EPA-650/4-74-005-1
November  1975
Environmental  Monitoring Series
            A
                UME IX * VISUAL
                              OfWMWY
                                                           §"'*•
                                                            I:
                                        Office of Research and Development,
                                       U.S. Environmental Protection Agency
                                                Washington, D.C. 20460

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                                  EPA-650/4-74-005-1
    GUIDELINES  FOR  DEVELOPMENT
OF A QUALITY ASSURANCE  PROGRAM
  VOLUME IX - VISUAL DETERMINATION
         OF OPACITY EMISSIONS
       FROM STATIONARY SOURCES
                      by

           Pamela Wohlschlegel and D.E. Wagoner

               Research Triangle Institute
         Research Triangle Park, North Carolina 27709
                Contract No. 68-02-1234
                  ROAP No. 26BGC
              Program Element No . 1HA327
          EPA Project Officer: Steven M. Bromberg

        Environmental Monitoring and Support Laboratory
          Office of Monitoring and Technical Support
         Research Triangle Park , North Carolina 27711
                  Prepared for

         U.S. ENVIRONMENTAL PROTECTION AGENCY
            Office of Research and Development
               Washington, B.C. 20460

                  November 1975

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                      EPA REVIEW NOTICE

This report has been reviewed by the U.S. Environmental Protection
Agency and approved for publication.  Approval does not signify that
the contents necessarily reflect the views and policies of the Environ-
mental Protection Agency, nor does mention of trade names or commer-
cial products constitute endorsement or recommendation for use.
                  RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S . Environ-
mental Protection Agency, have been grouped into series.  These broad
categories were established to facilitate further development and applica-
tion of environmental technology.  Elimination of traditional grouping was
consciously planned to foster  technology transfer and maximum interface
in related fields.  These series are:

          1.  ENVIRONMENTAL HEALTH EFFECTS RESEARCH

          2.  ENVIRONMENTAL PROTECTION TECHNOLOGY

          3.  ECOLOGICAL RESEARCH

          4.  ENVIRONMENTAL MONITORING

          5 .  SOCIOECONOMIC ENVIRONMENTAL STUDIES

          6.  SCIENTIFIC AND TECHNICAL ASSESSMENT REPORTS

          9.  MISCELLANEOUS

This report has been assigned to the ENVIRONMENTAL MONITORING
series. This series describes research conducted to develop new or
improved methods and instrumentation for the identification and quantifica-
tion of environmental pollutants at the lowest conceivably significant
concentrations. It also includes studies to determine the ambient concentra-
tions of pollutants in the environment and/or the variance of pollutants
as a function of time or  meteorological factors.
This document is available to the public for sale through the N.
Technical Information Service, Springfield, Virginia 22161.
                 Publication No. EPA-650/4-74-005-i
                                11

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                       TABLE OF  CONTENTS
List of Figures                                     v

List of Tables                                     vii

1.0  INTRODUCTION                                 1-1

2.0  VISUAL DETERMINATION OF  THE  OPACITY
     OF EMISSIONS FROM  STATIONARY SOURCES         2-1

     5.8  Visual Determination  of the
          Opacity of Emissions  from
          Stationary Sources                      2-2

          5.8.1  Reference Method                2-4
          5.8.2  Plan Activity  Matrix            2-15
          5.8.3  Operational  Procedures           2-26
          5.8.4  Auditing Procedures              2-56

3.0  FUNCTIONAL ANALYSIS OF TEST  METHOD           3-1

     3.1  Variable Evaluation and Error
          Range Data                              3-2

     3.2  Combining Error Terms                  3-6

     3.3  Precision Estimates                    3-7

LIST OF REFERENCES                                R-l

Appendixes

A    GLOSSARY OF SYMBOLS                          A-l

B    GLOSSARY OF TERMS                            B-l

C    TECHNICAL REPORT DATA SHEET                      C-l
                               111

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                        LIST OF FIGURES

Figure                                            Page

5.8.1   Method procedures relationship            2-5
5.8.2   Sequence of operations in training,
        certification, and field observations
        for determinations of visual emissions    2-27
5.8.3   Sample smoke generator log                2-37
5.8.4   Sample observation information form       2-44
5.8.5   Sample data log                           2-47
5.8.6   Sample form for testing determination
        of weather data                           2-51
5.8.7   Sample certification test form            2-53
5.8.8   Audit data form                           2-58
5.8.9   Sample data assessment form for each
        audit                                     2-60
5.8.10  Auditing period data assessment form      2-62
5.8.11  Example illustrating p < 0.10 and
        satisfactory data quality                 2-64
5.8.12  Example illustrating p > 0.10 and
        unsatisfactory delta quality               2-64
5.8.13  Sample course evaluation form             2-67
                                IV

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                         LIST OF TABLES


Table                                             Page


5.8.1  Methods of monitoring training variables   2-12

5.8.2  Methods of monitoring field variables      2-13

5.8.3  Sample plan constants, k for P (detecting

       a lot with proportion p outside limits L
       and U} > 0.9                               2-66

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                        ABSTRACT
     Guidelines for the quality control of the visual
determination of the opacity of emissions from stationary
sources are presented.

These include:

     1.  Good operating practices.

     2.  Directions on how to assess performance and to
         qualify data.

     3.  Directions on how to identify trouble and to
         improve data quality.

     4.  Directions to permit design of auditing activities.

     The document is not a research report.  It is designed
for use by operating personnel.
     This work was submitted in partial fulfillment of con-
tract Durham 68-02-1234 by Research Triangle Institute
under the Sponsorship of the Environmental Protection Agency,
Work was completed as of November 1975.
                              VI

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                           Section 1.0
                           Revision No.  0
                           Date:   November 1975
                           Page 1  of 3
1.0  INTRODUCTION
             1-1

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                                                   Section 1.0
                                                   Revision No. 0
                                                   Date:   November 1975
                                                   Page 2 of 3
                      1.0  INTRODUCTION

     This document presents guidelines for implementing a
quality assurance program for the visual determination of
the opacity of emissions from stationary sources.
     The objectives of this quality assurance program are
to:
     1.   Provide routine indications for unsatisfactory
          performance of personnel and/or equipment,
     2.   Provide for prompt detection and correction of
          conditions that contribute to the collection of
          poor quality data,
     3.   Collect and supply information necessary to de-
          scribe the quality of the data.
To accomplish the above objectives, a quality assurance pro-
gram must contain the following components:
     1.   Routine monitoring of training and qualification
          procedures,
     2.   Routine monitoring of the,variables and/or param-
          eters which may have a significant effect on
          data quality,
     3.   Development of statements and evidence to qualify
          data and detect defects,
     4.   Action strategies to increase the level of pre-
          cision in the reported data and/or to detect
          training equipment defects or degradation and to
          correct same.
Implementation of a quality a.ssurance program will result
in data that are more uniform in terms of precision and
accuracy.  It will enable each observation team or individual
to continuously generate data that approach the highest
level of accuracy attainable with the visual method.
                                     1-2

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                                              Section 1.0
                                              Revision No. 0
                                              Date:  November 1975
                                              Page 3 of 3
This document is divided into three sections, as follows:
1.   1.0  INTRODUCTION—This lists the overall objectives
     of a quality assurance program and delineates the
     program components necessary to accomplish the
     given objectives.
2.   2.0  VISUAL DETERMINATION OF THE OPACITY OF EMISSIONS
     FROM STATIONARY SOURCES—This section includes the
     method description, plan activity matrix, operational
     procedures, and auditing procedures.  Subsection
     numbering is consistent with section 5.8 of a
     larger document, The Quality Assurance Handbook
     for Air Pollution Measurements, Volume III, Station-
     ary Sources Specific Methods.
3.   3.0  FUNCTIONAL ANALYSIS—This section includes an
     estimate of the precisions and biases of the
     various measurements which collectively comprise
     Method 9, and an estimate of the total precision
     and bias of the method.
                                1-3

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                                                   Section 2.0
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 1 of 1
     2.0  VISUAL DETERMINATION OF THE OPACITY OF EMISSIONS
          FROM STATIONARY SOURCES*
*In this section,  subsection numbering is consistent with
 section 5.8 of a  larger document,  The Quality Assurance
 Handbook for Air  Pollution Measurements, Vol. Ill—
 Stationary Sources Specific Methods.
                                 2-1

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 1 of 67
5.8  VISUAL DETERMINATIONS OF THE OPACITY OF EMISSIONS FROM
     STATIONARY SOURCES
     This section describes a quality control program designed
specifically to check the validity of opacity data generated
from routine visual determinations.  To present the quality
control program more systematically, the section has been
divided into the following subsections:
               5.8.1  Reference Method,
               5.8.2  Plan Activity Matrix,
               5.8.3  Operational Procedures,
               5.8.4  Auditing Procedures.
     The formal reference method for Visual Determination of
the Opacity of Emissions from Stationary Sources is included
in section 5.8.1 for convenient reference.  Also included in
that section is figure 5.8.1, which delineates the procedures
for Method 9 in a block diagr5im.  Basically, the method can
be broken down into a series of operational categories
defined as:
     1.  Observer training,
     2.  Observer testing and certification,
     3.  Field observations,
     4.  Data analysis
Wj thin each category both routine and nonroutine procedures
are described.  The routine procedures form the basic criteria
needed for a school to adequately train, test, and certify
the observer, and for an observer to generate data.  The
nonroutine procedures provide characteristic checks for each
of the routine procedures to insure that valid data will be
ultimately collected and to properly assess the quality of
that data.
     The Plan Activity Matrix in section 5.8.2 includes the
characteristic checks for each of the operating procedures;
                                     2-2

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 2 of 67
the procedures themselves are outlined in section 5.8.3.

The audit procedures described in section 5.8.4 provide a

basis for assessing the performance in each operational

category.
                              2-3

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 3 of  67
5.8.1  Reference Method
                METHOD 9—VISUAL DETERMINATION OF THE

                          OPACITY OF EMISSIONS FROM

                          STATIONARY SOURCES
          Reproduced from Appendix A, "Reference Methods,"

   Federal Register, Vol 39, No. 219; Tuesday, November 12, 1974
                               2-4

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                                                        Section  5.8
                                                        Revision No.  0
                                                        Date:  November 1975
                                                        Page 4 of  67
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                                                                                 Section   5.8
                                                                                 Revision  No.  0
                                                                                 Date:   November  1975
                                                                                 Page  5 of 67
5.8.1.1   Variables  ACCUraCy-
  Many stationary sources discharge visible
emission* Into the Atmosphere;  these emis-
sions aro  usually In  the shape  of a plume.
This method involve* the  determination of
plume opacity  by qualified  observers.  The
method Includes procedures for  the training
and certification of observers, and procedures
to be used In the field for determination ctf
plume opacity. The Appearance of a plume &a
viewed by an observer depends upon a num-
ber of variables, some of which may be coo.-
trollable and  some of which  may not I*
controllable In the field. Variables which can
be controlled to an extent to which they no
longer exert » significant Influence  upon
plume appearance Include: Angle of the ob-
server with respect to the plume; angle of the
observer with respect to the sun;  point of
observation of attached and detached steam
plume;  and angle of the observer  with re-
spect to a plume emitted from a rectangular
•tack with a large length to width ratio. The
method includes  specific criteria applicable
to these variables.
  Other variables which may not be control-
lable In the field are  luminescence and color
contrast between thS plume and the back-
ground  against which the plume la viewed.
These variables exert an Influence upon the
appearance of a plume as  viewed by an ob-
server, and can affect the ability of the ob-
server  to accurately  assign  opacity  values
to the observed plume. Studies of the theory
of plume opacity and field studies have dem-
onstrated that  a  plume Is most visible and
presents the greatest apparent opacity when
viewed against  a contrasting background. It
follows from this, and Is confirmed by field
trials, that the opacity  of a plume, viewed
under conditions where a contrasting back-
ground  i» present can be assigned  with the
greatest degree of accuracy. However, the po-
tential for a positive error Is also the greatest
when a plume is viewed under such contrast-
ing conditions. Under conditions presenting
a less contrasting background, the apparent
opacity of a plume  is less and approaches
zero as the color and luminescence contrast
decrease toward zero. As a result, significant
negative  bias and  negative  errors can  be
made when a  plume Is  viewed under less
contrasting  conditions. A negative bias de-
creases rather than Increases the possibility
that a plant operator will be cited for a vio-
lation of opacity  standards due to observer
error.
  Studies have been undertaken to determine
the magnitude of positive errors which con
be made by qualified observers while  read-
ing plumes under contrasting conditions and
using  the  procedures  set   forth  in  this
method. The results of these studies  (field
trials) which  Involve a total of 769 sets  of
25 readings each are  as follows:
  (1) For black plumes (133 sets at a smoke
generator),  100 percent  of  the sets  were
read with a positive error * of less than 7.5
percent opacity; 99 percent  were read with
a positive error of .less than 5 percent opacity.
  (2) For white plumes (170 sets at a smoke
generator, 168 sets at a coal-fired power plant,
298 sets at a sulfurlc acid plant), 89 percent
of the sets were read with a positive error of
less than 7.5 percent opacity; 95 percent were
read with a positive error of less tlinu 5 per-
cent opacity.
  The positive observational error associated
with an average of  twenty-five readings Is
therefore established. The accuracy of the
method must  be  taken Into  account  when
determining possible  violations_ of  appli-
cable opacity standards.

  *For a set, positive error—avernge opacity
determined by observers' 25  observations —
average opacity determined from transmls-
Eometer's 25 recordings.
5.8.1.2    Principle  and  Applicability-
   1. Principle and applicability.

   1.1   Principle.  The opacity of editions
 from  stationary sources IB determined vis-
 ually  by a qualified observer.
   1 2   Applicability.  This method  la appli-
 cable  for the determination of the opacity
 of  emissions from stationary  sources pur-
 suant to §6011(b)  and for qualifying ob-
 servers for visually  determining opacity  of
 emissions.
5.8.1.3    Procedures  for  Opacity  Observations-
    2.  Procedures. The  observer qualified In
  accordance with paragraph S of this method
  shall use  the following  procedures for -rls-
  \ially determining the opacity of emissions:

    2.1  Position. The qualified obscncr shall
  stand  at  a distance sufficient to provide a
  clear view of  the emissions with the sun
  oriented In the 140* sector to hla back. Con-
  sistent with maintaining the above require-
  ment, the observer shall, as much as possible,
  make his observations from a position imch
  that hi«  line  of vision It approximately
  perpendicular to the plum* direction, and
  .when  observing opacity of emissions Irora
  rectangular outlets (e.g. roof monitors, open
  bughouses, nonclrcular stacks),  approxi-
  mately perpendicular to the longer  »xls of
  the outlet. The observer's line of sight should
  not Include more than one plume  at a time
  when  multiple stacks ar«  Involved,  «nil la
  any case  the observer should make  his ob-
  servations with his line of sight perpendicu-
  lar to the longer axis of such a set of m ultl-
  pie  stacks (eg. stub stacks on baghouses).
   2.2 Field  records,  Tho observer shall re-
 cord the name of the plant, emission  loca-
 tion, type  facility,  observer's  nam«  and
 affiliation, and the date on a field data  sheet
 (Figure »-l). The time, estimated distance
 to the emission location, approximate  -wind
 direction, estimated wind speed, description
 of the sky condition (presence and color of
 clouds), and plume background are recorded
 on a field data sheet at the time opacity read-
 ings are initiated and completed,
   2.3  Observations.  Opacity  observation
 shall be made at the point of greatest opacity
 in  that portion  of  the  plume  where con-
 densed water vapor  is not present. The ob-
 server shall not look continuously at the
 plume, but Instead shall observe the plume
 momentarily at 15-second Interval*.
   2.3.1  Attached steam plumes. When con-
 denied water vapor is present within the
 plume as It emerges from the emission out-''
 let,  opacity observations shall be made be-
 yond the point in the plume  at which con-
 densed water vapor  is no longer visible. The
                                           2-6

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39876
RULES AND REGULATIONS
                                                    Section 5.8

                                                    Revision No.  0

                                                    Date:  November  1975

                                                    Page 6 of  67
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                                                                             Section  5.8
                                                                             Revision  No.  0
                                                                             Date:    November  1975
                                                                             Page  7  of   67
5.8.1.3    Procedures   (cont.)-

observer shall record the approximate dU-    the average opacity of emission* tar a 15.
tance from the emission outlet to tho point    second period.
In the^plnme at  which  the observations are      2.5  Data Reduction. Opacity snail be de-
made,                                     termlned as an average of  24  consecutive
  232  Detached steam plume. When water    observations recorded at 15-second Interval!.
vapor In the  plume condenses and becomes    Divide €he observations recorded on the rec-
vislble at a distinct distance from Die cmls-    ord sheet Into sets of 24 consecutive obscr-
slon outlet, the opacity of emissions should    rations.  A set is composed of any 24 con-
be evaluated  at the emission outlet prior to    secutlve  observations. Sets need not be con-
the condensation of water vano' »nrt tiio for-    secutlve  in time and  In no  case slmll two
mation of the steam plume.                   sets overlap. For each set of 24 observations,
  2.4 Recording observations.  Opacity  on-    calculate the average by summing the opacity
servations shall be recorded to the nearest 8    of the 24 observations and dividing this sum
percent at 15-second  Intervals  on an  ob-    by 24. If an applicable standard  specifics an
servatlonal record sheet. (See Figure 0-2 for    averaging time requiring more than 24 ob-
nn example.)  A minimum of 24 observations    servations, calculate the average for all ob-
shall be recorded. Each  momentary obscrva-    servations  made  during the specified  time
tion recorded shall be deemed .to represent    period Record the average opacity on a record
                                           sheet. (See Figure B-l for an example.)



5.8.1.4    Qualifications  and  Testing-

  3  Qualifications and testing,
  S.I Certification requirements. To receive
certification as a qualified observer, a can-
didate must be tested and demonstrate  the
ability to assign opacity readings In 5 percent
increments to 25 different black plumes and
25  different  white plumes, with  an error
not to exceed 15  percent opacity on any  one
reading and an average 'error not to exceed
7 5 percent opacity In each category. Ca'ndi-
dates shall be tested according to the pro-
cedures described  In paragraph 3.2. Smoke
generators  used  pursuant to paragraph S3
shall be equipped with a smoke meter which
meets the requirements of paragraph 3.S.
  The certification shall be valid for a period
of 6 months, at which time the qualification
procedure must be repeated by any observer
In order to retain certification!
5.8.1.5    Certification  Procedure-

  32  Certification procedure. The certifica-
tion test consists of showing the candidate a
complete run of 50 plumes—25 black plumes
and 25 white plumes—generated by a smoke
generator. Plumes within each set of 25 black
,\nd 25 white runs shall be presented In ran-
dom order. Ths candidate aligns an opacity
value to each plume  and records  his obser-
vation on a suitable form. At the completion
of each run of 50 readings, the score of the
candidate is determined. If a candidate faila
to qualify, the complete run of 50 readings
must be repeated in  any retest. The smoke
test may be administered as part of a smoke
school or training program, and may be pre-
ceded by training or familiarization runs of
the smoke generator during which candidates
are shown black and white clumes of known
opacity.
                                           2-8

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                              RULES AND REGULATIONS
Section 5.8

Revision No. 0

Date:  November  1975

Page  8 of 67
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                                                                                    Section  5.8
                                                                                    Revision  No.  0
                                                                                    Date:    November  1975
                                                                                    Page  9  of  67
5.8.1.6    Smoke  Generator  Specitications-
   3.3  Smoke  generator specifications.  Any
 smoke generator  used  for the  purposes oC
 paragraph 3.2 shall be equipped with a smoke
 meter  Installed to measure opacity  across
 the diameter at the smoke generator stack.
 The smoke  meter output shall display In-
 stack opacity based upon a pathlcngth equal
 to the stack exit diameter, on a full 0 to 100
 percent  chart  recorder scale.  The  smoke
 meter  optical design and performance shall
 meet the specifications shown In Table 9-1.
 The smoke meter shall  be calibrated as pre-
 scribed In paragraph 3.3.1 prior to the con-
 duct of  each smoke reading  test.  At the
 completion of each test, the zero and span
 drift shall  be checked  and If the drift ex-
 ceeds ±1 percent opacity, the condition shall
 be corrected prior  to conducting any  subse-
 quent  test  runs. The smoke meter  shall be
 demonstrated, at the time of Installation, to
 meet the specifications listed In Table  9-1.
 This demonstration shall  be repeated  fol-
 lowing any subsequent repair or replacement
 of the  photocell or associated electronic clr-

5.8.1.7   Calibration  of
   cultry Including the chart recorder or output
   meter, or every 6 months, whichever occur*
   tint.
       TABU 0-1—SMOKE METER DESIGN AND
          PERFORMANCE SPECIFICATIONS
   Parameter:
   a. Light source	
   b. Spectral  response
       of photocell.
   c. Angle of view	

   d. Angle  of projec-
       tion,
   e. Calibration, error.

   f. Zero  and  span
       drift.
   g. Response  time—
Smoke  Meter-
   3.3.1  Calibration,  The  smoke  meter  Is
  calibrated after allowing a minimum of "30
  minutes warmup by  alternately producing
  simulated opc^jlty of 0 percent and 100 per-
  cent. When stable response at 0 percent or
  100 percent id-noted, the smoke meter Is ad-
  Justed to produce- an output of 0 percent or
  100 percent, as appropriate. This calibration
  shall be repeated until stable 0 percent and
  JOO percent readings  are produced without
  adjustment. Simulated  0  percent  and 100
  percent opacity values may be produced by
  alternately switching the power to the light
  source on and off while the smoke generator
  Is not producing smoke.


5.8.1.8    Smoke  Meter  Evaluation-
    Speciflcatiort
Incandescent   lamp
  operated at nominal
  rated voltage.
Photoplo    (daylight
  spectral response of
  the human  eye—
  reference  4.3).
16*  maximum  total
  angle.
15*  maximum  total
  angle.
i-3 %  opacity, maxi-
  mum.
rtl %   opacity,    30
  minutes.
£5 seconds.
    33.2  Smoke meter evaluation. The tmoke
  meter design and  performance are to be
  evaluated as follows:
    3 3 2.1  Light  source.  Verify from manu-
  facturer's data  and from -voltage measure-
  ments made at  the lamp, as Installed,  that
  the lamp is operated within ±:5 percent of
  the nominal rated voltage.
    3 3 2.2  Spectral  response  of  photocell.
  Verify from manufacturer's data that  the
  photocell has a photoplc  response;  1 e.,  the
  spectral  sensitivity  of the cell shall closely
  approximate the standard spectral-luminos-
  ity cur\e for photopic vision which  Is refer-
  enced in  (b) of Table 9-1.
    3.3.23  Angle of view. Check construction
  geometry to ensure that the total angle of
  view of  the smoke plume, as seen by  the
  photocell, does  not exceed  15'.  The total
  angle of view may  be calculated from:  9~2
  tan-' d/2L,  where  f~ total  angle of  view;
  d = the  sum of the photocell diameter •{• the
  diameter  of  the  limiting  aperture;  and
  L = the  distance from the photocell to  the
  limiting aperture. The limiting aperture Is
  the point in the path between the photocell
  and  the  smoke plume  where the angle of
  view Is most restricted. In smoke generator
  smoke  meters this Is normally  an orifice
  plate.
    3 3.2.4  Angle of projection.  Check con-
  struction geometry to ensure that the total
  angle of projection  of  the lamp  on  the
  smoke plume does not exceed 16*. The total
  angle of projection  may be calculated from:
  0—2 tan-' d/2L,  where 0= total angle of pro-
     jection; d=  the  sum of the length of the
     lamp fllnment -f-  the diameter ol the limiting
     aperture; and L-- the distance from the lamp
     to the limiting aperture.
       3325  Calibration error. Using  neutral-
     density niters  of known opacity, check the
     error between  the  actual response  and the
     theoretical  linear  response of  tbe smoke
     meter.  This  check  Is accomplished by first
     calibrating  the smoke  meter according to
     3.31 and then Inserting a, strics of three
     neutral-density filters of nominal opacity of
     20, 5O, and 75 percent In the smoke meter
     pathlength. Filters callbartcd v.lthin ±3 per-
     cent shall be  used. Care should be taken
     when inserting the fliters to  prevent stray
     light from affecting the meter. Make a  total
     of  five nonconsocutive  readings  for  each
     filter. The maximum error on  any one read-
     Ing shall be 3 percent opacity.
       3.3.2.6  Zero and span  drift. Determine
     the zero and span drift  by calibrating  and
     operating the smoke generator In a normal
     manner over a 1-hour period. The drift Is
     measured by checking the zero and span at
     the end of this period.
       3.3 2.7  Response time. Determine  the re-
     sponse time by producng the aeries of five
     simulated 0 percent and  100 percent opacity
     values  and observing the time  required to
     reach stable response. Opacity values  of  0
     percent and 100  percent may be simulated
     by alternately switching  the  power to the
     light source off'and on while the smoke
     generator Is not operating.
                                          2-10

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 10 of  67
     5.8.1.9  Quality Control Program Specifications—
     5.8.1.9.1  Quality control programs—purpose.  Each
observer training school and/or law enforcement agency shall
maintain a quality control program consistent with the proce-
dures described in this manual.  Such programs shall be
designed to assure the quality and scientific reliability of
visible emissions data.
     5.8.1.9.2  Quality control programs—provisions.   Each
quality control program shall contain provisions for the
management of quality, which shall include the following:
     1.  Requirements for the production of quality con-
         trol data and the use of quality control records,
     2.  Control of technical documents, training methods,
         calibration instructions, and observation pro-
         cedures,
     3.  Control of purchased material to include checks
         for conformance to specifications,
     4.  Audit of training procedures to include interschool
         and intraschool check programs,
     5.  Audit of observations to include inter- and
         intra-agency check programs,
     6.  Establishment of an organizational structure
         to carry out these provisions.
     The intraschool quality control program shall provide
for the establishment and maintenance of a system to assure
continued certification of observers sufficiently trained to
expertly handle the majority of situations that they might
encounter.  The system should include:
     1.  The checks and audits listed in table 5.8.1,
     2.  Routine use of nonscheduled observations made by
         an expert observer simultaneously with student
         observations,
                               2-11

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                                                      Section 5.8
                                                      Revision No. 0
                                                      Date:  November 1975
                                                      Page 11 of 67
       Table 5.8.1  Methods of monitoring training variables
      Variable
                       Method of monitoring (intraschool)
1.
2.
3.
4.
6.
7.
Student compre-
hension of
material covered
Practice runs of
smoke tests
Calibration of
smoke meter
Zero and span
drift
5.  System noise
Placement of
smoke generator
Transmissometer
readings
simultaneous with
blowing of the
horn

Smoke test sheets
Entertain questions between each lecture
and give students a 1-hour quiz at the
completion of the classroom training.
See section 5.8.3.3 page 38 of  67.

Sufficiently cover at several values
of opacity from 0 percent to 100
percent so that at least one-half of
class feels confident enough to commence
certification testing.  See section
5.8.3.5 page 49 of 67.

Check calibration error prior to each
school using neutral density filters.
See section 5.8.3.4 page 47 of  67.

Make 2,ero and span checks and adjust-
ments prior to each practice or certi-
fication run.  See section 5.8.3.4
page 47 of 67.

Check the strip chart record trace for
signs of noise after each certification
run as part of routine operating proce-
dure.  See section 5.8.3.4 page 47
of 67..

Choose; a location unaffected by downwash
from obstacles in the area and where the
students can observe the plume with the
sun behind them.  A contrasting back-
ground for the plume is also important.
See section 5.8.3.4 page 47 of  67.

Mark the reading on the strip chart
as the signal is given.  See section
5.8.3.5 page 49 of 67.
                         Students should record their readings
                         in duplicate; the original to be
                         turned in to the instructor prior to
                         announcing the correct values.  See
                         section 5,8.3.6 page 51 of 67.
                                 2-12

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 12 of 67
     3.   The use of NBS traceable filters to verify prop-
         er smoke generator operation during certifica-

         tion testing,
     The intra-agency quality control program shall provide
for the establishment and maintenance of a system to assure

continued precision and accuracy of the documented results
from visual determinations.  The system should include:
     1.   The checks and audits listed in table 5.8.2,
    Table 5.8.2.   Methods of  monitoring  field variables
   Variable
   Method of monitoring (intra-agency)
  Observer position
  with respect to
  sun and plume

  Prevailing meteor-
  ological con-
  ditions
  Point of observa-
  tion in plume
  Number of  obser-
  vations per set
  Data reduction
  errors
  Documentation of
  all necessary
  information
Position should be diagrammed prior
to making observations.  See section
5.8.3.6 page 51 of 67.

Use small hand-held instruments to
determine and document wind speed and
direction, ambient temperature, dewpoint
or relative humidity, and barometric
pressure.

Opacity observations should be made
at the point of greatest opacity at
a point  in the plume where no  condensed
water vapor is present.  The distance
of the point from the stack should be
documented.  See section 5.8.3.5 page  49
of 67.

Confirm the applicable legal require-
ments prior to commencement of obser-
vations.  See section 5.8.3.6 page  51
of 67.

Check all calculations of average
opacity when the possibility of vio-
lation of the standard exists.

Check for completion of observational
records after each average opacity
determination.
                              2-13

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                                                          Section  5.8
                                                          Revision No. O
                                                          Date:  November  1975
                                                          Page 13  of 67
      2.   Routine use of nonscheduled replicate  and/or

          duplicate  observations to check  questionable

          observations,

      3.   Recertification of observers at  6-month intervals,

      4.   The  use of X (mean)  or R (range)  or other control

          charts and tests  for significance or differences

          to gain more information about  controllable and

          noncontrollable variables.

      5.8.1.9.3  Quality control programs—records.  Each

laboratory should keep quality control records  sufficient to

demonstrate adherence to the requirements in this manual.


      5.8.1.10  Bibliography—


        4. Refercncei.
        4.1 Air Pollution Control District Rules
       and Regulations. Los Angeles County Ail
       Pollution Control District. Regulation IV,
       Prohibitions. Rule 60.
        4.2 Welaburd, Melvln I, Field Operations
       and Enforcement Manual for Air, UJ3. Envi-
       ronmental Protection Agency. Research Tri-
       angle Park.  N.C.. APTD-1100. August 1973..
       pp. 4.1-4.38.
        4.3 Condon, E. 17., and Odtshaw, H., Hand-
       book of Physics, McGraw-Hill Co., N.Y, N.T,
       1958. Table 3 1, p. 0-53.
                                          2-14

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                                                   Section  5.8
                                                   Revision No.  0
                                                   Date:  November  1975
                                                   Page 14  of 67
5.8.2  Plan Activity Matrix
      5.8.2.1  Purpose—Quality assurance procedures and
checks are designed to identify invalid data and to assure
that  reported data are of acceptable quality.  These pro-
cedures and checks should be integral parts of the normal
training, testing, and field functions.  Special quality
control excercises may be required of the instructors or the
field observers by their supervisors.
     An auditing or checking level of one check in every 10
training courses, or one check per year, whichever occurs
most frequently, is used in this manual for the audit of
smoke-reading schools.   All apparatus used in the certi-
fication testing program should satisfy the specifications
defined in the Federal Register, November 12, 1974, and the
manufacturer's recommendations should be followed whenever
possible.
     An auditing level of one check in every 10 sources
observed by the field observer or one check per month,
whichever is more frequent, is used in this manual for the
audit of individual field observers.  The observer may be
required to perform special quality control checks routinely
as prescribed by his supervisor.
     This section presents, in tabular matrix form, a synop-
sis of control procedures for important sources of variation
associated with each of the five operational categories.
Some control procedures,  such as the calibration of the
smoke meter, are performed periodically.  Others, such as
verification of the smoke meter design specifications, are
performed upon purchase of the instrumentation or upon
modification of a process or of equipment.   The information
in the columns across the page indicate:
     1.    Characteristic of an item of equipment or a com-
          ponent of the system under discussion,
                            2-15

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                                                 Section 5.8
                                                 Revision No.  0
                                                 Date:  November 1975
                                                 Page 15 of 67
     2.    Scope of the characteristic or acceptance limits
          for determining the adequacy of the characteristic
          or component,
     3.    Frequency of check or measurement for determining
          conformance with requirements specified in column 2,
     4.    Action required if the characteristic or component
          does not conform with description or meet the
          acceptance limits;,
     5.    Deposition of the record of check, action required,
          and date.
     Stepwise instructions for performing each operation in
the matrix appear in the corresponding subsection of Section
5.8.3,  "Operational Procedures," or, in the case of audit
instructions, refe-r to Section 5.8.4, "Auditing Procedures."
     The operational categories have been subdivided into
the following operational areas, which more readily lend
themselves to a tabular information:
     5.8.2.2   Observer Training
     5.8.2.3   Observer Testing and Certification
     5.8.2.4   Field Observations
     5.8.2.5   Data Reduction
     5.8.2.6   Procurement of Training Apparatus and
               Supplies
     5.8.2.7   Calibration of Training Equipment
     5.8.2.8   Regular and Preventative Maintenance of
               the Smoke Generator
     5.8.2.9   Auditing Procedures
                            2-16

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                    Section 5.8
                    Revision No. 0
                    Date:  November  1975
                    Page 16 of 67




































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-------
                     Section  5.8
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                     Date:  November 1975
                     Page  17  of 67































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2-18

-------
                                                     Section 5.8
                                                     Revision No. 0
                                                     Date:  November 1975
                                                     Page 18 of  67
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                                                                     Section  5.8
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                                                       Section  5.8
                                                       Revision No.  0
                                                       Date:  November 1975
                                                       Page 24  of 67
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-------
                                                   Section  5.8
                                                   Revision No.  0
                                                   Date:  November  1975
                                                   Page 25  of 67
5.8.3  Operation Procedures
     5.8.3.1  General Considerations—In the subsections
immediately following, specific procedures for the opera-
tional categories involved in method 9 are described.  The
sequence of operations to be performed is given in figure
5.8.2.  Two sets of columns are used.  The left-hand set,
with items numbered 1 through 47, lists routine procedures
in sequential order for smoke reading from training of the
observer, through certification, to actual field observa-
tions.  Items A through N depict the testing, calibration,
maintenance, and procurement procedures that are performed
periodically.  Quality checkpoints in each of the procedural
categories for which appropriate quality control limits have
been assigned are represented by blocks enclosed by heavy
lines.  Other checkpoints involve decisions by the instructor
or observer, which are based on good judgment and documented
guidelines.
     5.8.3.2  Procurement and Acceptance Testing of the Smoke
Generator—The smoke generator shall have the capability of
generating discrete levels of both white smoke and black
smoke and emitting the smoke through a stack.  Installed on
the generator must be a smoke meter designed to measure the
opacity across the diameter of the stack.  The smoke meter
must conform to those specifications detailed in section
5.8.1.6.  Procedures for the acceptance testing are described
below.
     5.8.3.2.1  The light source must be an incandescent, low
voltage lamp, with as short a filament as possible.
     5.8.3.2.2  The photocell which will sense the light
transmitted across the stack by the source, must have a photo-
pic spectral sensitivity  (the 400-700 nm wavelengths).
Verify the proper sensitivity from the characteristic curve
supplied by the manufacturer.
     5.8.3.2.3  The angle of view of the smoke plume, as
seen by the photocell, must not exceed 15°.  The total angle

                               2-26

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                                                                                   Revision No.  0
                                                                                   Date:    November  1975
                                                                                   Page  26  of  67

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                                                         Section  5.8
                                                         Revision No.  0

                                                         Date:  November 1975

                                                         iPage 27  of 67
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-------
                          Section 5.8
                          Revision No.  0
                          Date:   November 1975
                          Page  34 of  67
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2-35

-------
                                                 Section 5.8
                                                 Revision No.  0
                                                 Date:   November 1975
                                                 Page 35 of 67
of view can be calculated from the following equation:

                    6=2 tan"1 ~-                  (1)

where   0 = total angle of view
        d = diameter of the limiting aperture
            minus the diameter of the photocell
        L = distance from the photocell to the
            limiting aperture.
The limiting aperture is the orifice plate or equivalent in
the path between the photocell and the smoke plume which
limits the angle of view.  All of the physical measurements
called for in equation 1 can be readily measured in  the
laboratory using inside/outside calipers.  Record the calcu-
lated value in the Smoke Generator Logbook  (see figure  5.8.3)
      5.8.3.2.4  The total angle of projection of the lamp  on
the smoke  plume should not exceed 15°.   The  total angle of
projection can be calculated  from:

                         0 =  2 tan"1  2£-                  (2)

where    8  = total angle  of projection
         d  = diameter of  the limiting  aperture minus
            the length of the  lamp filament
         L  = distance from the  lamp of  the  limiting
            aperture plus the  length  of  filament.
The measurement of the length  of the  filament is critical  in
the determination of the angle of projection using equation 2
and cannot be done in the average laboratory with the required
accuracy.  To avoid the  need  for this  measurement, the  follow-
ing procedure is recommended  for this  portion of the accept-
ance  test.
      1.    Remove the source and aperture apparatus from the
           transmissometer.
      2.    Set up the apparatus on a flat,  horizontal surface
           making sure that the distance  between  the  light
           source and aperture  is the  same  as it  is in the
                               2-36

-------
                                                    Section 5.8
                                                    Revision No. 0
                                                    Date:  November 1975
                                                    Page 36 of 67
                      SMOKE GENERATOR LOG

GENERATOR NUMBER 	           OPERATOR
DATE                                OWNER
                                    MANUFACTURER
Calibration
Error:       20%  50%  75%    Zero Drift
                              Span Drift    	%
                              Response Time 	 seconds
Check the following procedures if accomplished during this
maintenance and calibration period:

Change Light Bulb  D                   Check Recorder for  Q
Changed Photocell  Q                     Malfunctions
Changed Strip      Q                   Checked Air Cleaner D
  Chart Paper                           Checked Electrical  D
Check Oil          Q                     Connections
                                        Checked Trailer     Q
List any other checks which are made:     	   	
List minor or major repairs performed on any part of the equip-
ment :
List recommendations for future checks or possible repairs which
may be necessary in the near future:  	
          *Figure 5.8.3.  Sample smoke generator log.
                               2-37

-------
          transmissometer.
     3.    Turn on light source and focus the light on a bare
          wall at a distance L from the aperture.   L should
          be large compared to the distance between the source
          and the aperture.
     4.    Measure the distance from the source to  the wall, L.
     5.    Measure the diameter of the circular projection on
          the wall, d.
     6.    Substitute these  measured values in equation 2 and
          calculate 6.
     7.    Record the calculated 9 value in the Smoke Genera-
          tor Logbook.
     5.8.3.2.5  Replace the source and photocell in proper
position in the smoke meter; perform a zero and span check
after allowing a minimum of 30 minutes' warm-up.  Simulate
opacities of zero and 100 percent alternately.  When a stable
response is evident for either of the values, adjust the
smoke meter to produce the appropriate output.  The zero per-
cent opacity value can be simulated by turning on the light
source with no obstruction in the stack.  The 100 percent
opacity value can be simulated by placing a 99.99 percent
neutral density filter in the smoke meter pathlength.
     5.8.3.2.6  The calibration error is determined using
neutral density filters of known opacity which are inserted,
one at a time, in the smoke meter pathlength.  These filters
must be calibrated, within +_ 2 percent, on a spectrophotometer
using equivalent NBS calibrated filters as standards.  The
filters should have nominal opacities of 20, 50, and 75
percent.
     Make a total of five nonconsecutive readings for each
filter and record the data in the Smoke Generator Logbook.
The maximum acceptable error on any one reading shall be
3 percent opacity.
     5.8.3.2.7  Determine the zero and span drift by cali-
brating the smoke meter and operating the smoke generator  for
30 minutes.  Check the zero and span at the end of this
operating period.  Neither the :zero nor span drift should  be
                              2-38
                                                    Section 5.8
                                                    Revision No. 0
                                                    Date:  November 1975
                                                    Paqe 37 of  67

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 38 of 67
greater than + 1 percent after a 30-minute operating period.
     5.8.3.2.8  Check the response time with a stopwatch by
determining the time it takes the smoke meter to reach a
stable resonse when a 100 percent opacity is simulated directly
following a 0 percent opacity value.  For this purpose, using
the power switch to turn the light source on and off is ade-
quate to simulate 0 percent and 100 percent opacity values
respectively.  Repeat this determination five times and record
the response times on the same page in the logbook as used
for the calibration data.  The response time for each of the
five determinations must be less than 5 seconds to be
acceptable.
     5.8.3.3  Observer Classroom Training—Each of the follow-
ing subjects is to be covered in a 1- to 2-day visible-
emissions classroom training schedule.  Preparation by the
instructor is a function of both his experience in the field
of air pollution and his experience in teaching the course.
Each instructor must gear his lectures or the lectures of
guest speakers to the degree of competence exhibited by each
individual class.
     5.8.3.3.1  Principles of "smoke reading."  This lecture
should discuss the evolution of visual determinations from using
the Ringelmann Chart to the present accepted means of deter-
mining "equivalent opacity."  Method 9 as duplicated in
Section 5.8.1 of this manual should be discussed in detail.
Special emphasis should be placed on the importance of
observer position, precise determination of weather conditions
(see section 5.8.3.2.3), and the choice of a contrasting back-
ground when viewing a plume.  Visual aids may be very useful
in depicting actual observer situations  (ref. 1).
     The following guidelines are suggested:
     1.   The sun should be in the 140° sector at the rear
          of the observer.
     2.   Readings should be made at right angles to the
          wind direction from a point not less than two
          stack heights and not more than .25 miles from
          the source.   (A triangulator should be used by
                              2-39

-------
                                                   Section  5.8
                                                   Revision No.  0
                                                   Date:  November 1975
                                                   Page  39  of 67
          a field observer to  determine  the actual  distance
          from the source.)
     3.    The observer should  have a clear, unobstructed
          view of both the stack and the background.
     4.    The background should be as contrasting as  possi-
          ble with the color of the plume.
     5.    If the source has a  rectangular outlet, the
          observer's view should be at right angles to the
          longer side of the outlet.
     6.    If possible, the observer's line of sight should
          not include more than one plume if two or more
          stacks are involved.
     7.    If guideline number  6 requirements cannot be met,
          the observer should  make his observation with his
          line of sight perpendicular to the longer axis of
          such a set of multiple stacks.
     8.    The observer should  view the portion of che plume
          nearest the stack which does not contain water
          vapor.
     Experimental data (ref. 2) have shown that the viewing
position influences the accuracy of the opacity data.  The
opacity value determined by the observer will generally
increase as the angle between  the viewer plume and sun
increased.  This is because the light scattered by the plume
in the direction of the viewer increases causing a decrease
in contrast between objects viewed through the plume and an
increase in contrast between the plume and its sky background
(ref. 3).  The amount of light scattered in the direction of
the observer is not only dependent upon the observer's posi-
tion, but also on the clarity  of the sky and the color of the
plume.  A discussion of these  parameters is found in reference
3.
     5.8.3.3.2  Procedures for the certification testing.
General procedures for certification testing should be dis-
cussed as detailed in Method 9.  Procedures characteristic
of a particular training school should be covered.  These
                               2-40

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 40 of 67
might include:  the number and procedure for practice runs,
the data recording process, grading methods, repeat testing,
certification procedures, and recertification requirements.
     5.8.3.3.3  Basic meteorology  Each student is to gain
sufficient meteorological expertise so as to perform an
assessment of the weather at a particular point in time.
He must be aware of all the meteorological factors that
affect the plume density and direction, and acquire ample
vocabulary to describe the weather conditions thoroughly and
accurately.  The factors most relevant to the dispersion of
contaminants include temperature, humidity, wind speed, and
wind direction.  Methods for determining each of these factors
are to be discussed in the classroom.  For example, the
recommended equipment list might include a sling psychrometer,
a wind gage with compass, and a barometer.
     The student is also taught to accurately differentiate
between and describe background sky conditions.  For instance,
precise definitions of terms such as "clear" and "partly
cloudy" should be made available.  The instructor should
demonstrate the use of photographs and moving pictures to
complete a description of the atmosphere surrounding a plume.
     5.8.3.3.4  Pollution sources.  The purpose of this
lecture is to enable the observer to identify various types
of industrial and commercial sources (ref. 2).  Particular
emphasis is placed on the types of sources prevalent in the
areas to be observed.  The observer must learn to describe
the composition of the emissions, i.e., fume, dust, vapor,
smoke, oil; the approximate sizes of the particulates involved;
and the color.  The differentiation should be made between
combustion and noncombustion sources.
     5.8.3.3.5  Combustion processes.  The instructor explains
efficient combustion and the conditions that produce incomplete
combustion.  Both the combustion of fuel oil and the combustion
of coal should be covered along with any other combustion
emissions prevalent in the area to be observed.  As a result
of the lecture, the student is able to identify types of
                               2-41

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 41 of 67
fuels, the elements that affect the amounts of smoke produced,
and the types of pollution control equipment available.
     5.8.3.3.6  Legal aspects of smoke reading.  A short
history of visual determinations helps the student under-
stand the meaning and usage of opacity measurements.  Docu-
ments discussing the validity and accuracy of visual deter-
minations can be referenced in discussions concerning the
constitutionality of health and safety codes which are based
on the equivalent opacity principle (refs. 5 and 6). Any
regulations pertaining to the prevention, abatement, and
control of visible emissions in effect in the region or area
where the course is being given must be defined.  Any out-
standing court proceedings that can be discussed would prove
beneficial.  It is highly recommended that a lawyer or legal
expert either give this lecture or be present to entertain
questions upon completion of the lecture.
     Emphasis should be made in this lecture on the importance
of documenting all information available on the source in
question, the weather conditions, background, and viewing
position.  In the event that a set of observations is the
basis for court action, the observer will have to rely on
the information documented at the time of the violation.
     5.8.3.3.7  Behavior of the expert witness.  Quite often
a smoke reader is required to act as an expert witness in a
court case (ref. 7).  The lectures must discuss the prepara-
tion for giving testimony, which includes the review of all
reports, photographs, and correspondence related to the
case.  In addition, topics such as dress, responsiveness to
questions, and definition of court procedures are to be
covered.
     5.8.3.3.8  Data forms.  The classroom instructor is to
outline each of the data that should be documented before
and/or after an observation.  Samples of forms which can be
used in reporting the data are shown on the following paaes.
                              2-42

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 42 of 67
     The Observation Information Form (see figure 5.8.4)
has blanks for information concerning the company under
observation, the observer's credentials, the observer's
position, and a summary of the opacity data collected.  On
the back of this form is a diagram, which should be used to
describe the relative positions of the stack under observa-
tion, the observer, and any significant natural or manmade
features of the region.
     The following is a list of each of the items that must
be filled in on the Observation Information Form at the
observation or shortly thereafter.
          1.  Date;
          2.  Company—name in full, including the name
              of the division;
          3.  Location—street name, number, and city or
              county where the source is located;
          4.  Type Facility—the category of the source,
              i.e., coal-fired electric generating plant,
              sulfuric acid plant, steel mill, pulp and
              paper mill, etc.;
          5.  Stack Number or Designation—a definition of the
              particular stack under observation in the ease
              of multiple stacks at a single facility;
          6.  Control Device—the type of equipment used
              to collect particles prior to emission
              from stacks;
          7.  Height of Discharge Point—approximate height
              of stack above ground;
          8.  Point of Emission—approximate distance
              from stack lip to point in plume where
              observation is made;
          9.  Type of Fuel;
         10.  Stack Dimensions—diameter of circular
              stack or length of sides of rec-
              tangular stacks;
         11.  Observer—name;
         12.  Observer Affiliation;
                               2-43

-------
                     Section 5.8
                     Revision No. 0
                     Date:  November 197o
                     Page 43 of 67














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-------
                                           Section 5.8
                                           Revision No. 0
                                           Date:  November 1975
                                           Page 44 of  67
                                                  NE
Figure 5.8.4 (con).
Sample observation information
form (reverse side).
                         2-45

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 45 of  67
         13.   Observer Certification Date—last time the
              observer was certified;

         14.   Time of Arrival—time the observer arrived
              at the position from where he observed the
              plume;

         15.   Time of Departure—the time the observer left
              his position after making the observations;

         16.   Background Description—brief description of
              what is in the observer's line of sight be-
              hind the plume;

         17.   Weather Conditions—estimated, read from
              instrumentation,  or taken from weather sta-
              tion data,

         18.   Plume Description--color of the plume and
              the approximate distance from the stack where
              the plume is still visible;

         19.   Observer Position Diagram—locate the stack
              under observation, any surrounding stacks, the
              observer position, the wind direction, and any
              significant topographical features;

         20.   Summary of Average Opacity—use the data
              recorded on the "Observation Data Record"
              to determine the sum and average opacity
              for each set.

     The Observation Data Record  (see figure 5.8.5) has a
            i
heading which asks for information from the Observation
Information Form for quick reference.   The observer should

record opacity every 15 seconds in the box under the appro-
priate second heading and check whether or not the plume was

attached or detached.

     5.8.3.3.9  Data reduction.  The instructor should go

through several opacity calculations based on the number of

readings per set required by the law enforcement agency.

     5.8.3.3.10  Testing.  The instructor is to give the stu-

dents a 1- to 2-hour written objective test.  The test

should serve two purposes:   (1) to determine the effectiveness

of the teaching procedures used, and  (2) to highlight the

more important information presented in the course.  The
                              2-46

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                                                              Section  5.8
                                                              Revision No.  0
                                                              Date:   November 1975
                                                              Page  46  of 67
                           OBSERVATION DATA RECORD
        COMPANY 	
        LOCATION 	
        TYPE FACILITY 	
        STACK NO. OR DESIGNATION
        POINT OF EMISSIONS
OBSERVER
DATE 	
HOUR 	
TEST NO.
COMMENTS:
MIN.
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
SECONDS
0






























15






























30






























45






























STEAM PLUME
ATTACHED






























DETACHED






























MIN.
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44 ]
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
SECONDS
0






























15






























30






























45






























STEAM PLUME
ATTACHED






























DETACHED






























                   Figure  5.8.5.  Sample  data  log.

                                   2-47

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 47 of  67
test should be graded and discussed in the class.  Each
student can keep his test, but the grade should be entered
in the student's permanent file.

     5.8.3.4  Preparation for Observer Field Training—The
following procedures are recommended for the smoke generator
operator in his preparation for a training session:
     5.8.3.4.1  Locate the generator on a very level ground
using the third wheel at the front of the generator to
compensate for slightly sloping ground.  Consider the back-
ground for the plume, making sure that the most contrasting
sky background available it? behind the generator.  Watch for
large buildings or tree stands which may cause considerable
downwash motions affecting the plume near the discharge
point.
     5.8.3.4.2  Check the generator for any obvious damage
in transport.
     5.8.3.4.3  Raise the stack following the manufacturer's
instructions.  If high winds are a possibility, take the
necessary precautions to secure the stack.  If it is evident
that high winds will persist through the testing period, an
elbow can be added to the top of the stack so that the smoke
will be emitted horizontally.  This will prevent shearing of
the plume and avoid loss of training time.
     5.8.3.4.4  Check the levels of all fuels and lubricants
required by the smoke generator.  In the case of a gasoline
engine:  the gasoline tank should be filled to its 1/2-
gallon capacity; fill the benzene tank with at least 5
gallons of industrial grade benzene or benzol; fill fuel
oil tank with at least 5 gallons of #2 fuel oil; and fill
the motor crankcase with 1 quart of oil.  Lubricate the main
blower motor with several drops of oil.  See reference 1 for
additional information.
                               2-48

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November  1975
                                                   Page 48 of 67
     5.8.3.4.5  Make the necessary electrical connections;
and then turn all of the necessary switches on the control
panel to the "on" position (i.e., main power switch, stack
fans, main blower, recorder,  and light source).
     5.8.3.4.6  Simulate 0 percent and 100 percent opacity
values.  The zero opacity can be simulated by turning on the
light source with no obstruction between the source and photo-
cell.  Zero the recorder as necessary.  It is recommended
that the 100 percent opacity be simulated by placing a 99.99
percent neutral density filter in the smoke meter pathlength.
Adjust the recorder for 100 percent opacity.  Before each run,
then, the operator should follow the same procedure for 0
percent opacity and do a check for 100 percent opacity by
turning off the light source.  Again the recorder should be
adjusted based on the results from these checks.
     5.8.3.4.7  Insert the 20 percent, 50 percent, and 75
percent neutral density filters one at a time in the smoke
meter pathlength for one set of calibration readings.  Make
a total of five sets of calibration readings and record
the data as it is taken (figure 5.8.3).  If the error on any
one reading within a set proves greater than 3 percent,
commence troubleshooting procedures which should include
checks for:
          1.   recorder malfunction,
          2.   photocell malfunction,
          3.   reflective light getting into photocell,
          4.   intensity of bulb.
     5.8.3.4.8  Check the zero and span drift after a 30-
minute warmup period and record  (figure 5.8.3).
     5.8.3.4.9  Complete the Smoke Generator Log  (figure
5.8.3).  The log shown here is merely a sample.  Any items
which may be inappropriate may be deleted or items which may
be more appropriate may be added to meet the characteristic
requirements of the particular generator in use.
                               2-49

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                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 49 of 67
     5.8.3.5  Observer Field Training—This training is to
consist of two parts:  (1)  developing judgment skills in the
area of weather data, and (2) developing judgment skills in
the evaluation of smoke opacities.
     Several times throughout the field training, the instruc-
tor should request that the students fill out a form such as
shown in figure 5.8.6.  After the students complete the
forms, the forms are collected and the answers compared with
the instructor's evaluation of the weather at the same time.
Any major variations are discussed immediately.
     The instructor should describe again the correct observer
positions with respect to the plume and the sun.  The back-
ground for the plume should be discussed so that the students
are capable of describing it on their test data forms.
     The smoke generator operator starts up the generator
(see section 5.8.4.3) and explains the procedures he will follow.
He then demonstrates at least 20 different shades of white
smoke and then 20 different shades of black smoke.  Repeating
the procedure he should place particular emphasis on those
shades just above and below the legal limit.  During these
demonstrations, the operator should set the output of the
generator, and when the strip chart reading stabilizes, he
calls out the value for all the students to hear.
     Following the demonstration, the instructor is to hand
out test data forms for the practice certification runs.  As
the operator signals when the strip chart has stabilized at
each value, the students are to glance at the plume and
record their determination on the test data.  The operator
himself must mark the reading on the stripchart simultaneously
with the signal which can be vocal or through the use of a
horn.  An event marker is suggested if the recorder can be
equipped with one.
                               2-50

-------
                                                         Section 5.8
                                                         Revision No.O
                                                         Date:   November 1975
                                                         Page 50 of 67
                         WEATHER DATA
                                     NAME

                                     DATE
                                     TEST NO.

                                     TIME
ESTIMATED DISTANCE FROM THE  GIVEN LOCATION	feet

ESTIMATED WIND SPEED                    	mph

APPROXIMATE WIND  DIRECTION               J	

CONDITION                               	

PLUME BACKGROUND                         	


List any changes  in the weather conditions:
      Figure 5.8.6.   Sample  form for  testing determination
                       of weather data.

                                 2-51

-------
                                                   Section 5«8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 51 of 67
     Each practice run should consist of 25 different white
plumes and 25 different black plumes.  After each run, the
students should grade their own paper as the operator reads
the transmissometer values aloud.  The number of practice
runs is determined by the level of skill demonstrated by the
students' grades.

     5.8.3.6  Certification Procedures—Following the practice
runs, the instructor hands out the test data forms (figure
5.8.7) for the certification testing.  Each form has a
carbon copy attached.  With an announcement that certifica-
tion tests will follow, the operator should adjust the
generator to generate black plumes.  At each different
opacity value, the operator wsiits for the recorder needle
to stabilize, blows the horn, and simultaneously marks the
reading on the stripchart. The same procedure is followed
for the white plumes.
          A set of 25 different shades of black plumes and 25
different shades of white plumes makes up one certifying
test.  After each test every student must turn in the original
copy of the test data sheet, keeping a carbon copy.  The
instructor then reads aloud the 50 opacity values marked on
the stripchart.  The students grade their own papers and
calculate the deviations from the transmissometer readings.
     If any of the plumes were read with a deviation greater
than 15 percent opacity, that student does not qualify.  The
student then calculates the average deviation for each cate-
gory  (black and white) using the formulas given.  If either
of the average deviations exceeds 7.5 percent opacity, the
student does not qualify.
     Repeat the testing procedure until all of the students
or a sufficient number of the students qualify for cerfici-
cation.  Prior to official certification, the instructor
                               2-52

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                                                              Section  5.8
                                                              Revision  No.  0
                                                              Oate:   November  1975
                                                              Page  52 of  67
  NAME OF OBSERVER

  AFFILIATION 	
           SMOKE EVALUATION PROFICIENCY EXAMINATION

          	    OBSERVER'S POSITION

                               TIME
    Wind Speed 	
    Wind Direction
    Temperature 	

    Humidity 	
                                 Sky Condition
                                 Run Number
BLACK PLUMES
Reading
Number
1
2
3
4
5
6
7
8
9
"10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Observer
Reading

























Trans .
Reaaing

























+
Dev.

























Dev.

























^_15%
Oev.

























WHITE PLUMES
Reading
Number
1
2
3
4
5
6
7
a
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Observer
Reading

























Trans.
Reading


























+
Oev.


























Dev.










115%
Dev.










1


























!
TOTALS:

Av. dev.
(Sum of -Kiev. )+(Sum of -Dev.)
          25
Av. dev.  for Black Plumes
                            Av.  dev.  for White Plumes
        Figure 5.8.7.  Sample certification  test form.


                                   2-53

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 53 of 67
must recheck the original of each qualifying test sheet to
confirm qualification.
     5.8.3.7  Field Observations—The certified field
observer shall follow the procedures listed in this section
upon arrival at a source location.
     5.8.3.7.1  Position yourself at a distance where you
have a clear view of the emissions.  The sun should be in
the 140° sector at your back.  Your line of sight should be
perpendicular to the plume direction.  In the case of a
rectangular stack, the line of sight shall be approximately
perpendicular to the longer axis of the outlet.  If there is
more than one stack in view, /our line of sight should be
perpendicular to the longer axis of the group of stacks.
     5.8.3.7.2  Record all of the information asked for on
the Observational Data Form, including the completion of the
Observer Position Diagram.
     5.8.3.7.3  Fill in the information at the top of the
Observation Data Record.
     5.8.3.7.4  Be sure to wear the same corrective lenses
that were worn for certification.  It is recommended that you
remove any sunglasses and allow time for the eyes to adjust
to the daylight as the case may be.  This avoids biasing the
data.
     5.8.3.7.5  With stopwatch in hand, observe the plume
momentarily at 15-second intervals for at least the number
of intervals required by law.  Opacity observations shall
be made at the point in the p>lume of greatest opacity where
condensed water vapor is not present.
     If an attached steam plume exists, readings shall be
taken at the point in the plume closest to the outlet where
the condensed water vapor is no longer visible.  In the
event of a detached steam plume, the opacity should be
evaluated at the stack outlet prior to the condensation of
water to form a steam plume.
                               2-54

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November  1975
                                                   Page 54 of 67
     5.8.3.7.6  The data will be recorded for each set on
the Observation Data Record.  Upon completion of a set or
sets of observations, the observer shall calculate the
average opacity by summing the opacities determined in a
given set and dividing by the number of readings in the set.
This information shall be recorded in the Summary of Average
Opacity on the Observation Information Form  (figure 5.8.4).
     Depending on the organizational structure, the observer
may or may not be responsible for these computations of the
average opacity.  In the case that he is not, an alternate
to the above procedure would require the deletion of the
Summary of Average Opacity from the Observation Information
Form and the generation of a separate form to be filled out
by the person responsible for the calculations.
                              2-55

-------
                                                    Section  5.8
                                                    Revision No.  0
                                                    Date:  November  1975
                                                    Page  55  of 67
5.8.4  Auditing Procedures

     In making special checks for auditing purposes, it is impor-
tant that the checks be accomplished independent of and without
disturbing the normal operating procedures.
     Two audit checks are recommended to properly assess the
quality of visually determined opacity data:
     1.   Assessment of field observations, and
     2.   Evaluation of training schools.
     Each audit check is treated separately in the ensuing
sections.  A detailed discussion of auditing procedures
including acceptance sampling plans and the use of control
charts is contained in the Quality Assurance Handbook for
Air Pollution Measurement Systems, Volume I—Principles,
published by EPA.
     5.8.4.1  Auditing of Field Observations—The method
recommended for auditing field performance requires that a
second expert observer make an observation of a given source
simultaneously with the field observer being audited.  The
audit should include an assessment of all variables that in
some way affect the accuracy of the opacity data.
     It is recommended that field observations be grouped by
observers and/or organizations to yield a group or lot size
of about 100  (i.e., N = 100) to be performed over a time
period of one calendar quarter when possible.  An auditing
level of 10 percent is recommended; that is, from the 100
field observations projected for a given calender quarter,
10 should be randomly selected for auditing.  In situations
where obtaining a lot size of 100 is impractical, an auditing
level of one audit check for each 10 field observations or
one audit per month, whichever is greater, is recommended.
     An audit is defined as not less than 3 runs of 24
readings, each performed simultaneously by the auditor and
the observer being audited.
                               2-56

-------
                                                   Section  5.8
                                                   Revision No.  0
                                                   Date:  November  1975
                                                   Page  56  of 67
     5.8.4.1.1  Method of auditing field observations.
     The auditor,  i.e.,  the individual performing the audit,
should be a currently certified smoke reader and should have
extensive background experience in all areas of smoke reading.
The following procedural guidelines are recommended for the
auditor in monitoring field performance:
     1.  Accompany the observer to the field site;
     2.  Choose an appropriate position for viewing the
         plume independent of the observer's choice;
     3.  Fill out the Observation Information Form  (figure
         5.8.4) independently, but at the same time that
         the observer fills out his form;
     4.  Using individual stop watches, commence a run of
         readings for the same time period observed by
         the observer.  Repeat this operation to obtain
         simultaneous readings for a series of three runs.
     5.  Record the determined opacity values for each run
         on separate Observation Data Records (figure 5.8.5);
     6.  Calculate the sum and/or the average of the opacities
         for each set of readings that cover the same time
         period as used by the observer to make his calcula-
         tion;
     7.  Complete an Audit Data Form  (figure 5.8.8) for each
         run.  If more space is required, use a blank sheet of
         paper and attach it to the audit data form;
     8.  Inform the field observer of the comparison results,
         specifying any area(s) needing special attention or
         improvement;
     9.  File the record for future data quality assessment
         (section 5.8.4.1.2).
     5.8.4.1.2  Data quality assessment of field observations.
     Three aspects of data quality assessment are considered
here.  They are:
                               2-57

-------
                                                       Section  5.8
                                                       Revision No. 0
                                                       Date:  November 1975
                                                       Page 57  of 67
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-------
                                                    Section  5.8
                                                    Revision No.  0
                                                    Date:  November  1975
                                                    Page  58  of 67
     1.    The use of control charts for plotting audit data
          as they are obtained to allow for corrective
          action to be taken, if necessary, after each audit.
     2.    The use of audit data to estimate the precision
          and bias of the field observations on a lot-by-lot
          basis.
     3.    Testing the data quality against given upper (U)
          and lower (L)  limits using sampling by variables
          to monitor and thereby help control the average
          percentage of reported field observations falling
          outside the limits.
     Each aspect is treated separately in the following para-
graphs.
     A.    Use of Control Charts
     A form such as shown in figure 5.8.9 is suggested for
recording individual audit data as they are obtained.  Fill
in the clerical information which includes the name of the
auditor, date of the audit, name of the observer being
audited, audit number, date that the audit period ends, and
date that the Data Assessment Form is filled out.
     Both the observer and the auditor are to calculate the
average opacity, 5. and 5  ., respectively, for each of the 3
                  D      aD
runs of 24 consecutive readings each.  Using the following
equation, calculate the difference between the auditor's and
observer's values for each run  (j = 1 to 3):

                      d.  = 0 .  - 0 . .
                       :     :     an
The three values of d. can then be plotted on a control chart
as shown at the bottom of the sample data assessment form in
figure 5.8.9.  The control chart is a quick visual check to
determine if the d. values are within acceptable limits.
     The values used in figure 5.8.9 for the upper control
limit (UCL) and lower control limit  (LCD represent + 3 standard

                               2-59

-------
                                                  Section 5.8
                                                  Revision No. 0
                                                  Date:  November 1975
                                                  Page 59 of 67
AUDITOR'S SIGNATURE

OBSERVER'S NAME 	

AUDIT NO.
              AUDIT DATE _

              TODAY'S DATE
of Audit Period Ending
DATA:
Opacity Values Audit Run Number

°j
Oaj
dJ = °j-°aj
1



2



3



           Check if  Id. I  > 3a-r- =  6
                     1  i'     d
Plot d; values

•r— i
ft!
IO
1
IO
II
T3

10.
6.

-6.
-10.


4
9

9
4


UCL
Warning

Warning
LCL
1 1 1
• 1 1
j=l J=2 j=3

Limit

Limit



Figure 5.8.9. Sample data assessment  form for  each audit.
                              2-60

-------
                                                   Section 5.8
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 60 of 67
deviations of the differences based on the between-observer
standard deviation, o,  = 2.45 percent opacity, reported from
a collaborative test of the method (ref. 3) and thus a
standard deviation of the differences of a, = /2  a.  =3.46
                                          d        b
percent opacity.  These limits should be recalculated and
adjusted if necessary as actual field data become available.
     If one or more d. values fall outside the UCL and LCL
limits or if the average difference of the three runs |d.| > 6,
action to correct possible deficiences should be taken before
the audited observer performs future field observations.  Such
action should include either informal or formal retraining of
the observer.
     The auditor should complete the data assessment audit
form or equivalent form and forward copies to his supervisor
and to the field observer's supervisor with appropriate
comments if either of the above performance criteria were
exceeded.
     B.   Estimating Precision and Bias of Field Observations
     The average difference, d., for the ith audit as recorded
on the sampla data assessment audit form of figure 5.8.9 is
used to fill in the data in the table at the top of figure
5.8.10 for a given auditing period.  That is, values for d.
for i=l, 2, 3, ..., n are recorded in the table for each
audit period.
     Bias of the field observations for that lot of field
observation data, obtained during the audit period, is
estimated by d calculated as shown in figure 5.8.10.
     The precision is estimated in terms of the standard
deviation of the average differences of the i audits, i.e.,
s-: .  The standard deviation of the differences is calculated
 d.
as shown in figure 5.8.10 and used as an estimate of the
standard deviation of differences for that lot of data.
                               2-61

-------
 AUDITOR'S SIGNATURE
                   Section 5.8

                   Revision No. 0

                   Date.  November 1975

                   Page 61 of 67

      AUDIT PERIOD      to
DBSERVER'S NAME
DATA:
TODAY ' S DATE


Average
difference Audit Number i

di
1

2

3

4

5

6

7

8

9

10



n



AUDIT NO
dT-d
 L   Q
      Figure  5.8.10  Auditing period data assessment  form.



                               2-62

-------
                                                    Section  5.8
                                                    Revision No.  0
                                                    Date:  November 1975
                                                    Page  62  of 67
     The field data for that lot or group of field observa-
tions are reported with the calculated values for bias T and
standard deviation of differences a,.
     C.   Testing data quality against given standards
     Because the lot size is generally small, N < 100, and
the sample size is small, say of the order n < 10, it is
important to assess the quality of the data with respect to
prescribed limits using sampling by variables to make as
much use as possible of the audit data.
     Some of the background concerning the assumptions and
the methodology will be repeated below for convenience.
However, a number of publications can be referred to for a
more detailed discussion of sampling by variables (see refs.
8, 9, and 10).  The discussion below will be given in
regard to the specific problem of analyzing visible opacity
data which has some unique features as compared with the usual
sampling plans.
     The plan as illustrated here is designed to provide a
probability of 0.9 of detecting a lot or group of field data
in which 10 percent or more of the differences, if all
observations had been audited, fall outside the limits L and U.
     Using the data from a collaborative study on this method
(ref. 3), the mean difference of opacity measurements made by
different observers has a standard deviation of 3.45 percent
opacity.  Assuming 3a-j limits, the values of -10.4 and +10.4
are used to define lower and upper limits, L and U,  respec-
tively, outside of which it is desired to control the portion
of differences, d..  Following the method given in reference
10, a procedure for applying the variables sampling plan is
described below.  Figures 5.8.11 and 5.8.12 illustrate
satisfactory and unsatisfactory data quality with respect to
the prescribed limits L and U.
     The variables sampling plan requires the following:
                               2-63

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                                                    Section  5.8
                                                    Revision No.  0
                                                    Date:  November 1975
                                                    Page  63  of  67
 Example 5.8.11.  Example  illustrating p < 0.10 and satisfactory
                  data  quality.
                                              p  (percent of measured
                                                differences outside
                                                limits L and U) > 0.10
Figure 5.8.12,
Example illustrating  p >  0.10 and unsatisfactory
data quality.
                                2-64

-------
                                                    Section 5.8
                                                    Revision No.  0
                                                    Date:   November 1975
                                                    Page 64 of 67
               d, the sample mean difference
              s-3, the standard deviation of the differences
               k, a constant whose value is a function of p
                  and n for a given sampling plan , and
               p, the portion of the differences outside the
                  limits L and U at which we want to detect with
                  a probability P.
For example, to control at 0.9 the probability of detecting
lots with data quality p equal to or greater than 0.10 (or 10%
of the differences outside of L and U) for a sample size of
n = 10, then the value of k = 2.112 is obtained from table
5.8.3.  Additional values of k for other sampling plans can
be determined from table II of reference 10.  The values of
3 and ST are calculated as shown in figure 5.8.10.
     Given the above information the test procedure is
applied and subsequent action is taken in accordance with
the following criteria:
     a.   If both the following conditions are satisfied,

                         U  = 3 + ks3- < U
                          c         d -

                         L  = d - ks-r- > L
                          c         d -
          then the measurements are considered to be
          consistent with prescribed data quality limits
          and no corrective action is prescribed.
     b.   If one or both of the inequalities is violated,
          possible deficiencies exist in the opacity deter-
          mination process as carried out for that particular
          lot of field observations.  These deficiencies
          should be identified and corrected before future
          field observations are performed.
Table 5.8.3 contains a few selected values of n, p, and k
for convenient reference.
                               2-65

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                                                    Section 5.8
                                                    Revision No. 0
                                                    Date:  November 1975
                                                    Page 65 of 67
      Table 5.8.3  Sample plan constants,   k for P (detecting a lot
           with  proportion p  outside  limits L and U}  >  0.9
Sample Size n
3
5
7
10
12
5.8.4.2 Evaluation
p = 0.
3.039
1.976
1.721
1.595
1.550
of Training
2 p = 0.1
4.258
2.742
2.334
2.112
2.045
Schools-- The method
recommended for monitoring a given training school requires
that an auditor attend one complete training course for
every 10 training courses held by the school.  If less than
10 training courses are held in 1 year, at least one of
the courses must be audited.  The audited courses are randomly
selected.
     5.8.4.2.1  Method of auditing_training  schools.  The auditor,
 i.e.,  the  individual  performing  the audit, should have extensive
 background experience in all of  the areas  listed in sections
 5. 8. 3.. 2  and  5.8.3.3.   In addition, the auditor must be a current-
 ly certified observer and have.' had experience in the  preparation
 and  implementation of a  training course.
     Attend  all of the lectures  and/or seminars, using a
 Course Evaluation Form as shov/n  in figure  5.8.13 as a guide-
 line for making quality  evaluations.   Upon completion of the
 course,  document the  evaluation  with  the designated grading system.
     Check the smoke  generator for any obvious malfunctions,
 following  procedures  similar  to  those in section  5.8.3.3. Us-
 ing  appendix A as a guideline, confirm that  the  generator meets
 those  specifications.  Document  all  results  on a Smoke Generator
 Log  (figure  5.8.5).
     5.8.4.2.2  Course-quality assessment.   It  is  recommended
 that the audit level  be  increased by  a factor of  two  if  either
 of the following situations occurs:

                               2-66

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                                                       Section  5.8
                                                       Revision No. 0
                                                       Date:  ••Jovon.bor 1975
                                                            66  of 67
                            METHOD 9

                        COURSE EVALUATION
 GRADING SYSTEM:
1 - Excellent
2 - Good
                                    3 - Fair
                                    4 - Poor
14. Other comments
QUALITY CHECK
1. Definition of course
objectives
?. Choice of subjects
3. Lecturer(s)' Knowledge
of subjects covered
4. Relevancy of the
material covered
5. Proper emphasis on
important facts
6. Presentation of
the lectures
7. Choice of visual aids
8. Use of visual aids
9. Organization
10. Field-lecture balance
11. Condition of smoke
generator
12. Calibration and
operation of smoke
generator
13. Testing procedures
1













2













3













4













COMMENTS













     Figure  5.8.13.   Sample course evaluation form.

                               2-67

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                                                      Section  5.8
                                                      Revision No.  0
                                                      Date:  November  1975
                                                      Page  67  of 67
     1.   Any of the quality checks in figure 5.8.13 falls
          below a grade 2;
     2.   The auditor notices; any other serious irregularity
          in the course proceedings.
The training school should be; audited continuously until either
         f
or both of the following situations are corrected:
     1.   Any of the quality checks is rated a grade 4, and
     2.   The smoke generator does not: meet the specifications
          stated in appendix A.
                                  2-68

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                                     Section 3.0
                                     Revision No. 0
                                     Date:  November 1975
                                     Page 1 of 1
3.0  FUNCTIONAL ANALYSIS OF TEST METHOD
                 3-1

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                                                   Section 3.1
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 1 of 4
             3.0  FUNCTIONAL ANALYSIS OF TEST METHOD

     Test Method 9—Visual Determinations of the Opacity
of Emissions from Stationary Sources, is described in the
Federal Register, November 12, 1974, and is reproduced in
section 5.8.1 of this document.  This method pertains to the
determination of the opacity of visible emissions by quali-
fied observers.  It requires the proper training and certi-
fication of the observers and the use of defined procedures
in the field when making the determinations.
     This method has been subjected to collaborative testing
(ref.  3); therefore, some quantitative information on the
precision and bias is available.  In some areas of variable
evaluation, though, quantitative data is not available, and
the functional analysis is forced to be somewhat general.  In
these cases, engineering judgments were used in estimating
variable limits.  The subject of error analysis is discussed
in references 11 and 12.

3.1  VARIABLE EVALUATION AND ERROR RANGE DATA
     The opacity of the visible emissions from a stationary
source where Method 9 is applicable is reported for enforcement
purposes in terms of the average opacity over a given period.
A set of at least 24 consecutive readings is generally
observed, with each reading taken at 15-second intervals.
From this set, the average opacity can be calculated with
the following equation:
                             m
                             I  0.
                         ° ^l—
                               m
                               3-2

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                                                    Section  3.1
                                                    Revision No.  0
                                                    Date:  November  1975
                                                    Page 2 of 4
where:
     6   = calculated average opacity, percent opacity,
     0.  = determined opacity for the jth reading, percent
           opacity,
     m   = number of consecutive intervals required by the
           law enforcement agency for computing average
           opacity to determine a violation of the applica-
           ble opacity standards.
     The plume at the time and point of the readings will
have a specific but unknown percent opacity (O').  The differ-
ence in the O1 (average of the true opacity over the same time
interval)  and 0,  as calculated in equation 1 above, is due
to a combination of errors in the observation process, some
of which are controllable, while others are not.  A short
description of each source of error is given in the following
list.
     1.  Position of the observer with respect to the plume.
The reference method (section 5.8.1) states that the observer
should locate himself at a sufficient distance from the source
such that he shall have a clear view of the plume.  It also
states that the observer should be perpendicular to the
plume direction in the case of a single stack.  Error due to
a deviation from this ideal positioning would depend on the
exact position, the shape of the plume, and the wind speed
and direction at the time of the readings.
     The reference method (section 5.8.1) also states that,
in the case of multiple stacks, the observer is to position
himself so that his line of sight is perpendicular to the
longer axis of the set of stacks.  Also, his line of sight
should not include more than one plume at a time.  A devia-
tion from either of these requirements could cause the data
to be biased.
     Although error can result from an improper observer
position,  his position can be considered a controllable
                               3-3

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                                                   Section  3.1
                                                   Revision No.  0
                                                   Date:  November  1975
                                                   Page  3 of  4
variable in the observational process.  Proper positioning
can almost always be realized at some point in time with
appropriate weather conditions.
     2.   Position of the observer with respect to the sun.
The qualified observer should be positioned so that the sun
is oriented in the 140° sector to his back.  Just as in the
source of error discussed above, the observer's position
with respect to the sun is a controllable variable, and the
errors due to this source can be minimized.  Test data  (ref.
1) has shown that the closer the sun is to being directly
behind the observer, the more accurate the observation
values will be.
     3.    Determination of the weather data.  Good judgment
and proper documentation of the weather data play an impor-
tant role in interpreting opacity data at a later date.
Inaccurate weather information or the lack of weather infor-
mation can serve to discredit the data in a court of law.
The use of weather measurement instrumentation, weather
station data, or charts, can greatly reduce error in judg-
ment.
     4.    Corrective or colored lenses.  The use of corrective
or colored lenses can be a major source of observational
error if they were not worn during the certification testing.
This source of error can be eliminated if the observer  takes
the precaution of removing any sunglasses or unnecessary
lenses while performing the visual determinations.
     5.    Background against which the plume is viewed.  The
plume is most visible and the observer will determine the
highest opacity value for a given plume when the background
is contrasting with the color of the plume.  It is with the
contrasting background that the plume opacity can be deter-
mined with the greatest degree of accuracy.  However, the
probability of positive error is also the greatest under
these conditions.  As the background becomes less contrasting

                               3-4

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                                                   Section  3.1
                                                   Revision No.  0
                                                   Date:  November  1975
                                                   Page 4 of  4
the apparent plume opacity diminishes and determinations tend
to assume a negative bias (which actually favors the plant
operator).   The results of studies undertaken to determine
the magnitude of the positive errors are given in the
Federal Register, November 12, 1974.
     6.   Momentary observations.  The observer should not
study the plume continuously, but instead should observe
the plume momentarily at 15-second intervals.  More than a
momentary glance can not only allow the observer to lose
his concentration but may also cause eye fatigue.
     7.  Point of observation.  Error can occur if the
observer exercises poor judgment in his determination of
the point of observation.  The point of observation should
be the point in the plume closest to the stack where con-
densed water vapor is not present.  The point should also
be where the plume exhibits the greatest opacity.  Error, if
any, due to readings taken at a point where condensed water
vapor is present is usually positive.  However, after compre-
hensive training, a certified observer can readily identify
the portion of the plume which contains condensed water vapor
and will avoid assigning an opacity to a plume which contains
any visible (condensed) water droplets.  Thus the probability
of error due to the presence of condensed water vapor is
negligible   (ref. 13) .  Readings taken at points other than
the point of greatest opacity cause the average opacity
value to be less than the actual opacity.  The probability
of this source of error, too, is a function of the quality
of training and the observer's experience, and can be consid-
ered almost nonexistent in observations made by certified
observers.
     8.  Experience of the observer.  The term "experience"
as used here refers to length of time the observer has been
                               3-5

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                                                    Section  3.2
                                                    Revision No.  0
                                                    Date:  November  1975
                                                    Page  1 of  1
certified, which can dictate his personal biases.  Collab-
orative tests have shown that the readings of the more
experienced observer are consistently more accurate than the
readings of the less experienced observer.  However, the
less experienced observer's error is almost always negative,
which is in the favor of the emission source.
     9.  Nighttime observations.  Visible emission monitoring
is difficult to apply at night.  Any observer who must make
observations at night should receive special training to
calibrate his eye for night conditions.  The background
under these conditions will generally be less contrasting,
hence the error will tend to be negative.  See number 6
above..
     10.  Calibration of the observer's eye.  The readings
are subject to error from inaccuracies in the calibration
of the; observer's eye.  Such an error would bias all obser-
vations made until the observer is tested and recertified.
This can be avoided with frequent auditing of the observer's
performance, stringent specifications on the smoke generator
used for certification, and frequent recertification.
     11.  Data processing.  Errors can occur in the calcu-
lation of the average opacity over a given time interval.
These errors can be avoided by consistently rechecking the
data.

3.2  COMBINING ERROR TERMS
     All of the error terms discussed thus far are indepen-
dent; at least there are no obvious reasons why they should
not be independent.  Therefore, the total bias in the visual
determination of opacity is the algebraic sum of the biases
of the individual terms.  The variance of the observational
data is the sum of the variances of the individual error
terms;
                               3-6

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                                                   Section 3.3
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 1 of 3
                     2    2^2,2,      ^2
                    OT = a1 + a 2 + a3 +	   an *

3.3  PRECISION ESTIMATES
     The variability will be larger when the measurements to
be compared are performed by different observers than when
they are carried out by a single observer performing repli-
cates.  Many different measures of variability are conceiv-
able according to the circumstances under which the measure-
ments are performed.  Only two situations will be discussed
here.  They are as follows:
     1.   Repeatability, r, is the value below which the
          absolute difference between duplicate results,
          i.e., two observations made on the same plume
          by the same observer over a short interval of
          time, may be expected to fall with a 95-percent
          probability.
     2.   Reproducibility, R, is the value below which the
          absolute difference between the observations
          made on the same plume by different observers
          may be expected to fall with a 95-percent prob-
          ability.
     The above definitions are based on a statistical model,
according to which each observation is the sum of three
components:
                         0 = 5 + b + e                 (2)
where
      0 = the measured value, percent opacity,
      O = the true average, percent opacity,
      b = an error representing the differences between
          observers, percent opacity,
      e = a random error occurring in each observation,
          percent opacity.
                               3-7

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                                                    Section 3.3
                                                    Revision No.  0
                                                    Date:   November 1975
                                                    Page 2  of 3
In general, b can be considered as the sum

                         b = b  + b                     (3)
                              •L    O

where b  is a random component and b  a systematic component.
The term b is considered to be constant during any series of
observations performed under repeatability conditions,  but to
behave as a random variate in a series of observations  per-
formed under reproducibility conditions.  Its variance  will
be denoted as
                         var b = OT ,                    (4)
                                  LI
the observer bias variance.
     The term e represents a random error occurring  in  each
measurement.  Its variance
                                  2
                         var e = a                      (5)
will be called the repeatability variance.
     For the above model, the repeatability, r, and  the
reproducibility, R, are give^n by

                    r = 1.96. /2~ o  = 2.77 a            (6)

and
                    R = 2.77  Jo2 +  a2 =  2.77  a_.       (7)
                              » r    LI          s\
       2
where a_. will be referred to as the  reproducibility  variance.
       K
Using the data available from a collaborative  study  (ref.  3)
the reproducibility standard deviation,  o  ,  is taken to  be
                                         K
3.46 percent opacity.  The  repeatability standard  deviation,
a , is assumed to be 2.0 percent opacity.  The repeatability
and reproducibility can be  calculated with these values  as
follows:
               r =  (2.77) (2.0) = 5.54 percent  opacity  (8)
                                3-8

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                                                   Section  3.3

                                                   Revision No.  0

                                                   Date:  November  1975

                                                   Page  3 of 3
and


               R= (2.77) (3.46) = 6.79 percent opacity. (9)


                                                       2
     Using the same data, the observer bias variance, a , is
                                                       LI

assumed to be 1.99.  When compared with the value of the

                                            2
within-observer or repeatability variance, a  = 4.0, the


observer bias variance makes up only a small portion of the


composite between observer or reproducibility variance,

 222
o=a  + a .  Hence the major sources of error are not
 K    r    LI

items 8, 9, and 10 above, but rather the other sources of


error which can be more readily controlled as discussed above.
                               3-9

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                        References
                        Revision No.  0
                        Date: November  1975
                        Page  1 of 3
REFERENCES

-------
                                                   References
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 2 of 3
                     LIST OF REFERENCES
 1.   Philip R. Sticksel, Editor, Instructor's and Operator's
     Manual for Evaluation of Visible Emissions for State and
     Local Air Pollution Inspectors, EPA Contract No. CPA
     70-175; Environmental Protection Agency, Air Pollution
     Control Office,  Institute of Air Pollution Training,
     Research Triangle Park, North Carolina; 1971.

 2.   Rober* Missen and Arnold Stein, Guidelines for Evaluation
     of Visible Emissions, EPA Contract No. 68-02-1390, Task
     Order No. 2; U.S. Environmental Protection Agency, Office
     of Enforcement,  Office of General Enforcement, Washington,
     D.C.; April  1975.

 3.   Henry F. Hamil,  Richard E. Thomas, and Nollie F. Swynnerton,
     Evaluation and Collaborative Study of Method for Visual
     Determination of Opacity of Emissions from Stationary
     Sources, EPA Contract No. 68-02-0626; Environmental
     Protection Agency, Research Triangle Park, North Carolina;
     January 1975.

 4.   William D. Connor and J. Raymond Hodkinson, Optical
     Properties and Visual Effects of Smoke-stack Plumes;
     Office of Air Programs, Publication Number AP-30;
     Environmental Protection Agency, Research Triangle Park,
     North Carolina;  Revised May 1972.

 5.   Pamela Giblin, "Opacity as a Readily Enforceable Standard,"
     paper presented  at 65th Annual Meeting of the Air Pollution
     Control Association, Miami Beach, Florida; June 1972.

 6.   Norman E. Edmisten, Geoffrey Stevens, and Dennis P. Holzschuh,
     "Effective Enforcement Through Opacity Provisions," paper
     presented at 75th National Meeting of the American Institute
     of Chemical  Engineers, Detroit, Michigan; June 1973.

 7.   Melvin I. Weisburd, Field Operations and Enforcement
     Manual for Air Pollution Control, Volume I:  Organization
     and  Basic Procedures;  EPA Contract Number CPA 70-122;
     Environmental Protection Agency, Office of Air Programs,
     Stationary Source Pollution Control Programs, Research
     Triangle Park, North Carolina; August 1972.

 8.   A. H. Bowker and H. P. Goode, Sampling Inspection by
     Variables, McGraw-Hill, New York; 1952.

 9.   A.  Hald,  Statistical  Theory with  Engineering Applications,
     John Wiley  and  Sons,  New York;  1952.

10.   D.  B.  Owen,  "Variables Sampling Plans Based on the Normal
     Distribution,"  Technometrics  9, No.  3; August  1967.


                            R-2

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                                                    References
                                                    Revision No.O
                                                    Date:   November 1975
                                                    Page 3 of 3


11.    Philip R.  Bevington,  Data Reduction and Error Analysis for
      the Physical Sciences,  McGraw-Hill, New York; 1969.

12.    D.  C.  Baird, Experimentation:  An Introduction to Measurement
      Theory and Experiment Design,  Prentice-Hall,  New Jersey; 1962.

13.    EPA Response to Remand Ordered by U.S.  Court  of Appeals
      for the District of Columbia in Portland Cement Association
      v.  Rickelshaus (486 F.  2d 375, June 29, 1973), Environmental
      Protection Agency,  Office of Air and Waste Management,
      Office of Air Quality Planning and Standards, Research
      Triangle Park, North Carolina; November 1974.
                            R-3

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                        Appendix A
                        Revision No. 0
                        Date:  November 1975
                        Page 1 of 3
APPENDIX A
       A-l

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                                                   Appendix A
                                                   Revision No.  0
                                                   Date:   November 1975
                                                   Page 2 of 3
                          APPENDIX A
                     GLOSSARY OF SYMBOLS
This is a glossary of the symbols used in this document.

Symbols used and defined in the reference method (section

5.8.1)  are not repeated here.

m     Number of readings in a given run.

0.    Opacity value measured by the observer when the jth
 -1    reading is taken.
0     Opacity value recorded by the transmissometer recorder
  j   at the jth reading during a certification test.

0 .   Average opacity value calculated from the auditor's
 ai   data for the jth run.

d.    Difference in the audit average opacity value and
 3    the value determined by the observer for the jth
      run.
S     Summation of the d. Vcilue for the three runs per
 1    audit.             D

d.    Average of the differences d. for the ith audit.
N     Lot size, ie., the number of field observations to
      be treated as a group..
n     Sample size for the auditing period.
Sy    Summation of d. values; for the n audits under assess-
      ment.         1
d     Bias of the field observations for a given lot or
      auditing period.
S-    Intermediate summation used in the calculation of
      Sd.'

S-T    Estimated standard deviation of the average of the
  i   differences between O. and 0
                            J      ^ •

a,    Between-observer standard deviation computed from
      collaborative test data.
a.    Standard deviation of the differences computed from
      collaborative test data.
L     Lower quality limit used in sampling by variables.

U     Upper quality limit used in sampling by variables.
L     Lower quality limit value calculated from audit data.
 c
U     Upper quality limit value calculated from audit data.
 C
                              A-2

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                                                   Appendix A
                                                   Revision No. 0
                                                   Date:  November 1975
                                                   Page 3 of 3
k     Constant used in sampling by variables.
P     Percent of differences outside of specified limits
i      L and U.
LCL   Lower control limit of quality control chart.
UCL   Upper control limit of a quality control chart.
   2
a     Total variance of the observational data.
r     Repeatability.
R     Reproducibility.
b     Error representing the differences between observers
e     Random error occurring in each observation.
b     Random component of b.
b     Systematic component of b.
 s
OT 2   Observer bias variance, also denoted by var b, cal-
      culated from collaborative test data.
o  2   Repeatability variance, also denoted by var e, cal-
      culated from collaborative test data.
aR   Reproducibility standard deviation calculated  from
      collaborative test data.
o     Repeatability standard deviation calculated from
      collaborative test data.
a     Reproducibility variance calculated from collaborative
      test data.
                               A-3

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                         Appendix B
                         Revision No.  0
                         Date:   November 1975
                         Page 1  of 2
APPENDIX B
    B-l

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                                                   Appendix B
                                                   Revision No.  0
                                                   Date:   November 1975
                                                   Page 2 of 2
                          APPENDIX B
                      GLOSSARY OF TERMS
The following glossary lists and defines the technical and
statistical terms as used in this document.
Bias


Duplicate
results

Lot


Observation
Quality
audit

Quality
control
check

Precision
Reading
Repeatabil-
ity

Reproduc-
ibility
Run
The systematic or nonrandom component of
system error.

The results from two observations made on
the same plume by the same observer.

A specified number of objects to be speci-
fied as a group.

A run or series of runs of visual determina-
tions made at a given source during a single
visit.

A management tool for independently assessing
data quality•

Checks made by training school personnel or
observers on certain items of equipment and
procedures to assure data of good quality.

A measure of mutual agreement among individual
measurements of the same opacity under pre-
scribed similar conditions and expressed in
terms of the standard deviation .
A single instantaneous glance at the plume
for the purpose of making a determination
of plume opacity.
The value below which the absolute difference
between duplicate results may be expected to
fall with a 95-percent probability^

The value below which the absolute difference
between the observations made on the same
plume by different observers may be expected
to fall within a 95-percent probability.

A series of consecutive readings from which an
average opacity can be determined.
                               B-2

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 1/16/76

 EPA-650/4-74-0051
 Guidelines for Development of a Quality Assurance
 Program:  Visual Determination of  Opacity  Emission
 from Stationary Sources
 ;  \,- '> •"
 P. Wohlschlegel, D. E. Wagoner
           .^November 1975
 Research Triangle  Institute
 P.O. Box 12194
 Research Triangle  Park, North Carolina   27709
             1HA327
           rr~i >' • i •. '.•.' "v.-
             62-02-1234
 Office of Research and Development
 U.S. Environmental Protection Agency
 Washington, D. C.  20460
       Guidelines for the quality control of  opacity  determination  by  the  Federal
 reference method are presented.  These  include:

       1.  Good operating practices.

       2.  Directions on how  to assess performance  and  to  quality data.

       3.  Directions on how  to identify trouble  and  to improve  data quality.

       4.  Directions to permit design of auditing  activities.

       The document is not a  research report.   It is  designed  for use  by operating
 personnel.
i Quality assurance
I Quality control
i Air pollution
! Stack gases
• Unlimited
Unclassified

Unclassified
                             13H
                             14D
                             13B
                             21B
95
                                           C-l

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