6
0
100



-------
           TABLE D-145
RESULT OF SEM PARTICLE COUOTS
Filter Number: 1106327

Monitor Location: Central Lab
Date of Sample: 9/9/76
(Second Examination)
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


75
0
0
0
0
75

950
250
28
1
0
1229

1050
300
96
6
1
1453
2757
(All Categories)
Total Mass of Particulates (mg) :
Coors: 42g Agency: 428
Calculated Mass (mg) : 231
3
Air concentration ( ug/m ) :
Coors: 219 Agency: 235
Percent By
Number


2


.7
0
0
0
0
2

34
9
1
0
.7

.4
.1
.0
.04
0
44

38
10
3
0
0
52
.6

.1
.9
.5
.2
.04
.7
100


Percent By Mass
All
Categories

0.4
0
0
0
0
0.4

5.6
11.8
17.9
3.2
0
38.6

3.4
7.9
34.2
10.7
4.8
61.0
100

Within
Category

100
0
0
0
0
100

14.6
30.7
46.4
8.3
0
100

5.7
12.9
56.0
17.5
7.9
100



-------
           TABLE  D-146
RESULTS OF SEM PARTICLE COUNTS
Filter Number: (Cover Filter)
1106328
Monitor Location: Central Lab
Date of Sample: 9/9/76
(Cover Filter for 1106327)
Category

Sphere
5-10u
10-20y
20-50y
50-75)j
>75U
Totals
Irregular
5-10u
10-20U
20-50y
50-75y
>75y
Totals
Agglanerate
5-10y
10-20y
20-50y
50-75p
>75y
Totals
TOTALS
Particle
Count


100
0
0
0
0
100

825
300
32
1
0
1158

1175
325
60
2
3
1565
2823
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency :
Calculated Mass (mg) : 219
3
Air concentration ( yg/m ) :
Coors : — Agency :
Percent By
Number


3.


5
0
0
0
0
3

29
10
1
0
5

2
6
1
04
0
41

41
11
2
0
0
55
0

6
5
1
.07
1
.4
100


Percent By Mass
All
Categories

0.6
0
0
0
0
0.6

5.1
15.0
21.6
3.4
0
45.0

4.1
9.0
22.5
3.7
15.1
54.4
100

Within
Category

100
0
0
0
0
100

11.4
33.2
47.9
7.5
0
100

7.5
16.5
41.3
6.9
27.8
100



-------
           TAfiLE D-147
RESULT OF SKM PARTICLE COUNTS
Filter Number: 1106353

Monitor Location: Hazelwood
Date of Sample: 9/9/76

Category

Sphere
5-10y
10-20y
20-50y
50— 75y
>75y
Totals
Irregular
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


625
25
0
0
0
650

250
100
12
1
0
363

1275
675
64
2
0
2016
3029
(All Categories)
Total Mass of Particulates (mg) :
Coors: 280 Agency: 238
Calculated Mass (mg) : 161
3
Air concentration ( yg/m ) :
Coors: 137 Agency: 140
Percent By
Number




20.6
0.8



0
0
0
21.4


8.2
3.3
0.4
0.3

0
12.0


42.1
22.2
2.1
0.07

0
66.6
100


Percent By Mass
All
Categories

4.7
1.5
0
0
0
6.2

2.1
6.8
11.0
4.6
0
24.5

6.0
25.5
32.6
5.1
0
69.2
100

Within
Category

75.8
24.2
0
0
0
100

8.6
27.7
44.9
18.7
0
100

8.7
36.8
47.2
7.4
0
100



-------
           TABLE D-148



RESULTS OF SEM PARTICLE COUNTS
Filter Number: UQ6386

Monitor Location: North Braddock
Date of Sample: 9/9/76
(First examination of stub)
Category

Sphere
5-lOy
10-20y
20-50y
50-7 5y
>75y
Totals
Irregular
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


725
100
8
0
0
833

375
200
36
0
1
612

1125
750
72
4
0
1951
3396
(All Categories)
Total Mass of Particulates (mg) :
Coors : 474 Agency : 532
Calculated .Mass (mg): 259
3
Air concentration (ug/m ):
Coors: 248 Agency: 272
Percent By
Number


21
2


.3
.9
0.2


24

11
0
0
.5

.0
5.9
1

.1
0
0.03
18.0

33

.1
22.1
2.1
0.1

0
57.4
100


Percent By Mass
A1J
Categories

3.4
3.8
4.1
0
0
11.2

2.0
8.4
20.6
0
7.7
38.7

3.3
17.6
22.8
6.4
0
50.1
100

Within
Category

30.3
33.5
36.2
0
0
100

5.1
21.8
53.1
0
19.9
100

6.6
35.1
45.6
12.7
0
100



-------
           TABLE  D-149
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106386

Monitor Location: North Braddock
Date of Sample: 9/9/76
(Second examination of stub)
Category

Sphere
5-10y
10-20y
20-50p
50-75y
>75M
Totals
Irregular
5-10M
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10u
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count


275
75
4
0
0
354

1850
775
80
1
0
2706

2175
1125
236
11
0
3547
6607
(All Categories)
Total Mass of Particulates (mg) :
Coors : 474 Agency : 532
Calculated Mass (mg) : 575
3
Air concentration (ug/m ):
Coors: 248 Agency: 272
Percent By
Number


4.
1.
0.


2
1
06
0
0
5.

28.
11.
1.
0.
4

0
7
2
02
0
41.

32.
17.
3.
0.
0

9
0
6
2
0
53
7
100


Percent By Mass
All
Categories

0.6
1.3
0.9
0
0
2.8

4.4
14.7
20.6
1.3
0
41.0

2.9
11.9
33.7
7.8
0
56.3
100

Within
Category

21.0
45.9
33.1
0
0
100

10.7
36.0
50.2
3.1
0
100

5.1
21.1
59.8
14.0
0
100



-------
            TABLE D-150



RESULTS OF  SI-..M PARTICLE COUNTS
Filter Number: (Cover Filter)
1106385
Monitor Location: North Braddock
Date of Sample: 9/9/76
(Cover Filter for 1106386)
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-lOy
10-20]J
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


350
100
4
0
0
454

1650
475
44
2
0
2171

1325
925
148
9
0
2407
5032
(All Categories)
Total Mass of Particulates (mg) :
Coors : — Agency : —
Calculated Mass (mg) : 398
3
Air concentration (yg/m ):
Coors : — Agency :
Percent By
Number




7.0
2.
0.
0
0
9.

32.
9.
0.
0.
0
43.

26.
18.
2.
0.
0
08


0

8
4
9
04

1

3
4
9
2
0
47.
8
100


Percent By Mass
All
Categories

1.1
2.4
1.3
0
0
4.8

5.7
13.0
16.3
3.7
0
38.7

2.5
14.1
30.5
9.3
0
56.4
100

Within
Category

22.1
50.5
27.3
0
0
100

14.6
33.6
42.1
9.6
0
100

4.5
25.0
54.1
16.4
0
100



-------
           TABLE D-151
RESULTS OF SEM PARTICLE OOUOTS
Filter Number: 1106383

Monitor Location: Duquesne II
Date of Sample: 9/9/76

Category

Sphere
5-10M
10-20y
20-50y
50-75y
>75M
Totals
Irregular
5-10y
10-20y
20-5 Oy
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
TOTALS
Particle
Count


475
25
0
0
0
500

375
400
16
2
0
793

1025
625
52
5
0
1707
3000
(All Categories)
Total Mass of Particulates (mg) :
Coors : 423 Agency : 524
Calculated Mass (mg) : 204
3
Air concentration (pg/m ):
Coors: 242 Agency: 260
Percent By
Number


15
0



16



.8
.8
0
0
0
.7

12.5
13.3
0.5
0.07

0
26.4


34.2
20.8



1.7
0.2
0
56.9
100
Percent By Mass
Al]
Categories

2.8
1.2
0
0
0
4.0

2.5
21.4
11.6
7.2
0
42.7

3.8
18.6
20.9
10.0
0
53.3
100

Within
Category

70.4
29.6
0
0
0
100

5.9
50.1
27.1
16.9
0
100

7.1
34.8
39.2
18.8
0
100



-------
           TABLE D-152
RESULTS OF SKM PARTICLE COUNTS
Filter Number: 1106388

Monitor Location: Liberty Boro
Date of Sample: 9/9/76

Category

Sphere
5-lOp
10-20y
20-50p
50-75y
>75)j
Totals
Irregular
5-lOy
10-20p
20-50u
50-75y
>75y
Totals
Agglomerate
5-10y
10-20p
20-50y
50-75y
>75M
Totals
TOTALS
Particle
Count


725
100
0
0
0
825

600
175
16
2
0
793

1825
900
88
12
0
2825
4443
(All Categories)
Total Mass of Particulates (mg) :
Coors : 471 Agency : 582
Calculated Mass (mg): 274
3
Air concentration (ug/m ):
Coors: 289 Agency: 315
Percent By
Number


16.
2.


3
2
0
0
0
18.

13.
3.
0.
0.
6

5
9
4
04
0
17.

41
20
2
0
8

1
2
0
3
0
63
6
100


Percent By Mass
All
Categories

3.2
3.5
0
0
0
6.8

3.0
7.0
8.6
5.4
0
24.0

5.0
19.9
26.3
18.0
0
69.3
100

Within
Category

47.5
52.4
0
0
0
100

12.5
29.1
36.0
22.5
0
100

7.3
28.8
38.0
25.9
0
100



-------
           TABLE D-153
RESULTS OF SB! PARTICLE COUNTS
Filter Number: 1106381

Monitor Location: Clairton
Date of Sample: 9/9/76

Category

Sphere
5-10y
10-20y
20-50y
50-75M
>75u
Totals
Irregular
5-lOy
10-20y
20-50p
50-75M
>75y
Totals
Agglomerate
5-10u
10-20p
20-50y
50-75jj
>75p
Totals
TOTALS
Particle
Count


400
25
0
0
0
425

400
300
20
3
0
723

575
500
56
2
0
1133
2281
(All Categories)
Total Mass of Particulates (mg) :
Coors: 293 Agency: 330
Calculated Mass (mg): 186
3
Air concentration (pg/m ):
Coors: 127 Agency: 178
Percent By
Number


17
1



18

17
13


.5
.1
0
0
0
.6

.5
.2
0.9
0.1

31

0
.7

25.2
21
2
.9
.4
0.09

0
49.7
100


Percent By Mass
All
Categories

2.6
1.3
0
0
0
3.9

2.9
17.6
15.9
11.9
0
48.3

2.3
16.3
24.7
4.4
0
47.8
100

Within
Category

66.7
33.3
0
0
0
100

6.1
36.4
32.8
24.6
0
100

4.9
34.1
51.7
9.2
0
100



-------
           TABLE D-154
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093294

Monitor Location: Airport
Date ol Sample: 9/9/76

Category

Sphere
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-7 5y
>75y
Totals
Agglomerate
5-10u
10-20u
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


75
0
0
0
0
75

550
150
8
1
0
709

800
125
8
7
1
941
1725
(All Categories)
Total Mass of Particulates (mg) :
Coors : 177 Agency : 294
Calculated Mass (mg) : 104
Air concentration (yg/m ):
Coors: 207 Agency: 147
Percent By
Number


4.


3
0
0
0
0
4

31
8
0
0
3

9
7
5
06
0
41

46
7
0
0
0
54
1

.4
.2
.5
.4
.06
.6
100


Percent By Mass
All
Categories

0.9
0
0
0
0
0.9

7.2
15.8
11.4
7.1
0
41.4

5.8
7.3
6.3
27.6
10.6
57.7
100

Within
Category

100
0
0
0
0
100

17.4
38.0
27.4
17.1
0
100

10.1
12.6
10.9
47.9
18.4
100



-------
           TABLE D-155



RESULT OF SEiM PARTICLE COUNTS
Filter Number: (Cover Filter)
1093295
Monitor Location: Airport
Date of Sample: 9/9/76
(Cover Filter for 1093294
Category

Sphere
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-lOp
10-20y
20-50p
50-75ij
>75y
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75u
Totals
TOTALS
Particle
Count


25
0
0
0
0
25

575
150
4
0
0
729

550
200
12
0
0
762
1516
(All Categories)
Total Mass of Particulates (mg) :
Coors : Agency :
Calculated ,\kss (mg): 56.6
3
Air concentration (ug/m ):
Coors : — Agency :
Percent By
Number


1.


6
0
0
0
0
1.

37.
9
0
6

9
9
3
0
0
48

36
13
0
1

.3
.2
8
0
0
50
.3
100


Percent By Mass
All
Categories

0.5
0
0
0
0
0.5

13.9
28.9
10.4
0
0
53.2

7.4
21.4
17.4
0
0
46.2
100

Within
Category

100
0
0
0
0
100

26.0
54.4
19.6
0
0
100

16.0
46.4
37.6
0
0
100



-------
           TABLE  D-156
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106310 Total Mass of Particulates (mg) :
Coors: 278 Agency: 214
Monitor Location: South Fayette Calculated Mass (mg): 230
3
Date of Sample: 9/9/76 Air concentration ( pg/m ):
Coors: 145 Agency: 107
Category

Sphere
5-10y
10-20y
20-50p
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


575
100
8
0
0
683

1150
350
40
0
0
1540

1050
400
40
6
0
1496
3719
(All Categories)
Percent By
Number


15.5
2.7
0.2
0
0
18.4

30.9
9.4
1.1
0
0
41.4

28.2
10.8
1.1
0.2
0
40.2
100

Percent By Mass
All
Categories

3.0
4.2
4.6
0
0
11.8

6.8
16.6
25.7
0
0
49.2

3.5
10.6
14.3
10.7
0
39.0
100

Within
Category

25.7
35.7
38.6
0
0
100

13.9
33.8
52.3
0
0
100

8.9
27.1
36.6
27.5
0
100



-------
          TABLE D- 157
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93227 & 1093228
(combined cover & primary filters)
Monitor Location: Midland
Date of Sample: 8/16/76

Category

Sphere
5-10y
10-20y
20-50vi
50~75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10u
10~20y
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count


500
100
4
0
0
604

2175
350
44
3
0
2572

1850
175
28
3
0
2056
5232
(All Categories)
Total Mass of Particulates (mg) :
Coors: 149 Agency: 166
Calculated Mass (mg) : 236
3
Air concentration (ug/m ):
Coors: 83 Agency: 80
Percent By
Number


9
1
0


6
9
08
0
0
11

41
6
0
0
5

.6
.7
8
06
0
49

35
3
0
0
.2

.4
.3
.5
.06
0
39
.3
100


Percent By Mass
Ail
Categories

2.6
4.1
2/2
0
0
8.9

12.6
16.2
27.5
9.4
0
65.7

5.9
4.5
9.7
5.2
0
25.4
100

Within
Category

28.8
46.2
25.0
0
0
100

19.2
24.6
41.9
14.3
0
100

23.4
17.7
38.3
20.5
0
100



-------
           TABLE D-158



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93229 & 1093230
(combined cover & primary filters)
Monitor Location: Airport
Date of Sample: 8/16/76

Category

Sphere
5-lOu
10-20y
20-50y
50-75y
>75u
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Agglomerate
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


150
0
4
0
1
155

1725
350
32
3
0
2110

2125
450
36
2
0
2613
4878
(All Categories)
Total Mass of Particulates (mg) :
Coors : 149 Agency : 151
Calculated Nkss (mg) : 237
3
Air concentration (yg/m ):
Coors : 76 Agency : 72
Percent By
Number




3.1
0

0.08
0

0.02
3.2


35.4
7.2
0.6
0.06
0
43.

43.
9.
0.
0.
0
53.

2

6
2
7
04

6
100


Percent By Mass
All
Categories

0.8
0
2.2
0
7.4
10.4

9.9
16.1
19.9
9.3
0
55.3

6.8
11.5
12.4
3.5
0
34.2
100

Within
Category

7.4
0
21.2
0
71.4
100

18.0
29.1
36.0
16.9
0
100

19.8
33.6
36.4
10.1
0
100



-------
           TABLE  D-159
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1Q93290 & 1093291
(combined cover & primary filters)
Monitor Location: Baden
Date of Sample: 8/28/76

Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
	 — — — — — _
Totals
TOTALS
Particle
Count


550
225
20
0
0
795

2275
800
152
5
1
3233

2250
1200
248
65
5
3768

7796
(All Categories)
Total Miss of Particulates (mg) :
Coors: 374 Agency: 351
Calculated Mass (mg) : !071
3
Air concentration (yg/m ):
Coors: 203 Agency: 183
Percent By
Number




7.0
2.9
0.2
0
0


10.2

29.
10.
1.
0.
0.
41.

28.
15.
3.
0.
0.
48".


2
3
9
06
01
5

9
4
2
8
06
T 	

100


Percent By Mass
. All
Categories

0.6
2.0
2.4
0
0
5.1

2.9
8.2
21.0
3.4
1.8
37.4

1.6
6.8
19.0
24.9
5.2
~~5T.^ 	

100

Within
Category

12.2
39.9
47.9
0
0
100

7.8
21.8
56.2
9.2
5.0
100

2.8
11.8
33.0
43.4
9.0
100




-------
          TABLE D- 160



RESULTS OF SEM PARTI CLE OOUMS
Filter Number: ^093247 & 1093248 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 433 Agency:
Monitor Location: Liberty Boro Calculated Mass (mg) : 1026
3
Date of Sample: 8/22/76 Air concentration (yg/m"):
Coors: 272 Agency:
Category
Sphere
5-10y
10-20y
20-50)j
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categorit
Particle
Count

275
0
0
0
0
275

2550
875
168
8
0
3601

3200
1225
356
39
3
4823
8699
)S)
Percent By
Number

3.2
0
0
0
0
3.2

29.3
10.0
1.9
0.09
0
41.4

36.8
14.1
4.1
0.4
0.03
55.4
100
Percent By Mass
All
Categories

0.3
0
0
0
0
0.3

3.4
9.3
24.2
5.8
0
42.7

2.4
7.2
28.5
15.6
3.2
57.0
100
Within
Category

100
0
0
0
0
100

8.0
21.8
56.7
13.5
0
100

4.2
12.7
50.0
27.4
5.7
100


-------
          TABLE D- 161
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 11 05398 & 1106309 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 151 Agency: 143
Monitor Location: Hazelwood Calculated Mass (mg) : 81
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors : 71 Agency : 76
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75p
Totals
TOTALS
Particle
Count


225
0
4
0
0
229

800
275
16
0
0
1091

700
50
0
0
0
750
2070
(All Categories)
Percent By
Number


10.9
0
0.2
0
0
11.1

38.6
13.3
0.8
0
0
52.7

33.8
24.2
0
0
0
36.2
100

Percent By Mass
All
Categories

3.4
0
6.5
0
0
9.9

13.5
37.1
29.2
0
0
79.8

6.6
3.7
0
0
0
10.3
100

Within
Category

34.2
0
65.8
0
0
100

16.9
46.5
36.6
0
0
100

63.6
36.4
0
0
0
100



-------
           TABLE  D-162
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093298 & 1093299 Total Mass of Particulates (mg) :
(confined cover & primary filters) Coors: 289 A&W- 214
Monitor Location: North Braddock Calculated Mass (mg) : 386
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors: 153 Agency: 108
Category

Sphere
5-10u
10-20y
20-50)j
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75u
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75M
>75y
Totals
TOTALS
Particle
Count


550
125
8
0
0
683

1625
400
24
9
1
2059

1975
350
80
11
2
2418
5160
(All Categories)
Percent By
Number


10.6
2.4
0.2
0
0
13.2

31.5
7.8
0.5
0.2
0.02
39.9

38.3
6.8
1.6
0.2
0.04
46.9
100

Percent By Mass
All
Categories

1.7
3.1
2.7
0
0
7.6

5.7
11.3
9.2
17.2
5.2
48.6

3.9
5.5
17.0
11.7
5.7
43.8
100

Within
Category

22.8
41.4
35.8
0
0
100

11.8
23.3
18.9
35.4
10.6
100

8.8
12.6
38.8
26.7
13.1
100



-------
           TABLE D-163
RESULTS OF SEM PARTICLE OOUOTS
Filter Number: 1105300 & 1106301 Total Mass of Particulates (mg) :
(combined cover & primary filters) Coors: 68 Agency: —
Monitor Location: Duquesne II Calculated Mass (mg) : 72
3
Date of Sample: 8/28/76 Air concentration (ug/m ):
Coors : — Agency :
Category
Sphere
5-lOy
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
(All Categoric
Particle
Count
0
0
0
0
0
0
450
50
24
0
0
524
300
250
4
1
0
555
1079
|S)
Percent By
Number
0
0
0
0
0
0
41.7
4.6
2.2
0
0
48.6
27.8
23.2
0.4
0.09
0
51.4
100
Percent By Mass
All
Categories
0
0
0
0
0
0
8.5
7.6
49.3
0
0
65.5
3.2
21.1
4.6
5.7
0
34.5
100
Within
Category
0
0
0
0
0
0
13.0
11.6
75.3
0
0
100
9.2
61.1
13.2
16.5
0
100


-------
           TABLE  D-164




RESULTS OF SEM PARTICLE COUNTS
Filter Number: HQ6302 & 1106303 Total Mass oC Particulates (mg) :
(combined cover & primary filters) Coors: 207 Agency: 271
Monitor Location: Liberty Boro Calculated Mass (mg) : 325
3
Date of Sample: 8/28/76 Air concentration (yg/m ):
Coors: 130 Agency: 136
Category

Sphere
5-lOy
10-20y
20-50y
50-75y
>75jj
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


925
50
0
0
0
975

1700
325
52
1
1
2079

3175
825
72
3
0
4075
7129
(All Categories)
Percent By
Number


13.0
0.7
0
0
0
13.7

23.8
4.6
0.7
0.01
0.01
29.2

44.5
11.6
1.0
0.04
0
57.2
100

Percent By Mass
All
Categories

3.5
1.5
0
0
0
5.0

7.2
10.9
23.7
2.3
6.1
50.2

7.4
15.4
18.2
3.8
0
44.9
100

Within
Category

69.8
30.2
0
0
0
100

14.2
21.8
47.2
4.5
12.2
100

16.5
34.4
40.6
8.5
0
100



-------
           TABLE D- 165
RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106327 & 1106328
(combined cover & primary filters)
Monitor Location: Central Lab
Date of Sample: 9/9/76
(second examination)
Category

Sphere
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50y
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


175
0
0
0
0
175

1775
550
60
2
0
2387

2225
625
156
8
4
3018
5580
(All Categories)
Total Mass of Particulates (mg) :
Coors: 429 Agency: 428
Calculated Mass (mg): 450
Air concentration (yg/m ):
Ccors: 219 Agency: 235
Percent By
Number


3.


1
0
0
0
0
3.

31
9
1
0
1

8
8
1
04
0
42

39
11
2
0
0
54
8

9
.2
8
.1
.07
.1
100


Percent By Mass
All
Categories

0.5
0
0
0
0
0.5

5.4
13.4
19.7
3.3
0
41.7

3.8
8.4
28.5
7.3
9.8
57.8
100

Within
Category

100
0
0
0
0
100

12.9
32.0
47.2
7.9
0
100

6.5
14.6
49.2
12.6
17.0
100



-------
           TABLE D-166



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1106386 & 1106385
(combined cover & primary filters)
Monitor Location: North Braddock
Date of Sample: 9/9/76
(first examination)
Category

Sphere
5-lOp
10-20y
20-50y
50-75y
>75y
Totals
Irregular
5-10y
10-20y
20-50)J
50-75y
>75y
Totals
Agglomerate
5-10y
10-20y
20-50y
50-75y
>75y
Totals
TOTALS
Particle
Count


1075
200
12
0
0
1287

2025
675
80
2
1
2783

2450
1675
220
13
0
4358
8428
(All Categories)
Total Mass of Particulates (mg) :
Coors: 474 Agency: 532
Calculated Mass (mg) : 657
3
Air concentration (ug/m ):
Coors: 248 Agency: 272
Percent By
Number


12.
2.
0


8
4
1
0
0
15

24
8
0
0
0
33

29
19
2
0
3

0
0
9
02
01
0

1
.9
.6
.2
0
51
.7
100


Percent By Mass
All
Categories

2.0
3.0
2.4
0
0
7.3

4.2
11.2
18.0
2.2
3.0
38.7

2.8
15.5
27.5
8.1
0
53.9
100

Within
Category

27.0
40.3
32.7
0
0
100

10.9
29.0
46.5
5.8
7.8
100

5.2
28.7
51.0
15.1
0
100



-------
           TABLE D-167



RESULTS OF SEM PARTICLE COUNTS
Filter Number: 1093294 & 1093295
(combined cover & primary filters)
Monitor Location: Airport
Date of Sample: 9/9/76

Category

Sphere
5-lOu
10-20y
20-50y
50-75p
>75y
Totals
Irregular
5-10y
10-20y
20-50u
50-75y
>75y
Totals
Agglomerate
5-10jj
10-20y
20-50y
50-75y
>75y
Total s
TOTALS
Particle
Count


100
0
0
0
0
100

1125
300
12
1
0
1438

1350
325
20
7
1
1703
3241
(All Categories)
Total Mass of Particulates (mg) :
Coors : 278 Agency : 274
Calculated Mass (mg) : 161
3
Air concentration ( yg/m ) :
Coors: 207 Agency: 147
Percent By
Number


3


1
0
0
0
0
3

34
9
0
0
1

.7
2
.4
03
0
44

41
10
0
0
0
52
.4

.6
.0
.6
.2
.03
.5
100


Percent By Mass
All
Categories

0.8
0
0
0
0
0.8

9.6
20.4
11.0
4.6
0
45.6

6.4
12.3
10.2
17.9
6.9
53.6
100

Within
Category

100
0
0
0
0
100

21.0
44.7
24.2
10.1
0
100

11.9
22.9
19.0
33.4
12.8
100



-------
TABLE D-168 through TABLE D-170 - SUMMARY OF EDAX ELEMENTAL ANALYSIS
                                 D-A6

-------
                           TABLE D- 168
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
    SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
             TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter-
Baden
1093219
0.00
0.00
0.00
1.48
1.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
0.02
0.00
0. 00
0. 00
0.00
0.00
0.00
0.00
Si
Beaver Falls
1093221
0.00
0.00
0.00
1. 75
1.00
0.16
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
SuS
Koppel
1093223
0.00
0.00
0.02
2.13
1.00
0. 14
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
Si, S
Brighton Twp
1093225
0.14
0.00
0.46
6.76
1.00
0.00
0.00
0.00
0.10
0.89
0.00
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca, Al,
Na, K
Midland
1093227
0.25
0.10
0.45
4.04
1.00
0.23
0.03
0.02
0.18
0.54
0.03
0.03
0.01
0.43
0.00
0.00
0.00
0.00
0.00
0.00
0.00
_Si, Ca, Al,
Fe, Na, S,
K, Mg

-------
                    TABLE D- 168  (Continued)

SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
    SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
              TO THE INTEGRAL ENERGY PEAK OF GOLD

Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
Midland
1093228
Cover Filter
0.33
0. 11
0.47
5.23
1.00
0.15
0.07
0.03
0.22
0. 67
0.05
0.04
0.01
0.45
0.01
0.00
0.00
0. 03
0.00
0.00
0.00
Si, Ca, Al,
Fe, Na, K,
S, Mg, Cu

Elco
1093213
0.00
0.00
0.00
1.43
1.00
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
Si


Downtown
1093215
0.00
0.00
0.00
1.64
1.00
0.01
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si


Central Lab
1093241
0.11
0.00
0.37
5.96
1.00
0.22
0. 00
0. 00
0. 11
0.75
0.00
0.00
0.00
0.04
0.00.
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca, Al,
S, Na, K


Hazelwood
1093201
0.00
0.00
0.08
1.50
1.00
0.08
0.00
0.00
0.04
0.22
0.00
0.00
0.00
0.05
0.00
0.00
0.00
0.01
0.00
0.00
0.00
Si, Ca



-------
                      TABLE D-168 (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976  FILTER
    SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
              TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
No. Braddock
1093203
0. 11
0.09
0.24
1. 70
1.00
0.24
0.09
0.08
0. 13
0.31
0,07
0.08
0.06
0. 10-
0.06
0.05
0. 04
0.06
0.04
0.03
0.04
Si, Ca, Al,
S, K, Na,
Fe, Cu, Hg,
Pb, As, Cl,
Cd, Cr, Ti
Duquesne II
1093205
0.00
0.00
0.07
1. 17
1.00
0. 12
0.00
0.00
0,04
0.26
0.00
0.00
0.00
0. 13
0.00
0.00
0.00
0.01
0.00
0.00
0.00
Si, Ca, Fe,
S

Liberty Boro
1093209
0.00
0.00
0. 07
1.61
1.00
0.09
0.00
0.00
0.05
0.28
0.00
0.00
0.00
0. 05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca


Clairton
1093211
0.00
0.00
0.00
0.32
1.00
0.00
0.00
0.00
0.00
0.04
0.00
0.00
0.00
0.19
0.00
0.00
0.00
0.00
o.oo
0.00
0.00
Si, Fe


Airport
1093229
0.24
0.03
0.32
3.56
1.00
0.26
0.06
0.05
0.17
0.51
0.06
0.02
0.01
0.45
0.01
0.00
0.00
0.04
0.00
0.00
0.00
jSi, Ca, Fe,
Al, S, Na,
K, Cu

-------
                      TABLE D-168  (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 16 AUGUST 1976 FILTER
    SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
              TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
Airport
1093230
Cover Filter
0. 14
0.07
0.46
3.59
1.00
0. 15
0.01
0.01
0. 11
0.55
0.04
0.05
0.02
0.27
0.00
0.00
0.00
0.00
0.00
0.00
0. 00
Si, Ca, Al.Fe
S, Na, K
So. Fayette
1093239
0.00
0.00
0. 13
3.79
1.00
0.03
0.00
0. 00
0.00
0.48
0.00
0.00
0. 00
0.00
0.00
0.00
0. 00
0.00
0.00
0.00
0.00
Si, Ca, Al






































































-------
                            TABLE D-169
' SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 28 AUGUST 1976 FILTER
     SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
               TO THE INTEGRAL ENERGY PEAK OF GOLD

Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Filter
Brighton Twp
1093284
0.08
0.00
0.36
5.36
1.00
0.37
0.00
0.00
0.06
0. 58
0.00
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, Ca, S,
Al


Hazelvvood
1106308
0.22
0. 10
0.39
3.58
1.00
0.45
0.02
0.01
0. 15
0.49
0.04
0.02
0.00
0.08
0.00
0. 00
0. 00
0.01
0.00
0.00
0.00
Si, Ca, S,A1,
Na, K, Mg


Hazelwood
1106309
Cover I- liter
0.24
0.10
0.45
4. 71
1.00
0. 15
0.02
0. 02
0. 16
0. 64
0.04
0.01
0.01
0. 12
0.00
0.00
0.00
0.01
0.00
0. 00
0.00
Si, Ca, Al,
Na, K, S, Fe,
Mg

No. Braddock
1093298
0.20
0.06
0.38
3. 32
1.00
0. 54
0.03
0.07
0. 17
0. 77
0.01
0.02
0.03
0. 35
0.02
0.01
0.01
0.01
0.00
0.00
0.00
_Si, Ca, S, Al,
Fe, Na, K


No. Braddock
1093299
Cover Filter
0.18
0.09
0.45
3.83
1.00
0.15
0.03
0.02
0.16
0.66
0.05
0.02
0.01
0.20
0.00
0.00
0.00
0.02
0.00
0.00
0.00
Si, Ca, Al,
Fe, Na, K, S



-------
                       TABLE D-169 (Continued)
SUMRTARY OF EDAX ELEMENTAL ANALYSIS FOR 28 AUGUST 1976 FILTER
     SAMPLES.  ENTRIES ARE RATK )S OF INTEGRAL ENERGY PEAKS
              rI'O THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fa
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Runic
Order
Filter
Duquesne II
1106300
0.27
0.15
0.58
6.35
1.00
0.12
0.10
0.08
0.30
0.87
0.07
0.06
0.05
0.08
0.03
0.02
0.01
0.03
0.01
0.00
0.00
Sij Ca, Al,
K, Na, Mg,
S, Cl, Cd, Ti,
Cu
Duquesne II
1106301
Cover Filter
0.24
0.10
0.48
5. 19
1.00
0.08
0.04
0. 00
0.20
0.60
0.04
0. 03
0.01
0. 14
0.00
0.00
0.00
0.01
0.00
0.00
0.00
Si, Ca, Al,
Na, K, Fe,
Mg
Liberty Boro
1106302
0. 10
0.04
0.44
3.65
1.00
0.45
0.02
0.03
0. 19
0. 53
0.06
0.04
0.03
0. 14
0.01
0.00
0.00
0.03
0.00
0.00
0.00
Si, Ca, S, Al,
K, Fe, Na,
Cu
Liberty Boro
1106303
Cover Filter
0.25
0.06
0.41
4.48
1.00
0.13
0.05
0.03
0. 18
0.59
0.05
0.02
0.02
0.43
0.02
0.00
0.01
0.01
0.00
0.00
0.00
Si, Ca, Fe,
Al, Na, K,
S
So. Fayette
1093278
0.06
0.02
0.37
2.55
1.00
0.43
0.01
0. 00
0. 14
0.34
0.03
0. 01
0.01
0. 19
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Si, S, Al,
Ca, Fe, K

-------
                           TABLE D-170
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 9 SEPTEMBER 1976 FILTER
    SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
             TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Filter
Downtown
1106323
0.04
0.00
0.32
5. 66
1.00
0.00
0.00
0.00
0.02
0.62
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0. 00
Sij Ca, Al
Central Lab
1106327
0. 11
0.08
0.41
3.64
1.00
0.67
0.06
0.09
0.23
0.87
0.10
0.02
0.08
0.35
0. 04
0.03
0.01
0.04
0.02
0.00
0.00
Si, Ca, S,
Al, Fe, K,
Na, Ti, Cd,
Cu
Central Lab
1106328
Cover Filter
0.13
0.08
0.47
4.43
1.00
0.27
0.07
0.05
0.22
1.00
0.07
0. 07
0.07
0.24
0. 04
0.05
0.03
0.02
0.00
0.00
0.00
J3i, Ca, Al,
S, Fe, K,
Na
Airport
1093294
0.16
0.04
0.35
4.36
1.00
0.28
0.00
0.21
0.70
0.06
0.00
0.06
0.05
0. 17
0.01
0.00
0.01
0.05
0.00
0.00
0.00
Si, K, Al,
S, Cd, Fe,
Na, Cu
Airport
1093295
Cover Filter
0.21
0.08
0.44
5.41
1.00
0.16
0.13
0.00
0.26
0.90
0.11
0.06
0.05
0.16
0.04
0.00
0.02
0.02
0.00
0.00
0.00
Si, Ca, Al,
K, Na, S, Fe
Cl, Ti

-------
                      TABLE D-170 (Continued)
SUMMARY OF EDAX ELEMENTAL ANALYSIS FOR 9 SEPTEMBER 1976 FILTER
    SAMPLES.  ENTRIES ARE RATIOS OF INTEGRAL ENERGY  PEAKS
              TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
hnportunt
Elements
In Rank
Order

Filter
So. Fayette
1106310
0. 31
0.44
0.85
2.36
1.00
0.67
0.81
0.64
0.71
0.59
0.49
0.31
0025
0.41
0.23
0. 11
0. 15
0. 19
0.09
0.07
0.09
Si, Al, CL, K,
S, Cd, Ca, Ti
Mg, Fe, Na,
Cr, Mn, Co,
Cu, Zn, Ni,
Hg, Pb, As






























































































-------
TABLE D-171 THROUGH D-216 - PARTICLE ANALYSIS OF SELECTED FILTERS
                                 D-47

-------
                           TABLE  D-171



            PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Baden Date of Sample: 16 August 1976
Filter Number: 1093219 Photomicrograph Stub Number: 45
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Fe, S, Mn
(low level)
Si, S, Ca
(low level)
Si, Ca
(low level)
Fe, Ca, Si
Si, Ca, Al, S
S, Si, Cl, Ca
(low level)
Ca, S
(low level)
Si, Ca, S
(low level)
Si, Ca
(low level)
S, Si, Ca
(low level)
Si, Zn, Ca, S
(low level)
Si, Fe, Ca, Al, S
(low level)
Dimension &
Description
40 microns
irregular
12 microns
irregular
15 microns
irregular
10 microns
irregular
10 microns
irregular
15 microns
irregular
50 microns
irregular
20 microns
irregular
12 microns
irregular
7 microns
irregular
10 microns
irregular
10 microns
irregular
Probable
Identification
organic - coal
organic - coal
organic - coal
organic - coal
organic - coal
organic - coal
organic - rubber
mineral
organic
organic
organic - coal
organic - coal
See Figure D-20

-------
               TABLE  D- 172



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Beaver Falls Date of Sample: 16 August 1977
Filter Number: 1093221 Photomicrograph Stub Number: 47
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca (low level)
Si, S, Ca (low level)
Si, Ca, S, Al (low
level)
S, Si, Ca, (low level)
Si, Al, S, Ca (low
level)
Fe, S, Si, Ca, Cl, K,
Al
Si, S, Ca (low level)
Si, S, Ca Fe
S, Si, Ca (low level)
S, Si, Ca, (low level)
Si, Al, S, Ca
Si, S, Ca, Cl, Fe
Dimension &
Description
55 microns
agglomerate
15 microns
irregular
25 microns
irregular
20 microns
irregular
15 microns
irregular
15 microns
agglomerate
60 microns
irregular
15 microns
agglomerate
12 microns
irregular
12 microns
irregular
15 microns
irregular
20 microns
irregular
Probable
Identification
organic -industrial
particle
organic
organic -industrial
particle
insect part
organic
iron-oxide
organic-coal
industrial particle
sulfate
organic
soil dust
soil dust

-------
                                TABLE D- 173

               PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Koppel * Date of Sample: 16 August 1977
Filter Number: 1093223 Photomicrograph Stub Number: 48
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Al (low level)
S, Ca, Si, Fe
S, Ca
S, Ca, Si, Al, Fe
Si, Al, S, Ca
S, Ca, Si (low level)
Si, Ca, S
S, Si, Ca, K
Si, S, Ca, Cl, Fe
Si, S, Ca
S, Ca, Si, Fe
Si, Ca, S, K, Cl, Al,
Fe
Dimension &
Description
45 microns
irregular
15 microns
irregular
25 microns
agglomerate
40 microns
agglomerate
30 microns
agglomerate
15 microns
irregular
20 microns
irregular
15 microns
irregular
20 microns
agglomerate
30 microns
irregular
15 microns
irregular
8 microns
irregular
Probable
Identification
organic
industrial particle
organic "industrial
particle
industrial particle
industrial particle
industrial particle
organic-coal
industrial particle
industrial particle
organic-coal
industrial particle
mineral
*Note:  Observer noted that 20 meters to the north there was an hibachi grill at the
 same  level as the monitor which could be a source of coal particulates.

-------
               TABLE  D-174



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Brighton Twp Date of Sample: 16 August 1977
Filter Number: 1093225 Photomicrograph Stub Number: 49
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8

9
10
11
12
Elements in Order of
Spectral Height
Si, Ca, Al, K
Si, Ca, Al, Fe, S,
Ti, Cl
Si, S, Al, Cl, Ca, K
Si, Ca, Al, S, K
K, Si, Al, Fe, Ca, S,
Ti
Si, K, Al, S, Cl
Si, Ca, K, Al, S
Si, Al, Cl, Ca, S

Si, Ca, S, Al, Fe
Fe, Si, Ca, Ti, Al, K,
Mn, S, Zn
Si, Fe, Ca, K, S, Al
Si, Ca, Al, Fe, S, K
Dimension &
Description
20 microns
spherical
15 microns
irregular
15 microns
irregular
15 microns
irregular
8 microns
spherical
20 microns
irregular
10 microns
irregular
15 microns
irregular
12 microns
irregular
15 microns
irregular
6 microns
irregular
8 microns
spherical
Probable
Identification
fly ash
mineral
soil dust
industrial particle
industrial particle
industrial particle
soil dust
industrial particle

soil dust
industrial particle
(iron-oxide)
mineral
flyash

-------
                       TABLE D-175
         PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Midland Date of Sample: 16 August 1977
Filter Number: 1093227 Photomicrograph Stub Number: 50
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, AL, K, Fe, Ca, S
Si, Al, Ca, Fe, Ti, Mg
Si, Al, Fe, Ca, K
Si, Fe, Al, S, Ca
Si, Fe, Al
Si, Al, Fe, K, S
Si, Al, Fe, Ca,K, S,
Mg
Si, Fe, Al, S, Ca, K
Si, Al, Ca, Fe, K, S
Si, Fe, S (low level)
Si, Ca, S, Mg, Fe,
Al, K
Ca, Si, Fe, Mg, S,
K, Al, Cl
Dimension &
Description
40 microns
irregular
10 microns
spherical
15 microns
agglomerate
10 microns
irregular
15 microns
irregular
10 microns
spherical
10 microns
spherical
20 microns
irregular
15 microns
irregular
20 microns
spherical
5 microns
agglomerate
7 microns
irregular
Probable
Identification
soil dust
fly ash
industrial particle
soil dust
soil dust
fly ash
fly ash
soil dust
soil dust
organic-coal
industrial particle
industrial particle
See Figure D-21

-------
                TABLE D-176



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Midland (Cover Filter) Date of Sample: 16 August 1977
Filter Number: 1093228 Photomicrograph Stub Number: 50C
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, K, Fe, Ca, Al, S,
Cl, Mg
Ca, Si, Fe. K, S, Al,
Cl, Mg, Ti, Mn, Zn
Si, Al, Fe, K, Ca
Si, Ca, Mg, Al, Fe,
Ti, K, S
Fe, Si, S
Si, Al, Fe, K, Ca,
Ti, S
Si, Fe, Al, Ca, Mg,
K, S
Si, Al, Fe, Ca, K
Si, Al, Fe, Ca, K,
S, Na
Si, S, Fe, Al, Ca
Si, Ca, Al, Fe, S
Si, Fe, Ca, Al
Dimension &
Description
30 x 18 microns
irregular
20 microns
irregular
5 microns
spherical
8 microns
irregular
8 microns
spherical
5 microns
spherical
20 microns
irregular
5 microns
spherical
12 microns
irregular
10 microns
irregular
20 microns
irregular
15 microns
irregular
Probable
Identification
industrial particle
industrial particle
( limestone )
fly ash
industrial particle
flyash - iron
oxide
flyash
soil dust
flyash
mineral
soil dust
soil dust
soil dust

-------
                              TABLE  D-177



              PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Elco Date of Sample: 16 August 1977
Filter Number: 1093213 Photomicrograph Stub Number: 44
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Fe, Ca, Si, Mn, Zn,
Ti
Cl, Si, Ca, S, Ti,
K, Al, Mg
Si, Ca, Cl, S
S, Si, Ca
Si, AI, Fe, Ca, S
Sjj K, Al, Cl, Ca.
Mg, S, Ti, Fe, Mn
Si, S, Ca
Ca, Cl, Si
Ca ( low level)
Si, Al, Fe, Ca, K
organic
Si, Al, S, Fe, Ca
Dimension &
Description
40 microns
irregular
8 microns
agglomerate
25 microns
agglomerate
20 microns
agglomerate
35 microns
agglomerate
8 microns
agglomerate
12 microns
spherical
20 microns
irreg. , square
15 microns
irregular
10 microns
spherical
15 microns
irregular
5 microns
irregular
Probable
Identification
industrial particle
industrial particle
industrial particle
sulfate (?)
industrial particle
industrial particle
organic
CaCl2
organic
industrial particle
organic
industrial particle
*  See Figure  D-22

-------
               TABLE  D-178



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Downtown Date of Sample: 16 August 1976
Filter Number: 1093215 Photomicrograph Stub Number: 45
Particle Number-
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca, Al
Si, Ca, S, Al
Si, Ca, S, Al
S, Ca, Si
S, K, Ca, Si
Si, Ca
Si, Ca
Si, Ca (low level)
S, Si, Ca, Fe
Si, Ca, S
Si, S, Ca, Fe
Si, Cl, Ca, S, Al, Fe
Dimension &
Description
30 microns
agglomerate
35 microns
agglomerate
22 microns
agglomerate
15 microns
agglomerate
30 microns
agglomerate
15 microns
irregular
20 microns
irregular
8 microns
spherical
12 microns
agglomerate
20 microns
irregular
25 microns
agglomerate
25 microns
agglomerate
Probable
Identification
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
organic
soil dust
fly ash
industrial particle
organic-coal
industrial particle
industrial particle

-------
                              TABLE D-179



              PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Central Lab Date of Sample: 16 August 1977
Filter Number: 1093241 Photomicrograph Stub Number: 21
Particle Number
on Photomicrograph5'
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca (low level)
Si, Al, Ti, Ca, Fe,
K
Si, Ca, Mg, Al, S, K,
Cl, Mn, Ti, Zn
Si, Al, S, Ca, le, K
Si, Al, S, Ca, Cl, Fe
Si, Al, K, Ca, TI,
Fe, Cl, S, Mn, Zn
Si, Ca, S, Al, K
Si, Ca, S, K
Si, Fe, Ca, K, Al,
Ti, Mn
Si, Ca, Fe, Al, S
Sij Ca, S, Al
Sij Al, Ca, Fe, S, K,
Ti
Dimension &
Description
15 microns
irregular
7 microns
agglomerate
5 microns
irregular
15 microns
agglomerate
7 microns
irregular
10 microns
irregular
20 microns
irregular
10 microns
agglomerate
25 microns
irregular
20 microns
agglomerate
15 microns
agglomerate
10 microns
agglomerate
Probable
Identification
organic-coal
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
mineral (indus-
trial origin)
industrial particle
soil dust
industrial particle
industrial particle
industrial particle
*  See Figure D~23a  and  2J-b

-------
                           TABLE  D-180



           PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood Date of Sample: 16 August 1977
Filter Number: 1093201 Photomicrograph Stub Number: 39
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
organic
Si, Ca, S, Al
Si, Ca, Fe, S
organic
Si (low level)
Si, S
organic
Si, Fe, Al
Si (low level)
Ca, Si
Si, Al, Mg, Fe
Al, Si
Dimension &
Description
55 microns
irregular
60 microns
agglomerate
35 microns
agglomerate
15 microns
agglomerate
20 microns
agglomerate
25 microns
irregular
50 microns
irregular
25 microns
agglomerate
15 microns
irregular
35 microns
irregular
25 microns
irregular
30 microns
irregular
Probable
Identification
organic-coal
industrial particle
industrial particle
organic - rubber
organic
industrial particle
organic - rubber
industrial particle
soil dust
soil dust
industrial particle
soil dust
See Figure  D-24a and  24-b

-------
               TABLE D-181



PAimCLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock Date of Sample: 16 August 1977
Filter Number: 1093203 Photomicrograph Stub Number: 40
Particle Number-
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Al, Ca
low level peaks
Si (low level)
Si, Ca, (low level)
low level peaks
Si, Ca
low level peaks
Ca, Si, S, Fe
Si, S
Cl
Si, Ca, S
Ca
Dimension &
Description
35 microns
irregular
25 microns
irregular
20 microns
agglomerate
25 microns
agglomerate
20 microns
agglomerate
30 microns
irregular
25 microns
spherical
15 microns
irregular
15 microns
agglomerate
20 microns
agglomerate
25 microns
irregular
40 microns
irregular
Probable
Identification
soil dust
organic-coal
industrial particle
industrial particle
organic -
industrial particle
industrial particle
organic
soil dust
soil dust
industrial particle
soil dust
industrial particle

-------
               TABLE D-182



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Duquesne II Date of Sample: 16 August 1977
Filter Number: 1093205 Photomicrograph Stub Number: 41
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Si, S, Al
Ca, Fe, S, Mn, Cl
S, Si, Ca
.Si, Mg, Ca
Ca, Fe, S, Si
Si, Ca, S (low level)
Si, Ca
Si, Ca, S
Ca, Fe, Si
Si, S, Ca (low level)
Si, Ca, Fe, S, Al, K
Si^ Al, Ca
Dimension &
Description
35 microns
agglomerate
20 microns
agglomerate
25 microns
agglomerate
15 microns
irregular
20 microns
irregular
10 microns
spherical
25 microns
agglomerate
6 microns
spherical
25 microns
agglomerate
15 microns
irregular
12 microns
irregular
20 microns
irregular
Probable
Identification
industrial particle
industrial particle
industrial particle
soil dust
industrial particle
fly ash
industrial particle
fly ash
industrial particle
organic-coal
industrial particle
soil dust

-------
               TABLE  D-183



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro Date of Sample: 16 August 1977
Filter Number: 1093209 Photomicrograph Stub Number: 42
Particle Number-
on Photomicrograph
1

2

3

4

5

6

7

8

9

10

11

12

Elements in Order of
Spectral Height
Si, Mg, Ca

Si, Ca

Si, Ca

Ca, S (low level)

Si, Ca

Si, Ca

Si, Al, Mg, Ca

Si, Ca

Fe, Si, Ca, Mn

Si, Ca

Si, Al, Ti, Ca

Si, Ca

Dimension &
Description
55 microns
irregular
18 microns
agglomerate
8 microns
irregular
10 microns
agglomerate
15 microns
irregular
20 microns
irregular
50 microns
irregular
35 microns
irregular
10 microns
agglomerate
20 microns
spherical
30 microns
irregular
15 microns
agglomerate
Probable
Identification
soil dust

industrial particle

industrial particle

coal or coke

soil dust

industrial particle

soil dust

coal or coke

industrial particle
(iron oxide)
flyash

industrial particle

industrial particle


-------
               TABLE D-184



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Clairton Date of Sample: 16 August 1976
Filter Number: 1093211 Photomicrograph Stub Number: 43
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Fe, Ca, S (low
level)
Si, Fe, Ca (low
level)
Si, Ca, Fe
Fe, Si, Ca, K, Al,
Pb
Si, Fe, Ca (low
level)
Si, Fe, Ca (low
level)
Si, Mg, Ca (low
level)
S, Si, Cl, Ca, Al,
Na, K, Zn
Al, Si, Ca
Al, Si, S, Ca (low
level)
Al, Ca (low level)
Si
Dimension &
Description
15 microns
irregular (long)
12 microns
irregular
20 microns
irregular
20 microns
irregular
25 microns
agglomerate
20 microns
irregular
15 microns
irregular
15 microns
irregular
20 microns
irregular (long)
15 microns
irregular
25 microns
irregular
8 microns
irregular
Probable
Identification
organic
organic-coal
mineral
iron oxide
industrial particle
organic-coal
organic-coal
industrial particle
(sulfate?)
industrial particle
organic-coal
organic-coal
organic-coal

-------
                                TABLE D-1S5

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:   Airport
   Filter Number:  1093229
                   Date of Sample:   16 August 1976
                   Photomicrograph Stub Number:   51
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension  &
Description
    Probable
  Identification
         10
         11
         12
                      Ca,  Si, Fe, S, A], K,
                      Cl,  Zn, Mn, Ti,  Mg

                      Si, Al, K, Fe, Mg,
                      Ca,  Ti, Cl, S, Mn,Zn

                      Si, Al, Fe, K, S, Ca
                       Si, Al,  Ca, S,  Fe,
                       K,  Mg

                       Si, Ca, S, Fe, Al
                       Si, Ca, Fe, K,  S, Al,
                       Ti, Mn, Cl,  Zn

                       Ca, S,  Si, Fe
 Si, S, Mn, Ca,  Cl,
 Fe,  Al,  K,  Zn

 Si, Fe, Al, Ca, S, K,
 Cl

 Si, Al, Fe, K,  Ca,
 S

 Si, Al, Fe, S, Ca, K
 Si, S, Fe, Ca, Al,
 Zn,  K
 25 microns
 irregular

 10 microns
 spherical

 15 microns
 irregular

 15 microns
 agglomerate

 6 microns
 irregular

 50 microns
 irregular

 15 microns
 irregular

 5 microns
 irregular

 6 microns
 irregular

 30 microns
 irregular

 10 microns
 irregular

 15 microns
 irregular
industrial particle


 flyash


industrial particle


industrial particle


industrial particle


industrial particle


industrial particle


industrial particle


industrial particle


 soil dust


 soil dust


industrial particle

-------
                TABLE D-186



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport (Cover Filter) Date of Sample: 16 August 1976
Filter Number: 1093230 Photomicrograph Stub Number: 51C
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order oi'
Spectral Height
Si, Al, Ca, S, Fe,
Mgj K, Cd, Cl, Ti,
Co, Na, Cr, Zn, Cu
Si, Ca, S, Fe, Al
Ca,_S, Si, Fe, Al
Ca, S, Si, Al, Fe
Si, S, Fe
Si, Al, K, Fe, Ca
Si, S, Fe, Ca, Al
Si, Al, K, Ca, Fe, S,
Mg
Si, Fe, Al, S, Ca, K
Si, Ca, AJ., _S, Fe,
Mg, Cl, Ti , Mn
Si, Ca, Al, Fe, S,
K, Na
Si, Al, Ca, K, Fe
Dimension &
Description
30 microns
irregular
20 microns
agglomerate
30 microns
agglomerate
20 microns
spherical
20 microns
irregular
40 microns
agglomerate
25 microns
agglomerate
10 microns
irregular
25 microns
agglomerate
25 microns
agglomerate
15 microns
irregular
25 microns
irregular
Probable
Identification
industrial particle
industrial partid e
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
soil dust
industrial particle
industrial particle
soil dust
industrial particle

-------
              TABLE D-187



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: So. Fayette Date of Sample: 16 August 1976
Filter Number: 1093239 Photomicrograph Stub Number: 52
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Ca, Al, K, S
Si, Ca, K
Si, Al, K
Si, Ca, Al, S, Fe, K
Si, K, S, Ca
Ca, Si, Al, K
Si, Al, K, Ca
Si, Ca, S
Si, S
Si, Al, Ca, S, K, Fe
Si, Ca, S, K
Si, Ca, Al, S
Dimension &
Description
20 microns
agglomerate
15 microns
spherical
8 microns
spherical
10 microns
irregular
15 microns
irregular
20 microns
agglomerate
10 microns
irregular
12 microns
agglomerate
12 microns
irregular
20 microns
agglomerate
10 microns
agglomerate
12 microns
agglomerate
Probable
Identification
industrial particle
fly ash
flyash
soil dust
industrial particle
industrial particle
soil dust
industrial particle
coal or coke
industrial particle
industrial particle
industrial particle

-------
                                TABLE D- 188

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:       Koppel
   Filter Number:    1093286
                   Date of Sample:   28 August  1976
                   Photomicrograph Stub Number:   19
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                      S,  K
                      S,  Si,  Ca, Al, Fe
                      Si
                      S,  Si,  Ca, Al, Fe
                       20 microns
                       irregular
                       35 microns
                       agglomerate
                       12 microns
                       irregular
                       25 microns
                       agglomerate
              industrial particle
              industrial particle
                soil dust
              industrial particle

-------
                                TABLE  D- 189

               PARTICLE ANALYSIS OF  SELECTED FILTERS
   Monitor Site:   Brighton Twp
   Filter Number:    1093284
                    Date of Sample:  28 August 1976
                    Photomicrograph Stub Number: 16
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
     Probable
  Identification
         10
         11
                      Si, Al,  Ca, Fe, K,
                      Ti, S, Mn,  Zn, Cl

                      SL Ca, Mg
                       S, _Zn, Si, K, Fe, Ca,
                       Al, Ti, Mn

                       Si, Al,  Fe, S, Ca, K
                       S, Si, Zn
                       Si, S, Ca, Al, K, Ti,
                       Fe,  Mg

                       Si, Ca, S, K, Al, Ti,
                       Cl,  Fe,  Mg, Mn, Zn

                       Si, Mg,  S,  Ca
 Si, Al, Mg,  Ca, S,
 K, Fe, Mn,  Cl,  Ti,
 Zn

 Si, S, Ca, Al
 Si, Al, K, Fe,  Ti,
 Ca, S
 12 microns
 irregular

 30 microns
 irregular

 15 microns
 agglomerate

 20 microns
 irregular

 20 microns
 irregular

 20 microns
 agglomerate

 10 microns
 agglomerate

 10 microns
 spherical

 45 microns
 irregular
  10 microns
  irregular

  10 microns
  irregular
                                      industrial particle
                                        soil dust
                                      industrial particle
                                       (sulfate)

                                      industrial particle
 industrial particle
  (sulfate)

industrial particle


industrial particle


  flyash


 industrial particle



 industrial particle


  soil dust

-------
               TABLE D-190



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Midland Date of Sample: 28 August 1976
Filter Number: 1093282 Photomicrograph Stub Number: 12
Particle Number-
on Photomicrograph
1

2

3

4

5



Elements in Order of
Spectral Height
Si, Fe, Al, S, K, Ca ,
Na
Si, Al, Fe, Ca, Na

Fe, Si, S, Al, Ni,
Cr, Na, Cl, K, Ca
S, Ca, Si, Fe, Al ,
Mg
Fe (very large Fe
peak)


Dimension &
Description
50 microns
agglomerate
25 microns
agglomerate
25 microns
irregular
30 microns
agglomerate
15 microns
spherical


Probable
Identification
industrial particle

industrial particle

industrial particle
(iron oxide)
industrial particle
(sulfate)
flyash
(iron oxide)
steel-making
process

-------
                               TABLE D-191

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:   Elco
   Filter Number:  1106306
                   Date of Sample:  28 August  1976
                   Photomicrograph Stub Number:  18
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                     Si, Fe, Al
                     Si, Fe
                     Si, Al, Fe, Ca
                     Si, Ti, Fe
                      30 microns
                      fused irreg-
                       ular
                      15 microns
                      irregular
                      20x6i> microns
                      irregular
                      30 microns
                      agglomerate
               soil dust
               soil dust
               soil dust
              industrial particle

-------
                TABLE D- 192



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood Date of Sample: 28 August 1976
Filter Number: 1106308 Photomicrograph Stub Number: 58
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ti, Al, Si, S, Ca
Si, Ca, Al, Na, K,
Cl, Mg, S, Fe
Si, Al, K, Fe, S
Si, S, Ca, Al
Si, Al, S, Cl, K, Ca,
Mg, Na, Ti, Fe, Mn
Si, Ca, Al, S, Mg,
Fe
S, Ca, Si, Al, K, Fe
Si, Al, K, Fe, S, Ca,
Mg
Ca, Si, S, Al, K, Cd
Fe, S, Si, Ca
Si, S, Al
Si, Ca, Al, S, Fe, K
Dimension &
Description
22 microns
spherical
12 microns
irregular
40 microns
irregular
20 microns
irregular
20 microns
irregular
30 microns
irregular
10 microns
irregular
15 microns
irregular
15 microns
irregular
20 microns
irregular
25 microns
irregular
20 microns
irregular
Probable
Identification
flyash (titanium
oxide)
mineral (salt)
industrial particle
soil dust
mineral (salt)
industrial particle
industrial particle
soil dust
industrial particle
iron oxide
coal or coke
industrial particle

-------
                TABLE  D-193



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Hazelwood (Cover Filter) Date of Sample: 28 August 1976
Filter Number: 1106309 Photomicrograph Stub Number: 58C
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Si, S, Al, Fe, K
Si, Ca, S, Al, Fe, K
K, Ca, Si, S, Al
Si, Al, Ca, Na, K,
Fe, S, Mg
Si, Ca, S (low peaks)
Al, Fe, Si, Ca, Zn
Si, Al, K, Fe, Ca,
S, Mg, Na
Si, S
Si, Al, Ca, K
Sij Ca, Al, K, S, Fe,
Na, Cl, Mg
Ca, Mg, Si, S, Fe,
Al, K, Cd
Si, S, Ca
Dimension &
Description
85x30 microns
irregular
10 microns
irregular
15 microns
irregular
22 microns
agglomerate
20 microns
irregular
30 microns
agglomerate
15 microns
irregular
15 microns
agglomerate
15 microns
irregular
35 microns
irregular
15 microns
agglomerate
30 microns
agglomerate
Probable
Identification
industrial particle
soil particle
industrial particle
industrial particle
organic
(biological)
industrial particle
soil dust
coal or coke
soil dust
soil dust
industrial particle
coal or coke

-------
                              TABLE D- 194



              PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock Date of Sample: 28 August 1976
Filter Number: 1093298 Photomicrograph Stub Number: 57
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, Al, _K, Fe, Ca,
Ti, S
Si, Ca, Fe, Cl, S
Si, Al, Fe, K, Ca, Ti
Si, K, S, Ca, Al,
Fe, Cl
Si, Al, Fe, S, K
.Si, Ca, Al, Fe, S,
Mg, K, Cl
Si, Al, Ca, K, Fe,
S
Si, Ca, S, Fe, Al
.Si, Al, Fe, K, Ca,
Ti, S
Si, Al, Fe, S, Ca, K
Si, Ca, S, Al, Fe, K
Si, Ca, S, Fe, Al
( low level)
Dimension &
Description
10 microns
irregular
15 microns
irregular
25 microns
irregular
12 microns
spherical
30 microns
agglomerate
35 microns
irregular
10 microns
irregular
15 microns
spherical
5 microns
spherical
12 microns
irregular
30 microns
agglomerate
55 microns
irregular
Probable
Identification
industrial particle
industrial particle
industrial particle
fly ash
industrial particle
soil dust
industrial particle
flyash
fly ash
industrial particle
industrial particle
organic - rubber
*  See Figure D-25

-------
                              TABLE D-195



              PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock (Cover Filter) Date ctf Sample: 28 Aug 1976
Filter Number: 1093299 Photomicrograph Stub Number: 57C
Particle Number
on Photomicrograph*
1
2
3
4
5
G
7
8
9
10
11
12
13
Elements in Order of
Spectral Height ^
JTe, S, Ca
Ca, Si, Fe, S, Al
Cl
Ca, _§, Si, Al
Ca, S, Si, Al
Si, Al, Ca, S, Fe, K,
Mg
Si, Ca, Ti, Al, K
Mn, Fe, S, Cl, Zn
Sij Al, K, Fe, Ca
Si, Fe, Ca, Al, K,
S, Ti
S (low level)
S, Si, Al, Fe, Ca
(low level)
Ca, S, Si, Fe, Al
Sij Al, Fe, S, Ca,
K
organic
Dimension &
Description
20 microns
spherical
20 microns
irregular
15 microns
irregular
50 microns
agglomerate
30 microns
irregular
15 microns
spherical
10 microns
irregular
20 microns
agglomerate
45 microns
irregular
20 microns
agglomerate
30 microns
agglomerate
40 microns
agglomerate
15 microns
spherical
Probable
Identification
flyash (iron
oxide)
soil dust -
limestone
industrial particle
industrial particle
flyash
flyash
flyash
industrial particle
organic - rubber
industrial particle
industrial particle
industrial particle
pollen
*  See Figure  0-26

-------
                                TABLE D-196

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:  Duquesne II
   Filter Number:  1106300
                   Date of Sample: 28 August 1976
                   Photomicrograph Stub Number:  59
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height]
Dimension  &
Description
  Probable
Identification
                       ij  Ca,  Al, K,  Mg, S
                      Si,  Ca,  Al, K
                      S,  Si, Al
                      Ca, S, Si, Fe,  Al, K
                      Si,  Cl, K, S
                      (low level)

                      Si,  S, Al
                      Si,  Ca,  Al, K,  S
                        60 microns
                      spherical with
                      elongated end

                        20 microns
                        irregular

                        15 microns
                        irregular

                        25 microns
                        irregular

                        50 microns
                        irregular

                        35 microns
                        agglomerate

                        25 microns
                        irregular
               industrial particle
                soil dust
                coal or coke
               industrial particle
                coal or coke
               industrial particle
                 ( coke)

               industrial particle

-------
                                TABLE D-197

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site: Duquesne II (Cover Filter)  Date of Sample:  28 Aug 1976
   Filter Number:   1106301               Photomicrograph Stub Number: 59C
  Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height]
Dimension £
Description
  Probable
Identification
                      Si, Fe, Al, S, Ca



                      Si, Al,  Ca, Fe


                      Si, Ca, Al
                      Sij Ca,  Al, K,  Fe,
                      Mg, Ti, S, Cl,  Mn,
                      Zn

                      Si, Al,  Cl, Ca, K
                      Si,  Ca, Al, Mg, S,
                      Fe, K, Cl
                        60 microns
                        irregular
                      (broken sphere)

                        15 microns
                        irregular

                        5 microns
                        spherical

                        25 microns
                        irregular
                        20 microns
                        irregular

                        6 microns
                        irregular
               industrial particle



                soil dust


                fly ash


               industrial particle



                mineral


               industrial particle

-------
                               TABLE  D-198



               PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro Date of Sample: 28 August 1976
Filter Number: 1106302 Photomicrograph Stub Number: 60
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
SL S, Ca, Al, Fe
Si, S, Fe, Ca
Si, S (low level)
Si, Al, Ca, S
Si, Al, K, Fe, Ca,
S, Ti
Si, S, Al
Si, S, Al
Si, S, Al, K, Fe, Ca
Sij S, Al, Ca
Si_, S, Al, K
SL Fe, S, Ca, Al
Si, Al, S
Dimension &
Description
20 microns
agglomerate
25 microns
agglomerate
30 microns
irregular
15 microns
spherical
15 microns
spherical
20 microns
agglomerate
15 microns
irregular
25 microns
agglomerate
25 microns
agglomerate
20 microns
agglomerate
15 microns
irregular
30 microns
agglomerate
Probable
Identification
industrial particle
industrial particle
organic-coal
fly ash
fly ash
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
industrial particle
*  See Figure  D-27

-------
                 TABLE D-198 (Continued)




          PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro (continued) Date of Sample: 28 August 1976
Filter Number: 1106302 Photomicrograph Stub Number: 60
Particle Number
on Photomicrograph*
13

14

15

16

17

18

19

20

Elements in Order of
Spectral Height '
Si, AL, Ca, K, Fe,
S
Sij S, Al, K, Ca, Fe

Si, Al, Ca, K, Fe,
S, Ti
Si, Al, S, Fe, K

Si, S (low level)

Si, Al, K, Fe, Ca,
S
S, Si, Al, Ca, Fe,
(low level)
Sij S, Al, Fe, K, Ca

Dimension &
Description
35 microns
agglomerate
10 microns
agglomerate
10 microns
irregular
10 microns
irregular
20 microns
irregular
5 microns
agglomerate
15 microns
irregular
7 microns
agglomerate
Probable
Identification
industrial particle

industrial particle

industrial particle

industrial particle

organic - coal

industrial particle

organic

industrial particle

See  Figure D-27

-------
                               TABLE  D-199




               PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro (Cover Date of Sample: 28 August 1976
Filter Number: 1106303 Filter) Photomicrograph Stub Number: 60C
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Fe, Si, S (low level)
Si, Fe, S, Al
Si, Fe, Al, Ca, S,
K, Cl, Na
Si, Ca, Fe, Cl, Ti,
S
Si, Al, Fe, S, Ca
Si, Al, Ca, Fe, K,
Mg, S
Si, Fe, Ca, Al, S
Si, Fe, Ca, Al, S
Si, S, Ca, Fe, Al, K
Cl, Si, Na, Fe, S,
Al, Ca, K
Si, S, Al, Fe, Ca
Si, Al, Fe, Ca, K,
Ti, S, Mn, Mg, Cl
Dimension &
Description
50 microns
irregular
30 microns
agglomerate
20 microns
irregular
15 microns
irregular
15 microns
irregular
10 microns
spherical
40 microns
irregular
60 microns
irregular
15 microns
irregular
20 microns
irregular
(square)
20 microns
agglomerate
10 microns
agglomerate
Probable
Identification
organic-coal
industrial particle
soil dust
industrial particle
industrial particle
fly ash
probable organic
insect part
probable organic
insect part
mineral
salt particle
industrial particle
industrial particle
*  See Figure  D-28a  and  28b

-------
                    TABLE  D-199 (Continued)




              PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Liberty Boro (Cover Date of Sample: 28 August 1976
Filter Number: 1106303 Filter) Photomicrograph Stub Number: 60C
(Continued)
Particle Number
on Photomicrograph*
13

14

15

16

17

18

19

20

Elements in Order of
Spectral Height
Si, Fe, Ca, K, Al,
S, Ti, Mn
Si, Al, S

Si, Ca, Fe, S, Al,
Na
Sij Al, Fe, S, Ca,
K
Si, Al, Fe, S, K,
Ti
Sij Al, Fe, Ca,
K, S
Si, Fe, Al, S, Ca

Sij Fe, S, Ca, K, Al

[Dimension &
Description
10 microns
irregular
25 microns
irregular
25 microns
agglomerate
30 microns
irregular
20 microns
irregular
10 microns
irregular
15 microns
agglomerate
10 microns
agglomerate
Probable
Identification
industrial particle

soil dust

industrial particle

industrial particle

soil dust

soil dust

industrial particle

industrial particle

*  See Figure D-28a and 28b

-------
               TABLE D-200



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport Date of Sample: 28 August 1976
Filter Number: 1093280 Photomicrograph Stub Number: 10
Particle Number
on Photomicrograph
1

2

3

4

Elements in Order of
Spectral Height
Si, Ca, Fe, Al , Mg

Si, Fe, Al, Cl, Mg,
Na, Ca, K
Si, S, Ca, Al, Fe,
Cu
Si, Fe, Al, Ca, Mg,
(low level)
Dimension &
Description
25 microns
agglomerate
20 microns
irregular
25 microns
agglomerate
30 microns
irregular
Probable
Identification
industrial particle

mineral

industrial particle

industrial particle


-------
               TABLE  D- 201



PARTICLE ANALYSTS OF SELECTED FILTERS
Monitor Site: South Fayette Date of Sample: 28 August 1976
Filter Number: 1093278 Photomicrograph Stub Number: 14
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Si, S, Ca, Fe, Al
Si, S, Fe, Ca
_Si, Al, Fe, K, S
Si, Al, Fe, K
Si, S, Al, Fe
Si, Al, K, Fe, Ca,
Ti, S
S, Si, Ca
Si, Al, Fe, S, K
S, Si, Al, Fe, K
Si, Fe, Al, S, Ca
Si, Al, K, Fe, S,
Ca
Si, Al, S, K, Fe
Dimension &
Description
65 microns
irregular
30 microns
irregular
8 microns
spherical
5 microns
spherical
16 microns
irregular
10 microns
irregular
20 microns
agglomerate
6 microns
spherical
10 microns
irregular
25 microns
irregular
3 microns
agglomerate
12 microns
irregular
Probable
Identification
soil dust
soil dust
f lyash
f lyash
industrial particle
industrial particle
industrial particle
f lyash
industrial particle
soil dust
industrial particle
soil dust

-------
               TABLE  D-202



PARTICLE ANALYSES OF SELECTED FILTERS
Monitor Site: Midland Date of Sample: 3 September 1976
Filter Number: 1106351 Photomicrograph Stub Number: i
Particle Number
on Photomicrograph
1
2
Elements in Order of
Spectral Height
Si, Ca, S
S, Si, Ca, Fe, K
Dimension &
Description
35x15 microns
irregular
20 microns
irregular
Probable
Identification
soil dust
industrial particle

-------
                                TABLE D-203

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:     Central Lab
   Filter Number:  1106333
                   Date of Sample:   3 September 1976
                   Photomicrograph Stub Number:  5
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                      S, Si, Fe,  Ca
                      Si
                      Ca,  Si,  S,  Fe
                      Fe
                      Si,  Fe,  S,  Mn
                      35 microns
                      agglomerate
                       30 microns
                       spherical
                       45 microns
                       agglomerate
                      55  microns
                      irregular
                      45x15  microns
                      irregular
              industrial particle
              industrial particle
              industrial particle
                 (limestone)
                iron  oxide
                soil  dust

-------
                                TABLE D- 204

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:       Hazelwood
   Filter Number:     1106325
                   Date of Sample:  3 September  1976
                   Photomicrograph Stub Number:   17
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                      S,  Si,  Ca,  Fe
                      Fe,  Ca,  S,  Si
                      Si,  S,  Fe,  Al
                      Si,  Al,  S,  K, Fe
                       18 microns
                       spherical
                       20 microns
                       irregular
                       20 microns
                       agglomerate
                       30 microns
                       irregular
              industrial particle
                iron oxide
              industrial particle
                soil dust

-------
                TABLE  D-205



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: No. Braddock Date of Sample: 3 September 1977
Filter Number: 1106315 Photomicrograph Stub Number: 15
Particle Number
on Photomicrograph
1


2

3

4

Elements in Order of
Spectral Height
Fe, Si, Al


Si, Fe, Ca, S, K, Al

Ca, Si, Fe

Ca, Si, Fe, Al , Mg

Dimension &
Description
30 microns
fused irreg-
ular
40 microns
agglomerate
20 microns
spherical
20 microns
agglomerate
Probable
Identification
industrial particle


industrial particle

industrial particle
(limestone)
industrial particle


-------
                               TABLE D-206

               PARTICLE ANALYSTS OF SELECTED FILTERS
   Monitor Site:      Duquesne  II
   Filter Number:    1106321
                   Date of Sample:  3 September 1976
                   Photomicrograph Stub Number:   ,13
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                      Si,  S,  Ca,  K,  Fe
                      Si,  S,  Ca,  K
                      Zn,  S,  Na
                     Mn,  S,  Si,  Al,  Ca,
                     Fe

                     Fe,  S,  Si,  Ca,  Al
                        25  microns
                        spherical

                        30  microns
                        irregular

                        20  microns
                        agglomerate

                        30  microns
                        agglomerate

                        15  microns
                        irregular
                flyash


                soil dust


              industrial particle


              industrial partical


                iron oxide

-------
                               TABLE D- 207

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:      Liberty Boro
   Filter Number:    1106329
                   Date of Sample:  3 September 1976
                   Photomicrograph Stub Number:   9
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                     Cl,  S,  Si,  K,  Ca,  Al
                     Si
                     Si,  S,  Ca,  Mg
                     Si, Al,  S,  Fe,  Ca
                      S,  Si,  Al,  Fe
                       40  microns
                       agglomerate
                       40  microns
                       Irregular
                       25  microns
                       irregular
                       20  microns
                       agglomerate
                      45 x20 microns
                       irregular
              industrial particle
                soil dust
                soil dust
              industrial particle
               industrial particle

-------
                                TABLE  D-208

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:   Clairton
   Filter Number:  1106331
                   Date of Sample:  3  September 1976
                   Photomicrograph Stub Number: H
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                      Si, Ca, Fe, Mg,  Na
                      S, Ca, Si, Fe,  Al
                      S_, S_i, Fe, Al,  Ca,
                      K, Mg


                      Si, Fe, K, Al,  Cl,
                      Ca, Mg, Na
                      20 microns
                      irregular

                      20 microns
                      agglomerate

                      40 microns
                      agglomerate

                      10 microns
                      spherical
              industrial particle
              industrial particle
               (sulfate)

              industrial particle
               (sulfate)

               flyash

-------
               TABLE D-209



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: South Fayette Date of Sample: 3 September 1976
Filter Number: 1106337 Photomicrograph Stub Number: 7
Particle Number
on Photomicrograph
1
2
3
4
5

6
Elements in Order of
Spectral Height
Si, S
Si, S, Ca, Fe
Si, Ca, S
Si, Al, S, K, Fe
Fe

S
Dimension &
Description
45 microns
agglomerate
25 microns
spherical
50 microns
irregular
8 microns
spherical
45 microns
irregular
40 microns
irregular
Probable
Identification
industrial particle
f lyash
soil dust
f lyash
iron oxide

industrial particle
(sulf ate )

-------
                                TABLE  D-210

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:      Brighton Township    Date of Sample: 9 September  1976
   Filter Number:   1110928              Photomicrograph Stub Number:  23
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
  Probable
Identification
                     S, Ca,  Si,  Zn,  Fe
                     S, Zn,  Si
                     S, Si,  Ca,  Zn,  Fe
                     Si, K,  Fe
                     Fe,  S,  Si
                      40 microns
                      agglomerate
                      30 microns
                      irregular
                       25 microns
                       agglomerate
                       20 microns
                       agglomerate
                       10 microns
                       spherical
              industrial particle
              industrial particle
              industrial particle
              industrial particle
               flyash
               (iron oxide)

-------
               TABLE  D-211



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Downtown Date of Sample: 9 September 1976
Filter Number: 1106323 Photomicrograph Stub Number: 55
Particle Number
on Photomicrograph
1
2
Elements in Order of
Spectral Height '
low level peaks
Si, Al, Ca, K, Fe,
M£, _S, Cl, Ti, Mn,
Zn
Dimension &
Description
20 microns
spherical
30 microns
agglomerate
Probable
Identification
organic - flyash
industrial particle

-------
                                TABLE  D-212

               PARTICLE ANALYSIS OF SELECTED FILTERS
   Monitor Site:    Central Lab
   Filter Number:  1106327
                   Date of Sample:   9 September  1976
                   Photomicrograph Stub Number:   55
 Particle Number
on Photomicrograph
Elements in Order of
   Spectral Height
Dimension &
Description
    Probable
  Identification
        10
        11
        12
                      Si,  S,  Al,  Fe, Ca, K
                      Si,  Fe,  TL, Ca_, _S,
                      Al,  K,  Mn, Zn, Mg,
                      Cl

                      Ca,  Si,  Fe, S, Al, K
                      Si,  Ca,  S, Al, Fe, K
                      Si,  Ca,  S, Al, Fe,
                      K,  Ti,  Cl

                      Si,  S,  Ca, Al, Fe, K
                      Si.,  Al, K, Ca, S, Fe
                      Cl

                      Si,  S,  Ca, Al
Si, S, Ca,  Fe,  Al,
K

Si., Al, Fe,  Ti,  K,
S

Si., Al, K,  S,  Fe,
Ca, Ti

Si, S, Al,  Cl,  Ca,
Fe, K (low  level)
35 microns
irregular

25 microns
irregular


25 microns
agglomerate

20 microns
agglomerate

20 microns
agglomerate

40 microns
agglomerate

20 microns
irregular

40 microns
agglomerate

30 microns
agglomerate

60x25 microns
agglomerate

45 microns
agglomerate

22 microns
irregular
                                     industrial particle
                                     industrial particle
                                     industrial particle
                                        (limestone)

                                     industrial particle
industrial particle


industrial particle


industrial particle


industrial particle


industrial particle


industrial particle


industrial particle


 organic - coal

-------
               TABLE D-213



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: ^ntralT,Lft> , Date of Sample: 9 September 1976
(Cover Filter)
Filter Number: 1106328 Photomicrograph Stub Number: 5^^
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
Ca, Si, S, Fe, K,
Al, Cl
Si, Al, Fe, K, Ca,
S
Si, Al, Ca, K, S,
Fe, Mg
Si, Ca, S, Al, K,
Fe, Mg, Cl
Si, Ca, S, Al, Fe, K
Ca, Si, Al, Mn, S,
Fe, K, Ti, Cl, Zn
Si, Al, K, Ca, S,
Fe
Si, S, Ca, Al, Fe
Si, Al, K, Ca, Fe,
S, Ti, Mg, Cl, Mn,
Zn
Si, Al, Fe, K, Ca, S
Si, Ca, S, Al, K, Fe
Si, Ca, Al, S, Fe, K
Dimension &
Description
70 microns
agglomerate
6 microns
irregular
6 microns
spherical
15 microns
agglomerate
8 microns
irregular
15 microns
irregular
30x10 microns
irregular
8 microns
irregular
30 microns
agglomerate
15 microns
irregular
10 microns
irregular
35 microns
agglomerate
Probable
Identification
industrial particle
( limestone)
soil dust
f lyash
industrial particle
soil dust
industrial particle
mineral
soil dust
industrial particle
soil dust
soil dust
industrial particle

-------
                           TABLE D-214



            PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: Airport Date of Sample: 9 September 1976
Filter Number: 1093294 Photomicrograph Stub Number: 53
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
13
Elements in Order of
Spectral Height
Si, S, Ca, Al
Si, Ca, Al, Fe, S, K
Si, Al, S, Ca, Fe, K
Si, Ca, Al, K, Mg
Ca, Fe, S, Si, K, Mn
Si, Al, Fe, Ca, K, Ti
Si, S, Al
Si, Al, S, Ca, Fe, K
Ca, S, Fe, Si, K, Al,
Mg, Cl, Mn, Ti, Na,
Zn
Ca, S, Si, Al, K, Fe
Fe, Si, Ca, S, Al , Ti
Si, Ca, Al, Fe
Si, Ca, Al, S
Dimension &
Description
15 microns
irregular
10 microns
agglomerate
10 microns
agglomerate
15 microns
irregular
15 microns
agglomerate
8 microns
spherical
10 microns
irregular
12 microns
agglomerate
5 microns
irregular
10 microns
irregular
10 microns
irregular
7 microns
spherical
10 microns
agglomerate
Probable
Identification
soil dust -
limestone
industrial particle
industrial particle
soil dust
industrial particle
f lyash
soil dust
industrial particle
industrial particle
soil dust
(sulfate?)
industrial particle
(iron oxide)
f lyash
industrial particle
See Figure  D-29a and 29b

-------
                TABLE D-215



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: ,-,irporr,..1 , Date of Sample: 9 September 1976
(Cover Filter)
Filter Number: 1093295 Photomicrograph Stub Number: cor.
Particle Number
on Photomicrograph
1
2
3
4
5
6
7
8
9
10
11
12
13
Elements in Order of
Spectral Height
Si, Al, Ti, pe, K,
Ca, S, Cl, Mg, Na
Si, Ca, Al, Mg, S,
Fe, K
Si, Al, Ca, S, K,
Fe, Mg, Cl, Ti, Na,
Mn, Zn
Ca, Fe, S_, Si, Al, K,
Mg, Ti, Mn, Zn
Si, Al, Ca, K, Fe,
S, Mg, Na, Ti
^i., Al, Ca, S
Si, Al, K, Fe, Ca,
S, Ti, Mg
Si, Al, Fe, K, Ca,
S, Mg
Si, Ca, Al, S, K
Si, Ca, S, Al, K,
Fe, Mg
Si, Ca, S^ Al, K, Fe
Si. Al, Ca, S, Fe,
K, Mg, Ti, Cl, Zn
Ca, J3, Si, Al, Ti
Dimension &
Description
25 microns
irregular
18x6 microns
irregular
12 microns
irregular
14 microns
irregular
8 microns
agglomerate
6 microns
irregular
8 microns
irregular
12 microns
irregular
10 microns
irregular
10 microns
agglomerate
8 microns
irregular
12 microns
agglomerate
8 microns
irregular
Probable
Identification
industrial particle
soil dust
industrial particle
industrial particle
Industrial particle
soil dust
mineral
mineral
soil dust
industrial particle
industrial particle
industrial particle
soil dust

-------
      TABLE D-215  (Continued)



PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Si to: /^irP°r^.i N Date of Sample: 9 September 1976
(Cover Filter) '
Filter Number: 1093295 Photomicrograph Stub Number: ^c
Continued")
Particle Number
on Photomicrograph
14
15
Elements in Order of
Spectral Height
Fe, Si, S, Ca, K,
Al, Ti
Si, Al, Ca, K, Fe,
Mg, S, Ti
Dimension &
Description
8 microns
irregular
8 microns
agglomerate
Probable
Identification
industrial particle
(iron oxide)
industrial particle

-------
                            TABLE D- 216



            PARTICLE ANALYSIS OF SELECTED FILTERS
Monitor Site: South Fayette Date of Sample: 9 September 1976
Filter Number: 1106310 Photomicrograph Stub Number: 54
Particle Number
on Photomicrograph*
1
2
3
4
5
6
7
8
9
10
11
12
Elements in Order of
Spectral Height
S_, Ca, Si, Fe, Ti,
K, Al
Ca, S, Si, Al
Si., Al, Fe
Ca, Si, S, Mg, Fe,
Al, K
SI, _S, Al, Ca, K, Fe
Si, S, Al, Ca
Si, S, Al, Fe
(low level)
Si, Al, Fe, K, Ca,
Mn, S, Ti
Si, Al, S, Fe, K,
Ca
_Si, Al, K S, Fe,
Ca, Ti
S, Si, Al
E^i, Al, S, Fe
Dimension &
Description
25 microns
irregular
20 microns
agglomerate
20 microns
irregular
15 microns
irregular
12 microns
agglomerate
15 microns
agglomerate
10 microns
irregular
20 microns
irregular
10 microns
spherical
3 microns
agglomerate
15 microns
irregular
15 microns
spherical
Probable
Identification
industrial particle
industrial particle
soil dust
soil dust -
limestone
industrial particle
industrial particle
organic
soil dust
f lyash
industrial particle
organic
pollen
See Figure  D-30

-------
TABLE D-217 THROUGH D-224 - ANALYSIS OF SELECTED LARGE PARTICLES
                                D-48

-------
               TABLE D- 21 7




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
Filter Number: 1110916
Particle Number
(see Figure)
1 ' (Fig.D-31a)


2 (Fig.D-31a)

3 (Fig.D-31a)

4 (Fig.D-31a)


5 (Fig.D-31a)

7 (Fig.I)-31b)


8 (Fig.D-31b)

1 (Fig.D-32)

2 (Fig.D-33)

4 (Flg.D-34)

5 (Fig.D-35)

Elements in Order of
Spectral Height
S (low level peaks)


Si, S (low level
peaks)
j3i, Zn, _S, Na, Fe

Si, Ti, Cl, Al, Fe,
Ca

S_, Cl, K, Zn

Si, S_, Al, Fe, Zn,
K, Ca

Ca, S_, Si

S, Fe, Zn, Al, Si,
K
jFe, Si, Cl, S

Si_, Al, Ti, Fe

Si, Fe, Zn, Al, S, K,
Ca
Dimensions &
Description
100x30
microns
irregular
75x20 microns
irregular
35 microns
irregular
40 microns
elongated
agglomerate
35 microns
irregular
70 microns
rough semi-
spherical
50 microns
agglomerate
40x20 micror
agglomerate
15 microns
fused
25x15 micror
irregular
45x25 micror
agglomerate
Probable
Identification
organic - coal


organic - coal

industrial
particle
industrial
particle

industrial
particle
industrial
particle

industrial
particle
industrial
particle
iron oxide

soil dust

industrial
particle

-------
                             TABLE D-218

              ANALYSIS OF SELECTED LARGE PARTICLES
 Monitor Site:   Brighton Township  Date of Sample:  10 August 1976
                (Cover Filter)
 Filter Number:   1110917
Particle Number
   (see  Figure)
  1    (Fig.D-36)
  la   (Fig.D-36)
   Ib   (Fig.D-36)
   Ic   (Fig.D-36)
   Id   (Fig.D-36)
   le   (Fig.D-36)
Elements in Order of
  Spectra] Height
The entire particle
was not analyzed by
EDAX but the follow-
ing individual parts
of it were

Cl, Si, K, Fe
!Si, Fe, S_, Al, Ca,
K, Cl
_C1_,  Si, K, Fe, Al,
Ca
 Cl, K,  Si,  Fe,  Al
 Si,  Al,  Fe,  K,  Ti
Dimensions &
Description
100 microns
with
particles
attached
agglomerate

10 microns
spVierical
protrusion
from main
particle

15 microns
fluffy
irregular
attached to
main
particle

20 microns
angular
piece of
main
particle

Area on
right side
of main
particle

5 microns
sphere
attached
to main
particle
   Probable
Identif ication
industrial
particle

-------
               TABLE D-218




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
(Cover Filter)
Filter Number: 1110917 (Continued)
Particle Number
(see Figure)
1 (Fig.D-37)
2 (Fig.D-37)
3 (Fig.D-38)
1 (Fig.D-39)
1 (Fig.D-40)
2 (Fig.D-40)
3 (Fig.D-41)
4 (Fig.D-42)
5 (Fig.D-43)
6 (Fig.D-44)
Elements in Order of
Spectral Height
Fe, Si + small peaks
Si, Cl, K, Fe, Zn,
Al , Na + low peaks
Fe, Si, S, K, Ca +
low peaks
Al, S±_, Fe
Fe
Si., Al, K, Fe
S_, Si, Cl, Ca, Fe,
Na + low peaks
Si, Ca, Al, Fe, S,
K
Cl, K, J3, Si, Fe
Ca, S
Dimensions &
Description
45 microns
sphere
35x1 5 microns
curved and
flat
35x25microB
agglomerate
65x45micron£
agglomerate
32 microns
sphere with
rough sur-
face
35 microns
fused
150 microns
like crum-
pled paper
65 microns
fused, rough
150 microns
flaky
25 microns
agglomerate
Probable
Identification
plastic
industrial
particle
industrial
particle
industrial
particle
iron oxide
fused ash
ash
industrial
particle
industrial
particle
limestone

-------
               TABLE D-218




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 10 August 1976
(Cover Filter) (Continued)
Filter Number: 1110917
Particle Number
(see Figures)
7 (Fig.D-45)

8a (Fig.D-46)
8b (Fig.D-46)
9 (Fig.D-47)
Elements in Order of
Spectral Height
Mn, Fe, Si, Ca, K +
low peaks

Fe
Ca, Si, S_, Fe, Al +
small peaks
K, Fe, Si
Dimensions &
Description
25 microns
sphere with
many small
attached
particles
25 microns
agglomerate
15 microns
irregular
35 microns
agglomerate
Probable
Identification
f lyash

iron oxide
soil dust
industrial
particle

-------
               TABLE D-219




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Central Lab Date of Sample: 10 August 1976
Filter Number: 1110908
Particle Number
(see Figure)
1 (Fig.D-48)
2 (Fig.D-48)
3 (Fig.D-48)
4 (Fig.D-48)
Elements in Order of
Spectral Height
Ca
Ca, IS, Si, K
Fe
Si,, Fe, Al
Dimensions &
Description
50 microns
agglomerate
50 microns
irregular
40 microns
irregular
40 microns
irregular
Probable
Identification
limestone
industrial
particle
iron oxide
industrial
particle

-------
               TABLE D-220




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Central Lab Date of Sample: 10 August 1976
(Cover Filter)
Filter Number: 1110909
Particle Number
(see Figure)
1 (Fig.D-49)
2 (Fig.D-49)
3 (Fig.D-.49)
4 (Fig.D-49)
1 (Fig.l)-50)
1 (Fig.D-51)
2 (Fig.D-52)

1 (Fig.D-53)
2 (Fig.D-53)
3 (Fig.D-53)
1 (Fig.D-54)
2 (Fig.D-54)
Elements in Order of
Spectral Height
Si, Ca, Cl
S±, Al, Ca, Fe, K
Si, S, Cl, Ca, K, Ti,
Na, Fe
Si, S, Mn
S, Fe small peaks, ma)
be organic
Ca, Si, S, Al, K, Cl
Si, S, Cl, Ca, K, Fe.
Al

Ca, Si, S
S_i, Ca
Ca, Ti, S
Si, S, Ca
_S, Ca, Si, K, Fe
Dimensions &
Description
30 microns
irregular
15 microns
spherical
40 microns
irregular
25 microns
irregular
95 microns
irregular,
flat
40 microns
agglomerate
250x60 mic-
rons angulai
agglomerate
40 microns
agglomerate
20 microns
irregular
70 microns
agglomerate
30 microns
agglomerate
30 microns
agglomerate
Probable
Identification
soil dust
fly ash
industrial
particle
industrial
particle
organic
industrial
particle
industrial
particle

industrial par-
ticle, limestone
industrial
particle
industrial
particle
soil dust
industrial
particle

-------
                     TABLE D-220 (Continued)

              ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site:   Central Lab
               (Cover Filter)
Filter Number   1110909
                                    Date of Sample: 10 August 1976

                                      (Continued)
Particle Number
   (see  Figure)
  3    (Fig.D-54)
  9    (Fig.D-55)
 10    (Fig.D-55)
 11    (Fig.D-55)
 12    (Fig.D-55)
 14    (Fig.D-56)
 15    (Fig.D-56)
 16    (Fig.D-56)
 17    (Fig.D-56)
 18    (Fig.D-56)
 19    (Fig.D-56)
                   Elements in Order of
                     Spectral Height
                   SI' Ca, Al, Fe, S,
                   K, Cl
                   Si, Ca, S, Cl, Fe
                   ^, Fe,low peaks
                   Si, Ca, Al, Fe, K
                   Si, S, Ca, Fe
                   Ca, Si
                   Si, Al, Ca
                   low peaks
                   Si, Ca, S, Fe
                   Ca, S
                   Fe, Si, Ca, Mn
Dimensions&
Description
15 microns
almost
spherical

75x30microni
irregular

70 microns
irregular

120 microns
agglomerate

40 microns
irregular

50 microns
irregular

100 microns
fluffy
agglomerate

70 microns
irregular

50 microns
agglomerate

50 microns
irregular

50 microns
spherical
   Probable
Identification
industrial
particle
indvistrial
particle

organic - coal
industrial
particle

soil dust
industrial
particle

industrial
particle
organic - coal
industrial
particle

gypsum
industrial
particle

-------
               TABLE  D-221





ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Duquesne II Date of Sample: 10 August 1976
Filter Number: 1110926
Particle Number
(see Figure)
1 (Fig.D-57)




2 (Fig.D-58)

3a (Fig.I)-59)

3b (Fig.D-59)




4 (Fig.D-60)

5 (Fig.D-61)

1 (Fig.D-62)


2 (Fig.D-62

3 (Fig.D-62)

5 (Fig.D-62)

Elements in Order of
Spectral Height
Si, Al, Ca, Fe, K,
Ti



Si, Al, K, Fe

Si, S + small peaks,
may be organic
_S_i, Ca, Fe, S, K
spectra may come
from attached parti-
cles

Fe

Zn, Cl, Si, Na, Fe

Al


Si, Ca, Fe, + small
peaks
Si, Fe + small peaks

SI., Al, Fe, K

Dimensions &
Description
40x20 microns
agglomerate
with
particles on
surface
40 microns
agglomerate
25 microns
crumpled
40 microns
irregular
with
particles
attached
25 microns
sphere
32 microns
agglomerate
80 microns
irregular

50 microns
irregular
100x20microns
angular
30 microns
irregular
Probable
Identification
industrial
particle



industrial
particle
ash

ash




iron oxide

zinc chloride

industrial par-
ticle (alumi-
num oxide)
coal

coal

soil dust


-------
      TABLE D-221 (Continued)




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Duquesne II Date of Sample: 10 August 1976
Filter Number: 1110926 (Continued)
Particle Number
(see Figure)
6 (Fig.D-62)

1 (Fig.n-63)



2 (Fig.D-63)



3 (Flg.D-63)




4 (Fig.D-63)

5 (Fig.D-63)


6 (FLg.D-63)




Elements in Order of
Spectral Height
Al, Mg, Si, Fe, Ca

Si, Ca (particles 1,
2 and 6 may be joined
into a single parti-
cle)
Si, Ca, Fe + small
peaks


Si, S, Ca, Fe




Fe, Si

Si, Ca, Fe


Ca




Dimension3 &
Description
60 microns
irregular
55x30 micron:
irregular
particles
on surface
45 microns
agglomerate,
particles
on surface
20 microns
spherical
with parti-
cles on its
surface
6 microns
spherical
20 microns
particles on
surface
12x17 micron:
triangular
with parti-
cles on the
surface
Probable
Identification
industrial
particle
industrial
particle


industrial
particle


industrial
particle



iron oxide

industrial
particle

limestone





-------
               TABLE D-222




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Duquesne II Date of Sample: 10 August 1976
Filter Number: (Cover Filter)
1110927
Particle Number
(see Figure)
2 (Fig.D-64)

3 (Fig.D-65)



4a (Fig.D-66)

4b (Fig.D-66)

1 (Fig.D-67)

2 (Fig.D-67)

3 (Fig.D-67)


4 (Fig.D-67)

Elements in Order of
Spectral Height
organic

SJ,, Al, Ca, Fe



Fe + low peaks

Ca, _S

S_i, K, Cl, S, Al

^i, Al

Fe, Cr, Si, Cu, Al


^i, Ca, S, Al, Fe,
Mn
Dimensions&
Description
35x15 micron
lumpy
20 microns
irregular
like
backbone
25 microns
irregular
20 microns
irregular
45 microns
irregular
25 microns
egg-shaped
35 microns
irregular

30 microns
agglomerate
Probable
Identification
organic
(rubber)
industrial
particle


iron oxide

industrial par-
ticle (gypsum)
industrial
particle
soil dust

industrial par-
ticle (iron
oxide)
soil dust


-------
                             TABLE D-223

              ANALYSIS OF SELECTED LARGE PARTICLES
 Monitor Site:    Central  Laboratory Date of Sample:  16  August 1976

 Filter Number:  1093241
Particle Number
   (see  Figure)
Elements in Order of
  Spectral Height
Dimensions &
Description
   Probable
Identification
  14   (Fig.D-68)
Fe
  15   (Fig.D-69)
  16   (Fig.D-70)
  17   (Fig.D-71)
  18   (Fig.D-72)
  19   (Fig.D-73)
S, Fe small peaks
S, Fe, Si
small peaks
Si, Al, K, Fe
Si, Al, S, Ca, Fe
230 microns
cluster,
angular
agglomerate

160 microns
angular,
frothy

130 microns
frothy

170 microns
flake

125 microns
angular

70 microns
hollow
fused
  iron oxide
  coke



  coke


  organic coal


  fused clay


  fused clay

-------
               TABLE D-224




ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 9 September 1976
Filter Number: 1110928
Particle Number
(see Figure)
1 (Fig.D-74a
& Fig.D-74b)
la (Fig.D-74b)
Ib (Fig.D-74b)
lc (Fig.D-74b)


2 (Fig.D-74a)
& Fig.D-75)
3 (Fig.D-74a
& Fig.D-76)
4 (Fig.D-74a
& Fig.D-77)
5 (Fig.D-78)

Elements in Order of
Spectral Height
The entire particle
was not analyzed by
EDAX but the follow-
ing parts of it were
Si, Fe, Ca, K, Al,
Cl
Si, Ca, Fe, Al, K,
Cl
Only small peaks


Fe, Ca, S
Si, S, Al, Fe, Zn,
Ti
_S, Ca, Fe, Zn, Si
Si., Al, Fe, K, Ca

Dimensions &
Description
370x160
microns
angular
flake
central 25%
of particle
participates
on particle
central area
of main
particle
(smaller than
25%)
80 microns
rough
surface
230 microns
fused
agglomerate
200x30
microns
irregular
rough
60 microns
hollow
sphere
Probable
Identification



organic


iron oxide
industrial par-
ticle possibly
coke
industrial par-
ticle of gypsum
f lyash
hollow


-------
                    TABLE D-224 (Continued)

              ANALYSIS OF SELECTED LARGE PARTICLES
 Monitor Site: Brighton Township    Date of Sample:  9 September 1976
 Filter Number:   1110928            (Continued)
Particle Number
  (see  Figure)
       (Fig.D-79)
 7    (Fig.D-80)


 8    (Fig.D-81)



 9    (Fig.D-82)



10    (Fig.D-83)
 11    (Fig.D-84)
 12
 13    (Fig.D-86)
Elements in Order of
  Spectral Height
Si, Al, Fe, Ca, K,
Zn
                    Si, Al, Fe, Zn + low
                    peaks

                    Ve_, Si, Zn + low
                    peaks
                    _S_i, S_, Al, Fe, Zn,
                    Ca
                    Ti, Si, Al, Fe, Cl
Si, Al
Si, Ca, Fe, Al, Zn
The entire particle
was not analyzed by
EDAX but the follow-
ing parts of it were
 Dimensions&
 Description
 55  microns
 agglomerate
 made  up  of
 many  spheres

 70  microns
 porous  flake

 95  microns
 flaky
 agglomerate

 65  microns
 agglomerate
 30 microns
 irregular ,
 rough
 surface

 70 microns
 lacy open
 structure

75x40 microns
 irregular
 flake with
 attached
 particles
 35 microns
 rough sphere
 with parti-
 cles attachdd
                                                         Probable
                                                      Identification
                                                       flyash
                                                       cluster
                                    coke
                                    coke
                                   industrial  par-
                                   ticle  with
                                   flyash sphere

                                    rutile
                                                       silicate
                                                       ash
                                                      industrial  par-
                                                      ticle mixed
                                                      chloride

-------
      TABLE D-224 (Continued)





ANALYSIS OF SELECTED LARGE PARTICLES
Monitor Site: Brighton Township Date of Sample: 9 September 1976
Filter Number: 1110928 (Continued)
Particle Number
(see Figure)
13a (Fig.D-86)
13b (Fig.D-86)
13c (Fig.D-86)
13d (Fig.D-86)
Elements in Order of
Spectral Height
_S, Cl, Zn, Fe
S_, Zn, Cl, Fe
Si, S, Al, Cl, Zn,
Fe
Cl, Zn, Fe, Al
Dimensions &
Description
central area
particle in
center
attached
sphere
particle
surface
Probable
Identification





-------
TABLE D-225 and D-226 - ELEMENTAL ANALYSIS OF FIVE SELECTED LARGE
                        PARTICLES
                                D-49

-------
                    TABLE D-225
ELEMENTAL ANALYSIS OF FIVE SELECTED LARGE PARTICLES
  ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS TO
         THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Rig
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
iAIn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Hunk
Order
Particle Number
1
0.00
0.00
0.01
0.10
1.00
0.18
0.03
0.00
0.01
0.11
0.01
0.00
0.02
0. 19
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, $ Ca,
Si
2
0.00
0.00
0.00
0.12
1.00
0.05
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.13
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, Si
3
0.00
0.00
0.03
0.00
1.00
0.06
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0. 12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe
4
0.00
0. 00
0.00
0.01
1.00
0. 12
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0. 16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, S
5
0.00
0.00
0.00
0.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe

-------
                  TABLE D-226
RESULTS OF ELEMENTAL ANALYSIS OF FIVE SELECTED
               LARGE PARTICLES
Particle Number
(See Figure)
1 (Fig.D-87)
2 (Fig.D-88)
3 (Fig.D-89)
4 (Fig.D-90)
5 (Fig.D-91)
Elements in Order of
Spectral Height
Fe, S, Ca, Si
Fe, Si (low level
peaks)
Fe (low level peaks)
Fe, S, (low level
peaks)
Fe (low level peaks)
Dimension &
Description
100 microns
lacy, agglo-
merate
110 microns
flat, irregular
160 microns
flat, irregular
140 microns
agglomerate
150 microns
angular, irreg-
ular
Probable
Identification
plant particle
industrial
particle
organic, ash
plant particle
(soot)
organic, coal

-------
TABLE D-227A THROUGH D-229B - EDAX ELEMENTAL ANALYSIS  OF LARGE
                                   SLAG PARTICLES
                                D-50

-------
                          TABLE D-227A
EDAX ELEMENTAL ANALYSIS OF LARGE PARTICLES WHICH WERE TAKEN
   FROM SLAG SAMPLES PRODUCED BY AN ELECTRIC ARC FURNACE.
         ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
             TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-92
and D-93)
A
0.01
0.67
0.02
0.26
1.00
0.12
0.00
0.00
0.00
0.35
0.05
0.08
0.34
1.12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Fe, Mg, Ca,
Mn, Si, S,
Cr, Ti

(Fig. D-96
and D-97)
B
0.00
0.00
0.03
0.99
1.00
0.06
0.04
0.00
0.05
3.19
0.01
0.01
0.07
0.51
0.00
0.00
0.11
0.04
0.00
0.00
0.00
Ca, Si, Fe,
Zn, Mn, Cu


(Fig.D-100)
C
0.00
0.07
0.17
0.82
1.00
0.04
0.01
0.00
0.08
1.21
0.02
0.00
0.00
0.46
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Ca, Si, , Fe,
Al, K, Mg


(Fig.D-101)
D
0.02
0. 07
0. 18
1.31
1.00
0. 14
0.05
0. 00
0.07
3.41
0.02
0.03
0. 06
0. 73
0.00
0.00
0. 02
0.00
0.00
0.00
0.00
Ca, Si, Fe,
Al, S, Mg,
K, Mn, Cl




























-------
                          TABLE D- 227B
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
      ON THE LARGE PARTICLES WHICH WERE TAKEN FROM SLAG
        SAMPLES PRODUCED BY AN ELECTRIC ARC FURNACE
         ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
              TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements

Na
Mg
Al
Si
Au
S
Cl
Cd
K
Cu
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-94)
A-l
0.00
0.00
0.00
0.35
1.00
0.02
0.04
0.00
0.00
1.57
0.00
0.01
0.00
0.42
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Ca, Fe, Si

(Fig.D-95)
A- 2
0.09
0.07
0.07
2.25
1.00
0.18
0.19
0.00
0.31
7.55
0.14
0.13
0.31
1.28
0.00
0.00
0.11
0.04
0.00
0.00
0.00
Ca, Si, Fe,
Mn, K, Cl,
S, Ti, Cr,
Zn, Na, Mg,
Al, Cu
(FLt;.D-98)
B-l
0.09
0.12
0.12
1.68
1.00
0.05
0.11
0.00
0.13
4.02
0.06
0.02
0.09
0.56
0.00
0.00
0.01
- 0.02
0.00
0.00
0.00
Ca, Si, ,Fe,K,
Mg, Al, Cl,
Mn, Na, Ti
(Fig.D-99)
B-2
0. 06
0.00
0.07
1.04
1.00
0.08
0. 10
0.00
0.07
3.68
0.05
0.07
0.08
1.05
0.00
0.00
0.05
0.05
0.00
0.00
0.00
Ca, Fe, Si,
Cl, Mn, S,
Cr.Al, K, Na,
Cu, Zn, Ti


























-------
                          TABLE D- 227C

EDAX ELEMENTAL ANALYSIS OF SMALL PARTICLES WHICH WERE TAKEN
     FROM SLAG SAMPLES PRODUCED BY AN ELECTRIC ARC FURNACE.
         ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
             TO THE INTEGRAL ENERGY PEAK OF GOLD

Elements

Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-102
and D-103)
E
0.02
0.06
0.15
1.14
1.00
0.13
0.06
0.00
0.11
4.18
0.07
0.21
0.09
0.26
0.00
0.00
0.04
0.06
0.00
0.00
0.00
Ca, Si, Fe,
Cr, Al, K, Mn
Ti, Cu, Mg

(Fig.D-106
and D-107)
F
0.00
0.02
0.07
0.86
1.00
0.10
0.03
0.00
0.10
3.80
0.09
0.26
0.33
1.04
0.00
0.00
0.24
0.19
0.00
0.00
0.00
Ca, Fe, Si, Mn
Cr, Zn, Cu,
S, K

(Fig.D-111)
G
0.10
0.34
4.45
1.15
1.00
0.24
0.33
0.00
0.46
19.76
0.46
0.74
0.72
2.62
0.00
0.00
0.61
0.68
0.00
0.00
0.00
Ca, Al, Fe.Si^
Cr, Mn, Cu,
Zn, Ti, K.Mg,
Cl, S, Na
(Fig.D-111)
H
0.00
0. 32
3.81
1.73
1.00
0.18
0. 15
0.00
0.31
5.20
0.08
0.19
0.26
1.08
0.00
0.00
0.24
0.29
0.00
0.00
0.00
Ca, Al,Si,
Fe, Mg, K, Ci
Mn, Zn, Cr,
S, Cl, Ti
(Fig.D-112)
I
0.00
0.21
0.55
1.26
1.00
0.10
0.01
0.00
0.04
2.27
0.07
0.06
0.05
0.10
0.00
0.00
0.00
0.02
0.00
0.00
0.00
Ca, Si, Al,
Mg, Fe, S,
Ti, Cr, Mn


-------
                          TABLE D-227D
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
 ON THE SMALL PARTICLES WHICH WERE TAKEN FROM SLAG SAMPLES
      PRODUCED BY AN ELECTRIC ARC FURNACE.  ENTRIES ARE
            RATIOS OF INTEGRAL ENERGY PEAKS TO THE
                 INTEGRAL ENERGY PEAK OF GOLD
Elements

Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig.D-104)
E-l
0.03
0.10
0.38
1.14
1.00
0.18
0.16
0.00
0.25
4.98
0.46
0.21
0.44
0.98
0.00
0.00
0.12
0.23
0.00
0.00
0.00
Ca, Si, Fe.Ti,
Mn, Al, K,.Cu
Cr, S, Cl, Zn,
Mg
(Fig.D-105)
E-2
0.00
0.03
0. 16
0.94
1.00
0.17
0.01
0.00
0.07
2.51
0.07
0.08
0. 13
0.25
0.00
0.00
0. 00
0.04
0.00
0. 00
0.00
Ca, Si, Fe, S,
Al, Mn, Cr, Ti
K, Cu
(Fig.D-108)
F-l
0.00
0.30
0. 58
1.53
1.00
0.28
0.18
0.00
0.28
7.30
0.12
0.30
0. 60
2.89
0.00
0.00
0. 53
0. 67
0. 00
0.00
0.00
Ca, Fe,,Si,
Cu, Mu, Al,
Zn, Mg, Cr, S
K, Cl, Ti
(Fig.D-109)
F-2
0. 15
0.42
0.46
3.02
1.00
0. 14
0.10
0.00
0. 13
4.21
0.09
0. 12
0. 10
0.24
0.00
0.00
0.03
0.03
0.00
0.00
0.00
Ca, Si, Al, Mg
Fe, Na, S, K,
Cr, Mn, Cl.Ti
(Fig.D-110)
F-3
0.05
0.00
0.57
1.67
1.00
0.09
0.01
0.00
0.25
0.77
0.05
0.11
0.10
0.49
0.00
0.00
0.04
0.07
0.00
0.00
0.00
Si, Ca, Al,
Fe, K, Cr,
Mn, S, Cu

-------
                         TABLE D-228A
EDAX ELEMENTAL ANALYSIS OF LARGE PARTICLES WHICH WERE TAKEN
       FROM SLAG SAMPLES PRODUCED BY A BLAST FURNACE.
         ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
             TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Jig
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig. D-113)
A
0.01
0.2G
0.37
1.67
1.00
0.14
0.08
0.00
0.38
3.20
0.14
0.08
0.11
0.61
0.00
0.00
0.07
0.08
0.00
0.00
0.00
Ca, Si, Fe, K,
Al, Mg, Ti.Mr
Cu, Cr, Cl, Zn
(Fig. D-113)
B
0.02
0.22
0. 11
1.17
1.00
0.13
0. 04
0.00
0.11
1.91
0.07
0.06
0.06
0.35
0. 00
0.00
0.04
0.01
0.00
0.00
0.00
Ca.Si, Fe,
Mg, S.A1, Ti
Cr, Mn
(Fig. D-113)
C
0.05
0.19
0.28
1.29
1.00
0. 19
0.04
0.00
0.21
2.54
0.09
0.04
0.08
0.30
0.00
0.00
0. 03
0. 05
0.00
0.00
0.00
Ca, Si, Fe.Al,
K, Mg,S, Ti,
Mn, Na, Cu















































-------
                         TABLE D-228B
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
   ON THE LARGE PARTICLES WHICH WERE TAKEN FROM SLAG SAM-
        PLES PRODUCED BY A BLAST FURNACE.  ENTRIES ARE
            RATIOS OF INTEGRAL ENERGY PEAKS TO THE
                 INTEGRAL ENERGY PEAK OF GOLD
Elements
Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In R a nls:
Order
Particle
(Fig.D-114)
A-l
0.02
0.07
0.28
0.97
1.00
0.09
0.05
0.00
0.05
1.87
0.02
0.01
0.01
0.11
0.00
0.00
0.01
0.01
0.00
0.00
0.00
Ca, Si, Al, Fe
S, Mg
(Fig.D-114)
A-2
0.01
0.22
0.32
1.80
1.00
0.08
0.04
0.00
0.06
2.36
0.06
0.01
0.02
0.10
0.00
0.00
0.01
0.01
0.00
0.00
0.00
Ca, Si, Al,
Mg, Fe, S
(Fig.D-114)
A-3
0.01
0.02
0.15
2.13
1.00
0.12
0.09
0.00
0.18
6.14
0.07
0.05
0.06
0.33
0.00
0.00
0.04
0.03
0.00
0.00
0.00
Ca, Si, Fe,
K, Al, S, Cl
(Fig. D-114)
A-4
0.00
0.11
0.40
1.18
1.00
0.12
0.01
0.00
0.10
2.78
0.04
0.10
0.05
0.30
0.00
0.00
0.02
0.02
0.00
0.00
0.00
Ca, Si, Al,
Fe, S, Mg,
Cr, K, Mn
(Fig. D-114)
A-5
0.04
0.00
0.27
0.77
1.00
0.08
0.01
0.00
0.20
2.40
0. 14
0.03
0.01
0.28
0.00
0.00
0.02
0.01
0.00
0.00
0.00
Ca, Si, Fe,
Al, K, Ti,
S

-------
                          TABLE D-229A
EDAX ELEMENTAL ANALYSIS OF LARGE PARTICLES WHICH WERE TAKEN
   FROM SLAG SAMPLES PRODUCED BY A BASIC OXYGEN FURNACE.
         ENTRIES ARE RATIOS OF INTEGRAL ENERGY PEAKS
             TO THE INTEGRAL ENERGY PEAK OF GOLD
Elements

Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Ranis
Order
Particle
(Fig. D-115)
A
0.10
0.09
0.15
1.25
1.00
0.20
0.07
0.00
0.17
6.19
0.18
0.16
0.24
1.20
0.00
0.00
0.12
0.14
0.00
0.00
0.00
Ca, Si, Fe,Mn,
S, Ti.K, Cr,
Al, Cu, Zn, Mg:
Cl
(Fig. D-115)
B
0.00
0.13
0.07
0.97
1.00
0.09
0.05
0.00
0.05
3.60
0.11
0.09
0.27
0.80
0.00
0.00
0.05
0.04
0.00
0.00
0.00
Ca.Si, Fe, Mn
Mg, Ti, Cr, S,
Al









































































-------
                         TABLE D-229B
EDAX ELEMENTAL ANALYSIS OF SELECTED SURFACE PARTICLES FOUND
  ON THE LARGE PARTICLES WHICH WERE FROM SLAG PRODUCED BY
         A BASIC OXYGEN FURNACE.  ENTRIES ARE RATIOS OF
            INTEGRAL ENERGY PEAKS TO THE INTEGRAL
                      ENERGY PEAK OF GOLD
Elements

Na
Mg
Al
Si
Au
S
Cl
Cd
K
Ca
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Hg
As
Pb
Important
Elements
In Rank
Order
Particle
(Fig. D-116)
A-l
0.21
0.45
0.91
7.54
1.00
0.97
0.50
0.00
0.71
29.20
0.38
0.24
0.71
2.38
0.00
0.00
0.16
0.25
0.00
0.00
0.00
Ca.SJjFe.S,
AI.Mn, K, Cl,
Mg, Ti, Cu, Ci
Nu.Zn
(Fig. D-116)
A-2
0.00
0.30
0.29
2.64
1.00
0.36
0.26
0.00
0.41
12.50
0.23
0.23
0.93
2.45
0.00
0.00
0.23
0.23
0.00
0.00
0.00
Ca, Si^Fe,
Mh.K.S, Mg,
Al, Cl,Ti, Cu,
Cr.Zn
(Fig. D-116)
A-3
0.00
0.30
0.77
2.76
1.00
0.37
0.17
0.00
0.34
0.78
0.14
0.08
0.11
0.67
0.00
0.00
0.06
0.09
0.00
0.00
0.00
Sij Ca, AJ.Fe,
S,K,Mg,Cl,
Ti, Mn, Cu, Cr,
Zn
(Fig. D-116)
A-4
0.03
0.02
0.34
1.33
1.00
0.21
0.07
0.00
0.22
3.87
0.09
0.07
0.08
0.51
0.00
0.00
0.01
0.04
0.00
0.00
0.00
Ca, Si, Fe.Al,
K, S, Ti, Mn,
Cr, Cl
(Fig. D-116)
A-5
0.11
0.23
0.36
1.03
1.00
0.23
0. 17
0.00
0.20
10.23
0.69
0. 65
2.34
6.72
0.00
0.00
0.33
0. 31
0.00
0.00
0.00
Ca, Fe, Mn,
Si, Ti, Cr, Al,
Zn, Cu, Mg, S
K, Cl, Na

-------
TABLE D-229B (Continued)
Elements

Na
Mg
Al
Si
An
s
Cl
Cd
K
Cu
Ti
Cr
Mn
Fe
Co
Ni
Zn
Cu
Ilg
As
Pb
Important
Elements
In Rank
Order
Particle
(Flg.D-116)
A-6
0.00
0.91
0.24
0.58
1.00
0.13
0.05
0.00
0.20
1.94
0.14
0.51
1.87
4.70
0.00
0.00
0.14
0.17
0.00
0.00
0.00
Fe, Ca, Mn,
Mg.Si.Cr.Al,
K, Cu, Zn.Ti,
S

































































































-------
TABLE D-230 THROUGH D-236 -  OPTICAL MICROSCOPY ANALYSIS BY
                             MeCRONE ASSOCIATES
                                D-51

-------
                             TABLE D-230

         OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
                      ON FILTER NUMBER 1093225
 Location:    Brighton Township
      Date:
16 August 1976
           Component
Percent By Number
     Size Range  (ym)
Combustion Products

fused ash (glassy spheres)
unfused ash
magnetite spheres
oil soot
coked coal

    Total Combustion Products
Minerals

iron oxide
quartz
calcite

    Total Minerals
Biological Materials
        18
        30
         2
         2
        li

        83
         6
         7
        _3

        16
   Not Detected
         10-40
         20-100
         20-40
         30-40
         20-100
         10-100
         20-60
         10-50

-------
                             TABLE D-231

         OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
                      ON FILTER NUMBER 1093227
 Location:
Midland
Date:
16 August 1976
           Component
                   Percent By Number
               Size Range (ym)
Combustion Products

oil soot
unfused ash
fused ash (glassy spheres)
coked coal

    Total Combustion Products
Minerals

iron oxide
quartz
calcite
feldspars

    Total Minerals
Biological Materials

spores
bark
diatoms
miscellaneous plant tissue

    Total Biological Materials
                           20
                           10
                            5
                           70
                            5
                           15
                            8
                          trace

                           28
                          trace
                          trace
                          trace
                          trace
                   30-100
                   30-50
                    4-12
                   30-100
                   10-100
                   10-50
                    5-60
                     50

-------
                   TABLE D-232

OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
            ON FILTER NUMBER  1093205
Location: Duquesne II Date: 16 August 1976
Component
Combustion Products
fused ash (glassy spheres)
unfushed ash
magnetite spheres
coked coal
Total Combustion Products
Minerals
clay
iron oxide
quartz
feldspars
calcite
mica
carborundum
Total Minerals
Biological Materials
starch
pollen
spores
bark
Total Biological Materials
Percent By Number
4
37
1
25_
67
8
5
7
1
3
2

-------
                   TABLE D- 233

OPTICAL MICROSCOPY ANALYSIS BY McCRONE ASSOCIATES
            ON FILTER NUMBER 1093209
Location: Liberty Boro Date: 16 August 1976
Component
Combustion Products
coked coal
oil soot
fused ash (glassy spheres)
unfused ash
magnetite spheres
coal (unburned)
Total Combustion Products
Minerals
feldspars
clay
quartz
calcite
iron oxide
Total Minerals
Biological Materials
pollen
spores
miscellaneous plant tissue
Total Biological Materials
Percent By Number

23
13
5
24
<1
_4
70

4
8
4
8
_2
26

<1
trace
<±
<2
Size Range (urn)

10-100
4-40
4-40
20-50
10-40
30-40


10-60
16-30
5-20
3-40
10-20


18-28
-
-


-------
                             TABLE D-234

          OPTICAL MICROSCOPY  ANALYSIS BY MeCRONE  ASSOCIATES
                      ON FILTER NUMBER 1093239
 Location:
South Fayette
Date:
16 August 1976
           Component
                   Percent By Number
               Size Range (urn)
Combustion Products

fused ash (glassy spheres)
unfused ash
magnetite spheres
coked coal
oil soot

    Total Combustion Products
Minerals

iron oxide
quartz
calcite

    Total Minerals
Biological Materials
                            2
                           35
                            1
                           11
                           62
                           30
                            5
                           _2

                           37
                       Not Detected
                   5-20
                  10-50
                  30-40
                  20-90
                  20-90
                  10-50
                   6-15
                   3-5

-------
                             TABLE D-235

         OPTICAL MICROSCOPY ANALYSIS BY MeCRONE ASSOCIATES
                      ON FILTER NUMBER 1093284
 Location:
Brighton Township
Date:     16 August 1976
           Component
                   Percent By Number
               Size Range (ym)
Combustion Products

fused ash (glassy spheres)
unfused ash
coked coal
unburned coal
magnetite spheres
oil soot

    Total Combustion Products
Minerals

iron oxide
mica
quartz
feldspars
calcite

    Total Minerals
Biological Materials

pollen
spores
bark
miscellaneous plant tissue

    Total Biological Materials
                           28
                            2
                           48
                            4
                            1
                           89
                          trace
                   8-40
                  10-50
                  20-100
                  20-40
                  15-20
                  20-40
                                            5-30
                                           30-80
                                           10-20
                                           40-50
                                           15-20
                                           18-25
                                           18-30
                                             90

-------
                             TABLE D-236

       OPTICAL MICROSCOPY ANALYSIS DONE BY McCRONE ASSOCIATES
                      ON FILTER NUMBER 1093284
Location:
                 Brighton Township
                                        Date:     August 28, 1976
         Component
                                  Percent by Number
                                                        Size Range (ym)
Combustion Products

fused ash (glassy spheres)
unfused ash
coked coal
unburned coal
magnetite spheres
oil soot

   Total Combustion Products
Minerals

iron oxide
mica
quartz
feldspars
calcite

   Total Minerals
Biological Materials

pollen
spores
bark
miscellaneous plant tissue

   Total Biological Materials
                                        28
                                         2
                                        48
                                         4
                                         1
                                        89
                                         2
                                         1
                                         2
                                         1
                                       trace
                                                             8-40
                                                            10-50
                                                            20-100
                                                            20-40
                                                            15-20
                                                            20-40
                                                             5-30
                                                            30-80
                                                            10-20
                                                            40-50
                                                            15-20
                                                           18-25
                                                           18-30
                                                             90

-------
FIGURE D-6 THROUGH D-19 - CUMULATIVE MASS DISTRIBUTIONS FROM THE
                          OPTICAL AND SEM ANALYSES
                                D-52

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    -------
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    -------
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    -------
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    -------
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    -------
    FIGURES D-20 THROUGH D-116 - PHOTOMICROGRAPHS
                                    D-53
    

    -------
    FIGURE D-20:  Stub Number 46 which shows a magni-
       fied portion of the filter taken from the
       Baden Monitor on 8/16/76. (Refer to Table
       D-171)
    FIGURE D-21:  Stub Number 46 which shows a magni-
       fied portion of the filter taken from the
       Midland Monitor on 8/16/76.  (Refer to Table
       D-175)
    

    -------
    FIGURE D-22: Stub Number 44 which shows a magni-
       fied portion of the filter taken from the
       Elco monitor on 8/16/76.  (Refer to Table
       D-177)
    

    -------
                                    HuJTT '"*& *i-'
                                    g^Sfe* ' -SP *" .' „-
    FIGURE D-23a:  Stub Number 21 which  shows  a  magni-
       fied portion of the filter taken  from the
       Central Lab Monitor on 8/16/76.   (Refer to
       Table D-179)
    FIGURE D-23b:  Stub Number  21 which  shows  a magni-
       fied portion of the filter taken  from the
       Central Lab Monitor on 8/16/76.   (Refer to
       Table D-179)
    

    -------
    FIGURE D-24a: Stub Number 39 which shows a magni-
       fied portion of the filter taken from the Hazel-
       wood Monitor on 8/16/76. (Refer to Table D-180)
    FIGURE D-24b: Stub Number 39 which shows a magni-
       fied portion of the filter taken from the Hazel-
       wood monitor on 8/16/76. (Refer to Table D-180)
    

    -------
     FIGURE  D-25:  Stub  Number 57  which shows a magni-
        fied portion of the  filter  taken from the No.
        Braddock Monitor on  8/28/76.   (Refer to Table
        D-194)
    FIGURE D-26: Stub Number 57C which shows a magni-
       fied portion of the cover filter taken from
       the No. Braddock Monitor on 8/28/76. (Refer
       to Table D-195)
    

    -------
    FIGURE D-27: Stub Number 60 which shows a magni-
       fied portion of the filter taken from the
       Liberty Boro Monitor on 8/28/76.  (Refer to
       Table D-198)
    

    -------
     FIGURE D-28a:  Stub Number  60C which  shows  a magni-
        fied portion  of the  cover filter  taken  from
        the Liberty Boro Monitor on  8/28/76.   (Refer
        to Table  D-199)
    FIGURE D-28b: Stub Number 60C which shows a magni-
       fied portion of the cover filter taken from
       the Liberty Boro Monitor on 8/28/76. (Refer
       to Table D-199)
    

    -------
    FIGURE D-29a: Stub Number 53 which shows a magni-
       fied portion of the filter taken from the
       Airport Monitor on 9/9/76. (Refer to Table
       D-214)
    FIGURE D-29b: Stub Number 53 which shows a magni-
       fied portion of the filter taken from the
       Airport Monitor on 9/9/76. (Refer to Table
       D-214)
    

    -------
    FIGURE D-30:  Stub Number 54 which shows a magni-
       fied portion of the filter taken from the
       So. Fayette Monitor on 9/9/76.  (Refer to
       Table D-21b)
    

    -------
     FIGURE D-31a:   Selected  large particles  taken from
        the Brighton Twp  filter which was exposed on
        8/10/76.   (Refer  to Table D-217)
    
    
    
    
    
                                    11-17-76
    FIGURE D-31b:  Se"icted large particles taken from
       the Brighton Twp filter which was exposed on
       8/10/76.  (Refer to Table D-217)
    

    -------
     FIGURE D-32:  Selected large particles taken from
        the Brighton Twp filter which was exposed on
        8/10/76.   (Refer to Table D-217)
    FIGURE D-33: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       8/10/76.  (Refer to Table D-217)
    

    -------
    FIGURE D-34:  Selected large particles  taken from
        the Brighton Twp filter which was exposed on
        8/10/76.   (Refer to Table D-217)
    FIGURE D-35: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       8/10/76.  (Refer to Table D-217)
    

    -------
    FIGURE D-36: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    FIGURE D-37: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    

    -------
    FIGURE D-38: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    FIGURE D-39: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    

    -------
    FIGURE D-40:  Selected  large particle  taken  from
        the Brighton  Twp  cover  filter which was  ex-
        posed  on 8/10/76.   (Refer  to Table D-218)
    FIGURE D-41: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    

    -------
    FIGURE D-42: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    FIGURE D-43: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    

    -------
    FIGURE D-44: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    FIGURE D-45: Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    

    -------
    FIGURE D-46:  Selected large particles  taken from
        the Brighton Twp cover  filter which was ex-
        posed on 8/10/76.  (Refer  to Table  D-218)
    FIGURE D-47:  Selected large particles taken from
       the Brighton Twp cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-218)
    

    -------
    FIGURE D-48: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/10/76.  (Refer to Table D-219)
    

    -------
    FIGURE D-49: Selected large particles taken from
       the Central Lab cover filter which was ex-
       posed on 8/10/76.  (Refer to Table D-220)
    FIGURE D-50: Selected large particles taken from
       the Central Lab cover filter which was exposed
       on 8/10/76.  (Refer to Table D-220)
    

    -------
                         1100X
    H-17-76
    FIGURE D-51:  Selected large particles taken from
       the Central Lab cover filter which was exposed
       on 8/10/76.  (Refer to Table D-220)
    FIGURE D-52: Selected large particles taken from
       the Central Lab cover filter which was exposed
       on 8/10/76.  (Refer to Table D-220)
    

    -------
    FIGURE D-53: Selected large particles taken from
       the Central Lab cover filter which was exposed
       on 8/10/76.  (Refer to Table D-220)
    FIGURE D-54: Selected large particles taken from
       the Central Lab cover filter which was exposed
       on 8/10/76.  (Refer to Table D-220)
    

    -------
     FIGURE D-55:  Selected  large particles  taken  from
        the Central  Lab  cover  filter which  was  exposed
        on 8/10/76.   (Refer to Table D-220)
    FIGURE D-56: Selected large particles taken from
       the Central Lab cover filter which was exposed
       on 8/10/76.  (Refer to Table D-220)
    

    -------
    FIGURE D-57: Selected large particles  taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    
       ^"N|t_
                                      11-16-76
    FIGURE D-58: Selected large particles taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    

    -------
    FIGURE D-59: Selected large particles taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    FIGURE D-60: Selected large particles taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    

    -------
    FIGURE D-61: Selected large particles taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    
    
    
    
    
    FIGURE D-62: Selected large particles taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    

    -------
    FIGURE D-63: Selected large particles taken from
       the Duquesne II filter which was exposed on
       8/10/76.  (Refer to Table D-221)
    

    -------
                       _,_ c-jfj-'-j
    
                      •        ! "
    FIGURE D-64: Selected large particles  taken  from
       the Duquesne II cover filter which  was  exposed
       on 8/10/76.  (Refer to Table D-222)
    FIGURE D-65:  Selected  large  particles taken from
       the Duquesne  II  cover  filter  which was exposed
       on 8/10/76.   (Refer to Table  D-222)
    

    -------
    FIGURE D-66: Selected large particles taken from
       the Duquesne II cover filter which was exposed
       on 8/10/76.  (Refer to Table D-222)
    FIGURE D-67: Selected large particles taken from
       the Duquesne II cover filter which was exposed
       on 8/10/76.  (Refer to Table D-222)
    

    -------
    FIGURE D-68: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/16/76.  (Refer to Table B-223)
    FIGURE D-69: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/16/76.  (Refer to Table D-223)
    

    -------
    FIGURE D-70: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/16/76.  (Refer to Table D-223)
    FIGURE D-71: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/16/76.  (Refer to Table D-223)
    

    -------
    FIGURE D-72: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/16/76.  (Refer to Table D-223)
    FIGURE D-73: Selected large particles taken from
       the Central Lab filter which was exposed on
       8/16/76.  (Refer to Table D-223)
    

    -------
    FIGURE D-74a: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.   (Refer to Table D-224)
    FIGURE D-74b: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    

    -------
    FIGURE D-75: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    FIGURE D-76:  Selected large particles  taken from
        the Brighton Twp  filter which was exposed  on
        9/9/76.   (Refer to Table D-224)
    

    -------
    FIGURE D-77: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.   (Refer to Table D-224)
    FIGURE D-78: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    

    -------
    FIGURE D-79: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    FIGURE D-80: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    

    -------
    FIGURE D-81: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    FIGURE D-82: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    

    -------
    FIGURE D-83: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    FIGURE D-84: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    

    -------
    FIGURE D-85: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    FIGURE D-86: Selected large particles taken from
       the Brighton Twp filter which was exposed on
       9/9/76.  (Refer to Table D-224)
    

    -------
    FIGURE D-87: Selected large particle Number 1,
       (Refer to Table D-226)
    FIGURE D-88: Selected large particle Number 2.
       (Refer to Table D-226)
    

    -------
    FIGURE D-89: Selected large particle Number 3.
       (Refer to Table D-226)
    FIGURE D-90: Selected large particle Number 4.
       (Refer to Table D-226)
    

    -------
    FIGURE D-91: Selected large particle Number 5.
       (Refer to Table D-226)
    

    -------
    FIGURE D-92: Large particle A from an electric
       arc furnace slag sample.  (Refer to Table
       D-227A)
    FIGURE D-93: Closeup of large particle A from an
       electric arc furnace slag sample.  (Refer to
       Table D-227A)
    

    -------
    FIGURE D-94: Surface particle A-l which had adher-
       ed to large particle A from an electric arc
       furnace slag sample. (Refer to Figure D-92 and
       Table D-227B)
    FIGURE D-95: Surface particle A-2 which had adher-
       ed to large particle A from an electric arc
       furnace slag sample. (Refer to Figure D-92 and
       Table D-227B)
    

    -------
    FIGURE D-96: Large particle B from an electric
       arc furnace slag sample.  (Refer to Table
       D-227A)
    FIGURE D-97: Closeup of large particle B from an
       electric arc furnace slag sample. (Refer to
       Table D-227A)
    

    -------
                      ^p%fKlppr'™        _J J
    FIGURE D-98: Surface particle  B-l which  had  adher-
       ed to large particle B from an electric arc
       furnace slag sample. (Refer to Figure D-96 and
       Table D-227B)
    FIGURE D-99: Surface particle B-2 which had adher-
       ed to large particle B from an electric arc
       furnace slag sample. (Refer to Figure D-96
       and Table D-227B)
    

    -------
    FIGURE D-100: Large particle C from an electric
       arc furnace slag sample. (Refer to Table
       D-227A)
    FIGURE D-101: Large particle D from an electric
       arc furnace slag sample. (Refer to Table
       D-227A)
    

    -------
    FIGURE D-102: Small particle E from an electric
       arc furnace slag sample  (Refer to Table
       D-227C)
    FIGURE D-103: Closeup of small particle E from an
       electric arc furnace slag sample.  (Refer to
       Table D-227C)
    

    -------
    FIGURE D-104: Surface particle E-l which had
       adhered to large particle E from an electric
       arc furnace slag sample. (Refer to Figure
       D-102 and Table D-227D)
    FIGURE D-105: Surface particle E-2 which had
       adhered to large particle E from an electric
       arc furnace slag sample. (Refer to Figure
       D-102 and Table D-227D)
    

    -------
    FIGURE D-106:  Small particle F from an electric
       arc furnace slag sample.   (Refer to Table
       D-227C)
    
                                     isajtow ' ™
    
                                          "iP%
    FIGURE D-107: Closeup of small particle  F  from
       an electric arc furnace slag  sample.   (Refer
       to Table D-227C)
    

    -------
    FIGURE D-108: Surface particle F-l which had
       adhered to large particle F from an electric
       arc furnace slag sample. (Refer to Figure
       D-106 and Table D-227D)
    FIGURE D-109: Surface particle F-2 which had
       adhered to large particle F from an electric
       arc furnace slag sample. (Refer to Figure
       D-106 and Table D-227D)
    

    -------
    FIGURE D-110: Surface particle F-3 which had
       adhered to large particle F from an electric
       arc furnace slag sample.  (Refer to Figure
       D-106 and Table D-227D)
    

    -------
    FIGURE D-lll: Small particles G and H from an
       electric arc furnace slag sample. (Refer to
       Table D-227C)
    FIGURE D-112: Small particle I from an electric
       arc furnace slag sample. (Refer to Table
       D-227C)
    

    -------
    FIGURE D-113: Large particles A, B and C from a
       blast furnace slag sample. (Refer to Table
       D-228A)
    FIGURE D-114: Surface particles A-l, A-2, A-3,
       A-4 and A-5 which had adhered to large parti-
       cle A from a blast furnace slag sample. (Refer
       to Table D-228B)
    

    -------
    FIGURE D-115: Large particles A and B from a basic
       oxygen furnace slag sample. (Refer to Table
       D-229A)
                              jjl   ,.
            ?M 80S SA    910X
    09-20-7?
    FIGURE D-116: Surface particles A-l, A-2, A-3,
       A-4, A-5 and A-6 which had adhered to large
       particle A from a basic oxygen furnace slag
       sample. (Refer to Table D-229B)
    

    -------