EPA-450/2-78-027R-C (NTIS No.^B 95-246401)^ SUPPLEMENT C TO THE GUIDELINE ON AIR QUALITY MODELS (REVISED) (Appendix W of 40 CFR Part 51) August 1995 U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Air and Radiation Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 ------- NOTE The following pages contained in Supplement C to the Guideline on Air Quality Models (Revised) are to be appropriately inserted in the Guideline. with Supplements A and B having already been incorporated. Noting the page numbers will indicate which pages are to be added and which are to replace previous pages. ------- 4.2 Recommendations 4.2.1 Screening Techniques Point source screening techniques are an acceptable approach to air quality analyses. One such approach is contained in the EPA document "Screening Procedures for Estimating the Air Quality Impact of Stationary Sources".18 A computerized version of the screening technique, SCREEN, is available.19'20 For the current version of SCREEN, see reference 20. All screening procedures should be adjusted to the site and problem at hand. Close attention should be paid to whether the area should be classified urban or rural in accordance with Section 8.2.8. The climatology of the area should be studied to help define the worst-case meteorological conditions. Agreement should be reached between the model user and the reviewing authority on the choice of the screening model for each analysis, and on the input data as well as the ultimate use of the results. 4-2 Revised 8/95 ------- TABLE 4-1 Preferred Models for Selected Applications in Simple Terrain Short Term (i.e., 1-24 hours) Single Source Multiple Source Rural Urban Rural Urban Complicated Sources" Rural/Urban Buoyant Industrial Line Sources Long Term (i.e., monthly, seasonal or annual) Single Source Multiple Source Rural Urban Rural Urban Complicated Sources'* Rural/Urban Buoyant Industrial Line Sources Land UseModel* CRSTER RAM MPTER RAM ISCST*** RuralBLP CRSTER RAM MPTER COM 2.0 or RAM*™* ISCLT*"" RuralBLP "The models as listed here reflect the applications for which they were originally intended. Several of these models have been adapted to contain options which allow them to be interchanged. For example, ISCST could be substituted for ISCLT. Similarly, for a point source application, ISCST with urban option can be substituted for RAM. Where a substitution is convenient to the user and equivalent estimates are assured, it may be made. ""Complicated sources are those with special problems such as aerodynamic downwash, particle deposition, volume and area sources, etc. ***For the current version of ISC, see reference 58 and note the model description provided in Appendix A of this document. used. *If only a few sources in an urban area are to be modeled, RAM should be 4-4 .Revised 8/95 ------- final plume rise, then the transitional (or gradual) plume rise option for stable conditions should be selected. The standard polar receptor grid found in the Valley Model User's Guide may not be sufficiently dense for all analyses if only one geographical scale factor is used. The user should choose an additional set of receptors at appropriate downwind distances whose elevations are equal to plume height minus 10 meters. Alternatively, the user may exercise the "Valley equivalent" option in COMPLEX I or SCREEN and note the comments above on the placement of receptors in complex terrain models. When using the "Valley equivalent" option in COMPLEX I, set the wind profile exponents (PL) to 0.0, respectively, for all six stability classes. 5.2.1.2 CTSCREEN CTSCREEN may be used to obtain conservative, yet realistic, worst-case estimates for receptors located on terrain above stack height. CTSCREEN accounts for the three-dimensional nature of plume and terrain interaction and requires detailed terrain data representative of the modeling domain. The model description and user's instructions are contained in the user's guide.25 The terrain data must be digitized in the same manner as for CTDMPLUS and a terrain processor is available.23 A discussion of the model's performance characteristics is provided in a technical paper." CTSCREEN is designed to execute a fixed matrix of meteorological values for wind speed (u), standard deviation of horizontal and vertical wind speeds (av, aw) , vertical potential temperature gradient (d6/dz), friction velocity (u,) , Monin- Obukhov length (L), mixing height (Zi) as a function of terrain height, and wind directions for both neutral/stable conditions and unstable convective conditions. Table 5-1 contains the matrix of meteorological variables that is used for each CTSCREEN analysis. There are 96 combinations, including exceptions, for each wind direction for the neutral/stable case, and 108 combinations for the unstable case. The specification of wind direction, however, is handled internally, based on the source and terrain geometry. The matrix was developed from examination of the range of meteorological variables associated with maximum monitored concentrations from the data bases used to evaluate the performance of CTDMPLUS. Although CTSCREEN is designed to address a single source scenario, there are a number of options that can be selected on a case-by-case basis to address multi-source situations. However, the Regional Office should be consulted, and concurrence obtained, on the protocol for modeling multiple sources with CTSCREEN to ensure that the worst case is identified and assessed. The maximum concentration output from CTSCREEN represents a worst-case 1-hour concentration. Time-scaling factors of 0.7 for 3-hour, 0.15 for 24-hour and 0.03 for annual concentration averages are applied internally by CTSCREEN to the highest 1-hour concentration calculated by the model. 5.2.1.3 COMPLEX I If the area is rural, COMPLEX I may be used to estimate concentrations for all averaging times. COMPLEX I is a modification of the MPTER model that incorporates the plume impaction algorithm of the 5-2 Revised 8/95 ------- 6.2.3 Models for Nitrogen Dioxide (Annual Average) A tiered screening approach is recommended to obtain annual average estimates of N02 from point sources for New Source Review analysis, including PSD, and for SIP planning purposes. This multi-tiered approach is conceptually shown in Figure 6-1 below: FIGURE 6-1 Multi-tiered Screening Approach for Estimating Annual NO2 Concentrations from Point Sources Tier 1: Tier 2 : Assume Total Conversion of NO to NO2 1 Multiply Annual NO, Estimate by Empirically Derived NO2 / NO, Ratio a) For Tier 1 (the initial screen), use an appropriate Gaussian model from Appendix A to estimate the maximum annual average concentration and assume a total conversion of NO to NO2. If the concentration exceeds the NAAQS and/or PSD increments for NO2, proceed to the 2nd level screen. b) For Tier 2 (2nd level) screening analysis, multiply the Tier l estimate(s) by an empirically derived NO2 / NO, value of 0.75 (annual national default).36 An annual NO2 / NO, ratio differing from 0.75 may be used if it can be shown that such a ratio is based on data likely to be representative of the location(s) where maximum annual impact from the individual source under review occurs. In the case where several sources contribute to consumption of a PSD increment, a locally derived annual N02 / NO, ratio should also be shown to be representative of the location where the maximum collective impact from the new plus existing sources occurs. In urban areas, a proportional model may be used as a preliminary assessment to evaluate control strategies to meet the NAAQS for multiple minor sources, i.e. minor point, area and mobile sources of NO,; concentrations resulting from major point sources should be estimated sepa- rately as discussed above, then added to the impact of the minor sources. An acceptable screening technique for urban complexes is to assume that all NOX is emitted in the form of NO2 and to use a model from Appendix A for nonreactive pollutants to estimate NO2 concentrations. A more accurate estimate can be obtained by: (1) calculating the annual average concentrations of NO, with an urban model, and (2) converting these estimates to NO2 concentrations using an empirically derived annual NO2 / NO, ratio. A value of 0.75 is recommended for 6-5 Revised 8/95 ------- ------- this ratio. However, a spatially averaged annual NO2 / NO, ratio may be determined from an existing air quality monitoring network and used in lieu of the 0.75 value if it is determined to be representative of prevailing ratios in the urban area by the reviewing agency. To ensure use of appropriate locally derived annual N02 / NO, ratios, monitoring data under consideration should be limited to those collected at monitors meeting siting criteria defined in 40 CFR 58, Appendix D as representative of "neighborhood", "urban", or "regional" scales. Furthermore, the highest annual spatially averaged NO2 / NO, ratio from the most recent 3 years of complete data should be used to foster conservatism in estimated impacts. To demonstrate compliance with N02 PSD increments in urban areas, emissions from major and minor sources should be included in the modeling analysis. Point and area source emissions should be modeled as discussed above. If mobile source emissions do not contribute to localized areas of high ambient N02 concentrations, they should be modeled as area sources. When modeled as area sources, mobile source emissions should be assumed uniform over the entire highway link and allocated to each area source grid square based on the portion of highway link within each grid square. If localized areas of high concentrations are likely, then mobile sources should be modeled as line sources with the preferred model ISCLT. More refined techniques to handle special circumstances may be considered on a case-by-case basis and agreement with the reviewing authority should be obtained. Such techniques should consider individual quantities of NO and NO, emissions, atmospheric transport and dispersion, and atmospheric transformation of NO to NO2. Where they are available, site-specific data on the conversion of NO to N02 may be used. Photochemical dispersion models, if used for other pollutants in the area, may also be applied to the NOX problem. 6-6 Revised 8/95 ------- transport distances are limited in detail. This limitation is a result of the expense to perform the field studies required to verify and improve mesoscale and long range transport models. Particularly important and sparse are meteorological data adequate for generating three dimensional wind fields. Application of models to complicated terrain compounds the difficulty. EPA has completed limited evaluation of several long range transport (LRT) models against two sets of field data. The evaluation results are discussed in the document, "Evaluation of Short-Term Long-Range Transport Models."99-100 For the time being, long range and mesoscale transport models must be evaluated for regulatory use on a case-by-case basis. There are several regulatory programs for which air pathway analysis procedures and modeling techniques have been developed. For continuous emission releases, ISC forms the basis of many analytical techniques. EPA is continuing to evaluate the performance of a number of proprietary and public domain models for intermittent and non-stack emission releases. Until EPA completes its evaluation, it is premature to recommend specific models for air pathway analyses of intermittent and non-stack releases in this guideline. Regional scale models are used by EPA to develop and evaluate national policy and assist State and local control agencies. Two such models are the Regional Oxidant Model (ROM)l01-102-103 and the Regional Acid Deposition Model (RADM) .l04 Due to the level of resources required to apply these models, it is not envisioned that regional scale models will be used directly in most model applications. 7-2 Revised 8/55 ------- ------- 7.2.2 Particulate Matter The new particulate matter NAAQS, promulgated on July 1, 1987 (52 FR 24634) , includes only particles with an aerodynamic diameter less than or equal to a nominal 10 micrometers (PM-10). EPA has also proposed regula- tions for PSD increments measured as PM-10 in a notice published on October 5, 1989 (54 FR 41218). Screening techniques like those identified in Section 4 are also applicable to PM-10 and to large particles. It is recommended that subjectively determined values for "half-life" or pollutant decay not be used as a surrogate for particle removal. Conservative assumptions which do not allow removal or transformation are suggested for screening. Proportional models (rollback/forward) may not be applied for screening analysis, unless such techniques are used in conjunction with receptor modeling. Refined models such as those in Section 4 are recommended for PM-10 and large particles. However, where possible, particle size, gas-to- particle formation, and their effect on ambient concentrations may be consid- ered. For urban-wide refined analyses CDM 2.0 or RAM should be used. CRSTER and MPTER are recommended for point sources of small particles. For source- specific analyses of complicated sources, the ISC model is preferred. No model recommended for general use at this time accounts for secondary particulate formation or other transformations in a manner suitable for SIP control strategy demonstrations. Where possible, the use of receptor models38-39-103'10*'107 in conjunction with dispersion models is encouraged to more precisely characterize the emissions inventory and to validate source specific impacts calculated by the dispersion model. A SIP development guideline,108 model reconciliation guidance,106 and an example model application109 are avail- able to assist in PM-10 analyses and control strategy development. Under certain conditions, recommended dispersion models are not available or applicable. In such circumstances, the modeling approach should, be approved by the appropriate Regional Office on a case-by-case basis. For example, where there is no recommended air quality model and area sources are a predominant component of PM-10, an attainment demonstration may be based on rollback of the apportionment derived from two reconciled receptor models, if the strategy provides a conservative demonstration of attainment. At this time, analyses involving model calculations for distances beyond 50km and under stagnation conditions should also be justified on a case-by-case basis (see Sections 7.2.6 and 8.2.10). As an aid to assessing the impact on ambient air quality of particulate matter generated from prescribed burning activities, reference 110 is available. 7-4 Revised 8/95 ------- ------- 7.2.5 Good Engineering Practice Stack Height The use of stack height credit in excess of Good Engineering Practice (GEP) stack height or credit resulting from any other dispersion technique is prohibited in the development of emission limitations by 40 CFR 51.118 and 40 CFR 51.164. The definitions of GEP stack height and dispersion technique are contained in 40 CFR 51.100. Methods and procedures for making the appropriate stack height calculations, determining stack height credits and an example of applying those techniques are found in references 46, 47, 48, and 49. If stacks for new or existing major sources are found to be less than the height defined by EPA's refined formula for determining GEP height,* then air quality impacts associated with cavity or wake effects due to the nearby building structures should be determined. Detailed downwash screening procedures18 for both the cavity and wake regions should be followed. If more refined concentration estimates are required, the Industrial Source Complex (ISC) model contains algorithms for building wake calculations and should be used. Fluid modeling can provide a great deal of additional information for evaluating and describing the cavity and wake effects. "The EPA refined formula height is defined as H + 1.5L (see Reference 46). 7-7 Revised 8/95 ------- 7.2.8 Air Pathway Analyses (Air Toxics and Hazardous Waste) Modeling is becoming an increasingly important tool for regulatory control agencies to assess the air quality impact of releases of toxics and hazardous waste materials. Appropriate screening techniques"4-"5 for calculating ambient concentrations due to various well-defined neutrally buoyant toxic/hazardous pollutant releases are available. Several regulatory programs within EPA have developed modeling techniques and guidance for conducting air pathway analyses as noted in references 116-129. ISC forms the basis of the modeling procedures for air pathway analyses of many of these regulatory programs and, where identified, is appropriate for obtaining refined ambient concentration estimates of neutrally buoyant continuous air toxic releases from traditional sources. Appendix A to this Guideline contains additional models appropriate for obtaining refined estimates of continuous air toxic releases from traditional sources. Appendix B contains models that may be used on a case-by-case basis for obtaining refined estimates of denser-than-air intermittent gaseous releases, e.g., DEGADIS;130 guidance for the use of such models is also available.131 Many air toxics models require input of chemical properties and/or chemical engineering variables in order to appropriately characterize the source emissions prior to dispersion in the atmosphere; reference 132 is one source of helpful data. In addition, EPA has numerous programs to determine emission factors and other estimates of air toxic emissions. The Regional Office should be consulted for guidance on appropriate emission estimating procedures and any uncertainties that may be associated with them. 7-10 Revised 8/95 ------- 8.2.5 Plume Rise The plume rise methods of Briggs56'57 are incorporated in the preferred models and are recommended for use in all modeling applications. No provisions in these models are made for fumigation or multistack plume rise enhancement or the handling of such special plumes as flares; these problems should be considered on a case-by-case basis. Since there is insufficient information to identify and quantify dispersion during the transitional plume rise period, gradual plume rise is not generally recommended for use. There are two exceptions where the use of gradual plume rise is appropriate: (1) in complex terrain screening procedures to determine close-in impacts; (2) when calculating the effects of building wakes. The building wake algorithm in the ISC model incorporates and automatically (i.e., internally) exercises the gradual plume rise calculations. If the building wake is calculated to affect the plume for any hour, gradual plume rise is also used in downwind dispersion calculations to the distance of final plume rise, after which final plume rise is used. Stack tip downwash generally occurs with poorly constructed stacks and when the ratio of the stack exit velocity to wind speed is small. An algorithm developed by Briggs (Hanna, et al.)57 is the recommended technique for this situation and is found in the point source preferred models. Where aerodynamic downwash occurs due to the adverse influence of nearby structures, the algorithms included in the ISC model58 should be used. 8-7 Revised 8/95 ------- ------- 8.2.7 Gravitational Settling and Deposition An "infinite half-life" should be used for estimates of particle concentrations when Gaussian models containing only exponential decay terms for treating settling and deposition are used. Gravitational settling and deposition may be directly included in a model if either is a significant factor. One preferred model (ISC) contains a settling and deposition algorithm and is recommended for use when particulate matter sources can be quantified and settling and deposition are problems. 8-9 Revised 8/95 ------- 9.3.3.2 Recommendations Site-specific Data Collection The document "On-Site Meteorological Program Guidance for Regulatory Modeling Applications"66 provides recommendations on the collection and use of on-site meteorological data. Recommendations on characteristics, siting, and exposure of meteorological instruments and on data recording, processing, completeness requirements, reporting, and archiving are also included. This publication should be used as a supplement to the limited guidance on these subjects now found in the "Ambient Monitoring Guidelines for Prevention of Significant Deterioration".63 Detailed information on quality assurance is provided in the "Quality Assurance Handbook for Air Pollution Measurement Systems: Volume IV".67 As a minimum, site-specific measurements of ambient air temperature, transport wind speed and direction, and the parameters to determine Pasquill-Gifford (P-G) stability categories should be available in meteorological data sets to be used in modeling. Care should be taken to ensure that meteorological instruments are located to provide representative characterization of pollutant transport between sources and receptors of interest. The Regional Office will determine the appropriateness of the measurement locations. All site-specific data should be reduced to hourly averages. Table 9-3 lists the wind related parameters and the averaging time requirements. Solar Radiation Measurements Total solar radiation should be measured with a reliable pyranometer, sited and operated in accordance with established on-site meteorological guidance.66 Temperature Measurements Temperature measurements should be made at standard shelter height (2m) in accordance with established on-site meteorological guidance .** Temperature Difference Measurements Temperature difference (AT) measurements for use in estimating P-G stability categories using the solar radiation/delta-T (SRDT) methodology (see Stability Categories) should be obtained using two matched thermometers or a reliable thermocouple system to achieve adequate accuracy. Siting, probe placement, and operation of AT systems should be based on guidance found in Chapter 3 of reference 66, and such guidance should be followed when obtaining vertical temperature gradient data for use in plume rise estimates or in determining the critical dividing streamline height. 9-16 Revised 8/95 ------- ------- Wind Measurements For refined modeling applications in simple terrain situations, if a source has a stack below 100m, select the stack top height as the wind measurement height for characterization of plume dilution and transport. For sources with stacks extending above 100m, a 100m tower is suggested unless the stack top is significantly above 100m (i.e., a200m). In cases with stack tops a200m, remote sensing may be a feasible alternative. In some cases, collection of stack top wind speed may be impractical or incompatible with the input requirements of the model to be used. In such cases, the Regional Office should be consulted to determine the appropriate measurement height. For refined modeling applications in complex terrain, multiple level (typically three or more) measurements of wind speed and direction, temperature and turbulence (wind fluctuation statistics) are required. Such measurements should be obtained up to the representative plume height(s) of interest (i.e., the plume height(s) under those conditions important to the determination of the design concentration). The representative plume height(s) of interest should be determined using an appropriate complex terrain screening procedure (e.g., CTSCREEN) and should be documented in the monitoring/modeling protocol. The necessary meteorological measurements should be obtained from an appropriately sited meteorological tower augmented by SODAR if the representative plume height(s) of interest exceed 100m. The meteorological tower need not exceed the lesser of the representative plume height of interest (the highest plume height if there is more than one plume height of interest) or 100m. In general, the wind speed used in determining plume rise is defined as the wind speed at stack top. Specifications for wind measuring instruments and systems are contained in the "On-Site Meteorological Program Guidance for Regulatory Modeling Applications".66 Stability Categories The P-G stability categories, as originally defined, couple near-surface measurements of wind speed with subjectively determined insolation assessments based on hourly cloud cover and ceiling height observations. The wind speed measurements are made at or near 10m. The insolation rate is typically assessed using observations of cloud cover and ceiling height based on criteria outlined by Turner.50 It is recommended that the P-G stability category be estimated using the Turner method with site- specific wind speed measured at or near 10m and representative cloud cover and ceiling height. Implementation of the Turner method, as well as considerations in determining representativeness of cloud cover and ceiling height in cases for which site-specific cloud observations are unavailable, may be found in Section 6 of reference 66. In the absence of requisite data to implement the Turner method, the SRDT method or wind fluctuation statistics (i.e., the aE and OA methods) may be used. The SRDT method, described in Section 6.4.4.2 of reference 66, is modified slightly from that published by Bowen et al. (1983)136 9-17 Revised 8/95 ------- and has been evaluated with three on-site data bases.137 The two methods of stability classification which use wind fluctuation statistics, the aE and OA methods, are also described in detail in Section 6.4.4 of reference 66 (note applicable tables in Section 6). For additional information on the wind fluctuation methods, see references 68-72. Hours in the record having missing data should be treated according to an established data substitution protocol and after valid data retrieval requirements have been met. Such protocols are usually part of the approved monitoring program plan. Data substitution guidance is provided in Section 5.3 of reference 66. Meteorological Data Processors The following meteorological preprocessors are recommended by EPA: RAMMET, PCRAMMET, STAR, PCSTAR, MPRM,135 and METPRO.24 RAMMET is the recommended meteorological preprocessor for use in applications employing hourly NWS data. The RAMMET format is the standard data input format used in sequential Gaussian models recommended by EPA. PCRAMMET138 is the PC equivalent of the mainframe version (RAMMET). STAR is the recommended preprocessor for use in applications employing joint frequency distributions (wind direction and wind speed by stability class) based on NWS data. PCSTAR is the PC equivalent of the mainframe version (STAR). MPRM is the recommended preprocessor for use in applications employing on-site meteorological data. The latest version (MPRM 1.3) has been configured to implement the SRDT method for estimating P-G stability categories. MPRM is a general purpose meteorological data preprocessor which supports regulatory models requiring RAMMET formatted data and STAR formatted data. In addition to on-site data, MPRM provides equivalent processing of NWS data. METPRO is the required meteorological data preprocessor for use with CTDMPLUS. All of the above mentioned data preprocessors are available for downloading from the SCRAM BBS." 9-18 Revised 8/95 ------- 11. Fox, D.G., 1981. Judging Air Quality Model Performance. Bulletin of the American Meteorological Society, 62(5): 599-609. 12. American Meteorological Society, 1983. Synthesis of the Rural Model Reviews. EPA Publication No. EPA-600/3-83-108. U.S. Environmental Protection Agency/ Research Triangle Park, NC. (NTIS No. PB 84-121037) 13. American Meteorological Society, 1984. Review of the Attributes and Performance of Six Urban Diffusion Models. EPA Publication No. EPA-600/S3-84-089. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No.PB 84-236850) 14. White, F.D.(Ed.), J.K.S. Ching, R.L. Dennis and W.H. Snyder, 1985. Summary of Complex Terrain Model Evaluation. EPA Publication No. EPA-600/3-85-060. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 85-236891) 15. Environmental Protection Agency, 1984. Interim Procedures for Evaluating Air Quality Models (Revised). EPA Publication No. EPA-450/4-84-023. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 85-106060) 16. Environmental Protection Agency, 1985. Interim Procedures for Evaluating Air Quality Models: Experience with Implementation. EPA Publication No. EPA-450/4-85-006. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 85-242477) 17. Environmental Protection Agency, 1992. Protocol for Determining the Best Performing Model. EPA Publication No. EPA-454/R-92-025. U.S. Environ- mental Protection Agency, Research Triangle Park, NC. 18. Environmental Protection Agency,1992. Screening Procedures for Estimating the Air Quality Impact of Stationary Sources, Revised. EPA Publication No. EPA-454/R-92-019. U.S. Environmental Protection Agency, Research Triangle Park, NC. 19. Environmental Protection Agency, 1989. Support Center for Regulatory Air Models Bulletin Board System (SCRAM BBS). Source Receptor Analysis Branch, Research Triangle Park, NC. (Docket Nos. A-88-04, II-J-4a and b) 20. Environmental Protection Agency, 1995. SCREENS User's Guide. EPA Publication No. EPA-454/B-95-004. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 95-222766) 21. Environmental Protection Agency, 1987. EPA Complex Terrain Model Development: Final Report. EPA Publication No. EPA-600/3-88-006. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 88-162110) 22. Perry, S.G., D.J. Burns, L.H. Adams, R.J. Paine, M.G. Dennis, M.T. Mills, D.J. Strimaitis, R.J. Yamartino and E.M. Insley, 1989. User's Guide to the Complex Terrain Dispersion Model Plus Algorithms for Unstable Situations (CTDMPLUS) Volume 1; Model Description and User Instructions. EPA Publication No. EPA-600/8-89-041. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 89-181424) 12-2 Revised 8/95 ------- 34. Environmental Protection Agency, 1992. Guideline for Modeling Carbon Monoxide from Roadway Intersections. EPA Publication No. EPA-454/R-92- 005.U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 93-210391) 35. Environmental Protection Agency, 1992. User's Guide for CAL3QHC Version 2: A Modeling Methodology for Predicting Pollutant Concentrations near Roadway Intersections. EPA Publication No. EPA-454/R-92-006. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 93-210250) 36. Chu, S. H. and E. L. Meyer, 1991. Use of Ambient Ratios to Estimate Impact of NOX Sources on Annual NO2 Concentrations. Proceedings, 84th Annual Meeting & Exhibition of the Air & Waste Management Association, Vancouver, B.C.; 16-21 June 1991. (16pp.) (Docket No. A-92-65, II-A-9) 37. U.S. Department of Housing and Urban Development, 1980. Air Quality Considerations in Residential Planning. U.S. Superintendent of Documents, Washington, DC. (GPO Order Nos. 023-000-00577-8, 023-000-00576-0, 023-000-00575-1) 38. Environmental Protection Agency, 1981. Receptor Model Technical Series. Volume I: Overview of Receptor Model Application to Particulate Source Apportionment. EPA Publication No. EPA-450/4-81-016a (NTIS No. PB 82-139429); Volume II: Chemical Mass Balance. EPA Publication No. EPA-450/4-81-016b (NTIS No. PB 82-187345); Volume III (Revised): CMB User's Manual (Version 7.0). EPA Publication No. EPA-450/4-90-004 (NTIS No. PB 90-185067); Volume IV: Technical Considerations In Source Apportionment By Particle Identification. EPA Publication No. EPA-450/4-83-018 (NTIS No. PB 84-103340); Volume V: Source Apportionment Techniques and Considerations in Combining their Use. EPA Publication No. EPA-450/4-84-020 (NTIS No. PB 85-111524); Volume VI: A Guide To The Use of Factor Analysis and Multiple Regression (FA/MR) Techniques in Source Apportionment. EPA Publication No. EPA-450/4-85-007 (NTIS No. PB 86-107638) . U.S. Environmental Protection Agency, Research Triangle Park, NC. 39. Pace, T.G., 1982. The Role of Receptor Models for Revised Particulate Matter Standards. A Specialty Conference on: Receptor Models Applied to Contemporary Pollution Problems. Air Pollution Control Association, Pittsburgh, PA; pp. 18-28. (Docket No. A-80-46, II-P-10) 40. Environmental Protection Agency, 1978. Supplementary Guidelines for Lead Implementation Plans. EPA Publication No. EPA-450/2-78-038. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 82-232737) 41. Environmental Protection Agency, 1983. Updated Information on Approval and Promulgation of Lead Implementation Plans (DRAFT). U.S. Environmental Protection Agency, Research Triangle Park, NC. (Docket No. A-80-46, II-B-38) 42. Environmental Protection Agency, 1979. Protecting Visibility: An EPA Report to Congress. EPA Publication No. EPA-450/5-79-008. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 80-220320) 12-4 Revised 8/95 ------- 54. Pasquill, F., 1976. Atmospheric Dispersion Parameters in Gaussian Plume Modeling, Part II. Possible Requirements for Change in the Turner Workbook Values. EPA Publication No. EPA-600/4-76-030b. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB-258036/3BA) 55. Turner, D.B., 1964. A Diffusion Model for an Urban Area. Journal of Applied Meteorology, 3(1): 83-91. 56. Briggs, G.A., 1975. Plume Rise Predictions. Chapter 3 in Lectures on Air Pollution and Environmental Impact Analyses. American Meteorological Society, Boston, MA; pp. 59-111. 57. Hanna, S.R., G.A. Briggs and R.P. Hosker, Jr., 1982. Plume Rise. Chapter 2 in Handbook on Atmospheric Diffusion. Technical Information Center, U.S. Department of Energy, Washington, DC; pp. 11-24. DOE/TIC-11223 (DE 82002045) 58. Environmental Protection Agency, 1995. User's Guide for the Industrial Source Complex (ISC3) Dispersion Models, Volumes 1 and 2. EPA Publication Nos. EPA-454/B-95-003a & b. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS Nos. PB 95-222741 and PB 95-222758, respectively) 59. Irwin, J.S., 1978. Proposed Criteria for Selection of Urban Versus Rural Dispersion Coefficients. (Draft Staff Report). Meteorology and Assessment Division, U.S. Environmental Protection Agency, Research Triangle Park, NC. (Docket No. A-80-46, II-B-8) 60. Auer, Jr., A.H., 1978. Correlation of Land Use and Cover with Meteorological Anomalies. Journal of Applied Meteorology, 17(5) : 636-643. 61. Brier, G.W., 1973. Validity of the Air Quality Display Model Calibration Procedure. EPA Publication No. EPA-R4-73-017. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB-218716) 62. Environmental Protection Agency, 1985 and ff. Compilation of Air . Pollutant Emission Factors, Volume I: Stationary Point and Area Sources (Fourth Edition; GPO Stock No. 055-000-00251-7), and Supplements; Volume II: Mobile Sources (NTIS PB 87-205266) and Supplement(s). EPA Publication No. AP-42. U.S. Environmental Protection Agency, Research Triangle Park, NC. 63. Environmental Protection Agency, 1987. Ambient Air Monitoring Guidelines for Prevention of Significant Deterioration (PSD). EPA Publication No. EPA-450/4-87-007. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 90-168030) 64. Landsberg, H.E. and W.C. Jacobs, 1951. Compendium of Meteorology. American Meteorological Society, Boston, MA; pp. 976-992. 65. Burton, C.S., T.E. Stoeckenius and J.P. Nordin, 1983. The Temporal Representativeness of Short-Term Meteorological Data Sets: Implications for Air Quality Impact Assessments. Systems Applications, Inc., San Rafael, CA. (Docket No. A-80-46, II-G-11) 12-6 Revised 8/55 ------- ------- 89. Environmental Protection Agency, 1986. Emissions Trading Policy Statement; General Principles for Creation, Banking, and Use of Emission Reduction Credits. Federal Register. 51(233): 43814-43860. 90. Environmental Research and Technology, 1987. User's Guide to the Rough Terrain Diffusion Model (RTDM), Rev. 3.20. ERT Document No. P-D535-585. Environmental Research and Technology, Inc., Concord, MA. (NTIS No. PB 88-171467) 91. Burns, D.J., S.G. Perry and A.J. Cimorelli, 1991. An Advanced Screening Model for Complex Terrain Applications. Paper presented at the 7th Joint Conference on Applications of Air Pollution Meteorology (cosponsored by the American Meteorological Society and the Air & Waste Management Association), January 13-18, 1991, New Orleans, LA. 92. Perry, S.G., 1992. CTDMPLUS: A Dispersion Model for Sources near Complex Topography. Part I: Technical Formulations. Journal of Applied Meteorology, 31(7): 633-645. 93. Paumier, J.O., S.G. Perry and D.J. Burns, 1992. CTDMPLUS: A Dispersion Model for Sources near Complex Topography. Part II: Performance Characteristics. Journal of Applied Meteorology, 31(7): 646-660. 94. Environmental Protection Agency, 1986. Evaluation of Mobile Source Air Quality Simulation Models. EPA Publication No. EPA-450/4-86-002. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 86-167293) 95. Shannon, J.D., 1987. Mobile Source Modeling Review. A report prepared under a cooperative agreement with the Environmental Protection Agency. (Docket No. A-88-04, II-J-2) 96. Environmental Protection Agency, 1991. Emission Inventory Requirements for Carbon Monoxide State Implementation Plans. EPA Publication No. EPA-450/4-91-011. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 92-112150) 97. Environmental Protection Agency, 1992. Guideline for Regulatory Application of the Urban Airshed Model for Areawide Carbon Monoxide. EPA Publication No. EPA-450/4-92-Olla and b. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS Nos. PB 92-213222 and PB 92-213230) 98. Environmental Protection Agency, 1992. Technical Support Document to Aid States with the Development of Carbon Monoxide State Implementation Plans. EPA Publication No. EPA-452/R-92-003. U.S. Environmental Protection Agency, Research Triangle Park, NC. {NTIS No. PB 92-233055) 99. Environmental Protection Agency, 1986. Evaluation of Short-Term Long- Range Transport Models, Volumes I and II. EPA Publication Nos. EPA-450/4-86-016a and b. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS Nos. PB 87-142337 and PB 87-142345) 12-9 Revised 8/95 ------- 131. Environmental Protection Agency, 1991. Guidance on the Application of Refined Models for Air Toxics Releases. EPA Publication No. EPA-450/4-91-007. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 91-190983) 132. Perry, R. H. and Chilton, C. H., 1973. Chemical Engineers' Handbook. Fifth Edition, McGraw-Hill Book Company, New York, NY. 133. Environmental Protection Agency, 1988. User's Guide to SDM - A Shoreline Dispersion Model. EPA Publication No. EPA-450/4-88-017. U.S. Environ- mental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 89-164305) 134. Environmental Protection Agency, 1987. Analysis and Evaluation of Statistical Coastal Fumigation Models. EPA Publication No. EPA-450/4-87002. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 87-175519) 135. Irwin, J.S., J.O. Paumier and R.W. Erode, 1988. Meteorological Processor for Regulatory Models (MPRM 1.2) User's Guide. EPA Publication No. EPA-600/3-88-043R. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 89-127526) 136. Bowen, B.M., J.M. Dewart and A.I. Chen, 1983. Stability Class Determination: A Comparison for One Site. Proceedings, Sixth Symposium on Turbulence and Diffusion. American Meteorological Society, Boston, MA; pp. 211-214. (Docket No. A-92-65, II-A-7) 137. Environmental Protection Agency, 1993. An Evaluation of a Solar Radiation/Delta-T (SRDT) Method for Estimating Pasquill-Gifford (P-G) Stability Categories. EPA Publication No. EPA-454/R-93-055. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 94-113958) 138. Environmental Protection Agency, 1993. PCRAMMET User's Guide. EPA Publication No. EPA-454/B-93-009. U.S. Environmental Protection Agency, Research Triangle Park, NC. 12-13 Revised 8/95 ------- APPENDIX A Table of Contents A.O INTRODUCTION AND AVAILABILITY A-l A.I BUOYANT LINE AND POINT SOURCE DISPERSION MODEL (BLP) . . . A-3 A. 2 CALINE3 A-7 A. 3 CLIMATOLOGICAL DISPERSION MODEL (COM 2.0) A-11 A.4 GAUSSIAN-PLUME MULTIPLE SOURCE AIR QUALITY ALGORITHM (RAM) A-15 A. 5 INDUSTRIAL SOURCE COMPLEX MODEL (ISC3) A-21 A.6 MULTIPLE POINT GAUSSIAN DISPERSION ALGORITHM WITH TERRAIN ADJUSTMENT (MPTER) A-25 A. 7 SINGLE SOURCE (CRSTER) MODEL A-29 A. 8 URBAN AIRSHED MODEL (UAM) A-33 A. 9 OFFSHORE AND COASTAL DISPERSION MODEL (OCD) A-39 A. 10 EMISSIONS AND DISPERSION MODEL SYSTEM (EDMS) A-43 A.11 COMPLEX TERRAIN DISPERSION MODEL PLUS ALGORITHMS FOR UNSTABLE SITUATIONS (CTDMPLUS) A-47 A.REF REFERENCES AR-1 A-i Revised 8/95 ------- A.5 INDUSTRIAL SOURCE COMPLEX MODEL (ISC3) Reference: Environmental Protection Agency, 1995. User's Guide for the Industrial Source Complex (ISC3) Dispersion Models, Volumes 1 and 2. EPA Publication Nos. EPA-454/B-95-003a & b. Envi- ronmental Protection Agency, Research Triangle Park, NC. (NTIS Nos. PB 95-222741 and PB 95-222758, respectively) Availabilitv The model code is available on the Support Center for Regu- latory Air Models Bulletin Board System and also from the National Technical Information Service (see Section A.O). Abstract: The ISC3 model is a steady-state Gaussian plume model which can be used to assess pollutant concentrations from a wide variety of sources associated with an industrial source complex. This model can account for the following: settling and dry deposition of particles; downwash; area, line and volume sources; plume rise as a function of downwind dis- tance; separation of point sources; and limited terrain adjustment. It operates in both long-term and short-term modes. a. Recommendations for Regulatory Use ISC3 is appropriate for the following applications: 0 industrial source complexes; 0 rural or urban areas; 0 flat or rolling terrain; 0 transport distances less than 50 kilometers; 0 1-hour to annual averaging times,- and 0 continuous toxic air emissions. The following options should be selected for regulatory applications: For short term or long term modeling, set the regulatory "default option"; i.e., use the keyword DFAULT, which automatically selects stack tip downwash, final plume rise, buoyancy induced dispersion (BID), the vertical potential temperature gradient, a treatment for calms, the appropriate wind profile exponents, the appropriate value for pollutant half-life, and a revised building wake effects algo- rithm; set the "rural option" (use the keyword RURAL) or "urban option" (use the keyword URBAN) ; and set the "concentration option" (use the keyword CONC) . A-21 Revised 8/95 ------- b. Input Requirements Source data: location, emission rate, physical stack height, stack gas exit velocity, stack inside diameter, and stack gas temperature. Option- al inputs include source elevation, building dimensions, particle size distribution with corresponding settling velocities, and surface reflec- tion coefficients. Meteorological data: ISCST3 requires hourly surface weather data from the preprocessor program RAMMET, which provides hourly stability class,wind direction, wind speed, temperature, and mixing height. For ISCLT3, input includes stability wind rose (STAR deck), average afternoon mixing height, average morning mixing height, and average air tempera- ture. Receptor data: coordinates and optional ground elevation for each receptor. c. Output Printed output options include: 0 program control parameters, source data, and receptor data; 0 tables of hourly meteorological data for each specified day; o "N"-day average concentration or total deposition calculated at each receptor for any desired source combinations; 0 concentration or deposition values calculated for any desired source combinations at all receptors for any specified day or time period within the day; 0 tables of highest and second highest concentration or deposition values calculated at each receptor for each specified time period during a(n) "N"-day period for any desired source combinations, and tables of the maximum 50 concentration or deposition values calcu- lated for any desired source combinations for each specified time period. d. Type of Model ISC3 is a Gaussian plume model. It has been revised to perform a double integration of the Gaussian plume kernel for area sources. e. Pollutant Types ISC3 may be used to model primary pollutants and continuous releases of toxic and hazardous waste pollutants. Settling and deposition are treated. A-22 Revised 8/95 ------- f. Source-Receptor Relationships ISC3 applies user-specified locations for point, line, area and volume sources, and user-specified receptor locations or receptor rings. User input topographic evaluation for each receptor is used. Elevations above stack top are reduced to the stack top elevation, i.e., "terrain chopping". User input height above ground level may be used when necessary to simulate impact at elevated or "flag pole" receptors, e.g., on buildings. Actual separation between each source-receptor pair is used. g. Plume Behavior ISC3 uses Briggs (1969, 1971, 1975) plume rise equations for final rise. Stack tip downwash equation from Briggs (1974) is used. Revised building wake effects algorithm is used. For stacks higher than building height plus one-half the lesser of the building height or building width, the building wake algorithm of Huber and Snyder (1976) is used. For lower stacks, the building wake algorithm of Schulman and Scire (Schulman and Hanna, 1986) is used, but stack tip downwash and BID are not used. For rolling terrain (terrain not above stack height), plume centerline is horizontal at height of final rise above source. Fumigation is not treated. h. Horizontal Winds Constant, uniform (steady-state) wind is assumed for each hour. Straight line plume transport is assumed to all downwind distances. Separate wind speed profile exponents (EPA, 1980) for both rural and urban cases are used. An optional treatment for calm winds is included for short term modeling. i. Vertical Wind Speed Vertical wind speed is assumed equal to zero. A-23 Revised 8/95 ------- j. Horizontal Dispersion Rural dispersion coefficients from Turner (1969) are used, with no adjustments for surface roughness or averaging time. Urban dispersion coefficients from Briggs (Gifford, 1976) are used. Buoyancy induced dispersion (Pasquill, 1976) is included. Six stability classes are used. k. Vertical Dispersion Rural dispersion coefficients from Turner (1969) are used, with no adjustments for surface roughness. Urban dispersion coefficients from Briggs (Gifford, 1976) are used. Buoyancy induced dispersion (Pasquill, 1976) is included. Six stability classes are used. Mixing height is accounted for with multiple reflections until the vertical plume standard deviation equals 1.6 times the mixing height; uniform vertical mixing is assumed beyond that point. Perfect reflection is assumed at the ground. 1. Chemical Transformation Chemical transformations are treated using exponential decay. Time constant is input by the user. m. Physical Removal Dry deposition effects for particles are treated using a resistance formulation in which the deposition velocity is the sum of the resistances to pollutant transfer within the surface layer of the atmosphere, plus a gravitational settling term (EPA, 1994), based on the modified surface depletion scheme of Horst (1983). n. Evaluation Studies Bowers, J. F., and A. J. Anderson, 1981. An Evaluation Study for the Industrial Source Complex (ISC) Dispersion Model, EPA Publication No. EPA-450/4-81-002. U.S. Environmental Protection Agency, Research Triangle Park, NC. Bowers, J. F., A. J. Anderson, and W. R. Margraves, 1982. Tests of the Industrial Source Complex (ISC) Dispersion Model at the Armco Middle- town, Ohio Steel Mill, EPA Publication No. EPA-450/4-82-006. U.S. Environmental Protection Agency, Research Triangle Park, NC. A-24 Revised 8/95 ------- Environmental Protection Agency/ 1992. Comparison of a Revised Area Source Algorithm for the Industrial Source Complex Short Term Model and Wind Tunnel Data. EPA Publication No. EPA-454/R-92-014. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 93-226751) Environmental Protection Agency, 1992. Sensitivity Analysis of a Revised Area Source Algorithm for the Industrial Source Complex Short Term Model. EPA Publication No. EPA-454/R-92-015. U.S. Environmental Protection Agency/ Research Triangle Park, NC. (NTIS No. PB 93-226769) Environmental Protection Agency, 1992. Development and Evaluation of a Revised Area Source Algorithm for the Industrial Source Complex Long Term Model. EPA Publication No. EPA-454/R-92-016. U.S. Environ- mental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 93-226777) Environmental Protection Agency, 1994. Development and Testing of a Dry Deposition Algorithm (Revised). EPA Publication No. EPA-454/R-94- 015. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 94-183100) Scire, J. S., and L. L. Schulman, 1981. Evaluation of the BLP and ISC Models with SF6 Tracer Data and S02 Measurements at Aluminum Reduction Plants. Air Pollution Control Association Specialty Conference on Dispersion Modeling for Complex Sources, St. Louis, MO. Schulman, L. L., and S. R. Hanna, 1986. Evaluation of Downwash Modification to the Industrial Source Complex Model. Journal of the Air Pollution Control Association, 36: 258-264. A-24a Revised 8/95 ------- ------- Catalano, J. A., 1986. Addendum to the User's Manual for the Single Source (CRSTER) Model. EPA Publication No. EPA-600/8-86-041. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 87-145843) Gery, M. W., G. Z. Whitten and J. P. Killus, 1988. Development and Testing of CBM-IV for Urban and Regional Modeling. EPA Publication No. EPA-600/3-88-012. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS No. PB 88-180039) Horst, T. W., 1983. A Correction to the Gaussian Source-depletion Model. In Precipitation Scavenging. Dry Deposition and Resuspension. H. R. Pruppacher, R. G. Semonin, and W. G. N. Slinn, eds., Elsevier, NY. Petersen, W. B., 1980. User's Guide for HIWAY-2 A Highway Air Pollution Model. EPA Publication No. EPA-600/8-80-018. U.S. Environmental Protection Agency, Research Triangle Park, NC. (NTIS PB 80-227556) Rao, T. R. and M. T. Keenan, 1980. Suggestions for Improvement of the EPA- HIWAY Model. Journal of the Air Pollution Control Association, 30: 247-256 (and reprinted as Appendix C in Petersen, 1980) . Segal, H. M., 1983. Microcomputer Graphics in Atmospheric Dispersion Modeling. Journal of the Air Pollution Control Association, 23: 598-600. AR-3 Revised 8/95 ------- APPENDIX B Table of Contents B.O INTRODUCTION B-l B.I AIR QUALITY DISPLAY MODEL (AQDM) B-3 B.2 AIR RESOURCES REGIONAL POLLUTION ASSESSMENT (ARRPA) MODEL . B-7 B.3 APRAC-3 B-ll B.4 COMPTER B-15 B.5 Deleted B.6 ERT VISIBILITY MODEL B-23 B.7 HIWAY-2 B-27 B.8 INTEGRATED MODEL FOR PLUMES AND ATMOSPHERIC CHEMISTRY IN COMPLEX TERRAIN (IMPACT) B-31 B.9 LONGZ B-35 B.O MARYLAND POWER PLANT SITING PROGRAM (PPSP) MODEL B-39 B.ll MESOSCALE PUFF MODEL (MESOPUFF II) B-43 B.12 MESOSCALE TRANSPORT DIFFUSION AND DEPOSITION MODEL FOR INDUSTRIAL SOURCES (MTDDIS) B-47 B.13 MODELS 3141 AND 4141 B-51 B.14 MULTIMAX B-55 B.15 Deleted B.16 MULTI-SOURCE (SCSTER) MODEL B-63 B.17 PACIFIC GAS AND ELECTRIC PLUMES MODEL B-67 B.I8 PLMSTAR AIR QUALITY SIMULATION MODEL B-71 B.19 PLUME VISIBILITY MODEL (PLUVUE II) B-75 B.20 POINT, AREA, LINE SOURCE ALGORITHM (PAL) B-79 B.21 RANDOM WALK ADVECTION AND DISPERSION MODEL (RADM) B-83 B.22 REACTIVE PLUME MODEL (RPM-II) B-87 B-i Revised 2/93 ------- B.23 REGIONAL TRANSPORT MODEL (RTM-II) B-91 B.24 SHORTZ B-95 B.25 SIMPLE LINE-SODRCE MODEL (GMLINE) B-99 B.26 TEXAS CLIMATOLOGICAL MODEL (TCM) B-103 B.27 TEXAS EPISODIC MODEL (TEM) B-107 B.28 A.VACTA II MODEL B-lll B.29 SHORELINE DISPERSION MODEL (SDM) B-115 B.30 WYNDvalley MODEL B-118 B.31 DENSE GAS DISPERSION MODEL (DEGADIS) B-122 B.32 HGSYSTEM B-127 B.33 SLAB B-131 B.REF REFERENCES BR-1 B-ii Revised 8/95 ------- B.32 HGSYSTEM: Dispersion Models for Ideal Gases and Hydrogen Fluoride References: Post, L. (ed.), 1994. HGSYSTEM 3.0 Technical Reference Manual. Shell Research Limited, Thornton Research Centre, Chester, United Kingdom. (TNER 94.059) Post, L., 1994. HGSYSTEM 3.0 User's Manual. Shell Research Limited, Thornton Research Centre, Chester, United Kingdom. (TNER 94.059) Availabilitv: Technical Contacts: Abstract: The PC-DOS version of the HGSYSTEM software (HGSYSTEM: Version 3.0, Programs for modeling the dispersion of ideal gas and hydrogen fluoride releases, executable programs and source code can be installed from floppy diskettes. These diskettes and all documentation are available as a package from API [(202) 682-8340] or NTIS (see Section B.0). Doug N. Blewitt AMOCO Corporation 1670 Broadway / MC 2018 Denver, CO 80201 (303) 830-5312 Howard J. Feldman American Petroleum Institute 1220 L Street, Northwest Washington, D.C. 20005 (202) 682-8340 HGSYSTEM is a PC-based software package consisting of mathematical models for estimating of one or more consecutive phases between spillage and near-field and far-field dispersion of a pollutant. The pollutant can be either a two-phase, multi-compound mixture of non-reactive compounds or hydrogen fluoride (HP) with chemical reactions. The individual models are: Database program: DATAPROP generates physical properties used in other HGSYSTEM models Source term models: SPILL HFSPILL LPOOL transient liquid release from a pressurized vessel SPILL version specifically for HF evaporating multi-compound liquid pool model Near-field dispersion models: AEROPLDME high-momentum jet dispersion model HFPLUME AEROPLUME version specifically for HF HEGABOX dispersion of instantaneous heavy gas releases Far-field dispersion models: HEGADAS(S,T) heavy gas dispersion (steady-state and transient version) PGPLUME passive Gaussian dispersion Utility programs: HFFLASH POSTHS/POSTHT PROFILE GET2COL flashing of HF from pressurized vessel post-processing of HEGADAS(S,T) results post-processor for concentration contours of airborne plumes utility for data retrieval The models assume flat, unobstructed terrain. HGSYSTEM can be used to model steady-state, finite-duration, instantaneous and time dependent releases, depending on the individual model used. The models can be run consecutively, with relevant data being passed on from one model to the next using link files. The models can be run in batch mode or using an iterative utility program. B-127 Revised 8/95 ------- a. Recommendations for Regulatory Use HGSYSTEM can be used as a refined model to estimate short-term ambient concentrations. For toxic chemical releases {non-reactive chemicals or hydrogen fluoride; 1-hour or less averaging times) the expected area of exposure to concentrations above specified threshold values can be determined. For flammable non-reactive gases it can be used to determine the area in which the cloud may ignite. b. Input Requirements HFSPILL input data: reservoir data (temperature, pressure, volume, HF mass, mass-fraction water), pipe-exit diameter and ambient pressure. . EVAP input data: spill rate, liquid properties, and evaporation rate (boiling pool) or ambient data (non-boiling pool). HFPLUME and PLUME input data: reservoir characteristics, pollutant parameters, pipe/release data, ambient conditions, surface roughness and stability class. HEGADAS input data: ambient conditions, pollutant parameters, pool data or data at transition point, surface roughness, stability class and averaging time. PGPLUME input data: link data provided by HFPLDME and the averaging time. c. Output The HGSYSTEM models contain three post-processor programs which can be used to extract modeling results for graphical display by external software packages. GET2COL can be used to extract data from the model output files. HSPOST can be used to develop isopleths, extract any 2 parameters for plotting and correct for finite release duration. HTPOST can be used to produce time history plots. HFSPILL output data: reservoir mass, spill rate, and other reservoir variables as a function of time. For HF liquid, HFSPILL generates link data to HFPLUME for the initial phase of choked liquid flow (flashing jet), and link data to EVAP for the subsequent phase of unchoked liquid flow (evaporating liquid pool). EVAP output data: pool dimensions, pool evaporation rate, pool mass and other pool variables for steady state conditions or as a function of time. EVAP generates link data to the dispersion model HEGADAS (pool dimensions and pool evaporation rate). HFPLUME and PLUME output data: plume variables (concentration, width, centroid height, temperature, velocity, etc.) as a function of downwind distance. HEGADAS output data: concentration variables and temperature as a function of downwind distance and (for transient case) time. PGPLUME output data: concentration as a function of downwind distance, cross-wind distance and height. B-128 Revised 8/95 ------- d. Type of Model HGSYSTEM is made up of four types of dispersion models. HFPLDME and PLUME simulate the near-field dispersion and PGPLDME simulates the passive-gas dispersion downwind of a transition point. HEGADAS simulates the ground-level heavy-gas dispersion. e. Pollutant Types HGSYSTEM may be used to model non-reactive chemicals or hydrogen fluoride. f. Source-Receptor Relationships HGSYSTEM estimates the expected area of exposure to concentrations above user-specified threshold values. By imposing conservation of mass, momentum and energy the concentration, density, speed and temperature are evaluated as a function of downwind distance. g. Plume Behavior HFPLUME and PLUME: (l) are steady-state models assuming a top-hat profile with cross-section averaged plume variables; and (2) the momentum equation is taken into account for horizontal ambient shear, gravity, ground collision, gravity-slumping pressure forces and ground-surface drag. HEGADAS: assumes the heavy cloud to move with the ambient wind speed, and adopts a power-law fit of the ambient wind speed for the velocity profile. PGPLUME: simulates the passive-gas dispersion downwind of a transition point from HFPLUME or PLUME for steady-state and finite duration releases. h. Horizontal Winds A power law fit of the ambient wind speed is used. i. Vertical Wind Speed Not treated. j. Horizontal Dispersion HFPLUME and PLUME: Plume dilution is caused by air entrainment resulting from high plume speeds, trailing vortices in wake of falling plume (before touchdown), ambient turbulence and density stratification. Plume dispersion is assumed to be steady and momentum-dominated, and effects of downwind diffusion and wind meander (averaging time) are not taken into account. B-123 Revised 8/95 ------- HEGADAS: This model adopts a concentration similarity profile expressed in terms of an unknown center-line ground-level concentration and unknown vertical/cross-wind dispersion parameters. These quantities are determined from a number of basic equations describing gas-mass conservation, air entrainment (empirical law describing vertical top- entrainment in terms of global Richardson number), cross-wind gravity spreading (initial gravity spreading followed by gravity-current collapse) and cross-wind diffusion (Briggs formula). PGPLDME: It assumes a Gaussian concentration profile in which the cross- wind and vertical dispersion coefficients are determined by empirical expressions. All unknown parameters in this profile are determined by imposing appropriate matching criteria at the transition point. k. Vertical Dispersion See description above. 1. Chemical Transformation Not treated. m. Physical Removal Not treated. n. Evaluation Studies PLUME has been validated against field data for releases of liquified propane, and wind tunnel data for buoyant and vertically-released dense plumes. HFPLUME and PLUME have been validated against field data for releases of HF (Goldfish experiments) and propane releases. In addition, the plume rise algorithms have been tested against Hoot, Meroney, and Peterka, Ooms and Petersen databases. HEGADAS has been validated against steady and transient releases of liquid propane and LNG over water (Maplin Sands field data), steady and finite-duration pressurized releases of HF (Goldfish experiments; linked with HFPLUME), instantaneous release of Freon (Thorney Island field data; linked with the box model HEGABOX) and wind tunnel data for steady, isothermal dispersion. Validation studies are contained in the following references. McFarlane, K., Prothero, A., Puttock, J.S., Roberts, P.T. and Witlox, H.W.M., 1990. Development and validation of atmospheric dispersion models for ideal gases and hydrogen fluoride, Part I: Technical Reference Manual. Report TNER.90.015. Thornton Research Centre, Shell Research, Chester, England. [EGG 1067-1151] (NTIS No. DE 93-000953) Witlox, H.W.M., McFarlane, K., Rees, F.J., and Puttock, J.S., 1990. Development and validation of atmospheric dispersion models for ideal gases and hydrogen fluoride, Part II: HGSYSTEM Program User's Manual. Report TNER.90.016. Thornton Research Centre, Shell Research, Chester, England. [EGG 1067-1152] (NTIS No. DE 93-000954) B-130 Revised 8/95 ------- B.33 SLAB Reference: Ennak, D.L., 1990. User's Manual for SLAB: An Atmospheric Dispersion Model for Denser-than-Air Releases (UCRL-MA- 105607), Lawrence Livermore National Laboratory. Availability: The computer code can be obtained from: Energy Science and Technology Center P.O. Box 1020 Oak Ridge, TN 37830 (615) 576-2606 The User's Manual (NTIS No. DE 91-008443) can be obtained from: Computer Products National Technical Information Service U.S. Department of Commerce Springfield, VA 22161 (703) 487-4650 (As of this publication, the computer code is also available on the Support Center for Regulatory Air Models Bulletin Board System (Upload/Download Area; see Section B.O.) Abstract: The SLAB model is a computer model, PC-based, that simulates the atmospheric dispersion of denser-than-air releases. The types of releases treated by the model include a ground-level evaporating pool, an elevated horizontal jet, a stack or elevated vertical jet and an instantaneous volume source. All sources except the evaporating pool may be characterized as aerosols. Only one type of release can be processed in any individual simulation. Also, the model simulates only one set of meteorological conditions; therefore direct application of the model over time periods longer than one or two hours is not recommended. a. Recommendations for use The SLAB model should be used as a refined model to estimate spatial and temporal distribution of short-term ambient concentration (e.g., 1-hour or less averaging times) and the expected area of exposure to concentrations above specified threshold values for toxic chemical releases where the release is suspected to be denser than the ambient air. B-131 Revised 8/95 ------- b. Input Requirements The SLAB model is executed in the batch mode. Data are input directly from an external input file. There are 29 input parameters required to run each simulation. These parameters are divided into 5 categories by the user's guide: source type, source properties, spill properties, field properties, and meteorological parameters. The model is not designed to accept real-time meteorological data or convert units of input values. Chemical property data are not available within the model and must be input by the user. Some chemical and physical property data are available in the user's guide. Source type is chosen as one of the following: evaporating pool release, horizontal jet release, vertical jet or stack release, or instantaneous or short duration evaporating pool release. Source property data requirements are physical and chemical properties (molecular weight, vapor heat capacity at constant pressure; boiling point; latent heat of vaporization; liquid heat capacity; liquid density; saturation pressure constants), and initial liquid mass fraction in the release. Spill properties include: source temperature, emission rate, source dimensions, instantaneous source mass, release duration, and elevation above ground level. Required field properties are: desired concentration averaging time, maximum downwind distance (to stop the calculation), and four separate heights at which the concentration calculations are to be made. Meteorological parameter requirements are: ambient measurement height, ambient wind speed at designated ambient measurement height, ambient temperature, surface roughness, relative humidity, atmospheric stability class, and inverse Monin-Obukhov length (optional, only used as an input parameter when stability class is unknown). c. Output No graphical output is generated by the current version of this program. The output print file is automatically saved and must be sent to the appropriate printer by the user after program execution. Printed output includes in tabular form: Listing of model input data; Instantaneous spatially-averaged cloud parameters - time, downwind distance, magnitude of peak concentration, cloud dimensions (including length for puff-type simulations), volume (or mole) and mass fractions, downwind velocity, vapor mass fraction, density, temperature, cloud velocity, vapor fraction, water content, gravity flow velocities, and entrainment velocities; B-132 Revised 8/95 ------- Time-averaged cloud parameters - parameters which may be used externally to calculate time-averaged concentrations at any location within the simulation domain (tabulated as functions of downwind distance); Time-averaged concentration values at plume centerline and at five off- centerline distances (off-centerline distances are multiples of the effective cloud half-width, which varies as a function of downwind distance) at four user-specified heights and at the height of the plume centerline. d. Type of Model As described by Ermak (1989), transport and dispersion are calculated by solving the conservation equations for mass, species, energy, and momentum, with the cloud being modeled as either a steady-state plume, a transient puff, or a combination of both, depending on the duration of the release. In the steady-state plume mode, the crosswind-averaged conservation equations are solved and all variables depend only on the downwind distance. In the transient puff mode, the volume-averaged conservation equations are solved, and all variables depend only on the downwind travel time of the puff center of mass. Time is related to downwind distance by the height-averaged ambient wind speed. The basic conservation equations are solved via a numerical integration scheme in space and time. e. Pollutant Types Pollutants are assumed to be non-reactive and non-depositing dense gases or liquid-vapor mixtures (aerosols). Surface heat transfer and water vapor flux are also included in the model. f. Source-Receptor Relationships Only one source can be modeled at a time. There is no limitation to the number of receptors; the downwind receptor distances are internally-calculated by the model. The -SLAB calculation is carried out up to the user-specified maximum downwind distance. The model contains submodels for the source characterization of evaporating pools, elevated vertical or horizontal jets, and instantaneous volume sources. g. Plume Behavior Plume trajectory and dispersion is based on crosswind-averaged mass, species, energy, and momentum balance equations. Surrounding terrain is assumed to be flat and of uniform surface roughness. No obstacle or building effects are taken into account. h. Horizontal Winds A power law approximation of the logarithmic velocity profile which accounts for stability and surface roughness is used. B-133 Revised 8/95 ------- i. Vertical Wind Speed Not treated. j. Vertical Dispersion The crosswind dispersion parameters are calculated from formulas reported by Morgan et al. (1983), which are based on experimental data from several sources. The formulas account for entrainment due to atmospheric turbulence, surface friction, thermal convection due to ground heating, differential motion between the air and the cloud, and damping due to stable density stratification within the cloud. k. Horizontal Dispersion The horizontal dispersion parameters are calculated from formulas similar to those described for vertical dispersion, also from the work of Morgan, et al. (1983) . 1. Chemical Transformation The thermodynamics of the mixing of the dense gas or aerosol with ambient air (including water vapor) are treated. The relationship between the vapor and liquid fractions within the cloud is treated using the local thermodynamic equilibrium approximation. Reactions of released chemicals with water or ambient air are not treated. m. Physical Removal Not treated. n. Evaluation Studies Blewitt, D. N., J. F. Yohn, and D. L. Ermak, 1987. An Evaluation of SLAB and DEGADIS Heavy Gas Dispersion Models Using the HF Spill Test Data, Proceedings, AIChE International Conference on Vapor Cloud Modeling, Boston, MA, November, pp. 56-80. Ermak, D. L., S.T. Chan, D. L. Morgan, and L. K. Morris, 1982. A Compar- ison of Dense Gas Dispersion Model Simulations with Burro Series LNG Spill Test Results, J. Haz. Matls., 6: 129-160. Zapert, J. G., R. J. Londergan, and H. Thistle, 1991. Evaluation of Dense Gas Simulation Models. EPA Publication No. EPA-450/4-90-018. U.S. Environmental Protection Agency, Research Triangle Park, NC. B-134 Revised 8/95 ------- Whitten, G. Z., J. P. Killus, and H. Hogo, 1980. Modeling of Simulated Photochemical Smog with Kinetic Mechanisms. Volume 1. Final Report. EPA Publication No. EPA-600/3-80-028a. U.S. Environmental Protection Agency* Research Triangle Park, NC. Beals, 6. A., 1971. A Guide to Local Dispersion of Air Pollutants. Air Weather Service Technical Report #214 (April 1971) . Colenbrander, G. W., 1980. A Mathematical Model for the Transient Behavior of Dense Vapor Clouds, 3rd International Symposium on Loss Prevention and Safety Promotion in the Process Industries, Basel, Switzerland. Green, A. E., Singhal R. P., and R. Venkateswar, 1980. Analytical Extensions of the Gaussian Plume Model. Journal of the Air Pollution Control Association, 30: 773-776. MacCready, P. B., Baboolal, L. B., and P. B. Lissaman, 1974. Diffusion and Turbulence Aloft Over Complex Terrain. Preprint Volume, AMS Symposium on Atmospheric Diffusion and Air Pollution, Santa Barbara, CA. American Meteoro- logical Society, Boston, MA. Slade, D. H., 1968. Meteorology and Atomic Energy. U.S. Atomic Energy Commis- sion, 445 pp. (NTIS No. TID-24190) Ermak, D. L., 19.89. A Description of the SLAB Model, presented at JANNAF Safety and Environmental Protection Subcommittee Meeting, San Antonio, TX, April, 1989. Morgan, D. L., Jr., L. K. Morris, and D. L. Ermak, 1983. SLAB: A Time- Dependent Computer Model for the Dispersion of Heavy Gas Released in the Atmosphere, UCRL-53383, Lawrence Livermore National Laboratory, Livermore, CA. BR-4 Revised 8/95 ------- TECHNICAL REPORT DATA (Please read Instructions on reverse before completing) 1. REPORT NO. EPA-450/2-78-027R-C 3. RECIPIENT'S ACCESSION NO. 4. TITLE AND SUBTITLE Supplement C to the Guideline on Air Quality Models (Revised) 5. REPORT DATE August 1995 6. PERFORMING ORGANIZATION CODE 7. AUTHOR(S) 8. PERFORMING ORGANIZATION REPORT NO. 9. PERFORMING ORGANIZATION NAME AND ADDRESS 10. PROGRAM ELEMENT NO. U.S. Environmental Protection Agency Emissions, Monitoring, and Analysis Division (MD-14) Office of Air Quality Planning and Standards Research Triangle Park, NC 27711 11. CONTRACT/GRANT NO. 12. SPONSORING AGENCY NAME AND ADDRESS 13. TYPE OF REPORT AND PERIOD COVERED 14. SPONSORING AGENCY CODE 15. SUPPLEMENTARY NOTES 16. ABSTRACT The Guideline (published as Appendix W to 40 CFR Part 51) serves as the basis by which air quality models are to be used for demonstrations associated with SIP (State Implementation Plan) revisions, AQMA (Air Quality Maintenance Area) analyses, regional classifications for episode planning, new source review, including that pertaining to PSD (Prevention of Significant Deterioration). It is intended for use by EPA Regional Offices in judging the adequacy of modeling analyses performed by EPA, by State and local agencies, and by industry and its consultants. It also identifies modeling techniques and data bases that EPA considers acceptable. The Guideline makes specific recommendations concerning air quality models, data bases, and general requirements for making estimates. This document is Supplement C to the Guideline. Supplement C: (1) revises the ISC model by incorporating improved area source and dry deposition algorithms (the integrated model is renamed ISC3); (2) adopts a solar radiation/delta-T method for estimating Pasquill-Gifford stability categories using on-site meteorological data; (3) adopts a new screening approach for assessing annual NO2 impacts; and (4) adds SLAB and HGSYSTEM as alternative models in Appendix B. 17. KEY WORDS AND DOCUMENT ANALYSIS DESCRIPTORS b. IDENTIFIERS/OPEN ENDED TERMS c. COSATI Field/Group Air Pollution Atmospheric Dispersion Modeling Atmospheric Diffusion Meteorology Dispersion Modeling Gaussian Plume Models Clean Air Act 18. DISTRIBUTION STATEMENT Release Unlimited 19. SECURITY CLASS (Report) Unclassified 21. NO. OF PAGES 32 20. SECURITY CLASS (Page) Unclassified 22. PRICE EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE ------- |