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 AEERL-P-842a
                 TECHNICAL REPORT DATA
          (Please read Inunctions on the reverse before complel
 1. REPORT NO
    EPA/600/J-92/046
                                                        3.
                                              PB92-15061U
 4. TITLE AND SUBTITLE
 Fuel Cell Energy Recovery from Landfill Gas
                                                        5. REPORT DATE
                                                        6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)
 G. J. Sandelli (IFC) and R. J.  Spiegel (EPA)
                                                         I. PERFORMING ORGANIZATION REPORT NO.
 9. PERFORMING ORGANIZATION NAME AND ADDRESS
 International Fuel Cells  Corporation
 195 Governors Highway
 South Windsor, Connecticut  06074
                                                        10. PROGRAM ELEMENT NO.
                                        11. CONTRACT/GRANT NO.
                                         68-01-0008
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA,  Office of Research and Development
   Air and Energy Engineering Research Laboratory
   Research Triangle Park-,  North Carolina  27711
                                        13. TYPE OF REPORT AND PERIOD COVERED
                                        Journal article;  1-9/91
                                        14. SPONSORING AGENCY CODE

                                         EPA/600/13
 is.SUPPLEMENTARY NOTES AEERL projectofficer is RonaldJ<  Spiegel.  MailDroP63. 919/
 541-7542.  Journal of Power Sources, 37 (1992), 255-264.
 i6. ABSTRACTThe paper discusses Phase I results of an EPA-sponsored program to
 demonstrate energy recovery from landfill gas using a commercial phosphoric acid
 fuel cell power plant. 3PA is interested in fuel  cells for this application because it
 is the cleanest energy conversion technology available.  Phase I is  a conceptual de-
 sign, cost,  and evaluation study.  The conceptual design of the fuel energy recovery
 concept is described and its  economic and environmental feasibility is projected.
 Phase II covers the construction and testing of a landfill gas pretreatment system
 which will render l«\ndfill gas suitable for use in the fuel cell. Phase III is the demon-
 stration  of the energy recovery concept.
17.
                              KEY WORDS AND DOCUMENT ANALYSIS
                 DESCRIPTORS
                                            b.lDENTIFIERS/OPEN ENDED TERMS
                                                                     c. COSATl Field/Group
 Pollution
 Fuel Cells
 Gases
 Earth Fills
 Energy
 Phosphoric Acids
                           Pollution Control
                           Stationary Sources
                           Landfill Gas
                           Energy Recovery
13 B
10B
07D
13C
14G
07B
 8. DISTRIBUTION STATEMENT
 Release to Public
                           19. St-CURITY CLASS (This Report)
                           Unclassified
21. NO. OF PAGtS
      IX
                                            20. SECURITY CLASS (This page)
                                            Unclassified
                                                    22. PRICE
EPA Form 2220-1 (3-73)
REPRODUCED BY
U.S. DEPARTMENT OF COMMERCE
        NATIONAL TECHNICAL
       INFORMATION SERVICE
       SPRINGFIELD. VA 22161

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                                                                             PB92-15061U
                                                   EPA/600/J-92/046
Journal <•/ Amvr Source. 37 (I'WJT. 255-2(i4
                                                                               255
                                                          ,,c*
Fuel cell  energy recovery from landfill gas
G.  J. Sandelli
International Fuel Cells Corporation,  195 Governor,  Highway. South  Windsor.  CT 06074 (USA)

R.  J. Spiegel"
U.S. Environmental Protection Agency, Air and Energy Engineering Research Laboratory,
Research Triangle Park, NC 27711 (USA)
Abstract

International Fuel Cells Corporation is conducting a US Environmental Protection Agency
(EPA) sponsored program to demonstrate energy recovery from landfill gas using a commercial
phosphoric acid fuel cell  power plant. The  US  EPA is interested in fuel cells  for this
application because it is the cleanest energy conversion technology available. Thfs paper
discusses the results of Phase  I, a conceptual design, cost,  and evaluation study.  The
conceptual design of the fuel cell energy recovery concept is  described and its economic
and environmental feasibility is projected. Phase II will include construction and testing
of a landfill gas pretrcatmcnt system which will render  landfill gas suitable for use in the
fuel cell. Phase III will be a demonstration of the energy  recovery concept. •,
 Introduction

     The  US  Environmental  Protection Agency (EPA) has proposed standards and
 guidelines [1]  for  the  control of  air emissions from municipal solid waste (MSW)
 landfills. Although not directly controlled under the proposal, the collection and disposal
 of waste methane, a significant contributor to the greenhouse effect, would result from
 the  emission  regulations. This EPA action  will provide  an opportunity for energy
 recovery from  the waste  methane  that could further benefit the environment. Energy
 produced from landfill gas could offset the use of foreign oil, and air emissions affecting
 global warming,  acid rain, and other health  and environmental  issues.
     International Fuel Cells Corporation (IFC) was awarded a contract by the US
 EPA to demonstrate energy recovery from landfill gas using a commercial phosphoric
 acid fuel  cell. IFC is conducting a three-phase program to show that fuel cell energy
 recovery is economically  and  environmentally feasible in commercial operation. Work
 was  initiated in Jan. 1991. This  paper discusses the results of Phase I, a conceptual
 design, cost, and evaluation study, which addressed  the problems associated with landfill
 gas as the feedstock for fuel cell  operation.
    'The research described in this article has been reviewed by the Air and Energy Engineering
Research Laboratory of the US EPA and approved for publication. Approval docs not necessarily
reflect  the view and policy of  the Agency nor does mention of trade  names or  commercial
products  constitute  endorsement or recommendation for use.
   "Author to whom correspondence should be  addressed.
NTIS is authorized to reproduce and sell this
 report. Permission lor further reproduction
must be obtained from the copyright owner.
                                             1992 - Elsevicr Sequoia. V\ll rights reserved
                                                                 >   '

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     Phase II  ol  the piourain includes  construction and  testing i>l  the landfill  JMS
prelrcatmciil module to be used in the demonstration. Its objective will be lo determine
the cll'ectiveiiess ot the pretrcalmenl system design lo remove critical  fuel cell catalyst
poisons such as sulfur and lialides. A  challenge test is planed  to show the  feasibility
of using the pretreatment process at any landfill in  conjunction  with  the  fuel  cell
cncigy recovery concept. A preliminary description of the gas pretieater is presented
here.
     Phase III of this program will be a demonstration of the fuel cell energy recovery
concept. The demonstrator will operate at Pcnrosc station,  an  existing landfill gas-to-
cncrgy facility owned by Pacific Energy in Sun Valley, CA. Pcnrosc Station  is an 8.9
MW internal combustion engine  facility  supplied with landfill gas from four landfills.
The electricity produced by the demonstration will be sold  to the electric utility grid.
     Phase II activities began in Sept. 1991 and Phase III activities are  i-chedulcd to
begin in Jan.  1993.
Landfill  gas

Availability
     The MSW landfills in the US were evaluated to determine the potential power
output which could be derived using a commercial 200 kW fuel  cell. Each fuel cell
would consume  100000 SCFD of landfill gas to generate 200 kW, assuming a heating
value of 500 Btu per  cubic foot.
     The potential power generation mavket available for fuel cell energy recovery was
evaluated using an  EPA estimate of  methane emissions in the year 1992  [2aj.  An
estimated 4370 M\V of power could be generated from the 7480 existing and closed
sites identified. The largest number of potential sites greater than 200 kW occurs in
the 400  to 1000 kW range. This segment  represents a market of 1700 sites  or 1010
MW.
     The assessment concluded  that these sites  are  ideally suited  to the  fuel cell
concept. The concept  can provide a generating capacity tailored  to  the site  because
of the modular  nature of the commercial fuel cell. Sites in this  range arc  also less
well served by competing options, especially Rankinc and Brayton Cycles which exhibit
poorer emission characteristics at these  power ratings.
     As a result  of the assessment, the conceptual design of the commercial  concept
was required to be modular and  sized to  have the broadest impact on  the market.

Characteristics
     The available information on landfill gas compositions was evaluated to determine
the range of gas characteristics which a fuel  cell landfill gas-to-cnergy power plant
will encounter. This information was used to set the requirements for the gas pretreatment
and fuel cell power plant designs.
     A summary of landfill gas characteristics is shown in Table 1. The heating value
of the landfill gas varies from 350 to 600 Btu per cubic foot, with a typical value of
500 Btu  per  cubic foot. The major non-methane constituent of landfill gas is carbon
dioxide. The  carbon dioxide ranges from 40 to 55% by volume of the gas  composition
with a typical value of 50%. Other diluent gases include nitrogen and oxygen, which
arc indicative of air  incursion into the well  (most frequently in  perimeter wells).
Nitrogen concentrations can range as high as 15% but typical values arc 5% or less.
Oxygen concentrations are monitored  closely and  held low for  safety reasons.

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                                                                             257
TAW.I: I
Larullill g.is ch.ic.i(.tcriNtiCM
Characteristic
Healing value
(111 IV) (Lilu/ll1)
CII4 (%)
CO, (%)
N; (%)
0, (%)
Sulfur as H:S (ppmv)
Halulcs (ppnivj
Non-methane organic compounds
(NMOCs) (ppmv)
Range
350-600
35-58
40-55
0-15'
0-2.5'
1-700
N/A
237-14000
Typical
500
50
45
5
< [% (for safety)
21
132
2700
"Highest values occur in perimeter wells.
     Landfill gas constituent compounds reported by EPA [2b] indicate a typical value
 for the total non-methane organic compounds (NMOCs) of 2700 ppmv (expressed as
 hcxanc). The NMOC concentration in the landfill gas is an important measure of the
 total capacity required in the  gas prctreatment system, while  the  specific individual
 analyses provide  a basis for  gas  pretreatmcr.t subcomponent  sizing.  The  specific
 contaminants  in  the landfill gas, of interest to the fuel cell, are sulfur and  halidcs
 (chiefly chlorides  and  fluorides). The sulfur level  ranges from  1  to 700 ppmv, with a
 typical value in the order of 21 ppmv. Sufficient data were not available to assess the
 range of the halidcs, but a typical value of 132 ppmv was calculated for this contaminant
 [2e].  The  range of contaminant values varies not only from site to site, but  also at
 any given site with time due to seasonal weather or moisture content. These characteristics
 require the prctreatment system design to be  capable  of handling these gas quality
 variations to avoid expensive site specific engineering of the prctrcatmcnt design which
 would alTcct the  marketability and economics of the concept.
Emissions requirements
     Existing US regulations do not address methane emissions from landfills directly.
Proposed new  EPA regulations [1]  would control NMOCs from large landfills (150
Mg per year and up)  and hence would indirectly control  methane emissions.
     Landfill gas emission requirements are primarily determined at the state and local
level. State requirements arc generally limited to controlling explosion hazards, typically
limiting methane concentrations to below 25% of the lower explosion limit. An evaluation
of state regulations revealed that collection and control requirements generally necessitate
venting,  or  the use of a flare.  However, Federal Clean  Air  Act  requirements arc
driving the  state and  local air  quality rules, especially in areas  identified as non-
attainment regions. For instance, non-attainment regions for ozone  may lead to strict
requirements for secondary emissions including  NO,,  carbon monoxide and NMOCs.
The  best known cxampl: of strict local  emission requirements is the South Coast Air
Quality Management District  (SCAQMD) in  southern  California.

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25S

Commercial fuel coll lanillHl  gas  to energy system conceptual design

    This  section describes the commercial fuel cell  landfill gas to  energy  system
conceptual design.  The  design is based  on providing a modular, packaged,  energy
conversion system which can operate on landfill gases with a wide range of compositions
as typically found in the US. The complete system incorporates the landfill gas collection
system, a fuel gas pretrcalmcnt system and a fuel cell energy conversion system. In
the fuel gas pretrcatment section, the raw landfill gas is treated to  remove contaminants
to a level  suitable  for the fuel cell energy conversion system. The fuel  cell  energy
conversion system converts the treated gas to electricity and useful  heat.
    Landfill gas collection systems are presently in  use in over 100 MSW landfills in
the US.  These systems have  been proven effective  for the  collection  of landfill  gas.
Therefore  these design and evaluation  studies were  focused  on the energy conversion
concept.

Overall system description
    The commercial landfill gas to energy conversion system is illustrated in Fig. 1.
The fuel prctreatmcnt system has provisions for handling a wide range of gas con-
taminants. Multiple  prctreatmcnt  modules can be used to accommodate a wide range
of landfill sizes. The wells and collection system collect the raw landfill gas and deliver
it  at  approximately ambient  pressure  to the gas prctreatmcnt  system.  In  the  gas
prctreatmcnt system the  gas is treated to  remove NMOCs including trace constituents
which  contain halogen and sulfur compounds.
    The commercial energy conversion system shown in Fig.  1  consists  of four  fuel
cell power plants. These power plants  arc designed to provide 200 kW output when
operating on landfill gas with a heating value of 500 Btu per standard  cubic foot  and
for accommodating higher contaminant concentrations. The  output from  the fuel  cell
is  utility grade a.c.  electric power.  It can be  transformed and  put  into the electric
grid, used  directly at nearby facilities, or used at  the landfill itself. The power plants
arc capable of recovering  co-generation heat for nearby use or rejecting it to air.
                        800 KW FUEL CELL POWER PLANT
                         OPERATING ON LANDFILL GAS
   LANDFIIX CAS WEliS
    AND COLLECTION
       SYSTEM
    OmCF. AND
     BLOWER
                                            MULTIPLE
                                            FUEL CELL
                                          POWER PLANTS
CAS PRETREATMENT
    SYSTEM
Fig. 1. Fuel cell energy rccoveiy commercial concept.

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    As configured) in l;ig. 1, the commercial system c;m process ;ipproximately 18000
standard cubic (cut  per  liour  of landfill gas  (mitigate 9050 SCFH of methane)  with
minimum environmental impact in terms of liquids, solids or air pollution. Details of
the individual sub-elements in the energy conversion system follow this discussion.

Fuel prcttcatmcnt system
    A block diagram of the landfill  gas pretrcMmcnt system is shown in Fig. 2. The
fuel prelrealnicnt system incorporates two stages of refrigeration combined with three
rcgenerablc adsorbent steps.  The use  of staged refrigeration provides tolerance  to
varying landfill gas constituents. The first stage significantly reduces the water content
and removes  the bulk of the heavier hydrocarbons from  the  landfill gas. This  step
provides flexibility  to accommodate varying  landfill characteristics  by delivering a
relatively narrow cut of hydrocarbons for the  downstream beds in the prctrcatmcnt
system. The second refrigeration step removes additional hydrocarbons by a proprietary
process and enhances the effectiveness of the activated carbon and  molecular sieve
beds, which remove  the remaining volatile organic compounds and hydrogen sulfide
in the landfill gas. This approach is more flexible  than utilizing dry bed adsorbents
alone and has built-in  flexibility for the  wide range of contaminant concentrations
which can exist from site to site and even within a single site varying with  time.
    The three adsorbents are rcgenerzted by using heated gas from the process stream.
Each step consists of two beds  in parallel. In  operation, one bed is  adsorbing while
the parallel bed is being regenerated. The regeneration path and sequence are shown
as dashed  lines in Fig.  2. A small portion of the treated landfill gas (approximately
8%) is heated by regeneration with the incinerator gases and then passes through the
beds in the sequence shown. After  exiting the final bed, the  regeneration gas is fed
into the low NO, incinerator where it is combined with the  vaporized condcnsatcs
from the refrigeration processes and the mixture is combusted to provide 98% destruction
of the NMOCs from  the raw landfill gas. The exhaust from the incinerator is essentially
CO2 and water. The pretrcatmcnt system design provides treated gas to the  fuel cell
power plant in an efficient, economic, and environmentally acceptable manner.
    The prctrcatmcnt system design provides flexibility for  operation  on a wide range
of landfill gas compositions, it has minimal solid wastes, high thermal efficiency, and
low parasite power requirements. The pretreatment system is based upon modification
of an cxistjji«  system and utilizes commercially available  components. The  process
train and opciating characteristics need to be validated by demonstration. Key dem-
                                                   REOCNCIUriON OAS
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7
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BfRIOf flATKW -*S WOC SltVE PS
CONOCHSCA >"^ DCHVOAAItON \r
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PRESSURE
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CECX>NO 1


RCOCNEHABLC 1
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COWOCN SATES


'BCQCN
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Tig. 2. Simplified block diagram of commercial landfill gas prctrcatr.icnt system.

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onstr;iuons in Phase II will  include:  Ihc achievement of low total halide  contaminant
levels in i lie neatctl gas; elleclivencssot the regeneration cycle as a Heeled by regeneration
time  and  temperature; durability of the  regenerable  beds;  and low  cnviionmental
emissions.
    The fuel pretieatment system described above was analyzed to estimate the overall
thermal efficiency, internal electric power requirements and maintenance characteristics.
The estimated thermal efficiency is 92% with the balance of  thermal energy  used for
regeneration, vaporization of the condensate and incineration of regeneration gases.
Electric power is used for  pumping the gases and the  refrigeration stages and is
accounted for as a parasite power characteristic of the system. Maintenance requirements
consist of maintaining and  adjusting controls and valves  in  the regeneration system
and replacement of fully regenerated spent bed materials on an annual basis.
    The pretrcatment system was evaluated  to define anticipated air emissions, and
liquid and solid effluents. The incinerator is designed for 98% destruction of all NMOCs
and NC), emissions of less than 0.06 pounds per million Btu of fuel consumed. There
is no liquid effluent from the system since all condensates are vaporized and subsequently
incinerated. Solid disposal  involves removing spent regenerable  bed materials at  the
factory and  treatment by an approved reclamation processor.
     cell power plant
    The commercial landfill gas energy conversion conceptual design incorporates four
200 kW fuel cell power units. Since each of the four units in the concept is identical,
this discussion  will focus on the  design issues  for a single 200 kW power unit.
    A preliminary design of a fuel  cell power plant was established to  identify the
design requirements which  allow optimum operation on  landfill gas.  Three issues
specific to landfill  gas  operation were identified  which reflect a departure  from a
design optimized for operation on natural gas. A primary issue is to protect the fuel
cell from sulfur  and halidc compounds not scrubbed from the gas in the fuel pretrcatmcnt
system. An absorbent bed was incorporated into the fuel cell  fuel preprocessor design
which contains  both sulfur and halide absorbent catalysts. A second issue is to  provide
mechanical components in the reactant gas supply systems to accommodate the larger
flow rates that  result  from use of dilute methane fuel. The third issue is an increase
in the heat rate of the power plant by approximately 10% above that anticipated from
operation on natural gas. This is a result of the inefficiency of using the dilute methane
fuel. The inefficiency results in an increase in heat recoverable from the  power plant.
Because  the effective fuel cost is relatively low, this decrease in power plant efficiency
will not have a significant impact on the overall power  plant economics.
    The landfill gas power plant design provides a packaged, truck transportable, self-
contained fuel  cell power plant with a continuous electrical rating of 200  kW. It is
designed for automatic, unattended operation, and can be remotely monitored. It can
power electrical loads cither in parallel with the utility grid or isolated from the grid.
    In summary, a landfill  gas fueled power plant  can be designed to provide 200
kW of electric  output without need for technology developments. The  design would
require selected components to increase reactant flow rates with a minimum pressure
drop. To implement the design would require non-recurring expenses for system and
component design, verification testing of the new components, and system  testing to
verify the power plant performance and overall system integration.

Environmental and economic assessment of the fuel cell energy conversion  system
    The commercial  application  of the concept to  the  market described previously
was assessed. For the purpose of the evaluation, a site capable  of supporting four

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tucl cell pi me I  modules wax selected  'I'hc site cti.irude[istics .issiniK'il are the typical
values disused earlier. The site would produce appioximatcly -13-4 (100 standard cubic-
led ol  landfill gas  per day.  The  gas  contains approximately  50% i;ielh;iiie  with  ;i
healing v;ilue of  500 Bin per standard cubic loot.
    The analysis dt the environmental impact shows that both  the  fuel cell  and the
Hare  system  can  be designed  to eliminate the methane  and the NMOCs from the
landfill  gas  system. For  the example site  considered,  the  methane elimination  is
essentially complete for both systems and V89c of the NMOCs are destroyed. Trace
amounts of SO,  and  NO,  will be emitted in each  case. With the fuel  cell system,
however,  significant reductions of NO, and SO, will be achieved due to the fuel cell
energy generation.  This analysis  assumes an 80%  capacity factor for the fuel cell and
otlsetting  emissions from  electric  utility power generation  using  a coal-fired plant
meeting New Source Performance Standards.  For the example site, the fuel cell energy
conversion system provides 5.6 million kW h of electricity per year, with a net reduction
of NO, of 35.2 tons per year and a  reduction of SO, of 16.8  tons per  year. These
reductions can  be used as environmental offsets,  particularly in critical areas such as
California or other locations with  severe environmental restrictions.
    The environmental impact of application of the fuel cell concept to the potential
market  is shown in Table  2.  The data  show that  both  the Hare  and  (he fuel cell
mitigate  methane  and NMOCs under the proposed standards and guidelines [2].
However, the flare merely converts these emissions lo CO2, and rain and other unhealthy
pollutants. The fuel cell can provide a net reduction in global pollution by offsetting
energy production  from coal.
    Economically the fuel  cell energy system has the  potential for.deriving revenues
from  electric sales, thermal sales and emission offsets  credits. These revenues can be
used  to offset the investment cost associated with  gas collection, gas prctrcatmcnt and
fuel cell  power units.  The level of  these  revenues depends upon the  value of the
electricity, the  amount and value  of ihe  heat used, and the value of ihe emissions
offsets.

Economics
    Electric rates  vary considerably with geographic  location and  the  purchaser of
the electric  energy. Commercial  rates are applicable where the electricity can be used
at the landfill  or in nearby commercial facilities. Commercial rates vary  from a high
of  13.68 cents  per kW h to a low of 2.71 cents  per kW h. The median  rale in Ihe
US is approximately 7 cents per kW h.  The rates  charged to industry arc generally
TAHLE2
Emissions impact of fuel cell energy recovery from landfill gas

Abatement    Global warming                        Acid  rain and health
technology    	    	
              Methane      NMOC      CO2          SO2         NO,        CO
              (Mg/yr.)      (Mg/yr.)     (Mg/yr.)      (Mg/yr)     (Mg/yr.)     (Mg/yr.)

Venting [2]    1 8x 107        52100
 only
Flare         0              -10200     +4.94x10'     +2972       +29720    +14860
Fuel cell      0              -10200     -6.45x10'    -53500      -259000     -8620

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lower and are closer 10 the fully burdened avoided eost for  the  uli'ity These rates
range from 10.0 ccnis per  kW  h to a low of 1.64 cents  per kW h with the mean value
of approximately 5 cents per  k\V h. In general, both  the commercial  and industrial
rates are higher  in locations with high population  density and/or with air emissions
problems.  These locations are ideal for the use of the fuel cell energy  conversion
system with its favorable environmental impact. Since the rates vary  considerably, the
analysis in this section is done  on a  parametric basis for a wide range of electric rates.
     The fuel  cell energy conversion system was studied to establish  the net revenues
or costs  for processing landfill gas to  mitigate methane emissions. For the purposes
of the analysis it was assumed  that the fuel cell  energy conversion system and the
flare system would have an overall  annual capacity factor of 80%.  For this analysis,
two  levels of  fuel cell installed  costs  were considered. The lower level represents a
fully mature cost when  the power plant has been accepted into the  marketplace, and
is routinely produced in large quantities. The upper  level represents a price level when
the  power plant is  being  introduced  >nto the marketplace,  and is produced on  a
moderate and continuous  basis.
     Figure 3  shows the fuel cell revenues for the most stringent application situation
(no emission credits or thermal  energy utilization).  In  this case, the  fuel cell receives
revenues only from the sale of electricity. Although the emissions  arc lower fiom the
fuel  cell, no specific credit or value is attached to them for this example. Under these
conditions the fuel cell is  still  the economic choice for most locations  at the mature
product  installed cost.  At  the entry cost the  fuel  cell is economical in  those areas
where the value of electricity is  9 cents per kW h or higher. This  would primarily  be
areas such as California, New York, and other parts of New England. With the potential
for  revenue from thermal  energy or emission offset credits,  the  economics become
more comp-titive. Thus the applicability of the  concept would  become attractive to
a broader market.
     Other energy conversion systems could also produce electric and/or thermal energy.
Both the internal combustion engine and the gas turbine engine have been suggested
as options for methane  mitigation at  landfill sites. For the landfill  size selected for
o
UJ <3
s ri
z c
o g
er 5
u- 2

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this  .in.ilvsis, ihc inicin.il  combustion engine is more  cllcclivc  th.in  the  gas  turbine
options lor cleanup. This is used .is the basis for the coinpansons provided here. The
internal combustion engine can provide both heat and electric energy while consuming
the  methane at  the landlill  ;;as  site. With the present state-of-the-art  technology,
however. .1 lean-burn  internal :ombustion engine has higher levels of NO, emissions
than a  (uH cell  unless special precautions arc taken  to clean  the exhaust.  For our
analysis IAO cases were considered. The first case assumes  no cleanup of  the internal
combustion engine  exhaust, and  the second assumes that the exhaust is cleaned with
selective catalytic reduction (SCR). Since  the SCR  employs a catalyst in  the cleanup
system, the landlill  gas will have  to be pretreated in a  manner similar to the  fuel cell
system. For those cases with  a SCR cleanup system, a pretrcatment  system  has also
been included  as part of the total  system cost.
     Figure 4 shows the results of the economic analysis for the fuel  cell system and
the internal combustion engine system. Since both systems can provide electricity, the
comparison between the systems is based on the  cost of  electricity  generated from
the energy conversion  system with appropriate credit for thermal  sales  and/or emission
olTscts.  The fuel  cell is competitive at the  full mature price  when no  exhaust cleanup
is required with the internal combustion engines. However, the operation of the internal
combustion engine at  the landfill  site would be quite  dirty, and significant amounts
of NO, would  be added  to the ambient air. For many locations where  the  fuel cell
would be considered,  such as California or other high emissions areas,  the exhaust
cleanup option  is required. Consequently, the fuel cell option would be fully competitive
with the internal combustion engine option for most cases  where on-sitc cleanup of
the internal combustion engine is required. In areas where a SCR would be employed
to clean up an  internal combustion engine  exhaust, the  fuel  cell concept is competitive
at entry level cost.
     Based on the analysis of both the Hare  option and other energy conversion options,
the fuel cell power plant is fully competitive in all situations in the mature production
situation.  For initial power plant  applications with limited lot production, the  lucl cell
power plant  is competitive in areas with  high electric  rates and/or severe emissions
restrictions at  the local  landfill site.
• ELECTRICITY SALES
• THERMAL RECOVERY
• EMISSIONS OfTsETS
F
MATURE
RODUC
COST

WITH
SCR
EXHAUST
CLEANUP
T
NO
EXHAUST
CLEANUP
I


FUEL CELL IC.E.
ENERGY CONV. ENERGY CONV.
SYSTEM SYSTEM
Fig. 4. Comparison of fuel cell to internal combustion engine energy conversion system.

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Conclusions

     Based on (lie environmental and economic evaluation of the commercial fuel cell
energy system, the  t'ollosving conclusions can  be made.
• The fuel cell landfill gas to energy conversion  system provides a  net  reduction in
  total  emissions svhile simultaneously mitigating the methane  from the landfill gas.
• Fuel  cells will be competitive at initial  product prices on  landfill sites  located in
  high electric cost areas or where [he thermal energy can be utilized. The fuel cell
  will also  be attractive where  there is a credit for the environmental  impact of fuel
  cell energy conversion.
• When the projected mature product price is achieved, fuel cells will  be competitive
  for most application scenarios. In many situations, fuel cells will provide net revenues
  to  the  landfill owners.  This could,  in  the  long term, result  in methane  mitigation
  without additional  cost to the ultimate consumer.
References

 1 (AS l-'edcral Register, May 30, 1991, Fart III Environmental Protection Agency, 40 CFR  Parts
   51. 52 .mil 60,  Standards ol Performance for New Statiorary Sources and Guidelines tor
   Control of pAistmj; Sources, Municipal Solid Waste Landfill!,; Proposed Rule, Guideline and
   Nonce ot  Puhhc Healing
 2 Air emissions from municipal solid waste landfills — background  information  for proposed
   si.md.irds  .mil L'mdelmes. KP.-\-450l3-90-Olla (NTIS  l'B91 -197061), Mar.  l'J9l. (a) p  3-30.
   (I)) p  .i-_\  (O I'.ihles 3 6, p[i  3-2S to  3-2K

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