EPA-450/3-76-018-d
April 1977
DETERMINING
INPUT VARIABLES
FOR CALCULATION
OF IMPACT OF NEW
SOURCE PERFORMANCE
STANDARDS: WORKSHEETS
FOR MINERAL PRODUCTS
INDUSTRIES
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air and Waste Management
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
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EPA-450/3-76-018-d
DETERMINING INPUT VARIABLES
FOR CALCULATION OF IMPACT OF NEW
SOURCE PERFORMANCE STANDARDS:
WORKSHEETS FOR MINERAL
PRODUCTS INDUSTRIES
by
The Research Corporation of New England
129 Silas Deane Highway
Weathersfield, Connecticut 06109
Contract No. 68-02-1382
EPA Project Officer: Gary D. McCutchen
Prepared for
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air and Waste Management
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
April 1977
-------
This report is issued by the Environmental Protection Agency to report technical
data of interest to a limited number of readers. Copies are available free of
charge to Federal employees, current contractors and grantees, and nonprofit
organizations - in limited quantities - from the Library Services Office (MD-
35), Research Triangle Park, North Carolina 27711; or, for a fee, from the
National Technical Information Service, 5285 Port Royal Road, Springfield,
Virginia 22161.
This report was furnished to the Environmental Protection Agency by The Research
Corporation of New England, Weathersfield, Connecticut 06109, in fulfillment
of Contract No.68-02-1382 . The contents of this report are reproduced herein
as received from The Research Corporation of New England. The opinions,
findings, and conclusions expressed are those of the author and not necessarily
those of the Environmental Protection Agency. Mention of company or product
names is not to be considered as an endorsement by the Environmental Protection
Agency.
Publication No. EPA-450/3-76-018-d
11
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FOREWORD
/
During 1974, two studies were initiated that ultimately resulted in the
establishment of priorities for developing and promulgating New Source
Performance Standards (NSPS) . The procedures used to determine these
priorities produced a great deal of information that is believed to be useful
in the industries involved and, accordingly, is being published in this series
of reports (EPA-450/3-76-017, EPA-450/3-76-018, EPA-450/3-76-019, and
EPA-450/3-76-020) . This information is organized as follows:
EPA-450/3-76-017 discusses (1) the mathematical model (Model IV) used
to determine NSPS impacts over a 10-year period; (2) the methods used to
attain input variables; and (3) the summary tables which are the heart of
this study. Included in the summary tables are data related to (1) emission,
growth, and replacement rates; (2) present and future production and
capacity; (3) nationwide emissions; and (4) NSPS impact. These tables
include information on 13 pollutants and nearly 200 stationary source
categories.
EPA-450/3-3-76-018-a, -b, -c, -d, -e, and -fare the calculation sheets,
showing how the input vairables reported in EPA-450/3-76-017 were derived. All
information sources, assumptions, and calculations are documented and explained.
The appropriate worksheets are arranged alphabetically in the following volumes:
018-a - Stationary Combustion Sources
018-b - Chemical Processing Industries
018-c - Food and Agricultural Industries
018-d - Mineral Products Industries
018-e - Metallurgical Industries
018-f - Miscellaneous Sources (Evaporation Losses, Petroleum
Industry, Wood Products Industry, and Assembly Plants
iii
-------
The 018-a -f series is of interest only to those concerned with the detailed
calculations used to determine the Model IV input variables.
EPA-450/3-76-Q19-a provides additional results and information produced
during the priority study. Its major purpose is to describe the computer program
used to rank all the Model IV input and output variables by pollutant (these rankings
are reported in 019-b and -c) . In addition, it contains (1) summaries of the
control systems considered "best" for each source, (2) equipment retirement ages,
and (3) emission trends for each source category.
EPA-450/3-76-019-b and c present the computer-generated ranked data for
each pollutant. Ranking is from highest to lowest for each of the 21 variables,
e.g., A (nationwide capacity) and Eu (uncontrolled emission rate) . Volume 019-b
contains ranked data for particulate, nitrogen oxide (NOX) , and sulfur oxide (SOX)
sources. In Volume 019-c, the remaining pollutant sources are ranked: hydrocarbons,
carbon monoxide (CO), fluorides, hazardous material, acid mist, lead, ammonia,
sulfides, chlorine, and trace metals.
EPA-450/3-76-020, the final document in this series, takes the objective
impact values from EPA-450/3-76-017, adds subjective judgements, and uses
these combined criteria to produce a priority list for NSPS development. The
report then calculates nationwide emission trends over the next 15 years for
each criteria pollutant (particulate, SOX, NOX, hydrocarbons, and CO) based
on a series of scenarios (e.g., no NSPS, 20 NSPS per year, etc.)
In summary, documents EPA-450/3-76-017 and 020 present the results of
this study. Each stands alone, but they also complement each other, with 020
building on the results of 017. The remaining documents (018-a -f and 019-a -c)
present additional and/or more detailed information derived from the impact
and priority studies.
IV
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DETERMINATION OF INPUT VARIABLES
FOR
THE MINERAL PRODUCTS INDUSTRY
-------
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut (T6109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway «•
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Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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TRC — The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut" 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
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125 Silas Deane Highway
Wethersfield, Connecticut 0610°"
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Industrial Factors
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut (16109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Industrial Factors
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Source
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut' 06109
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Computation Sheet For Emission Factors
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Source
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane HigRway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highwety
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
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Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards_
Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors .
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Industrial Factors
Calculations Done By A&jlf£ . Date
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 N_ew Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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TRC — The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
Calculations Done By iL^-erft Date
Source
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut* 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
Calculations Done By MofQtg. Date
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106
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Emission Factors
Calculations Done By /3fc)/ft£^ Date
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Industrial Factors
Calculations Done By /9oX^!V Date_
Source
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The largest use for calcium carbide is for production of acetylene Most Reppe chemicals and
acetylenic alcohols are made from calcium carbide-derived acetylene. Some tnchloroethylene and perrhloroethylene are made
from calcium carbide-derived acetylene, however, most tnchloroethylene and perchloioethylene are now manufactured from
ethylene or hydrocarbon-acetylene (eg, acetylene manufactured by the partial oxidation of methane) At one time, all neo-
piene was manufactured from calcium carbide-derived acetylene, but now butadiene is the mam raw material Ethylene and
hydrocarbon-acetylene have very nearly replacerl all calcium carbide derived acetylene in vinyl acetate manufacture, and have
replaced calcium carbide derived acetylene in vinyl chloride manufacture Acrylic acid and esteis manufacture is no longer
based on calcium caibide-acetylene Piopylene has completely replaced calcium carbide-derived acetylene in acrylomtrile
manufacture One souice believes that calcium caibide-denved acetylene may cease to be used lor the manufacture of
chemicals by 1973 (See the CEH ACETYLENE report for further information on chemical uses for acetylene) The mam
non-chemical use for calcium carbide derived acetylene is in welding
Calcium carbide is used in metallurgy for desulfunzing and deoxidizing In Canada, it is used to produce calcium cyanamide,
calcium cyanamide is not produced in the United States, however. (See the CEH data sheet "Calcium Cyanamid — Imports"
for further information )
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TRC — The Research Corporation ,pf New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Industrial Factors
Calculations Done By r* Date
Source
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TRC -- The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
Project Number - 32391 New Source Performance Standards
Computation Sheet For Industrial Factors
Calculations Done By /4fe?>»3gv'g/ Date_
Source
72.
The largest use for calcium carbide is for production of acetylene Most ,Reppe chemicals and
ace ty lei ic alcohols are made1 from calcium carbide-derived acetylene. Some tnchloroethylone and perchloroethylene arc made
from calcium carbide-derived acetylene, however, most trichloroethylene and perchloroethylene are now manufactured from
ethylene or hydrocarbon-acetylene (eg, dcetylene manufactured by the partial oxidation of methane) At one time, all neo-
prone was manufactured from calcium carbide-derived acetylene, but now butadiene is the mam raw material Ethylene and
hydrocarbon-acetylene have very nearly replaced all calcium 'carbide-denvnd acetylene in vinyl acetate manufacture, and have
replaced calcium carbtde-derived acetylene in vinyl chloride manufacture Acrylic acid and esters manufacture is no longer
based on calcium carbide-acetylene Propylene has completely replaced calcium carbide-derived acetylene in acrylomtnfe
manufacture One source believes that calcium carbide-derived acetylene may cease to be used for the manufacture of
chemicals by 1973 (See the CEH ACETYLENE report for further information on chemical uses for acetylene.) The main
non-chemical use for calcium carbide-derived acetylene is m welding.
Calcium carbide is used in metallurgy for desulfunzmg and deoxidizing. In Canada, it is used to produce calcium cyanamide;
calcium cyanamide is not produced in the United States, however. (See the CEH data sheet "Calcium Cyanamid - Imports"
tor further information.)
(-6.7%)
113
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125 Silas Deane Highway
Wethersfield, Connecticut 06109
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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Project Number - 32391 New Source Performance Standards
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Hi'ghway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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125 Silas Deane Highway
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1 . REPORT NO
EPA 450/3-76 - 018d
3. RECIPIENT'S ACCESSIOf*NO.
4. TITLE AND SUBTITLE
Determining Input Variables for Calculation of Im-
pact of New Source Performance Standards: Work-
sheets for Mineral Products Industries
5. REPORT DATE
April 1977
6. PERFORMING ORGANIZATION CODE
7 AUTHOR(S)
Thomas G. Hopper
William A. Marrone
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
TRC - The Research Corporation of New England
125 Silas Deane Highway
Wethersfield, Connecticut 06109
10. PROGRAM ELEMENT NO.
2AC129
11. CONTRACT/GRANT NO.
68-02-1382
12. SPONSORING AGENCY NAME AND ADDRESS
EPA-Office of Air Quality Planning and Standards
Emission Standards and Engineering Division
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Task Final; 7/74 - 7/76
14. SPONSORING AGENCY CODE
EPA - OAQPS
15. SUPPLEMENTARY NOTES
Project Officer for th?s Report is
G. D. McCutchen, Mail I rop 13, Ext. 271
16. ABSTRACT
The purpose of this do tment is to present the results of a study to determine the
impact of new source peiformance standards on nationwide emissions. The work pre-
sented covers 14 potentixl pollutants from approximately 200 source categories for
the year 1985. The results are being used by EPA as input to the development of an
overall standard setting strategy. The report contains information regarding con-
trolled and uncontrolled e. ission factors, State emission limitations, industrial
capacity, utilization, grx, *h and retirement rates. The results of this study have
been published as three vox les which encompass ten separate documents. This docu-
ment contains Appendix 4D of Volume II - Calculation Sheets for the Mineral Products
Industry.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Air Pollution
Air Pollution Control
Industrial Processes
Combustion
Regulations
Economic Factors
Priorities
Chemical
Industry
Paper
Industry
Petroleum
Industry
Metal
Industry
Agricultural
Mineral
Flyash
Exhaust
Gases
18. DISTRIBUTION STATEMENT
Unlimited
19. SECURITY CLASS (ThisReport/
Unclassified
21. NO. OF PAGES
247
20. SECURITY CLASS (This page)
Unclassified
22. PRICE
EPA Form 2220-1 (9-73)
242
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