RESULTS OF 1969
WATER QUALITY MONITORING PROGRAM
LAKE HURON BASIN OFFICE
LHBO 33-A
APRIL 1970
U.S. DEPARTMENT OF THE INTERIOR
Federal Water Pollution Control Administration
Great Lakes Region
Lake Huron Basin Office
Grosse lie, Michigan
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TABLE OF CONTENTS
Introduction
Special Study Daca Results ..,...,,>,... 4
1969 Oil Observation - Irenton Chaiutel - Detroit; River . 72
Observation Runs - 1969:
Raisin Rivet ....,„,.„.,.,„,..., Si
Detroit and Rouge Rivers . .. . , . . , . , „ 87
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LIST OF FIGURES
Figure No. Page No.
I Lake Hurun BasLn Office Sampling Araa 2
Location of Sampling Station;
2 Cheboygan Harbor 3
3 Alpena Harbor 7
4 Tawas Bay 14
5 Lower Saginaw Bay 21
6 Lake Huron Phytoplankton 28
7 Secchi Disc Transparencies - Lake Huron 29
Phytoplankton
8 Biomass Distribution - Surface, Lake 30
Huron Phytoplankton
9 Biomass Distribution - 50* Depth, Lake 31
Huron Phytoplankton
10 Station Locations - Beach Problem Survey 35
11 Attached Algae Survey Areas 38
12 Location of Stations - Special Iron Study 41
Lake St. Clair
13 Station Locations - Coliform Study - 46
Detroit River
14 Sampling Locations - Fighting Island 52
Location of Sampling Stations:
15 Rouge River 59
16 Raisin River 65
17 Location of Range DT 8,7 and Automatic 71
Monitor Intake
18 1969 Automatic Monitor - Temperature, 75
Conductivity, Dissolved Oxygen
ii
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LIST OF FIGURbS
(conr'd)
Figure No. Page No.
Indu&tridl Outfalls;
19 Detroit River 81
20 Raisin River 82
21 Location of Samp1lag Stations - 1969 92
Bacteriological Study - Western
Lake Erie
22 Station Locations - Interim Pesticide 101
Monitoring Program
111
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LIST OF TABLES
Table No. Page No.
1969 Sample Analysis Results:
1 Lake Huron: Cheboygan 4
2 Lake Huron: Alpena 8
3 Tawas Bay 15
4 Lower Saginaw Bay 26
5 Physical Observations, Lake Huron Phyto- 32
plankton Study, Sept. 1968
6 Phosphorus Concentrations, Lake Huron 34
Phytoplankton Study, Sept. 1968
7 Lake Huron Beach Observations - 1969 36
8 Attached Algae (Survey I, June 1968) 39
Lake Erie, Detroit River, Lake St. Clair,
St. Clair River, and Lake Huron
9 Attached Algae (Survey II, Sept. 1968) 40
Lake Erie, Detroit River, Lake St. Clair,
St. Clair River, and Lake Huron
1969 Sample Analysis Results:
10 Lake St. Clair - Special Iron Study 42
11 Detroit River 47
12 Fighting Island 53
13 Rouge River Study - October-November 1969 60
14 Raisin River Study - October-November 1969 66
15 A Guide to Reporting Qualitative Descriptions 69
of Odors - 1969
16 A Guide to Reporting Qualitative Oil Film 70
Observations - 1969
17 1969 Oil Observations, Detroit River 73
IV
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LIST OF TABLES
(cont'd)
Table No. Page No.
18 1969 Automatic Monitor Results, 76
Detroit River at Gibraltar, Mich,
19 1969 Bacteriological Study of Western Lake
Erie Beaches and Tributaries:
Detroit River - DT 3.9 (U.S.) 93
" " " (Canadian) 94
11 " - Gibraltar Monitor 95
June Survey 96
Raisin River and Sterling State Park 97
Lake Erie and Raisin River 98
20 1969 Sample Analysis Results, Interim 102
Pesticide Monitoring Program
Laboratory Methods 103
Summary of Laboratory Procedures 104
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INTRODUCTION
The Lake Huron Basin Office located in Grouse lie, Michigan,
administers the Federal Water Pollution Control Administration Programs
in the Lake Huron drainage basin and Southeastern Michigan drainage basin
to Lake Erie,
The primary goal of the Federal Water Pollution Control Admin-
istration is to enhance and maintain the quality of the water resources
in the United States<= In directing this effort,,quantitative information
is required on levels of water quality and how these levels vary over
periods of time and how they compare to standards, The purpose of this
report is to present information collected by the Lake Huron Basin Office
during 19&9 for use by pollution control agencies on improving the
environment^
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LAKE HURON BASIN OFFICE ,'
LOCATION OF SAMPLING STATIONS j
LOWER SAGINAW BAY <
U.S. DEPARTMENT OF THE INTERIOR
FEDERAL WATER POLLUTION CONTROL ADMINISTRATION
GREAT LAKES REGION GROSSE ILE, MICHIGAN ;
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TABLE 4
1969 Sample Analysis Results
Lower Saginaw Bay
Station:
Date
7-8
7-30
8-13
Max.
Min.
7-8
7-30
8-13
Avg.
Max.
Min.
Saginaw River
X110 X105 X100
23-5
25.0
25.0
25.0
23.5
7.9
7.9
8.3
8.0
8.3
7-9
Parameter:
23.0
25°5
24.0
25-5
23-0
Parameter:
8.0
7.8
8.3
8.0
8.3
7.8
H238
Temperature (
20.0
24.5
22.5
24.5
20.0
pH
8.8
8.7
8.7
8.7
8.8
8.7
19.0
23.5
22.0
23*5
19.0
8.8
8.3
9.0
8.7
9.0
8.3
Saginaw Bay
H240 H242
°0
19-0
23.5
22.0
23°5
19.0
8.5
8.4
8.8
8.6
8.8
8.1*
19.5
23.5
23.0
23-5
19-5
8.8
9.0
8.8
8.9
9-0
8.8
FWPCA, LHBO
H243
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23.0
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8.4
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M
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NS
7-30
7-30
333 333
Parameter: Dissolved Oxygen (mg/l)
3.1 2.6 9«2 8.2 7-3 9°5
Parameter: % Saturation
38 32 111 98 87 113
Parameter: Conductivity (umhos/cm)
7-8
7-30
8-13
Avg.
Max.
Min.
650
760
800
71*0
800
650
660
820
830
770
830
660
hoo
450
kio
it 20
450
it 00
360
i*00
3^0
370
koo
3kO
380
iao
380
390
ino
380
350
1^60
390
koo
460
350
87
340
NS
22
-------
TABLE k
1969 Sample Analysis Results
Station:
Date
7-30
NS
7-8
7-30
8-13
Avg.
Max.
Min.
NS
7-8
8-13
7-8
7-30
8-13
Avg.
Max.
Min.
NS
Saginaw River
X110 X105 X100
Lower Saginaw Bay
H238
Saginaw Bay
H2l*0
Parameter: Phenol (ug/l)
1 1* 1* 11
Parameter: Chloride (mg/l)
8U
39
150
91
150
39
3
38
59
69
55
69
38
3
160
200
.8
1.0
.6
.8
1.0
.6
3
90
120
1**0
117
ll*0
90
3
Parameter
37
61
66
55
66
37
3
Parameter
160
170
Parameter
.7
.9
.7
.8
• 9
• 7
3
1*2
ii*o
1*7
76
ll*0
1*2
3
: Sulfate
30
32
28
30
32
28
3
35
1*7
1*1*
k2
kj
35
3
(mg/l)
26
27
27
27
27
26
3
1*0
**9
42
1*1*
1*9
1*0
3
29
28
26
28
29
26
3
32
61
1*2
**5
6l
32
3
2k
33
26
28
33
2i*
3
: Alkalinity (mg/l)
100
ll*0
: Nitrate
< .1
.1
.1
.1
.1
< .1
3
97
9^
(mg/l)
< .1
< .1
< .1
„
< .1
< .1
_
100
100
< .1
< .1
.1
„
.1
< .1
-
100
100
< .1
< .1
< .1
M»
< .1
< .1
_
FWPCA, LHBO
H2l*3
33
20
< .
23
-------
TABLE 4
1969 Sample Analysis Results
Station:
Date
7-8
7-30
8-13
Avg.
Max.
Min.
NS
7-8
7-30
8-13
Avg.
Max.
Min.
NS
7-8
7-30
8-13
Avg.
Max.
Min.
NS
Lower Saginaw Bay
Saginaw River Saginaw Bay
: X110 X105 X100 H238 H240 H242
A7
.08
.74
A3
• 74
.08
3
.78
< .05
1.3
.71
1-3
< .05
3
.40
.30
.37
.36
.4o
• 30
3
Parameter:
.46
.16
.68
A3
.68
.16
3
Parameter:
.72
.68
1.0
.80
1.0
.68
3
Parameter:
.30
.36
.41
.36
.30
3
FWPCA, LHBO
H243
Ammonia-N (mg/l)
^76
,21
.41
.76
.21
3
.15
.17
.15
.17
3
.38
37
.30
.28
3
.22
.19
. 34
.25
.34
.19
3
.17
-
-
Organic-N mg/l)
.74
.76
.88
•79
.88
.74
3
Total
.06
.08
.13
.09
.13
.06
3
'.83
.68 .
.83
3
Phosphorus
.08
.09
.07
.09
.04
3
• 54
.59
.64
.59
.64
3
(mg/l)
.07
.10
.11
.09
.11
.07
3
.62
.99
.65
.75
.99
.62
3
.05
.11
.10
.09
.11
.05
3
.51
:
-
.04
-
_
24
-------
NS
NS
TABLE k
1969 Sample Analysis Results
Station:
Date
Lower Saginaw Bay
Saginaw' River
X110 X105 JCLQQ H238
Parameter: Total
7-8
7-30
8-13
Avg.
Max.
Min.
.2k
.22
.26
,2k
.26
.22
.20
.06
.26
.17
.26
.06
.02
,0k
.03
,0k
.02
Saginaw Bay
H2J+0 H2^2
FWPCA, LHBO
E2k3
Sol. Phosphorus (mg/l)
.01
.03
.02
.02
.03
.01
.02
.05
.07
.05
.07
.02
.02
.06
.01
.03
.06
.01
.008
-
Parameter:
3 3
Turbidity (JCU)
7-8
7-30
8-13
Avg.
Max.
Min.
25
25
20
25
25
20
25
25
20
25
25
20
8
15
20
15
20
8
5
10
6
7
10
5
15
10
20
15
20
10
9
15
15
15
15
9
Parameter: Iron (ug/l)
7-8
8-13
7-8
7-30
8-13
Avg.
Max.
Min.
1,100
820
490
620
670
590
670
k90
1,000
890
Parameter:
510
650
61*0
600
650
510
290
500
Total
310
320
310
310
320
310
150
100
Solids
260
300
290
280
300
260
330
350
(mg/l)
280
300
300
290
300
280
510
280
270
360
300
310
360
270
10
260
NS
25
-------
TABLE 4
1969 Sample Analysis Results
Lower Saginaw Bay
FWPCA, LHBO
Station:
Date
7-8
7-30
8-13
Avg.
Max.
Min,
NS
7-8
7-30
8-13
Avg.
Max.
Min.
NS
7-30
7-30
Saginaw River
; XUO X105 X100
38
35
2k
32
38
24
3
460
580
640
560
640
460
3
3,700
490
Parameter:
30
34
23
29
34
23
3
Parameter;
480
620
620
570
620
480
3
Parameter:
13,000
Parameter:
830
H238
Saginaw Bay
H240 Hg4g
H243
Suspended Solids (mg/l)
12
12
23
16
23
12
3
9
12
16
12
16
9
3
19 10
7 12
21 14
16 12
21 14
7 10
3 3
11
OB
-
Dissolved Solids (mg/l)
300
310
290
300
310
290
3
Total
< 20
Fecal
< 2
250
280
270
270
280
250
3
CoHform
190
Coliform
< 20
260 260
300 350
280 290
280 300
300 350
260 260
3 3
(MF/100 ml)
< 10 < 10
(MF/100 ml)
< 20 < 20
250
-
-
< 10
< 20
26
-------
TABLE k
1969 Sample Analysis Results
Lower Saginaw Bay, 7/30/69
FWPCA, LHBO
Station: Sago 1 Sago 2 Sag. 3 Sag, k Sag, 5 Sago 6
Parameter
Temperature (°C) 23«5 23=5 23°5 23=5 23-5 23.0
PH 9=0 8.8 806 8»6 8,7 8.1*
Dissolved Oxygen (mg/l) 9.4 8,6 7.6 7»6 8.2 7«4
% Saturation 112 102 90 90 98 87
Conductivity (umhos/cm) 450 450 4lO 420 400 360
Phenol (ug/1) 234212
Chloride (mg/l) 6l 60 51 51 48 39
Sulfate (mg/l) 33 33 30 30 29 25
Nitrate (mg/l) .1 .1 .1 < ol < .1 < .1
Ammonia-N (mg/l) .21 .20 .24 .17 .19 .19
Organic-N (mg/l) 1.0 .90 ,73 «5^ «75 °^7
Total Phosphorus (mg/l) .11 .10 .08 .07 .07 .06
Total Sol. Phosphorus (mg/l) .01 .02 .01 .01 .01 .005
Turbidity (JCU) 15 15 15 10 10 10
Total Solids (mg/l) 360 360 310 320 300 260
Dissolved Solids (mg/l) 3^0 3^0 300 310 280 250
Suspended Solids (mg/l) 20 19 16 Ik 12 7
Total Coliform (MP/100 ml) 10 < 20 10 < 20 < 10 < 5
Fecal Coliform (MF/100 ml) <2 <2 <2 <2 <2 <2
27
-------
FIGURE 6
40 60
28
LAKE HURON BASIN OFFICE '
LOCATION OF SAMPLING STATIONS
LAKE HURON PHYTOPLANKTON STUDY
SEPTEMBER, 1968 •
U 8. DCPARTMfNT OF TNC INTERIOR
FEDCftAL WATER POLLUTION CONTROL ADyINItTftATION
• KCAT LAKES ftCtlON 9R05SC ILE, UlCKiaAN
-------
FIGURE 7
MICHIGAN
I I Secchi Disc Tronsparencies
SCALE IN MILES
10 O 10 20 30 40 00
29
LAKE HURON BASIN OFFICE
SECCHI DISC TRANSPARENCIES
LAKE HURON PHYTOPLANKTON STUDYJ
SEPTEMBER, 1968
U.». DEPARTMENT OP THC INTERIOR
FEDERAL WATCH POLLUTION CONTROL ADUINKTRATION
• REAT LAKE* REtlON OROSIC ILE. HICHI9AN
-------
o-oo.o.
MICH I G A N
"\* * *»O **"•**«
.V"A'.v.0.Y.v-\v>
x&xVviUrv-
LEGEND (Average Biomass)
.027 Mi
per Liter
|»,**«i_o| .04 Microliter per Liter
. I Microliter per Liter
SCALE IN MILES
IO 0 IO 20 30 40 60
LAKE HURON BASIN OFFICE
BIOMASS DISTRIBUTION-SURFACE
LAKE HURON PHYTOPLANKTON STUDY
SEPTEMBER, 1968
ftDI«»L WATCH POLLUTION CONTROL »0IIIKilTR«TIOK
«RCAT LAKES RCaiON «ROSSC ILC. UICHI6AN
30
-------
FI C o^%vy- V-N
.** «US^iw»..:.JUeAi a « o ^« o "ol° o O^
' tSSS>.. **- a~~.« *
-------
TABLE 5
Physical Observations
Lake Huron Phytoplankton Study
September 1968
FWPCA,LHBO
Station
H100
HDLOk
H110
H113
H125
H130
H132
H133
EL3^
H136
H200
H202
~B2Qk
H206
H20T
H212
H250
H252
H254
H320
H32.1
H322
R32b
H326
H328
H330
H3TO
H3T2
H374
H3T6
H3T8
H380
H382
Date
9/11
9/11
9/11
9/10
9/10
9/10
9/10
9/10
9/10
9/10
9/9
9/9
9/9
9/9
9/9
9/9
9/10
9/10
9/9
9/9
9/9
9/9
9/9
9/9
9/9
9/9
9/8
9/8
9/9
9/8
9/8
9/8
9/8
Temp.
at 0'
If£l_
19
19
19
18
18
20
19
20
20
20
19
18
18
1.8
19
19
18
19
19
19
IT
18
IT
IT
18
18
15
15
15
15
16
16
16
Temp.
at 50'
l££l_
19
IT
IT
18
11
20
19
20
•:'.i
20
17
18
18
10
14
18
10
19
18
19
17
17
17
IT
18
18
15
15
15
.15
16
16
16
Secchi
Disc
(ft.)
17.0
17.0
17.0
8.0
16.0
20,0
18.0
19.0
25.0
16.0
8.0
18.0
18.0
16.0
7.0
8.0
18.0
29 oO
2T.O
26.0
21.0
26.0
26 oO
28.0
28.0
2T.O
25.0
25.0
25.0
2T.O
30.0
29.0
2T.O
Cloud Cover
(percent)
95
99
95
90
ko
80
90
55
80
60
90
90
95
90
90
90
95
95
TO
80
90
T5
T5
60
T5
T5
95
95
TO
60
TO
60
60
Euphotic Zone*
to bottom (20')
to bottom (50s)
to bottom (30')
to bottom (^-6*)
to bottom (45')
+ 100
+ 100
+ 100
+ 100
to bottom (U01)
36
80
77
to bottom (60')
29
30
+ 100
+ 100
+ 100
+ 100
75
•4- 100
+ 1.00
+ 100
+ 100
to bottom (50')
to bottom *65 ' )
90
+ 100
+ 100
+ 100
+ 100
to bottom (90")
*$Jepth at which one percent of surface light remains.
32
-------
NS
TABLE 5
Physical Observations
Lake Huron Phytoplankton Study
September 1968
FWPCA.LHBO
Station
H420
H422
H424
H426
H428
H432
H530
H532
H534
H536
H8l4
H502
Max.
Min.
Avg.
Date
9/7
9/7
9/7
9/7
9/7
9/6
9/6
9/6
9/7
9/7
9/6
9/6
Temp.
at 0'
15
15
15
16
17
17
15
16
15
16
15
18
20.0
15.0
17«5
Temp.
at 50'
(0C)
15
15
14
15
17
10
15
16
15
10
15
17
20.0
10.0
16.1
Sec chi
Disc
(ft.)
19.0
28.0
29.0
29.0
27.0
22.0
17.0
18.0
23.0
25.0
19.0
13-0
30
7
21.4
Cloud Cover
(percent) Euphotic Zone*
80
85
70
40
20
30
50
50
10
10
10
99
99
10
71
87
+ 100
+ 100
+ 100
+ 100
89
to bottom (35s)
99
+ 100
90
90
73
+ 100
29
*Depth at which one percent of surface light remains.
33
-------
Station
P31
H100
H104
KL10
HI 3?
H324
H376
TABLE 6
Phosphorus Concentrations
Lake Huron Phytoplankton Study
September ,1968
Date
9/11
9/11
9/11
Total soluble
Phosphorus
,005
.004
.OCA
.006
H532
.00,3
FWPCA,IflBO
Total
Phosphorus
,006
,OOT
.ooU
oOO^
.005
Avg.
»003
.007
.004
oOO1?
NS
34
-------
FIGURE 10
LAKE
SUPERIOR
LAKE HURON BASIN OFFICE
STATION LOCATIONS
BEACH PROBLEM SURVEY
LAKE HURON
U C DEPARTMENT Of THE INTERIOR
WAT(R POLLUTION CONTROL AOm NKTRATION
«REAT LAKII RI«ION
LAKE
MICHIGAN
Lakeport State Park
Port Sanilac
Harbor Beach
Grindstone City
Port Austin
Port Crescent State Park
Sleeper State Pork
Caseville Park
Bay Port
Bay City State Park
MICHIGAN
SCALE IN MILES
C 10 IB 2O 28 3O
-------
43
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-------
Fl C U K E
ONTARIO
SAMPLING AREA
I Monroe
2 Stony Point
3 Grosse lie
4 Grosse Pf. Forms
5 Mt. Clemens
6 Aigonoc
7 Port Huron
8 Port Sanilac
9 Harbor Beach
0 Grindstone
Port Austin
2 Caseville
i 3 Sebewaing
14 Bay City
1 5 Pinconning
6 Au Gres
7 Tawas
18 Oscoda
19 Horrisville
20 Ossineke
21 Alpena
22 Rogers City
23 Huron Beach
24 Cheboygan
25 Mackinaw City
MICHIGAN
j
/ERIE
LAKE HURON BASIN OFFICE
ATTACHED ALGAE SURVEY
1963
U S. OTPASTMENT OF THE INTERIOR
FtDCRAL *ATF« ^CLi-UTION CO\TROL A 0 M I M S T R
GRt'AT LiKE3 Rt'jIOPJ Gr
-------
TABLE 8
Attached Algae (Survey I, June 1968)
Lake Erie, Detroit River^ Lake St. Clair
St. Clair River and Lake Huron
3FHPCA, LHBO
Attached Algae % Algal Cover Predominant
Area Sta* Length _{inoj of _Sub§trates Typ.§jgJL Aj-gae
111 1 Cladophora, Stigeoclonium
12 < 1 50 Cladophora, Stigeoclonium
130 0 None
21 6 30 Cladophora
311 - Cladophora, blue-green slime
4 1 8 50 Cladophora
4 2 16 50 Cladophora
511 - Cladophora, Spirogyra
52 22 100 Cladopnora, Ulothrix
5 3 '> .I-.-} 'Ulothrix
6l 8 30 Cladophora
J10 0 Hone
8 1 21 25 Cladophora
8 2 11 25 Cladophora
912^ - FoCrispus, Cladophora
10 1 10 - Ulothrix, Cladophora
11 1 16 - Cladophora
11 2 12 - Ciadopho-ra
11 3 < 1 0 Blue-green slime
12 1 Ik 90 Cladophora
Ik 1 < I 0 Blue-green Algae
Ik 26 50 Cladophora
15 1 2k - Cladophora
16 1 12 - Cladophora, Ulothrix
17 l Ik - Cladophora, Chara
17 2 7 - Cladophora, Chara
18 1 7 - Cladophora^ Chara
19 1 1 10 Zygnema
21 1 - Chara, Cladophora
21 2 3 - Ulothrix, Zygnema
22 1 < 1 0 Blue-green slime
23 1 0 0 None
2k I 3 - Cladophora
25 1 8 90 Cladophora, Zygnema
25 2 2 - Cladophora
39
-------
TABIE 9
Attached. Algae (Survey II ^ September 1968}
Lake Erie,, Detroit River, Lake St« Glair
Sto Clair River and lake Huron
FWPCA, LHBO
Area Sta.
1
1
1
2
3
It
14
5
5
5
6
7
8
8
9
10
11
11
11
12
Ik
lk
15
16
17
17
18
19
21
21
22
23
2k
25
25
1
2
3
1
1
1
2
1
2
3
1
1
1
2
1
1
1
2
3
1
1
2
1
1
1
2
1
1
1
2
1
1
1
1
2
Attached Algae
Length_ _(in^)__
< 1
3
3
2
5
8
J£
< 1
J
2
< 1
3
< 1
1
2
< 1
< 1
3
< 1
o
2
.1
1
6
o
< i
3
o
l
3
6
2
Algae Cover Predominant
.1
20
10
95
,10
.100
0
1
5
60
10
Stigeoclonium
Cladophora
Cladophora
Cladophora
Cladophora
Cladophora
Cl adopiio ra , t> 1 tie -g reer< si i me
Ciadopho ra
j w.
.„
^
SO
10
30
5
2
2
1
60
10
0
1
1
J.
100
0
Cladophora
Cladophora
Mo ug eat la
Cladophora
Cladophora
Cladophora
Cladophora
Cladophora
Cladopftora
Cladophora
Claaophora
Blue-green,
None
Cladophora
Cladophora
Cladophora
Cladophora
None
Spifogyra
Chara
Chara, Cladophora
Cladophora
None
Cladophora^ Ulothrlx
Cladophora
Cladophora
Cladophora^ Chara
40
-------
FIOURE 12
MICHIGAN
ST. C L A I R
LAKE HURON 8ASIN OFFICE
LOCATION OF SPECIAL
I.RON STUDY STATIONS
LAKE ST. CLA1R
U S. DEPARTMENT OF THE INTERIOR
FEDERAL WATER POLLUTION CONTROL ADMINISTRATION
CHEAT LAKES RCfltON AROSSC ILC, U1CHICAN
41
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Fl CURE 13
ONTARIO
Sampling Ranges
1969 Coliform Sampling Stations
Sewage Treatment Plant Outfalls
_
1000 0 1000 300 D 5000 70 OO
MILES
LAKE HURON S A S i N OFFICE
STATION uOCAT.ONS
COL (FORM STUDY
DETROIT RIVER
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FIGURE 14
MICHIGAN
Grassy
Island
Sampling Ranges j
© Sampling Stations!
SCALE IN FEET
1000 2OOO 3000 4000
LAKE HURON BASIN OFFICE
Turkey
Island
SAMPLING LOCATIONS
FIGHTING ISLAND
U $ DEPARTMENT OF THE INTERIOR
FEDERAL WATER POLLUTION CONTROL A 0 hi h 1ST RATION
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56
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H
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wf
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wl
oil
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58
-------
r i c, ,j R £ i i
-------
. TABLE 13
ROUGE RIVER STUDY
OCTOBER - NOVEMBER 1969
FIELD OBSERVATIONS
FWPCA,LHBO
Sta.
No.
TB-A
TB-B
T-lfl
T-15
T-12
DT-A
DT-B
Date
10/31
11/3
11/4
11/5
11/6
10/31
n/3
11/4
11/5
11/6
10/31
n/3
n/4
11/5
11/6
10/3.1
11/3
11/4
11/5
11/6
10/31
11/3
11/4
n/5
n/6
10/31
H/3
11/4
11/5
11/6
10/31
11/3
11/4
11/5
11/6
Time
1235
0905
0830
0835
0905
1250
0900
0840
0843
0855
1225
0920
0850
0850
0920
1215
0930
0900
0900
0930
1202
0940
0910
0910
0935
1155
0950
0920
0917
0945
1320
0955
0930
0925
0955
'Lab.
No.
44805'
45805
45825
45845
45865
44806
45806
45826
45846
45866
44804
45804
45824
45844
)|
-------
TABLE 13
ROUGE RIVER SOOTY
ANALYTICAL RESULTS - OCTOBER THRU NOVEMBER 1969
FWPCA.LHBQ
Sta.
No.
TB-A
Averaj
TB-B
Averaf
T-18
Averaj
T-15
Averaf
T-12
Date
10/31
11/3
11/4
11/5
11/6
?e
10/31
11/3
11/4
11/5
11/6
56
10/31
11/3
11/4
H/5
11/6
56
10/31
H/3
11/4
11/5
11/6
je
10/31
11/3
11/4
11/5
n/6
pH
7.8
7.5
7.5
7.4
7.6
7.6
7.5
6.7
7.1
7.4
7.2
7.2
7.6
7.5
7.4
7.2
7.5
7.4
7.6
7.5
7-5
7.2
7.4
7.4
7.8
7.7
7.6
7.4
7-9
Cond.
360
48o
420
4oo
4oo
4lo
290
380
340
350
300
330
320
380
370
340
340
350
320
380
390
360
340
360
320
320
340
330
260
Phenol
230
64
290
180
150
180
11
21
9
5
8
11
58
15
8
8
6
19
3
8
5
5
4
5
4
7
5
2
5
D£
7.1
5.4
5.2
6.0
6.1
6.0
8.7
5-0
5.7
5.0
7.3
6.3
5.9
5.8
4.5
5.8
6.3
5.7
9.0
3-7
4.0
4.0
5.6
5.3
5.4
7.1
8.6
6.5
9.9
BOD
-
M
-
_
.
-
-
M
_
_
M
-
-
4
6
5
3
2
4
m (
m
.
„
-
Percent
Saturation
80
58
55
62
63
64
95
52
58
51
77
67
62
59
46
59
66
50
94
36
40
41
56
53
54
67
81
62
88
Average
7.7
310
7.5
70
Note: Unite of Measurements on pg.
. 61
-------
TABLE 13
ROUGE RIVER STUDY
AKALYTIGAL RESULTS - OCTOBER THRU NOVEMBER 1969
FWPCAjLHBO
Sta.
Wo.
DT-A
Average
DT-B
Average
Date
10/31
11/3
llA
H/5
11/6
10/31
11/3
11/14.
11/5
11/6
£3,
7.9
8.2
8.1
8.0
8.1
8.1
8.1
7.9
7.8
7.7
7.9
i •'..'
Ccmd.
220
220
220
220
210
220
240
2'+0
240
2)4-0
21+0
2l*>
Phenol
2
5
6
1
1
3
15
3
9
1
>
c>
DO
11.3
11.3
11.3
10.9
11.0
11.2
11.3
10.6
10.2
9.9
10.6
10.5
BOD
„
«M
M
«*
-
-
k
3
2
2
1
2
Percent
Saturation
97
98
97
93
96
97
96
9U
101
96
Note: Units of measurements on page
62
-------
TABLE 13
ROUGE RIVER SURVEY
ANALYTICAL RESULTS - OCTOBER THRU NOVEMBER
1969
FWFCAjLHBO
Sta.
No . Date
TB-A 10/31
11/3
iiA
11/5
11/6
Average
TB-B 10/31
H/3
11/4
11/5
n/6
Average
T-18 10/31
11/3
nA
n/5
n/6
Average
T-15 10/31
11/3
11/4
11/5
11/6
Average
T-12 10/31
11/3
nA
n/5
n/6
Total
Iron
3,600
4,300
3,500
3,400
3,800
3,700
2,300
14,000
9,300
2,700
4,000
6,500
3,500
3,600
3,200
2,600
2,500
3,100
2,100
2,400
3,000
2,600
3,500
2,700
1,600
1,200
1,700
2,000
1,100
Oil &
Grease
6
16
7
4
8
8
4
7
4
6
7
6
4
6
7
6
9
6
4
4
5
3
8
5
3
2
3
4
7
Average
1,500
41
20
54
20
30
19
29
36
57
43
30
28
39
31
42
31
29
50
37
25
32
25
32
20
27
240
130
230
220
200
160
190
160
220
210
200
190
200
160
220
260
220
190
210
170
130
200
190
140
180
280
150
280
240
240
180
220
200
200
260
230
220
240
200
260
290
250
240
250
190
210
220
220
160
200
56,000* 1,100*
900
>8,000
14,000
34,ooo
12,000
12,000*
5
>600
200
1,400
500
500*
1,800 190
>8o,ooo^>6o,ooo
180,000 7,700
20,000 700
24,000 1,200
24,000* 1,200*
3,200 500
>80,000 > 6,000
350,000 12,000
20,000 1,000
16,000 900
20,000* 1,000*
8,500
>8o,ooo
260,000
56,000
48,000
140
>600
13,000
1,500
2,400
56,000* 1,500*
*Median
Note: Units of measurements on page
-------
TABLE 13
ii HivEu ivmm
ANALYTICAL KKGULT3 - OCTOBUH TlOttJ NOVEMBER
FWPCA,I,HBO
fll.0.
No.
UT-A
IVi be
30/31
11/3
1 J /'<
-1 1/5
1 1 A)
Average
nr-n
A v? rtti
Jo/U
3 3 /3
J 1/H
3 Lfr
11/0
(',n
Total
Iron
s6o
360
J"JO
pHo
100
330
,-.".o
730
690
730
HHo
670
Oil &
Grcnoc
H
2
2
?
6
3
r -
2
3
fj
6
h
Gunp.
Solido
13
19
10
lH
10
13
?l
33
13
23
.1.1
20
DLnn.
Sol b l.o
IPO
110
IPO
IP' 1
IPO
120
120
110
HO
130
130
.1 20
Totnl
Solids
130
130
130
130
130
3-30
I'lO
iHo
150
lUO
1HO
Total
Coliform
60
5,600
1,100
100
HO
100*
00
^ 0,000
66,000
HH,ooo
U5,ooo
4U,ooo*
Fecal
Collfoj-M
f, r
H20
Us
H •
h
-•' ')*
r,
- 300
U,Hoo
2,200
2, OCX)
2.00O*
Note: Units of measurements on pape
-------
65
-------
TABLE ik
RAISIN RIVER STUDY
OCTOBER - NOVEMBER 1969
FIELD OBSERVATIONS
FWPCA,LHBO
Sta. Temp.
No. Date Time (°C)
Color
Odoi*
Visible Wastes**
T-84
T-83
RR-A
T-80
L-28
10/31
11/3
IiA
11/5
n/6
10/31
11/3
nA
11/5
n/6
10/31
11/3
iiA
11/5
11/6
10/31
n/3
iiA
11/5
n/6
10/31
11/3
nA
11/5
11/6
1355
12^0
1200
1210
1247
13^0
1235
n5o
1250
1240
1320
1215
1140
1155
1230
1310
1205
nso
1145
1215
1300
1155
1120
1135
1155
13
10
8
7
8
13
11
9
9
9
9
11
9
9
9
9
9
9
9
10
9
9
8
8
8
.0
.0
.0
.5
.0
.0
.0
.5
.5
.5
.0
.0
.5
.0
.0
.0
.0
.5
.5
.0
.0
.0
.0
.0
.0
black
black
green
green
It, green
beige
jet black
milky
beige
black
murky green
black
dk, gray
beige
gray-brown
murky green
black
dk. gray
murky green
It. green
green
green
green
green
It. green
(Ch), (M)
none
none
none
none
pulp(M)
pulp(M)
none
(Ch), (M)
none
pulp
none
oily(Ch)
oily(Ch)
oily(Ch)
oily(Ch)
none
none
oily(Ch)
none
none
none
fishy(Df)
none
none
hvy, oil, blk.
blk, water
It. oil
trace of oil
none
hvy, oil, pulp.
pulp islands
water
, algae
white paper waste
pulp 8s oil
blk. water
hvy. oil, pulp.
It. oil
It. oil
mod, oil
It. oil
It. oil
It. oil
It. oil
mod. oil
It. oil
none
mild oil film
none
none
none
, algae
* For detailed odor description see Table 15.
**For detailed oil film descriptions see Table 16.
66
-------
TABLE Ik
RAISIN RIVER SURVEY
ANALYTICAL RESULTS - OCTOBER THRU NOVEMBER
1969
FWPCA,LHBO
Sta.
No . Date
T-84 10/31
11/3
11/4
11/5
11/6
Average
T-83 10/31
11/3
11/4
11/5
11/6
Average
RR-A 10/31
11/3
11/4
11/5
11/6
Average
T-80 10/31
11/3
11/4
H/5
11/6
Average
L-28 10/31
11/3
11/4
11/5
11/6
|>H
7.4
8.3
8.2
8.3
8.4
8,1
7.2
7»7
8,1
8.2
8.1
7.9
8.3
7.5
7.7
7.8
7.7
7.8
8,5
8,0
7.5
7.8
7.7
7.9
8.1
8,3
8.4
8.1
8.4
Cond.
750
710
700
680
690
710
690
130
720
680
720
710
420
610
610
610
620
570
380
380
620
660
640
540
330
310
320
260
310
Phenol
29
2
4
14
4
11
69
8
4
30
7
24
4
11
16
16
21
14
4
3
11
1.1
14
9
5
1
1
3
3
£2,
10.9
9.9
10.0
9.8
11,1
10,3
0.4
8,7
9.6
4,0
10,5
6,6
9.7
2,0
11,1
3.2
3.6
5.9
11.3
8,8
1.3
10,7
2,2
6.9
9.9
10,5
4.6
10,7
11,4
BOD
>180
4
4
9
4
40
>180
11
18
32
14
51
7
12
5
15
12
10
5
5
10
18
12
10
3
3
6
5
5
Percent
Saturation
104
88
84
81
93
90
4
79
84
35
92
59
84
18
98
28
31
52
98
76
11
94
20
60
86
91
39
90
96
Average
8.3 310
9.4
80
Note: Units of measurements on page 104.
67
-------
TABLE 14
RAISIN RIVER SURVE, '
ANALYTICAL RESULTS - OCTOBER THRU NOVEMBER 1969
Sta,
No. Date
Susp* Diss, Total Total Fecal
Solids Solids Solids Coliform Coliform
FWPCA,LHBO
Phyto-
Cyanides plankton
T-84 10/31
11/3
11/4
11/5
11/6
Average
T-83 10/31
H/3
11/4
11/5
11/6
Average
RR-A 10/31
11/3
11/4
11/5
11/6
Average
T-80 10/31
11/3
11/4
11/5
11/6
Average
L-28 10/31
11/3
11/4
11/5
11/6
350
21
16
16
20
85
120
25
34
24
38
48
31
26
22
32
26
27
36
22
27
37
29
30
32
15
29,
13
12
720
480
450
450
420
500
410
510
490
490
500
480
230
410
390
400
390
360
180
230
4oo
420
400
330
150
180
190
150
180
1,100
500
470
470
440
600
530
530
520
520
540
530
260
440
410
430
410
390
220
250
420
460
420
350
180
190
220
170
190
330,000
29 ,000
13,000
11,000
7,400
13,000*
690,000
10,000
180,000
8,000
1,700
10,000*
300
> 800
280
1,600
13,000
> 800*
100
> 800
12,000
3,800
1,200
1,200*
500
50
90
40
32
10,000
1,400
820
900
460
900*
>100
100
>l6o
-
<100
>100*
>100 ^ .01
80 <1 ,01
< 10 ,02
,01
>100 < ,01
> 90* < ,01
^10 <1 ,01
32 < ,01
^ 50 ^,01 .
,04
< 10 ,02
21* .02
^10
4
^2 1
< 2
< 2
-------
TABLE 15
A GUIDE TO REPORTING QUALITATIVE 1ESCRIPTIONS OF ODORS*
FWPCA-LHBO 1$6£
Description (Such as Odors of;)
camphor, cloves, lavender, lemon
Code
A
Ac
B
Bg
Bn
Bs
Bv
C
Cc
Ch
Cm
Cs
D
Df
Dp
Ds
E
Ep
G
M
Mm
V
Nature of Odor
Aromatic (spicy)
cucumber
Balsamic (flowery)
geranium
nasturtium
sweetish
violet
Chemical
chlorinous
hydrocarbon
medicinal
sulfuretted
Disagreeable
fishy
pigpen
septic
Earthy
peaty
Grassy
Musty
moldy
Vegetable
•^Standard Methods of Examination
P. 255.
geranium, violet, vanilla
i'
Asterioaella
Aphanizomenon
Coelosphaerium
Mallomorias
industrial wastes or treatment
chemicals
free chlorine
oil refinery wastes
phenol and iodoform
hydrogen sulfide
( pronounced , unpleasant )
Uroglenopsis, Dinobryon
Anabaena
stale sewage
damp earth
peat
crushed grass
decomposing straw
i
damp cellar
root vegetable
of Water & Wastewater, llth Edition,
69
-------
TABLE 16
A GUIDE TO REPORTING QUALITATIVE OIL FILM OBSERVATIONS*
1969
FWPCA.LHBO
Severity Severity
Code Description
0
1
2
6
7
none
trace
mild
light
moderate
serious
Gal. Oil/
sq.mi.
<25
25
50
100
200
666
heavy 1,332
extreme >1,332
Approx. Film
Thickness
(in.) 10-5
1.5
3-0
6.0
12.0
1*0.0
80.0
Appearance
Not visible
Barely visible
Visible as silvery
sheen
First trace of
color observed
(iridescent)
Bright bands of
color visible
(iridescent)
Colors begin to
turn dull
Colors much darker
Viscous opaque layer
of black, brown,
amber, yellow or
greenish oil
* Based on American Petroleum Institute (19^9) studies and Oil and
Hazardous Materials, Emergency Procedures in the Water Environment
(1968).
70
-------
F I 6 0 ft P 17
ELIZABETH J
MICHIGAN
G R 0 S S £
CALF
/ /ISLAND
GROSSE ILE
NAVAL AIR
STATION
\\ GIBRALTAR
Monitor Intake
SCALE IN F£ET
LAKE HURON SASIN OFFICE
LOCATION OF
RANGE DT S.7W AND
AUTOMATIC MONITOR INTAKE
-------
1969 OIL OBSERVATIONS
Trenton Channel, Detroit River
During the first three months of 1968, and again in 1969, the Lake
Huron Basin Office has been conducting a daily oil slick vigil of the
Trenton Channel of the Detroit River. The information collected is part
of the Michigan Bureau of Water Management study to determine the cause of
winter duck mortalities in the lower Detroit River.
The relative oil concentration for each sampling day is listed in
the following table, along with a summary of the field observations,, Oil
observed at each of the six stations (R91 thru R96) across the Ttenton
Channel is given according to the. following key:
Key to Oil Film Observations:
0 = No oil observed
X = Light traces of silvery oil or small spots of iridescent
oil
XX = A large film of iridescent oil
XXX = A thick or heavy cover of oil, dark iridescent or opaque
in color
72
-------
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-------
FIGURE 13
TEMPERATURE-CONDUCTIVITY-DISSOLVED OXYGEN
AUTO M AT 1C MOW TO 3
969
TEMPERATURE (°F)
W t, CT 0> -4 O
/.• X\ /
•«»x
1 1 1 1
U^
/-'
1 1 1 1
££
•/
f
i i i i
/ —
S#
...-/
i i i i
--~ —
i i i i
'*\
^
\£
III!
*T^v
N'C\
\*0
%
.1, ,,.L, I.I,.
'
^ !
r— •• -
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i
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i i i i. !
C 10 15 20 25 30 35 40 45 Si
WEEK NO.
sou
o
o
6
>
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> 380
0
O 3OO
o
0 250
I /
vv
*••• • • •
s, ^
v. _/
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\
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till
i\
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LEGEND
____
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I 1 1 J
MINI M U M
^\^~ -'
i i i i
i
|
1
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10
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WEEK NO.
40
13
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c
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7 \ \
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LEGEND
_____
lift
5 4
AVERAGE
MINI M U M
l 1 ! 1
;> 4
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;
1
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1 j j |
s
WEEK NO.
7J
-------
TABLE 18
1969 AUTOMATIC MONITOR RESULTS
Detroit River at Gibraltar, Michigan
FWPCA,LHBO
Week
No.
1
2
3
4
5
6
7
8
9
10
Date
12/29
1/5 -
1/12
1/19
1/26
2/2 -
2/9 -
2/16
2/23
3/2 -
-1/4
l/li
-1/18
- 1/25
-2/1
2/8
2/15
- 2/22
-3/1
3/8
Avg,
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min,
Avg,
Max,
Min.
Avg,
Max
Min,
Avg,
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Temp.
(°F)
39
41
37
38
39
36
39
4l
36
39
42
37
38
41
36
38
40
36
39q
40
37
39
41
37
39
40
37
39
40
38
Dissolved Oxygen Conductivity
(mg/l) (umhos/cm)
11
18
10
11
13
8
12
13
12
12
12
11
12
13
12
12
13
12
13
13
12
13
13
12
12
13
11
11
13
11
.5
,0
.1
.9
.4
.8
•9
• 3
°3
.5
.9
,4
.9
.3
06
,8
.2
.2
.2
.7
.7
.2
.7
.4
• 5
.4
,8
.8
.4
.3
340
420
320
330
380
300
330
400
300
330
380
300
360
430
320
330
410
300
320
350
300
310
320
290
300
340
280
320
350
300
76
-------
^ TABLE 18
1969 AUTOMATIC MONITOR RESULTS
Detroit River at Gibraltar, Michigan
FWPCA.LHBO
Week
No.
11
12
13
14
15
16
17
18
19
20
Temp.
Date
3/9
3/16
3/23
3/30
4/6
Vl3
4/20
4/27
5/4
5/n
-3/15
- 3/22
- 3/29
-4/5
- 4/12
-4/19
- 4/26
-5/3
- 5/10
- 5/17
I
Avg,
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max,
Min.
[op)
39
42
36
42
47
39
44
47
42
42
47
39
48
51
45
51
53
48
50
54
48
57
61
52
59
61
55
57
62
54
Dissolved Oxygen Conductivity
(rag/1)
12.4
14,4
11.2
12,3
14.8
11.1
11,8
13.0
10,9
12,1
12.8
10.9
11,4
12,7
9.8
9.5
10.3
8.3
9.5
11.1
7.9
9,1
10,5
5.7
9.2
10.9
8,1
8.7
10,3
7.5
(umfaos/cm)
320
340
300
320
460
300
350
430
300
340
420
320
350
380
340
350
390
340
350
370
330
360
480
330
330
360
310
320
350
300
77
-------
TABLE 18
1969 AUTOMATIC MONITOR RESULTS
Detroit River at Gibraltar, Michigan
FWPCAoLHBQ
Temp,
Date
Dissolved Oxygen
(mg/1)
Conductivity
(umhos/cm)
21
22
23
5/25 - 5/31
6/1 - 6/7
(Dredging upstream
27 6/29 - 7/5
28
29
30
31
32
33
7/6 - 7/12
7/13 - 7/19
7/20 - 7/26
7/27 - 8/2
8/3 - 8/9
8/10 - 8/16
Avg,
Max.
Min,
Avg.
Max.
Min.
Avg.
Max.
Min.
61
67
59
63
66
61
65
67
62
8.3
8.6
8.0
8.3
8,8
7,1
01
_
_
330
370
320
330
370
300
320
340
300
monitor shut off)
Avg.
Max.
Min.
Avg.
Max.
Min,
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg.
Max.
Min.
Avg,
Max.
Min.
71
73
70
71
75
69
76
79
72
77
79
75
79
80
77
77
80
76
78
80
76
9.4
11,0
7.4
8.2
9.7
6.5
5^4
8.4
2,2
3.6
7.3
1.6
6.8
9.3
4.7
8.4
9.7
6.7
7.5
8.1
6.9
310
330
290
320
350
300
310
330
290
320
350
300
320
340
300
310
360
290
310
340
290
78
-------
TABLE 18
1969 AUTOMATIC MONITOR RESULTS
Detroit River at Gibraltar, Michigan
FWPCA,LHBO
Week
No.
34
35
36
3T
38
39
4o
42
43
Date
8/17 - 8/23 Avg,
Max.
Min.
8/24 - 8/30 Avg.
Max.
Min.
8/31 - 9/6 Avg.
Max.
Min.
9/7 - 9/13 Avg.
Max.
Min.
9/14 - 9/20 Avg.
Max.
Min.
9/21 - 9/27 Avg.
Max.
Min.
9/28 - 10/4 Avg.
Max.
Min.
10/5 - 10/11 Avg.
Max.
Min.
10/12-10/18 Avg.
Max,
Min.
10/19-10/25 Avg.
Max.
Min,
Temp,
78
80
76
78
79
75
78
79
76
75
79
71
71
72
70
69
71
67
67
68
66
66
68
63
62
65
57
55
57
52
Dissolved Oxygen
(ng/D
8.2
9»3
6,9
Conductivity
(umhos/cm)
300
340
260
300
330
280
320
340
300
320
350
300
330
360
300
320
360
310
320
370
300
310
360
290
310
340
300
310
350
290
79
-------
TABLE 18
1969 AUTOMATIC MONITOR RESULTS
Detroit River at Gibraltar, Michigan
FWPCA.LHBO
Week
No.
Tempo
Date
10/26-11/1 AVg. 52
Max. 54
Min. 50
n/8-11/15 Avg. 51
Max. 53
Min. 50
11/16-11/22 Avgo 55
Max. 58
Min. 50
11/23-11/29 Avg, 5^
Max. 56
Min, 50
11/30-12/6 Avg. 52
Max. 5^
Min, 51
Dissolved Oxygen
(ag/D
Conductivity
(umhos/cm)
320
350
300
320
360
300
320
3^0
310
360
IflO
330
320
3^0
310
80
-------
FIGURE )9
MICHIGAN
LEGEND
DETROIT EDISON
UNITED STATES RUBBER CO/A
INDUSTRIAL OUTFALLS (U.S.)
PUBLIC UTILITY OUTFALLS
INDUSTRIAL OUTFALLS (CAN.)
ANACONDA - AMERICAN BRASS
CO.
REVERE COPPER AND
BRASS INCORPORATED
PLASTIC DIVISION .,
ALLIED CHEMICAL CORR '7
PEERLESS CEMENT
FORD MOTOR CO.
DARLING 8 CO
SCOTT PAPER CO
GENERAL CHEMICAL DIV.
ALLIED CHEMICAL CORR
GREAT LAKES STEEL CORP.
HOT STRIP MILL
DANA CORP.
GREAT LAKES STEEL CORP.
ECORSE MILL
WYANOOTTE CHEMICAL CORR
NORTH SIDE WORKS
PARK DAVIS
FORD MOTOR co.
OF CANADA
HIRAM WALKER a SONS LTD
©MISTERSKY POWER STA.
INDUSTRIAL CHEMICALS DIV.
ALLIED CHEMICAL CORP. DETRO|T -EDISON
® DELRAY PLANT
SEMET - SOLVAY DIV
ALLIED CHEMICAL CORP.
GREAT LAKES STEEL CORR
BLAST FURNACE DIV.
CANADA SALT CO. LTD.
INDUSTRIAL CHEMICALS DIV.
ALLIED CHEMICAL CORP.
DETROIT EDISON
RIVER ROUGE PLANT
E.I. du PONT de NEMOURS 8 CO INC.
INDUSTRIAL a BIOCHEMICALS DEPT.
WYANDOTTE CHEMICALS
ONTARIO
WYANDOTTE
MUNICIPAL PLANT
SCALE IN MILES
DETROIT
TRENTON
EDISON
CHANNEL
ALLIED CHEMICAL OF CANADA LTD.
_ CALVERT DISTILLERIES LTD.
AMPLEX DIV.
LAKE HURON BASIN OFFICE
INDUSTRIAL OUTFALLS
DETROIT RIVER
U S DEPARTMENT OF THE INTERIOR
FED
RtAT LAKH REGION
WYANDOTTE CHEMICAL CORP.
SOUTH SIDE WORKS
PENNSALT CHEMICALS,
CORP. E 8 W.
FIRESTONE TIRE & RUBBER CO.
FIRESTONE STEEL PRODUCTS DIV.
McLOUTH STEEL CORP.
TRENTON PLANT
MOBIL OIL CO.
CHRYSLER CORP.
TRENTON ENGINE PLANT
MONSANTO CHEMICAL,
CO.
TRENTON RESINS
CORR
RYSLER CORP.
EMICAL PRODUCTS DIV.
:LOUTH STEEL CORP.
3RALTAR PLANT
81
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FIGURE 20
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OBSERV&IIQN RUNS - 1969
1/17 Oil -was seen on river surface at several locations: Perm -General
RR bridge, in vicinity of Elm Street at Dixie Highway ,? and
outfall at Monroe Steel and Casting Company .
1/gY Flooding due to ice occurred at site of Monroe water treatment
plant.,
1/31 Heavy oil concentrations were seen extending downstream for TV
from Consolidated Packaging Corp. -North Plant outfall Wl62<> Light
oil concentration's v« ••<=• seen further downstream at Renault Great
Lakes,, Inc<, outfall '•«'!:/.>. Pulp fiber -was observed at Elm Street
and Dixie Highway and at the site of Consolidated Packaging Corp.
South Plant outfall Wl^.
2/2J[ Oil was ivuud in the river at Monroe Steel Casting Company outfall
Wl63» Further downstream, oil and oil traces were observed at
Consolidated Packaging Corp. outfall Wl62»
3./11 Oil traces were found in the area of Monroe Steel Casting Company
outfall, An oil film was observed in the river at US 223 bridge
at Palmyra o Oil traces were seen in Mason Run at W162 and in the
turning basin and dockside area of Renault Great Lakes, Inc,
outfall W155° Milky effluent and heated pulp residues were
evident on the river bank in the area of Consolidated Packaging
Corp. outfall ¥L5k»
3/27 Heated, milky water covered with brown scum was observed near
the Time Container Corp. water intake. Oil traces continued at
Monroe Steel Casting Company (¥1.63) and oil and paper pulp wastes
83
-------
Raisin River (cont.)
observed at Elm Street bridge and Dixie Highway. In Mason Run at
Dixie Highway crossing, there was evidence of heated paper pulp
wastes.
Area above the industrialized lover portion of the river was clear.
A black area of heavy pulp concentration was observed in the
in the vicinity of outfall Wl65. Water between W15U and W152
varied from a dark green containing heavy pulp concentrations
to a milky color containing oil, suspended solids, and a soapy
substance. At the mouth of Mason Run, water was milky and
contained oil.
6/°._ Effluents from eleven outfalls varied in color from light clear to
a dark gray. Some grease was observed at the Monroe sewage
treatment plant outfall Wl80. Paper mill wastes were observed
at outfalls of Consolidated Packaging Corp. South and Worth plants.
Oil traces were detected at Ford Motor Company outfall W152. Over-
all, the river appeared clean.
T/29 Paper mill wastes were observed at Time Container Corp. outfall
Wl65. Paper pulp wastes were also observed at Consolidated
Packaging Corp.-South Plant outfall. Waste covered an area
approximately 1,000Ixl75t« Paper pulp waste was also observed
in Mason Run at the site of the Ford Company bridge. The waste
area extended 1,000'x50'. At the mouth of Mason Run, a light
gray waste area, with a sewage odor, extended 500'xlOO'. Some
oil was observed at the Union Camp Corp. drain WITT as well as
the Dilution Canal at W150.
84
-------
Raisin River (conto)
8/10 A gray-colored effluent Containing heavy concentrations of paper
pulp waste was observed at Consolidated Packaging Corp« South Plant
outfall W15^o The gray°eolored pulp carrying discharge covered
a 400'x759 area of the river„
Darkj, milk-colored effluent containing paper waste extended for an
area 400',x758 from the Consolidated Packaging Corp. "South Plant
outfall W?*K At the same time., the entire length of Mason Run
was colored MOI^O lip 3 v earn on tne rlvei-^, a aar&-'S;ray discharge
poured frora outfall Wl64 at the site oi Consolidated Packaging
Corpo-West Plant,, Heavy oil concentrations occupying 25B^10' area
observed0 Downstream from the Penau.lt Company out fall. ^ a
lKy colored ei'fluent with an oil area 25* square was
observed<• A black effluent was observed pouring out of the Ford
Motor Company sewage treatment (Wl8l)o
Heavy concentrations of paper pulp were observed in the gray
effluent emanating from Consolidated Packaging Corp0"South Plant
outfall W1.54o The area affected extended for 300'xlOO'. Paper
wastes were also observed in a 300'xlOO' area at the mouth of
Mason run (W153)o
Light to medium oil concentrations were observed at outfall Wlj?l
and W150? respectively-
10/16 Paper reprocessing wastes and odors were observed at a number of
outfallso A beige-colored effluent with characteristic paper
processing odor was observed flowing strongly from the Time Con-
tainer Corp. outfall. The effect was visible from 50' offshore
to 200 yards downstream* Downstream, small paper pulp deltas
85
-------
Raisin Jtiver (conto)
were building ap in front of Consolidated Packaging Corp."North
Plant outfall W1.62 and the South Plant outfall
In the turning basin} a grayish discharge was observed coming
from the Renault Great Lakes outfall <> An oil odor was detected
at a 75" diameter iridescent oil slick around a boil in the river
at Ford's submerged outfall W150,
-------
OBSERVATION ROTS - 1969
j^SE5L^L52y5O™5S
toieral_Pb3erYati.ons-
1/9 There was oil on the surface of the water from 300" above ¥1^0
t»A=*S«=
to the mouth of the Rouge River„ Grease and meat fat were
observed at Darling and Company and downstreams
Ford turning basin and slip were a bright rust color traceable
downstream to the Jefferson Avenue bridge<>
1/16 The Rouge Blver appealed a. rust eo.ior VLtn a trs,e
-------
Oil wp.s observe*! e'iong the .v«* in1 <-.i-.o;:«: 01 th*-.- rivt-ro The oid
ciiannel. ,l,oo>ve'i b^t'^er tna/i noi'.ri?u .>
'•>(.' A Halve, oil. zilift vr,^; observed o-. !,hi& i.ppe? ro-j^f- ri.-.'vi i row Wl to
Fora's turning t"33"jj wn*:r'o it s-'-e.'^J to o 1; «x of •>-•.!• „ 01 x or t-Sir
suost/ince «?*u the ?-'b"l•'.';. -.iv^^n Ph friage >;??.> ti'.^.c^'i to a, Iea;< or
otjivi'o'll l COM Lr:e *!''"'•,.ru 11 1 Aspr.'^.,.1.'1 Coir-TY\tvy <> Ttt; o',d 'jViat'.r.ei E-'n-;^,;.? e
•L'i good cone i txoi; o
. , !•,:,."?? ".es^;, c1;,^ r.j.•;',,.;-: .-; Det ...no '".he sriliiijier -,-if..t'/c
WlB'-'o ^''— '^?'^'iv"'t''j -•-,. i^;.x /' ./t'r--yr; rrj-';^*; bad ^t^i'^ea to ftcve oat
and i.ravel covHsUro^.., T'fie olo ctv-inriRi ^ppenvea gooa despite
Great lAke^ RtfccJ t;IOi aiiv-naz^nit; a r..L«^H ^ar-jt^nceo The snore-
cut c'nanrjeJ. nau & X;,£,;i*. Latinisn foLor and a film of oil on it°
"^ie downi'iver ena oi Ine skljTBiier at, TMx Avenue farldge was opened
and oi!5 grease., ."Jia +,ra'3,r floated downstream,, Ttje old channel oi
the Pouge Birer >?;• t'tvi,' G,~. the turn I tig ba&in appeared goodo 'Ehe
water did not ICCK f,& ruaiy K.S usual„
j/2.1 Upsireaaa pajjt Tei,ofo--.apn Koao, tlie Bouge Fiver is being f'iliea in
with dirto
The sklmne*' at the no^rawest COI...-M 01 Dlx: j\venue "bridge wa5 moved,
Oak wood Runping Station canal bad oil in It that was typsr.sing
the Bkii.ij.ier- ,-?nd. enienng u?e Fouge River 0
-------
Detroit _rinl jt.r.ige._ lasers (rciit.)
3/'?8 O.il v^s leaking fro and the -.,.... irg a,,.d p. I trie. e^irf! n iv'^r :-•. .":(•: n*, ii\
>/13«X Osltve.ofl P^Ttniixg St'it Inn c--\nal .a ill h-id oil le<-.tur.?u T-K--
ol d ej-i.irinel ap;ne;ired go'-i, "1 UA;:;^"- •.oai-'? wf-i.it e sef ?ie;U.f, .of jMr«I RKbrid£i«.
4/sO i'ij fr-nrn. P'trestotif:- wit and ^or.^jaH1--^ TreeM w^^ :i~ dcf;:^;\ v r^ observed coaiiiig ito^i life
Ecorse Croeir.
"Water was hl^'r. .. tn-J.rc-T-ir'f"1.,, rrin.-t ."'f *:JM~ ouiiXliS wer*^ -.ufrmtirfit1'*,' or
partly subaer^.i , The r'""r.?'">it. r,^-'^: v*4S f'all of sewagn and deV. r::
from street runoff and combinea sever overflows Blood s snail
pieces of meat^ and :ini,a:a,l entrisls ve,.re flowing Firom the DnEois
sewer.
Ford had a "boom iicross the river south of W126v There was, no
flow at Scott Paper Co, (W109) or Allied Chemicals (W100), An
oil slick T5! wide .and I^OC' tn iBOO8 long was observed on the
ILS, side^ sotth of the Mb&ssaaor Bridge, The Detroit River
appeared fairly c,*e^r>9 as did Connors Creek=. The Rouge River had
little iron oxide jV except for che north half of the turning "bEsiri-
Due to high water i-?^! ^ 60 percent of the outfalls were
submerged. The Bouge River vas clear of rust-colored water » In
the old channel, creosote spots 6" jc 8" covered the entire
89
-------
Detroit and Rouge Rivers (cont'd„)
A "boom was across the channel at the Ford foundry. The Rouge River
looked "black with a light oil film covering the river surface.
6/26 The Rouge River was free of oil and looked go6d. The "bank near the
Inland Lime and Stone Company was "being cleaned "by a barge-tug.
Scrap iron, piled near the Rouge River on the Detroit Marine
Terminal property^ had slid into the river. This was reported
to the Detroit Corps of Engineers. On 7/7* a crane and electromagnet
were observed retrieving the metal from the river.
7/9 High water and light traces of oil and debris were observed on the
Rouge River. Debris was very heavy at the Ford turning basin.
7/25 The Detroit River north of the Rouge River looked very clear.
Dredging operations were underway at Great Lakes Steel and
grease-coated debris was floating in the area* The Detroit
STP outfall (R155) had slight traces of sewage solids.
8/8 Oil slicks (50'x30', 10'x5', and 15'xlO') were seen in Ford's
boat slip behind the oil skimmer.
8/19 There was heavy black oil along both banks of the Rouge River
from the mouth to the turning basin at Ford's. Traces of oil
and a creosote-type material were found in the old channel.
The turning basin contained heavy iron oxide. Little debris was
found near the Dix Avenue bridge.
8/22 Heavy iron oxide concentrations were evident in the Rouge River
turning basin. Light traces of oil and possible creosote were
found in the old channel, A boom was across the Rouge River at
Ford's W126, with a crew of men cleaning up the river behind the boom.
90
-------
Detroit and Rouge Rivers (cont.)
8/28 Heavy areas of oil^ probably creosote, vere seen in the old channel
near Zug Island as well as along the north bank downstream from the
turning basin at Roulo Creek and downstream from the Ford foundry
(W130)o The oil boom downstream from the Ford foundry was out of
position and full of scraps and oil. The river was a heavy iron
color downstream from the foundry» Heavy oil was found at W12T
and coming from under the skimmer below W130. Oakwood Pumping
Station was free of oil«
10/2*1 The Rouge River was black with leaves and solids on the surface„
Behind the middle skimmer at Ford's W125? the area was filled
with oil.
10/30 The upper Detroit River water was clear, blue-green color with
some weeds. Lower Detroit River was green and turbid with an
abundance of floating weeds and some sewage and grease. Few oil
slicks were observed. The Rouge River had little visible effect
on the Detroit River. The general condition of the Detroit River
was above average.
Monsanto was working on their lagoons and a steady flow of gray
solids was pouring out of the south dike opening. Gas bubbles
were observed rising in the adjacent river area.
91
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ON i AR 10
Detroit River Lt.
SCALE IN MILES
LAKE HURON BASIN OFFICE
LOCATION OF SAMPLING STATIONS
BACTERIOLOGICAL STUDY -1969
WESTERN LAKE ERIE
U.S. DEPARTMENT or THE INTERIOR
FEDERAL. WATER POLLUTION CONTROL AOVtK|«Tft*T(ON
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Date
Jan. 2
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April 9
April 23
May 7
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June 4
TABLE 19
196Q Western Lake Erie Beaches and Tributaries
,-, Detroit River - Gibraltar Monitor
Parameter - Total Coliform (MF/100 rjil)
FWPCAS LHBO
MF/100 ml
1,300
13,000
21,000
3,900
1*9,000
7,900
18,000
16,000
1,100,000*
19,000
5,500
Date
June 11
June 16
June 25
July 2
July 16
July 30
Aug. 13
Sept. 11
Octo 8
Octo 20
Nov. 3
Nov. 17
Med. 19,000/100 ml
Max. 1,100,000/100 ml
Min. H60/100 ml
NS 2k
^Dredging going on upstream
MF/100 ml
290,000
39,000
170,000
76,000
67,000
39,000
19,000
650
87,000
81+0
38,000
900
95
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FIGURE 22
ONTARIO
M I C H KG A N
;
B Tributary Samples
© Lake Samples
T3IO~-f«-I60S
LAKE .
LAKE HURON BASIN! OFFICE
SVATIOW LOCA'.'iC.XS
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LABORATORY METHODS
The analytical methods used by the laboratory for physical, chemical,
and biological analyses were the procedures published in "Standard
Methods for the Examination of Water and Wastewater," 12th Edition, 1965.
Also, procedures were followed from the FWPCA Methods for Chemical
Analysis of Water and Wastes, September 1969. Additional analytical
procedures and modifications developed by the Great Lakes Region Committee
on Analytical Methods, FWPCA, were employed as required in the analysis
of bottom sediment material. Modifications have been made on some of the
methods to improve the sensitivity or to expedite a systematic analytical
scheme. Before adopting any modification, a thorough study was made to
evaluate the effect of the change.
To assure contiilually reliable data, reference standards of known
composition and blanks were analyzed simultaneously with all tests.
A summation of the analyses performed is shown on the following
pages. Specific techniques or modifications to "Standard Methods"
procedure are shown where applicable.
103
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Lake Huron Basin Office
Summary of Laboratory Procedures
Analysis Unit
Temperature °C
Conductivity Jtaihos/cm
pH SU
Dissolved oxygen fflgA
Initial dissolved oxygen demand mg/1
Biochemical oxygen demand mg/1
Chemical oxygen demand rog/1
Chloride mg/1
Sulfate mg/1
Acidity mg/1
Alkalinity mg/1
Nitrate-Nitrogen mg/1
Nitrite-N mg/1
Ammonia-N rog/1
Organic-N mg/1
Total KJeldahl-N mg/1
Total phosphorus ng/1."
Total soluble phosphorus mg/1
Phenol jug/1
Iron >ug/l
Turbidity JOJ
Oil and grease mg/1
Technique or Modification
No modification
Specific conductance cell
Glass electrode method
Method A - Alsterberg (Azide),
modification of the
Winkler method
No modification
Dissolved oxygen analyzer
No modification
Mercuric nitrate
Barium aulfate, autoanaiyzer
No modification
Potentionmetric pH U.5 and
PH 8.3
Brucine sulfate method
No modification
Minor modification "Standard
Methods"
Potassium antimony tartrate
method
Aminoantipyrlne
1,10 phenanthroline
Hach "2100" turbidimeter
Hexane extraction
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Lake Huron Basin Office
Summary of Laboratory Procedures(conto)
Analysis
Total solids
Dissolved solids
Suspended solids
Total volatile solids
Total volatile dissolved solids
Volatile suspended solids
Settleable solids
Non-settleable solids
Volatile settleable solids
Volatile non-settleable solids
Chlorine residual
Cyanide
Sodium
Potassium
Magnesium
Calcium
Hardness
Total coliform
Fecal coliform
Fecal Streptococcus
Total plate count
Phytoplankton
Unit
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Wl
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
MF/100 ml
MF/100 ml
MF/100 ml
MF/100 ml
Orpr/ml
Technique or Modification
Total residue, procelain dish
By difference (total solids
minus suspended)
Filtrable residue, Gooch
cruicible
No modification
By weight, Gooch cruicible
Orthotolidine method
Elly modification of
Serf ass method
Flame photometry
No modification manually,
autoanalyzer
EDTA titration, murexide
indicator
EDTA titration, calmagite
indicator
No modification
Sedgwick-Rafter cell clump
counts
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