EPA-450/2-74-006
SEPTEMBER 1974
            SYSTEMS AND COSTS
TO CONTROL HYDROCARBON EMISSIONS
       FROM STATIONARY SOURCES
        U.S. ENVIRONMENTAL PROTECTION AGENCY
           Office of Air and Waste Management
        Office of Air Quality Planning and Standards
        Research Triangle Park, North Carolina 27711

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                                    EPA-450/2-74-006
           SYSTEMS AND  COSTS
                      TO
CONTROL  HYDROCARBON  EMISSIONS
                     FROM
         STATIONARY SOURCES
    EMISSION STANDARDS AM) ENGINEERING DIMSIOIN
      U.S. ENVIRONMENTAL PROTECTION AGENCY
          Office of Air and Waste Management
      Office of Air Quality Planning and Standards
      Research Triangle Park, North Carolina 27711
                  September 1974

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The EPA-450/2 series of reports is issued by the Office of Air Quality
Planning and Standards, Office of Air and Waste Management, U.S.
Environmental Protection Agency, to report technical data of interest
to a limited number of readers. Copies of these reports are available
free of charge to Federal employees, current contractors and grantee;s ,
and non-profit organizations - as  supplies permit - from the Air Pollu-
tion Technical Information Center, U.S. Environmental Protection
Agency, Research Triangle Park, North Carolina 27711  or may  be
obtained, for a nominal cost, from the National Technical Information
Service, 525 Port Royal Road,  Springfield, Virginia 22151.
        Office of Air Quality Planning and Standards
             Publication No. EPA-450/2-74-006

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                                   CONTENTS
                                                          Page
Summary                                                     1
Introduction                                                3
Organic Solvent Usage
     Degreasing                                             5
     Dry Cleaning                                           9
     Graphic Arts                                          13
     Surface Coatings                                      17
Petroleum Refining and Marketing '
     Petroleum Refineries                                  21
     Petroleum Product Liquid Storage                      23
     Gasoline Distribution                                 26
Petrochemical Manufacture
     Carbon Black                                          32
     Acrylonitrile                                         34
     Formaldehyde                                          36
     Ethylene Dichloride                                   39
                                     n i

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                    TABLES OF EMISSIONS AND ECONOMICS

                                                                Page

Table 1 - Hydrocarbon Emissions from Stationary Sources           3

Table 2 - Degreaser Control Costs                                 7

Table 3 - Solvent Emissions from Typical Dry Cleaning Plant      10

Table 4 - Estimated Emissions from Various Types of Printing     15
          Plants
Table 5 - Emissions Control Costs in the Graphic Arts Industry   16

Table 6 - Investments - Floating Roof vs. Fixed Roof Tanks       24

Table 7 - Control Costs for Retrofiting Fixed Roof Tanks to
          Covered Floating Roofs                                 25

Table 8 - Hydrocarbon Emissions from an Uncontrolled Gasoline
          Distribution System                                    27

Table 9 - Control Costs per Service Station Dispensing
          25,000 Gal/month of Gasoline                           29

Table 10 - Estimated Emissions from a 200 Million Pounds per
           Year Acrylonitrile Plant                              34

Table 11 - Emissions from an Uncontrolled 100 Million Pounds
           Per Year Formaldehyde Plant                           37

Table 12 - Emissions from an Uncontrolled 700 Million Pounds
           Per Year Ethylene Dichloride Plant                    39
                                      IV

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SUMMARY
     Organic solvent usage has  been  identified  as  a major  source  of  hydrocarbon
emissions.   However, the technical  information  necessary to  evaluate many  of
the emission control systems  that could  be  employed 1n  this  area,  or their
emission control  costs,  is marginal  or completely  lacking  in most cases.   For
example, it is  evident that the adoption of water-based coatings  would
significantly reduce emissions  from  industrial  surface  coatings operations.
However, neither  the extent to  which water-based coatings  could be used  in
place of organic  solvent-based  coatings, nor the costs  associated with
converting  large  surface coating operations to  the use  of  these coatings,  is
known.  Furthermore, the time tables necessary  for industrial  conversion are
not known,  nor is the impact on small  job operators known.   The same is  true
in the graphic  arts industry.  While adoption of a regulation  patterned
after the LAC-APCD Rule  66, will accelerate development of reformulated
surface coatings  and emission control  technques for smaller  operations such
as degreasing,  an assessment at this time of the impact of such a regulation
on the national level is not possible.  Consequently, various  alternative
regulations, more stringent than Rule 66, will  be  quite difficult to justify.
     Another area of concern is gasoline distribution and  marketing.  In this
area, while most  of the  technology is well  demonstrated and  generally  available,
some is still under development.  Consequently, control of this source should  be
implemented in two phases.  Phase I  would reduce hydrocarbon emissions by  about
55 percent, by controlling emissions during gasoline  loading into tank trucks  and
trailers and during gasoline deliveries  to  service stations.  Although a number
of problems such  as demonstration of safe wintertime  operation of vapor  recovery
units and adaptability and scale down of these  units  to small  loading  racks
remain to be resolved, this should not delay rapid implementation of this  phase.
                                  1

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Phase II, control of emissions during the refueling of automobiles, would
reduce hydrocarbon emissions by an additional 30 to 35 percent, but is far
more complex than Phase I.  Many basic technical problems such as successful
design of a tight-fit gasoline dispensing nozzle, standardization of automobile
fuel tank fill pipes, and establishing the reliability and safety of small
vapor recovery units at gasoline service stations remain to be resolved.

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INTRODUCTION
     Table 1 summarizes the major stationary sources of hydrocarbon emissions
which have been identified.
                               Table 1
             Hydrocarbon Emissions from Stationary Sources
      Source                                   Range of Emissions

Organic Solvents Usage                       (10  tons/year)
   Degreasing                                 0.6 - 0.9
   Dry Cleaning                               0.3 - 0.4
   Graphic Arts                               0.2 - 0.3
   Surface Coatings                           3.0 - 4.0
Petroleum Refining and Marketing              3.6 - 4.0
Chemical Industries                           1.0 - 1.4

     Industrial surface coating operations and architectural  coating applications,
are estimated to contribute equally to the emissions from surface coatings shown
in Table 1.  Petroleum refining and marketing, which represents one of
the largest emission sources, includes three subsource categories.   These
are petroleum refining (excluding petroleum storage), petroleum storage
and gasoline distribution and marketing.
     A major study is currently in progress to identify emissions and available
control techniques within the petrochemical Industry.  Screening studies of 40
petrochemical processes indicate that 30 of these processes emit about 600,000
tons per year of hydrocarbons.  In-depth studies have been completed on processes
for the manufacture of carbon black, acrylonitrile, formaldehyde and ethylene
                                                                      3

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dlchloride.  The manufacture of these four petrochemicals accounts for about
40 percent of the 600,000 tons per year of hydrocarbon emissions which have
been identified.  The emission control  systems to limit these emissions and
the costs associated with these systems are reviewed in this report.

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DEGREASING
     Degreasing is  a  term broadly  applied to the use of various organic solvents
to dissolve and remove grease and  soils  from metal objects.  If the solvent
is near or at room  temperature,  the  process is termed "cold solvent cleaning";
if the solvent 1s maintained at  its  boiling point, the process is referred
to as "vapor degreasing".  Vapor degreaslng accounts for most of the solvent
emissions from this source category.
     Most vapor degreasers consist of an open tank equipped with a liquid
heater, a vapor zone above the liquid surface, and a narrow water-cooled
jacket (chiller) near the top of the tank to restrict the vapor zone.  A
free board area extends beyond the vapor zone and this also restricts vapor
emissions to some extent.  A hood  is normally Installed above the degreaser
to collect and discharge the solvent vapors which escape to the atmosphere.
     When cool metal  objects are lowered into a vapor degreaser, solvent
vapors condense on  the metal surfaces until the metal reaches the vapor
temperature.  Soils such as dirt,  metal  cutting fines and grease are washed
off the metal objects by the condensing  vapors and drop back into the tank.
Emissions
     The vapor escape rate from  an open  top degreaser is estimated to be
                                  2                  2
in the range of 0.5 to 1.0 Ib/hr-ft   of  open tank area.   Vapor emissions
are accelerated by  air currents  passing  over the open or partially open
degreaser, by opening the lid if the degreaser has one, by spraying the
articles with solvent, and moving  the articles in and out of the degreaser.
However, there is little data available  on various types of degreasers
to estimate typical hydrocarbon  emission factors.

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Control  Systems and Costs                             ^
     Most emission control  techniques  for degreasers  attempt  to  prevent
hydrocarbon emissions from the tank through improved  operating techniques,
rather than control the exhaust gases.   This includes instrumentation  to
prevent excessive overboil  in the degreaser by temperature controllers and
interlock systems to prevent operation of the unit if there is not  adequate
coolant flow through the cooler jacket.  These techniques have been cited
                                                           3
as capable of reducing emissions by about 20 to 30 percent.  The use  of
a refrigerated cooling jacket is cited as capable of reducing emissions by
about 10 percent and if tank lids are  installed, it is estimated that
                                             3
emissions can be reduced by about 50 percent.
     The solvents primarily used within the industry are trichloroethylene,
perch!oroethylene and 1,1,1 trichloroethane.  The industry prefers tri-
chloroethylene in lieu of 1, 1, 1 trichloroethane.  In the presence of
moisture, 1,1,1 trichloroethane can  hydrolyze to hydrochloric  acid which
can harm the products being degreased.
     Emission control costs are summarized in Table 2 for three  alternatives.
These costs are based on an open tank vapor degreaser operating  40  hours
per week with uncontrolled  emissions of 660 pounds per week  of  trichloro-
                                        p
ethylene (16.5 Ibs/hr or 0.825 Ibs/hr-ft ).   In Case 1, the degreaser
is fitted with temperature  control instrumentation and operated  according to

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procedures recommended  by the  solvent manufacturer.  This reduces solvent
                         2
emissions to 0.5 Ib/hr-ft  and results  1n  a  net annual  savings.  In Case 2,
the degreaser is fitted with temperature control  instrumentation and refri-
gerated cooling coils  around the  top of the  vessel.  This case also shows
a net annual savings due to the value of the recovered  solvent.  Case  3
is based on the best practical control, carbon adsorption, which achieves
a 90 percent reduction  in emissions.  Although many  existing degreasers
could probably not be adequately  vented to capture all  of the evaporated
solvent, Case 3 assumes that no ventilation  problems exist.  It should
be noted however, that not many plants  would find it economically feasible
to make the large investment necessary  for carbon adsorption (relative to
the basic investment necessary for the  degreaser),  if other alternatives
to degreasing were available.
                               Table  2
                        Degreaser Control  Cost
Control Equipment
          ,3,4
          ; Cor
plus Good Operation
                             Case V
                        Temperature Controls
  Case 23'4
  Case 1 plus
Case 3^
Carbon
Refrigerated Coils   Adsorption
Emissions to ~
Atmosphere Ib/hr-ft
Capital Costa ($)
Net Annual Cost
or (Savings) ($/yr)

0.50
300

(1,428)

0.41
3000

(1,070)

0.08
19,500

620
          a  The basic degreaser unit cost is about $2,000.

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Rules and Regulations
     In some State Implementation Plans (SIP's)  proposed by the States
and EPA, degreasing operations have been isolated from other organic
solvents usage.  A number of SIPs permit only perch!oroethylene or saturated
halogenated hydrocarbons to be used in degreasing.  This bans the use of
trichloroethylene, regardless of the control  efficiencies that could be
achieved.

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DRY CLEANING
     Most industrial  dry cleaners  use  either  petroleum  solvents, which
are referred to as "Stoddard"  solvents or,  perchloroethylene, which  is
referred to as "Perc".   Stoddard solvents are flammable mixtures of  paraffins,
cycloparaffins, and aromatics, while Perc is  a non-flammable chemical.
Solvent consumption is  not indicative  of the  tonnages of  fabrics dry-
cleaned by each solvent.  Since Stoddard solvent  has a  value of $0.25 per
gallon and Perc has a value of $1.39 per gallon,  economic incentives have
prompted the development of systems for the recovery of Perc, but  not for
Stoddard solvents.
     Emissions inventory data  on dry cleaning operations, with a reasonable
breakdown of fabric tonnages cleaned by each  solvent, and the size dis-
tribution of dry cleaning establishments is lacking.  Preliminary  estimates
indicate a 55/45 split  between Perc and Stoddard  usage  in terms of the
fabric tonnages cleaned, but this  has  not been validated.  It is doubtful
however, if many new plants using  Stoddard  solvents will  be constructed
in the future, since most Stoddard solvents have  a minimum flash point of
100°F.  For safety reasons, a  number of local zoning commissions and
insurance underwriters  are prohibiting the  use of Stoddard solvents.
     In a typical dry cleaning plant using  Stoddard solvents, the  washer
and drier are usually separate pieces  of equipment.  The  solvent extracted
by centrifuging in the  washer is  filtered and reclaimed by vacuum  distillation.
The muck remaining, which contains unrecovered solvent, is disposed  of by
whatever means are available.   The solvent  remaining  in the clothing is
sent to a drier, evaporated and exhausted to  the  atmosphere.

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     Dry cleaning plants utilizing perch!oroethylene normally unitize the
cycle by combining the washing and drying in one piece of equipment.   While
this may reduce dry cleaning thruput per unit, a greater control  over
perch!oroethylene consumption 1s possible.  Perchloroethylene extracted
after washing is filtered and recovered by distillation.  In addition,
cookers are normally operated to recover solvent from the filter muck.
Emissions
     Solvent emissions from a typical uncontrolled industrial dry cleaning
plant with a 50 pound washer handling 500 pounds of fabric per day are
shown in Table 3.  The Stoddard plant is a washer-extractor (cold transfer)
type equipped with a regenerative filter and the Perc plant is a conventional
utilized system (dry to dry) equipped with a distillation still, regenerative
filter, cooker and condenser.
                                Table 3
              Solvent Emissions From Typical Dry Cleaning Plants

Solvent                            Stoddard          Perchloroethylene

Emissions to Atmosphere, Ibs/day
    Evaporated at Tumbler               95                 14
Other Loses, Ibs/day
    Retained in Filter Muck             25                 22
    Retained in Still Residue             5                  8
Total Loses, Ibs/day                  125                 44
10

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Control Systems and Costs

     The value of Perc makes its recovery economically attractive.   A

number of manufacturers offer packaged carbon adsorption systems, which

permit recovery of essentially all  the Perc not recovered by condensers

on the distillation still and muck cooker.

     A carbon adsorption system for the Perc dry cleaning plant presented

in Table 3 would cost about $1,400.   Perc emissions would be reduced by

about 98 percent and the value of the recovered solvent would offset the

annual costs for this equipment.   Thus, installation and operations of the

adsorber would impose no increased costs on the dry cleaning plant.

     Control of solvent emissions from a dry cleaning plant using Stoddard

solvent is not as straightforward.   Carbon adsorption, which could  probably

reduce emissions by about 90 percent, appears to be the logical emission

control technique.  However, the low value of Stoddard solvent makes the

economics of recovery unattractive except for large plants.  In addition,

the physical properties of Stoddard solvents make them more difficult to

adsorb  and desorb than Perc.  Consequently, carbon adsorption systems

have not been applied to small Stoddard dry cleaning plants of the  size

shown in Table 3.  For a Stoddard dry cleaning plant about four times the

size of the plant shown in Table 3, one manufacturer has estimated  the
                                                                 o
capital costs for a carbon absorption system to be about $17,000.    After

taking credit for the recovered solvent, the annual emission control costs,

based on a one shift operation, would be about $2,100 or approximately
                                              Q
$0.22 per pound of Stoddard solvent recovered.

     Substitution of perch!oroethylene for Stoddard solvent may be  impractical

at many existing plants because of equipment differences.  Perch!oroethylene
                                                                          11

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is corrosive under various conditions and cannot be handled in Stoddard
washers and driers which are designed for non-corrosive solvents.  This
means that essentially all of the equipment in a conventional Stoddard
dry cleaning plant might have to be replaced if Perc were substituted.
                                                               o
Preliminary estimates of this cost are about $30,000 per plant.   Furthermore,
the dry cleaning associations have indicated that perchloroethylene can-
not be used to dry clean all fabrics.
Rules and Regulations
     Rule 66 of the LAC-APCD exempts perchloroethylene from control and
allows the use of Stoddard solvent without control if its aromatics content
is less than 8 percent and emissions do not exceed 3000 Ibs. per day.
Variations of this rule appear in many State Implementation Plans and recent
EPA proposals.  However, this approach of exempting perchloroethylene and
Stoddard solvents from control, has come under question by the Chemistry
and Physics Laboratory (ORM, NERC, Research Triangle Park, N. C.).  Recent data
gathered from smog chamber experiments indicates that both Stoddard solvents
and perchloroethylene are photochemically "reactive."
12

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GRAPHIC ARTS
     Commercial  printing within the graphic  arts  industry refers to the
following printing processes:   lithography;  letterpress; gravure;  flexography
and screen.   The solvents used in the various  ink formulations  are a  source
of hydrocarbon emissions.  Heat set inks,  such as those used  in lithography
and letterpress printing, generally contain  30 to 40  percent  solvent.
Gravure, flexographic and screen inks however, generally contain 55 to  75
percent solvent.
     Lithography is the fastest growing segment of the commercial  printing
industry.  The lithographic process transfers  ink from an  image plate to
a rubber surface, which in turn transfers  the  ink to  the surface being
printed.  The non-image area on the image  plate is essentially  at the same
level as the image area.  However, the non-image  area is wet  by water
only, while the image area is wet by ink.  Lithography is  widely used
for printing newspapers, magazines, and books. In addition,  most all
metal decorating operations have adopted lithography.
     In the letterpress printing process,  the  ink is  transferred directly
to the material being printed by the image plate.  The image  area of  the
plate is raised relative to the non-image  area and only the image area
is wet with ink.  Letterpress printing was the major  printing process
employed within the commercial printing industry  until recently.  In
the last few years, the use of letter press  printing  has declined, while
the use of lithography has increased.  Letterpress printing is  still  widely
used however, to print newspapers, magazines and  periodicals.
     Gravure printing is widely used to print  newspapers and  advertising
                                                                         13

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supplements and catalogs,  and various  packaging  materials  such  as  gift
wrap and labels.  In this  type of printing,  the  Image area on the  Image
plate 1s recessed relative to the non-Image  area.   As Ink  1s transferred
to the image plate, it 1s  picked up by a "doctor blade".   The Image plate
is then used to transfer ink directly  to the surface of the material  being
printed.
     Flexography is essentially a letterpress process employing rubber
image plates.  Although the flexographlc process is widely used to print
packaging materials, its major use is  1n the printing of paper-back
"pocket" books.  Most all  paper-back "pocket" books are now printed by
flexography.
     Screen printing represents one of the smallest segments  of the printing
industry.  It is however,  employed extensively 1n the specialized  area of
printing paper and cardboard signs, posters, and displays.  Although not
normally considered as part of the commercial printing industry, a rapidly
growing application of screen printing 1s 1n the production of microcircuits.
The  image area  in screen printing, is  a fine screen through which  ink can
be forced.  Non-image areas are produced by coating or impregnating the
screen with a wax to prevent the flow of ink through that portion  of the screen.
Emissions
     Emissions  vary considerably from one printing job to the next and are
dependent on the solvent content of the ink used, press operating  speed,
and  ink coverage.  Presses do not normally operate continuously and may be
idle for considerable periods of time during plate changing, press repair,
and  slack periods of work.  Although emissions are difficult to estimate,
a  range of  emissions is presented in Table 4 for the various types of  printing
operations.

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                                Table  4
                                                                    910
           Estimated Emissions from Various  Types  of  Printing  Plants' '
                                                     1970  Percent  of
Process	Ibs/hr	Market  Sales	
Gravure (Roto)               50 - 250                    6.6
Flexography (heatset inks)     2 -  15                    4.3
Lithography
Web offset
Metal decorating
Letterpress (heatset inks)
Screen printing
4
4
2

- 25
- 5
- 15
low
51.0
—
35.5
2.6
Control  Systems and Costs
     Incineration is the most commonly employed control  technique  for
reducing emissions from commercial  printing operations.   Although  incineration
can be applied to all printing processes, it is more adaptable to  those
processes which use ovens to evaporate the solvent from  the ink.   If the
inks used in the process are free from materials which could poison or form
a coating on the various catalysts  employed, both catalytic and thermal  incin-
eration is effective.
     Adsorption can be employed as  an emission control technique to some
extent.   Normally, adsorption is practical only where solvent emissions have
not been partially oxidized.  Consequently, it is generally not adaptable to
driers or ovens.  Most applications of adsorption have been in gravure
printing, where large amounts of solvent are emitted.
                                                                     15

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     Emission control  costs  for reducing  ink  solvent  emissions  from
lithographic and letterpress printing  operations,  based  on  incineration
of the drying oven off-gases, are summarized  1n  Table 5.  Although these
costs are considered typical, the wide range  of  conditions  which  exist within
the commercial printing industry could result in substantial  deviations from
these costs for specific installations.   The  costs for the  web  offset
lithographic process and the letterpress  process,  reflect incineration of
the emissions from one drying oven.  The  costs for the metal  decorating
lithographic process,  reflect incineration of the  emissions from  two ovens.
                                Table  5
              Emissions Control Costs in the Graphic Arts Industry
                                                                  11
Process
 Web Offset  Lithography/
 Letterpress
              Metal  Decorating
              Lithography
Emissions
(Ibs of carbon/hr)
Gas volume (scfm)
Control Device
Operating time
(hr/yr)
Capital Cost ($)
Annual Cost ($/yr)
5
5,000
Thermal
Incinerator
1,300
31 ,000
13,500


Catalytic
Incinerator
1,820
50,000
12,900
40
10,000
Thermal
Incinerator
4,160
48,000
55,200


Catalytic
Incinerator
4,160
70,000
27,100
Annual Cost per pound
carbon removed (S/lb)
2.08
1.98
0.33
0.16
 16

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INDUSTRIAL SURFACE  COATINGS
     Industrial  surface  coatings  refers  to  the application of protective or
decorative coatings.   Frequently, the  coating 1s an organic solvent-based
paint,  which is  applied  by a  spray gun 1n a  paint  spray  booth.  The freshly
painted surface  is  then  dried in  an oven where the solvent which normally
comprises about  60  percent of the paint  volume, is evaporated.  The size of
paint spray operations ranges from as  low as one gallon  per day, to as high
as several hundred  gallons per day. According to  the  1967 Department of
Commerce census, industrial  users consume about two-thirds of the paint
manufactured in  the United States.
Emissions
     Insurance regulations require that paint spray booths be vented to the
atmosphere to prevent the build-up of  solvent vapor concentrations within
                                                                   2
the enclosure  to more than  25 percent of the lower explosive limit.
Consequently, paint spray booths  are normally ventilated at a rate of
                                               2
100 to 150 fpm per  square foot of booth opening.   Aerosols resulting from
overspray in the spray booth, are removed by filters and water  washers, to
prevent their release to the atmosphere. However, these devices normally
have little effect  on solvent vapors.   Although paint  spray booths are a
source of hydrocarbon emissions,  the quantity of  these emissions depends
primarly on the degree of overspray within  the  booth,  which can vary from
                                                            2
as little as 5 to 10 percent, to  as much as 80  to  90  percent.   Normally
however, the degree of overspray  in the paint spray  booth is kept relatively
low and the drying  ovens are the  major source of  hydrocarbon emissions.
Control Systems and Costs
     Incineration of the solvent  vapors contained  in  the exhaust gases from
                                                                       17

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the paint spray booths and the drying ovens,  is  the control  technique  normally
employed to limit emissions from industrial  paint spraying operations.   The
costs of incineration are a funciton of the  gas  volume and small  paint spraying
operations would probably experience emission control  costs similar to those shown
for the graphic arts industry in the previous section.  Many surface
coating operations however, exhaust much larger  volumes and the emission
control costs would be greater.  For example, the capital  cost for an
incinerator on both the paint spray booths and the drying  ovens of a large
paint spray line emitting about 45 pounds of solvent per hour, is estimated
                               12
to be in the range of $400,000.    In general however, data to estimate
annualized costs for both large and small paint spray operations are lacking.
     Currently, within the domestic paint manufacturing industry, a great
deal of effort is being devoted to the development of new paint formulations
which require limited amounts of hydrocarbon solvents.  While some of these
new formulations can be used for certain coating applications, a number
of limitations prevent them from being used  for all applications.  However,
their use is rapidly increasing within the industry and if faced with the
alternative of incineration, the use of these new formulations is expected
to accelerate.
     Water-based paints have been used for many years as architectural
coatings and some manufacturers currently dip-coat and flow-coat parts with
these paints.  The use of water-based paints can result in a major decrease
in hydrocarbon solvent emissions.  If auto bodies are primed by electrodeposition
for example, where the paint formula  is about 90 percent solids and 10 percent
                                                                            13
water, emissions are reduced by about 90 percent over conventional spraying.

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Converting to the electrodeposition  process  however, requires completely
scrapping existing paint spraying  equipment  and  Involves a  large capital
investment in new equipment.   Elaborate  washing  systems and surface
preparation systems are required,  in addition  to the basic  electrodeposition
equipment.  Color change is Impractical  during assembly-line operation and
the coated surface normally has  a  dull appearance which does not meet the
gloss standards necessary on  many  products.  Consequently,  electrodeposition
can be used only for primer coats  1n most applications.
     Although finish coats of high gloss appearance can not be applied by
electrodeposition, the application of water-based paints for finished coatings
by spraying shows promise.  The  General  Motors assembly plant in Los Angeles  is
converting to a water-based paint  spray  system.   Complete conversion is
                        13
expected by August 1974.    Since  water  evaporation rate is critical to the
surface appearance, complex drying ovens and air conditioning equipment are
being installed and as a result, power requirements may increase as much as
50 percent at this plant.
     In assessing the technical  availability of  water-based paint  spray
systems for applying finish coats  of high gloss  appearance, it must be kept
in mind that this General Motors assembly plant  in Los Angeles is  the first
major installation to attempt the  use of water-based paints for finish coats.
Consequently, until the plant has  started up and resolved the problems
that may arise, the use of water-based paint spray systems  to apply finish
coats must be considered as currently under  development for most applications.
     Powder coatings are applied by  electrostatic spraying  of fluidized
bed techniques.  The.coated objects  are  then heated to about 450°F.  This
                                                                        19

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melts the powder into a solid surface film.   Most powder coatings  consist  of
various plastics such as vinyls,  acrylics,  polyesters,  epoxies,  nylons
and butrates.  The application of coatings  in this manner reduced  hydro-
carbon emissions by more than 90  percent, compared with conventional  solvent-
based coatings.  One drawback however, is the high baking temperature.
This prevents preliminary assembly of plastic or rubber parts  prior to  coating.
While most powder coatings lack the weather resistence of conventional  paints,
they do excel! on parts which are not exposed to the outdoors  and  where orange
peel effects are not objectionable.  Although powder coatings  are  finding
use in some specific applications, water-based coating are generally considered
to be more acceptable for wide-spread application than powder  coatings
at present.  As the technology of powder coatings is developed however,
they are expected to replace both water-based and conventional hydrocarbon
solvent based coatings, as a result of lower investment costs  due  to a  smaller
oven and shorter process line, lower fuel costs for drying and baking,
                                                                          12
lower labor costs, and lower paint loss because overspray can  be recycled.
     It is apparent, however, that the surface coatings area definitely needs
a great deal of further study to determine the most feasible methods of
control.   Incineration can be viewed as the most straight forward method of
control.  The high investment costs for incineration equipment and the
demand for large quantities of fuel however, make it an unattractive choice
in many cases.  In general, there  is a serious lack of data available on
investments, costs and time required to retrofit in this area, which make
it difficult to develop compliance schedules and determine cost effectiveness.
20

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PETROLEUM REFINERIES
General
     There are literally hundreds  of sources  of hydrocarbon  emissions
in a modern petroleum refining complex,  exclusive of the emissions  from
product storage and distribution.   Prominent  among these sources  are waste
water collection and disposal  systems, blowdown systems, catalyst regenerators,
compressors, pumps, valves, vacuum jets, asphalt air blowing,  and process
heaters and boilers.  Although recent efforts have been directed  toward
identifying emission levels from a number of  these sources,  emissions will
vary widely from refinery to refinery.   In addition, wide variations are
possible within a specific refinery depending on the mechanical condition
of critical items of equipment, as well  as differences  in operating conditions.
     The emission control systems  that could  be used to reduce emissions
from many of these sources are well demonstrated and should  be an integral
part of any new refinery design and construction.  Retrofit  of many of these
control systems in existing refineries with a few exceptions,  should be
relatively simple and require minimal lead times.  However,  with  the
exception of carbon monoxide boilers, which are primarily used to reduce
carbon monoxide emissions from fluid catalytic cracking unit catalyst
regenerators, the data is not available  to estimate installation  costs
and control effectiveness of these systems.
     Plans for new refinery construction merit careful  review and existing
refineries merit careful inspection to determine the adequacy of  emission
control equipment and in particular, the maintenance practices of the
operator.  For example, the collection and disposal of volatile hydrocarbons
                                                                       21

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emitted from waste-water collection and disposal equipment, can be
accomplished by sealing the sewers and junction boxes and venting the vapors
to an  incinerator.  Hydrocarbon emissions can be reduced from centrifugal
pumps  by the use of mechanical seals rather than soft packing (rubber, leather,
etc.)  to prevent leakage.  Hydrocarbon emissions from vacuum jets, which
are  commonly used on crude oil vacuum distillation towers, can be collected
and  incinerated in process heaters and boilers, or sent to sulfur recovery
units  if the sulfur dioxide or hydrogen sulfide content of the non-condensibles
is appreciable.  These few examples illustrate the need for careful review
and  inspection.
22

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Petroleum Product Liquid Storage
     Evaporative emissions  of hydrocarbons  from  storage  tanks occur
in all  phases of the petroleum Industry,  from production of  crude  oil
through final storage of finished products  in the  distribution and
marketing system.  As a result of legislative enactments and economic
incentives in some cases, the industry has  achieved  a  reasonable degree
of control over hydrocarbons emissions from storage  tanks.   Most studies
report that conservation measures are currently  practiced on about 75
percent of the liquid hydrocarbon storage capacity in  the petroleum
industry.  Nevertheless, it has been estimated that  national emissions
from petroleum product storage could be reduced  by 50  percent 1f present
control practices were extended to the remaining uncontrolled tankage.
Emissions
     Hydrocarbon emissions  from storage tanks depend essentially on  three
basic mechanisms:  breathing loss, working loss, and standing storage  loss.
Breathing and working losses are associated with cone  or fixed roof
tanks, variable vapor space tanks, and low pressure  tanks.   Standing storage
losses are generally associated with floating roof tanks. The magnitude
of emissions depends on factors such as the physical properties of the
material being stored, climatic conditions, and  the  size, type, control,
and condition of the storage tank.  An addendum  to the second edition  of
the EPA publication "Compilation of A1r Pollutant  Emission Factors",
(AP-42, April 1973), is being published which will provide guidance  to
local control agencies in estimating hydrocarbon emissions from various types
of tankage storing numerous products under varying conditions.
                                                                       23

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Control  Systems and Costs
     The emission control  system commonly employed within  the  Industry  to
meet various State and local  regulations  which  Hm1t  emissions  from  hydrocarbon
storage facilities, is the "floating roof" tank.  This  tank  1s  generally
acceptable up to hydrocarbon  vapor pressures  under actual  storage  conditions,
of 11.0 - 12.0 psia.  Beyond  this range,  more effective measures are
necessary.  These normally consist of pressure  tanks  equipped  with emergency
relief valves, which prevent  emissions to the atmosphere under normal
conditions, or vapor recovery systems. Vapor recovery  systems  may afford
a somewhat higher degree of control than  the  floating roof,  if compressors
are spared.  Capital and operating costs  for  vapor recovery  systems  are
normally considerably higher  than either  pressure tanks or "floating
roof" tanks.  However, the necessary data to  make reasonable cost  comparisons
are lacking.
     Due to wide-spread adoption of the "floating roof" tank within  the
industry, investment costs and costs effectiveness for  this  type of
liquid hydrocarbon storage will be considered.   Investment costs are
presented in Table 6.
                              Table 6
                                                              14
               Investments - Floating Roof vs. Fixed  Roof Tanks

Cost to Retrofit
Tank Size
Diameter
in feet
20
40
60
90
no

Normal
Capacity
bblsa
1,100
9,000
22,000
54,000
80,000
Fixed
Covered
Floating
Roof
$17,000
$26,000
$42,000
$53,000
Roof to:
Internal
Floating
Cover
$2,800
$6,500
$12,000
$22,000
$40,000
A Cost for New Construction
Floating
roof type vs
External Covered
Pontoon Floating
Floating Roof Roof
+ $20,000
+ $25,000
+ $27,000
n.a.
+ $17,000
+ $23,000
+ $33,000
. Fixed roof
Internal
Floating
Cover
$ 2,800
$ 7,000
+$12,000
+$24,000
--
       a 42 gals/bbl
 24

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     Construction considerations usually dictate that internal  floating  covers
be used for small size tanks and covered floating roofs  for  intermediate size
tanks.  Extremely large tanks usually use the external type  of  floating  roof,
either double-deck or single-deck pontoon.
     The emission control  costs associated with storing  a  high  volatility
material such as gasoline and a low volatility material  such as jet naphtha,
in floating-roof tanks rather than fixed-roof tanks,  are shown  in Table  7.
                               Table 7
              Control Costs for Retrofitting Fixed Roof  Tanks
                           to Covered Floating Roofs

Product                       Gasoline                  Jet  Naphtha

Tank Size (103 bbls)       1.1        22    80       1.1      50      80

Investment Floating
vs. Fixed (103$)           2.8      26.0  53.0       2.8     26.0   53.0

Annual 1 zed Cost3
(103$)                    (0.2)    (1.9)  (15.0)     0.3      2.4    2.8
Cost per gallon
thruput-
-------
Gasoline Distribution
     A typical  gasoline distribution  pattern  consists of delivery by
pipeline, barge, or tanker to Intermediate storage,  then by  pipeline or
barge to bulk terminals.  From the bulk terminal,  the gasoline  is delivered
by tank truck or trailer to the service station  or to a bulk plant and then
by tank truck or trailer to the service station.  At the service station,
the gasoline is transferred from the  tank trucks into underground storage
tanks which are vented to the atmosphere.  Automobiles are refueled from
the underground tanks via the service station pump island.
Emissions
     In uncontrolled bulk terminal tank truck loading operations, service
station deliveries and automobile refueling,  the vapors displaced by the
gasoline are normally released directly to the atmosphere.   The amount of
hydrocarbons which are contained in these vapors Is  highly variable depending
on the manner 1n which the tank truck is loaded at the  terminal; the amount
of gasoline contained in the vapors carried by the returning truck; the
manner in which the gasoline is delivered to the service  station; operator
practice in automobile refueling; and a number of  other factors such as
physical properties of the gasoline;  geographical  and seasonal  effects;
and meteorological conditions.
     To estimate the emissions and control costs associated  with  reducing
hydrocarbon emissions from gasoline distribution,  a  hypothetical  gasoline
marketing system has been examined.  This consists of:   300  gasoline  service
                               •>"-v
stations each dispensing 250,000 gallons per day and 15 tank trucks  equipped
with top loading to service the service stations.   Emissions from this
 26

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distribution and marketing system under normal  summer operating conditions
are shown in Table 8.

                              Table 8
        Hydrocarbon Emissions from an Uncontrolled  Gasoline

Loading loss
Tank Truck Delivery
Breathing loss
Diurnal Loss
Subtotal
Automobile
Refuel ing
Total
Distribution System3
300 Service Stations15
25,000 gal /month per station
103lbs/yr gals per 103
gals handled

671 1 .44
77 0.17
neg.
748 1 .61
675 1 .44
1,423 3.05
Bulk Terminal16
250,000 gal /day
103lbs/yr gals per 103
gals loaded

520 1.1 Ob
520 1.10
520 1.10
     Excludes tankage evaporative losses from bulk plant and terminal
     Submerged loading.
Control Systems and Costs
     Achieving a substantial  reduction in emissions throughout the gasoline
distribution system requires  emission controls at gasoline service stations.
This in turn requires vapor recovery during tank truck loading at bulk plants
and terminals.  The most "feasible" approach for reducing emissions by 85
to 90 percent is as follows:
                                                                     27

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Phase I (55 percent control-short range):
1.   Modify tank trucks and Install  the necessary equipment  at  service
     stations to recycle the vapors  displaced from the  underground  storage
     tanks at service stations back  to the tank truck during gasoline delivery.
2.   Install vapor recovery systems  to collect and recover the  vapors
     collected at the service station, as they are displaced from the tank
     truck during reloading at bulk  plants and terminals.
Phase II (30 to 35 percent control-long range):
1.   Install special gasoline dispensing nozzles, hoses and  vapor return
     lines on the gasoline pumps at  the service stations to  collect and
     return vapors displaced from the automobile fuel tank during refueling,
     to the underground storage tanks at the service station.
2.   Install vapor recovery equipment on the underground storage tanks  at the
     service station if necessary, to achieve an overall reduction in  emissions
     of 90 percent at the service station.
     Capital investments, annual costs, and cost effectiveness, on a per
station basis are summarized in Table 9.  These estimates are based on
retrofit, since the number of existing service stations and  loading racks
far outnumber anticipated new construction.
28

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                              Table 9

             Control  Costs per Service Station Dispensing15'17'18'19
                      25,000 Gal/month of Gasoline
Phase I (55 Percent Reduction 1n Emissions)
Investment($)

Emission Reduction
Recycle Vapor
To Tank Truck

   1,073
Vapor Recovery        Phase I
at Bulk Terminal      Total

        783           1,856
(lbs/yr)
(gal/yr)
Annual Cost
($/yr)
($/lb recovered)
U/gal pumped)
1,933
372

97
0.05
0.03
1,733
334

70
0.04
0.02
3,666
706

167
0.045
0.055
Phase II (35 Percent Reduction 1n Emissions)
Investment ($)

Emission Reduction
   (Ibs/yr)
   (gal/yr)

Annual Cost
   ($/yr)
   ($/lb recovered)
   U/gal pumped)
              Carbon
              Canister

               6,090
               2,300
                 443
               1,298
                0.56
                0.43
                Refrigeration-
                Condensation

                  12,678
                   2,300
                     443
                   2,693
                    1.17
                    0.89
                                                                        29

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                         Table 9 (cont.)

Phase I + II (90 Percent Reduction In Emissions
Investment ($)

Emission Reduction
   (Ibs/yr)
   (gal/yr)

Annual Cost
   ($/yr)
   ($/lb recovered)
   U/gal pumped)
Carbon Canister

   7,946
   5,966
   1,149
   1,465
    0.24
    0.48
Refrigeration-Condensation

   14,534
    5,966
    1,149
    2,860
     0.48
     0.95
 30

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     The quality of the Phase I investment data and emission control
efficiencies are considered "moderate".  Recycle of the vapors displaced
from the underground storage tanks at the service station, to the
tank truck during gasoline delivery, 1s feasible and has been demonstrated.
Vapor recovery systems to collect and recover the vapors displaced from
the tank trucks at bulk terminals during reloading, have proven feasible
during warm weather operations.  However, operability and safety in cold
weather conditions are still in question.  Nevertheless, Phase I could be
implemented at this time.
     The quality of the Phase II data should be considered "questionable".
Investments would be much.lower if a simple displacement vapor collection
and recycle system could be made to work successfully during automotive
refueling, without requiring the installation of vapor recovery facilities.
The use of carbon canisters or refrigeration-condensation techniques, are
two alternative approaches for vapor recovery and vendors of this equipment
are limited.  Special vapor collection and return nozzles, to effect a tight-
fit between the gasoline dispensing nozzle and the automobile fuel tank
fill pipe, are required and these are still in the development stage.  With
many existing vehicles and available nozzle designs a tight-fit is not
possible because of location or design of the automobile fuel tank fill pipe.
Vacuum-assist, which could be used to overcome some of the disadvantages of
a lack of tight-fit between the nozzle and the automobile fill pipe, has
been identified by the industry as a possible explosive hazard.
                                                                       31

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PETROCHEMICALS
Carbon Black
     Most of the carbon black produced 1n  the United  States  Is  produced
                                    20
by the furnace process (83 percent).     Although the  thermal  process  and
the channel  process are also used,  they account for only a small  amount
                                                                              20
of the total carbon black production  (14 percent and  3  percent,  respectively).
The thermal  process however, is not a major source of emissions  and the
channel process is viewed as obsolete within the industry.   Consequently,
the furnace process is of most concern in terms of pollutant emissions.
     In this process, natural gas and heavy oil are introduced  into a furnace
with a limited amount of air.  A combination of cracking and combustion
occurs, which leads to the production of carbon.  The hot gases from  the
furnace are cooled and passed through bag filters in  which the  carbon is
collected.  The gases are then normally discharged directly to  the atmosphere,
although in some cases, the waste gases are combusted before release  to
the atmosphere.
Emissions
     The production of carbon black by the furnace process can  be a major
source of emissions.  It has been estimated for example, that about 14,000
pounds per  hour of carbon monoxide and 700 pounds per hour of various
hydrocarbons could be emitted to the atmosphere from an uncontrolled carbon
black plant producing 90 million pounds of carbon black a year, using the
,               20
furnace  process.
Control  Systems and Costs
     Waste  heat boilers,  thermal incinerators  or catalytic incinerators
                                                        20
could  be used  to  reduce emissions  by about 100 percent.    Plume burners
32

-------
which are a type of flare,  are somewhat less efficient,  although they could
                                                20
be used to reduce emissions by about 90 percent.     Only one carbon  black
plant in the United States  uses an Incinerator waste heat boiler,  although
                                        20
several are equipped with plume burners.
     The most effective emission control  technique for a new plant would be
the use of a thermal incinerator or a waste heat boiler.  No supplemental
or auxiliary fuel would be  required 1n either case.   Heat recovered  in a
waste heat boiler could be  used to preheat the Incoming  gas and to generate
the steam necessary to operate the plant.   Although flame control  could be
difficult in some cases, flameouts could be prevented if adequate burner
controls were provided.  For a new 90 million Ibs/yr carbon black plant
using the furnace process,  the installation of a waste-heat boiler would
                                                  20
increase the capital Investment by about $720,000.    However,  the waste-
heat boiler would have a net operating savings of $10,500 per year,  due
                                   20
to the credit for steam generation.
     A plume burner would actually be more costly and less effective.
Although the initial capital Investment would only be increased by about
                                                                20
$150,000, the net capital costs would be about $33,000 per year.    This is
                                                          20
equivalent to an increase of 0.04<£/lb 1n production costs.
                                                                        33

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 Acrylonitrile
      The  use of the Sohio propylene ammoxidation process 1s universal within
                                                      pi
 the  United  States for the production of acrylonitrile.    Vaporized
 propylene and ammonia are mixed with air and steam and Introduced into
 a  catalytic reactor.  The gaseous reaction products are withdrawn and
 processed through a countercurrent absorber where the acrylonitrile is
 absorbed  in water.  The gases are then vented directly to the atmosphere
 in many cases.  The aqueous acrylonitrile solution is fractionated to
 recover the acrylonitrile.
 Emissions
      The  production of acrylonitrile can be a major source of emissions of
 carbon monoxide and various hydrocarbons.  Table 10 summarizes.- the estimated
 emissions released to the atmosphere from an uncontrolled acrylonitrile
 plant producing 200 million pounds of acrylonitrile per year.
                              Table 10
                                                                            21
   Estimated Emissions from a  200 Million Pounds per Year Acrylonitrile Plant
                Carbon Monoxide               3,000 Ibs/hr
                Propane and Propylene         1,400 Ibs/hr
                Hydrogen Cyanide                 10 Ibs/hr
                Acrylonitrile                   10 Ibs/hr
                Acetonitrile                    160 Ibs/hr
 Control Systems and Costs
      Waste  heat boilers, thermal  incinerators or catalytic incinerators
                                                                   21
 could be  used  to  reduce  hydrocarbon emissions by about  100 percent.
34

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Plume burners are generally considered to be less efficient, although it
                                                                  21
is estimated that they could reduce emissions by about 90 percent.     None
of the acrylonitrile plants in the United States currently operate  any control
                             21
equipment to limit emissions.    However, waste-heat boilers, thermal incinerators,
catalytic incinerators and plume burners are in use on similar processes
and could be installed at acrylonitrile plants.
     A large amount of steam is produced in most acrylonitrile plants, con-
sequently, most of the steam that could be produced in an incinerator-
waste heat boiler used to reduce emissions, would have to be exported.
The heating value of the pollutant concentrations in the waste gases  is
normally quite low and a supplemental or auxiliary fuel would have  to be
used to achieve complete  combustion.  This method of emission control for
a typical 200 million Ibs/yr acrylonitrile plant would cost about $115,000,
                                               21
assuming a steam credit of 75<£/thousand pounds. .
     Probably the most feasible emission control device is a thermal  incinerator.
Although a small amount of supplemental fuel would be required, heat  could
be recovered to preheat the propylene, ammonia and combustion air introduced
into the acrylonitrile reactor.  An incinerator for a typical 200 million
Ibs/yr acrylonitrile plant could cost about $350,000 initially and  would
                                                         pi
have a total net annual operating cost of about $135,000.
                                                                     35

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Formaldehyde
     All the formaldehyde produced 1n the United States  is  manufactured  by
                                                            22
two methods, both of which use methanol  as the raw material.     The first
uses an iron-oxide catalyst and a large  excess of air.   The second uses  a
silver catalyst and requires only about  one-eighth as much  air as the
iron-oxide process.  In both methods, the formaldehyde  is produced in a
reactor and then absorbed from the exit  gases by a water scrubber.  The
scrubber off-gases are normally vented directly to the  atmosphere.  The
formaldehyde is marketed as a water solution, although  it is purified
before sale.
     About 22 percent of the domestic formaldehyde production is based on
                                                                        22
the iron-oxide process and about 78 percent based on the silver process.
Emissions
     The release of the absorber off-gases directly to  the atmosphere is
the primary source of emissions associated with the production of formaldehyde.
In a plant using an iron-oxide catalyst, the composition of these off-gases
may vary considerably, depending on the  degree to which they are recycled
within the plant.  Most of the iron-oxide plants currently operating however,
                             22
operate with maximum recycle.    In a plant using a silver catalyst, the
recycle of absorber off-gases is not general practice,  since it offers no
advantages to the operator as it does in a plant using an iron-oxide catalyst.
     Estimated emission rates from an uncontrolled formaldehyde plant
producing 100 million Ibs/yr of formaldehyde as a 37 percent aqueous
solution, are presented in Table 11.  The emissions from the plant using an
iron-oxide catalyst are based on maximum recycle of the absorber off-gases.
36

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                                Table 11
                                                                        22
    Emissions from an Uncontrolled 100 Million Ibs/yr Formaldehyde  Plant
                                    Iron-oxide Catalyst     Silver  Catalyst
Formaldehyde (Ibs/hr)                         5                  10
Methanol  (Ibs/hr)                            20                  30
Dimethyl  Ether                               10
Hydrogen  (Ibs/yr)                            --                  120
Carbon Monoxide (Ibs/hr)                      --                  60
Control Systems and Costs
     Thermal incineration of the absorber off-gases 1s the most feasible
method of reducing emissions from formaldehyde plants which use an  Iron-
oxide catalyst.  Although some auxiliary fuel 1s required to ensure complete
combustion, there is normally not enough heat released to make steam  generation
attractive.  A plume burner could be used rather than a thermal Incinerator,
but would be somewhat less efficient 1n reducing emissions.  A water  scrubber
could also be used to remove about 95 percent of the formaldehyde and
methanol  from the absorber off-gases, however, none of the dimethyl ether
                 22
would be removed.
     One iron-oxide formaldehyde plant currently operating 1n the United States,
employs a water scrubber to reduce emissions from the absorber.  None however,
use thermal incinerators, although this 1s not due to any technical problems
which might prevent their use.  The use of an Incinerator at a 100  mill ion
Ib/yr iron-oxide formaldehyde plant would cost about $44,000 initially and
the operating cost would be about $35,000 per year.
     The most feasible method of reducing emissions from formaldehyde plants
which employ a silver catalyst, would be to combust the absorber off-gases
                                                                       37

-------
in the utility boilers associated with  the  formaldehyde  plant, or chemical
complex.   The absorber off-gases  from the silver  process have a much  higher
heating value than those from the 1ron-ox1de  process  and could be combusted
without auxilliary fuel.  However, because  of the relatively small volume
of gases the installation of a separate waste-heat boiler 1s not practical.
This approach would cost about $45,000  Initially, to  make the necessary
modifications to the utility boilers, but would show  a net operating
                                 22
savings of about $3,000 per year.
     The use of a plume burner would be less  costly initially, requiring
                                22
an outlay of only about $20,000.     However,  the  net  operating cost would
be about $5,500 per year.
38

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Ethylene Dichloride

     In 1970 about 55 percent of all  ethylene  dlchlorlde was  produced
                               23
by oxychlorination of ethylene.     The remaining  45  percent was  produced
                            23
by chlorlnation of ethylene.     However,  the ethylene  chlorlnation process

is relatively unpolluting compared  to the oxychlorination  process and

therefore is not of major interest  here.

     In the oxychlorination process,  ethylene, air and hydrochloric

acid are introduced into a reactor.  In the presence of a  catalyst,

these materials react to yield ethylene dlchlorlde.  The ethylene dichloride

is absorbed from the reactor effluent gases and the  gases  are normally

vented directly to the atmosphere.

     There are a number of variations 1n  the basic oxychlorination process.

Although one plant uses oxygen rather than air 1n the  reactor,  the

reaction sections are similar.  The ethylene dlchlorlde recovery systems,

however, vary significantly from plant to plant and  thus emissions to

the atmosphere vary from plant to plant.

Emissions

     Estimated emissions from a typical uncontrolled oxychlorination plant

producing 700 million Ibs/yr of ethylene  dichloride  are summarized in

Table 12.

                                Table 12
                                                                            00
   Emissions  from  an  Uncontrolled 700 Million  Ib/yr Ethylene Dichloride Plant

     Carbon Monoxide                        600  Ibs/hr
     Methane                                 500  Ibs/yr
     Ethylene                               400  Ibs/hr
     Ethane                                  600  Ibs/hr
     Ethylene Dichloride                     600  Ibs/hr
     Ethylene Chloride                       500  Ibs/hr
                                                                       39

-------
Control  Systems and Costs
     Incineration with or without steam generation  or  heat  recovery,
followed by a water or dilute caustic scrubber would reduce hydrocarbon
                                              po
(and chlorine) emissions by about 100 percent.   However,  none  of  the
oxychlorination plants currently operating,  use incineration to  reduce
emissions.  Heat recovery or steam generation from  incineration  would be
difficult because of the corrosive nature of the  hydrochloric acid  formed.
     The installation of a waste heat boiler and  caustic scrubber in a
typical  700 million Ibs/yr plant would cost about $900,000  initially, and
                                                         23
the net operating costs would be about $300,000 per year.    The use of a
thermal  incinerator and scrubber would only cost about $63,000 initially,
                                                                 23
however, the net operating cost would be about $400,000 per year.    It
should be noted that due to the corrosive environment  existing in the
waste heat boiler or incinerator, special alloy materials might be  required
and these estimated costs could be 1n error by a considerable margin.
  40

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                               References
 1.   Hydrocarbon  Pollutant Systems Study; EPA Contract No. EHSD 71-12; MSA
     Research  Corporation; Evans City, Pennsylvania; Volume 1; October, 1972.

 2.   Air Pollution  Engineering Manual; Second Edition, AP-40; May, 1973.

 3.   Meeting between  EPA  and  Hooker Chemical Company; E. G. Richardson
     (Hooker),  J. Wllkenfeld  (Hooker), R. K. Burr  (EPA), D. P. Armstrong (EPA),
     R.  C.  Clark  (EPA), and P. A. Boys (EPA); Durham, North Carolina;
     August 6,  1973.

 4.   E.  G.  Richardson (Hooker Chemical Company) In telephone conversation to
     Paul  Boys  (EPA), August  8, 1973.

 5.   D.  Larson  (V1c)  and  C. Gorman (V1c); V1c Manufacturing Company; Trip
     Report by G. R.  Stevens  (EPA) on visit to V1c Manufacturing Company,
     Minneapolis, Minnesota (August 6, 1971); August 16, 1971.

 6.   Effect of Environmental  Control on Dry Cleaning Plants; Paper presented
     at  the International Fabricare Institute and  Laundry and Cleaners
     Allied Trades  Association, Incorporated, R. T. Walsh (EPA) and R. K. Burr
     (EPA); November  7, 1973.

 7.   National  Institute of Dry Cleaning; Technical Bulletin No. T-472;
     Silver Springs,  Maryland; June, 1971.

 8.   Letter from  C. Gorman (V1c) to R. K. Burr (EPA); Vic Manufacturing Company;
     Minneapolis, Minnesota;  June 25, 1973.

 9.   Evaluation of  Emissions  and Control Technologies in the Graphic Arts
     Industries;  EPA  Contract No. CPA 22-69-72; Graphic Arts Technical
     Foundation;  August,  1970.

10.   Evaluation of  Emissions  and Control Technologies 1n the Graphic Arts
     Industries,  Phase II:  Web-Offset and Metal Decorating Processes; EPA
     Contract No. 68-02-001;  Graphic Arts Technical Foundation; May, 1973.

11.   EPA estimates  based  primarly on A1r Pollution Control Engineering and
     Cost Study of  the Paint  and Varnish Industry; EPA Contract No. 68-02-0259;
     Air Resources, Incorporated; (Draft Report).

12.   R.  K.  Anderson and D. N. Hunder; The Economics of Powder Coatings;
     Paper No.  FC 73-543; Presented at the 1973 SME meeting, Dearborn, Michigan.

13.   H.  W.  Schiller (GM)  and  N. C. Kachman (GM); General Motors Corporation;
     Trip Report  by R.  B. Atherton (EPA) on visit  to the South Gate GM assembly
     plant, South Gate, California (July 12, 1973); August 8, 1973.
                                                                      41

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14.  Letter from R.  K.  Burr  (EPA)  to  Mrs.  Betty Perkins  (Environmental
     Improvement Agency,  Sante  Fe,  New Mexico), November 17, 1972.

15.  Cost Effectiveness of Methods  to Control Vehicle Refueling Emissions;
     API Project EF-14; Phase I  -  Interium Report; April, 1973.

16.  Procedures for  Estimating  Evaporation and Handling  Losses; API Publication
     4080; July, 1971.

17.  R.  J. Meyer (Humble); Personal Communication with R. K. Burr  (EPA);
     Humble Oil and  Refining Company, Houston, Texas; November 3,  1971.

18.  H.  F. Klein (SOCAL); Personal  Communication with R'. K. Burr  (EPA);
     Standard Oil Company of California  -  Western Operations; San  Francico,
     California; May 31,  1973.

19.  R.  A. Nichols (Parker-Hannifin); Personal Communication with  R.  K. Burr
     (EPA); Parker-Hannifin  - Fueling Division; Irvin, California, May 22, 1973.

20.  Carbon Black Manufacture by the  Furnace  Process  (Draft Report);  EPA
     Contract No. 68-02-0255; Houdry  Division of Air  Products and  Chemicals,
     Incorporated; January,  1973.

21.  Acrylonitrile Manufacture (Draft Report); EPA Contract No. 68-02-0255;
     Houdry Division of Air  Products  and Chemicals, Incorporation,
     February, 1973.

22.  Formaldehyde Production (Draft Report);  EPA Contract No. 68-02-0255;
     Houdry Division of Air  Products  and Chemicals, Incorporated,  June, 1973.

23.  Ethylene Dichloride  Manufacture  (Draft  Report);  EPA Contract No.
     68-02-0255; Houdry Division of Air  Products and  Chemicals, Incorporated;
     May, 1973.
 42

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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1 RhPORT NO 2.
EPA-450/2-74-006
4 I ITLE AND SUBTITLE
Systems and Costs to Control Hydrocarbon E
from Stationary Sources
7 AliTHORlS)
9 PERFORMING ORGANIZATION NAME AND ADDRESS
Environmental Protection Agency
Office of Air Quality Planning and Standard
Research Triangle Park, North Carolina 277
12 SPONSQRINp AGENCY NAME AND ADDBESS „
U. S. Environmental Protection Agency
Research Triangle Park, North Carolina 277
3. RECIPIENT'S ACCESSION-NO.
5 REPORT DATE
7)1551005 ^ptpmhpr 1Q74
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
^ 11. CONTRACT/GRANT NO.
n
13. TYPE OF REPORT AND PERIOD COVERED
I 14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16 ABSTRACT
Costs associated with techniques for controlling hydrocarbon emissions
from certain important stationary sources are discussed. Sources
discussed include organic solvent usage, petroleum refining and marketing,
and certain petrochemical manufacturing operations.
17. KEY WORDS AND DOCUMENT ANALYSIS
a DESCRIPTORS
Air pollution control equipment
Hydrocarbons, Petroleum Refining
Coatings Carbon Black
Dry Cleaning Degreasing
13 DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group

19. SECURITY CLASS (This Report) 21. NO. OF PAGES
unclassified 47
20. SECURITY CLASS (This page) 22. PRICE
unclassified
EPA Form 2220-1 (9-73)
                                                                                                                    43

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