AUGUST  1985
ATMOSPHERIC DIFFUSION MODELING BASED ON BOUNDARY LAYER PARAMETERIZATION
                ATMOSPHERIC SCIENCES RESEACH LABORATORY
                  OFFICE OF RESEARCH AND DEVELOPMENT
                U. S.  ENVIRONMENTAL PROTECTION AGENCY
                  RESEARCH TRIANGLE PARK, NC  27711

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ATMOSPHERIC DIFFUSION MODELING BASED ON BOUNDARY LAYER PARAMETERIZATION
                                   by
                              J. S. Irwin
                  Meteorology and Assessment Division
                Atmospheric Sciences Research Laboratory
                      Research Triangle Park, USA
                             S. E. Gryning
                        Ris«i National Laboratory
                           Roskilde,  Denmark
                           A. A. M. Holtslag
               Royal Netherlands Meteorological Institute
                        DeBilt, The Netherlands
                              B. Sivertsen
                  Norwegian Institute for Air Research
                           Lillestrjfa, Norway
                ATMOSPHERIC SCIENCES RESEACH LABORATORY
                  OFFICE OF RESEARCH AND DEVELOPMENT
                U. S. ENVIRONMENTAL PROTECTION AGENCY
                  RESEARCH TRIANGLE PARK, NC  27711

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                                 NOTICE
       The  information  in  this  document has  been  funded  in  part by  the United
  States  Environmental  Protection Agency  (EPA), under  agreement DW-13931239
  between the  EPA and the  Air Resources Laboratories  (ARL), National  Oceanic
  and  Atmospheric Administration (NOAA).   It has  been  subjected to  the Agency's
  peer and  administrative  review, and  it  has been approved  for publication as
  an EPA  document.   Approval does not  signify  that  mention  of trade names or
  commercial products constitute endorsement or recommendation for  use.
                              AFFILIATION

Mr. John S. Irwin is on assignment from the National Oceanic and Atmospheric
Administration, U. S. Department of Commerce.
                                    11

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                             PREFACE






During September 12-16, 1983 at the Royal Netherlands Meteorological Institute




and in June 25-29, 1984 at the Ris^ National Laboratory, a workgroup of scien-




tists from four air research and meteorological agencies met to review and




discuss methods for characterizing diffusion meteorology.  The contents of




this report summarizes the discussions of these meetings.  Based on this




report, the workgroup drafted two papers which were presented at the 15-th




International Technical Conference on Air Pollution Modeling and Its Appli-




cation (16-19 April 1985 at St.  Louis, MO):




     Parameterization of the  atmospheric boundary layer for air pollution




     dispersion models by A.A.M. Holtslag, S.E. Gryning, J.S. Irwin and




     B. Sivertsen.




     Atmospheric dispersion modeling based upon boundary layer parameter-




     ization by B. Sivertsen, S.E. Gryning, J.S. Irwin and A.A.M. Holtslag.




These two papers extend the concepts presented in this report and demonstrate




the performance of the suggested dispersion modeling using nonbuoyant tracer




data from field experiments conducted in Denmark and Norway.  A bound version




of the proceedings of the conference will be made available through Plenum




Press as Air Pollution Modeling and Its Application V.
                                  iii

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                                ABSTRACT









     The conclusions of a workgroup are presented outlining methods for




processing meteorological data for use in air quality diffusion modeling.  To




incorporate the proper scaling parameters the discussion is structured in




accordance with the current concepts for the idealized states of the planetary




boundary layer.  We recommend a number of models, the choice of which depends




on the actual idealized state of the atmosphere.  Several of the models




characterize directly the crosswind integrated concentration at the surface,




thus avoiding whenever justified the assumption of a Gaussian distribution of




material in the vertical.  The goal was to characterize the meteorological




conditions affecting the diffusion for transport distances on the order of 10




km or less.  Procedures are suggested for estimating the fundamental scaling




parameters.  For obtaining the meteorological data needed for estimating the




scaling parameters, a minimum measurement program to be carried out at a mast




is recommended.  If only synoptic data are available, methods are presented




for the determination of the scaling parameters.  Also, methods are suggested




for estimating the vertical profiles of wind velocity, temperature, and the




variances of the vertical and lateral wind velocity fluctuations.
                                     iv

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                          CONTENTS


Notice	     ii

Preface	    iii

Abstract	     iv

List of Symbols	     vi

1.  Introduction 	      I

2.  The Boundary Layer	      3

    2.1  The Unstable Boundary Layer  	      3
    2.2  The Stable Boundary Layer 	      7

3.  Parameters	      9

    3.1  The Surface Roughness Length   	      9
    3.2  The Monin-Obukhov Length     	     10
    3.3  Mixing Height and Inversion Height   	     14

4.  Profiles	     16

    4.1  Wind Profile	     16
    4.2  Temperature Profile 	     18
    4.3  Turbulence Profiles 	     19

5.  Diffusion	     23

    5.1  The Surface Layer	     26
    5.2  The Mixed Layer	     29
    5.3  The Free Convection Layer	     30
    5.4  The Entrainment Layer	     31
    5.5  The Near Neutral Upper Layer	     32
    5.6  The Local Scaling Region	     32

6.  Discussion	     34

7.  References	     37

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                               LIST OF  SYMBOLS
      a = an empirical constant,  used  in Eq  (4-4)  in the  estimation of  the
          nighttime potential  temperature profile

  al»a2 = empirical constants  used  in  shape  parameter equations
  t>i,b2
  c,p
      b = empirical constant,  used  in  Eq (5-15)

    A,B = shape constant  functions  used  to describe  general  solution to the
          two-dimensional diffusion equation

     Aw = empirical constant,  used  in  Eq (4-5)  in  the estimation of the
          variance of the vertical  wind  speed fluctuations

d,di,d2 = empirical constants  used  in  parameterization of the net radiation
c,ci,c2
c3

  C4,C5 = empirical constant,  used  to  determine  mixing height in Eq (3-7)

     C6 = empirical constant,  used  to  determine  mixing height in Eq (3-8)

     Cp = specific heat capacity at constant pressure

      d = empirical constant,  used  in  Eq (4-5)  in  the estimation of the
          variance of the vertical  wind  speed fluctuations

      D = angle between the surface wind direction and the geostrophic wind
          direction

      f = Coriolis parameter

  fs,fg = weighting functions  used  in  the estimation of the vertical profile of
          the wind

  fy,fz = empirical functions  describing the growth of the disperision
          parameters,  ay and  az

      F = plume buoyancy, gQa/^pCpTo
                                         2
     F* = plume buoyancy parameter, F/(UwAzi)

      g = acceleration due to  gravity

      G = geostrophic wind speed
                                        vi

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 Go  = soil  heat  flux

  h  = surface  temperature  inversion height
  H = pcpw'0',  sensible  heat  flux

 Hj = integral  of  heat flux,  Eq  (4-4)

  k = Von Karman constant

  K = vertical  eddy  diffusivity  of matter

  L = Monin-Obukhov  length

  N = fraction  of  sky covered by cloud

  N = Brunt-Vaisala  frequency



  P = fraction  of  material  that  stabilzes  in  capping  inversion

  Q = emission  rate

 QH = rate of output of  heat  from a  chimney

 Q* = net radiation

  r = albedo of surface

 R0 = Rossby number

'£) = Lagrangian autocorrelation function

  s = shape parameter, Eq 5-13 and Eq 5-14

 t0 = transition time, the  instant when  the net  sensible heat flux  at  the
      surface changes sign  from  positive to negative

  T = air temperature

 Te = empirical time scale, used in  Eq  (5-5)

 TL = Lagrangian integral time scale

 T0 = stack gas temperature
                                   vi i

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     u = horizontal wind speed

    uf = free convection scaling velocity
    u* = /t/p surface friction velocity

     U = estimated horizontal wind speed assuming surface  layer  similarity

    Ur = near-surface reference wind speed

 UZ,VZ = components of horizontal wind in the vertical relative  to a coordinate
         system alined along the surface-layer reference wind direction

    w* = mixed layer scaling velocity

x,y,z  = rectangular coordinates, x usually along mean wind and  z  vertical

    xo = integration constant used in describing variation of the  mean height
        of particles as a function of distance downwind

    x' = typical distance to upwind obstacle

     X = (x/zi)(w*/U)

    X' = (x/zs)(w*/U)

    z0 = surface roughness length

    zr = measurement height of the near-surface reference  wind speed

    zs = release height above ground

    z^ = mixing height

     a = empirical constant, accounts for the strong correlation between
         surface heat flux, net radiation and soil heat flux in Eq (3-2)

     p = empirical constant, accounts the portion of the sensible heat flux
         not related to the net radiation or the soil heat flux in Eq (3-2)

    Yi = lapse rate above unstable mixed layer

   Y/s = thermo-dynamic function of temperature

    AT = vertical temperature difference

    A9 = used in defining the nighttime potential temperature
         profile, 0(t,z)-00

   A0i = potential temperature  jump at  top of unstable mixed layer
                                      viii

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   A9S = 0s(t) - 00

     C = z/L

    Cr = zr/L

     Q = potential temperature

   0gL = mixed layer temperature

9(t,z) = nighttime potential temperature

 d0/dz = potential temperature gradient

    Qf = free convection scaling temperature

    0m = mixed layer scaling temperature

    Q0 = the potential temperature of the adiabatic profile at transition
         time

 Qs(t) = the surface potential temperature found at time t since transition

    0* = surface layer scaling temperature

     < = horizontal wave number

     £ = the length scale, estimated as, (l/lg + l/Jln)    where  I  is
         the stable length scale and Jln is the neutral length scale,
          2
    As = y 
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        = induced lateral dispersion due to buoyancy effects

    o"yO = lateral dispersion due to ambient turbulence

    ays = induced lateral dispersion due to wind direction shear in the
          vertical

    azo = vertical dispersion due to ambient turbulence

    °"zb = vertical dispersion due to buoyancy effects

      T = -pu'w', momentum shear stress

       = elevation of sun above horizon


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                              1.  INTRODUCTION









     The purpose of the following discussion is to outline a set of methods




for processing meteorological data for use in diffusion modeling.  In this




discussion, the emphasis will be on those methods considered both physically




realistic and numerically efficient.




     Most of the early attempts to estimate the diffusion of air pollutants




were based on the Gaussian-plume model, for example see Sutton (1953).




Pasquill (1961) gave simple rules for obtaining the lateral spread based on




wind-direction trace data and suggested the effects of thermal stratification




in the lower atmosphere be represented in broad categories of stability,




defined in terms of meteorological data routinely available in surface




weather observations.  By the early 1970's, air quality simulation models




were viewed as a means to estimate the relative magnitudes of concentration




distributions from various sources and thereby provide a rational basis for




strategies leading to air quality improvement or maintenance.  Most of the




air quality simulation models developed in response to these modeling




requirements were based on the general Gaussian-plume model.  Invariably the




models were constructed assuming that the dispersive characteristics of the




atmosphere were vertically and horizontally homogeneous.




     Current concepts regarding the structure of an idealized boundary layer,




are briefly reviewed and the basic meteorological variables of interest to




diffusion modeling are identified.  Methods are proposed for specifying each




of these basic variables.  The goal is to characterize the meteorological

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conditions affecting the diffusion for trans-port distances on the order of 10




km or less over reasonably flat and homogeneous terrain.  In this description




of turbulence, the effects of clouds and fog are only considered as far as




these affect the radiation and the surface energy balance.  The relationship




and importance of the variables to diffusion processes are reviewed.  The




final section reviews the conclusions and envisioned future research activi-




ties.

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                              1.  INTRODUCTION









     The purpose of the following discussion is to outline a set of methods




for processing meteorological data for use in diffusion modeling.  In this




discussion, the emphasis will be on those methods considered both physically




realistic and numerically efficient.




     Most of the early attempts to estimate the diffusion of air pollutants




were based on the Gaussian-plume model, for example see Sutton (1953).




Pasquill (1961) gave simple rules for obtaining the lateral spread based on




wind-direction trace data and suggested the effects of thermal stratification




in the lower atmosphere be represented in broad categories of stability,




defined in terms of meteorological data routinely available in surface




weather observations.  By the early 1970's, air quality simulation models




were viewed as a means to estimate the relative magnitudes of concentration




distributions from various sources and thereby provide a rational basis for




strategies leading to air quality improvement or maintenance.  Most of the




air quality simulation models developed in response to these modeling




requirements were based on the general Gaussian-plume model.  Invariably the




models were constructed assuming that the dispersive characteristics of the




atmosphere were vertically and horizontally homogeneous.




     Current concepts regarding the structure of an idealized boundary layer,




are briefly reviewed and the basic meteorological variables of interest to




diffusion modeling are identified.  Methods are proposed for specifying each




of these basic variables.  The goal is to characterize the meteorological

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 conditions  affecting the  diffusion for trans-port  distances on the order of 10




 km or less  over reasonably flat  and homogeneous  terrain.   In this description




.of turbulence,  the effects of  clouds and fog are  only considered as  far as




 these affect the radiation and the surface energy balance.  The relationship




 and importance  of the variables  to diffusion processes are reviewed.  The




 final section reviews the conclusions and envisioned future research activi-




 ties.

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                           2.   THE BOUNDARY LAYER






     Atmospheric diffusion is controlled by the turbulence in the air.  The




parameters describing the scales of turbulence are therefore of fundamental




importance in a description of atmospheric diffusion.  Most air pollution




sources emit into the boundary layer which can be defined as the lower layer




of the atmosphere where the influence of the surface is present due to fric-




tion.  The character and turbulent state of the boundary layer is strongly




affected by the diurnal heating and cooling cycle.






                     2.1   The Unstable Boundary Layer






     The unstable boundary layer is directly affected by solar heating of the




ground.  The layer has a very pronounced diurnal variation, and typically




reaches a height of 1-2 km over land in summertime.  For the characterization




of turbulence within this layer three length scales are important.  These are




the mixing height, z^, the height above the ground, z, and the Monin-Obukhov




stability length, L.  The mixing height z^ defines the height above the




surface in which pollutants are mixed by presence of turbulence.  From these




three parameters, two independent dimensionless parameters can be formed.




The unstable boundary layer can be divided into several layers defined in




terms of these parameters.  Fig. 2-1 'is a schematic diagram showing idealized




limits of validity of the scaling techniques together with the corresponding




parameters for the turbulence.  This figure is similar to those presented




by Nicholls and Readings (1979) and Olesen et al. (1984).  Traditionally, the




boundaries between the individual layers have not been expressed in the same




set of dimensionless parameters.  This makes any sketch of the boxes  look

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      EMTRAINMENT LAYER
MIXED LAYER

     w»

     Zj
     g/T
FREE CONVECTION
     LAYER
       uf
       *f
       z
       g/T
NEAR NEUTRAL
UPPER LAYER
     Zj
     z
     u«
                 SURFACE LAYER

                      u»
                      0,
                      z
                      g/T
                                    Z/Zj
                                  1.0
                                  0.8
                                   0.1
-100
-1.0

Z/L
                                 -0
                                                            LIMIT
                                                     LOCAL AND z-LESS
                                                     SCALING REGION
                                                            u*(local)
                                                            N(local)
                                                            g/T(local)
                            SURFACE LAYER

                                 u*
                                 0,
                                 z
                                 g/T
                                         +0
1.0

Z/L
                                                           10.0
 Figure 2-1.  Idealized  view of the states  of  the Planetary Boundary
              Layer  and  the limits of validity of the scaling
              techniques.

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fairly complicated.  Here,  we have sacrificed some of the detailed structure


that arises from the traditional way of describing the boundaries.  Our pro-


posed simplified version in some cases slightly deviates from the viewpoints


traditionaly held of the boundaries.




2.1.1  The surface layer  (zo « z , Min(0.lz±;-L))



     This is the layer where wind shear plays a dominant role.  The control-


ling parameters are the height,  z, the momentum shear stress, T = -pu'w',


the sensible heat flux at the ground, H = pCpW'0", and the buoyancy parameter,


g/T (Businger, 1973).  From these parameters we can form the equivalent

                                                                       o
parameters, z, L, u* and Q* where L is the Monin-Obukhov length, L = -u*/


[k(g/T)(H/pcp)], k the Von Karman constant (~0.4), the friction velocity u*


= /T/p and the scaling temperature  Q* = -H/(pcpu*).  Monin-Obukhov similarity


theory postulates that dimensionless local groups formed with u* and 0*


become universal functions of z/L.  The surface layer is confined to the


layer 20z0 < z < -L and z < O.lz^, where zo is the surface roughness length.




2.1.2  The free convection layer (-L < z < O.lz.^)



     Above z = -L, is a layer where T is no longer important in describing


the atmospheric turbulence and z.£ is not yet important, thus the controlling
parameters are z and the surface layer values of w'0' and g/T.  The free


convection layer exists for -L < z < O.lz^.  Tennekes (1970) described the


scaling velocity and temperature as,
                               uf = (w^T z g/T)1/3,


                               0f = w'0'/uf .

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2.1.3  The mixed layer (O.lz.^ < z < O.Sz^ and Z/-L > 1)






     In this layer the turbulence structure is insensitive to i as in the




free convection layer, but also the height loses its importance as a scaling




parameter.  Hence the mixing height, z-£, emerges as the controlling length




scale.  The scaling velocity and temperature become, Deardorff (1970),




                            w* = (z± g/T ^r9r





                           9m  = W'QS/W*.
where w'0' and g/T are surface layer values.






2.1.4  The entrainment layer (O.Sz^ < z < l.2z^_ )






     The turbulence structure is dominated by entrainment processes from




the overlying stable air in the capping inversion.  The turbulence structure




in this region is poorly understood.  Recent measurements suggest that the




distance to the inversion,  | z^ - z| enters as a scaling length, see Driedonks




and Tennekes (1984).  The scaling velocity and temperature relevant to this




layer have not as yet been  proposed.






2.1.5  Near neutral upper layer  (O.lz^ < z < 0.8z-^ and Z/|L| < 1)









     The layer will only rarely be found over land but is not unusual over




the sea.  The scaling parameters for'the surface  layer are relevant for  the




near neutral upper layer; in addition the height  of the inversion, z^, is




also important.  For profiles of mean quantities  the  Rossby  number, Ro =




G/fzo  (G  the geostrophic wind speed and f the Coriolis parameter) might  be




of importance.

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                     2.2  The Stable Boundary Layer






     .The stable boundary layer is created by cooling of the air adjacent to




the ground.  The depth of the inversion layer, h, is often taken as the




height at which the (negative) heat flux has fallen to a certain (low)




proportion of its surface value.  The study of the stable boundary layer is




much less advanced than its unstable counterpart.  As buoyancy forces




suppress the turbulence under stable conditions, the magnitude of fluctua-




tions generally are very low and consequently difficult to measure.  Also




the structure of the turbulence is masked by other physical processes that




are supported in a stable atmosphere.  Such processes are gravity waves,




drainage and slope flows, intermittent turbulence and radiation divergence.




The coexistence of these processes and turbulence complicate the interpre-




tation of the data.  No simple relation exists between the depth of the




surface inversion, h, and the mixing height, z^, through which the turbu-




lence exchange processes take place.  The depth, z^, of the turbulent stable




boundary layer can become progressively smaller at the same time as the depth




of the surface based inversion h grows.






2.2.1  The surface layer (zo « z , Min (O.lz^L))






     This layer is the stable counterpart of the unstable surface boundary




layer, and the same scaling parameters apply.  The layer is in principle lower




than the height, z - L or z < 0.1 z^, whichever is smaller.  Most times the




limit is given by O.lz-j_.

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2.2.2  Local and z-less scaling region (Min(0.Iz^jL) < z < z-^ and z/L < 10)



     The range where local scaling applies is still unsettled and a matter

                                                                   •
of discussion.  We define it as the whole stable boundary layer except the


surface layer part.  The local scaling approach is an extension of Monin-


-Obukhov similarity theory to the whole stable boundary layer (Nieuwstadt,


1984).  Here A is called the local Monin-Obukhov length, defined as  A =
-u*/[k(g/T)w'0'] where u* and -w'0" are the local values of the kine-


matic momentum flux and heat flux.  The temperature scale for this region

can be defined as 0^ = (w'0')/u*.  In the local scaling region only two

length scales arise, z and A.  Nieuwstadt"s (1980b) model of the stable

boundary layer suggests that A ~ L (l-z/h)^/^.   As z/A •* 1, local scaling


conforms to z-less scaling (Wyngaard, 1973), where z is no longer an impor-

tant length scale for the turbulence.  This results from the stable tempera-


ture stratification becoming increasingly more effective in inhibiting

vertical motions.  The turbulence within the z-less region is intermittent

and difficult to characterize.  Some success has been achieved in describing

the low frequency part of the horizontal velocity spectra using the local

value of the Brunt-Vaisala frequency N2 = (g/T)(50/dz).

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                             3.   BASIC PARAMETERS






                       3.1  The Surface Roughness Length






     The surface roughness length z0 forms the lower boundary in diffusion




models (Pasquill and Smith, 1983).  The length zo is in principle the height




at which the wind speed is zero.  The length zo is related to the roughness




characteristics of a homogeneous terrain or landscape.  When the terrain is




homogeneous, the roughness length can be determined from wind profiles




observed in near-neutral conditions.




     Very often, we have relatively smooth terrain disturbed by occasional




obstructions or by large perturbations.  In such cases an effective rough-




ness length was found appropriate for use in the flux-profile relations




(Nieuwstadt, 1978; Beljaars, 1982).  As discussed by Wieringa (1981) and




Beljaars (1982) for a rough to smooth transition, the turbulence adjusts more




slowly to the underlying surface than does the wind profile.  For this reason




the roughness averaged over the upwind fetch can be better evaluated from




 o"u/u or gustiness than from wind profiles (Wieringa, 1976, 1980).  0U is the




root mean squared (rms) variance of the wind speed u and u is the average




wind speed.  Conversely, this means that the wind profile can be described




with the effective roughness length only above a certain height.  Beljaars




(1982) estimates this height as 2£, where  £ is the height of the major




obstacles.  Closer to the surface the flux-profile relations differ from




those over uniform terrain  (Beljaars et al., 1983) and are usually location




dependent (Wieringa, 1981).  When no measurements are available, we can




obtain from a visual terrain description a crude value for the  effective




roughness length (Hogstrom and Hogstrom, 1978; Davenport, 1960).  In Table

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3-1 an example is given.  For the application of the above methods for

determining zo, we select as many wind direction sectors as needed to

distinguish between major variations.  In general,  no sectors less than 30

degrees in angular extent are expected to be suitable in practice.
 TABLE 3-1. TERRAIN CLASSIFICATION IN TERMS OF EFFECTIVE SURFACE ROUGHNESS
        LENGTH z0.  TABLE PARTLY EXTRACTED FROM DAVENPORT (1960).
 Short terrain description                                           zo(m)


 Open sea, fetch at least 5 km                                        0.0002

 Mud flats, snow; no vegetation, no obstacles                         0.005

 Open flat terrain; grass, few isolated obstacles                     0.03

 Low crops, occasional large obstacles, x'/£ > 20*                    0.10

 High crops, scattered obstacles, 15 < x'/C < 20                      0.25

 Parkland, bushes, numerous obstacles, x'/C - 10                      0.5

 Regular large obstacle coverage (suburb, forest)                 (0.5 - 1.0)



  * x' = typical distance to upwind obstacle; £ = height of obstacle.



                      3.2 The Monin-Obukhov Length


     From  the surface fluxes of sensible heat and momentum, the Monin-Obukhov

length for dry air can be formed,

                              L = - uJ/[k(g/T)(H/pcp)],                (3-1)
                                    10

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Here we have Ignored the moisture influence"which is typically small above


a land surface.  Values for u*, H and thus L can be obtained from turbulence


measurements.
                                                    •

     When no turbulence measurements are available the fluxes can be obtained


from profiles of wind and temperature near the surface (Businger et al., 1971;


McBean, 1979; Irwin and Binkowski, 1981).  The profile method gives good


agreement with turbulence measurements and energy budget measurements, if an


effective roughness length is used in the wind profile (Nieuwstadt, 1978).


These derived fluxes are representative for a larger area than would be


measured with an instrumented meteorological tower located on-site.  This


becomes important, for instance, for the estimation of wind profiles at


larger heights from a single wind speed and the surface fluxes.  In such


cases, the surface fluxes should be representative of the larger area.  This


is demonstrated by Korrell et al. (1982) for the Boulder tower and by Beljaars


(1982) and Holtslag (1984a) for the Cabauw tower.  Furthermore, the horizontal


velocity fluctuations scale on the friction velocity representative of the


larger area  (Beljaars et al., 1983).


     When a vertical temperature profile in the surface layer is not avail-


able, we must parameterize the sensible heat flux H.  Holtslag and Van Ulden


(1983) and Van Ulden and Holtslag (1983) have given procedures for the deri-


vation of the sensible heat flux from routine weather data.


     During daytime over land, H is obtained from a modified Priestley-


Taylor formula (De Bruin and Holtslag, 1982),


                              1 - a + Y/S

                          H =              (Q* - G0) - p ,                (3-2)
                                   11

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where Q* is net radiation, GQ is soil heat flux (typically 0.1Q*).  y/s

equals Cp/(X.oqs/oT) where \ is the latent heat of water vaporization and qs

is the saturation specific humidity.  For T between -5 and 35 C, y/s can be

approximated as exp [(279.57-T)/17.78] , T in degrees K.  It can be shown that

when saturated air passes over a wet surface a -*• 1 and  (3 -*• 0 (Priestley,

1959).  For other climatological and surface conditions a and  p must be

adjusted.  Table 3-2 shows typical values for a and p as a function of sur-

face moisture availability.  Reiff et al. (1984) use  (3-2) with a. = 1 and

P as a varying function of time.  Around sunrise, p = 0, but (3 increases

with time up to p = 20 Wm~2 in a few hours.

     In Holtslag and Van Ulden (1983) procedures are  discussed for the evalu-

ation of Q* from the fraction of sky covered by cloud, N, the elevation of

the sun above the horizon,   , and the shelter temperature,
                     (1 - r)[d,sin<|> + do](l + cN) + ClT  4
               Q* =  -        (3-3)
                                       1 + C3

where r is the albedo of the surface (typically  0.26  for short  grass).  Values
                                                                       _n
for the empirical constants in  (3-3) [d,d^ ,&2> c>ci >C2^ are  [3.4,  990Wm~ ,

-30Wm~2,-0.75,5.31xlO~13Wm~2K~6,60Wm~2].  Values for  the surface  heating

cofficient C3 are listed in Table  3-2.  This parameter describes  the

relative increase of surface temperature with  net  radiation Q*.   As  shown

by Holtslag  and  Van  Ulden  03 depends primarily on  a and air temperature T.

Therefore,   a is the crucial parameter for  the surface energy budget

parameterization (see De Bruin,  1983;  Van Dop,  1983).   In  combination with

  a, P and C3 the sensible  heat  flux  is obtained  from  (3-2).  Afterwards,  u*

and L are obtained  from  (3-1) and  a  single  wind  speed observation and the
                                    12

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integrated wind profile.  The values of a, J3 and 03 should reflect the

site.  At present, we suggest the values listed in Table 3-2 be used for

guidance.
TABLE 3-2.  TYPICAL VALUES OF THE COEFFICIENTS a, p AND c3 FOR SEVERAL
CASES.  NOTE THAT C3 IS A FUNCTION OF AIR TEMPERATURE T AS WELL  (SEE
HOLTSLAG AND VAN ULDEN, 1983).  
-------
     A simple analysis indicates that a constant value of 9* can be assumed




during nighttime.  The sensible heat flux can be obtained from an approx-




imation for the scaling temperature, Q*.  A typical value for clear conditions




is 8* - O.IK (Venkatram, 1980).  Van Ulden and Holtslag (1983) present




methods for estimating 9* as a function of total cloud cover.






                    3.3   Mixing Height And Inversion Height






     The mixing height z^ defines the layer above the surface through which




pollutants are mixed by the presence of turbulence.  During daytime convective




conditions or neutral stability conditions the mixing height may extend to




the height where vertical mixing is capped by the inversion (inversion height




h).  During nighttime stable conditions, however, it is important to distin-




guish between the mixing height z-^ and the surface inversion depth h.  In




part, the difference between z^ and h results because the turbulence is




supressed in the presence of a stable temperature gradient, which extends




above the mixing height.




     For conditions of negligible synoptic scale mean vertical velocity, the




equations governing the rate of growth of the convectively driven mixed




layer are,




          d9BL/dt = (l/zi)(w^90" - w^")                   (3-4)




          dA0i/dt = yidzi/dt - d0BL/dt
                                 -  (w'0Q - w'9i)/Zi       (3-5)




           dz-j/dt = -w~70T/A0i                             (3-6)




                                         .                 (3-7)
     is the mixed  layer  temperature,  the subscripts  o and  i  refer  to  values




 at  the surface and  the  top of  the mixed layer, A0^  is  the temperature  jump
                                    14

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at the top of the mixed layer (A0£ > 0) and yi i-3 the lapse rate above the




mixed layer.  Laboratory and atmospheric measurements suggest 04 = 0.2 and




05 = 5.  The numerical solution to the set of equations, employing a morning




radiosonde and the shelter temperatures through the day, is discussed in




detail by Tennekes and Driedonks (1981) and Wilczak and Phillips (1984).




Driedonks (1982) discusses practical application of the above method for




cases with convective and mechanical entrainment into the mixed layer.




     Based on dimensional arguments, many researchers speculate that the




mixing height during neutral conditions can be determined from,




                                Z£ - c6u*/f,                            (3-8)




where f is the Coriolis parameter and eg is an empirical constant (typically




0.2 - 0.3).   As discussed by Yu (1978) and Wetzel (1982), the correlation of




estimates of z^ by (3-8) with values determined from the Wangara field data,




range between 0.2 and 0.5, indicating no more than 20% of the variability of




z^ is explained.  When an inversion is present, z± is given by the inversion




base or (3-8), whichever yields the smallest value.




     For nighttime stable conditions, we propose the mixing height be deter-




mined from (Zilitinkevich, 1972; Andre, 1983),




                                z± =  0.4 (u*L/f)1/2.                   (3-9)




     As stated before, the turbulent mixing depth may differ from the surface




inversion depth during stable conditions.  Several authors have worked on




the evolution of the nocturnal surface inversion depth in combination with




the temperature profile in the boundary layer (Yaraada, 1979; Nieuwstadt




1980a; Stull, 1983a,b).  At present, we suggest the inversion depth be




estimated during stable conditions as suggested by Stull (1983a,b).  This




will be discussed in section 4.2.





                                   15

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                                  4.   PROFILES


                               4.1   Wind Profile


      In the atmospheric surface layer the wind profile can be described

successfully with Monin-Obukhov similarity theory (Yaglom,  1977).   In the

mixed layer and free convection layer during daytime, the wind speed and

direction remain nearly uniform with height.  For stable conditions, however,

the wind speed increases with height often to a maximum, or low-level jet,

near the top of the inversion layer.

    A procedure is proposed for the derivation of the wind profile from a

single observation of wind speed near the surface (10 m), an estimate of

the roughness length zo and the Obukhov length L.  If estimates of geo-

strophic wind speed or free atmospheric wind speed are available,  these can

be employed as well.

     For the mixed layer, we assume uniform distributions for wind speed.

In the free convection and surface layer, the variation of the wind speed

is given by,
                             In(z/z0 - ?(
                     U = Ur - ,                         (4-1)
                            In(zr/z0) - Y(zr/L)

where a general expression for ¥ is given by Paulson (1970) and 2r is the

measurement height of the wind speed Ur.

     For the near neutral upper layer, we assume U is given by (4-1).  The

change of wind direction is expected to be quite small during these neutral

conditions, of the order of 10X over the first 200m.  A procedure proposed
                                    16

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by Van Dop et al. (1982) could be employed to approximate the wind profile

as,
             uz * fs u + fg G cos D>                                   (4-2a)

             Vz = fg G sin D,                                          (4-2b)

where U2 and Vz are the components of the wind speed, D is the angle

between the surface wind direction and the direction of the Geostrophic wind

and G is the Geostrophic wind speed.  Note that we have chosen the x-axis

along the surface wind direction.  The precise characterization of the

weighting functions (fs and fg) is of little concern so long as they are

continuous, vary smoothly as a function of z/z^ between 0 and 1 with fs +

fg = 1, and fs = 1 for z/z-^ = 0.

     For stable conditions with z/L < 0.5, the wind speed can be estimated

using (4-1) and (4-2).  When z/L > 0.5, U can be better estimated using a

semi-empirical extension of the log-linear profile given by Holtslag (1984a)

as,

                       ln(z/z ) + 7 InC + 4.25/C - 0.5/C2 + 0.852
              U  = Ur  	 ,      (4-3)
                                  In(zr/z0) + 5£r

where C = z/L and Cr = zr/~L.  With this profile it was shown that relatively

good estimates can be obtained of the magnitude of U in very stable con-

ditions up to z^.  A yet unresolved problem with the stable boundary layer is

a description of the significant~turning of wind with height.  This turning

can be 40* or more over the first 200m.

     In the above, we have used values of G.  For G we may use the surface

geostrophic wind speed evaluated from surface pressure charts.  Also, a  free

atmospheric wind or the 850 mb wind obtained from linear interpolation between
                                    17

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subsequent radiosondes may be used.   Neither estimate of G is considered

very accurate.


                           4.2   Temperature Profile


     The potential temperature is constant within the mixed layer and the

free convection layer (Tennekes and  Driedonks, 1981).  For heights greater

than z^, the temperature profile has to be obtained from radiosonde data.

For heights below z^, conditions are well mixed and the potential temperature

is that recorded at the highest level of a tower or in the case when such

measurements are not available at shelter height.  This neglects the con-

ditions that occur during strong heating, where a strong temperature gradient

exists near the ground.

     In the -absence of strong heating or cooling at the surface or when the

wind speeds are strong (6 m/s or more), day or night, the interpolated

radiosonde temperature can be used with no modifications.

     During the nighttime with strong radiational cooling or weak winds,

the temperature profile and the inversion depth can be estimated using the

procedures proposed by Stull  (1983a,b).  The nighttime sensible heat-flux

history,  together with the surface temperature decrease after sunset, are

used to define the potential  temperature profile as,

          A0/A0S   =    exp (-az/Hx), "             .                       (4-4)

where     A0S      =    Qs - 0O

          0s(t)    =   the surface potential temperature found
                      at  time t since transition,

          00       =   the potential  temperature  of  the  adiabatic
                      profile at transition time,
                                    18

-------
         A0       •-   0(t,z) - 00,

         9(t,z)   =   the potential temperature at height z at time
                      t since transition,
                              t	
         HI       =   (1/A0S) / (w'0') dT,
                             to
         a        »    an empirical constant found to be about 0.77 by
                       Stull for the Wangara and Koorin experiments (nearly
                       uninhabited sites that were relatively dry).

The time of transition to is defined as that instant when the net sensible

heat flux at the surface changes sign from positive to negative.  Stull(1983b)

demonstrates using Wangara field data that h is well estimated as 5Hj.  For

large-scale advection effects, the surface temperature 9S could be increased

(decreased) to account for increases (decreases) of the 700 mb temperatures

between successive radiosondes.  Such a procedure was employed successfully

by Benkley and Schulman (1979) and Garrett (1981) to adjust for large-scale

advection effects in their estimates of the growth of the unstable boundary

layer.


                            4.3  Turbulence Profiles


     In the mixed layer, Caughey (1982) notes that the observations of the

rms variance of the vertical velocity o"w suggest a broad maximum centered
                o         9
at z./2 where ov,  is 0.4w* .  The numerical simulations of the convective
    J_          W

boundary layer by Deardorff (1974) suggest the height of maximum variance

is ZjL/3.  Caughey (1982) reports that near z-^, water tank and numerical
                   n         e\
results indicate aw  is O.lw*  in agreement with the 1976 Ashchurch field

                                        9                    7
data.  Above z^, Caughey reports that o"w  decreases to O.Olw*  near 1.5z^.

     During the nighttime, when the atmosphere is stratified, the vertical

wind-speed fluctuations in theory decrease in amplitude as a function of
                                    19

-------
height, to near-zero values at z^ (Caughey, 1982 and Yamada, 1979).  A


reasonable fit to the 1973 Minnesota stable field data is,


                             crw2/u*2 = Aw(l - z/z.)d,                 (4-5)


where o*w is the standard deviation of the vertical wind-speed fluctuations,


AW - 2.2 and d = 3/2.  Nieuwstadt (1983) using data collected from the 213 m


meteorological tower at Cabauw found Aw =» 1.7 and d = 3/2.  The significance -


of Nieuwstadt's results is that he arrived at (4-5) using local scaling

                             o
arguments.  Measurements of a^ may be considerably influenced by gravity


wave contributions.  For that reason, Nieuwstadt employed high pass filtered


data for the determination of ^ and d.


     The standard deviation of the cross wind-speed fluctuations, av, in


the surface layer is poorly characterized using Monin-Obukhov similarity


scaling, especially within the stable surface layer, see Panofsky et al.


(1977).  During convective conditions, the numerical simulations of the


convective boundary layer and the atmospheric data suggest a. slight maximum

                                                                  2
near O.Sz^ in a ; the average value over the entire profile for o~v  is


0.4w*2.


     During stable conditions the mean wind direction show sizeable inter-


mittent sudden changes  (meandering).  This phenomenon may result from various


factors such as the slope of the terrain, location of hills in the upwind


fetch  and movement of weather systems.  Although meander  is most often  observed


during very stable conditions, this does not preclude its occurence during


other  times.  Strong mixing during unstable conditions  might mask  the  contri-


butions due to meander  to av  but the  contributions  to the energy spectra  are
                                      20

-------
still present.  Hjjjstrup (1981, 1982) and Berkowicz and Prahm (1982) found

success in modeling the velocity spectra as consisting of a buoyancy-produced

part and a shear-produced part.  The modeled variances by H^jstrup (1982)

agree well with data from the Kansas and Minnesota field experiments.  His

results for the w-spectra are valid only for the lower half of the boundary

layer, where the long-wavelength fluctuations can be assumed to be damped by

the presence of a solid lower boundary mechanically impeding the vertical

fluctuations.  As a working hypothesis for modeling the vertical velocity

variance, we could combine the shear-produced variance, as modeled by H«5jstrup

(1982), with the buoyancy-produced variance, as modeled by Baerentsen and

Berkowicz (1984).  The resulting characterizations of the lateral and vertical

variances would be,

                         2/3     2.7(l-z/z.)2
                0.7(Zi/L)2/:i +  - =~-                 for L < 0
                                (1+2.8Z/Z,)2/3
                                         1                            (4-6)
                      (1-z/z.)2
                                                               for L >0
                    (l+2.8z/zi)2/3
              f 1.54[z/(-kL]2/3exp(-2z/z.) + 1.457(l-z/z.)2    for L < 0

         '     \              7                                        (4'
              ^ 1.457(l-z/Z;L)2                                 for L >_ 0
The expression (4-7) fits quite well the 1973 Minnesota field data for

unstable conditions .

     The estimate of the lateral variance neglects meander.  The linear

decrease of aw with height, while appropriate during daytime neutral con-

ditions, would not reflect the height dependence observed during stable

conditions.  This deficiency although noticeable in the mean under ideal
                                   21

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conditions would likely not be noticeable in" practice, owing to the vari-




ations caused by conditions differing from ideal.  Recently, the low fre-




quency part of the spectra of the velocity components under stable conditions




has been successfully modeled by Larsen et al. (1983).  The low frequency




part of the horizontal velocity components were found to be fairly well  .




described by a N2<~3 law, where N is the Brunt-Vaisala frequency and < the




horizontal wave number.
                                      22

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                              5.0   DIFFUSION






     The applicability of employing scaling parameters for describing the




turbulence in the air depends on the extent to which the actual circumstances




approach the idealized conditions specified in the basic theoretical and




experimental studies.  Reliable specification of the turbulence and thereby




the diffusion cannot be expected if the airflow is uncertain or calm, or if




the airflow has been complicated by local circulations induced by heating or




cooling or hilly terrain.  Little success can be expected in the immediate




vicinity of buildings and obstacles.  The methods described here for diffusion




estimates do not account for effects of deposition or reactions in the atmos-




phere, and are only valid for distances less than 10 km.




     Even when the actual conditions approach the ideal conditions, the prac-




tical problems of estimating the expected distribution of concentration are




significant.  The comparison results summarized in Pasquill's (1974) Table




6.XI suggest that even under ideal circumstances 20 to 30% deviations from




the mean concentration values can be expected for ensemble average estimates




for particular meteorological conditions.  For individual comparisons devi-




ations of about 50% appear likely (Gryning and Lyck, 1984).




     This chapter summarizes some of the relationships of the basic scaling




parameters to diffusion processes.  A description of the pollutant distribu-




tion necessarily includes (implicitly or explicitly) the shape of the distri-




bution, the dimensions of the diffusing cloud, and the boundary conditions.




The shape describes the vertical and horizontal profiles of the cloud.  The




dimensions are often specified by the root mean squared deviations o~y and az




of the pollutant mass along the coordinate axes.  The values ay and az are
                                   23

-------
typically referred Co as the dispersion parameters.  Often they are associated


with a Gaussian shaped distribution but, of course, this is not necessary.


     A traditional basis for describing diffusion is the Taylor diffusion

                                                              2
theory which relates the mean square particle displacement, o"v , to the cross

                          2
wind velocity variance, cr,through,


                        t T

           ov2 = 2 a 2  / / R(5) d^dT,

            *           oo                                             (5-1)


where t is travel time and R (£) the Lagrangian autocorrelation function and,

                  T

             Urn  / R(5) d£ = TL,
            T -» « o


the Lagrangian integral time scale.  In the limit  (5-1) becomes,


           o-y = 
-------
Sivertsen (1978) argues that fy responds to "the overall structure of the


turbulence;  whereas, av describe the local features of the terrain.


     A comparison was performed of five empirical forms suggested for fy


(Irwin, 1983) with field tracer data collected at 11 sites.  Draxler's (1976)


scheme performed best, a finding which is in agreement with Gryning and Lyck


(1984).  Irwin (1983) noted that selecting a simple expression for fy that is


invariant with height resulted in little overall loss in performance.  We


recommend,
                         f  - 1/[1 + 0.9 (t/Te)i/z],                    (5-5)
where Te = 1000 s.


     If we view the total diffusion as the summation of individual effects of


each process [Hb'gstrom (1964) and Pasquill (1976)], then,

                          rt2_rt2,2,2                        /C.N
                           y  ~  y°    yb    ys'                       t-> o;
where oVo ^s estimated using (5-4) and (5-5), ayb is the induced diffusion


due to buoyant plume rise effects, and o"ys is the induced diffusion due to


wind direction shear in the vertical.  At this time, the magnitude of the


buoyancy effects on the lateral diffusion is uncertain.  It seems o~yO


dominates initially with 0ys becoming of increasing importance at large


downstream travel time.  Pasquill and Smith  (1983) investigated the effect


of wind shear on the horizontal diffusion and found the distance of travel


at which the effect of o"ys becomes important.  They conclude that the effect


is not important within about 5 km from an elevated source or within about


12 km of a ground-level source.


     In the following, expressions are provided for characterizing the dis-


persion for each of the regimes described in Chapter 2.  In some cases,


expressions are given for estimating the crosswind integrated concentration,
                                   25

-------
where x (x,y) is the surface concentration.  The x-coordinate axis is aligned




along the surface wind direction.  Given -^7 we can compute x  assuming a




Gaussian distribution of the material in the crosswind as,






                                           ).                          (5-7)
                           o-y




Even though the vertical distribution of material may be other than Gaussian,




the lateral distribution is well approximated using (5-7), as discussed by




Deardorff and Willis (1975), Gryning and Lyck (1980) and Gryning et al.,




(1978).




     In general, the total vertical diffusion is a combination of turbulent




diffusion and the effects of buoyant plume rise, azb> as
For elevated sources well above the surface and below the inversion, a




similar approach for estimating azo as shown above for ay, (5-4), could be




applied when o"w is available.  Field data suggest that azb scales with plum




e rise (Briggs, 1975).




     In the following, examples are given demonstrating the relationship of




the basic meteorological parameters to the description of vertical diffusion




for each of the regimes described in Chapter 2.






            5.1   The Surface Layer (unstable and stable conditions)






     A number of investigations have demonstrated the applicability of Monin-




Obukhov similarity theory to describing  the diffusion of near  surface




releases by use of K models, (Nieuwstadt and Van Ulden,  1978,  Gryning et




al., 1983, Sivertsen et al., 1983).




                                    26

-------
     Within the surface layer, the vertical' eddy diffusivity of matter, K,

can be expressed generally as,

                           K = ku*z/«*h(z/L),                           (5-9)

where ^(z/L) is an empirical function that describes the dependency on

atmospheric stability, Table 5-1.  When the wind and K profiles are

represented by power laws, a general solution of the two-dimensional

diffusion equation can be written as (Van Ulden, 1978),

                       Xy(z)/Q = (A/iu~) exp [-(Bz/F)S]               (5-10)

                      A = s r(2/s)/[ r(l/s) ]2                       (5-11)

                      B = F(2/s)/ F(l/s),                            (5-12)

where r is the gamma function.  The following equations are suggested for

specifying the shape parameter s (Gryning et al., 1983) and the mean height

of particles z" (Van Ulden, 1978).

For L > 0:

     1 + 2 bi cz/L          1 + b2 cz/L
      1 + bj cz/L       In(cz/z0) + b2 cz/L
                                                                    (5-13a)
x + XQ = (F/k) [{ln(czVz0) +                                       (5-13b)

                2 b2PF/(3L)} (1 + blPF/(2L) + (bj/4 - b2/6)PF/L)].

For L < 0:
     1 - ai cz~/(2L)       (1 - a2cF/L
s = - ~      +  - - - : - ~ — ,                      (5-14a)
      1-a  cz/L
x + XQ = (/k) [ In (c/zQ) - y (cF/L) ] [1 - p aj_  /(4L)]~.    (5-14b)


x0 is an integration constant and is determined with  x = 0 and z equal to the

release height zs.

     For stable conditions (L > 0), we solve for the crosswind integrated

concentration by first determining z (iteratively from 5-13b) for the given

                                   27

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distance downwind.  With z, we can solve for A and B for use in 5-10.  A

similar approach is followed for unstable conditions (L < 0).

     Dyer(1974) proposed a^ = a2 = 16; bj = b2 = 5 with k = 0.41.  These

coefficients were used by Gryning et al. (1983) and Holtslag (1984b).  In

the original derivation, Van Ulden (1978), used the coefficients proposed

by Businger et al,, 1971).  In Table 5-1, the «$m and ^ functions are given

together with the expression for the mean wind speed, u, over the plume.

The coefficients p and c are in fact dependent on s.  For practical appli-

cations we propose p = 1.55 (Van Ulden,  1978) and c = 0.6 (Gryning et al.,

1983).
TABLE 5-1.  THE ^, «5m AND u FUNCTIONS NEEDED FOR THE APPLICATION OF
EQUATIONS (5-9) THROUGH (5-14).
For L < 0:

                    z/L)~1/2

                   z/L)-1/4

  ¥(z/L) = 21n {(1 + x)/2} +  In {(1 + x2)/2}  -  2  tan"1(x)  +

 where x = (l/«*m),

   ku7u* = In(cz7z0) - ?(cz/L).

For L > 0:

 <$h(z/L) = d(l + b! z/L),

«$m(z/L)  = 1 + b2  z/L,

   ku/u* = In(cz/z0) + l>2  z/L .
                                      28

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     Elliott (1961) found the shape parameter ranged from s = 1.0 from un-




stable conditions to about s = 2.0 for stable conditions.  For a Gaussian




concentration distribution s = 2, hence under unstable and neutral conditions




a Gaussian concentration profile does not fit the observed vertical distri-




bution.






                              5.2  The Mixed Layer






     The mixed layer scaling is appropriate when zs/z^ > 0.1 and zs/-L > 1,




where zs is the release height.  Deardorff and Willis (1975), Willis and




Deardorff (1978), Lamb (1978, 1979) reported the results of a series of




laboratory and numerical simulations of dispersion of nonbuoyant material in




a well developed mixed layer.  Deardorff and Willis presented tabulations of




the dimensionless mean crosswind integrated concentration values at various




heights and distances from the release at zs/z^ of 0.067.




     As an extension of these results, Briggs (1985) reanalyzed the dimension-




less cross-wind integrations both from the laboratory and the numerical




simulations.  It was found that the mean cross-wind integrated concentration




results at the surface could be well characterized as,




                         0.9 X 9/2 Z  -11/2

 y   U/Q .    	
                 [Z -J/* + 0.4 X y// Zc
                  j                  S
9/2

    ^s    J



                                     (5-15)
                                   Z      + 50
                                    S



where X = (x/Zj_) (w*/U) and Zs = Zg/z-^.  This expression applies for nonbuoyant




releases when 1 > Zs > 0.04.




     Recently, Willis and Deardorff (1983) reported the findings of a series




of laboratory simulations of buoyant releases within a well developed




convective boundary layer.  They found that plume buoyancy effects became




                                   29

-------
noticeable in the diffusion results where the plume buoyancy parameter F* =

     f\
F/(Uw^z^), exceeded about 0.02, where F .is the standard definition of plume


buoyancy.  The vertical distribution of concentration within the plume was


highly skewed and non-Gaussian.  Tabulations of •%? are not available for a


wide variety of values of F* and a suitable number of release heights for a


recharacterization of (5-15) including buoyant plume rise effects.



                         5.3  The Free Convection Layer



     Free convection exists in the layer above z = -L and and below z ~ O.lz^


where z, Uf and 9f are the controlling parameters.  Nieuwstadt (1980b) ana-


lyzed the portion of the Prairie Grass data measured under convectively


unstable conditions and found that free convection similarity scaling was


appropriate for those cases downwind when 0.03 < X < 0.23.  The normalized


crosswind integrated concentration is then given by,


                      X^U/Q = bX~3/2                                 (5-16)


where b is 0.9.  Holtslag (1984b) compared the surface similarity pre-


dictions by (5-10) versus the free convection predictions by (5-15) using


the Prairie Grass data.  At x = 50 m it was seen that the surface layer


model performed better than the free convection model, comfirming that at x


= 50 m the plume was still within the surface layer.  At x = 200 m and 800


m the surface  layer model and the free  convection model predictions were


similar.  This would suggest that both  scaling principles can be applied  to


these distances.  Deposition was not considered in the analyses by Nieuwstadt


(1980b) and Holtslag  (1984b).  Gryning  et al.  (1983) show that consideration


of deposition  significantly improves the  predictions of Che surface  layer


model, especially at  x =  800 m.
                                      30

-------
                           5.4  The Entrainment Layer






     For unstable conditions, the entrainment layer extends between z >




O.Sz^ and z < 1.2z^.  For strongly buoyant releases, the possibility exists




for material to become stabilized in the layer above z^.  The amount of




material which "penetrates" into the stable layer capping the mixed layer




is dependent on (Briggs, 1975),




                       PS = F/(UYi.z£3)                               (5-17) *



where  z^' = z^ - zs and yi = the potential temperature gradient in the




capping inversion.  The fraction of material, P, that stabilizes in the




capping inversion is estimated by Weil and Brower (1982) as,




                        P - 1.5 - (l/2.6)/ps1/3.                       (5-18)




This penetration estimate suggests that full penetration occurs when ps >




0.44.  Penetration of 50 % is estimated when ps = 0.129.  These estimates




suggest that it requires only 13% as much buoyancy to achieve 50% penetration




as that required to penetrate fully.  Laboratory simulations for a strongly




buoyant effluent (F* > 0.1) with a strong capping density jump (ps < 0.05),




suggest that the plume tends to loft against the capping inversion (Willis




and Deardorff, 1983).  It appears that the plume still retains sufficient




buoyancy to resist mixing down towards the surface.






                          5.5 Near Neutral Upper Layer






     Knowledge of the diffusion in the near neutral upper layer is very




limited.  For releases in the near neutral upper layer we therefore recommend




the use of the traditional Gaussian plume model for estimating concentrations.
                                   31

-------
Measurement of crw and  where Y ' 0.522,

      An = ocz, where a  = 0.36,
                                    32

-------
       N = the local value at z of the Brurit-Vaisala frequency,

           [(g/TXae/az)]1/2,

      o*w = the local value at z of the standard deviation of the vertical
           velocity fluctuations.

     Substituting typical values into (5-19) and solving for TL, shows T^ is

approximately 8 to 12 s.  The expressions (5-5) and (5-19) for fz are nearly

equivalent when Te = 4.861^.   Hence,  these results reported by Venkatram et al,

(1983) are in accord with the findings reported by Irwin (1983)  for Te = 50 s

for stable conditions.  The information provided by Venkatram et al. (1983)

shows that local z-less scaling arguments can be employed to describe the

diffusion processes.
                                   33

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                               6.0 DISCUSSION






     An outline of methods for processing meteorological data for use in




diffusion modeling has been presented.  To incorporate the proper scaling




parameters the discussion was structured in accordance with current concepts




for the idealized states (regimes) of the planetary boundary layer.  The




goal was to characterize the meteorological conditions affecting the




diffusion for transport distances on the order of 10 km or less.  The




distance to the maximum ground-level concentration is often within this




range.




     The diffusion is routinely found to be other than Gaussian in the




vertical (Gryning and Lyck, 1984).  Therefore, whenever justified we have




recommended the use of techniques that characterize directly the crosswind




integrated concentrations at the surface.  For elevated releases within the




near neutral upper layer and the stable (local scaling region) we recommend




use of the Gaussian plume model, where the dispersion parameters are




estimated using statistical methods.  Little is known regarding diffusion




within the entrainment layer.




     A special complication in the use of the suggested methods arises when




the proper state of the diffusion process is at the border line between two




regimes.  Such cases will give rise to a jump in concentration dependent on




the choice.  No procedures have been  devised to avoid these  jumps  in  calcu-




lated concentration.
                                      34

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     For obtaining the meteorological data "needed for estimating the




fundamental meteorological scaling parameters, we recommend as a minimum a




measurement program as presented in Table 6-1.  The measurements should be




carried out at a mast.  The upper measurement level should be at a height




100zo, but not less than 10m.  The lower measuring level should be at 20zo,




but not less than 1m.  Here, zo is the effective surface roughness length




and can be estimated from Table 3.1.  Also discussed in this report are




methods for determining the fundamental scaling parameters if only synoptic




meteorological data are available.




     We anticipate that the suggested characterizations of the diurnal




variation of the wind speed and direction profiles are too simplistic and




will need further development.  Furthermore, the turbulence profiles are




highly idealized as the assumption is made that above the mixed layer the




turbulence is negligible.  To complete the development of a meteorological




processor, the methods outlined should be tested using available data.




With the test results, future research can focus on those estimation methods




requiring the greatest improvement and on developing methods to characterize




the spatial variations in the meteorological variables.
                                     35

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       TABLE 6-1.   RECOMMENDED  MINIMUM "MEASUREMENT PROGRAM
       THE TYPICAL SAMPLING DURATION SHOULD BE 10 MINUTES.
 PARAMETER
SAMPLING
RATE (sec)
 MEASURING
  HEIGHT
  EXAMPLE
INSTRUMENTS
                                                              **
 Wind speed

 Wind direction

 Longitudinal
 Turbulence

 Wind direction
 fluctuation
  1 to 5

  1 to 5
Upper level    Cup anemometer

Upper level    Wind vane

Upper level    Cup anemometer


Upper level    Wind vane
Temperature
Temperature
difference
10
10
Upper level
Upper level
to
lower level
Resistance
Fast
Thermocouples

*  Estimated from wind speed and direction measurements.

** Instruments should be well designed for the purpose.
   Minimum instrument requirements are given in Hoffnagle et al.
   (1981)  Table 1.
                                36

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                                   7.0 REFERENCES


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                                       37

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Deardorff, J. W.,  1974:  Three-dimensional numerical study of the height and
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                                        38

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Gryning, S.E., E. Lyck and K Hedegaard, 1978:  Short-range diffusion experiments
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                                      39

-------
Korrell, A., H.A. Panofsky, and R.J. Rossi, 1982:  Wind profiles at the Boulder
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                                        40

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   *^^™^ — ^^^^^-     — -   •

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                                        42

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                                       43

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                                  TECHNICAL REPORT DATA
                           (Please read Instructions on the reverse before completing)
 REPORT NO.
                             2.
                                                           3. RECIPIENT'S ACCESSION NO.
. TITLE AND SUBTITLE

 ATMOSPHERIC DIFFUSION MODELING BASED ON
 BOUNDARY LAYER PARAMETERIZATION
                                                           5. REPORT DATE
            6. PERFORMING ORGANIZATION CODE
. AUTHOH(S)
 J.S. Irwin1, S.E. Gryning2,  A.A.M. Holtslag3,
 B. Siversten*
                                                           8. PERFORMING ORGANIZATION REPORT NO.
 PERFORMING ORGANIZATION NAME ANO ADDRESS
 1. ASRL, RTP, NC, USA
 2. Ris«J National Laboratory, Roskilde, DENMARK
 3. KNMI, DeBilt, THE NETHERLANDS
 4. LILU, Lillestrrfn, NORWAY
            10. PROGRAM ELEMENT NO.
             CDTA1D/08  -  2182(FY85)
            1 1. CONTRACT/GRANT NO.
2. SPONSORING AGENCY NAME AND ADDRESS
 Atmospheric Sciences Research Laboratory - RTP, NC
 Office of Research  and Development
 U. S. Environmental Protection Agency
 Research Triangle Park,  NC  27711
             13. TYPE OF REPORT AND PERIOD COVERED
              Final
             14. SPONSORING AGENCY CODE


             EPA/600/09
5. SUPPLEMENTARY NOTES
6. ABSTRACT

     The conclusions  of  a workgroup are presented outlining methods for
processing meteorological data for use in air quality diffusion modeling.  To
incorporate the proper scaling parameters the discussion is structured in
accordance with the  current concepts for the idealized states of the planetary
boundary layer.  We  recommend a number of models, the choice of which depends
on the actual idealized  state of the atmosphere.  Several of the models
characterize directly the crosswind integrated concentration at the surface,
thus avoiding whenever justified the assumption of  a  Gaussian distribution of
material in the vertical.  The goal was to characterize the meteorological
conditions affecting the diffusion for transport distances on the order of 10
km or less.  Procedures  are suggested for estimating  the fundacental scaling
parameters.  For obtaining the meteorological data  needed for estimating the
scaling parameters,  a minimum measurement progrSn to  be carried out at a mast
is recommended.  If  only synoptic data are available, methods are presented
for the determination of the scaling parameters.  Also, methods are suggested
for estimating  the vertical profiles of wind velocity, temperature, and the
variances of the vertical and lateral wind velocity fluctuations.
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