United States Office of Water Planning & Standards Environmental Protection Criteria and Standards Division 625/2-80-025 Agency Washington DC 20460 Technology Transfer x>EPAw Capsule Report Restoration of Medical Lake ------- Shore Front Park at Medical Lake ------- Technology Transfer EPA-625/2-80-025 Capsule Report Restoration of Medical Lake August 1980 This report was developed by the Center for Environmental Research Information, Office of Research and Development, U.S. Environmental Protection Agency Cincinnati, Ohio 45268 ------- Medical Lake Before Restoration ------- 1. Summary The Clean Lakes Program began in 1975 to implement section 314 of the Federal Water Pollution Control Act Amendments of 1972 (PL 92-500) which gives the States the responsibility for cleaning up their lakes. Specifically, the States must classify their lakes accord- ing to trophic conditions; identify procedures, processes, and methods to control the sources of pollution affecting the lakes; and restore water quality. The goal of theprogram is to aid the States in restoring freshwater lakes for public use. To qualify for a Clean Lakes grant, a lake must be open and accessible for public use and classified as freshwater. Futher- more, restoration must result in long-term benefits. This report discusses the restora- tion of Medical Lake, a fresh water lake located in eastern Washington State. The lake lies in a closed basin adjacent to the town of Medical Lake, approxi- mately 24 km (15 miles) south- west of Spokane. For several de- cades, a high phosphorus con- centration in the lake [0.3 ppm (0.3 mg/l)] contributed to the re- currence of algal blooms and bouyant mats of algae. Recrea- tional use of the lake diminished with the presence of a thick algal surface scum and odors as- sociated with decaying algae and hydrogen-sulfide-laden bottom waters. The restoration procedure cho- sen for Medical Lake consisted of successive applications of aluminum sulfate (alum). The purpose of the alum treatment was to disrupt the internal phos- phorus cycle, which was found to be responsible for the high phos- phorus concentration. The alum treatment was selected as the most practical restoration technique after studying the his- tory of the lake, analyzing its water quality and biota, and re- viewing other methods of treat- ment. Over a 5-week period beginning in August 1977, 935 metric tons (1031 tons) of liquid alum were applied to Medical Lake. Continu- ous water quality monitoring has shown a marked reduction in the phosphorus content along with a dramatic improvement in water clarity. 2. Theory Laboratory analyses of Medical Lake water samples showed a high concentration of phos- phorus. Futher study of the lake and surrounding environment indicated that most of the phos- phorus was being produced from within the lake. Significant exter- nal input was ruled out because, other than a few stormwater drains from the town, the lake re- ceives no sewage effluents or ag- ricultural runoff and has no sur- face inlets or outlets. Within the lake, the major sources of phosphorus were decompos- ing algae atthe bottom sediment, which released the nutrient dur- ing the summer. The phosphorus was then mixed throughout the lake during the fall. In the spring, algae were "fertilized" by the phosphorus in the water and grew very quickly. As they died, they sank to the bottom and de- composed. Their decomposition released phosphorus and caused oxygen levels to decrease which, in turn, caused more phosphorus to be released from the sediment. Thus, the algal production of one growing season served to stimu- late algal growth during the fol- lowing growing season (Figure 1). ------- 3. Procedure Selection Several methods of disrupting the internal phosphorus cycle in Medical Lake were considered. These methods included dredg- ing the lake bottom to remove nutrient-rich sediments; drawing down the water level to allow the exposed sediments to dry and consolidate, and thereby minimize phosphorus release; aerating either the whole lake or only the anoxic bottom waters to prevent phosphorus release from the sediments; and inactivating the phosphorus by chemicals. All of these methods had already been successfully applied to other lake restoration projects. Phosphorus inactivation by chemical precipitation was selected because the lake's small drainage area and lack of surface inputs limited the amounts of phosphorus entering the lake. Consequently, inactivating the phosphorus present in the lake system was expected to achieve long-term quality improvement. In addition, previous successful attempts at in-lake chemical pre- cipitation of phosphorus proved encouraging. Furthermore, chemical precipitation appeared to be the most economical method. Alum is a widely known chemical for inactivating phosphorus. It reacts with the natural alkalinity of water to form a cotton-like aluminum hydroxide complex called floe.The floe chemically reacts with phosphorus in the water to form an insoluble mass which is denser than water and, therefore, settles out. In addition, the settling floe coagulates and physically entraps algal cells and organic detritus, thus resulting in further removal of phosphorus from the water. An effect perhaps more important than removal of phosphorus from the water column is that the floe forms a chemical barrier on the sediment, which prevents phosphorus release during periods of low or absent oxygen concentrations. 4. Laboratory Analysis Study of the literature indicated that at least an 87 percent reduc- tion of the phosphorus concentra- tion in Medical Lake was neces- sary to eliminate algal blooms. Laboratory tests confirmed that the 87 percent reduction was the most cost effective. The amount of alum required for the treatment was initially esti- mated after studying the results of other whole-lake alum treat- ments and the literature on phos- phorus removal by aluminum sul- fate.The literature on the chemis- try of phosphorus inactivation with alum showed that alkalinity and pH affect the efficiency of the phosphorus inactivation process such that the amount of alum needed to remove a given amount of phosphorus increases as the alkalinity and pH of the water increase. Thus, laboratory experiments were clearly re- quired to determine the exact alum requirements for Medical Lake. Tests performed on Medical Lake water samples indicated that an ------- Summer Algae die, sink to the bottom, and decompose. Phosphorous is released. Algae also bloom on the surface. Fall Bottom waters mix with upper waters (turnover), spreading the phosphorous throughout the lake. Winter The high phosphorus concentration remains below the ice cover. Spring The high phosphorous concentration present in lake water fertilizes the algae. The algae bloom throughout the lake. Figure 1 Internal Phosphorus Cycle ------- 87 percent reduction in ortho- phosphorus(a) occurred only when the alum concentration equaled 150 mg/l, resulting in an alum to orthophosphorus ratio of almost 1000:1 (Table 1). Additional tests indicated that vigorous mixing of the alum as a liquid slurry rather than as dry crystals was necessary to achieve the 87 percent orthophosphorus reduction at an alum concentra- tion of 150 mg/l (Table 2). Tests also indicated that multiple alum doses could be more effective in reducing orthophosphorus levels than a single dose, and that com- bined surface and subsurface ap- plications could provide a greater reduction than surface applica- tions alone. The amount of alum necessary to achieve a final whole-lake con- centration of 150 mg/l was 935 metric tons (1031 tons), much higher than the original estimate. This difference again proved that laboratory tests were critical in determining the appropriate amount of alum. (a)Orthophosphorus is dissolved reactive phosphorus. For the laboratory analyses, orthophosphorus was measured as an indi- cation of overall phosphorus reduction. Table 1. Medical Lake Jar Test to Determine the Concentration of Alum for Effective Phosphorus Reduction Alum (mg/l) Ortho-P(mg/l) % Reduction 0 40 125 150 200 0.156 0.149 0054 0020 0005 0 4 65 87 97 Table 2. Medical Lake Tank Test to Determine the Kind of Mixing Affecting Phosphorus Reduction Alum (mg/l) Mixing Ortho-P (mg/l) % Reduction 0 150 150 150 None Light Strong Vigorous 0.26 0.14 0.09 0035 0 46 65 87 ------- 5. Dispensing System Alum Dispensing System and Barge The alum dispensing system was designed to provide a fast, effi- cient, and safe means of placing alum into the water at prescribed depths in a well-mixed uniform concentration. Two pontoon barges were used to disperse the alum, a 12-m (40-ft) barge for deeper areas and a 8.5-m (30-ft) barge for shallow areas. Each barge was outfitted with tanks, pump, and injection man- ifold.The tanks were filled by an onshore distribution system. The barge tanks were constructed from the bottom halves of fiberglas septic tanks which were reinforced and coated internally with an epoxy resin. The tanks were vented at the top and fitted with outlets at the bottom for transferring alum to the pump. Four tanks were mounted under the large barge and two under the small barge. The tanks were in- terconnected to inhibit massive "sloshing". The tanks were mounted underneath the barges to permit the lake water to sup- port some of the alum weight, thus allowing each barge to carry more alum than could be sup- ported directly on the barge deck. The distribution pumps were 5-cm centrifugal pumps made of fiberglas-reinforced thermoplas- tic polyester. Each pump was dri- ven by a 3-hp gasoline engine. The distribution manifolds were designed for even distribution of the alum and consisted of lengths of PVC pipe drilled with an in-line series of holes of varying sizes. The large barge had a 5.0-cm (2- in.)diameter manifold, 4.0 m (13 ft.) long with 156 holes spaced 2.5 cm (1 in.) apart. The holes in the pipe diminished in diameter near the center of the manifold to give uniform distribution. The small barge had a 3.8-cm (1 1/2-in.) diameter manifold, 2.7 m (9 ft) long with 108 holes. Again, the holes diminished in size toward the center. The piping was strap- ped to a manifold angle-iron frame leading to the deck. The manifold frame and piping formed a rectangle. The angle- iron frame was rotated for surface or subsurface application. The onshore system consisted of a supply tank and pump with a supply line down a dock to a valve and short flexible hose for con- nection to the fill lines on the barges. Loading took about 20 to 30 minutes for the large barge and 15 minutes for the small barge. The time for dispensing the alum varied depending on the type of application. Subsurface injection took about 45 minutes with the large barge and 25 mi- nutes with the small barge. Sur- face discharges took less time be- cause the barges experienced less manifold drag and the pump- ing rate was increased. ------- 6. Application The lake was divided into six equal zones with marker buoys to facilitate the systematic applica- tion of alum. The perimeter of the lake was also marked with buoys at the 5-m (16-ft) depth to indicate shallow water. The sequence of applications (passes) was as follows: two sub- surface applications; two surface applications; two more subsur- face applications followed by one surface and one subsurface ap- plication. Two successive appli- cations were not made in the same zone until all other zones had been treated. An entire zone could not be completed with a single barge load, so an indica- tion buoy was placed to mark the point where the alum in the barge was depleted. The barge pilots treated each zone in a series of back and forth passes utilizing the zone marker buoys and land- marks onshore to maintain orien- tation. Initially, attempts were made to control alum flow rate and barge speed to insure even application. However, the flow meters failed because of the high acidity of the alum solution. Consequently, barge speed was maintained by pilot judgment, generally not ex- ceeding the speed achievable when the barge was fully loaded with alum. Aerial View of Alum Application ------- Medical Lake After Alum Treatment 7. Water Quality Monitoring Water quality monitoring was conducted prior to, during, and after the alum application. The most critical parameters were continuously monitored. These parameters included total phos- phorus and orthophosphorus and chlorophyll a. Secchi disk read- ings were also taken. Orthophos- phorus is the most readily availa- ble form of phosphorus for biological uptake, although de- pending on water conditions, phosphorus may be found in dif- ferent phases. Total phosphorus therefore, also was monitored to determine if the phosphorus was actually being removed from the ------- ALUM TREATMENT DJMAMJJASONDJ FMAMJJASONDJ FMAMJJASOND Figure 2. Mean monthly total and orthophosphorous concentrations (mg 1~1 P) before, during and following alum treatment. ALUM TREATMENT DJMAMJJASONDJ FMAMJJASONDJFMAMJJASOND Figure 3. Mean monthly chlorophyll a concentrations (mg nv3) before, during and following alum treatment. ------- cycle or just changing its form (Figure 2). Levels of chlorophyll a were important to follow because they indicate the amount of algae present in the water column (Fig- ure 3). Secchi disk readings were taken to monitor the clarity of the water. The results of the monitoring to date show that the alum applica- tion to the lake was highly suc- cessful in decreasing phosphorus levels, eliminating nuisance algal blooms, and greatly increasing water clarity. Total phosphorus levels have remained below 0.1 ppm (mg/l) since the treatment. Chlorophylls data showthatalgal concentrations in the water col- umn dropped significantly after the alum treatment and have re- mained consistently low ever since. No enhanced algal growth has occurred after spring thaw, indicating that phosphorus is no longer being supplied to the lake in significant amounts by the sed- iments during the previous sum- mer. The treatment improved water clarity as evidenced by increased Secchi disk visibilities (Figure 4). Improved water clarity is another indication of reduced algal growth. DJMAMJJ ASONDJ FMAMJ JASONDJ FMAMJ JASOND Figure 4. Mean monthly Secchi disk visibilities (meters) before, during and following alum treatment. ------- 8. Project Costs Total project costs (Table 3) in- clude the cost of alum; labor costs for monitoring alum application, data analysis, and project man- agement; and equipment rental and outfitting. Water quality monitoring and data analysis for the 3-year project accounted for a large part of the expenditures. The price of the alum was also significant. Table 3. Project Costs for Medical Lake Restoration (1977 $) Alum S 90,000 Labor Monitoring (1 /77-6/80) (Biological, Physical, Chemical) 55,000 Chemical Application (8/77-9/77) 5,000 Project Management Planning, Coordination, and Data Analysis (1 /77-6/80) 72,000 Equipment Barge Rental 8,000 Vehicle Rental 1,150 Pumps, Supplies 7,250 Bond 1,500 Total $239,900 9. Benefits The absence of algal scums and noxious odors as well as the increase in water clarity and fish habitat, resulted in changes in the use of the lake. Some of these changes include swimming, boat- ing, and fishing. Recreational users of the shore front park increased on summer weekends from fewer than 100 to an estimated 1,000. Property val- ues rose accordingly. Futher- more, the Washington State De- partment of Game experimen- tally stocked the lake with rain- bow trout 6.4 cm (21/2-in.fingerl- ings) in 1978 and 1979. By July 1979, some of the fish had grown to47 cm (181/2-in.). Publicfishing is expected to be permitted dur- ing 1981. GPO1980-M-660-948 ------- |