600J88010
 TRICKLING FILTER/SOLIDS CONTACT PERFORMANCE
             WITH ROCK FILTERS  AT
             HIGH ORGANIC LOADINGS
                      by
              Raymond N.  Matasci
                David L.  Clark
               James A.  Heidman
               Denny S. Parker
                 Bruce Petrik
               Darrel Richards
Presented at the 59th Annual Conference of  the
      Water Pollution Control Federation
               October 9, 1986
            Los Angeles, California

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            TRICKLING FILTER/SOLIDS CONTACT  PERFORMANCE
                        WITH ROCK FILTERS AT
                        HIGH ORGANIC LOADINGS

                                 by

                         Raymond N. Matasci
                           David L. Clark
                          James A. Heidman
                          Denny  S. Parker
                            Bruce Petrik
                          Darrel  Richards


    The  trickling  filter process  was  formerly the  most  popular
method  for treating  municipal wastewater.   In  1975,  about  4,300
trickling  filter  plants were  operating in the United States,  which
was almost two times the number  of  activated sludge plants.    The
popularity  of  the  trickling  filter  process  declined  in the  1970s
and early  1980s  because  the  existing plants  were  often  exceeding
the newly  established secondary  treatment  standard  of 30  milligrams
per liter  (mg/1)  for  total  suspended solids  (TSS) and  5-day  bio-
chemical oxygen demand  (BOD^).

    Recent 4work  on  the  trickling  filter/solids  contact  (TF/SC)
process2'3' '  has  demonstrated  that trickling filters can  reliably
achieve  secondary treatment and  advanced  treatment standards  with
relatively simple plant modifications.  The  popularity of the  TF/SC
process  has  increased  dramatically  since  its  development  in  1979
because  it produces significantly better  effluent  than  the trick-
ling filter process alone.  The process  is applicable to  new plants
as well as existing trickling  filter plants.

    The U.S. Environmental Protection Agency  (USEPA) estimated  that
approximately  55  percent  of   the  existing  2,700  trickling filter
plants will  be upgraded  or abandoned  by the year  2000.     Many  of
these  changes  are  necessary  to  treat  increasing  plant loads  or
improve effluent  quality.  Substantial savings would be  realized  if
relatively  simple  modifications  could  enable  existing  trickling
filter  plants  to operate  at  higher  loads  with  greater  reliabi-
lity.   The TF/SC  process  is  an important topic of  study  because  it
shows  promise  for  producing   just   these  results—significant
improvements  in  effluent and  plant  reliability,  even  at higher
organic loadings.

Study Objectives

    Most of  the  operating trickling  filter  plants  use rock media.
To  test  TF/SC  performance  with  rock  filters at  high   organic

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loadings,  USEPA  sponsored  full-scale  studies  at  the  Morro Bay-
Cayucos  TF/SC  plant.    The  studies also  included  an assessment of
trickling   filter  performance  with   flocculator-clarifiers  and
reaction  rate  coefficients  for  soluble  carbonaceous BODr  (SCBODc)
removal  in rock trickling filters.

    The  studies  included 9 weeks  of  field investigations  at the
Morro  Bay-Cayucos facility  in Morro  Bay,  California.   The  field
investigations  data  were supplemented with operating records from
the  Morro  Bay-Cayucos  plant  and   from  plants  in  Coeur  d'Alene,
Idaho; Corvallis, Oregon; and Oconto Falls, Wisconsin.


            PLANT  FACILITIES AND EXPERIMENTAL PROCEDURES
    The  investigators conducted  full-scale  studies  at  the Morro
Bay-Cayucos plant  between March and June  1986.   The  plant .and the
experimental procedures are described below.

Plant Description

    The Morro  Bay-Cayucos plant is located on the Pacific  coast  in
central California.   The  original plant  was  constructed  in 1954.
It was  expanded in 1964  and  again in  1983.   The recent  expansion
was  designed  to comply  with the  1978  Water  Quality Control  Plan
for Ocean Waters of California.  In 1985,  the  City of Morro Bay and
Cayucos  Sanitary  District  obtained  a  waiver  of full   secondary
treatment  in  accordance  with  Section  301(h) of  the  1977 Clean
Water Act.

    The plant  uses split treatment  to  meet its discharge  require-
ments.   Figure 1  shows  the plant's flow  schematic.   Raw  influent
undergoes   preliminary   treatment   (screening  and   aerated   grit
removal)  and  then  primary sedimentation.  A portion of the primary
effluent  receives  secondary treatment  with the TF/SC process.  The
remaining  fraction of primary  effluent is  blended  with  secondary
effluent  and chlorinated  before discharge  to  the  ocean outfall.

    Table  1 lists  -the  plant's  design  data.   The Mode  III TF/SC
process,  which  includes   return sludge  aeration and aerated  solids
contact  provides   secondary  treatment.    The  two  rock  filters are
relatively  shallow with a mean  loading  of  750  grams per cubic meter
day  (g/irr-d)  [47 pounds per day per  1,000  cubic feet   (ppd/1,000  cu
ft)]  at  the secondary treatment  design flow  of  0.042 cubic  meters
per second  (nr/s)  [0.97 million gallons  per day  (mgd)].   The return
sludge aeration and aerated solids contact times  at design flow are
13 and 3.3 minutes, respectively.

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                                              RETURN SLUDGE
                                              AERATION
                                                 AERATED SOLIDS
                                                 CONTACT
      PRELIMINARY
      TREATMENT
  RAW

  INFLUENT
                                                FLOCCULATOR-
                                                CLARIFIER
                PRIMARY
              SEDIMENTATION
                 TANKS
                                                               OUTFALL
                         Figure 1. Plant Schematic
    The  secondary effluent  TSS for  the  TF/SC process  for the year
before  the  full-scale  studies is  shown  on  Figure  2.    The TF/SC
process  generally produced  effluent with TSS between 5  and 10 rag/1
at the design flow of about 0.043 m /s (1.0 mgd).   In August 1985,
the  plant  staff  changed operation from  split  treatment  to full
secondary  treatment.  The  average secondary effluent TSS increased
to  19  mg/1  when  the   secondary  flow  increased   50  percent  to
accommodate  full secondary treatment.

Experimental  Program

    The   plant   has  unusual   flexibility  because   of   its  split
treatment  feature.    This   flexibility allowed  the  study  team  to
conduct  relatively closely controlled  experiments  on the full-scale
secondary  treatment process.

    The  experimental  program  consisted   of   three  phases.    In
Phase 1, the  secondary process operated in the  TF/SC mode with both
rock  filters in  operation.    In  Phase  2, the  study team stopped
secondary  solids recirculation, and the secondary  process operated
in the  trickling  filter mode.   In  Phase  3,  the secondary process
operated  in  the TF/SC mode  with only one  filter to  determine TF/SC
performance  at  high organic loadings.

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                               Table  1.  Design Data
                          Parameter
                                                                   Value
    PLANT CAPACITY

     Flow, n3/s (ngd)
       Average dry-weather flow (ADWF)
       Peak seasonal dry-weather flow (PSDWF)
       Peak dry-weather  flow  (PDWF)
       Peak wet-weather  flow  (PWWF)
     Waste strength, iag/1
       Biochemical oxygen demand   (BODj)
       Total suspended solids  (TSS)

    PRIMARY TREATMENT

     Sedimentation tanks
       Number
       Diameter, m (ft)
         Tank 1
         Tank 2
     Average side water  depth, m tft)
     Overflow rate at PSDWF, m3/mz-d  (gpd/sq ft)

    TRICKLING FILTERS (in partial secondary
       treatment mode of operation)

     Flow distribution at PSDWF, raVs (ngd)
       Filter 1
       Filter 2
     Diameter, m (ft)
       Filter 1
       Filter 2
     Average media height, m  (ft)
       Filter 1
       Filter 2
     Hydraulic loading rate,  1/m -s  (gpm/sq ft)
       Filter 1
       Filter 2
     BODj loading rate,  g/m^-d  (ppd/1,000 cu ft)

    SOLIDS CONTACT CHANNEL

     Channel length, m (ft)
       Reaeration portion
       Contact portion
     Channel depth, m (ft)
     Channel width, m (ft)
     Reaeration time (based
     Aerated solids contact
       including 33 percent  return),  minutes

    SECONDARY CLARIFIER

     Diameter, m (ft)
     Average sidewater depth,  m  (ft)
     Overflow rate at PSDWF,  mj/n  -d  (gpd/sq ft)
on 33 percent return), minutes
time (based on total flow
                                 0.090
                                 0.103
                                 0.291
                                 0.289

                                   280
                                   280
                                    IS
                                    12
                                   2.7
                                  29.7
                                 0.017
                                 0.025

                                    18
                                    21

                                   1.4
                                   1.5

                                  0.23
                                  0.26
                                   750
7.6
7.6
1.2
1.2
 13

3.3
                                    17
                                   4.6
                                   16.6
           (2.06)
           (2.36)
           (6.64)
           (6.60)
             (50)
             (40)
              (9)
            (730)
           (0.39)
           (0.58)

             (60)
             (70)

            (4.5)
            (5.0)

           (0.34)
           (0.38)
             (47)
                                                 (25)
                                                 (25)
                                                  (4)
                                                  (4)
              (55)
              (15)
             (408)
     The  filter  organic  loading  for the  TF/SC process was  increased
from  480  g/m3-d   (30  ppd/1,000  cu   ft)  in  Phase  1  to  960  g/m  -d
(60 ppd/1,000  cu  ft)  in  Phase  3.   A study  of  63 trickling  filter

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plants  in  the northern United States showed that 86 percent of the

plants  had organic  loadings less the 960 g/m -d  (60  ppd/1,000 cu
ft) and 62  percent  had  loadings  less  than  480  g/nr-d  (30  ppd/
1,000 cu   ft).    Thus,  the  filter  organic  loadings  tested  at
the Morro  Bay-Cayucos  plant  are above  average  to  high values.
     30
o>

 •t

to
CO
H

H

UJ

-1
u.
u.
UJ
Q

o
o
HI
CO
20
      10
               SPLIT TREATMENT : SECONDARY FLOW

               r 1.0 mgd


               FULL SECONDARY TREATMENT:

               SECONDARY FLOW = 1.5 mgd
         MAR APR MAY JUN JUL AUQ SEP OCT NOV DEC JAN FEB


                       1985                          1986
     Figure 2. Secondary Effluent Suspended Solids at the Morro Bay-
             Cayucos TF/SC Plant

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The  filter  organic loading  rate  during Phase  2  (trickling filter
mode) was  445 g/nr-d (28  ppd/ 1,000 cu  ft).   Phases  1,  2,  and 3
lasted  4,  2-1/2,  and  3-1/2  weeks,  respectively.   The  study tean
allowed  1  to  2  weeks  between  phases  before  resuming  sampling  to
allow the secondary process to  equilibrate.

    Figure 3  shows  a  typical diurnal flow  curve  for plant inflow.
Plant inflow  varies significantly within each hour because of the
intermittent  operation  of  large  constant  speed  pumping  stations
nearby in the collection system.

    The  flow  controller ^Figure 3) maintains a flow to the filters
of approximately 0.043 nr/s  d  mgd)  at  all  times.   To maintain the
desired  filter wetting rate, the plant also  incorporates  recycle of
a fraction of unsettled  trickling filter effluent back through the
filters.   This  operating  approach kept  the  secondary  clarifier
overflow rates,  aerated  solids contact  times  (Phases 1 and.3), and
filter wetting  rates  at  consistent  levels  during  the three phases
of the study.

    The  primary  effluent  samples  were  taken downstream of  the flow
controller  thus  accounting  for  dilution  with  returned  secondary
effluent during  the low  flow  periods.   BOD^ and  TSS  analyses of
selected samples  (Figure  3)  during a  24-hour period  showed that
concentrations were slightly  lower  during periods  of  low inflow.
For the  purposes of this paper, the  term primary effluent refers to
the  trickling  filter  influent,   which  may  include  the  recycled
fraction of secondary effluent  during periods  of low  inflow.

Sampling and Analytical Procedures

    The  study team  used   refrigerated  automatic   ISCO  samplers  to
collect  24-hour  composited samples  of  primary effluent,  unsettled
trickling  filter effluent,  and secondary effluent  three days per
week.   The  composite sample collection  began  at  8:30 a.m. and was
completed  the following  morning.   The  treatment  plant staff col-
lected  grab   samples of  mixed  liquor  and  return  secondary sludge
during  the  days of  composite  sample collection.   The plant  staff
also  collected  a grab sample  of  secondary  effluent  near  the peak
daily flow  (10  a.m.) for  TSS  analysis.  The  study team and  plant
staff  used  a Secchi  disk  to measure clarity  of  the  secondary
effluent.

    The  field   investigators   packed  'all   composite   samples  and
grab samples  of mixed  liquor  and  return  secondary sludge  in an
ice chest and  shipped  them  by  bus  to  the  Brown  and  Caldwell
Pasadena laboratory for  analysis.  The  laboratory staff  analyzed
primary  effluent   and   secondary  effluent   for  TSS,   BOD5,  and
SCBOD5.  They analyzed  effluent from each trickling  filter for TSS
and SCBODc and the  mixed liquor and  return  secondary  sludge samples
for TSS  and volatile suspended  solids  (VSS).

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fi)
Saf
         SECONDARY TREATMENT PLOW
      8:30cm 9:30 10:30  11:30 12:30pm 1:30   2:30   3:30  4:30  8:30   8:30   7:30 8:30pm

                                  APRIL 18, 1988

    2OO
ce
a.'
    180


    100


     SO
,TSS
                       BOO
                                      PLANT INFLOW

                                        SECONDARY TREATMENT FLOW
                                                                          O
      8:30pm 9:30 10:30 11:30 12:30«n 1:30  2:30   3:30  4:30  5:30   8:30   7:30 8:30«m

             APRIL 18, 1988                     APRIL 19, 1988


        Figure 3.  Diurnal Flow and Variation  in Primary Effluent Quality
     Analytical determinations were  performed in accordance with the
 16th  edition  of   Standard  Methods.   The  laboratory  staff  used  a
 Whatman  934AH glass fiber  filter  to distinguish between particulate
 and  "soluble"  substances.    They  also  used  a  Hach  nitrification
 inhibitor  to measure  the carbonaceous  fraction of the soluble  BOD5
 samples.

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    The  study  team  determined  the  significance   o£  differences
with the _t_-test at  the  95-percent  confidence  level.    They  used
the modified  Velz  equation, to  compute K^Q values   and  a specific
surface value of 44.3 mvm  (13.5 ft /ft3) for the  rock media.

    Professor  David  Jenkins  and associates  at  the  University of
California at Berkeley performed microscopic examinations of  unset-
tled  trickling  filter  effluent and  solids  contact  tank samples.
They  characterized  floe  size and shape  and  identified  and quan-
tified filamentous organisms.


                           STUDY RESULTS


    Table  2   lists  the  results  of  the Morro  Bay-Cayucos studies.
Raw waste  concentrations  of  TSS and  BODc were significantly  higher
during Phase  3  than in Phases 1 and  2.  The significant increase in
primary effluent BODc during  Phase 3 seems to have  been caused  by  a
higher soluble  fraction.   Primary effluent TSS did not vary  signi-
ficantly between  phases,  yet the Phase  3 SCBOD^ was significantly
higher than in  the other two  phases.

Secondary Performance

    The  secondary  effluent   TSS  significantly  increased  15  mg/1
based  on  the  composite  samples and  10  mg/1  based on  the  grab
samples when  the  plant  switched from  the  TF/SC  mode to  the  trick-
ling  filter  mode.   When the filter  organic  loading increased to
960 g/m3-d  (60  ppd/1,000  cu  ft)   in the  TF/SC  mode,   the  mean
composite  secondary  effluent TSS  value  was  2  mg/1  higher  than
observed in  Phase  1 TF/SC operation,  although this  difference was
not  significant.     The  grab samples  of  secondary  effluent  TSS
indicated  a   slight   (4   mg/1),  but  statistically significant,
increase in secondary effluent TSS.

    The Secchi  depths shown  in Table 2 indicate the  differences in
secondary  effluent clarity  between  phases.  TF/SC  at above  average
filter  loadings (Phase  1)  produced  the  highest  clarity followed
by TF/SC at  high loadings  (Phase 3).   The  trickling filter  mode
(Phase 2)  had the  lowest  clarity as  indicated by the  lowest  Secchi
depth.  Differences between phases were statistically significant.

    Figure  4   shows  the  relationship  between  Secchi   depth  and
secondary  effluent  TSS.   The  data  are  based on  grab  samples of
secondary  effluent  taken by  the plant staff  at  the same time the
Secchi depth  was measured.  The  trend  line was based  on Beer's  law,
which  states  that  light  absorbance  (100  percent  for  the  Secchi
depth test) is  proportional to depth multiplied by  concentration.

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                                    Table  2.  Study Results
Parameter
Secondary treatment mode
Flow, m3/s (mgd)
Plant influent
Secondary treatment
Return secondary sludge
Waste temperature, degrees C
Concentration, rag /I
Raw waste
TSS
BOD5
Primary affluent
TSS
BOD5
SCBOOj
Trickling filter effluent
TSS - Filter 1
TSS - Filter 2
SCBOD5 - Filter i .__.--
SCBODj - Filter 2
Secondary effluent
TSS
BOOS
SCBODj
Secchi depth, • (ft)
Plant secondary effluent3
TSS
Secchi. depth, o (ft)
Operating parameters
Filter hydraulic loading rate.
l/t»2-s (gpm/sq ft)
Filter 1
Filter 2
Filter BODj loading rate, g/m -d
(ppd/1,000 cu ft)
Filter 1
Filter 2
Filter reaction r*te coefficient (K2g)
Filter 1, (l/m2-s)°*5
(gpm/sq ftl0'5
Filter 2, °'5
(gpm/sq ft)0'5
Return sludge parameters
Return secondary solids, mg/1
Reaeration time, minutes
Aerated solids contact parameters
Mixed liquor TSS, mg/1
Sludge volume index, ml/g
Solids contact time, minutes
Flocculator center well time," minutes
Secondary clarifier overflow rate,
m3/m -d (gpd/sq ft)
Phase
1
TF/SC

0.061 (1.40)
0.047 (1.07)
0.021 (0.47)
17.9


275
236

66
114
39

52
47
11
14

13
19
11
1.0 (3.4)

6
0.94 (3.1)



0.23 (0.34)
0.28 (0.41)


460 (29)
500 (31)
5.3 x 10"'
(6.4 x 10"')
3.2 x 10"*
(3.9 x 10"3)

4,210
9.3

1,140
129
2.8
19
18.4 (451)
2
TF

0.054 (1.24)
0.046 (1.06)
-
18.6


254
212

81
99
45

53
61
9
10

28
19
12
O.SS (1.8)

16
0.46 (1.5)



0.23 (0.34)
0.27 (0.40)


430 (27)
460 (29)
6.7 x 10"3
(8.1 X 10~3)
5.7 x 10'3
(6.9 x 10'3)

-
-

-
-
-
.
13.2 (447)
3
TF/SC

-
0.045 (1.03)
0.024 (0.54)
20.2


334
232

79
133
77

-
43
-
16

15
19
12
0.73 (2.4)

10
0.61 (2.0)



-
0.28 (0.41)


-
960 (60)

7.7 x 10'3
(9.4 X 10~3)

5,340
3.3

2,390
101
2.8
18
17.6 (43J)
"Collected downstream of flow controller for  secondary treatment.
b24-hour composite samples except for Secchi  depth.
cCrab samples taken during peak plant flow.
 Includes filter  recycle.
*Based on total flow in the center well including recycle.

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10
X
 o>



CO
CO


H


UJ
 u.
 u.
 UJ
o
o
UJ
CO
                              SECCHI DEPTH , ft


        Figure 4.  Relationship Between Clarity and Secondary Effluent TSS

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                                                                     11
    Secondary effluent  BODc, values  did not  increase in Phase  2 as
expected,  although  the  TSS  increased  and  the  clarity  decreased
significantly.   The secondary effluent particulate  BODc  (BODc minus
SCBODc)  to TSS  ratios  for Phases  1, 2, and  3  were  0.62,  0.25, and
0.47,  respectively.  In our experience,  the particulate  BODc, to TSS
ratio  is  almost always  above  0.5.   The  Phase  2  value  of  0.25 is
unlikely  and  probably  indicates  the secondary effluent  BODc  was
actually higher.

Microscopic  Examinations

    Microscopic   examinations  and  identification   of   filamentous
organisms  have   been  useful  in  developing  an  understanding  of
activated  sludge  operating  conditions.     These  examinations  can
also  provide useful  information  on  the operation of TF/SC  plants.
Table  3  summarizes  results of  the  microscopic  examinations  per-
formed during Phases 1 and 3 on  unsettled trickling  filter effluent
and mixed  liquor samples.

 Table 3    Filamentous Organisms in Trickling Filter  Effluent and Mixed Liquor
Date
April 21, 1986
(Plus* 1)
June 16, 1986
(Plus* 3)
Sample
TF Effluent
Mixed Liouor
TF Effluent
Nixed Liquor
Filamentous
organism
type
H. hydrossis
Thiothrix
Type 1701
S. natans
S. natans
Thiothrix
Type 1701
H. hydrossis
S. natans
Beqgiatoa
H. hydrossis
Thiothrix
S. natans
Thiothrix
Filament
abundance
Few
Few
Rare
Rare
Some
Few
Few
Few
Few
Few
Few
Few
Abundant
Some
Some- to-few
Suspected operating condition'
Low food-to-aicroorqanism
_ b
Low dissolved oxygen
low dissolved oxygen
low dissolved oxygen
_o
Low dissolved oxygen
Low food-to-«icroorganiim
Low dissolved oxygen
Sulfides
Low food-to-microorganism
Sulfidee
Low dissolved oxygen
^b
ratio
ratio
ratio
      Based on Reference 9*
     bThiothrix species possibly indicative of presence of sulfida*. nutrient deficiency, or low-dissolved
      oxygen.

     Note:  Ranking—abundant, common, some, few, rare, none*

    The  examinations  revealed  that the  trickling filter  solids and
contact  tank floe  were  generally  firm,  round,  and  compact.   They
also  identified five  different  types   of   filamentous  organisms.
These  organisms indicated  that  low  food-to-microorganism  (F/M)
conditions  and  low  dissolved  oxygen  concentrations  existed  con-
currently in  the  trickling  filters.    The  filamentous  organisms
identified  in the  trickling  filter samples were  often present  in
the mixed liquor samples.   The  abundance of filamentous  organisms

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12
was highest during Phase  3 when  the  filter  loading  was  highest.   In
Phase 3, the presence of  Beggiatoa  indicated  significant  amounts  of
sulfides existed  in  the  trickling  filter.   Beggiatoa  became  abun-
dant  in the  solids  contact  tank.    Many of  these organisms were
dispersed and reduced the clarity of  the  secondary  effluent.

Other Results
    The  first-order  reaction  rate  coefficients  (K^cP  for  SCBODs
removal  in  the  trickling filters are  shown  in Table 2.  The  Morr
Bay-Cayucos K20  values  fpr the rock, filters ranged from  3.2  x  1Q~
to 7.7 x 10~J  ri/m^-s)u*b[3.9  x  10~3 to  9.4  x  10"3  (gpm/sq  ft)0'5].
Filter  1  yielded  slightly higher  removal  rate  coefficients  than
filter 2.   For each filter, the removal rate  coefficient increased
as primary  effluent SCBOD5 increased.   The return sludge  aeration
and aerated solids  contact times were  short.  Studies at the Morro
Bay-Cayucos plant   indicated  that  the aerated solids contact  tank
removed about  1  to  2 mg/1 of  SCBODg.   Additional SCBOQ5  removal  in
the contact tank would  require longer detention times.


                      PERFORMANCE COMPARISONS


    The following  discussion  draws on  results of previous  studies
as well  as  the Morro  Bay-Cayucos  study.    It  covers   the  effect
of trickling filter loading on TF/SC performance/  trickling  filter
performance with f locculator-clarif iers, and  reaction rate  coeffi-
cients for rock media trickling  filters.

Trickling Filter Loading

    Trickling  filter  loading  had  some effect  on  TF/SC  perfor-
mance.  Loading did  not have  the same effect at each  plant.   Varia-
tions  may  be  due   to  differences   in  operating  conditions.    This
section compares  the effect  of  loading on  the performance  of  the
Morro Bay-Cayucos plant with  the other plants.

    Morro Bay-Cayucos.    The  lack  of substantial  effect of  filter
loading on  effluent TSS  at the Morro  Bay-Cayucos  plant indicates
that  the  TF/SC process will  produce good  effluent  as  long  as  the
trickling filters can operate  at the higher  loads.  The  presence  of
significant quantities  of  Beggiatoa,  however, suggested the  rock
trickling  filter  was  approaching  its'  limit at  the  loading  of
960 g/m-^-d (60 ppd/1,000  cu ft).

    Beggiatoa  are  aerobic  autotropMc  organisms  that use  sulfides
as their primary source of energy.  °  Sulfides are a by-product  of
anaerobic activity  and are often  associated  with  highly or over-

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                                                                   13
loaded  rotating  biological  contactors    and  trickling   filters.
Despite the high loadings,  the  trickling  filter  did  not  produce  any
noticeable odors.

    Figure 5  shows the effect  of  filter  loading at the Morro Bay-
Cayucos plant  and  other TF/SC plants with rock  filters.   The Morro
Bay-Cayucos composite  samples  are  the  Phase  1 and  3 averages from
the  full-scale  studies.    The  grab samples  are  monthly  average
values  (based  typically on 20  samples  per month) collected by  the
plant staff the  year before the study and phase  averages  collected
during  the  study.   The  Morro  Bay-Cayucos  plant  results are  the
only data  available  for  rock   filter  loadings  above  480 g/m -d
(30 ppd/1,000  cu  ft).    The   composite  samples  showed  a  2  mg/1
increase  in effluent TSS  when  the  loading was doubled  from 480  to
960 g/nr-d  (30 to  60 ppd/1,000  cu  ft).   The grab samples showed  a
4 mg/1 increase  in effluent TSS.

    The highest  secondary effluent TSS  shown on  Figure  2  (19 mg/1)
occurred when  all of the plant  flow [0.066 m /s  (1.5 mgd)]  received
secondary treatment,  rather than  a fraction  [typically 0.043 irr/S
(1.0  mgd)]  when split  treatment  was  used.    The  filter  loading
increase  occurred  because  of  the higher  primary effluent flow  to
the filters.   The 50 percent primary effluent  flow increase reduced
contact times  and  increased  the secondary clarifier overflow rate
by  50  percent.  Consequently,  large changes  in contact  times  and
overflow  rate  in addition  to  filter loading,  probably  contributed
to the increase  in secondary effluent TSS.

    The  Morro  Bay-Cayucos  plant  performed   well  at  the  high
loadings.    One  factor that may  contribute to  the unusually good
performance  at  the  Morro  Bay-Cayucos  plant  is  the  consistent
secondary treated  flow.   As  noted  earlier,  the  secondary  treated
flow was  maintained  at about 0.043  m /s  (1.0  mgd) with no diurnal
variation.   This  consistency  should  improve clarification.    The
secondary effluent TSS  increase during  full secondary treatment  may
have been affected by  the  diurnal  flow  variation in  addition to  the
contact time reduction  and  overflow rate  increase noted  earlier.

    Corvallis.  At Corvallis,   the  secondary effluent TSS  increased
from  8 to  11 mg/1  when   filter   loading  increased  from  160   to
400 g/nr-d (10 to  25 ppd/1,000  cu ft).   One of  the  two  filters  was
shut down briefly  in September  1980 to  assess the effect  of higher
loading.    Filter  loading  was   increased  to   about   640 g/nr-d
(40 ppd/1,000  cu ft),  but  the test -was discontinued  because   of
odors.

    The Corvallis filters  developed  odors  at loadings significantly
lower than  loadings  successfully  applied  to  the  Morro  Bay-Cayucos
filters.   The Corvallis  rock  filters  are  2.4-m (8-feet) whereas
the Morro   Bay-Cayucos  filter  depths  are  1.4-  and   1.5-m  (4.5-
and 5-ft).    As  a  result,  the  Corvallis filters  may  have  less

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14
      35
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    O OCONTO FALLS, 8/3/84 - 8/16/84

   . A OCONTO FALLS, 6/11/84- 7/11/84

    Q OCONTO FALLS, 7/83 - 11/83

    Q MORRO BAY - CAYUCOS (COMPOSITE), 3/86 - 6/86

    V MORRO BAY - CAYUCOS (GRAB), 3/85 - 6/86
   MORRO BAY-CAYUCOS
       FULL SECONDARY
            TREATMENT
                     V
10
                 10
                   20
30
40
50
60
            FILTER ORGANIC LOADING, ppd BODg/1000 cu ft

      Figure 5. Effect of Loading on TF/SC Performance with Rock Filters

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                                                                   15
ventilation.    Also,  for  an  equivalent  volumetric  BODc  loading,
deeper  filters receive  higher  loadings in  the  top portion of  the
filter  where most  BOD^  removal occurs.   The higher loadings  near
the filter  top may  create  an  overload  condition  and cause odors.

    Oconto  Falls.    Data collected  at  the  Oconto Falls  TF/SC  plant
for  months  with  a  similar  waste  temperature  indicated a  greater
effect  of  loading  on  TF/SC performance  than  at   the  Morro  Bay-
Cayucos and  Corvallis  TF/SC plants.  Average secondary  effluent  TSS
increased  8  mg/1  when  loading was  increased  from 160 to 400 g/m -d
(10  to 25  ppd/1,000 cu ft),  instead  of  3  mg/1  as at  Corvallis.
Loading  may  have   had  a  greater  effect  at Oconto  Falls  than  at
Corvallis  or Morro  Bay-Cayucos  because Oconto Falls only  averages
8 minutes  of  aerated  solids  contact   time  with no return sludge
aeration,  which  decreases  the  opportunity for physical  and biolo-
gical  flocculation.

Trickling Filter Performance With
Flocculator-Clarifiers

    Flocculator-clarifiers  generally include high  sidewater depths
(5.0 to 6.3  m), flocculator center  wells,  hydraulic sludge  removal,
and inboard  effluent launders.   The benefits of  flocculator-clari-
fiers have been discussed   ';  however, no  data  has  been presented
to  show how they  can  improve   trickling  filter plant  performance
when an aerated solids contact  tank is not  used.   Recent data  from
the Morro  Bay-Cayucos facility  and long-term data from the  Coeur
d'Alene,  Idaho,  plant demonstrate  that flocculator-clarifiers  can
significantly  improve  performance of trickling  filters  plants with
conventional shallow clarifiers.

    Morro  Bay-Cayucos.    The   trickling   filter  mode   (Phase   2)
produced secondary  effluent with an average  TSS  of  28 mg/1  when  the
trickling filter  loading was  445 g/nr-d (28 ppd/1,000 cu ft).   The
secondary effluent  quality was  not  as  good as the TF/SC  process  but
did meet  secondary effluent standards.  The  clarity of  the  second-
ary effluent was  significantly less than  the TF/SC process  because
of the lack  of aerated solids contact  for  flocculation.

    Coeur  d'Alene.    The  Coeur  d'Alene operating  records  provide
long-term  data to  assess  the  effect  of  flocculator-clarifiers  on
trickling  filter   performance.    The  Coeur  d'Alene  plant  has  an
average  dry  weather  flow of   0.10  m3/s   (2.3   mgd)  and  a  2.1-m
(7-foot) deep  roclt trickling  filter with  an  average filter  loading
of  about  290  g/mj-d  (18  ppd/1,000  cu ft).    The original  plant
included  a   shallow  2.1-m   (7-foot)  deep  secondary clarifier with
peripheral   effluent  weirs  and  a  scraper  mechanism   for sludge
removal.   In  1983, the shallow secondary  clarifier  was  replaced
with a  flocculator-clarifier,  the  only major modification made  to
the plant.

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16
    Figure  6  shows  the  effect  of  the  flocculator-clarifier  on
plant performance.  The flocculator-clarifier significantly reduced
the average  effluent  TSS from  25  mg/1 to 16 mg/1.   Additionally,
the plant  operated more  stably as noted  by the reduction  in  the
standard  deviation of  the  monthly average  values.    No  secondary
treatment  permit  violations have  occurred since the  flocculator-
clarifier was installed.
       50
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       10
              STANDARD
           SHALLOW CLARIFIER
                                   FLOCCULATOR - CLARIFIER
                                 AVERAGE TSS s 25 mg/l
                                 STANDARD DEV = 5.8 mg/1
                                                  A
                                                          I
                                                              ,\;
                                    AVERAGE TSS  =16 mg/l
                                    STANDARD DEV s 3.6 mg/l
                                                            i ,
              1982
                           1983
1984
1985
1986
   Figure 6. Effect of Flocculator-Clarifier on Trickling Filter Performance at
           Coeur d'Alene, Idaho
    It  should  be noted that  the  new flocculator-clarifier is 23-m
(75-foot)  in  diameter,  while the  old  clarifier was 18-m  (60-foot)
in  diameter.     The  reduction  in  average  effluent  TSS  with  the

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                                                                  17
flocculator-clarifier, however, is not attributable to the  increase
in clarifier  surface area.  The  performance  of. the two clarifiers
was compared at the  same overflow rate  [24 mVm -d  (590 gpd/sq ft)]
using low flow data  with  the  old  clarifier and high flow data with
the flocculator-clarifier.   The  flocculator-clarifier  yielded the
same average  effluent  TSS  value (16  mg/1), while the old clarifier
yielded  a  higher  average  effluent  TSS value  (31  mg/1).   Conse-
quently,  the   flocculator-clarifier   improved   effluent  quality
because of its inherent features and not because of the increase  in
clarifier surface area.

Reaction Rate Coefficients

    The  K2Q  values  computed  from  the  Morro  Bay-Cayucos  data
were substantially   higher  than   the   K2g   values  reported  for
plastic media.   Studies  at Oconto Falls yielded  the js^me  range  in
K2Q  values   for   rock  filters.     Richards,   et  al.    summarized
K2n values  for  cross-flow jnedia  from  various .studies  and showed
they ranged  from  1.7 x 10~* to 2.1  x  10~3 (l/mz-s)g'5 [2.0 x 10"3
to 2.6  x 10~3  (gpm/sq ft)0*5],.   Drury,  et  al.15  reported  a K20
value of 3.2  x  10~3 (l/m2-s)u>5  [3.9 x  10~3  (gpm/sq ft)0'5]  for  a
1.02-m  (3.33-ft)  deep filter with cross-flow media.

    K20 values developed  with  the modified-Velz equation show that
a  unit  of  rock  media surface  area  is more  efficient  at  removing
SCBODg  than  a  unit of plastic media surface  area.   Differences  in
K2g values may  be caused  by  a.decrease in the  resistance to mass
transfer  in   the  liquid  film    when  comparing  rock  and  plastic
media.   Differences  in K2g values may also be caused in part by the
inadequacy  of ttie  modiried-Velz  equation to  account  for depth.
Drury,   et  al.,    noted  relatively high K™. values  for  a shallow
plastic media  filter,  although the K2Q  values were in  the low end
of the  range measured with  the rock filters  at  Morro Bay-Cayucos
and Oconto Falls.  Plastic media,  however,  typically has a  specific
surface area (media surface area/unit of media volume) that is 2  to
3  times  as  great   as   rock   media,   which  may  compensate  for
differences in efficiency.

    The  K2Q  values  from   the  Morro  Bay-Cayucos  studies  increased
with  influent  SCBOD5.    This  relationship  indicates  that  the
modified-Velz equation does  not accurately describe SCBOD5 removal
in rock trickling filters.


                            CONCLUSIONS


    The Morro  Bay-Cayucos  studies  showed  that  TF/SC  can  produce
high quality effluent with rock filters even up to  loadings as high
as 960  g/m^-d  (60  ppd/1,000 cu ft).   Results  indicate  that if the

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18
 trickling  filter can operate satisfactorily at  this  high  load,  the
 TF/SC  process  will  produce  its  typically high  quality effluent.

     The  study  team noted  the  presence  of  Beggiatoa  in  trickling
 filter effluent at  960  g/m-'-d (60 ppd/1,000  cu ft)  loadings.   These
 bacteria   became abundant   in  the  solids  contact  tank.    Their
 presence  indicates  an  increase An anaerobic  activity  in the filters
 and  suggests  that  the  960  g/nr-d loading may mark  an  upper  limit
 for  good  trickling  filter  performance  at  the Morro  Bay-Cayucos
 plant.

     Nevertheless,  these loadings are significantly higher than  the
 previously tested 400  g/nr-d (25 ppd/1,000  cu  ft) loadings  at  the
 Corvallis  TF/SC plant.   They  provide  a  wide margin  of  potential
 increased  capacity  at  existing  rock  filter plants and indicate that
 these  plants   can  be  expanded  merely  by  adding  solids  contact
 features  without constructing  new  trickling  filters.   Each  plant
 should be evaluated  individually,  since  all  rock filters may  not
 operate effectively at  such high  loadings.   The possibility of such
 economical expansion  is particularly important in view of  the large
 number of rock  filter  plants that will need  upgrading  by the year
 2000.  The USEPA has  estimated  that  number to  be about 1,500.

     VJork   at  the Morro Bay-Cayucos  plant  and  long-term data  at
 the  Coeur  d'Alene  plant showed   that  effluent  quality  from  rock
 trickling  filter plants can  be  improved significantly  simply  by
 replacing  conventional  secondary  clarifiers  with flocculator-clari-
 fiers.  The  flocculator-clarifier at Coeur  d'Alene  reduced average
 effluent  TSS from 25 mg/1  to 16  mg/1.   The  plant effluent was also
 more  stable  and has   not  exceeded  secondary  treatment  discharge
 limits since addition  of the flocculator-clarifier.

     Another  result  has  implications  for the  design of expansions to
 rock filter  plants.  K2o values  reported  for  filter  SCBOD5 removal
 are  often higher  for  rock media filters than  for  deeper plastic
 media  filters.   The  higher I^g  values  indicate  rock media  ade-
 quately  removes SCBODg  and  compensates for  its   lower  specific
 surface  area with higher reaction rates.  The differences indicate
 a  unit of rock media surface area is more efficient  than  a unit of
 plastic  media  surface  area.   The ^Q  values  increased with  SCBOD^
 concentration   indicating  the   modiried-Velz  equation  does  not
 accurately describe SCBODe  removal  in  rock  media filters.  Design-
 ers  must  be  aware of the limitation of'the modified-Velz equation.


                          ACKNOWLEDGMENTS


     This  material  has  been  funded  wholly or  in part  by  the USEPA
 under  contract 68-03-1818  to  Brown  and Caldwell.    It   has  been
 subject   to  the  Agency's  review,  and  it  has  been  approved  for

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                                                                  19
publication  as  a  USEPA  document.    Mention  of  trade  names  or
commercial   products    does    not   constitute   endorsement   or
recommendation for use.

Credits

    This  paper  was  presented at  the  59th  Annual  Conference of the
Water  Pollution  Control   Federation/   Los  Angeles,   California,
October  9,  1986.   Curtis  Weeks  collected  a significant portion of
the  data  at  the  Morro  Bay-Cayucos  treatment   plant  under  the
supervision  of  Professor  Samuel Vigil.   Curtis  Weeks  and Samuel
Vigil are  associated  with  California Polytechnic University at San
Luis  Obispo.     The  author   acknowledges  the   cooperation  and
operational  support  given  by  the staff members  at  the Morro Bay-
Cayucos  plant.   The  authors  also wish  to  acknowledge Tom Liston,
plant superintendent  at  Coeur d'Alene,  Idaho,  for providing plant
data.

Authors
    Raymond  N.  Matasci  is  a  project  manager  with  Brown  and
Caldwell, Pleasant  Hill,  California.  David  L.  Clark is a project
manager  with  Brown  and  Caldwell,  Seattle,  Washington.   James A.
Heidman  is  a  staff engineer with  the Water Engineering Research
Laboratory,  U.S.   Environmental   Protection  Agency,  Cincinnati,
Ohio.   Denny  S. Parker  is  a senior vice president  for  Brown and
Caldwell,  Pleasant  Hill, California.   Bruce Petrik  is  a project
manager with Brown and Caldwell, Denver, Colorado.  Darrel Richards
is   the  water   quality   control   superintendent  for  Morro   Bay,
California.    Correspondence  should  be  addressed  to  Raymond N..
Matasci at  Brown and  Caldwell,  3480 Buskirk Avenue, Pleasant Hill,
California 94523.
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1.  U.S.  Environmental  Protection  Agency.    "Technical  Support
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2.  Matasci,  R.N.,  et  al.    "Full-scale  Studies of  the Trickling
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3.  Brown and  Caldwell.  Trickling  Filter/Solids  Contact  Process;
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4.  Fedotoff,  R.C.    "The  Trickling Filter  Finds a  New Partner."
    Water-Engineer & Management, June (1983).

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 20
 5.   Norris,  D.P.,  et  al.    "Production  of High  Quality  Trickling
     Filter  Effluent  Without   Tertiary   Filtration."   _J_.	Water
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 6.   Pierce, D.M.   Upgrading Trickling  Filters.   Prepared  for the
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 7.   American Public  Health Association.    Standard  Methods  for the
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 8.   Parker, D.S.,  and D.T.   Merrill.   "Effect  of  Media  Configu-
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 9.   Richard, M.G., et al.  "Growth Kinetics of Sphaerotilus Species
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10.   Hawkes,  H.A.     The  Ecology  of  Waste Water Treatment.    The
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11.   Brenner,   R.C.,   et   al.     Design   Information   on  Rotating
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12.   Parker,   D.S.      "Assessment    of    Secondary   Clarification
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13.   Parker,  D.S.,  and  R.J.  Stenquist.     "Flocculator-Clarifier
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14.   Richards, T., and D. Reinhart.   "Evaluation of Plastic Media in
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15.   Drury,  D.D.,  et  al.   "Evaluation  of High  Density Cross Flow
     Media  for  Rehabilitating  an Existing Trickling Filter."   J.
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16.   Logan,  B.E.  "A Fundamental Model  for Trickling Filter Process
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     Pollution   Control   Federation,   Los   Angeles,   California,

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