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                         REFERENCES
    Energy and Environmental Analysis,  Inc., "Sources of Atmospheric
    Cadmium," Draft Report to EPA Under Contract No.  68-02-2836,
    February 1978.
2/
 '   Fulkerson, William, et al.,  Cadmium, The  Dissipated Element,
    BRNL-NSF-EP-21, January 1973, p.  63.

3//  Ibid.

4/
 '   Fulkerson, op. cit., p. 174.

 '   Fulkerson, op. cit., p. 6.

 '   Sargent, Donald, et al., Technical  and Microeconomic Analysis
    of Cadmium and Its Compounds, EPA 560/3-75-005, June 1975.

    Battelle Columbus Laboratories, Determination and Evaluation
    Environmental Levels of Cadmium,  EPA #68-01-1983, July 13,
    1977.

8/
 '   Deane, Gordon L., Lynn, David A., and Suprenant,  Norman F.,
    Cadmium: Control Strategy Analysis, EPA #68-02-1337, GCA,
    Bedford, Massachusetts, p. 150.

9'   Lee, Russell, et al., Single Source (CRSTER) Model, EPA 450/
    2-77-013, Research Triangle Park, North Carolina, July 1977.

    U.S. Department of Commerce, Master Enumeration District List,
    Bureau of Census, Technical Documentation, October 1970.

  '  Energy and Environmental Analysis,  Inc.,  "Economic Impact of
    New Source Performance Standards on Sinter Plants," Draft
    Report to EPA submitted April 29, 1977.

127
    Energy and Environmental Analysis,  Inc.,  op. cit., Reference
    #1.

  '  American Iron and Steel Institute,  Directory of Iron and
    Steel Works of the United States and Canada, Washington, D.C.,
    July 1977.

  '  Dun and Bradstreet, Metalworking Directory, 1976, New York.

    U.S. Bureau of Census, "Survey of Plant Capacity, 1975," un-
    published data, Washington, D.C., April 1977.
                              88

-------
  '  Battelle Columbus Laboratories,  op.  cit. ,  Reference #7.
  '  EEA,  op. cit. , Reference fl.
18/
    Fenton, R.,  "Present Status of Municipal  Incinerators,"
    Incinerators and Solid Waste Technology,  J.  W. Stephenson,
    et al., Ed., ASME, New York, New York,  1975.
19/
    Sargent, Donald, et al.,  op. .cit.,  Reference #6.
207
    International Directory of Mining and Mineral Journal, McGraw-
    Hill, New York, New York, 1976.
217
  '  Marketing Economics Key Plants,  1975-76,  New York.
227
    Battelle Columbus Laboratories,  op.  cit. ,  Reference #7.
237
    Deane, Gordon L., op. cit., Reference #8.
                               89

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-------

450R78102
                        DRAFT
          ATMOSPHERIC CADMIUM:
     POPULATION EXPOSURE ANALYSIS
          U.S. ENVIRONMENTAL PROTECTION AGENCY
              Office of Air and Waste Management
            Office of Air Quality Planning and Standards
           Research Triangle Park, North Carolina 27711

-------
                                                          DRAFT
         ATMOSPHERIC CADMIUM:
POPULATION EXPOSURE  ANALYSIS
                              by
                R. Coleman, J. Lent, E. Burns and P. Siebert
                 Energy and Environmental Analysis, Inc.
                       1111 North 19th Street
                           6th Floor
                      Arlington, Virginia 22209
                       Contract No. 68-02-2836
                  EPA Project Officer: Richard Johnson

                    Environmental Protection Agency
                      Pollutant Strategies Branch
                Research Triangle Park, North Carolina 27711
                          Prepared for

              U.S. ENVIRONMENTAL PROTECTION AGENCY
                   Office of Air and Waste Management
                Office of Air Quality Planning and Standards
                Research Triangle Park, North Carolina 27711

                          March 17, 1978      Envirorrr?i

-------
     This report was furnished to the Environmental Protection
Agency by Energy and Environmental Analysis, Inc., Arlington,
Virginia in partial fulfillment of Contract No. 68-02-2836
Tasks 3 and 6.  The contents of the report are reproduced
herein as received from the contractor.  The opinions, findings,
and conclusions expressed are those of the authors and not
necessarily those of the Environmental Protection Agency.

-------
                        TABLE OF CONTENTS
          TITLE                                            PAGE


ACKNOWLEDGEMENTS	 ii

EXECUTIVE SUMMARY	  1

SECTION I:      INTRODUCTION	  8

SECTION II:    CADMIUM IN THE ENVIRONMENT	 10

     A.   Introduction	 10
     B.   Physical and Chemical Characteristics
            of Cadmium	 10
     C.   Multi-Media Nature of Cadmium Exposures	 12

SECTION III:   METHODOLOGY	 17

     A.   Introduction	 17
     B.   Source Selection and Location	 17
     C.   Determination of Annual Concentrations	 18
     D.   Population Data	 19
     E.   Population Exposed	 20

SECTION IV:    IRON AND STEEL MILLS	 25

     A.   Introduction	 25
     B.   Geographic Distribution of Sources	 27
     C.   Estimated Ambient Levels	 27
     D.   Population Exposed	 30

SECTION V:     MUNICIPAL INCINERATORS	 35

     A.   Introduction	„	 35
     B.   Geographic Distribution of Sources	 36
     C .   Estimated Ambient Levels	 36
     D .   Population Exposed	 39

SECTION VI:    PRIMARY NON-FERROUS SMELTERS	 43

     A.   Introduction	 43
     B .   Geographic Distribution of Sources	 44
     C .   Estimated Ambient Levels	 44
     D .   Population Exposed	 49

-------
                  TABLE OF CONTENTS  (Continued)

         TITLE                                             PAGE

SECTION VII:   SECONDARY SMELTERS	  49

     A.   Introduction..	  51
     B.   Geographic Distribution of Sources	  51
     C .   Estimated Ambient Levels	  51
     D.   Population Exposed	  54

APPENDICES:

     APPENDIX A:    POPULATION EXPOSURE METHODOLOGY	  58

     APPENDIX B:    fi-lt  IRON AND STEEL MILLS  	-64

                    B-2:  POPULATION EXPOSED TO ATMOSPHERIC
                      CADMIUM FROM IRON AND  STEEL MILLS-...  70

     APPENDIX C:    C-l:  MUNICIPAL  INCINERATORS  	  76

                    C-2:  POPULATION EXPOSED TO ATMOSPHERIC
                      CADMIUM FROM MUNICIPAL INCINERATORS  .  Bl

     APPENDIX D:    PRIMARY SMELTERS  	  86

     APPENDIX E:    SECONDARY SMELTERS  	  87

REFERENCES	  88

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                        LIST OF TABLES
Table
Number     Title	     Page


    1      Study Results                                    3

    2      Population Exposed to Greater than 0.1 gn/m3
           of Cadmium                                       5
    3      Comparison of Cadmium Exposures Among
           Sources                                          6


 II-l      Physical Properties of Cadmium                  11

 II-2      Cadmium Content of Selected Adult Foods         15

 II-3      Media Contributions to Normal Retention of
           Cadmium                                         16


 IV-1      Cadmium Emission Factors for Iron and Steel
           Manufacturing                                   26

 IV-2      Assumed Stack Characteristics for Iron and
           Steel Mills                                     29

 IV-3      Measured Cadmium Levels in Cities Containing
           Iron and Steel Mills                            31

 IV-4      Estimate of Population Exposed to Concentra-
           tions >0.1 ng/m3 from Iron and Steel Mills      32

 IV-5      Estimate of Cumulative Population Exposed
           to Specified Cadmium Concentrations from
           Iron and Steel Mills                            33

  V-l      Cadmium Emission Factors                        35
  V-2      Assumed Stack Parameters for Municipal
           Incinerators                                    37
  V-3      Estimate of Population Exposed to Cadmium
           Concentrations £0.1 gn/m3 from Municipal
           Incinerators                                    39

  V-4      Estimate of Cumulative Population Exposed
           to Specified Cadmium Concentrations from
           Municipal Incinerators                          41

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LIST OF TABLES CONTINUED
Table
Number
VI- 1
VI-2
VI- 3
VI- 4
VII-1
VII-2
VII- 3
VII-4
Title
Emission Factors for Primary Smelters
Primary Smelters
Measured Cadmium Levels Near Primary
Smelters
Estimate of Population Exposed to Cadmium
Concentrations from Primary Smelters
Emission Factors for Secondary Smelters
Location of Secondary Zinc and Copper
Smelters
Assumed Stack Conditions for Secondary
Smelters
Estimate of Population Exposed to Specified
Levels from Secondary Smelters
Pa 9
45
46
48
50
52
53
54
56

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LIST OF FIGURES
Figure
Number
1
III- 1
III- 2
Title
Regional Breakdown
Population of Charlottesville, Virginia
Population of Washington, D.C.
Page
7
21
22

-------
                       ACKNOWLEDGEMENTS
     Preparation of this report by Energy and Environmental
Analysis Inc., was carried out under the overall direction
of Mr. Robert Coleman.  Special assistance was received from
Messrs. James Lent,  Paul Siebert,  Craig Miller,  and Ms.
Elizabeth Burns of EEA.

     EEA gratefully acknowledges the assistance, helpful
suggestions and review of the EPA Task Officer Mr.  Richard
Johnson.

     The conclusions presented in the study are, of course,
solely the responsibility of Energy and Environmental
Analysis, Inc.

-------
                      EXECUTIVE SUMMARY
     This report is one of a series of reports which will be
used by EPA in responding to the Congressional mandate under
the Clean Air Act Amendments of 1977 to determine whether
atmospheric emissions of cadmium post any threat to public
health.  This report identified the population exposed to
specified cadmium levels from selected point sources.  A
companion report ' had identified the specific sources of
interest.

     Although cadmium is a true multi-media pollutant this
report focuses only on ambient air concentrations of cadmium.
Even though significant exposures of cadmium are caused by all
media and atmospheric emissions may contribute to other media
through various deposition mechanisms these are not considered
here.  This report focuses on the exposure caused by specific
stationary sources.  The sources considered are iron and steel
mills, municipal  incincerators, primary smelters  (zinc, copper,
lead, cadmium), and secondary smelters  (copper and zinc).

Methodology

     The basic methodology used in this report involved the
following procedures:

     •  Determination of the size and location of each
        source within each source category.   In this
        regard, size data were obtained from  trade
        directories, etc., and locations  from United
        States Geologic  Survey  (USGS)

-------
     •  Determination of annual concentration
        caused by each source within each source
        category.  For this purpose, annual
        concentration of cadmium caused by each
        were developed and were determined using
        general diffusion models and model plants.

     •  Determination of population exposed by
        each source.  Estimates of annual con-
        centrations due to each source and 1970
        Census data were combined to give an
        estimate of the population exposed by
        each source.

     As would be expected in any analysis of this type,
many assumptions were made based on limited data.  Analysis
was carried out on a very detailed level and errors are
possible stemming from:  source size and location, the actual
emissions of cadmium from each source, the type and efficiency
of control technologies employed at each source, and the
general nature of the dispersion modelling.  In all cases, the
best data available were used.  The estimates of population
exposure should be considered to provide a reasonable accurate
estimate of the number of exposed individuals.

Results

     Table 1 shows a summary of the results of this analysis.
This table shows the population exposed to concentration greater
the 0.1 ng/m , the the average level to which this population is
exposed and the total exposure (expressed as nanagrams-person-
year) caused by each source type.  As shown in Table 1, municipal
     This is approximately the current level of detectability for
     cadmium.

-------
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incinerators are the chief contribution to the population ex-
posed; have the highest annual average; and cause the greatest
exposure.  The chief source of cadmium in incinerators is the
combustion of plastics containing cadmium stabilizers and the
combusion of materials with cadmium containing paint.

     Iron and steel production is the second most significant
source in each catagory.  Cadmium emissions from this source
result from the processing of steels coated with zinc or cadmium.

     Table 2 shows the population exposed to cadmium levels
greater than 0.1 ng/m  by region.  The regional breakdown shown
on Table 2 is based on EPA regions shows in Figure 1.

     It is evident from the data on Table 2 that municipal
incinerators in the Northeast and Midwest expose the largest
number of people and also cause high average exposures.  Iron
and steel mills rank second in exposure.  None of the other
sources appear to expose a large number of people.

     Table 3 shows a regional breakdown of the exposure  (expres-
sed in nanograms per person-year) due to each source type.
Again, municipal incinerators dominate the list, with iron and
steel mills ranking second.  Also, as before, the Northeastern
and Midwest areas show  the highest levels.

-------
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                         SECTION I
                        INTRODUCTION
     This report is one in a series of reports which will
assist EPA in responding to the Congressional mandate in Section
122 of the Clean Air Act Amendments of 1977.  Under this Section
of the act, EPA is required to review the current data on the
health and welfare effects of cadmium (as well as other substances)
and determine "whether or not emissions of... cadmium...into the
ambient air will cause, or contribute to, air pollution which
may reasonably be anticipate to endanger public health."

     This report addresses one area of information needed
to make this determination—the estimation of the population
exposed to atmospheric levels of cadmium from "significant
cadmium sources"  (those source types for which individual plants
can produce an ambient concentration of 0.1 ng/m  on an annual
basis.)  This report draws no conclusions as to the health
consequences of atmospheric cadmium levels, nor does it provide
a total estimate of the population exposed to specified cadmium
levels.  Rather, the purpose of the report is to provide a
relative ranking of sources by magnitude of population exposed
and to present this information in such a way that EPA can make
estimates of the health implications of the reported exposures.

     The report is organized into several sections summarized
below:

     •  SECTION II provides an overview of the physical
        and chemical properties of cadmium as well as
        the routes through which human exposures to
        cadmium could  occur.

-------
     •  SECTION III provides an overview of the  metho-
        dology  used in the report.

     •  SECTIONS IV through VII provide  estimates of
        the population exposed to cadmium emissions
        from selected sources.  The sources consider-
        ed are:

        Section IV—Iron and Steel Mills
        Section V—Municipal Incinerators
        Section VI—Primary Smelters (copper, lead, zinc,
           and cadmium)
        Section VII—Secondary Smelters (cooper and zinc)

     The background data for this report is based primarily on
information presented in a companion report   which focused on:

     •  the development of cadmium emission factors;

     •  the estimation of total atmospheric emissions
        of cadmium from all sources; and

     •  the screening of sources to determine if indi-
        vidual sources within a source category can
        cause measurable ambient levels of cadmium
        (based on the annual average).

Many of the assumptions and information used in this report are
documented in the companion report.

-------
                         SECTION II

                 CADMIUM IN THE ENVIRONMENT
A.  Introduction
    This section discusses the physical and chemical properties
of cadmium and the multi-media nature of cadmium exposures.  Al-
though this report focuses only on atmospheric exposures to cad-
mium, it is important to keep in mind that there are many other
types of human exposure to cadmium including food, water, and
tobacco smoke.

B.  Physical and Chemical Characteristics of Cadmium

    Cadmium is a relatively rare element in the earth's crust.
It occurs at a concentration of 0.1 to 0.5 ppm.  It is of low
abundance, ranking between mercury and silver, and thus, not in
                                            2/
sufficient quantities to be mined as an ore. '  Table  II-l
shows the physical properties of cadmium.  Cadmium is always
associated with zinc and is usally present as sulfide.

    The most important characteristic of cadmium, from an air
pollution viewpoint, it its high volatility.  This is evidenced
by its low melting  (312° C) and boiling  (765° C) points.  Thus,
any high temperature process, such as metallurgical processes
 (e.g., steel-making, sintering) or incineration, are likely to
release whatever cadmium is present in the feed.
                               10

-------
                           TABLE  II-l




              PHYSICAL PROPERTIES OF CADMIUM
         a,b/
Atomic Number



Atomic Weight



Color



Crystal Structure




Hardness



Ductility



Density



     20°C  (68°F)(solid)



     330°C  (626°F)(liquid)



Melting point



Boiling point



Specific heat



     25°C  (77°F)(solid)



Electrochemical  equivalent



     Cd"1"1"  ion



Electrode  potential



     Cd++  ion
48



112.41



silver-white



hexagonal pyramids



2.0 Mohs



Considerable








8.65 g/cc



8.01 g/cc



321°C  (609.8°F)



767°C  (1412.6°F)








0.055 g-cal/g








0.582 mg/coulomb








-0.40 volta//
a/ From Reference  4



   National Bureau of  Standards nomenclature, H,
                               11

-------
     Vaporized cadmium metal is quite reactive and should react
very quickly to form an oxide,  sulfate,  or other compound.  In
these forms, cadmium is quite stable and of very low solubility
in water.

     Cadmium metal is very ductile, easily soldered, can be
                                                              4 /
readily electroplated, and maintains a lustrous finish in air. '
These properties lead to the use of cadmium as a protective
coating on iron and steel products.

C.  Multi-Media Nature of Cadmium Exposures

    While this report is focused on atmospheric emissions of
cadmium, it is important to recognize the overall cycle of cadmium
in the environment.  Measurable levels of cadmium occur in all
phases of environmental concern (air, water, food, solid waste),
and in almost all areas.  One author ' refers to cadmium  as the
"dissipated element."  EPA in 19756' estimated that about 1,800
Mg/year of cadmium was lost to the environment.  Of this, about
18 percent was in atmospheric emissions,  75 percent in solid
waste, and the remainder in water-borne emissions.

     Measurable cadmium levels have been  found in air, water,
soil, and food.  Atmospheric concentrations generally have been
measured in the center of urban areas and generally range from
ten ng/m  down to below the detectable limit.  Typical urban
concentrations are in the range of three  ng/m  .  Due to the
low solubility of cadmium compounds, levels of cadmium in
water supplies are generally low.  Main sources of cadmium
are discharges from mining operations, leaching from soil
disposal of wastes, and fall-out from atmospheric emissions.
                               12

-------
     Cadmium in food results from a wide variety of sources.
Listed in order of importance from a recent Battelle Report,
they are:

     1.  Direct contact by plants or uptake from soils
         by plant roots.

         a.  Naturally as a normal constituent of
             soils, particularly of marine origin.

         b.  As an impurity (cadmium oxide) in
             phosphate-treated soils, especially in
             those treated with "superphosphate."

         c.  By fertilization with sludge con-
             taining cadmium.

         d.  By desposition of cadmium-containing
             pesticides or as a contaminant of
             zinc-containing pesticides.

         e.  From run-off of mine tailings or from
             electroplating washing process.

     2.  Accumulation in animal tissues due to:

         a.  Feeding on crops which have absorbed
             cadmium (the organs of such animals
             may have very high cadmium concentrations)^

         b.  Treatment with cadmium-containing hel-
             minth killers ^used especially in swine.
                               13

-------
     3.   Concentrations of cadmium by molluscs,
         crustaceans and most other aquatic organisms
         from ambient waters.

     4.   Use of zinc-galvanized containers, cans,  cook-
         ing implements or vessels, or utensils used in
         food preparation, particularly grinders,  press-
         ing machines, or galvanized netting used  to dry
         fish and gelatin.

     5.   Absorption of cadmium contained in wrapping
         and packaging materials such as paper, plastic
         bags, and tin cans.

     6.   Use of cadmium-contaminated water in cook-
         ing or processing operations.

     Table  II-2 lists the average cadmium concentration of
selected adult foods.

     Cigarette smoking also provides a large contribution to
total cadmium exposure.  The estimated intake from two packs per
day ranges from four to six micrograms.  This can amount to about
20 times the exposure due to atmospheric levels in large urban
areas.

     Even for smokers, food provides the greatest overall exposure
to cadmium, and based on a 6.4 percent retention rate, the greatest
daily input  (except for three packs-per-day-smokers).  Table
II-3 summarizes the sources  of cadmium exposure.
                             14

-------
                           TABLE II-2
           CADMIUM CONTENT OF SELECTED ADULT FOODS
                                                   a/
                                                          Standard
Commodity
Carrots, roots fresh
Lettuce, raw crisp head
Potatoes, raw white
Butter
Margarine
Eggs, whole fresh
Chicken fryer, raw
  whole or whole cut up
Bacon, cured raw, sliced
Frankfurters
Liver, raw beef
Hamburger, raw ground beef
Roast, chick beef
Wheat flour, white
Sugar refined, beet or cane
Bread, white
Orange juice, canned frozen concentrate
Green beans, canned
Beans, canned with pork and tomato sauce
Peas, canned
Tomatoes, canned
Diluted fruit drinks, canned
Peaches, canned
Pineapple, canned
Applesauce, canned
NO. Of
Samples
69
69
71
71
71
71
71
71
69
71
71
71
71
71
70
71
71
71
71
71
71
71
71
71
Average
ppm
0.051
0.062
0.057
0.032
0.027
0.067
0.039
0.040
0.042
0.183
0.075
0.035
0.064
0.100
0.036
0.029
0.018
0.009
0.042
0.042
0.017
0.036
0.059
0.020
Deviation,
ppm
0.077
0.124
0.139
0.071
0.048
0.072
0.088
0.160
0.111
0.228
0.122
0.034
0.150
0.709
0.063
0.095
0.072
0.000
0.113
0.113
0.052
0.061
0.153
0.027
a/
     Source:  Reference 8
                               15

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                         TABLE  II-3

           MEDIA CONTRIBUTIONS TO NORMAL RETENTION

                        OF CADMIUM*/
  Medium              Exposure Level           Daily  Retention
a'   Source;  Reference  8.
     Based on 0.11  pg  per  cigarette.
c/
 '   Assumes a  6.4  percent retention  rate.
Ambient air               0.03 yfl/m                   0.15
Water                       1 ppb                     0.09
Cigaretts :
  Packs/Day               yig/day '
     1/2                    1.1                       0.70C/
      1                     2.2                       1.41C/
      2                     4.4                       2.82C/
      3                     6.6                       4.22C//
Food                      50  yg/day                   3.0
                               16

-------
                         SECTION III

                         METHODOLOGY
A.  Introduction

    This section describes the general methodology used in deter-
mining the population exposed to specified levels of cadmium.
In simplest terms, the methodology can be view as having four
components:

     •   Selection  and  location of  significant  sources
         of  cadmium and estimation  of  emissions  from  those
         sources;

     •   Determination  of  ambient concentrations of
         cadmium caused by these sources;

     •   Development  of a  population data base;  and

     •   Integration  of estimated cadmium concentrations
         with  the estimates of population residing in
         that  area.

B.  Source  Selection and  Location

    Based  on  the results  of  the companion  study, noted pre-
viously, which screened all  potential cadmium  sources  on the
basis of measurable  contribution to annual average ambient levels
                   *
levels  of  cadmium,   four  source categories were selected for
exposure analysis:
                                               3
    Cadmium  annual  averages  as  low  as 0.1 ng/m   are  assumed mea-
    surable.
                             17

-------
           (1)   Iron and Steel Mills
           (2)   Municipal Incinerators
           (3)   Primary Smelters (copper, lead,
                  zinc, and cadmium)
           (4)   Secondary Smelters  (copper and
                  zinc

     Information on the precise nature and capacity of each
source in the above categories was obtained from various trade
directories and other data sources which are of recent vintage
(generally 1976 or 1977).  The sections of this report which
deal with individual emission sources list the specific
references used.

     Most of these references also provided street addresses
and zip codes for individual plants.  From USGS maps, street
were identified within the zip code and in this way, relatively
precise locations for each source were obtained.

     This method of locating sources is relatively accurate,
generally to within one to two km.  This is a satisfactory
level of accuracy given the accuracy of other data items.
(The sections dealing with the individual source types include
the location and size of each source).

     In estimating emissions from each source, "best judgement"
emission factors which were developed in the companion report
to this study were used.  Variability of emission factors for
individual sources and  among source types can be quite large.
Emissions were  computed assuming that facilities are operated
at their nominal capacity.

C.   Determination of Annual Concentrations

     Annual concentrations for each type of plant were computed
                                         9/
by using an EPA diffusion model, CRSTER.   The annual concentration
                              18

-------
of model plant types were then determined.  These model plants
were designed in such a way as to represent the probable ranges
of typical industrial facilities.  The factors which were varied
to define the model plants were:  stack height, flow rate and
temperature.  Surface meteorological data from Dallas/Fort Worth
and upper air data from Oklahoma City were used in the analysis.
These sets of data ever used because the meteorology is understood
to be fairly typical of many areas in the country in terms of
wind speed and stability classes.  If a detailed analysis of
any of the sources identified here were conducted in the future,
more site-specific meteorological data would be sesirable.

     Detailed descriptions of the particular assumptions used in
the analysis of each source type are discussed in the following
sections.      '

D.  Population Data

    The population data were obtained from the 1970 Master Enu-
meration District List  (MED List)    obtained from the Bureau of
the Census.  This list provides the population and geographic
location of each enumeration district in rural areas and of each
block group within urban areas.  An enumeration district contains
approximately 800 people and is no larger than the area one
enumerator could reasonably be expected to cover.  A block group
consists of continguous city blocks with a total population of
about 1,000.  In a central business district, the block groups
are further subdivided into individual blocks.  The geographic
locator for each of these three census divisions is the latitude
and longitude coordinate of the centroid of the division.

     The population data associated with these centroids were
transferred to a grid which spans the contiguous United States.
Each grid cell was 1/30 of a degree longitude by 1/30 of a degree
latitude.  Thus, this resulted in the average grid cell being
                                 19

-------
approximately ten square kilometers.  With this grid cell size,
reasonably adequate definition was developed.  Figure II-l
illustrates an example of a medium size town and its environs.
For this example, the population of the city itself shows up in
six different grid cells.  The city's suburbs show up in several
additional cells.  In the rural areas of the map, the population
of individual enumeration districts appear as a single grid cell
entry.  In rural areas the grids which show zero population do
not necessarily have no population but rather these areas are
part of an enumeration district and all population in each enu-
meration is shown at the centroid of each enumeration district.
Figure II-2 illustrates an example of a large metropolitan area.
As one moves from the central city area westward towards the
suburbs, a very definite population gradient can be observed.
Grid cells within the city which contain large areas of public
land appear as lower density grid cells.

     The actual transfer to the grid was made as follows:  the
population of every enumeration district and of every block
group whose centroid was located in a given two-minute-by-two-
minute grid cell was summed to give the population of the grid
cell.  The information for each of 26 areas or maps which described
the county was stored in a matrix.  After all 26 maps were con-
structed, a count was made of the number of people loated by
this method.  The toal of 201,744,383 accounts for 99.5 percent
of the 1970 population of the contiguous United States.

E.  Population Exposed

     The purpose of the model developed in this chapter is to
integrate the data on source location, and resulting ambient
concentrations caused by the source, with the population data
described above  thus determining the number of people exposed
                                20

-------
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-------
to specified levels of cadmium. The methodology used is des-
cribed in detail in Appendix A.  As described in this Appendix,
two independent procedures were used to estimate population
exposed.   In brief terms, the two procedures are:

     1.  Total Exposure

     This procedure involves locating a source by latitude and
longitude and, through emissions and diffusion modelling,
determining the radius at which specified concentrations occur.
Once the radius is determined, the population in population grids
completely contained in the radius were determined.  After this,
the population in each partially covered grid is determined based
on the percent of the grid circumscribed by the radius.

     This procedure is carried out on a source-by-source basis.
If people are exposed to more than one source, they would be
counted twice.  The primary use for this result is in determining
the total exposure  (nanograms-person-year) caused by specific
source types.  This type of estimate is suitable for use in a
linear health risk model  (i.e., such models which treat two
people exposed to one ng/m  as equivalent to the risk of health
effects as one person exposed to two ng/m ).

     2.  Population Exposed.

         In addition to estimating total exposure, the model
was applied to estimate the population exposed to specified levels
of atmospheric cadmium. As in the case of the exposure modelling,
the population estimate was developed from a source-by-source
analysis.  However, in this procedure, the result is the pop-
ulation exposed to  a given concentration from at least one source.
                               23

-------
     This form of the model provides an estimate of the pop-
ulation exposed to specified concentrations.  The purpose of
this form of the model is to estimate the gradient in exposure
levels caused by source catagories.  However, the estimates
do not take into account that a person can be exposed to more
than one source and that the actual level of exposure is the
sume of the concentrations produced by the sources.  As such,
the estimates of population, to some degree, may underestimate
the population exposed to high concentrations.
                               24

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                           SECTION  IV

                       IRON AND  STEEL MILLS
*A.   Introduction

     The estimation of population exposure to atmospheric cadmium
 emitted from the production of iron and steel is discussed in
 this section.

     The primary sources of cadmium emissions from iron and steel
 manufacturing are the use of scrap containing cadmium in steel-
 making furnaces and,  to a much lesser degree, the cadmium in the
 coal used to make coke.  Table IV-1 lists the emission factors
 used in analysis.

     One of the source types listed in Table IV-1 (sinter plants)
 does not involve the  use  of  cadmium scrap directly.   Sincere  plants
 agglomerate fine iron-containing material (iron ore,  flue dust,
 etc.)  into a material suitable for use in the blast furnace.  Due
 to  decreases in the amount of natural iron charged to blast fur-
 naces and increasingly stringent air pollution control requirements
 on  steel-making furnaces, more and more of the feed to sinter
 plants is fine dust collected from steel-making furnaces.  '

      This resultant change in feed to sinter plants leads to the
 charging of relatively large amounts of cadmium to the sinter
 plant.  Therefore, even with relatively high levels of air pollu-
 tion control (90 percent), significant amounts of cadmium can be
 released.  The companion volume of this report discusses the
 emissions of cadmium from iron and steel production in considerable
 detail.
                                25

-------
Bept
Judgement
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B.  Geographic Distribution of Sources

    The location of iron and steel-producing facilities in the
United States is show in Appendix B.  The primary source of
capacity estimaded in this table comes from the American Iron
and Steel Institute's Iron and Steel Works Directory of the
United States and Canada.  '   Locations of these facilities
were determined from the Dun and Bradstreet Metal-Working
         147
Directory  '  and USGS maps.

    Appendix B also shows the estimated cadmium emission rates
from each facility.  These estimates were derived by multiplying
the emission factors from Table IV-1 by the production for
each facility type, assuming that all plants operate at the hours
of operation defined by the Department of Commerce as full
operation.     It must be emphasized that these emission factors
are average emissions based on national average uses of cad-
mium scrap or on a limited number of stack tests.  As such, it
is likely that some over-estimates of emissions result from
some sources and underestimated emissions from others.  However,
on the average, these emission estimates probably provide an
adequate basis for the purpose of this analysis.

C.  Estimated Ambient Levels

    Estimates of annual concentrations of cadmium from iron and
steel manufacturing are complicated by the large size of inte-
grated mills and their wide variation in size.  Large inte-
grated mills can cover hundreds of acres and may have many
stacks.  Mini-mills, or scrap reprocessing facilities with a
low number of small electric arc furnaces, may cover only a
few acres and have few stacks.  Due to a lack of information on
the physical size of all the facilities, it was assumed that
all stacks were located together.  In addition, conservative  (i.e.,
conditions not conducive to good dispersion) assumptions were
                              27

-------
made concerning stack characteristics.  All stacks were assumed
to have the characteristics as shown on Table IV-2.  The
flowrate assumed for the iron and steel stacks is an average
figure for all types of units.  The net effect of these
assumptions is to overestimate the air quality impact of the
facilities to some unknown degree.

     Based on the stack conditions shown in Table IV-2 and the
results of a CRSTER model run  (with Dallas/Fort Worth meteorology)
for a few selected distances from the source, a regression equation
was developed which estimates the concentration resulting from a
1.0 g/sec emission rate at any distance.  From iron and steel
plants, the equation developed was:

              LnY - 1.71  (InX) - 2.35  (1/X) + 3.19         (1)

where:  Y is the concentration (ng/m  ) caused by an emission
rate of 1.0 g/sec of cadmium and X is the distance from the
source to the receptor point  (Km).  This equation has a co-
efficient of determination of greater than 0.99 as a predictor
of ambient concentrations computed by CRSTER run.

     The emission rate  for each plant was multiplied by the
computed concentration  ratio to provide and estimate of con-
centration at any distance.  Modelling results were not carried
out beyond 20 km due to the questionable validity of this type
of dispersion modelling beyond these  distances.

     Current monitoring programs are  not designed to measure
maximum impacts of point  sources such as iron and steel mills.
However, some indication  of the plausibility of both the modelling
techniques and  the emission estimates can be made by comparing
measured levels in areas  with  major  iron and  steel  facilities with
the concentrations predicted  by  the modelling technique.
                               28

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           TABLE IV-2





  ASSUMED STACK CHARACTERISTICS




    FOR IRON AND STEEL MILLS
Stack Height     100 feet
Temperature      250°F
Diameter         8 feet






Flow             125,000 cfm
                29

-------
     Ambient cadmium levels can vary greatly from year to year
the little data available shown (Table IV-3) that annual average
levels from five to 10 ng/m  are not uncommon.  Of course, in
these cities, the observed levels cannot be attributable solely
to iron and steel mills since other sources are quite likely
present.  Estimated annual cadmium levels from iron and steel
mills developed in this study using the technique described
above are also five to ten ng/m .  This suggests that, although
very conservative assumptions were used, the estimated con-
centrations from iron and steel mills are reasonable.  However,
the actual degree of precision of these predicted levels cannot
be determined reasonably.

D.  Population Exposed

    Table IV-4 shows an estimate of the population exposed to
cadmium concentrations greater than 0.1 ng/m  and the estimated
average concentration to which each of the  exposed populations
is subjected.  The regional breakdown shown on Table  IV-5 is based
on EPA regions as shown on Figure IV-1.  As discussed in  Section III,
these estimates were obtained by super-imposing the modelled
ambient concentrations caused by emissions  from iron  and  steel
mills on the distribution of population.

     As would be expected, both the largest number of people exposed
and the highest average exposures are in EPA  Regions  III, IV,  and
V.  This is due to the large concentration  of integrated  steel
mills in the Pittsburgh, Birmingham,  and Gary areas, respectively.

     Table IV-5 shows a breakdown of  population by exposure  level.
As described in the methodology  section, care must be used  in  in-
terpreting the results of this table  due to the potential for
exposure caused by several sources.   As explained in  the  meth-
odology section and Appendix A, the results on Table  IV-5 should
                                30

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                          TABLE IV-3


               MEASURED CADMIUM LEVELS IN CITIES

              CONTAINING IRON AND STEEL MILLS
                           Annual
     Cits
East Chicago, IN


Ashland, KY


Youngstown, OH


Cleveland, OH


Allentown, PA


Bethlehem, PA
B (ng/irr')
4.6
6
5.6
8.8
13.4
6.8
Year
1974
1974
1970
1970
1974
1973
                                                           b/
a/
b/
Source: Reference 16.

Data reported for the latest year measurements are
available.
                             31

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                  TABLE IV-4





        ESTIMATE OF POPULATION EXPOSED




         TO CONCENTRATIONS > 0 .1 ng/m3




           FROM IRON AND STEEL MILLS
                   Average
Population
Region
1
2
3
4
5
6
7
8
9
10
Exposure
0.
1.
2.
2.
1.
1.
1.
-
1.
0.
(ng/m )
4
4
7
8
5
5
2

.2
.7
liu peopj-e;
93
1,649
4,543
1,611
8,710
1,575
108
—
778
833
TOTAL
                       1.8
     19,900
                      32

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                        TABLE IV-5




   ESTIMATE OF  CUMULATIVE POPULATION EXPOSED TO SPECIFIED




     CADMIUM CONCENTRATIONS FROM IRON AND STEEL MILLS




                          (10  people)




Region         	Annual Concentration  (ng/m )

1
2
3
4
5
6
7
8
9
10
>10
0
0
52
177
143
0
0
0
0
0
>5
0
49
137
341
339
29
0
24
15
0
> 1
0
470
1,965
578
1,852
521
23
176
161
33
>0.1
93
1,649
4,543
1,610
8,710
1,575
108
224
774
833
                              33

-------
be interpreted as the population exposed to a concentration
greated than or equal to that specified from at least one
source.  As such, the total population estimated is accurate,
but the distribution has some bias towards the lower concentration
levels.

     Appendix B shows the population exposed to individual sources,
                               34

-------
                           SECTION V

                    MUNICIPAL INCINERATORS
A.  Introduction

    This section estimates the population exposed to cadmium
emitted from municipal incinerators.

    Cadmium emissions from incinerators originate from the com-
bustion of cadmium-containing waste materials.  These waste mate-
rials are plastics which contain cadmium as a stablizer, cad-
mium-plated materials, nickel cadmium batteries, and materials
painted with cadmium-based pigments.

    Cadmium is released from incinerators due to its low boiling
point (765°C) and the considerable higher  ( > 1,400° C) tempera-
tures characteristic of incinerator combustion.  The estimated
cadmium emission factors for incinerators are shown in Table V-l.

                          TABLE V-l

                    CADMIUM EMISSION FACTORS17/
               Emission Factor  (Ibs/ton of refuse)

                                           Controlled
                                                  _2
   Best Judgement                           1.2x10
   Maximum                                  1.0xlO~
                                                  -4
   Minimum                                  6.0x10

A large amount of variability among incinerators in emissions can
be expected because of variations in input feed rate,  feed
                              35

-------
composition, combustion temperature (and other operating con-
ditions) , and control equipment efficiency.  This variability
cannot be taken into account in this type of analysis.

B.  Geographic Distribution of Sources

    Appendix C lists the locations and capacities of municipal
incinerators analyzed in this study.  The primary source of this
                                                        18/
capacity data is Incinerator and Solid Waste Technology.  ' The
facilities were located by street address through a telephone
survey of each town and city.  Street addresses were translated
into latitude and longitude coordinates from detailed USGS maps
(seven and a half minute quadrangles) for integration with the
population data.

    Appendix C also shows the estimated cadmium emissions from
each incinerator.  The emissions shown are simply the product of
the "best judgement" emission factors and daily capacity figures.
As previously mentioned, wide variation in these estimates can be
expected due to variation in cadmium feed and control efficiency.

C.  Estimated Ambient Levels

    Estimates of ambient levels due to cadmium emissions from
incinerators were based on the results of CRSTER runs using
Dallas/Fort Worth meteorology.  Four combinations of  stack
height  and  flow rate were used to represent the range of current
proactice.  Table V-2  shows  the stack parameters used in this
analysis.   The data  in Table V-2 are based on engineering  judge-
ment; it  is recognized that  considerable divergence from these
assumptions may be possible.

    As  in the case of the iron and  steel analysis, the  equations
relating  ambient concentrations to  distance are based on the
CRSTER  runs.  These  equations extend the CRSTER results to cover
                              36

-------
                            TABLE V-2


                     ASSUMED STACK PARAMETERS

                    FOR MUNICIPAL INCINERATORS
Incinerator
   Size
 (tons/day)

 >1,000


 300-1,000


  150-300


  <150
Stack
Height
(ft.)

 125
 125


  50


  50
Temperature   Diameter
    (°F)         (ft)
250


250


250


250
                 12
                  3


                  2
 Flow
(acfm)

210,000


 50,000


 25,000


  5,000
                                37

-------
all distances of interest.  The equations developed are shown
below:
        For capacities of 1,000 tons/day
        LnY = -1.58  (InX) - 3.05  (1/X) + 2.78
(1)
     •  For capacities between 300 and 1,000 tons/day
        LnY = -1.75  (InX) - 2.07  (1/X) + 3.26            (2)

     •  For capacities between 150 and 300 tons/day
        LnY = -1.60  (InX) - 0.57  (1/X) + 3.16            (3)
        For capacities less than 150 tons/day
        LnY = -1.53  (InX) - 0.05 (1/X) + 3.04
(4)
where:  Y is the concentration  (ng/m  ) caused by an emission  of
1.0 g/sec of cadmium and X is the distance to the receptor  point
(km) .

     These equations all had a  coefficient of determination
greater than 0.99.

     Concentrations caused by each plant were computed  by multiply-
ing the plant emission  rate in  grams/second by  the concentration
resulting from  a 1 gram/second  emission rate.   As with  the  iron
and steel mills, modelling results were not carried out beyond 20
km.

     Very high  cadmium  concentrations were computed from some in-
cinerators using this techniques.  The relatively low stack heights,
typical of many urban incinerators, lead to low plume rise and very
high  (  > 100 ng/m  ) localized concentrations.   These  high concen-
trations occur  very near  ( < 1.5  km)  the  source but drop off
quickly so that within  5 km of  the source  they  are down to  less
           3
than  1 ng/m  .   Most incinerators  are  located  in urban areas
where there  are multiple smaller  sources  of cadmium probably
                              38

-------
distributed in a non uniform spatial pattern.  Existing monitoring
programs, therefore, do not provide an adequate basis to judge,
even qualitatively, the precision of these modelling results.

D.  Population Exposed

    Table V-3 shows the estimate of the population exposed to
cadmium concentrations greater than 0.1 ng/m  originating from
incincerators and the average concentration to which each person
is exposed.  The regional breakdown shown on Table V-3 based on
EPA regions.

     The greatest number of people exposed and the highest aver-
age concentration are in EPA Region II, which includes New York
and Pennsylvania.  Each state has a large number of incinerators
located in high density urban areas (New York City and Phila-
delphia) .  Region V has the second highest number of people ex-
posed.  In this region, the average concentration is much lower
than in Region II.  This is due primarily to the more dispersed
nature of a smaller number of incinerators located in high density
areas (Chicago).  The opposite situation occurs in Region VI
where a relatively small number of people (one million) are
exposed, but the average concentration is high.

     Table V-4 shows a breakdown of population exposure by level.
As described in the methodology section, care must be used in
interpreting these data.  As the average exposure level decreases
the population exposed increased very quickly, as does the degree
of multiple counting.  This happens because the concentrations
decrease from their maximum rather slowly and concentrations above
the 0.1 ng/m  can  occur at distances out to 20 km and beyond.
                                39

-------
                           TABLE V-3


                ESTIMATE OF POPULATION EXPOSED


              TO CADMIUM CONCENTRATIONS >0.1 ng/nf

                   FROM MUNICIPAL INCINERATORS
Region


   1


   2


   3


   4


   5
     Average
Exposure  (ng/ro3)
Population
(103 people)
   8


   9


  10
6.1
11.4
4.6
4.0
5.4
10.4
3.3
3.4
6,571
15,163
8,742
2,995
12,501
1,122
1,760
173
        TOTAL
       7.2
  49,026
                                40

-------
                        TABLE V-4




   ESTIMATE OF CUMULATIVE POPULATION EXPOSED TO SPECIFIED




     CADMIUM CONCENTRATIONS FROM MUNICIPAL INCINERATORS




                          (10  people)




Region	Annual Concentration  (ng/m  )

1
2
3
4
5
6
7
8
9
10
>10
409
336
369
31
458
59
0
3
0
0
>5
1,209
3,319
1,390
390
2,252
310
133
36
0
0
>1
4,762
11,697
5,363
2,315
8,182
906
1,022
128
0
0
>
6
15
8
2
12
1
1



0.1
,570
,163
,742
,995
,501
,122
,760
173
0
0
                               41

-------
At these distances, the areas of influence of many incinerators
will overlap due to their proximity to each other in urban
locations, and thus, include large proportions of densely
populated urban areas.

     Appendix C lists the population exposed to each municipal
incinerator.
                                42

-------
                         SECTION VI

                PRIMARY NON-FERROUS SMELTERS
A.  Introduction

    Cadmium is found in significant quantities combined with  zinc
and to a much lesser degree, with lead and copper.  The source of
cadmium emissions from all smelters is basically the same.  During
high temperature pyrometallurgical processing cadmium, which
has a lower boiling point than other metals, is vaporized and
released.  The differences in cadmium emissions among  the primary
smelters are briefly discussed below.

    The amount of cadmium released into the atmosphere varies for
different zinc production processes.  The pyrometallurgical pro-
cess used at older plants (of which only three are still in existence)
first roasts the ore at temperatures between 900 and 1,000°C  to
drive off S0_ and produce a concentrate.  Following this operation,
the ore is sintered to provide a product which is easier to handle
and retort.  The final step is the reduction of zinc oxide to
zinc in a retort.

    Both the roasting and sintering steps appear to have the
highest potential for cadmium emissions.  One recent report,
however, indicates that due to an excess of oxygen, close
temperature control  (900-1,000 C) , and the high efficency of
existing air pollution control, little cadmium is emitted from
the roaster.  This hypothesis is supportable.3/
 l'   In all existing zinc smelter, the SO«-rich offgas from the
     roaster goes to a sulfuric acid plant.  Since cadmium oxide
     is soluble in sulfuric acid, the recovered acid should show
     high cadmium levels if large amounts of cadmium are leaving
     the roaster.  Cadmium levels reported in the recovered acid
     are quite low.19/
                                 43

-------
Sintering operations appear, therefore, to be the primary cadmium
emission point.

     Since electrolytic operations use concentrate directly from
the roasting operation and do not subject the concentrate to
elevated temperatures, there appears little potential for cadmium
emissions.  Thus, cadmium emissions from this process are assumed
to be zero for this analysis.

     Cadmium emissions from lead and copper smelting result from
similar high temperature such as sintering operations.  Cadmium
is present in most lead ores and some copper ores,  and is  released
during high temperature processing.

     Table VI-1 shows the estimated emission factors for primary
smelters which are considered to be upper bound estimates.  This
is especially true for primary zinc smelting where the data are
based only on one plant which was operating relatively inefficiently
(i.e.,  with high zinc losses).

B.   Geographic Distribution of Sources

     Table VI-2 shows the location of the primary smelters re-
viewed in this analysis.  General location and capacity data were
obtained from various EPA and industry reports;  -'^*-' an(j  specific
locations were determined from USGS maps.

C.   Estimated Ambient Levels

     The annual levels of cadmium due to smelters were not esti-
mated for two reasons.  First, the estimates of emissions from
any particular source due both to stack and operating character-
istics are more variable than for any other source.  Second, the
terrain around many  smelters is extremely rough; thus, generalized
source modelling results under these circumstances are difficult
to interpret.
                               44

-------
                         TABLE  VI-1
            EMISSION FACTORS  FOR PRIMARY SMELTERS





              (Pounds of Cadmium/Ton of Product)
                                                  I/
Smelter Type





   Zinc





   Lead





   Copper





   Cadmium
                     Minimum
1.43
5.20x10
       -2
                                      Maximum
2.96
2.60x10
                            Best Judgement
                                2.50
                        -1
                                 1.10x10
7.00x10 2
25.00
2.90x10"
30.50
1.50x10
28.00
                                       -ib/
                                               -3
 a/   controlled level may be  as  low as 5.20x10^  Ibs/ton of product.
                                               -3
 b/   Controlled  level may  be  as  low as 7.00x10"   Ibs/ton of product
                               45

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                                                            47

-------
                           TABLE VI-3
        MEASURED CADMIUM LEVELS NEAR PRIMARY SMELTERS
                                                     a/
     Cit'i
Helena
                  State
                 Montana
Concentration
   (ng/m3)
     15
Year
1971
                                                                b/
El Paso
                    Texas
                                         24
                     1974
Kellogg
                 Idaho
    247
1975
Jefferson County    Missouri
                                        111
                     1975
a/
b/
SOURCE:   Reference 22.
Last year for which data is available,
                               48

-------
     Monitoring data can be used to give a rough approximation
of the ambient levels which occur around smelters.  Table VI-3
lists observed atmospheric cadmium levels in areas near smelters.
It is obvious that very high cadmium levels are not uncommon
around smelters.  As before, it is difficult to attribute all
the measured cadmium to the smelters.  However, due to the lack
of population and industry around most smelters, it is very likely
that most of the measured concentrations are due to smelter
emissions.

     To approximate the population exposed to cadmium emissions
from smelters, the population living within 20 km of the smelter
was assumed to be exposed to cadmium levels greater than 0.1 ng/m ,

D.   Population Exposed

     Table VI-4 shows the estimated population exposed to cadmium
emissions from primary smelters.  It is obvious that in comparison
to the preceding sources, fewer people are exposed to emissions
from primary smelters.  The distribution of population is very
biased.  Two regions  (and two plants) account for the majority of
the population exposed.

     The low number of people exposed by smelters is due to the
very low population density around the smelters.  It appears,
therefore, that while primary smelters are a large source of cad-
mium emissions to the atmosphere, they do not  (with the exception
of two plants) expose large numbers of people to these emissions.
However, the exposure levels can be quite high as is evident from
Table VI-3.
                              49

-------
                        TABLE VI-4
         ESTIMATE OF POPULATION EXPOSED TO  CADMIUM




           CONCENTRATIONS FROM PRIMARY SMELTERS




                        (10  people)
Region
1
2
3
4
5
6
7
8
9
10
Primary Primary Primary
Zinc Lead Copper
_
_
258
19
100 - 3
- 16
35 -
28 92
- 29
41 17 461
Primary
Cadmium
-
-
100
-
86
41
-
-
-
17
TOTAL
399
80
620
245
                                50

-------
                          SECTION VII

                       SECONDARY SMELTERS
A.   Introduction

     The recycling of zinc and copper can potentially lead to
emissions fo cadmium due to the cadmium contained in metals.  The
high temperatures involved with the melting of the scrap will
release most of the cadmium.  The cadmium associated with the metal
will be vaporized and potentially release into the atmosphere.

     Table VII-1 shows the assumed emission factors for secondary
smelting.  The high degree of control shown is based on the assump-
tion that fabric filters are used for control.

B.   Geographic Distribution of Sources

     Table VII-2 shows the geographic distribution of secondary
copper and zinc smelters in the United States.  Location data were
determined from various trade directories.  '     Latitude and
longitude coordinates were obtained from detailed USGS maps.

     Information on the size of each smelter was not available.
Accordingly, the assuirrotion was made that all smelters were of
                               237
"average" size.  One reference     does indicate a relatively
small size range for these types of smelters.   Therefore,  the
assumption may be reasonable.

C.   Estimated Ambient Levels

     Estimates of ambient cadmium levels resulting from emissions
 of secondary smelters were based on CRSTER runs using Dallas/
                               51

-------
                          TABLE VII-1
            EMISSION FACTORS FOR SECONDARY SMELTERS
              (Pounds of Cadmium/Ton of Product)
            UNCONTROLLED
                                          CONTROLLED
                                                      a/
Smelter                         Best
 Type     Minimum   Maximum   Judgement  Best Judgement
Zinc    8:OxlO~3   1.4xlO~2
                                           5.0xlO
                                                 ~4
 Copper    2.6
                   4.0
3.0
3.0x10
                                                 -1
a/
     Fabric  filter  assumed.
                               52

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                  73    
-------
Fort Worth meteorology.  Different stack conditions were assumed
for copper and zinc smelters.  Table VII-3 shows the assumed
stack conditions.

     As in the case of other industries, a regression equation
was developed based on the CRSTER runs.  The equations developed
are shown below:

     •  For secondary copper smelters—

        LnY = -1.57 (LnX)  - 0.35  d/X) +3.12

     •  For secondary zinc smelters—

        LnY	1.75 dnX)  _ 2.07  d/X) + 3.26

where:  X is the concentration (ng/m )  caused by an emission rate
of  one g/sec of  cadmium,  X is  the distance  to  the  receptor point
 (Km) .

     Concentrations caused by each plant were computed by multiply-
ing the plant emission rate in grams/second, by the concentration
resulting from one g/sec emission rate.  As with other industries,
no modelling was carried out beyond 20 Km.

D.   Population Exposed

     Table VII-4 shows the estimated cumulative population  exposed
to  specified cadmium concentrations and the average concentration
each person is exposed to.  Though there are only  very few secondary
copper smelters, the population exposed is high.   This is  due to
the urban location of the smelters and the high  (even when controlled)
emission factor.
                               54

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                          TABLE VII-3
                 ASSUMED STACK CONDITIONS FOR
                      SECONDARY SMELTERS
STACK PARAMETER
        SMELTER TYPE
  Height (ft)
Temperature (°F)
Flow (ACFM)
Diameter (ft)
  Zinc






   120






   250






40,000






     4
 Copper





    50





   250





10,000





     2
                                55

-------
                         TABLE VII-4
         ESTIMATE OF POPULATION EXPOSED TO SPECIFIED




         LEVELS FROM SECONDARY SMELTERS (103 People)
                            Concentration (ng/m )
      Smelter
>10     >5    >1   >0.1   Average Exposure
Secondary Copper
296
798   5710  9891
                                                       2.3
Secondary Zinc
                       37
                        0.47
                              56

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     Secondary zinc smelting appears to be an insignificant
source of atmospheric cadmium with few people exposed and very
low emissions.  However, it must be pointed out that it was not
possible to take into account the difference in plant sizes.  It
is not clear how this would affect the results.

     Appendix E shows the estimated population exposed to each
secondary smelter.
                              57

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                        APPENDIX A
              POPULATION EXPOSURE METHODOLOGY
     The population exposure model is used to calculate the
number of people who live within a fixed distance of a specific
set of latitude and longitude.  The imputs to the model are the
location of the center point and the radius under consideration.
The data base for the model is the set of population maps that
were constructed from the Medalist data.  The center point
corresponds to the smoke stack of a point source polluter.  The
radius corresponds to the maximum distance from the stack that
a specific concentration of a pollutant could be found.  The
estimate of the radius is determined by the predominant methodology
(in the Dallas Fort Worth data set).  The circle drawn around the
point is therefore an overestimate since this, in effect, assumes
every direction from the source is downwind.

     Given the imputs, the first step is to identify the map on
which the source is located.  This is accomplished by comparing
the latitude and longitude of the source to the set of map bound-
aries.  Next, the latitude and longitude of the source are con-
verted to the appropriate map grid point using the same method  that
was used to locate the population data on the maps.  This, how-
ever, may not fully access the data on the population affected  by
the source.  If the source is located near a map boundary, the
affected population may be located on up to three additional maps.
If a source is located within 20 kilometers of another map, that
map may also be accessed.
                                58

-------
     After loading the appropriate map file from computer tape
into core and reading the necessary information onto the map
grid, the next step is to construct a coordinate system centered
at the same location since all grids are not the same size.
The grid points at which the source has been located becomes the
origin.  The value which is calculated is based on the latitude
of the source.  The distance between any point and the origin or
source is therefore easily calculated by triangulation from the
coordinates of that point with the origin.

     Each grid cell within 20 kilometers of the source is Sys-
tematically examined.  First, the corners of the cell are
located on the coordinate system.  With this information, the
total amount of area inside the cell and included within the
selected radius from the source is calculated.  The symmetry of
the analysis allows the computer program to actually look only at
the grid blocks that lie in or border the first quadrant.  The
values for each of the blocks outside the first quadrant can be
inferred from the results of the first quadrant.

     There  are  five distinct  cases  encountered when  one  attempts
to calculate  the  area of a grid  block which is  included within
a circle of given radius  (see  Figure A-l):

     •  The first  case encountered  is the  area of  the  grid
        cell that  has the  source  located at its  center and
        is  larger  than the  circle enclosed by the  selected
        radius.  Here, a simple approximation is made.   The
        area included is taken  to be the area of the circle
        of  the given  radius divided by  the area  of the grid
        cell to obtain the  fraction of  the cell  included in
        the circle.   Once  the area  of  the  circle exceeds the
        area of the  grid block, it  is  assumed that the entire
        areas  of the  grid  cell  is included within  the radius.
                                59

-------
                 FIGURE A-l
CASE#1
CASE #2
CASE #3
CASE #4
                   CASE #5
                      60

-------
     •  The second case involves grid cells located along
        either the x-axis or the y-axis.   Here,  the area
        included is taken to be the arc of the rectangle
        defined by the interesection of the radius and the
        block boundaries included, plus the area of the
        remaining arc defined by the radius.  Special
        cases occur when the radius intersects the edges
        of the grid cells which are perpendicular to the
        axis.  The general form of the solution remains
        the same.

     •  Case three occurs where only one of the vertices
        of the cell is included; the area included is the
        sum of the area of the enclosed triangle and the
        area of the enclosed arc.

     •  Case four occurs when two vertices are included
        or all are included.  In this case, the area
        covered equals the sume of the area of the trap-
        ezoid and the area of the enclosed arc.

     •  Case five occurs when three vertices are included.
        The area of the cell included equals the area
        of the cell minus the area of the excluded tri-
        angle plus the area of the included arc.

     Once the area of the grid cell which is included in the
exposed area has been calculated, it is divided by the area of
the grid cell yielding the percentage of the area included.  In
order to calculate the number of people who live within the in-
cluded area, it is assumed that the population is uniformly
distributed throughout the grid cell.  Therefore, the population
affected is the product of the percentage of the area included
times the population of the grid cell.  By summing up the pop-
ulation included in all the cells, the total number of people
who live within a given radius of a source can be estimated.

                                61

-------
     By choosing several radii for each source, the number of
people who reside between a given pair of radii can be calculated
by a simple subtraction.  Since each radius corresponds to a
specific pollution level, this type of calculation yields an
estimate of the number of people who are exposed to various
concentration levels for a single source.

     By summing up the effects of several sources, either by
source type or location, one can gain insight into which type
of source appears to effect the largest number of people.  How-
ever, the total number of people exposed may be misleading.
In areas where there are many point sources located close to-
gether, much multiple-counting will occur.  (For example, a
person exposed to a given ambient concentration produced
separately by three sources will counted three times).  There-
fore, this approach does not give an accurate estimate of
population exposed to specific levels from sources.  However,
the model does give an accurate respresentation of total ex-
posure  (expressed as concentration per person-year) for use
in linear health models  (i.e., those in which one person exposed
to two ng/m  is treated  the same as two people each exposed to
one ng/m ).

     To obtain an estimate of the population exposed  to various
concentrations, a slightly different approach is used.  The
major difference is that once people are determined to lie with-
in any radius of any plant, they are subtracted from  the map.
In other words, no single person is ever counted by more than
one  source.  In addition, the model is not run source-by-source
as before, but pollution level-by-pollution level.  By choosing
several pollution levels and  starting with the level  that yields
the  smallest radius and  working out the  actual number of people
who  are exposed to at  least one source at each, a  pollution
level  can be estimated.
                                62

-------
     This model also has its limitations.  Individual source
totals are meaningless since the sources which are run first
will tend to count more people simply because there are more
people initially on the map.  There is also no way to arrive
at the total pollutant concentration times person estimate
because no account is made of cumulative effects.
                                63

-------
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