EPA/453/R-94/066/B
             United States         Office of Air Quality
             Environmental Protection  Planning and Standards
             Agency            Research Triangle Park, NC 27711
EPA-453/R-94-066-B
    March 1995
             Air
 & EPA
                          STUDY OF
        VOLATILE ORGANIC COMPOUND EMISSIONS
                            FROM
         CONSUMER AND COMMERCIAL PRODUCTS
         Comprehensive  Emissions  Inventory

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                                     EPA-453/R-94-066-B
          REPORT TO CONGRESS
VOLATILE ORGANIC  COMPOUND  EMISSIONS
                    FROM
 CONSUMER AND COMMERCIAL PRODUCTS
                 VOLUME 2

 COMPREHENSIVE EMISSIONS INVENTORY
              Emission Standards Division
         Office of Air Quality Planning and Standards
           U.S. Environmental Protection Agency
         Research Triangle Park, North Carolina 27711
                  December 1994

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                              ACKNOWLEDGEMENT
     This study was completed with a great degree of cooperation and assistance from the
Chemical Specialties Manufacturers Association, the Cosmetic, Toiletry, and Fragrance
Association, the Soap and Detergent Association, the National Aerosol Association, the
Automotive Chemical Manufacturers Council, and the Adhesive and Sealant Council.

     Most of the studies in Section 4 were conducted under the auspices of the EPA's Air
and Energy Environmental Research Laboratory.
                                          u

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                            TABLE  OF CONTENTS

Section                                                                       Page

1.0  INTRODUCTION                                                        1-1

1.1  The Problem                                                              1-1

     1.1.1       Ozone Nonattainment and Small Sources of VOC Emissions           1-1
     1.1.2       VOC' s or NOX -- Which Should We Control?                       1 -1
     1.1.3       Relative Photochemical Reactivity                                 1-2

1.2  Congressional Response:  The Clean Air Act of 1990                           1-3

     1.2.1       Requirements Under §183(e) - Consumer/Commercial Products        1-3
     1.2.2       Scope  of Consumer/Commercial Products Under §183(e)              1-4
     1.2.3       EPA's Study and Report to Congress - Purpose and Structure          1-4

1.3  Inventory of VOC's in Consumer and Commercial Products                      1-5

     1.3.1       Role of the Consumer and Commercial Products Inventory            1-5
     1.3.2       Elements of the Inventory                                        1-6

1.4  Adjustments to Inventory Data                                              1-7

     1.4.1       Fate of Consumer Product VOC's in Wastewater and Landfills        1-8
     1.4.2       Emissions in Nonattainment Areas                                 1-8

1,5  Summary of Findings                                                      1-9

1.6  References                                                               1-13

2.0  CONSUMER PRODUCTS SURVEY                                        2-1

2.1  Background                                                               2-1

     2.1.1       Previous Efforts and the Need for the Survey                        2-1
     2.1.2       Development of the Survey Approach and Format                    2-3
     2.1.3       Features of the Survey                                           2-5
     2.1.4       Other Uses of the Information                                    2-6
                                        111

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                       TABLE OF  CONTENTS  (Continued)

Section                                                                        Page

2.2  Survey Questionnaire and Mailing List                                        2-6

     2.2.1      The Survey Questionnaire                                        2-7
     2.2.2      Electronic Reporting Option                                       2-8
     2.2.3      Development of the Mailing List                                  2-12

2.3  Handling of Survey Responses                                              2-13

     2.3.1      Response Handling and Safeguarding of Confidential Information     2-14
     2.3.2      Data Entry                                                     2-17
     2.3.3      Batch Files                                                     2-24
     2.3.4      SAS  Data Sets                                                  2-27

2.4  Results of the Survey                                                      2-29

     2.4.1      Response Rate                                                  2-30
     2.4.2      Information Obtained from the Survey                             2-31

2.5  References                                                               2-54

3.0  PRODUCTS AFFECTED BY EXISTING OR ONGOING FEDERAL
           REGULATORY  PROGRAMS                                        3-1

3.1  Introduction                                                               3-1

3.2  Category Descriptions and Sources of VOC Emissions                          3-4

     3.2.1      Architectural and Industrial Maintenance Coatings                    3-4
     3.2.2      Automobile Refmishing Products                                   3-5
     3.2.3      Aerospace Coatings                                              3-6
     3.2.4      Wood Furniture Coatings                                         3-6
     3.2.5      Ship  and Boat Coatings                                           3-7
     3.2.6      Metal Furniture Coatings                                         3-7
     3.2.7      Flat Wood Paneling Coatings                                      3-8
     3.2.8      Large Appliance Coatings                                        3-9
     3.2.9      Magnet Wire Coatings                                          3-10
     3.2.10     Metal Can Coatings                                             3-11
     3.2.11     Metal Coil Coatings                                             3-12
     3.2.12     Other Metal Product Coatings                                    3-13
     3.2.13     Auto and Light Truck Assembly Coatings                          3-14

                                        iv

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                       TABLE OF  CONTENTS  (Continued)
      3.2.14     Paper, Film, and Foil Coatings                                    3-16
      3.2.15     Magnetic Tape Coatings                                          3-19
      3.2.16     Business Machine Plastic Parts Coatings                            3-19
      3.2.17     Automotive Plastic Parts Coatings                                 3-20
      3.2.18     Flexible Packaging Printing                                       3-20
      3.2.19     Rotogravure Publication Printing                                  3-21
      3.2.20     Lithographic Printing                                             3-22
      3.2.21     Letterpress Printing                                              3-23
      3.2.22     Tire Manufacturing Cements                                      3-24
      3.2.23     Miscellaneous Industrial Adhesives                                3-25
      3.2.24     Metal Cleaning Solvents                                          3-26
      3.2.25     Industrial Cleanup Solvents                                       3-27
      3.2.26     Petroleum Drycleaning Solvents                                   3-29
      3.2.27     Agricultural Pesticides                                           3-30
      3.2.28     Cutback Asphalt Paving Materials                                 3-31
      3.2.29     Synthetic Fiber Spinning Solvents                                 3-32
      3.2.30     Fabric Coatings                                                 3-34
      3.2.30     Fabric Printing                                                  3-35

3.5   References                                                                 3-35

4.0   PRODUCTS ADDRESSED BY SPECIAL STUDIES                           4-1

4.1   Introduction                                                                  4-1

4.2   Construction Materials                                                         4-1

      4.2.1      Building Materials and Indoor Air Sources                           4-1
      4.2.2      Roofing Materials                                                  4-8
      4.2.3      Asphalt Concrete Paving Materials                                4-14
      4.2.4      References                                                      4-15

4.3   Foods, Beverages, and Tobacco                                              4-17

      4.3.1      Alcoholic Beverages                                             4-17
      4.3.2      Deep Fat Frying                                                 4-19
      4.3.3      Cigarette, Cigar, and Pipe Tobacco                                4-24
      4.3.4      References                                                      4-32

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                       TABLE OF CONTENTS  (Continued)

Section                                                                          Page

4.4  Small Combustion Sources                                                   4-34

     4.4.1      Kerosene Space Heaters                                          4-34
     4.4.2      Camp Stoves and Lanterns                                        4-39
     4.4.3      Fire Starting Materials                                            4-41
     4.4.4      References                                                      4-44

4.5  Miscellaneous Products                                                      4-48

     4.5.1      Mold Release Agents                                             4-48
     4.5.2      Products Used in the Manufacture of Fiberglass Boats                4-51
     4.5.3      Automotive  Repair Parts Washers                                 4-54
     4.5.4      Products Used in the Textile Industry                              4-56
     4.5.5      References                                                      4-70
                                         VI

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                                LIST  OF FIGURES
Figure 2-1       Company Sheet
Figure 2-2       Page One of the Product Sheet
Figure 2-3       Page Two of the Product Sheet
Figure 2-4       Consumer Product Survey Response Handling System
Figure 2-5       Distribution of Survey Questionnaires
 2-9
2-10
2-11
2-15
2-30
                                LIST OF  TABLES
Table 1-1        VOC Emissions from Consumer/Commercial Products                1-10
Table 1-2        Sources of VOC Emissions in 1990 (Nationwide)                    1-13
Table 2-1        Results of the Consumer Products Survey                           2-33
Table 3-1        Emissions from Products Affected by Existing/Ongoing Programs       3-2
Table 4.1-1      Emissions from Products Addressed by Special Studies                4-2
Table 4.2-1      Substantiated Building Material Sources of VOC Emissions            4-5
Table 4.2-2      Emission Factors for Various Building Materials                      4-7
Table 4.2-3      Summary of Roofing Area Worked by Roof Type (1989)             4-12
Table 4.2-4      VOC Emissions from Roofing Application                          4-14
Table 4.3-1      Volatile Compounds Identified in Alcoholic Beverages                4-19
Table 4.3-2      Major Constituents of Mainstream Smoke                           4-28
Table 4.3-3      Estimated Emissions of VOC Constituents of Mainstream Smoke       4-30
Table 4.4-1      Kerosene Heater Characteristics                                    4-34
Table 4.4-2      Average Kerosene Heater  Emission Factors                         4-36
Table 4.4-3      Estimated 1990 Emissions from Kerosene Heaters                    4-38
Table 4.5-1      Emissions from Mold Release Agents by Industry                    4-51
Table 4.5-2      Emissions from Parts Washer Solvents (Garment Screen Printing)      4-66
Table 4.5-3      Platen Adhesive Emissions                                        4-67
Table 4.5-4      Spot Cleaner Emissions (Garment Screen  Printing)                   4-69
                                        VII

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                               1.0  INTRODUCTION
1.1    THE PROBLEM

1.1.1  Ozone Nonattainment and Small Sources of VQC Emissions

       National air quality monitoring data from 1986 through 1988 indicate that there are
approximately  100 geographic areas which failed to attain the national ambient air quality
standards (NAAQS) for ozone.  Ozone is a major component of smog which poses major
health and environmental concerns when present in high concentrations at ground level.  It is
a photochemical oxidant which is formed in the atmosphere through a series of complex
chemical reactions between precursor emissions of volatile organic compounds (VOC's) and
oxides of nitrogen (NOX) in the presence of sunlight.

       While most of the large,  stationary sources of VOC emissions are covered by existing
regulations, an examination of emissions data completed in 1989 by  the Office of Technology
Assessment (OTA) indicates that individually small, dispersed sources of VOC's (area
sources) contribute significantly to  the continuing ozone nonattainment problem.  According
to the OTA report, Catching Our Breath - Next Steps for Reducing Urban Ozone , one area
source of VOC emissions is the use of a wide range of consumer and commercial products.
1.1.2  VOC's or NOX  --  Which Should We Control?
       Ground-level (tropospheric) ozone is formed through a series of complex chemical
reactions involving VOC's and NOX in the presence of sunlight.  Reductions in the amount
of ozone formed can be obtained through reducing the concentrations of VOC and/or NOV
                                                                                X
available for reaction.  A recent report, Rethinking the Ozone Problem in Urban and
                    j
Regional Air Pollution ,  published by the National Research Council explains that a key
factor in reducing ozone  formation is the ratio of VOC to NOY in the ambient air.  When the
                                                       A
VOC-to-NOx ratio is greater than 10:1, VOC reductions have little effect because of the
excess  concentration of VOC's available for reaction.  In such "NOx-limited" scenarios,

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NOX controls may be much more effective than VOC controls alone in reducing ozone
formation.  Conversely, in airsheds which are not NOx-limited, VOC controls can be
effective in reducing ozone formation.

       Although VOC controls alone may offer little reduction in ozone formation under
some conditions, there are many instances in which the VOC-to-NOx  ratio favors VOC
controls. The U.S. Environmental Protection Agency (EPA) does not anticipate
abandonment of efforts to reduce ozone formation through reduction in VOC emissions,
especially in the case of area sources such as consumer and commercial products. However,
this new way of thinking could affect future strategies for stationary and mobile sources for
which NOX and VOC controls could be tailored to specific conditions.

1.1.3  Relative Photochemical Reactivity

       Relative reactivity can be described as the propensity of a VOC species to react in the
presence of NOX and sunlight to form ozone. This phenomenon has been subject to
continuing scientific investigation since well before the mid-1970 's when the EPA adopted its
present  scheme of classifying compounds as reactive or negligibly reactive. Although there
has been much discussion over the years among atmospheric scientists, there has been no
broad acceptance, within either the scientific  or regulatory communities, of any single
reactivity scale which could be used to make reliable predictions of the ozone formation
potential of specific VOC's.  This difficulty arises from the fact that the relative reactivity of
a species is affected by VOC-to-NOx ratios,  the presence of other VOC's, and radiation
conditions.  Each of these factors can vary widely according to the meteorologic and
geographic conditions not only in the immediate airshed but  several days downwind as well.
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1.2    CONGRESSIONAL RESPONSE: THE CLEAN AIR ACT OF 1990

1.2.1  Requirements Under §183(e)  -  Consumer and Commercial Products

       Although control of one small source of VOC emissions may contribute little to
overall ambient air quality, VOC reductions obtained through regulation of multiple small
sources could have a beneficial additive effect. Section  183(e) of the Clean Air Act (CAA)
as amended in 1990 requires the EPA to conduct a study of emissions of VOC's into the
ambient air from consumer and commercial products.  The objectives of the study are (1) to
determine the potential of consumer and commercial product VOC emissions to contribute to
ozone levels which violate the NAAQS for ozone; and (2) to establish criteria for regulating
consumer and commercial products or classes  or categories of products under the authority of
§183(e) of the CAA. In establishing criteria for regulating consumer and commercial
products, the EPA must take into consideration (1) the uses, benefits, and commercial
demand of consumer and  commercial products; (2) any health or safety functions served by
the products; (3) those consumer and commercial products that emit highly reactive VOC's
into the ambient air; (4) those products that are subject to the most cost-effective controls;
and (5) the availability of any  alternatives to such consumer and commercial products that are
of comparable costs, considering health, safety, and environmental Impacts.  On completion
of the study, the EPA must submit a report to Congress  that documents the results of the
study.

       Upon completion of the report, the EPA must list those categories of products which
are determined, based on  the study, to account for at least 80  percent of the total VOC
emissions, on a reactivity-adjusted basis, from consumer and commercial products in areas
which violate the NAAQS for ozone.  The EPA must  divide the list into 4 groups by
priority.  Pursuant to this  requirement, the EPA will publish the prioritized category list in
the Federal Register following submittal of the report  to Congress.  Beginning no later than 2
years following publication of the list, the EPA must regulate one group every two years
until all 4 groups are regulated.
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1.2.2  Scope of Consumer and Commercial Products under S183(e)

       According to the definition in §183(e),  "the term 'consumer or commercial product'
means any substance, product (including paints, coatings, and solvents), or article (including
any container or packaging) held by any person, the use, consumption, storage, disposal,
destruction, or decomposition of which may result in the release of volatile organic
compounds. The term does not include fuels or fuel additives regulated under  section 211,
or motor vehicles, non-road vehicles, and non-road engines as defined under section 216."

       The EPA has determined that the statutory definition of consumer or commercial
product is much broader than just the "traditional" consumer products (e.g., personal care
products, household cleaning products,  household pesticides, etc.).  Instead, consumer and
commercial products include virtually all VOC-emitting products used in the home, by
businesses, by institutions,  and in industrial manufacturing operations. Among these
products are a wide range of surface coatings,  metal cleaning solvents, graphic arts inks,
industrial adhesives, agricultural pesticides, asphalt paving materials,  and many other
products used in industrial  manufacturing processes, many of which have been previously
regulated by the EPA and/or by the States.

1.2.3  EPA's Study and Report to Congress —  Purpose and Structure

       The primary purpose of the study and report to  Congress is to educate the EPA and
Congress on consumer and commercial products as contributors to ozone nonattainment and
to identify opportunities for reduction of VOC  emissions from the use of these products.  In
addition, some information obtained from the EPA studies was used to establish criteria for
regulation of consumer and commercial products and utilized during the process of exercising
the criteria to develop the regulatory agenda.

       In order to prepare the report, the EPA conducted several individual studies. Some
of these studies pertain to specific categories of products for which the EPA has little or no
existing information; five "generic"  studies focus on topics which do  not relate to any
particular category of products.  The 14 individual studies address the following topics:
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(1) inventory of VOC emissions from consumer and commercial products; (2) fate of
consumer and commercial product VOC's in landfills; (3) fate of consumer and commercial
product VOC's in wastewater; (4) aerosol products and packaging systems; (5) economic
incentives to reduce VOC emissions from consumer and commercial products; (6) underarm
antiperspirants and deodorants; (7) hair care products; (8) aerosol spray paints; (9) adhesives
and sealants; (10) household cleaning products; (11) nonagricultural pesticides (including
antimicrobials); (12) automotive aftermarket products; (13) air fresheners; and (14)
architectural and industrial maintenance coatings.

       The report to Congress is comprised of five volumes which document the results of
the generic  studies, plus one volume (the executive summary) which contains (1) a summary
of findings  of the EPA's study of consumer and commercial products; (2) a discussion of
relative photochemical reactivity as it applies to  §183(e);  (3) criteria developed by the EPA
for regulating products under §183(e); and (4) summaries of each of the 14 individual
studies. The six volumes of the report are:

       Volume 1: Executive Summary
       Volume 2: Comprehensive Emissions Inventory
       Volume 3: Fate of Consumer and Commercial Products in Landfills
       Volume 4: Fate of Consumer and Commercial Products in Wastewater
       Volume 5: Economic Incentives to Reduce VOC Emissions from Consumer Products
       Volume 6: Aerosol Products and Packaging Systems
1.3    INVENTORY OF VOC's IN CONSUMER AND COMMERCIAL PRODUCTS

1.3.1  Role of the Consumer and Commercial Products Inventory

       The purpose of the inventory effort was to develop estimates of annual VOC
emissions in ozone nonattainment areas for every consumer and commercial product category
subject to §183(e). These estimates, along with other information,  were used to develop a
prioritized list of categories to be regulated as required by §183(e).  Seven criteria for

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regulating consumer and commercial products have been developed based on the factors
listed in §183(e). Three of these criteria (emissions of highly reactive compounds,
availability of lower-VOC alternatives, and annual VOC emissions) will be evaluated based
on the inventory data.  These criteria are presented in Volume 1 of the Report to Congress.

       The emission estimates and per capita emission factors presented in this report can
also be used by State and local agencies in developing emission inventories for specific mixes
of products and categories within their jurisdiction.

1.3.2  Elements of the Inventory

       Because of the wide variety of products subject to §183(e), emission estimates were
developed independently for three major subdivisions of the universe of consumer and
commercial products.

1.3.2.1       Traditional Consumer Products (including institutional uses)

       These are products which most people associate with the term  "consumer products."
This group includes such products as personal care products, household cleaning products,
household pesticides, automotive maintenance and detailing products, and  many others.
Institutional and commercial uses of these or similar products  are also  considered within the
scope of traditional consumer products.  Emission estimates for these  categories were
obtained through a 1993 census survey of consumer product manufacturers.  This segment of
the inventory is discussed in detail in Section 2.

1.3.2.2       Industrial Products Affected by Existing or Ongoing Regulatory Programs

       The statutory definition of "consumer or commercial product"  is much broader than
just the traditional consumer products and includes virtually all VOC-emitting products used
in the home,  by businesses, by institutions, and in industrial manufacturing operations. This
segment of the consumer and commercial products inventory includes those products which
are used industrially and are affected by existing or ongoing regulations developed by the

                                          1-6

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EPA and/or by the States.  These products include a wide range of surface coatings, metal
cleaning solvents, adhesives, inks, agricultural pesticides, asphalt paving materials, and a
host of others.  Estimates of VOC emissions from these products were obtained from
background documentation developed for the respective regulations or guidance documents.
Emission estimates for previously regulated categories are based on "residual"  emissions
(i.e., emissions which continue after controls have been applied). Estimates for categories
associated with ongoing standards development are 1990 "baseline" emission estimates from
those categories (i.e, emissions before any controls have been applied).  This segment of the
Inventory is discussed in detail in Section 3.

1.3.2.3      Products Addressed by Special Studies

       Many consumer and commercial products fall outside the scope of the consumer
products survey and the categories affected by existing or ongoing regulatory programs.
This third segment of the inventory  is comprised of products which do not fall within the
first two segments.  It includes such products  as foods, beverages,  and tobacco; small
combustion  sources such as kerosene heaters,  camp stoves, artificial fireplace logs, and
commercial explosives; products used in the roofing and textile industries; and a wide range
of miscellaneous products including  but not limited to, mold release agents, automotive parts
washers, and fiberglass boat manufacturing products.  Emission estimates for these products
were obtained through special studies conducted by the EPA.  These studies were limited to
searches of the  literature for relevant scientific investigations in which VOC emissions from
these products were characterized and quantified.  This segment of the inventory is discussed
in detail in Section 4.

1.4    ADJUSTMENTS TO INVENTORY DATA

       In accordance with §183(e), an effort was undertaken to develop estimates  of VOC
emissions from consumer and commercial products in ozone nonattainment areas.  Because
the "raw"  data from the consumer products survey and the other sources were  primarily for
nationwide mass emissions based on the VOC content of the products, the following factors
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were considered in an effort to develop realistic estimates which could be used to satisfy the
requirements of §183(e).

1.4.1   Fate of Consumer Product VQC's in Wastewater and in Landfills

       Historically, inventories of VOC emissions from consumer and commercial products
have been based on the assumption that all VOC's contained in these products eventually
volatilize, enter the ambient air, and are thus available to react to form ozone. However, the
VOC's in some products such as soaps, laundry detergents, household cleaners,
mouthwashes, disinfectants, etc. may be combined with water during and/or following use
and enter the wastewater stream. In order to ensure that the inventory results reflected actual
VOC emissions rather than VOC content, the EPA initiated an investigation to identify
information on the fate of consumer  product VOC's that enter the wastewater stream.  This
topic is discussed  in detail in Volume 4 of the Report to Congress. Based on this
information, and information provided by the major consumer product industry trade
associations 3>4»5>"; final emission estimates for several product categories reported in this
inventory reflect a "percent VOC content emitted" of somewhat less than 100 percent.

       Another area of concern  was  that it may be possible for a portion of the unused
product (and VOC content) to remain in the container packaging following disposal in
landfills.   A study was undertaken by EPA to determine whether some adjustment of the
emission  estimates should be made to account for this phenomenon.  Based on the study,
presented in Volume 3 of the Report to Congress, the EPA determined that, because of the
scarcity of information and the variability of landfill operating procedures, it was not possible
to adjust  the emission  estimates  to account for fate of the VOC's  in landfills. Consequently,
for the purpose of this inventory study, the assumption was made that any remaining VOC
content in the disposed products is eventually emitted to the air.

1.4.2  Emissions  in Nonattainment Areas

       Section 183(e)  primarily  focuses on VOC emissions in ozone nonattainment areas.
Because much of the emissions data  collected reflects nationwide emissions, some adjustment
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was necessary to obtain estimates for nonattainment areas.  Since emissions from traditional
consumer products are roughly proportional to population, the nationwide estimates from the
consumer products survey were scaled down based on the distribution of population in ozone
nonattainment areas.  In 1990,  approximately 148 million of the 248 million persons in the
U.S. resided in ozone nonattainment areas (59.7 percent). Based on this distribution, the
nationwide emission estimates for traditional consumer products were multiplied by a factor
of 0.6 to reflect emissions in nonattainment areas.

      For many categories of industrial products, estimates were developed based on actual
locations of emission sources.  Consequently, nonattainment area emission estimates were
developed for those products directly. For any categories for which specific locations of
emission sources were unknown, the population scaling method discussed above was
employed.

1.5   SUMMARY OF FINDINGS OF THE INVENTORY STUDY

      Based on estimates developed for the many categories of products investigated in this
study, VOC emissions from the use of consumer and commercial products in ozone
nonattainment areas totalled 3,332,145 tons in  1990.  Table 1-1 presents a summary of the
estimates which were developed during this study.  More detail is provided in Sections 2,  3,
and 4.

      Following Table 1-1  is a discussion of the relative contribution of consumer and
commercial products among all sources of man-made VOC emissions nationwide.
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                      TABLE 1-1
VOC  EMISSIONS FROM CONSUMER/COMMERCIAL PRODUCTS
        IN  OZONE NONATTAINMENT AREAS (1990)
Product Category
Traditional Consumer Products
Personal care products
Household products
Automotive aftermarket products
Adhesives and sealants
FIFRA-regulated products
Coatings & related (except AIM)
Other traditional consumer products
Architect & Indust Maint (AIM) Coatings
Industrial Adhesives
Tire manufacturing cements
Platen adhesives (textile industry)
Miscellaneous industrial adhesives
Industrial Solvents
Metal cleaning solvents
Industrial cleanup solvents
Petroleum drycleaning solvents
Synthetic fiber spinning solvents
Textile industry equipment cleaning
Textile industry spot cleaners
Automotive repair - parts washers


174,115
55,095
106,469
45,467
121,464
89,405
5,194


26,400
2,092
201,600

36,000
150,000
54,600
46,200
68
848
2,607
Emissions in
Nonattainment
Areas (tons/yr)
597,209







315,000
230,092



290,323







                        1-10

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                 TABLE 1-1 (Continued)
VOC EMISSIONS FROM CONSUMER/COMMERCIAL PRODUCTS
        IN OZONE NONATTAINMENT AREAS (1990)
Product Category
Industrial Coating Operations
Automobile refinishing products
Aerospace paints and coatings
Wood furniture coatings
Ship and boat coatings
Metal furniture coatings
Flat wood paneling coatings
Large appliance coatings
Magnet wire coatings
Metal can coatings
Metal coil coatings
Other metal product coatings
Auto and light truck assy coatings
Paper, film, and foil coatings
Magnetic tape coatings
Business machine plastic part coatings
Automotive plastic part coatings
Flexible packaging printing
Rotogravure publication printing
Lithographic printing
Letterpress printing
Fabric coating
Fabric printing
Mold release agents


55,000
107,500
60,000
15,100
63,000
20,000
15,600
4,800
45,000
21,600
218,400
75,000
65,000
5,500
5,500
16,500
150,000
20,000
600,000
28,200
21,000
25,200
75,400
Emissions in
Nonattainment
Areas (tons/yr)
1,713,300























                         1-11

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                            TABLE 1-1 (Continued)
       VOC EMISSIONS  FROM CONSUMER/COMMERCIAL PRODUCTS
                IN OZONE  NONATTAINMENT AREAS (1990)
Product Category
Asphalt Paving and Roofing Materials
Cutback asphalt paving materials
Asphalt concrete paving materials
Roofing - built-up
Roofing - elastomeric
Roofing - modified bitumen
Other Consumer/Commercial Products
Fiberglass boat manufacturing
Alcoholic beverage use
Smoking tobacco
Kerosene space heaters
Camp stoves and lanterns
Artificial fireplace logs
Agricultural pesticides

ALL §183(e) CATEGORIES


128,400
360
7,126
9,123
2,276

12,100
11,600
37
39
6
154
15,000


Emissions in
Nonattainment
Areas (tons/yr)
147,285





38,936








3,332,145
      To put the VOC contribution from consumer and commercial products into
perspective, a 1990 estimate of all man-made VOC emissions was derived by modifying an
                   "I
existing 1985 estimate.  The old estimate was modified by grouping all of the emission
sources which fall within the scope of §183(e) and replacing the sum of their individual 1985
estimates with the new estimate developed in this study.  To compare consumer and
commercial products with other large sources of man-made VOC emissions, it was  necessary
                                     1-12

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to modify the estimate developed for nonattainment areas to reflect nationwide emissions
from consumer and commercial products.  Employing the population distribution factor (0.6)

discussed in Section 1.4.2, the nonattainment area estimate (3,332,145 tons/yr) for all
categories under §183(e) was scaled up to a nationwide estimate of about 5,500,000 tons/yr,
or about 26 percent of all man-made VOC emissions.  This scaled-up estimate is rough and
should be used only for this comparison exercise.  The principal source categories and their

respective VOC emission estimates are presented in Table 1-2.
    TABLE 1-2   SOURCES OF VOC  EMISSIONS  IN 1990 (NATIONWIDE)
Emission Source Category
Mobile Sources
Consumer/ Commercial Products
Petroleum Marketing
Fuel Combustion (Stationary Sources)
Forest, Agricultural, and Other Burning
Petroleum Refineries
Organic Chemicals Manufacturing
Industrial Manufacturing
TOTAL FOR ALL SOURCES
Nationwide
Emissions (tons/yr)
7,920,000
5,500,000
2,460,000
2,300,000
990,000
820,000
550,000
400,000
20,940,000
Share of Total
(percent)
37.8
26.3
11.8
11.0
4.7
3.9
2.6
1.9
100.0
1.6   REFERENCES

1.    U.S. Congress, Office of Technology Assessment, Catching our Breath: Next Steps
      for Reducing  Urban Ozone, OTA-O-412, Government Printing Office, Washington,
      D.C., July 1989.

2.    National Research Council, Committee on Tropospheric Ozone Formation and
      Measurement, Rethinking the Ozone Problem in Urban and Regional Air Pollution,
      Washington, D.C., 1991

3.    Letter from D. Fratz, Chemical Specialties Manufacturers Association, to B. Moore,
      U.S. EPA, Office of Air Quality Planning and Standards, Comments on raw survey
      data concerning compounds reported, percent VOC emitted, and market share
      reporting,  March 25, 1994.
                                       1-13

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4.    Letter from J. Graf, Cosmetic, Toiletry, and Fragrance Association, to B. Moore,
      U.S. EPA, Office of Air Quality Planning and Standards, Comments concerning
      survey - percent VOC emitted and market share reporting, May 6,  1994.

5.    Letter from R. Sedlak, Soap and Detergent Association, to B. Moore, U.S. EPA,
      Office of Air Quality Planning and Standards, Comments on percent VOC emitted
      and market share reporting, May 16, 1994.

6.    Letter from R. Sedlak, Soap and Detergent Association, to B. Moore, U.S. EPA,
      Office of Air Quality Planning and Standards, Further comments on percent VOC
      emitted  from laundry and dishwashing products, August 8, 1994.

7.    U.S. EPA, Office of Air Quality Planning and Standards, Research Triangle Park,
      North Carolina, Alternative Control Techniques - Control Techniques for Volatile
      Organic Compound Emissions from Stationary Sources (EPA-453/R-92-018),
      December 1992.
                                        1-14

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                    2.0 CONSUMER  PRODUCTS  SURVEY


2.1   BACKGROUND


      One important segment of the inventory of VOC's from consumer and commercial

products are the "traditional consumer products" described in Section 1.3.2.1.  In order

to develop an accurate, reliable emission estimate for this segment, the EPA and the
consumer products industry undertook a massive effort to assemble accurate formulation

and sales information for over 24,000 individual consumer products.   The following

sections describe the survey process and the results obtained from that effort.


2.1.1  Previous Efforts and the Need for the Survey


      There are four major studies that were previously conducted and are believed to
be the best, publicly available, comprehensive inventories of VOC content in consumer
and commercial products prior to the current effort.  The four studies are listed below:
       1.     Photochemically Reactive Organic Compound Emissions from Consumer
             and Commercial Products, performed by Science Applications International
             Corporation (SAIC) for EPA Region H (EPA-902/4-86-001, November
             1986)

       2.     Compilation and Speciation of National Emissions Factors for
             Consumer/Commercial Solvent Use, performed by SAIC for EPA's Office
             of Air Quality Planning and Standards (EPA-450/2-89-008, April 1989)

       3.     Analysis of Regulatory Alternatives for Controlling Volatile Organic
             Compound (VOC) Emissions from Consumer and Commercial Products in
             the Afew York City Metropolitan Area (NYCMA), performed by Pacific
             Environmental Services,  Inc. (PES)  for the New York State Department of
             Environmental Control (NYDEC) (January 1990)

       4.     Expansion  of the New York Study: Evaluation of VOC Emission Reduction
             Alternatives from Selected Consumer and Commercial Products,  performed
             by PES for EPA's Air and Energy Engineering Research Laboratory
             (February 1990)

       The first three studies are represented as being VOC emissions inventories,

although they are actually inventories of the VOC content of the consumer and

                                      2-1

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commercial products.  The third study identified brands of products sold in the New York
City area. The fourth study compared brands sold in four other cities to those reported
in the third study.  The number of product categories, the geographic coverage, and the
species of interest vary from study to study, due to the different objectives for each
study.

       The formulation data used  in the first two studies are dated.  Many of the
formulations date back to the chlorofluorocarbon  (CFC) propellant era or shortly after the
CFC propellant ban in 1978.  The formulations used in these two studies were also
primarily generic formulas.  The sales data for these two studies are also somewhat old,
dating generally from  1981 to 1985.  The PES study uses  formulation data gathered
directly from manufacturers and distributors and includes individual species.  Both the
formulation and usage data for the PES study  are from 1988.  None of the listed studies
was able to match brand-specific sales data with specific product formulations.  Both the
second SAIC and the two PES studies indicate that some data are available, but that such
data are inadequate to develop the comprehensive emissions inventory required under
§183(e).

       Market share data were not used in developing the typical formulations nor in
apportioning total sales volume  to specific  brands in any of the existing inventories. The
NYDEC study performed by PES contains a great deal of brand-specific formulation
data; however,  these data were  obtained by a  voluntary letter survey of suppliers and
distributors of commercial and institutional product brands in the New York area.  These
brands were rarely the same as  the nationally  marketed  retail consumer brands for which
market share information is available.  Formulation information for  nationally marketed
retail consumer products is, therefore, one of  the main items  missing from previous
inventories.  Market share and total sales volume data for these products are available
from a variety of market research organizations.

       A second area  of concern is the total sales volume  and market share data for
products marketed for commercial and institutional use. The NYDEC study's letter
survey obtained many formulation and sales data for individual products in this  category.

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These data were extrapolated through the assumption that the total market volume was
five times the volume represented in the survey responses because only a 20 percent
response was obtained from the survey. A more defensible extrapolation method must be
implemented to represent the total market volume for commercial and institutional use.
Available market research data appear to address only the retail consumer market.

       Many sources of market share data and sales volume data are available, but the
boundaries of the market represented by the data are not always clear.  It is also very
possible that widely different sales volumes will be reported by different market research
firms.  This is the third major consideration for assessing the accuracy of inventories of
the consumer/commercial products categories.

       None of these existing inventories are adequate for regulatory assessment and
development purposes.  In addition, no adequate speciated inventories exist for any
significant consumer product category.

2.1.2  Development of the Survey Approach and Format — A Cooperative  Effort

       The following discussion summarizes the events that led to  the development of the
Consumer and Commercial Products Survey.

2.1.2.1      Events Prior to the Clean Air Act Amendments of 1990

       In anticipation of the Clean Air Act Amendments, the EPA conducted a
symposium in November 1989  on regulatory approaches for reducing VOC emissions
from the use of consumer products.  The purpose of the symposium was to initiate a
dialogue among the EPA, the States, and industry toward working cooperatively in
addressing this source of emissions.  Approximately 100 companies and trade associations
participated in the symposium.   State environmental agencies from California, Michigan,
New Jersey, New York, North Carolina, Texas, and Virginia were represented as well.
The proceedings of that symposium were documented in an EPA report (EPA-450/3-90-
008, January 1990).
                                       2-3

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       One of the key issues raised by industry representatives at the symposium was the
lack of a reliable, speciated inventory of VOC emissions from traditional consumer
products.  The industry demanded that the EPA employ a census survey of consumer
product manufacturers and distributors to develop such an inventory.

2.1.2.2      Development of the Survey Questionnaire and Approach

       In November of 1990 the EPA and the Cosmetics, Toiletries, and Fragrances
Association (CTFA) met twice with the Chemical Specialties Manufacturers Association
(CSMA) at CSMA's headquarters in Washington, D.C. to discuss the plan for developing
the inventory.  It was suggested that the best approach for a number of consumer product
categories would be through a survey of the manufacturers of those products.
Information for this consumer products survey would be collected by the EPA via
questionnaires  distributed under the authority of Section 114 of the CAA.  This approach
was suggested  by the consumer products industry,  specifically the CSMA.

       Refinements to the survey  approach were made over the next two years by the
work group consisting of EPA,  CSMA, CTFA, the Soap and Detergent Association
(SDA), several other associations, and representatives of several companies (L&F
Products, Sherwin-Williams, Procter  & Gamble, Drackett, Gillette, S.C. Johnson Wax,
United Industries, Aeropres Corporation,  CCL Custom Manufacturing, Helene Curtis,
Inc., and Carter-Wallace, Inc.).  This work group  met on several occasions to develop  a
joint protocol for the consumer products inventory effort.

       In December 1991, the survey questionnaire developed by the work group was
sent to nine test respondents. The responses from  this test were analyzed and the results
presented at the March 1992 meeting of the work group. Revisions to the questionnaire
were made and sent to the  work group members for final endorsement.
                                       2-4

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2.1.2.3      Approval to Conduct the Survey

       It was recognized early in the planning of the survey that, due to the large number
of survey questionnaires necessary, Office of Management and Budget (OMB) approval
would be required through the submission of an information collection request (ICR).
The CSMA offered to endorse the ICR and state that the industry and EPA reached a
consensus that the Section 114 approach is the most suitable vehicle for gathering the
required information.  The ICR was submitted to OMB in July 1992,  and approval was
granted by OMB in December 1992.

2.1.3  Features of the Survey

       The survey focus was to establish a reasonably  accurate inventory of the VOC
content of consumer and  commercial products.  This is the first step necessary to
determine the VOC emissions from these products. Separate studies have been conducted
to estimate the fraction of VOC content emitted to the  atmosphere for various products.

       The product categories included in the survey were selected to ensure the most
comprehensive database possible without  causing an unreasonable economic burden. The
list of product categories  (along with the category codes used with each) are given in
Appendix A, under Attachment A to the survey form (Enclosure 1).

       Listing of individual VOC ingredients (speciation)  was necessary to develop the
most useful, accurate, and reliable data base of VOC content in consumer and
commercial products.  If speciation were  not provided  by  the manufacturers in the course
of the inventory, it would have to be developed or assumed by EPA, and would be
challenged  as inaccurate.  Therefore, the  goal of the survey was to create an accurate
estimate of total VOC for each product category with small ranges of uncertainty for each
species in each category.  Speciation data for each category creates greater flexibility,
allowing the data to be used in a number  of ways:

1.     To perform quality assurance checks on the submitted formulation data.
                                        2-5

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2.     To estimate the fraction of the VOC content which escapes to the ambient ab-
       using the known fate pathways identified in other EPA studies.
3.     To develop hazardous air pollutant and indoor air pollution inventories.
2.1.4  Other Uses of the Information

       The primary use of the survey was to provide the basic information (VOC
content) that was used to develop VOC emission estimates for consumer and commercial
products.

       A secondary use of the inventory could be in the preparation of a national
hazardous air pollutant (HAP) inventory.  The CAA requires the EPA to list major
sources of hazardous air pollutants, including urban area  sources.  Some of the major
HAP's in consumer and commercial products  include methylene chloride, trichloroethane,
toluene, xylene,  and methanol.  Some additional toxic materials are present in smaller
quantities.  These include hexane, ethylene glycol, diethanolamine, chlorobenzene,
methyl ethyl ketone, and methyl isobutyl ketone.  The consumer products portion of the
HAP inventory may be particularly useful for indoor air pollution assessments.

       A third use of the inventory derived from the survey will be to provide per capita
emission factors  for the States to use in State Implementation Plan (SIP) inventories.
Some differences in per capita use of specific products by geographic region or season
may exist, but identification of these variables is beyond  the scope of this study.

2.2    SURVEY QUESTIONNAIRE AND MAILING LIST

       Survey packets were mailed to approximately 3,700 respondents from a mailing
list developed with the assistance of several trade associations.  The survey packets
consisted of a cover letter, the survey questionnaire form (Enclosure  1), a computer
floppy diskette with a computer program that emulated the questionnaire (Enclosure 2),
and supporting documents explaining EPA's regulatory authority and procedures  for
                                        2-6

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protecting confidential business information (Enclosures 3 through 5). Appendix A
contains an example of a survey packet without the accompanying computer diskette.
Appendix B contains the original mailing list.

2.2.1  The Survey Questionnaire

       The purpose of this section is to give an overview of the information requested in
the survey questionnaire.  The survey questionnaire form and instructions explain the
information  being requested and should be referred to for greater detail. The survey
questionnaire consists of two  "sheets", each requesting different information.

       The Company Sheet requests general information on the company and/or division
providing the survey information. The Company Sheet also allows the company to
indicate that the information request does not apply to them either because they do not
produce any of the products listed as included in one of the survey categories (Attachment
A to the  Survey Form) or that they are not identified on the product  label as the  "owner"
of the brand name.  Figure 2-1 shows the Company Sheet.

       The Product Sheet consists of a two-page form that requests product-specific
information.  The information requested includes the Company and Division reporting the
information, the product category code taken from a list of categories listed in
Attachment A to the survey form, the product or product group name, information on
product packaging and sizes, the sales of the product in 1990 (in pounds), the total
amount of reportable VOC (RVOC) in the product (percent of product net weight), a list
of each RVOC  ingredient  (defined in Attachment B of the survey form)  that comprises at
least five percent of the total product weight, the percentages of methylene chloride and
1,1,1-trichloroethane in  the product  (exempt as VOC but of interest as toxic air
pollutants), and which classes of information should be  considered confidential business
information  (CBI).  The list of RVOC ingredients  is requested in  Item 11A on the  survey
questionnaire. If the responding company  did not  have this information, they were
instructed to provide an alternate contact (company) that could provide that information.
This can  occur when a company, such as a large chain store, sells it's brand of a product

                                        2-7

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(e.g., spray paint) that is actually produced and packaged by second firm (e.g., a contract
packager).  Figure 2-2 shows page 1 and Figure 2-3 shows page 2 of the Product Sheet.

2.2.2  Electronic Reporting Option

       The computer version of the survey form consisted of an introductory screen that
appeared at the beginning of the program, two data entry screens emulating the two pages
of the product sheet, and a closing screen used at termination of a session with the
program.  Additional functions allowed the person  using the  software to get context-
specific help (help related to the current data being entered),  to  search the data files for a
specific record (information on a specific product), print the  data in the data files by
either record number or by alphabetical listing by product name, and to create an export
disk for submittal of the entered data. The computer files generated by the software were
designed to be sent on  computer disk instead of on individual paper forms for each
product.  The Company Sheet, however, should have accompanied each submission,
whether on disk or paper.  This was done intentionally to avoid problems when the data
on the disk is unreadable or when questions arise on data that was entered, that a contact
person could be reached.  An  additional reason was to ensure that a signature from a
company employee always accompanied a data submittal.
                                        2-8

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                            FIGURE 2-1  COMPANY  SHEET


1.    Company Name:

      Division Name:

2.    Person to Contact:

3.    Address:

4.    Phone:

5.    Type of Business (mark with "X" for all that apply):
        Manufacturer
Retailer
Distributor
Private Label
                                                                          Custom Contract
                                                   Contract Packager       Packager
6.  Indicate Number of Product Sheets Attached:    	

    or Zero Product Sheets Are Attached Because:

                   This company  does not manufacture,  distribute, or sell  any  of the
                   reportable products listed in Attachment A.
                   This company does manufacture, distribute, or sell some of the reportable
                   products  listed  in  Attachment  A,  but this company is not the party
                   responsible to report because it is not named on the product label.


7.  Certification.   The company  or division officer who is  responsible  for environmental
    compliance or government affairs must sign the certification statement below:

        "I hereby certify that, to the best of my knowledge and belief, all information
        entered on this Company Sheet and any attached Product Sheets is complete
        and accurate."
                       NAME                                           SIGNATURE
                       TITLE                                           DATE SIGNED
                                           2-9

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                  FIGURE  2-2  PAGE  ONE  OF  THE  PRODUCT SHEET
                                                                                     Page 1 of 2
1.      Company Name :
       Division Name :
2.     Product Category Code (see Attachment A):
       Description (from Attachment A and/or additional descriptions):
3.     Product Form :
Aerosol
Spray Pump   I	I  Liquid
  Gel
                              Solid
            Other
4.     Full Product or Product Group Name
5.      If the data on this Product Sheet represent more than  a single Stock Keeping Unit (SKU), enter the
       number of SKU's represented (see instructions on grouping products): 	
6.     Major Customer Type :
        Household
           Comm/lnst
7.     Product Size -by Volume :

        to 55 gal.  I	1  >55 gal.
           or
                       0 to 32 fl.oz.
             -by Weight :
       0 to 1 Ib.
to 5 Ib.
Industrial
                              >32 fl.oz. to 5 gal. I	I >5
                              5 to 20 Ib.
                   >20 Ib.
8.    Net Product Weight sold in the U.S. for 1990 (pounds) :
9.    Total Reportable VOC (weight % of net products):
      Do not include methylene chloride or 1,1,1-trichloroethane in this total.

      If formulation information is not available to your company, go to item 11B.


10. Total Number of Reportable VOC ingredient compounds :	
                                              2-10

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                  FIGURE 2-3   PAGE TWO  OF THE  PRODUCT  SHEET
                                                                                         Page 2 of 2
11 A.    List the largest reportable VOC ingredient compounds and their weight %'s for all reportable VOC that
        are 5% or more of the total net product weight.  Use the criteria listed in Attachment B to determine
        if the compound is an RVOC. Please list these compounds in order of highest to lowest weight percent,
        if possible. Do not report individual components of ingredients which are fragrance materials.
                              Reportable VOC Ingredient Compounds
                                Name
                                                                    CAS No.
                                                                                 Weight % in Final
                                                                                     Product
1.
2.
3.
4.
5.
6.
7.
8.







All Other Reportable VOC








Total Reportable VOC %
(should match item 9)









     Additional information is requested separately for two other compounds: methylene chloride and 1,1,1-trichloroethane.
     Do not include these compounds in total RVOC.

Methylene chloride
1,1,1-tnchloroethane
75-09-2
71-55-6




11B.    Enter name  and address  of company with formulation information if you  do not have the  data to
        complete item 11 A. This requirement does not apply to ingredients which are fragrance materials.
12.
Indicate which items contain Confidential Business Information :
         Sales
              Total RVOC %
Ingredients
Ingredient Wt.  %s
                                              2-11

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2.2.3           Development of the Mailing List

    The mailing list for the survey questionnaires was derived from a number of sources, most
notably CSMA, CTFA, SDA, the Motor Equipment Manufacturers Association (MEMA), the
Adhesives and Sealants Council, and the California Air Resources Board (CARB). There was
a degree of overlap between the lists provided by the various sources, and although methods
were used to eliminate as many duplications as possible, there were some that remained in the
final version of the mailing list.  These became apparent only after responses to the survey were
returned.  There were over 9,000 entries on the mailing list before any deletions of duplicates
were performed.

    The list provided by CSMA included their membership, as well as the list of companies to
whom  they occasionally send promotional material (i.e., potential CSMA members and other
interested parties).  The list provided by CTFA included names listed in two documents that they
publish: CTFA -  Who's Who 1992 (their membership directory) and the Cosmetic Industry ON
CALL 1992, which is put out jointly with the American Academy of Dermatology. The list from
the Adhesives and  Sealants Council was  taken from their membership  directory.   The
membership lists often consisted of sales managers or administrative officers who were not the
best contact person for receiving the survey questionnaire.  In many  cases, addressing survey
packets to these  individuals resulted in delayed responses  and may have reduced the overall
response rate (see  discussion in Section 2.4).  The CTFA "On  Call" list gives the technical
and/or emergency contact person for companies that produce cosmetics  and cosmetic ingredients.
The list from CARB was found to  be the least reliable, with  many companies out-of-business
and/or not responding.  The lists provided by MEMA and SDA were given after the preliminary
list from the other  sources was  compiled and reviewed by them. They then submitted potential
respondents that  were not already included on the list.

    After all contributions  to the survey mailing list were completed,  the list was printed in
alphabetical order to account for obvious duplications.  This reduced the number of listings by
one-half. A second reduction was accomplished by doing a  search of the data file by substrings
(unique parts) of each company's name to look for similarities in  other records of the data file.
Both of these strategies were tempered by not eliminating possible subsidiaries or divisions of

                                         2-12

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the parent  company in  different locations.  This conservative  approach did lead to some
duplication; however, the result was more often justified by the fact that many responses were
received from divisions or subsidiaries which were not included on the mailing list.

    The final mailing list was comprised of 3,610 potential respondents.  After the mailing was
completed,  a number of additional contacts were added to the mailing list through forwarding
of survey packets to companies  that had  moved or been  sold,  and to divisions requesting
additional forms to be sent to other divisions or subsidiary companies.  The final number of
"contacts" included in the mailing list data file is 3,802.

2.3 HANDLING OF SURVEY RESPONSES

    The data collected from the Consumer and Commercial Products Survey were entered into
     ®
dBase  database files either by the  company providing the information or by EPA contractor
                                                                            ®
staff working on the survey project.  The SURVEY software, developed using Clipper  Version
5.0 and provided on the disk enclosed with the survey questionnaire,  was the usual method for
this entry into the data files.  This software was also used by the EPA contractor staff when the
responding  company provided their response via paper forms.  In some cases, the responding
company provided information in a format other than those used  in the database files or hard
copy forms provided with the survey questionnaires; these were handled on a case-by-case basis.
All responses to the survey (either on disk or hard copy) were handled as confidential business
information (CBI) using  a CBI Plan approved by the document control officer (EPA-DCO) in
the Emission Standards Division  (ESD) of the Office of Air  Quality Planning and Standards
(OAQPS), U.S. EPA, Research Triangle Park, North Carolina, and only after a notice of EPA's
need for CBI handling was published in the Federal Register (FR Vol.  58, No. 137, 38758, July
20, 1993).  The CBI plan is presented in Appendix C.

    The discussion in this section covers the methods used to handle an individual response to
the survey.  The discussion includes the following steps in the information flow:

1)  data entry from a hard copy form,
2)  creation of batch files containing response data from several responding companies,

                                        2-13

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3)  quality assurance (QA) checks performed on the batch data,
                             ®
4)  building of an interim SAS  data set,
                                              ®
5)  additional QA checks performed on the SAS data set, and
6)  migration of this data to the final data set used to create the summary data tables presented
    in this report.

2.3.1           Response Handling and Safeguarding of Confidential Business Information

    There were several procedures used in handling responses to the survey that helped assure
protection of CBI as outlined in Appendix C, and for the processing of survey data (Figure 2-4).
When an envelope with a potential response was received, it was held in the CBI-approved file
cabinet until  the Document Control Officer (DCO) could open and log the response into the
system designed for that purpose.  The paper forms (hard copy) of the survey were placed into
a data entry queue while those responses received on diskette were tested for the presence of
viruses and to  assure that the file structure corresponded with those used in  the data entry
program.   All materials contained within an envelope was placed in a CBI file folder for the
responding company and given a CBI log-in number.  If additional submissions were received
for that company and division they were appended to that same file.
    The log-in system was built around the database file used to generate the mailing list. That
file was updated to track responses received, survey forms returned as undeliverable, and the
processing of the data in the survey response.  Upon log-in, CBI cover sheets and a CBI control
record were added to the file.  Hard copy survey responses were keyed into a. separate set of
data files for each file folder,  with the data diskette kept with that file.  Several data entry
personnel performed these tasks simultaneously on separate personal computers (PC's).  Control
of CBI files was maintained  by following the standard CBI handling procedures discussed in
Appendix C.

                                        ®
    All disks with data to be read into SAS  were checked for the presence of viruses and for
proper file structure.  These checks were conducted regardless of whether the data was entered
by the project staff or by the respondent company. This data was then read into batch files for

                                          2-14

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                     Paper Forms
                                            CBl File
Data Entry
 Queue
                                           Batch
                                           Queue
                  DATA ENTRY
                                            5AS
                                           Queue
                                            Hoidino
                                                                BATCH  OPERATIONS
Figure 2-4.     Consumer and Commercial Product Survey Response handling system.


more efficient transfer of the data into SAS  , and more effective quality assurance.


    Below is an outline of the responsibilities of the various project staff in handling of the
survey responses and the data derived from those responses.  A more detailed discussion  is
presented later.
                                         2-15

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2.3.1.1         Document Control Officer (DCO)

    The Document  Control  Officer  was responsible  for  the envelopes containing  survey
responses from the time they arrived until they were archived  at the end of the project.  The
DCO opened the  envelope with a response  and performed  the log-in using the software
developed for that  purpose.  These responsibilities included the following:

1)  Update the file based on the information on the respondent's Company Sheet;
2)  Enter the Postmark date on the envelope;
3)  Enter the date the envelope was received;
4)  Assign a CBI  Control Number to  the file and either attach  that number to the disk or to a
    blank disk added to the file;
5)  Set up a file for the response and  all materials associated with that response;
6)  Place the file into the proper queue (Data  Entry, Batch,  or Holding) in the file cabinet or
    give to the data review person for determination on anomalous submissions; and        J
    date a file moves from one queue to the next.
Responses were not processed  unless all the above steps could be completed in that same day.
The DCO assured that the responses being handled by data entry  were secured (filed and locked)
daily, and that the  CBI Log was updated.

2.3.1.2         Data Entry

    There were a  number of data entry  personnel working at any one time.  When a file was
checked out from the data entry queue, the data entry person was required to sign the control
record for that file and leave it with the DCO. After completing the data entry, the file was
returned with the data diskette to the DCO for  filing in the "batch" queue.

2.3.1.3         Batch Operator

    The Batch Operator's duties included checking the format and contents of all data on disks
                                                      ®
to ensure that it met the requirements for entry to the SAS  data set. Disks were checked-out

                                         2-16

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from the DCO with the entire file. If any anomalies on the disk were noted that could not be
rectified immediately, the file and disk were returned to the DCO to be stored in the batch queue
until the problem could be resolved.  After work with a disk was complete, the file and disk
were returned to the DCO and filed under "Holding." The diskette containing the batch files
                   ®
was held in the SAS queue.

2.3.1.4          SAS  Operator

    The responsibilities of the SAS  Operator were to  maintain  the SAS data  sets, generate
reports, ensure that the information in the data sets passed QA checks, and perform any analyses
as directed. There  were  a number of tasks that this person was required to perform that was
dictated by the  nature of the responses received.  The primary data handling function of this
                                              ®
person was the  reading of batch files  into the SAS  data sets.

2.3.1.5         Data  Reviewer

    The task of data review was  conducted by the project manager and  a data entry person.
Any disks that contained  a virus were investigated to determine if an uncontaminated disk or
other version of the data could be acquired.  Data formats other than those constructed for the
project were viewed using various software to determine if it could be read into the data files
or in some other way used in the project.  Additional review and/or revisions to the data entered
into batches was conducted if there were problems identified by the SAS Operator.

2.3.2           Data Entry

    As mentioned previously, the data entry  step was performed either by the responding
company where they provided data via computer diskette, or by the EPA contractor staff when
the responding  company  provided data via  hard copy form.  In  cases where the responding
company provided a response by  some alternate format (flat ASCII files,  other data formats,
etc.), every attempt was made to enter the data into the proper format. Sometimes, however,
the data was unusable and the file was never entered into the final data set.  The following
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discussion covers the data entry step, including the automated QA checks performed by the data
entry program.

    The data entry program was included along with the required data files in a self-extracting
file on a 360 kilobyte double-sided, double-density 5.25 inch diskette. This format was used so
                                        ®
that a responding  company  with  any IBM  compatible, personal  computer could use the
software.  A company unable to use that format was requested to call the Survey technical
support  line for assistance in  acquiring another disk. When the INSTALL batch file (included
on the Survey diskette) was executed, it created a directory on the computer's hard drive called
"SURVEY," extracted all the files needed from the floppy disk, and copied these files onto the
hard disk in the SURVEY directory.  At that point the software was ready for use.

    The software was designed to gather the information from the PRODUCT SHEETS of the
survey questionnaire (Appendix A).  The information from the COMPANY SHEET was not
included as part of the electronic data gathering to ensure that a signed, hard  copy  form was
returned, which gave authentication to the data submittal and a method to contact the respondent
if the data on a data disk was unreadable. Appendix D presents the data dictionaries for the data
files used by the Survey software.

    Each data item asked for in the Survey software is presented below  along with a discussion
of validity checks performed internally by the software  for that item.  These  validity checks
allow only a certain range of possible entries to be allowed. Many data items were mandatory
and trying to  skip over that item or leave a value at zero would not be  allowed by the validity
checks.

2.3.2.1          Company Name and Division Name

    Company Name information was mandatory and the program would not progress to the next
data entry item nor to the second page of the data entry screen unless some entry was made for
the Company  Name. The Division Name was not mandatory but was requested in the event that
one company would be providing information for many divisions, either in one submittal or by
separate submittals from each division.  The information in these two fields,  along with the

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Product Name and Product Form information, were included in the indexes used with the data
files,  and in the linkages  between the three data files used for storing the  survey data (the
Product file, the RVOC Ingredient file, and the Alternate Contact file).

    The Company Name  and Division  Name entered  in the first record were held in the
computer memory and automatically entered when a second record was added to the data files.
This process was continuous, whereby the Company Name and Division Name for the third
record was automatically entered from the information in the second record.  In this way, any
change to these fields resulted in the "new" company and division names being read into records
subsequently added to the data files.

2.3.2.2         Product Category Code

    The Category  Code was limited to those valid codes listed in Attachment A to the survey
questionnaire (Appendix A).  The Survey software read this information into an array hi the
computer memory.   Any  entries attempted in this field were checked  against the array for
validity.  If the data entry person attempted to enter blanks or an  invalid code, the software
presented a series of pop-up menus that allowed a correct category name and code to be chosen
and entered into Product  file.  Categories  were added to the list based on the information
available to estimate the market  share of the responding companies,  and upon the nature of the
responses collected from the survey.  A discussion of these revisions to the list of categories is
included in Section 4.

2.3.2.3         Product Form

    There were six valid options for entry as the Product Form: "A" for  Aerosols, "P" for
Spray Pump,  "L" for Liquid, "G" for Gel,  "S" for Solid, or  "O" for Other.   In the software
version, this was the entry of the appropriate letter while on the hard copy form check-off boxes
were used. If "Other" was chosen, the data entry person was asked to provide a more detailed
description of the product form.
                                         2-19

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2.3.2.4         Full Product or Product Group Name

    This item was intended to be a unique entry so that no other product could have the same
Company  Name, Division Name,  Product Form, and Product Name.  The check for a valid
entry involved first reading the information for all of the items listed above in the Product file
at start-up into an array in the computer memory; then checking an attempted entry against that
array.  As new products were entered, the information was added to the array. If the validity
check was passed, the Product Name was entered into the Product file.  If the name was edited,
any records linked  to that Product Name in the RVOC Ingredient file or the Alternate Contact
file, and in the validity check array were also changed.  Blanks were not allowed for the Product
Name.

    Companies were  allowed to  group information for a number of products with similar
formulations into one product sheet/record.  The stipulations for grouping products were that the
products all had to be in the  same category (have the same four-digit category code), have the
same product form, and not differ  by more than five percent in total RVOC.  This was done to
reduce the number of separate product sheets a company would need  to submit and thereby
reduce the overall burden of reporting.

2.3.2.5         Stock Keeping Units (SKU's)

    Stock Keeping Units were used as  a barometer of how  many package sizes and grouped
products would be  represented by  any product sheet.  The data entry person was instructed to
enter the number of SKU's represented for the product sheet. It was suggested  by the trade
associations as being a useful and easily identifiable number for responding companies.  This
information was not mandatory. The default value was one.

2.3.2.6         Major  Customer Type

    The data entry person was  instructed  to check off all customer types that applied  to the
listed product or product group.  The purpose of the question was to determine if the product
or products  being  used  by any one group had differences  in formulation  that would  affect

                                         2-20

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emissions of VOC's.  This information will be useful to EPA in future determinations of
effective regulation of individual product categories.  The software presented this question as
a series of logical (Yes/No) choices; the hard copy form presented check-off boxes. No choices
in this set of logical fields were required.

2.3.2.7          Product Size

    The data entry person had the opportunity to answer yes or no to a set of product size
ranges in a manner similar to  how Item 6 above was done.  There was an additional choice,
however, where the data entry person could change from weight ranges to volume ranges by
pressing  the < Alt> and  keys simultaneously, which changed the value in the Product
file. Both sets of ranges were presented as check-off boxes on the hard copy form. No choices
for size ranges were required by the software.

2.3.2.8          Net Product  Weight Sold in the U.S. for 1990 (Pounds)

    The net product weight sold in the U.S. for 1990 (Item 8) was a required entry.  The data
entry person was instructed to  enter the total number of pounds of the product sold in the U.S.
for the year 1990.  The responding companies were given the option to use a fiscal year with
the stipulation that the fiscal year cover the major portion of calendar year 1990. In many cases,
the responding  companies  requested using a  more recent year because the data were more
accessible.  This  was allowed  as long as the responding company documented any divergence
from the survey  instructions or any  adjustments made to the data in a cover letter.

2.3.2.9          Total Reportable VOC

    The total reportable VOC  percent (Item 9) was the first data item requested in the  second
page of the data entry screens  in the Survey software,  although on the hard copy form  Item 9
and Item 10 were found on the first page.  The data entry person was prompted to answer yes
or no as to whether they had formulation data for the product before any information was
requested for the second data entry screen.  If the answer to this logical question was yes, the
second data entry screen presented  requests for Item 11 A; if the answer was no, the  screen

                                         2-21

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requested information for Item 1 IB. Regardless of the response to this query, Items 9, 10 and
12  were requested;  however, requests  for Item  11A  and 11B information  were mutually
exclusive.

    The responding  company was instructed  to evaluate the list of ingredients for products
containing RVOC, as defined in Attachment B to the survey questionnaire (Appendix A), and
enter the total weight percent that those ingredients  represented. The instructions for the survey
questionnaire requested that individual ingredients  be listed in Item  11A for those comprising
five percent or greater of the total product weight.  This total should have included all RVOC
ingredients and not only those that were greater than five percent and required to be listed in
Item 11 A.  A zero entry was allowed in this field.

2.3.2.10        Total Number of VOC Ingredient Compounds

    The intention of this data item was for the  responding company to provide the total number
of ingredients they have identified as RVOC, regardless of the percent weight that any individual
ingredient may have.  The entry in this item should have included all RVOC that comprised the
total RVOC entered in Item 9 and not only those to be listed individually in 11 A.  A zero was
allowed if the total RVOC percent entered in Item 9 was zero, and/or no items were previously
entered in Item 11 A.

2.3.2.11        List of RVOC Ingredients or Alternate Contact

    Two options were available for the responding company to answer Item 11: the first was
to give the list of all RVOC ingredients that comprise five percent or more of the final product
weight, and the second was to give an alternate contact company that could provide the RVOC
ingredient list.  The first option was available  as Item 11A and the second as Item 11B on the
Survey questionnaire. These options were both shown on the hard copy form but were mutually
exclusive in the Survey software.  The only exception to this exclusivity were the requests for
information on methylene chloride (MeCl) and 1,1,1-tricnloroethane (TCA).  The request for
what information was done as described  for Item 9 in Section 2.3.2.9 above.
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    An array was created in the computer's memory after a response to Item 10 was registered
for storing RVOC ingredient information.  After the entry of RVOC ingredients was complete,
the data  was  transferred  as  separate records  in the  RVOC Ingredient file for individual
ingredients.   If data was previously entered in the RVOC Ingredient file for the current
Company/Division/Product/Form combination,  that information was read into the array  for
editing and replaced afterward. Internal QA checks on the ingredient array included confirming
that the number of ingredients listed did not exceed the number entered in Item 10, and that the
total RVOC percent in the ingredient list did not exceed the value reported in Item 9.  If either
of these checks were failed, the data entry person was prompted to either change the entries to
the ingredient list, or to Item 9 or Item 10 as appropriate.  Another QA check was to determine
the average weight percent of the remaining unlisted ingredients (average of "Other").  This
check was performed as described in the formula below:

       Average "Other" RVOC  -     (Item 9 Entry  ~  Total RVOC Usted)
                                   (Item 10 Entry  -  Number of RVOC Listed)


    Until the QA checks were passed, data entry was halted at the RVOC ingredient list.  The
entries for MeCl and TCA were not included in the RVOC ingredient list,  however,  the QA
checks were failed if values for these items plus those for the RVOC list were greater than 100
percent.

    If the information for an alternate contact was being entered, the information was stored in
a discrete  record  in  the Alternate  Contact  file for the Company/Division/Product/Form
combination from the Product file.   The request for MeCl and TCA information was  also
included if Item 11B information was being entered.

2.3.2.12         Claims of Confidentiality

    Confidentiality claims could be made in four logical fields that were synonymous with the
check-off boxes  in  the Survey  questionnaire: claiming sales, the total  RVOC percent,  the
ingredient list, and/or the ingredient weight percents as Confidential Business Information. This
                                         2-23

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information was not required by any validity checks.   This information was included at the
request of OMB, even though all responses to the survey were to be treated as confidential.

2.3.3           Batch Files

    Data for single companies were provided on  separate diskettes either by the responding
company or through entry of the data from paper forms by the EPA contractor staff.  These
diskettes were held in CBI files with all other materials sent with the data submissions.  The
large number of diskettes, some listing only a few products were then combined with the data
from several other companies into "batch" files so that QA analysis could be performed more
                                           ®
effectively, the data could be read into the SAS data set more efficiently, and the original data
files would remain unchanged.  The following discussion gives the details of how the batch files
were compiled, the procedures for performing QA analysis, the procedures for changing the data
failing the QA analysis, and how those changes were documented.  The discussion of how the
                              ®
data were transferred to the SAS  data sets is  presented in Section 2.3.4.

2.3.3.1          Compilation of Batch Files

    As  mentioned above, the data  from the  three data files for individual companies were
combined into similar files that contained data for several companies.  There were two additional
fields added to these batch files that contained the disk identification number (DISK_ID) and the
identification number for the batch (BATCHJGD). Disk numbers were assigned to data diskettes
at the time the survey responses were opened and logged into the CBI tracking system used for
the project (detailed in the CBI Plan in Appendix C). Batch numbers  were assigned sequentially
through the software that read individual data diskettes into the batch  files. The batch files were
named such that the batch number was incorporated into the batch file name.  Product file data
from the individual data disks was read into the PROnnn.DBF file, where nnn refers to the batch
number.  In a similar manner, the data from the RVOC Ingredient  file and Alternate Contact
file were read into the RVOnnn.DBF and PROnnn.DBF files, respectively.

    Two checks were performed on  the data diskettes, however, before any data was read into
batch files.  The first data check was for the presence of computer viruses, and the second was

                                         2-24

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a check for readability and proper file format. Many companies submitted data in a format other
than the dBase  format provided for use with the Survey software, which would cause problems
when attempting to read the file into a batch.  If a problem occurred during the generation of
a batch and the batch files were unusable, that batch number was abandoned and the diskette that
caused the problems was reviewed and revised.  Revisions were performed on copies of the
original data diskettes that were kept unchanged in the file for that data submission.

     Batches were created by reading the data files from individual CBI file folders, all from the
same type of disk (either 3.5"  or 5.25") onto a disk of the other size. This avoided writing  data
to the hard drive of the computer running the batch creation software, and the need to then erase
that file from the hard drive and/or lock-up the computer. The disks containing the batch files
could then be stored along with the other CBI file folders as specified in the CBI plan (Appendix
C).  The data read into a batch was not ordered in any way other than availability at the time
that the batch was being created.

2.3.3.2          Quality Assurance Checks for Batch Files

                                                   ®
     After the data was transferred to batch files, a dBase   program (QA_RVOC) was executed
that performed some of the QA and validity checks used in the data entry program and wrote
exceptions to a series of text files for later review.  This program performed six checks on the
data in the Product file and the RVOC Ingredient file:

1)  If the category code was  missing in the Product file;
2)  If there were any duplications for a Company/Division/Product/Form in the Product file;
3)  If there were  no matching records in the RVOC Ingredient file for records  found in the
    Product file;
4)  If the RVOC percent listed in the Product file matched the total RVOC for all ingredients
    listed in the RVOC Ingredient file for that Company/Division/Product/Form combination;
5)  That the pounds sold in 1990 listed in the Product file was greater than 1; and
6)  If there were records in the RVOC Ingredient file with no match in the Product file.
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    If problems requiring revisions to the data in the batch files were found, the original batch
was not edited directly.  A new batch number was assigned by adding 1000 to the original batch
number and the files (PROnnn, RVOnnn, and ALTnnn) were copied to a new diskette with the
new batch number incorporated into the file name. Therefore, if the original batch number was
54, the original product data for the batch was contained in the PRO54.DBF file; and the batch
file that was created for revisions to the data was PRO1054.DBF, with a batch number of 1054.
If additional revisions to the data were determined to be necessary, the next cycle of revisions
would be found in the 2054 batch file. Whenever a change to a particular record was made, it
was documented on a form that was filed with the other documents in the CBI file for that
companies data submission, in the log book used to track the creation of batches, and in a data
review log book.   This redundancy allows the tracking of all changes to the data if ever an audit
of data from a particular company  or product needs to be performed in the future.

2.3.3.3          Revisions to Batch files

                       ®
    Two additional dBase  programs were written to correct the most common errors found in
the batch files.  These programs were executed on the "1000"  series of batches because they
performed some automated additions, deletions, and revisions to data in the batch  files.  These
programs documented these changes  in reports particular to the program  being executed.

    The first  program (DUP_RVOC) marked any duplicated records for deletion in the RVOC
ingredient file (RVOnnnn.DBF) for a particular Company/Division/Product/Form combination
when  the ingredient name was identical for a second record.  This type of error seemed to be
an artifact of incomplete deletion  of records  if the data entry  person made additions and/or
deletions to the list of RVOC ingredients in Item 11A in  the SURVEY software.  The records
marked for deletion were not removed permanently from the data file until after the person
performing the data review had checked the data file and verified that deletion was indeed
warranted.

    The second program (FIX_MISS) was written to add missing RVOC ingredient records to
the RVOnnnn.DBF file if none existed for a record found in the PROnnn.DBF file.  The first
step was  to determine the average RVOC percent by dividing the total RVOC percent in the

                                        2-26

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RVOC field by the number of RVOC ingredients as entered in the PROnnnn.DBF file for the
Company /Division/Product/Form combination. If that value was less than five percent, a record
in the RVOnnnn.DBF file was created with the  appropriate Company/Division/Product/Form
data entered, "Other" listed as the ingredient name, 0 as the RVOC Number (Appendix D) and
the total RVOC from the Product file entered as  the RVOC percent.  If the average value was
greater than five percent, two records were added for the Company/Division/Product/Form listed
in the Product file, one that listed "Other" as the  ingredient name with 0 as the RVOC percent,
and the second listed as "Unknown" with the total RVOC percent from the Product file entered
as the RVOC percent.

     Additional revisions to the batch were performed by the person performing the data review
as needed and based on the reports generated by the QA_RVOC program. These changes were
documented on standardized sheets, one for each disk number,  so that these error sheets could
be filed with the other original information for the  data submission.

2.3.4           SAS  Data Sets

                                                            ®
     There were three steps involved in the development of the SAS  data sets used to generate
the table  presented in Section  2.4. The first step involved the reading of the data in the batch
files into a temporary data set and performing rudimentary, automated QA analysis on the data
from that batch.  The second step involved the appending of the data in the temporary data set
into a set of "validation" files upon which additional QA was performed. Data  were read into
the final  master data set after  passing all validation checks and were analyzed with the results
used to create the table shown in Section 2.4. No revisions to the data were performed on the
master data sets. The discussion below gives additional detail on these three steps.

2.3.4.1          Reading  of Batch Files

            ®
    The  SAS  data sets were created from the batch files that were compiled as  described  in
Section 2.3.3 above.  As batch files became available, they were read individually into a set  of
temporary data sets, where a number of QA checks were performed and had to be passed before
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the data for the batch were added to a validation file.  The QA  checks performed on the

temporary data sets included those listed below.


1)  Uniqueness

    •           only one product record for a combination of

                                   Company
                                   Division
                                   Product Name
                                   Product Form

    •           only one RVOC record per product (as defined above) with a unique RVOC
                number

    •           only one alternate contact per product (as defined above)

2)  Checks of entered CAS registry numbers in the RVOC Ingredient file for validity.

3)  Checks that the Product Form entry is valid: either A, P, L, G, S, or O.

4)  Checks for a valid Category Code as specified in the Survey.

5)  Checks for a valid record in the Product file for each listed RVOC ingredient in the RVOC
    file.

6)  Check for a mandatory RVOC record when the number of RVOC ingredients is greater than
    zero, the average RVOC percent  is greater than five, and there is no Alternate record for
    the product.

7)  Check that the total RVOC percent listed in the RVOC list for a product matches the RVOC
    percent entered in the Product file.


    Whenever a problem with a batch was encountered that did not allow it to be read into the
    ®
SAS  data sets, the batch was revised by the data review person as a "1000" series batch as
                                                             ®
previously described. After the data from a batch was read into SAS , the diskette holding that
                                                                                    ®
batch data was filed in holding along with all the original data submission files.  All the SAS
                                ®
data sets were stored on a Bernoulli disk drive (a high capacity, removable storage media) that

was removed from the computer running SAS  for OS/2 , and placed in a locked CBI file

cabinet when not in use.
                                        2-28

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2.3.4.2         Validation Data Sets

    There were three validation files used, one for each of the three data files used in the
Survey software and batch files: PRVALID for the Product data, RWALID for the RVOC
ingredient data, and ALVALID for the Alternate contact data. The validation files were created
to have various QA checks performed upon them.  Their contents were compared to those of
batch files being read into the temporary data sets previously described.  These comparisons
                                                  ®
ensured that no duplicated data were read into the SAS  data sets.

    When revisions to the data in a batch file were required after the batch data was read into
a validation file, the 1000 series batch file was generated by the data review person,  the SAS
operator erased the old batch data, and appended the 1000 series batch data to the validation file.
If this process were repeated, the second revision to the batch would be in the "2000"  series,
and that data would replace the 1000 series data in the data sets.  Simple editorial changes to
                                                    ®
data were performed,  when feasible, directly on the SAS  data sets and documented.

2.3.4.3         Master Data Sets

    All revisions were conducted on the batch files and validation files.  After all QA tests were
satisfactorily passed and the data were believed to be valid, the master data sets were created.
No revisions  or editorial changes were enacted upon the master data sets.  The analyses used
to create  the table shown  in Section 2.4 were performed on the master data sets.

2.4 RESULTS OF THE SURVEY

    An overview of the response rate to the survey and a summary of the survey responses are
discussed in the following section.   The total number of questionnaires mailed was  3,610;
however, a  number  of companies had  responses from more than one division and some
companies forwarded  copies  to companies that were not on the original mailing list.  These
additional sources of survey responses brought the total number of questionnaires being tracked
to 3,802.
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2.4.1           Response Rate

    The response  rate is illustrated graphically in Figure 2-5.  Out  of the  3,802 survey
questionnaires accounted for in the tracking system, only 1,283 questionnaires (approximately
one-third) are included in the No Response category.  An additional 352 (9.3 percent) were
returned as undeliverable by the U.S. Postal Service. Approximately one-quarter of the survey
questionnaires were responded to by the company indicating that they  did not manufacture,
distribute, or sell any  of the products found in one of the product categories (Company Sheet
Only).  Responses  via either product sheets or data diskettes were provided by the remaining
companies.  Thirty responses (0.8 percent) were obviously inappropriate and could not be used
in the survey without lengthy follow-up.  The remaining responses were complete with product
information.  An additional 35 completed responses were provided for a company by a third
party  (e.g.,consulting  firm, custom  packager, etc.). There were, therefore,  1,173  complete
responses  (including product formulation data) from companies  manufacturing consumer  and
commercial products.
                                                              Response
                                       ^                   | by  A 11ernate
                     I Co   Sheet  On Iv
                           964        /                    /     D 9%
                           25 4%
                                     / Va i id  Response
                                   Figure 2-5.      Distribution of survey
questionnaires
                                         2-30

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    Not all of the 1,173 complete responses, however, could be used in the final analysis.  A
number of problems were encountered when the information was attempted to be entered into
the data entry system from both hard copy product sheets and data diskette submissions.  In all
cases, attempts were made to contact the company  when problems were identified, but these
attempts were not always successful.  In many cases, information vital to the project was not
provided,  such  as the pounds of product sold in 1990.  In a number of other cases, products
were  inappropriately  grouped (i.e., products from more than one category were reported
together).   These problems and a number of others were not resolved and 96 such responses
were not included in the final data set.  Therefore,  the final data set included 1,077 complete
responses.

2.4.2           Information Obtained from the Survey

    The compiled survey data are presented in  several ways.  The following sections describe
the outputs of the survey which have been generated to date.  Other analyses of the data may
be generated by the EPA as the need arises.

2.4.2.1           Total RVOC Emissions by  Individual Product Category

    The primary purpose of the survey was to develop 1990 estimates of VOC emissions from
traditional consumer  products, including commercial and institutional  uses.   Table 2-1, the
principal output of the  survey,  presents RVOC emission  data for each product  category
surveyed.   Specifically, this table provides  information for  each category on (1) number of
products reported; (2) product sales reported  (tons); (3) RVOC content reported (tons); (4)
estimated market  coverage (i.e. what percentage of the market for a particular category was
captured by the survey); (5)  adjusted product sales (reported sales scaled up based on market
coverage); (6) adjusted RVOC content (reported content scaled  up based on market coverage);
(7) RVOC content emitted (i.e., the percentage of the product's RVOC content which enters the
ambient air after fate adjustments); (8) tons of RVOC emitted nationwide; (9) pounds of RVOC
emitted per 10,000 persons; and (10) RVOC emissions in ozone nonattainment areas (tons).
                                        2-31

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    Items 1, 2, and 3 were obtained directly  from the survey responses.   Item 4 (market
coverage) was estimated based on information furnished by CSMA,  CTFA, and SDA following
their reviews of the initial results of the survey  and lists of companies responding in each
        19^
category 1'Z>J.  Adjusted product sales (item 5) and adjusted RVOC content (item  6) were
obtained by dividing  reported sales and reported RVOC content by the estimated market
coverage percentage.   The adjustments were made in the following manner:
                                                =  AdjustedTonnage
                   Estimated Market Coverage
    Percent RVOC emitted was obtained by multiplying the RVOC content by a fate adjustment
factor.  The  adjustment  factor ranged from  1  percent to  100 percent and was based  on
information supplied by CSMA, CTFA, and SDA*'^'"''  ' .  The fate adjustments were made
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than being emitted to the air.  A fate adjustment factor of 100 percent means that all the RVOC
content of the product is emitted to the air. Conversely, an  adjustment factor of 1 means that
only 1 percent of the RVOC's are emitted.

    Probably the most useful of the items  in Table 2-1 are items 9 and 10. Data on emissions
in ozone nonattainment areas will be used by the EPA in determining which categories will be
targeted for regulation under §183(e).  The per capita emission factors (in this case, pounds of
RVOC emitted per 10,000 persons)  will enable the  EPA,  States, and local environmental
agencies  to develop  emission  estimates  for  specific  combinations  of products based  on
population.  This is by far the most comprehensive and accurate set of emission factors ever
developed for consumer products.
                                        2-32

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2.4.2.2         Distribution of Products of Various VOC Contents within Categories

    In order for the EPA to assess the availability of lower-VOC alternatives, histograms were
prepared for individual product categories which show the distribution of market share (by tons
of product sold) at various levels of VOC content.  On these histograms, tons of product sold
is plotted against RVOC content levels in 5 percent increments.  By examining the histograms,
the EPA can identify the distribution of high-VOC and low-VOC products and can use this
information to assess the possible emission reductions which could be obtained from a given
VOC limit.  This information can also enable the EPA to determine (for a given category) to
what extent lower-VOC alternatives are accepted by consumers.

    In addition to the histograms  discussed above, graphs were prepared for each product
category which present the cumulative tons of product sold versus the percent of RVOC content.
Because of space limitations, these histograms and graphs are not presented in this report but
can be used in the regulatory phase.

2.4.2.4         Formulations of Consumer Products

    Another useful output of the survey is a compilation of formulations for every product
reported. Except in the confidential files of survey responses, the formulations are not identified
by  product brand name or manufacturer.  To further protect  the  confidentiality  of  the
formulation data, the products are presented in descending order of RVOC content within each
category. This compilation is quite voluminous; for example, there were over 1,100 individual
formulations of aerosol spray paints reported.  Consequently,  these formulations could not be
included in this report, but can be used during the regulatory phase.

2.4.2.4         RVOC Ingredients of Consumer Products

    Another important output of the survey is information  on individual chemical species
contained in consumer products. This information will allow the EPA to identify those products
                                         2-53

-------
which contain highly reactive compounds and/or compounds which are considered  to  be
hazardous air pollutants.


    Although methylene chloride and 1,1,1 trichloroethane are not defined as VOC's by the
EPA, these compounds are of interest to the EPA.  Therefore, respondents to the survey were
required to report the amounts of these  compounds used as ingredients in their products.
However, these compounds were not counted as RVOC's, and Table 2-1 does not present them
as RVOC emissions.


    Due to the large volume, information on specific ingredients is not included in this report.
1.  Letter from D. Fratz, Chemical Specialties Manufacturers Association, to B. Moore, U.S.
    EPA, Office  of Air Quality Planning  and Standards, Comments on  raw survey data
    concerning compounds reported, percent VOC emitted, and market share reporting, March
    25, 1994.

2.  Letter from J. Graf, Cosmetic, Toiletry, and Fragrance Association, to B. Moore, U.S.
    EPA, Office of Air Quality Planning and Standards, Comments concerning percent VOC
    emitted and market share reporting, May 6, 1994.

3.  Letter from R. Sedlak, Soap and Detergent Association, to B. Moore, U.S. EPA,  Office
    of Air Quality Planning and Standards,  Comments on percent VOC emitted  and market
    share reporting, May 16, 1994.

4.  Letter from D. Fratz, Chemical Specialties Manufacturers Association, to B. Moore, U.S.
    EPA, Office  of  Air Quality  Planning  and  Standards,  Further comments  concerning
    compounds reported and percent VOC emitted, June 27, 1994.

5.  Letter from R. Sedlak, Soap and Detergent Association, to B. Moore, U.S. EPA,  Office
    of Air Quality Planning and Standards, Further comments on percent VOC emitted from
    laundry and dishwashing products, August 8, 1994.
                                       2-54

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        3.0   PRODUCTS  AFFECTED  BY  EXISTING  OR  ONGOING
                    FEDERAL  REGULATORY PROGRAMS

3.1   INTRODUCTION

      This segment of the consumer and commercial products inventory includes those
products which are used industrially and are affected by existing or ongoing regulations
developed by the EPA and/or by the States.  These products include a wide range of
surface coatings, metal cleaning solvents, adhesives, inks, agricultural pesticides, asphalt
paving materials, and a host of others.  Estimates of VOC emissions from these products
were obtained from background documentation developed for the respective regulations or
guidance documents.  Emission estimates for previously regulated categories are based on
"residual"  emissions (i.e., emissions which continue after controls have been applied).
Estimates for categories associated with ongoing standards development are 1990
"baseline" emission estimates from those categories (i.e, emissions before any controls
have been applied).

      The purpose of this inventory study was to develop estimates of VOC emissions in
ozone nonattainment areas.  Accordingly, the estimates presented in this report reflect
nonattainment area emissions.  For many of the industrial products  discussed in this
section, estimates were developed based on actual locations of emission sources, and
include only those emissions in nonattainment areas.  For categories for which specific
locations of sources are unknown, the scaling method discussed in Section  1.4.2 was used
to apportion emissions based on population distribution.

      Table 3-1 presents  a summary of VOC emissions in  nonattainment areas
attributable to industrial products and activities subject to §183(e) for which Federal
regulatory programs are existing or under development.
                                       3-1

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                 TABLE 3-1
    VOC EMISSIONS IN NONATTAINMENT AREAS
FOR PRODUCTS AFFECTED BY EXISTING OR ONGOING
           REGULATORY PROGRAMS
Category
Architect & indust maint coatings
Automobile refinishing products
Aerospace paints and coatings
Wood furniture coatings
Ship and boat coatings
Metal furniture coatings
Flat wood paneling coatings
Large appliance coatings
Magnet wire coatings
Metal can coatings
Metal coil coatings
Other metal product coatings
Auto and light truck assy coatings
Paper, film, and foil coatings
Magnetic tape coatings
Business mach plastic part coating
Automotive plastic part coatings
Flexible packaging printing
Rotogravure publication printing
Lithographic printing
Letterpress printing
Tire manufacturing cements
Nonattainment
Emissions
(tons/yr)
315,000 a
55,000 a
107,500
60,000
15,100
63,000 a
20,000 a
15,600 a
4,800 a
45, 000 a
21, 600 a
218,400 a
75,000
65,000
5,500
5,500
16,500
150,000
20,000
600,000
28,200 a
26,400 a
Year
of
Estim
1990
1990
1990
1990
1990
1985
1985
1985
1985
1985
1985
1985
1990
1985
1990
1990
1990
1990
1990
1990
1985
1985
Ref
1
2
3
4
5
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
Federal
Control
Measure
Bb
Ab
Mb
Mb
A, Mb
C, N
C
C, N
C
C, N
C, N
C
C, N
C, N
C, N
Cb, N
Cb
C, N
C, N
C

C, N
                    3-2

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                                    TABLE 3-1
                 VOC EMISSIONS IN NONATTAINMENT AREAS
           FOR PRODUCTS AFFECTED BY EXISTING OR ONGOING
                           REGULATORY PROGRAMS
                                    (Continued)
Category
Miscellaneous industrial adhesives
Metal cleaning solvents
Industrial cleanup solvents
Petroleum drycleaning solvents
Agricultural pesticides
Cutback asphalt paving materials
Synthetic fiber spinning solvents
Fabric coating
Fabric printing
TOTAL FOR THIS TABLE
Nonattainment
Emissions
(tons/yr)
201, 600 a
36,000
150,000 a
54,600 a
15,000 a
128,400 a
46,200 a
21, 000 a
25,200 a
2,611,100
Year
of
Estim
1985
1990
1990
1985
1987
1985
1985
1985
1985

Ref
6
6
7
6
8
6
6
6
6

Federal
Control
Measure

C, Nb
A
C, N
A
C
N
C, N
C

       Nonattainment area emission estimates were obtained by adjusting nationwide estimates according
       to the distribution of nationwide population in nonattainment areas in 1990.  Estimates for
       categories without this footnote were developed for nonattainment areas and needed no adjustment.
        148 million (nonattainment areas)
             248 million (nationwide)
=   59.68%  =   60%
b      Document or regulation currently being developed

A      Alternative Control Techniques Document (ACT)

B      Regulation requiring Best Available Controls under §183(e)

C      Control Technology Guidelines Document (CTG)

N      New Source Performance Standards (NSPS)

M      Maximum Achievable Control Technology (MACT) Standard


                                        3-3

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3.2    CATEGORY DESCRIPTIONS AND SOURCES OF VOC EMISSIONS
3.2.1  Architectural and Industrial Maintenance Coatings
                                                    1
       The U.S. architectural and industrial maintenance (AIM) coating industry is
composed of roughly 500 manufacturers.  AIM coatings are used by do-it-yourself,
professional, and industrial painters.  AIM coatings include house paints, wood finishes,
cement coatings, roof coatings, traffic paints, and industrial maintenance coatings.  For
purposes of regulation, AIM coatings have been further classified into numerous coating
categories. These categories include:
Alkali Resistant Primers
Anti-fouling Coatings
Bituminous Coatings & Mastics
Chalkboard Resurfacers
Concrete Protective Coatings
Extreme High Durability Coatings
Flat Coatings
Flow Coatings
Graphic Arts Coatings
High Temperature Coatings
Industrial Maintenance (I/M) Coatings
Lacquer Stains
Mastic Texture Coatings
Multi-Color Coatings
Nuclear Power Plant Coatings
Pre-Treatment Wash Primers
Quick Dry Coatings
Roof Coatings
Sanding Sealers
Shellacs
Swimming Pool Coatings
Traffic Marking Paints
Waterproofing Sealers
Antenna Coatings
Anti-Graffiti Coatings
Bond Breakers
Concrete Curing Compounds
Dry Fog Coatings
Fire-Retardant/Resistive Coatings
Floor Coatings
Form Release Compounds
Heat Reactive Coatings
Impacted Immersion Coatings
       Lacquers
Magnesite Cement Coatings
Metallic Pigmented Coatings
Non-Flat Coatings
Ornamental Metal Lacquers
Primers and Undercoaters
Repair/Maint Thermoplastic Coatings
Rust Preventative Coatings
Sealers
Stains
Thermoplastic Rubber  Coatings
Varnishes
Wood Preservatives
                                       3-4

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3.2.2  Automobile Refinishing Products

       The steps involved in automobile refinishing include surface preparation, coating
application, and spray equipment cleaning. Each of these steps can be a source of VOC
emissions.  Emissions can be reduced by using waterborne surface preparation products,
and by using coatings that are inherently low in VOC, such as urethanes. Emissions
could also be reduced by reformulating conventional coatings to lower their VOC content.
Improved transfer efficiency reduces VOC emissions by decreasing the amount of coating
overspray.  Gun cleaning equipment that controls evaporative losses also recirculates
solvent for several cleanings to reduce solvent use.

       The active ingredient in low-VOC  surface preparation products is detergent rather
than solvent.  Low-VOC surface preparation products reportedly work as well as
conventional products, but they must be allowed to remain on the surface longer before
being wiped off and they require additional rubbing for thorough removal.

       Emissions from coating applications can be reduced by: (1) applying coatings with
lower VOC content, (2)  using spray equipment that  has a higher transfer efficiency so
that less coating is waste, and (3) abatement.

       Gun cleaning is a source of solvent emissions.  Spray equipment can be cleaned
manually with little to no control of evaporative emissions or with gun cleaning
equipment designed to reduce solvent consumption,  evaporation, and worker exposure.
Solvent may be emitted from gun cleaning equipment both during actual cleaning
operation (active losses)  and during standby (passive losses).  An estimated 60 percent
reduction in VOC emissions is achieved by shops that switch from cleaning guns
manually to a gun cleaner.
                                        3-5

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3.2.3 Aerospace Coatings *

      The most common coatings used are the broad categories of non-specialized
primers and topcoats.  There are also numerous specialty coatings ranging from
temporary protective coatings to radiation effect coatings designed to shield aircraft from
radar detection.  Coatings are applied to aerospace vehicles and components using several
methods of application.  The methods most commonly used are spraying, brushing,
rolling,  flow coating, and dipping.  Spray application systems include conventional air
spray, airless spray, air-assisted airless, electrostatic, and high volume low pressure
spray.  Emissions from coating applications occur from the evaporation of the solvents
during mixing, application,  drying, and overspray.

3.2.4 Wood Furniture Coatings 4

      Wood furniture coatings are used in the manufacture of furniture.  Adhesives are
used in  assembling furniture components,  in laminating veneers, and in installing
upholstery.  Solvents are used to thin coatings, to remove coatings from furniture that did
not meet specifications, and to clean equipment.

      Formaldehyde may be emitted from conversion varnishes, a type of coating used
to finish kitchen cabinets and  some office  furniture. Styrene may  be emitted from some
ultraviolet light cured coatings and polyester coatings.

      There are many low-VOC coating  alternatives available. These include
waterborne topcoats and sealers.  Some ultraviolet light cured coatings may be 100
percent  solids (no VOC). Some coatings  replace some of the VOC with liquid CC^.
More efficient application methods such as high volume, low pressure spray equipment
can be used to further reduce  emissions.
                                        3-6

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3.2.5  Ship and Boat Coatings

       Emissions from shipyard operations are primarily VOC emissions that result from
painting operations.  Emissions of VOC's from painting operations result in three
components: (1) organic solvent in the paint "as supplied" by the paint manufacturer, (2)
organic solvent in the thinner, which is added to the paint prior to application and
becomes part of the paint  "as applied", and (3) any additional volatile organic released
during the cure.  The organic solvents from both components are emitted as the applied
paint dries/cures. This organic solvent portion of a paint is composed of a mixture of
different solvents that perform either of two equally important functions: (1) reduce
viscosity so the paint can be atomized as it leaves the spray gun, or (2) provide essential
surface characteristics of the paint once it is applied.  Solvents used for atomization
typically have low boiling points and flash to a vapor upon leaving the spray gun.  These
solvents evaporate relatively quickly during initial drying to prevent excessive flow.
Solvents responsible for imparting the desired surface characteristics must have higher
boiling points and subsequently evaporate more slowly than atomizing solvents to allow
sufficient leveling and adhesion.  Of the solvents used in marine paints, most are VOC's.
The most significant reductions in VOC emissions  would result from shipyards
transitioning to reformulated coatings.

3.2.6  Metal Furniture Coatings °

       Metal furniture coating consists of the application of prime and top coatings to any
piece of metal furniture or metal part  included in the categories of household furniture,
office furniture, public building and related furniture, and partitions and fixtures.
Typically, the metal substrate is first cleaned,  rinsed in a phosphate bath, and oven-dried
to improve coating adhesion.  If a prime coat  is necessary, the part  may be dipped,
sprayed, or flow  coated and then dried in a curing oven. Subsequent  topcoats, or in the
event no prime is required, the single topcoat  is usually by spray. The freshly coated
parts are conveyed to the oven through a flash-off tunnel during which the coating  "flows

                                         3-7

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out" to a uniform thickness and some of the solvent evaporates. The parts are baked in
single or multi-pass ovens at 150-230°C.

       There are approximately 1400 known domestic metal furniture coating plants,
including 445 for household and 253 for office furniture.  There are likely several
hundred more that custom manufacture, finish, or refinish metal furniture that have not
yet been identified.

       Specific emission sources on the coating line are the coating application, the flash-
off area, and the bake oven.  On the average conveyorized spray coating line, it is
estimates that about 40 percent of the total VOC emissions come from the application
station, 30 percent from the flash-off area, and 30 percent from the bake oven.  In
addition, fugitive emissions also occur during mixing and transfer of coatings.

       Control techniques used by this industry include converting to low-solvent
coatings, improving transfer efficiency with state-of-the-art application equipment or
incineration.  Adoption of high-solids or waterborne coatings can reduce VOC emissions
from prime-coating operations by 70 and 92 percent,  respectively.   Conversion to an
electrodeposition prime coat can reduce emissions by 94 percent. Emissions from
topcoats can be reduced by conversion to waterborne, high-solids,  or powder coatings,
giving reductions of up to 80 percent, 70 percent, and 99 percent,  respectively.
3.2.7  Flat Wood Paneling Coatings 6
       A typical flat wood coating facility applies stains and varnishes to natural plywood
panels used for wall coverings.  Other plants print wood grain patterns on particle board
panels that were first undercoated with an opaque coating to mask the original surface.
Coatings applied to flat wood paneling include fillers, sealers, "groove" coats, primers,
stains, basecoats, inks, and topcoats.  Most coatings are applied by direct roll coating.
Filler is usually applied by reverse roll coating.  The offset rotogravure process is used

                                         3-8

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where the coating and printing operation requires precision printing techniques.  Other
coating methods include spray techniques, brush coating, and curtain coating.  A typical
flat wood paneling coating line includes a succession of coating operations.  Each
individual operation consists of the application of one or more coatings followed by a
heated oven to cure the coatings.  A typical production line begins with mechanical
alterations of the substrate (filling of holes, cutting of grooves, sanding, etc.), followed
by the coating operations, and packaging/stacking for shipment.  Approximately 60
domestic plants coat flat wood paneling.

      Emission of VOC from a flat wood coating occurs primarily  at the coating line,
although some emissions also occur at pain mixing and storage areas.  All solvent that is
not recovered can be considered a potential emission.

      Control techniques for flat wood panels include add-on controls, materials
changes, and process changes. Conversion to waterborne coatings can lower VOC
emissions by at least 70 percent. Use of low solvent coatings that cure by ultraviolet
light is gaining greater acceptance and, where applicable, effects a near 100 percent
reduction of VOC emissions.

3.2.8 Large Appliance Coatings *>

      Large appliance products include kitchen ranges, ovens, microwave ovens,
refrigerators, freezers,  washers, dryers, dishwashers, water heaters,  and trash
compactors. A "large appliance surface-coating line" consists of the coating operations
for a  single assembly line within an appliance assembly plant.  Typically, the metal
substrate is first  cleaned, rinsed in a phosphate bath, and oven dried to improve  coating
adhesion. If a prime coat is necessary, the part may be dipped, sprayed, or flow-coated
and dried in a curing oven.  Subsequently, the topcoat is applied, usually by spray. The
fresh  coated parts are conveyed through a flash-off tunnel to evaporate solvent and cause
                                        3-9

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the coating to flow our properly.  After coating and flash-off, the parts are baked hi
single or multipass ovens at 150-230°C.

       There are approximately 170 plants in the United States that manufacture large
appliances.

       A surface coating line has three main sources of emissions. Major emissions
occur at the application  (spray booth) area, flash-off area,  and the curing oven.  Fugitive
emissions occur during mixing of coatings. Emissions from top-coat application can be
reduced by use of waterborne, high-solids, or powder coatings, giving reductions of 80
percent, 70 percent, and 99 percent, respectively, from levels typical of high VOC
coatings.

3.2.9  Magnet Wire Coatings ^

       Magnet wire coating is the process of applying a coating of electrically insulating
varnish or enamel  to aluminum or copper wire for use in electrical machinery.  The
uncoated wire is unwound from spools and passed  through an annealing furnace to make
the wire more pliable and to bum off oil and dirt left from previous operations.  The
wire passes from the furnace to the coating applicator. At a typical applicator, the wire
acquires a thick coating  by passage  through a coating bath.  The wire is then drawn
vertically through an orifice or coating die which scrapes off excess coating and leaves a
film of the desired thickness.  The wire is routed from the coating die into an oven where
the coating is dried and  cured. A typical oven has two zones. The wire enters the
drying zone,  held at 200°C, and exits through the curing zone, held at 430°C.  A wire
may pass repeatedly through the  coating applicator and oven to build a multilayered
coating.  After the final pass through the oven, the wire is rewound on a spool for
shipment. There are approximately 30 plants nationwide which coat  magnet wire.
                                        3-10

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       The oven exhaust is the most important emission source in the wire coating
process.  Solvent emissions from the applicator are low due to the dip coating technique.
Emission reductions achieved through coating reformulations would require replacement
of conventional solvent-borne coatings with either high-solids coatings (greater than 77
percent solids by volume) or waterborne coatings (i.e., 29 volume percent solids,  8
volume percent organic solvent,  63 volume percent water). Use of powder coatings, hot
melt coatings, or waterborne emulsions, which contain little or no organic solvent, would
eliminate VOC emissions.

3.2.10       Metal Can Coatings 6

       There are two major types of cans.  Coating application methods used by can
manufacturers vary with the type of can.  The coatings used depend on the type of can
and the type of product to be packed in the can. A "three-piece" can is made from a
cylindrical body and two end pieces.  A large metal sheet is first roll coated with  both an
exterior and an interior coatings, then cut to size, rolled into a cylinder (body) and sealed
at the side seam.  A bottom end piece formed from coated metal is then attached to the
body.  The can interior may then be spray coated before the can is filled with a product
and sealed with the top end piece.   A "two-piece can body and bottom is drawn and wall
ironed from a single shallow cup.  After the can is formed, exterior and interior coatings
are applied by roll coating and spraying techniques, respectively. The can is then filled
with product and the top end piece is attached.

       The metal can industry consists of over 400 plants  nationwide. In recent years
there has been a dramatic shift from three-piece cans to two-piece cans.  Almost all
beverage cans and many food cans are now two-piece.

       Solvent emissions from can coating operations occur from the application area,
flash-off area, and the curing/drying oven.  Emissions vary with production rate, VOC
content of coatings used, and other factors.  Substitution of waterborne or high-solids

                                        3-11

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coatings for conventional coatings can reduce VOC emissions by 60 to 90 percent at
many of these operations.

3.2.11        Metal Coil Coatings 6

       The metal coil coating industry applies coatings to metal sheets or strips that come
in rolls or coils.  The metal strip is uncoiled at the beginning of the coating line, cleaned,
and then pretreated to promote adhesion of the coating to the metal surface.  When the
coil reaches the coating application  station, a coating is applied, usually by rollers, to one
or both sides of the metal strip.  Some coil coatings are applied by electrodeposition.
The strip then passes through an oven to cure the coating and is then water or air
quenched.  If the line is a "tandem" line, the metal strip passes through a second
sequence of coating applicator, oven, and quench station.  Finally, the coil is rewound
for shipment or further processing.  In 1980, there were 109 plants containing an
estimated 147 coil coating lines in the United States.

       Approximately 90 percent of the total VOC content of the coating evaporates in
the curing ovens.  Of the remaining 10 percent, about 8 percent evaporates at the
applicator station and 2 percent at the quench station.  The rate at which VOC emissions
occur is determined by the operating parameters of the line,  including:  (1) the width of
the metal strip, (2) the VOC and  solids content of the coating,  (3) the speed at which the
strip is processed, (4) the thickness  at which the coating is applied, and (5) whether
emission abatement equipment has been installed.

       Low solvent and waterborne coatings are also available for many end uses.  These
coatings may achieve emission reductions of up to 90 percent compared to conventional
solvent-borne materials.
                                        3-12

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3.2.12       Other Metal Product Coatings *

       The original equipment manufacturers discussed here have been referred to by a
variety of names, including coalers of miscellaneous metal parts.  The category includes
hundreds of small- and medium-sized industries and their companies which coat metal
parts for which more specific regulatory guidance was not published as part of the
guideline series (i.e., can, coil, wire, automobile and light-duty truck, metal furniture,
and large appliances).  Although many products are coated by manufacturers in this
category, the coating processes have many features in common. Typically, the metal
substrate is first cleaned, rinsed in a phosphate bath, and oven-dried to minimize
contamination and maximize coating adhesion. If a prime coat is used, it may be applied
by dipping, spraying, or flow-coating.  The part is then dried in a curing oven.
Subsequent top coats, or if no  prime is used, the single topcoat is usually applied by
spray.  The freshly-coated parts are often conveyed through a flash-off tunnel or room,
permitting the coating to flow out to a uniform thickness. Some of the solvent will
evaporate during this time.  The parts are then baked in single  or multi-pass ovens at
150-230°C.  Large products with high mass such as large industrial, construction, and
transportation equipment are usually coated with materials that  will  cure by air- or forced
air-drying, rather than baking, since the specific heat capacity of the large mass makes
raising its temperature high enough  to cure a coating in an oven prohibitively expensive.

       Organic emissions from coating miscellaneous metal parts and products are
emitted from the application, flash-off area, and the bake oven  (if used).  The bulk of
VOC emitted by lines which spray or flow coat, evaporates from the application and
flash-off areas.   For dip-coating operations, the bulk of the VOC is emitted from  the
flash-off area and bake oven.   Fugitive emissions also occur during mixing and transfer
of coatings.

       Control techniques available  to the industries that coat miscellaneous metal parts
and products include converting to low-solvent coatings, improving  transfer efficiency

                                        3-13

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with state-of-the-art application equipment, or incineration.  Spray application of
waterbome coatings can reduce emissions by 70 to 95 percent; use of higher solids
coatings from 50 to 80 percent; and powder coatings,  95 to 98 percent. Use of
electrodeposition (EDP)  to apply prime coats can reduce emissions up to 94 percent over
conventional coatings used for operations.  Transfer efficiency is the ratio of the amount
of coating solids deposited onto the surface of the coated part to the total amount of
coating solids used. Improvements in transfer efficiency will decrease the volume of
coating that must be sprayed to cover a specific part.  Of course, the less paint used, the
lower the total VOC emission rates.

3.2.13       Auto and  Light Truck Assembly Coatings ^

      The automobile and light-duty (less than 8,500 pounds gross vehicle weight) truck
assembly industry receives parts from a variety  of sources and produces finished vehicles
ready for sale to vehicle dealers.  The automobile and light-duty truck coziting process is
a multistep operation performed on an assembly line producing up to 90 units per hour.
There were about 65 automobile or light-duty truck assembly plants in the United States
in 1984.

      Body surfaces to  be coated are cleaned with various  materials which  may include
solvents to remove oil and grease. Then a phosphating process prepares the surface for
the prime  coat.  The primer is applied to protect metal surfaces from corrosion and to
ensure good adhesion of the topcoat.  Primer may be solvent-based or walerborne.
Solvent-based primer is  applied by a combination of manual and automatic spraying, flow
coat  or dip processes.  Waterbome primer is most common now and is most often
applied in an electrodeposition (EDP) bath.  The prime coat is oven cured before further
coating. When EDP is used to apply primer, the resulting film may be too thin and
rough to compensate for all surface defects, so a guide coat (primer-surfacer) is usually
applied and oven-cured before the topcoat application. Recent developments in EDP
technology produce a thicker dry film which in  some cases eliminates the need  for the

                                       3-14

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guide coat.  On some vehicles an additional coating called a chip guard or anti-chip
primer is applied along the bottom of the doors and fenders.  These flexible urethane or
plastisol coatings help protect susceptible parts of the coated vehicle from damage by
stones or gravel.

       The topcoat (color) is then applied by a combination of manual and automatic
spraying.  The topcoat requires multiple applications to ensure adequate appearance and
durability.  An oven bake may follow each topcoat application, or the individual coats
may be applied wet-on-wet with a final oven back.

       The painted body is then taken to a  trim operation area where vehicle assembly is
completed.  Some additional coating may be done in a final off-line repair step if needed
to correct paint defects or damage.

       Single coating (not clearcoated) lacquer and enamel topcoats have traditionally
been used in this industry.  Since 1980, the entire domestic auto industry has converted to
a composite, two coating, topcoat system which consists of a thin layer of a highly
pigmented basecoat followed by  a thick layer of clearcoat.  These two coating systems
are referred to as basecoat/clearcoat.  They can provide higher gloss and better chemical
resistance than conventional single coating  topcoats, especially for metallic colors.  Some
domestic manufacturers are switching all of their colors to  basecoat/clearcoat while others
are using basecoat/clearcoat for metallic colors only.  The switch to basecoat/clearcoat
was prompted by the use of basecoat/clearcoat on virtually all imported metallic  colored
cars.

       Solvent emissions occur in the application and curing stages of the surface coating
operations.  The application and curing of the prime coat, guide coat,  and topcoat
accounted for a majority of the VOC emitted from most assembly plants in the past.
Conversions to lower VOC content  coatings and more efficient application equipment has
reduced the  contribution of these operations to total plant-wide VOC emissions at many

                                        3-15

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assembly plants.  Final topcoat repair, cleanup, adhesives, sound deadeners, and
miscellaneous coating sources account for the remaining emissions.  Approximately 70 to
90 percent of the VOC emitted during the application and curing process is emitted from
the spray booth and flash-off areas, and 10 to 30 percent from the bake oven.

       Use of waterborne EDP coatings is the most common control technique for prime
coats.  Waterborne guide coats and topcoats have been used in three plants.

       The industry and its suppliers have focused primarily on developing higher solids
solvent-borne enamels and improving transfer efficiency. Most of the coating
development work has been directed toward basecoat/clearcoat coatings.  Low  solids,
high VOC content basecoat/clearcoat materials have been used since the  mid-1960's,
especially on metallic-colored imported cars.  Higher solids basecoat/clearcoat  topcoats
have been developed to help meet VOC emission regulations and match the appearance of
imported vehicles. These coatings are in use at many plants,  including two of the plants
that used waterborne topcoats. (The third plant that used waterborne topcoats has
closed.)

3.2.14       Paper. Film, and Foil Coatings 6

       Paper is coated for a variety of decorative and functional purposes with a variety
of coatings which may be waterborne, organic solvent-borne,  or solventless extrusion
type materials.  A coating operation is defined as the application of a uniform layer
across a substrate. This definition of coating also includes saturation processes.  In
paper-coating operations, the coating mixture is usually applied by means of a reverse
roller, a knife, or a rotogravure roller to a web of paper. The major components o a
paper-coating line are, in sequence:  the unwind roll (from which the paper is fed to the
process), the coating applicator, the oven, tension and chill rolls, and the rewind roll.
Ovens may be divided into from two to five different temperature zones.  The  first is
usually maintained at about 43°C.   The other zones have progressively higher

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temperatures up to 200°C to cure the coating after most of the solvent has evaporated.
The large volume organic solvents used in paper coating mixtures are toluene, xylene,
methyl ethyl ketone, isopropyl alcohol, methanol, acetone, and ethanol. There are
approximately 800 plants nationwide where paper-coating operations are employed.

       The coating of pressure sensitive tapes and labels (PSTL) is an operation in which
a backing material such as paper, cloth, or cellophane is coated one or more times to
create a tape or label that sticks on contact.  Adhesives and release agents are the two
primary types of coatings applied in this industry. Essentially all of the VOC emissions
from  the PSTL industry come from solvent-based coatings which are used to produce 80
to 85  percent of all PSTL products.

       In the solvent-based coaling process, a roll of backing material is unrolled, coated,
dried, and rolled up. The coating may be applied to the web by knife coaler, blade
coaler, metering rod coaler, gravure coaler, reverse  roll coaler, or a dip and  squeeze
coaler.  After Ihe coaling has been applied, Ihe web moves inlo a drying oven where the
web coating is dried by solvent evaporation and/or cured lo a final finish.  Direct-fired
ovens are Ihe most common lype used. Drying ovens are lypically mullizoned wilh a
separale hoi air supply  and exhausl for each zone. The lemperalure increases from zone
lo zone in Ihe direction in which the web is moving, thus the zone maintained at Ihe
highesi temperature is the final zone thai Ihe web iraverses before exiting Ihe oven.  A
large  drying/curing oven may have up lo six zones ranging in lemperalure from 43 °C to
204°C.

       A tandem coating line is one in which the web undergoes a sequence of coating
and drying steps wilhoul rewinding belween sleps.  Tandem coaling lines are usually
employed by planls that manufacture large volumes of the same product.

       Over 100 plants with a total of about 300 coaling lines produce pressure sensitive
tapes  and  labels in the  Uniled Slales.

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       The main emission points from paper-coating lines are the coating applicator and
the oven.  In a typical paper-coating plant, about 70 percent of all emissions are from the
coating lines.  The other 30 percent are emitted from solvent transfer, storage, and
mixing operations.  Most of the VOC emitted by the line are from the first zone of the
oven.

       Use of low-solvent coatings can achieve significant reductions in VOC emissions
when substituted for conventional organic solvent-borne coatings.  One type, waterbome,
can effect an 80 to 99 percent reduction.

       Fugitive emissions  from solvent transfer, storage, and mixing operations can be
reduced through good housekeeping practices, such as maintaining lids on mixing vessels,
and good maintenance, such as repairing leaks promptly.

       By definition, all PSTL products have an adhesive coating. It is generally the
thickest coating applied and the source of 85 to 95 percent of the total emissions from a
line.  In an uncontrolled facility, essentially all of the solvent used in the coating
formulation is emitted to the atmosphere.  Of these uncontrolled emissions, 80 to 95
percent are emitted  from the drying oven.  A small fraction of the coating solvent may
remain in  the web after drying. The  remaining 5 to 20 percent of applied solvent is  lost
as fugitive emissions by evaporation from a number of small sources such as the
applicator system  and the coated web upstream of the drying oven.  Some fugitive losses
also occur from storage  and handling of solvent, spills, and mixing tanks, and during
cleaning of equipment, such as a gravure roll.

       An emission control technique is the use of low-VOC coatings such as
waterborne,  hot-melt, and radiation cured coatings.  Emissions of VOC from such
coatings are negligible.
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3.2.15        Magnetic Tape Coatings 6

       Organic solvent, metal-oxide particles, and suitable resins are combined to form
the coatings used by magnetic tape coating operations.  The coating equipment consists of
an unwind roll for the plastic film substrate, a coating applicator, a drying oven, and a
windup roll for the coated tape.  The coating mixture is supplied to the plastic film
substrate by the coating applicator (often via some sort of roll or rotogravure coater).
The plastic film is carried through the drying oven where organic solvent evaporates.
The plastic substrate with the dried  magnetic coating is then rewound at the end of the
line.  Slitting operations to produce the consumer product are almost always performed
later as an off-line operation.

       Roughly 10 percent of the solvent used by a plant evaporates from mix and
storage tanks. Another 10 percent evaporates from the coating applicator and the flash-
off area between the coater and the  oven.  The remainder evaporates in the drying oven
and is exhausted through the oven exhaust  stack.

3.2.16        Business Machine Plastic Parts Coatings "

       Plastic parts for business machines are coated for several reasons.  Exterior
coatings are applied to improve appearance, color match, and provide chemical
resistance. Metal-filled coatings are applied to interior surfaces to provide
electromagnetic interference/radio frequency interference (EMI/RFI) shielding.  This
limits both escape and intrusion of stray electronic signals, and in many cases is required
by Federal Communications Commission (FCC) regulations.  Coatings are generally
spray applied in this industry,  using air-atomized spray equipment.  Many of the
conventional and lower VOC content coatings used in this industry are two-component
urethane coatings.
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       VOC emissions from plastic parts coating occur in the spray booth flash-off area
and back oven.  Up to 90 percent of all VOC emissions come off in the spray booth.
Substitution of waterborne or high-solids coatings for conventional coatings can  reduce
VOC emissions from exterior coating and EMI/RFI shielding by 60 to 80 percent.

3.2.17        Automotive Plastic Parts Coating ^

       These coatings are used to finish interior and exterior plastic parts used in
automotive and other transportation equipment.  Examples include bumpers, bumper
covers, body panels, dashboards, and other interior and exterior parts.

       Emissions can be reduced through the use of low-VOC coatings,  which appear to
be readily available.

3.2.18        Flexible Packaging Printing 6

       The image areas on the image cylinder of a flexographic press  are raised above
the nonimage areas. A distinguishing feature is that the image carrier is made of rubber
which is attached to the cylinder.  A feed cylinder which rotates in an ink fountain
delivers ink to a distribution roll, which in turn transfers  ink to  the image cylinder.
following transfer from the  image cylinder to substrate, the ink  dries by  evaporation in a
high velocity,  low temperature (< 120°F) air dryer.  Some solvent is absorbed into the
web.  Typical  ink solvents are alcohols,  glycols, esters, hydrocarbons, and ethers.  An
estimates 21,400 flexographic presses were in operation in the United  States in 1984.

       The major emission points from a flexographic press are the ink fountains, feed
cylinder, distribution roll, image cylinder, printed web, and dryer exhaust.  The potential
amount of VOC emissions is equal to the total amount  of solvent consumed by the
printing plant if none of the ink reacts to form an organic by-product.  This includes the
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solvent in the raw inks, solvent in any extenders used, the solvent added at the press, and
clean-up solvent.

       Emissions from flexographic printing operations can be reduced by improvements
in the equipment for containment of the emissions from the print station and installation
of an incineration system.  Overall, a capture efficiency of 65 to 70 percent and a
combustion efficiency of 90 percent (for an overall reduction of 60 percent) appears
reasonable.  Some flexographic packaging operations can now use waterborne inks.
Emission reductions equal to or better than those achieved by incineration can be attained
when the solvent portion of the ink consists of 75 volume percent water and 25 volume
percent organic solvent (solids to liquid ratio remaining the same).  Higher-solids inks
with 60 percent solids are becoming available.

3.2.19       Rotogravure Publication Printing "

       In the rotogravure printing process, image areas are recessed relative to nonimage
areas.  The rotating cylinder picks up ink  from  an ink trough or fountain.  Excess ink is
scraped from the blank area by a steel doctor blade.  The ink is then transferred directly
as the roll contacts the web.  The web is then dried in a low temperature dryer. Typical
ink solvents include alcohols, aliphatic naphthas, aromatic hydrocarbons, esters, glycol
ethers, ketones, and nitroparaffins.  It is estimated that there were approximately 1,600
rotogravure presses in the United States in 1984.

       The major emission points from a rotogravure press are the ink fountains, wet
printing cylinders, wet printer web, and drier exhaust.  The total amount of organic
solvent consumed by the printing plant is the maximum potential VOC emission (if no
reaction by-products are formed during the drying operation).  This consists  of solvent in
the raw ink, solvent contained in any  extenders used, solvent added at the press, and
solvent used for cleanup.  New publication rotogravure presses with good capture or
containment devices can achieve better than 84 percent overall control. For some

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printing operations, equivalent emission reductions may be possible through use of
waterbome and/or high ink solids.
3.2.20       Lithographic Printing
       Lithography is a printing process characterized by a planographic image carrier
(i.e., the image and nonimage areas are on the same plane) which is mounted on a plate
cylinder.  The image area is made water repellant while the nonimage area is water
receptive.  Rotation of the place cylinder causes the image plate to first contact an
aqueous fountain solution which typically contains up to 25 weight percent isopropyl
alcohol.  This solution wets only the nonimage area of the plate. The image plate then
contacts the ink which adhered only to the image area.  In offset lithographic printing,
the ink is transferred from the image plate to a rubber-covered blanket cylinder. The
blanket cylinder then transfers the image to the web.  Lithographic heatset inks,
containing approximately 40 volume percent solvent,  require a heated dryer to solidify
the printed ink.  Other lithographic inks, containing about 5 volume percent solvent, dry
by oxidation or by absorption into the substrate.

       There are approximately 400 printing plants in the United States operating over
1000 heatset web offset lithographic printing presses.

       Emission points on a web-offset lithographic printing line include the ink fountains
and associated inking  rollers, the water fountains and associated dampening rollers, the
plate and blanket cylinders, the  dryer, and the final printed product.  Alcohol is emitted
from the dampening system and the plate and blanket cylinders at a rate of about 0.5
kilograms per kilogram of ink consumed.  Wash-up solvents are a small source of
emissions from the inking system  and  the plate and blanket cylinders.  When heat-set inks
are printed, the drying oven is the major source of VOC emissions with 40 to 60 percent
of the ink solvent evaporating from the oven.
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       Two approaches for controlling VOC emissions from heat-set web offset
lithographic printing presses are (1) material reformulation,  and (2) add-on control.
Substitution of polyols, such as ethylene glycol, for the alcohol in the aqueous fountain
solution can result in a reduction of VOC emissions from fountain solutions.  Ink
reformulation to reduce the solvent content will reduce VOC emissions from the dryer
somewhat.

3.2.21       Letterpress Printing *>

       Letterpress is the oldest form of moveable type printing, with the image areas
raised relative to the blank or nonimage  areas.   The image carrier may be made of metal
or plastic.  Viscous ink is applied to the image carrier and transferred directly to paper or
other substrate.  Letterpress is the dominant printing process for periodical and
newspaper publishing.  Newspaper ink is composed of petroleum oils and carbon black,
but no volatile solvent. The ink  "dries"  by adsorption into the substrate.  Web presses
printing on nonporous substrates  employ solvent-borne inks  which dry by evaporation.
Sheet-fed presses employ solventless inks which dry by air oxidation. There are over
10,000 commercial letterpress  printing plants in the United States.

       The major VOC emission points on web letterpress printing lines are the image
carrier and inking mechanism of the press, the dryer, the chill rolls, and the printed
product.  About 60 percent of the solvent in the ink is lost in the drying process. Use of
washup solvents contribute to overall VOC emissions.

       Use of the ultraviolet curing inks in place of solvent-borne inks can essentially
eliminate emissions. Use of heat reactive inks which contain only 15 percent of the
organic solvent content of conventional inks will reduce overall emissions by 80 percent.
A similar reduction is achievable with waterborne inks.
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3.2.22       Tire Manufacturing Cements °

       In 1984, the rubber tire manufacturing industry consisted of approximately 60
plants nationwide.  The tire manufacturing process generally consists of four main steps:
(1) compounding of raw materials, (2) transforming the raw materials into tire
components and preparing the components for assembly, (3) assembling the components
(tire building), and (4) molding, curing, and finishing of the assembled components into
the final product.  Each of these steps is a potential source of VOC emissions.

       During compounding, raw crumb rubber is combined with fillers, extenders,
accelerators, antioxidants, and pigments. This mixture is then transferred to roll mills
which knead the material and form it into sheets.

       Tire components are made in several parallel operations.  Rubber stock and other
raw materials, including wire and fabric, are used to make tire tread,  sidewalls, cords,
belts,  and beads.  The major source of VOC emissions during this step is the evaporation
of VOC's from solvent-based cements.  Tire building is the assembly  of the various tire
components to form an uncured or "green"  tire.  The assembly takes place on a
collapsible, rotating drum.  Organic solvents may be applied to some tire components in
this step to further "tackify" (make sticky) the rubber.  Green tires are then sprayed on
the inside with lubricants and on the outside with mold release agents  before molding and
curing in automatic presses. Curing usually takes 20 to 60 minutes at a temperature of
100°C to 200°C.  The cooled tire is finished with buffing and grinding operations.

       Each of the four production steps may include one or more sources of VOC
emissions.  Organic solvent-based green tire spraying, undertread cementing,  sidewall
cementing, tire building, tread end cementing, and bead cementing contribute 97 percent
of the total VOC's emitted from tire production.
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       Emission control by either incineration or carbon adsorption is applicable to
undertread cementing, sidewall cementing, automatic or manual tread end cementing,
bead cementing, and green tire spraying.  With an 80 percent efficient capture system,
emission reductions of 75 percent can be attained for each of these processes.

       In addition to add-on control technology, there are low solvent use techniques
which are applicable to several processes.  Limiting the amount of solvent used during
tread  end cementing and bead cementing can effectively reduce emissions from these
sources by as much as 85 percent.  VOC emissions from water-based green tire  sprays
are 90 to 100 percent less than emissions from organic solvent-based sprays.

3.2.23       Miscellaneous Industrial Adhesives "

       Adhesives are  used for joining surfaces in assembly and construction of a large
variety of products.  Adhesives allow faster assembly speeds, less labor input, and more
ability for joining dissimilar materials than other fastening methods.  By far the largest
use of adhesives is for the manufacture of pressure  sensitive tapes and labels.  Other
large  industrial users are automobile manufacturing (including especially attachment of
vinyl  roofs),  packaging laminating,  and construction of shoes. Adhesives may be
waterborne, organic solvent-borne,  or hot-melt.  Only organic solvent-borne adhesives
have the potential for significant VOC emissions.

       Approximately 75 percent or more of all rubber-based adhesives are organic
solvent-borne cements.  Methods of application commonly used are brush application,
spraying, dipping, felt pad application, and roller coating.  Solvents used in solvent-borne
adhesives include aliphatic and aromatic hydrocarbons, alcohols, and ketones.

       The VOC emissions from solvent-based adhesives are a result of the evaporation
of the solvents in the adhesive.  Emissions arise mainly at the point of application and in
many cases are swept from the area with local ventilation systems.  Essentially all of the

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organic solvent in an adhesive is emitted to the atmosphere as the adhesive dries.
Adhesives vary widely in composition but a typical solvent-borne adhesive might contain
80 weight percent solvent so that approximately 0.8 kg of VOC evaporates for every kg
of adhesive used.

       The trend in control technology for solvent adhesives is not to control emissions
from a solvent-borne adhesive, but rather to replace them with a low solvent type which
can perform as well  as the solvent-borne adhesive.  Various types of low solvent adhesive
include waterborne,  hot-melt,  solventless two-component, and radiation-cured.  VOC
reductions of 80 to 99 percent can be achieved by such replacement.  Hot-melt adhesives
are the most widely  used of these alternative processes.   Use of waterborne adhesives is
expected to increase  significantly in the future.
3.2.24        Metal Cleaning Solvents 6
       Solvent metal cleaning (degreasing) uses organic solvents to remove soluble
impurities from metal surfaces.  Organic solvents include petroleum distillates,
chlorinated hydrocarbons, ketones, and alcohols.  Industrial uses include solvent metals
cleaning include automobiles, electronics, appliances, furniture, jewelry, plumbing,
aircraft,  refrigeration, business machinery, and fasteners.

       Methods of solvent metal cleaning include cold cleaning, open top vapor
degreasing, and conveyorized degreasing.  Cold cleaning uses all types of solvents with
the solvent maintained below its boiling point.  Open top vapor degreasers use
halogenated solvents heated to their boiling points.  Both cold cleaners and open top
vapor degreasers are batch operations.  Conveyorized degreasers are loaded continuously
and may operate as vapor degreasers or as cold cleaners.

       For cold cleaners, emission sources are as follows:  (1) bath evaporation,  (2)
solvent carry-out,  (3) agitation, (4) waste solvent evaporation, and (5) spray evaporation.

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Emission rates vary widely with the average emission rate estimated to be about 0.3
megagrams (.33 tons) per year per unit.

       Unlike cold cleaners, open top vapor degreasers lose a relatively small proportion
of their solvent in the waste material and as liquid carry-out. Most of the emissions are
vapors that diffuse out of the degreaser into the work place.  These fugitive emissions
escape to the atmosphere through doors, windows, and exhausts.  An average open top
                                        9      9
degreaser with an open top area of  1.67 mz (18 fr) has an emission rate of 4.2
kilograms (9.3 pounds) per hour or 9,500 kilograms (21,000 pounds) per year.

       Emission sources  for conveyorized degreasers include bath evaporation,  carry-out
emissions, exhaust emissions,  and waste solvent emissions.  Carry-out emissions are the
largest single source.   An average emission rate for a conveyorized degreaser is about 25
megagrams (28 tons) per year while that for a nonboiling conveyorized degreaser is
almost 50 megagrams (55 tons) per year.

       Controls to reduce emissions from  the solvent bath include the following:  (1)
improved cover, (2) high freeboard, (3) chilled water and refrigerated chillers, (4) carbon
adsorption, and (5) safety switches.  Carry-out emissions from cold cleaners can be
reduced by using drainage racks and by controlling the velocity at which parts are
introduced and withdrawn. Carry-out emissions from conveyorized degreasers are
reduced by using a drying tunnel and rotating baskets.

3.2.25       Industrial Cleanup Solvents  7

       A variety of cleaning solvents are used by industry to remove contaminants such
as adhesives, inks, paint, dirt, soil,  oil, and grease.  Parts,  products,  tools, machinery,
equipment, vessels, floors, walls, and other work areas are cleaned for a variety of
reasons including housekeeping,  safety, operability, and to avoid product contamination.
Solvents are used in enormous volumes and a portion evaporates during use, making

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cleaning fluids a major source of emissions of VOC.  Data collected by EPA show
nationwide usage of VOC solvent from only six industries is about 380,000 megagrams
per year (Mg/yr) (410,000 tons per year [tons/yr]). Less comprehensive data from other
sources suggest total VOC solvent usage for cleaning by all U. S. industry is more than 1
million tons each year.

       On average, 25 percent or more of the solvent that was used for cleaning purposes
by the six industries (automotive,  electrical equipment, metal furniture, photographic
supplies, packaging, and magnetic tape) used for the study was lost by spillage or
evaporation.  This value varied  significantly among industries  depending on the type of
cleaning performed.

       All use of solvent for cleaning can be evaluated on the basis of one of only nine
general types: cleaning of spray guns, spray booths,  equipment, large manufactured
components,  small manufactured components, floors, tanks, lines, and parts.  Within
each group, however, there is considerable variation, including differences in cleaning
techniques, soils removed, solvency,  and a likely host of others.

       Emission reduction techniques can be grouped into two categories - those that
reduce evaporation at the source (unit operation) and those that control emissions.
Actions that may reduce emissions at the source include switching to a different cleaner,
reducing usage rates, and increasing collection of used solvent. Reduced usage and
increased collection may be accomplished by changing work practices, modifying
equipment (e.g., tools used in cleaning, solvent storage vessels, solvent dispensers), or
changing a process.  After the release of emissions, the only way to reduce emissions is
with containment or capture and use of an add-on air pollution control device.
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3.2.26        Petroleum Drycleaning Solvents "

       Dry cleaning is a service industry, involved in the cleaning of apparel or renting
apparel.  Basically, the industry is segregated into three areas based on customers and
types of services offered.  These areas are:   (1) coin-operated, (2) commercial, and (3)
industrial.  The industry is also subdivided according to the type of solvent used which
are: petroleum solvents, perchloroethylene (perc), and trichlorotrifluorethane (Freon-
113®).  Freon-113 and perc will not be discussed further since they are considered
negligibly reactive.  Dry cleaning operations are similar to detergent and water wash
operations.  There are approximately 6,000 facilities in the United States with petroleum
dry cleaning  equipment.

       VOC's are emitted from dryers, washers, solvent filtration systems, settling tanks,
stills, and piping and ductwork associated with the installation and operation of these
devices.  Because of the large number of variations  in the types of equipment and
operating practices, in dry cleaning plants there is a large variation in emission rates.
For that reason, details on emission factors  or typical plant emission  rates will not be
discussed here.  The emission sources in dry cleaning plants can be characterized  in two
broad groups - vented and fugitive emissions.  Solvent is vented from article dryers,
solvent stills, and filter and article drying cabinets.  The largest source of vented
emissions is  from article dryers.  Fugitive emissions occur from all equipment in dry
cleaning facilities, however, these emissions vary greatly since they are dependent on
equipment  operating and good housekeeping practices.  The major fugitive emission
sources are solvent or liquid leaks from pipes or ductwork, and wet or not completely
dried articles, used-wet filters,  and  solvent and still  waste which are all left in open
containers  in or outside dry cleaning facilities.

       New petroleum article dryers using water cooled condensers have only  recently
been available and have been demonstrated to achieve emission reductions of
approximately 80 percent (or reduced outlet emissions to 3.5 kilograms per 100 kilograms

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of articles cleaned).  Fugitive emission sources are controlled by improved operating and
maintenance practices.

3.2.27        Agricultural Insecticides and Herbicides °

       Insecticides are used in agriculture to destroy or control populations of harmful
insects.  Herbicides are chemical weed killers that are used extensively on farms and
other areas.  Herbicides are grouped using a multiple-classification system based on
selectivity, mode of action (contact versus translocation), timing of application,  and areas
covered. Herbicides are classed as selective when they are used to kill weeds without
harming the crop and as nonselective when the purpose is to kill all vegetation.   Contact
herbicides kill the plant parts to which the chemical is applied, whereas translocated
(systematic) herbicides are absorbed by roots or above-ground parts of plaints and then
circulate within the plant system to distant tissues.

       Until the introduction of synthetic organic insecticides in 1940, a variety of
materials had been used as insecticides, including extracts of pepper and tobacco,
vinegar, turpentine, fish oil, brine, sulfur, hydrogen cyanide gas, and petroleum oils.
Since the introduction of synthetic organic insecticides, a variety of compound classes
have been used, including organochlorines, organophosphates, organosulfurs, carbamates,
formamidines,  dinitrophenols, and synthetic pyrethroids.  These compound classes have
various modes  of action including physical toxicants,  axonic poisons, central nervous
system  synaptic poisons, enzyme inhibition, metabolism, and  narcotics.

       Pesticides may be applied as liquids, dry solids, or gases.  Liquid pesticides are
applied as a spray of water or oil droplets containing a solution or suspension of active
ingredients.  Pesticides formulated as dusts or granules are  normally applied dry.
Pesticides that  exist in a gaseous state at ambient temperature and pressure may be
applied either as gases or pressurized liquids or as solids that vaporize upon release.
This type of pesticide application is known as fumigation.

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       World usage of pesticides is valued at approximately $23 billion annually. The
United States is the leading user of pesticides, accounting for an estimated 29 percent of
the total world volume of pesticide usage (in pounds of active ingredient) in 1989. The
U.  S. produced approximately 1.3 billion pounds (Ib) of the active ingredients used in
pesticides, valued at $7.5 billion retail.

       The VOC emission reduction from agricultural pesticide application has been  on
the solvent content in the formulations of emulsifiable concentrates.  In addition  to
reducing the VOC content in solvent-based liquid pesticides, reasonable control
alternatives include reducing the use of organic fumigants and improving efficiency of
application methods.  In general, these control alternatives can be applied to agricultural
pesticides; however, there may not be an alternative formulation for a given emulsifiable
concentrate or a pesticide substitute for a fumigant in a certain situation.

       Emissions of VOC's from pesticide applications are the result of volatilization of
the active ingredient (AI), organic solvents, emulsifiers, and other organic compounds
that may be used in the formulation.

3.2.28        Cutback Asphalt Paving Materials 6

       Liquefied asphalts are generally prepared by cutting back or blending asphalt
cement with petroleum distillate or by emulsifying asphalt cement with water and an
emulsifying agent.  Heated asphalt cement  is generally used to make asphalt pavements
such as asphalt concrete.  Cutback and emulsified asphalt are used in nearly all paving
applications.  In most applications, cutback and emulsified asphalt are sprayed directly on
the road surface; the principle other mode is in cold mix applications normally used for
wintertime patching.

       Emissions from cutback asphalt occur as the petroleum distillate (diluent)
evaporates; the average diluent content in the cutback is 35 percent  by  volume.  The

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percentage of diluent to evaporate is dependent on the cure type. The emission factors
are: slow cure (SC) - 20 to 30 percent of diluent content, average 25 percent; medium
cure (MC) - 60 to 80 percent, average 70 percent; rapid cure (RC) - 70 to 90 percent,
average 80 percent. These factors are independent of the percent of diluent in the mix
within the normal range of diluent usage for cutback asphalts.

       The technology to control hydrocarbon emissions from these paving operations
consists of substituting emulsified asphalts in place of cutback asphalts. Emulsified
asphalts use water and non-volatile emulsifying agents for liquefaction; virtually no
pollutants are emitted  during the curing of emulsions.  Emulsified asphalts are used
widely in the construction and maintenance of pavements ranging from high traffic
volume highways and airports to low-volume rural roads and city streets.

3.2.29       Synthetic Fiber Spinning Solvent ^

       Synthetic fibers are manufactured as continuous filaments (which may then be
chopped into staple) of modified cellulose or manmade polymers.  They are used to
manufacture carpets, apparel, industrial textiles, rope, tires, cigarette filters, and
composite materials.  There are three broad  manufacturing classifications:  melt spinning,
solvent spinning, and reaction  spinning.

       In the melt-spinning process, a thermoplastic polymer is heated to  aibove its
melting point and is forced (extruded) through a spinneret (a group of orifices).  The
filament solidifies as it is quenched in a stream of cool air or other medium.   Typical
polymers suitable for melt spinning are polyesters, nylons, and polyolefins.  Melt-
spinning accounts for the preponderance of synthetic fiber production in the United States
with 2,300,000 Mg (5.0 billion Ibs) produced in  1983. There are approximately 130
plants engaged in melt-spinning.
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       Solvent spinning can be subdivided into two types of processes, wet or dry.  Both
first require the polymer to be dissolved in a suitable solvent at a ratio of about three
parts solvent to one part polymer.  In wet spinning, the polymer solution is extruded
through a spinneret that is submerged in a liquid that extracts the solvent, thereby
precipitating the polymer filament. In dry spinning the polymer solution is extruded into
a zone of heated gas that evaporates the solvent leaving the polymer filament behind.

       A third process, reaction spinning, is much like wet spinning.  A low molecular
weight fluid  "prepolymer" is extruded into a bath containing a co-reactant which causes
formation of the filament by polymerization.  This process is  minor tonnage-wise and
henceforth will be included in the discussion of the wet spinning process.

       Typical polymers suitable for  solvent spinning are acrylics, modacrylics, acetates,
triacetates, rayon, and spandex.  Approximately  1,400,000 Mg (3.0 billion Ib) of solvent-
spun fiber were produced in the U. S. in 1983 at approximately 20 plants.

       Once spun, all fibers undergo post-spinning processing.  It may involve one  or
more of  the following:  washing, stretching,  cutting (into staple),  crimping, twisting,
drying, and finally packaging.

       Solvents are not used in melt-spinning; therefore, all VOC emissions are due to
unreacted monomer and oils applied to the filaments as they emerge from the spinneret.
Emissions may occur in the exhaust from the quenching step or any of the post-spinning
processing steps that require steam, hot water, or dry heat.  The monomer concentrations
are usually quite low.  The lubricating oils have rather low  vapor pressures and often
condense into a visible aerosol.

       Melt spinning and the associated post-spinning processes, if controlled at all, are
usually served by fabric filters, rotoclones, scrubbers,  or electrostatic precipitators.  Since
the uncontrolled emission rates are small, controls are installed at the plant's discretion.

                                         3-33

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Removal efficiencies have not been determined by EPA.  The textile industry has
reported reductions of similar types of emissions by 70 to 95 percent.

3.2.30        Fabric Coating ^

       Fabric coating involves the application of decorative or protective coatings to a
textile substrate.  A large segment of this industry is application of rubber coatings to
fabrics. More specifically,  for purposes of the regulatory program, fabric coating is the
uniform application of (1) an elastomeric or thermoplastic polymer solution, or (2) a
vinyl plastisol or organisol,  across all of one (or both) side of a supporting fabric surface
or substrate.  The coating imparts to the fabric substrate such properties as elasticity,
strength, stability, appearance, and resistance to abrasion, water, chemicals, heat, fire, or
oil.  Coatings are usually applied by blade, roll coater, reverse roll coater, rotogravure
coater,  or dip coater.

       The basic fabric coating process includes preparation of the coating, the
application of the coating to the substrate,  and the drying/curing the applied coating.  The
web substrate is unwound from a continuous roll, passed through a coating applicator and
drying/curing oven,  and then rewound.   There are at least 130 fabric coating plants
located throughout the United States.

       The major sources of VOC emissions in a fabric coating plant are the mixer and
coating storage vessels, the  coating applicator,  and the drying oven.  The relative
contribution of these three areas are estimated at 10 to 25 percent,  20 to 30 percent, and
45 to 70 percent, respectively. The potential VOC emissions from a fabric coating plant
are equal to the total solvent used at the plant.

       Incineration is the most common means for control of coating application and
curing emissions  on fabric coating lines which use a variety of coating formulations.
Coalers which use a single solvent can be most economically controlled by carbon

                                         3-34

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adsorption.  Either of these control devices can reduce the VOC emissions in the gases
directed to the device by 95 percent or more.  Inert gas  condensation systems may be
applicable to some fabric coating lines.  Such systems are estimated to be about 99
percent efficient in the recovery of solvent which passes through the system.
3.2.31       Fabric Printing 6
       Fabric printing is application of a decorative design to a fabric by intaglio (etched)
roller (another name for rotogravure),  rotary screen, or flat screen printing operation.
The fabric web passes through the print machine where a print paste is applied to the
substrate.  After leaving the print machine, the web passes over steam cans or through a
drying oven to remove water and organic solvent from the printed product.  After the
drying process, the fabric is washed and dried again.  There are approximately 200 fabric
printing plants located throughout the United States.

       The most significant source of VOC emissions in a fabric printing plant is the
drying process, either the steam cans or the ovens.  Other emissions occur as fugitive
VOC.  These are as evaporation from  wastewater streams, open print paste barrels,
printing troughs, the printing rollers and screens, "strikethrough" onto the backing
material, and from the printed fabric before  it reaches the  drying process. Average
emission factors for printing fabric are 142 kg VOC per 1000 kg fabric for roller
printing, 23 kg VOC per 1000 kg fabric  for rotary screen  printing, and  79 kg VOC per
1000 kg fabric for flat screen printing.

3.5    REFERENCES
1.    U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
      North Carolina, Architectural and Industrial Maintenance Coatings, Draft Report,
      September 1994.
                                       3-35

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2.     U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
       North Carolina, Alternative Control Techniques - VOC Emissions from Automobile
       Refinishing, (EPA-453/R-94-031), April 1994.

3.     Aerospace Paints and Coatings NESHAP - Proposed Rule under 40 CFR Part 63,
       59 FR 29216, June 6, 1994.

4.     U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
       North Carolina, Wood Furniture Coatings NESHAP - background for proposed
       rule (under development)

5.     U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
       North Carolina, Alternative Control Techniques - Surface Coating Operations At
       Shipbuilding and Ship Repair Facilities, (EPA-453/R-94-032), April 1994.

6.     U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
       North Carolina, Alternative Control Techniques - Control Techniques for Volatile
       Organic Compound Emissions from Stationary  Sources,  (EPA-453/R-92-018),
       December 1992.

7.     U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
       North Carolina, Alternative Control Techniques - Industrial Cleaning Solvents,
       (EPA-453/R-94-015), February 1994.

8.     U.S. EPA Office of Air Quality Planning and Standards, Research Triangle Park,
       North Carolina, Alternative Control Techniques - Control of VOC Emissions from
       Agricultural Pesticide Application, (EPA-453/R-92-011), March  1993.
                                      3-36

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             4.0   PRODUCTS  ADDRESSED BY  SPECIAL STUDIES

4.1       INTRODUCTION

   Several categories of products fall outside the scope of categories covered in Sections 2
and 3. These categories were the subjects of special studies carried out to develop 1990
emission estimates based on information in the literature. For those products for which data
on emissions was not available, any useful information (such as VOC content and function of
the product) was summarized and included here.  Specific methodology is discussed for each
category included.  All emission estimates discussed in the following sections are nationwide
estimates.  However, the summary estimates presented in Table 4.1-1 and in Section 1.5
have been scaled down based on population in ozone nonattainment areas (see Section 1.4.2).

4.2       CONSTRUCTION MATERIALS

4.2.1      Building Materials and Indoor Air Sources

4.2.1.1    Description

   Since the mid-1970's, a growing number of complaints have surfaced regarding the
indoor environment to which occupants of modern buildings are exposed.  Energy efficiency
also became increasingly important during this time. Consequently, new buildings were
being built with less outside air infiltration, thus confining more indoor air pollutants. Since
the early 1980's, much work has been done by the EPA and other groups to identify and
measure VOC emission rates from building materials and consumer products in small test
chambers and laboratories. * The purposes of this section are to describe the latest efforts in
determining emission rates from building materials and to try and develop a national VOC
emissions estimation for these building materials.
                                         4-1

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               TABLE 4.1-1
VOC EMISSIONS IN NONATTABSMENT AREAS FOR
   PRODUCTS COVERED BY SPECIAL STUDIES
Category
CONSTRUCTION MATERIALS
Particle board
Plywood
Wallpaper
Carpeting
Roofing - built-up
Roofing - elastomeric
Roofing - modified bitumen
Asphalt concrete paving materials
FOODS, BEVERAGES, TOBACCO
Alcoholic beverages
Deep-fat frying oils
Smoking tobacco
SMALL COMBUSTION SOURCES
Kerosene space heaters
Camp stoves, lanterns, heaters
Artificial fire logs
TEXTILE INDUSTRY
Platen Adhesives
Equipment cleaning solvents
Spot Cleaners - Screen Printers
Nonattain Area
Emissions
(tons/year)

#
*
*
*
7,126 a
9,123 a
2,276 a
360 a

11,600 a
*
37 a

39 a
6a
154 a

2,092 a
68 a
848 a
Year





1989
1989
1989
1991

1990
1990
1987

1990
1990
1990

1990
1990
1990
Ref

9
9
9
9
10
10
10
11

9
9
9

9
9
9

12
12
12
                  4-2

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                                  TABLE 4.1-1
              VOC EMISSIONS IN NONATTAINMENT AREAS FOR
                  PRODUCTS COVERED BY SPECIAL STUDIES
                                   (Continued)
Category
Spot Cleaners - Woven Goods
Spot Cleaners - Knit Goods
MISCELLANEOUS PRODUCTS
Mold Release Agents
Automotive Repair - Parts Washers
Fiberglass Boat Manufacturing Products
TOTAL FOR THIS TABLE
Nonattain Area
Emissions
(tons/year)
0
0

75,400 a
2,607 a
12,100 a
123,836
Year
1990
1990

1989
1987
1990

Ref
12
12

10
11
13

Key to Table 4-1

*  This category was investigated and is discussed in the text, but an emission estimate
   could not be developed based on the available information.

a  Nonattainment area emission estimates were obtained by adjusting nationwide estimates
   according to the distribution of nationwide population in nonattainment areas in 1990.
   Estimates for categories without this footnote were determined specifically for
   nonattainment areas and needed no further adjustment.
    148 million (nonattainment areas)
         248 million (nationwide)
=   59.68%
60%
                                      4-3

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   The building materials source category contains a number of different product lines, each
with a variety of manufacturers and manufacturing methods.  For the purposes of this report,
the term building materials refers to carpet, plywood, particle board, chipboard, fiberboard,
treated lumber, gypsum board, laminated plastics, insulation, linoleum, and wallpaper. Each
of these materials has been found to have the potential of emitting various types of VOC's
during their expected lifetime. These materials are present in many kinds of structures
including apartments, automobiles,  commercial buildings, hospitals, mobile homes, nursing
                                             f\
homes, office buildings, residences, and schools.   The use or consumption of new building
materials is highly dependent upon  the current economic situation. Higher economic growth
generally leads toward business expansion, house building, automobile sales, etc., which
cause an increase in building material consumption.

   The available information on the qualitative analysis of speciated VOC emissions  from
various building materials is presented in Table 4.2-1.  This table includes sources for which
some current substantiated data on  speciated VOC's are available.  Substantiated sources are
those for which either quantitative or qualitative emissions data have been obtained.   The
information presented in Table 4.2-1  should be used with some caution because the
composition of materials and products changes over time as manufacturers alter their
                                   o
manufacturing processes and products.

4.2.1.2   Estimating VOC Emissions from Building Materials

   Previous studies of building materials have shown emissions to be very dependent upon
test variables such  as air exchange  rate, temperature, humidity, product loading (area of
product/volume of test chamber), and age of material.  ''   To date, much research  has
been conducted to  determine the concentrations of speciated VOC's in the ambient air
surrounding building materials. This research has been performed in chamber tests,
laboratory experiments, and  on-site tests of various types of buildings.  However, only a
limited number of  these studies have developed emission rates for these materials.  Several
short term tests (/. e., days and weeks) have specified emission rates calculated as an  average
for the duration of the experiment.  However, based on the current available literature, no
                                          4-4

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 TABLE 4.2-1. .SUBSTANTIATED BUILDING MATERIAL SOURCES OF VOCsa
        VOC
 Chemical
 Formula
                      Substantiated
                         Sources
Formaldehyde

Ethanol
Acetone
Methyl acetate1
Isopropanol
2-Butanone (MEK)
Benzene
Ethylacetate
n-Butanol
n-Hexane
2-Methylpentane
Benzaldehyde
Toluene

Heptane
Styrene
Xylenes
Ethylbenzene
Nonane
1,2,4-Trimethylbenzene
n-Propylbenzene
Isopropylbenzene
Limonene
a-Pinene
Decane
Undecane
4-Phenylcyclohexene
CH2O
C4H80
C4H802
C4H100
C6H14
C6H14
C7H8
C7H16
C8H8
C8H10
C8H10
C9H12
C9H12
C10H16
C10H16
C11H24
C12H14
carpeting, particle board, plywood, paneling, fiberboard,
chipboard, gypsum board, ceiling panels, urea foam insulation,
linoleum
fiberboard
particle board
plywood
particle board
fiberboard, particle board
particle board
linoleum floor covering
linoleum
chipboard, gypsum board, insulation foam
chipboard, gypsum board, insulation foam, wallpaper
fiberboard, particle board
chipboard, wallpaper, vinyl coated wallpaper, linoleum floor
covering
particle board
fiberboard, insulation foam
wallpaper
chipboard, fiberboard, insulation foam
chipboard, wallpaper
chipboard, linoleum floor covering, vinyl coated wallpaper
chipboard, insulation foam
insulation foam
chipboard
fiberboard, gypsum board, chipboard
chipboard, fiberboard, wallpaper
gypsum board, chipboard, wallpaper
latex backing on carpets
From reference 2 except where noted.
                                          4-5

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long term tests (i.e., one year) have been conducted to determine an annual average speciated
VOC emission rate from any one specific type of building material. Therefore, no
annualized total or speckled VOC emission estimates from building materials can be
developed at this time.

   Some emission rates have been developed for formaldehyde from wood products-*'4'5 and
4-phenylcyclohexene from carpeting" and are presented in Table 4.2-2. No information is
presented  for chipboard, gypsum board, laminated plastics, insulation, linoleum, or
wallpaper.  Only one source had information for chipboard and gypsum board, and no test
parameters or conditions were given.  Also, no information was available for laminated
                                                                    *j
plastics, although one contact is currently conducting tests on the material.'

   Table 4.2-2 shows that measured formaldehyde emission  rates for particle board vary
across two orders of magnitude based on information from three separate references. The
second and third table entries for particle board illustrate the significance  of time variation
(age of material) on emissions (/. e.,  emissions decrease with time as a building material ages
and loses VOC content).  Plywood emissions exhibit similar  characteristics; two separate
studies indicate a very wide range of formaldehyde emission rates.

   Table 4.2-2 also illustrates the variability of the magnitude of carpet emissions.   One
reference cited the range (from separate studies) of measured formaldehyde emissions from
                                       9                                        5
carpeting to  be between zero and 2.7 fig/m  h (micrograms per square meter per hour).
Another reference indicated that 4-phenylcyclohexene emissions from latex-backed carpets
may drop  by nearly 50 percent in a period of one week.   Emissions of 4-phenylcyclohexene
have been found to be the cause of the "new carpet" smell.

   Separate studies have also shown that indoor ventilation rates can have a significant
impact on the both the concentration of VOC in a building and the  amount of VOC emitted
from a particular building material.  '° Specifically, one study of carpet revealed that, as the
rate of air changes per hour (ACH) increased (outside air), the concentration of VOC's
dropped.  However,  the actual emission rate of VOC from carpet may increase due to the
                                         4-6

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  TABLE 4.2-2. EMISSION FACTORS FOR VARIOUS BUILDING MATERIALS
Source
Particle board
Particle board
Particle board
Particle board
Plywood
Hardwood
plywood
Softwood plywood
Wallpaper
Carpeting
Latex-backed
carpet
Latex-backed
carpet
Emission
Factor
(Mg/nA)
200
2,000
140
83 - 1,040*
5 - 720C
62.5 - l,420a
1 -lla
0.1
0 - 2.7a
150
80
Condition
2 yrs old
new
low density -
aged 8 months
NAb
after 24 hours
NA
NA
NA
NA
1 week old
2 weeks old
Compound(s)
total vapor-phase
organic compounds
formaldehyde
formaldehyde
formaldehyde
formaldehyde
formaldehyde
formaldehyde
total vapor-phase
organic compounds
formaldehyde
4-phenylcyclohexene
4-phenylcyclohexene
Reference
4
4
3
5
1
5
5
4
5
4
4
a The range of emission
studies.
presented is
on
s own summary of various
  NA denotes information not available.

c Four different brands of plywood were tested in this study; the results show the range of emission factors
found.
                                       4-7

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                                                        o
increased movement of air particles around the carpet fibers.

   Based on these findings, there does not appear to be enough consistent emission rate data
available to warrant a reliable annual emissions estimation from building materials. Although
current testing is under way to obtain more reliable data,  it would not be feasible at this time
to develop  emissions estimations for the building material products described in this report.
However,  when these data become available, estimations of emissions for these product
categories can be made with some degree of reliability.

4.2.2     Roofing Materials 9

4.2.2.1   Description

   A modern roof design normally  includes a structure to carry loads, insulation to control
heat flow, a barrier to control air and vapor flow, and vapor retarders to prevent water
retention.   Several different types of roofs have been developed to accomplish these
objectives.   The main types of roofs used today are sloped roofing materials (e.g., asphalt
shingles, wood shakes and shingles, slate roofs, thatched roofs, etc.), built-up roofing
(BUR), elastomeric (primarily ethylene-propylene-diene monomer,  or EPDM), thermoplastic,
modified bitumen (MBR), and liquid-applied roofing.

   The total amount of commercial/industrial roofing performed in 1989 was approximately
3.3 billion  square feet, with 1.3 billion square feet as BUR, 1 billion square feet as EPDM,
and 0.7 billion  square feet as MBR.  These three roofing types make up over 90 percent of
the commercial roofing market.  This report focuses on the processes and emissions from
BUR, EPDM, and MBR.  Sloped roofing materials, which are used primarily in residential
situations, are considered to be a very minor source of emissions.  Thermoplastic and liquid-
applied roofing applications are not included here due to their relatively minor share of the
total roofing market.
                                          4-8

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4.2.2.2   Built-Up Roofing

   In 1970, BUR was 90 percent of the roofing market; in 1989 it was less than 40 percent.
In the BUR application process, several layers of felts, insulations, and other materials are
applied using hot asphalt, asphalt emulsions, or asphalt mastics.  Coal tar may be used in
place of asphalt.

   BUR processes vary by manufacturer specifications, however, three major types of BUR
processes have been identified. These processes are differentiated by the type of adhesive
used to bond the roofing materials to the roof.  The three most common types of adhesives
are hot asphalt, asphalt emulsions, and asphalt mastics. A typical BUR reroofing job begins
with surface preparation of the roof by removing the old roof and surfacing material (e.g.,
gravel).  After the surface is prepared, an asphalt primer is applied if the deck is constructed
of concrete.  Next,  a base ply or insulation layer is applied using hot asphalt or cold process
asphalt.  Several layers of felts are then attached to the roof with an intermediary layer of
asphalt between each layer.  A cap sheet  layer is then applied, followed by  a flood coating of
asphalt to seal the roof.  Flashing, vents, and other areas of the roof receive a layering of
flashing cement to provide extra sealing capabilities in these areas.  Solvent cleaners are  used
to remove asphaltic materials from tools and may also be used by workers to clean their
hands.  Emissions points for BUR are the application of roofing  materials using asphaltic
compounds, flashing cements, asphalt primers, and cleaning operations.

4.2.2.3   Elastomeric Roofing

   Elastomeric roofing consists of natural and synthetic rubbers and rubberlike materials.
The most common elastomeric roofing material is ethylene-propylene-diene  monomer
(EPDM). Three methods have been identified for the application of EPDM roofing systems:
loose-laid and ballasted, comprising 70 percent of the total; fully-adhered, comprising 20
percent of the total; and mechanically-fastened, comprising  10 percent of the industry. A
typical fully-adhered EPDM roofing process involves removing the old roofing system,
surfacing  materials, and debris, leaving a clean substrate.  EPDM sheets are laid side-by-side
                                          4-9

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with a three inch overlap and are bonded to the roof using bonding cement. The seams are
cleaned and primed in preparation for taping. Tape is applied to each seam leaving a
waterproof surface. General cleaning operations are carried out daily to remove roofing
materials from skin, tools, clothing, etc.  Emissions result from the use of primers, cements,
and cleaners.

4.2.2.4   Modified Bitumen Roofing

   The MBR process is very similar to the BUR category.  Modified bitumen sheets are
constructed using asphaltic materials like BUR felts and plies, but are augmented by adding
thermoplastic materials like styrene-butadiene-styrene (SBS) or atactic polypropylene (APP).
These plasticizers lend greater elongation and roof movement tolerance. The modified
bitumen sheets are typically built-up in the factory.  Fewer layers of modified bitumen sheets
are applied in a typical roofing job than  in a BUR job since the MBR sheets are already built
up.

   Modified bitumen can be applied in several ways, including hot asphalt, propane torch-
activated adhesive and self-adhering sheets; squeegee-applied cold adhesives; and spray-
applied  cold adhesives.  The most common means of attaching MBR are hot asphalt, torch
activation, and self-adhering sheets, representing 99 percent of the market.  Title hot asphalt-
applied  MBR process is similar to the BUR process.  The old roofing material or surfacing
material is removed, or the roofing surface is cleared, leaving a clean substrate. An asphalt
primer is applied to concrete decks.  The MBR plies are applied  using hot asphalt.  Only a
few MBR plies are required where the BUR process requires several plies.  Flashing cement
is used around vents and other exposures.  General cleaning operations are performed on an
intermittent basis.  The squeegee-applied and spray-applied MBR systems are similar in the
application process, but much higher in emissions.
                                         4-10

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4.2.2.5   Other Roofing Types

    Several other types of roofing are used in the roofing industry:  asphalt shingles, metal,
thermoplastics, foam, and others.  These roofing processes are not considered in this report
due to their limited usage in the roofing industry or their low VOC emissions potential.
These alternate roofing types and some possible emissions points are described below.

    Asphalt shingles are composed of asphalt, minerals, binders, and fillers.  Some heat-
activated adhesives are used which bond the shingles to the roof after they are mechanically
attached.  Emissions from these adhesives are not expected to be significant.

    Metal roofs are typically applied using mechanical fasteners.  Sealants and caulks may be
used for waterproofing attachment areas.  Also, rust inhibitors and metal preparation solvent
may be used to protect the metal from corrosion.  Emissions points include the sealants,
caulks,  rust inhibitors, metal solvents, and general cleanup operations.

    Thermoplastics such as hypalon roofing  materials are similar to EPDM in their
application processes.  Thermoplastics are applied in sheets and may be bonded by heat or
solvent welding.  Emissions points include the solvent used for welding, cleaners for
thermoplastic surface preparation, and general clean up operations.  No significant emissions
are expected from heat welding.

    Polyurethane foams and other types of foam roofing  materials have found a small niche
in the roofing industry.   The foam is applied in  liquid form to the roof.  The liquid foam
expands and  hardens to form a waterproof layer.  The blowing agent used to spray the liquid
foam onto the roof may be a significant source of emissions for this category.  Emissions
may also be associated with the protective paints and coatings and cleaning solvents used.
                                          4-11

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4.2.2.6   Development of VOC Emission Estimates

   Emissions were estimated for the three major roofing types (BUR, EPDM, and MBR)
based on total square feet worked for each roofing type, material usage per square foot of
roof by roofing type, and VOC content of the materials used.  Assumptions were required
where no data were readily available.  Table 4.2-3 provides estimates of total area worked
annually in million square feet by roofing category.
 TABLE 4.2-3   SUMMARY OF ROOFING AREA WORKED BY ROOF TYPE (1989)
ROOFING TYPE
Built-Up Roofing
Hot Asphalt
Asphalt Emulsion
Asphalt Mastic
EPDM
Fully-Adhered
Loose-Laid
Mechanically Fastened
Modified Bitumen
Hot Asphalt/Torch/Self-Adhering
Squeegee Applied Adhesive
Spray Applied Adhesive
TOTAL
AREA WORKED
(million square feet)

1,235
32.5
32.5

200
700
100

630
35
35

1,300



1,000



700



3,000
                                      4-12

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   Within BUR, emissions were estimated for three processes:  hot asphalt, asphalt
emulsions, and asphalt mastics.  Approximately 1.3 billion square feet of BUR was applied
in 1989.  According to a roofing manufacturer representative, 95 percent or more of BUR
was applied using hot asphalt and five percent or less used asphalt emulsion or asphalt
mastic. It is assumed that the remaining five percent is divided equally between asphalt
emulsion and asphalt mastic.

   The total square footage of elastomeric roofing in 1989 was 1 billion square feet.
Elastomeric roofs are dominated by EPDM and may be applied by three different processes.
The elastomer may be loose-laid and ballasted, fully-adhered, or mechanically fastened.
Loose-laid EPDM is applied 70  percent of the time, fully-adhered represents 20 percent of
the total, and mechanically fastened represents 10 percent of the total. Only loose-laid and
fully-adhered EPDM systems were evaluated in this study.  Fully-adhered elastomeric roofs
are most commonly applied using bonding cement which consists of solvent and rubber
compound. Composition and usage rates for EPDM roofing were taken  from a roofing
manufacturer's specifications.

   The total amount of MBR applied in 1989 was  700 million square feet.  Hot asphalt,
torch-activated adhesive, and self-adhesive sheets make up 90 percent of the MBR market.  It
is assumed that the squeegee-applied and spray-applied cold adhesives make up five percent
each of the MBR market.

4.2.2.7   Summary of Emission Estimates from Roofing Application

   Total nationwide VOC emissions are 30,874 tons for application of roofing materials.
The total square  footage for roofing work in  1989 was 3 billion. The resulting average
emission factor is 0.021  pounds  VOC per square foot. A summary of the roofing processes,
emissions, and emission  factors  is given in Table 4.2-4.
                                         4-13

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         TABLE 4.2-4   VOC EMISSIONS FROM ROOFING APPLICATION
Roofing
Category
BUR



EPDM



MBR


TOTAL
Application
Process
Hot Asphalt
Emulsion
Asphalt Mastic

Fully-Adhered
Loose-Laid
Mech Fastened

Hot asphalt
Squeegee
Spray

Total VOC
Emissions
(tons/yr)
6094
860
4922

10678
4527
0

3186
207
400
30,874
Area Worked
Annually
(106 ft2)
1235
32.5
32.5

200
700
100

630
35
35
3,000
Emission
Factor
(Ibs/ft2)
0.01
0.05
0.30

0.11
0.01
0

0.01
0.12
0.23
0.021 a
   Weighted average of emission factors and total square footage.
4.2.3
Asphalt Concrete Paving Materials
                                          10
4.2.3.1    Description

   Generally, paved roads are constructed of either bituminous asphalt concrete or portland
cement concrete.  Asphalt concrete is blended at a facility that may be located several hours
from the job site.  The hot asphalt concrete mixture (hot mix) is blended and maintained at
approximately 300°F until being laid and compacted.  The major constituent of asphalt
                                        4-14

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concrete is aggregate, a mixture of sand and gravel.  Asphalt, a derivative of the bottom cut
in the distillation of crude oil, serves as the binder for the aggregate.  A variation is
formulated by dissolving asphalt with kerosene and naphtha (i.e. cutback asphalt). Emissions
from cutback asphalt paving materials are presented in Section 3 of this report.  Therefore,
the following discussion is limited to asphalt concrete.

    An estimated 460 to 500 million tons of hot mix was prepared in 1991. This estimate
does not include cutback asphalt.   Approximately 5 percent of the hot mix is asphalt.
Asphalt concrete contains low concentrations of VOC's when properly prepared.  A common
test to determine the suitability of asphalt concrete is the "loss on heating" test.  When
heated,  if more than 0.5 percent volatilizes, the material is rejected.  In practice, asphalt
concrete typically contains about 0.0025 percent  VOC.

4.2.3.2     VOC Emissions from Asphalt Concrete

    Based  on 500 million tons of asphalt concrete used annually, the usage of asphalt cement
in this material (5%) is estimated to be 25 million tons nationwide.  At a typical VOC
content  of 0.0025 percent, the asphalt cement contains approximately 600 tons of VOC.  It is
assumed that all the VOC's contained in the concrete are emitted.

    In the  asphalt paving industry, regular equipment cleaning currently is performed using
high pressure water sprays rather than solvents, although this has not always been the
practice.  However, many construction crews coat the truck and hopper beds with diesel fuel
to prevent sticking. The asphalt concrete absorbs any excess liquid, which ultimately
evaporates.  Diesel fuel is also used to clean shovels and rakes. There is insufficient data to
develop an estimate of these additional emissions.

4.2.4     References for Section 4.2

1.        van der Wai, Jan F., Steenlage, Ronald,  and Hoogeveen, Ank W.  "Measurement
          of Organic Compound  Emissions from Consumer Products in a Walk-in Test
          Chamber" in the Proceedings of the 5th International Conference on Indoor Air
          Quality and Climate.  Volume 3.  Ottawa, Canada.  July 29-August 3,  1990.
                                         4-15

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2.        Samfield, Max M.  Indoor Air Quality Data Ease for Organic Compounds. EPA-
          600-R-92-025. U.S. Environmental Protection Agency, Air and Energy
          Engineering Research Laboratory, Research Triangle Park, N.C. February 1992.

3.        Mason, Mark A. and Tichenor, Bruce A.  "Organic Emissions from Consumer
          Products and Building Materials to the Indoor Environment" in the Journal of the
          Air Pollution Control Association.  38: 264-268, 1988.

4.        Tucker, W. Gene.  "Emissions of Air Pollutants from Indoor Materials:  An
          Emerging Design Consideration"  Paper presented at the 5th Canadian Building
          and Construction Congress.  Montreal, Canada.  November 27-29, 1988.

5.        Godish, Thad, Indoor Air Pollution Control Lewis Publishers, Chelsea, MI 1989.

6.        Singhvi, R., Burchette, S., Turpin, R., and Lin, Y.  "4-Phenylcyclohexene from
          Carpets and Indoor Air Quality" in the Proceedings  of the 5th International
          Conference on Indoor Air Quality and Climate.   Volume 4.  Ottawa, Canada.
          July 29-August 3, 1990.

7.        Teleconference between J. Todd of Scientific Consulting Group in Rockville, MD,
          and L. Loe of TRC Environmental Corporation in Chapel Hill, N.C.  August 28,
          1992.  Discussed current emissions tests.

8.        U.S. Environmental Protection Agency.  Carpet Policy Dialogue - Compendium
          Report September 27, 1991.  EPA/560/2-91-002. Office of Toxic Substances,
          Washington, D.C.  September 1991.

9.        U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
          Park, North Carolina, Source Characterizations and Emission Estimates for Mold
          Release Agents and Roofing Applications, September 1993.

10.       U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
          Park, North Carolina, Evaluation of Volatile Organic Emissions Data for
          Nonprocess Solvent Use in 15 Commercial  and Industrial Business Categories,
          (EPA-600/R-94-019), February 1994.

11.       U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
          Park, North Carolina, Nonprocess Solvent Use in the Textile Industry, August
          1993.

12.       U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
          Park, North Carolina, Project Summary - Assessment of VOC Emissions from
          Fiberglass Boat Manufacturing, (EPA-600/S2-90/019), June 1990.
                                        4-16

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4.3       FOODS, BEVERAGES, TOBACCO

4.3.1     Alcoholic Beverages

4.3.1.1   Description

    Alcoholic beverages include wine, beer, and distilled spirits (e.g., whiskey, rum, brandy,
gin and vodka).  During 1990, consumption of domestic beer in the United States was
estimated to be 192.6 million barrels (5.97 billion gallons (22.6 billion liters)).1  In 1990,
the consumption of domestic wine including wine cooler beverages, was estimated at 509.1
                                  fj
million gallons (1,926 million liters).  In 1990, the consumption of all distilled spirits was
estimated to be 542.4 million gallons (2,053 million liters).  Grain  alcohol, a distilled spirit,
                                                        T
represented 90 percent  of the total distilled spirits consumed.

    It is important for the alcoholic beverage industry to impart desirable characteristics to
these beverages making them acceptable to the consumer. The most important characteristic
of the alcoholic beverages is the flavoring.  Various flavoring and aroma compounds are
added to alcoholic beverages to formulate their typical taste and odor.   These additions may
include many different  volatile and nonvolatile organic compounds, which can be divided into
several groups according to their chemical nature.  Fusel alcohols,  fatty  acids, and esters
form the quantitatively  and qualitatively largest groups in the volatile aroma fraction of
alcoholic beverages.  Carbonyl compounds and phenols, which are relatively smaller in
quantity, are used in flavoring alcoholic beverages.

4.3.1.2   Methods for Estimating VOC Emissions from Consumption of Alcoholic Beverages

    Literature searches  were  conducted for information on emissions from the use of
alcoholic beverages.  Available information  on the VOC components in alcoholic beverages
was identified and reviewed.  Trade associations thought to be knowledgeable on the subject
of alcoholic beverages were identified through the 1993 National Trade and Professional
Associations of the United States.   The Beer Institute, Wine Institute, and the Distilled
                                         4-17

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Spirits Council were contacted to identify and obtain any useful information on emissions
from the use of alcoholic beverages. The only information available from the professional
                                                •I n q
associations was estimates on beverage consumption. 1>Z'J

   The literature search revealed several studies which were performed to determine the
types of compounds and the characteristics they offer to various alcoholic beverages.  All  of
the analytical studies identified were performed on distilled beverages, such as whisky, rum
and scotch; none were identified for beer and wine.  Table 4.3-1 presents some of the
volatile components which were identified through these analyses of distilled spirits.  The
compounds present in Table 4.3-1 were found to be the most abundant in the spirits.
However,  none of the brief reports which summarized the test analyses of distilled spirits
defined the particular spirit analyzed.

   Although numerous VOC compounds have been identified in distilled beverages,
information on the VOC concentration and/or emissions from the consumption and/or
disposal of the product(s) was not available.  Emission factors presented in the Compilation
of Air Pollutant Emission Factors (AP-42) document are specific to alcoholic beverage
production processes and do not address emissions on the consumption or disposal of
alcoholic beverages.

   Although accurate estimates of VOC emissions from the consumption of alcoholic
beverages  were not available, the EPA made a rough estimate  based on annual consumption
and the following assumptions:
   (1)    Alcohol  contents (by volume) for beer, wine, and distilled spirits are 6%, 12%,
          and 40%, respectively.
   (2)    Approximately 5 % of the alcohol content is emitted.

   This procedure  resulted in an  estimate of nationwide VOC  emissions from alcoholic
beverages  of 19,300 tons per year, or approximately 156 pounds per 1000 persons.
                                        4-18

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 TABLE 4.3-1. VOLATILE COMPOUNDS IDENTIFIED IN ALCOHOLIC
                BEVERAGES                                 	
 Compound Group
Volatile Compound
 Fusel Alcohols
3-methyl-1 -butanol
2-methyl-l-butanol
1-propanol
2-methyl-1 -butanol
 Fatty Acid Esters
ethyl acetate
ethyl 9-hexadecenoate
 Phenols
phenol
o-cresol
m-cresol
p-cresol
4.3.2 Deep Fat Frying

4.3.2.1    Description

   Deep fat frying involves the cooking of foods in hot oils or greases.  Potatoes are the
most commonly fried food; other foods include doughnuts, fritters, croquettes and breaded
and batter-dipped fish and meat.  The foods are cooked in externally heated cooking oil vats
at temperatures ranging from 325° to 400°F.7  Volatile organics, paniculate matter, and
entrained fat particles are emitted during the frying process.
   Volatile organic compound (VOC) emissions derive from cooking oils, vegetable oils,
and animal fats which are steam distilled during the frying process.  Most foods contain
approximately 30 to 75 percent moisture before cooking, which causes fats and oils to be
                                        4-19

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steam distilled from the cooking vat.  Cooking oils are usually compounded within
reasonably narrow boiling ranges and, when fresh, very little of the oil is steam distilled.
Most emissions therefore result from  either the food product or from the use of old, "spent"
cooking oil. In general, fish and meat products, which contain higher percentages of fats
and oils, produce greater VOC emissions than do vegetable products.  In addition, excessive
overheating may cause smoke problems. Smoke has been shown to consist of finely divided
particles of fat and oil distilled from either the product or the cooking oil/

   Deep fat fryers are used in restaurants and fast food facilities (commercial deep fat
fryers), and in the kitchens of private homes (residential deep fat fryers).   Most private
kitchens have a hood filter installed over the stove, which may trap some of the paniculate
matter or suspended oils and fats emitted during frying. However, self-contained deep fat
fryers may or may not be used under the hood. Any emissions which are  not vented to the
                                               0
atmosphere may be an  indoor air pollutant  concern.

   Residential deep fat fryers operate mainly during the dinner hours, between 5:00 and
8:00 PM. Although there are many restaurants which operate deep fat fryers only during the
dinner hours of 5:00 or 6:00 to 8:00 PM, peak operating hours for a typical restaurant or
fast food facility are from 11:00 AM  to 2:00 PM,  and again from 5:00 to  9:00 PM, seven
days per week.   Emissions from deep fat  fryers are likely to be highest during these tunes.
It is  unlikely that this source will show much temporal or regional  variation.  It is likely,
however, that the extent of deep fat fryer operation will correlate with population variability.
As a result, trends in deep fat fryer emissions are expected to follow trends in population
growth or dimmishment.

4.3.2.2   Method for Estimating VOC Emissions from the Deep Fat Frying Category

   Emissions of total  organic gases (TOG) from the operation of deep fat  fryers at
restaurants and fast food facilities have been estimated for the South Coast Air Basin  (SCAB)
and the Southeast Desert  Air Basin (SEDAB) of Los Angeles and Riverside counties.^ Total
organic gases are defined by the California Air Resources Board (CARB) as all  gases
                                         4-20

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consisting of substances that contain carbon, except carbon monoxide, carbon dioxide,
carbonic acid,  metallic carbides or carbonates, and ammonium carbonate.  More closely
related to the definition of VOC is a group of compounds known as reactive organic gases
(ROG).  The major difference between the CARE definition of ROG and the EPA definition
of VOC is that the CARB considers the compound ethane to be reactive.  Reactive organic
gases can be determined from TOG by applying an ROG fraction, calculated based on an
assigned profile code for specific SIC/SCC combinations.  The profile code for deep fat
fryers is 600, corresponding to a "species unknown" profile in which it is assumed that 25
percent of the  total organic gases consist of methane (additional compounds included in the
"species unknown" profile include cyclopentane, ethane, ethylene, isobutane, isomers of
hexane, isomers of nonane, isomers of pentane,  n-butane, n-heptane, n-hexane, n-pentane,
propane, toluene, and 2,2,4-trimethylpentane).  Thus, emissions of ROG from this source
category are equal to 75 percent of the TOG emissions.

   Emissions estimates for deep fat fryers are based on an emission factor which has been
developed using total fried food production as the activity factor.  The emission factor, 1.25
Ib TOG per 1000 Ib of product  fried (or 0.94 Ib ROG per 1000 Ib), is based on available
source tests. The source tests were primarily limited to commercial fryers that fry potatoes,
which are considered most representative of the deep fried foods.  Although a typical deep
fat fryer may fry a variety of foods, the majority are potatoes.

   The emission factor for deep fat fryers was developed as follows.

The amount of material processed by each fryer:
          Batch size = 3 pounds/batch
          Batch time = 4 minutes/batch

   Process weight
          = 3 pounds/batch x 1 batch/4 minutes x 60 minutes/hr
          = 45 pounds/hour
                                         4-21

-------
A typical fryer operates in essentially two modes:

   Peak hours (11:00 AM to 2:00 PM, 5:00 to 7:00 PM) during which it is estimated that
   the fryers operate at 75 percent capacity.
          7 hours x 45 Ib/hr x 0.75 = 236.25 Ib

   Off hours (2:00 to 5:00 PM and 9:00 to 10:00 PM) during which it is estimated that the
   fryers operate at 35 percent capacity.
          4 hours x 45 Ib/hr x 0.35 = 63.0 Ib

Total daily production
          236.25 + 63.0 = 299.25 Ibs (use 300 Ib/day as a maximum)

Total yearly production
          300 Ib/day x 360 days/year = 108,000 Ib/year

Reactive Organic Gases emitted
          108,000 Ib/yr x 1.25 Ib TOG/1000 Ib production =
          135 Ibs TOG/year per fryer x 0.75 (ROG/TOG)    =
          101.25 Ibs ROG/year per fryer.

   Emissions in the South Coast Air Basin and the Southeast Desert Basin were estimated
using the above developed emission factor together with activity data for total number of
deep fat fryers operating in the respective  areas.  The total number of deep fat fryers was
obtained on a county-wide basis from estimates made by a representative of the Southern
California Gas Company. The total number of fryers was apportioned to each basin of the
county according to relative population data.

   Based on methods presented in the SCAQMD report (reference  9),  total emissions from
commercial deep fat fryers operated on a country-wide  basis can be estimated using current
U.S. population  data together with the published TOG emission factor (Ib/year per fryer).  A
                                         4-22

-------
more accurate estimate can be obtained with current data on the total number of deep fat
fryers operating commercially in the U.S..  This information may be found through
investigations into trade association data, county business patterns, census bureau
information, or perhaps, as with the SCAQMD study, from estimates made by local gas
companies.

   The accuracy  of emissions estimates made using either of these techniques is dependent
on the accuracy of the emission factor, developed from source tests which were primarily
limited to commercial deep fat fryers frying potatoes.  Emissions from facilities frying food
of a higher fat content such as meat or fish are  expected to be higher. More testing is
necessary to develop emission factors for other  food products which have higher percentages
of fats and oils. In lieu of such testing, however, the SCAQMD emission factor may be a
reasonable approximation for commercial deep fat frying, given the assumption that potatoes
are the most frequently fried product. The additional assumption that commercial fryers
operate at 75 and 35 percent capacity during peak and off hours, respectively,  should be
investigated to ensure that these estimates are realistic. These assumptions can be
investigated through telephone or personal interviews with a range of restaurant and fast food
facility personnel.

   Application of the above method for commercial deep fat fryers to estimate emissions
from residential, or home-kitchen fryers, is difficult.   As with  commercial fryers,  emissions
from frying meat and fish are  expected to exceed the estimated rate of 1.25 Ib  TOG per 1000
Ib fried food.  The assumption that potatoes are the most frequently fried food  may not be a
reasonable assumption for residential cooking, where meats and/or fish may be the more
frequently fried products.  In addition, the SCAQMD emission factor has been developed
from controlled frying processes.   More variations in cooking temperature, cooking time and
moisture content are likely in residentially fried foods. These variables are identified in AP-
40 as important factors affecting the amount of  emissions expected from deep-fat frying ?

   In addition to  obtaining an appropriate emission factor for VOC emissions from
residential deep fat fryers, a major obstruction to estimating emissions from residential fryers
                                          4-23

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is the development of an activity factor.  Quantitative information on the number of
residential fryers (number of households which own a deep fat fryer) and the extent of their
operation (daily/weekly/monthly), as well as the typical mass of food fried per use, can be
used to develop the necessary activity factor,  in units of pounds of food fried per year.
Information on the number of deep fat fryers in use may be estimated using sales data or
production data from deep fat fryer producers.  However,  this approach will not give an
accurate  estimate of the extent of fryer use.  Such information was beyond the scope of this
study.  Consequently, it was not possible to develop an estimate of VOC emissions from
deep fat frying oils.

4.3.3     Cigarette. Cigar, and Pipe Tobacco Smoking

4.3.3.1   Description

   Combustion of cigarettes and the use of other tobacco products such as cigars and pipes
produces VOC's which are released into indoor and outdoor air.  Cigar and pipe smoking are
believed  to represent only a small fraction of total tobacco smoked, so cigarette smoking will
be the  focus of this section.

   By 1936, 120 combustion products were identified in tobacco smoke. Currently, the
estimated number of known compounds in tobacco smoke has increased to over 4,000.
The physical composition, constituents, and shape of cigarettes have changed significantly in
the 30 years since the Surgeon General's  Report on Smoking and Health first called attention
to the nature and composition of tobacco  smoke. Processed uncontaminated dry tobacco
contains primarily carbohydrates and proteins. Other major constituents include alkaloids
(0.5 to 5 percent), terpenes (0.1 to 3 percent), polyphenols (0.5 to 4.5 percent), phytosterols
(0.1 to 2.5 percent), carboxylic acids (0.1 to 7 percent), alkanes (0.1- to 0.4 percent), and
alkali nitrates (0.01 to 0.7 percent).    Trace elements  include aromatic hydrocarbons,
aldehydes,  ketones, amines, nitriles,  N- and O-heterocyclic compounds, pesticides, and
metallic compounds.
                                          4-24

-------
   The physicochemical changes in cigarettes over time, particularly changes in tobacco
composition, have brought about changes in the chemical characteristics of tobacco smoke.
Cellulosic acetate, which is commonly used for filter tips, can reduce emissions of some
phenols and N-nitrosamines from cigarette  smoke.  Perforated filter tips can remove some
CO and HCN, while charcoal filters may decrease emission of aldehydes  and HCN.  Another
change has been a trend towards generally  lower levels of pesticide residues.

   Researchers generally distinguish between mainstream smoke (MS), sidestream smoke
(SS), and environmental tobacco smoke (ETS).  Mainstream smoke is drawn from the unlit
end of the cigarette, while sidestream smoke is emitted from smoldering cigarettes between
puffs.  This means that the temperature of  combustion for MS is higher (800-900°C) than for
SS (~600°C).11  ETS consists of SS and exhaled MS, although for practical purposes, ETS
can be considered equal to SS.  One study  estimates that 85 percent of the smoke actually in
a room where people are smoking is SS.^ Mainstream smoke and SS differ in the amounts
of tobacco burned, the temperature at which combustion occurs, and in that the tobacco and
filter may absorb some constituents of MS.  ETS differs from MS and SS in that MS and SS
                                                                    19
may undergo chemical and physical changes when they cool and react in  air.    Indoor
temperature and humidity  also influence the evaporation rate of VOC's from cigarette
smoke.

   Mainstream smoke is further divided into a vapor phase and a paniculate phase.  The
vapor phase tends to contain more free radicals and highly reactive oxygen and carbon
compounds, while the paniculate phase consists of relatively stable radicals.  Table 4.3-2
lists the major compounds of MS identified in laboratory analyses and estimates of their
fractional concentrations per cigarette.   [The  Department of Health and Human Services
(DHHS) notes that these laboratory studies do not fully reflect actual emissions from
cigarette smokers, since smokers of low-nicotine cigarettes tend to compensate  for the lower
nicotine levels by drawing smoke more intensely and inhaling more deeply.  ]
                                        4-25

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4.3.3.2   Method for Estimating VOC Emissions from Cigarette Smoking

   Generally, in calculating emissions, an emission factor (for example, in grams of
pollutant per cigarette) is multiplied by an activity rate (number of cigarettes smoked
annually).  In effect, the numbers listed in Table 4.3-2 are rough estimates of emission
factors for the volatile components  of mainstream smoke.  A leading researcher of
environmental tobacco smoke or ETS indicates that there are currently few good estimates of
volatile emissions from sidestream  smoke, although these numbers may be available within
2 years.    MS and SS contain the same types of compounds, although the quantities of the
constituents may differ.

   In order to estimate emissions,  some basic assumptions are required. First, it is assumed
that complete combustion (smoking) of each cigarette occurs.  Also, as much as 50 percent
                                                           1 ^
of the VOC may adsorb to interior surfaces in homes or offices.    Underestimation of VOC
emissions may occur because  MS is considered to constitute only  10 to 15 percent of the
combustion products of cigarettes, with SS making up the rest, so using emission factors for
                                                                                 1 o
MS only will seriously underestimate the magnitude of VOC emissions from this source.
Because emission factors  for SS are not yet available, only an estimate of the order of
magnitude of emissions from this source is possible using the method described here.

4.3.3.3   Estimated Emissions From Cigarette Smoking

   Using the fractional constituent  factors given in Table 4.3-2, Table 4.3-3 lists estimated
1987 emissions by VOC species for cigarette smoking. These values were derived from the
following equation:

   emission factor x activity level x conversion factors = emissions estimate
   ug/cigarette x cigarettes/yr x pounds/ug = emissions estimate

The emission factor used are the values listed in Table 4.3-2.  Where a range of values  was
given,  the mean was used in the calculation.  The activity level  is the 1987 consumption of
                                         4-26

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cigarettes in the United States, 575 billion cigarettes.    Again, because of the lack of
availability of sidestream smoke emission factors and other uncertainties, these numbers
represent order of magnitude estimates only.
                                          4-27

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TABLE 4.3-2. MAJOR CONSTITUENTS OF
UNFBLTERED CIGARETTES
Constituentsfa)
Volatile alkanes (20)
Volatile alkenes (16)
Isoprene
Butadiene
Acetylene
Benzene
Toluene
Styrene
Other volatile aromatic hydrocarbons (29)
Formic acid
Acetic acid
Propionic acid
Methyl formate
Other volatile acids (6)
Formaldehyde
Acetaldehyde
Acrolein
Other volatile aldehydes
Acetone
Other volatile ketones (3)
Methano]
Other volatile alcohols (7)
Acetonitrile
Other volatile nitriles (10)
Furan
Other volatile furans (4)
Pyridine
Picolines (3)
3-Vinylpyridine
Other volatile pyridines (25)
Pyrrole
Pyrrolidine
N-Methylpyrrolidhie
Volatile pyrazines (18)
Methylamine
MAINSTREAM SMOKE
FROM
Concentration/cigarette
1
0.4-0.5
0.2-0.4
25-40
20-35
12-50
20-60
10
15-30
200-600
300-1700
100-300
20-30
5-10
20-100
400-1400
60-140
80-140
100-650
500-100
80-180
10-30
100-150
50-80
20-40
45-125
20-200
15-80
10-30
20-50
0.1-10
10-18
2-3
3-8
4-10
mg(b)
mg
mg
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug(b)
ug
ug
ug
ug
ug
ug
ug
ug(b)
ug
ug(b)
ug
ug(b)
ug
ug
ug
ug(b)
ug
ug
ug
ug
ug
(continued)
   4-28

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     TABLE 4.3-2. MAJOR CONSTITUENTS OF MAINSTREAM SMOKE FROM
                  UNFILTERED CIGARETTES (continued)
Constituents(a)
Nicotine
Other aliphatic amines (32)
Nicotine
Nornicotine
Anatabine
Anabasine
Bipyridyls (4)
Naphthalene
Other naphthalenes (23)
Phenol
Other phenols (45)
Catechol
Other catechols (4)
Scopoletin
Cyclotenes (10)
Solanesol
Neophytadienes
Limonene
Linolenic acid
Lactic acid
Indole
Skatole
Quinolines (7)
Benzofurans (4)
Stigmasterol
Sitosterol
Campsesterol
Cholesterol
Tobacco-specific N-nitrosamines (4)
Glycerol
Concentration/ci garette

3-10
1000-3000
50-150
5-15
5-12
10-30
2-4
3-6
80-160
60-180
200-400
15-30
15-30
40-70
600-1000
200-350
30-60
150-250
60-80
10-15
12-16
2-4
200-300
40-70
30-40
20-30
10-20
0.34-2.7
120

ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
(a)Numbers in parentheses represent individual compounds identified in a given group.
(b)Estimate.
                                     4-29

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     TABLE 4.3-3. ESTIMATED 1987 EMISSIONS OF VOC CONSTITUENTS OF
	MAINSTREAM SMOKE	
 Constituents                                                          Estimated ^.missions (lbs/yr)
 VolatUe alkanes (20)                                                              12,650
 Volatile alkenes (16)                                                               5,693
 Isoprene                                                                         3,795
 Butadiene                                                                         405
 Acetylene                                                                         354
 Benzene                                                                           392
 Toluene                                                                           506
 Styrene                                                                           127
 Other volatile aromatic hydrocarbons (29)                                              291
 Formic acid                                                                      5,060
 Acetic acid                                                                      12,650
 Propionic acid                                                                    2,530
 Methyl formate                                                                    316
 Other volatile acids (6)                                                              101
 Formaldehyde                                                                     759
 Acetaldehyde                                                                    11,385
 Acrolein                                                                         1,265
 Other volatile aldehydes                                                            1,392
 Acetone                                                                          4,744
 Other volatile ketones (3)                                                            949
 Methanol                                                                        1,645
 Other volatile alcohols (7)                                                           253
 Acetonitrile                                                                      1,581
 Other volatile nitriles (10)                                                           822
 Furan                                                                             380
 Other volatile furans (4)                                                            1,075
 Pyridine                                                                         1,392
 Picolines (3)                                                                       607
 3-Vinylpyridine                                                                    253
 Other volatile pyridines (25)                                                         443
 Pyrrole                                                                            63
 Pyrrolidine                                                                        190
 N-Methylpyrrolidine                                                                 32
 Volatile pyrazines (18)                                                               76
 Methylamine                                                                       89
                                           (continued)
                                             4-30

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    TABLE 4.3-3.  ESTIMATED 1987 EMISSIONS OF VOC CONSTITUENTS OF
                     MAINSTREAM SMOKE (continued)


Constituents                                                        Estimated emissions (Ibs/yr)
Other aliphatic amines (32)                                                         76
Nicotine                                                                    25,300
Nornicotine                                                                   1,265
Anabasine                                                                      114
Bipyridyls (4)                                                                   253
Naphthalene                                                                     38
Other naphthalenes (23)                                                            63
Phenol                                                                        1,518
Other phenols (45)                                                             1,518
Catechol                                                                      3,795
Other catechols (4)                                                              291
Scopoletin                                                                      291
Cyclotenes (10)                                                                 696
Solanesol                                                                   10,120
Neophytadienes                                                                3,479
Limonene                                                                      569
Linolenic acid                                                                  2,530
Lactic acid                                                                     886
Indole                                                                         164
Skatole                                                                        177
Quinolines (7)                                                                    38
Benzofurans (4)                                                                3,163
Stigmasterol                                                                    696
Sitosterol                                                                      443
Campsesterol                                                                   316
Cholesterol                                                                     190
Tobacco-specific N-nitrosamines (4)                                                  19
Glycerol       	1,518	

TOTAL VOC EMISSIONS                                                    121,136
                                          4-31

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4.3.4     References for Section 4.3

1.         Teleconference between Phillip Katz of the Beer Institute and Scott Lowe of TRC
          Environmental Corporation.  Discussed beer consumption and emissions
          information.  April 14, 1993.

2.         Teleconference between Wade Stevens of the Wine Institute and Scott Lowe of
          TRC Environmental Corporation.  Discussed wine consumption and emissions
          information.  April 14, 1993.

3.         Teleconference between David Byrd of the Distilled Spirits Council of the United
          States and Scott Lowe of TRC Environmental Corporation. Discussed distilled
          spirits consumption and emissions information. April 15, 1993.

4.         Leftonen, Matti and P. Jounela-Eriksson. "Volatile and Non-Volatile Compounds
          in the Flavor of Alcoholic Beverages," Flavour of Distilled Beverages, Origin
          and Development.  Ellis Horwood Series. New York, N.Y.  1983.

5.         1993 National Trade and Professional Associations of the United States, 28th
          Edition.  Columbia Books Inc. Washington, D.C. 1993.

6.         U.S. Environmental Protection Agency.  Compilation of Air Pollutant Emission
          Factors,  (AP-42).  Office of Air Quality  Planning and Standards.  Research
          Triangle Park, N.C. October 1986.

7.         U.S. Environmental Protection Agency.  Air Pollution Engineering Manual,
          Second Edition.  AP-40.  Research Triangle Park, NC. May 1973.

8.         U.S. Environmental Protection Agency, Office of Research and Development,
          Washington, DC  Identification and Characterization of Missing or Unaccounted
         for Area Source Categories.  Final Report,  September 1991.

9.         Eugster,  H.R., and W.J Dennison. Area Source Emissions for C/Y1989 from
          Deep Fat Frying in the SCAQMD Air Basin.  C.E.S. No. 66811.  South Coast Air
          Quality Management District Engineering Division Report. October  1990.

10.       Surgeon  General, Reducing the Health Consequences of Smoking:  25 Years of
          Progress, U.S. Department of Health and Human Services, Public Health Service,
          Centers for Disease Control, Rockville, MD, 1989.

11.       Guerin, M.R., R.A. Jenkins, and B.A. Tomkins,  The Chemistry of Environmental
          Tobacco Smoke:  Composition and Measurement,  Center for Indoor Air Research,
          Lewis Publishers, Ann Arbor, 1992.

12.       Special Projects Office of the Health Program, Office of Technology Assessment,
          Passive Smoking in the Workplace:  Selected Issues, May 1986.

                                        4-32

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13.       Teleconference between Joan Daisey, Indoor Environment Division, Lawrence
         Berkeley Laboratories and Wienke Tax, TRC Environmental Corporation. August
         20, 1992. Discussed estimates of emissions from mainstream and sidestream
         cigarette smoke.

14.       U.S. Department of Health and Human Services, Public Health Service, Centers
         for Disease Control, Smoking Tobacco and Health: A Fact Book, DHHS
         Publication No. (CDC) 87-8397,  revised 10/89.
                                       4-33

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4.4       SMALL COMBUSTION SOURCES

4.4.1     Kerosene Space Heaters

4.4.1.1   Description

    Kerosene heaters are typically used as a supplemental heat source in areas in which: 1)
residential central heating systems are not installed, 2) inadequate heat is available and/or 3)
temperatures are extremely cold. Kerosene heaters usually supplement other heating sources
such as electric, fuel oil and gas furnaces.  Portable kerosene heaters are limited to
supplemental heating because the kerosene tank on each heater is too small to provide
continuous heating without constant refilling.  Table 4.4-1 lists two of the most popular
kerosene heater sizes and some of the features.
             TABLE 4.4-1. KEROSENE HEATER  CHARACTERISTICS
Size
Small
Large
Output
(Btu/hr)
9,000
23,000
Tank Size
(gal)
0.98
1.6
Fuel Consumption Rate
(gal/hr)
0.075
0.17
   In the past 18 years, there has been a dramatic increase in kerosene heater usage,
possibly caused be the increased operating expense for central heating systems.  In 1974,
there were only 3,400 portable heaters sold in the United States. By 1979, the market had
increased to sales of four million heaters annually.   Current estimates place today's annual
sales for kerosene heaters between 400,000 and 1,000,000 units, with approximately 4.2
million heaters currently in use in the United States. 1'^>3>4 Overall, 17 million heaters have
                            sy
been sold in the United States/ Kerosene heater usage is most common in the northern
regions of the United States and least common in the southwest regions of the United  States.

   Kerosene heaters can be divided into three main categories:  (1) convective (white flame),
(2) radiant (blue flame) and (3) hybrid (two-stage).  The most popular type of portable
                                         4-34

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 kerosene heater among consumers is the convective heater. These three types of heaters are

.described here.
    1)    The convective (white flame) heater operates at relatively high combustion
          temperatures.  It uses a relatively simple unobstructed wick.
    2)    The radiant (blue flame) heater operates at lower temperatures than does the
          convective heater. It uses a cylindrical wick.  Flames extend up from the wick
          into a perforated metal baffle, consisting of two concentric cylinders inside a glass
          plenum.  After the warm up period the metal baffle glows red hot, causing a
          portion of heat to be output as radiative heat.
    3)    The hybrid (two-stage) heater is similar to the radiant heater, except a second
          chamber is located above the radiant element where more combustion air is
          introduced.  In this region the flame temperature is allowed to  rise, the color
          becomes white, and secondary combustion of unburned hydrocarbons with an
          increase in carbon monoxide production occurs before the combustion product
          leaves the burner.  This type of heater incorporates features from both radiant and
          convective heaters; thus it is appropriately named "hybrid."
    Although kerosene heaters are a logical choice for supplementing a central heating

 source, their lack of exhaust ventilation has prompted a considerable amount of research on

 the effects of emissions from kerosene heaters on indoor air quality.  These studies have

 quantified emissions rates and provide the basis for a general  methodology to estimate

 emissions from portable kerosene heaters.


 4.4.1.2    Methods for Estimating VOC Emissions from Kerosene Heaters


    The major VOC pollutant from portable, unvented kerosene heaters is the unburnt

 combustible formaldehyde (HCHO).  Significant quantities of formaldehyde are produced and

 emitted to an indoor atmosphere under the conditions which portable heaters are normally

 operated.  The average emission factors of the currently known VOC species, formaldehyde,

 are given in Table 4.4-2.5'6'7'8'9'1" A four-hour operating  cycle was assumed as a basis

 for developing the emission factors.  The cycle was based on  engineering judgment and

 discussions with industry representatives.  The cycle contains  two operating modes, a warm-


                                         4-35

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up mode and a steady-state mode.  The emission factors in Table 4.4-2 are a combination of
warm-up and steady-state data. The emission factors are based on reported data from six
independent experiments, and were obtained through interpolation of experimental heater
burns at 60, 90 and 720 minutes.  The four-hour operating cycle assumed ten minutes of
operation in the warm-up mode and the remaining 230 minutes in the steady-state mode.
Once the emission factors were estimated, an overall rate was calculated using the following
equation:
                           AEF =  (1° x WPK230 x  55)
                                            240
where:
   AEF  = average emission factor
   WU = warm up rate
   SS = steady-state rate
   10 = time (minutes) for the warm up stage
   230 =  time (minutes) for the steady-state stage
   240 =  time (minutes) for the total cycle
 TABLE 4.4-2.  AVERAGE KEROSENE HEATER EMISSION
_ FACTORS (LBS/1.000 GAL) _
 Heater Type _ HCHO _
 Convective                         0.381
 Radiant                            0.133
 Hybrid _ 0.011 _

   Organic emissions from kerosene fuel evaporation during the fueling and refueling of the
kerosene heater tank are composed primarily of C-8 to C-15 alkenes.  Other vapor-phase
organics present include the C-13 alkenes which are probably the products of incomplete
combustion.   Further research is needed to assess the exact VOC species present during
evaporation and incomplete combustion of kerosene fuel.

   Kerosene emissions are highly variable and are a function of kerosene content and
operating practices.  Generally, two types of kerosene fuels are used in the heaters. The first
and more common fuel (K-l) is a low sulfur content fuel (i.e. 0.04 percent maximum).  K-2,
                                        4-36

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the second fuel type, has a higher sulfur content than K-l (i.e. 0.3 percent maximum). K-2
fuel was used more often in early portable kerosene heaters, but is now most often used as
the main heating fuel in homes with kerosene furnaces.  The higher grade low-sulfur fuel (K-
1) is used in modern kerosene heaters to reduce sulfur dioxide production.  Kerosene heaters
should be  operated at a wick setting that is recommended by the manufacturer as being most
efficient.  Operating the heater at lower wick heights  reduces the amount of fuel
consumption, but causes more pollutant emissions.

    The proposed methodology for estimating formaldehyde emissions from kerosene heaters
is based on estimating the emissions during the burn cycle of the three types of kerosene
heaters. The methodology requires the following input data:

    •     Emission rates for kerosene heaters (which are estimated above)
    •     Typical kerosene consumption and kerosene heater data for the national level

    Kerosene  heater activity is based on the number of households using kerosene as a
supplemental  fuel reported in  Census of Housing and  the assumption that these households
each operate one kerosene heater. If the Census of Housing is not available the identical
information maybe obtained from the Department of Energy's Housing Characteristics
document.

    The fuel consumption rate (gallons per year) is calculated, as shown below,  by averaging
the consumption rates from Table 4.4-1 to obtain an average fuel consumption rate for
kerosene heaters. The average rate is then multiplied by the assumed bum cycle (four hours
per day) and  then by the average winter usage (90 days per year).
                          (0.17 + 0.075)                                            „.
          Consumption -  _ *L x it x  ^^  . 44.1^       (2)
                                  2              day        yr         yr
                                         4-37

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The following equation is used for estimating emissions from kerosene heaters:

             Emissionsijtufiyyrt = EF^ x  heatersStiutyjr2 x  consumption          (4)
where:
   study        =
   yr2
   Emissions;    =
   EF
      i
   heaters
   consumption  =
the pollutant being studied (HCHO)
the study area (national level)
the study year (1990)
emissions of pollutant i (HCHO)
emission factor for pollutant i (Ibs of pollutant per gallon of
kerosene)
number of households using kerosene as a supplementary fuel (from
the Census of Housing or Housing Characteristics)
44.1 gallons per year assumed as kerosene consumption per
household using kerosene as a supplementary fuel
 4.4.1.3 Estimated Emissions from Kerosene Heaters


   The total United States emission estimates for HCHO for 1990 are presented in Table 4.4-

 3.  Emissions have been estimated for the three types of kerosene heaters which are

 manufactured.  The emissions presented in Table 4.4-3 are based on kerosene consumption,

 the heating cycle and the number of days the heater is used in the year.
  TABLE 4.4-3.
ESTIMATED 1990 EMISSIONS FROM KEROSENE HEATERS
IN THE UNITED STATES
ACTIVITY
Heating
TOTAL
PRODUCT
Convective Heater
Radiant Heater
Hybrid Heater
VOC SPECIES
Formaldehyde
Formaldehyde
Formaldehyde
Formaldehyde
ESTIMATED 1990
U.S. EMISSIONS
(POUNDS)
70,569
24,634
2,037
97,240
                                         4-38

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4.4.2    Camp Stoves. Camp Lanterns, and Outdoor Portable Heaters

4.4.2.1  Description

  Camp stoves, camp lanterns and portable heaters are used in the U.S. for various outdoor
activities including backpacking and camping, or work in open areas.  Two primary kinds of
camp stoves sold in the U.S. are backpack type single burner stoves and family type two or
three burner stoves.  These stoves are designed to burn Coleman® fuel (C^Hj^), regular
unleaded gasoline,  kerosene, or propane gas. Other fuels used less frequently include
aviation gas, starter fluid (ethyl ether), butane and isobutane.  Many camping supply stores
sell propane and butanes as liquefied gases in pressurized containers.H»12

  Camping lanterns used include single or dual mantle lanterns which burn propane gas,
Coleman® fuel, unleaded gasoline or kerosene. Portable heaters, used for outdoor heating
jobs, include the standard single-head or double-head bulk mount types which are usually
designed to operate on propane gas.

                                                                                  i ^
  One of the primary manufacturers of camping products is The Coleman Company, Inc.
Most of their products are designed to bum on Coleman® fuel. It is estimated that about 5 to
6 million gallons (18.9 to 22.7 million liters) of Coleman® fuel is  sold each year.   No
information was located  on actual numbers of camping stoves, lanterns or heaters used in the
U.S.  4,15,16^ however, a spokesman from  Coleman estimated that approximately 40
million Coleman® stoves (that burn Coleman® fuel) and 2 million Coleman® stoves (that
                                                  1 ^
burn unleaded gasoline) are currently used in the U.S.    Other smaller-scale manufacturers
                                                     19
of camping products include MSR, Primus, and Optimus.   Primus and  Optimus were not
contacted for this brief study. MSR was contacted for information on  fuel combustion
efficiencies from their products.  They were unable to provide any additional information.
                                         4-39

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4.4.2.2  Method for Estimating VOC Emissions from Camp Stove, Camp Lantern and
        Outdoor Portable Heater Fuels

  The methodology that could be used to determine total annual VOC emissions from the use
of fuels in camping/outdoor equipment is as follows:17

        Determine the U.S. sales volumes for fuels in camping/outdoor recreational
        activities by fuel type and product type - (Vol)
        Conduct laboratory testing to determine emission factors for VOC's from fugitive
        emissions and incomplete combustion by fuel type and product type - (EF)
        Multiply emission factor by the sales by fuel type and product type to calculate total
        annual VOC emissions using the following equation

        Total annual VOC emissions = (Vol) * (EF)

  A spokesman from the Coleman® company estimated that average emission concentrations
from total unburnt carbon in Coleman® lanterns are less than 10 to 15 ppm (as carbon) and
less than 10 to 60 ppm  (as carbon) from Coleman® stoves.  This information is based
specifically on the use of Coleman® fuel although it was stated, that emission concentrations
from the use of other fuels in Coleman® stoves and lanterns would be approximately the
same, " Based on this information and the test parameter given the total annual emissions
were calculated for the  use of Coleman® fuel in Coleman® camp stoves and lanterns.
However,  it should be noted that these emissions concentrations do not take into account
fugitive emissions that would occur during storage, transport, and use of the fuel. These
fugitive losses would probably account for a greater proportion of VOC  emissions than VOC
emissions from incomplete combustion, and would vary greatly depending  on consumer use
practices such as fuel transfer methods and open containers. Furthermore, Coleman® fuel is
used in camping products  manufactured by other companies whose products might differ in
their combustion efficiencies.  A  spokesman from MSR indicated that some of their products
using Coleman® fuel bum with a 55% combustion efficiency.  ° Also note that the
concentrations mentioned by Coleman® are based on total unburnt carbon emissions which
                                        4-40

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may exclude common gaseous products of organic combustion but could include carbon
from products not considered VOC's that may be present in fuel formulations.

  Given the limited time and the difficulty in obtaining all the relevant information, it was
not possible to accurately calculate the total annual VOC emissions from this product
category during this study.

4.4.2.3 Estimated Emissions from Camp Stoves, Lanterns, and Outdoor Portable Heaters

  Based on the information provided by Coleman® from the use of Coleman® stoves and
lanterns, a first approximate estimate of total VOC emissions per year was calculated to be
less than 10 tons of unburnt Coleman® fuel.  Emissions calculation data are not provided due
to the lack of more accurate emissions concentrations which should include the fugitive
emissions  sources mentioned earlier.  Accurate emissions estimates from this source category
can only be  calculated if more accurate emissions data are obtained.

4.4.3   Fire Starting Materials

4.4.3.1 Description

  Fire starting materials are products used to aid or initiate the combustion process of
various consumer products.  Fire starting  materials include solid and gel starters, and
alternative combustion materials such as self-starting charcoal and artificial fire logs.1^
These products may be used for household fireplaces and for outdoor cooking purposes as in
                     90
grills and  camp stoves.    These materials may be used throughout the year.  However it is
not likely  to expect as much camping or outdoor activities in the winter than in the summer.

  Several  trade associations and manufacturers were contacted in an attempt to better
categorize the various types of fire starting materials that are currently manufactured in the
U.S.. None  of these sources were able to  immediately provide a comprehensive list of the
different products sold in the U.S. marketed as "fire starting materials".  1.22,23,24
                                         4-41

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  Solid starters usually consist of wood shavings held together with paraffin wax.19'23  The
actual percentages by volume/weight of these components  could not be found at this time
                                                                   je
although the material was found to be similar to manufactured fire logs.    The Department
of Ecology, State of Washington stated that products of combustion due to the burning of one
type of solid starter (Lightening Bug Nuggets) are not found to be any more polluting than
the burning of artificial fire logs.  Gel starters are usually alcohol-based products. 1" Alco
Brite®  manufactures  a gelled alcohol fuel called Cook 'n' Heat Fuel* which contains 1000
ppm ethanol (75 percent) and 200 ppm (3 percent) methanol.  Other similar gel products
include the Snap-On-Stove® and Alco Brite® Fire Starter.   It was not possible during the
time period of this study to find out whether Alco Brite has performed any emissions testing
of its products.  Another manufacturer makes a product known as  Mautz Fire Ribbons which
consists of a standard petroleum-based solvent, usually p-naphtha,  mixed with clay. This
product consists of 95 percent solvent and is often used to start fires in bar-b-que grills and
       99
torches.    No other product types or consumption data from  solid or gel starters were
located during the time period of this study.

  Artificial household fire logs are made by compressing sawdust  and petroleum wax.   >2
Canadian Firelog Ltd. makes a product that contains cedar sawdust (38 percent), paraffin
                                                                              10 98
wax (61 percent), calcium carbonate (0.75 percent) and copper sulfate  (0.5 percent).Ly^°
One source indicated that the product composition of fire logs does not vary drastically from
                            9Q
manufacturer to manufacturer/7  A representative  from  Duraflame Firelogs estimated that
approximately 40 to  60 percent of households in the U.S.  use artificial fire logs and of these
15 percent  are regular users  and up to 30 percent are occasional users.  He projected that
between 10 to 12 million log cases,  each  weighing 30 to 36 pounds are sold each year in the
U.S.27

4.4.3.2 Method for Estimating VOC Emissions from Fire Starting Materials

  Numerous sources of were researched to find emissions information  for this
category.19'21'22'23'27  These included the EPA and local university libraries, and several
Professional and Trade Associations.  One such source was able to provide emissions testing
                                         4-42

-------
data for the burning of artificial fire logs. ° No emissions information was available for
other fire starting materials.

  In 1987 the Canadian Firelog Ltd. had research conducted to test atmospheric emissions
from the burning of their product.  The test was conducted by measuring stack emissions
from a wood burning stove.  This testing measured emissions for various products of
combustion including polynuclear aromatic hydrocarbons (PAHs).  The results of the study
indicated that the total PAHs were at minimal concentrations of no greater than 0.02
     -1 OO
mg/m  .  °  Using the information from this study it is possible  to estimate emissions from
similar products  manufactured in the U.S.  The assumption made here is that the composition
of artificial fire logs does not greatly vary from manufacturer to manufacturer and therefore
emissions will be similar.
Calculation for Total PAH Emissions from Artificial Household Fire

Test Parameters
Flow rate:  95 acfm
Test Time:  11:50 to 12:20; O.5 hrs (average)
Mass of fire log used in the study:  5 pounds
Consumption Data
Number of cases of fire logs sold in the U.S. annually: 10 to 12 million; 11 million
(average)
Mass of each case:  30 to 36 pounds; 33 pounds (average)

Calculation
PAH emissions from test:
   < = [(0.02 mg/m3)*(95 ft3/min)*(0.5 hrs)*(60 min/hr)*(0.3048 m/ft)3]
   < = 1 .6 mg PAH/5 pounds firelog
                                        4-43

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PAH emissions in the US from artificial firelog combustion:
  < = (1.6 mg PAH/5 Ibs firelog)*(ll x 106 cases/yr)*(33 Ibs/case)
  <= 1.16x 108mg/yr
  < = 256 Ibs/vr

4.4.3.3  Estimated Emissions from Fire Starting Materials

  From these calculations, it is estimated that the total PAH emissions from the combustion
of artificial fire logs does not exceed 256 tons/yr.  It should be noted that this information
does not include fugitive emissions that might result from product shelf life.  Furthermore, it.
is likely that this emissions test may result in an underestimation of total VOC releases since
the  measured PAH emissions may not comprise all the VOC's that might be present hi the
stack emissions.

  Due to their composition, it is expected that fugitive emissions and  emissions from
combustion could result from the alcohol-or solvent based component of solid and gel
starters.  However, until emissions and consumption data are available from the use of these
products, total VOC emissions cannot be accomplished.

4.4.4    References for Section 4.4

1.       Telecon.  Lowe, Scott, Alliance Technologies Corporation, with Mindi Farber,
         Energy Information Administration. Kerosene heater sales and other general
         information. September 5, 1991,
2.       Telecon.  Lowe, Scott, Alliance Technologies Corporation, with Dr. Harold Smith
         of the National Kerosene Heater Association.  Kerosene space heater statistics.
         July 13, 1991.
3.       Housing Characteristics, DOE/EIA-0314(90), U.S. Department of Energy, Energy
         Information Administration, Washington,  DC.  Triennial Publication.
4.       White, J.  Summary of U.S. EPA  Sponsored Large Chamber Characterizations of
         Emissions from Unvented Kerosene Space Heaters, EPA/600/D-90/100, U.S.
         Environmental Protection Agency, Research Triangle Park, NC, 1990.
                                         4-44

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 5.       Apte, M.G. and G.W. Traynor. Comparison of Pollutant Emission Rates from
         Unvented Kerosene and Gas Space Heaters, NITS DE86-015133, Lawrence
         Berkeley Laboratory, Berkeley, CA, May 1986.

 6.       Dudney, C.C., A.R. Haythorne, K.P. Monar, M.A. Cohen, and J.D. Spengler.
         Impact of Kerosene Heater Usage on Indoor SO2 Exposures in 50 east Tennessee
         Homes, NITS DE88-016813, Oak Ridge National Laboratory, Health and Safety
         Research  Division, Oak Ridge, TN, July 1988.

 7.       Jackson, M.D., S.A. Rasor, R.K. Clayton, and E.E. Stephenson, Jr.  Paniculate
         and Organic Emissions from Unvented Kerosene Heaters, test House Study, EPA-
         600/D-88/226, U.S. Environmental  Protection Agency, Research Triangle Park,
         NC,  October 1988.

"8.       Lionel, T., R.J. Martin, and N.J. Brown. A Comparative Study of Combustion in
         Unvented Space Heating Devices, NTTS DE85-000673, Lawrence Berkeley
         Laboratory, Berkeley, CA, October 1984.

 9.       Traynor,  G.W., M.G. Apte, H.A. Sokol, and J.C. Chuang.  Comparison of
         Measurement Techniques for Quantifying Selected Organic Emissions from Kerosene
         Heaters, EPA-600/D-86/142, U.S. Environmental Protection Agency, Research
         Triangle Park,  NC, February 1990.

 10.      Traynor,  G.W., M.G. Apte, H.A. Sokol, J.C. Chuang and J.L. Mumford.
         Selected Organic Pollutant Emissions from Unvented Kerosene Heaters, EPA-
         600/D-86/142, U.S. Environmental  Protection Agency, Research Triangle Park,
         NC,  July  1986.

 11.      Coleman Product Information  Guide (1993 edition). The Coleman Company®, Inc.
         Wichita, Kansas 67202.

 12.      Teleconference between Randy Lowe, Recreational Equipment Inc., and Sheila
         Thomas, TRC Environmental Corporation.  Discussed camping equipment and
         fuels.  April  13, 1993.

 13.      Teleconference between Randy May, The Coleman Company® and Sheila Thomas,
         TRC Environmental Corporation. Discussed camping equipment and fuels.  April
         13, 1993.

 14.      Teleconference between Mike Walsh,  Sierra Club, and Sheila Thomas, TRC
         Environmental Corporation. Discussed camping equipment and fuels.  April 13,
         1993.

 15.      Teleconference between Sanjay Mishra, Green Peace,  and Sheila Thomas, TRC
         Environmental Corporation. Discussed camping equipment and fuels.  April 13,
         1993.
                                        4-45

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16.     Teleconference between Ruth Lister, American Camping Association, and Sheila
        Thomas, TRC Environmental Corporation.  Discussed camping equipment and
        fuels.  April 13, 1993.

17.     U.S.  Environmental Protection Agency.  Identification and Characterization of
        Missing or Unaccounted For Area Source Categories. EPA-600-R-92-006.  Air and
        Energy Engineering Research Laboratory, Research Triangle Park, N.C. 1992.

18.     Teleconference between Dan Vorhees, MSR and Sheila Thomas,  TRC
        Environmental Corporation, with .  Discussed camping equipment and fuels.  April
        13, 1993.

19.     U.S.  Environmental Protection Agency.  Estimation of Emissions from Charcoal
        Lighter Fluid and Review of Alternatives (Final Report).  EPA/600/2-90/003. Air
        and Energy Engineering Research Laboratory, Research Triangle Park, N.C.
        January 1990.

20.     Teleconference between Randy Lowe, Recreational Equipment Inc. (REI) and
        Sheila Thomas, TRC Environmental Corporation.  Discussed camping equipment
        and fuels. April 13, 1993.

21.     Teleconference between Caroline Desseji, Hearth Products Association and Sheila
        Thomas, TRC Environmental Corporation.  Discussed product types and emissions
        from fire starting  materials. April 19, 1993.

22.     Teleconference between Doug Mall, Mautz  Paint Co. and Sheila  Thomas, TRC
        Environmental Corporation. Discussed product  types and emissions from fire
        starting materials.  April 20, 1993.

23.     Teleconference between Steve Marshall, Lightening Starters Inc.® and Sheila
        Thomas, TRC Environmental Corporation.  Discussed product types and emissions
        from fire starting  materials. April 19, 1993.

24.     Teleconference between Linda Hansen, Hearth and Home Magazine and Sheila
        Thomas, TRC Environmental Corporation.  Discussed product types and emissions
        from fire starting  materials. April 23, 1993.

25.     Letter  from Michael Landon, State of Washington, Department of Ecology to
        Marshall Thompson,  Lightening  Starters, Inc.®  Evaluation of Lightening Bug Fire
        Starters.  Letter dated June 17, 1992.

26.     Alco Brite®.  Dealer  Catalog 1993 Products. Hildale, Utah.

27.     Teleconference between Chris Caron, Duraflame Fire Logs and Sheila Thomas,
        TRC Environmental Corporation. Discussed product types and emissions from fire
        starting materials.  April 23, 1993.
                                        4-46

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28.     Canadian Firelog Ltd.  Emissions Testing Report.  Richmond, British Columbia.
        December 8,  1987.

29.     Teleconference between Dave Eckert, Canadian Firelog Ltd. and Sheila Thomas,
        TRC Environmental Corporation.  Discussed product types and emissions from fire
        starting materials. April 20, 1993.
                                       4-47

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4.5      MISCELLANEOUS PRODUCTS

4.5.1    Mold Release Agents *

4.5.1.1  Description

  A mold release agent (MRA) can be genetically described as any substance used to control
or eliminate the adhesion of a material to itself or to another material.  The MRA prevents
the molded product from sticking to the mold so that the product can easily be removed in
one piece.  Factors such as penetration, chemical reaction and compatibility, low surface
tension, surface configuration,  and differences in polarity between the two materials influence
adhesion between materials.  MRA's may also be known as abherents, anti-blocking agents,
external or surface lubricants, parting agents,  and slip aids.  The MRA consists of the active
ingredient (the ingredient that actually causes the abhesion) and a carrier or additive that is
used to apply the MRA.  The active ingredient is most often inert, that is, it contains no
VOC.  The carriers and additives often contain VOC, although non-VOC carriers and
additives may  be used. Major industrial applications for MRA's include casting, molding,
forming, and materials transfer operations in a wide variety of industries, including plastic
(or polymer) processing,  rubber, metal processing, glass, food processing, textiles, printing,
and others.

  The  category is divided into  two major types of agents: topical coatings and semi-
permanents. Topical coatings, which currently dominate the MRA market, are further
divided into external MRA's and internal MRA's. External MRA's operate much in the
same manner as oil, lard, and nonstick sprays operate on cookware.  Abherents can be
applied to a surface by standard coating methods  such as spraying, brushing, dusting,
dipping, electrostatic powder coating, and plasma arc coating. The product (e.g., resin,
metal,  rubber,  glass, etc.) is injected, laid, rolled, sprayed, etc., in the mold where the
product is cured.  The part is then released from the mold and the MRA is reapplied to the
mold.
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  Internal MRA's, typically metallic stearates, ate agents that are added to the resin itself.
While there is no consensus as to how such agents work, one hypothesis is that the MRA
migrates to the surface of the resin, that is, to the part/mold interface, during the interval
between the injection and the ejection.  The agent then acts as an external release agent,
essentially lubricating the boundary.  A number of factors influence the performance of
internal MRA's, including solubility in the resin, rate of migration, lubricity, melting point
                                                9 o
of the additive, and extent of electrostatic inhibition. fj

  Semipermanents,  or multiple release products, are a relatively new concept in release
agents.  Semipermanents allow a large number of processing cycles to occur before re-
application of the MRA is needed. They are  usually water- or solvent-based with the latter
predominantly used in heat-cured systems.  They can be used to coat the mold or can be
applied  to become an integral part of the mold.  Advantages include low buildup, promotion
of excellent part surface and finish, minimal transfer to the part, high release efficiencies,
low or non-toxicity  of some products and high temperature stability (up to 375°C).

4.5.1.2   Mold Release Agents as Sources of VOC Emissions

  Emissions from MRA use can occur at several points in the application process and depend
primarily on the mode of application.  With external MRA's,  VOC emissions will occur
from  the application of sprays and liquids.  Emissions points are the applicator, the mold and
the product.  With internal  MRA's, emissions may occur from the surface of the  mold and
the surface of the product.  However, most internal mold release agents are not mixed with
additives and carriers, and therefore, there would be no VOC emissions. Emissions points
for application and use of Semipermanents are similar to those of external MRA's.  However,
since  these MRA's are not  applied as frequently as externals,  their relative emissions
(assuming the same VOC content as a comparable external MRA) will be lower.

  Another source of emissions from the MRA application process involves clean up
activities. Mold surfaces are cleaned at regular intervals to increase the efficiency of the
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MRA. Many of the products used in clean up are solvents with high VOC contents (e.g.,
mineral spirits,  trichloroethylene).

4.5.1.3  VOC Emission Estimates

  Total VOC emissions from MRA's were estimated by calculating emissions for aerosol
MRA's and liquid MRA's.  This resulted in an estimate of 125,592 tons of VOC per year
for all MRA's.  Using industry-specific data on amount of active ingredient consumed,
assumptions on application method, and the total emissions estimate for MRA's,  industry-
specific emissions estimates were developed.   Three major assumptions were used in this
process:

• Assume that the relationship of additives and carriers for the industry to total additives and
  carriers is the same as the relationship of active ingredients for the industry to  total active
  ingredients. For example, polyurethanes consume 23.6 percent of total active  ingredient.
  Therefore,  polyurethanes consume 23.6 percent of total additives and carriers.
• Based on the  first assumption, assume that the proportion of additives and carriers in an
  industry to the total additives and carriers is the same as VOC emissions for the industry to
  total VOC emissions. For example, MRA active ingredient consumption by polyurethanes
  is 23.6 percent of total MRA active ingredient and, therefore,  VOC emissions  for
  polyurethanes are 23.6 percent of total additive and carrier consumption.  Thus, assume
  polyurethanes carries 23.6 percent of the total VOC emissions.
• Since no information is available on the application/delivery mode by industry, assume that
  the overall distribution (47.5 percent sprays, 33.9 percent liquids, and 18.6 percent dusts)
  applies to each industry.

  Using these three assumptions, MRA VOC  emissions for specific industry segments were
calculated and are presented in Table 4.5-1.
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 TABLE 4.5-1  EMISSIONS FROM MOLD RELEASE  AGENTS BY  INDUSTRY
INDUSTRY
Polyurethanes
Polyesters
Epoxies
Other Thermosets
Polyvinyl chloride
Polystyrene
Other Thermoplastics
Rubber Processing
Metal Processing
Glass Industry
Other Non-Polymers
TOTAL
VOC EMISSIONS (tons)
29,624
15,440
3,891
4,895
6,904
6,653
5,272
20,586
15,440
9,540
7,155
125,529
4.5.2   Products Used in the Manufacture of Fiberglass Boats L

4.5.2.1  Description

  The fiberglass boat manufacturing and repair industry consists of about 1,800 facilities.
These facilities employ about 47,000 people and are located in 34 of the 48 continental
United States.  About 88 percent of these establishments are small operations, employing less
than 50 people.  States that have a large number of boat manufacturing facilities include
California, Florida, Illinois, Indiana, Michigan, North Carolina, South Carolina, Tennessee,
Texas, and Washington.

  The most common fiberglass boat production method is open contact molding. This
method consists of laying up plies of fiberglass reinforcement impregnated with resin on an
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open male (convex) or female (concave) mold.  For manufacturing boats, a female mold is
generally preferred since it yields a smooth outer surface which is more desirable for hulls
and decks.  The layers are built up to the desired thickness and allowed to cure.

  The initial layer of resin is formed without any reinforcing material by spraying gel coat
(unsaturated polyester resin, catalyst, and pigments) into the empty mold to a precise
thickness.  After allowing the gel coat to cure fully, laminates of resin and fiberglass are
applied by machine lay-up, hand lay-up, or spray lay-up. Machine lay-up involves the
simultaneous mechanical application of fiberglass reinforcement material and is generally
reserved for large hull boats; e.g., sailboats with deep keels.  In hand lay-up,  resin is
brushed or sprayed on the tacky surface of the gel coat,  the fiberglass reinforcement material
is placed into the mold, then the laminate is completely wet out with resin and rolled by hand
to remove air pockets and other imperfections.  The spray lay-up method uses a chopper gun
which simultaneously deposits chopped strand fiberglass  and catalyzed resin on the mold,
after which rollers are used, as in hand lay-up, to remove entrapped air.

  Two alternative closed molding methods which have been experimented with in the
fiberglass boat manufacturing industry are bag molding and resin transfer molding (RTM).
Bag molding uses a bag or flexible membrane to apply vacuum or pressure during the
molding operation.  Vacuum bag molding applies pressure against the laminate by drawing a
vacuum under a cellophane, vinyl, or nylon bag which covers the laminate.  Pressure bag
holding forces the bag against the laminate using compressed air or steam. In the RTM
process, fiberglass reinforcement consisting of continuous or chopped strand glass fiber mats
is placed between halves of a mold.  After the mold is closed, catalyzed resin  is injected into
the mold and allowed to cure. The mold is then opened and the finished part removed. The
major technical difficulty in  using this process for boat manufacturing is that resin void
spaces may occur, rendering the part unusable.  Also, highly skilled labor is required for
RTM to be successful.
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4.5.2.2  VOC Emissions from Fiberglass Boat Manufacturing

  VOC emissions from fiberglass boat manufacturing consist mainly of acetone and styrene.
There are four areas in the fiberglass boat production process where VOC may be emitted to
the atmosphere:  resin storage, production, assembly, and waste disposal.  The major
emissions sources are exhausts from gel coat spray booths, room exhausts from the
lamination area,  and evaporation of acetone or other solvents during cleanup.  Emission
factors for resin  application in open contact molding range from 5 to 13 Ib styrene per 100 Ib
of styrene used.  Emissions from gel coat application and curing are 26 to 35 Ib per Ib of
styrene monomer used.  Cleaning solvent emissions, primarily acetone, can account for 36
percent of the total VOC emissions and are about equal to 56 percent of the  styrene
emissions.  Total VOC emissions per plant are estimated to range from 2 to  140 tons per
year.  Total nationwide VOC emissions are estimated to be 20,150 tons per year.

4.5.2.3  Emission Controls

  The two general types of VOC emission control techniques available are process changes
and add-on controls. The process change offering the greatest potential for VOC  emission
reductions at low cost is the  substitution of lower VOC-containing materials.  These include
vapor-suppressed resins, low styrene  resins, water-based emulsions  for cleanup, and dibasic
ester compounds for cleanup.

  Vapor-suppressed resins contain additives which reduce VOC emissions during  resin
curing.  The most common vapor suppression additive is paraffin, which migrates to the
surface of the resin  layer and reduces the volatilization of free styrene during resin curing.
Styrene emissions reductions ranging from 20 to 35 percent can be achieved on a  per plant
basis.  Vapor-suppressed resins are not currently being used universally in the fiberglass boat
manufacturing industry due to problems in secondary bonding which reduce product strength.

  The emission reduction from low styrene resins is less than that of vapor- suppressed
resins; however, low styrene resins are currently available and being used in the industry.
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Styreoe emissions can be reduced by about 14 percent using a 35 percent styrene by weight
resin.  Conventional resins contain 40 to 50 percent styrene by weight. A number of boat
plants have reduced the styrene content in their resins to 38 to 40 percent styrene with
satisfactory results.   Very few boat manufacturers have been able to reduce styrene content
below 35 percent without sacrificing some of the structural integrity of the boat.

  Water-based emulsions can be used to replace about 50 percent of the solvent used for
cleanup. These emulsion cleaners would be expected to reduce clean-up emission by about
50 percent.  The cleaners are successfully being used commercially in boat plants for resin
cleanup and their use has been required  as a permit restriction to reduce VOC emissions
from fiberglass boat plants in some recent best available control technology (BACT)
decisions. These emulsions, however, appear to be inadequate for gel coat or cured resins
cleanup.

  Alternative cleaning compounds containing dibasic esters (DBE's) are currently being
tested at a number of fiberglass boat plants.  These cleaning solutions show great potential to
replace  acetone completely for resin and gel coat cleanup.  Due to the much lower vapor
pressure of DBE's,  these substitutes can provide dramatic  VOC emission reductions.  Based
on preliminary tests, an estimated reduction of VOC  emissions from cleanup activities of 75
percent  can be achieved if DBE's are used in place of acetone.  The DBE cleaner is currently
two to three times more expensive than acetone; however,  it lasts longer because it
evaporates at a slower rate and it can be recycled.

                                         ••5
4.5.3    Automotive Repair Parts Washers J

  A large variety of services may be offered by an automotive repair facility. In addition to
engine maintenance, these facilities may repair and service brakes, transmissions, and
cooling, air conditioning, and electrical systems. Parts cleaning is common to most facilities
and often involves the use of a parts washer.
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  These washers, which may be maintained and serviced by the facility itself or by an
outside company, usually consist of a sink which covers a drum containing; solvent and a
pump with a filtered intake. The pump circulates solvent from the drum to the sink through
a flexible hose.  A brush,  sometimes mounted to the nozzle of the hose, is used to aid
cleaning.  Many newer models have a lid that closes to reduce solvent loss through
evaporation.  Some older parts washers consist of a grate over an open reservoir of solvent.
Self-contained systems for immersing parts in solvent for several hours are widely used.

  The solvents used in parts washers can vary, but most are based on petroleum distillates.
One commonly used solvent contains 85 percent petroleum distillates.  Carburetors are
usually cleaned by immersion in cleaners that may contain other solvents.  One  such solvent
system used for carburetors is 2-butoxy-l-ethanol and n-methyl-pyrolidine.  Other solvents
may include methlyene chloride.

  Emissions can be attributed to evaporation from the sink and solvent loss through
splattering, spillage, or incomplete drainage of cleaned parts.  For older washers,
evaporation occurs even when the cleaner is not in use.  In newer models, the solvent is
returned  to the drum, and the sink is equipped with  a cover to reduce emissions when the
cleaner is not in use.  Typical parts washers have a  storage capacity of 20 gallons.  The
washers are usually serviced every 30 days, when the dirty solvent is collected and clean
solvent installed in the machine.

  Estimates of VOC emissions from these cleaners were made based on the assumption that
10 percent  (2 gallons) of the solvent is lost during the typical  service interval of 1 month.
The annual losses are estimated to  be 157 pounds per machine.  In 1990,  there were
approximately 55,000 repair facilities nationwide. Assuming one machine per shop,
nationwide emissions were estimated to be 4317 tons per year.
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4.5.4    Products used in the Textile Industry

4.5.4.1  Description

  The textile industry includes facilities involved in the following activities:

  •     fiber preparation followed by manufacturing of yarn and thread;
  •     manufacturing of woven fabrics, knit fabrics, carpets, and rugs from yarn;
  •     dyeing and finishing of fiber, yam, fabric,  knit, and woven apparel;
  •     manufacturing of apparel and other articles from yarn; and
  •     manufacturing of nonwoven fabrics and other miscellaneous textiles.

  Both man-made and natural fibers are processed.  Examples of the latter group include
cotton, wool, silk, flax, and jute while the former include such fibers as rayon, polyester,
acetate, and nylon.  Blends of these fibers may also  be processed.

4.5.4.2  Yarn Production

  Yarn production begins with the blending of fiber  from several bales. Dirt and impurities
are mechanically removed. Carding aligns the fibers into a thin web and further separates
impurities. The thin web is gathered into a rope-like strand called a sliver.  To produce yarn
from sliver, one of two methods of spinning is employed:  ring or open-end spinning. In
ring spinning, several strands of sliver are combined and drawn, or drafted,  into a longer and
thinner form that is  about one-eighth of its original diameter, which is called roving.  The
roving is drafted to  a smaller diameter and fed through a ring that rotates about and wraps
the yarn around a bobbin. The yarn from several bobbins is  combined onto a  larger cone in
a process called winding.

  In open-end spinning, individual fibers are removed  from the sliver and reassembled with
twist to form yarn.  Open-end spinning utilizes the action of water, air, or mechanical rotors.
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  During yam production, yarn is often wound from one type of tube or cone to another.
For example, after ring spinning, yam is wound from spinning bobbins to cones or dye
tubes, depending on how the yarn is subsequently processed.  Yarn that is to be shipped to
other facilities may also be wound onto bulk cones.  Some package dyeing facilities purchase
yam on bulk cones and wind it onto dye tubes.  After package dyeing,  yarn is wound from
dye tubes to cones.  Winding machines that wind yarn onto dye tubes for subsequent package
dyeing are called tube winders; those that wind yarn onto cones for knitting or weaving are
called cone winders.

4.5.4.3 Fabric Production

  In general, fabrics may be classified as woven, nonwoven,  or knit. The following
discussion describes the production process for each type of fabric.

  Woven fabric is produced when yarns are interlaced at right angles.  Warp yarns are the
yarns oriented along the length of the woven fabric while fill  yarns are  those that run
perpendicular to the warp yarns. Warp yarn is prepared in a  process called warping by
placing cones of yarns on creels and winding them onto warp beams. During warping, the
yarns may be coated with size  to protect them from the  stresses of weaving.  A yarn
conditioning fluid may also be  applied to the yarn as it is wound onto a beam.  Prior to
weaving, a warp beam is loaded on the front of the loom and the yarn is pulled through
heddles, which are metal strips that control each individual yarn.  The heddles are connected
to a harness which controls groups of yarn.  When a harness  is raised,  an opening is created
in which fill yarns are inserted. The order of raising and the number raised is varied to
produce patterns on the fabric.   Different types of woven fabrics include the plain, twill,
satin, dobby, and Jacquard.

  Looms may be described by  what method is used to insert the fill yarn.  Shuttle looms
send a carrier  with a small bobbin of yarn across the warp. Shuttleless weaving machines
use a projectile, a rapier, or a jet of air or water to carry the  end of the fill yarn across the
warp.
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  Knit fabrics are produced by the interlooping of yarn.  These fabrics may be designated as
warp or weft knits.  Weft knits are characterized by yam that runs perpendicular to the
length of the fabric.  Circular and flat-bed machines are used to manufacture these fabrics.
The former type of machine utilizes needles that are arranged in a circle to produce a tubular
fabric.  In this way, goods, such as hosiery, T-shirts,  and turtlenecks, may be produced
without vertical seams.  Flat-bed knitting machines employ needles that are arranged parallel
to each other to produce small items, such as knitted hats and scarves.  Because this type of
machine does not operate at high speeds, long lengths of knitted fabrics are usually produced
on circular knitting machines.

  Warp knits are produced by interlooping yarn in the lengthwise direction of the fabric to
produce a flat good with straight edges. Specific types of warp knits include tricot, raschel,
Milanese, and simplex.  Warp knitting machines produce fabric at a greater speed than weft
knitting machines.

  Nonwoven fabrics are produced by using thermal, mechanical, or chemical means to bond
or entangle the fibers or filaments that  are laid in a random orientation. Nonwovens may be
incorporated into disposable or durable goods, such as household wipes, diapers, protective
clothing, road underlays, dpparel interfacing, and carpet.

4.5.4.4  Fabric  Preparation

  Greige goods refer to unfinished fabrics from the loom or knitting machines. They may be
sold as is or further processed for apparel or household use.  The additional processes
include fabric preparation,  dyeing or printing, and finishing.

   The fabric is prepared to promote a clean, uniform substrate for subsequent dyeing,
printing, and finishing.  The preparation of cotton fabric may begin with singeing, a process
that removes lint, surface dirt, and loose fiber. This is accomplished by brushing the fabric
and then passing it by a natural gas flame.  Desizing uses  a sulfuric acid, or enzyme,
depending on the size that was applied, to remove sizing that was added to facilitate the
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weaving process. The fabric may be scoured in a hot, alkaline solution to remove waxes,
oils, and any sizing compounds that may be present in the fabric. A chlorine- or
peroxide-based bleach may be used to obtain a uniform-white appearance.  Mercerization,
treatment of the goods in a caustic soda solution while under tension, is used to increase the
luster and strength of the fabric while improving the dyeability.

  Synthetic fabric proceeds through a similar sequence, although, in most cases,  it requires
less preparation than cotton.  Wool fabric is prepared  by carbonizing, a step that uses
sulfuric or hydrochloric acid to reduce to carbon the vegetable matter that adheres to the
fibers.  The fabric is bleached and singed.  Additional chemical and mechanical techniques,
such as decating and fulling, may be used to develop the appearance and hand, or feel, of the
fabric.

4.5.4.5  Fabric Dyeing

  Dyeing is the process of adding color to fiber, yarn, and fabric.  The dyes may be natural
or synthetic and are classified  by  their chemical makeup. Acid dyes are suited for the dyeing
of wool, silk, polyamides, and some acrylic and polyester fibers.  Azoic dyes are used on
natural and man-made cellulosic fibers, nylon, polyester, and silk.  Basic dyes will dye
acrylic and some nylon and polyester fibers.  Direct dyes are used to dye cellulosic fibers
while disperse dyes are applied to synthetic fibers.  Reactive dyes are used on cellulosic,
wool, silk, and nylon fibers.  Sulfur and vat dyes are  used on cellulosics.  Pigments are
insoluble colorants added to the fiber-spinning solution in synthetics manufacturing or
attached to the  surface of a textile with resin binders.

  There are several methods for dyeing that can occur at most any step of the textile
production process.  For example, fiber dyeing and solution dyeing occur prior to yarn
spinning.  Yarn dyeing, which occurs after the spinning process, can be performed in a
variety of ways.  Package dyeing involves the dyeing  of yarn that has been wound onto
perforated  spools. The spools are placed on perforated pipes in a package-dyeing machine
where dye  solution is pumped through the packages.  In skein dyeing, loops  of yarn are
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placed on rods and immersed in a dye solution. Beam dyeing, similar to package dyeing,
may be performed to obtain dyed warp yam for weaving.

  Piece dyeing is the batchwise dyeing of fabric, woven or knitted.  Beam dyeing is
characterized by the pumping of dye through fabric that is wound onto beams.  Fabric is
sewn into a continuous loop and dyed in rope form in beck and jet dyeing.  Becks
mechanically pull the fabric through a heated dyebath.  Jets use the hydraulic pressure of the
dyebath to move the fabric through  the machine. Jig dyeing transfers the fabric from a
supply beam, through a dyebath, onto a take-up beam, and vice versa.

  Garment dyeing is the dyeing of textile products  that have already been sewn.  They are
often dyed in machines that resemble large washing machines.  Continuous dyeing is
conducted on a range where the fabric or yarn is passed through  a series of dye and chemical
baths, heat or steam for dye fixation, and hot water washes.

4.5.4.6  Fabric Printing
  The printing process involves the transfer of color patterns to the surface of the fabric.
Dyes and pigments are applied by roller, screen, and transfer printing.

  Typically, pigments are used in roller printing.  The pigments may be dispersed in water
or solvent. Print pastes may be formulated with or without solvents.  Some solvent-based
print pastes, which contain up to 70 percent Varsol 18, are prepared as emulsions.

  Roller printing uses chrome-plated, copper rolls that are engraved or etched with a pattern.
The cylinders are positioned around a central impression roller. The unprinted fabric
contacts a back greige which is carried by the print belt.  Print paste is transferred from a
trough to the cylinder by means of a rotating, cylindrical, furnishing brush.  A doctor blade
removes excess print paste from the cylinder before it contacts the fabric. After the last print
cylinder, the cloth is lifted from the back greige and is heated on steam cans or in an oven to
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fix the color.  Excess print paste is washed from the fabric on a continuous range before it is
forwarded to the finishing ranges.  The back greige is used only once before being washed.
The print belt is brushed and washed as it returns to the front of the machine.

  In screen printing, a squeegee is used to force ink or dye through a porous screen mesh.
An image is formed because the stencil, which is added to the screen, blocks out certain
areas on the mesh.

  Screen printing of textiles may be performed with either flat-bed or rotary screen presses.
Garment screen printers use flat-bed presses to print on garments and fabric pieces. These
presses may be either manually or automatically operated.  On manual pressies, each printing
step including the use of the squeegee is hand operated.   On automatic presses, the garments
are manually loaded and unloaded on the press, but the garment moves automatically from
color-station to color-station. Also automatic in operation are the squeegee and flood bar,
which redistributes the ink on the screen after the squeegee has been  used.  Six- and eight-
color manual presses are commonly used;  automatic presses with up to 12 color-stations were
observed during the site visits.

  Most garment screen printers use plastisol inks.  These inks  contain no volatiles since they
consist of two components, polyvinyl chloride (PVC) resins and a plasticizer, that fuse
together when the ink is exposed to heat.  A relatively small number of garment screen
printers use water-based inks. These inks cure through evaporation and may contain some
solvent component.

  Rotary screen presses use metal  cylindrical screens to print on rolls of fabric.  Each screen
on a press rotates as fabric moves  on a belt that travels under it. Ink that is continuously
pumped inside the screen is forced through the stencil by a  stationary squeegee-like blade
that is inside of each screen.  During the site visits, rotary screen presses with as many as 14
color-stations were observed.
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  Typically, the print pastes used in rotary screen printing are water-based systems.  One
printer stated that varsol-containing print pastes for pigments are no longer used. The
pigments and dyes are similar to, if not the same as, those used for dyeing.

  Prior to the first production run on the rotary screen printing machines, samples are often
prepared on a strike-off table.  These prints enable  the facility to check the screens for
pattern registration and the print-paste formulations for the proper shade.  A strike-off table
consists of a stationary belt onto which  several yards of fabric are adhered.  A screen is
mounted in a carrier, print paste is  placed inside the screen, and the screen is rolled down
the length of the fabric.  The process is repeated  for each additional screen.

  A variety of methods may be used to produce stencils.  The photostencil method may be
used with both flat-bed and rotary screens.  In the case of flat-bed screens, it is the dominant
process for stencil making.  Photostencils are produced by coating the screen with a light-
sensitive emulsion.  After the emulsion  dries,  a film positive is placed on it and the emulsion
is exposed to light.  The light hardens the exposed areas  of the emulsion; the rest is  washed
away with water. Equipment is available that prints a digitally-stored image directly onto the
emulsion of flat-bed screens using an opaque,  water-based ink.  The screen can then be
exposed to light without the use of  a film positive.  Knife-cut stencils are only used on flat-
bed presses.  These stencils are produced by cutting away areas on a piece of water- or
lacquer-soluble film and adhering the film directly to the screen.  The type of film that is
used depends on whether a water- or solvent-based  ink is used.  Some stencils on rotary
screens  are produced using a laser.   In this system,  the screen is coated with an emulsion and
after the emulsion dries, a laser is used to etch a pattern  in it.

  There are two major types of transfer printing which involve the transfer of color  from a
paper surface to the fabric.  In vapor-phase  transfer printing, dyes are printed  onto paper
which is placed on the fabric surface. Heat causes  the dye to vaporize and condense onto the
fabric.  The pattern is fixed with heat and pressure.  Melt transfer printing is performed in a
similar way, except that heat is used to transfer dye and a thermoplastic binder to the textile.
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4.5.4.7  Fabric Finishing

  Chemical finishes are applied to fabric to impart certain characteristics.  For example,
permanent-press, soil-release, soil-resistant, and stain-resistant finishes may be applied to
make caring of the fabric easier.  To provide comfort and safety, absorbent, antistatic,
flame-retardant, chemical-resistant, and water-repellent finishes may be applied.  The feel of
fabric may be improved with softeners. These finishes are applied by padding a solution or
resin onto the fabric,  drying it on a tenter frame to specific dimensions, and curing it in an
oven.

  Other finishes are applied by physical means. Calendering is a process where fabric is
passed over heated rolls, imparting a slick  and shiny surface.  Other mechanical finishing
processes that can alter the texture of the fabric include napping, sueding, brushing, and
shearing.

4.5.4.8  VOC Emissions from  Products Used in the Textile Industry

  Estimates of VOC emissions can be made for certain  solvent-containing products that are
used in the textile industry.  In this section, estimates are calculated for emissions from:

  •      parts washer solvents used by garment screen printers;
  •      platen adhesives; and
  •      spot cleaners.

Garment screen printers primarily use  parts washer solvents to clean ink from press parts.
Most garment screen  printers also use  platen adhesives.  Spot cleaners may be used in any
textile facility that produces a finished product (e.g., thread, yarn, fabric, garments, etc.).

  In some instances, it is difficult or impossible to estimate emissions from a specific
product.  For example, estimates of emissions from winder cleaners are complicated by the
                                          4-63

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fact that facilities may use products that contain very different amounts of solvent. Estimates
of emissions from cot adhesives pose a similar problem since some facilities use fiber-,
metal-, or plastic-lined cots that do not require adhesive.  The same difficulty is encountered
when attempting to determine emissions from the screen cleaners used in garment screen
printing facilities.  Some facilities use products containing 100 percent petroleum distillates
while others use water-based products containing d-limonene. Similarly, the screen
reclaimers that are used may or may not contain solvent.  Although data were collected
during the site visits on each of these specific products, this information may not represent
the true distribution of their use within the industry and, therefore, cannot be extrapolated on
a national basis for emission estimates.

  Parts Washer Solvent

  Two factors  may affect the emission of solvent from parts washers: evaporation from  the
sink and evaporation from depleted solvent that is splattered or carried out of the washer on
wet parts.  In general, newer models  of parts washers are designed so that the  solvent returns
by  gravity to the reservoir, where it is less likely to evaporate.  Therefore, for the purposes
of this estimate, emissions due to evaporation from the sink will be ignored. In some
instances, these emissions may be significant (e.g., at a facility where an older parts washer
with an open reservoir is used). Exact measurements of solvent depletion through carryout
are not available.  Therefore, an assumption that 10 percent of the solvent is lost during the
interval of usage was used for this calculation.

  The emission estimates are also based on usage data collected from site visits to three
garment screen printing facilities.  The amount of parts washer solvent used by a printer will
depend not only on the number of press pieces cleaned but also, to some extent, on the
number of garments printed.  Therefore, an estimate of the amount of parts cleaning solvent
used per garment was  calculated and used to determine emissions.
                                          4-64

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  Results from these estimation methods are shown in Table 4.5-2.  Emissions from facilities
that print 100 dozen or fewer garments each day are ignored since it is assumed that facilities
this small will not operate a parts washing machine.
                                         4-65

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  Platen Adhesives

  The emissions estimates for platen adhesives, shown in Table 4.5-3, were determined from
two sources of data: platen adhesive usage data collected from the SPAI survey and the total
number of garment screen printing facilities, determined from the SPAI 1990 Industry Profile
Results. The outcome of the estimate shows that 4,935.9 tons of platen adhesives are used
by garment screen printers each year. Water-based platen adhesives account for 2.6 percent,
or 126.6 tons, of the usage.  Yearly VOC emissions are 3,486.4 tons, of which 37.6 percent
is from VOC propellants.  Non-VOC organic chemicals emissions are 797.1 tons; 1,1,1-TCA
and MeCl2 account for 44.0 and 56.0 percent, respectively, of this amount.
                                    TABLE 4.5-3
                          PLATEN  ADHESIVE EMISSIONS

Total Usage
Usage of Water-based Products
Total Organic Emissions
• VOC Emissions
-- VOC Propellants
• NonVOC Emissions
1,1,1-TCA
- MeCl2
Average per
Facility, Ibs
939.4
(16,467.2 fl. oz.)
24.1
815.2
663.5
249.7
151.7
66.8
84.9
Estimated Yearly Amounts
Pounds
9,871,797.8
253,161.4
8,566,963.7
6,972,764.2
2,624,221.3
1,594,199.5
702,086.6
892,112.9
Tons
4,935.9
126.6
4,283.5
3,486.4
1,312.1
797.1
351.0
446.1
                                       4-67

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  Spot Cleaners

  Only emissions from garment screen printers and finishers of woven or knit goods were
determined in this section.  Estimates of emissions for spot cleaners used by garment screen
printers are presented in Table 4.5-4.  Garment screen printers use 3,256.3 tons of VOC-
based spot cleaners each year.  Finishers of woven and knit goods use spot cleaners which
contain no VOC's but which contain 1,1,1 trichloroethane. Therefore, no VOC emissions
can be attributed to the use of spot cleaners in these two segments of the industry.
                                         4-68

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4.5.5   References for Section 4.5

1.      U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
        Park, North Carolina, Source Characterizations and Emission Estimates for Mold
        Release Agents and Roofing Applications, September 1993.

2.      U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
        Park, North Carolina, Project Summary - Assessment ofVOC Emissions from
        Fiberglass Boat Manufacturing, (EPA-600/S2-90/019), June 1990.

3.      U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
        Park, North Carolina, Evaluation of Volatile Organic Emissions Data for
        Nonprocess Solvent Use in 15 Commercial and Industrial Business  Categories,
        (EPA-600/R-94-019), February 1994.

4.      U.S. EPA Air and Energy Engineering Research Laboratory, Research Triangle
        Park, North Carolina, Nonprocess Solvent Use in the Textile Industry,  August 1993.
                                       4-70

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