EPA/540/2-89/027
                                   tNVIRONMENTAI
                                    PROTECTION
                                      AGENCY
                                   DALLAS, TEXAS
                                     LIBRARY
     SUPERFUNDTREATABILITY
            CLEARINGHOUSE
               Document Reference:
 Acurex Corp., Environmental Systems Divisions, Combustion Research Facility.
 "CRF Test Burn of PCB-Contaminated Wastes from the BROS Superfund Site."
Approximately 300 pp. Prepared for U.S. EPA Office of Research and Development.
                      March 1987.
              EPA LIBRARY NUMBER:

           Superfund Treatability Clearinghouse - E
           PIFfi^F RH F*T P"-.^.'?" rpCP fPO&IlV
           riJLAaC, yy E.^J ^^,,;w;^ Hil^l Liyi\^Hf

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                 SUPERFUND TREATABILITY CLEARINGHOUSE ABSTRACT
 Treatment  Process:

 Media:

 Document Reference:
 Document  Type:

 Contact:
Site Name:
Location of Test:
Thermal - Rotary Kiln

Soil/Clayey

Acurex Corp., Environmental Systems Divisions,
Combustion Research Facility.  "CRF Test Burn of
PCB-Contaminated Wastes from the BROS Superfund
Site."  Approximately 300 pp.  Prepared for U.S.
EPA Office of Research and Development.  March
1987.

EPA ORD Report

Donald Lynch
U.S. EPA - Region II
26 Federal Plaza
New York,  NY  10278
212-264-8216

BROS Superfund Site (NPL)

Jefferson, AR
BACKGROUND;  This report provides results of test burns at the EPA Combus-
tion Research Facility on waste from Bridgeport Rental and Oil Service
(BROS) Superfund site, NJ.  The purpose of the study was to:  (1) determine
if waste could be incinerated safely; (2) comply with the Toxic Substances
Control Act  (TSCA) regulations governing PCB-contaminated waste; and  (3)
determine if residuals could be classified as non-hazardous.
OPERATIONAL INFORMATION;  Rotary kiln was cocurrent propane fired and had a
maximum design capacity of 900°C (1650°F) with a gaseous residence time of
1.7 seconds for 10* excess 0« in flue gas.  Containerized solvents were fed
in 1.5 gallon fiber packs using a ram feeder.  Liquids and sludge were fed
using a progressive cavity pump through a water-cooled lance.  Air pollu-
tion control (APC) equipment included a venturi scrubber/quench with  a 30
inch. U.D. pressure drop followed by a packed tower scrubber.  A backup dry
air pollution control system was utilized to ensure ultimate emissions
would be within the  applicable regulatory limits.  Scrubber system
blowdown was directed to a chemical sewer, if non-hazardous, or stored in
tanks for management at a RCRA facility, if hazardous.  Waste included:
lagoon surface oil, lagoon sludge, and soil.  Average composition:  210-600
ppm PCB, low to 38* water, 23.2-10,000 BUT/lb.  The soil was a clay mud
containing rocks, grass, roots, and twigs.
    Twelve tests were performed during 7/21/88 through 9/4/88 (test time
was five weeks).  Tests involved variation of:  waste feed, kiln tempera-
ture, excess 0«, rotation time (solid retention time).  The report provides
specific information on unit design (schematic diagram included) and
provides test data.  Sampling and analysis and QA information is also
provided.
3/89-48                                                 Document Number:   EXPC
    NOTE:  Quality assurance of data may not be appropriate for all uses.

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PERFORMANCE;  Table  1 summarizes  the PCB emission results.  The  test failed
to meet  the TSCA  regulations  for  99.9999 percent destruction efficiency
(DE) at  the stack gas effluent as measured after the scrubber discharge
flue gas.  DE results ranged  from 99.992 to 99.9998.  On average DEs were
highest  for surface  oil and lowest  for  the soil sludge mixtures.  Data
indicated no clear correlation between  key process parameters and DE.
Analysis indicates that a gas residence time of 2.0 seconds in the after-
burner and a temperature of 1200°C  would be required for this unit to
achieve TSCA requirements.  This  is twice the residence time achieved in
this test.
    Scrubber blowdown PCB content was below detection levels (<1 ug/L).
Kiln ash was below detection  level  for  PCBs except for ash from surface oil
which tested at 2.55 ug/g.  Particulate and HCL emissions were within
regulatory limits.   Metal concentrations in leachate samples from ash were
below the EP toxicity limit.
CONTAMINANTS;

Analytical data is provided in the treatability study report.
breakdown of contaminants by treatability group is:
                                The
Treatability Group

WOA-Halogenated Aliphatic
     Solvents
CAS Number

75-35-4
78-87-5
56-23-5
79-01-6
75-34-3
W07-Heterocyclics and Simple   71-43-2
     Aromatics                 108-88-3
                               71-43-2
WlO-Non-Volatile Metals
Wll-Volatile Metals
W13-0ther Organics
7440-39-3
7440-47-3

7439-92-1
7440-38-2

110-54-3
Contaminants

1,1-Dichloroethene
1,2-Dichloropropane
Carbon Tetrachloride
Trichloroethene
1,1-Dichloroethane

Benzene
Toluene
Benzene

Barium
Chromium

Lead
Arsenic

Hexane
Note:  This is a partial listing of data.
       information.
            Refer to the document for more
3/89-48                                                 Document Number:  EXPC

    NOTE:  Quality assurance of data may not be appropriate for all uses.

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                                             March 1987
   CRF TEST BURN OF PCB-CONTAMINATED WASTES
         FROM THE BROS SUPERFUND SITE
                      by

     Johannes W. Lee, Robert W. Ross, II,
   Carlo Castaldini, and Larry R. Waterland
              Acurex Corporation
        Environmental Systems Division
         Combustion Research Facility
          Jefferson, Arkansas  72079
          EPA Contract No. 68-03-3267
              EPA Project Officer

               Robert Mournighan
Hazardous Waste Engineering Research Laboratory
         Combustion Research Facility
          Jefferson, Arkansas  72079
     U.S. ENVIRONMENTAL PROTECTION AGENCY
      OFFICE OF RESEARCH AND DEVELOPMENT
            WASHINGTON D.C. 20460

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                                 CONTENTS
Figures	     iv
Tables  	      v

  1.  Introduction  	 .....      1
  2.  Facility Description and Operation  	      3
      2.1  Facility Description 	      3
      2.2  Waste Characteristics  	     10
      2.3  Facility Operation 	     17
  3.  Sampling and Analysis Protocols 	     24
      3.1  Sampling Location and Methods  	     24
      3.2  Analysis Protocols 	     26
  4.  Test Results	     33
      4.1  PCB Destruction	     33
      4.2  Volatile Organic Emissions 	     41
      4.3  Particulate and HC1 Emissions	     41
      4.4  Trace Element Emissions  	     51
  5.  Quality Assurance and Quality Control  	     55
      5.1  Measurement of Q-jn	     55
      5.2  Measurement of Qout	     56
      5.3  Volatile Organic Spike Recoveries  	     57

References	     60
Appendicies

  A.  Sampling Locations and Methods  	    A-l
  B.  Sample Recovery and Analysis Methods  	    B-l
  C.  Waste Feed Data	    C-l
  D.  Sampling Data	    0-1
  E.  Analytical Reports  	    E-l
                                    iii

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                                  FIGURES

Number                                                                   Page
   1   Rotary kiln Incinerator system  	      4
   2   Rotary kiln and afterburner detail  	      6
   3   Kiln temperature and residue time as a function  of heat
       input	      8
   4   Afterburner temperature as a function of total heat Input  ...      9
   5   Sampling Protocol 	     25
   6   PCS DEs	     35
   7   PCB DE as a function of excess 02	     37
   8   PCB DE as a function of gas flowrate	     38
   9   PCB DE as a function of mean temperature	     39
  10   PCB DE versus mean temperature/gas flowrate	     40
                                     iv

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TABLES
Numbei
1
2
3
4
5
6
7
8
9
10

11
12

13

14

15

r
Design Characteristics of the CRF Rotary Kiln System 	
Summary Analysis Data for the BROS Soil 	





Analysis Performed for Kiln PCB Test Burn of BROS Wastes . . .

Volatile Organic Compounds Routinely Analyzed by GC/EDC at
the CRF 	

Volatile Organic Constituent Concentrations for the BROS

Volatile Organic Constituent Concentrations for the BROS

Volatile Organic Constituent Concentrations for the BROS
Soil /Sludge Tests 	
Volatile Organic Constituent Concentrations for the BROS

Page
5
10
11
13
16
18
20
27
28

31
34

42

43

44

45

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                             TABLES (concluded)

Number                                                                   Page
  16   Volatile Organic Feed and Emission Rates   	     46
  17   Volatile Organic Feed and Emission Rates   	     47
  18   Volatile Organic Feed and Emission Rates   	     48
  19   Volatile Organic Feed and Emission Rates   	     49
  20   Particulate Emissions 	     50
  21   HC1  Emissions	     52
  22   Trace Element Emissions 	     53
  23   EP Leachate Concentrations  	     54
  24   Volatile Organic Constituent Spike Sample Recovery  	     58
  25   Volatile Organic Constituent Spike Recovery in VOST Samples . .     59
                                     vi

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                                 SECTION 1
                                INTRODUCTION

       One of the primary functions of the Combustion Research Facility  (CRF)
is to support Environmental Protection Agency (EPA)  Regional  Offices  1n  1
evaluations of the potential for'Incineration as a dfsposat option" for wastes
generated through remedial action taken at Superfund sites'.  One priority^
site in Region II 1s the Bridgeport Rental and Oil Services (BROS)  Superfund
site in Bridgeport, New Jersey.  This site has high priority  in the Region's
Remedial  Action Program (1).  Several hazardous wastes will be generated
through remedial  actions at this site.  Among these are PCB-contaminated
lagoon surface oil, lagoon sludge and.contaminated soil.. Region II requested
test burns of these wastes plus a mixture of the soil and sludge at the  CRF
to support evaluations of thermal  treatment options for decontamination  of
soil and  destruction of incinerable wastes.
     This report  presents results of a 5-week test bum program conducted  at
the CRF during July 21 to September 4, 1986.  The rotary kiln Incineration
system was used for these tests.  The primary objectives of the program  were
as follows:
     •   Detemlne 1f t«cn BROS-generated waste can be safely Incinerated  in
         compliance with the Toxic Substance Control Act (TSCA) regulations
         governing incineration of PCB-contaminated wastes.

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     •   Determine If residual  streams  generated  from the incineration
         process can be classified  as non-toxic,  arnLnoncontaminated
         facilitating final  disposal into £h«,land.  .
     •   Measure volatile products  of Incomplete  combustion and compare with
         those observed during  a TSCA trial  burn  also conducted at the CRF
The third objective calls for a comparison  of  organic emission measured
during this program with those  observed during a  TSCA trial burn in which
PCB-contaminated sorbent was incinerated in the rotary  kiln.  The results of
the TSCA trial burn are presented in greater detail  in  the trial burn report
submitted to the EPA for permit issuance (2).

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                                  SECTION 2
                     FACILITY DESCRIPTION AND OPERATION

     The test burn program was performed using the rotary kiln  incinerator
system at the CRF Iji ,Jefferson, Arkansas.  Figure 1 is a simplified  schematic
                               *  ****.
of the system.  Design and operating characteristics of the CRF kiln,
afterburner, and air pollution control  devices (APCDs) are presented in
Table 1.
2.1  FACILITY DESCRIPTION
     Figure 2 illustrates a three-dimensional layout of the primary  and
secondary thermal  chambers (kiln  and afterburner).  As noted, the kiln has
1.2m (4 ft) wide diameter and is  2.4m (8 ft)  long.  The rotational speed can
be set in the 0.1  to 0.5 rpm range.   Propane  is fired through one or two
530 kW (1.8 x 106  Btu/hr) capacity burners positioned for either cocurrent  or
countercurrent operation.  However,  the current kiln-to-afterburner  flue duct
arrangement limits operation to cocurrent firing of propane using the front
burner.  The kiln  has *«wx1 muni design  operating temperature of 900°C
                      j , ^   — -          -                              >
(1,650°F) with a corresponding minimum  residence time of 1.7 sec for a
nominal 10 percent exCels*tJ2~1n"the flue gas.
     The afterburner has a 0.9m (3 ft)  inner  diameter and is 3.1m (10 ft)
long.  This chamber can also be fired with propane at up to 530 kW (1.8  x
    Btu/hr) heat input.  Maximum design temperature for the afterburner  is

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      TABLE 1.  DESIGN CHARACTERISTICS OF THE CRF ROTARY KILN SYSTEM
Characteristics of the Kiln Main Chamber

  Length                 2.44m (8 ft)
  Diameter               1.22m [4 ft)
  Chamber volume         2.88 m3 (100 ft3)
  Rotation               Clockwise or counterclockwise 0.1 to 1.5 rpm
  Construction           0.63 cm (0.25 in.) thick cold rolled steel
  Refractory             12.7 cm (5 in.) thick high alumina castable
                         refractory, variable depth to produce
                         a frustroconical effect for moving inerts
  Solids retention time  1 hour (at 0.5 rpm)
  Burner                 Iron Fireman, Model C-120-G-SMG rated at 530 kW
                         (1.8 MMBtu/hr)
  Primary fuel           Propane
  Feed system            Liquids: Front face, water-cooled lance
                         with positive displacement pump
                         Semi liquids:  Front face, water-cooled lance
                         with Moyno pump
                         Solids: Metered twin auger screw feeder
  Temperature            900°C (1,650°F) maximum operating

Characteristics of the Afterburner Chamber

  Length                 3.05m (10 ft)
  Diameter               0.91m (3 ft)
  Chamber volume         2.096 m3 (74 ft3)
  Construction           0.63 cm (0.25 in.) thick cold rolled steel
  Refractory             15.24 cm (6 in.) thick high alumina castable
                         refractory
  Retention time         Depends on temperature and excess air
  Burner                 Iron Fireman, Model C-120-G-SMG rated at 530 kW
                         (1.8 MMBtu/hr)
  Primary fuel           Propane
  Temperature            1,200°C (2,200°F) maximum operating

Characteristics of the Air Pollution Control Systems

  System capacity        Inlet gas flow of 106.8 m3/min (3,773 acfm) at
                         1,200°C (2,200°F). at 101 kPa (14.7 psig)

  Pressure drop          Venturi 7.5 kPa (30 1n. WC)
                         Packed tower 1.0 kPa (4 in. WC)
  Liquid flow            VentuM 77.2L/min (20.4 gpm) at 69 kPa  (10 psig),
                         Packed tower 116L/min (30.6 gpm) at 69 kPa
                         (10 psig)
  pH control             Feedback control by NaOH solution addition

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Burner No. 2
    Burner No. 1
                                                          Waste feed
                                 Afterburner
                                 10'  x 3'  ID
                                                                          5
              Figure 2.   Rotary kiln and afterburner detail,

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 1.200*G (2,200*F>.  At a maximum heat input of about  1.1  MW  (3.6 x
 10^ Btu/hr) to both chambers the resulting bulk gas residence time in the
 afterburner is approximately 1.4 sec.  Figures 3 and  4  illustrate the
 approximate relationships between heat input,  gas temperature, and residence
 time for the two thermal  chambers.
     The kiln waste feed can accommodate liquids, slurries and sludges, bulk
 solids, and containerized solids.  Liquids and sludges  can be fed using a
 progressive cavity pump through a water-cooled lance.   Containerized solids
 are fed in 5.8L (1.5 gal) fiber packs using a  ram feeder.  For
 noncontainerized solids, a twin auger screw feeder can  also  be used.  During
these tests, the soil was containerized in fiber packs  and fed into the kiln
 using the ram feeder.  Nominal  retention time  of solids in the kiln is 1 hour
for a rotational  speed of 0.5 rpm.  Kiln ash is collected in the ash bin.
     The primary particulate and HC1  emission  control system reflects what
might be considered typical  equipment for a commercial  or Industrial
incinerator.  The venturi scrubber/quench is designed to  operate at 7.5 kPa
 (30 in. W.C.)  pressure drop.  From the venturi, combustion gases flow through
a wetted elbow to a packed tower scrubber.  Slowdown  from the scrubber system
can be directed to the National Center for Toxicological  Research (NCTR)
chemical  sewer if the blowdown  is determined to be nonhazardous.  If residual
streams are determined to be hazardous they can be stored in several tanks at
the site and ultimately disposed of in RCRA-approved  hazardous waste sites.
     In addltftitto the. wet control system, a  backup  dry  air pollution
control systJTift utilized to ensure that ultimate emissions to the
atmosphere will remain within applicable regulatory limits.  This dry control

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system consists of a carbon bed absorption  unit  for vapor phase orgarvfc*
compound renoval §nd a high efficiency  particulate (HEPA) filter-f^c-;final
particulate removal.
2.2  WASTE CHARACTERISTICS
     Four waste materials  from the  BROS site were tested in the rotary  kiln
system at the CRF.  These  waste materials consisted of  PCB-contaminated
(1) lagoon surface oil, (2) soils from  Area 1  of the  BROS site, (3)  lagoon
sludge, and (4) a mixture  of soil and lagoon sludge.  Tables  2 through  4
summarize data on the concentration of  several hazardous constituents and
other properties of the Area 1 soil, lagoon surface oil, and  lagoon  sludge
determined prior to this test program  (3).
     The soil can be characterized  as clumped  clay mud  containing rocks,
grass, roots, and twigs.  The data  in Table 2  show that the contaminated
soil contains an average of about 660 ppm PCBs based  on an average of
19 analyses.  The physical appearance of the lagoon surface oil reveals a

            TABLE 2.  SUMMARY ANALYSIS  DATA FOR  THE BROS SOILa
Parameter
Organic sulfur, percent
Sulfide, mg/kg
PCBs, mg/kg
PCB-1254|
PCB- 1248:1
PCB-12604
Range
0.16-1.65
<2-51
<16-1,010 *
<0.8-590 '

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    TABLE 3.  CHARACTERIZATION OF THE BROS LAGOON  SURFACE OIL3

Ignitability
Flashpoint (°F)
Oxidizer (mg/kg)
Organic sulfur
(percent)
Sulfide (Mg/kg)
Heating value (MJ/kg,
(Btu/lb))
Ash (percent)
Moisture (percent)
Specific gravity
Total PCBs (mg/kg)
PCB-1254
PCB-1248
PCB-1260
Volatile organic
priority pollutants
(mg/kg)C:
Toluene
Total xylenes
Ethyl benzene
Range

109-150
<25
0.08-0.80

19-82
8.8-35.5
(3,800-15,300)
0.18-2.1
17-48
0.86-0.95

120-310 /
100^150
140-280



<1-13
1.7-20
<1-5.0
Average*5

135
<25
0.33

44
23.2
(10,000)
0.87
38
0.91

240
115
200



7.5
9.7
2.7
Number of
Median analysis

135
<25
0.34

43
23.0
(9,900)
0.84
42
0.92

270
130
190



8.0
11
2.5

56
56
56

11
56

56
11
56

11
11
11



11
11
11
                                                          (continued)
Reference 3.
bLess than detection limit assumed to be 0 for averaging
 purposes.
cBenzene and t-1,2 dichloroethene were found  at quantifiable
 amounts 1n one sample each.   No other volatile organic priority
 pollutants were detected in  any sample at a  detection limit  of
 1 mg/kg.
"No other semi volatile organic priority pollutants  were detected
 in any sample at a detection limit of 10 mg/L.
eThe average for all samples  was less than the detection  limit of
 10 mg/L; therefore, the average was assumed  to be  the detection
 limit.
                                 11

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                       TABLE  3.   (concluded)
                            Range
Averageb  Median
Number of
analysis
Semivolatile organic
priority pollutants
(mg/L)d:
Acenaphthene
1,2,4-trichlorobenzene
Fluoranthene
Naphthalene
Bis(2-ehtylhexyl)
phthalate
Butyl benzyl phthalate
Di-n-butyl phthalate
Di-n-octyl phthalate
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Chrysene
Acenaphthylene
Anthracene
Fluorene
Phenanthrene
Pyrene
<10-21
<10-32
21-110
48-210
120-520

79-420
<10-49
13-96
<10-31
<10-15
<10-31
<10-80
<10-72
<10-32
<10-88
110-460
26- 92
10e
106
54
110
330

240
19
55
10d
10d
14
33
33
13
42
250
50
10
<10
53
97
370

220
24
52
<10
<10
15
42
27
15
39
240
49
11
11
11
11
11

11
11
11
11
11
11
11
11
11
11
11
11
Reference 3.
bLess than detection limit assumed to be 0 for averaging
 purposes.
cBenzene and t-1,2 dichloroethene were found at quantifiable
 amounts in one sample each.   No other volatile organic priority
 pollutants were detected in  any sample at a detection  limit  of
 1 mg/kg.
dNo other semi volatile organic priority pollutants  were detected
 in any sample at a detection limit of 10 mg/L.
eThe average for all samples  was less than the detection  limit  of
 10 mg/L; therefore, the average was assumed to be  the  detection
 limit.
                                 12

-------
      TABLE 4.  CHARACTERIZATION OF THE BROS LAGOON SLUDGE3
                     Parameter
Value
Heating value, MJ/kg (Btu/lb)                          16.7  (7200)

Ash content, percent                                   2

Moisture content, percent                              13

Specific Gravity                                       1.31

PCB content, mg/kg dryb
  PCB-1248                                             140
  PCB-1260                                             72

Volatile organic priority pollutantsc, mg/kg dry
  1,1,1-trichloroethane                                0.23
  t-l,2-dicloroethy1ene                                0.11
  Ethylbenzene                                         0.74
  Toluene                                              1.7

Other volatile organicsd, mg/kg
  Acetone                                              0.75
  2-butanone                                           1.2
  4-methyl-2-pentanone                                 0.11
  Total xylenes                                        2.7

                                                       (continuedT
Reference 3.
bPCBs-1242, 1254, 1221, 1232 and 1016 were also analyzed for and
 not found at a detection limit of 9 mg/kg dry.
CA11 other volatile organic priority pollutants not detected at a
 detection limit of 0.1 mg/kg dry.
dCarbon disulfide, vinyl acetate, 2-hexanone, and styrene were
 also analyzed for and not found at a detection limit of 0.1 mg/kg
 dry.
eAll other semi volatile organic priority pollutants not detected
 at a detection limit of 20 mg/kg dry.
^Benzyl alcohol, 2-methyl phenol, 4-methyl phenol, benzoic acid,
 4-chloroaniline, 2,4,5-trichlorophenol, 2-nitroaniline,
 3-nitroaniline, 2-dibenzofuran, and 4-nitroaniline were also
 analyzed for and not found at a detection limit of 40 mg/kg dry.
                                13

-------
                      TABLE 4.   (concluded)
                     Parameter
   Value
Semivolatile organic priority pollutants6, mg/kg dry
  Fluoranthene
  Naphthalene
  Bis (2-ethylhexyl)phthalate
  Butyl  benzyl phthalate
  Chrysene
  Acenaphthylene
  Fluorene
  Phenanthrene
  Pyrene
Other semivolatile organics^,  mg/kg dry
  2-Methyl naphthalene

EP toxicity leachate concentration, mg/L
  Arsenic
  Barium
  Calcium
  Chromium
  Lead
  Mercury
  Selenium
  Silver
  Endrin
  Lindane
  Methoxychlor
  Toxaphene
  2,4-D
  Si 1 vex
33
180
130
130
21
21
37
170
52
240
<0.5
<5.0
<0.1
<0.5
2.86
<0.02
<0.5
<0.5
<0.0001
<0.00005
<0.0005
<0.0025
<0.005
<0.0005
aReference 2.
bPCBs-1242, 1254, 1221, 1232 and 1016 were also analyzed for and
 not found at a detection limit of 9 mg/kg dry.
CA11 other volatile organic priority pollutants not detected at a
 detection limit of 0.1 mg/kg dry.
dCarbon disulfide, vinyl acetate, 2-hexanone, and styrene were
 also analyzed for and not found at a detection limit of 0.1 mg/kg
 dry.
eAll other semivolatile organic priority pollutants not detected
 at a detection limit of 20 mg/kg dry.
^Benzyl alcohol, 2-methyl phenol, 4-methyl phenol, benzoic acid,
 4-chloroaniline, 2,4,5-trichlorophenol, 2-nitroaniline,
 3-nitroaniline, 2-dibenzofuran, and 4-nitroaniline were also
 analyzed for and not found at a detection limit of 40 mg/kg dry.
                                14

-------
 dark  brown syrup substance containing some debris.  Data in Table 3 for
 flash point, oxidizer, organic sulfur, heating value, ash content, and
 specific gravity of lagoon surface oil are based on 56 analyses of
 54 composite samples.  Data for moisture content and organic priority
 pollutant content are based on 11 analyses of 10 oil composites.  These data
 show that surface oil contains an average of about 550 ppm total PCBs.  In
 addition, several semivolatile organic compounds are also present at average
 concentrations exceeding 100 ppm.  These are naphthalene (120 ppm by weight
 in the oil), phenanthrene (270 ppm) and two phthalates, bis(2-ethylhexyl)
 phthalate (360 ppm) and butyl  benzyl phthalate (260 ppm).  Proximate analysis
 of the oil  reveals 38 percent  water content, 0.87 percent ash, 0.92 specific
 gravity and a gross heating value of 23 MJ/kg (10,000 Btu/lb).
     The lagoon sludge appears as a black gel in much water.  The sludge
 contains several  kinds of debris including grass, roots, and twigs.  The data
 in Table 2-4 show that the BROS lagoon sludge contains an average of 210 ppm
 PCBs and other semivolatile organics also found in the lagoon surface oil.
 In addition, the metal and pesticides concentrations in an EP toxicity
 leachate of the lagoon sludge  fall below values which would cause the sludge
 to be considered characeristic EP toxic.  The heating value of the sludge has
 been reported at 16.7 MJ/kg (7200 Btu/lb) with 13 percent moisture, 2 percent
 ash, and a  specific gravity of 1.3.
     Waste  analyses were performed on each of the waste materials tested at
the CRF.  Table 5 summarizes the result of these analyses.  Waste heating
values ranged from zero for the soil to 10.1 MJ/kg (4,350 Btu/lb) for the
 lagoon sludge which contained  significant quantities of water.  The average
total  PCBs  for the soil and lagoon surface oil were measured at only 110 and
                                     15

-------
TABLE 5.  BROS WASTE CHARACTERIZATION —  COMPOSITION
Ultimate
analysis
(t by weight as fed)
C
H
0
N
S
Cl
Total
High heating Value
MJ/Kg (Btu/lb)
Total PCBs
(mg/kg as Arochlor
1254)
Metals (mg/kg):
Arsenic, As
Barium, Ba
Cadmium, Cd
Chromium, Cr
Lead, Pb
Mercury, Hg
Selenium, Se
Silver, Ag
EP toxlclty leachate
Arsenic, As
Barium, Ba
Cadmium, Cd
Chromium, Cr
Lead. Pb
Mercury, Hg
Selenium, Se
Silver. Ag
Area 1
soil
11.4
4.6
25.0
0.1
0.4
0.44
41.94

0
67.3-167



<1
744
<1
55
756
<1
<1
<5
(mg/L):
<0.1
0.12
<0.1
<0.1
0.46
<0.1
<0.1
<0.1
Lagoon
surface
• oil
54.4
10.9
29.9
0.1
0.7
0.1
96.1
8.62
(3,716)
270-300
(286)b


2
1,035
<10
46
2,888
<1
<1
<10

<0.1
<0.1

-------
 286  ppm by weight, respectively, compared to concentrations of about 660 and
 550  ppm from the preliminary analyses (see Table 2).  The PCB concentration
 for  the sludge was comparable to that from the preliminary analysis.  The
 mixture of soil and sludge resulted in a total PCB concentration of 123 ppm
 from an average of three analyses on one composite sample.  Barium, chromium,
 and  lead were the principal metals detected in these wastes.  Highest
 concentrations of these elements were measured primarily in the lagoon
 surface oil.
 2.3  FACILITY OPERATION
     Tables 6 and 7 summarize the operation of the rotary kiln incinerator
 and  air pollution control systems.  A total of 12 tests were performed (three
 tests for each of the four waste feeds).
     For the first series of three tests, the lagoon surface oil was fed into
 the  kiln using the progressive cavity pump at an average rate of 18 to
 24 kg/hr (39 to 53 Ib/hr).  Average kiln and afterburner temperatures were
 varied from about 680 to 890°C (1,250° to 1,640°F), respectively, to
 determine the impact of thermal environments on PCB ORE.  Excess Og, measured
 at the afterburner exit, was maintained relatively constant between 5.6 and
 6.5  percent.  Following completion of the surface oil tests, three tests were
 conducted with the contaminated soil which was fed into the kiln in 5.7L
 (1.5 gal) fiberpacks using the ram feeder.  The average feedrate of the soil
during each test was maintained relatively constant for the test series at
 about 45 kg/hr (100 Ib/hr).  Lowest kiln temperature, about 700°C (1,290°F)
was  investigated during the second soil test.  Afterburner temperature was
maintained relatively constant at about 1,130°C (2,060°F) for each test.
Average excess 03 at the afterburner exit was varied from 6.7 to 8 percent.

                                     17

-------












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-------
TABLE 7.  AIR  POLLUTION CONTROL  SYSTEM OPERATING  CONDITIONS
Test
d*te
7-21-86



7-28-86



7-29-86



8-4-86



8-5-86



8-7-86



8-12-86



8-13-86



Test
duration
11:00 -
17:20


10:15 -
16:15


10:00 -
19: IS


12:10 -
17:16


10:30 -
15:20


9:45 -
14:00


9:38 -
14:39


9:40 -
14:41


Test
material
BROS
surface
oil

BROS
surface
oil

BROS
surface
oil

BROS
soil


BROS
soil


BROS
soil


BROS
soil +
sludge

BROS
soil »
sludge

Venturl
scrubber
1 1 quor
rate
L/*1n
(9P«)
68
68-68
(18)
(18-18)
68
68-68
(18)
(18-18)
68
68-68
(18)
(18-18)
64
64-64
(17)
(17-17)
64
64-64
(17)
(17-17)
64
64-64
(17)
(17-17)
64
64-64
(17)
(17-17)
64
64-64
(17)
(17-17)
Venturl
scrubber
gas
AP
kPa
C«e)
6.8
4.5- 10.0
(27.3)
(18.0-40.0)
5.4-
5.5-4.5
(21.6)
(22.0-18.0)
5.8
5.0-8.7
(23.3)
(20.0-35.0)
2.7
2.7-2.7
(11.0)
(11.0-11.0)
2.1
2.0-2.2
(8.4)
(8.0-9.0)
4.7
5.7-3.5
(18.9)
(23.0-14.0)
9.0
7.0-9.7
(36.1)
(28.0-39.0)
8.8
9.7-7.7
(35.2)
(39.0-31.0)
Packed
column
liquor
rate
L/Kin
(9P«>
114
114-114
(30)
(30-30)
114
114-114
(30)
(30-30)
114
114-114
(30)
(30-30)
114
114-114
(30)
(30-30)
114
110-114
(30)
29-30
106
106-106
(28)
(28-28)
110
110-110
(29)

114
114-114
(30)
(30-30)
Scrubber
liquor
PH

8.2
2.5-8.2


8.1
8.0-8.2


8.2
8.2-8.2


8.2
8.2-8.2


8.2
8.2-8.2


7.2
6.0-7.8


7.3
7.0-7.5


7.0
6.2-8.0

Scrubbing
liquor
temperature
•c
cn
73
71-75
(164)
(159-167)
73
71-74
(163)
(160-166)
74
72-75
(165)
(161-167)
75
74-77
(167)
(165-170)
76
74-77
(168)
(166-170)
74
71-76
(165)
(159-168)
73
72-74
(163)
(162-165)
73
70-74
(164)
(158-166)
Makeup
•ater
rate
L/nln
(gp">
22.6
13.2-28.0
(6.0)
(3.5-7.4)
26.3
19.9-34.9
(6.9)
(5.2-9.2)
21.9
16.0-28.0
(S.8)
(4.2-7.4)
20.6
9.8-29.9
(5.5)
(2.6-7.9)
20.9
12.5-30.7
(5.5)
3.3-8.1
21.5
6.8-30.8
(5.7)
(1.8-8.1)
20.6
7.9-28.6
(5.5)
(2.1-7.5)
20.5
6.5-29.0
(5.4)
(1.7-7.7)
Slowdown
•ater
rate
L/«in
(9P«)
9.5
9.1-11.7
(2.5)
(2.4-3.1)
12.1
12.1-12.1
(3.2)
(3.2-3.2)
12.5
11.7-15.1
(3.3)
(3.1-4.0)
13.2
13.2-13.2
(3.5)
(3.5-3.5)
13.6
13.6-13.6
(3.6)
(3.3-3.6)
12.5
12.5-12.5
(3.3)
(3.3-3.3)
12.5
12.5-12.5
(3.3)
(3.3-3.3)
12.5
12.5-12.5
(3.3)
(3.3-3.3)
                                                             (continued)
                               20

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Kiln rotational speed of 0.19 rpm corresponds  to  about 2.5 hr solid retention
t i me.
     The mixture of soil and lagoon sludge  was also  fed  into the kiln with
fiberpacks at an average feedrate of about  42  kg/hr  (93  Ib/hr).  Two kiln
rotational speeds were investigated, namely 0.19  rpm for the first two tests
and 0.36 rpm for the third test;  the latter corresponding to about 1.4 hr
solid retention time.  The lowest kiln  temperature investigated during these
tests was 718°C (1,320°F).  Kiln  design temperature  of about 895°C (1,650°F)
was utilized during the other two tests. The  afterburner temperature was
maintained constant throughout this series  of  tests  at 1,120°C  (2,050°F).
Afterburner exit 03 ranged from 6.8 to  8.5  percent on the average for each
test.
     Sludge only tests were performed with  two temperature settings  for  each
of the kiln and afterburner chambers.  The  lowest temperature combination of
656°C (1,210°F) for the kiln and  1,116°C (2,040°F) for the afterburner was
investigated during the first test.  Higher kiln  and afterburner
temperatures to about 880°C (1,620°F) and 1,210°C (2,210°F)  for the  kiln and
afterburner, respectively, were alternatively  tested during  the remaining two
tests.  Lowest temperature settings were tested with the highest  excess  02
(10 percent) at the afterburner exit.  The  average excess 02 for  the other
tests was held constant at 6.2 percent.  The sludge  was  pumped  to the kiln
which rotated at 0.36 rpm.
     Table 7 summarizes the operational settings  of  the  major components of
the wet air pollution control system.  For  the most  part the scrubbing  liquor
flowrate, pressure drops, and pH  levels were held relatively constant
throughout the test program with  the exception of the venturi scrubber

                                     22

-------
pressure drop which showed a range of average settings  between  2.1  kPa
(8.4 in. W.C.) during tests with contaminated soil  and  9.7  kPa  (39  in.  W.C.)
during tests with lagoon sludge.
                                     23

-------
                                  SECTION 3
                       SAMPLING AND ANALYSIS PROTOCOLS

     In order to achieve the objectives of the test burn, an extensive
sampling and analysis (S&A) program was executed.  This section summarizes
the SAA protocols and methods used.  More detail on actual equipment  and
procedures can be found in Appendices A and B of this report.
3.1  SAMPLING LOCATION AND METHODS
     Figure 5 illustrates the sample locations and test methods.   Waste,
propane, and combustion air feedrates to the kiln were monitored  using
process monitoring equipment available at the facility.  Waste  feedrate  was
monitored by recording the cumulative weight of waste feed to the kiln  over
the duration of each test.  The rate of feed was then obtained  by the slope
of the cumulative weight versus time graphs presented in Appendix C.
     Incineration residuals were accounted for in the protocol  by taking
samples of the kiln ash from the ash bin following the conclusion of  each
test.  When solid waste feeds (soil and soil plus lagoon sludge)  were
incinerated, multiple kiln ash samples were taken for analysis  of organics
and metals.  Composite scrubber blowdown samples were also collected
throughout the duration of each test.
     Continuously monitored (CM) gaseous emissions were  limited to
measurements for 03 and C02 concentrations at four locations  in the
incinerator system namely at the exits of the kiln,  afterburner,  wet  APCD

                                     24

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system and the stack.  Details of the  03  and  C0£ traces at each of these
locations are shown in Appendix D.  Measurements for participate, PCBs, and
semi volatile organics in the gas stream were  made using the modified EPA
Method 5 (MM5) at the packed tower scrubber outlet  (downstream of the wet
particulate and acid gas control system).  Measurements for volatile products
of incomplete combustion (PICs) were performed  at the afterburner and packed
tower scrubber exit locations using the standard EPA Volatile Organic
Sampling Train (VOST).  Particulate and HC1 emissions measurements were also
made at the stack to measure compliance with  the operating permit at the
CRF.
3.2  ANALYSIS PROTOCOLS
     Table 8 summarizes the total number  of samples collected and analyses
performed on each sample.  The analytical  protocols are summarized in
Table 9.  The laboratory analyses procedures  included:
     •   Analyzing all waste feed samples, the  composite  kiln ash samples,
         all blowdown water samples, and  all  MM5 train  samples  for PCBs.
     •   Analyzing one composite waste feed sample, the composite kiln  ash
         sample, all scrubber blowdown samples  taken upstream of the  carbon
         bed, and all MM5 train samples  for the semi volatile organic
         priority pollutants.
     •   Analyzing one composite waste feed sample, the composite kiln  ash
         sample, and all scrubber blowdown samples  taken  upstream of  the
         carbon bed for 21 volatile organic compounds  visible to the  Electron
         Capture Detector (ECD) and routinely determined  at the CRF  (see
         Table 10.
                                     26

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              TABLE  10.   VOLATILE  ORGANIC  COMPOUNDS  ROUTINELY
                          ANALYZED  BY  GC/EDC AT  THE CRF
               Methylene  chloride        Trichloroethylene
               1,1-dichloroethylene      Benzene
               1,1-dichloroethane        1,1,2-trichloroethane
               t-l,2-dichloroethylene    Hexane
               Chloroform               Bromoform
               1,2-dichloroethane        Tetrachloroethylene
                                         plus Tetrachloroethane
               1,1,1-trichloroethane     Isooctane
               Carbon tetrachloride      Toluene +  Heptane
               Bromochloromethane        Chlorobenzene
               1,2-dichloropropane       Octane
               t-l,3-dichloropropylene
     •   Analyzing one composite sludge  sample, the  composite  kiln  ash
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         water treatment carbon bed for  the 8  EP toxicity trace  metals.
     •   Subjecting one composite sample of each waste  feed  and  a composite
         kiln ash sample to EP toxicity  extraction  (Method 1310,
         Reference 4) and trace element  analysis
     •   Subjecting one composite waste  feed sample  to  ultimate  analysis
     •   Analyzing all VOST samples for  the 21 volatile organic
         compounds visible to the ECD and routinely  determined at the
         CRF (see Table 10)
       Ultimate analyses (C, H, 0, N, S, and Cl) were  in  accordance with
approved ASTM methods as documented in Reference 5.  Waste feed  and kiln  ash
were sonicatlon extracted in accordance  with Method  3550.  Scrubber blowdown
were extracted in accordance with Method 3510.  All  resultant  extracts  were
be concentrated and analyzed for PCBs via direct injection GC/ECD  by
Method 8080, and for the semi volatile organic  priority  pollutants  by
                                      31

-------
Method 8270 except those for scrubber blowdown  taken downstream of the carbon
bed which were only analyzed for PCBs.
       One composite waste feed sample,  the composite  kiln ash sample, and
all scrubber blowdown samples taken  upstream of the carbon bed were analyzed
for the volatile chlorinated organics by purge  and trap  6C/ECD in accordance
with Method 8010.
       Trace element analyses were performed by atomic absorption in
accordance with the 7000 series methods.  Appropriate  acid digestion  of  solid
samples were performed as needed by  Method 3010. EP toxidty extraction and
extract analyses were performed for  one  composite surface oil and lagoon
sludge and for individual test samples of soil  and soil  plus sludge.   (See
Table 5). Composite kiln ash samples were also  subjected to  EP toxicity
analyses.
       MM5 train samples (filter catch,  sorbent resin, condensate,  and
impinger solutions) were Soxhlet extracted in accordance with Method  3540.
Resulting extracts were analyzed for PCBs via direct  Injection GC/ECD by
Method 8080 and for the semi volatile organic priority  pollutants  by
Method 8270.  VOST traps were analyzed for halogenated volatile  organics by
thermal desorption, purge and trap (Method 5030) GC/ECD  in accordance with
Method 8010.
                                     32

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                                  SECTION 4
                                TEST RESULTS

     This section summarizes emission results and PCB destruction efficiency.
Details on sampling and analytical reports can be found in Appendices D
and E, respectively.
4.1  PCB DESTRUCTION
     Table 11 summarizes PCB emissions  (as Arochlor  1254) and  DE  for  each  of
the 12 tests performed.  On the average PCB emissions were highest  for the
lagoon surface oil and lowest for the soil and sludge waste  streams when
incinerated individually rather than in combination.  DE  calculations
indicate that a PCB destruction in the  99.992 to 99.9998  was achieved during
these tests as measured in the scrubber system discharge  flue  gas.  Thus
destruction performance measured at this  location failed  to  meet  the
requirements under TSCA regulations for 99.9999 percent efficiency.   As
reflected by the  relative emission rate for each waste  feedstock,  the lowest
DE values were recorded for the lagoon  surface oil  (mass  weighted average  for
the three tests at 99.9944 percent) and highest for  the sludge (mass  weighted
average for the three tests at 99.9992  percent).  Figure  6  Illustrates  the
relative levels of DEs achieved.  In this figure the ordinate  (or y-axis)
represents the number of nines 1n destruction efficiency, thus a value  of
four signifies 99.99 percent DE.
                                      33

-------
                                PCB DE SUMMARY
99.9999
             Test 1
LACOON on.  1771
                           son.
Test  2
17771  SOL+SUJDGE
                             Figure 6.  PCB DEs.
                                     35

-------
     Figures 7 through 9 illustrate attempts at correlating key process
parameters (excess Q£ at the afterburner exit, gas flowrate, and mean
temperature) with DE.  In general, no definitive trends are evident from
these graphs.  Gas flowrate shows the greatest effect on DE with decreasing
PCB destruction as gas flowrate is increased.  Gas flowrate was increased
during tests tests primarily by increasing the amount of excess air as
evidenced by increased 63 concentrations at the afterburner exit.  Some of
this excess air was the result of air infiltration through the kiln seals
thus directly affecting the gas residence time in the afterburner  chamber.
Also note that the highest DE volume was recorded when the average oxygen
concentration at the afterburner exit was 10 percent, the highest  setting
during these tests.  This data point would suggest that very high  excess  air
levels are also conducive to high levels of PCB destruction.
     When the mean gas temperature; defined as the arithmetic  average  of  the
kiln and after burner temperatures, is normalized by the actual gas flow  rate
(essentially inverse residence time) a more visible trend is observed  as
shown in Figure 10.  If the high DE at high excess 02 data point  is
disregarded, extrapolation of these data would suggest that at  a  mean
temperature of 960°C (1,760°F) a gas flowrate of 1.18 m3/sec would be
required for 99.9999  percent ORE.  This gas flowrate corresponds  to  gas
residence time in the afterburner of about 2.0 sec at a temperature of
1,200°C (2,200°F).  This is about twice the actual residence time achieved
during these tests.
     Scrubber blowdown and kiln ash were also analyzed for PCB content.
Concentrations in the blowdown were below detection  (<1 ug/L)  for each test
sample.  In the kiln ash the concentration was also  below detection

                                     36

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                       37

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                                   38

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                             39

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                                    40

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 (<0.4 ng/g) for all samples except for the composite ash from the surface oil
 test which revealed a concentration of 2.55 ug/g.
 4.2  VOLATILE ORGANIC EMISSIONS
     Tables 12 through 15 summarize the measured concentrations of volatile
 organics in the kiln feed material and in each of the three discharge
 streams, namely the kiln ash, scrubber blowdown, and flue gas.  Most of the
 volatile organics were detected in the lagoon surface oil in concentration
 ranging from about 3 to 68 ppm by weight.  The kiln ash and scrubber blowdown
 streams were found to be mostly devoid of volatile organics with the
 exception of methylene chloride in the scrubber blowdown.  Flue gas
 concentrations of individual compounds ranged from as low as 0.5 ug/dscm to
 1,730 ug/dscm.  Highest concentrations were generally reported for methylene
 chloride.
     Tables 16 through 19 list corresponding mass flowrates in ug/sec for the
 volatile organic compounds.  Typically, emission rates of benzene, methylene
 chloride, bromoform, and tetrachloroethylene were higher than those
 accountable by the waste being incinerated.  Except for bromoform, these are
 common PICs.   Highest total emissions were recorded for the surface oil test
 due primarily to highest average emissions for benzene and methylene
 chloride.
 4.3  PARTICIPATE AND HC1  EMISSIONS
     Table 20 summarizes particulate matter concentration at each flue gas
 location tested.  Not surprisingly, the highest emissions were measured
during soil and soil plus sludge tests.  However, scrubber discharge
concentrations were well  below the hazardous waste Incinerator regulatory
limit of 180  mg/dscm for all tests.

                                     41

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                                                              48

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          TABLE 19.  VOLATILE ORGANIC FEED AND EMISSION RATES (SLUDGE)
                                     Average emission rate (yg/sec)


Compound
Waste feed
into kiln
(ug/sec)

Test 1 Test 2
8-28 9-3

Test 3
9-4

Average all
tests
Methylene chloride           NO
1,1-dichloroethylene         NO
1,1-dichloroethane           NO
t-l,2-dichloroethylene       NO
Chloroform                   NO
1,2-dichloroethane          140
1,1,1-trichloroethane        NO
Carbon tetrachloride        630
Bromodichloromethane         NO
1,2-dichloropropane         250
t-l,3-dichloropropylene      NO
Trichloroethylene           120
Benzene                      21
1,1,2-trichloroethane        NO
Hexane                       60
Bromoform                    NO
Tetrachloroethylene +       160
  tetrachloroethane
Toluene                      47
4.9
 ND
 NO
 ND
2.6
 ND
 ND
2.3
 ND
0.63
 ND
1.6
3.8
 ND
4.2
 ND
3.9

2.3
  13
   ND
   2.0
   ND
   4.2
   ND
   ND
   ND
   ND
0.32-0.41
   ND
   0.95
   3.0
   ND
   1.0
   ND
   ND

   1.3
9.0
ND
1.0
ND
3.4
ND
ND
1.2
ND
0.50
ND
1.3
3.4
ND
2.6
ND
2.0

1.8
                                       49

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                  TABLE 20.   PARTICIPATE EMISSIONS
       Test
                      Afterburner
                    exit paniculate
                       (mg/dscm)
                    Scrubber discharge
                        paniculate
                         (mg/dscm)
                                                                   Stack
                                                                paniculate
                                                                 (mg/dscm)
          Corrected            Corrected           Corrected
Measured  to  71 02   Measured  to 71 02a  Measured  to 71 02
Lagoon surface oil

  Test 1              19.7       17.9       0.5        0.5
  Test 2               8.9        8.3       <0.3       <0.3
  Test 3              13.6       13.1       <0.2       <0.2

Soil

  Test 1             259        279        11.9       12.8
  Test 2              47.6       48.3       16.7       16.9
  Test 3              52.2       51.1       9.9        9.7
                                           15.7
                                           11.5
                                           21.3
                                                                        18.5
                                                                        13.7
                                                                        26.1
  Test 1             24.8       31.9       6.2        8.0      12.2      12.7
  Test 2             33.0       31.2       7.4        7.0       9.7      12.5
  Test 3             19.3       18.3       6.0        4.7      38.1      45.7

Soil plus sludge
Test 1
Test 2
Test 3
14.1
216C
98.4
15.8
224
97.0
8.3
9.3
126
9.3
9.6
124
30.0
134
146
39.6
166C
182C
•02 not measured  In the scrubber discharge;  correction assumes scrubber discharge
 02 1s the same as afterburner exit 02.
bNot measured for these tests.
cData suspect due to unusually high proportion of  paniculate catch 1n the probe
 rinse.
                                      50

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     HC1 emissions, summarized in Table 21, indicate afterburner  exit
 concentrations in the range of about 5 to 31 mg/dscm for all  tests.  The
 corresponding mass emission rates at this location  of 0.007 to  0.0034  kg/hr
 (0.015 to 0.075 Ib/hr) are also well below the hazardous waste  incinerator
 regulatory limit of 1.8 kg/hr (4.0 Ib/hr).  Stack emission  rates  measured
 downstream of the scrubber were all  below detection limits.
 4.4  TRACE ELEMENT EMISSIONS
     Waste feed and discharge streams from the incinerator were analyzed for
 arsenic, barium, cadmium, chromium,  lead, mercury,  selenium,  and  silver.
 Metals analyses of leachates were also performed to determine whether  these
 would be considered EP toxic hazardous wastes.  Only barium,  chromium,  and
 lead were consistently found in each of the samples analyzed.  Trace amounts
 of arsenic and cadmium were detected in selected samples.
     Table 22 summarizes the concentrations of most common  trace  elements.
 Lead showed the highest concentrations in the waste feeds with  nearly
 3,000 ppm detected in the lagoon surface oil.  The higher concentration of
 lead in the scrubber blowdown solids compared with the kiln ash,  during the
 soil and soil plus sludge tests, clearly shows that lead partitions to the
 flue gas particulate rather than in  the kiln ash and 1s eventually caught  in
the scrubber.  Both chromium and barium showed nearly equal concentrations  in
the two discharge streams.
     Table 23 summarizes barium, chromium, and lead concentrations in
each of the leachate samples.  A11 measured levels were less  than 1 mg/L,
well below the respective EP toxlclty limits.
                                     51

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                       TABLE 21.  HC1 EMISSIONS
       Test
                    Afterburner exit HC1
                                                Stack HC1
                              ppm                    ppm
                    mg/dscm   dry  Kg/hra  mg/dscm   dry  kg/hr
                                                                  Feed Cl
                                                                  content
Lagoon surface oil

  Test 1              9.6     6.3   0.015
  Test 2             12.6     8.3   0.024
  Test 3             17.3    11.4   0.020

Soil

  Test 1             30.9    20.4   0.016
  Test 2             16.8    11.1   0.016
  Test 3             17.8    11.6   0.024

Sludge

  Test 1             <4.9    <3.2  <0.007
  Test 2              7.2     4.8   0.011
  Test 3              5.7     3.8   0.009

Soil plus sludge
<9.6   <6.4  <0.010
<8.1   <5.3  <0.007
<8.1   <5.3  <0.009
<9.8   <6.5  <0.013
<9.7   <6.4  <0.012
<8.3   <5.4  <0.013
                                                                   0.10
                                                                   0.04
                                                                   0.009
Test
Test
Test
1
2
3
17
23
20
.8
.2
.8
11.7
15.3
13.7
0
0
0
.026
.034
.026
<9.3
<9.5
<10.1
<6.1
<6.3
<6.7
<0
<0
<0
.010
.012
.011
0.06


aFlue gas flowrate not measured at afterburner exit; scrubber discharge
 flowrate assumed for mass flow calculation.
bMethod 5 train not run at the stack for this test.
                                   52

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             TABLE 22.  TRACE ELEMENT EMISSIONS
       Test/sample
                                     Concentration (ppm)a
Arsenic    Barium  Chromium    Lead
Lagoon surface oil
Composite feed
Composite kiln ash
Soil
Composite feed
Average kiln ash0
Average blowdown solids0
Sludge
Composite feed
Composite kiln ash
Soil plus sludge
Composite feed
Average kiln ash°
Average blowdown solids0

2
<2

<1
<2
<60

<1
<2

11
<2
24

1,040
120

740
550
980

23
680

820
740
820

46
1,090

55
130
100

12
110

65
87
73

2,890
2,160

760
910
2,400

46
800

1,030
450
5,010
aNo mercury, selenium, nor silver was found in any sample;  no
 cadmium was found in any sample except the composite soil
 plus sludge at 4 ppm and the blowdown solids from soil  plus
 sludge, Test 3, at 49 ppm.
°Average over three tests.
cAverage over Tests 2 and 3; Test 1 blowdown contained no solids,
                              53

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          TABLE 23.  EP LEACHATE CONCENTRATIONS
                            Leachate concentration
                                   (mg/l)a
        Test/sample            Barium  Chromium     Lead
EP Toxicity Limit              100       5.0         5.0
Lagoon surface oil
Composite feed
Composite kiln ash
Average blowdown liquidb
Ml
Composite feed
Average kiln ashb
Average blowdown liquidb
0.33 <0.1
0.54 0.16

0.12 <0.1
0.45 <0.1
0.33 0.29
0*.23
0.70

0.46
1.3
Sludge

  Composite feed                <0.1    <0.1        <0.1
  Composite kiln ash            <0.1     0.17       <0.1
  Average blowdown liquidb       0.41    0.17        0.1

Soil plus sludge

  Composite feed                 0.30   <0.1        0.12
  Average kiln ashb              0.32   <0.1        <0.1
  Average blowdown liquidb       0.37    0.31        0.12
aNo arsenic, cadmium, mercury, selenium, nor silver was
 found in any leachate.
^Average over three tests.
                           54

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                                 SECTION 5
                    QUALITY ASSURANCE AND QUALITY CONTROL

     The quality assurance and quality control efforts performed during  these
tests aimed at demonstrating that the rotary kiln incinerator system could
achieve a destruction efficiency of at least 99.9999 percent for
polychlorinated biphenyls (PCBs).
     The parameters germane to DE determination were the amounts of PCB
entering (Q-jn) and leaving (Q0ut) tne incinerator system.  Hence the QA/QC
effort focused on the measurements of the parameters that affect the incoming
and outgoing POHC.  These QC activities will be discussed below.
5.1  MEASUREMENT OF QIN
     The feed rate of Arochlor 1254 depended on the feed rate of the waste
material and the concentration of Arochlor 1254 in the individual waste.
     The lagoon surface oil  and the sludge were contained in a stirred tank
which sat on the platform of a weigh scale.  The weigh scale had been
calibrated with known weights.  The tank was connected to the pump by
flexible hoses.  The readout of the weigh scale was located in the control
room.  At nominal !5-tn1nute intervals, the weight registered on the weigh
scale and the corresponding clock time were recorded.  The weigh scale was
accurate to 0.5 Ibs.  The time was recorded to within 15 seconds.  Hence the
feed rate of this waste material was determined by dividing the weight loss
                                     55

-------
by the elapsed time between weight readings  and  is a highly reliable
measurement.
     The PCB-contaminated soil  and the mixture of soil plus lagoon sludge was
contained in preweighed 5.7L (1.5 gal) fiberpacks.  The  rate of feed was
determined by the cummulative weight  or  number of fiberpacks fed into the
kiln using the ram feed system over the  duration of each test.
     The concentrations of the PCB in the waste  was determined by standard
EPA methods as discussed in Section 3 and Appendix B and were found to be
100 to 250 ppm by weight for the four waste  materials  used.  Again, the
accuracy of these analyses is commensurate with  the method capability.
5.2  MEASUREMENT OF QQUT
     The amount of PCB leaving the incinerator was dependent on the flue gas
flow rate and the the PCB concentration  in the flue gas.
     Stack velocity measurement with  a calibrated pitot  probe during Method 5
sampling activities provided the data to calculate flue  gas flow rate.
Strict adherence to the specified procedure  ensured that the data quality
would conform to the method specifications.
     Concentrations of the POHC in the various sampling  locations were
determined by following standard accepted methodologies  as described earlier.
For this test series, the analytical  system, namely the  6C/ECD, was
calibrated with a blank at the beginning of  each test  day.  After every  four
injections, a calibration standard sample was injected to  verify that  the
system was functioning and responding properly.
     An additional procedure was followed in an  attempt  to detect and  prevent
cross-contamination of samples taken  from the same  location on  successive
days.  Following the probe sample recovery procedure,  the  probe was  rinsed

                                     56

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 with a solvent which was then collected and subjected to analysis to verify
 absence of contaminants.
 5.3  VOLATILE ORGANIC SPIKE RECOVERIES
     Spike and recovery studies for volatile organics were performed on feed
 materials, kiln ash, and scrubber blowdown.  Internal standards of octane and
 isooctane were also included in these analyses.  Results of these studies are
 presented in Table 24.  Internal standard recoveries were in the range of 89
 to 107 percent for all spiked samples.  With the exception of
 1,2-dichloroethane, carbon tetrachloride and bromoform, which had recoveries
 of approximately 145 percent, all recoveries from the spiked feed material
were between 93 and 108 percent.  Kiln ash spike recoveries were in the 89 to
 112 percent range, with the exception of carbon tetrachloride, which had a
 recovery of 140 percent.  Recoveries from spiked scrubber blowdown were all
between 84 and 116 percent with the exception of methylene chloride which had
 recoveries of 104 to 213 percent.
     Recoveries from VOST trap internal standards were presented in Table 25.
Recoveries were between 50 and 185 percent for octane and between 48 and
602 percent for isooctane with the exception of of the first series of tests
which had relatively poor recoveries between 5 and 1,560 percent.  Recent
evaluation of VOST trap Isooctane recoveries from many test series has shown
that relatively poor and irreproducible recoveries for this compound are
common.   In future, isooctane will no longer be used as an internal standard
for VOST analyses.
                                     57

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TABLE 24.  VOLATILE ORGANIC CONSTITUENT SPIKE SAMPLE RECOVERY
                    Spiked
                     feed
                   material
Spiked
 kiln
  ash
      Spiked
scrubber blowdown
  concentration
   (% recovery)
concentration
Compound (% recovery)
Methylene chloride
1,1-dichloroethylene
1,1-dichloroethane
t-l,2-dichloroethylene
Chloroform
1,2-dichloroethane
1,1,1-trichloroethane
Carbon tetrachloride
Bromodi chl oromethane
1,2-dichloropropane
t-l,3-dichloropropylene
Trichloroethylene
Benzene
1,1,2-trichloroethane
Hexane
Bromoform
Tetrachloroethylene +
tetrachloroethane
Toluene
Chlorobenzene
1,3-dichlorobenzene
1 ,2-di chl orobenzene
1,4-di Chlorobenzene
Internal standard
Isooctane
Octane
94
106
99
96
94
147
93
144
98
95
94
106
97
95
108
145
105

100
97
96
95
99

102
107
concentration
(X recovery) 7-28
90
108
94
84
86
112
88
140
95
89
89
89
93
90
86
108
90

89
89
90
90
90

85
88
125
84
104
89
91
92
91
96
92
91
93
87
93
92
87
86
93

91
92
91
91
91

89
93
8-5
104
96
105
98
96
99
98
96
96
98
98
98
98
97
98
96
98

98
98
98
98
98

99
100
8-13
143
93
102
92
94
91
94
96
95
94
95
94
97
86
90
90
92

94
94
94
95
95

92
94
9-3
213
109
114
111
116
113
114
74
116
114
113
113
113
114
106
115
112

111
112
110
111
110

107
106
                             58

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TABLE 25.  VOLATILE ORGANIC CONSTITUENT SPIKE
           RECOVERY IN VOST SAMPLES3

Test date
7-21
7-28
7-29
8-4
8-5
8-7
8-12
8-13
8-14
9-3
9-4
Percent
Isooctane
404-1,560
134-684
114-189
66-602
64-138
69-172
52-75
48-62
62-67
64-146
102-161
Recovery
Octane
5-38
72-108
161-185
81-106
106-114
50-116
54-112
76-90
99-112
106-122
100-102
        alnternal  standards used were
         Isooctane and octane.
                     59

-------
                                 REFERENCES
1.  Memo from W.J. Librizzi, Director, Emergency and Remedial response
    Division to W.A. Cowley, Acting Director, Hazardous Waste Engineering
    Research Laboratory, "Request for Technical Assistance Utilizing the EPA
    Combustion Research Facility (CRF) for the Bridgeport Rental and Oil
    Services (BROS) Superfund Site," February 11, 1986.

2.  Lee, J., R. W. Ross, II, and L. R. Waterland, "PCB Trial Burn Report for
    the U.S. EPA Combustion Research Facility Rotary Kiln Incinerator
    System," Acurex Draft Report under EPA Contract 68-03-3267, March 1987.

3.  Personal Communication, J. Pearson, Ecology and Environment, Inc.,
    Buffalo, New York, March 1986.

4.  "Test Methods for Evaluating Solid Wastes: Physical Chemical Methods,"
    EPA SW-846, 2nd ed., July 1982

5.  Harris, J. C., et al., "Sampling and Analyzing Methods for  Hazardous
    Waste Incineration," EPA-600/8-84-002, February 1984

6.  Schlickenreider, L. M., et al., "Modified Method 5 Train and Source
    Assessment Sampling System Operators Manual," EPA-600/8-85-003,  February
    1985.

7.  40 CFR Part 60, Appendix A

8.  Hansen, E.M., "Protocol for Collection and Analysis of Volatile  POHC
    Using VOST," EPA-600/8-84-007, March 1984.
                                      60

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                                 APPENDIX A
                       SAMPLING LOCATIONS AND METHODS

     Figure A-l lists the sampling methods and sample locations.   Gas  samples
were taken at the stack, the afterburner chamber exit,  and  the  carbon  bed
inlet.  The stack samples were required to satisfy permit requirements; the
afterburner exit and carbon bed inlet samples were taken to provide
information on the PCB destruction efficiency and PIC emissions prior  to  flue
gas scrubbing.
     The CRF staff performed monitoring of the flue gas for COg and  Og with
continuous emission analyzers (CEAs)  throughout the test period.   Og and  C02
were monitored simultaneously at the  kiln exit, stack,  afterburner exit,  and
scrubber outlet locations.  Volatile  organic species were sampled with VOST.
A standard M5 sampling strain extracted samples for HC1 and particulate
concentration determinations.  Semi volatile organic compounds were sampled
with the MM5 sampling train.
     The following sections describe  the various test methods,  equipment, and
procedures used.  Appendix D provides a summary of the sampling data for
VOST, M5, and MM5, and continuously recorded emissions.
A.I  CONTINUOUS EMISSION MONITORING
     Table A-l lists the CEAs, their  operation principles and their
analytical range sensitivities.
                                     A-l

-------
I  -
    s
   *
Method 5
(Pirtlcu
               b. M •- <•
                    • 91
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-------
                    TABLE A-l.  CONTINUOUS GAS ANALYZERS
Instrument
Bendix 304
02 analyzer
Species
measured
02
Principle
of
detection
Zirconium oxide
detector
Instrument
concentration
range
0-25 percent
0-10 percent
Known
interferences

High combustibles
Lead, antimony,
arsenic
Bendix 8903        CO/COg   NDIR
CO/C02 analyzer

Infrared Systems   CO/COg   NDIR
CO/C02 analyzer

Theta Sensors      03       Fuel cell
Og analyzer
C02 0-10 percent  None
CO  0-1000 ppm

C02 0-20 percent  None
CO  0-2000 ppm

0-5 percent       None
0-15 percent
0-25 percent
                                     A-3

-------
     Samples of combustion products  were drawn  continuously from the
afterburner exit and the stack.   After passing  through the sample
conditioning system which removes the moisture  and particulates, the
combustion products were analzyed for 02 and  C02«  Figures A-2 and A-3 show
the sample conditioning system details for the  afterburner chamber and the
stack, respectively.
     From the afterburner chamber, gas laden  with moisture and particulates
was withdrawn through a 61 cm (24 in.) long,  6.4 mm  (1/4 in.) diameter
uncooled SS316 tubing.   The gas  passed through  a Graham glass condenser coil
and was cooled by 7°C (45°F) water.   The condensate  was trapped and retained
in a 500-ml glass impinger.  The cleaner dried  gas sample then passed through
a glass fiber particulate filter and was pumped to the gas analyzers.
     From the stack, the gas was withdrawn through a 61 cm (24 in.) long,
9.5 mm (3/8 in.) diameter uncooled SS 316 tubing.  Since the stack gas was
saturated with water at about 71°C (160°F),  it  was passed through a water
drop-out glass jar to remove the condensate.  Particulates were then  removed
by a glass fiber filter.  The sample was further dried by a 30.5 cm  (12 in.)
Graham glass condenser chilled by 7°C (45°F)  water.   The condensate was
collected in a 500-ml glass container.  The  clean dry gas was then pumped to
the 02, CO, and C02 analyzers.
A.2  VOLATILE ORGANIC SAMPLING TRAIN
     The VOST was designed to collect trace  volatile organic compounds  in
combustion product streams (7).   The equipment  used  during these tests  is
shown in Figure A-4.  Essentially, the train consisted of:
     •   An unheated probe.  A 5.1 cm (2 in.) long glasswool  plug  at  the
         probe tip acted as a soot trap.  The afterburner  probe was  Hastenoy

                                     A-4

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         C-76, 71 cm (28 in.)  long  and  9.5 mm  (3/8 in.) diameter.  The stack
         probe was 316 SS,  61  cm (24  in.) long and 6.4 mm (1/4 in.)
         diameter.
     •   A piece of 6.4 mm  (1/4  in.)  diameter  SS 316 interconnecting tubing.
     •   A primary sample gas  moisture  condenser consisting of a 38 cm (15
         in.) long and 6.4  mm  (1/4  in.) diameter teflon-lined aluminum tubing
         encased in a water-cooled  22.9 cm  (9  in.) long PVC shell.
     •   A 12.7 cm (5 in.)  long  SS  316  primary resin cartridge containing
         1.6g Tenax.
     •   A glass condensate catch reservoir.
     •   A piece of 81 cm (32  in.)  long and 6.4 cm (1/4 in.) diameter Teflon
         tubing.
     •   A secondary gas moisture condenser similar to the primary
         condenser.
     •   A secondary resin  cartridge, similar  to the primary resin
         cartridge.
     •   A 50 ml silica gel desiccator.
     The VOST methodology in use at the CRF was designed for sampling
organics with boiling points between  40°C  (104°F to 252°F).  Three  duplicate
VOST samples were collected daily on  each test day.  They were taken at
approximetely 90-minute intervals' in  order  to  cover the typical  4-  to 5-  hour
tests.  The VOST samples were  taken for 20  minutes at  a 1 liter/minute.
Nominally, 20 liters of gas passed  through  the Tenax resin traps.
Approximately 50 ng per sample train  is sufficient for quantification of  most
volatile compounds.
                                     A-8

-------
 A.3  EPA M5 SAMPLING
                                                                        •
     The EPA M5 train was used to sample participates,  stack  gas moisture,
 and HC1 (4),  Figure A-5 shows the sampling train  which consisted of the
 following:
     •   A heated glass-lined probe
     •   A heated particulate filter
     •   Two impingers containing 0.1 N sodium acetate  (for collecting HC1)
     •   One empty impinger
     •   One impinger containing 200g silica gel
 M5 sampling in compliance with federal  regulations (40  CFR 60,  Reference 6)
 was performed at the stack and at the afterburner  exit.
 A.4  EPA MM5 SAMPLING
     The MM5 sampling train was used to extract semi volatile  organic
 compounds from combustion product streams (5).  During  these  tests, samples
were collected over a 4 to 5 hour test  period from the  afterburner chamber
 exit and the stack.  The sampling trains for the afterburner  chamber and the
 stack locations differed slightly to account for the sample gas temperature
 and moisture differences.  Figure A-6 illustrates  the train used for the
 scrubber outlet sample location.
     The MM5 train consisted of the following components:
     •   A 1.2 m (4 ft) long glass-lined, heated probe/pitot  tube  assembly
         with a 9.5 mm (3/8 in.) OD SS 316 nozzle
     •   A heated filter 1n a 121eC (250°F) oven
     •   A 30 en (12 1n.) long and 9.5 mm (3/8 in.) diameter  OD teflon
         interconnecting tubing
     •   A water-cooled glass capsule containing 30g XAD-2

                                     A-9

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     •   A 4-liter glass condensate  catch  reservoir
     •   A desiccator.
     Prior to assembly, the glassware  and  all tube fittings upstream of the
condensate catch were sonicated in a 1:1 solutin of methylene chloride in
methanol.  Subsequently, they were rinsed  with  100 ml of clean solution which
was then extracted and analyzed by GC/FID  to ensure that the fittings and
glassware were clean.  Following assembly  and prior to sample collection, the
trains were leak-tested.  All connections  upstream of the second condensate
catch were Teflon-to-glass joints or SS 316 tube fittings.  After the
sampling was completed, the trains were again leak-tested.
     During the sampling period, the sample temperatures downstream of the
probe, at the filter and downstream  of the resin capsule were monitored and
controlled at about 121, 121 and 20°C  (250, 250 and 68°F),  respectively.  The
samples were withdrawn at approximately 0.02 m^/min (0.75 ft^/min) for 4  to
5 hours.  At this rate, about 5.4 dscm (200 dcsf) was passed through the
train.  Upon test completion, the probe,  interconnecting tubings,  filter, and
resin capsule were disassembled, sealed with aluminum foil, and  immediately
transported to the CRF analytical laboratory for sample  recovery.  All the
train components' internal surfaces  exposed to  the  gas were brushed  and
rinsed with a 1:1 solution of methylene chloride in methanol.   The individual
rinse solutions, the particulate filters,  the condensate, and  the  XAD-2  resin
were then subjected to a series of  analysis  procedures which  are discussed  in
Appendix B.
                                     A-12

-------
                                 APPENDIX B
                    SAMPLE RECOVERY AND ANALYSIS METHODS

     The samples collected by the CRF sampling team were recovered  and
analyzed onsite.  This appendix describes the sample recovery  procedures  and
the analysis methods followed by the CRF analytical laboratory.
B.I  SAMPLE RECOVERY
B.I.I  VOST Samples
     No special sample recovery procedure was needed except for  capping the
resin traps to prevent contamination and storing them on ice prior  to
analysis.  The traps were immediately delivered to the onsite  analytical
laboratory where desorption and analysis were performed on the same day.
B.I.2  EPA MS Samples
     The CRF sampling staff recovered the samples from the EPA M5 sampling
train, following procedures in accordance with those described in
Reference 6.  The following discussion is a brief description  of the recovery
activities.
     After sampling a post-test checks were completed, the probe was
disassembled from the train.  The outside of the sampling nozzle and the  ball
joint were wiped clean.  The partlculate filter holder was removed  from the
train and the glass joints were wiped clean.  The subsequent recovery
procedure collected the following samples:
                                     B-l

-------
     •   The outside surfaces  of  the probe, nozzle, and filter holder were
         wiped clean to prevent inadvertent collection of dust and
         particulate.
     •   The filter and the particulate  cake were carefully removed from the
         filter holder and placed in a labeled petri dish.  The inside
         surface of the front  half of the  filter holder was brushed with
         clean, dry nylon bristles.  The particulate removed with the
         brushing was added to the filter  in the petri dish.
     •   The inside surfaces of the probe, nozzle, and filter holder front
         half were rinsed with an acetone  solution repeatedly until no
         visible particulates  were washed  out.  The wash was collected in a
         clean, sealed amber glass container.
     •   The silica gel was weighed directly in the impinger before and after
         the sampling to note  the moisture trapped.  The silica gel was then
         regenerated.
     •   The condensate catch  in  the impingers was weighed and the condensate
         color was noted.
     The samples were then delivered to  the onsite analytical laboratory  for
chemical analysis.  These analyses are discussed in Section 5.2.
B.I.3  EPA MM5 Samples
     The CRF analytical laboratory staff recovered the samples from the MM5
sampling train in accordance with procedures outlined in Reference 5.  A
brief description of the procedures is given below.
     The sample recovery took  place immediately  following the conclusion  of
each test as follows:
                                     B-2

-------
•    The  filter  and  the  participate  cake,  in their  unmodified  state, were
     carefully removed from  the  filter holder with  forceps  and
     transferred into a  desiccator for drying overnight  prior  to weighing
     and  subsequent  Soxhlet  extraction.
•    The  1:1 methanol/methylene  chloride solution containing the
     particulates washed from the inside of the  probe  and the  probe
     nozzle and the  front-half of the filter holder—the outside
     surfaces of these components were wiped free of particulates.  The
     inside surfaces were brushed with clean nylon  bristles and rinsed
     with the above  solution repeatedly.   The wash  was volume-reduced in
     a Kuderna-Danish apparatus, dried, and combined with the  extracts of
     other train components.
•    The  XAD-2 resin in  its  capsule  was quantitatively transferred to a
     Soxhlet in which extraction began immediately.
•    The  fluid volume and pH of  the  condensate collected in the
     condensate knock-out vessel were measured and  recorded.   The  fluid
     was  transferred to  a separator  funnel for liquid-liquid extraction
     on the next day.
•    The  1:1 methanol/methylene  chloride solution collected from washing
     the  train components between the fiber filter  and the  first wet
     impinger was collected  by repeatedly  brushing  and rinsing the
     various components, combined with the above probe washes.
•    The  silica gel  1n the fourth impinger was transfered to a clean,
     sealed container.
                                B-3

-------
     •   The unused portion of the 1:1 methanol/methylene  chloride wash
         solution to be used as blank was transferred  into a  clean,  sealed
         glass bottle.
B.2  ANALYSIS METHODS
     The samples from the recovery efforts were subjected  to  analysis  to
determine the amounts of Arochlor 1254, and other organic  constituents
trapped in the resins and sample extracts.  The following  describes  briefly
the analytical procedures employed at the CRF laboratory.
B.2.1  VOST  Samples
     Analysis of the VOST samples was performed in accordance with purge  and
trap method (7).  The Tenax-GC resin traps were thermally  desorbed for 15
minutes at 180°C with organic-free nitrogen gas at a flowrate of 40  ml/min,
bubbled through 5 ml of organic-free water, and trapped on an analytical
absorbent trap.  After the 15-minute desorption, the analytical  absorbent
trap was rapidly heated to 180°C with the carrier gas  flow reversed  so that
the effluent flow from the analytical trap was directed into  the GC.  The
volatile volatile were separated by temperature programmed gas chromatograpy
and detected by a electron capture detector.
     The list of organic compounds sought with this analytical method is
given in Table B-l.  The primary focus of the tests was to determine the  DEs
of Arochlor 1254, which is analyzed with MM5 samples as described in
Section B.2.3.
B.2.2  EPA MS Samples
     The rinse materials collected in the recovery procedure  were combined
and the entire aliquot was measured volumetrically to the nearest 1  ml and
quantitatively transferred to a tare-weighed beaker.  The sample was

                                     B-4

-------
 evaporated  to  dryness  on  a steam table  in  a  140°C  (289°F)  oven  for 1 hour.
 After  it  had cooled  in a  desiccator,  the sample  was  weighed  to  the nearest
 0.1  mg.   A.  200-ml  aliquot  of  unused  acetone  was  processed  in the  same manner
 to account  for blank weight gain.
     The  filter  paper  was  transferred to a petri dish  and  dried in a 140°C
 (289°F) oven for 2.5 hours and  weighed  to  the  nearest  0.4  mg.  An unused
 filter was  processed in the same manner to act as  blank.
     The  solution  in the two  impingers  was measured  volumetrically and
 transferred to the CRF laboratory  for chloride analysis  by specific ion
 electrode.  The  silica gel  and  the impinger  were weighed to  the
 nearest 0.5g.
 B.2.3  EPA MM5 Samples
     The  samples derived from this sampling  method were  analyzed  for PCBs and
 other semivolatile chlorinated  organic  compounds in  accordance  with
 Method 8080 which used gas  chromatography/electron capture detection
 (GC/ECD).  Samples were first extracted via  separatory funnel liquid-liquid
 extraction  (Method 3510),  sonication  (Method 3550),  or Soxhlet  extraction
 (Method 3540)  as appropriate.
 B.3  OTHER SAMPLES
     In addition to the samples  discussed  earlier, samples of the waste feed,
 kiln ash, and  blowdown water  were  collected  and  analyzed in  the CRF
 laboratory.   All PCB analyses were performed using direct  injection GC/ECD by
Method 8080 following  extraction in accordance with  Methods  3540, 3550,
or 3510.  Analyses for semivolatile priority pollutants  were performed by
Method 8270.   Trace element analyses were  performed  by atomic absorption in
accordance with  the 7000 series  methods.   Appropriate  add digestion of solid

                                     B-5

-------
samples was accomplished as needed by Method 3010.   EP extractions of
Individual  waste material  and kiln ash were also performed with trace element
analyses by 7000 series methods.
                                     B-6

-------
  APPENDIX C



WASTE FEED DATA
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 APPENDIX D



SAMPLING DATA
     D-l

-------
                                         TabIt.   Gas Concentration on July 21,  1986
1
1
TINE
Start Stop
1115 1195
1135 1155
1155 1215
1215 1235
1235 1266
1255 1315
1316 1336
1335 1355
1355 1415
1415 1435
1435 1455
1455 1515
1515 1535
1535 1555
1555 1615
1615 1635
1635 1655
1655 1715
1715 1735
1735 1755
1755 1815

TIME
Start Stop
1115 1136
1136 1166
1155 1216
1216 1236
1236 1265
1255 1315
1315 1335
1335 1355
1355 1415
1415 1435
1435 1455
1455 1515
1515 1535
1635 1555
1555 1615
1615 1635
1635 1655
1655 1715
1715 1735
1735 1755
1755 1815
AFTERBURNER EXIT
Oxygan
Concentration
(« Dry as Mas'd)
Hin Max Mean

NA NA NA
HA NA NA
4.5 6.5 6.5
4.0 6.3 6.1
6.0 6.0 6.5
NA NA NA
NA NA NA
NA NA NA
NA NA NA
6.5 6.0 5.8
5.5 6.0 5.8
NA NA NA
NA NA NA
NA NA NA
5. 5 6.0 5.8
NA NA NA
NA NA NA
Carbon Dioxide
Concentration
(* Dry as Mas'd)
.
Min Max Mean

8.5 9.4 9.0
NA NA NA
3.1 8.7 6.9
7.6 9.2 8.4
8.0 8.7 8.4
NA NA NA
7.8 8.4 8.1
8.0 8.5 8.3
NA NA NA
3.2 5.3 4.3
3.2 8.4 5.8
0.4 8.5 4.5
0.0 0.0 0.0
NA NA NA
Carbon Monoxide
Concentration
(* Dry as Mas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

KILN EXIT
Oxygen
Concentration
(X Dry •• Mas'd)
Hin Max Mean
NA NA NA
12.0 13. t 12.1
•.8 14.5 11.6
NA NA NA
NA NA NA
NA NA NA
NA NA NA
12.8 13.3 13.0
13.0 13.3 13.1
12.5 13.3 12.*
12.5 13.3 12.9
NA NA NA
NA NA NA
NA NA NA
12.3 12.8 12.5
12.3 13.0 12. »
10.8 13.3 12.0
NA NA NA
NA NA NA
NA NA NA
NA M* NA
Carbon Dioxide
Concentration
(k Dry as Mas'd)
Min Max 'tan
3.6 .9 4.3
1.1 .1 1.0
NA NA NA
4.1 .2 4.2
3. .2 4.1
3. .2 4.1
3. .3 4.1
NA NA NA
3, .1 3.9
3. .1 3.9
3. .1 3.9
3. .1 3.7
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Carbon Monoxide
Concentration
(* Dry •• Mas'd)
..
Hin Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
CARBON BED INLET
Oxygen | Carbon Dioxide
Concentration j Concentration
(* Dry as swas'd) | (* Dry as Mas'd)
1
Min Max Mean| Min Max Mean
11.3 13.0 12. 1| 6.1
NA NA NA | 6.7
NA NA NA | 6.8
11.3 13.8 12. S| NA
11.8 12.« 12.3| S.O
12.5 12.8 12. 6| 6.1
12.5 12.8 12.6| 6.7
NA NA NA j 6.1
NA NA NA | 6.1
NA NA NA | NA
NA NA NA | 6.6
12.0 12.8 12. 4| 5.7
12.0 12.8 12. 4| 5.9
12.0 12.8 12.4| 6.9
NA NA NA | NA
NA NA NA j 5.9
NA NA NA I 6.9
12.0 12.5 12.3| 6.1
12.0 12.5 12.3) 2.0
NA NA NA | NA 1
NA NA NA I NA 1
.9
.3
.3
IA
.7
.0
.7
.3
.2
A
.5
.3
.4
.3
*A
.4
.5
.3
.5 i
«A 1
4A 1
.0
.5
.1
IA
.4
.1
.2
.2
.2
IA
.1
.0
.2
.1
A
.2
.2
.7
1.9
W |
M
Carbon Monoxide
Concentration
(* Dry as Mas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

STACK
Oxygen | Carbon Dioxide Carbon Monoxide
Concentration j Concentration j Concentration
(* Dry •• Mas'd) |(* Dry as Mas'd) | (* Dry as Mas'd)
1
Min Max Mean
NA NA NA
11.0 U.8 12.4
NA NA NA
NA NA NA
NA NA NA
NA NA NA
6.1 12.8 12.8
6.1 13.0 12.8
6.0 13.0 12.6
NA NA NA
NA NA NA
NA NA NA
12. S 13.0 12.8
12.6 13.0 12.8
11.5 13.0 12.3
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Min
.6
NA
.8
.7
.5
.8
NA
.8
.5
.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
Max Mean
.7
NA
.2
.0
.0
.2
NA
.3
.3
.4
NA
NA
NA
NA
NA
NA
NA
NA
NA
.6
NA
.0
.9
.3
.9
NA
5.9
6.1
5.9
6.0
NA
NA
NA
NA
NA
NA
NA
NA
NA
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA - Data not taken

-------
                                        Table.
Gas Concentration on July 28.  1986

TIME



Start Stop
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1SOO
1500 1620
1S20 1S40
1540 1600
1600 1620
1620 1640
1640 1700
1700 1714
AFTERBURNER EXIT
Oxygen
Concentration
Carbon Dioxide
Concentration
Carbon Honixide
Concentration
(* Dry as Mas'd) |(k Dry as Mas'd) |(* Dry as Mas'd)


-
Min Max Mean) Min Max Mean) Min Max Man
.0 .6 6.4
NA NA NA
.8 .0 4.4| NA NA NA
A A NA
HA NA NA
NA NA NA
NA NA NA
4.2 4.3 4.3| NA NA NA
4.0 4.4 4.2| NA NA NA
.3 .6 .5| NA NA NA
.5 .0 .8| NA NA NA
.8 .0 .»| NA NA NA
.8 .0 .9| NA NA NA
.6 .0 .9) NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
3.7 4.0 .9| NA NA NA
3.7 3.9 .8| NA NA NA
3.7 3.9 .B| NA NA NA
3.7 3.9 .8| NA NA NA
3.7 3.9 .8| NA NA NA
5.8 6.3 .0| NA NA NA
4.5 (.8 .6| NA NA NA
6.0 6.0 .0) NA NA NA
6.0 6.0 .0) NA NA NA
6.0 10.3 .1| NA NA NA
7.3 7.3 7.3
NA NA NA
L • l
NA NA NA
NA NA NA

NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA HA

CARBON BED INLET
Oxygen
Concentration
Carbon Dioxide | Carbon Monoxide
Concentration j Concentration
(X Dry as Mas'd) |(t Dry as Mas'd) |(t Dry as Mas'd)
_
I-
Min Max Mean| Min Max Mean| Mm Max Mean
. 10.6 .1
NA NA NA | NA NA NA
10.0 .6| NA NA NA | NA NA NA
NA NA A
NA NA NA
3.7 4.4 4.1| NA NA NA
4.0 4.4 4.2| NA NA NA
• .8 .6| NA NA NA | NA NA NA
10.0 .6 1 NA NA NA j NA NA NA
10.0 .9) NA NA NA | NA NA NA
9.8 .6) NA NA NA | NA NA NA
9.8 .8| NA NA NA | NA NA NA
HA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
6.6 .7 .6) NA NA NA
6.5 .7 .6| NA NA NA
6.5 .7 .6| NA NA NA
6.5 .7 .6| NA NA NA
6.5 .4 .0| NA NA NA
.8 6.3 .0| NA NA NA NA NA NA
.5 6.8 .6| NA NA NA NA NA NA
.0 6.3 .1| NA NA NA NA NA NA
.0 6.0 .0| NA NA NA NA NA NA
.0 10.3 . 1| NA NA NA NA NA NA
7.3 7.3 7.3| NA NA NA NA NA NA
NA NA NA

| NA NA NA NA NA NA

1

TIME



Start Stop
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 14*0
1440 1500
1500 1620
1520 1S40
1540 1600
1600 1620
1620 1640
1640 1700
1700 1714

Oxygen
Concentration

KILN EXIT
Carbon Dioxide
Concentration


Carbon Monixide
Concentration
(\ Dry as Mas'd) |(* Dry as Mas'd} ((* Dry as Mas'd)

.
-
Min Max Mean] Min Max Mean) Min Max Mean
NA NA NA
NA NA NA
.2 9.6 .9
NA NA NA
.6 10.0 .8) NA NA NA
0.0 14.3 7.1| A NA NA
14.0 14. S 14.3| NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
.3 .5 .4| NA NA NA
.2 .5 .4
NA NA NA
.1 .5 .3| NA NA NA
.1 .3 .2) NA NA NA
.1 .3 .21 NA NA NA
0.0 14.6 7.4| NA NA NA
14.5 15.0 14.6| NA NA NA
14.6 15.0 14.9) NA NA NA
14.5 15.0 14.81 NA NA NA
15.0 15.0 15.01 NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
.9 9.3 .1| NA NA NA
.5 10.0 .3| NA NA NA
.0 .1 .1| NA NA NA
.1 .2 .21 NA NA NA
.4 .1 .8
NA NA NA
7.9 .5 .2| NA NA NA
6.3 .6 .4
NA NA HA
STACK
Oxygen
Concentration
Carbon Dioxide | Carbon Monoxide
Concentration j Concentration
(* Dry as Mas'd) |(* Dry as awas'd)|(* Dry as Mas'd)
	
1
Min Max Mean| Min Max Mean| Min Max Mean
NA NA NA
NA HA NA
6.S 6.5 7.S| NA NA NA
6.6 7.4 7.1) NA NA NA
10.0 10.3 10.1] NA NA NA | NA NA NA
10.3 10.3 10.3| 6.8 7.1 7.0| NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
.0 7.2 7.1| NA NA NA
.9 7.2 7.1| NA NA NA
.8 7.1 7.0) NA NA NA
.8 7.1 7.0| NA NA NA
.8 7.1 6.5| NA NA NA
10.3 10.5 10.4) NA NA NA | NA NA NA
10.5 10.5 10.5) NA NA NA | NA NA NA
10.5 10.5 10.5) NA NA NA | NA NA NA
10.5 10.5 10. SJ NA NA NA j NA NA NA
10.0 10.5 10.3| 6.6 7.2 6.9| NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA HA NA
6.3 8.3 7.3| NA NA NA
6.6 6.9 6.9| NA NA NA
6.8 7.1 7.0| NA NA NA
4.6 7.1 6,9| NA NA NA
4.6 6.3 S.S| NA NA NA
6.2 6.3 6.3| NA NA NA
6.2 6.3 6.3| NA NA NA
'
NA - Data not taken

-------
                                         Table.     Gas Concentration  on  July  29.  1966
TIME
_ _
Start Stop
950 1010
1010 1030
1030 1050
1050 1110
1110 1130
1130 1160
1150 1210
1210 1230
1230 1250
1250 1310
1310 1330
1330 1350
1350 1410
1410 1430
1430 1450
1450 1510
1510 1630
1530 1550
1550 1610
1610 1630
1630 1650
1650 1710
'1710 1730
1730 1750
1750 1810
1810 1830
1830 1850
1850 1900

AFTERBURNER EXIT


CARBON BED INLET |
1 1
Oxygen | Carbon Dioxide | Carbon Monoxide | Oxygen | Carbon Dioxide Carbon Monoxide |
Concentration | Concentration j Concentration j Concentration j Concentration | Concentration |
(* Dry a* •was'd)|(% Dry as s*as'd)|(* Dry as Mas'd) |(k Dry as Mas'dlKk Dry as Mas'd) | (X Dry as at«s'd)|
1 1 1 1 1 1
Min Max
3.6 6.0
4.0 6.6
4.8 9.3
6.0 9.5
6.0 19.6
20.0 20.5
6.0 20.5
1.5 4.5
1.5 10.5
7.5 13.5
3.6 7.5
3.0 6.0
4.5 6.8
NA NA
NA NA
NA NA
NA NA
S.S 5.5
5.3 5.5
5.3 .3
.0 .3
.0 .5
.0 .0
.0 .0
.0 .0
6.0 .0
6.0 .0
NA NA
Mean | Min Max Mean)
4.8| 9.3 10.0 9.7|
4.8| 9.1 10.0 9.6|
7.0| 7.1 8.2 7.7|
7.3| 9.3 10.0 9.7|
12. 4| 0.0 9.7 4.9|
20.3| 0.0 2.5 1.3|
12. 8| 6.0 10.0 8.0|
3.0| 10.0 10.0 10.0|
6.0| 4.6 10.0 7.3|
10.5| 7.0 9.2 8.1|
5.6| 6.7 10.0 9.4|
4.8| 9.2 10.0 9.6|
S.1| 9.3 10.0 9.7|
NA | NA NA NA |
NA | NA NA NA |
NA j NA NA NA j
NA | NA NA NA |
5.5| .2 .3 .3|
6.4| .2 .3 .3|
5.3| .4 .5 .5|
5.6| .8 .7 .6|
.31 .2 .7 .3|
.01 .2 .3 .3|
.0| .2 .3 .3)
.0! .2 .3 .3)
.0| .2 .3 .4)
.0| .3 .4 .4|
NA | .3 .4 .4|
1 1
Min
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Max
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Mean| Min Hax Mean| Min Hex Meanj Min Max Mean|
NA | .5 10.0 9.3| 6.8 7.9 7.4| NA NA NA |
NA .3 10.3 9.3| 5.1 7.5 6.3| NA NA NA |
NA | 1 .3 12.3 11.1| 6.1 .7 6.4| NA NA NA |
NA | .3 16.8 12. 0| 3.1 .5 6.3| NA NA NA |
NA | .8 21.5 1S.1J 0.2 .4 3.8| 12.3 5.5 8.3|
NA 1 .3 21.5 19. 9| 0.2 .9 4.1| NA NA NA |
NA .5 18.0 12.3| 7.3 .6 8.4| NA NA NA |
NA 1 .S 16. 6 12.1| ,1 .4 4.6| NA NA NA |
NA ) .5 12.6 10. 1| .5 .S 7.5| NA NA NA |
NA .8 9.0 6.4| .0 8.0 7.5| NA NA NA |
NA .0 9.0 8.6| .5 7.6 7.1 NA NA NA |
NA NA NA NA | NA NA NA NA NA NA |
NA NA NA NA | NA NA NA NA NA NA |
NA NA NA NA | NA NA NA NA NA NA |
NA NA NA NA | NA NA NA NA NA NA |
NA .5 .5 .S| .2 .5 9.4| NA NA NA |
NA .5 .5 .5| .4 .6 9.5| NA NA KM ,
NA .5 .5 .0| .5 .7 y.b| NM n* ,M ,
NA .0 .0 .0| .8 .7 9.3| NA NA NA |
NA .0 .0 .0| .2 .3 9.3| NA NA NA |
NA .0 .0 .U| .-. . . ... ,
NA .0 .0 .U| .< .• »..»i n~ «» — ,
NA .0 .0 .01 .2 .4 9.3| NA NA NA I
NA .0 .0 .0| .3 .4 9.4J NA NA NA |
NA .0 .0 .01 .3 .4 9.4| NA NA NA |
1 1 1

TIME



Start Stop
950 1010
1010 1030
1030 1050
1050 1110
1110 1130
1130 1150
1150 1210
1210 1230
1230 1250
1250 1310
1310 1330
1330 1350
1350 1410
1410 1430
1430 1450
1450 1510
1510 1530
1630 1550
1650 1610
1610 1630
1630 I860
1660 1710
1710 1730
1730 1750
1760 1610
1810 1630
1830 1650
1850 1900
KILN EXIT
Oxygen
Concentration
(* Dry •* Mas'd)

Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA MA NA
NA HA NA
NA MA NA
Carbon Dioxide | Carbon Monoxide
Concentration j Concentration
(* Dry •• ettM'd)|(* Dry as Mas'd)
1
Min Max Mean) Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
0.0 IS.) 6.1| 6.5 6.5 6.0| NA NA NA
11.0 IS.) 11.6| S.6 6.4 S.0| NA NA NA
11.3 12.3 11.8| S.6 6.3 6.0| NA NA NA
11.1 12.1 11. 8| S.7 8.1 6.0| NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
HA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
1 	 1
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
1 	 1
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
STACK
-
Oxygen
Concentration
(* Dry •• Bees' d)

Hin Max Mean
NA NA HA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
Carbon Dioxide
Concentration
(\ Dry as Mas'd)

Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA HA
NA NA NA
NA NA HA
NA NA NA
NA NA NA
Carbon Monoxide
Concentration
(t Dry as Bcas'd)

Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
9.5 10.0 9.6| 6.5 7.0 6.6| NA NA NA
9.5 9.8 9.6) 6.7 7.0 6.9| NA NA NA
9.5 9.8 9.6) 6.6 7.3 7.0| NA NA NA
9.6 9.6 9.8| 7.1 7.5 7.3| NA NA NA
NA NA NA NA NA NA
HA NA NA NA NA NA
NA HA NA NA HA NA
NA HA NA NA NA NA
NA HA HA NA HA HA
HA HA HA HA HA HA
NA HA HA HA NA NA
HA HA HA HA NA NA
HA NA NA HA HA NA
NA HA NA NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA - Data not taken

-------
                                             Gas  Concentration on August 4, 1986
TIME
Start Stop
910 »20
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1500
1SOO 1520
1520 1540
1540 1600
'1600 1620
1620 1640
1640 1700
1700 1720
1720 1740
AFTERBURNER EXIT
Oxygen | Carbon Dioxide | Carbon Monoxide
Concentration | Concentration | Concentration
(* Dry as Mas'd) |(* Dry •• Mas'd) |(k Dry as Mas'd)
1 1
Min Max Mean) Kin Max Mean) Min Max Man
NA HA NA | 0.0 0.0 0.0| NA NA NA
B. 3 20.8 14.5| 0.0 .3 3.2| NA NA NA
9.0 21.0 14.5| 0.0 .7 4.9| NA NA NA
12.3 21.0 16.6) 0.0 .1 3.1| NA NA NA
.5 11. S $.0| (.2 1 .0 7.6) NA NA NA
.0 15.8 11.9| 9.4 .6 6.0| NA NA NA
.8 14.0 10.4| 8.1 .9 T.0| NA NA NA
.0 7.S .3| 8.7 10.0 9.4| NA NA NA
.5 6.S .0| 10.0 10.0 10. OJ NA NA NA
.5 6.3 .9) 9.7 10.0 9.9) NA NA NA
.0 7.5 .3| 9.0 10.0 9.5) NA NA NA
.0 7.6 .3| 8.9 10.0 9.5| NA NA NA
NA NA NA | 7.7 10.0 8.9| NA NA NA
NA NA NA j NA NA NA j NA NA NA
HA NA HA | HA NA HA | HA NA NA
3.5 10.0 .8| 7.6 10.0 8.8) NA NA NA
3.8 6.8 .3| .3 10.0 9.7J NA NA NA
4.0 6.5 .3| .6 10.0 9.8| NA NA NA
4.0 7.0 .51 .4 10.0 9.7| NA NA NA
6.0 7.3 .1| .4 10.0 9.7| NA NA NA
6.0 7.3 .1| .5 10.0 9.8) NA HA NA
NA NA NA | NA NA NA | NA NA NA
NA NA NA | NA NA NA | NA NA NA
NA NA NA | NA NA NA | NA NA NA
NA NA HA | NA NA NA | HA NA NA
1 1
CARBON BED INLET
Oxygen Carbon Dioxide
Concentration | Concentration
(* Dry as Mas'd) |(t Dry as Mas'd)
Carbon Monoxide
Concentration
(I Dry as Mas'd)
N1n Max Mean | M1n Max Mean) Min Max Mean
NA NA NA |
6.6 11.0 8.3|
.0 9.8 8.4|
.0 16.0 11.6)
1 .3 13. S 11.9|
.5 11.6 10.0|
.5 .0 7.8)
7.0 .3 8.1|
6.3 .8 7.5|
7.5 .0 6.3|
7.0 .0 6.01
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
.6 9.3 8.1
.2 9.3 7.3
.3 6.1 7.2
.4 7.7 6.1
6.9 6.3
7.3 6.3
8.7 9.0
8.1 7.3
8.9 7.9
8.3 7.4
6.5 7.7
r. 6.3 7.9
*A NA NA
HA HA HA
«A NA NA
NA NA NA
WA NA NA
NA NA NA
KA NA NA
7.3 8.0 7.6| 7.1 8.7 7.9
7.8 8.3 6.0| 7.1 8.3 7.7
1
NA HA NA
NA NA NA
NA NA NA
NA NA NA
12.3 6.5 8.3
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA
NA NA NA
[ NA NA NA
| NA NA NA
NA NA HA
NA NA NA
NA NA HA .
NA NA HA (
NA NA NA
| HA HA NA
| NA NA NA
| NA NA NA
| NA HA HA
j NA NA NA

TIME


Start Stop
910 920
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1600
1600 1620
1820 1640
1540 1600
1600 1620
1620 1640
1640 1700
1700 1720
1720 1740

KILN EXIT
Oxygen
Concentration
(* Dry as Mas'd)
Min Max Mean
NA NA NA
NA NA NA
NA HA NA
NA NA HA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Carbon Dioxide | Carbon Monoxide
Concentration j Concentration
(* Dry as Mas'd)
(t Dry as Mas'd)
Min Max Mean) Min Max Mean
HA HA HA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
NA MA HA
HA HA NA
NA NA NA
NA NA HA
NA HA HA
NA HA HA
HA HA NA
MA NA NA
NA HA NA
HA HA HA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
HA NA HA
HA HA NA
NA NA NA
NA NA NA
NA HA HA
3.0 9.6 6.4) 7.6 10.0 8.8| NA NA NA
6.3 10.8 8.6) 6.9 10.0 8.5| NA NA NA
6.5 11.3 8.9| 6.4 10.0 6.2| NA HA NA
HA HA HA NA HA HA HA HA HA
NA NA NA HA NA NA NA NA NA
NA NA NA NA NA NA NA HA NA
NANAHANANANANANANA
NA NA NA NA NA NA NA NA NA
NA NA NA NA NA NA NA NA NA
NA HA NA NA NA NA NA HA NA
4.5 9.0 6.8| 8.6 10.0 9.3| NA NA NA
7.S 10.6 9.0J 7.5 9.4 6.SJ NA NA NA
8.0 10.6 9.4| 7.4 10.0 8.7| NA NA NA
6.5 10.8 8.6| 7.6 10.0 8.6
1
NA NA NA

T
STACK |
1
Oxygen
Concentration
(t Dry as Mas'd)
_
Min Max Mean
HA HA HA
HA NA HA
NA NA HA
HA HA NA
HA NA NA
NA HA HA
HA HA HA
HA HA NA
NA NA HA
HA NA NA
NA HA NA
NA NA NA
NA NA HA
NA NA NA
NA NA NA
Carbon Dioxide
Concentration
(« Dry as Mas'd)
Min Max Mean
NA NA NA
NA NA NA
NA HA NA
HA HA HA
NA NA NA
NA NA NA
NA HA HA
HA HA NA
NA NA NA
NA NA NA
NA NA NA
NA NA HA
HA HA NA
NA NA HA
Carbon Monoxide I
Concentration |
(k Dry as Mas'd) |
_ - 1
Min Max Mean
NA NA NA L
NA NA NA*J
NA NA HA™
NA NA KA
NA NA NA
NA NA NA
NA NA NA
NA NA HA
NA NA HA
NA NA NA
NA NA NA
NA NA NA
NA NA HA
NA NA NA
.3 6.7 7.5| NA NA HA
.5 10.0 9.3| .2 7.6 6.9| NA NA HA

.8 10.0 9.4| .0 7.6 6.6| NA NA HA
.8 9.6 9.3) .4 7.3 6.9| NA NA NA
.8 9.8 9.3) .3 7.5 6.9) NA NA NA
.3 9.3 6.6| .6 7.8 7.2| NA NA NA
NA NA NA NA HA HA NA HA HA
NA NA NA HA HA HA HA NA NA
HA NA NA NA NA NA NA NA NA
NANANANANANANANA NAJ
	 -1
NA - Data not taken

-------
                                             Gas Concentration on August 5, 1986

TIME



Start Stop
«20 940
•40 1000
1000 10ZO
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1SOO
1SOO 1S05
1SOS 1530

AFTERBURNER EXIT
Oxygen Carbon Dioxide | Carbon Monoxide
Concentration Concentration | Concentration
(t Dry as «*i«'d) (* Dry as Mas'd) |{* Dry as Mas'd)
1
Mtn Max Mean Min Max Mean; Min Max Mean
4.0 14.5 .3|
7.3 10.0 .6|













.5 13.5 .0|
.S 9.0 .8
.0 8.5 .3|
.5 8. 8 7.6|
A NA NA |
A NA NA 1
.8 15.0 10.9)
.8 7.8 6.8|
.8 8.0 6.9|
.0 S.S 4.8|
.5 6.0 6.3|
.3 6.0 S.1|
.5 6.8 5.6|
.5 8.3 7.4|
KM iv% HM |
NA NA NA |
.6 8.7
.4 9.5
.1 10.0
.9 10.0
.0 10.0
.2 10.0
.1 10.0

-------
                                            Oas Concentration en August T, 1986
TIME
Start Stop
•45 1005
1005 1025
1025 1045
1045 1105
1105 1125
1125 1145
1145 1206
1205 1225
1225 1245
1245 1305
1305 1325
1325 1345
1345 1405
1405 1425
AFTERBURNER EXIT
-
Oxygen
Concentration
(* Dry as Mas'd)
M1n Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
7.S 10.0 8.9
1.8 8.8 5.3
5.0 7.0 6.0
Carbon Dioxide
Concentration
(* Dry as Mas'd)
M1n Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
7.4 9.2 8.3
8.2 10.0 9.1
9.3 10.0 9.7
Carbon Monoxide
Concentration
(* Dry as Mas'd)
H
-------
                                            Qts Concentration on August 12, 1986
TIME
Start Stop
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
AFTERBURNER EXIT
Ox'ygtn | Carbon Dioxide | Carbon Monoxide
Concentration j Concentration j Concentration
(t Dry as Mas'd) |(* Dry as Mas'd)|(* Dry as Mas'd)
1 1
Hin Max Mean! Min Max Meanj Min Max Mean
3.5 9.S 6.5| 6.2 9.2 7.7| NA NA NA
6.5 8.8 7.1| 6.4 9.7 8.1| NA NA NA
6.3 9.S 7.9| 6.9 10.0 8.5| NA NA NA
NA NA NA | 7.0 9.7 8.4| NA NA NA
NA NA NA | NA NA NA | NA NA NA
NA NA NA | NA NA NA | NA NA NA
NA NA NA | NA NA NA j NA NA NA
NA NA NA I NA NA NA j NA NA NA
7.0 11.0 .0| 7.4 9.8 .6| NA NA NA
.5 10.3 .4| 7.1 10.0 .6| NA NA NA
.5 10.8 .6| 6.8 10.0 .4| NA NA NA
.5 10.5 .S| 6.9 10.0 .5| NA NA NA
.0 10.5 .8) 7.0 10.0 .51 NA NA NA
.5 10.3 .4| 7.1 10.0 .6| NA NA NA
.3 10.5 .4| 7.0 10.0 .5| NA NA NA
I I
CARBON BED INLET
Oxygen | Carbon Dioxide Carbon Monoxide
Concentration Concentration Concentration
<* Dry as Mas'd)|(* Dry as Mas'd) (* Dry as Mas'd)
Min Max Mean) Min Max Mean Min Max Mean
10.0 11.8 10.9| 3.8 6.3 5.1 NA NA NA
9.3 11.0 10.1J 5.0 7.1 6.1| NA NA NA
9.5 11.0 10. 3| 6.5 7.3 6.4| NA NA NA
9.3 10. S 9.9| 5.3 6.9 «.1| NA NA NA
NA NA NA 6.5 7.2 6.9| NA NA NA
NA NA NA NA NA NA | NA NA NA
NA NA NA NA NA NA | NA NA NA
NA NA NA NA NA NA j NA NA NA
NA NA NA NA NA NA | NA NA NA
.6 10.8 9.8| 6.3 6.5 .4| NA NA NA
.0 11.0 10.0| 5.5 7.8 .7| NA NA NA
.0 11.0 10. OJ 5.4 7.5 .5) NA NA NA
.0 11.0 10.0| 6.5 7.5 .5| NA NA NA
.3 10.8 9.5| 6.5 6.1 .8| NA NA NA
.8 10.3 9.5| 6.2 8.2 7.2| NA NA NA
I

TIME



Start Stop
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440

KILN EXIT
Oxygen
Concentration
Carbon Dioxide
Concentration
Carbon Monoxide
Concentration
(* Dry as Mas'd) | (« Dry is Mas'd) j (* Dry as Mas'd)


-
Min Max Mean) Hin Max Mean) Min Max Mean
NA NA NA
NA NA NA
NA NA NA | NA NA NA
NA NA NA
NA NA NA
NA NA NA | NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
6.3 14.8 10.5| 3.3 5.6 4.5| NA NA NA
12.3 14.8 13.5| .6 .1 4.9| NA NA NA
12.0 15.0 13. 5| .4 .5 6.0| NA NA NA
13.0 15.3 14. 1| .5 .0 4.8| NA NA NA
13.0 16.3 14. 1| .4 .8 4.6| NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

.7 .2 5.0| NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

STACK
Oxygen
Concentration
Carbon Dioxide
Concentration
(* Dry as Mas'd) |(* Dry as Mas'd)
1
Min Max Mean) Min Max Mean
NA NA NA NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
Carbon Monoxide
Concentration
(% Dry as Mas'd)

Mm Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA .2 7.0 .6| NA NA NA
9.5 11. 10.5| .4 7.2 .3| NA NA NA
9.3 11. 10. 3| .5 7.4 .5| NA NA NA
9.8 11. 10.8| .5 7.0 .3| NA NA NA
9.5 12. 10.9| .3 7.3 .8
NA NA NA
10.0 11. 10. 9| .9 6.9 .9| NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

NA NA NA NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
1'
NA • Data not taken

-------
                                            Gas Concentration  on August  13,  1986
TIME
Start Stop
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1500
AFTERBURNER EXIT
Oxygtn | Carbon Dioxide | Carbon Monoxide
Concentration j Concentration j Concentration
(* Dry a* swas'd)|(* Dry M Mas'd)|(t Dry as Mas'd)
1 1
Min MX Nean| Kin Max Mean) M1n H«x Mean
.
i.O 7.3
Z.5 7.8
.5 .0
.5 .3
.0 .0
.0 .0
.0 .3
.0 .3
.3 10.0
.0 9.8
.5 19.8 1
.0 9.S
.0 10.0
.5 10.0
.0 9.S
.8 10.0
.5 10.3
.1| 8.5 10.0
.1| 8.2 10.0
.3| 8.6 10.0
.9| 8.7 10.0
.0| 8.3 10.0
.5| 8.5 10.0
.1| 8.3 10.0
.6| 7.7 10.0
.1) 8.0 10.0
.9) 7.9 10.0
.1| 6.3 10.0
.8| 8.1 10.0
.0| 7.6 10.0
.3| 7.6 10.0
.8) 7.6 10.0
r.9| 8.0 10.0
l.4| 7.4 10.0
1
.3| NA NA HA
.2| HA MA NA
.3| NA NA NA
.4) NA NA NA
.2| NA NA NA
.3| NA NA NA
.2| NA NA NA
.9| NA NA NA
,0| NA NA NA
.0| NA NA NA
.2) NA NA NA
.1| NA NA NA
.6) NA NA NA
.8| NA NA NA
.9| NA NA NA
.0| NA NA NA
.7| NA NA NA
1
1
CARBON BED INLET |
Oxygtn | Carbon Dioxide I Carbon Monxide
Concentration j Concentration j Concentration
(* Dry M awas'd) j (k Dry as Mas'd) |(* Dry as Mas'd)
1 1
Mln Max Mean) Hln Max Hean| Hin Max Mean
1
1
1
1
1
1
1.0 9.5
r.8 10.3
1.6 10.5
r.o 10.0
r.6 10.0
.8 9.5
.0 10.8
.5 10.3
.5 10.6
.3 10.3
.3 10.3
.5 10.5 11
.5 10.0
.0 11.5 1
.6| 1
.01 :
.6| 1
.5|
••1
.S|
• •I
•«l
• 51
.91
•3|
3.0|
l.3|
).3|
S.9 8.3 7.1| NA NA NA
t.S 6.0 5.3J NA NA NA
!.4 7.4 6.4| NA NA NA
.6 7.1 6.4| NA NA NA
.6 6.3 7.0| NA NA NA
.0 7.8 6.9| NA NA NA
.1 7.6 .3| NA NA NA
.4 7.t .3| NA NA NA
.2 7.3 .3| NA NA NA
.3 7.4 .4| NA NA NA
.6 .4 .5| NA NA NA
.3 .2 .3| NA NA NA
.2 .0 .1| NA NA NA
5.3 .0 .21 NA NA NA
.3 11.3 10.3| 4.7 .7 5.7| NA NA NA
1 1

TIME


Start Stop
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1600

KILN EXIT
Oxygen
Concentration
(* Dry as e*as'd)
Mln Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

Carbon Dioxide
Concentration
(* Dry as aeas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

Carbon Monoxide
Concentration
(* Dry as awas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
STACK
Oxygen
Concentration
(* Dry as aeas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
1
Carbon Dioxide
Concentration
(t Dry as Mas'd)
Mm Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

Carbon Monxide
Concentration
(X Dry as Beas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
.0 6.3 6.7|
.2 7.0 6.6|
.0 7.7 7.0|
.5 7.6 1.11
.0 7.S 6.6
.7 7.9 7.3
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA

NA - Data not taken

-------
                                            Gas Concent™ ft on on August  14,  1986

TIME



Start Stop
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
AFTERBURNER EXIT
Oxygen | Carbon Dioxide | Carbon Monoxide
Concentration j Concentration | Concentr*tion
(* Dry as •eas'd)|(k Dry as Mas'd) j(* Dry as Mas'd)
1 1
Win Max Mean| Min Max Mean| Hin Max Mean
4.5 6.0 .3|
4.0 T.5 .8|
5.0
6.0
4.8
5.0
S S
6.0
6.5
6.0
6.8
5.5
7.0
.0 .5|
.0 .0|
.5 .1|
.0 .5|
.5 .5)
.0 T.5|
.8 7.6|
.5 7.3|
.8 7.3|
.3 6.9|
.0 7.9)
NA NA NA |
.1 10.0
.0 10.0
.0 10.0
.0 10.0
.7 10.0
.4 10.0
.1 10.0
.6 10.0
.8 10.0
.9 10.0
.3 10.0
.2 10.0
.7 10.0
.1 10.0
.6| NA NA NA
.5| NA NA NA
.5| NA NA NA
.S| NA NA NA
.9| NA NA NA
.7| NA NA HA
.6| NA NA NA
.3| NA NA NA
.4| NA NA NA
.5 1 NA NA NA
,7| NA NA NA
.6| NA NA NA
.4| NA NA NA
.6| NA NA NA
NA NA NA j NA NA NA | NA NA NA
1440 1500 JNA NA NA | NA MA NA | NA NA NA
1 1 1
CARBON BED INLET
Oxygen | Carbon Dioxide | Carbon Monoxide
Concentration j Concentration j Concentration
(* Dry as Mas'd)|(* Dry as Mas'd)|(» Dry as neas'd)
1 1
Min Max Meanj Min Max Mean| Min Max Mean
6.0 10.0
7.1
8.:
7.1
7.:
7.1
7.!
7.
7.
8.
7.
7.
8.
1
1
»
1
I
!






.3
.3
.3
.6
.5
.8
.3
.3
.3
.0
.3
.8
• 0|
•5|
•«l
.3|
•0|
• 11
• «l
• 5|
• 5|
•»l
.31
.51
•0|
NA NA NA |
.2 .1 6.7| NA NA NA
.6 .4 7.5| NA NA NA
.6 . 7.5J NA NA NA
.7 . 7.3J NA NA NA
.0 . 7.6| NA NA NA
.2 . 7.9J NA NA NA
7.6J NA NA NA
7.3J NA NA NA
7.2| NA NA NA
7. 3 j NA NA NA
7.6| NA NA NA
.0 . 7.7) NA NA NA
.7 7.7 7.2| NA NA NA
.7 7.4 7.1| NA NA NA
NA NA NA | NA NA NA | NA NA NA
NA NA NA | NA NA NA | NA NA NA
" 1

TIME



Start Stop
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1500
KILN EXIT
Oxygen
Concentration
(\ Dry as Mas'd)

Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Carbon Dioxide
Concentration
(* Dry as Mas'd)

Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA MA NA
NA NA NA
NA NA NA
STACK
Carbon Monoxide Oxygen
Concentration Concentration
(* Dry as Mas'd) (* Dry as Mas'd)

Min Max Mean Min Mix Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
4.0 12.0 8.0 5.4 7.4 6.4| NA NA NA
9.5 13.0 11.3 6.7 0. 5 7.6
NA NA NA
8.6 11.6 10.1 7.1 9.6 6.3| iw 11* n*
NA NA NA
NA MA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA VA NA
Carbon Dioxide
Concentration
(* Dry as Mas'd)

Hin Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Carbon Monoxide
Concentration
(t Dry as Mas'd)

Nin Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA NA NA NA
NA NA NA NA NA NA
8.3 tS.O 9.1| 6.7 7.9 7.3| NA NA NA
8.5 9.5 9.0J 6.1 7.4 6.8J NA NA NA
Jm «um m • Kl C J T T VI) *** **A u*
• 0 INT* v * * ' 1 • • ** f*( < • i
i
t!**j VWM f*M
MA - Data not taken

-------
                                            Gas Concentration on August 28, 1986
TIME
Stirt Step
•00 920
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 144S
AFTERBURNER EXIT
Oxygtn Carbon 01 ox Id* | Carbon Monoxide
Concentration Concentration j Concentration
(k Dry as awas'd) (* Dry as a*as'd)|(* Dry as a*as'd)
1
Mln
»
•
•
.1
10.1

T1HE
Start Stop
900 920
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1445
Max Man H1n Max Mean) M1n Max Man
12.0 10. 9| T.2 10.0 .61
11. 8 10. 5| .3 10.0 .1
11.0 10. 4| .3 10.0 .2
11.3 10. 4| .1 10.0 .1
10.8 10. 3| .8 10.0 .4
10.3 10. 0| .7 9.9 .3
10.8 10.0| .7 10.0 .4
11.3 10.3| .3 10.0 .2
11.0 10.3| .1 10.0 .1
10.8 9.9| .1 10.0 .1
10.3 9.9| .5 10.0 .3
10.8 10.2| .7 10.0 .4
10.0 9.4| .3 10.0 .1|
10.8 9.8| .4 10.0 .2
5 11.0 10. 3| .3 10.0 .2
) 10.8 10. 4| .9 10.0 .5
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
CARBON BED INLET
Oxygen Carbon Dioxide
Concentration | Concentration
(* Dry as Mas'd) |(* Dry as Mas'd)
Min Max Meanf Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA HA
NA HA HA
HA HA NA
NA NA NA
NA NA HA
HA HA HA
NA NA NA
NA HA HA
NA NA NA
NA HA HA
HA NA NA
HA HA NA
HA NA HA
10.0 10. S 10.3
10.0 10. • 10.4

KILN EXIT
Oxygen
Concentration
(* Dry as Mas'd)
Min
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Max Mean
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
Carbon Dioxide
Concentration
(* Dry as Mas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Carbon Monoxide
Concentration
(I Dry as Mas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA HA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA
HA HA NA
HA HA NA
NA MA HA
HA NA HA
NA NA NA
HA HA HA
HA HA NA
HA HA NA
HA HA NA
HA HA NA
HA HA NA
HA HA NA
6.6 6.9 6.9
6.1 7.6 6.9
Carbon Monoxide
Concentration
(* Dry as Mas'd)
Min Max Mean
MA NA NA
NA NA HA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
| NA NA NA
| NA NA NA i

STACK
Oxygen Carbon Dioxide Carbon Monoxide
Concentration j Concentration j Concentration
(* Dry as Mas'd) |(% Dry as Mas'd)|(* Dry as atas'd)
1
Hin Max Mean) Min Max Mean) Min Max Mean

1.3 .8 7.S| S.I .7 S.9
6.8 .3 7.0| 4.9 .9 5.9
7.0 .8 7.9| S.6 .5 6.1
8.8 .5 7.7| 5.9 .7 6.3
6.8 .3 7.5| .9 6.9 6.4
6.6 .3 7.5| .9 7.1 6.S
7.0 .3 8.4| .6 7.1 6.4
7.5 .3 8.4| .1 7.1 6.6
7.6 9.3 8.51 .5 6.9 6.2

8.6 10.0 9.4| .9 7.0 6.5
9.5 10.8 10.1J .5 7.1 6.3
9.5 11.0 10.3J .6 6.4 6.3
HA HA HA NA NA NA
| NA NA NA
| NA NA NA
| NA NA NA
| NA NA NA
| NA NA NA
NA NA NA
j NA NA NA
j NA NA NA
| HA NA NA
| NA NA NA
| NA NA NA |
| NA NA NA '
| NA NA NA
| NA NA NA
| NA NA NA
| NA NA NA
| NA NA NA
NA NA NA
NA - Data not taken

-------
                                           Oas Concentration on September 3,  1986

TIKE


Start Stop
900 920
920 9*0
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1SOO
1500 1520
AFTERBURNER EXIT
Oxygen | Carbon Dioxide | Carbon Honoxide
Concentration | Concentration j Concentration
(* Dry as Mas'd) j(* Dry as Mas'd) |{* Dry as Mas'd)
1 1
M1n Max Mean | Min Max Mean| Mm Max Mean



















.8 7.8
.5
.5
.3
.0
.3
•
M
.3
,0
.8
.0
•
.3
.8
.0
.3
.0
.3
.3
.0
.5
.8
.3
.3
.3
.3
.0
.8
.8
.3
.8
«
.3|
•«l
• 3|
•4|
• 9|
• 31
.3|
.0|
•3|
.0|
• 8|
•9|
•3|
.0|
.01
.3 7.1|
.3 9.3|
.5 7.3|
.4 10.0
.9 10.0
.1 10.0
.1 10.0
.1 10.0
.9 10.0
.0 10.0
.0 10.0
.9 10.0
.0 10.0
.1 10.0
.9 10.0
.9 10.0
.7 10.0
.7 10.0
.8 10.0
.0 10.0
.1 10.0
.7 1 NA NA NA
,1| NA NA NA
,2| NA NA NA
. 1 1 NA NA NA
.4 1 NA NA NA
.3| NA NA NA
.4| NA NA NA
.2 1 NA NA NA
.1| NA NA NA
.1| NA NA NA
.3| NA NA NA
,4| NA NA NA
.2| NA NA NA
.1| NA NA NA
.2| NA NA NA
.2| NA NA NA
.2| NA NA NA
.5| NA NA NA
.0 7.1 1 NA NA NA | NA NA NA
I I
CARBON BED INLET
Oxygen
Concentration
(* Dry as Mas'd)
-
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA . NA
NA NA NA
NA NA NA
NA NA NA
Carbon Dioxide
Concentration
(* Dry as Mas'd)
M1n Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
Carbon Honoxide
Concentration
(* Dry as Beas'd)
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
10.0 .4| .0 6.7 .4| NA NA NA
10.0 .4| .1 7.4 .8| NA NA NA
10.0 .4| .1 7.4 .8| NA NA NA
10.0 .5| .2 7.3 .8| NA NA NA
10.8 .8| .1 6.3 .2| NA NA NA
7. 10.8 .3J NA NA NA
1
NA NA NA
1

TINE



Start Stop
900 920
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440
1440 1500
1500 1620
KILN EXIT
Oxygen
Carbon Dioxide
Concentration | Concentration
(* Dry as Mas'd) |(X Dry as Mas'd)
1
Min Max Mean] Min Max Mean
NA NA NA
NA NA NA
HA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA
NA NA HA
NA HA NA
NA HA HA
HA HA NA
HA NA NA
HA NA NA
NA NA NA
NA NA NA
NA HA NA
NA NA NA
NA NA HA
NA HA HA
NA NA HA
NA NA HA
NA NA NA
HA NA NA
NA NA NA
NA HA NA
NA HA NA
HA HA NA
NA NA NA
NA NA NA
NA NA HA
Carbon Monoxide
Concentration
(* Dry as Mas'd)
-
Min Max Mean
NA NA NA
NA NA NA
NA NA NA
HA NA NA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA HA
HA NA NA
NA NA NA
NA NA NA
NA NA NA
NA HA NA




STACK
Oxygen
Concentration
Carbon
Dioxide
Concentration
Carbon Monoxide
Concentration
(* Dry as Mas'd) |(X Dry as Mas'd) |(t Dry as Mas'd)



Min Max Mein| Min Max Mean















•

.

.
.
.
.
.
,
.
.
•
12.3 10.9|
13.5 11.6|
10.3 10.0)
10.5 10.0)
10.5 10.0|
10.5 10.1)
10.5 10|
10.5 9.9|
10.8 10.1J
10.5 9.9|
10.8 10. 0|
10.5 9.9|
10.5 9.4J
10.8 9.9|
NA NA HA
HA HA HA
NA NA NA
NA NA NA
NA NA HA
.7
.3
. 1
.1
.1
.0
.0
.0
.7
.0
.8 5.8
.9
.0
.1
.0
.9
.9
.2
.9
.0
.0 7.0
.1 7.0
.0 7.0
.8 7.7

Min Max Mean
NA NA NA
.6| NA NA NA
.6| NA NA NA
.6) NA NA NA
.6| NA NA NA
.5) NA NA NA
.5| NA NA NA
.6| NA NA NA
.8| NA NA NA
.5| NA NA NA
.5| NA NA NA
.6| NA NA NA
.5| NA NA NA
.9
NA NA NA
NA HA NA
NA NA NA
NA HA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA NA NA
NA - Data not takwi

-------
                                            Gas Concentration on September 4,  1986

TIME



St»rt Stop
900 920
920 940
940 1000
1000 1020
1020 1040
1040 1100
1100 1120
1120 1140
1140 1200
1200 1220
1220 1240
1240 1300
1300 1320
1320 1340
1340 1400
1400 1420
1420 1440

AFTERBURNER EXIT
Oxygen | C»rbon Dioxide | Carbon Monoxide
Concentration j Concentration | Concentration
(* Dry as »eas'd)|(* Dry as «««s'd)|(X Dry as Meas'd)
1 1
Hin Max Mean] Min Max Mean| Min Max Mean
4.5 5.3 4.9| 7.4 10.0 9.7| NA HA NA
S.3 .5 S.9| 9.3 10.0 10. 0| NA NA NA
S.3 .3 $.8| 10.0 10.0 10.0| NA NA NA












.5 .3 6.9|
.8 .3
.8 .5
.5 .8
.0 7.3
.3 7.3
.3 7.3
.5 7.3
.3 7.0
.3 7.0
.0 6.8
.0 6.5
S.8 6.5
5.8 6.5
•0|
.11
•1|
•«l
••1
• •1
•
-------
               E-DUCT 02 7-21-86
                                                                      KILN  O2 7-21-86
    10
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-------
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-------
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-------
          E-DUCT CO2 7-28-86
     KILN C02 7-28-86
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-------
            E-DUCT  O2 7-29-86
                                                                   KILN  02  7-29-86
                                                      21
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-------
          E-DUCT CO2 7-29-86
           KILN  CO2  7-29-36
 1000
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-------
            E-DUCT  O2 8-4-86
     KILN O2 8-4-86
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-------
           E-DUCT  C02 8-4-86
                                                                         KILN  CO2  8-4-86
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-------
                 E-DUCT  O2 8-5-86
                                                                     KILN  O2 8-5-86
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-------
          E-DUCT C02 8-5-86
KILN CO2 8-5-86
                                                  11


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-------
                E-DUCT O2  8-7-86
                                                                    KILN  O2 8-7-86
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-------
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-------
                 E-DUCT  O2  8-12-86
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-------
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-------
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-------
                       E-DUCT  O2  8-14-86
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-------
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-------
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-------
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-------
                                     E-DUCT 02  9-04-86
                         10
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-------
        Table  - . Schedule of Vest, Method 5, And Modified Method 5 Sampling
Feed
Material
Surface
Oil
• Soil
Soil
And
Sludge
Mixture
Sludge
Date
7-21-86
7-28
7-29
8-04
8-05
8-07
8-12
8-13
8-14
8-28
9-03
9-04
Stack
MS
NO
NO
NO
1324-1432
1105-1217
1000-1106
1002-1108
1000-1108
1015-1121
945-1055
940-1042
930-1032
E-Duct
VOST MM5
1203-1233
1410-1430
1610-1630
1111-1132
1330-1350
1530-1550
1407-1427
1610-1630
1805-1825
1328-1348
1500-1528
1630-1650
1111-1137
1318-1338
1410-1430
1000-1022
1135-1156
1330-1350
1001-1027
1138-1158
1200-1320
1001-1021
1136-1201
1330-1350
1015-1040
1206-1237
1330-1356
NO
940-1000
1200-1220
1330-1449
930-950
1120-1140
1330-1350
1203-1722
1114-1622
1405-1916
1324-1735
1100-1528
1000-1410
1004-1441
1001-1439
1015-1453
951-1455
940-1446
930-1429
Afterburner
M5
1157-1307
1119-1245
1415-1623
1320-1420
1105-1214
1000-1100
1006-1135
1000-1116
1015-1126
955-1120
951-1108
937-1044
*  - 2400 Clock Time
NO - No Data

-------
TluB Sas Flow Rates for Kiln PCB Trial Burr a»d
Tests
Location

Surf act Oil 7-81
7-28
7-2S
Soil B-A
8-5
8-7
Soil * Slucce 6-12
6-13
8-14
Slucce 6-26
5-3
9-4
Flue Flew Ra
Scrubber
26. 4
22.2
16. 9
16.3
15.8
22.6
24.0
24.1
20.9
24.4
24.9
25.5
te (dscn/iin)
Stack
*t
H
«
IS. 4
16.2
20. £
22. S
24.8
20.4
22.5
25.0
28.8 !
Flue Flo* !«aj
StruSaer
532
1137
e&
574
557
TSc
847
850
737
860
661
BS9
ie (ssc*»)
i
Stae< '
1
I
« :
i
t* !
I
** !
t
6ft !
f
rr< •
to ' A '
7c5
8:0 '
670
721
7r2
6£2
10:7

-------
    APPENDIX E



ANALYTICAL REPORTS
         E-l

-------
   ACUREX
   Corporation
                                                        Energy & Environmental Division

                                                             page 1 of 15

 October  10,  1986                                            Distribution:
 Dr.  Larry  R.  Waterland                                      Johannes Lee
 Program  Manager                                              Jerry Lewis
 US  EPA Combustion  Research Facility (CRF)                    Ralph Vocque
 c/o NCTR.  Building 45
 Jefferson, Arkansas  72079


 Subject:     VOST Analytical  Results

 Reference:   EPA  Contract  68-03-3267


 Dear Dr. Waterland:

      The  tables which follow  summarize the results of analyses  performed on
 Volatile Organic Sampling Trains  (VOST) taken at the CRF between July 8, 1986
 and September 4, 1986.  These  data  are  associated with the performance of the
 rotary kiln  system  during incineration  of  the following:  Askarel + Auto Dry;
 BROS surface oil;  BROS soil: BROS soil  - sludge and BROS sludge.

      Sampling and  analysis  were performed in general  accordance with
 "Protocol For The  Collection And Analysis  Of Volatile  POHC'S Using VOST", EPA-
 600/8-84-007. March 1984.  Variations  from this protocol are documented in
 "Proceedings of the Eleventh Annual Research Symposium:   Incineration and
 Treatment of Hazardous  Waste",  EPA/600/9-85/028,  September 1985, pages 252-
 260.
Sincerely
Robert W. Ross, II
Senior Chemist
              NCTR. Building 45. Jefferson, AR 72079  (501)541-0004  FAX. (501) 536-6446
    555 Clyde Avenue. P.O Box 7555. Mountain View. CA 94039 (415) 964-3200 Telex. 34-6391 TWX. 910-7796593

-------
ABLE 8.  COMPOUNDS ROUTINELY  DETERMINED  IN  VOST SAMPLES
Compounds
Mtthyltne Chloride
1 ,1-D1 chloroethjrlene
1,1-01 chl orethane
trans-1, 2-01 chl oroethylene
Chloroform
1 ,2-01 chl oroethane*
2-butanone
1,1,1-Trl chl oroethane
Carbon Tetrachloride
Brooodl chl oronethane
1 ,2-Di chl oropropanc
trans-1 ,3-01 chl oropropene
Trtchloroethylene
Benzene
1 .1 ,2-Tr1 chl oroethane*
Chl orodl bronomethane
Hexane
Browforai •
Tetrachloroethylene*
1 ,1 .2 ,2-Tet rachl oroethane
1so-octane
Toluene*
Hepane
Chlorobenzene
Octane
1 ,3-01 chl orobenzen*
1 ,2-01 chl orobenzene
1,4-tH Chlorobenzene
Abbreviation
H/C
1,1-DCEENE
1,1-DCCANE
t-l,2-DCE£NE
Chloroform
1,2-DCCANE
2B
1.1.1-TCEANE
CC14
BOCM
1.2-DCPRAHE
t-1.3-DCPRENE
C13-EENE
BZ
1,1,2-TCEANE
CDBM
HEX
BroBofom
CU-EENE/ANE
1$o-octane
Tol
Hep
Cl-BZ
Octane
1.3-DCBZ
1,2-OCBZ
1.4-DCBZ
        Total of 28 co^ounds
        * Elute at sa«e  retention t1
                            41

-------
                      TABLE 3.  VOST ANALYSIS (Total ug/Train)

                          JULY 21,  1986 -   BROS  SURFACE  OIL
COMPOUNDS
M/C
1,1-DCEENE
1,1-DCEANE
T-1,2-DCEENE
CHLOROFORM
1,2-DCEANE+2B
1,1,1-TCEANE
CC14
BOCM
1,2-DCPRANE
T-1.3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1,3-DCBZ
1,2-OCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E0721 1203V
-B-
-B-
-B-
-B-
-B-
-B-
-B-
.102
-B-
-B-
-B-
-B-
*68.3
-B-
-B-
-B-
.048
1560%
-B-
-B-
19«
-B-
-B-
-B-
E07211410V
-B-
-B-
-B-
-B-
-B-
-B-
-B-
.046
-B-
-B-
-B-
-B-
*1.96
-B-
-B-
-B-
.061
404*
-B-
-B-
5*
-B-
-B-
-B-
E07211610V
-B-
-B-
-B-
-B-
-B-
.279
-B-
*.224
-B-
-B-
-B-
-B-
*40.9
-B-
-B-
-B-
.101
1215%
.100
-B-
38«
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification liait
**   These compounds are internal standards.
The number reported is \ Recovery.

-------
                      TABLE 4.  VOST ANALYSIS (Total jig/Train)

                          JULY 28, 1986 -  BROS SURFACE OIL
COMPOUNDS
M/C
1,1-DCEENE
1,1-DCEANE
T-1.2-DCEENE
CHLOROFORM
1.2-OCEANE+2B
1,1,1-TCEANE
CC14
BOCM
1,2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE 4- ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1,3-DCBZ
1,2-OCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E07281111V
*2.29
-B-
-B-
-B-
.072
.104
-B-
*3.39
.096
-B-
-B-
-B-
.017
-B-
.111
.020
.069
134%
.110
-B-
104*
-B-
-B-
-B-
E07281330V
.634
-B-
-B-
-B-
.061
.216
-B-
*.726
-B-
-B-
-B-
-B-
.020
-B-
.129
.017
.044
192%
.058
-B-
108%
-B-
-B-
-B-
E07281530V
*11.9
-B-
-B-
-B-
.060
.050
-B-
*.311
-B-
-B-
-B-
-B-
-B-
-B-
.082
-B-
-B-
694k
-B-
-B-
72%
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification limit
**   These compounds are internal standards.  The number reported  is %  Recovery.

-------
                       TABLE 5.   VOST ANALYSIS  (Total ug/Train)

                          JULY 29, 1986 -  BROS SURFACE OIL
COMPOUNDS
M/C
1,1-DCEENE
1,1-DCEANE
T-1,2-DCEENE
CHLOROFORM
1,2-DCEANE+2B
1,1,1-TCEANE
CC14
BOCM
1,2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1 ,3-DCBZ
1,2-DCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E07291407V
.561
-B-
-B-
-B-
.183
-B- '
-B-
*.642
.146
.067
-B-
.089
.061
-B-
.026
-B-
*.402
568*
*1.84
.115
508*
*1.60
*1.48
-B-
E07291610V
.291
-B-
-B-
-B-
.077
*.608
-B-
*.579
-B-
-B-
-B-
-B-
-B-
-B-
.011
-B-
.105
114*
.097
-B-
161*
-B-
-B-
-B-
E07291805V
*.739
-B-
-B-
-B-
.207
*1.211
-B-
*.823
-B-
-B-
-B-
-B-
-B-
-B-
*.243
-B-
.193
189*
*.296
-B-
185*
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification liait
**   These compounds are internal standards.  The number reported is * Recovery.

-------
                      TABLE 6.  VOST ANALYSIS (Total jig/Train)

                             AUGUST 4,  1986 - BROS SOIL
COMPOUNDS
M/C
1,1-DCEENE
1 , 1 -DCEANE
T-1.2-DCEENE
CHLOROFORM
1.2-DCEANE+2B
1,1,1-TCEANE
ecu
BOCM
1,2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE *• ANE
ISO-OCTANE**
TOLUENE
Cl-BZ
OCTANE**
1,3-DCBZ
1,2-DCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E08041328V
*1.43
.018
-B-
-B-
.057
-B-
*.269
.189
-B-
-B-
-B-
-B-
-B-
-B-
*.138
-B-
.277
602%
*.278
-B-
81t
-B-
-B-
-B-
E0804 1500V
.380
-B-
-B-
-B-
.033
-B-
-B-
.110
.019
-8-
-B-
.009
.024
-B-
-B-
-B-
.213
66%
.124
-B-
106*
-B-
-B-
-B-
E08041630V
.458
-B-
-B-
-B-
.056
-•-
~9-
.171
-B-
-B-
-B-
.009
.026
-B-
.027
.116
.179
99%
.135
-B-
104%
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification limit
**   These compounds are internal standards.  The number reported is \ Recovery.

-------
                       TABLE 7.  VOST ANALYSIS  (Total ug/Train)

                             AUGUST 5, 1986 -  BROS SOIL
COMPOUNDS
M/C
1,1-DCEENE
1 , 1 -OCEANE
T-1,2-OCEENE
CHLOROFORM
1,2-DCEANE+2B
1,1,1-TCEANE
ecu
BOCM
1,2-DCPRANE
T-1,3-OCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1,3-DCBZ
1,2-DCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E08051111V
.196
-B-
-B-
-B-
.055 -
-B-
.003
.064
-B-
.010
-B-
-B-
.020
.020
.029
.088
.068
64*
.096
-B-
114*
-8-
-B-
-B-
E08051318V
.403
-B-
-B-
-B-
.049
-B-
-B-
.112
-B-
-B-
-B-
-B-
.026
-B-
.059
.141
.175
138*
.124
-B-
106*
-B-
-B-
-B-
E0805 1410V
.260
-B-
-B-
-B-
.039
-B-
-B-
.084
.015
-B-
-B-
-B-
.038
-B-
.017
-B-
.197
72*
.194
-B-
110*
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification  limit
**   These compounds are internal standards.  The number reported is * Recovery.

-------
                      TABLE 8.  VOST ANALYSIS (Total pg/Train)

                            AUGUST 7.  1986  -  BROS  SOIL
COMPOUNDS
M/C
1,1-DCEENE
1,1-DCEANE
T-1,2-DCEENE
CHLOROFORM
1.2-DCEANE+2B
1,1,1-TCEANE
CC14
BOCM
1,2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
Cl-BZ
OCTANE**
1,3-DCBZ
1,2-DCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E0807 1000V
*.8S9
.066
-B-
-B-
.094
-B-
.192
*.367
-B-
-B-
-B-
-B-
-B-
-B-
-B-
-B-
.237
93\
.212
-B-
50%
-B-
-B-
-B-
E08071135V
.455
.042
-B-
-B-
.087
*.861
-B-
*.189
-B-
-B-
-B-
-B-
.029
-B-
.015
.033
.250
172*
.179
-B-
114*
-8-
-B-
-B-
E08071330V
*.721
.021
-B-
-B-
.070
-B-
.048
*.307
-B-
-B-
-B-
-B-
-B-
-B-
.018
-B-
*.412
69*
.245
-fl-
ue*
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification limit
**   These compounds are internal standards.
The number reported is * Recovery.

-------
                       TABLE  9.  VOST ANALYSIS (Total ug/Train)

                       AUGUST 12,  1986 -  BROS SOIL PLUS SLUDGE
COMPOUNDS
M/C
1,1-DCEENE
1,1-DCEANE
T-1,2-DCEENE
CHLOROFORM
1,2-DCEANE+2B
1,1,1-TCEANE
CC14
BOCM
1,2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1,3-DCBZ
1,2-OCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E08121007V
*1.19
-B-
-B-
-B-
.060 .
-B-
.023
*.521
-B-
-B-
-B-
-B-
.023
-B-
-B-
-B-
-B-
75*
.116
-B-
iia
-B-
-B-
-B-
E08121138V
.586
-B-
-B-
-B-
.046
-B-
-8-
*.218
-8-
-8-
-B-
-B-
.008
-B-
.115
.055
.035
56*
.072
-B-
103*
-B-
-B-
-B-
E08121300V
*.860
-B-
-B-
-B-
.088
-B-
-B-
*.312
-B-
-B-
-B-
-B-
.050-
-B-
.214
.063
.095
52*
.086
-B-
54*
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification liMit
**   These compounds are Internal standards.
The number reported 1s * Recovery.

-------
                      TABLE 10.  VOST ANALYSIS (Total

                      AUGUST 13, 1986 -  BROS SOIL PLUS SLUDGE
COMPOUNDS
M/C
1,1-DCEENE
1,1-OCEANE
T-1,2-DCEENE
CHLOROFORM
1.2-DCEANE+2B
1,1,1-TCEANE
CC14
BOCM
1.2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1,3-DCBZ
1,2-OCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E08131001V
*3.53
-B-
-B-
-B-
.065 .
-B-
-B-
*.398
-B-
-B-
-B-
-B-
.020
-B-
*.230
.050
.050
62*
.045
-B-
90*
-B-
-B-
-B-
E08131136V
*9.04
-B-
-B-
-B-
.070
-B-
-B-
*.281
-B-
-B-
-B-
-B-
.018
-B-
*.150
-B-
.053
48*
.040
-B-
90*
-B-
-B-
-B-
E08 131 330V
*2.16
-B-
-B-
-B-
.204
-B-
-B-
*.449
-B-
-B-
-B-
-B-
.038
-B-
*.230
.109
.101
50*
.134
-B-
76*
-B-
-B-
-B-
*    Greater than calibration range
-6-  BelOH quantification liait
**   These compounds are internal standards.
The number reported is * Recovery.

-------
                      TABLE 11.  VOST ANALYSIS {Total ug/Train)

                      AUGUST  14,  1986  -  BROS SOIL PLUS SLUDGE
COMPOUNDS
M/C
1,1-OCEENE
1,1-DCEANE
T-1,2-OCEENE
CHLOROFORM
1.2-DCEANE+2B
1,1,1-TCEANE
CC14
BDCM
1,2-DCPRANE
T-1,3-OCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
Cl-BZ
OCTANE**
1.3-DCBZ
1,2-OCBZ
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E08U1015V
.507
-B-
-B-
-B-
.070
-B-
-B-
*.255
-B-
-B-
-B-
-B-
.024
-B-
.023
-B-
.110
62*
.116
-B-
112*
-B-
-B-
-B-
E08141206V
.332
-B-
-B-
-B-
.050
-B-
-B-
*.247
-B-
-B-
-8-
-B-
.026
-B-
.016
-B-
.132
62*
.082
-B-
99*
-B-
-B-
-B-
E08141330V
.317
-B-
-B-
-B-
.060
-B-
-B-
*.289
-B-
-B-
-B-
-B-
.061
-B-
.017
.047
.130
67*
.094
-B-
101*
-B-
-B-
-B-
*    Greater than calibration range
-B-  BeloM quantification liaiit
**   These compounds are internal standards.
The number reported is X Recovery.

-------
                      TABLE 12.  VOST ANALYSIS (Total  jig/Train)

                           AUGUST 28, 1986 -  BROS SLUDGE
COMPOUNDS
M/C
1,1-DCEENE
1,1-DCEANE
T-1,2-DCEENE
CHLOROFORM
1,2-DCEANE+2B
1,1,1-TCEANE
CC14
BDCM
1,2-DCPRANE
T-1,3-DCPREN
CL3-EENE
BENZENE
1,1,2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
Cl-BZ
OCTANE**
1,3-DCBZ
1,2-OC8Z
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.02S2
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E08281043V
*5.68
-B-
-B-
. -B-
*11.7
-B-
-B-
-B-
*52.3
-B-
-B-
*19.1
-B-
-B-
*3.92
-B-
-B-
5005%
-B-
-B-
7645%
-B-
-B-
-B-
E08281152V
.304
-B-
-8-
-B-
*.S20
-B-
-B-
.120
*3.19
.129
-B-
*.377
*4.41
-B-
*.212
-B-
-B-
130%
*1.84
.044
136%
-B-
-B-
-B-
*    Greater than calibration range
-6-  Below quantification  liait
**   These compounds are internal standards.
The number reported is \ Recovery.

-------
                      TABLE 13.  VOST ANALYSIS (Total jig/Train)

                          SEPTEMBER 3,  1986  -  BROS  SLUDGE
COMPOUNDS
M/C
1,1-DCEENE
1,1-OCEANE
T-1,2-DCEENE
CHLOROFORM
1.2-DCEANE+2B
1.1,1 -TCEANE
CC14
BDCM
1,2-DCPRANE
T-1.3-OCPREN
CL3-EENE
BENZENE
1,1, 2 -TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
Cl-BZ
OCTANE**
1,3-DCBZ
1,2-OC8Z
1,4-DCBZ
QUANTIFICATION
LIMIT
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
E09030940V
.084
-B-
-B-
-B-
.081
-B-
-B-
.127
-B-
.025
-B-
.051
.113
-B-
.075
-B-
.150
64*
.074
-B-
106*
-8-
-B-
-B-
E0903 1200V
.367
-B-
-B-
-B-
.086
-B-
-B-
.091
-B-
.042
-B-
.073
*.333
-B-
.092
-B-
.170
88*
.134
-B-
122*
-B-
-B-
-B-
E0903 1330V
.185
-B-
-B-
-B-
.175
-B-
-B-
.088
-B-
.018
-B-
.082
.053
-B-
*.383
-B-
.204
146*
.097
-B-
114*
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification H«it
**   These compounds are internal standards.  The number reported is * Recovery.

-------
                      TABLE 14.   VOST ANALYSIS (Total ug/Train)

                          SEPTEMBER 4, 1986 -  BROS SLUDGE
 COMPOUNDS
QUANTIFICATION
    LIMIT
E09040930V    EO9041120V
E09041330V
M/C
1,1-DCEENE
1,1-OCEANE
T-1,2-DCEENE
CHLOROFORM
1.2-DCEANE+2B
1,1.1-TCEANE
CC14
BOCM
1,2-DCPRANE
T-1,3-OCPREN
CL3-EENE
BENZENE
1,1.2-TCEANE
HEXANE
BROMOFORM
CL4-EENE + ANE
ISO-OCTANE**
TOLUENE
C1-BZ
OCTANE**
1,3-DCBZ
1,2-DCBZ
1,4-DCBZ
0.063
0.0126
0.0126
0.0126
0.0211
0.0253
0.0126
0.0126
0.0211
0.0126
0.0252
0.0126
0.0127
0.0337
0.0127
0.0211
0.0252
0.0127
0.0254
0.063
0.0127
0.063
0.063
0.063
.568
-B-
.140
-B-
*.258.
-B-
-B-
-B-
-B-
.026
-B-
.068
.151
-B-
.066
-B-
-B-
161*
.078
-B-
102%
-B-
-B-
-B-
*1.16
-B-
.037
-B-
.156
-B-
-B-
-B-
-B-
-B-
-B-
.041
.041
-B-
.045
-B-
-B-
102*
.038
-B-
100*
-B-
-B-
-B-
.059
-B-
.083
-B-
.146
-B-
-B-
-B-
-B-
.016
-B-
.039
.196
-B-
.025
-B-
-B-
134*
.062
-B-
100*
-B-
-B-
-B-
*    Greater than calibration range
-B-  Below quantification limit
**   These compounds are internal standards.
                       The number reported is % Recovery.

-------
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-------
  ACUREX
  Corporation
                                                       Energy & Environmental Division

                                                                        ]  of 3
October 3. 1986
Dr. Larry R. Waterland
Program Manager
US EPA Combustion Research Facility  (CRF)
c/o NCTR. Building 45
Jefferson, Arkansas 72079
Subject:          Chloride Analysis Results

Reference:        EPA Contract 68-03-3267


Dear Dr. Waterland:
      This communication summarizes the results of  chloride  analyses performed
on EPA Method 5 impinger catches taken at  the CRF between  July  8  and
September 4. 1986.  These data are associated with  the  performance of the
rotary kiln system during incineration of  the following:   Askarel  * Auto Dry;
BROS surface oil; BROS soil; BROS soil + sludge and BROS sludge.

      Measurements of chloride ion concentration were made with a  specific ion
electrode, calibrated on each analytical day at three levels which encompassed
those found in the samples.  Samples are identified as  specified  in the CRF
Quality Assurance Project Plan. August 15,  1986.  All values are  reported as
total mg HC1.

                            Sample
                          Identifier             «g HCL
                         S07081606I1              <3.7

                         S07081606I2              <2.2

                         S07081606I3              <2.1

                         S0709160311              <3.4

                         S07091603I2              <3.7

                         S07091603I3              <3.4

                         S07101325I1              <4.0

                         S07101325I2              <3.7

                         S07101325I3              <3.5
              NCTR. Building 45. Jefferson, AR 72079  (SOD 541-0004  FAX (501) 536-6446


    555 Clyde Avenue. PO Box 7555. Mountain View. CA 94039 (415) 964-3200 Telex 34-6391  TWX  910-7796593

-------
                                         page 2   of  3
  Sample
Identifier             jng HCL

A07211207I1              9.7
A07211207I2             <2.2
A07281116I1             14.2
A0728116I2              <2.2
A07291404I1             24.9
A07291404I2             <1.9

A08041319I1             26.3
A08041319I2             <1.8
A08051100I12            10.8
A08071001I12            12.6
S08041324I1             <4.2
S08041324I2             <5.1
S08051105I12            <6.5
S08071008I12            <7.6

A08121004I12            15.8
A08131001I12            21.8
A08141020I12            17.4
S08121002I123           <9.1
S08131000I123           <9.9
S08141015I123           <9.4

S08191150I              <8.8

A08280955I12            <4.8
A09030951I123            7.6
A09040937I123            5.2
S08280945I123           <9.3
S09030950I123           <10.3
S09040930I123           <9.9

-------
                                                                   page  3 of  3
Each batch of impinger collection meduim (0.1N sodium acetate)  used was
analyzed and found to contain <10 mg/L chloride,  the detection  limit of the
analytical method.
Sincerely,
R.W. Ross, II
Senior Chemist
RWR:Sf 048L
CC:  Johannes Lee
     Jerry Lewis
     Sharon King
                                                                                 •

-------
    IftftV W SAUaHAlTM. •- 3

     CMAIIIMAM Of TMt 10*110
                                 KCNNCTM S  WOODS
  GAIL. H MUTCMIN»
CXCUTIVI viet • rn««io«MT
                                                    VILMA
                                                    I»C««T»
                                                                                         RUSSCLL
                                                                i, Qnc.
   P O. BOX 4187
   2323 SYCAMORE OR.
QUANTITATIVE MICROANALYSES
       ORGANIC - INORGANIC
      KNOXVILJLC. TENNESSEE 37921
                         PHONE 546-1333
                         AREA CODE 615
            Mr. Ralph Vocque
            Acurex Corporation
            555 Clyde Avenue
            Post Office Box 7555
            Mountain View, California
       94039
                                           November 14, 1986
                 Received: Octooer 3rd
            Dear Mr. Vocque:

            Analysis of your compounds gave the following results:
            Your #,

            USEPA-CRF
            BU8141145
    Our #,       Total Metals in Filtrates,

    Q-6934     mg/liter Arsenic             < 0.2
                mg/liter Barium             0.37
                mg/liter Cadmium           < 0.1
                mg/liter Chromium          0.37
                mg/liter Lead               < 0.1
                mg/liter Mercury            < 0.2
                mg/liter Selenium            < 0.2
                mg/liter Silver              < 0.1


                Total Metals in Solids,

                ppm Arsenic                24
                ppm Barium                 507
                ppm Cadmium               49
                ppm Chromium              78
                ppm Lead                   8237
                ppm Mercury                < 15
                ppm Selenium               < 15
                ppm Silver                  < 15
LETTER AND SHIPMENTS BY U.S. MAIU . P O «OX 4187. OTHER CARRIERS - 2323 SYCAMORE OR.. KNOXVILLE. TN. 379S

                                         ESTABLISHED 19SO

-------
Mr. Ralph Vocque

November 14, 1986
Your #,


USEPA-CRF
B07211315  *
Our #,      Total Metals in Filtrates,

Q-6926      mg/liter Arsenic             < 0.2
            mg/liter Barium             0.58
            mg/liter Cadmium           < 0.1
            mg/liter Chromium          0.17
            mg/liter Lead               0.28
            mg/liter Mercury            < 0.2
            mg/liter Selenium           < 0.2
            mg/liter Silver              < 0.1
Your #,


USEPA-CRF
B07281335  *
Our#,


Q-6927
Your #,

 USEPA-CRF
 B07291645  *
Our f,

 Q-6928
Your #,

 USEPA-CRF
 B08041407  '
Our#,

 Q-6929
Total Metals in Filtrates,

mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium
mg/liter Lead
mg/liter Mercury
mg/liter Selenium
mg/liter Silver

Total Metals in Filtrates,

mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium
mg/liter Lead
mg/liter Mercury
mg/liter Selenium
mg/liter Silver

Total Metals in Filtrates,
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
                   < 0.2
                   0.43
                   < 0.1
                   0.20
                   0.73
                   < 0.2
                   < 0.2
                   < 0.1
                    < 0.2
                    0.61
                    < 0.1
                    < 0.1
                    1.10
                    < 0.2
                    < 0.2
                    < 0.1
< 0.2
0.30
< 0.1
0.18
2.58
< 0.2
< 0.2
< 0.1
   There were no Solids remaining from  filtering the blowdown water.
                         GALBRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986
 Your #,

USEPA-CRF
B08051325
 Our #,      Total Metals in Filtrates,

Q-6930      mg/liter Arsenic            < 0.2
            mg/liter Barium            Q.39
            mg/liter Cadmium          < Q.I
            mg/liter Chromium         Q.39
            mg/liter Lead              1.15
            mg/liter Mercury           < 0.2
            mg/liter Selenium          < 0.2
            mg/liter Silver             < o.i


            Total Metals in Solids,

            ppm Arsenic               < 26
            ppm Barium                877
            ppm Cadmium              < 26
            ppm Chromium             89
            ppm Lead                  1008
            ppm Mercury               < 26
            ppm Selenium              < 26
            ppm Silver                 < 26
Your #,

USEPA-CRF
B08071100
Our #,      Total Metals in Filtrates,

Q-6931      mg/liter Arsenic            < 0.2
            mg/liter Barium            0.29
            mg/liter Cadmium          < o.l
            mg/liter Chromium         0.29
            mg/liter Lead              0.14
            mg/liter Mercury           < 0.2
            mg/liter Selenium          < 0.2
            mg/liter Silver             < 0.1


            Total Metals in Solids,

            ppm Arsenic               < 60
            ppm Barium                1085
            ppm Cadmium              < 60
            ppm Chromium             119
            ppm Lead                  3787
            ppm Mercury               < 60
            ppm Selenium              < 60
            ppm Silver                 < 60
                        GALBRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986
Your f,

USEPA-CRF
B08121030
Our f,      Total Metals in Filtrates,

Q-6932      mg/liter Arsenic            < 0.2
            mgAiter Barium            0.35
            mg/liter Cadmium          < o.l
            mg/liter Chromium         o.26
            mg/liter Lead               o.l4
            mg/liter Mercury           < 0.2
            mgAiter Selenium           < 0.2
            mg/liter Silver             < o.l
                                 Total Metals in Solids,

                                 ppm Arsenic               < 23
                                 ppm Barium               737
                                 ppm Cadmium             < 23
                                 ppm Chromium             75
                                 ppm Lead                 2723
                                 ppm Mercury              < 23
                                 ppm Selenium              < 23
                                 ppm Silver                 < 23
Your #,

USEPA-CRF
B08131030
 Our #,      Total Metals in Filtrates,

Q-6933      mg/liter Arsenic            < 0.2
            mg/liter Barium            0.39
            mg/liter Cadmium          < 0.1
            mg/liter Chromium         0.31
            mg/liter Lead              0.11
            mg/liter Mercury           < 0.2
            mg/liter Selenium          < 0.2
            mg/liter Silver             < 0.1
                                 Total Metals in Solids,

                                 ppm Arsenic
                                 ppm Barium
                                 ppm Cadmium
                                 ppm Chromium
                                 ppm Lead
                                 ppm Mercury
                                 ppm Selenium
                                 ppm Silver
                                      < 35
                                      1206
                                      < 35
                                      66
                                      4065
                                      < 35
                                      < 35
                                      < 35
                                      < 35
                        GAUBRAITH LABORATORIES. INC. .

-------
 Mr. Ralph Vocque

 November 14, 1986
 Your #,'

USEPA-CRF
B08281005  *
 Our #,      Total Metals in Filtrates,

Q-6935       mg/liter Arsenic           < 0.2
             mg/liter Barium           0.29
             mg/liter Cadmium         < 0.1
             mg/liter Chromium        0.13
             mg/liter Lead              < 0.1
             mg/liter Mercury          < 0.2
             mg/liter Selenium          < 0.2
             mg/liter Silver            < 0.1
 Your #,

USEPA-CRF
B09031010  *
 Our #,

Q-6936
 Your #,

USEPA-CRF
B09041050  *
 Our #,

Q-6937
 Your #,

USEPA-CRF
B09241100BK *
 Our#,

Q-6938
Total Metals in Filtrates,

mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium
mg/liter Lead
mg/liter Mercury
mg/liter Selenium
mg/liter Silver

Total Metals in Filtrates,

mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium
mg/liter Lead
mg/liter Mercury
mg/liter Selenium
mg/liter Silver

Total Metals in Filtrates,
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
mg/liter
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
                  < 0.2
                  0.65
                  < 0.1
                  0.18
                                                              0.1
                                                              0.2
                                                              0.2
                                                              0.1
                  < 0.2
                  0.30
                  < 0.1
                  0.20
                  < 0.1
                  < 0.2
                  < 0.2
                  < 0.1
0.2
0.1
0.1
0.1
0.1
0.2
0.2
0.1
* There were no Solids remaining from filtering the blowdown water.
                        GALBMAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986
 Your #,

USEPA-CRF
B07281335SK
 Our #,      Total Metals in Filtrates,

Q-6939      mg/liter Arsenic           < 0.2
            mg/liter Barium            1.64
            mg/liter Cadmium          < 0.1
            mg/liter Chromium         4.73
            mg/liter Lead              11.39
            mg/liter Mercury           12.49
            mg/liter Selenium          < 0.2
            mg/liter Silver             < 0.1
                                  Total Metals in Solids,

                                  ppm Arsenic
                                  ppm Barium
                                  ppm Cadmium
                                  ppm Chromium
                                  ppm Lead
                                  ppm Mercury
                                  ppm Selenium
                                  ppm Silver
                                      < 26
                                      4771
                                      < 26
                                      9733
                                      46.41
                                      3.58
                                      < 26
                                      656
 Your #,

 USEPA-CRF
 B08131030SK
 Our #,     Total Metals in Filtrates,

 Q-6940     mg/liter Arsenic
            mg/liter Barium
            mg/liter Cadmium
            mg/liter Chromium
            mg/liter Lead
            mg/liter Mercury
            mg/liter Selenium
            mg/liter Silver


            Total Metals in Solids,

            ppm Arsenic
            ppm Barium
            ppm Cadmium
             %   Chromium
            %   Lead
            ppm Mercury
            ppm Selenium
            ppm Silver
< 0.2
< 0.1
< 0.1
< 0.1
32
3.69
< 0.2
< 0.1
                                                            131
                                                            108
                                                            < 11
                                                            3.83
                                                            38.67
                                                            571
                                                            < 11
                                                            145
                         GALBRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986
Your #,
Our #,
USEPA-CRF           Q-6941
T0828(09(3,4) 1200
Based on Leachate of Kiln Ash by EP Toxicitv
Test Procedure # 1310.
            mg/liter Arsenic
            mg/liter Barium
            mg/liter Cadmium
            mg/liter Chromium, Total
            mgAiter Lead
            mg/liter Mercury
            mg/liter Selenium
            mg/liter Silver


            Total Metals in Kiln Ash,

            ppm Arsenic
            ppm Barium
            ppm Cadmium
            ppm Chromium
            ppm Lead
            ppm Mercury
            ppm Selenium
            ppm Silver
                          < 0.1
                          < 0.1
                          < 0.1
                          < 0.1
                          0.12
                          < 0.1
                          < 0.1
                          < 0.1
                                                            < 2
                                                            632
                                                            < 2
                                                            113
                                                            796
                                                            < 2
                                                            < 2
                                                            < 2
Your*,
USEPA-CRF
T08141200
Our #,       Based on Leachate of Kiln Ash by EP Toxicity
            Test Procedure # 1310,

Q-6942      mg/liter Arsenic            < 0.1
            mg/liter Barium            0.43
            mg/liter Cadmium           < 0.1
            mg/liter Chromium, Total    < 0.1
            mg/liter-Lead               < 0.1
            mg/liter Mercury            < 0.1
            mg/liter Selenium           < 0.1
            mgAiter Silver              < 0.1

            Total Metals in Kiln Ash,

            ppm Arsenic                < 2
            ppm Barium                504
            ppm Cadmium              < 2
            ppm Chromium             66
            ppm Lead                  228
            ppm Mercury               < 2
            ppm Selenium               < 2
            ppm Silver                 < 2
                        GALBRAITH LABORATORIES. INC.

-------
Mr. Ralph Vocque

November 14, 1986
Your #,
USEPA-CRF
T08131200
Our #,


Q-6943
Based on Leachate of Kiln Ash by EP Toxicity
Test Procedure # 1310,
mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium, Total
mg/liter Lead
mg/liter Mercury
mg/liter Selenium
mg/liter Silver


Total Metals in Kiln Ash,

ppm Arsenic
ppm Barium
ppm Cadmium
ppm Chromium
ppm Lead
ppm Mercury
ppm Selenium
ppm Silver
< 0.1
0.43
                                                             0.1
                                                             0.1
                                                             0.1
                                                             0.1
                                                             0.1
                                                             0.1
                                                            < 2
                                                            983
                                                            < 2
                                                            97
                                                            382
                                                            < 2
                                                            < 2
                                                            < 2
Your #,
 USEPA-CRF
 T08071200
Our#,


 Q-6944
Based on Leachate of Kiln Ash by EP Toxicity
Test Procedure # 1310,
mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium, Total
mg/liter-Lead
mg/liter Mercury
mg/liter Selenium
mg/liter Silver

Total Metals in Kiln Ash,

ppm Arsenic
ppm Barium
ppm Cadmium
ppm Chromium
ppm Lead
ppm Mercury
ppm Selenium
ppm Silver
 < 0.1
 0.99
  0.1
  0.1
  0.1
  0.1
  0.1
  0.1
                                                            < 2
                                                            844
                                                            < 2
                                                            95
                                                            489
                                                            <2
                                                            < 2
                                                            <2
                         GALBMAITH LABORATORIES. INC.

-------
  Mr. Ralph Vocque

  November 14, 1986
  Your #,
USEPA-CRF
T08051200
  Our #,      Based on Leachate of Kiln Ash by EP Toxicity
             Test Procedure # 1310,

Q-6'J45       mg/liter Arsenic           <  0.1
             mg/liter Barium           0.10
             mg/liter Cadmium         <  0.1
             mg/liter Chromium, Total  <  0.1
             mg/liter Lead             <  0.1
             mg/liter Mercury          <  0.1
             mg/liter Selenium          <  0.1
             mg/liter Silver            >  0.1
                                  Total Metals in Kiln Ash,

                                  ppm Arsenic
                                  ppm Barium
                                  ppm Cadmium
                                  ppm Chromium
                                  ppm Lead
                                  ppm Mercury
                                  ppm Selenium
                                  ppm Silver
                                      < 2
                                      296
                                      < 2
                                      192
                                      1825
                                      < 2
                                      < 2
                                      < 2
 Your #,
USEPA-CRF
T08041200
 Our #,
Q-6946
Based on Leachate of Kiln Ash by EP Toxicity
Test Procedure # 1310,

mg/liter Arsenic           < o.l
mg/liter Barium           o.26
mg/liter Cadmium         < o.l
mg/liter Chromium, Total  < o.l
mg/liter-Lead             < 0.1
mg/liter Mercury          < 0.1
mg/liter Selenium         < 0.1
mg/liter Silver            < o.l

Total Metals in Kiln Ash,

ppm Arsenic              < 2
ppm Barium               498
ppm Cadmium             < 2
ppm Chromium            94
ppm Lead                 408
ppm Mercury             < 2
ppm Selenium             < 2
ppm Silver                < 2
                        QALBNAITH LABORATORIES. INC.

-------
Mr. Ralph Vocque

November 14, 1986
Your #,
Our#,
USEPA-CRF           Q-6947
707(21,28,29) 1200
Based on Leachate of Kiln Ash by EP Toxicity
Test Procedure # 1310,
           mg/liter Arsenic
           mg/liter Barium
           mg/liter Cadmium
           mg/liter Chromium, Total
           mg/liter Lead
           mg/liter Mercury
           mg/liter Selenium
           mg/liter Silver


           Total Metals in Kiln Ash,

           ppm Arsenic
           ppm Barium
           ppm Cadmium
           ppm Chromium
           ppm Lead
           ppm Mercury
           ppm Selenium
           ppm Silver
                          < 0.1
                          0.33
                          < 0.1
                          < 0.1
                          0.23
                          < 0.1
                                                            < 2
                                                            121
                                                            < 2
                                                            1088
                                                            2161
                                                            < 2
                                                            < 2
                                                            < 2
                         GALBRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986


 Your #,

USEPA-CRF
F0828(09)(3,4) 1200
 Our #,      Total Metals in Feed,

Q-6949      ppm Arsenic
            ppm Barium
            ppm Cadmium
            ppm Chromium
            ppm Lead
            ppm Mercury
            ppm Selenium
            ppm Silver
< 1
23
< 5
12
46
< 1
< 1
< 5
                                  Ultimate Analysis,

                                  % Carbon
                                  % Hydrogen
                                  % Nitrogen
                                  % Sulfur
                                  % Chlorine
                                  % Oxygen
                                      0.96
                                      11.12
                                      0.038
                                      0.99
                                      0.0094
                                      81.78
                                  Based on Leachate of Feed by EP Toxicity
                                  Test Procedure it 1310,
                                  mg/liter Arsenic
                                  mg/liter Barium
                                  mg/liter Cadmium
                                  mg/liter Chromium, Total
                                  mg/liter Lead
                                  mg/liter Mercury
                                  mg/liter Selenium
                                  mg/liter Silver
                                      0.19
                                        0.1
                                        0.1
                                        0.1
                                        0.1
                                        0.1
                                        0.1
                                        0.1
                         GALBRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986


 Your #,

USEPA-CRF
F08(4,5,7) 1200
 Our #,      Total Metals in Feed,

Q-6950      Ppm Arsenic               < 1
            ppm Barium               744
            ppm Cadmium             < 1
            ppm Chromium             55
            ppm Lead                 756
            ppm Mercury              < i
            ppm Selenium              < i
            ppm Silver                 < 5
                                  Ultimate Analysis,

                                  % Carbon
                                  % Hydrogen
                                  % Nitrogen
                                  % Sulfur
                                  % Chlorine
                                  % Oxygen
                                      11.35
                                      4.60
                                      0.099
                                      0.38
                                      0.037
                                      25.03
                                  Based on Leachate of Feed by EP Toxicity
                                  Test Procedure # 1310,

                                  mg/liter Arsenic            < 0.1
                                  mg/liter Barium            0.12
                                  mg/liter Cadmium          < 0.1
                                  mg/liter Chromium, Total   < 0.1
                                  mg/liter Lead              0.46
                                  mg/liter Mercury           < 0.1
                                  mg/liter Selenium          < 0.1
                                  mg/liter Silver             < 0.1
                         GALBftAITH LABORATORIES. INC.

-------
Mr. Ralph Vocque

November 14, 1986
   Your #,
 USEPA-CRF
 T08121200
  Our #,


Q-8049
Based on Leachate of Kiln Ash by EP Toxicity
Test Procedure # 1310,
mg/liter Arsenic
mg/liter Barium
mg/liter Cadmium
mg/liter Chromium, Total
mg/liter-Lead '
mg/liter Mercury
mg/liter Selenium
mgAiter Silver

Total Metals in Kiln Ash,

ppm Arsenic
ppm Barium
ppm Cadmium
ppm Chromium
ppm Lead
ppm Mercury
ppm Selenium
ppm Silver
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
                                                            < 2
                                                            738
                                                            < 2
                                                            99
                                                            767
                                                            < 2
                                                            < 2
                                                            < 2
                                                               PROTECTION
                                                                 AGENCY

                                                             DALLAS.  TEXAS
                         GALSRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986
 Your #,

USEPA-CRF
F08(12,13,14) 1200
Our #,      Total Metals in Feed,

           ppm Arsenic              11
           ppm Barium               823
           ppm Cadmium             4
           ppm Chromium            65
           ppm Lead                 1034
           ppm Mercury              < 1
           ppm Selenium              < 1
           ppm Silver                < 5
                                  Ultimate Analysis,

                                  % Carbon
                                  % Hydrogen
                                  % Nitrogen
                                  % Sulfur
                                  % Chlorine
                                  % Oxygen
                                      13.13
                                      4.67
                                      0.11
                                      0.43
                                      0.058
                                      32.29
                                  Based on Leachate of Feed by EP Toxicity
                                  Test Procedure # 1310,

                                  mg/liter Arsenic            < 0.1
                                  mg/liter Barium            0.30
                                  mg/liter Cadmium          < 0.1
                                  mg/liter Chromium, Total   < 0.1
                                  mg/liter Lead              0.12
                                  mg/liter Mercury           < 0.1
                                  mg/liter Selenium          < 0.1
                                  mg/liter Silver             < 0.1
                         GALBRAITH LABORATORIES. INC.

-------
 Mr. Ralph Vocque

 November 14, 1986


 Your #,

 USEPA-CRF
 F07(21,28,29) 1200
 Our #,      Total Metals in Feed,

Q-8050      ppm Arsenic            2
            ppm Barium             1035
            ppm Cadmium           < IQ
            ppm Chromium          45
            ppm Lead               2888
            ppm Mercury            < i
            ppm Selenium           < i
            ppm Silver              < 10
                                  Ultimate Analysis,

                                  % Carbon              54.53
                                  % Hydrogen            10.35
                                  % Nitrogen             0.085
                                  % Sulfur               o.69
                                  % Chlorine             o.lO
                                  % Oxygen              29.87

                                  Based on Leachate of Feed by EP Toxicity
                                  Test Procedure # 1310,
                                  mg/liter Arsenic
                                  mg/liter Barium
                                  mg/liter Cadmium
                                  mg/liter Chromium,
                                  mg/liter Lead
                                  mg/liter Mercury
                                  mg/liter Selenium
                                  mg/liter Silver
                                   < 0.1
                                   < 0.1
                                   < 0.1
                              Total< o.l
                                   < 0.1
                                   < 0.1
                                   < 0.1
                                   < 0.1
Sincerely yours,

GALBRATTH LABORATORIES, INC.
GaU R. Hutche
Exec. Vice-President

GRH:sc
                         GAURAITH LABORATORIES. INC.

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