U. S. ENVIRONMENT flfy itCTION
AGENCY ,s-
1445 ROSS AVENUE ¥"
DALLAS, TEXAS 75202'
EPA-453/R-95-010
BEYOND VOC RACT CTG REQUIREMENTS
CONTROL TECHNOLOGY CENTER
SPONSORED BY:
Information Transfer and Program Integration Division
Office of Air Quality Planning and Standards
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
Air and Energy Engineering Research Laboratory
Office of Research and Development
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711
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April 1995
Page left blank for production
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EPA-453/R-010
April 1995
BEYOND VOC RACT CTG REQUIREMENTS
Prepared by:
Ming Tedijanto and Greg LaFlam
Pacific Environmental Services, Inc.
5001 S. Miami Boulevard
P.O. Box 12077
Research Triangle Park, NC 27709
EPA Contract Number: 68-D1-0116
Work Assignment No. III-06
Task Officer: Mohamed Serageldin, Ph.D.
Emission Standards Division
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
Prepared for:
Control Technology Center
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
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NOTICE
This report has been reviewed by the Emission Standard Division of the Office of Air Quality Planning and
Standards, EPA, and approved for publication. Mention of trade names or commercial products is not
intended to constitute endorsement or recommendation for use. Copies of this report are available through
U. S. EPA's Office of Air Quality Planning and Standards (OAQPS), Technology Transfer Network (TTN)
under the clean Air Act Ammendments Main Menu, Title 1, Policy and Guidance or from the Control
Technology Center (MD-13) in OAQPS. Copies may also be obtained from the National Technical
Information Services (NTIS), 5285 Port Royal Road, Springfield, Virginia 22161 [800] 553-NTIS.
IV
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PREFACE
The Control Technology Center (CTC) was established by EPA's
Office of Research and Development (ORD) and Office of Air
Quality Planning and Standards (OAQPS) to provide technical
assistance to State and local air pollution control agencies.
Several levels of assistance are provided by the CTC. First, a
CTC Hotline is available to provide telephone assistance on
matters related to air pollution control technologies. Second,
more in-depth engineering assistance is provided when
appropriate. Third, the CTC can provide technical guidance by
designing technical guidance documents, developing personal
computer software, and presenting workshops on control technology
matters. The CTC is also the focal point for the Federal Small
Business Assistance Program (SBAP), and maintains the Reasonably
Available Control Technology/Best Available Control
Technology/Lowest Achievable Emission Rate (RACT/BACT/LAER)
Clearinghouse and International Technology Transfer Center for
Global Greenhouse Gases (ITTCGGG). Information concerning all
CTC products and services can be accessed through the CTC
Bulletin Board System (BBS), which is part of the OAQPS
Technology Transfer Network (TTN) bulletin board system.
Technical guidance projects such as this one focus on topics
of national or regional interest that are identified through
contact with State and local agencies. This study was requested
by the Lake Michigan Air Directors Consortium. It provides
technical information that will help agencies develop strategies
for achieving additional reductions in VOC emissions for CTG
Groups I, II, and III, and for enhancing pollution prevention
aspects of State rules.
v
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ACKNOWLEDGEMENT
This report was prepared by Ms. Ming Tedijanto and Mr. Greg
LaFlam both in Pacific Environmental Services, Inc.'s
Environmental Engineering Department located in Research Triangle
Park. The U.S. Environmental Protection Agency (EPA) project
manager was Dr. Mohamed Serageldin of the Office of Air Quality
Planning and Standards.
The cooperation of numerous members of the work group is
greatly appreciated. Special thanks are due to the work group
members Ms. Anne E. Arnold in Region I, Mr. William Denman in
Region IV for providing detailed and timely comments and Bill
Johnson of the Ozone Policy and Strategies group at OAQPS.
VI
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TABLE OF CONTENTS
Chapter No. Page
1.0 EXECUTIVE SUMMARY ................... 1-1
2.0 INTRODUCTION 2-1
3.0 COMPARISON CRITERIA 3-1
4.0 DISCUSSION OF FINDINGS BY SOURCE CATEGORY 4-1
4.1 Cutback Asphalt 4-1
4.2 Fixed-Roof Petroleum Tanks 4-2
4.3 Gasoline Bulk Plants 4-3
4.4 Gasoline Loading Terminals 4-4
4.5 Miscellaneous Refinery Sources 4-5
4.6 Stage I Vapor Recovery 4-6
4.7 Solvent Metal Cleaning (Degreasing) 4-7
4.8 Surface Coating of Automobiles and Light-Duty
Trucks .......... ...... 4-9
4.9 Surface Coating of Cans . 4-11
4.10 Surface Coating of Fabrics 4-12
4.11 Surface Coating of Large Appliances 4-14
4.12 Surface Coating of Metal Coils 4-15
4.13 Surface Coating of Metal Furniture 4-16
4.14 Surface Coating of Magnet Wire 4-17
4.15 Surface Coating of Paper 4-18
4.16 External Floating Roof Petroleum Tanks 4-19
4.17 Gasoline Tank Truck and Vapor Collection System
Leaks 4-20
4.18 Graphic Arts 4-20
4.19 Leaks from Petroleum Refinery Equipment .... 4-22
4.20 Surface Coating of Miscellaneous Metal Parts
and Products 4-24
4.21 Pneumatic Rubber Tire Manufacturing 4-25
4.22 Surface Coating of Flat Wood Paneling 4-25
4.23 Synthesized Pharmaceutical Products 4-26
4.24 Air Oxidation Processes - SOCMI 4-27
4.25 Equipment Leaks from Natural Gas/Gasoline
Processing Plants 4-28
4.26 Large Petroleum Dry Cleaners 4-29
4.27 Polymer Manufacturing 4-30
4.28 SOCMI and Polymer Manufacturing Equipment Leaks 4-31
Appendices
APPENDIX A:
APPENDIX B:
COMPARISON OF STATE/LOCAL VOC RULES TO
FEDERAL RACT FOR GROUP I CTG CATEGORIES
COMPARISON OF STATE/LOCAL VOC RULES TO
FEDERAL RACT FOR GROUP II CTG CATEGORIES
A-l
B-l
VI1
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TABLE OF CONTENTS (Concluded)
APPENDIX C:
APPENDIX D:
APPENDIX E:
APPENDIX F:
APPENDIX G:
APPENDIX H:
COMPARISON OF STATE/LOCAL VOC RULES TO
FEDERAL RACT FOR GROUP III CTG CATEGORIES . . C-l
COMPARISON OF BAAQMD AND SCAQMD VOC RULES
TO FEDERAL RACT FOR GROUPS I, II, AND III
CTG CATEGORIES D-l
DETERMINING THE AMOUNT OF THINNING SOLVENT
ALLOWED E-l
CONVERTING EMISSION LIMIT UNITS FROM MASS
VOC/VOL COATING TO MASS VOC/MASS SOLIDS
(NONVOLATILES) IN COATING F-l
EPA VOC POLICY WORK GROUP G-l
LIST OF GROUPS I, II, AND III CTGs H-l
VI11
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Table No.
LIST OF TABLES
Page
TABLE 1.1
SUMMARY OVERVIEW OF STATE REGULATION
FINDINGS
1-5
LIST OF FIGURES
Figure No.
FIGURE E.I
ESTIMATING MAXIMUM THINNING ALLOWANCE
Page
. . E-9
IX
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1.0 EXECUTIVE SUMMARY
Air pollution control agencies that have ozone nonattainment
areas within their jurisdiction are required under the Clean Air
Act (CAA) to develop State implementation plans (SIPs) that will
lead to attainment of the national ambient air quality standards
(NAAQS) for ozone. This effort includes the development and
implementation of rules that require Reasonably Available Control
Technology (RACT) for sources of volatile organic compounds (VOC)
located within the designated ozone nonattainment areas. In
order to obtain the required VOC emission reductions, these
agencies are required to establish RACT for source categories not
already covered by EPA's Control Technique Guidelines (CTGs) in
addition to tightening RACT for source categories for which RACT
has already been defined.
This study was performed at the request of the Lake Michigan
Air Directors Consortium (LADCO). It identifies and compares, by
CTG source category, examples of State and local agency rules
that exceed or may exceed the RACT requirements that are speci-
fied in the Federal CTGs. This study is limited to CTG Groups I,
II, and III only, which cover 28 source categories. Tables
summarizing these comparisons are provided in Appendices A
through D. There is no summary table for Air Oxidation Processes
- SOCMI (Group III CTG, Appendix C), because no State or
California District rules were reviewed for this source category.
Existing Federal CTGs for each source category that define RACT
were thoroughly reviewed and evaluated. Also, EPA's "Blue Book"
("Issues Relating to VOC Regulation Cutpoints, Deficiencies, and
Deviations - Clarification to Appendix D of November 24, 1987
1-1
-------
Federal Register," May 25, 1988, revised 1/11/90) was used to
clarify CTG related issues. Comparison and analysis of EPA's
Model VOC Rules for RACT were not included in the scope of the
project. This study also does not include CTGs that are
currently under development.
In this report, regulations from eight states (Colorado,
Connecticut, Maine, New Jersey, New York, Rhode Island, Texas,
and Utah) and two California control districts were examined for
as many of the source categories as time allowed (see Table 1.1).
The two California Districts evaluated were the Bay Area Air
Quality Management District (AQMD) and the South Coast AQMD.
Information for each source category was obtained primarily from
EPA's VOC Policy Work Group members (listed in Appendix G);
additional information was obtained from the SNA Environment
Reporter. However, due to time constraints and limited
resources, a comprehensive review of all of the State VOC
regulations contained in the Environment Reporter was not
accomplished.
State and local regulations received for each source
category were reviewed and compared for stringency with the
guidelines in the applicable Federal CTG. Stringency evaluations
were based on, but were not limited to, VOC content limits of
coatings, emission limitations, percent emission reduction
(capture and control), and transfer efficiency requirements.
Other differences between the regulations and the Federal CTGs
(such as equipment specifications, recordkeeping, and work
practice requirements) were categorized as having the potential
to "enhance" the pollution prevention aspects of a rule, but not
necessarily as being more stringent in and of themselves, unless
quantifiable emission reductions could be attributed to the
measure. If, for example, a State or District rule has more
stringent recordkeeping requirements, it is noted in the
stringency column in the summary tables (Appendices A through D)
through a footnote. This 'qualifying1 statement indicates that
the more stringent recordkeeping requirements may result in
pollution prevention.
1-2
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A discussion of the rule identification methodology is
presented in Chapter 2, Introduction. Chapter 3 addresses the
criteria description and ranking criteria used for evaluating the
State and District regulations reviewed in each CTG source
category. The rules reviewed are summarized and compared to the
Federal CTG and against each other when appropriate. A maximum
of six State rules were considered for each source category.
Chapter 4 discusses the findings of this study by source
category. The report contains several appendices. Appendices A
through C provide summary tables of the State/local rules by CTG
group, whereas Appendix D provides a summary of the California
District rules. Appendices E and F focus on computational
aspects of the study. Appendix G lists the members of EPA's VOC
Policy Work Group. Appendix H contains a listing of the 28 Group
I, II, and III CTGs.
Table 1.1 summarizes the State regulations that were found
to be more stringent than the Federal CTGs. The study found that
at least one State (or District) regulation was more stringent
than Federal RACT in 24 of the 28 CTG categories considered.
State regulations were as stringent as Federal RACT in only four
CTG categories. As mentioned above, one CTG category, Air
Oxidation Processes - SOCMI, was not covered by any of the State
or District rules reviewed.
The Bay Area and South Coast regulations are generally more
stringent than Federal RACT and the State regulations.
Regulations for these two Districts are as stringent as the
Federal CTG requirements in two CTG categories: Stage I Vapor
Recovery and Surface Coating of Magnet Wire. Four CTG categories
were not found in the District rules. These include: Gasoline
Tank Truck and Vapor Collection System Leaks/ Air Oxidation
Processes - SOCMI, Polymer Manufacturing, and SOCMI and Polymer
Manufacturing Equipment Leaks.
Of the eight States and two California Districts, the Bay
Area District has the most rules that exceed Federal RACT (20 of
the 28 CTG categories). The South Coast AQMD is second with 17
rules, and Connecticut is third with 4 rules that exceed CTG
1-3
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RACT.
Overall, the State and California District rules reviewed
exceed CTG RACT in about 50 instances. Table 1.1 provides a
convenient way of identifying more stringent regulations and
those that have pollution prevention provisions. The "X" under
the column labelled "Stringency" identifies those rules found to
be more stringent than the CTG. The X under the column labelled
"Applicability" is used to identify those rules that provide
specific exemptions or affect different source populations than
indicated in the CTG. There were some cases where the State or
District rules were applicable to a smaller population of sources
than recommended in the Federal CTG. However, these State or
District rules were not termed less stringent. Instead, the term
applicability was used to highlight the possibility that the rule
may result in lower reductions. Therefore, in this study a
distinction is made between two aspects of a rule that affect the
emission reduction achievable: the stringency of the rule and the
applicability of the rule. If a rule appeared more attractive
from a pollution prevention perspective (as discussed in Chapter
3), it was not classified as more stringent than the Federal CTG
unless the reductions were quantifiable. As an example, work
practices that lead to quantifiable emission reductions are
considered more stringent. Such regulations were marked with an
X under the "Pollution Prevention" columns. Other work or
operating practices may enhance the rule but do not necessarily
lead to quantifiable emission reductions. Such additional
requirements ("additions") to the State rules were not considered
to make the rule more stringent. They are entered in Table 1.1
under the column entitled "Potential Emission Reduction."
1-4
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2.0 INTRODUCTION
Reasonably Available Control Technology (RACT) is defined as
the lowest emission limit that a particular source is capable of
meeting through the application of control technology that is
reasonably available considering technological and economic
feasibility. For surface coating source categories generally,
the Federal CTGs define RACT in terms of the VOC content limits
of a coating; i.e., mass of VOC per unit volume of coating (minus
water) as applied (ready for application). In some cases,
however, RACT is defined in terms of the percentage emission
reduction achieved with add-on control devices, equipment
specifications and recordkeeping, reporting requirements, and
exemption levels.
For the purposes of this study, 28 CTG documents addressing
28 source categories were reviewed. Information related to State
rules that may go beyond RACT recommendations as specified in the
CTGs and the "Blue Book" was solicited from members of EPA's VOC
Policy Work Group. This report is based on the Work Group's
responses to these information requests. The Work Group did not
identify any State or District regulations as exceeding Federal
RACT for the Air Oxidation Processes - SOCMI and Large Petroleum
Dry Cleaner source categories.
State rules reviewed for this project were those sent by
members of the Work Group following a request by the Office of
Air Quality Planning and Standards. The California District
rules were provided by the EPA Work Assignment Manager.
Additional information with regard to State regulations came from
the Environment Reporter. The Federal CTG for each source
category was reviewed and summarized; the State and the District
rules pertaining to each source category were compared to the
Federal CTG.
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Although the RACT limits in the Federal CTG's developed in
the late 1970"s and early 1980's do not mention "exempt"
compounds in the coating limit expressions, it is assumed that
exempt compounds are treated as water in mass of VOC per gallon
of coating (less water) calculations as called for in the "Blue
Book."1 "Exempt" compounds are those compounds classified by EPA
as having negligible photochemical reactivity as listed in 40 CFR
51.100 (s) . For the purposes of this study, baseline RACT
consists of guidance in the CTG documents plus subsequent
clarifying policy guidance included in the "Blue Book." This
point clarifies why State coating VOC limits were sometimes not
considered to be more stringent than the Federal CTG coating
limits when the numerical limits were equal. Some States added
requirements to their rules that enhance pollution prevention
aspects of the rules. For example, a State may have specified
how soon a leak must be repaired from the time it is detected,
whereas the applicable CTG may not have such a provision. When
additional requirements in a State regulation did not appear to
result in a quantifiable extra reduction in pollution, the rule
was not termed more stringent than the CTG RACT level. Hence,
when a rule required or modified work practices in general terms
it was not considered more stringent unless the emission
reduction benefit could be quantified. However, when the
requirement enhanced the rule, that fact was acknowledged in the
summary table for that State rule.
When a rule increased (or decreased) the population of
emission unit operations (or items of equipment) covered with
respect to the applicable Federal CTG, this was noted by an "X"
in the column headed "Applicability." Comparisons of stringency
were reserved for rules that affected the same population of
units or processes. Several States converted limits from mass of
VOC per volume of coating (less water and exempt solvents) to an
1 Issues Relating to VOC Regulation Cutpoints, Deficiencies,
and Deviations - Clarification to Appendix D of November 24, 1987
Federal Register - May 25, 1988 (Revised 1/11/90); U.S. EPA
(AQMD); Research Triangle Park, N C.
2-2
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equivalent solids (nonvolatiles) basis. The States, however, did
not explicitly state the assumptions or indicate the volume of
solids (nonvolatiles) used for the conversion. Appendix F
discusses a procedure for performing this conversion.
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3.0 COMPARISON CRITERIA
Several criteria were used to compare State regulations to
the Federal RACT guidance in the CTGs in order to determine
relative stringency. The following criteria were used:
(1) more stringent VOC emission limits (e.g., mass of VOC
per unit of production);
(2) more stringent limits on the VOC content of a coating
(e.g., paint, inks, or other);
(3) a requirement for a greater "percent reduction" than
recommended as RACT;
(4) an improved transfer efficiency requirement;
(5) a requirement for more efficient capture of emissions;
(6) inclusion of work practice requirements not present in
the CTG; and
(7) any other pollution prevention method.
In most cases, evaluation of criteria 1 through 3 for
relative stringency was straightforward. In some cases, however,
it could not be determined whether an emission limit was
equivalent to a suggested overall control efficiency for a
control device because the emission rate from the process was
unknown.
Criteria 4 through 7 proved to be the most difficult to
evaluate for stringency. For example, based on the information
available, equivalency for design criteria, equipment
specifications, or work practices is difficult to rank. However,
in evaluating the source categories, more equipment and design
specifications delineated by the State regulations were presumed
to indicate greater stringency. This is especially true where
such changes appear to result in quantifiable reductions. The
design criteria and equipment specifications noted in the tables
shown in Appendices A through D are, in most cases, in addition
3-1
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to the Federal CTG specifications. An example of this type of
additional requirement would be for all openings in floating roof
tanks to provide a projection below the liquid surface, or for an
emergency roof drain to be provided with a slotted membrane
fabric cover or equivalent cover that covers at least 90 percent
of the opening.
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4.0 DISCUSSION OF FINDINGS BY SOURCE CATEGORY
4.1 Cutback Asphalt
Cutback asphalts are mixtures of solvent and a base asphalt
of selected hardness or viscosity. There are rapid curing,
medium curing, and slow curing cutback asphalts. Emulsified
asphalts consist of asphalt suspended in water (98 percent)
containing an emulsifier (2 percent). Water in emulsified
asphalt evaporates during curing while the emulsifier is retained
in the asphalt. Federal RACT for cutback asphalt is defined in
terms of substitution of emulsified asphalt for cutback, rather
than in terms of an emission limit. The CTG provides no
exemptions for this source category. In general, the State
regulations that were reviewed had stipulations for substitution
of emulsified for cutback asphalt with some variation.
State and District regulations were ranked according to
stringency of State/District requirements versus Federal RACT.
The criteria used to rank these regulations involved the
requirements of substitution and the allowable solvent content.
In other words, the State regulations reviewed define RACT in
terms of how and when the cutback would be substituted, in
addition to including added specifications for emulsified
asphalt. Although the CTG does not discuss any exemptions, the
"Blue Book" suggests seasonal exemptions. In general, the State
regulations echo the Federal CTG for the substitution of
emulsified asphalt.
The Rhode Island regulation allows the use of cutback
asphalt during certain periods of the year. Rhode Island also
places several restrictions on the type of cutback asphalt that
may be used during the ozone season. These restrictions will not
4-1
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result in quantifiable reductions, but will enhance the quality
of the rules.
The Bay Area AQMD regulations, however, prohibit the use of
any rapid-cure liquid asphalt and liquid asphalt or emulsified
asphalt in paving material or in paving and maintenance
operations. These prohibitions are not specified in the CTG or
the South Coast regulation and have not been used to determine
stringency; this is an issue of applicability. The Bay Area and
the South Coast specify lower VOC content for any slow-cure
liquid asphalt and emulsified asphalt than the CTG. Therefore,
the Bay Area and South Coast regulations are similar and more
stringent than the Rhode Island or Colorado rules, or the CTG.
4.2 Fixed-Roof Petroleum Tanks
The Federal CTG does not provide an emission limit, but
recommends equipment specifications. These specifications
include internal floating roofs equipped with a closure seal or
seals, or alternative equivalent controls. The CTG, however,
does not specify the exact types of controls that can be used to
achieve this.
Stringency for this source category is determined by the
storage tank capacity cutoff level, control efficiency, and
additional equipment specifications where the benefits are
readily quantifiable. Additional requirements are defined as
conditions beyond what the CTG specifies.
Two State regulations and the two California District
regulations were reviewed. In general, the Utah and Colorado
regulations are as stringent as the CTG. In addition, these
rules provide additional operating practices that are not found
in the CTG. These practices enhance the pollution prevention
aspects of the rule and may result in potential emission
reductions. The State of Colorado also specifies exemptions that
result in fewer sources subject to the rule.
The Bay Area and South Coast regulations specify a lower
product vapor pressure cutoff than Utah, Colorado, or the Federal
CTG. Therefore, more operations will be required to comply with
the rule. These regulations also require the same control
4-2
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efficiency for an approved emission control system, but higher
than that specified in the CTG. The effect of these requirements
is more emission reduction. The Bay Area and South Coast
regulations also have more detailed operating requirements than
the CTG. These requirements, however, were not used for
determining stringency.
4 . 3 Gasoline Bulk Plants
The Federal CTG defines a bulk plant as having a throughput
of less than 76,000 liters of gasoline per day, averaged over the
work days in 1 year. In addition, the CTG specifies types of
bulk plant facilities, control techniques used in bulk plants,
and type of operations and maintenance required to prevent leaks.
No emission limit or exemptions are specified for this source
category.
Two State and the two California District regulations were
reviewed for stringency and compared to the corresponding CTG
RACT. The criteria used to rank these regulations are the bulk
plant definition (capacity), recovery system efficiency, and the
required VOC emission limit (if available) during gasoline
transfer.
Both the Colorado and Texas regulations define a bulk plant
as having an average daily throughput of less than 76,000 liters
calculated over a period of 30 days, instead of over the work
days in 1 year as stated in the CTG. The shorter the timeframe
(30-day period) for calculating the average throughput to meet a
set limit, the better should be the compliance with the rule.
The Bay area regulation defines a bulk plant as having an
annual throughput of not more than 23,000 cubic meters (6,000,000
gallons). Assuming 360 work days in 1 year (30 work days per
month for 12 months), the calculated daily throughput is 17,000
gallons. The Bay Area defines a bulk plant with a lower
throughput cutoff than other States or the Federal CTG;
therefore, it is considered the most stringent.
The Texas and Bay Area regulations specify a maximum VOC
emission limit associated with product transfer. The Bay Area
emission limit is less than half that required by the Texas
4-3
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regulation. No emission limit is specified in the Federal CTG or
the Colorado or South Coast regulations. In addition to the bulk
plant definition and emission limit, the Bay Area requires a
higher vapor recovery system efficiency than the South Coast or
the Federal CTG. The Bay Area and South Coast regulations also
provide work practices and a shorter timeframe for repairing
leaks that are not specified by the other States or the Federal
CTG. For example, both regulations place a limit on the gauge
pressure developed in a delivery tank during transfers, which
should result in quantifiable reductions.
The Bay Area has the most stringent regulation on the basis
of the VOC emission limit, lower capacity cutoff, and higher
recovery efficiency. These criteria should result in a
substantial reduction in emissions. On the same scale, the Texas
regulation is more stringent than the South Coast, followed by
Colorado and then the CTG.
4.4 Gasoline Loading Terminals
The Federal CTG describes sources and type of emissions,
control techniques, compliance test methods (test conditions and
test procedures) and monitoring techniques, and emission test
procedures. The recommended RACT VOC emission limit for this
category is 80 milligrams per liter (0.67 lb/1,000 gal) of
gasoline loaded.
The State and District regulations were ranked according to
their stringency versus Federal RACT. The criteria used to rank
these regulations involved emission limit requirements.
Three State regulations (Colorado, Utah, and Texas) and the
two Districts were reviewed for this category. The Utah emission
limit is slightly lower than Colorado's, which is identical to
the emission limit stated in the Federal CTG. Although the
Colorado regulation specifies loading procedures, it is less
stringent than the Utah regulation.
Certain areas in Texas (Beaumont/Port Arthur, Dallas/Fort
Worth, El Paso, and Houston/Galveston) have a lower emission
limit (40 mg VOC/I (0.33 Ib VOC/1,000 gal) of gasoline
transferred), except for Gregg, Nueces, and Victoria counties.
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The Texas regulation, in general, is more stringent than the Utah
and Colorado rules.
The Bay Area sets the lowest emission limit and requires
work practices to be followed and a maximum control efficiency
for vapor control systems. Such requirements would result in
quantifiable emission reductions. The South Coast emission limit
is slightly lower than Texas. The South Coast also requires a
shorter repair period than the Federal CTG. Therefore, the Bay
Area regulation is ranked as the most stringent, followed by the
South Coast, Texas, Utah, and Colorado. The Colorado regulation
is as stringent as the Federal CTG.
4.5 Miscellaneous Refinery Sources
Miscellaneous refinery sources include vacuum producing
systems (VPSs), wastewater separators (WSs), and process unit
turnarounds (PUTs). The Federal CTG defines RACT for VPSs and
WSs in terms of equipment specifications, and specifies that
regulations for PUTs should be written in terms of operating
procedures. In general, the State regulations define RACT in
terms of equipment specifications and operating procedures.
State, Bay Area, and South Coast regulations were ranked
according to stringency of the State requirements versus Federal
RACT. The criteria used to rank these regulations involved
comparing add-on equipment control efficiency and operating
procedures. In general, State regulations that were reviewed are
as specified in the CTG, with several "additions." The additions
include the covering of forebays and separator sections, use of
EPA approved test methods to determine compliance with the
emission limitations, the use of a vapor recovery system that has
at least 90 percent control efficiency, additional vapor control
options, as well as specifications for the use of safety pressure
relief valves.
The Colorado regulation specifies a minimum control
efficiency for control equipment and contains more "additional"
stipulations than Utah or the CTG. These additional provisions
involve covering forebay and separator sections, the use of EPA
Reference Test Methods to determine compliance, and control of
4-5
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depressurization venting and process blowdowns. These additional
requirements cannot be used to determine stringency since they
will not result in quantifiable emission reductions. The Utah
regulation, in this case, is considered as stringent as the
Federal CTG.
The Bay Area and South Coast regulations require a greater
combined collection and control efficiency than the Colorado
rule. The CTG does not specify an add-on control efficiency.
The South Coast regulation also specifies a VOC emission limit at
a fixed distance (1 cm) from the drain opening and requires a
shorter timeframe for repair than the CTG. Therefore, the South
Coast regulation is considered more stringent than the Bay Area
regulation, followed by Colorado, then the CTG.
4.6 Stage I Vapor Recovery
The Federal CTG defines RACT for this source category in a
number of ways, suggesting several methods by which to conduct
displaced vapors from underground storage tanks to tank trucks.
It also suggests that system "design criteria" be developed to
accomplish efficient control of emissions.
Stringency for this category is determined by the VOC
emission limit and by any "additional" requirements or
specifications beyond what the Federal CTG requires. Only those
additional requirements including work practices that result in
quantifiable emission reductions are considered to determine the
stringency of a regulation.
The Colorado, Texas, Bay Area, and South Coast regulations
were reviewed for this source category. All regulations except
Colorado's contain standards that exceed the requirements
specified in the CTG.
The State of Texas requires control equipment to be operated
during the transfer of gasoline, and VOC emissions to be reduced
to a certain limit. The CTG document does not specify a VOC
emission limit for this category and the "Blue Book" only
specifies control efficiency for Stage I emission control
equipment. Providing an emission limit (mg/1 of gasoline
transferred) is more significant for the purpose of reducing
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emissions than only requiring a control system efficiency. In
addition to the emission limit, Texas also specifies a tank size
exemption and required gauge pressure and vacuum pressure relief
limits for the tank of the fuel delivery truck. Pressure relief
settings are not specified in the Federal CTG.
In general, the Bay Area and South Coast regulations have
adopted the guidelines in the CTG. The Bay Area regulation,
however, exempts gasoline storage tanks with a capacity less than
260 gallons in this source category. The CTG exempts several
tank sizes that are not found in the Bay Area. For example, if
the gasoline is used for agricultural purposes, the storage tank
capacity cutoff is over twice the capacity cutoff specified in
the Bay Area. The Bay Area also has additional exemptions that
are not specified in the CTG, but these were not used to
determine stringency of the rule. These exemptions will result
in fewer sources being required to comply with the rule.
The South Coast rule exempts gasoline storage tanks with
capacities less than 250 gallons. In addition, the rule also
exempts tanks used primarily for the fueling of implements of
husbandry and agricultural wind machines. These exemptions will
result in fewer affected sources. The South Coast regulation
also includes work practices that would result in quantifiable
emission reductions.
In conclusion, the Texas regulation is the most stringent,
followed by the South Coast. The Bay Area and Colorado rules are
as stringent as the CTG.
4 . 7 Solvent Metal Cleaning (Deareasincr)
The Federal CTG divides this source category into three
separate types of parts cleaning (degreasing) operations: cold
cleaning, open top "vapor parts cleaners (degreasers)," and
"conveyorized parts cleaners." It further specifies the control
device options for each type. Stringency for this source
category is defined through the efficiency of control equipment
and the freeboard ratio value.
Four State and the two California District regulations were
reviewed for this category. All State regulations, except for
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Rhode Island, mirror the Federal CTG and include several
additional work practice requirements. The Rhode Island
regulation specifies a slightly higher freeboard ratio (0.75 vs.
0.70) for all cold cleaning units than the CTG. Freeboard
primarily serves to reduce drafts near the air/solvent interface.
A freeboard ratio is determined by the freeboard height divided
by the width of the parts cleaner's air/solvent area. The higher
the ratio, the less emissions are released. The CTG also
indicates that an increase in ratio from 0.5 to 1.0 may yield
about a 50 percent reduction in emissions.
The Bay Area and South Coast regulations specify the same
control equipment for open top vapor parts cleaners, cold
cleaners, and conveyorized parts cleaners, but require a greater
control efficiency than the CTG. The Bay Area specifically
indicates that solvent agitation must be accomplished only by
pump recirculation or by means of a mixer; air agitation may not
be used. The CTG states that agitation is generally accomplished
through the use of pumping, compressed air, vertical motion, or
ultrasonic. The CTG allows the use of air agitation involving
dispersing compressed air from the bottom of the "soaking;" the
air bubbles provide a scrubbing action. This type of agitation
is prohibited by the Bay Area because air bubbles may create more
emissions.
For facilities using the freeboard ratio as a control
option, the Bay Area and South Coast regulations specify a
slightly higher freeboard ratio than the CTG (0.75 vs. 0.70).
The South Coast regulation provides additional operating
requirements not specified in the Bay Area regulation or the CTG
that may have potential in reducing emissions. The CTG exempts
conveyorized parts cleaners with less than 2.0 m2 of air/vapor
interface from the requirement for a control device.
One of the general requirements specified in the Bay Area
regulation prohibits waste solvent residues that are treated
prior to final disposal at an appropriate waste disposal facility
to contain more than 10 percent solvent by volume. The CTG does
not allow waste solvent to be disposed of or transferred to
-------
another party such that greater than 20 percent of the waste (by
mass) can evaporate into the atmosphere. Both rules were
developed to restrict the amount of solvent in the waste, but
they are not specified in the same manner (units). The effect of
each requirement can be clarified by the following example.
Assume 1 gallon of waste solvent residue will be treated prior to
final disposal and that it contains 10 percent by volume of
solvent. Using an average solvent density of 6.7 Ib/gal and a
residue density of 9.2 Ib/gal, the mass of solvent and of residue
in the waste are 0.67 Ib and 8.28 Ib, respectively. The
concentration of solvent by mass in the waste is 7.5 percent.
When the concentration of solvent is increased to 15 percent by
volume, the concentration of solvent in the waste increases 12.9
percent by mass. Note: This is in violation of the Bay Area
rule, but not the Federal CTG.
In conclusion, the Bay Area regulation is as stringent as
the South Coast regulation, but more stringent than Rhode
Island's rule, since it has additional requirements that will
result in extra, quantifiable emission reductions.
4.8 Surface Coating of Automobiles and Light-Duty Trucks
The Federal CTG recommends different emission limits for
prime application, topcoat application, and final repair
application coatings. The State and District regulations were
ranked according to criteria including VOC emission limitations,
additional emission limit for coating operations, transfer
efficiencies, and control efficiencies.
Colorado, New Jersey, and the two District regulations were
reviewed and ranked for this source category. The Colorado
regulation echoes the emission limits specified in the CTG. The
Colorado regulation also provides an alternative method to meet
the emission limit for topcoat application in terms of mass of
VOC per unit volume of solids (nonvolatiles) deposited on the
coated part. This emission limit is not specified in the Federal
CTG. However, the alternative emission limit can be calculated
using the guideline given in Appendix E or F. The calculated
emission limit for topcoat application is 4.5 Ibs VOC/gal of
4-9
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solids, not 15.1 Ibs VOC/gal of solids.
New Jersey emission limits for topcoat application and final
repair application are identical to the emission limits stated in
the Federal CTG. The State of New Jersey divides prime
application into two operations (electrophoretic dip prime and
spray prime) with two emission limits. The averaged value of
these limits is identical to the emission limit for prime
application stated in the Federal CTG. This shows that New
Jersey regulation is more process-specific than the Federal CTG,
but not necessarily more stringent. In addition, the New Jersey
regulation specifies two additional VOC emission limits for
custom topcoating and refinishing operations. These emission
limits are higher than the Federal CTG and Colorado limits for
all three operations. These limits provide additional reduction
of emissions and are therefore more stringent.
The New Jersey regulation requires that the emission
reduction of the control apparatus be demonstrated on an hourly
basis or on the basis of hourly emission rate calculated on a
solids (nonvolatiles) applied basis. The CTG does not require
the efficiency of a control apparatus to be demonstrated on an
hourly basis. Although New Jersey's requirement may not result
in quantifiable emission reductions, it will allow compliance to
be evaluated more accurately.
The Bay Area specifies a lower VOC emission limit for primer
application than the CTG. It also provides four additional VOC
emission limits for flexible primer, color topcoat,
basecoat/clearcoat, and off-line coating. The emission limit for
basecoat/clearcoat is lower than that for basecoat specified in
the New Jersey regulation.
The South Coast regulation provides VOC emission limits for
several coating (primer, topcoat, and final) and application
methods (electrophoretic dip, manual electrostatic spray, and air
atomized spray). The emission limits for the topcoat and final
repair coating categories are higher than those specified in the
CTG and, therefore, are less stringent. The CTG specifies an
emission limit for primer application based on use of an
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electrophoretic system. The South Coast regulation specifies a
lower VOC emission limit for electrophoretic applied primer than
that in the CTG. In addition, the South Coast regulation
provides emission limits for primer surfacer, spray primer,
basecoat, and clearcoat that are not found in the CTG. The South
Coast regulation also requires higher transfer efficiencies than
the Bay Area. The Bay Area regulation follows the "Blue Book"
guidelines for transfer efficiencies.
Due to a lower VOC emission limit for primer application and
additional emission limits, the Bay Area regulation is ranked
first, followed by the South Coast's, New Jersey's, and the CTG.
Colorado's rule is considered as stringent as the CTG.
4.9 Surface Coating of Cans
The Federal CTG defines RACT limits for four coating
categories: sheet base coat and over-varnish and two piece can
exterior; two and three-piece can exterior body spray and two-
piece can exterior end; three-piece can side-seam spray; and end
sealing compounds. ( Three State and the two District
regulations were reviewed and ranked according to stringency of
the State and District requirements versus CTG RACT. The
criteria used to rank these regulations were based on the
required VOC emission limits for several coating applications,
additional emission limit, and the required control efficiency of
a control device.
The Colorado, Maine, and New Jersey regulations specify the
same VOC emission limits as the CTG. Colorado also sets an
additional emission limit for "any other coating," which is not
provided in the CTG or the New Jersey regulation. The New Jersey
regulation also requires that the efficiency of a control
apparatus be achieved on an hourly basis or on the basis of
hourly emission rate calculated on a solids applied basis. This
requirement will evaluate more accurately the compliance
performance than having an initial or one emission test in a
year. The New Jersey regulation requires the same control
efficiency as the CTG and provides exemptions that are not found
in the CTG. With regard to the smaller population of sources to
4-11
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which the rule is applicable, the rule is not considered more
stringent than the CTG. The Maine regulation contains a
provision that will enhance the pollution prevention aspects of
the rule.
The Bay Area regulation specifies separate emission limits
for sheet basecoat and two-piece can exterior basecoat. These
emission limits are lower than the limit specified in the CTG and
thus are more stringent. The South Coast regulation has lower
emission limits for three-piece base, two-piece exterior
basecoat, and two-piece interior body spray than the CTG. In
addition, the South Coast regulation specifies two emission
limits for end sealing compound applicable to food and non-food
cans. The Federal CTG specifies the same emission limits
applicable to both food and non-food cans. The South Coast
emission limit for non-food cans is lower than the CTG. The
South Coast regulation also provides two additional emission
limits and higher control efficiency than the Bay Area and New
Jersey rules, and the CTG.
In conclusion, the South Coast regulation is the most
stringent, followed by that of the Bay Area. The Colorado
regulation is more stringent than New Jersey's. This is because
of an additional emission limit that will apply to a greater
population of sources. The New Jersey and Maine regulations are
as stringent as the CTG in terms of coating emission limits and
control efficiency. However, the regulations require compliance
to be based on hourly emission reduction or hourly emission rate
calculated on a solids applied basis.
4.10 Surface Coating of Fabrics
This category is divided into two coating operations: fabric
and vinyl coating lines. The CTG defines RACT emission limits in
terms of mass of VOC per unit volume of coating applied (minus
water and exempt solvents). These emission limits are based on
the use of an add-on control device that recovers or destroys at
least 81 percent of the VOC introduced in the coating. In the
CTG, the limitation for fabric coating can also be achieved by
the use of a high solids coating containing about 60 volume
4-12
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percent solids (nonvolatiles) or a waterborne coating with a
solids content of about 24 volume percent.
Five State regulations (Colorado, New Jersey, Utah, Rhode
Island, and Maine) and the two California District regulations
were reviewed for this category. These regulations were ranked
according to stringency of the State requirements versus the
Federal RACT guidance. Ranking was accomplished by comparing the
VOC emission limits and the required control efficiency.
The emission limits stated in all of the State regulations
reviewed are identical to the emission limits stated in the
Federal CTG. Only the Utah and Rhode Island regulations provide
equivalent emission limits for fabric and vinyl operations in
terms of mass of VOC per unit volume of solids (nonvolatiles).
These limits were calculated using the guideline specified in
Appendix F. The New Jersey regulation also requires the control
device to achieve the emission reduction on an hourly basis or
the hourly VOC emission rate should not be greater than the
hourly emission rate calculated on a solids applied basis. The
hourly requirement is not specified in the CTG. This aspect of
the New Jersey regulation will evaluate more accurately
compliance performance than on the basis of the requirements in
the Colorado regulation or the CTG. Such a requirement also
enhances the pollution prevention aspects of the rule, but may
not necessarily result in a quantifiable reduction in emissions.
The Rhode Island regulation requires a higher number for the
overall control efficiency and, therefore, is are more stringent
than the New Jersey or Colorado rule, or the CTG. Although the
Maine regulation has an attractive provision, this rule is not
considered more stringent than the CTG.
The Bay Area and South Coast regulations specify a lower
emission limit for fabric coating processes than the CTG. The
South Coast regulation requires a higher control efficiency and
transfer efficiencies than the Bay Area rule or the CTG. In
addition to emission limits for fabric and vinyl coating, the
South Coast regulation has separate and lower emission limits for
the plastisol and wash primer used in these coating operations.
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Additional work practices are also found in the South Coast
regulation that are not found in the Bay Area or other State
regulations, or the CTG. In conclusion, the South Coast
regulation is ranked the most stringent, followed by the Bay Area
rule, the Rhode Island rule, and then the Federal CTG. The
Colorado, Maine, and New Jersey regulations are as stringent as
the CTG.
4.11 Surface Coating of Large Appliances
The Federal CTG recommends a single emission limit for a
large appliance coating line in terms of mass of solvent per unit
of coating applied (minus water and exempt solvents). This
emission limit is derived based on the use of low organic solvent
coatings containing at least 62 volume percent solids
(nonvolatiles) or any waterborne equivalent. An equivalent
method for achieving the desired reduction would be the use of an
add-on control device such as an incinerator or a carbon adsorber
that can achieve approximately an 81 percent overall emission
reduction.
Four States (Colorado, Utah, Maine, and New Jersey) and the
Bay Area regulation were reviewed and ranked according to the
stringency of State requirements versus Federal RACT
requirements. All State regulations have the same emission limit
as specified in the Federal CTG. The Maine regulation provides
an incentive (by allowing monthly rather than daily
recordkeeping) for facilities that demonstrate that only low-VOC
coatings are used. Although this provision was not factored into
determining the stringency of the rule, the provision enhances
the pollution prevention aspects of the rule. The New Jersey
regulation has an additional requirement for a control device to
achieve an efficiency on an hourly basis or an hourly VOC
emission rate shall not be greater than the allowable hourly
emission rate calculated on a solids applied basis. This hourly
requirement is not specified in the Federal CTG. This
requirement is not used to determine stringency since it may not
result in quantifiable emission reductions, but it does provide
for more accurate compliance performance than the CTG
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recommendation. These State regulations are, therefore, as
stringent as the CTG.
The Bay Area regulation has a lower emission limit and a
higher overall control efficiency requirement than the CTG or the
other regulations reviewed. As a result, the Bay Area regulation
has been ranked the most stringent.
4.12 Surface Coating of Metal Coils
The Federal CTG specifies only a single emission limit for
surface coating of metal coil operations. This emission limit is
expressed as mass of VOC per unit volume of coating as applied
(minus water).
Two State (Colorado and New Jersey) and the two California
District regulations were reviewed and ranked according to
stringency of the requirements in comparison to RACT. Stringency
is based on the required emission limit, control efficiency, and
other additional requirements. The Colorado and New Jersey
regulations specify a VOC emission limit identical to the
emission limit stated in the Federal CTG.
An alternate means of complying with the emission limit is
through the use of control technologies such as add-on control
devices or low-solvent coatings. The CTG states that the use of
thermal or catalytic incinerators can achieve over 90 percent
emission reduction. The New Jersey regulation specifies the same
emission control efficiency as the CTG, but requires the VOC
control device to reduce the emissions on an hourly basis or to
achieve the maximum allowable hourly emission rate calculated on
a solids applied basis. Although this requirement may not result
in quantifiable reductions, it will, however, provide for more
accurate evaluation of the compliance performance than the
specifications in the CTG. The New Jersey regulation also
specifies an exemption for daily coating usage. This exemption
will result in a smaller population of sources being subject to
the rule, but it is an issue of applicability and not the
stringency of the rule. Thus, although the New Jersey regulation
is more attractive, it is considered equivalent to the CTG.
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The Bay Area and South Coast regulations specify the same
emission limit for this category, but the limit is lower than the
one specified in the CTG. In addition to the emission limit, the
South Coast regulation requires greater emission control and
transfer efficiency than the CTG. Therefore, the South Coast
regulation is considered the most stringent, followed by the Bay
Area regulation, and then the CTG.
4.13 Surface Coating of Metal Furniture
The Federal RACT emission limit for a metal furniture
coating line is expressed as mass of VOC per unit volume of
coating as applied (minus water). This emission limit is based
on the use of low organic solvent coatings. The limit can also
be achieved by the use of waterborne coatings or an add-on
control device. The control device must have at least an 80
percent overall control efficiency.
Rules for four States (Colorado, New Jersey, Maine, and
Utah) and one of the California Districts (Bay Area) were
reviewed and ranked according to stringency of these requirements
versus Federal RACT. The criteria used in determining stringency
include the emission limitation, required control efficiency, and
alternative emission reduction.
All of the regulations reviewed have the same emission limit
as the Federal CTG. For the surface coating operation served by
a control device, the New Jersey regulation requires that
emission reductions be achieved on an hourly basis or an hourly
VOC emission rate no greater than the maximum allowable hourly
emission rate calculated on a solids applied basis. The CTG does
not require the control efficiency to be demonstrated on an
hourly basis. New Jersey's requirement, however, will result in
more accurate compliance performance evaluation than the CTG.
Maine provides an incentive for facilities that demonstrate that
only low-VOC (compliant) coatings are used, by allowing them to
keep monthly rather than daily records as indicated in the "Blue
Book." This provision was not factored into determining the
stringency of the rule. However, the provision encourages
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pollution prevention actions. In general, the State regulations
are as stringent as the CTG.
The Bay Area regulation specifies two VOC emission limits
for this operation based on the drying techniques employed. Both
emission limits are lower than those recommended in the CTG. The
Bay Area also requires a slightly higher control efficiency and
transfer efficiency. Therefore, the Bay Area regulation is
considered to be the most stringent.
4.14 Surface Coating of Magnet Wire
The Federal CTG recommends a single emission limit for
magnet wire coating operations. This limit is given in terms of
mass of VOC per unit volume of coating as applied (minus water).
This emission limit may also be achieved using an add-on control
device such as an incinerator, provided 90 percent control
efficiency is achieved.
Three State (Colorado, New Jersey, and Utah) regulations and
the South Coast regulation were reviewed and ranked according to
the stringency of these requirements versus Federal RACT. The
criteria used in determining stringency include the VOC emission
limitation and the required control efficiency.
The State and South Coast regulations specify the same
emission limit as the Federal CTG. Utah specifies an equivalent
emission limit in units of mass of VOC per unit mass of solids.
Guidelines for equivalency calculations are given in Appendices E
and F.
For surface coating operations with a control device, the
New Jersey regulation requires the device to have at least 90
percent emission reduction each hour or an hourly VOC emission
rate no greater than the maximum allowable hourly emission rate
calculated on a solids applied basis. The CTG specifies the same
control efficiency as the New Jersey regulation, but it does not
require the efficiency of a control device to be demonstrated on
an hourly basis. The New Jersey provision should result in more
accurate evaluation of the compliance performance. The rule is
not, however, necessarily more stringent than the CTG.
The South Coast regulation does not have any requirements
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that will affect the relative stringency of the rule. However,
they have provided several exemptions that are not specified in
the CTG, which reduces the number of sources to which the rule is
applicable.
4.15 Surface Coating of Paper
The Federal RACT emission limit for a paper coating line is
defined in terms of mass of VOC per unit volume of coating
applied (minus water). The Federal CTG also states that the
emission limit can be achieved using alternative means such as
incinerators, carbon adsorbers, or coatings that contain low
fractions of organic solvents.
Five State (Colorado, New Jersey, Utah, Rhode Island, and
Maine) and the two California District regulations were reviewed
and ranked for this category. The State regulations specify the
same emission limit for paper coating lines as the CTG. In
addition to the emission limit, New Jersey specifies coating
cutoff exemptions and requirements for an hourly emission
reduction or an hourly emission rate calculated on a solids
applied basis. This requirement may not result in quantifiable
reductions, but it will allow the compliance performance to be
more accurately evaluated. The Maine and Rhode Island
regulations provide equivalent emission limits for paper coating
operations in terms of mass of VOC per unit volume of solids
(nonvolatiles). These limits were calculated using the
guidelines specified in Appendix F. The Maine regulation
contains a provision that provides an incentive (monthly rather
than daily recordkeeping) for facilities which demonstrate that
only low-VOC coatings are used. The provision enhances the
pollution prevention aspects of the rule, but it was not used to
determine relative stringency. Maine's regulation also applies
to all paper coating lines (rather than only those above the
CTG's emission cutoffs), which is an applicability rather than a
stringency issue.
The Bay Area and South Coast regulations specify the same
emission limit, which is lower than that specified in the CTG.
The South Coast regulation also specifies an emission limit for
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plastisol, the required capture efficiency, and operating
requirements. Such information is not found in the Bay area
regulation or the CTG. These operating requirements are provided
to reduce or prevent emissions, but the reduction is not
quantifiable. In conclusion, the South Coast regulation is the
most stringent, followed by the Bay Area, then the CTG. The five
State regulations are considered as stringent as the CTG.
4.16 External Floating Roof Petroleum Tanks
The Federal CTG defines RACT in terms of an applicability
cutoff related to the storage capacity of a tank and the type of
seals or closure devices that must be installed on the tank.
Stringency for this category is defined through additional
equipment requirements which result in quantifiable emission
reductions. The exemption levels required by the State
regulations for this category were also evaluated. However,
exemption levels for this category are not appropriate for
evaluation of stringency, since the exemptions are more related
to the capacity cutoff levels. Although one of the regulations
reviewed for this source category was numerically less stringent
than the CTG, the difference in the allowable seal gap
specifications is not believed to be significant.
Two States (Colorado and Utah) and the two District
regulations were reviewed for this category. The State of
Colorado exemption levels mirror those found in the CTG, with one
addition. Colorado exempts external floating roof (EFR) tanks
that store any material whose true vapor pressure as stored
"never exceeds" 1.3 psia (8.96 kPa), while the CTG exempts EFR
tanks with a higher vapor pressure cutoff level (1.5 psia).
Therefore, more tanks are likely to be subject to the Colorado
rule. The Utah regulation cited in the summary table allows
greater gap space between the seal and tank wall than the CTG.
The impact on emissions is unlikely to be quantifiable.
The Bay Area and South Coast regulations have similar tank
capacity cutoff requirements to the CTG, but they have a lower
vapor pressure cutoff. Therefore, these regulations are more
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stringent than the CTG and the other States evaluated. The Bay
Area regulation also requires a greater overall control
efficiency as well as a smaller gap between the tank shell and
the secondary seal than the South Coast regulation or the CTG.
The South Coast regulation also specifies additional operating
requirements that are not found in the CTG. These additional
requirements include specifications for all openings in the roof
and any emergency roof, and the type of tank used for storing
crude oil containing hydrogen sulfide. These requirements may
not result in a quantifiable reduction in emissions, but they
enhance the pollution prevention aspects of the regulation. In
conclusion, the Bay Area provisions are considered the most
comprehensive relative to the CTG, followed by the South Coast
regulation.
4.17 Gasoline Tank Truck and Vapor Collection System Leaks
The RACT level for this source category is delineated in
terms of control approaches. The control approach is a
combination of testing, monitoring, and equipment design to
ensure that good maintenance practices are employed to prevent
leaks from truck tanks or tank compartments and vapor collection
systems during gasoline transfer at bulk plants, bulk terminals,
and service stations. The CTG recommends that a reading should
be less than or equal to 100 percent of the lower explosive limit
(LEL) at 2.5 centimeters around the perimeter of a potential
leaking source as detected by a combustible gas detector. The
CTG further specifies how vapor collection and vapor processing
equipment should be designed and operated so as to prevent leaks.
Both the Colorado and Texas regulations mirror the Federal
CTG requirements. In addition, the Colorado regulation requires
periodic visual inspections. This requirement provides a
desirable feature, but it does not result in a quantifiable
reduction. Therefore, in general, the Colorado and Texas
regulations are as stringent as the Federal CTG. (Information
regarding this source category was not found in the Bay Area or
South Coast regulation).
4.18 Graphic Arts
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The Federal CTG defines RACT in terms of percentage of
emission reduction through the application of add-on control
technology or product substitution. The "Blue Book" provides a
RACT emission limit for this category in terms of mass of VOC per
unit mass of solids applied [0.5 kg VOC/kg (0.5 Ibs VOC/lbs)
solids on a per-line basis]. The percentage of solids
(nonvolatiles) required in the coating is not specified. This
emission limit is applicable to both flexographic and rotogravure
printing processes, and to both publication and packaging
printing in which maximum theoretical VOC emissions (including
solvents used to clean each of these printing presses) without
control devices from all printing presses are greater than or
equal to 90.7 megagrams (100 tons) per year with 8,760 operating
hours or maximum production. The CTG RACT does not apply to
offset lithography or letterpress printing.
Six State regulations (Colorado, Connecticut, Maine, New
Jersey, New York, and Utah) were reviewed and ranked according to
the stringency of State requirements versus the CTG RACT
requirements. The criteria used to rank these regulations depend
upon how the specific concentration of nonvolatile (solid)
material in inks or the volatile portion of waterborne inks was
calculated. The percentage emission reduction and the
requirements for an alternative control technology also affect
the stringency.
The Colorado and Utah regulations basically mirror the
Federal CTG. However, the Connecticut regulation requires a
control system to achieve the emission limit on an hourly basis
or every adsorption cycle. Due to these requirements, the
Connecticut regulation will result in more accurate compliance
performance evaluations than the CTG and may thus help to
identify areas having potential emission reduction.
The Maine and New York regulations specify a lower VOC
emission cutoff (50 tons per year or less for some New York
areas) than the CTG, and thus, more facilities are subject to the
rules. The New Jersey regulation exempts surface coating
operations (commercial and research operations) that use coatings
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containing VOC below the cutoff hourly or daily rate. The New
Jersey regulation also specifies the emission limit in terms of
mass of VOC per unit volume of coating. To compare stringency
between the Federal RACT and the New Jersey regulation, the units
of the emission limit were converted to mass of VOC per unit mass
of solids using the procedure specified in Appendix F. The
calculated emission limit is 0.3 Ib VOC/lb of solids and is lower
than the limit specified in the CTG (0.5 Ib VOC/lb of solids).
Therefore, the New Jersey regulation is considered more stringent
than the CTG and the other State regulations. The Utah
regulation is applicable to "special printing operations," which
results in more printing operations subject to the rule.
Overall, the State regulations other than New Jersey's are as
stringent as the CTG.
The Bay Area and South Coast regulations specify the same
emission limits in terms of mass of VOC per unit volume of
coating. The calculated emission limit in terms of mass of VOC
per unit mass of solids (nonvolatiles) is 0.24, which is lower
than the limit specified in the "Blue Book" or the New Jersey
regulation. Therefore, the Bay Area and South Coast regulations
are more stringent than the New Jersey regulation or the CTG.
The Bay Area, however, requires a higher overall control
efficiency than the South Coast (85 vs 70 percent). The Bay Area
also specifies emission limits for two additional coatings that
are not specified in the South Coast regulation or the CTG. In
conclusion, the Bay Area regulation is considered more stringent
than the South Coast rule, followed by New Jersey, and then the
CTG.
4.19 Leaks from Petroleum Refinery Equipment
The Federal CTG defines RACT in terms of operating
procedures, monitoring program, and timeframe for repairing
leaks. Stringency for this category is defined by a shorter
timeframe for repairing leaks, additional monitoring, and
operating requirements. The Utah, Colorado, and Bay Area
regulations contain some requirements that are considered more
stringent than the Federal CTG.
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Stringency for this source category was difficult to
quantify since all of the listed requirements consist of specific
recordkeeping procedures, specific monitoring requirements, and
additional specifications for equipment. These requirements,
although necessary for determining compliance, are difficult to
rank and their benefits are not readily quantifiable. Also, some
of the additional equipment specifications that are now required
may not have existed at the time the Federal CTG was published.
Therefore, no clear distinction between "additional" requirements
beyond RACT can be made.
The Utah, Colorado, and Bay Area regulations were reviewed
for this category. Utah and Colorado include additional
"administrative" requirements, such as specification of a time-
frame for a proposed monitoring program, as well as documentation
and notification of the proper authorities when inspecting a
leak. Each State regulation reviewed lists the same EPA
Reference test methods, calibration procedures, and similar VOC
monitoring procedures. The Utah regulation exempts some
equipment from monitoring requirements, thereby making them
applicable to a smaller population of sources than the Federal
CTG and the Colorado rule. As shown in the table in Appendix B,
the exemptions are specifically related to the vapor pressure of
stored product, location of pressure relief valves, and the
contents of the stream composition. The "unsafe to monitor"
requirements found in the Utah regulation are not specifically
found in the Federal CTG, the Colorado regulation, or the "Blue
Book." However, the "Blue Book" recommends consistency with the
SOCMI guidance in relation to "unsafe to monitor" requirements,
which mirrors the requirements advised by the State (Utah)
regulation. As described above, there are very minor differences
in the State regulations and they are considered generally
comparable. Therefore, both the Utah and Colorado regulations
are determined to be as stringent as the CTG.
The Bay Area regulation defines a leak with lower VOC
concentration (500 ppm from any valve or connector and 1,000 ppm
from any pump or compressor) and provides a shorter timeframe for
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repairing leaks (7 days vs 15 days) than the CTG, Utah, or
Colorado. Both requirements will result in substantial and
quantifiable emission reductions. Therefore, the Bay Area
regulation is considered the most stringent.
4.20 Surface Coating of Miscellaneous Metal Parts and Products
The Federal CTG defines RACT in terms of emission limits for
several types of coating categories. The recommended limits are
given in terms of mass of VOC per unit volume of coating as
applied (minus water). The CTG gives "case examples" of how to
calculate emission limits and emission factors. It lists a
typical solids (nonvolatiles) content for a conventional coating,
but does not indicate to which of the five coating categories the
example applies. Thus, the CTG does not give "typical" coating
compositions for the coating of miscellaneous metal parts.
Stringency for this category is defined by comparing the
emission limit, control efficiency, additional emission limits,
and other requirements which may result in quantifiable
reductions. Four State regulations and the two District
regulations were reviewed for this category.
The State regulations (Utah, Colorado, Maine, and New
Jersey) specify the same emission limits as the CTG. In addition
to the emission limits, the Maine regulation provides an
incentive for facilities which demonstrate that only low-VOC
coatings are used by allowing them to keep monthly rather than
daily records. The CTG specifies daily recordkeeping.
The Bay Area and South Coast regulations specify a lower
emission limit than the CTG for air dried items. The South Coast
regulation provides two emission limits for various coatings
depending upon how the coatings are dried (air dried or baked).
The emission limits for coatings that are baked are usually lower
than for air dried. In addition to the emission limits, the
South Coast regulation also requires a greater control efficiency
for control systems and provides emission limits for "additional
coatings" that were not specified in the CTG (including limits
for cleaning materials). Therefore, the South Coast regulation
is considered the most stringent, followed by the Bay Area, and
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then the CTG.
4.21 Pneumatic Rubber Tire Manufacturing
The Federal CTG defines RACT under four main operations
involved in the manufacture of rubber tires, listing control
options for each of these operations and giving the expected
capture and destruction efficiencies. Stringency for this source
category is determined by comparing the control options and their
respective efficiencies.
Two State regulations (Colorado and Connecticut) and the Bay
Area regulation were reviewed for this source category. Both the
Colorado and Connecticut regulations generally mirror the Federal
CTG in almost all requirements. However, the Connecticut
regulation could be considered more stringent since it requires
the use of control equipment able to achieve higher control
efficiencies than required by the CTG. The CTG states that the
expected capture and control efficiency is between 65 and 85
percent. However, the State of Connecticut requires a control
efficiency of at least 85 percent; therefore, its rule is
considered to be more stringent. In addition, the Connecticut
regulation requires the efficiency of a control system to be
maintained on an hourly basis (for incinerators) or on each
adsorption cycle (for carbon adsorption systems). This latter
requirement will result in a more accurate compliance performance
evaluation, but does not affect the stringency of the rule.
The Bay Area regulation specifies a higher overall control
efficiency for emission reduction systems for this category than
the Connecticut regulation or the CTG.
4.22 Surface Coating of Flat Wood Paneling
The Federal CTG defines RACT in several ways. The emission
limits are expressed as mass of VOC per unit area coated, mass of
VOC per unit volume of coating, and mass of VOC per unit volume
of solids (nonvolatiles).
The relative stringency of rules for this category is
determined by comparing the emission limits and the required
control efficiency of a control device, and by examining
additional emission limits. Four State regulations (New Jersey,
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Maine, Texas, and Utah) and the two California District
regulations were reviewed for this category. The State
regulations specify the same emission limits as the CTG. In
addition to these limits, the Maine regulation provides an
incentive for facilities that demonstrate that only low-VOC
(compliant) coatings are used (monthly rather than daily
records). This incentive was not factored into determining the
relative stringency; however, this provision does encourage
pollution prevention activities.
The Bay Area and South Coast regulations specify only one
emission limit for wood flat stock coatings. Wood flat stock is
defined as panels containing wood including but not limited to
redwood stocks, plywood panels, particle boards, composition
hardboards, and any other panels containing solid wood or wood
product. To compare stringency between the CTG and the District
rules, the emission limits specified in the CTG were averaged.
The averaged emission limit is 0.3 kg/1 (2.53 Ib/gal) of coating
and is higher than the limit specified in the Bay Area or South
Coast regulation. In addition to the limit, the South Coast
regulation requires higher destruction and capture efficiencies
than the CTG. Therefore, The South Coast regulation is
considered the most stringent, followed by the Bay Area
regulation, and then the CTG.
4.23 Synthesized Pharmaceutical Products
The Federal CTG defines RACT in several ways for this source
category. It specifies that vents that emit at least a certain
amount per day of VOC must install surface condensers or
equivalent controls. The CTG gives temperature and vapor
pressure specifications for surface condensers. Production
equipment emitting over a certain mass per day of VOC must
control to a specified percentage emission reduction. The CTG
also specifies a cutoff for VOC-containing storage tanks, and
contains additional work practice provisions.
Stringency for this category is defined by additional
equipment and operation requirements that are not found in the
Federal CTG. Both the Colorado and Connecticut regulations
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generally mirror the Federal CTG. They also provide additional
requirements to those specified in the CTG. These requirements
include covers for all in-process tanks and making repairs
immediately, rather than within 15 days as allowed by the CTG.
However, the benefit of these requirements is not readily
quantifiable, and therefore they are not factored into
determining the stringency. For these reasons, the Colorado and
Connecticut rules are ranked as stringent as the CTG.
The relative ranking of Colorado, Connecticut, and the
Federal CTG is very close. As stated earlier, the differences
between the three are minor with the segregating factor related
to how many "additions" there are.
In addition to requirements specified in the CTG, the Bay
Area and South Coast regulations specify requirements for
centrifuges, rotary or vacuum filters, or any other filters. The
Bay Area also requires the use of chemical sterilizers, which is
not contained in the South Coast regulation or the CTG.
4.24 Air Oxidation Processes - SQCMI
Federal RACT is applicable to any air oxidation facility in
the synthetic organic chemical manufacturing industry (SOCMI) in
which air is used as an oxidizing agent to produce an organic
chemical. Any equipment used to collect VOC for sale or reuse
from a product recovery system of an oxidation facility is
subject to RACT.
The CTG specifies that each air oxidation process vent
stream must use a control device that reduces total organic
compound emissions by 98 percent by mass or to 20 ppmv. However,
this is not required for facilities that have a total resource
effectiveness (TRE) index value greater than unity. The TRE
index is a measure of the supplemental total resource requirement
per unit VOC reduction, associated with VOC control by thermal
oxidation. All resources that are expected to be used in VOC
control by thermal oxidation are taken into account in
determining the TRE index.
No State or District regulations concerning air oxidation
processes - SOCMI were provided through the Work Group. Several
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State regulations (Texas, Pennsylvania, Rhode Island, and
Colorado) were consulted, but no State regulations pertaining to
this category were located.
4.25 Equipment Leaks from Natural Gas/Gasoline Processing
Plants
The Federal CTG for this source category defines equipment
specifications and suggests a leak detection and repair (LDAR)
program. The CTG also recommends the appropriate test methods to
be used to determine compliance with any standards set forth, and
provides an inspection schedule.
Relative stringency for this source category depends on a
shorter timeframe for leak repair and by additional inspection
requirements not set forth in the CTG. The Texas regulation and
the two California District regulations were reviewed for this
category.
The Texas regulation specifies monitoring and repair
requirements for relief valves that have vented to the atmosphere
within 24 hours at manned facilities or within 30 days at
unmanned facilities. The CTG does not provide any timeframe for
repairing leaks from relief valves. This provision, however, is
not used to determine stringency since the benefit is not readily
quantifiable.
The Bay Area regulation specifies the distance to measure
the concentration of VOCs from the source of a leak and the time-
frame for repairing any leak. The regulation provides two time-
frames for repairing leaking equipment, which depend upon whether
or not the equipment is essential. The Bay Area rule defines the
term "essential" as applying to any equipment that cannot be
taken out of service without shutting down the process which it
serves. The Bay Area regulation specifies that if the leaking
equipment is not essential or the equipment can be repaired
without interrupting the process, the leak must be repaired
within 24 hours. This part of the rule is more stringent than
the CTG. For essential equipment, the Bay Area requires the leak
to be minimized within 24 hours and if the leak persists and
exceeds a concentration of 10,000 ppm, the equipment is to be
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repaired at the next scheduled maintenance. Stringency could
have been determined based on the length of time required to
minimize the losses from leaks but, in this case, the requirement
may not result in a quantifiable reduction in emissions. It
does, however, enhance the pollution prevention aspects of the
rule.
The South Coast regulation specifies several timeframes for
different concentrations of leaks. The rule requires repair of a
minor gas leak (in excess of 1,000 ppm but less than 10,000 ppm)
within 14 calendar days. This range of concentration is not
considered a leak in the CTG or the Bay Area rule, and no repair
is needed. The South Coast regulation requires a leak with a VOC
concentration of greater than 10,000 ppm to be repaired within 5
days (not 15 days as specified in the CTG). The timeframe is
further reduced to 1 day for repairing a gas leak with VOC
concentration over 50,000 ppm or any liquid leak. These
requirements should result in a significant reduction in
emissions.
The Bay Area and South Coast regulations also provide
additional operating requirements pertaining to uncovered
vessels, liquid pools, and operator inspection that will enhance
the pollution aspects of the rules.
4.26 Large Petroleum Drv Cleaners
The Federal CTG for large petroleum dry cleaners sets an
emission limit in terms of mass of VOC per unit mass of articles
cleaned. It specifies the control equipment and a timeframe for
repairing leaks.
The relative stringency for this category is determined on
the basis of lower VOC emission limits or alternative emission
limits, longer draining time, and additional requirements that
may result in reducing emissions.
No State regulations for controlling large petroleum dry
cleaners were provided through the Work Group. New York,
Pennsylvania, and Texas rules were consulted, but they addressed
only percholoroethylene dry cleaners.
The Bay Area and South Coast regulations require cartridge
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filters to be drained in the filter housing for at least 12 hours
before removal. The CTG is less stringent than the Bay Area or
the South Coast regulation since it requires only 8 hours of
draining time. The Bay Area and South Coast regulations also
provide specific operating requirements for transferring articles
to the dryer within a specified time limit, which will result in
quantifiable emission reductions. The South Coast regulation
specifies the same emission limit as the CTG for a dry cleaning
facility with a solvent filtration system. The South Coast
regulation also provides an alternative method to meet the
emission limit in terms of mass of VOC per mass of solvent still.
This means that if the first emission limit is not applicable,
the alternative method must be used to comply with the rule. The
Bay Area, on the other hand, specifies a lower VOC emission limit
and a lower solvent flow rate from a solvent recovery dryer than
the South Coast regulation or the CTG. These provisions would
likely result in significant emission reductions. Therefore, the
Bay Area regulation is considered more stringent than the South
Coast rule or the CTG.
4.27 Polymer Manufacturing
The Federal CTG divides this source category into three
types of polymer manufacturing plants: polystyrene,
polypropylene, and high-density polyethylene. RACT for this
category is defined in terms of emission limits and percentage
emission reductions or emission rates. An emission limit in
terms of mass of VOC per unit volume is specified only for
polystyrene plants using continuous processes. Recommended
limitations for both polypropylene and high-density polyethylene
plants are given in terms of percent of emission reduction or
emission rates. The Federal CTG states that the RACT
recommendations were made on the basis of a single control device
controlling all vents of VOC emissions.
Only one State regulation (Connecticut) was received from
the Work Group members and reviewed for this source category. No
RACT rule for this category was located in the Bay Area or South
Coast regulation. The Connecticut regulation specifies only an
4-30
-------
emission limit (in terms of mass of VOC per unit volume) for
polystyrene plants. No information is available for
polypropylene or high-density polyethylene plants. The State
emission limit for polystyrene plants is the same as in the
Federal CTG (0.12 kg of VOC/1,000 kg of product). However,
Connecticut's emission limit for polystyrene plants must be
achieved over a 1-hour period. In order to meet the limit, it is
necessary to monitor or document the performance of the control
equipment every hour. The Connecticut regulation also requires
the owner or operator of a facility to maintain monitoring
records for a period of 2 years, while the Federal CTG does not
specify a timeframe over which these records must be kept. For
these reasons, the Connecticut regulation is considered to be
more stringent than the Federal CTG.
4.28 SOCMI and Polymer Manufacturing Equipment Leaks
RACT is applicable to components that appear to be leaking.
These components include pumps, compressors, valves, open-ended
lines, safety relief valves, etc. The CTG also specifies
inspection and maintenance requirements.
Only one State regulation (Connecticut) was reviewed for
this category, since information was not located for this
catgegory for the Bay Area or the South Coast. The criteria used
to determine relative stringency are based on compliance and
reporting requirements.
The Connecticut regulation requires leaking equipment found
during monitoring or on the basis of sight, smell, or sound to be
repaired within 15 days after detection. Providing a specific
timeframe to repair equipment leaks should help reduce VOC
emissions significantly. The State regulation also requires 10-
day notification prior to the scheduled quarterly monitoring.
This requirement is part of the monitoring procedures to be in
compliance, but it does not have any impact in reducing
emissions. In general, the Connecticut regulation is more
stringent than the Federal CTG.
4-31
-------
APPENDIX A.
COMPARISON OF STATE/LOCAL VOC RULES TO FEDERAL RACT
FOR GROUP I CTG CATEGORIES2
2This appendix describes Federal RACT for source categories
covered in the Group I CTGs, as well as regulatory requirements
for the same categories as contained in selected State/local VOC
rules.
A-32
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APPENDIX C.
COMPARISON OF STATE/LOCAL VOC RULES TO FEDERAL RACT
FOR GROUP III CTG CATEGORIES2
2This appendix describes Federal RACT for source categories covered in
the Group III CTGs, as well as regulatory requirements for the same
categories as contained in selected State/local VOC rules.
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APPENDIX E.
ESTIMATING THE AMOUNT OF
THINNING SOLVENT ALLOWED
E-l
-------
APPENDIX E5
DETERMINING THE AMOUNT OF THINNING SOLVENT ALLOWED
This may be achieved in two steps:
1. Estimating volume of nonvolatile matter (solids) - Part A.
2. Calculating the volume of thinning solvent allowed - Part B.
The allowed amount of thinning solvent is any volume that is less
than the thinner volume calculated based on the given equation.
The equation can be represented in graphical form and used for
rapidly estimating thinning allowances pertaining to a VOC emission
limitation. The curve in Figure E.I was generated assuming that
the VOC limit is 571 g/L of nonvolatiles (solids) , the thinning
solvent density is 1,200 g/L, and the solvent is 100% VOCs.
A procedure for converting an emission limit from one set of units
to another is also illustrated:
from mass of volatiles/unit volume of coating or mass of
volatiles/unit volume of coating (less water and
'exempt'7 solvents)
to mass of volatiles per volume of nonvolatile matter
(solids) in a coating.
M. Serageldin, EPA, to Project File. Procedure for Determining Nonvolatiles (Solids), Equivalent
Paint VOC or VOHAP Limits, and Allowed Amount of Thinning Solvent - NESHAP for Shipbuilding
and Ship Repair Facilities (Surface Coating), June 30,1994. (Docket No. A-92-11, Document No. II-B-
26).
6The terms "nonvolatiles" and "solids" are used
interchangeably to refer to the film forming material of a
coating.
7An 'exempt' compound (solvent) is an organic compound that
would be considered a VOC if it were not classified by EPA as
having negligible photochemical reactivity. These compounds are
listed in 40 CFR 51.100(s).
E-2
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Part A
ESTIMATING VOLUME OF NONVOLATILE MATTER (SOLIDS)
The amount of film forming material or nonvolatiles (solids) in
a coating is usually calculated from formulation data. Some paint
companies, however, report the percentage of nonvolatiles using
methods which are based on those developed by ASTM (American
Society for Testing and Materials) . Since there is presently no
approved EPA method for measuring the amount of film forming
material, the discussion will focus only on the procedure for
calculating what may be termed the theoretical volume of
nonvolatiles (solids) .
CASE 1 : Coatings containing no exempt solvents or water
An example calculation (in standard international units) follows
for a coating where the volatiles are all VOCs :
Coating volume (Liter) = VNV (Liter) + Vvoc (Liter) E.I
where V^, stands for volume of nonvolatile matter and Vvoc for volume
of volatile organic compounds, VOCs. In the above representation,
it is assumed that the volumes of the different components in a
coating are additive, which is not necessarily true.
Basis 1 Liter of coating:
VNV (L) = 1 (L coating) - Vvoc (L) E.2
Divide by total liters of coating:
VNV (L) Vvoc (L)
voc
1 L coating L coating
-, voc
L coating
VNV ( by vol.' - 1 - -vou •- E'3
E-3
-------
„ , , 1 ) = I 1 - VQC content of coating (g VOC/L coating)
m Y vo • ^ average density of solvents (g VOC/L VOC)
If the average density of the VOCs in this paint is 839 g/L, and
the VOC content is 340 g VOC/L, then:
NV
(vol.
340 g VOC 1 L VOC
— 5 v .. _
x
L coating 839 g VOC
vol.) = [ 1 - -405 ] = 0.595 ( 59.5 percent;
The VOC content in terms of nonvolatiles is:
340 g VOC /L coating
0.595 L NV /L coating
which is equal to 571 g VOC/L of nonvolatiles.
CASE 2. Coatings containing VOC, water, and exempt compounds
To calculate the ratio of VOCs to nonvolatiles (solids) in a
coating, the facility has to account for the volume of water and
'exempt' compounds in determining the volume of nonvolatiles
(solids). We therefore need to rewrite equation E.2 as follows:
VNV = 1 - [Vvoc + Vex + VJ E.4
where:
vvoc = voc volume (fraction) in the coating as supplied
(L VOC/L of coating);
Vex = 'exempt' solvent volume (fraction) in the coating as
supplied (L exempt solvents/L of coating);
Vw = water volume (fraction) in the coating as supplied
(L water/L of coating).
NOTE: Cure volatiles (those released due to chemical reactions in
E-4
-------
some coating films) will be dealt with at the end of this document,
Example:
If a coating having a VOC content of 208 g/L is made up of three
volatile components [25% (vol.) VOC solvent, 10% (vol.) 'exempt'
solvent, and 15% (vol.) water], one can determine the nonvolatile
volume to 3 significant figures as follows:
VNV = 1 - [0.250 + 0.100 + 0.150] = 0.500 L (50.0 percent)
The VOC content of this paint can be expressed in several wavs:
o 208 g VOC/L of coating
o (208/0.750) or 277 g VOC/L of coating less water and exempt
solvents
o (208/0.500) or 416 g VOC/L of nonvolatiles (solids).
E-5
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Part B
CALCULATION OF THINNING ALLOWED
Paint manufacturers or users add solvents to modify the flowing
properties of a coating. To determine the amount of thinning
solvent allowed, the user should know how much VOC is already in
the coating and the emission limit for that coating category. To
be in compliance, the total mass of VOCs in a coating must be less
than that set by the appropriate limit as indicated by the first
ratio in equation E.5.
mVOCl _ MVOC2
V,
V
th
E.5
NVl
' NV2
One can rewrite equation E.5 to determine Vth,
where:
Vth = maximum volume of thinner permitted, L/L of
coating;
a = the volume fraction of VOCs in the thinner, equal
to 1 if 100% VOC;
Dth = average density of thinning solvent (thinner) ,
g/L solvent;
= mass of VOCs in the coating, g/L coating;
= volatile organic compound;
= volume of nonvolatiles (solids), L/L coating;
= mass of VOC in limiting coating over
volume of nonvolatiles, g/L.
m
VOC
V
NV
VOC1/V
NVl
th
1
a D
LVOC1
V,
' \
NVl
E. 6
The subscript 1 stands for the limits of a compliant coating and 2
for the as-supplied coating (paint received from the paint
manufacturer) that needs to be thinned before application. The
maximum amount of thinner allowed should be less than Vth determined
E-6
-------
above for a given coating limit.
Scenario: Coating does not contain water, exempt solvents.
or cure volatiles
Problem: The user needs to determine the maximum amount of
solvent thinner that can be added to a coating. The VOC content of
the coating is 300 g/L of coating and the average density of the
VOC portion is 850 g/L of solvent. The thinner has a density of
900 g/L. Assume that the VOC limit for a coating category in a
rule is 340 g VOC/L of coating (minus water and exempt solvents);
this is equivalent to 571 g VOC/L of nonvolatiles (see Part A, CASE
1) .
Solution Steps:
1. Record the applicable limit for the coating category: 571 g
VOC/L of nonvolatiles.
2. Record the mass of VOC in a liter of coating: 300 g VOC/L of
coating (minus water and exempt solvents).
3. Calculate the (theoretical) volume of nonvolatiles VNV2 using
equation E.3.
VNV2 = 1 - (VOC)
= 1 - 0.353
= 0.647 L/L coating.
4. Record the density of thinning solvent Dth and the fraction
of VOC in the thinner: Dth= 900 g/L and a = 0.8.
5. Determine Vth using equation E.G.
E-7
-------
V
1
th
(0.8) (900)
571 g VOC 0>647 L W2) - (300 g VOC2
1 L NV1 y
0.096 L thinner/L of coating.
As a rule, the amount of thinning that is allowed for a
coating decreases with an increase in solvent density. Figure E.I
provides a rapid method for estimating the amount of thinning that
is allowed. For a coating with the same VOC content as in the
previous example (300 g/L of coating), the volume of thinner when
Dth= 900 g/L is around 0.08 L of thinner/L coating.
General Equation:
- *c\ E-7
where, as given before Vth is the maximum volume of thinner
permitted, L/L coating; a is the volume fraction of VOCs in the
thinner, equal to 1 if 100% VOC; Dth is the average density of
thinning solvent (thinner), g/L solvent; m is the mass of VOCs in
the coating, g/L coating; VOC = volatile organic compound; VNV is
the volume of nonvolatiles (solids), L/L coating; and VOC1/VNV1 is
the mass of VOC in limiting coating over volume of 2nonvolatiles,
g/L. The term mc stands for mass of cure volatiles that are VOCs
(e.g., formaldehyde). When a coating does not release cure
volatiles, mc should be deleted from equation E.7. The maximum
amount of thinner added should be less than Vth determined above for
a given coating limit.
-------
0.6 i—
0.5
i
«
o
o
I
I
0.4
0.3
0.2
0.1 -
0.0
imit f 571 g VOC/ L nonvolatiles '(solids)
© Solvent density - 840 g/L
Q Solvent density = 1,200 g/L
0 50 100 150 200 250 300 350
As-supplied Coating, g VOC/L coating
Figure E.I. Estimating Maximum Thinning Allowance
(NOTE: This figure applies when all the volatiles in
the coating are VOCs. The av. density of the
volatiles in a coating was assumed equal to 840 g
E-9
-------
solvent/L solvent.
E-10
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APPENDIX F.
CONVERTING EMISSION LIMIT UNITS FROM MASS VOC/VOL COATING
TO MASS VOC/MASS SOLIDS (NONVOLATILES) IN COATING
F-l
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APPENDIX F
CONVERTING EMISSION LIMIT UNITS FROM MASS VOC/VOL COATING
TO MASS VOC/MASS SOLIDS (NQNVOLATILES) IN COATING
Some of the rules reviewed presented their emission limits as
VOC per unit mass of solids (nonvolatiles), whereas the VOC limits
in these CTGs were presented in terms of coating volume. To
compare these rules, the CTG limits were converted into these
alternate limits using the steps outlined in the example below.
Given:
Emission limit: 0.3 kg VOC/L of coating (minus water and
exempt solvents), VOC density: 883 g/L (7.36 Ib VOC/gal) of
solvent, assuming all volatiles are VOCs.
Solution Steps:
To perform this conversion, one needs to know the density of
the solids (nonvolatiles) in the coating. Assume the density of
nonvolatiles is 16 Ib solids/gal solids.
Step 1: Convert the units of the emission limit to
Ib VOC/gal coating.
. 3 kg VOC # 2.20 Ib ^ 3.78 L = 2.49 Ib V
L coating 1 kg 1 gal coating 1 gal coat
F-2
-------
Step 2: Calculate volume of VOCs in a gallon,
0.660 lb VOC ^ I gal VOC = 0.339 gal VOC
I gal coating 7.36 lb VOC I gal coating
Step 3: Determine the nonvolatiles volume.
The theoretical nonvolatiles volume can be
calculated using equation E.3 (Appendix E).
Basis 1 gallon of coating:
1 gal coating - Vvoc = V^
F-3
-------
= 1 - 0.339 = 0.661 gal solids/gal coating
Step 4: Calculate Ib VOC/lb solids.
I gal coating ^ 1 gal solids ^ 2.49 Ib VOC
0.661 gal solids 16 Ib solids 1 gal coating
0.236 Ib VOC
I Ib solids
F-4
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APPENDIX G.
EPA VOC POLICY WORK GROUP
G-l
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Anne Arnold
U.S. EPA Region I
Room 2203
JFK Federal Building
Boston, MA 02203-2211
Phone: (617) 565-3166
FAX: (617) 565-4939
Paul Truchan
U.S. EPA Region II
Room 1005
26 Federal Plaza
New York, NY 10278
Phone: (212) 264-2518
FAX: (212) 264-7613
Lisa Wild
U.S. EPA Region III
Air Enforcement Branch
841 Chestnut Building
Philadelphia, PA 19107
Phone: (215) 597-9318
FAX: (215) 597-7906
Cynthia Stahl
U.S. EPA Region III (3AM10;
Air Programs Branch
841 Chestnut Building
Philadelphia, PA 19107
Phone: (215) 597-9337
FAX: (215) 597-7906
Diane Altsman
U.S. EPA Region IV
Air Programs Branch
345 Courtland Street, NE
Atlanta, GA 30365
Phone: (404) 347-2864
FAX: (404) 347-5246
Steve Rosenthal
U.S. EPA Region V (5AR-26;
Air & Radiation Branch
77 West Jackson Street
Chicago, IL 60604
Phone: (312) 886-6052
FAX: (312) 886-5824
Guy Donaldson
U.S. EPA Region VI
Suite 1200
1445 Ross Avenue
Dallas, TX 75202-2733
Phone: (214) 655-7242
FAX: (214) 655-2164
Joshua Tapp
U.S. EPA Region VII
Air Branch
726 Minnesota Avenue
Kansas City, KS 66101
Phone: (913) 551-7606
FAX: (913) 551-7065
Tim Russ
U.S. EPA Region VIII (8ART-AP)
999 18th Street
Denver Place, Suite 500
Denver, CO 80202-2405
Phone: (303) 293-1814
FAX: (303) 293-1229
Dave Hodges
U.S. EPA Region IX
Air Programs Branch (A-2-3)
75 Hawthorne Street
San Francisco, CA 94105
Phone: (415) 744-1197
FAX: (415) 744-1076
G-2
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Chris James Christine Lee
U.S. EPA Region X U.S. EPA Region X (AT-092;
Air & Radiation Branch (AT-092) Air & Radiation Branch
1200 Sixth Avenue 1200 Sixth Avenue
Seattle, WA 98101 Seattle, WA 98101
Phone: (206) 553-1194 Phone: (206) 553-1814
FAX: (206) 553-0110 FAX: (206) 553-0110
G-3
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APPENDIX H.
LIST OF GROUPS I, II, AND III CTGs
H-l
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Group I CTGs (Pre-1978)
1. Control of Volatile Organic Compounds from Use of Cutback
Asphalt. EPA-450/2-77-037. U.S. EPA, OAQPS. December 1977.
OAQPS No. 1.2-090.
2. Control of Volatile Organic Emissions from Storage of
Petroleum Liquids in Fixed-Roof Tanks. EPA-450/2-77-036.
U.S. EPA, OAQPS. December 1977. OAQPS No. 1.2-089.
3. Control of Volatile Organic Emissions from Bulk Gasoline
Plants. EPA-450/2-77-035. U.S. EPA, OAQPS. December 1977.
OAQPS No. 1.2-085.
4. Control of Hydrocarbons from Tank Truck Gasoline Loading
Terminals. EPA-450/2-77-026. U.S. EPA, OAQPS. October 1977.
OAQPS No. 1.2-082.
5. Control of Refinery Vacuum Producing Systems, Wastewater
Separators and Process Unit Turnarounds. EPA-450/2-77-025.
U.S. EPA, OAQPS. October 1977. OAQPS No. 1.2-081.
6. Design Criteria for Stage I Vapor Control Systems--Gasoline
Service Stations. U.S. EPA, OAQPS. November 1975. (Design
Criteria Document.)
7. Control of Volatile Organic Emissions from Solvent Metal
Cleaning. EPA-450/2-77-022. U.S. EPA, OAQPS. November 1977.
8. Control of Volatile Organic Emissions from Existing Stationary
Sources - Volume II: Surface Coating of Cans, Coils, Paper,
Fabrics, Automobiles, and Light-Duty Trucks. EPA-450/2-77-
008. U.S. EPA, OAQPS. May 1977. OAQPS No. 1.2-073.
9. Control of Volatile Organic Emissions from Existing Stationary
Sources - Volume V: Surface Coating of Large Appliances.
EPA-450/2-77-034. U.S. EPA, OAQPS. December 1977. OAQPS No.
1.2-088.
10. Control of Volatile Organic Emissions from Existing Stationary
Sources - Volume III: Surface Coating of Metal Furniture.
EPA-450/2-77-032. U.S. EPA, OAQPS. December 1977. OAQPS No.
1.2-086.
11. Control of Volatile Organic Emissions from Existing Stationary
Sources - Volume IV: Surface Coating of Insulation for Magnet
Wire. EPA-450/2-77-033. U.S. EPA, OAQPS. December 1977.
OAQPS No. 1.2-087.
H-2
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Group II CTGs (1978
Control of Volatile Organic Emissions from Petroleum Liquid
Storage in External Floating Roof Tanks. EPA-450/2-78-047 .
U.S. EPA, OAQPS. December 1978. OAQPS No. 1.2-116.
Control of Volatile Organic Compound Leaks from Gasoline Tank
Trucks and Vapor Collection Systems. EPA-450/2-78/051 . U.S.
EPA, OAQPS. December 1978. OAQPS No. 1.2-119.
Control of Volatile Organic Compounds from Existing Stationary
Sources - Volume VIII: Graphic Arts - Rotogravure and
Flexography. EPA-450/2-78-033 . U.S. EPA, OAQPS. December
1978. OAQPS No. 1.2-109.
Control of Volatile Organic Leaks from Petroleum Refinery
Equipment. EPA-450/2-78-036 . U.S. EPA, OAQPS. June 1978.
OAQPS No. 1.2-111.
Control of Volatile Organic Emissions from Existing Stationary
Sources - Volume VI: Surface Coating of Miscellaneous Metal
Parts and Products. EPA-450/2-78-015 . U.S. EPA, OAQPS. June
1978. OAQPS No. 1.2-101.
Control of Volatile Organic Emissions from Manufacture of
Pneumatic Rubber Tires. EPA-450/2-78-030 . U.S. EPA, OAQPS.
December 1978. OAQPS No. 1.2-106.
Control of Organic Emissions from Existing Stationary Sources
- Volume VII: Factory Surface Coating of Flat Wood Paneling.
EPA-450/2-78-032. U.S. EPA, OAQPS. June 1978. OAQPS No.
1.2-112.
Control of Volatile Organic Emissions from Manufacture of
Synthesized Pharmaceutical Products. EPA-450/2-78-029 . U.S.
EPA, OAQPS. December 1978. OAQPS No. 1.2-105.
Group III CTGs (Post-1978)
1. Control Volatile Organic Compound Emissions from Air Oxidation
Processes in Synthetic Chemical Manufacturing Industry. EPA-
450/3-84-015. U.S. EPA, OAQPS. December 1984.
2. Control of Volatile Organic Compound Equipment Leaks from
Natural Gas/Gasoline Processing Plants. EPA-450/3-83-007.
U.S. EPA, OAQPS. December 1983.
H-3
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Group III CTGs (Concluded)
3. Control of Volatile Organic Compound Emissions from Large
Petroleum Dry Cleaners. EPA-450/3-82-009. U.S. EPA, OAQPS.
September 1982.
4. Control of Volatile Organic Compound Emissions from
Manufacture of High-Density Polyethylene, Polypropylene, and
Polystyrene Resins. EPA-450/3-83-008. U.S. EPA, OAQPS.
November 1983.
5. Control of Volatile Organic Compound Leaks from Synthetic
Organic Chemical and Polymer Manufacturing Equipment. EPA-
450/3-83-006. U.S. EPA, OAQPS. March 1984.
H-4
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TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO.
EPA-453/R-95-
010
4. TITLE AND SUBTITLE
BEYOND VOC RACT (
2.
:TG REQUIREMENTS
7. AUTHOR (S)
9. PERFORMING ORGANIZATION NAME
Pacific Environnu
Central Park Wes1
5001 South Miami
PO Box 12077
Research Triangl
; AND ADDRESS
=ntal Services, Inc.
b
Boulevard
5 Park, NC 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
Director
Office of Air Quality Planning and
Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
April 1994
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D1-0116
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
EPA Project Manager: Mohamed Serageldin, Ph.D. (919) 541-
2379
16. ABSTRACT
This document contains a comparison of State (and local) and
Distict regulations with control techniques guideline (CTG)
source categories. The purpose was to identify those State
regulations that exceed the reasonably available control
technology (RACT) requirements that are specified in the Federal
CTGs. This study is limited to CTG groups I, II, and III only,
which cover 28 source categories.
17.
a. DESCRIPTORS
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS c. COSATI
Field/ Group
Air Pollution, Summary of VOC, CTG,
State and District Air RACT Review
Regulations, Comparison of Stringency
State Regulations with Pollution Prevention,
Federal Control Technique Regulations, Rules
Guidelines (CTGs)
18. DISTRIBUTION STATEMENT
Release Unlimited
19. SECURITY CLASS (Report) 21. NO. OF PAGES
Unclassified 346
20. SECURITY CLASS (Page) 22. PRICE
Unclassified
H-5
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EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
H-6
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'
l$. «»£WTAL PROTECTION
AGENCY
1445 ROSS AVENUE /
DALLAS, TEXAS 75202
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