Office of Pesticides gpA 560/4-91 -002 and Toxic Substances December 1990 EPA The Emergency Planning and Community Right-to-Know Act Section 313 Release Reporting Requirements vyo Printed on Recycled Paper ------- ------- This brochure contains information about the Emergency Planning and Community Right-to-Know Act. This law estab- lishes a structure at the state and local levels to assist communi- ties in planning for chemical emergencies and requires facilities to provide information on various chemicals present in the com- munity. The Act requires that this information be made available to the public One of the requirements concerns the reporting of annual releases of toxic chemicals to the air, water, and land. These provisions are outlined in Section 313 which mandates annual release reporting for over 300 chemicals. Other reporting requirements are included elsewhere in the Act This booklet deals with Section 313. It is important that you read this information to see if you are subject to Section 313 reporting requirements The first reports under this Section, covering the 1987 calendar year, were due by July 1, 1988. Reports for subsequent calendar years are due the following July 1 EPA is responsible for ad- ministering this Section and developing a database that will make information in the reports available to the public. The Emergency Planning and Community Right-to-Know Act is important in providing to the public information about chemicals in the community. I look forward to working with you to make its implementation a success. William K. Reilly Administrator, Environmental Protection Agency ------- ------- THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT EPA has prepared this brochure to alert businesses to their reporting obligations under Sec- tion 313 of the Emergency Planning and Community Right- to-Know Act (EPCRA)*, and to help you de- termine whether your facility is covered under the law. If you are covered, this brochure will also help you prepare to meet your reporting obligations. If you are uncertain whether you are covered, it will tell you how to get assistance. This brochure deals with reporting requirements of only one section of the Emergency Planning and Community Right-to-Know Act: Section 313, which pertains to release reporting. Other EPCRA plan- ning and reporting requirements may also affect your business. The nearest EPA regional office can provide complete details, but the other basic re- quirements of EPCRA are as follows: Facility owners/operators that have on their premises chemicals designated under EPCRA as "extremely hazardous sub- stances" must cooperate with state and local planning officials in preparing comprehensive emergency plans (Sections 302 and 303); • Facility owners/operators must report acci- dental releases of "extremely hazardous sub- stances" and CERCLA "hazardous sub- stances" to state and local response officials (Section 304); and * The Act is also known as Title III of SARA (the Superfund Amendments and Reauthorization Act of 1986). ------- Facility owners/operators must make Material Safety Data Sheets (MSDSs) available to local and state officials and must also report, to lo- cal and state officials, Inventories (including locations) of chemicals on their premises for which MSDSs exist (Sections 311 and 312). • For more information on the Emergency Plan- ning and Community Right-to Know Act, ask your regional EPA office for the EPCRA Fact Sheet; or call the Emergency Planning and Community Right-to-Know Information Hotline, (800) 535-0202 or (202) 479-2449 (in Washington, D.C. and Alaska). REPORT TOXIC CHEMICAL RELEASES Under Section 313 of the Emergency Planning and Community Right-to-Know Act, certain busi- nesses are required to submit reports each year on the amounts of toxic chemicals their facilities re- lease into the environment, either routinely or as a result of accidents. The purpose of this reporting requirement is to inform government officials and the public about releases of toxic chemicals into the environment. Section 313 requires facilities to re- port releases to air, water, and land. The reports must be sent to the United States Environmental Protection Agency (EPA) and to designated state agencies. Reports are due by July 1 each year. Those who fail to report as required are subject to civil penalties of up to $25,000 a day. The final Toxic Chemical Release Inventory rule under Section 313 was published in the Federal Register on February 16, 1988. ------- WHO MUST REPORT A plant, factory, or other facility is subject to the provisions of Section 313 if it meets aH three of the following criteria: It conducts manufacturing operations (Is In- cluded In Standard Industrial Classification (SIC) codes 20 through 39, listed on page 9); and • It has 10 or more full-time employees; and • It manufactures, Imports, processes, or other- wise uses any of the toxic chemicals listed on pages 15-24 in amounts greater than the "threshold" quantities specified below. At present, 318 Individual chemicals and 20 cate- gories of chemicals are covered. The list may be changed In future years. • THRESHOLDS Thresholds are specified amounts of toxic chemicals used during the calendar year that trigger reporting requirements. If you manufacture or import any of the listed toxic chemicals, the threshold quantity will be: • 25,000 pounds per toxic chemical or category over the calendar year. If you process any of the listed toxic chemicals, the threshold quantity will be: • 25,000 pounds per toxic chemical or catagory over the calendar year. If you otherwise use any listed toxic chemical (without incorporating it into any product or produc- ing it at the facility), the threshold quantity is: • 10,000 pounds in per toxic chemical or catagory over the calendar year. ------- What is meant by the terms "manufacture," "process," or "otherwise use'"? • Manufacture - means to produce, prepare, import or compound one of the toxic chemi- cals on the list. For example, if you make a dye for clothing by taking raw materials and react- ing them, you are manufacturing the dye. You would also be covered if you were a textile manufacturer who imported a dye on the list for purposes of applying it to fabric produced at your plant. • Process - in general, is the incorporation of a toxic chemical into a product and includes making mixtures, repackaging, or using atoxic chemical as a feed-stock, raw material, or starting material for making another chemical. Processing also includes incorporating a toxic chemical. Examples of processing include: a Adding a solvent as a diluent when mak- ing a paint, coating, or other mixture; n Using a chemical as a reactant in the manufacture of a pesticide (e.g., using chemical A to make chemical B). • Otherwise Use - applies to any use of a toxic chemical at a covered facility that is not cov- ered by the terms "manufacture" or "process" and includes use of a toxic chemical contained in a mixture or trade name product. A toxic chemical that is otherwise used by a facility is not intentionally incorporated into a product distributed in commerce. Examples include: D Using a metal cutting fluid that contains diethanolamine; n Using a heat transfer fluid containing biphenyl; n Using trichloroethylene to degrease tools; a Using chlorine in waste water treatment; D Using Freon 113 as a refrigerant to coo! process streams. ------- Section 313 defines a "facility" as all buildings, equipment, structures, and other stationary items which are located on a single site or on contiguous or adjacent sites and which are owned or operated by the same person. Warehouses on the same site as covered facilities are covered at the threshold levels given above. Stand-alone warehouses that do not support a manufacturing operation are not currently covered. The reporting thresholds apply to toxic chemi- cals known by the owner or operator to be used in amounts above the thresholds. Section 313 re- quires suppliers of mixtures and trade name prod- ucts to notify customers of the presence of Section 313 listed chemicals in their products beyond cer- tain de minimis concentrations (these cutoffs are discussed under "Exemptions"). This supplier notifi- cation requirement has been in effect since January 1,1989. EXEMPTIONS Under certain circumstances, some or all of the reporting requirements under Section 313 may not apply to a facility. The following are the major exemptions: >• De minimis concentrations of a toxic chemical in certain mixtures. In determining whether the amount of a toxic chemical used at your facility exceeds the reporting threshold listed on page 3, you are not required to count the amount of toxic chemical present in a mixture if its concentration is less than 1 percent of the mixture, or • its concentration is less than 0.1 percent of the mixture when the chemical is defined by the Occupational Safety and Health Administration (OSHA) as carcinogenic; the chemical list beginning on page 15 identifies these chemicals. ------- ^ Articles. In considering whether a reporting thresh- old has been exceeded, you are not required to count toxic chemicals present in articles processed or used at your facility. An "article" is a manufactured item: (1) which is formed to a specific shape or design during manufacture; (2) which has end use functions dependent in whole or in part upon its shape or design during end use; and (3) which does not release a toxic chemical un- der normal conditions of processing or use of that item at the facility or establishments. ^ Specified Uses. In considering whether a reporting threshold has been exceeded, you are not required to count toxic chemicals that are used at your facility for any of the following purposes: As a structural component of the facility; In routine janitorial or facility grounds mainte- nance; In foods, drugs, cosmetics, or other items for personal use, Including supplies of such Items (for example, In a facility-operated cafeteria); In motor vehicle maintenance (Including mo- tor fuel); or In process water and non-contact cooling water as drawn from the environment or from municipal sources, or In air used either as compressed air or as part of combustion. ------- ^ Laboratories. In considering whether a reporting threshold has been exceeded, you are not required to count toxic chemicals that are manufactured, processed, or otherwise used for research or qual ity control in a labo- ratory at a covered facility under the supervision of a tech- nically qualified individual. This exemption does not ap- ply to production, processing, or the use of toxic chemi- cals in pilot plant scale operations and laboratories for distribution in commerce. >> Owners of Leased Property. The owner of a cov- ered facility is not subject to reporting under Section 313 if the owner's only interest in the facility is ownership of the real estate upon which the facility is operated. How- ever, the operator of the facility must report if the criteria are met. ------- HOW TO REPORT The owner or operator of a covered facility must report annually. Each report must be submitted on or before July 1 for activities during the previous calendar year. EPA will provide a reporting form (EPA Form R) with instructions and technical guidance on how to calculate toxic chemical releases or emissions from your facility. To obtain the reporting form, instruc- tions, and technical guidance, write a letter or check the boxes for those publications on the back cover, detach the cover, and mail it to: Emergency Plan- ning and Community Right-to-Know Document Dis- tribution Center, P.O. Box 12505, Cincinnati, OH 45212, or any of the EPA regional offices listed on pages 13-14. You are not required to measure or monitor re- leases for purposes of Section 313 reporting. You may use readily available data to report the quanti- ties of chemicals that you use and the amounts re- leased into the environment. If you have no data available, the law permits you to report reasonable estimates. EPA's technical guidance on calculating releases can help you in making estimates. ------- STANDARD INDUSTRIAL CLASSIFICATION (SIC) GROUPS SUBJECT TO SECTION 313 SIC INDUSTRY GROUP 20 Food 21 Tobacco 22 Textiles 23 Apparel 24 Lumber and Wood 25 Furniture 26 Paper 27 Printing and Publishing 28 Chemicals 29 Petroleum and Coal 30 Rubber and Plastics 31 Leather 32 Stone, Clay, and Glass 33 Primary Metals 34 Fabricated Metals 35 Machinery (excluding electrical) 36 Electrical and Electronic Equipment 37 Transportation Equipment 38 Instruments 39 Miscellaneous Manufacturing If you do not know your SIC code, check with your finan- cial office, trade association, or legal counsel, or contact your local Chamber of Commerce or State Department of Labor. For more information on SIC codes, please consult "Standard Industrial Classification Manual 1987," available in most libraries or for purchase from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Phone: (703) 487-4650 Document Number: PB 87-100012 $30.00 ------- WHAT YOU MUST REPORT You must report on EPA Form R the following information for each listed toxic chemical manu- factured, imported, processed, or otherwise used at your facility in yearly amounts which exceed the threshold: The name and location of your facility; • The identity of the listed toxic chemical (un- less you claim Its Identity to be a trade secret): • Whether you manufacture, import, process, or otherwise use the toxic chemical; • The maximum quantity of the toxic chemical on-site at any time during the year; The total quantity of the toxic chemical re- leased during the year, including both acci- dental spills and routine emissions - separate estimates must be provided for releases to air, water, and land (e.g., deep well injection, per- mitted landfill); • Off-site locations to which you shipped wastes containing the toxic chemical and the quantities of that toxic chemical sent to those locations; and • On-site treatment or disposal methods used for wastes containing the toxic chemical and estimates of their treatment efficiency for each toxic chemical. • For purposes of Section 313, a release is de- fined as any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or disposing into the environ- ment (including the abandonment or discarding of barrels, containers, and other closed receptacles) of any "toxic chemical" (i.e., any of the toxic chemicals on pages 15-24). 10 ------- PUBLIC ACCESS TO REPORTS The law requires facilities covered by Section 313 to send toxic chemical release reports both to EPA and to the state in which the facility is located. At EPA, the Office of Toxic Substances is responsi- ble for receiving and processing the data. The agency designated to receive reports in your state is listed in the instructions for Form R. EPA is required by law to make the data in the reports available to the public through a computer database. (You can claim the toxic chemical iden- tity to be a trade secret, but you must justify the claim to EPA. The final Trade Secret rule was pub- lished in the Federal Register on July 29, 1988.) The database is intended to help answer citizens' questions about toxic chemical releases in their community. The users of the data are also likely to include researchers from the government or universi- ties conducting environmental analyses. EPA ex- pects to use the data in a variety of ways, including targeting problem pollution areas and as a screen- ing tool for developing standards and regulations. WHAT YOU CAN DO NOW You can begin planning now to make compliance with Section 313 as easy and inexpen- sive as possible. The steps are as follows: GO If you have 10 or more full-time employees (that is, if the total annual hours worked by all employees is at least 20,000 hours), check the SIC code list on page 9 to determine whether your facility is covered. 11 ------- g] Check the list of toxic chemicals covered by Section 313 (pages 15-24) to see if any are manufactured, imported, processed, or other- wise used by your facility. For reporting year 1989 and subsequent years, your chemical supplier is required to inform you if any of the Section 313 toxic chemicals is contained in mixtures sold to you. Also, the document Common Synonyms for Section 313 Chemi- cals can assist you in identifying toxic chemi- cals. m Determine whether you handle any toxic chemical on the list in an amount greater than the thresholds on page 3. g) If you meet the criteria, request copies of the reporting form, instructions, and any of the appropriate guidance documents listed at the back of this brochure. O Begin to develop the appropriate information to report your releases. H Maintain a recordkeeping system that will help you estimate releases for future years. You should designate someone at your facility to be responsible for reporting under Section 313. That person should obtain reporting forms and in- structions and should be aware of the reporting deadline: July 1 of each year. The reporting forms and instructions can be ob- tained by mailing in the order form on the inside back cover or by calling one of the EPA regional offices listed on pages 13-14. 12 ------- SECTION 313 EPA REGIONAL CONTACTS Region 1 Pesticides & Toxics Branch USEPA Region 1 (APT2311) JFK Federal Building Boston, MA 02203 (617) 565-3230 Connecticut, Massachusetts, Maine, New Hampshire, Rhode Island, Vermont Region 2 Pesticides & Toxics Branch USEPA Region 2 (MS240) Woodbridge Avenue, Building 209 Edison, NJ 08837-3679 (201) 906-6890 New Jersey, New York, Puerto Rico, Virgin Islands Region 3 Toxics & Pesticides Branch USEPA Region 3 (3AM31) 841 Chestnut Street Philadelphia, PA 19107 (215) 597-1260 Delaware, Maryland, Pennsylvania, Virginia, West Virginia, District of Columbia Region 4 Pesticides & Toxics Branch USEPA Region 4 345 Courtland Street Atlanta, GA 30365 (404) 347-1033 Alabama, Florida, Georgia, Kentucky, Mississippi, North Carolina, South Carolina, Tennessee Region 5 Pesticides & Toxic Substances Branch USEPA Region 5 (5SPT-7) 230 South Dearborn Street Chicago, IL 60604 (312) 353-5907 Illinios, Indiana, Michigan, Minnesota, Ohio, Wisconsin 73 ------- SECTION 313 EPA REGIONAL CONTACTS Region 6 Pesticides & Toxic Substances Branch USEPA Region 6 (6TPT) 1445 Ross Avenue Dallas, TX 75202-2733 (214) 655-7244 Arkansas, Louisiana, New Mexico, Oklahoma, Texas Region 7 Office of Congressional and Intergovernmental Liaison USEPA Region 7 (CIGL) 726 Minnesota Avenue Kansas City, KS 66101 (913)551-7005 Iowa, Kansas, Missouri, Nebraska Region 8 Toxic Substances Branch USEPA Region 8 (8AT-TS) 999 18th Street Denver, CO 80202-2405 (303) 293-1730 Colorado, Montana, North Dakota, South Dakota, Utah, Wyoming Region 9 Pesticides & Toxics Branch USEPA Region 9 (A-4-3) 215 Fremont Street San Francisco, CA 94105 (415) 974-7054 Arizona, California, Hawaii, Nevada, American Samoa, Guam, Commonwealth of the Northern Mariana Islands Region 10 Pesticides & Toxic Substances Branch USEPA Region 10 (AT083) 1200 Sixth Avenue Seattle, WA 98101 (206) 442-1091 Alaska, Idaho, Oregon, Washington 14 ------- ALPHABETICAL LIST OF SECTION 313 CHEMICALS CAS De Minimis Number Chemical Name Concentration (percent) 75-07-0 Acetaldehyde 0.1 60-35-5 Acetamide 0.1 67-64-1 Acetone 1.0 75-05-8 Acetonitrile 1.0 53-96-3 2-Acetylaminofluorene 0.1 107-02-8 Acrolein 1.0 79-06-1 Acrylamide 0.1 79-10-7 Acrylic acid 1.0 107-13-1 Acrylonitrile 0.1 309-00-2 Aldrin [1,4:5,8-Dimethanonaphthalene, 1.0 1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a- hexahydrc~(1.alpha.,4.alpha.,4a.beta., 5.alpha.,8.alpha.,8a.beta.)-] 107-18-6 Allyl Alcohol 1.0 107-05-1 Allyl chloride 1.0 7429-90-5 Aluminum (fume or dust) 1.0 1344-28-1 Aluminum oxide (fibrous form) 0.1 117-79-3 2-Aminoanthraquinone 0.1 60-09-3 4-Aminoazobenzene 0.1 92-67-1 4-Aminobiphenyl 0.1 82-28-0 1-Amino-2-methylanthraquinone ... 0.1 7664-41-7 Ammonia 1.0 6484-52-2 Ammonium nitrate (solution) 1.0 7783-20-2 Ammonium sulfate (solution) 1.0 62-53-3 Aniline 1.0 90-04-0 o-Anisidine 0.1 104-94-9 p-Anisidine 1.0 134-29-2 o-Anisidine hydrochloride 0.1 120-12-7 Anthracene 1.0 7440-36-0 Antimony 1.0 7440-38-2 Arsenic 0.1 1332-21-4 Asbestos (friable) 0.1 7440-39-3 Barium 1.0 98-87-3 Benzal chloride 1.0 55-21 -0 Benzamide 1.0 71-43-2 Benzene 0.1 92-87-5 Benzidine 0.1 98-07-7 Benzoic trichloride (Benzotrichloride) . 0.1 98-88-4 Benzoyl chloride 1.0 * Those chemicals marked with an asterisk have been added to the section 313 list, effective July 8, 1990. These chemicals will be subject to reporting for the 1991 reporting year with the first reports due by July 1, 1992, 15 ------- CAS Number Chemical Name De Minimis Concentration (percent) 94-36-0 Benzoyl peroxide 100-44-7 Benzyl chloride 7440-41-7 Beryllium 92-52-4 Biphenyl 111-44-4 Bis(2-chloroethyl) ether 542-88-1 Bis(chloromethyl) ether 108-60-1 Bis(2-chloro-1-methylethyl) ether ... 103-23-1 Bis(2-ethylhexyl) adipate *353-59-3 Bromochlorodifluoromethane (Halon 1211) Bromoform (Tribromomethane) Bromomelhane (Methyl bromide) Bromotrifluoromethane (Halon) 1,3-Butadiene Butyl acrylate n-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol Butyl benzyl phthalate 1,2-Butylene oxide Butyraldehyde Acid Green 3 Basic Green 4 Basic Red 1 Direct Black 38 Direct Blue 6 Direct Brown 95 Disperse Yellow 3 Food Red 5 Food Red 15 Solvent Orange 7 Solvent Yellow 3 Solvent Yellow 14 Solvent Yellow 34 (Auramme) ... Vat Yellow 4 Imium Calcium cyanamide Captan [1H-lsoindole-1,3(2H)-dione, 3a,4,7,7a-tetrahydro-2- [(trichloromethyl)thio]-] 63-25-2 Carbaryl [1-Naphthalenol methylcarbamate] 75-15-0 Carbon disulfide 56-23-5 Carbon tetrachloride 463-58-1 Carbonyl sulfide 75-25-2 74-83-9 *75-63-8 106-99-0 141-32-2 71-36-3 78-92-2 75-65-0 85-68-7 106-88-7 123-72-8 4680-78-8 569-64-2 989-38-8 1937-37-7 2602-46-2 16071-86-6 2832-40-8 3761-53-3 81-88-9 3118-97-6 97-56-3 842-07-9 492-80-8 128-66-5 7440-43-9 156-62-7 133-06-2 Broi Broi Broi 1,3- But' n-B sec tert- But< 1,2- But' C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. C.I. Cac Cah Cap 1.0 1.0 0.1 1.0 1.0 0.1 1.0 1.0 1.0 1.0 1.0 1.0 0.1 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.1 0.1 0.1 0.1 1.0 0.1 0.1 1.0 0.1 0.1 0.1 1.0 0.1 1.0 1.0 1.0 1.0 0.1 1.0 16 ------- CAS Number Chemical Name De Minimis Concentration (percent) 120-80-9 Catechol 1.0 133-90-4 Chloramben [Benzole acid 1.0 3-amirto-2,5-dich!oro-] 57-74-9 Chlordane [4,7-Methanoindan 1.0 1,2,4,5,6,7,8,8- octachloro- 2,3,3a,4,7,7a-hexahydro-] 7782-50-5 Chlorine 1.0 10049-04-4 Chlorine dioxide 1.0 79-11-8 Chloroacetic acid 1.0 532-27-4 2-Chloroacetophenone 1.0 108-90-7 Chlorobenzene 1.0 510-15-6 Chlorobenzilate [Benzeneacetic acid, 1.0 4-chloro-.alpha.-(4- chlorophenyl)- .alpha. -hydroxy -, ethyl ester] 75-00-3 Chloroethane (Ethyl chloride) 1.0 67-66-3 Chloroform 0.1 74-87-3 Chloromethane (Methyl chloride) 1.0 107-30-2 Chloromethyl methyl ether 0.1 126-99-8 Chloroprene 1.0 1897-45-6 Chlorothalonil [1,3- 1.0 Benzenedicarbonitrile, 2,4,5,6- tetrachloro-] 7440-47-3 Chromium 0.1 7440-48-4 Cobalt 1.0 8001 -58-9 Creosote 0.1 7440-50-8 Copper 1.0 120-71-8 p-Cresidine 0.1 1319-77-3 Cresol (mixed isomers) 1.0 108-39-4 m-Cresol 1.0 95-48-7 o-Cresol 1.0 106-44-5 p-Cresol 1.0 98-82-8 Cumene 1.0 80-15-9 Cumene hydroperoxide 1.0 135-20-6 Cupferron 0.1 [Benzeneamine, N-hydroxy-N-nitroso, ammonium salt] 110-82-7 Cyclohexane 1.0 94-75-7 2,4-D [Acetic acid 1.0 (2,4-dichloro-phenoxy)-] 1163-19-5 Decabromodiphenyl oxide 1.0 2303-16-4 Diallate [Carbamothioic acid.bis 1.0 (1-methylethyl)-, S-(2,3-dichloro-2-propenyl) ester] 615-05-4 2,4-Diaminoanisole 0.1 39156-41-7 2,4-Diaminoanisole sulfate 0.1 17 ------- CAS De Mlnimis Number Chemical Name Concentration (percent) 101-80-4 4,4'-Diaminodiphenyl ether 0.1 25376-45-8 Diaminotoluene (mixed isomers) 0.1 95-80-7 2,4-Diaminotoluene 0.1 334-88-3 Diazomethane 1.0 132-64-9 Dibenzofuran 1.0 96-12-8 1,2-Dibromo-3-chloropropane (DBCP)0.1 106-93-4 1,2-Dibromoethane 0.1 (Ethylene dibromide) * 124-73-2 Dibromotetrafluoroethane 1.0 (Halon 2402) 84-74-2 Dibutyl phthalate 1.0 25321-22-6 Dichlorobenzene (mixed isomers) ... 0.1 95-50-1 1,2-Dichlorobenzene 1.0 541-73-1 1,3-Dichlorobenzene 1.0 106-46-7 1,4-Dichlorobenzene 0.1 91-94-1 3,3'-Dichlorobenzidine 0.1 75-27-4 Dichlorobromomethane 1.0 *75-71-8 Dichlorodifluoromethane (CFC-12) ..1.0 107-06-2 1,2-Dichloroethane 0.1 (Ethylene dichloride) 540-59-0 1,2-Dichloroethylene 1.0 75-09-2 Dichloromethane (Methylene chloride) 0.1 120-83-2 2,4-Dichlorophenol 1.0 78-87-5 1,2-Dichloropropane 1.0 78-88-6 2,3-Dichloropropene 1.0 542-75-6 1,3-Dichloropropylene 0-1 *76-14-2 Dichlorotetrafluoroethane (CFC-114) 1.0 62-73-7 Dichlorvos [Phosphoric acid, 2 1.0 dichloroethenyl dimethyl ester] 115-32-2 Dicofol [Benzenemethanol, 4-chloro- 1.0 .alpha.- 4-chlorophenyl)- .alpha.- (trichloromethyl)-] 1464-53-5 Diepoxybutane 0.1 111-42-2 Diethanolamine 1.0 117-81-7 Di-(2-ethylhexyl) phthalate (DEHP) .. 0.1 84-66-2 Diethyl phthalate 1.0 64-67-5 Diethyl sulfate 0.1 119-90-4 3,3'-Dimethoxybenzidine 0.1 60-11-7 4-Dimethylaminoazobenzene 0.1 119-93-7 3,3'-Dimethylbenzidine(o-Tolidine) .0.1 79-44-7 Dimethylcarbamyl chloride 0.1 57-14-7 1,1-Dimethyl hydrazine 0.1 105-67-9 2,4-Dimethylphenol 1.0 131-11-3 Dimethyl phthalate 1.0 77-78-1 Dimethyl sulfate 0.1 ------- CAS Number Chemical Name De Minimis Concentration (percent) 99-65-0 m-Dinitrobenzene 1.0 528-29-0 o-Dinitrobenzene 1.0 100-25-4 p-Dinitrobenzene 1.0 534-52-1 4,6-Dinitro-o-cresol 1.0 51-28-5 2,4-Dinitrophenol 1.0 121-14-2 2,4-Dinitrotoluene 1.0 606-20-2 2,6-Dinitrotoluene 1.0 25321-14-6 Dinitrotoluene 1.0 (mixed isomers) 117-84-0 n-Dioctyl phthalate 1.0 123-91-1 1,4-Dioxane 0.1 122-66-7 1,2-Diphenylhydrazine 0-1 (Hydrazobenzene) 106-89-8 Epichlorohydrin 0.1 110-80-5 2-Ethoxyethanol 1.0 140-88-5 Ethyl acrylate 0.1 100-41-4 Ethylbenzene 1.0 541 -41 -3 Ethyl chloroformata 1.0 74-85-1 Ethylene 1.0 107-21-1 Ethylene glycol 1.0 151-56-4 Ethyleneimine (Aziridine) 0.1 75-21-8 Ethylene oxide 0.1 96-45-7 Ethylene thiourea 0.1 2164-17-2 Fluometuron [Urea, N,N-dimethyl-N'- 1.0 [3 - (trif luoromethyl) pheny I] -] 50-00-0 Formaldehyde 0.1 76-13-1 Freon 113 [Ethane, 1,1,2-trichloro-1,2, 1.0 2-trifluoro-] 76-44-8 Heptachlor [1,4,5,6,7,8,8-Heptachloro- 1.0 3a,4,7,7a-tetrahydro-4,7- methano-1H - indene] 118-74-1 Hexachlorobenzene 0.1 87-68-3 Hexachloro-1,3-butadiene 1.0 77-47-4 Hexachlorocyclopentadiene 1.0 67-72-1 Hexachloroethane 1.0 1335-87-1 Hexachloronaphthalene 1.0 680-31-9 Hexamethylphosphoramide 0.1 302-01 -2 Hydrazine 0.1 10034-93-2 Hydrazine sulfate 0.1 7647-01-0 Hydrochloric acid 1.0 74-90-8 Hydrogen cyanide 1.0 7664-39-3 Hydrogen fluoride 1.0 123-31-9 Hydroquinone 1.0 78-84-2 Isobutyraldehyde 1.0 ------- CAS De Minimis Number Chemical Name Concentration (percent) 67-63-0 Isopropyl alcohol (manufacturing- .. 0.1 strong acid process, no supplier notification) 80-05-7 4,4'-lsopropylidenediphenol 1.0 120-58-1 Isosafrole 0.1 7439-92-1 Lead 0.1 58-89-9 Lindane 0.1 [Cyclohexane, 1,2,3,4,5,6-hex- achloro- ,(1.alpha.,2.alpha.,3. beta., 4.alpha.,5.alpha.,6.beta.)-] 108-31-6 Maleic anhydride 1.0 12427-38-2 Maneb [Carbamodithioic acid, 1,2- ..1.0 ethanediylbis-, manganese complex] 7439-96-5 Manganese 1.0 7439-97-6 Mercury 1.0 67-56-1 Methanol 1.0 72-43-5 Methoxychlor [Benzene, 1,1'-(2,2,2- . 1.0 trichloroethylidene)bis [4-methoxy-] 109-86-4 2-Methoxyethanol 1.0 96-33-3 Methyl acrylate 1.0 1634-04-4 Methyl tert-butyl ether 1.0 101-14-4 4,4'-Methylenebis(2-chloro aniline) .. 0.1 (MBOCA) 101-61-1 4,4'-Methylenebis (N,N-dimethyl) ...0.1 benzenamine 101-68-8 Methylenebis(phenylisocyanate) (MBI) 1.0 74-95-3 Methylene bromide 1.0 101-77-9 4,4'-Methylenedianiline 0.1 78-93-3 Methyl ethyl ketone 1.0 60-34-4 Methyl hydrazine 1.0 74-88-4 Methyl iodide 0.1 108-10-1 Methyl isobutyl ketone 1.0 624-83-9 Methyl isocyanate 1.0 80-62-6 Methyl methacrylate 1.0 90-94-8 Michler's ketone 0.1 1313-27-5 Molybdenum trioxide 1.0 *76-15-3 Monochloropentafluoroethane 1.0 (CFG-115) 505-60-2 Mustard gas [Ethane, 1,1'-thiobis ... 0.1 [2-chloro-] 91-20-3 Naphthalene 1.0 134-32-7 alpha-Naphthylamine 0.1 91-59-8 beta-Naphthylamine 0.1 7440-02-0 Nickel 0.1 20 ------- CAS Number Chemical Name De Minimi's Concentration (percent) 7697-37-2 Nitric acid 1.0 139-13-9 Nitrilotriacetic acid 0.1 99-59-2 5-Nitro-o-anisidine 0.1 98-95-3 Nitrobenzene 1.0 92-93-3 4-Nitrobiphenyl 0.1 1836-75-5 Nitrofen [Benzene, 2,4-dichloro- .... 0.1 1-(4-nitrophenoxy)-] 51-75-2 Nitrogen mustard [2-Chloro-N-(2- ..0.1 chloroethyl) -N- methylethanamine] 55-63-0 Nitroglycerin 1.0 88-75-5 2-Nitrophenol 1.0 100-02-7 4-Nitrophenol 1.0 79-46-9 2-Nitropropane 0.1 156-10-5 p-Nitrosodiphenylamine 0.1 121-69-7 N,N-Dimethylaniline 1.0 924-16-3 N-Nitrosodi-n-butylamine 0.1 55-18-5 N-Nitrosodiethylamine 0.1 62-75-9 N-Nitrosodimethylamine 0.1 86-30-6 N-Nitrosodiphenylamine 1.0 621-64-7 N-Nitrosodi-n-propylamine 0.1 4549-40-0 N-Nitrosomethylvinylamine 0.1 59-89-2 N-Nitrosomorpholine 0.1 759-73-9 N-Nitroso-N-ethylurea 0.1 684-93-5 N-Nitroso-N-methylurea 0.1 16543-55-8 N-Nitrosonornicotine 0.1 100-75-4 N-Nitrosopiperidine 0.1 2234-13-1 Octachloronaphthalene 1.0 20816-12-0 Osmium tetroxide 1.0 56-38-2 Parathion [Phosphorothioic acid, o, ..1.0 o-diethyl-o-(4-nitrophenyl) ester] 87-86-5 Pentachlorophenol (PCP) 1.0 79-21-0 Peracetic acid 1.0 108-95-2 Phenol 1.0 106-50-3 p-Phenylenediamine 1.0 90-43-7 2-Phenylphenol 1.0 75-44-5 Phosgene 1.0 7664-38-2 Phosphoric acid 1.0 7723-14-0 Phosphorus (yellow or white) 1.0 85-44-9 Phthalic anhydride 1.0 88-89-1 Picric acid 1.0 1336-36-3 Polychlorinated biphenyls (PCBs) ... 0.1 1120-71 -4 Propane sultone 0.1 57-57-8 beta-Propiolactone 0.1 123-38-6 Propionaldehyde 1.0 114-26-1 Propoxur [Phenol, 2- 1.0 (1 - methylethoxy) -, methyIcarbamate] 21 ------- CAS Number Chemical Name De Minimis Concentration (percent) 115-07-1 Propylene (Propene) 1.0 75-55-8 Propyleneimine 0.1 75-56-9 Propylene oxide 0.1 110-86-1 Pyridine 1.0 91-22-5 Quinoline 1.0 106-51-4 Quinone 1.0 82-68-8 Quintozene [Pentachloronitrobenzene] 1.0 81-07-2 Saccharin (manufacturing, no supplier 0.1 notification) [1,2- Benzisothiazol -3(2H)-one, 1,1-dioxide] 94-59-7 Safrole , 0.1 7782-49-2 Selenium 1.0 7440-22-4 Silver 1.0 100-42-5 Styrene 0.1 96-09-3 Styrene oxide 0.1 7664-93-9 Sulfuric acid 1.0 100-21-0 Terephthalic acid 1.0 79-34-5 1,1,2,2-Tetrachloroethane 0.1 127-18-4 Tetrachloroethylene 0.1 (Perchloroethylene) 961-11-5 Tetrachlorvinphos 1.0 [Phosphoric acid, 2-chloro-1-(2,3,5- trichlorophenyl) ethenyl dimethyl ester] 961-11-5 Tetrachlorvinphos 1.0 [Phosphoric acid, 2-chloro-1- (2,3,5-trichlorophenyl) ethenyl dimethyl ester] 7440-28-0 Thallium 1.0 62-55-5 Thioacetamide 0.1 139-65-1 4,4'-Thiodianiline 0.1 62-56-6 Thiourea 0.1 7550-45-0 Titanium tetrachloride 1.0 1314-20-1 Thorium dioxide 1.0 108-88-3 Toluene 1.0 584-84-9 Toluene-2,4-diisocyanate 0.1 91-08-7 Toluene-2,6-diisocyanate 0.1 26471-62-5 Toluenediisocyanate 1.0 (mixed isomers) 95-53-4 o-Toluidine 0.1 636-21-5 o-Toluidine hydrochloride 0.1 8001-35-2 Toxaphene 0.1 68-76-8 Triaziquone [2,5-Cyclohexadiene 0.1 -1,4-dione, 2,3,5-tris(1 -aziridinyl) -] 22 ------- CAS De Minimis Number Chemical Name Concentration (percent) 52-68-6 Trichlorfon [Phosphonic acid, (2,2,2-. 1.0 trichloro-1-hydroxyethyl)-, dimethyl ester] 120-82-1 1,2,4-Trichlorobenzene 1.0 71-55-6 1,1,1-Trichloroethane 1.0 (Methyl chloroform) 79-00-5 1,1,2-Trichloroethane 1.0 79-01-6 Trichloroethylene 1.0 *75-69-4 Trichlorofluoromethane 1.0 95-95-4 2,4,5-Trichlorophenol 1.0 88-06-2 2,4,6-Trichlorophenol 0.1 1582-09-8 Trifluralin [Benzeneamine, 2,6- 1.0 dinitro-N,N-dipropyl-4-(trifluoromethyl)-] 95-63-6 1,2,4-Trimethylbenzene 1.0 126-72-7 Tris(2,3-dibromopropyl) phosphate .. 0.1 51-79-6 Urethane (Ethyl carbamate) 0.1 7440-62-2 Vanadium (fume or dust) 1.0 108-05-4 Vinyl acetate 1.0 593-60-2 Vinyl bromide 0.1 75-01-4 Vinyl chloride 0.1 75-35-4 Vinylidene chloride 1.0 1330-20-7 Xylene (mixed isomers) 1.0 108-38-3 m-Xylene 1.0 95-47-6 o-Xylene 1.0 106-42-3 p-Xylene 1.0 87-62-7 2,6-Xylidine 1.0 7440-66-6 Zinc (fume or dust) 1.0 12122-67-7 Zineb [Carbamodithioic acid, 1,2- ... 1.0 ethanediylbis-, zinc complex] 23 ------- CHEMICAL CATEGORIES Section 313 requires emissions reporting on the toxic chemical categories listed below, in addition to the specific toxic chemicals listed above. The metal compounds listed below, unless other- wise specified, are defined as including any unique chemical substance that contains the named metal (i.e., antimony, copper, etc.) as part of that chemical's struc- ture. Toxic chemical categories are subject to the 1 per- cent de minimi's concentration unless the substance involved meets the definition of an OSHA carcinogen for which the 0.1 percent de minimis concentration applies. • Antimony Compounds • Arsenic Compounds • Barium Compounds • Beryllium Compounds • Cadmium Compounds • Chlorophenols • Chromium Compounds • Cobalt Compounds • Copper Compounds • Cyanide Compounds - X+CNT where X = H + or any other group where a formal dissociation may occur. For example KCN or Ca(CN)2 • Glycol Ethers - includes mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol. Polymers are excluded from the glycol ether category. • Lead Compounds • Manganese Compounds • Mercury Compounds • Nickel Compounds • Polybrominated Biphenyls (PBBs) • Selenium Compounds • Silver Compounds • Thallium Compounds • Zinc Compounds 24 ------- FOR MORE INFORMATION Write to: Emergency Planning and Community Right-to-Know Information Hotline, 401 M St., SW (OS-120) Washington, D.C. 20460 Or for regulatory and technical assistance, call: Emergency Planning and (800) 535-0202 Community Right-to-Know or Information Hotline, (202) 479-2449 (in Washington, D.C. and Alaska) Asbestos and Small (800) 368-5888 Business Ombudsman or Hotline (703) 557-1938 (in Washington, D.C. and Virginia) Other Information: • EPA is developing a series of videotapes to help ex- plain the Emergency Planning and Community Right-to-Know Act. For more information on the video tapes, call the Emergency Planning and Com- munity Right-to-Know Information Hotline. • EPA's technical guidance on Estimating Releases (EPA 560/4-90-009) is available f.om: Emergency Planning and Community Right-to-Know Document Distribution Center, P.O. Box 12505, Cincinnati, OH 45212. • EPA's Comprehensive List of Chemicals Subject to Reporting under the Act (Title III List of Lists) is avail- able as an IBM compatible disk from: The National Technical Information Service, 5285 Port Royal Road, Springfield, VA 22161, (703) 487-4650. Docu- ment Number: PB 90-501479, $80.00. 25 ------- ------- AVAILABLE FROM EPA Oheck the boxes below to receive reporting forms and publications about Section 313. Remove this page, put it in an envelope, and mail it to: Emergency Planning and Community Right-to- Know Document Distribution Center, P.O. Box 12505, Cincinnati, OH 45212. (Please correct your mailing label if necessary.) D Toxic Chemical Release Inventory Reporting Pack- age (EPA 560/4-91-001) a Title III Section 313 Reporting Form R and Instruc- tions (EPA 560/4-91-007) a TRI Magnetic Media Submission Guidance Pack- age (EPA 560/7-91-008) n Toxic Chemical Release Inventory Questions and Answers Document (EPA 560/4-91-003) D Common Synonyms for Section 313 Chemicals (EPA 560/4-91-005) D Comprehensive List of Chemicals Subject to Report- ing under the Act (Title III List Of Lists) (EPA 560/4-91-011) ci Supplier Notification Requirements Brochure (EPA 560/4-91-006) n Estimating Releases and Waste Treatment Efficien- cies (EPA 560/4-88-009) Note: These documents will not be available until January 1991. Industry Specific Technical Guidance Documents for estimating releases: n Monofilament Fiber Manufacture (EPA 560/4-88-004a) a Printing Operations (EPA 560/4-88-004b) a Electrodeposition of Organic Coatings (EPA 560/4-88-004C) D Spray Application of Organic Coatings (EPA 560/4-88-004d) n Semiconductor Manufacture (EPA 560/4-88 -004e) u Formulating Aqueous Solutions (EPA 560/4-88-004f) Electroplating Operations(EPA 560/4-88-004g) Textile Dyeing (EPA 560/4-88-004h) Presswood and Laminated Wood Products Manu- facturing (EPA 560/4-88-004I) Roller, Knife, and Gravure Coating Operations (EPA 560/4-88-004J) Paper and Paperboard Production (EPA 560/4-88-004k) Leather Tanning and Finishing Processes (EPA 560/4-88-004I) Wood Preserving (EPA 560/4-88-004p) Rubber Production and Compounding (EPA 560/4-88-004q) ------- I - •$. •> m c 8:5 =s 5> Q. ® r\? d C g CD « 8 I m I ^ a x QfQ 1 s? ------- |