ORPLV804
EPA
Airborne Particulate
Radioactivity
Measurements
In Pocatello, Idaho
KP 520/
LV-PO -4
              US ENVIRONMENTAL PROTECTION AGENCY
              EDISON, N. J. 08817

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                                            Technical Note
                                            ORP/LV-80-4
AIRBORNE PARTICULATE RADIOACTIVITY MEASUREMENTS
                     IN
              POCATELLO, IDAHO
               Gregory G. Eadie
              Donald L.  Lambdin
                August  1980
      U.S. Environmental  Protection Agency
         Office  of Radiation Programs
              Las Vegas  Facility
           Las Vegas, Nevada 89114

             IBRARY

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                                  DISCLAIMER

    The Office of Radiation Programs  - Las  Vegas Facility,  U.S.  Environmental
Protection Agency, has  reviewed  this  report and approved it  for  publication.
Mention of trade names or commercial  products does not  constitute  endorsement
or recommendation.

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                                    PREFACE

     The  Office  of Radiation  Programs of the  U.S.  Environmental  Protection
Agency conducts a national  program designed to evaluate population exposure to
ionizing and  nonionizing radiation  and to  promote  development  of  controls
necessary to  ensure  the public  health and safety.   This report describes  a
study conducted in the Pocatello,  Idaho area  to evaluate  the  ambient  airborne
particulate  concentration  of   naturally  occurring   radioactive  materials.
Readers are  encouraged  to  inform this  Office  of  any  omissions  or  errors.
Comments or requests  for further information  are also  invited.
                                                  cj.
                                       D.  W.  Hendricks,  Director
                                      Office  of Radiation Programs
                                          Las Vegas Facility
                                     m

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                              TABLE OF CONTENTS

                                                                          Page

PREFACE	Ill

LIST OF TABLES AND FIGURES	    vi

INTRODUCTION  	     1

SUMMARY AND CONCLUSION  	     2

AIR SAMPLING PROGRAM DESCRIPTION  	     3

    Sampling Locations  	     3
    Sampler Description and Operating Procedures  	     5
    Analytical Procedures 	     5
    Meteorological Measurements 	     6
    Results and Discussion  	     7
    Dose Estimates	    11

REFERENCES	    15

APPENDIX A - Composited Monthly Ambient Airborne
             Particulate Radioactivity Concentrations (pCi/m )	    17

APPENDIX B - Composited Monthly Ambient Airborne
             Particulate Radioactivity Concentrations (pCi/g) 	    25

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                                LIST OF TABLES

Number                                                                    Page

  1      Annual  average ambient airborne participate
         radioactivity (in pCi/irr)	    9

  2      Annual  average net airborne particulate
         radioactivity concentrations (in pCi/rtr)	     12

  3      Average annual lung dose (mrem/year) for
         insoluble radionuclides 	   13
                               LIST OF FIGURES
Number
1
2

Pocatello air sampling locations
Average wind rose for Pocatello,
(April 1974 to March 1975). . . .

(1974-75 study) . . .
Idaho
Page
	 4
	 8
         Volume-weighted average concentration of airborne
         particulate radioactivity (in pCi/m3) f0r
         locations in Pocatello, Idaho 	 10
                                      VI

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                                 INTRODUCTION


    In 1974,  the  Idaho Department  of  Health and  Welfare requested that  the
Office of Radiation Programs-Las  Vegas  Facility  (ORP-LVF) provide support  in
sampling  the air at  five locations near  the two phosphate plants  in Pocatello,
Idaho.

    From  April 1974 through June  1975, the ORP-LVF evaluated the  radiological
consequences of airborne effluents containing low  levels  of  naturally  occurr-
ing radioactive materials.   In addition,  "background"  samples were obtained at
Howe and  Arco, Idaho,  from July through  September 1977.

    Reported  here  are  the airborne  concentrations  of  isotopic   uranium  and
thorium,  and radium-226.  Technical  difficulties  prevented the  full assessment
of the radiological  impact of polonium-210 and lead-210.

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                           SUMMARY  AND  CONCLUSIONS

    Seven sites near Pocatello, Idaho were sampled and evaluated to  determine
levels  of  several   of  the  naturally  occurring  radionuclides  in  airborne
particulates.    At  the  Pocatello  Sewage  Plant,  airborne  concentrations  of
natural   uranium  (U-234,  -235,  and  -238), radium-226,  and thorium-230  were
found to  be higher  than the  levels measured at the  other  sites and  about  an
order of  magnitude  greater  than   levels  measured  at  Howe, the "background"
location.   A  correlation   between  the  concentrations  measured  at  the  sewage
plant location and  meteorological  data   indicates  that  emissions  from  the
phosphate plants  caused  the elevated levels in  this  area.

     The  other four locations in the Pocatello area  are  at least three miles
from the  phosphate  plants  and  are  not  in  the  predominant  downwind  direction.
Concentrations appear to be at background  levels reported  for Chicago and New
York  City  (NCRP,  1975) and  are   within  about a  factor  of  three   of  levels
measured  at  Howe.    Moreover,  uranium  and  radium  concentrations measured  at
Howe  and Arco were  about  an  order of  magnitude less  than the  reported NCRP
"background"  values, further indication  that  the airborne  particulate  radio-
activity  near Pocatello exceeds the levels in the surrounding  areas.

      The impact  of  polonium-210 and lead-210  concentrations  is not reported
here because  technical  difficulties were encountered during the radiochemical
analyses  of  these  samples.    Nonetheless,  findings  indicate  a  probable
significant radiological  influence from  these  two  radionuclides.   To resolve
this  issue, future  studies should  involve additional  sampling  and  a thorough
evaluation of airborne  polonium-210 and lead-210 radioactivity.

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                       AIR SAMPLING PROGRAM DESCRIPTION

SAMPLING LOCATIONS

    Figure  1 shows  the five  air sampling  locations  selected  by  the  Idaho
Department of Health  and  Welfare  (IDHW).   The basis for choosing these  sites
was either  their proximity  to population  centers  or  the direction  of  the
prevailing winds  relative to  the  phosphate plants.  A brief description  of
each site location follows:

         #581 Hayes   Fire  Station  2,   Pocatello  (four miles   southeast   of
              the plants)

         #582 Pocatello Sewage Plant,  Interstate  15W,  Pocatello  (one-half mile
              northeast of the plants)

         #583 NOAA  Weather  Station  at  the  Pocatello   Airport,   Pocatello
              (three miles west of the  plants)

         #584 Courthouse Building,  Center  St.  and  5th  Ave., Pocatello  (five
              and one-half miles southeast  of the plants)

         #585 The Chubbuck School, 5045 Hawthorne Road,  Chubbuck, Idaho (thre~
              miles  northeast of the plants)

    During the  summer of  1977,  the ORP-LVF made background airborne  radio-
activity determinations in Howe and Arco,  Idaho.  Both communities  are  about
70 miles  northwest  of Pocatello and have  no industrial activities  that  could
"technologically enhance" the amount of radioactivity  in their environment.

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SAMPLER DESCRIPTION AND OPERATING PROCEDURES

    The IDHW conducted  volume particulate  air  sampling  using heavy  duty  air
samplers (Research Appliance Corp., Allison Park, PA; or  Tempest  Air Sampler,
Gelman  Instrument  Corp.,  Ann  Arbor,  MI)  that  ran   continuously  without
requiring  routine maintenance.

     Each  sampler has a carbon-vane pump  driven  through  a V-belt system by  a
110 volt,  3/4  hp motor with overload  protection, and a free  flow capacity of
10.5 cubic  feet  per minute  (CFM).    Each  unit  has  a  built-in vacuum  gauge,
individually calibrated for pressure  drop versus  air flow rate.   A cumulative
time-meter,  reading  to tenths  of  an  hour,  provided total  elapsed  sampling
time.  The  air volume  passing  the filter  was  determined  by averaging the "on"
and  "off"   flow  rates  and  multiplying  by  the  total  elapsed time  for  the
sampling period.   A quick-change 110-mm-diameter filter  holder was mounted  one
meter above ground  and was secured so that the  open face of the  filter  was
toward the ground.  The filters (Gelman Type E,  102-mm  (4-inch) diameter glass
fiber) were  changed weekly.

    The sampling period for three of the five stations extended from April  5,
1974 to June  20, 1975.   Sampling site #585 operated only through  August  22,
1974, and  site #584 operated through November 4,  1974.
ANALYTICAL PROCEDURES

    ORP-LVF analyzed each filter radiochemically at the U.S.  EPA-Environmental
Monitoring and  Support  Laboratory  (EMSL)  for radium-226,  thorium-230,  and
-232,  and uranium-234,  -235,   and  -238.   Standard radiochemical  procedures
(Johns, 1975) were used.

    Radiochemical  analyses for polonium-210 and lead-210 indicate that concen-
trations  of  these radionuclides may  have a significant  radiological  impact;
however,  technical   difficulties  encountered   during   the  analyses  prevent
ORP-LVF  from reporting  its  determinations  here.    These  difficulties  are
discussed in  two previous ORP-LVF reports on the Idaho  phosphate industry (EPA

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1977  and  1978).   A thorough  evaluation focusing  on  the  polonium and  lead
concentrations will  have to wait for another sampling because the  air  filters
collected during this study were consumed during  analysis.   However, a  similar
study (U.S. AEC, 1970) indicates that the polonium-210 content  averaged  about
88 percent of the gross alpha  radioactivity measured on  air samples collected
in the Pocatello area in 1969-70.

    In 1976, Eadie and Bernhardt reported the radioactivity  analysis of  blank
Gelman Type  E  glass  fiber filters.   They  also  described  methods for  blank
subtraction  of  composite  samples,  standard  deviation   determination  of  net
results,   and volume  weighting of  monthly  averages.    ORP-LVF  obtained  the
sample net  activity  for this  study  by subtracting the  average blank  filter
content from the measured gross analytical  result.
METEOROLOGICAL MEASUREMENTS

    Meteorological  data  for  the Pocatello  area were  prepared  by  the  U.S.
Department  of  Commerce,  National   Oceanic  and  Atmospheric  Administration
(NOAA),  Environmental  Data Service.   Measurements  cover  one year  beginning
April  1,  1974.    The  weather  station  is  located  at  the Pocatello  Airport
(Station #24156).  Data are based on eight observations  per day.

    Figure 2 shows the 12-month  average wind  rose.  Each  bold faced  number in
a  sector  refers   to  the  percentage  of  total   time  the  wind  was  from  the
direction  indicated and  was  between the  velocities  (mph)   defined  at  the
interface  of each  concentric  circle  along the north  axis.   Look, for example,
at the ENE sector; the wind was blowing 18 to 24 mph  towards the WSW less than
0.05  percent  of the time, 13 to  18  mph  0.2 percent  of the time,  and  4  to 13
mph 2.5  percent of the time over one year.  The figure in the  center indicates
a calm of  0 to  4 mph and is considered nondirectional.

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RESULTS AND DISCUSSION

    Table 1 summarizes the study data.   Appendix  A shows  the  composite  monthly
airborne particulate radioactivities at each sampling station, as well  as  the
grand volume weighted  average  of monthly  results and the  associated  standard
error of the  mean based  on  the t-distribution at the  95 percent  confidence
level.

    All  results represent  ambient  airborne  concentrations  (natural  background
levels  have not been subtracted).  For some of the air samples,  dust  particu-
late loading was  determined by  measuring  the  mass of dust  collected  on  each
air sample filter.  Appendix B  shows the  specific activity of the  dust.   The
solubility of the airborne particulate  material was not  determined.

    Figure  3  shows the  average concentration (pCi/m3)  of  each  radionuclide
by  location for  the  entire  sampling period.    Stations  are  arranged  in
geographical order,  relative  to the  phosphate   plants,  from  west to  east-
southeast.  The relative percentage of  time each  station  was  downwind  from the
plant location  is noted  at  the top of each  set of bar  graphs  for  a  given
station location.   Station #582  (the  sewage  plant), predominantly downwind,
had the highest airborne  concentration  of  radioactivity—the levels are about
an order of magnitude  greater  than  levels measured at Howe,  the  "background"
location.   As  shown  in  Figure  3,  the  measured  concentrations at  the sewage
plant appear  to  correlate  with meteorological  data, indicating    that  these
levels were probably due to emissions from the  two phosphate  plants.

    The other  four  locations in the Pocatello area are at  least three miles
from the two phosphate plants  and  are  not in the  predominant  downwind direc-
tion.   Concentrations  appear to be at background  levels  reported for  Chicago
and  New York City  (NCRP, 1975) and are  within  about  a  factor  of three  of
levels measured at Howe.  Moreover, uranium and radium concentrations  measured
at Howe and Arco were about an  order of magnitude  less than  the  reported  NCRP
"background"  values,   further  indication  that   airborne  particulate  radio-
activity near Pocatello exceeds the levels in the surrounding areas.

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Station: #24156 Pocatello, Idaho
Period: 4/74-3/75 (8 obs/day)
Job# 16089
X = Less than 0.05%
        Figure 2.  Average surface wind  rose  for  Pocatello,  Idaho
                  (April 1974  to March  1975).
                                      8

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DOSE ESTIMATES

    Defining natural background levels of  airborne  concentrations  of  specific
radionuclides in the  Pocatello area is  difficult.    The  National  Council  on
Radiation Protection  and  Measurements Report  No.  45 (NCRP,  1975)  summarized
natural   background  airborne   levels  for  several   radionuclides  at   diverse
geographic  sites.   These levels  appear  in  Table  1.   For  this  study,  the
measured  airborne   concentrations  of   uranium  and  radium-226 at   the  two
background locations  (Howe  and Arco) are  roughly  an order of  magnitude less
than the NCRP-reported background  values.  However, the  thorium concentrations
measured at  Howe and  Arco are greater (but  within  a factor of  two)  than the
NCRP background estimates  for thorium levels.

    In order to establish  the "above background" concentrations for  the five
locations in  Pocatello,  the measured results  from Howe have  been  subtracted
from the ambient results.   Table 2 shows  the  resultant "net concentrations."

    Table 3  lists the  dose  conversion  factors for  each radionuclide  measured
in this study.  (The doses  due to radium-228,  polonium-210, and lead-210 have
not been  estimated  because these  radionuclides  were not  evaluated  for this
study.)   These  factors represent  the  average  annual dose  equivalent  in rems
for each  year  of chronic  inhalation at a concentration  of  1  pCi/m3.   Dose
estimates have  been maximized  by  assuming  that the indoor  airborne  concen-
trations would equal the  measured  outdoor  ambient  levels.   The  highest  total
dose  of  10  millirem was  calculated for an  individual  exposed to the annual
average ambient radionuclide  concentrations  measured outdoors  at  the  sewage
plant  (assuming  a  continuous exposure  for  the  entire year  at the  average
ambient values as reported in Table 1).   Similarly,  a total dose of less than
1  millirem  was calculated  for an individual  exposed  to  the  annual  average
ambient radionuclide concentrations measured outdoors at Howe  — the  location
having the  lowest  measured  airborne concentrations.   Therefore,  considering
Howe as representative of "background"  conditions,  the maximum additional dose
(above background)  to an  individual  in  the Pocatello  area would  be  about 9
millirem for each year of exposure to airborne radionuclide concentrations as
measured during this study.
                                      11

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    However,  the  major  dose  would  probably  be  due to  the  inhalation  of
elevated concentrations  of  polonium-210  and  lead-210,  based  on  previously
reported  data  (U.S.   AEC,  1970)   indicating   that   the   majority   of  alpha
radioactivity (i.e., 88 percent)  was due to  the polonium-210  content.
                                       14

-------
                                  REFERENCES


EADIE, Gregory G. and David  E.  Bernhardt,  (December 1976), Sampling  and  Data
Reporting Considerations for Airborne  Participate  Radioactivity,  ORP/LV-76-9,
U.S. EPA.

Idaho  Department  of  Health  (IDH),  (1973),  Rules  and  Regulations  for  the
Control of Radiation in  the State of Idaho,  Part C, May 9,  1973,  Appendix A.

JOHNS,  Frederick  B.,  ed.,  (1975),  Handbook  of  Radiochemical   Analytical
Methods, U.S. EPA, EPA-680/4-75-001, Las Vegas, Nevada.

National  Council  on  Radiation   Protection  and Measurements  (NCRP),  (1975),
Natural  Background  Radiation in  the United States,  November 15,  1975;  NCRP
Report No. 45.

SULLIVAN, Robert  E.,  (June 1977),  Plutonium  Air  Inhalation  Dose   (PAID)  -  A
Code  for Calculating  Organ  Doses   Due  to  the Inhalation  and  Ingestion  of
Radioactive  Aerosols,  U.S.  Environmental  Protection  Agency, Technical  Note
ORP/CSD-77-4.

U.S.  Atomic  Energy  Commission,  Health Services Laboratory,  Idaho  Operations
Office,  (1970),  Pocatello  and Vicinity  Environmental  Air  Sampling    Results
for December 1969 through May 1970.

U.S.  Environmental   Protection  Agency,  (1973),   Part  I   -  Fuel   Supply  -
Environmental Analysis of the Uranium Fuel  Cycle,  October,  1973.

U.S.  Environmental  Protection  Agency,   (1977),  Radiological  Surveys  of  Idaho
Phosphate  Ore   Processing   -   The   Thermal   Process  Plant,   ORP/LV-77-3,
November 1977.

U.S.  Environmental  Protection  Agency,   (1978),  Radiological  Surveys  of  Idaho
Phosphate Ore Processing - The Wet Process  Plant,  ORP/LV-78-1, April 1978.
                                      15

-------
                           APPENDIX A

Composited Mcrit.hl> Ambient, Airborne Particulate Radioactivity
                  Concentrations (pCi/ni3)
                                17

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                          APPENDIX B

Composited Monthly Ambient Airborne Participate Radioactivity
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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
1. REPORT NO.
 ORP/LV-79-4	
4. TITLE AND SUBTITLE
 Airborne Particulate Radioactivity Measurements  in
 Pocatello,  Idaho
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 Gregory  G.  Eadie  and Donald L. Lambdin
                                                            8. PERFORMING ORGANIZATION REPORT NO.
                                                            3. RECIPIENT'S ACCESSION NO.
             5. REPORT DATE
               August  1979
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Office  of Radiation Programs-Las Vegas Facility
 U.S.  Environmental  Protection Agency
 P.O.  Box  18416
 Las Vegas,  Nevada  89114
                                                            10. PROGRAM ELEMENT NO.
              11. CONTRACT/GPANT NO.
12. SPONSORING AGENCY NAME AND ADDRESS
 Same  as  above
                                                            13. TYPE OF REPORT AND PERIOD COVERED
                                                              Final
                                                            14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
is.
               particulate radioactivity levels of naturally  occurring radionuclides were
 measured at  seven  sites  near Pocatello, ID. At one of the sites (Pocatello Sewage Plant)
 airborne concentrations  of natural uranium, radium-226,  and thorium-230 were found to  be
 higher than  the  levels measured at the other sites and about an order of magnitude
 greater than levels  measured at the "background" location at the village of Howe. There
 appears to be some correlation between the measured concentrations at the sewage plant
 and meteorological data  to indicate that the measured levels were probably due to e 
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