905R80011
                        U.S. Environmental Protection Agency
                                      Region V
                           Environmental Services Division
                               Eastern District Office

                 Great Miami River Dilution and Exposure Risk Study


I.  General Description
   The Great Miami River Dilution Study was conducted to determine the water quality
impact  of the  heavy concentration  of  industrial  and  municipal dischargers  in the
Middletown, Ohio area.  The study area extended from Middletown to Hamilton, Ohio with
special consideration to the impact of Dick's Creek (Figure 1).  Water, sediment, and fish
samples were collected to determine the effect of major dischargers on stream conditions.
An additional fish sample was collected near the mouth of Great Miami River to assess
the potential exposure/risk to toxic pollutants from upstream sources.

   B. Sampling Date

      September 24-25, 1980

   C. Participants

      U.S. EPA - EDO

          Charles Beier, Engineering Technician
          Joseph Good, General Mechanic
          Donald Schregardus, Engineer (author, did not participate in sampling)

   D. Study Segment Description

   The Great Miami River Basin is located in southwestern Ohio.  The basin drains an area
of 5,385 square miles of which 3950 square miles are in Ohio.  The river originates in west
central  Ohio  (Logan  County) and flows 172 miles  in  a south and southwest direction
through the cities of Dayton,  Middletown and Hamilton emptying into the Ohio River, near
the Ohio-Indiana State line (Figure 1). The study segment  from Middletown (RM  51.7) to
Hamilton  (RM 34.9) is approximately 17 miles long and includes two industrialized cities.
Figure 2  shows the  limits  of  the  study   area, sampling stations,  major  dischargers,
tributaries and USGS  gaging station.  Table 1 provides a site description,  river mile, and
latitude and longitude of each sampling station.
   The  Great Miami River has relatively high sustained flows in the study segment due to
the large  size of  the drainage area  and  partial low  flow  augmentation by upstream
reservoirs.  At the USGS gaging station in  Hamilton (RM 34.8) the average river flow is
3273 cfs with a historic range of 155 cfs to 102,000 cfs.  The seven day, ten year low flow
at the Hamilton gage is 268 cfs, however the Ohio EPA has calculated a waste load
allocation design flow of 530 cfs at the gage. The difference  is due  to flow augmentation
provided by upstream reservoirs and increases  in municipal discharge flows.   During the
survey the river flow at the gage was 1070 cfs.
   The  study segment contains two significant tributaries, Dick's  Creek and Four Mile
Creek, and several small tributaries.  Flow in Dick's  Creek is composed almost entirely of
wastewater  discharges  from the ARMCO Inc.  Middletown  Plant (four outfalls) and

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                                 FIGURE  1
   /)    H  A   R   D  I   N
   '               ~*
                                             A   U   G   L  A   I
          I.E8ENO


        CHANNEL IMPROVEMENTS


                DA3M9


        INCORPORATED AREAS


[     |  9REAT MIAMI RIVER BA8IH
GREAT MIAMI RIVER BASIN
           AND

   ADJACENT BASINS

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        Table 1
Sample  Site Description
Site
Number
1

2


3
4

5

6

Description
Great Miami River, Middletown
State Route 122
Great Miami River,
0.2 miles downstream of
Dick's Creek
Dick's Creek near mouth
Dick's Creek at Cincinnati
Dayton Road
Great Miami River, Hamilton
Peshing Avenue
Great Miami River, New Baltimore

River Mile Latitude
51.7 84°24'45"

46.5 84°25'26"


0.2 84°25'25"
5.3 84°20'32"

34.5 89°34'17"

20.9 84°40'05"

Longitude
39°31>13"

39°27'59"


39°28'15"
39°27'W

39°23'41"

39°15'47"

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 Hardings  Jones Paper Company (one outfall).  During the survey Dick's Creek was dry
 upstream of the ARMCO Inc. discharges.  Flow was not measured in Dick's Creek during
 the dilution study.  However, a  flow of 16 cfs was measured at the mouth of Dick's Creek
 during  an Ohio  EPA  intensive  survey conducted  the week  prior to the  dilution  study
 (September 16-19, 1980).
    Four Mile Creek is larger than Dick's Creek (i.e., 321  square miles versus 48 square
 miles) but has no major dischargers near the mouth.  Stream flow at the mouth  of Four
 Mile Creek during the  Ohio EPA survey was 56 cfs.

II.  Wastewater Dischargers

    There are eight major wastewater dischargers in the study area, two municipal sewage
 treatment plants, five  industrial dischargers and  one municipal steam-electric power
 plant.  A  brief description of each  facility  and  its wastewater treatment system is
 presented below. The number in parenthesis beside  the name of  the facility refers to the
 number on Figure 2.  Table 2 presents basic discharge information about the facilities.
 Current permit limitations are included in the Appendix.

    ARMCO Steel Company,  Middletown Works (1)

    The Middletown Works of  ARMCO Inc. is  a  fully integrated  steel  mill.   The plant
 manufactures iron, steel and coke and  produces hot and cold rolled steel sheets and coils.
 A small percentage  of the operations consists of making tube and applying aluminum, zinc
 and organic coatings  to coils.  The  facility discharges treated  wastewater through five
 outfalls,  the  largest going to Great  Miami River and four others discharging to Dick's
 Creek.
    Outfall 001  discharges treated wastewaters  from three separate treatment systems to
 the Great Miami River.  Wastewaters  from the blast furnace recycle  system, the  sinter
 plant, and the North Plant water softener clarifier are treated by settling,  neutralization,
 coagulation and clarification.   Wastewater generated in  metal finishing and cold rolling
 operations are  neutralized, aerated,  and clarified.   Chemicals  are added  prior  to
 clarification to improve solids removal. Boiler house scrubber water and wastewater from
 the boiler house lime softening  plant and North  Area Lime Softening plant are treated in a
 similar fashion to the  metal  finishing wastes but in a separate system.
    Outfall 002  receives  noncontact  cooling  water  from  the coke  plant.   Process
 wastewater from the  coke plant is piped to Middletown STP for  treatment.   Slowdown
 water  from the basic  oxygen furnace is used as makeup  water for the  open hearth fume
 abatement system.   Slowdown from this latter system  is  neutralized, coagulated, and
 clarified prior  to discharge  through  Outfall 003 to  Dick's Creek.  Pickle rinse water and
 cold mill rinse water are neutralized, aerated, and clarified prior to discharge to a sixteen
 acre lagoon.  The lagoon overflows through Outfall 004 to Dick's Creek.
    Outfall 005 receives intermittent  clarified blowdown from  the hot strip mill  water
 clarification  plant,  noncontact  cooling water  from  the annealing area, dewatering well
 water, and storm runoff.  Most of the clarified water from the hot strip mill treatment
 plant  is recycled to  the hot strip and slab mills.

    Middletown Sewage Treatment Plant (2)

    The Middletown STP provides secondary treatment for approximately  23  MGD. The
 facility uses  the activated sludge process with chlorination of the final  effluent.  The
 plant  receives approximately 5.5 MGD of wastewater from industrial sources primarily
 local paper plants, and ARMCO Inc. Middletown Works coke plant.

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                                            Table  2
                                       Major Dischargers
          Discharger

        Inc.,  Middle-town  Plant
                                                           Average
NPDES  Permitted
^iddletown STP


>ystal Tissue Company

-larding  Jones Paper Company

-esourdsville  STP


\RMCO Inc., New Miami Plant
Outfall
001
002
003
004
005
001
001
001
001
001
002
003
004
002
004
005
002
003
River Mile
50.6
46.8 (2.9)
46.8 (3.8)
46.8 (5.1)
46.8 (4.2)
47.5
47.2
46.8 (0.8)
44.7
38.0
38.2
38.3
38.5
36.4
36.38
36.4
36.0
36.1
Flow (MGD)
18.2
1.2
.3
1.2
1.1
23.0
2.4
1.0
1.8
7.3
.05
.3
7.0
130.5
0.14
0 (runoff)
18.6
0.5
Pollutants
Temp. ,pH,TSS,BOD,
O&G, Ee,Diss Fe,Zn
Pb,Cr ,CN, Phenol,
NH3-N
pH, Temp.
pH,TSS,Diss. Fe,Pb,
Zn, F
pH,TSS,Fe,Diss. Fe,
Zn, Chlorides
pH,T5S,O&G,Diss. Fe,
Zn
pI-^TSSjBODjNI-L-N,
Fecal Col., Cl Res.
pH,TSS,BOD,DO,Temp.
pH , DO , TSS , BOD , NH?-N
pH,TSS,BOD,NH,-N,P,
Fecal Col., Cl Res.
pH , TSS , BOD , O&G , NH3-N :
CN, Phenol, Diss. Fe, Zn
pH,TSS,BOD,NH3-N
pH
pH,TSS,O&G,NH.,-N,CN,
Phenol
pH , Temp . , Res . Cl . , Cu , Fe
pH, TSS, O&G
pH,TSS
pH,Temp.
pH,Temp.
Hamilton Municipal Power  Co.
"hampion International
1)   Effluent limits corresponding to internal monitoring points are listed opposite the outfall to which
     they discharge, see Appendix 1 for details.

2)   Values in parentheses are river miles for discharges to Dick's Creek.

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   Crystal Tissue Company (3)

   Crystal Tissue  Company  manufactures  specialty  tissue  paper products  excluding
sanitary tissue paper.  The facility purchases raw pulp and combines it with recycled stock
and Whitewater to produce paper pulp. Wastewater from the fourdrainier paper machines
(whitewater) is recycled.  Excess Whitewater, stock cleaner wastewater, and waters from
converting and cleaning the paper machines are directed to the central treatment system.
Here the  wastewater  is treated with polymers, clarified  and passed through  a  trickling
filter prior to being discharged  to the Great Miami River through Outfall 001.  Effluent
flow averages  about 2 MGD.

   Harding Jones Paper Company (4)

   Harding 3ones Paper Company manufactures about 25 ton/day of various grades of fine
writing paper from purchased pulp.  Raw materials used at  the plant  include clay, titanium
dioxide, starch and four  grades of  pulp.  Wastewater generated from  the fourdrainier
paper machine passes through an air-flotation save all with the effluent going to the waste
treatment system along with cooling water, wash water, boiler blowdown and softener
backwash. The treatment system consists  of a clarifier  followed  by  an aerated lagoon
with a 3.5 day detention time.  Nutrients are added to the wastewater before the aeration
lagoon to improve BOD removal.   The overflow  from  the lagoon,  about  1.9 MGD, is
directed  to Dick's  Creek through  Outfall 001.   Process  water  is  supplied  from  ground
water wells on the company property.

   Lesourdsville Regional Sewage Treatment Plant (5)

   Lesourdsville Regional STP provides tertiary  treatment to approximately  1.8  million
(MGD) of domestic sewage.  In  operations since  November  1977, the  plant has a design
capacity of 4.0 MGD.  Treatment is provided by preaeration tanks, primary settling tanks,
rotating biological  discs,  secondary clarifiers,  rapid  sand filters and cascade aerators.
Alum is  added to the wastewater before secondary clarification to enhance  phosphorus
removal.  The effluent is chlorinated during the summer months (May-October).

   ARMCO Steel Company, New Miami Plant (6)

   ARMCO Steel Company's, New  Miami  Plant  produces  pig  iron,  coke and coke  by-
products.  The molten  iron is shipped to ARMCO's Middletown Plant for steel production.
Wastewater from the  blast  furnace scrubber  system,  lime soda softener  and boiler
blowdown are collected and treated by chemical addition, settling  and cooling.   Most of
the treated wastewater is  recycled to the blast furnace scrubber with a small blowdown
(.7 MGD)  discharging  to Outfall 001.  Outfall 001 also receives noncontact cooling water
from the  barometric  condensers.  Sanitary  wastes from  the blast furnace area receive
biological treatment (extended aeration), clarification and chlorination before discharging
through Outfall 002 to the Great Miami River.   Coke quenching water and  noncontact
cooling water  from the coke plant are discharged untreated  through Outfall 004.  Process
wastewaters  from  the coke plant  area (ammonia liquor processing  waste, benzol yard
runoff, flare stack wastewater and sanitary wastewater) are neutralized  and treated in a
biological  treatment  plant (extended aeration and clarification) before discharging to
Outfall 004.   Outfall 003 receives  noncontact  cooling water from the compressor after-
coolers.

   Hamilton Municipal Power Plant (7)

   The Hamilton Municipal power plant produces up to 85 kw of electricity with coal fired
boilers and an additional  1.5 kw with the hydroelectric generating  equipment located on
the Hamilton  hydraulic canal. Water withdrawn from the Hamilton hydraulic canal is used

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                                   TABLE 3
                     PARAMETERS TO BE MEASURED IN SAMPLES
PRIORITY POLLUTANTS
COMPOUNDS
tr 7eMoropT.i:ool
,ro-m-crc-.ol
O'ophcnoj
chlorophcnol
ime I hyl phenol
rophcnol
rophcnol
jnitrophcnol
'imtro-o-Cresol

I

5A5H/KF.UTRAI. COMPOUNDS
^romop^l^h^l" ether
bis (2-chloroiiop/rOjOy!) ether
bis (2-cKIorocthoxy) rnethsne
hcxbchlorobutidlene
hcxiChlorocyclopentaikne
ijophorcne
naol.thaicn-
nitrobc-n7.cn:
N-nitroiodiiticthylamine

N-ni;rciodi-n-prcpv!amine
bh (2-cthylhcsv!) ohthalatt
/NEUTRAL COM POUNDS — but/' benzyl phthaiatc 	
phthcn-
cfioe
trichlorobcnzcne
hlorobcnzcner
di-n-butyS phthalatt
di-n-octy! ohtha:&te

dirne-thyl chthalat'-

hloroclhane b.-n-'ofalDvr'vi.-
ch]or&clhyl)ctrv;r
sronaphthalene
ichlorobcri7cne>
ic'f.Iof obcnzcrne
ichjorobenzcne

•bc"zo('>')'iuc'2Ttrxr'-
C-lrvicne
acTasS-'-vic"*
£n^.-ac=r.e
icMofobenzic>r>- bvnzcCsh'OocrvIc.-ic
Hnitrotolucne
JiniUoloIucnc
TipScny Ihy dra zirvs
:obcnzene)
jnthcw
lorophcnyl pncny! ct5»cr
•
li-jwcne
VOLATJLE5
^cr'c&Jo
acrylomtrili
benzene
Carbon tctrach'oricTe
ch'orobenzcnc
1,2-dichlorocthine
1,1 ,l-trich!oroc thane
l,f-dich)orocthan=
1,1 ,2-trichIoroethane
1,1 ,2,2-tctrachIoroethane
2-ch!oroetny!vinyl ether
chloroform
__ 1,1-dichIoroethylens
1 ,2-trans-dicfiIoro-thylene
] ,2-dichloropropane
I , J-dichloropropy !ene
PESTICIDES
aldrin
dicld.-in
• chlordane
'i.'/'-DDT
'(.'('-DDE
4 V-DDD
Csf -endosulfan
*G -cndosulfan
endosulfan sulfate
encirin
endrin aldshyd-
hes'.achlor
hrolachior cpoxicJ:
Ci -BMC
yO.RMC
t^^f - C' . • W
T--EHC
S -3HC
PCS-12^2
ethylbcnzens P(~n_i7s/,
methy!ene chloride
methyl chloride
PC&-1221
PCEH232
methyl bromide P^~^_i7ts
bromoform
dichlorobrofnotne thane
trichlorofluoroi net Sane
dichlor odi floor oir.tt h.ine
chlorodibromoti.ctharw
pScrs.-.nthrcrvs tctrachlorocthylenc

> r ^ \
irx;c-noU,2,3-cd)p>rene •
\

~ •* A. > i f-» *
2,3,7 ,5-^ctrach! or ocibcnzo—
9-tJictnin
tr iclilorocthylene
vinyl cfvior»<5c

Conventional Pollutants
!T'3crp-srcitur« - Water only
pH - - Water only
5total Organic Carbon - Water only
Cheaical Oaygen J>aasancl - " "
'JVital Kn«rv»n^»r« ^•O^t? ~ " "
PC5-12SO
PC&-101S
toxaphene
KET£T S/INORGANICS
•Arsenic (Total)
•ferylliia (Total)
*Ca6slu» (Total)
•Chrtatltia (Tot»l)
•Coppsr (Total)
•Cyanlda (Total)
'•tead (To til)
*Xercury (ToUl) j
•Mickel (Total) t
•Sllvsr (Total) j
•Zinc (Totil) j
                                                                                         t
                                                                                         fc~'
                                                                                         »
                                                                                         I
                                                                                         I
                                                                                         
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 for noncontact condenser cooling water and then discharged to Great Miami River through
 Outfall 002.  Low volume wastewaters (i.e., ash sluicing water, softener  regenerant, coal
 pile runoff and boiler blowdown) are discharged virtually untreated either directly to the
 Great Miami River or into the condenser cooling water prior to discharge.

    Champion International, Hamilton Mill (8)

    Champion International's  Hamilton Mill produces an average of  550  tons/day of fine
 coated and  uncoated printing paper from purchased pulp and recycled  stock.   Process
 wastewater  is collected and conveyed to the  company's wastewater treatment system and
 then to the Hamilton Municipal Sewage Treatment Plant. Noncontact cooling  water from
 the coal  fired boiler  house is  discharged  to the Great Miami River  via  Outfall 002.
 Cooling water is shock chlorinated once each week during  summer months  to prevent
 slime buildup.   Storm water runoff  and small amounts (.5 MGD) of cooling water are
 discharged untreated via Outfall 003.

III.  Sampling Procedures

    Water, sediment and  fish  samples were collected  in  the  Great Miami  River  on
 September 24-25, 1980. Grab water samples  were collected at midstream in a  wide mouth
 glass jar,  poured into individual prepreserved bottles then placed in ice chests. At the
 station downstream  of  Dick's Creek  (RM M.7) the sample  was collected by  wading out
 about fifteen feet from the east bank since  there was no bridge from which to sample.
 Sediment  samples were collected with  an Eckman dredge generally within fifty feet of the
 river banks.  Fish were collected by placing  trotlines baited  with worms in the  water on
 September 2k and picking them up the following day.  Carp were caught at the  Middletown
 and Hamilton sites and a catfish was caught at  the  New Baltimore station.  Fish were
 placed on dry ice and kept frozen until shipped to  Region V Central Regional Laboratory.
    Samples  were  analyzed for  the constituents shown in  Table 3.  Due to  a sample
 shipping error and  laboratory  mix-up water  samples  were not analyzed  for volatile
 organics and fish samples were not analyzed for metals and volatile organics.  The Eastern
 District Office laboratory analyzed water  samples for suspended  and  dissolved solids,
 conductivity, turbidity,  BOD,  cyanide  and  phenol.   The  Region V Central  Regional
 Laboratory  ran the  nutrients, inorganics, metal and volatile  organic analyses.   Organic
 analyses including acid compounds, base/neutral compounds, pesticides, and  PCBs were
 performed by a contract laboratory, California Analytical Laboratories, Inc.

IV.  Presentation of Monitoring Data

    Tables ^, 5 and  6 contain the data for water, sediment  and fish respectively.   Only
 organic compounds with positive values are tabularized.  The detection limit  for organics
 in water was 1 ug/1.

 V.  Findings and Conclusions

    Water samples collected at the three  Great Miami River sampling stations contained
 detectable concentrations of the priority  pollutants cyanide,  chromium, copper,  mercury,
 pentachlorophenol,  phenol  and bis(2-ethylhexyl) phthalate.   Dicks's  Creek contained the
 same priority  pollutants as well  as arsenic and zinc.   Of  the priority pollutants only
 mercury  concentrations in  the  Great  Miami  River  and  mercury, arsenic  and  zinc
 concentrations in Dick's Creek  exceeded the Ohio Water Quality Standards  or  the EPA
 water  quality criteria in Table 7.  Regarding mercury no source or sources were identified
 since concentrations at all sampling locations are virtually the same.  The arsenic and zinc
 found  in  Dick's Creek are likely attributable to ARMCO Inc.'s Middletown  Plant since

-------
these pollutants are found in steel plant wastes but are not found in paper mill wastes, see
Tables 8 and 9.  Also, ARMCO's Outfalls 003, 004 and 005 have permit limits for zinc.  In
evaluating  the  mercury  and  arsenic  data  it  is  important to  note that  measured
concentrations are  very  close  to the detection limit  of the  test procedures.  At  these
levels the accuracy  of the analytical procedures is plus or minus 50 to 100 percent.
   The U.S. EPA's Monitoring Branch of the Monitoring and Data Support Division (MDSD)
recently completed  an area wide study  of potential toxic pollutants in the Dayton, Ohio
area (August 26, 1980).  The  study conducted pursuant to Paragraph 12 of the revised
EPA/NRDC Settlement  agreement found that  instream  concentrations  for  16  toxic
pollutants  may  exceed water quality  criteria even after BAT is  implemented.  These
pollutants include:

                  Metal and
                  Inorganics                  Organics

                  Arsenic         Trichloromethane (chloroform)
                  Beryllium       1,1,2,2-Tetrachloroethane
                  Cadmium       Pentachlorophenol
                  Chromium
                  Copper
                  Cyanide
                  Lead
                  Mercury
                  Nickel
                  Selenium
                  Silver
                  Thallium
                  Zinc

   The study  concludes that all these constituents accept pentachlorophenol may exceed
water  quality  criteria at Middletown during low flow conditions and arsenic, beryllium,
cadmium, copper, cyanide, mercury and silver may exceed criteria at Middletown during
mean flow  conditions.  Samples collected on September 24-25, 1980 failed to confirm the
criteria exceedances  except for mercury.   Flow during the  September 1980 survey was
about  twice low flow and only one third  the  mean  annual  flow recorded at  Hamilton
(3067 cfs).  Selenium, thallium, trichloromethane and 1,1,2,2-tetrachloroethane, however,
were not analyzed in this study.
   Ohio EPA  monthly monitoring data at Hamilton, Ohio indicate cyanide, phenol, copper,
lead, and zinc concentrations ocassionaly  exceed water quality standards.  To resolve
these water quality problems  Ohio EPA initiated a  Waste Load  Allocation Study of the
Great  Miami River  Basin in the summer of 1980. The study included weekly sampling  at
fourteen stations on the Great Miami River and two intensive water quality surveys which
involved  simultaneously sampling of major dischargers, tributaries  and the Great Miami
River mainstem. The final Waste Load  Allocation Report, due out in March 1982, will set
permit limits  for conventional pollutants and  metals  for  the major dischargers  in the
basin.
   Regarding  sediments, the samples showed significant increases in metals concentra-
tions through  the study reach  (see  Table 5).  Aluminum and iron  tripled in concentration
between  sample points 1  and  2.   The priority pollutant  metals,  arsenic,  beryllium,
cadmium, copper, lead, nickel, silver and zinc  snowed increases  ranging from 50 to 300
percent in  this segment.  Between sampling points 2 and 5 arsenic, cadmium, copper, lead,
and zinc concentrations increased an additional 50 to 300 percent. These metals are  likely

-------
                                      Table  8
                              Regulated  Pollutant List
                               Iron and  Steel Industry
                                   1
                                     Effluent
                       Regulation     Limits
                        Considered  Established
                                      1
                                        Effluent
Acrylonitrile                 X
Benzene                      X
Hexachlorobenzene           X
1,1,1-Trichloroethane         X
Parachlorometacresol         X
Chloroform                   X
2-Chlorophenol               X
2,4-Dimethylphenol           X
2,4-Dinitrotoluene            X
2,6-Dinitrotoluene            X
Ethylbenzene                 X
Fluoranthene                 X
Isophorone                   X
Naphthalene                 X
2, Nitrophenol                X
4,6-Dinitro-o-cresol          X
Pentachlorophenol            X
Phenol                       X
Bis(2-ethylhexyl)phthalate    X
Butyl benzylphthalate         X
Di-n-butylphthalate           X
Di-n-octylphthalate           X
Diethylphthalate              X
Dimethylphthalate            X
Benzo(a)anthracene          X
Benzo(a)pyrene              X
Chrysene                     X
Acenaphthylene              X
Anthracene                   X
Fluorene                     X
X
X
X
                           Regulation  a   Limits
                            Considered Established
Phenathrene             X
Pyrene                  X
Tetrachloroethylene      X
Toluene                 X
Antimony               X
Arsenic                 X
Cadmium               X
Chromium               X
Copper                  X
Cyanide                 X
Lead                    X
Mercury                 X
Nickel                  X
Selenium                X
Silver                   X
Thallium                X
Zinc                    X
Xylene                  X
Aluminum               X
Ammonia               X
Dissolved Iron           X
Fluoride                 X
Hexavalent Chromium   X
Oil and Grease          X
pH                     X
Phenolic Compounds     X
Sulfide                  X
Total Suspended Solids   X
                                           X
                                           X

                                           X
                                           X

                                           X
X
X
X

X
(1)  Source:  Federal Register, Volume 26, No.4,  Wednesday,  January 7, 1981,

-------
TA1HK 9
UJMHARY OF TOXtC POLLUTANTS
OF CONCERN UY SUBCATECORY
Toxic Pol lutuntH 	
•.5 64 65 67 68 70 85 86 ~R7 106~ li)7 110 111 121 122 128
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SOURCE: Development Document for Effluent Limitations
Guidelines and Standards for the Pulp, Paper
and Paperboard and the Builders' Paper and
Board Mills Point Source Categories, Proposed
EPA440/l-80/025b, November 1980
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 discharged by ARMCO Inc.'s Middle-town Plant and  Middletown STP in the upstream
 segment  and the ARMCO Inc.  New  Miami  Plant  in  the  downstream segment.  Metal
 discharges from the remaining dischargers are insignificant.
    In addition to metals,  the sediment samples contained twenty-two organic compounds
 on the priority  pollutant list.   While most of these constituents  remained  relatively
 constant through the study reaches.  Chrysene, benzo(a)pyrene, pyrene and  trichloro-
 rnethane (chloroform) concentrations increased at  least 50 percent.   These organics are
 found  in  discharges  from steel making operations (see  Table 9).   PCB (arclor  1254)
 concentrations drop 50 percent through the study reach suggesting there are PCB sources
 upstream of Middletown.
    Fish samples were collected at both  ends of the study segment and at New Baltimore
 approximately  14 miles  downstream of Hamilton.   Results  of the  organic  analyses
 (Table 6) show the fish contain the priority pollutants phenol, phthalates and PCB.  While
 the phenol concentrations may  be  high  enough to affect the taste and smell  of fish,
 measured values are well below toxicity criteria (3.5 mg/1).  Regarding PCBs, the fish  at
 the downstream site contained one  half  as much PCBs as  were found in  the fish at the
 other two sites.  While the concentrations are  significant all values are  below the FDA
 action level of  5.0  mg/1.   Phthalates  are  likely  a  result  of  field  or  laboratory
 contamination.
    In addition to the fish  collected in this study, Ohio EPA collected  fish at seven sites  on
 the Great Miami River for PCB analysis by the U.S.  EPA Laboratory in Duluth, Minnesota.
 Fish were collected with  electro-shocking equipment from September  through November
 1980.  Results of the  study (Table 10) confirm the  presence of  PCBs in fish in  the Great
 Miami River.  At three of the  seven sites PCB  concentrations  exceeded the FDA action
 level.  The results of the two studies can not be  directly compared since the types of fish
 caught were different.   However,  the data  indicate PCB levels  in fish  are a potential
 problem  in the Great Miami River.

VI.  Conclusions and Recommendations

    Results  from this study indicate mercury  and PCB's  are potential problems in the
 Great Miami River although they are  not necessarily  attributable to  dischargers in the
 study  segment.   Regarding mercury  additional fish  samples should be collected and
 analyzed to  assess the bioaccumulation of mercury in fish.  Also, a review  should be made
 of the hazardous waste  permit applications from industrial  facilities in  the basin  to
 determine where mercury is being  used, stored, or disposed.  Additional water quality
 sampling may be necessary to find the source or sources of mercury.
    A review of  PCB sales records from  Monsanto showed the following companies in the
 Dayton/Middletown area have purchased  large quantities of PCBs.

                  ARMCO, Inc.                          Middletown
                  Dayton Malleable                      Dayton
                  Dayton Forging and Heat Treating      Dayton
                  Chrysler Corporation                   Dayton
                  GHR Foundry - Division of              Dayton
                   Dayton Malleable
                  Champion Paper                       Hamilton

    Also  Dayton Power and Light Company is known to  use PCB  oils in capacitors. In view
 of the elevated PCB levels found in  sediment and fish samples, the above facilities should
 be inspected to determine if PCBs  are being properly  handled  and disposed.  Inspections
 could  be prioritized  based on  the  quanity  of  PCB purchased by  the facility and the
 proximity to the Great Miami River or its tributaries.

-------
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   Conventional pollutants and inorganic metals (excluding mercury) are being evaluated
by the Ohio EPA in a Waste Load Allocation Report.  The final report, which is scheduled
for completion  March 1982,  will recommend NPDES permit  limitations for the  major
dischargers in the basin.

-------
     APPENDIX




NPDES Permit Limits

-------
                                                             Po£c   1   of   25

                                          '   OEPA Permit No.      D  101  *AD

                                             Application No.       OH. 0009907

                                                              Ohio Environmental Proieclion Ar-s?
                OHIO ENVIRONMENTAL PROTECTION AGENCY    TIH^^ f,j--.:f;T.1TS KJ'JT,-'^

                AUTHORIZATION  TO DISCHARGE  UNDER THE         ^LC £ j? j^g

          NATIONAL POLLUTANT  DISCHARGE ELIMINATION  SYSTEM
      In compliance  with  the  provisions  of the Federol Water Pollution. Control
Act, as amended,  (33  U.S.C.  1251  et. seq.;  the "Act"), and the Ohio Water
Pollution Control Act (Ohio Revised Code Chapter  6111),

                         Armco Steel Cozporation
                         703 Curtis
                         Middletown, Ohio 45942

is authorized to discharge from a facility located fit

                         Middletown Works
                         Middle-town, Ohio

to receiving waters  named Dick's Creek tributary  to Great Mitni  River and
the Great Miami River,

in accordance with effluent limitations,  monitoring requirements and other
conditions  set forth  in Parts I, II, and  III hereof.

      This  permit  shall "become effective on  December 22, 1976

      This  permit  and the authorization  to discharge shall expire at midnight,
December 21,  1981        .  Permittee shall not discharge after the above date of
expiration.   In order to receive authorization to discharge beyond the above
date of expiration, the permittee shall submit such information and  forms as
are required by the Ohio EPA no later  than  180  days prior to the above date-
of expiration.
                                              |  cert-fy V.vs t^ be a t-..e aod  ^cur^te copy o.^ne
                                               .•r. . i  .•    .. -  v   - -i!.^^ 'r* •i-i-^ |CCC-!C":S O; k..- vis-'
                                              ffiiC..-   ~"    •   l '   '»->-• I  ' '"w "--''•
Ned E. Williams , P.E.                         Tnv;,'. . . - .I... .-ix:o-ii.»n Agency.
Director

-------
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                                                      i*

                                                1 of 18

                                           OEPA Permit No. E603*BD

                                           Application No. OH0026522

                                           Effective Date: May 23, 1980

                                           Expiration Date: May 22, 1985
                      OHIO ENVIRONMENTAL PROTECTION AGENCY

                      AUTHORIZATION TO DISCHARGE UNDER THE

                 NATIONAL POLLUTANT DISCHARGE  ELIMINATION SYSTEM
          In compliance with the provisions of the Federal Water Pollution
Control Act, as amended (33 U.S.C. 1251 et. seq. hereinafter referred to as
"the Act"), and the Ohio Water Pollution Control Act (Ohio Revised Code
Section 6lll),

                               City of Middletown

is authorized by  the Ohio Environmental Protection Agency, hereafter referred
to as  "Ohio EPA",  to discharge from the wastewater treatment works located

at 300 Oxford State Road, Middletown, Ohio and from associated collection
system combined sewer  overflows and bypasses

and discharging to the Great Miami River

in accordance with the conditions specified in Parts I, II and III of this
permit.

          This permit  and the authorization to discharge shall expire at
midnight on the expiration date shown above.  In order to receive authori-
zation to discharge beyond the above date of expiration, the permittee shall
submit such information and forms as are required by the Ohio EPA no later
than 180 days prior to the above date of expiration.
'Director
 OSPA-NPDES-1J8

-------
                                                           Page 2 of 18
                                                           OEPA  E603*BD

PART I, A, 2 - FINAL EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS

1.  During the period beginning on the effective date of this permit and lasting
    until the expiration date, the permittee is authorized to discharge in
    accordance with the following limitations and monitoring requirements from the.
    following outfalls: E603001.  SEE PART II, OTHER REQUIREMENTS, for location of
    effluent sampling.
  EFFLUENT CHARACTERISTIC

 REPORTING
Code  UNITS PARAMETER
                                   DISCHARGE LIMITATIONS
                             Concentration
                         Other Units(Specify)
                           30 day     7 day
    Loading*
     kg/day
30 day    7 day
  MONITORING
 REQUIREMENTS
Meas.   Sample
Freq.   Type	
50050 MGD   Flow

00010 Deg.  Temperature
      Cent.

00530 mg/1  Suspended Solids 30

00310 mg/1  BOD5             30

31616 Count Fecal Coliform   1000
    #/lOOml (Summer only)

00610 mg/1 Ammonia (N)       8
            (summer only)

00665 mg/1 Phos.,Total

00550 mg/1 Oil & Grease
                                      2000
                                       12
                   Daily   Continuous

                   Daily   Max.  Ind.
                           Thermometer

 5500     8200     Daily   Composite

 5500     5500     Daily   Composite

                   Daily   Grab


 1500     2200     Daily   Composite


                   1/week  Composite

                   1/month Grab
2.  The  pH  (Reporting Code 00400)  shall not be less than 6.5 S.G. nor greater than
    9.0  S.U. and shall be monitored daily by grab sample.

3>  The  Chlorine Residual  (Reporting  Code 50060) shall be maintained at a level not
    to exceed 0.5 mg/1 and shall be monitored daily by grab sample. (Sumner only)

1.  See  Part II OTHER REQUIREMENTS
     The  average  effluent  loading  limitations are established using the following
     flow value:  48.0. Also  see  part  II  item F
 OEPA-NPDES-18

-------
                                           Page  1  of Q

                                           OEPA  Permit  No. A100*CD

                                           Application  Mo. OH0009539

                                           Effective Date:

                                           Expiration Date:   March  31,  1981
                      OHIO ENVIRONMENTAL PROTECTION AGENCY
                      AUTHORIZATION TO DISCHARGE UNDER THE

                NATIONAL  POLLUTANT  DISCHARGE ELIMINATION SYSTEM
          In compliance with the provisions of the Federal Water Pollution
Control Act, as amended (33 U.S.C. 1251 et. seq. hereinafter referred  to  as
"the Act"), and the Ohio Water Pollution Control Act (Ohio Revised Code
Section 6lll),

                           The Crystal Tissue Company

is authorized by the Ohio Environmental Protection Agency, hereafter referred
to as "Ohio EPA", to discharge from the wastewater treatment works located

on South Verity Parkway, Middletown, Ohio

and discharging to Great Miaifli River

in accordance with the conditions specified in Parts I, II and III of this
permit.

          This permit and the authorization to discharge shall expire at
midnight on the expiration date shown above.  In order to receive authori-
zation to discharge beyond the above date of expiration, the permittee shall
submit such information and forms as are required by the Ohio EPA no later
than 180 days prior to the above date of expiration.
James F. McAvoy
Director
OEPA-NPDES-48

-------
                                                           Page 2 of 9
                                                           OEPA  A100*CD

PART I, A - FINAL EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS

1.  During the period beginning on the  ffective date of this permit and
    lasting until the expiration date, 'he permittee is authorized to
    discharge in accordance with the fo:lowing limitations and monitoring
    requirements from the following outfalls: A100001.  SEE PART II, OTHER
    REQUIREMENTS, for location of efflu-nt sampling.
  EFFLUENT CHARACTERISTIC

REQUIREMENTS
 REPORTING
Sample
Code  UNITS PARAMETER
          DISCHARGE LIMITATIONS
                     MOMITORING
    Concentration

Other Units(Specify)

  30 day    Daily
    Loading

     kg/day        Meas.

30 day   Daily	Freq.    Type
50050 MOD   Flow

00310 mg/1  BOD5

00530 mg/1  Suspended Solids -

00610 rag/1  Ammonia NH^N

00300 mg/1  Dissolved Oxygen -

00010 Deg   Temperature
      Cent
             3' (max)
                   Daily   Total

 253      380      Weekly  24 hr comp

 316      950      Weekly  24 hr comp

                   Weekly  24 hr comp

                   Weekly  Grab

                   Daily   Max. Ua3ue
2.    The  pH  (Reporting Codes 00400) shall not be less than 6.5 S.U. nor greater than
      9.0  S.U. and shall be monitored weekly by grab sample.

3-    Samples taken  in compliance with monitoring requirements specified above shall
      be taken at Sampling Stations described in Part II, OTHER REQUIREMENTS.

4.    See  PART II, OTHER REQUIREMENTS.
 OEPA-NPDES-48

-------
                                           Page 1 of 9

                                           OEPA Permit No. A102*CD

                                           Application No. OH0009130

                                           Effective Date: February 6, 1980
                                             /'
                                           Expiration Date: March 31,  1981
                      OHIO ENVIRONMENTAL PROTECTION AGENCY

                      AUTHORIZATION TO DISCHARGE UNDER THE

                 NATIONAL  POLLUTANT  DISCHARGE  ELIMINATION  SYSTEM
          In compliance with the provisions of the Federal Water Pollution
Control Act, as amended (33 U.S.C. 1251 et. seq. hereinafter referred to as
"the Act"), and the Ohio Water Pollution Control Act (Ohio Revised Code
Section 6111),

                           Harding-Jones Paper  Company

is authorized by the Ohio Environmental Protection Agency, hereafter referred
to as "Ohio EPA",  to discharge from the wastewater treatment vrorks located

at 3561 South Main Street, Middletown, Ohio

and discharging to Dicks Creek

in accordance with the conditions specified in Parts I,  II and III of this
permit.

          This permit and the authorization to discharge shall expire at
midnight on the expiration date shown above.  In order to receive authori-
zation to discharge beyond the above date of expiration, the permittee shall
submit such information and forms as are required by the Ohio EPA no later
than 180 days prior to the above date of expiration.
  raes F. MoAvoy
  -ector
OEPA-NPDES-18

-------
                                                           Page 2 of 9
                                                           OEPA  A102*f,D

PART I,  A - FINAL EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS

1.  During Che period beginning on the effective date of this permit and lasting
    until the expiration date, the permittee is authorized to discharge in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: A102001.  SEE PART IT, OTHER REQUIREMENTS, for location of
    effluent sampling.

  EFFLUENT CHARACTERISTIC          DISCHARGE LIMITATIONS             MONITORING
                             Concentration          Loading         REQUIREMENTS
 REPORTING               Other Units(Specify)        kg/day        Keas.   Sample
Coda  UNITS PARAMETER	30 day    Daily      30 day   Daily     Freq.   Type	

50050 MGD   Flow             -                   -        -        Daily   24 hr total

00300 mg/1  Dissolved Oxygen 6.3(rain) -          -                 I/week  Grab

00310 mg/1  BOD5             _                   91       135      I/week  Composite

00530 tng/1  Suspended Solids -                   91       136      I/week  Composite
                      Total

00610 ing/I  NH3-N            -        -          3.6      7.2      I/week  Composite

2.  The pH (Reporting Code 00400) shall not be less than 6.5 S.U. nor greater than.
    9.0 S.U. and shall be monitored I/week by a grab sample.

3.  Samples taken in compliance with monitoring requirements specified above srs! :
    be taken at Sampling Stations described in Part II, OTHER REQUIREMENTS.

4.  See PART II, OTHER REQUIREMENTS.
OEPA-NPDES-48

-------
                                              Page  1  ofl<>

                                              OEPA  Permit No.K 611 *BD

                                              Application No.  OH 0049417

                                              Effective Date:  September 15, 1978

                                              Expiration Date:  September 14,  1981
                 OHIO ENVIRONMENTAL PROTECTION AGENCY
                 AUTHORIZATION TO DISCHARGE UNDER THE
           NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
compliance with the provisions of the Federal Water Pollution  Control Act,
mended (33 U.S.C. 1251 et. seq. hereinafter referred to as  "the Act"),
 the Ohio Water Pollution Control Act (Ohio Revised Code Section 6111),

                        Board of County Commissioners
                        Butler County ^,—

authorized by the Ohio Environmental Protection Agency,  hereafter  referred  to
'Ohio EPA", to discharge from the vzastewater treatment works located at
tourdsville RegionalJWastewater Treatment Plant located at S.R.  4 & S.R.  63,
iourdsville, Ohio
The Great  Miami River                   ~

accordance with the conditions specified in Parts I, II  and  III of this  permit.

  This permit and the authorization to discharge shall expire  at midnight on
 expiration date shown above.  In order to receive authorization to discharge
ond the above date of expiration, the permittee shall submit such  information
 forms as are required by the Ohio EPA no later than 180 days  prior to the
ve date of expiration.
 E. Williams, P.E.
ector
A-NPDES-48

-------
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-------
                                           Page  1  of 16

                                           OEPA  Permit No.  D102*HD

                                           Application No.  OH0009989

                                           Effective Date:

                                           Expiration Date: September 30,  1980
                      OHIO ENVIRONMENTAL PROTECTION AGENCY
                      AUTHORIZATION TO DISCHARGE UNDER THE
                NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
          In compliance with the provisions of the Federal Water Pollution
Control Act, as amended (33 U.S.C. 1251 et. seq. hereinafter referred to as
"the Act"), and the Ohio Water Pollution Control Act (Ohio Revised Code
Section 6111),

                                  Armco, Inc.

Is authorized by the Ohio Environmental Protection Agency, hereafter referred
to as "Ohio EPA", to discharge from the wastewater treatment works located

at Augspurger Road, Hamilton, Ohio

and discharging to Great Miami River

in accordance with the conditions specified in Parts I, II and III of this
permit.

          This permit and the authorization to discharge shall expire at
midnight on the expiration date shown above.  In order to receive authori-
zation to discharge beyond the above date of expiration, the permittee shall
submit such information and forms as are required by the Ohio EPA no later
than 180 days prior to the above date of expiration.
James F. McAvoy
Director
OEPA-NPDES-48

-------
                              -5-
                                                           OEPA  D102*HD
1.  During the period beginning on the effective date of this  permit and lasting
    until the expiration date, the permittee is authorized to  discharge in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: D102611.  SEE PART II, OTHER REQUIREMENTS, for location of
    effluent sampling.
  EFFLUENT CHARACTERISTIC
          DISCHARGE LIMITATIONS
 REPORTING
Code  UNITS PARAMETER
    Concentration
Other Units(Specify)
  30 day    Daily
   *Loading
     kg/day
30 day   Daily
50050 MGD
01092 ug/1
01046 ug/1
00550 mg/1
00530 mg/1
00720 mg/1
32730 ug/1
00610 mg/1
Flow
Total Zinc - -
Dissolved Iron - -
Oil & Grease** - -
Suspended Solids - -
Total
Total Cyanide
Phenol
Ammonia — —
-
36
54.5
120
60
13.3
4.86
150
-
108
164
358
180
39.8
. 15
450
**During periods when an oil-bearing burden is used on average of 10 mg/1 Oil and
Grease shall apply for this outfall.

 2. The pH  (Reporting Code 00400) shall not be less than 6.5 S.U. nor greater than
    9.0 S.U. and shall be monitored I/month by grab sample.
                    ATTACHMENT II & Ilia
OEPA-NPDES-48

-------
                               -6-
                                                           OEPA  D102*HD
1.  During the period beginning on the effective date of this permit and  lasting
    until the expiration date, the permittee is authorized to discharge in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: D102621.  SEE PART II, OTHER REQUIREMENTS,  for  location of
    effluent sampling.

  EFFLUENT CHARACTERISTIC          DISCHARGE LIMITATIONS
                             Concentration         *Loading
 REPORTING               Other Units(Specify)        kg/day
Code  UNITS PARAMETER	30 day    Daily	30 day   Daily

50050 MGD   Flow             _        _          _

00550 mg/1  Oil 6 Grease     -        -          109      327

 2. The pH (Reporting Code 00400) shall not be less than 6.5 S.U. nor greater than
    9.0 S_U. and shall be monitored I/month by grab sample.
               ATTACHMENT II  &  Ilia
 OEPA-NPDES-48

-------
                                -7-
                                                          OEPA  D102*HD
1.  During the period beginning on the effective date  of  this permit and lasting _
    until the expiration date, the permittee is authorized  to discharge  in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: D102001.  SEE PART II, OTHER REQUIREMENTS,  for location of
    effluent sampling.

  EFFLUENT CHARACTERISTIC          DISCHARGE LIMITATIONS
                             Concentration          Loading
 REPORTING               Other Units(Specify)       kg/day
Code  UNITS PARAMETER      30 day    Daily '     30 day   Pail?

00010 Deg.  Temperature*     -                      .     -
      Cent.

This discharge is limited to the discharges from outfalls D102S11,  D102621  and
uncontaminated stormwater.

  2. The pH (Reporting Code 00400) shall not be less than  6.5 S.U. nor greater than
    9.0 S.U. and shall be monitored 1/month by grab sample.
           ATTACHMENT  II & Ilia
 OEPA-NPDES-48

-------
                              -3-
                                                           OEPA  D102*HD
1.  During the period "beginning on the effective date of this permit and lasting
    until the expiration date, the permittee is authorized to discharge in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: D102002.  SEE PART II, OTHER REQUIREMENTS,  for location of
    effluent sampling.
  EFFLUENT CHARACTERISTIC

 REPORTING
Code  UNITS PARAMETER
          DISCHARGE LIMITATIONS
    Concentration
Other Units(Specify)
  30 day    7 Day
              Loading
               kg/day
          30 day   Daily
50050 MGD   Flow

00610 mg/1  Ammonia

00310 mg/1  BOD5
    5.0
    30
7.5
45
31616 Count Fecal Coliform   200/100  400/100
      /100ml
00530 ing/1  Suspended Solids 30
                      Total
             45
2.  The pH  (Reporting Code 00400) shall not be less than 6,5 S.U. nor greater than
    9.0 S.U. and shall be monitored 2/month by grab sample.
                ATTACHMENT II  & Ilia
 OEPA-NPDES-48

-------
-9-
                                                        C
                                                           OEPA  D102*HD
1.  During the period beginning on the effective date of this permit and lasting"
    until the expiration date, the permittee is authorized to discharge in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: D102003.  SEE PART II, OTHER REQUIREMENTS,  for location of
    effluent sampling.

  EFFLUENT CHARACTERISTIC          DISCHARGE LIMITATIONS
                             Concentration          Loading
 REPORTING               Other Units(Specify)        kg/day
Code  UNITS PARAMETER      30 day    Daily	30 day   Daily

50050 MGD   Flow             -                   -

00010 Deg.  Temperature*   .  -
      Cent.

For the purpo&e of this permit, this discharge is limited to non-contact cooling
water including boiler blowdown water, but free from process wastes and other
contaminants.

  2. The pH  (Reporting Code 00400) shall not be less than 6.5 S.U. nor greater than
    9.0 S.U. and shall be monitored I/month by grab sample.
             ATTACHMENT III  &  Ilia
 OEPA-NPDES-48

-------
                            -10-
                                                           OEPA  D102*HD
1.  During the period beginaing on the effective date of this permit and lasting
    until the expiration date, the permittee is authorized to discharge in
    accordance with the following limitations and monitoring requirements from the
    following outfalls: D102004.  SEE PART II, OTHER REQUIREMENTS, for location of
    effluent sampling.
  EFFLUENT CHARACTERISTIC

 REPORTING
Code  UNITS PARAMETER
          DISCHARGE LIMITATIONS
    Concentration
Other UnitsCSpecify)
  30 day    Daily
    Loading (net)
     leg/day
30 day   Daily
50050 MGD
00720 mg/1
32730 ug/1
00610 mg/1
00550 mg/1
00530 mg/1
Flow
Total Cyanide
Phenol
Ammonia - -
Oil & Grease
Suspended Solids - -
• -
17.8
2.4
144
17.2
57.6
-
53.4
7.2
432
51.6
172.8
00010 Deg.  Temperature*     -                   -
      Cent.

 2. The pH  (Reporting Code 00400  (average) shall not be less than 6,5 S.U. nor
    greater than 9.0 S.U. and shall be monitored I/week by grab sample-
                ATTACHMENT II & Ilia
 OEPA-NPDES-48

-------
                                                                Pap;e  1  of
                                           OEPA Permit Ho. B  108  *AD

                                           Application No. OH 0010413
                 OHIO ENVIRONMENTAL PROTECTION AGENCY

                 AUTHORIZATION TO DISCHARGE UNDER THE

           NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
        In compliance vith the provisions of the Federal Water Pollution
 Control Act, as amended, (33 U.S.C. 1251 et. seq; the "Act"), and the Ohio Water
 Pollution Control Act  (Ohio Revised Code Chapter 6lll),

                          City of Hamilton
 is authorized to discharge froa a facility located at

                          Municipal Electric Plant
                          960 North Third Street
                          Hamilton, Ohio  45011
 to receiving waters named


               Great Miami River and the Hamilton-Rossville Hydraulic Canal
 in accordance vith effluent limitations> monitoring requirements and
 other conditions set forth in Parts I, II, and III hereof.

        This permit shall become effective on  May 12, 1975
        This permit and the authorization to discharge shall expire
 at midnight»May 11, 1980.         Permittee shall not discharge after
 the above date of expiration.  In order to receive authorization to
 discharge beyond the above date of expiration, the permittee shall
 submit such information and forms as are required by the Ohio EPA no
 later than 180 days prior to the above date of expiration.
Ned E. Williams, P.E.
Director
  OEPA-NPDES-7

-------
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                                                                Page   1  of  13


                                           OEPA Permit No. A 109 *AD

                                           Application No. OH 0010065


                 OHIO ENVIRONMENTAL PROTECTION AGENCY

                 AUTHORIZATION TO DISCHARGE UNDER THE

           NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM


        In compliance with the provisions of the Federal Water Pollution
 Control Act, as amended, (33 U.S.C. 1251 et. seq; the "Act"), and the Ohio Water
 Pollution Control Act (Ohio Revised Code Chapter 6lll),
                   Champion International
                   Knightsbridge
                   Hamilton, Ohio  45020

 is authorized to discharge from a facility located at

                   601 North B Street
                   Hamilton, Ohio  45020                                    .  •

 to receiving waters named


                   Great Miami River
 in accordance with effluent limitations, monitoring requirements and
 other conditions set forth in Parts I, II, and III hereof.

        This permit shall "become effective on  August 15,  1975.
        This permit and the authorization to discharge shall expire
 at midnight, December  29,  1979.    Permittee shall not discharge after
 the above date of expiration.  In order to receive authorization to
 discharge beyond the above date of expiration, the permittee shall
 submit such information and forms as are required by the Ohio EPA no
 later than 180 days prior to the above date of expiration.
Ned E. Williams, P.E.
Director
  OEPA-NPDES-7

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                                                                              Page   3   of   13
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-------
                                               MONITORING  H
                               AREA-BY-AREA STUDIES
                                         Reporting  Form C
Sc.-.5 = -:e '{YRHHOHDA)
"1 P' «'»'\-D 9°^inn:na Da'*? Sol 7 1 /£ Cneinn f
1} COMPLETED "Beginning Date^L/ JL/£2 Ending
Date^b/ JL//Z
DatBfiia/yj&s"

Survey Icentifjc3tiorv/Name:_ _ ., / 0 / /
Primary Receiving Water Name(s):
^40. uses
EPA hciqts. Use


Hydrolop.ic Unic;



50. Reach Seament I.D.:
            ?
                                  County/Parish:
                                                                  State:
                                 Region:
  Sits  I.D. HO:
                                              Agency  Code/Station numbsr(s)
Total Nc
mbier.t
4
). Stations
Effluent
o
Rnish»d
DrinWng Water
O
Ground Water
O
80. Total No. "Samples
Analyzed by Stats
Analyzed by Region
Analyzed by OWHS
Contractor
Water

4-
-f
Ssdiment

3
3 "
Total 1 4 f 3
, 'Tissusf


z.
2.
EC? <">**• $ (fWrt Work Yo3rc: 0. /S A/,,* /*.£/£><-//*« /*A a/.^s/r
iTRUCTlON'S: Check one or more variables, as appropriate.
3-
T..
  No. Samples by  Media
   4   Surfacs water
 __— .  Ground watsr
   3   Sediment
  . e   Ftsh/Sheil fish
 _ Effluent
       Precipitation
       Surface runoff
       r,- ,  •   i
       Biological
       (planirton, etcJ
       Other.
                            110. Water Body
                                 Typeis)
                               a. P^.   Strftam
                               b, ( )   Laka
                               c. ( )   impoundment
                               d. ( )   Estuary/Bay
                               e. ( )   Ccaan
                               f. ( )   Groundwater
                               8- ( )   Other:
3.

3.
C.
d.
e.
f.
g-
Ju
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P-
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  fc$   Dissolved oxygen
  &<)   Oxygen demanding
       Physical
       Biological
       Bactsrioiogical
       Nutrients
       Solids
       Oil and grsas*
       Organics
       Meals
       Pesticides
       Cyanides and Phenols
       Reaction Rates
       Radionuclides
       Streamfiow
       Bioassay/static
       Bioassay % flow thru
       Microtox/other toxichy
       Amcs/carcinogsnicity/
       mutagenicity
       Othar.
  ( )
  ( )
  I )
  { )
  fc<)
  k)
  0-~   •"•— •

-------

-------
          REGIONAL TOXICS MONITORING PROGRAM —
                                EXPOSURE/RISK
                                  Reporting Form D
10. Schedule
D PLANNED
D COMPLET1
20. Primary Receiving
&r~&c/ 7 / /S Endina Da
ED Beginning Data32/.L/*l Ending C
Water Nams(s):
/ A/6/^r
County/Parish:
'- ' BoS/er
^YR)(«0)(DA).
ts'^SJlJIZ
3ata5«;lJ£S-
EPA Hdqts. Usa

30. U.j* V
•• Agency Coda/Station


fti^nberCs)

 INSTRUCTIONS: Chsck ona or more variables as approprsta.
                        T
80. No. Samples by Media
  ?    Surfacs wata*
  b. _ Ground wars*
  c. _ Sadimwit
  d._i_ Rsh/Sheilfbh-
  «  , fr Effluent
  i,.-. — Prsciphatcfr
  g. _ Surface
  h _ Biological
       Other.
£0. Water Body
   Typs(s)
  x U Srraam
  b; (} Laks
  c. () Impoundment
  d. {) Estusry/bay
  9. {} Cosstal
  f,  U Cc«n
  g, {} Dthsr	
1 CO,  Parameter Group(s) Measured
  a. t) DwiscHvad oxygen    L $4
  b. {) Qxygan-damar-ding   }. ()
  c, O Physical
  d. U Biological
  9, (} Bdctar JoJcgicil
  f.  O Nutrient*
  g. U SoKds
  h, H Oilsrxi
k. {* Psstksdes
L {) Cyanides and phaod
m. {)
n. O
o. (}

-------