EPA-600/3-76-093
August 1976
Ecological Research Series
v«r??
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RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into five series. These five broad
categories were established to facilitate further development and application of
environmental technology Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The five series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5 Socioeconomic Environmental Studies
This report has been assigned to the ECOLOGICAL RESEARCH series. This series
describes research on the effects of pollution on humans, plant and animal
species, and materials. Problems are assessed for their long- and short-term
influences Investigations include formation, transport, and pathway studies to
determine the fate of pollutants and their effects This work provides the technical
basis for setting standards to minimize undesirable changes in living organisms
in the aquatic, terrestrial, and atmospheric environments.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
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EPA-600/3-76-093
August 1976
ANALYSIS OF AIR POLLUTANTS BY MASS SPECTROSCOPY
by
Alden L. Crittenden
University of Washington
Seattle, Washington 98195
Grant No. R801119
Project Officer
Ronald K. Patterson
Atmospheric Chemistry and Physics Division
Environmental Sciences Research Laboratory
Research Triangle Park, North Carolina 27711
ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711
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DISCLAIMER
This report has been reviewed by the Environmental
Sciences Research Laboratory, U. S. Environmental Protec-
tion Agency, and approved for publication. Approval does
not signify that the contents necessarily reflect the views
and policies of the U. S. Environmental Protection Agency,
nor does mention of trade names or commercial products
constitute endorsement or recommendation for use.
11
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ABSTRACT
High-resolution mass spectroscopy was shown to be a useful
means of characterizing the organic fraction of urban aero-
sols. Quantitative accuracy was limited, particularly for
compounds of low abundance. Some ambiguities were found in
the assignment of origins of ions formed in the mass spec-
trometer.
Major constituents of fine particles in urban atmospheres
are sulfuric acid or sulfates, and hydrocarbons. Other
compounds that can be detected include phenols; aromatic
carboxylic acids and, possibly, esters of these; and ali-
phatic dibasic acids. Evidence was found of several other
difunctional compounds, including nitrate or nitrite spe-
cies.
Strong evidence was found for the presence in some urban
aerosols of compounds reported by others as products of the
oxidation of toluene in smog chamber reactions. Lesser
evidence was found for products of the oxidation of ter-
penes.
A few samples of automobile exhaust particulates have been
analysed. The occurrence of benzoic acid and the benzoyl
ion in mass spectra appear to be possible indicators of
automotive contribution to the organic components.
Results for a large number of compounds are provided for
88 samples of aerosols taken at 11 sites.
This report was submitted in fulfillment of Grant Number
R801119, under the sponsorship of the Environmental Pro-
tection Agency.
111
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CONTENTS
Abstract iii
Figures vi
Tables vii
Acknowledgements. ...... viii
I. Introduction , 1
II. Conclusions 3
III. Recommendations 6
IV. Characteristics of Mass Spectra from
Compounds in Aerosols 8
V. Experimental Procedure 11
VI. Data Reduction 15
VII. Compound Files and the Basis for
Identification. 18
VIII. Accuracy of the Method 20
IX. Aerosol Samples Studied 23
X. Discussion of Results 28
References 66
Publications 68
Appendix 69
v
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FIGURES
Number
1 Sample Insertion Probe 13
2 Diurnal Variations of Alkenes and Alkanes. . 33
3 Diurnal Variations at West Covina for
Hydrocarbons and Phenols 34
4 Diurnal Variations at Seattle for Alkenes,
Alkanes, Benzoyl Ion, and Diacids 35
5 Diurnal Variations in Benzoyl Ion 42
6 Diurnal Variations at West Covina for
Diacids and CONH 44
7 Diurnal Variations of Some Oxygen
Difunctional Compounds at West Covina. . . 49
8 Total Oxygen Difunctional Compounds 50
9 Diurnal Variations at Seattle for Oxygen
and Nitrogen Difunctional Compounds and
Toluene Products 51
10 Total Nitrogen Difunctional Compounds .... 54
11 Possible Nitrogen Difunctional Compounds
at West Covina 55
12 Possible Toluene Products 57
13 Some Possible Toluene Products at West
Covina 58
14 Sulfates as Sulfuric Acid at Pomona, West
Covina, and Washington University 1973 . . 62
15 Sulfates as Sulfuric Acid at Washington
University 1974, Holiday Inn, and
National City 64
16 Some Diurnal Variations in Ammonium Nitrate. 65
VI
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TABLES
Number Page
1 Comparison of Duplicate Analyses 20
2 Comparison of Sulfate Results, West Covina. 21
3 Comparison of Sulfate Results ,
Washington University 22
4 Sample Times 21
5 Average Amounts of Hydrocarbons 31
6 Average Amounts of Phenolic Compounds ... 36
7 Distribution of Phenols 37
8 Automotive Exhaust - Benzoyl Ion and
Benzoic Acid 38
9 Average Amounts of Benzoic Acid and
Related Compounds 39
10 Ratios of Benzoyl Ion to Benzoic Acids. . . 40
11 Average Abundances of Diacids 45
12 Average Total Abundances - Difunctional
Compounds, Toluene and Terpene Products . 47
13 Relative Distributions of Oxygen
Difunctionals 48
14 Distribution of Nitrogen Difunctionals. . .53
15 Distributions of Toluene Products 59
16 Distributions of Terpene Products 60
vii
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ACKNOWLEDGEMENTS
Dennis Schuetzle, who was responsible for the early work
in this laboratory, developed the sampling apparatus and
the general methodology.
Richard L. Knights supervised most of the sample acquis-
ition and performed most of the mass spectrometric work
reported here.
Dagmar R. Cronn did much of the data reduction and cont-
ributed much of the interpretation of results.
Robert J. Charlson provided instruction and guidance in
the field of atmospheric chemistry and in site selection
and provided assistance at sampling sites.
Michael Higgins assisted with sampling and data reduction,
Roger F„ Parry performed the work on automotive exhausts.
B. R. Appel and other personnel of the Air and Industrial
Hygiene Laboratory of the State of California Department
of Health provided the Los Angeles samples and gave finan-
cial assistance for processing that data.
The support of the U. S. Environmental Protection Agency
and the assistance of W. E. Wilson and R. K. Patterson,
Project Officer, is gratefully acknowledged.
vixi
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SECTION I
INTRODUCTION
The chemical characterization of atmospheric aerosols is of
great importance in order to determine the sources and
distribution of materials in the atmosphere, to elucidate
the reactions that occur in the atmosphere, and to deter-
mine the hazards" to health resulting from the presence of a
wide variety of compounds in the atmosphere. Chemical com-
pounds present in the atmosphere include both materials
present in the gas phase and those present in liquid or
solid aerosols.
Of the gaseous components, ozone, sulfur dioxide, nitrogen
oxides, and gaseous hydrocarbons have been studied exten-
sively.
The chemical composition of aerosols is of interest because
of the common formation of such aerosols in urban areas,
with accompanying decrease in visibility, and because of the
ease with which such aerosols are respired into the lungs.
Most studies of atmospheric aerosols have been concerned
with physical properties and with the atomic composition.
A number of methods of chemical analysis have been brought
to bear on the problem of atomic composition. These include
classical wet chemical analyses, atomic emission and absorp-
tion, X-ray fluorescence, neutron activation and infrared
absorption. Of these, only the last offers the possibility
of determining molecular compositions.
Relatively little has been published regarding the molecular
species present in the organic portion of aerosols, despite
the observation that organic materials can represent a
large fraction of the total material present in some urban
aerosols (1). Most of the data available have been deter-
mined by chromatographic methods and consist mainly of data
on hydrocarbons. Presumably, this reflects the difficulty
in passing polar compounds through columns without prior
derivitization. More recently, the use of gas chromatogra-
phy, with mass spectrometric detection, has been applied to
air pollution problems. Raymond and Guiochon have studied
hydrocarbons in Paris air (2). Boyer and Laitinen have
reported an extensive study of organic compounds in auto-
mobile engine exhausts (3). Although large amounts of polar
compounds were found, they were unable to identify these.
Mass spectroscopy has long been recognized as a powerful
means of identifying organic compounds, although it is often
difficult to distinguish between isomers. The first use of
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mass spectra in the study of air pollutants was reported by
Happ, Stewart and Brockmyre in the identification of chlo-
rinated solvents (4). Shortly thereafter, Shepard et al.
used mass spectrometry in identifying a number of hydro-
carbons arid classes of other compounds in smog samples (5).
The instruments used by these early workers were of low
resolving power and were capable of measuring ion masses to
only unit mass. Even now, almost all gas chromatographic
mass spectrometry is conducted with instruments capable of
only unit mass resolution. With unit mass resolution, it
is difficult to identify individual mass numbers by empir-
ical formula, and compound identification must rest upon
the study of many different ion masses produced by a single
compound. This requires that separations be made so that
spectra of individual compounds can be observed without
interference by other compounds.
In recent years, mass spectrometers of much higher re-
solving power and mass accuracy have become available.
Since the atomic masses of various isotopes are not precise
integers, it is often possible to resolve ion peaks that
have the same nominal unit mass but differ in actual mass
because of different empirical formula. If sufficient
accuracy in mass measurement can be obtained, it is pos-
sible to determine the empirical formula of a given ion, or
at least to limit the empirical formula to a few possibl1-
ities. The ability of high-resolution mass spectrometers
to provide empirical formulas for ions is a great help in
elucidating the structures of pure compounds and is of real
assistance in unraveling the mass spectra of mixtures.
Such instruments are seldom used with chromatographs because
of the relatively slow rate at which spectral scans can be
repeated, compared to the time interval in which a compound
emerges from the column. In addition, the large volume of
data produced in a short period of time becomes awkward,
even with computer assistance. At about the time that work
on aerosols began in this laboratory, Sharkey and co-workers
reported the use of high-resolution mass spectroscopy in the
study of aerosols (6).
The prime objectives in the present work were (1) to examine
the usefulness of high-resolution mass spectroscopy without
prior chemical separations in determining the composition of
the organic portion of atmospheric aerosols and (2) to in-
vestigate the composition of real aerosols samples at var-
ious urban sites. Work was begun in this laboratory in
1970, with support from the Environmental Protection Agency
beginning in July, 1972.
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SECTION II
CONCLUSIONS
1. High-resolution mass spectroscopy without prior separa-
tion of components is a useful, if not ideal, tool for
characterizing the organic fraction of urban aerosols. The
precision of abundance measurements is insufficient to
follow the relatively small variations found at many loca-
tions. Sensitivity factors for many compounds are not
known.
2. High-resolution mass spectra without prior separation
seldom permit unambiguous identification of specific com-
pounds without the use of other data or chemical intuition.
It is usually necessary to use the most intense ions for
identification. Ion fragments useful for confirmation are
often either of very low intensity or are missing altogeth-
er. Separations of species based upon the time/temperature
of evaporation from an ion probe are not very reliable.
Rates of evaporation are subject to matrix effects.
3. High-resolution mass spectra are useful for semi-quan-
titative and exploratory studies and reveal the presence
of a great many organic compounds at detectable levels in
urban aerosols.
4. The distribution of types of organic compounds in urban
aerosols is remarkably uniform for the sites studied; the
principal variation is in total amounts of materials.
5. Many compounds of presumably photochemical origin are
often found in abundance late at night. Stability of many
compounds appears to be sufficient to permit long persist-
ence in the atmosphere.
6. The study of diurnal variations of specific compounds
at a site is seldom informative. Variations are often small
and reflect the past history of the air parcel. Sites in
the Los Angeles area are more likely than other sites to
show useful diurnal variations.
7. It is difficult to distinguish compounds emitted direct-
ly into the atmosphere from those formed by reaction in the
atmosphere by examining diurnal variations. Many different
types of compounds show similar variations and may simply
reflect the ability of the aerosols to adsorb materials from
the gas phase.
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8. The major components of fine particles in urban aerosols
are sulfates and hydrocarbons. Most of the other compounds
regularly found are polar organic compounds of low vapor
pressure and at least fair solubility in water.
9. Compounds usually found in urban aerosols include phenol
and substituted phenols, benzoic acid and isomers of higher
homologs, dicarboxylic acids of five to seven carbon atom
chains, and related difunctional compounds. Some evidence
of the presence of polynuclear aromatic hydrocarbons is
found.
10. The difunctional compounds appear to contain a mixture
of alcohol, carboxy acid, aldehyde, nitrate, and acyl ni-
trate or nitrite functionalities. These, together with
dicarboxylic acids, would be expected to be formed from cy-
clic olefins. The nitrogen-containing difunctional com-
pounds are found in large amounts only where large amounts
of other difunctional compounds and diacids are found. Some
sites contained large amounts of diacids with small amounts
of other difunctional compounds. Products of cyclic olefins
appear to be important contributors to urban aerosols.
11. A series of compounds found by others to be products of
the oxidation of toluene in smog chamber experiments was
present in urban aerosols. These toluene derivatives are
important components of urban aerosols. Lesser evidence for
products of oxidation of terpenes was found.
12. Benzoic acid was found to be a major component in auto-
mobile exhaust. The benzoyl ion formed in the ion source of
the mass spectrometer from benzoic acid (and from other com-
pounds) is an intense peak in mass spectra from automobile
exhausts. Benzoic acid and benzoyl ion may be useful indi-
cators of automotive activity, but it is not known whether
other common sources produce these materials.
13. No evidence of lead or its compounds was found. Lead
compounds may be of insufficient volatility to permit in-
troduction into the spectrometer by evaporation from a
probe at temperatures below 300° C.
14-. Little organic material other than small amounts of
hydrocarbons was detected in large (supermicron) particles.
The use of impactors to remove large particles does not
appear to alter the composition of organic fractions ap-
preciably.
15. The use of high-resolution mass spectra without prior
separations is relatively free from sources of accidental
sample contamination and is less time-consuming than careful
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chemical and chromatographic separations, but is not nearly
as satisfactory for identification of specific compounds and
structures. The study of aerosols by high-resolution mass
spectroscopy for exploratory purposes nicely complements
careful chemical separations of model aerosols.
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SECTION III
RECOMMENDATIONS
1. The study of diurnal variations should be conducted only
at sites providing very favorable conditions such that mate-
rial from the past history of the air parcel is minimal.
Midcontinental sites appear unsuitable. For favorable
sites, strong inversions are needed, with samples taken to
provide at least 2-hour time resolution.
2. Samples from the eastern mountainous areas in the summer
should be studied to determine whether terpene products are
important components of aerosols in these areas.
3. The study of specific sources of organic compounds
should be extended. Automobile exhausts should be examined
with and without aging. Efforts should be made to find
sites with large amounts of aerosols but with the aerosols
dominated heavily by single type sources, coal-burning power
plants, automotive activity, etc. Such source studies
would require fewer samples and produce more useful infor-
mation than diurnal studies at sites having multiple sources
of organics.
4. The use of impactors does not appear worthwhile. Fil-
ters used in high-volume samplers should produce satisfac-
tory samples which can easily be obtained by people involved
in other work.
5. Some simple and rudimentary separation prior to the
introduction of samples into the mass spectrometer would be
useful. If most (but not necessarily all) of the sulfates
and/or hydrocarbons could be removed, the total ion current
from the ion source would be lowered. Since current methods
use only a very small sample, the amounts of sample could be
increased with consequent increase in sensitivity and reli-
ability fcr observation of the more interesting polar organ-
ic compounds.
6. If diurnal variation studies are replaced with fewer,
more specific source studies, the number of samples could be
reduced to make it practical to run samples in multiplicate
to improve precision. Improvements in the automation of
the mass spectrometer-computer system would help.
7. Pure samples of the compounds produced from olefins,
toluene, and terpenes should be prepared, and their mass
spectra and sensitivity factors determined.
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8. The mass spectrometer used in these studies is by now
somewhat obsolete technically. Instruments available in
other laboratories could be expected to provide better re-
solving power and mass accuracy, with somewhat greater sen-
sitivity. Increased sensitivity would probably not be use-
ful without removal of the bulk of the hydrocarbons, how-
ever.
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SECTION IV
CHARACTERISTICS OF MASS SPECTRA FROM
COMPOUNDS IN AEROSOLS
It would seem that it would be extremely difficult to inter-
pret even high-resolution mass spectra of complex mixtures
found in atmospheric aerosols. Although ambiguities cer-
tainly exist, there are factors that make high-resolution
mass spectra without chemical separations useful. The
avoidance of separations minimizes sample handling and the
chance for accidental contamination. Also, much less time
is required.
Some ions are formed from large numbers of compounds.
Some of these ions can, however, be used to estimate the
amounts of classes of compounds present. These ions are
usually fragments of small mass. For example, the presence
of the Ci»H9 ion can be used as a measure of total alkanes,
even if other compounds can form the ion, since hydrocar-
bons are present in great amounts and dominate the mass
spectrum. The abundances of a few ions such as the
tropylium ion (CyH?) and the benzoyl ion (C7H50) are useful
as parameters characteristic of groups of limited numbers
of related compounds.
The identification of specific compounds requires the pro-
duction of ions reasonably specific for a given compound.
Such specific ions are not produced by all compounds of
interest.
Simple alkanes and alkenes fragment greatly with no ions
characteristic of individual compounds or isomers. We have
made no attempt to estimate specific components.
Aromatic hydrocarbons produce useful ions, in many cases.
Ions corresponding to the unfragmented molecule (parent
peak) are usually intense, and these compounds are quite
unsaturated. Other hydrocarbons can form such ions by
multiple fragmentation, but intensities should be low.
Polynuclear aromatic compounds produce intense parent ions
of relatively high molecular weight and great unsaturation.
Many compounds of interest contain atoms other than carbon
and hydrogen, such as nitrogen and oxygen. Many compounds
contain several such atoms. These compounds form ions con-
taining these atoms, and such ions can be separated from
hydrocarbon ions and the empirical formulas determined.
The fragmentation of molecules containing functional groups
is usually simpler than for hydrocarbons.
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For many of the oxygen-containing compounds found in aero-
sols, the parent ion is very intense and is often the most
intense ion in the spectrum. This is true of phenol, sub-
stituted phenols, and aromatic acids. Most nitrogen species
show intense parent ions or an intense ion formed by loss of
a single hydrogen atom from the molecule. In this case, the
ion retains the nitrogen-atom characteristic mass.
Dicarboxylic acids produce ions primarily by the loss of
C02H2 from the molecule. Information is lost in this pro-
cess, since the oxygen content of these compounds is a major
characteristic. The parent ions can be found, however, in
samples containing relatively large amounts of these com-
pounds .
In an examination of a sample, material is evaporated from
the spectrometer probe into the ion source over a period of
time as the temperature of the probe is raised in a pro-
gramed manner. During this time, a series of mass spectra
of the effluent gases is recorded. From these, plots of ion
abundance against temperature-time are made for specific
ions. We call these plots "mass thermograms". Similar pro-
files from different thermograms imply that the ions origi-
nated from compounds evaporated at the same temperature. If
the spectrum of a suspect compound is known from the litera-
ture or can be reasonably deduced from the spectra of relat-
ed compounds, the ions expected to be produced in large
amounts can be determined. The compound can be identified
by the appearance of similar mass thermograms for the ions
expected. Care must be taken to anticipate alternate com-
pounds of similar spectra. Many compounds were originally
identified in this way from studies of samples containing
relatively large amounts of material. For some compounds,
the occurrence of thermograms for several identifying ions
is seen only for samples containing relatively large
amounts. Other samples may be of such low concentration
that only the major ion is seen. It is assumed that the
origin of the major ion remains the same. This is a risky
procedure, but appears to be the best that can be followed.
Details of the computer system for identifying compounds by
similar means in routine analyses are given in Section VI.
The above method or technique of identification is certainly
not completely satisfactory. It is always possible that
ions identified as parent ions could have arisen as frag-
ments of other molecules. It is fortunate that, for the
major organic molecules containing the functional groups
discussed below, the abundances of different compounds are
not widely different. Thus, very weak ions from one com-
pound are not likely to interfere with major ions from an-
other.
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Mass spectra of isomers are often similar. It is nearly
impossible to determine the positions of ring substituents
on aromatic rings. In such cases, only the presence of
total isomers can be reported.
We believe that identification of most of the compounds
found to be present in substantial amounts is correct and
consistent with other data, except for ambiguities noted in
the computer reports and in Section X. The computer-
produced reports should riot be used without careful reading
of Section X, and the recider should be aware that errors
probably exist, particularly for compounds not found in
substantial amounts.
10
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SECTION V
EXPERIMENTAL PROCEDURE
SAMPLE COLLECTION. Except for samples from the Los Angeles
area, samples studied in this work were collected using an
apparatus described by Schuetzle (7,8,9). This apparatus
consists of an impactor designed to collect particles of
larger diameter than 1 or 2 micrometers on small gold
plates. Following the impactor, Gelman Type A glass fiber
filters were used to collect fine particles. The impactor
back-up was always used, whether or not the large particles
were later examined. The glass filters and impactor plates
were cleaned by heating to 550°C. for 21 hours. They were
then stored in glass vials with Teflon lined caps. After
sampling, the filters and impactor plates were returned to
glass vials and cooled to dry-ice temperature. Samples were
maintained at dry-ice temperature during shipment and stor-
age until just before introduction into the mass spectrom-
eter. Filters and impactor plates were handled with tools
which had been flamed to remove organic materials, and
handling was carried out in a clean zone of aluminum foil.
Samples from West Covina, Pomona, and Dominguez Hills were
collected by personnel of the Air and Industrial Hygiene
Laboratory of the State of California Department of Health,
under supervision of Bruce Appel. A two-stage high-volume
sampler, equipped with a cyclone for removal of large par-
ticles, was used. Samples were cut from large Gelman Type
A glass fiber filters and shipped in dry-ice.
Volumes of air taken were calculated from times of sampling
and flow rates determined by rotameters. Rotameters were
calibrated by direct water displacement.
MASS SPECTROSCOPIC MEASUREMENTS. An Associated Electronics
Industries Type MS 9 mass spectrometer, having Nier-Johnson
geometry, was used in this work. The resolving power was
set to 7000 to 10,000. The spectrometer was interfaced to
a Digital Equipment Corporation PDP-12 computer. During
operation, the computer provided the timing for initiation
of spectral scans and recorded the spectral data on magnetic
tape. The same computer was used off-line for subsequent
data processing. As is common in high-resolution mass
spectrometry, perfluorokerosene was admitted to the ion
source during scans to provide ions of known mass to serve
as mass markers. Because of the large number of fluorine
atoms in these ions, they are mass deficient and are seldom
confused with ions from other compounds.
11
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Samples were introduced into the spectrometer using a probe,
shown in Figure 1. Measured portions of glass fiber filters
were punched from the sampling filter as discs of 6-mm diam-
eter. Occasionally, more than one disc was used. The probe
was cooled to room temperature, and the cap removed. The
filter disc was sandwiched between gold plates on the probe
body near the thermocouple. Impactor plates were inserted
on the probe body, with the sampling surface away from the
probe body and covered with a gold plate or gold grid. The
assembly was held by a pressure spring and the probe cap.
The probe could then be inserted through an air lock so that
the glass capillary tip extended into the ion chamber and
terminated near the electron beam. Probes were cleaned be-
fore use by heating to 380° C for 15 to 30 minutes.
Once the probe was inserted, the ion source was brought into
operation. This required about 1 minute. Mass scans were
then begun, coincident with the start of a programmed heat-
ing of the probe. The probe was provided with a cartridge
heater, controlled by a Hewlett-Packard Model 240 tempera-
ture programmer and monitored by use of a thermocouple lo-
cated in the probe near the sample. The probe temperature
was increased from 25° C at a rate of 30° C per minute, un-
til a temperature of 380° C was reached. At this point,
the temperature was held constant for the remaining scan
period. Mass spectra were scanned every 50 seconds, with
36 seconds used for scan and 14 seconds used for magnet
recovery between each scan. The first scan began at the
start of heating. Usually 35 scans were made on a sample,
with a total heating time of about 30 minutes. It was
difficult to determine in advance the volatile materials
.loading of the samples. Since inadequate sensitivities or
detector overloads were produced by improperly set detector
gains, such scans were often repeated in order to obtain
good spectra.
The sensitivity of the mass spectrometer varies with detec-
tor gain and with slit widths used in the ion beam. Ac-
cordingly, some standard compound must be used to monitor
sensitivity. Initially, measured amounts of biphenyl were
added in methanol solution to each filter disc or impactor
to serve as an internal standard for sensitivity. This
proved to be unsatisfactory, with biphenyl occasionally
being lost during sample preparation and insertion.. The
use of o-bromobenzoic acid was substituted. This compound
was not ordinarily added to actual samples. Rather, after
instrument stability had been obtained and operating para-
meters had been fixed, blank filters were treated with
measured amounts of o-bromobenzoic acid in methanol and
these run as calibration samples immediately prior to run-
ning a series of unknowns.
12
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ION SOURCE WALL
GLASS CAPILLARY
SPRING AND GOLD PLATE
SAMPLE ON GOLD PLATE
THERMOCOUPLE WELL
HEATER
SCALE 3X
FIGURE 1, SAMPLE INSERTION PROBE.
13
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At the conclusion of scans for a sample, the data for about
35 mass spectra of the sample compounds, plus the perfluoro-
kerosene markers, had been recorded on magnetic tape for
subsequent processing. Usually 3 or 4 tapes were needed
for a single sample.
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SECTION VI
DATA REDUCTION
Raw spectral data recorded during mass spectrometer opera-
tion must be processed through a number of steps for final
results to be produced. The raw data consist of a series
of ion currents arriving at the detector. Ion current is
sampled by the computer every 80 microseconds over a 36-
second scan. Ion currents are not logged on magnetic tape
unless the current exceeds a threshold value, preset
slightly above the zero ion current base line to remove
noise. A typical beam of ions of a given mass passes
across the detector slit during mass scan to produce a
series of from 10 to 30 ion current measurements, following
a more or less gaussian peak profile. These ion current
measurements are logged, together with the precise time at
which the peak terminated.
The raw data are examined by computer programs, to calcu-
late the heights of peaks and to compute the time of oc-
currence of the peak. The time is taken as the time at
which the center of gravity (centroid) of the peak profile
occurred. These data are logged on the same magnetic tape.
A second computer pass through the data is then conducted.
The computer is provided with a spectrum of the perfluoro-
kerosene used as a marker. The computer requires operator
interaction to identify a few of the perfluorokerosene
peaks in the aerosol spectrum with perfluorokerosene peaks
in the known spectrum. The computer programs then attempt
to identify a series of selected perfluorokerosene peaks in
the aerosol spectrum by comparing the two spectra. Usually
45 to 48 peaks are identiifed. If identifications are not
satisfactory, operator interaction can be used to assist.
Once the perfluorokerosene is identified, these known
masses are used as mass standards. The masses of other
peaks in the aerosol spectrum are calculated by interpola-
tion between known peaks on a time basis. Masses are cal-
culated to 0.0002 atomic-mass units, with errors seldom
exceeding 0.003 atomic-mass units. The calculated masses
and peak intensities are logged on the same magnetic tape
and can be displayed or printed out as desired. Data re-
duction to this point is widely used in this laboratory for
many purposes and is similar to data reduction from comput-
er-controlled high-resolution mass spectrometry used in
many laboratories.
Mass spectra at this point can be examined for quality and
can be used to search for compounds not previously identi-
fied. Previously identified compounds were routinely
15
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detected, and the computer-prepared reports, included as
part of this document, were obtained by the following
process.
The computer is provided with a "mass file" on magnetic
tape. This file is a listing of all precise masses used
to identify all compounds to be reported. The current mass
file contains 388 entries. For each mass in the file, a
search is made of all the 35 mass spectra from a sample for
the presence of ion current peaks having calculated masses
within a specified tolerance of the listed mass. The tol-
erance was usually 0.003 to 0.005 atomic-mass units. If
such peaks are found, a mass thermogram for that mass is
accumulated and stored or, a separate magnetic tape.
The set of observed mass thermograms is printed out and ex-
amined for erroneous mass identifications and, if needed,
corrections made by the operator. Similar mass thermograms
and printouts are used for sensitivity calibration runs on
o-bromobenzoic acid. The thermograms are ion intensities
as functions of time. The average area under the thermo-
grams for the four intense peaks for o-bromobenzoic acid is
divided by the weight of o-bromobenzoic acid used to obtain
instrument sensitivity factors.
A series of "compound files" have been prepared listing
specific compounds or classes of compounds to be reported.
These files are used in binary form on magnetic tape.
Printed versions of the files are included with the data
base in this report. The origins of these files are dis-
cussed in Section VII. For each compound, the name of the
compound is given, together with the parent mass of the
compound if it is not a class of compounds. An identifying
mass is included. The sensitivity of this ion relative to
o-bromobenzoic acid is given. Tl and T2 are time limits
within which the compound is expected to be evaporated from
the probe. Where possible, two confirming masses are pro-
vided, together with the known ratio of their intensities
to that of the identifying mass.
Computer-prepared final reports are compiled in the follow-
ing manner. For each compound in a compound file, the mass
thermograms are examined for entries corresponding to the
identifying mass within the time limits specified. No re-
port is compiled if no such entries are found. If accept-
able identifying masses are found, the expected heights of
confirming masses are computed from the ratios in the com-
pound file. The thermograms are examined, scan by scan,
for the presence of confirning ions of proper intensity. A
tolerance of a factor of two is usually used. It is
16
-------
possible to print out the number of expected intensities
actually found and the number missed, together with the
number of confirming mass entries calculated to be below
detection limits. For large compound abundances, the con-
firming masses are usually found within a factor of two.
We have not printed out the data on confirming masses in
this report because (1) it would increase the volume of
printouts considerably and (2) such confirming masses are
not found for samples of low concentration or suitable
masses cannot be found.
The amounts of compounds reported are calculated from the
areas under the mass thermograms for the identifying masses,
using (1) the sensitivity of the identifying mass, (2) the
volume of air sampled, (3) the aliquot taken for analysis,
and (U) the instrument sensitivity as determined from
o-bromobenzoic acid.
All results in this report are stated in micrograms per
cubic meter of air.
17
-------
SECTION VII
COMPOUND FILES AND
THE BASIS ?OR IDENTIFICATION
Since the bulk of this work is reported by computer-pre-
pared results, the origins of the compound files upon
which the computer results are based are discussed here.
The compounds that appear in the compound files were selec-
ted for various reasons. Many compounds have been included
because evidence of their presence in at least some aero-
sols was found by studying mass spectra obtained from
actual aerosols. Some of these compounds were found in
early work in this laboratory but were not found in the
samples reported here. For example, in an early sample,
taken in Seattle, three ion masses were found in substantial
amounts which could not be accounted for by ions containing
carbon, hydrogen, oxygen and nitrogen. These ions did
correspond to the parent ion and the two major fragments in
the spectrum of arsenious oxide (Asi»0e). Arsenious oxide
was then included in the files.
Many compounds have been included because their presence in
the atmosphere or in common sources had been reported or
suggested. Some compounds were added since they were ob-
viously related to known or suggested pollutants and were
expected to be possible pollutants. Some compounds have
been found in smog chamber experiments by others (10,11).
Some compounds were included simply because they were com-
pounds of interest and could possible be detected. A
series of chlorinated pesticides and biphenyls was included
for this reason.
In some cases, the presence of ions characteristic of a
class of compounds is reported. Some of these are repre-
sentative of large classes of compounds, but may be useful
parameters for characterizing aerosols.
In order to identify compounds by examining mass spectra
and to determine identifying and confirming masses, the
spectrum of the compound must be known and care must be
taken to consider other possible compounds having similar
spectra. Spectra were obtained in this laboratory in some
cases- More often, data were used from the literature.
Several large compendia of spectral data are available (12,
13,14). Beynon, Saunders, and Williams (15) and McLafferty
(16,17) have provided useful general treatments of the
spectra of organic compounds.
18
-------
The selection of identifying masses was based on several
criteria. To begin with, the ion must be of strong inten-
sity and sufficiently removed in mass from likely inter-
fering ions. Also the ion must be as characteristic as
possible of the compound. Smaller fragments and fragments
containing only carbon and hydrogen are generally useless
except as representatives of a few large classes of com-
pounds. Often the unfragmented parent ion satisfies these
conditions. Some compounds were included in the files even
though their spectra were not known, using the parent ion
for identification. Such entries would call attention to
the possible presence of such compounds by the appearance
of the entries in the routine printouts. In a few cases,
compounds of possible interest could not be included
because no suitable ions are formed.
Sensitivity factors and the ratios of intensities of con-
firming masses to identifying masses were calculated from
literature data, or, in some cases, were estimated. For a
few important compounds, the factors have been determined
by preparing synthetic samples from pure compounds. For
ions representing classes of compounds, average values for
the more likely members of the class were used.
Time limits were obtained by examining the thermograms for
synthetic samples or by examining the thermograms from
actual aerosols that contained large amounts of the com-
pounds. For many compounds, the time limits were not known
and were simply set wide enough to include the entire range
of time available.
Names to be reported were chosen to reflect, as well as
possible, the identity of the material, subject to limita-
tions on the number of characters storable in the files.
Questionable identities and likely isomer confusions have
been indicated in most cases. For a number of cases, where
ions could arise from multiple sources, the empirical for-
mulas of the ions have been used. Thus, for some entries,
the name is simply a convenient label for a parameter of
the mass spectra. Individual compounds are discussed in
more detail in Section X. Estimated or arbitrarily assign-
ed sensitivities are indicated by the notation EST or E,
following the name. The letter L indicates use of litera-
ture values, and C indicates a class of compounds. An
arabic number following the compound name indicates the
number of standardization runs on pure compounds on which
sensitivity factors were based.
19
-------
SECTION VIII
ACCURACY OF THE METHOD
An estimate of the reproducibility of the methods used in
this work may be obtained from Table 1. Here are compared
results from two separate analyses of a sample taken at
Washington University on the morning of September 8, 1973.
In the first analysis, data system overloads occurred re-
sulting in the loss of most of the data from these scans.
Since the same sample was used, errors in sampling are not
shown, but we believe these to be minimal compared to other
sources of error. The loss of the scans does not affect
the results for many compounds, since these compounds were
not evaporated from the probe in significant amounts during
the missing times in the other sample. For the compounds
indicated with an asterisk, large amounts of evaporation
from the probe should have occurred during the missing
scans.
Table 1
Comparison pjf Duplicate Analyses
Compound Reported Abundance Relative
Micrograms/Cubic Meter Error
Sulfates 6.2 6.7 7%
NH..N03 1.0* 1.4 29
NH.+ C1 0.24* 0.40 40
Glutaric Acid 0.37 0.37 0
Adipic Acid 0.55 0.86 36
Total Alkanes 0.12 0.14 14
CgHia 0.18 0.24 25
Pentandioic Acid 0.11* 0.40 72
Total Acids 0.13 0.17 24
C^HsNa 0.05* 0.17 70
Phthalates 0.25 0.35 29
C6H602 0.14 0.18 22
The average relative error is 31% for all of the results
and 20% if one ignores the four compounds strongly affected
by the missing runs. Relative errors are generally smaller
for compounds found in larger amounts. Compounds not found
in concentrations as large as 0.1 microgram per cubic meter
are not included in the Table and can be expected to be much
larger, especially as the concentrations approach the limits
20
-------
of detection. The reproducibility of the data is deter-
mined primarily by the magnitudes of ion currents detected.
Reproducibility may be expected to be better for samples
where large volumes of air and large aliquots were used.
Low-sensitivity factors for compounds indicate production
of strong ion currents and improved precision. It is dif-
ficult to provide specific information for all of the re-
sults reported here, but a reasonable estimate is that, for
compounds at concentrations greater than about 0.2 micro-
gram per cubic meter, the precision should usually be about
20%. It is possible that an occasional very erroneous re-
sult could be reported by confusion of a weak mass spectrum
peak with a nearby strong peak for another compound. We
have tried to avoid this error for the compounds of major
interest, discussed in Section X, by careful examination of
the mass thermograms prior to preparation of reports.
The accuracy of the results depends not only upon the repro-
ducibility but also upon the accuracy of the sensitivity
factors assigned. The same sensitivity factors have been
used throughout this report so that comparisons of relative
amounts, from one sample to another and between sample sites,
are valid. For those compounds for which the reports in-
dicate calibrations with pure compounds, the accuracy should
be about the same as the reproducibility. We estimate that
sensitivity factors are within 50% of true value for data
based on the literature. For those compounds having arbi-
trarily determined sensitivities, only relative comparisons
should be made.
Some interlaboratory comparisons of results for sulfates
have been made. Results obtained by Bruce Appel, of the
Air and Industrial Hygiene Laboratory of the State of
California Department of Health are shown in Table 2; these
results are compared with results obtained in this work on
samples provided by him. The average discrepancy is about
12%. Table 3 compares sulfate results with those obtained
Table 2_
Comparison of Sulfate Results - West Covina
This work 26 12 12 26 34 43 69 37 29
Appel 23.6 13.2 15.6 23.7 38.8 42.5 69.5 33.8 22.4
by Paul Roberts of the California Institute of Technology,
using samples taken in this work at Washington University.
The agreement is less satisfactory.
21
-------
Table 3_
Comparison of Sulfate Results - Washington U,
This work 7.7 5.1 15 13 3.6
Roberts 8.2 3.3 16.4 5.5 2.2
22
-------
SECTION IX
AEROSOL SAMPLES STUDIED
The major part of this report consists of computer-prepared
results of the analyses of 88 field samples, together with
a few samples of automotive exhaust. Each sample represents
about 35 mass spectra, with the total data base representing
over 3000 mass spectra.
Samples were taken at times to represent stable air, with
low wind velocities and smoggy conditions. The results
probably do not represent average conditions at the several
sites. We do not have detailed meteorological data on some
of the sites, nor is the author of this report competent to
discuss this subject.
Six sets of samples were obtained in the St. Louis area, in
collaboration with the Regional Air Pollution Study. Sam-
ples were taken on the "intensive study" days to permit
future comparison with other work. The Tyson Valley site
was used to provide a rural site near St. Louis. A smaller
number of samples were taken at three sites in the Denver
area, including a site at the National Center for Atmos-
pheric Research at Boulder. A series of samples were taken
in Seattle during a period of low visibility and smog alert.
In addition to the above samples, samples were supplied by
Bruce Appel, of the Air and Industrial Hygiene Laboratory
of the California Department of Health, from three sites in
the Los Angeles area.
Good time-resolution was obtained only in the 1974 St. Louis
samples and in the Pomona and West Covina sites in the Los
Angeles area. These two latter sites show the most inter-
esting diurnal variations because of high concentrations of
pollutants, good time-resolution and wide variation in
abundances.
Sampling Site Locations:
Washington University 1973 - height, 4 meters at the top of
the EPA trailer on the campus of Washington University
on the soccer field near the intersection of Forsythe
and Big Bend roads.
Washington University 1974 - height, 10 meters on tower at
east end of Francis field on the campus of Washington
University north of Forsythe road.
23
-------
height, 50 meters on top of Holiday Inn hotel
in downtown St. Louis.
~ height, 4 meters on top of EPA trailer in
the industrial area in National City, Illinois.
1973 - height, 6 meters on tower mounted on
truck at Tyson Valley reservation, a wooded area about
35 km southeast of St. Louis.
- height, 2 meters on roof of old radio
,
sack at Tyson Valley.
S_e.d±_tle - height, 12 meters and 2 meters above the top of
More Hall on University of Washington campus about 8
km northeast of downtown area.
Denver - height, 42 meters and 2 meters above roof of
Regency Inn, about 10 km west northwest of downtown
Denver and adjacent to freeway.
Morrtb_eJ_l_o - height, 22 meters and 2 meters above roof of
Montbello State Bank., about 50 km east northeast of
downtown Denver.
NCAR - height, 4 meters on truck-mounted tower at the
National Center for Atmospheric Research site in the
hills near Boulder, Colorado.
Sampling times are shown in Table 4.
Table 4
Wes 1 Coviiia PDT
______ 2 2 ^ 2 Q
TB0195 2:20
TBG198 7:20
TB0199 9:20
TB0200 11:20
TB0201 13:20
TB0202 15:20
TB0203 17:20
TB0204 19:20
Pomona PDT
LAP289 21:10
LAP290 1:20
LAP291 7:20
LAP292 9:10
LAP293 11:10
LAP294 13:10
LAP295 15:10
Sample Times
7/23/73 to
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
8/16/73 to
8/17/73
8/17/73
8/17/73
8/17/73
8/17/73
8/17/73
2
7
9
11
13
15
17
19
22
20
20
20
20
20
20
20
20
20
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
7/24/73
1:20
6:20
9:10
11:10
13:10
15:10
17:10
8/17/73
8/17/73
8/17/73
8/17/73
8/17/73
8/17/73
8/17/73
24
-------
Table 4 (continued)
Pomona PDT
LAP296 17:10
LAP297 19:10
Dominguez Hills PDT
LAD239 22:10
LAD244 11:10
LAD245 13:10
Denver MST
DERI 19:30
DER2 12:10
DER3 8:10
DER4 18:40
Montbello MST
DEMI 9:50
DEM2 20:05
NCAR (Boulder) MST
DEN1 18:00
DEN3 16:40
Washington University
SLW14 17:30
SLW15 0:25
SLW16 7:55
SLW17 12:40
SLW18 16:45
SLW19 23:40
Washington University
SLW62 18:50
SLW63 1:30
SLW64 4:00
SLW65 8:00
SLW66 10:00
SLW67 12:40
SLW68 14:45
SLW69 19:10
SLW70 22:25
SLW71 2:10
Holiday Inn CDT
SLH8 16:00
SLH9 23:10
SLH10 6:50
SLH11 11:45
8/17/73
8/17/73
10/4/73
10/5/73
10/5/73
11/6/73
11/7/73
11/8/73
11/8/73
11/8/73
11/8/73
11/6/73
11/8/73
1973 CDT
975773
9/6/73
9/6/73
9/6/73
9/6/73
9/6/73
1974 CDT
8/19/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/21/74
9/5/73
9/5/73
9/6/73
9/6/73
to
to
to
to
to
to
to
19:10
22:00
22:00
13:10
15:10
12:00
8:00
18:10
8:10
19:50
8:50
16
9
23
7
12
16:
23:
14
19
22
2:
7
40
50
30
15
15
25
05
8:40
1:15
3:45
7:30
9: 50
12:30
:30
:00
15
00
45
23: 00
6:40
11:30
15:45
8/17/73
8/17/73
10/5/73
10/5/73
10/5/73
11/7/73
11/8/73
11/8/73
11/9/73
11/8/73
11/9/73
11/7/73
11/9/73
9/6/73
9/6/73
9/6/73
9/6/73
9/6/73
9/7/73
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/21/74
8/21/74
9/5/73
9/6/73
9/6/73
9/6/73
25
-------
Table 4 (continued)
Holiday Inn CDT
SLH12
SLH13
SLH16
National City
SLN62
SLN63
SLN6U
SLN65
SLN66
SLM67
SLN68
SLN69
SLN70
SLN71
15:50
22:40
10:10
CDT
18:10
0:45
3:15
7 : 05
9:15
12:00
14:00
18:35
21:40
1: 30
9/6/73
9/6/73
9/9/73
8/19/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/21/74
22: 30
8:10
8:15
0:20
3:05
7:00
9:06
11:15
13:40
18:20
21: 30
1:20
7:00
9/6/73
9/7/73
9/11/73
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/20/74
8/21/74
8/21/74
Tyson Valley 1973 CDT
SLT1
SLT2
SLTS
SLTii
SLTS
S^TB
SLT7
SLTS
19:
18:
9:
18:
9:
13:
11:
14:
00
07
11
20
09
45
55
05
9/4/73 to
9/5/73
9/6/73
9/6/73
9/7/73
9/8/73
9/9/73
9/10/73
17:35
8:26
18:10
8:56
13:35
11:45
11:55
16:25
9/5/73
9/6/73
9/6/73
9/7/73
9/8/73
9/9/73
9/10/73
9/11/73
Tvson Vallev 1974 CDT
SJL.TC
3LT6
SLTS
SLT6
SLIT
SLTS
SLT6
o!-T6
QT T"^
SLT7
OLT?
2
3
4
5
5
o
•s
q
0
j_
M
c
18:
0:
3:
7:
9:
11:
13:
15:
18:
21:
0:
00
00
00
00
00
00
00
00
00
00
00
8/19/74 to 24
8/
8/
8/
8/
8/
20/74
20/74
20/74
20/74
20/74
8/20/74
8/
8/
8/
8/
20/74
20/74
20/74
21/74
3
7
9
11
13
15
18
21
24
7
:00
:00
:00
:00
:00
:00
:00
:00
: 00
:00
:00
8/19/
8/
8/
8/
8/
8/
8/
8/
8/
8/
8/
20/
20/
74
74
74
20/74
20/
20/
20/
20/
20/
20/
21/
74
74
74
74
74
74
74
Seattle PD'T
StU3
SEU4
SEU5
SEU6
SEU7
3EU8
SEU9
8:25
11:40
16:40
22:10
9:20
16:20
23:10
10/17/74
10/17/74
10/17/74
10/17/74
10/18/74
10/18/74
ID/18/74
to 11
16
22
9
16
23
12
35
30
00
10
10
00
50
10/17/74
10/17/74
10/17/74
10/18/74
10/18/74
10/18/74
10/19/74
26
-------
Three aerosol samples, taken directly at the tail pipe of
automobiles, were analysed. Sample SEA 2 was taken from a
1973 Land Rover, equipped with a 2.3-liter, 4-cylinder en-
gine, operating at idle. SEA 6 and SEA 7 were obtained
from a 1975 Mercury Montego, equipped with a 5.6-liter
engine. SEA 6 was obtained at idle, and SEA 7 was obtained
with the engine at high speed but without load. The Rover
did not have a catalyst in the exhaust system, but the
Mercury did.
27
-------
SECTION X
DISCUSSION OF RESULTS
LARGE PARTICLES.
We found that very little organic material of interest is
found in particles collected on impactor plates. Mueller
and co-workers found that most of the organic materials
were present in the small particles (accumulation mode) in
Pasadena, California (18). Although a number of impactor
samples have been taken in this work, we have not regularly
prepared computer reports on such samples and have largely
discontinued collection of such samples.
An example of a typical composition found on impactor
plates is included in the reports for a sample taken at
Washington University in 1974. Very little material is
seen. Small amounts of sulfates, ammonium chloride, and
ammonium nitrate are found, together with traces of hydro-
carbons .
CLASSIFICATION OF COMPOUNDS.
Chemical species found in aerosols may be classified on
several bases. Compounds can be classified as primary or
secondary, depending on the mode of entry into the atmos-
phere. We use here the idea that primary compounds are
those emitted into the atmosphere initially as that spe-
cific chemical species. Secondary compounds are species
formed in the atmosphere by chemical reactions. Such
reactions may occur in the gas phase or on particulate
surfaces. It is difficult to determine the physical state
of primary compounds as they were emitted, since they are
collected on aerosols. Similarly, the physical state of
secondary compounds, at formation, cannot be deduced from
the experiments described in this work.
It would be desirable to classify compounds on the basis of
the original sources of primary compounds and precursors of
secondary compounds. Sources of emissions can only be
guessed from studies of atmospheres in complex urban areas.
Many compounds appear to be stable in the atmosphere.
These can travel long distances, and emissions from vari-
ous sources become hopelessly intermingled. Studies of
specific sources would be desirable.
In the following discussion, compounds will be classified
mainly on the basis of the chemical functionalities in-
volved, since this is the major sort of information
28
-------
provided by the analyses reported here.
DIURNAL VARIATIONS.
Variation in the abundance of compounds over a daily period
is interesting for the deduction of sources of emissions
and for the detection of evidence of photochemical forma-
tion. Some rather strict conditions must be met. A low
mixing height and stable air mass are needed so that suf-
ficient concentrations are built up to permit reasonable
accuracy in measurement. The air mass must be clean in-
itially and must not be burdened with materials from its
past history. At the same time, a means of slow but defin-
ite removal of components is needed. Otherwise, stable
compounds will simply accumulate over long periods of
time. These conditions do not appear to be met in most of
the observations reported here. The most informative sam-
ples are those taken at West Covina, California.
If a chemical species in the atmosphere in the gas phase is
strongly adsorbed upon, or dissolves in, the surface of
aerosol particles, the aerosol becomes an effective means
for extracting materials from the gas phase. If the ex-
traction is essentially complete, the materials in the
aerosol represent the actual amounts of materials in the
air mass. If extraction is only partial, however, the
amounts of compounds found in aerosols depend on both (1)
the amounts of compounds present and (2) the amount of
extracting surface and its effectiveness. Thus, diurnal
variations could reflect changes in the amounts of total
aerosol, superposed upon changes resulting from primary
emissions and secondary formation.
HYDROCARBONS.
Mass spectrometry is not a satisfactory way to analyse com-
plex mixtures of hydrocarbons without extensive prior sepa-
rations. Hydrocarbons fragment extensively, with a given
fragment ion often arising from fragmentation of a large
number of compounds. It is, therefore, probable that many
compounds contribute to many of the individual results re-
ported here. In many cases, a result reflects largely a
class of compounds; the name used in the report is often
simply a convenient name for a fragment, not necessarily a
correct specification of the precise compound.
The situation is somewhat better for aromatic, and particu-
larly polynuclear aromatic compounds. These compounds
produce abundant parent (unfragmented) ions, which are used
29
-------
for identification. In addition, the high degree of unsat-
uration makes it unlikely that ions of the same empirical
formula would be extensively produced by fragmentation of
much more saturated compounds. There is, however, a possi-
bility that such unsaturated ions could be produced in
small amounts from fragmentation of large amounts of other
compounds. Unfortunately, the amounts of aromatics are
generally small, relative to alkanes and alkenes.
Alkanes and Alkenes. We have attempted to determine the
amounts of these classes of compounds in a rather arbitrary
manner. The abundance of the CsHii ion is used for report-
ing TOTAL ALKANES. The abundance of the C6Hi3 ion, togeth-
er with separation based on the temperature of the probe,
is used in an attempt to get a rough division of alkanes
into ALKANES LOW MW (molecular weight), ALKANES MED. MW,
and ALKANES HI MW. Similarly, the C5H9 unsaturated ion is
used for TOTAL ALKENES, and the C6Hii ion for the various
fractions of ALKENES. These ions can be formed from a wide
variety of compounds, including compounds that are not
hydrocarbons. The alkene fragments can be formed from al-
kanes. The sensitivity factors vary widely from one com-
pound to another. These ions are found in all spectra in
great abundance and can, therefore, be measured with fairly
good precision. Since hydrocarbons appear to be present in
very large amounts relative to other organics, it is r>rob-
able that non-hydrocarbons do not contribute much to the to-
tals. Thus, we believe that, despite the many interfer-
ences, these ions serve as useful, if arbitrary, measures
for comparison of general hydrocarbon levels in the samples.
Pinene and Terpenes. The CgHi3 ion abundance is reported
as ALPHA PINENE, and the CyHg ion abundance is reported as
TERPENES AS ALPHA PINENE. These two ions are the major
fragments formed from many, but not all terpenes. Unfor-
tunately, terpenes fragment badly, and the two ions are not
peculiar to terpenes. The ratios of terpenes reported to
alkanes and alkenes are about the same for all samples
studied, and we must conclude that we cannot distinguish
terpenes from the large amounts of other hydrocarbons pre-
sent .
Aromatic Hydrocarbons. A number of alkyl-substituted aro-
maticcompounds are reported based upon the abundances of
the parent ions. Such compounds produce strong parent ions,
The entry XYLENES, MON SUB BENZENES is based on the abun-
dance of the CyH? (tropylium) ion. This ion is produced in
large amounts in the fragmentation of many substituted ben-
zenes, including xylenes, and many monosubstituted alkyl
benzenes. The most abundant compounds seen are usually the
tropylium ion and the CgHi2 ion.
30
-------
The compound files include the parent mass for biphenyl.
This is, therefore, reported where it occurs. The entries
after BIPHENYL are to be_ ignored, however, since biphenyl
was often added to the samples as an internal standard in
earlier samples.
Polynuclear Aromatic Compounds. The parent ions are used
as measures of the amounts of a series of polynuclear aro-
matic compounds. These compounds form abundant parent ions
of high unsaturation and represent better cases for identi-
fication than other hydrocarbons. They are observed only
in trace amounts in most samples, with large relative er-
rors in concentrations.
Hydrocarbon composition of_ Aerosols. The amounts of hydro-
carbons were found to vary markedly between sampling sta-
tions and, often, with time, at a single station. The ra-
tios of amounts found to total alkanes and alkenes for the
various types of hydrocarbons are, however, quite uniform
over the data base. We have been unable to find signifi-
cant variations in the distribution of hydrocarbons into
the various types. Either the interferences between types
are sufficiently severe to hide varying compositions, or
the aerosols contain essentially the same distributions of
compounds. Average values for hydrocarbon types at various
stations are given in Table 5.
Table 5.
Average Amounts of Hydrocarbons
Site
Pomona
West Covina
Dominguez
Seattle
Denver
Montbello
Wash. U, 73
Wash. U. 74
Holiday
Nat'l City
Tyson 73
Tyson 74
NCAR
Alkanes
plus
Alkenes
1.74
5.24
1.8
3.0
5.3
1.3
3.1
0.81
2.1
0.86
0.34
0.79
0.84
Alpha
Pinene
0.67
2.7
0. 50
1.5
2.0
0.37
1.7
0.33
1.1
0.45
0.14
0.29
0.41
Xylene,
Mon Sub
Benzene
0.34
1.2
0.24
0.48
0.50
0.16
0.49
0.15
0.48
0.15
0.10
0.21
0.12
0.93
3.7
0.82
2.4
3.4
0.70
2.4
0.49
1.6
0.49
0.21
0.60
0.58
Naphthalene
0.028
0.21
0.021
0.063
0.057
0.016
0.15
0.014
0.14
0.066
0.026
0.006
0.015
31
-------
Most hydrocarbons would be expected to be primary compounds
in aerosols and would have great stability, permitting long
persistence in the atmosphere. The amounts found would be
expected to represent past history of the air parcel super-
posed upon the local emissions. Diurnal variations of al-
kanes and alkenes are shown in Figs. 2, 3, and 4. As would
be expected, there is no evidence of photochemical effects
on the amounts of hydrocarbons. There is only a little ev-
idence of the influence of automotive activity on hydrocar-
bon abundances. There is a morning and an afternoon peak
in the data for West Covina, where the largest amounts of
hydrocarbons were found. In general, however, the diurnal
variations were erratic, with large amounts of hydrocarbons
often found late at night. The Seattle samples show a some-
what erratic general increase over a 2-day period.
The amounts of aromatic hydrocarbons found are smaller than
the amounts of aliphatic compounds and appear to vary in a
manner similar to aliphatic compounds, except that, at West
Covina, there appear to be differences, with the morning
peak not found. Data for aromatic compounds for West
Covina are shown in Fig. 3.
The amounts of polynuclear aromatic compounds reported are
quite small, with large relative errors. The presence of
pyrene and chrysene is barely detectable, although these two
were detected in all of the West Covina and Washington Uni-
versity 1973 samples and in most of the 1973 Holiday Inn
samples. The apparent presence of these compounds is worri-
some, but it is possible that fragments of other hydrocar-
bons are responsible for the observations. Better evidence
should be sought.
We had expected to find evidence of hydrocarbon composi-
tions in the coal-burning areas that are different from
those in areas where little coal is burned. This is not
the case. It appears that little can be learned from the
hydrocarbon data reported here, except that the composition
of the hydrocarbon fraction seems to be quite uniform at
the various stations.
AROMATIC OXYGENATED COMPOUNDS.
The mass spectra were searched for a number of aromatic ox-
ygen-containing compounds. The identifying mass for each
is the parent ion, except for the entry PHENOL+N02,CHO,C02H.
This entry is based on the abundance of the CeHsO ion. A
wide variety of substituted phenols can contribute to this
ion abundance. Generally, phenol and alkyl phenols form
little of this ion, but phenols with ring-substituted
32
-------
Pomona
Washington U. 1973
1
till
I
ashington
u. :
L97U
•
Holiday Inn
National
City
1
1
1
••
I I I I I
1800 2400 600 1200 1800 2400
Vertical tics indicate 1 microgram per cubic meter.
FIGURE 2. DIURNAL VARIATIONS OF ALKENES (Above)
AND ALKANES (Below).
33
-------
Alkenes
Alkanes
I
V«T T ^
Xyle
ne , Mo
n Sub Benzc
r
i
jnes
Alky
1 Benz
enes Ce
*»
I
Total Phenols
1800 2400 600 1200 1800 2400
Vertical tics indicate 2 micrograms per cubic meter,
FIGURE 3. DIURNAL VARIATIONS AT WEST COVINA
HYDROCARBONS AND PHENOLS.
-------
Alkenes
Alkanes
Benzoyl Ion
Hexandioic Acid
Pentandioic Acid
1200 2400 1200 2400
Vertical tics indicate 1 microgram per cubic meter.
FIGURE 4. DIURNAL VARIATIONS AT SEATTLE.
35
-------
functional groups often form substantial amounts of this
ion. We do not know specifically what compound or com-
pounds are responsible for the occurrence of this ion in
the spectra. The ion is, however, the most abundant ion
found in this class of compounds.
Phenols can arise by primary emission. Some phenols were
detected in one of the automotive exhaust samples run as
part of this project. Phenols could arise also as second-
ary compounds, formed by oxidation of alkyl benzenes in the
atmosphere.
The amounts of phenolic compounds were generally small,
with the largest amounts found in the West Covina samples.
With the exception of the West Covina samples, diurnal
variations of phenols did not show definite patterns.
There are always larger relative errors in compounds of low
concentrations. There was some tendency for the diurnal
variations to follow hydrocarbons, but this is not definite.
The variation of total phenols with time at West Covina is
shown in Fig. 3. The definite afternoon peak suggests that
photochemical formation of phenols as secondary compounds
is possible, but this is inconsistent with the data below.
Average values for various phenolics are given in Table 6.
Table 6.
Average Amounts of Phenolic Compounds
Site
Pomona
West Covina
Dominguez
Seattle
Denver
Montbello
Wash. U. 73
Wash. U. 74
Holiday
Nat'l City
Tyson 73
Tyson 74
NCAR
Phenol
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
053
21
028
044
020
006
086
024
084
023
015
018
Oil
Phenol+
NO 2
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
,CHO
17
65
23
22
040
015
63
012
23
049
03C
058
028
Trimethyl
Phenol
0
0
0
0
0
0
0
0
0
0
0
0
0
. 050
.27
.014
.012
.025
.021
.12
.060
.094
.042
.012
.093
.007
Cresols
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
033
16
Oil
024
014
020
065
021
048
012
010
028
_
Dihydroxy
Benzenes
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
031
33
07
128
042
046
11
049
087
020
023
046
014
35
-------
Some data showing the remarkable uniformity of the distribu-
tion of various compounds in the organic part of aerosols
are given in Table 7. The average ratio of phenol and other
Table 7.
Ratio to Total
Alkanes+Alkenes
Site
Phenol Other
Pomona
West Covina
Dominguez
Seattle
0.031
0.038
0.016
0.015
Denver
Montbello
Wash. U. 73
Wash. U. 74
Holiday
Nat'l City
Tyson 73
Tyson 74
NCAR
0.004
0.005
0.028
0.030
0.040
0.027
0.044
0.023
0.013
Phenolic
0.16
0.27
0.18
0.13
0.08
0.08
Per Cent of Total Phenols
Phenol Cresols Phenol+
N02,CHO
0
0
30
18
0.22
0.14
16%
12%
10%
9%
16%
10%
10%
6%
6%
9%
50%
40%
51%
62%
43%
0
0
22
28
0.06
phenolics to total alkanes and alkenes does not vary by more
than a factor of 2 or 3 for most of the stations studied.
It does appear that there were somewhat smaller amounts of
phenols in the Denver area stations (Denver, Montbello,
NCAR), compared to hydrocarbons. Table 7 also shows rela-
tive distributions of three kinds of phenols for those sites
where larger amounts of phenols were found. Again, the
uniformity in the distribution among the phenols is striking,
If phenols were produced by photochemical activity at West
Covina, one would expect to see larger amounts of phenols,
compared to hydrocarbons. This is not, however, the case.
Two important interferences should be noted. The entry BEN-
ZALDEHYDE is based upon the parent peak of the compound.
Benzoic acid and other compounds produce ions resembling the
spectrum for benzaldehyde. Benzaldehyde might be expected
to be formed, but it is readily oxidized to benzoic acid.
The identification of this entry is probably incorrect, but
large amounts of benzaldehyde were found in one sample of
automotive exhaust. The other samples of automotive exhaust
did not show benzaldehyde, despite the detection of large
37
-------
amounts of benzole acid. There is a second source of pos-
sible misidentification in that the mass spectra from
cresols are very similar to the spectrum from benzyl alco-
hol. We cannot distinguish between these two possibili-
ties.
AROMATIC CARBOXYLIC COMPOUNDS.
The compound files enable a search for members of an inter-
esting class of compounds related to benzoic acid. These
are identified in the reports as BENZOIC ACID, METHYL BEN-
ZOIC, ETHYL BENZOIC, and TRIMETHYL BENZOIC, together with
an arbitrary measure of the abundance of the BENZOYL ION in
the mass spectra. The identification of the substituted
benzoic acids is uncertain, since mass spectra of reason-
able isomers are similar. These compounds were not found
in large amounts, and the minor fragments needed to estab-
lish firm identification are weak or missing. It is diffi-
cult to distinguish between methyl benzoic acids, phenyl
acetic acid, and methyl benzoate. Similar problems exist
for the other substituted benzoic acids. The benzoyl ion
is formed in abundance from a variety of compounds, includ-
ing benzoic acid, benzaldehyde, phenyl ketones, and ben-
zoate esters.
These kinds of compounds appear to be possible secondary
compounds formed in the atmosphere by the oxidation of
alkyl aromatic compounds. Wilson, Schwartz and Kinzer (10)
found benzoic acid in auto exhaust particulates. In the
three samples of auto exhaust reported here, benzoic acid
and benzoyl ion are among The few compounds found in sub-
stantial amounts, other than hydrocarbons and sulfates.
The amounts are shown in Table 8. It is attractive to ex-
amine these compounds as measures of automotive activity,
as suggested by Wilson et al.
Table 8_.
Automotive Exhaust Samples
iri micro grams per cubic meter
SEA 2_ SEA 6_ SEA 7_
Benzoyl ion 1700 160 210
Benzoic Acid 260 66 94
Ratio 6.54 2.42 2.23
The sensitivity factor for benzoic acid has been reported
in the literature and verified in our laboratory by running
standards. We have established an arbitrary sensitivity
-------
for the benzoyl ion, since this would depend upon the spec-
ific compound forming this ion. Benzoic acid itself pro-
duces 1.3 times as much berizoyl ion as parent ion used to
measure benzoic acid. Since the aribtrary sensitivity fac-
tor for benzoyl ion is 0.5 that for benzoic acid, the re-
ports should show 2.6 times as much benzoyl ion as benzoic
acid, if all benzoyl ion originates from benzoic acid. For
the second two samples of auto exhaust measured here, the
ratio of benzoyl to benzoic acid is close to that expected
for the presence of benzoic acid alone. The first sample
apparently contains other benzoyl-producing species. We
have found no evidence of other substituted benzoics in
auto exhaust. Large amounts of benzaldehyde were reported
for the first sample, however. This would provide addition-
al benzoyl ion. A more detailed search for benzoyl-pro-
ducing compounds should be conducted in auto exhausts.
The compound files used for preparing computer reports were
based on studies of atmospheric aerosols, and these were
simply used by the computer in preparing the reports on
auto exhausts.
Wilson et al.,found phenyl acetic acid in auto exhaust
along with benzoic acid. We did not find this compound in
auto exhaust. (It would be reported as methyl benzoic
acid.) We do, however, find methyl benzoic acid (possibly
phenyl acetic) and higher homologs in urban aerosols along
with benzoic acid and benzoyl ion. Average amounts of
these compounds found are given in Table 9. The results
Site
Table 9_.
Benzoic Methyl Ethyl Trimethyl Benzoyl
Ion
West Covina
Seattle
Denver
Montbello
Wash. U. 73
Wash. U. 74
Holiday
Tyson 73
Tyson 74
NCAR
0.14
0.17
0.04
0.06
0.12
0.02
0.06
0.006
0.07
0.02
Benzoic
0.
0.
0.
0.
0.
0.
0.
17
06
03
0
05
01
04
003
0
0
Benzoic
0
0
0
0
0
0
0
0
.0
.1
0
8
2
.01
.0
.0
.0
.0
.0
0
5
1
2
0
0
3
5
Benzoic
0
0
0
0
0
0
.07
.02
0
0
.03
0
.02
.001
.00
0
05
1
0
0
0
0
0
0
0
0
01
83
27
25
60
,13
29
04
20
0.12
for Pomona, Dominguez, and National City must be ignored.
Unfortunately, bromobenzoic acid, used as a standard for
measurement of spectrometer sensitivity, was added to some
samples, and the standard added to these was later found to
have been contaminated with fr^e benzoic acid.
-------
Table 10_.
Abundance Ratios (Average)
Site
Total Benzoics
to Alkanes +
Alkenes
0.09
0.12
0.01
0.05
0.08
0.05
0.07
0.10
Benzoyl Ion
to Total
Benzoics
2.2
2.2
3.9
3.6
2.4
3.2
2.1
2.6
Benzoyl Ion
to Benzoic
7.2
4.9
6.8
4.2
5.0
6.5
4.8
2.9
West Covina
Seattle
Denver
Montbello
Wash. U. 73
Wash. U. 74
Holiday
Tyson
In Table 10 are given ratios of benzoic acids to the sums
of alkanes and alkenes, and the ratio of the benzoyl ion to
benzoic acid alone and to the sums of all benzoic acids.
Sites showing little material have been omitted. Total
benzoic acids do not correlate well with hydrocarbons.
This would be expected if benzoic acids represented auto-
motive activity, but hydrocarbons arise from other sources
as well. It is interesting that the highest value occurred
at Seattle, a city where little coal is burned.
Some suggestion as to the identity of the reported substi-
tuted benzoic acids may be seen in Table 10. If the com-
pounds are really ring substituted benzoics, they would not
contribute much to benzoyl ion. Similarly, phenyl acetic
acid and higher homologs would not contribute much. The
ratio of the benzoyl ion to benzoic acid is always too high
to account for benzoyl from benzoic acid alone. Benzoate
esters do contribute large amounts of benzoyl ion. If one
assumes that the compounds reported as substituted benzoic
acids are, in reality, benzoate esters, then all should
contribute about equally to benzoyl ion. In this case, the
ratio of the benzoyl ion to all benzoates should be about
2.6. This is close to the values calculated in the table,
particularly if one ignores sites with little material.
Thus it is tempting to believe that the compounds reported
are benzoic acid and its esiters.
None of the substituted benzoiu acids (or esters) were
found in auto exhausts. It is possible that these are not
emitted directly in auto exhaust, but are formed later.
The auto exhausts reported hern were sampled by placing a
filter directly adjacent tc the tail pipe, with the filter
plane perpendicular to the fl>~,w of gases and at the edge of
40
-------
the stream. Samples were cooled after collection in dry
ice. It is possible that ester formation could have occur-
red had the samples been permitted to age.
Diurnal variations for the benzoyl ion are shown in Figs. U
and 5. The individual compounds are not present in large
amounts, and there is large relative error in the observa-
tions. The benzoyl ion is, however, produced in larger
amounts. The largest amounts are found at West Covina,
where a morning and afternoon peak is found. The correla-
tion with hydrocarbons is only fair. At the other stations,
the diurnal variations show no correlation with peak rush-
hour traffic, and do not correlate well with hydrocarbons,
except for Holiday Inn. In the data taken in the morning
at Seattle, there is, for both benzoic acid and benzoyl
ion, a single high value which does not show in the hydro-
carbons. Even though auto exhaust does contain large
amounts of these materials, there is no evidence of their
relation to automotive activity, except, possibly, at West
Covina. Again, the data probably represent a lot of past
history of the air parcel.
DICARBOXYLIC ACIDS
The presence of diacids having carboxylic functions on each
end of a saturated carbon chain has been interpreted as a
secondary formation of such compounds by reaction of ozone
with cyclic olefins. The mass spectrometric behavior of
these compounds is peculiar. The major ion seen results
from loss of C02H2 from the molecule. The parent (unfrag-
mented) ions are quite weak. This results in the use of
the fragment for estimation of abundances. This fragment
contains only two oxygen atoms and can be formed from other
compounds, such as unsaturated simple carboxy acids and di-
aldehydes. The abundances of these compounds based upon
the loss of C02H2 are reported as PENTANDIOIC, HEXANDIOIC,
and METHYL HEXANDIOIC ACIDS. As a check on identification,
we included estimates of the amounts of these compounds by
parent ion under the names GLUTARIC, ADIPIC, and METHYL
ADIPIC in the secondary difunctionals. The sensitivity of
the parent ions is very poor, and, often, they do not show
at all. We do find that, for samples containing large
amounts of the compounds (e.g., at Pomona), roughly equiva-
lent amounts of material were found by parent ion for most
cases. Thus, we believe that we know the proper empirical
formulas for these compounds. There is still the possibil-
ity that other isomers are involved. The identification of
the species seen is based upon chemical reasonableness.
-------
West Covina
Washington U, 1973
Washington U, 1974
Holiday Inn
[
— .
1800 2400 600 1200 1800 2400
Vertical tics indicate 0.5 microgram per cubic meter,
FIGURE 5. DIURNAL VARIATIONS IN BENZOYL ION.
42
-------
For example, the seven-carbon compound is believed to be
a methyl-substituted hexandioic acid, rather than a
straight chain compound, because methyl cyclohexene would
be expected to be much more likely as a precursor than
cycloheptene. We would caution against using the data from
parent ions except as an indication of identification.
Although these compounds were found in substantial amounts
at all stations, the amounts vary from site to site and
also vary with time, at a given site, in a very erratic
manner. Very large amounts were found at West Covina,
Seattle, and, surprisingly, at Tyson in 1974. Somewhat
smaller amounts appear in the Washington University sam-
ples. Low amounts were found in the Denver area, Pomona,
and Tyson in 1973. We do not understand the erratic occur-
ance of these compounds. Hexandioic acid does not follow
pentandioic acid very well.
The only evidence of photochemical formation of these com-
pounds lies in the West Covina data, where a strong maximum
occurred in the late afternoon and corresponded to the
maximum ozone concentration (19). At other stations, large
amounts were often found late at night. We do not have
ozone data for these stations; it would be interesting to
see if correlations exist.
At the moment, we can only conclude that these compounds
are found at all sites in large amounts and that they are
subject to rapid fluctuations for unknown reasons. Average
amounts are given in Table 11, with a plot of diurnal vari-
ation at West Covina given in Fig. 6 and, for Seattle, in
Fig. 4.
ACIDS (AS ACETIC ACID).
This entry is an arbitrary measure of the abundance of the
CH3C02H ion only. This ion is found in large amounts and
can arise from a number of compounds, including many acids.
Since we have found it to be of little use, we will not
discuss the matter here.
NITROGEN COMPOUNDS.
Identification of nitrogen-containing fragments is often
difficult. The mass of a CHa portion of a molecule is
14.0156 a.m.u., which is very rlose to the mass of a nitro-
gen atom at 14.0031 a.m.u. It is easy to confuse nitrogen-
containing species with hydrocarbon fragments, particularly
at high molecular weights. The compound files contain a
43
-------
Pentandioic Acid
I h
Hexandioic Acid
CONH Fragment
1800 2400 600 1200 1800 2400
Vertical tics indicate 5 micro-grams per cubic meter,
FIGURE 6. DIURNAL VARIATIONS AT WEST COVINA,
44
-------
Site
Pomona
West Covina
Dominguez
Seattle
Denver
Montbello
Wash. U. 73
Wash. U. 74
Holiday
Nat'l City
Table 11.
Average Abundances of Diacids
Pentandioic Hexandioic Methyl Hexandioic
Tyson
Tyson
NCAR
73
74
Acid
0.45
2.70
1.0
1.8
0.50
0.08
0.90
0.91
0.92
0.37
0.20
1.74
0.27
Acid
0.95
5.00
1.6
2.25
1.30
0.21
Acid
57
70
92
1
0
1
0,
0,
1
09
89
25
31
23
51
0.10
0.94
0.40
0.21
0.73
0.47
0.52
0.11
0.08
0.14
0
number of nitrogen-containing species of fairly unusual
molecular weights, but these are not seen in sufficient
abundance to permit meaningful conclusions. Pyridine com-
pounds were inserted into the compound files for attempts
(unsuccessful) to trap sulfuric acid with pyridine vapor.
In the compound files, we have included a few small nitro-
gen-containing fragments, which, because of the low molecu-
lar weights, can be measured with greater freedom from con-
fusion with hydrocarbon fragments. Of these, the most
abundant at most sites is the CONH fragment. This fragment
was found in two of the three auto exhaust samples studied
here. This fragment could be formed from a great many com-
pounds, but is, we expect, most commonly formed from amides,
The largest amounts were found at West Covina. A plot of
the diurnal variation in CONH at West Covina is shown in
Fig. 6. This appears to be a simple buildup of material,
with a clear and smooth maximum in the afternoon as would
be expected from photochemical formation. Diurnal varia-
tions at other stations appear.1 to be random. A huge amount
of CONH was found in a single sample at Washington Univer-
sity, 1974, taken in the evening. It appears that this
fragment can arise from primary automotive emissions and
also by photochemical reactions; it possibly arose from a
specific and unknown source a I Washington University in
1974, and, possibly, elsewhere. We conclude that the CONH
45
-------
peak and others of simple structure can arise from so many
possible mechanisms that little use can be made of them.
SECONDARY DIFUNCTIONAL COMPOUNDS.
In addition to the dibasic carboxylic acids discussed above,
oxidation of cyclic olefins would be expected to produce
compounds of intermediate oxidation and, in the presence of
nitrogen oxides, nitrogen-containing derivatives.
Oxygen-Containing Secondary Compounds. We have included in
the compound files entries corresponding to the parent ions
of a series of partially oxidized cyclic olefins. Some of
these compounds, together with nitrogen-containing species,
have been identified in smog chamber reaction by Wilson et
al. (10). These authors provide mass spectra of methylated
derivatives. We have not prepared any of the methyl deriv-
atives or the free compounds and have been unable to locate
spectral data in the literature. The compounds have all
been assigned the same arbitrary sensitivity factors. The
parent ions expected for the various types of compounds
are:
Alcohol-Aldehyde C7H1U02 C6H1202 C5H1002
Alcohol-Acid C7H1403 C6H1203 C5H1003
Aldehyde-Acid C7H12C3 C6H1003 C5H803*
Aldehyde-Aldehyde C7H1202 C6H1002** C5H802**
AThis mass is included among the products of toluene
and is not listed under secondary difunctionals.
**These masses are attributed to dicarboxylic acids and
appear under carboxylic acids.
There is undoubtedly some "crosstalk" between, or among,
these entries. Aldehyde parents can be formed in small
amounts from acids. The chain lengths are such as to make
fragmentation by forming cyclic intermediates possible.
Aldehydes are easily oxidized, and the possibility of
chemical changes occurring during sampling and during ship-
ment and storage is very real. The significance of a
single compound is low. The important observation is that
large amounts of one compound at a site are usually accom-
panied by large amounts of "nost, or all, of the others.
Thus, the group taken together may represent a significant
characterization of the aerosol.
46
-------
The reports include under possible secondary difunctional
compounds the parent masses for the dicarboxylic acids
METHYL ADIPIC, ADIPIC, GLUTARIC, and SUCCINIC. The first
three of these are discussed above. These are not included
in the totals for difunctionals discussed below.
The ion CsHsOs is often seen in mass spectra in general and
is formed in large amounts from phthalates. It is often
attributed to phthalate contamination. We find the ion in
all samples, including large particle fractions collected
on impactor plates. We believe it to be an experimental
artifact resulting from phthalate contamination. The ion
is not found in significant amounts on blank samples. We
have been unable to trace the source. The samples make
contact with no plastics during collection and analysis.
This ion is not included in the totals for difunctionals
discussed below. Table 12 lists average abundances for
Table 1_2.
Average Total Abundances
Site
Pomona
West Covina
Dominguez
Seattle
Denver
Montbello
Wash. U. 73
Wash. U. 7i4
Holiday
Nat'l City
Tyson 73
Tyson 74
NCAR
Oxygen
Nitrogen
T- > ,- h*i-—r-
Toluene Terpene
Difunctional Difunctional Products Products
0.26
3.0
0.03
0.24
0.67
0.23
1.2
0.38
1.3
0.09
0.21
0.10
0.08
0.08
1.7
0
0.55
0.34
0.16
0
0
0.
0
0
0
0
,50
,13
,45
,07
,05
,11
,04
0.96
6.6
1.2
2.6
0.64
0.69
2.1
0.85
1.8
0.37
0.32
0.80
0.03
0.06
0.94
0.03
0.07
0.07
0.04
0.26
0.03
0.27
0.05
0.01
0.03
0
total oxygen difunctional compounds (less diacids and
phthalates), together with average total nitrogen difun-
tionals, toluene products, and terpene products.
The stations showing very high abundances of difunctionals
(West Covina, Washington University 1973, and Holiday) also
show high abundances of diacids. Large amounts of diacids
47
-------
were found also at Seattle and at Tyson 1974, but these
show relatively little of the difunctional compounds. It
may be that the difunctional compounds represent intermedi-
ate stages in the oxidation of cyclic olefins, and, at
Seattle and Tyson 1974, sufficient oxidants exist to take
the olefins rapidly to the fully oxidized diacid compounds.
Washington University shows similar amounts of diacids in
1973 and 1974, but considerably smaller amounts of difunc-
tional compounds in 1974.
Diurnal variations in the various difunctional compounds so
not show useful correlations except at West Covina. At this
site, diurnal variations show quite rapid changes in abun-
dances, with a tendency for peaks in the difunctional to
occur coincident with, or somewhat preceeding, the peaks in
the diacids and with more rapid disappearance later. This
is what would be expected if difunctional are intermediates,
ultimately oxidized to diacids. Diurnal variations at West
Covina are given in Fig. 7 and diurnal variations for total
oxygen difunctional compounds at other sites in Figs. 8 and
9. It does not seem worthwhile, for purposes of this
study, to discuss individual members of this group of com-
pounds. An idea of relative distributions among types may
be gained from Table 13. The average amounts of all com-
Table 13_.
Relative Distributions of Oxygen Difunctionals
Holiday Inn West Covina Wash. U. 1973
Acid-Alcohol (1) (1) (1)
Acid-Aldehyde 0.70 1.05 0.85
Aldehyde-Alcohol 0.60 0.50 0.30
Di-aldehyde 0.40 0.56 0.30
C5 1.35 0.56 0.51
C6 (1) (1) (1)
C7 0.73 0.34 0.48
pounds corresponding to the parent ions of acid-alcohol,
acid-aldehyde, aldehyde-alcohol, and di-aldehyde are given,
normalized to acid-alcohol. The distribution by carbon
chain length are given, normalized to the six-carbon chain.
It is seen that no particular compounds dominate the com-
positions at the three sites where large amounts were
found. At the other sites, smaller amounts were found, but
even there most of the compounds were observed occasionally.
Since these compounds may indicate intermediates formed in
important aerosol reactions, efforts should be made to
identify these compounds further and to characterize them.
-------
03
C6HJ203
C6Hi003
C6Hi202
02
i . r~
— i
1800 2400 600 1200 1800 2400
Vertical tics indicate 1 microgram per cubic meter
FIGURE 7. DIURNAL VARIATIONS OF SOME OXYGEN
DIFUNCTIONAL COMPOUNDS AT WEST COVINA.
-------
West Covina
I
Washington U. 1973
Holiday Inn
Washington U .
197H
I
1800 2400 600 1200 1800 2400
Vertical tics indicate 2 micrograms per cubic meter.
FIGURE 8, TOTAL OXYGEN DIFUNCTIONAL COMPOUNDS
EXCEPT DIACIDS.
50
-------
Oxygen
Difunctionals
n
Nitrogen
Difunctionals
Toluene
Products
I
1200 2400 1200 2400
Vertical tics indicate 1 microgram per cubic meter.
FIGURE 9. DIURNAL VARIATIONS AT SEATTLE,
OXYGEN AND NITROGEN DIFUNCTIONALS, TOLUENE PRODUCTS
,51
-------
It does not appear that the methodology used in this report
can be made to produce significantly greater information.
Nitrogen-Containing Difunctional Compounds. In addition to
the difunctional compounds discussed above, we have search-
ed for the occurrence of ions corresponding to the parent
(ui.fragmented) ions of a number of nitrogen-containing spe-
cies. Five types of compounds are involved with varying
?,ar>bon chain lengths:
1. Carboxy acid - alkyl nitrate
2. Aldehyde - alkyl nitrate and/or acid - alkyl nitrite
3. Carboxy acid - acyl nitrate and/or acid - peracyl
nitrite
4. Aldehyde - acyl nitrate and/or acid - acyl nitrite
5. Aldehyde - acyl nitrite
As for the oxygen difunctional compounds, we do not have
mass spectra for the pure compounds and the identifications
are uncertain. Again, there is possible "crosstalk" among
the entries. We have arbitrarily assigned the same sensi-
tivity factors as were assigned to the oxygen difunctional
compounds. These compounds, whatever they are, occur to-
gether. Sites that are high for one compound are high for
others. All of these ions were found in West Covina, Wash-
ington University in 1973, and at Holiday Inn in 1973.
Many of the compounds were found in nearly all samples at
these sites. Lesser amounts were found at other stations,
but traces were found for some of the compounds at all
stations. The six-carbon chain carboxy acid - nitrate com-
pound has been reported by Schwartz (11) as a product of
the reaction of cyclohexene in smog chamber studies.
Average amounts of nitrogen difunctional compounds are giv-
en in Table 12. The abundance of nitrogen compounds is
usually about one half that of the difunctionals containing
oxygen only. The Seattle samples are quite different in
that larger amounts of nitrogen species are found. The
Seattle data do not have good time resolution and none of
the compounds is found in all samples.
Distributions by compound type at the four stations showing
large amounts of nitrogen difunctionals are given in Table
14. The distributions are similar for all four stations.
52
-------
Site
Table 14- .
Distribution of_ Nitrogen Difunctionals
Acid- Aldehyde- Acid- Aldehyde- Aldehyde
Nitrate Nitrate Acyl Acyl Acyl
Nitrate Nitrate Nitrite
West Covina 18%
Wash. U. 73 30%
Holiday Inn 33%
Seattle 22%
39%
26%
29%
42%
6%
2%
2%
4%
28%
28%
27%
31%
8%
3%
7%
2%
It is unfortunate that we do not have good time resolution
at any of the sites showing large amounts, except at West
Covina. Diurnal variations in total nitrogen difunctionals
are shown in Figs. 9 and 10. Nitrogen difunctionals do not
correlate with oxygen difunctionals. The variation with
time of day varies with the site. At Holiday Inn the maxi-
mum occurs in the afternoon, as would be expected from
photochemical activity, but the peak is very unimpressive.
At Washington University in 1973, the largest amounts were
found late at night. Diurnal variations for classes of
nitrogen difunctional compounds are given for the West
Covina station in Fig. 11. This is the only station having
good time resolution and large amounts of material. Large
and erratic changes in abundances occur, but large amounts
occur in the late afternoon.
The nitrogen-containing difunctional compounds are similar
to the oxygen difunctionals in that they show rapid changes
in abundance, with little discernable pattern in the vari-
ations. We do not believe that this is largely error in
measurement technology, since, at West Covina and else-
where, smoother variations in other kinds of compounds were
found. These compounds are probably formed and decompose
rather rapidly; they may be intermediates in reactions to
form more stable molecules.
The data for both kinds of difunctional compounds at West
Covina should be compared with ozone and nitrogen oxides
data. At this writing, we do not have this data.
PRODUCTS OF TOLUENE.
Schwartz (11) has identified eight compounds formed from
toluene in smog chambers. We have entered into the com-
pound files the parent ions for each of these. The last
two (C?H7NOi+ and NITROCRESOLS) are aromatic rings with
certain positions of ring-substituted hydroxyl and nitro
53
-------
West Covina
I
Washington U, 1973
Holiday Inn
r — ' ' "
i
i
!
1800 2UOO 600 1200 1800 2400
Vertical tics indicate 1 microgram per cubic meter.
FIGURE 10. TOTAL NITROGEN DIFUNCTIONAL COMPOUNDS.
-------
Acid - Nitrate
Aldehyde - Nitrate
hyde - Acyl Ni
trate
Aldehyde - Acyl Nitrite
Acid - Acyl Nitrate
tl
1800 2400 600 1200 1800 2400
Vertical tics indicate 1 microgram per cubic meter,
FIGURE 11. POSSIBLE NITROGEN DIFUNCTIONAL COMPOUNDS
AT WEST COVINA.
55
-------
groups. The other compounds are not aromatic. We have not
prepared these compounds, nor do we find mass spectra re-
ported with sufficient information to provide sensitivity
factors. We have assigned to these compounds the same
sensitivity as was assigned to the difunctional compounds,
except for the two ring nitro compounds. We have assigned
10 times the sensitivity for these compounds to reflect
the usual tendency for aromatic nitro compounds to form
strong parent ions. If the same sensitivity factors had
been used as for the rest of this series, the results
reported on the two ring nitro compounds would have been
10 times greater. The very small amounts of ring nitro
compounds reported here may reflect a misjudgement in
assignment of sensitivity factors.
There is a large possibility that some of these ions arise
from fragmentation of other molecules. The members of this
class do appear to occur together, however, in the samples
run. The compounds were included primarily to see if there
is evidence that the compounds reported by Schwartz really
occur in real aerosols. We believe that the work here
provides good evidence that the smog chamber work is a good
model of real aerosols. The first three compounds in the
file, C6H602, CeH802 and CyHioOa, were detected in all of
the samples at West Covina, Holiday Inn, and Washington
University 1973, while the fourth, CsHeOs, was missing only
once at these sites. The first three compounds were also
found in the majority of samples at all other sites. All
eight compounds were detected, usually in several samples,
at West Covina, Holiday Inn, Washington University 1973,
and Seattle. At least some of the eight compounds were
detected at all stations. Average values of total toluene
products at various stations are shown in Table 12. It
should be noted that the compound CsHsOs should also con-
tain contributions from the five-carbon chain oxygen di-
functional compound with aldehyde and carboxy acid func-
tions. The distribution of abundances of these compounds
at the sites rich in these compounds is given in Table 15.
The distribution is about the same for all. Diurnal vari-
ations of total toluene products are shown for several
sites in Figs. 9 and 12. No significant pattern is dis-
cernible. As is the case with other compounds, the data at
West Covina provide more information. The diurnal varia-
tions shown in Fig. 13 for the more abundant compounds and
for the total toluene derivatives show a well-defined af-
ternoon maximum, with low levels at night. This strength-
ens the case for photochemical formation of these com-
pounds. It appears that photochemical reaction of toluene
contributes about as much to atmospheric aerosol as does
56
-------
West Covina
I
Washington U. '73
1
1 1
Holiday Inn
1800 2400 600 1200 1800 2HOO
Vertical tics indicate 2 micrograms per cubic meter,
FIGURE 12. POSSIBLE TOLUENE PRODUCTS.
57
-------
C6H602
C6H802
C5H803
io03
i
I T
1800 2400 600 1200 1800 2400
Vertical tics indicate 2 micrograms per cubic meter
FIGURE 13. SOME POSSIBLE TOLUENE PRODUCTS
AT WEST COVINA.
58
-------
Table 15_.
Distribution of Toluene Products
C6H602
C6H802
C7Hi002
C5H803
West
Covina
43%
32%
12%
10%
2%
1%
0.2%
0.05%
Seattle
42%
32%
12%
11%
0.5%
0.5%
2%
0.2%
Wash. U.
7
3
41%
25%
16%
13%
2%
3%
C . 0 8 %
0.1%
Holiday
Inn
42%
28%
10%
17%
2%
1%
0.06%
0.06%
Dominguez
52%
32%
9%
5%
2%
0
0
0
Nitrocresol
photochemical formation of diacids from cyclic olefins,
assuming that our assignments of sensitivity factors are
reasonable. The contribution of the ring nitro compounds
appears to be very small, even if the sensitivity factors
for these are reduced by a factor of 10. The presence of
many of the compounds at some stations late at night sug-
gests that some are fairly stable.
PRODUCTS OF TERPENES.
We have looked for occurrences of six parent ions, corres-
ponding to possible secondary compounds formed from reac-
tions of terpenes in the atmosphere. These ions have the
formulas C9Hii»02, Ci0Hi602, CioHi^Oa, Ci0Hi603, C8Hi2CU
(norpinic acid?), and CgHinOit (pinic acid?). The first
four of these have been identified by Schwartz (11) as
being formed from alpha pinene in smog chamber reactions.
The last two are also possible terpene products in that
they have been found in this work only at sites where fair
amounts of the first four were found.
As for the toluene products, there is opportunity for many
misidentif ications in relation to these compounds. One can
suggest many molecules capable of producing these ions, and
some of the molecules identified by Schwartz would be ex-
pected to contribute to the parent ions of other terpene
products by fragmentation.
These compounds were found mainly at sites where large
amounts of other, presumably secondary, compounds of photo-
chemical origin (di-acids, oxygen and nitrogen difunction-
als , and toluene products) wtsre found. These possible
terpene products were found mostly at West Covina, Washing-
ton University in 1973, and Holiday Inn. Only occasional
-------
traces were found at Seattle, despite the large forest
areas surrounding this site. The Seattle samples were
taken in the fall, with relatively low temperatures. The
low terpene products found may merely reflect the low
vapor pressures of terpenes, and low emissions. It is un-
fortunate that we cannot determine terpenes themselves.
The Seattle site is peculiar also in that the abundance of
oxygen dif unctionals is low, but abundance of nitrogen
difunctionals and toluene products is high.
The six possible terpene products were not detected as con-
sistently at the above sites as were toluene products. The
four compounds identified by Schwartz occur in most, but
not all, of the West Covina, Washington University 1973,
and Holiday Inn sites. Diurnal variations are erratic, and
the four compounds do not follow each other at all well.
The relative distributions among the compounds are not con-
sistent from site to site, as shown in Table 16.
Table 16_.
Distribution of Possible Terpene Products
West Covina Wash. U. 1973 Holiday Inn
C9Hi<,02 37% 25% 32%
Ci0Hi602 21% 11% 9%
CioHmOa 20% 43% 20%
CioHi603 10% 7% 19%
aCU 10% 14% 12%
^CU 3% 1% 8%
Total average terpene products for various sites are shown
in Table 12.
Overall, only slight evidence is found of the presence of
these terpene products, and the compounds detected could
have arisen from other sources. Certainly, the evidence is
less satisfactory than that for toluene products. It
appears that, at least for the sites studied, terpenes do
not contribute heavily to secondary compounds in aerosols.
It is unfortunate that we do not have data from eastern
mountain sites in the summer; there terpene chemistry may
be more important.
INORGANIC COMPOUNDS .
Although the methods used in this work were designed to
study organic molecules in aerosols, a few inorganic com-
pounds can be measured since they are sufficiently volatile
60
-------
to be introduced into the mass spectrometer. It is very
easy to program the computer to report these, with negli-
gible increase in processing time, so they have been in-
cluded although they are not a major interest in this work.
Sulfates. The amounts of sulfates are reported on the
basis of the intensity of the SO fragment, confirmed by the
SOa peak. We cannot distinguish between free sulfuric acid
and ammonium sulfates. Sulfates are, as expected, the most
abundant single species, in most aerosols, that is reported
in this work. Diurnal variations are shown in Figs. 14 and
15.
We do not regard mass spectroscopy as a suitable way to
determine sulfates, although agreement with other observa-
tions is fairly good.
Chlorides. We report (as ammonium chloride) the abundance
of the HC1 peak, confirmed by the Cl peak using the Clss
isotope. We assume that these ions arise from ammonium
chloride; the primary basis for the assumption is that this
is the only likely inorganic chloride, other than hydro-
chloric acid, that we have found to be volatile enough to
be detected. It appears unlikely that free hydrochloric
acid is present in any substantial amounts in aerosols. It
is possible that organic chlorides could be contributors to
these peaks, but we have been unable to detect significant
amounts of such compounds. Ammonium chloride shows excel-
lent mass thermograms, which help to distinguish it from
other compounds.
Ammonium and Sodium Nitrates. These are reported on the
basis of the abundance of the NOa peak and are confirmed by
the NO peak. The separation between ammonium and sodium
salts is based upon the time-temperature of volatilization
from the probe. Ammonium nitrate is much more volatile
than other nitrates. The data for sodium nitrate would
include other non-volatile nitrates. We do not know wheth-
er sodium nitrate produces N02 by evaporation and subse-
quent ionization, or by thermal decomposition on the probe.
Some diurnal variations for ammonium nitrate are shown in
Fig. 16.
Arsenious Oxide. This laboratory had detected arsenious
oxide in Seattle aerosol using the methods described above,
but prior to the start of this project. Its identity was
well established from the characteristic fragmentation
pattern of AsnO&. We have not detected the compound since,
but we have little Seattle data.
61
-------
Pomona
West Covina
Washington U, 1973
1800 2400 600 1200 1800 2400
Vertical tics indicate 20 micrograms per cubic meter,
FIGURE 14. SULFATES AS SULFURIC ACID.
62
-------
Lead. We have regularly looked for ions of the isotopes of
lead, but have found none.
CHLORINATED COMPOUNDS.
Extensive data have been published on the mass spectra of a
number of chlorine-containing pesticides and chlorinated
biphenyls (20). These compounds should be relatively easy
to distinguish from other types because chlorine isotopes
are quite mass deficient; that is, the masses in atomic
mass units are much less than integers. Of the elements
usually involved in this work, only oxygen and sulfur are
mass deficient, and these are only slightly so. Thus, com-
pounds containing large amounts of chlorine should produce
ions of less than unit mass. This effect would be nulli-
fied, if the ion contains much hydrogen, since this atom is
considerably greater than unit (1.0078 a.m.u.).
We have included in the compound files, ions reported as
being formed in the mass spectra of a number of pesticides
and polychlorinated biphenyls to see if evidence of their
presence would be found.
The reports show occasional occurrences of a few of these
compounds. We believe these to be artifacts. The most
commonly reported compound, CsHsCl (heptachlor fragment?),
can arise as a major fragment in the mass spectra of sever-
al polychlorinated methanindenes. This ion is not mass de-
ficient because of the high hydrogen-to-chlorine ratio, and
it is easily confused with other ions, not containing
chlorine. It is also possible that some of these compounds
represent chlorine-containing impurities in the perfluoro-
kerosene used in the mass spectrometer ion source as a
mass marker.
63
-------
Washington U. 1974
Holiday Inn
National City
1800 2400 600 1200 1800 2400
Vertical tics indicate 20 micrograms per cubic meter
FIGURE 15, SULFATES AS SULFURIC ACID.
64,
-------
West
Covina
Pomona
Washington U, 1974
National City
1800 2400 600 1200 1800 2400
Vertical tics indicate 2 micrograms per cubic meter.
FIGURE 16. SOME DIURNAL VARIATIONS IN AMMONIUM
NITRATE.
-------
REFERENCES
1. Grosjean, D., and Friedlander, S. K., "Gas-Particle
Distribution Factors for Organic Pollutants in the Los
Angeles Atmosphere", paper presented at the 67th.
meeting of the Air Pollution Control Association,
Denver, Colorado, June 1974.
2. Raymond, A., and Guiochon, G., Environ. Sci. Technol.,
8_, 143 (1974).
3. Boyer, K. W., and Laitinen, H. A., Environ. Sci.
Technol. , 9_, 457 (1975).
4. Happ, G. P., Stewart, D. W., and Brockmyre, H. F.,
Anal. Chem., ££, 1224 (1950).
5. Shepard, M., Rock, S. M., Howard, R., and Stormes, J.,
Anal. Chem. , 2_3, 1431 (1951).
6. Sharkey, A. G., Shultz, J. L., Kessler, T., and
Friedel, R. A., "Mass Spectral Investigation of
Organic Contaminants in Airborne Particulates",
Proceedings of the 2nd International Clean Air
Congress, New York, 1971, pages 539-544.
7. Schuetzle, D. , "Computer Controlled High Resolution
Mass Spectrometric Analysis of Air Pollutants",
Thesis, University of Washington, 1972.
8. Schuetzle, D., Crittenden, A. L., and Charlson, R. J.,
iL. Air Pollut. Contr. Assoc., 23, 704 (1973).
9. Schuetzle, D., Cronn, D., Crittenden, A. L., and
Charlson, R. L. , Environ. Sci. Technol. , 9_, 838 (1975)
10. Wilson, W. E., Schwartz, W. E., and Kinzer, G. W.,
"Haze Formation - Its Nature and Origin", Battelle-
Columbus report to the U. S. Environmental Protection
Agency (CPA 70-Neg. 172), January 1972.
11. Schwartz, W. E. , "Chenjical Characterization of Model
Aerosols", Battelle-Columbus report to the U. S.
Environmental Protection Agency (EPA-650/3-74-011),
August 1974.
66
-------
12. "Catalog of Mass Spectra", American Petroleum Institute,
Texas ASM University, College Station, Texas.
13. Stenhagen, E., Abrahams son, S., and McLafferty, F. W.,
"Atlas of Mass Spectra Data", Interscience, New York,
1969.
14. Cornu, A., and Massot, R. , "Compilation of Mass Spectral
Data", Heydon £ Son, London, 1966.
15. Beynon, J. H. , Saunders, R, A., and Williams, A. E.,
"The Mass Spectra of Organic Molecules", Elsevier,
New York, 1968.
16. McLafferty, F. W., "Mass Spectral Correlations",
Advances in Chemistry Series No. 40, American Chemical
Society, Washington, D. C., 1963.
17. McLafferty, F. W., "Interpretation of Mass Spectra",
Benjamin, New York, 1966.
18. Mueller, P. K., Mosley, R. W., and Price, B.,
J. Colloid Interface Sci., 39, 235 (1972).
19. Appel, B. R. , Wall, S. W., Wesolowski, J. J., and
Knights, R. L., "Characterization of Carbonaceous
Materials in Atmospheric Aerosols by High Resolution
Mass Spectrometric Thermal Analysis", paper presented
at the Pacific Conference on Chemistry and Spectroscopy,
Los Angeles, California, October 1975.
20. Safe, S., and Hutzinger, 0., "Mass Spectrometry of
Pesticides and Pollutants", CRC Press, Cleveland,
Ohio, 1973.
67
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PUBLICATIONS
1. Schuetzle, D. , Crittenden, A. L., and Charlson, R. J.,
"Application of Computer Controlled High Resolution
Mass Spectrometry to the Analysis of Air Pollutants",
J. Air Pollut. Contr. Assoc., 23, 704 (1973). This
paper was presented at the 65th annual meeting of the
Air Pollution Control Association at Miami Beach, Fla.,
June 1972.
2. Schuetzle, D. , Cronn, D. , Crittenden, A. L., and
Charlson, R. J., "Molecular Composition of Secondary
Aerosol and Its Possible Origin", Environ. Sci.
Techno1., £, 838 (1975). This paper was presented at
the 166th national meeting of the American Chemical
Society, Symposium on Surface and Colloid Chemistry in
Air Pollution Control, Chicago, 111., August 1973.
3. Knights, R. L., Cronn, D. , and Crittenden, A. L.,
"Diurnal Patterns of Several Components of Urban
Particulate Air Pollution", paper presented at the
Pittsburgh Conference on Analytical Chemistry and
Applied Spectroscopy, Cleveland, Ohio, March 1975.
U. Cronn, D. R., "Analysis of Atmospheric Aerosols by
High Resolution Mass Spectrometry", Thesis to be
submitted to the University of Washington, December
1975.
6.S
-------
This appendix contains compute.: prepared and printed
results of the analyses of the samples mentioned in Sec-
tion IX and represents the entiv1^ da':a base upon which
the preceeding discussion^ ir-t. O3sec' , The data have not
been edited in any way 0.110 'Hey contain errors. The ident-
ities of some compounds are uuoci tain. Some very low
concentrations reported i:cr .'s.vpond to-, signals only slight-
ly above instrument aca.se levels. The data should not be
used without consideration :jF the ^aterial in Sections
VII and X.
The compounds for i7hi.'S< r?<. azx'it--,? vi;-e wade are shown in
the compound files include:! : v this-- appendix, All of the
samples were examined ior- ev '..•'• -. n^e cf each of the comp-
ounds. A report of a coirpo oc' rile title without follow-
ing results simply indicate;!' i:h?t searches were made for
the compounds in thax file, tare aone v/erc found,
The second, third, and fcur'ch l\nr-o at ~rhe beginning of
each report contain data to I/
-------
Contents of the Appendix (Cont'd)
Site Page
Washington University, 1974 168
Holiday Inn 188
National City 209
Tyson Valley, 1973 229
Tyson Valley, 1974 245
Seattle 267
Automobile Exhausts 282
Example of Large Particle Results 286
70
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THERE ARE 0017 COMPOUHDS IN FILE 005.1, DATED 082575
STD. IS MAS1:; 0201. 9454 IH 0-BPOMOBENIOIC ACID
HVDROCAPBOHS
COMPOUND PARENT MASS CODE TI T£
I DENT MASS SENS. SECOND MASS RATIO THIRD MASS RATIO
TOTAL ALKANEiS _ CL 0000. 0000 OOOO OOOO 4000
0071. 0869 0. 1 14E+2 '
ALKANES LOU MU CL OOOO.OOOQ 0009 0000 0300
00S5.101b 0.893E+1
ALYANES MED MM CL 0000. OO0O 0000 0310 66OO
0085.1016 0.800E+1
A L KA H E S H I M M C L O O O 0. 0 9 0 0 O 0 9 9 0 619 499 9
0085.1916 0.765E+1
TOTAL ALKENE-S 0000.9999 9999 0099 4900
9969.0794 9.114E+2
ALKEHES LOU MU CL 9000.9909 9909 0900 9£70
.0983. 0869 9. 893E+1
A L KE N E S ME D. M U C L 9 0 0 9. 9 9 O 0 0 9 0 O 0279 0 51O
99S3.0869 0.890E+1
ALKENES HI MU CL 9999.9930 9099 9519 4999
9 0 8 3 . 0 8 6 9 9 . 7 6 5 E + 1
ALPHA PINENE: oi36. 1250 9900 0000 4000
0121.1016 O.209E+1 9136.1250 0.599E+0
TERPENES AS PINENE CL 0136.1259 9999 9999 4999
0033.0704 0.360E+1
XYLEHES,MOH SUB BENZENES CL 9900.9900 OOOO OOOO 4000
0091.0548 9.175E+2
X Y L E N E S, E T H Y L B E H Z E H E C L 0106.07 8 2 0 0 9 9 9 O O 9 4 9 9 O
9106.0782 9.893E+1
ALKYL BENZENES C9H12 CL 9129.9938 9900 0900 4999
0119.0860 O.177E+1
ALKYL BENZENES C10H14 CL 0134.1094 OOOO 0900 4090
9134.1994 9.423E+1
BIP H E N Y L 19154.97 8 2 0 0 9 9 0 0 0 9 0 4 9 9
0154.0732 9.159E+2 0153.9704 n.259E+9 0152.0626 0.209E+0
D I P H E N Y L M E " H A N E + IS 0 M E R S C: L 0 1 6 8 . 0 9 3 8 0 0 9 0 0 0 0 9 1 O 0 O
0168.0938 9.655E+1 0167.0860 0.370E + 6 0165.0794 0.33011 + 0
71
-------
FILE NO. 00:51. PHGE 02.
COMPOUND PARENT MASS CODE Tl T2
IDEHT MASS SENS. SECOND MASS RATIO THIRD MttSS RATIO
DIPHENYL ETHANE & ISOMERS L 8182.1094 0960 0088 1000
0182.1094 0.364E+1
-------
THERE ARE Cn.H 0 COMPOUHDS IN FILE 605-2. DATED 082575
S T D. I 3 M A S •;;. 6 2 Ol. 9454 I N 0 - D R 0 M 0 B E H Z 0 I C A 0 I D
P 0 L Y C Y C LIC H Y D R 0 C H R B 01-1S
COMPOUND PARENT MASS COHE Tl T2
IDEHT. MASS SENS. SECOND HnSS PATIO THIRD flASS PATIO
N A P H T H H L E N E 10128. 0 6 2 6 0 0 O O 0 0 0O 0 60 0
0 128. U 6 2 6 0.2 0 0 E H- 2 O 1 2 7 . 0 546 0 1 O 9 E + 0 O 1 2 9 . 066 O O . 1 O 9 E + @
M E T H Y L H A P H " H A L E N E S + I H T L 8 1 4 2 . 0 7 8 2 O O 0 0 0 0 O 0 0 6 0 0
0142.0782 0. 105E + 2 0141. 0704 0.719E+0 0115. 0548 0.250E + 0
ALKYL NAPHTHALENES C12H12 L 0156.0938 0000 0000 0600
0156. 0 9 3 8 0. 9 0 0 E +1 01 41. 07 O 4 0. 7 0 W E + O
ANTHRACEHE-PHENHNTHREUE 2 0178 0782 0000 0000 0800
0178.0782 0.289E + 2 0176.0626 O 169E + 0
P Y P E N E £ I S 0 M E P S C 1 6 H i 0 L 0 2 0 2 . O 7 8 2 O O 0 0 (j 0 0 0 0 6 O O
0202.0782 O. 709E+1 0101 0390 0.250E + 0 0203 OS 16 0.169E+0
C H PY S E H E, IG0 M E P S C1BH12 L 022 8. 0 9 3 8 0 0 0 O n0G0 0 6 08
0228.0938 0.600E+1 0226.0782 0.219E+0
P E R Y L E N E.. I ?> 0 M E P S C 2 8 H 1 2 L 0 2 5 2 . 0 9 3 8 O 0 O 0 0 0 0 0 8 6 O O
0252.0938 0.999E+1 0253.0972 0.199E + 0 0250.0782 0.219E + 0
B E N Z 0 P E P. Y L E N E +1 N T E P F E R . E 027 6 . 0 9 3 8 O 0 0 0 (5 0 0 O O 8 0 O
0276. O 9 3 8 O. 6 O 8 E +1
DIBEHlHNTHPACENES C22H14 E 0278.1094 0000 0006 0800
O 2 78. 1 0 9 4 0.5 O O E + 1 O 2 "" 6 O 9 3 i::i O 1 9 9 E + 0 O 2 7 9 . :. 1 2 8 O . 23 9 E + O
C 0 R 0 H E N E ? E 0 3 O O . 0 ? 3 8 0 O O 0 0 0 O 0 1 0 6 O
O 3 O 0. 0 9 3 8 O' 5 O O E + 1
73
-------
THERE ARE 0093 COMPOUNDS IN FILE 0053, DATE]) 082575
STU. IS MASS 9201. 9454 IN 0-BROMOBENZOIC AC IB
A R 0 M H TIC 0 X Y G E N A T E D C P D S
COMPOUND PARENT MASS CODE Tl T2
I DENT MASS SENS. SECOND MASS RATIO THIRD MASS RATIO
C R E S 0 L S < B E N 2 V L A L C 0 H 0 L ? '•' C L 010 8.0574 9 9 O 0 0 9 0 8 4 9 9 O
9188.0574 8. 153E+2 9107.0436 U.393E+0
P H E N 0 L + N 0 2, C H 0, C 0 2 H ? E S T . 9 9 9 9. 9 9 9 9 9 9 9 9 0 9 O 9 4 9 9 9
0033.0340 0.399E+1
T R I M E T H Y L P H El H 0 L + IS 0 M E R S E S T 913 6. 9 8 8 8 9 O 9 9 0 9 9 9 4 9 9 9
9136.9888 8.350E+1
DIH YD R 0 XYBENZENES 1 0110.036 8 9999 099 0 4 999
9110.0368 9.833E+1
B E N Z 0 0. Li IN 0 HE! L 91 9 8.021 9 9 9 9 9 0 9 9 9 4 9 9 9
9198.6210 0.550E+1
N A P H T H 0Q UIH 0 N E ? E S T. 915 8.936 8 0 999 09 O0 4 999
9158.8368 8.599E+1
BEHZALDEHYDE (+INTERF.) L 9106.0418 9009 0900 9609
0106.8418 U.773E+1 9105.9340 9.999E+9 9077.0390 9.109E+1
P H E N 0L 10934.0418 0999 0 990 96 0 9
9034.0418 9.338E+1 0066.046B 0.233E+0 0065.0390 0.259E+0
-------
THERE HRE 0009 COMPOU! IDS IH FILE 0054. DATE]! 082575
STD. IS MAS'". 010] 94-54 IN 0-BPOMOBEMZOIC HI!: ID
c A F: B o:: v Lie A c i D s
COMPOUND PARENT HnSS CODE Tl T2
I DENT MAST. SENS SECOND Mri:.,S PhTIO THIF'D MASS PATIO
BEN ZOIC ACID 2 d 12 2. 036 6 0000 0008 0310
8122 0 366 0 S 0 0 E + 1 0 i 0 5 0 ':' -: 0 0 . 1 2 9 E + 1 0077. 0 3 H 0 6 . 1 2 0 E +1
METHYL B E N 2111 C I S u H E P S L S T 0 1 3 6 0 5 2 4 0 0 0 n 0 0 0 0 S 6 0 0
0136. 0 52 4 0 3 5 'J E + i B 0 ''•'I 0 c_> N :: 0 1 09E i-1
ETHYL BENZO'iC I S J MIr-''": EST. 015>J 0680 0000 0000 06 00
0 150. 0 6 8 0 0 3 5 O E H 0 0 q 1 . 0 5 -i i.) 0 2 6 9 E + 1
TPI METHYL t'tlHZO I C I SOU EST 0164 OS36 OOOO 080O 0600
0164. 0 3 3 6 8 3 5 0E +1
P E N T AN DI 0 IC H CID E S T. 013 2. 0422 0 00 8 8 00 0 8 6 08
0 8 S 6 . 0 3 6 8 0 4 4 Q E + 0 0 132 0 -1 2 „.' 0 9 9 9 E - 2
H E! •: A N H I 0 I C H C ID 4014 6 0 5 7 8 0 O 0 0 0 2 0 O 8 8 0 8
8108.0524 8 379E+0 0146. 057.': 0 999E-2
M E T H Y L H E!! H i i ]"' I 0 I C H C 111 1 U 1 6 0 . 0 7 3 6 S 0 0 0 f'j 2 0 0 0 8 0 8
8114. O 6 8 0 8 4 •-, 9 L + O O 1 b O 0 7 3 6 0 9 9 9 E - 2
B E H Z 0 Y L I 0 *•-•' ' H F B I T F H F Y • 0 0 0 0 0 U 0 0 0 0 8 0 0 0 0 0 4 8 0 8
8 105. 0 3 4 0 0 4 0 0 E +1
ACIDS 'AS H i i E TIC u CID ' E ST 0 0 0 0 0 0 0 0 0 0 0 0 0 O 0 0 4 O 0 0
0 O 6 O O 2 1 0 C i 5 0 0 L + 1
-------
THERE ARE 0014 COMPOUNDS IN FILE 8055.. DATED 082575
STD. IS MASS 9201. 9454 IH 0-BROMOBENZOIC ACID
NITROGEN COMPOUNDS
COMPOUND PRRENT MASS CODE TI T2
I DENT MASS SENS. SECOND MASS RATIO THIRD MASS RATIO
C H 2 C N FRAG M E: N T < R E L A TI V E ) 0 8 0 0. 0 0 8 8 0 9 8 8 0 0 0 0 4 0 8 0
0040.0186 8.999E+8
C0H H FRAGMENT C R E L A TI V E ) 0 0 0 8.8 8 8 8 0 0 0 0 0 8 0 8 4 8 0 8
8043.8858 0.999E+8
C3H5N2 FRAGMENT (RELATIVE) 0008.8808 808Q 0800 4008
8869.0452 8.999E+0
CH2H03 FRAGMENT (RELATIVE!:' 0808.8800 8080 8808 4000
0876.8034 8.208E+1 0845.9928 8.388E+1 8829.9980 0.999E+0
C4H8N2 FRAGMENT (RELATIVE) 0808.8680 8888 8888 4888
8 8 8 4.86 8 6 8. 9 9 9 E + 0
C4H9N2 FRAGMENT (RELATIVE) 0880.8080 0008 8888 4080
0085.8764 8.999E+8
P Y RID I N E + P V RID V L C P D 5 L 8879.84 2 2 8 8 0 8 8 8 8 8 8 6 8 8
8879.8422 8.149E+2 8852.8136 8.729E+8 8851.0108 8.379E+0
PIPERIDINE S ( + I S 0 M E R S '• E S T 0885. 8 8 9 8 8 8 8 8 0 0 8 8 4 8 8 8
8084.0812 8.998E+1
CARBAZOLE L 0167.0734 0888 8880 8600
0167.6734 0.119E+2 8166.8656 8.169E+8
A C R IDI H E & :. S 0 M E R S L 01 7 9 . 0 7 3 4 8 8 0 0 0 8 8 8 8 6 0 8
8179.8734 8.919E+1 8178.8656 8.199E+8 0180.8768 8.139E+8
Q UIH 0 LINE ( --1 N T E R F E R ? :• L 8 1 2 9 . 8 5 7 8 8 8 8 8 0 8 8 8 8 6 8 0
8129.8578 G.134E+2 8182.0468 8.219E+8 0128.8508 8.169E+Q
PIP E R A Z I H E'"' E S T 8 0 8 6. 0 8 440 0 8 O 8 8 8 8 4 8 0 8
8886.0844 0.998E+1 8835.0764 6.169E+1
NITROHHPHTHALENE EST 0173.8476 8888 8009 4808
8173. 8476 8. 199E + 2
P V RIDIN E S U L F A T E EST 0177.809 4 8 8 O 8 8 8 O 8 4 8 0 8
8177.0894 0.150E+1
76
-------
THERE ARE 0026 COMPOUNDS IN FILE 0056, DATE]! 082575
STD. IS MAS-:> 0201. 9454 IN 0-DPOMGBEN.ZOIC MOID
P0 SS I B L E S ELC . D I F U H C T I 0 N A L •••,
COMPOUND PARENT MttSS CODE Tl T2
I DENT MASS SENS. SECOND MASS RATIO THIRD MASS PATIO
C 7 H1 2 8 4 f. M E " H V L A D I P I C '•' D U P 6160.973 6 O 0 0 d 0 0 0 0 4 0 8 0
0160.0736 O 499E-1
C8H503 •:. PHTHALnTES'•
0149.0238 O.999E+0
C7H1403 ISOMERS
0146. 0942 0.9 9 9 E + 0
C 6 H 1 0 0 4 <:. A D " P IC A C ID )
0146.0578 0.499E-1
C7H1203 ISOHEPS
g14 4 _ 07 B g 0 9 y 9 E + 0
C6H1203 ISOMERS
0132. 0786 0. 999E + 0
0 0 0 0 . 0 0 0 0 0 0 0 0 0 0 0 0 4 0 O O
EST 0146.0942 0000 0060 4000
D U P O 146. 0 5 7 8 0 O 80 0 0 O O 4 O O O
EST 0144.0786 O 00 O 0 00 © 4 © O 0
EST 0132.07 8 6 00 OO 0 00 0 4 O 00
C 5 H 8 0 4 < G L U " A R I C A C I D ? ':> EST 0 1 3 2 . O 4 2 2 0 0 0 0 0 O O 0 4 0 9 0
0132.0422 0.499E-1
C7H1402 ISOI-1EPS
0130.0994 0.999E+0
C6H1003 ISOMERS
O 130. 063 0 0. 9 9 9 E + 9
C7H1202 ISOHERS
01 2 8. O 8 3 6 0 . 9 9 9 E + O
E S T 0 1 3 O . O 9 9 4 O O 0 0 0 0 0 O 4 O O 0
E S T 013 0.06 3 0 O 0 0 0 (J OO0 4 8 0O
E S T 012 8. 0 8 3 6 0080 0 0 0 0 4 000
C5H1003 ISOMERS
011 8. 0 63 9 0. 9 9 9 E + 0
E S T Oil 8. 063 0 O 0O 0 « 0 O O 4 0 OO
C4H604
-------
FILE HO. 8856, PAGE 82.
COMPOUND PARENT MASS CODE
I DENT. MASS SENS. SECOND MASS RATIO THIRD
Tl T2
MASS PATIO
HCO>::CH2>60N02+ISOMERS
0175.6844 8.999E+8
H C 0 < C H 2 ':> 5 0 H 0 2 + I S 0 M £ R S
01 61 Q 6 8 8 0 . S 3 9 E + 0
H C 0 < C H 2 '.> 4 0 H 02+1S 0 M E R S
0147.0532 0.999E+0
HOOC'::CH2>4COOH02
0191.0430 0.999E+0
HOOC'-:CH2::'3COON02
0177.8272 0.999E+0
E S T 0175. O 8 440 O0& O 0 80 4 00 O
EST 0161.0688 0000 0000 4000
EST 0147.0532 0000 0000 4008
EST 0191.0430 0000 0000 4000
EST 8177.0272 8000 0888 4880
H C 0 (. C H 2 :? 5 C 0 0 H 0 2 +1 S 0 M E R S EST 0189.06 3 6 0 0 0 0 0 0 0 8 4 0 0 0
8189.0636 8.999E+0
H C 0 < C H 2 >4C 0 0 N02+1S 0 M E R S EST 8175.04 8 8 8 8 8 8 0 8 88 48 8 O
8175.8488 0.999E+0
H C 0 (. C H 2 ':> 3 C 0 0 N 02+1 S 0 M E R S EST 0161.8324 O 0 0 O 0 0 8 8 4 O 0 O
0161.0324 8.999E+6
HCCKCH2MCQOHO
0159.8532 0.999E+8
HCOCCH2;'3COUNO
8145.6374 8.999E+8
EST 8159.8532 8 0 8 8 (18 8 8 4 8 8 O
EST 8145.8374 8088 8888 4888
78
-------
THERE APE 0003 COMPOUNDS IN FILE 0057, DATEP 082575
STD. IS MAS:.": 0201 9454 IH O-DROMOEENZOIC HI: ID
TENTATIVE "OLUENE PRODUCTS
COMPOUND PARENT MASS CODE TI 12
I DENT MASS SENS SECOND MASS RATIO THIRD MASS RATIO
C6H602 I SO ME! PS
Oil 0. 0 3 68 0. 9 9 9 E + 0
C6H802 iSOME:PS
0112.0524 0 999E+0
C7H1002 I SunEPS
0126.0680 0.999E+S
C5H803 ISOME;RS
0116.0472 0 999E + 0
C5H604 ISOME:RS
0 130. 0 26 6 0 . 9 9 9 E + 0
C6H804 I SOME:PS
0144. 0 4 22 0. 9 9 9 E + 0
C7H7N04 I SOHERS
0169.0374 O 99SE+1
NITROCRESOL:::;?
0153.0426 O.99SE+1
E S T 0110.03 6 8 0 0 0 0 O O 0 O 4 0 SO
EST 0112.0524 OOOO OOOO 4000
E S T 0126.O 6 8 O O O O O f j O O O 4 0 O O
EST 0116.0472 OOOO OOOO 4000
EST 0130.0266 OOOO OOOO 4000
EST 0144.0422 OOOO OOOO 4000
E S T 0169. 0 374 0 O 0 0 U O O 0 4 O 0 0
L 0153.0426 O 0 8 0 0 0 0 0 4 O 0 O
79
-------
THERE ARE 0006 COMPOUNDS IN FILE 6053, DATED 032575
STD. IS MASS 0281. 9454 IN 0-BROMOBENZOIC ACID
TENTATIVE "ERPEHE PRODUCTS
COMPOUND PARENT MASS CODE TI T2
I DENT. MASS SENS. SECOND MASS RATIO THIRD MASS RATIO
C9H1402 ISOMERS EST 0154.0994 0000 0000 4000
0154.6994 0.999E+9
C10Hlt"02 ISOMERS EST 0163.1150 0000 0000 4000
0168.1150 0.999E+0
C10H1403 ISOMERS EST 0182.0942 0060 0000 400Q
0182.9942 6.999E+0
ci OH1603 '::P::HONIC AC ID?) EST 0134. 1093 0000 0000 4000
0184.1098 0.999E+0
C8H1204 (NORPINIC AC ID?)EST 0172.0736 0000 0000 4000
0172.0736 0.999E+0
C9H1404 CPIHIC ACID?) EST 0186.0892 0000 0000 4000
0186.8892 O.999E+0
-------
THERE ARE 8f!Q6 COMPOUNDS IN FILE 0059, DATED 082575
STD. IS MAS'l; 02Q1. 3454 IN Q-BRQMQBENZOIC ACID
INORGANIC r,OMPOUNB3
COMPOUND PARENT MASS CODE TI T2
I DENT. MASS SENS. SECOND MASS RATIO THIRD, MASS RATIO
SULFATE3 AS SULFUR 1C ACID 4 0097.9670 0080 8080 4888
6047.9678 0. 120E+1 0063.9618 0.508E + 8
A M M 0 NIU M C H1.0 PID E 36053. O 03 6 0 0 8 0 0 60 8 855 8
0835.9766 0 629E+1 8034.9688 0.999E-1
A M M 0 NIUM NI"RA T E 2 8 8 3 8. 0 222 8 8 8 8 8 0 0 0 855 8
8845.9923 0.388E+1 8829.9988 8.480E+1
SODIUM NITPfiTE 1 8068.9330 0008 055O 4808
0845.9928 0.279E+1 8829.9988 8.419E+1
H P S E N 10 !j S 01 =: I U E 18395.655 8 8 O 0 8 8 O 0 8 4 8 8 8
0395.6553 8.589E+1 0233.7444 8.599E+8 8898.9164 8.199E+0
LEAD EST 8287.9766 0088 0888 4800
8287.9766 8.999E+8 8205.9744 8.449E+8 8286.9758 8.429E+8
81
-------
THERE ARE 0098 COMPOUNDS IN FILE 8069.. DATE]) 082575
STD. IS MASS 0201. 9454 IN 0-BROMOBENIOIC ACID
CHLORINATE ]) C 0 M P 0 U N D S
COMPOUND F'HRENT MASS CODE Tl T2
IDENT. MASS SENS. SECOND MASS RATIO THIRD MASS RATIO
HEPTACHLOROEHPHENYL EST 0391.8054 9008 0000 4008
0395.7794 0.288E+1 0397.7964 0.999E+0 6393.9024 6.568E+8
C12H4CL4 FRAG. PCB? EST 0287.9066 0000 0000 4000
0289.9038 8.200E+1 0287.9866 8.758E+0 0291.9088 0.508E+8
C12H5CL3 FRAG PCB? EST 6253.9456 0806 0800 4800
0253.9456 8 280E+1 0255.9426 0.999E+8 6257.9398 8.338E+8
ISODRIN EST 6361.9756 8880 0880 4688
6192.9378 0.159E+1
ENDRIN •<• DIEILDPIN EST 8377.8766 8606 0608 4688
8262.8578 6.159E+1
DDT, DDD EST 8351.9158 6086 8688 4886
8235.8888 8.288E+1 0237.6852 8.669E+8
LI H D A N £ E S T O 2 8 7 . 8 6 6 6 8 8 8 0 0 8 8 0 4 6 8 8
8188.9378 8.159E+1
C 5 H 5 C L >', H E P " A C H L 0 R ? ':> E S T 8 0 8 8 . 8 8 0 6 8 8 8 0 0 8 8 8 4 8 8 8
8166.0888 0.268E+1 6162.0850 8.330E+8
82
-------
WEST COVIHA 2220 TO 0220 PD" 7/24/73
TB0197RV 2 FILTERS
FILE HO. 09(31, FIT TOL.
993 ailLLIMASSj RUN 0001 TO RUN 003(3
DATE 051474, PAS'!
ERROR 26
506 a'RACTION), SMOOTHED
+0
CPU. F::LE oosi, DATE 002575, HYDROCARBONS
TOTAL ALKANE:S
ALKANES LOW MU
ALKANES MEn. MU
ALKAHES HI MW
TOTAL ALKEHEIS
CL 0. 90 UGM. / M-T-3
CL 0.21 UGM. / M-T-3
CL 0. 23 UGM. /M-T-3
CL O. 24 UGM. /M-r-3
1. 1 UGM. /M-T-3
ALKEHES LOU MU
ALKEHES MED. MW
ALKEHES HI Ml.l
ALPHA PIHENE-:
TERPEMES AS PIHENE
CL 0.13 UGM. /M-T-3
CL 0. 47 UGM. /M-T-3
CL O. 50 UGM. / M-T-3
1 . 1 UGM. /M-T-3
CL O. 54 UGM. /M-r-3
X '•( L E H E S, M 0 N S U B B E N Z E H E S C L 0.53 U G M . / M -r- 3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0.16 UGM. /M-T-3
CL 1. 3 UGM. /M-T3
CL 0.18 UGM. /M-T-3
1 0.18 UGM. /M-T-3
DIPHEHYL ME~HANE+ISOMERS CL 8.0875 UGM. /M-T-3
D I P H E N Y L ETHANE * I S 0 M E P. S L 0.028 U G M / M -T- 3
CPU. F::LE 0052, HATE 002575,
NAPHTHALENE 1
METHYL HAPH"HALEHES+IHT. L
ALKYL NAPHTHALENES C12H12 L
A N T H R A C E N E - F '• H E H A N T H R E N E 2
PYRENE & I30MERS C16H10 L
071
022
033
0
0
O . 0 O 9 3
@. 01 9
POLYCYCL:C
UGM. /M-T-3
UGM /M-T-3
UGM /M-T-3
UGM. /M-T-3
UGM .--M-T3
HYDROCARBONS
PERYLENE, I15QMEPS C 2 01-11 2 L
DIBENZANTHRACENES C22H14 E
O. 0043 UGM. /M-T-3
0.017 UGM. /M-T-3
CPD. F::LE 0053, DATE 002575
CRESOLS C BENZYL ALCOHOL? ;• CL O.
PHENOL+N02,CHO,C02H? EST. 0.
TRIMETHYLPHEINOL+ISOMEP.S EST 0.
DIHYDROXYBENZENES 1 O.
BENZOQUINONE: L
AROMATIC
055 UGM. /M-T-3
28 UGM. .--M-T-3
21 UGM. /M-T-3
096 UGM. /M-T-3
OXYGENATED CPDS
O. 032 UGM /M-T-3
H A P H T H 0 0 U I N 0 N E "' EST. 0.02 4 U G M . / M -T- 3
BEHZALDEHYDE; C + INTERF. :;> L 0.039 UGM /M-T-S
PHENOL 1 0. 063 UGM /M-T-3
83
-------
PAGE 082.
CPD. F::LE 0054, DATE 0(32575, CAI?BOXVL::C ACIDS
BENZOIC AC 1 11 2 0.
METHYL BENZOIC ISOMERS EST. 0.
E T H Y LEE N Z 0 " C I S 0 M EPS EST. 0.
TR I METHYL BE:NZQIC I SOU. EST 0.
PENTANDIOIC ACID EST. 1.
617
042
045
049
UGM./Mt-3
UGM ,"M-t3
U G M / M -t- 3
U G M . .••" M -t- 3
2 UGM./M+3
HEXANDIOIC ACID
METHYLHEXANUIOIC ACID
B E N Z 0 Y L I 0 N <. A P B I T P A R V ?
ACIDS CAS ACETIC ACID;'
4 2.0 UGM . ,-"M-t-3
1 1.1 UGM . .-'M-t 3
0.37 U G M . .-- M -t- 3
EST 8.53 U G M . / M -t- 3
CPD. F:LE 0055, DATE
C H 2 C N FRAG M El N T ( P E L A T I V E '>
CONH FRAGMENT (RELATI
C3H5N2 FRAGMENT ('RELA
C4H8N2 FRAGMENT (RELA
C4H3N2 FRAGMENT '.RELA
P V R I D I N E + P Y R I D Y L C P
PI PER I DINES ( + ISOMERS
A C R I D I N E & :: S 0 M E R S
QU INCLINE -T--INTERFER??
PIPERAZINE">
CPD. F::LE oese,
C 7 H 1 2 0 4 ( M E "' H Y L A D I P I
C3H503 (PHTHALATE3?
C 7 H 1 4 0 3 I S 0 M E R S
C6H1804 (Rrrpn: ACID?
C7H1203 ISOMERS
C6H1203 ISOMERS
C5H304 (GLU"ARIC ACID
C7H14O2 ISOMERS
C6H1003 ISOMERS
C7H1202 ISOMEPS
C5H1003 ISOMEPS
C6H1202 ISOMERS
C 5 H 1 8 0 2 I S 0 M E P S
HOOC(CH2?50N02
H C 0 ( C H 2 ? 6 0 N 0 2 + I S 0 M E R S
002575, NITROGEN
0 . 7 8 U G M . .•' M -t- 3
VE
TI
TI
TI
DI-.
o
;i
?
•)
VE?
VE?
VE?
L
EST
L
L
EST
DATE 08
c ?
?':>
DUP
EST
DUP
EST
EST
EST
EST
EST
EST
EST
EST
EST
EST
EST
4
0
0
8
8
8
O
O
8
O
8
3
O
1
0
O
2
0
0
0
0
0
8
0
0
. 2 UGM xM-t-3
. 17 UGM. .-'M-t-3
.037 UGM. .--M-t-3
. 33 UGM. .-"M-t-3
. 8064 UGM. .-"M-t-3
. 072 UGM /M-t-3
. 010 UGM. /Mt-3
.8041 UGM. .--Mt3
. 0037 UGM. --M-t-3
575, POSSIBLE
. 62 UGM. .•'Mt-3
. © UGM. -•' M-t-3
. 862 UGM. .-'M-t-3
. 8 UGM. xM-t-3
. 29 UGM. .'Mt-3
.831 UGM. xM-t-3
.2 UGM. .-'M-t-3
. 031 UGM .-Mt-3
. 18 UGM. .-Tit- 3
.843 UGM .--M-t-3
. 33 UGM. .-'Mt-3
. 12 UGM. .-'M-t-3
. 12 UGM. .--M-t-3
. 081 UGM .--Mt-3
. 068 UGM. .-'M-t3
' H CO ( CH2? 5 ON02+ ISOMERS EST 0.087 UGM x M-t-3
H C 0 ( C H 2 ? 4 0 N 0 2 + I S 0 M E P S E S T 0.0 6 2 U G M . .-" M -t 3
H C 0 •: C H 2 ? 5 C 0 i .1 N 0 2 + I S 0 M E R S E S T 0.24 U G M . ."' M -t- 3
COMPOUNDS
SEC. DIFUNCTIONALS
-------
PAGE 003.
HCOCCH2MCQON02-USOMERS EST 8.087 UGM /M + 3
HCOCCH254COOHO EST 0.043 UGM. /M-t-3
CPD. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUCES
C6H602 ISOMEIRS
C6H8G2 ISOMfIRS
C7H1002 ISOMERS
C5H803 ISOMEIRS
C5H604 ISOMERS
C7H7N04 ISOMERS
EST 0. 80 UGM. /M-t-3
EST 0. 75 UGM. /M-t-3
EST 0. 037 UGM. /M + 3
. 087 UGM. /M-t-3
. 037 UGM. /M-t-3
EST
EST
EST 0.010 UGM. /M-t-3
CPD. F::LE 0053,
C9H1402 ISOMERS
C10H1602 ISOMERS
C16H1403 ISOMERS
DATE 902575.. TENTATIVE
EST 0.11 UGM. /M-t-3
EST 0.037 UGM./M*3
EST 0. 087 UGM. /M-t-3
TERPENE PRODUCTS
C8H1204 CNOFJPINIC ACID?>EST
099 UGM xMt-3
CPD.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
HI"RATE
COMPOUNDS
SODIUM NITRATE
CPD. F::LE 0060,
DDT, DDD
LINDANE
C5H5CL
DATE 082575, INORGANIC
ACID 4 26. UGM. ,-'M-t3
3 0. 44 UGM. .--M-t-3
21.4 UGM. /M-t-3
1 0.11 UGM. /M-t-3
DATE 0B2575, CHLORINA"ED COMPOUNDS
EST 0.021 UGM./M*3
EST 0. 038 UGM. /M-t-3
EST 0. 059 UGM. /M-t-3
85
-------
WEST COVIHA 9220 TO 0720 PD" 7/24/73
TB0195RV 2 FILTER
FILE NO. 00(J1. FIT TOL. 083
-------
PAGE 092.
CPD. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
BEHZOIC ACID 2
METHYL BEHZOIC ISOMERS EST.
ETHYL BEHZOIC ISOMERS EST.
PEHTAHDIOIC ACID EST.
HEXAHIHOIC ACID 4
METHYLHEHANIHOIC ACID 1
BENZOYL ION CARBITRARY)
ACIDS CAS ACETIC ACID;> EST
0. 031 UGM. /M-t-3
0. 033 UGM. /M-t-3
0. 087 UGM. /M-t-3
0.61 UGM. /M-t-3
1. 5 UGM. /M-t-3
0. 35
0. 58
0. 55
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t-3
CPD. F::LE 0055.. DATE 0^2575. NITROGEN COMPOUNDS
CH2CH FRAGMENT EST
CARBAZOLE L
ACRIDINE & "SOMERS L
NITROHAPHTHflLENE
PYRIDINE SUL.FATE
973
011
013
023
UGM. /M-t3
UGM, /M-t-3
UGM /M-t-3
UGM. /M-t-3
0. 0093 UGM. /M-t-3
EST 0.0024 UGM./M-t-3
EST 0. 073 UGM. /M-t-3
CPD. F::LE 0056, DATE 992575. POSSIBLE
C7H1234 CME"HYL ADIPIC) DUP 2.6 UGM. /M-t-3
C8H503 (PHTHALHTES) 10. UGM./M-1-3
C7H1203 ISOMERS EST 0.21 UGM. /M-t-3
C6H1203 ISOMERS EST 0.18 UGM. /M-t-3
C6H1003 ISOMERS EST 0.56 UGM. /M-t-3
SEC. DIFUNCTIONALS
C7H1202 ISOMERS
C5H1003 ISOMERS
C6H1202 ISOMEPS
C5H1002 ISOMERS
HOOCCCH2)40N02
HCO
-------
PAGE 603.
CPD. F::LE 0057, DATE 002575, TENTATIVE; TOLUENE PRODUC-S
C6H602 ISOMHRS EST 0.95 UGM./M+3
C6H802 ISOME:RS EST 0.56 UGM./M^S
C7H1802 ISOT1ERS EST 0.20 UGM. /M-t-3
C5H803 ISOME-RS EST 0.29 UGM./M + 3
C7H7H04 ISOMERS EST 0.0048 UGM.''M-t-3
CPD. F::LE 0053, DATE 002575, TENTATIVE TERPENE PRODUC-S
C10H1603
DATE 002575, CHLORINA"ED COMPOUNDS
EST 0. 024 UGM. /M-t-3
EST 0.12 UGM. /M-r-3
88
-------
WEST COVIHA 0728 TO 0.920 PD^ 7V24/73.
TB0198RV 2 FILTERS
FILE HO. 0001, FIT TOL. 803 RUN 0066 TO RUN 009T>
DATE 051474, PASS3 ERROR 26
31 IE +0 CUET.C METERS, ALIQUOT = 0. 560E +0
TOTAL SAMPLE[ =
INST. SENSI"IVITY=9.
374E
CHECK HEIGH" RATIO=0. 508 (TRACTION), SMOOTHED
CPD. F:LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANES
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE
TERPEHES AS PINENE
CL 3. 1 UGM. /M-t-3
CL 0. 32 UGM. /M-t-3
CL 1. 6 UGM. /M-t-3
CL 0. 75 UGM. /M-t-3
3.1 UGM./Mi" 3
CL 0.16 UGM./M+3
CL 1. 3 UGM. /M +3
CL 1.6 UGM./M-t-3
3. 1 UGM. /M-t-3
CL 1. 1 UGM. /M+3
XYLENES, MON SUB BENZENES CL 1.0 UGM./M-t-3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C3H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 38 UGM. /M + 3
CL 3.6 UGM./M-t-3
CL 0. 36 UGM. xM-r-3
1 0.18 UGM./M+3
DIPHEHYL ME"HANE+ISOMERS CL 0.063 UGM./M-r3
DIPHENYL ETHANE & ISOMERS L 0.867 UGM./M*3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.20 UGM./M*3
METHYL NAPH"HALENES + INT. L 0.14 UGM./'M + S
ALKYL NAPHTHALENES C12H12 L 6.051 UGM./M-1^3
ANTHRACEHE-PHENANTHREHE
PYRENE & ISOMERS C16H10
2 0.026 UGM./M+3
L 0.068 UGM./M+3
CHRYSENE, ISOMERS C18H12 L 0.015 UGM./M^3
CPD. F::LE 0053, DATE 002575,
CRESOLS CL
PHENOL+H02,CHO,COSH? EST.
TRIMETHYLPHENQL+ISOMERS EST
DIHYDROXYBENZENES 1
BENZOQUINONE:
e. 11
0. 73
0.19
0. 17
AROMATIC
UGM.xM+3
UGM. /M-t-3
UGM. /M-t-3
UGM..
L 0. 050 UGM. xM-t-3
OXYGENATED CPDS
NAPHTHOQUINOHE? EST. 0.015 UGM./M+3
BENZALDEHYDE: < + INTERF. > L 0.011 UGM./ri-t-3
PHENOL 1 0.14 UGM. /M-t-3
CPD. F::LE 0054,
BENZOIC AC ID
DATE 082575,
2 0.092
CARBOXYL::C ACIDS
UGM. /M-t-3
89
-------
PAGE 002.
METHYL BEHZOIC ISOMERS EST. 0.15 UGM./M*3
ETHYL BENZO:C ISOMERS EST. 0.022 UGM./M-t-3
TRIMETHYL BEIHZOIC ISOM. EST 0.866 UGM./Mt3'
PENTAHDIOIC ACID EST. 1.0 UGM.
HEXANDIOIC: ACID
METHYLHEXAHD101C AC ID
BENZOYL I OH
-------
PAGE 803.
CPU. F::LE 0057,
C6H602 I SOWERS
C6H802 ISOME:RS
C7H1002 ISQMERS
C5H803 ISOMEIRS
C5H604 ISOME-:RS
NITROCRESQL8?
CPD. F:LE 0053,
C9H1402 ISOMERS
C10H1602 ISOMERS
C10H1403 ISOMERS
DATE 082575, TENTATIVE: TOLUENE PRODUC"S
EST 1.4 UGM./M*3
EST 0.62 UGM./M-t-3
EST 0.21 UGM. /M-t-3
EST 0. 58 UGM. /M-t-3
EST 0. 29 UGM. /M-t-3
L 0. 0061 UGM. /M-t-3
DATE 082575, TENTATIVE TERPENE .PRODUCT'S
EST 0.23 UGM.xM+3
EST 0.27 UGM./M*3
EST 0. 26 UGM. /M-t-3
C10H1603 EST 0.092 UGM./M-t-3
CPD. F::LE 0059,
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM NI"RATE
SODIUM NITRATE
CPD. F::LE 0060,
ISODRIN
LIHDANE
C5H5CL
-------
WEST COVINA 0920 TO 1120 PD~ 7/24/73.
TB0199RV 2 FILTERS
FILE HO. 0001, FIT TOL. 003 (MILL I MASS) RUN 0097 TO RUN 0128
DATE 051474, PASS3 ERROR 26 CM ILL I MASS)
TOTAL SAMPLE = 0. 303E +0 CUBiiC METERS, ALIQUOT = 0. 560E +0
INST. SENSI"IVITY=0. 412E + J5
CHECK HEIGH" RAT 10 = 0. 500 CL
PHENOL+N02,OHO,C02H? EST.
TRIMETHYLPHENOL+ISOMERS EST
DIHYDROXYBENZENES 1
BENZOQUINONE: L
21
45
22
27
UGM. /M-t3
UGM. /M-t-3
UGM. /M-t-3
AROMATIC
UGM. .--M-t-3
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t3
OXYGENATED CPUS
0. 086 UGM. /M-t-3
NAPHTHOQUINONE?
BENZALHEHYDE: OINTERF.
PHENOL
EST. 0. 837 UGM. /M-t-3
> L 0. 065 UGM /M-t3
1 0. 23 UGM. /M-t-3
92
-------
PAGE 092.
CPD. F::LE 0054, DATE 002575.. CARBOXYL::C ACIDS
BENZOIC ACID 2
METHYL BEHZOIC ISOMERS EST.
ETHYL BENZOIC ISOMERS EST.
TRI METHYL BEEHZOIC ISOM. EST
PEHTAHDIOIC ACID EST.
HEXAHDIOIC ACID 4
METHYLHEXANIHOIC ACID 1
BEHZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID) EST
0. 18 UGM, /M-t-3
0. 22 UGM. /M-t-3
0.15 UGM. /Mt-3
0. 024 UGM. /M-t-3
3. 2 UGM. /M-t-3
5. 7
3. 4
1. 3
1. 1
UGM. /M-t-3
UGM./M*3
UGM. /Mt-3
UGM. /Mt-3
CPD. F::LE 0055, DATE
CH2CN FRAGMENT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
082575, NITROGEN
1. 5 UGM. /Mt-3
9. 3 UGM. /M-t3
0. 46 UGM. .-'M-t-3
0.33 UGM./Mt-3
0.11 UGM. /Mt-3
COMPOUNDS
C4H9N2 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPUS L
PI PER I DINES < +ISOMERS) EST
CARBAZOLE L
ACRIDINE & ::SOMERS L
QUINOLIHE (--INTERFER?) L
PIPERAZINE? EST
PYRIDINE SUL.FATE EST
0.10 UGM. /M-t-3
0. 028 UGM. /M-t-3
0.11 UGM./M+3
0. 040 UGM. /M-t-3
0.015 UGM. /M-t3
0. 0096 UGM. /M-t-3
0. 0672 UGM. /M-t-3
0.15 UGM. /Mt-3
CPD. F::LE 0056, DATE
C8H503 (PHTHALATES)
C7H1403 ISOMERS EST
C6H1004 (AD::PIC ACID) DUP
C7H1203 ISOMERS EST
C6H1203 ISOMERS EST
082575, POSSIBLE
4. 5 UGM. /M-t-3
0. 34 UGM. /M-t-3
10. UGM./M+3
0.10 UGM. /M-t-3
0. 44 UGM. /M-t-3
SEC. DIFUNCTIONALS
C5H804 (GLU"ARIC ACID?) EST 2.3 UGM./M+3
C7H1402 ISOMERS
C6H1003 ISOMERS
C7H1202 ISOMERS
C5H1903 ISOMERS
EST 0. 072 UGM. /M-t-3
EST 0. 70 UGM. /M-t-3
EST 0.21 UGM. /M-t-3
EST 0. 45 UGM. /M-t-3
C 4 H 6 0 4 ( S U C C I N 1C ACID ? ) EST 6.4 U G M . / M -t- 3
C6H1202 ISOMERS
C5H1002 ISOMEPS
HOOC(CH2)50N02
HOOC(CH2)40N02
EST 0. 057 UGM. /Mt-3
EST 0. 23 UGM. /Mt-3
EST 0.15 UGM. .--M-t-3
EST 0.17 UGM. /Mt-3
93
-------
PAGE 903.
HCOCCH2>50N02+ISOMERS EST
HCOCCH2::'40N02+ISOMERS EST
HOOC3COQN02 EST
HCO
DATE 082575, CHLORINA"ED COMPOUNDS
EST 0.045 UGM./M+3
EST 0. 24 UGM. /M-t-3
EST 0. 24 UGM. /M-t-3
-------
WEST COVINA 1120 TO 1326 PD" 7^24/73
TB0200RV 2 FILTERS
FILE NO. 0901, FIT TOL. 003 RUN 0130 TO RUN
DATE 051474, PASS3 ERROR 26 < MI LL I MASS)
TOTAL SAMPLEI = 0. 303E +0 CUB"C METERS, ALIQUOT = 0. 560E +0
IHST. SENSI"IVITY = 0. 374E +J5
CHECK HEIGH" RATIO=0. 500 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 0532575, HYDROCAREJONS
TOTAL ALKAHE-S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE-S
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PIHENE:
TERPEHES AS PINENE
CL 2. 2 UGM. /M-t-3
CL 0. 60 UGM. /M + 3
•CL 0. 72 UGM. /M-t3
CL 0.41 UGM. /M + 3
2.. 9 UGM. /M-t-3
CL 0. 23 UGM. /M-t-3
CL 0. 94 UGM. /Mt-3
CL 0.86 UGM./M-t-3
2.5 UGM./M + 3
CL 1. 2 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 1 . 1 UGM./M+3
XYLENES, ETHYL BENZENE CL 0.56 UGM..'M + 3
ALKYL BENZENES C9H12 CL 3.7 UGM./M+3
ALKYL BENZENES C10H14 CL 0.25 UGM./M+3
BIPHENYL 1 0.41 UGM./M+3
DIPHENYL ME~HANE+ISOMERS CL 0.041 UGM.xM-t3
CPD. F:LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.14 UGM. .--M'T-3
METHYL NAPH"HALENES+IHT. L 8.963
ALKYL NAPHTHALENES C12H12 L 0.0044
ANTHRACEHE-PHENANTHRENE 2 9.053 UGM.xM-t-3
PYREHE & ISOMERS C16H10 L 0.054 UGM./M+3
CHRYSENE, ISOMERS C18H12
PERYLENE, ISOMERS C20H12
BENZOPERYLEHE+INTERFER.
DIBENZANTHROCENES C22H14
CORONENE?
L 8. 826 UGM. /M-t-3
L 8.015 UGM. /(it3
E 0.013 UGM./M+3
E 0.038 UGM.
E 0. 025 UGM.
CPD. F:LE 0053, HATE 082575,
CRESOLS (BENZYL ALCOHOL?>CL 0.23
PHENOL+N02,CHO,C02H? EST.
TR i METHYLPHE;HOL+ISOMERS EST
DIHYDROXYBENZEHES 1
BENZOQUINOHE: L
0.92
0.44
0. 46
0.11
AROMATIC
UGM-. /M-t-3
UGM . /M-t-3
UGM./M*3
UGM. /M-t-3
UGM. /M-t-3
OXYGENATED CPDS
NAPHTHOQUINONE?
BENZALDEHYDE < +
PHENOL
EST. 0.02
INTERF.) . L 0.12
1 0. 23
UGM./M+3
UGM . /M-t-3
UGM. /M-t-3
95
-------
PAGE 002.
CPD. F:LE 0054. DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0.26 UGM./M+3
METHYL BENZOIC ISOMERS EST. 0.24 UGM. /M-t-3
ETHYL BENZO::C ISOMERS EST. 0.056 UGM. /M-t-3
TRIMETHYL BEINZOIC ISOM. EST 0.18 UGM./M-t-3
PENTANDIOIC ACID EST. 2.8 UGM./M-t-3
HEXANDIOIC ACID 4 5. 6 UGM./M + 3
METHYLHEXANIHOIC ACID 1 2.8 UGM./M-t-3
BENZOYL ION (ARBITRARY) 1.0 UGM./M-t-3
ACIDS (AS ACETIC ACID) EST 1.4 UGM./M-T-3
CPD. F:LE 0055.. DATE 082575, NITROGEN COMPOUNDS
CH2CH FRAGME-IHT (RELATIVE) 1.7 UGM./M+3
UGM. /M-t-3
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
12.
9. 42 UGM. ."-M-t-3
0. 27 UGM. /M-t-3
0. 32 UGM. /M-t-3
C4H9N2 FRAGMENT (RELATIVE)
PYRIDIHE + PYRIDYL CPDS L
PI PER I DINES ( + ISOMERS "> EST
CARBAZOLE L
ACRIDIHE & ISOMERS L
QU INCLINE (--INTERFER?) L
NITROHAPHTHALENE EST
PYRIDINE SULFATE EST
0. 39 UGM. /M-t-3
0. 057 UGM /M-t-3
0. 033 UGM /M-t-3
0. 026 UGM. /M-t-3
0.013 UGM. /Mi-3
0.017 UGM. /M-t-3
0. 6071 UGM. /M-t-3
0. 095 UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, POSSIBLE SEC. DIFUNCTIONAL*
C7H12G4 (ME"HYL ADIPIC) DUP
C8H503 (PHTHALATES)
C7H1403 ISOMERS EST
C6H1004 (AD::PIC ACID) DUP
C7H1203 ISOMERS EST
1. 3 UGM. /M-t-3
7. 6 UGM. /M-t-3
0.14 UGM. /M-t-3
17. UGM. /M-t-3
0.41 UGM./M-t-3
C6H1203 ISOMERS EST 0.
C5H804 (GLU"ARIC ACID?) EST 1.
C7H1402 ISOMERS EST 0.
C6H1003 ISOMERS EST 0.
C7H1202 ISOMERS EST 0.
38 UGM. /M-t-3
5 UGM. /M-t-3
095 UGM /M-t-;
25 UGM. /M-t 3
15 UGM. .--M-t-3
C5H1Q03 ISOMEPS
C4H604 (SUCCIHIC
C6H1202 ISOMERS
C5H1902 ISOMERS
HOOC(CH2)40N02
EST 8.63 UGM./M+3
ACID?) EST 3. 4 UGM. /M-t-3
EST 0.12 UGM. /M-t-3
EST 0. 53 UGM. /M-t-3
EST 0. 33 UGM. /M-t-3
96
-------
PAGE 803.
HCO60H02+I SOMERS
HCO40N02+ISOMERS
HOOC3COON02
HCO 5CQON02+1SOMERS
HCQ3CQON02+ISOMERS
HCOCCH2)3COONO
EST 9. 095 UGM. /M-t-3
EST 0.11 UGM./M + 3
EST 0. 62 UGM. /M-t-3
EST 0. 11 UGM. /M + 3
EST 0. 28 UGM. /M-t-3
EST 0. 53 UGM. /M-t-3
EST 0.063 UGM./M + 3
EST 0.073 UGM./M + 3
CPU. F::LE 0057, DATE 002575.. TENTATIVE- TOLUENE PRODUCTS
C6H602 ISOMEERS
C6H802 ISQME-RS
C7H1002 ISOMERS
C5H604 ISOMEIRS
C6H804 ISOME-RS
C7H7N04 I SOMERS
HITROCRESOLB?
EST 3. 3 UGM. /M + 3
EST 2. 7 UGM. /"Mt-3
EST 1. 9 UGM. /M-t-3
EST 0. 31 UGM. /M-t-3
EST Q.14 UGM. /M-t-3
EST 0. 0079 UGM.
L 0. 015 UGM. /M-t-3
F::LE 0058,
ISOMERS
ISOMERS
CPD.
C16H1602
C10H1403
C10H1603 EST
DATE 082575, TENTATIVE!
EST 0. 079 UGM. /M-t-3
EST 0. 36 UGM. /M-t-3
0. 095 UGM. /M-t-3
0.41 UGM..'M-t-3
0.079 UGM./M*3
TERPENE PRODUC"S
CPU. F::LE 0059,
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM NI"RATE
SODIUM NITRflTE
CPU. F::LE 0050,
LINDAHE
C5H5CL
COMPOUNDS
DATE 082575, INORGANIC
ACID 4 34. UGM. /M-t-3
3 8. 93 UGM. /M-t-3
23.3 UGM./M+3
1 0. 48 UGM. /M-t-3
DATE 982575, CHLORINA"ED COMPOUNDS
EST 0. 069 UGM. /M-t-3
EST 0. 34 UGM. /M-t-3
97
-------
WEST COVINA 1329 TO 1520 PD" 7/24x73
TB02G1RV 1 FILTER
FILE HO. 0801, FIT TOL. 003 CM ILL I MASS) RUN 0364 TO RUN 0399
DATE 651474, PASS3 ERROR 26
-------
PAGE 882.
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0.060 UGM. /M-t-3
METHYL BENZOIC ISOMERS EST. 0.36 UGM. /M-t-3
ETHYL BEHZO::C ISOMERS EST. 0.17 UGM. /M-t-3
TRIMETHYL BEINZOIC ISOM. EST 0.14 UGM./M-t-3
PEMTANDIOIC ACID EST. 2.3 UGM. ./M-t-3
HEXAHDIOIC fiCID 4 8.3 UGM./M-t-3
METHYLHEXANDIOIC ACID 1 5.4 UGM./M*3
BENZOYL I ON f. ARE ITRARY ) 1.4. UGM . /H-t-3
ACIDS <:AS ACETIC ACID:) EST 2.4 UGM./M*3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMENT < RELATIVE ) 4.2 UGM./M+3
23. UGM./Mt3
3. 0 UGM. /M-t-3
0. 32 UGM. /M-t-3
0. 19 UGM. /M-t-3
CONH FRAGMENT (. RELAT IVE)
C3H5N2 FRAGflEHT C RELAT I VE)
C4H8N2 FRAGMENT (RELATIVE)
C4H9H2 FRAGMENT CRELATIVE)
PYRIDINE + PYRIDYL CPUS
PI PER I DI HES <: + ISOMERS >
CARBAZOLE
ACRIDINE & ::SOMERS
QUINOLI HE <. -1NTERFER? )
NITROHAPHTHnLEHE
PYRIDINE SULFATE
L
EST
L
L
L
0. 065
0. 067
0. 033
0. 813
UGM.
UGM
UGM.
UGM.
UGM.
/ M-t-3
/M-t-3
/•M-t-3
/ M-t-3
/Mt-3
EST 6.0996 UGM./M+3
EST 0.13 UGM. /M-t-3
CPD. F:LE 0055, DATE 002575.. POSSIBLE SEC. DIFUHCTIONOLS
C7H1204 : CH2 ) 4COOH02+ I SOMERS
HCOCCH2)3COOHO
EST 0. 45 UGM. /M-t-3
EST 1. 6 UGM. /M-t-3
EST 0. 25 UGM. /M-t-3
EST 0. 35 UGM. /M-t-3
EST
EST
EST
EST
EST
9. 35
0.19
0. 12
0.12
0. 25
UGM.
UGM.
UGM.
UGM.
/M-t-3
/M-t-3
/M-t-3
/ M-t-3
UGM. .--M-t-3
991
-------
PAGE Q03.
CPD. F::LE 0057,
C6H602 ISOMEi'RS
C6H302 ISQME-RS
C7H1002 ISOMERS
C5H803 ISQME-RS
C6H804 ISOMEIRS
DATE 002575, TENTATIVE: TOLUENE PRQDUC"S
EST 5.5 UGM./M*3
EST 3. 1 UGH. /Mt-3
EST 0. 96 UGM. /M-t-3
EST 2. 0 UGM. /M-t-3
EST 0.16 UGM. /M-t-3
C7H7N04 ISOflERS
EST 0. 037 UGM. /M-t-3
CPD. F::LE 0053.
C9H1402 ISOMERS
C10H1602 ISOMERS
C10H1403 ISOMERS
C10H1603 EST 0.16 UGM./M-t-3
ACID?>EST 0.16 UGM./M-t-3
CPD.
SULFATES
AMMONIUM
AMMONIUM
F:LE 00.59,
AS SULFUR 1C
CHLORIDE
NI"RATE
SODIUM NITRflTE
DATE 002575, INORGANIC
ACID 4 43. UGM. /M-t-3
31.0 UGM. /M-t-3
21.6 UGM. /M-t3
1 0. 60 UGM. /M-t-3
COMPOUNDS
CPD. F::LE 0060,
LINDANE
C5H5CL CHEP"ACHLOR?)
DATE 8B2575, CHLORINA"ED COMPOUNDS
EST 0. 26 UGM. /M-t-3
EST 0. 33 UGM. /Mt.3
100
-------
WEST COVIHA 1529 TO 1720 PD" 7/24/73.
TB0282RV 1 FILTER
FILE HO. 0001, FIT TOL. 003 CM ILL I MASS) RUN 0323 TO RUN 0363
DATE 851474, PASS3 ERROR £6
TOTAL SAMPLEI = 0. 30IE +0 CUBiiC METERS, ALIQUOT = 0. 2S0E +0
INST. SEHSI"IVITY=0. 374E +K
CHECK HEIGH" RAT 10 = 0. 590 L 0.27 UGM./n-t-3
PHEHOL 1 0. 35 UGM. /M-t-3
101
-------
PAGE 082.
CPD. F::LE 0054* DATE 082575, CARBOXYL::C ACIDS
BENZOIC ACItt 2 0.32 UGM./M-t3
METHYL EEHZOIC ISOMERS EST. 0.21 UGM./M-t-3
ETHYL BENZO::C ISOMERS EST. 0.054 UGM./M-t-3
TRI METHYL BEIHZOIC ISOM. EST 0.045 UGM./M-t-3
PENT AUDI QIC ACID EST. 4.7 IJGM./M-t-3
HEX AND I QIC ACID 4 8.9 UGM./M-t-3
METHYLHEXANDIOIC ACID 1 4.3 UGM./M-t-3
BEHZOYL ION (ARBITRARY) 1.4 UGM./M+3
ACIDS CAS ACETIC ACID) EST 3.0 UGM./M-t-3
CPU. F:LE 005;
CH2CH FRAGMEINT ( RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5.N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H9N2 FRAGMENT (RELATIVE)
DATE 082575, NITROGEN COMPOUNDS
3. 1 LIGM. /M-t-3
13. UGM./M-t-3
1 . 2 IJGM. /M-t-3
0. 064 UGM /'M-t-3
0.12 UGM. /M-t-3
PYRIDINE + PYRIDYL CPUS
P I PEP. ID IHES ( + ISOMERS >
CARBAZOLE
ACRIDINE $-. ."SOMERS
QUINOL I NE (--1 NTERFER? )
PYRIDINE SUl.FATE
L
EST
L
L
L
0. 021 UGM /M-t-3
0. 060 UGM / M-t-3
0. 021 UGM. /M-t-3
0. 013 IJGM .-- M-t-3
0. 084 UGM / M-t-3
EST 0. 29 UGM. /M-t-3
CPD
C8H503 (
C7H1403
C6H1
C7H1
C6H1
004
203
203
C5H804 (
C7H1
C6H1
C7H1
C5H1
C6H1
C5H1
HOOC
HOOC
HCO(
402
003
202
003
202
002
(CH2
(CH2
CH2)
. F::LE 0055, DATE 082575
PHTHALATES) 8.8
I
(
I
I
SOMERS
AD:: PI
SOMER
SOMER
GLU"AR
I
I
I
I
I
I
)
)
6
SOMER
SOMEP
SOMEP
SOMER
SOMER
SOMER
50N02
40N02
OH 02 +
C ACID)
C*
C
1C ACID?)
t~-
C;
s
'-'
c-
C;
ISOMERS
EST
DUP
EST
EST
EST
EST
EST
EST
EST
EST
EST
EST
EST
EST
0
1
0
1
3
0
1
1
0
©
0
0
0
0
. 1
6.
6
. 95
9
. 8
. 2
2
. 6
2
. 68
. 44
. 6
. 1
. 1
. 3
4
b
6
8
POSSI
UGM. /M-t-3
UGM
UGM.
UGM
UGM.
UGM.
UGM
UGM.
UGM.
UGM
UGM
UGM
UGM
UGM
UGM
BLE SEC
. /M-t-3
/M-t-3
. /M-t-
/M-t-3
/M-t-3
. /M-t-
/M-t-3
/M-t-3
. /M-t-
3
3
3
. /M-t-3
-7'1-t-
3
. /M-t-3
. /Mt
. /M-t-
3
T|
DIFUNCTIONALS
HCO(CH2)50H02+ISOMERS
EST 1.3 UGM. /M-t-3
102
-------
PAGE 003.
H C 0 C C H 2 "•' 4 OHO 2 + IS 0 M E R S
HOOC5COriHO 2+ISOMERS
HCOO:H2:>3r.O!JN02+ISOMERS
EST
EST
EST
EST
EST
0.
0.
0.
0.
0.
79
O«=j
35
41
••"» -i
iii
UGM.
UGM.
UGM.
UGM.
UGM.
/M-t-3
/M-t-3
••'M-t-3
/ M-t-3
/M1--3
CPD. F::LE 0057,
C6H602 ISOME:RS
C6HS02 ISOME:PS
C7H1002 ISOMERS
C5H803 I SO ME". PS
C5H604 ISOME:RS
C6H304 ISOME:RS
C7H7N04 ISOMERS
CPD. F::LE 0053,
C9H1402 ISOMERS
C10H1403 ISOMERS
C3H1404 •'PIN 1C ACID?:
CPD. F::LE 0053,
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM HI "RATE
SODIUM NITRATE
DATE OB2575, TENTATIVE! TOLUENE PRODUCT'S
EST 4. 3 UGM. /M-t-3
EST 5.2 UGM. .-'M-t-3
EST 2.0 UGM. /-M-t-3
EST 1 . 2 UGM. /M-t-3
EST 0. 13 UGM. /M-t-3
EST 0. 35 UGM. .-'M-t-3
EST 6. 633 UGM .-'Mt-3
DATE 082575, TENTATIVE": TERRENE PRODUCTS
EST 0. 65 UGM. /M-t-3
EST 0. 44 UGM. /M-t-3
EST 0. 12 UGM. /M-t-3
DATE 0825?c
ACID 4 63.
31.1
22.0
i, INORGANIC
UGM. /M-t-3
UGM. /M-t-3
UGM. /Mt-3
COMPOUNDS
1 O. 60 UGM. .--M-t3
CPD. F::LE 0050,
LINDANE
C5H5CL
DATE 082575, CHLORINATED COMPOUNDS
EST 0.14 UGM. /M-t-3
EST 0, 39 UGM. /M-t-3
103
-------
WEST COVIHA 1728 TO 1929 PD" 7/24/73.
TB8203RV 1 FILTER
FILE HO. 0Q01, FIT TOL. 083
-------
PAGE 082.
CPD. F::LE 0054. DATE 002575, CARBOXYL::C ACIDS
BEHZOIC ACT]) 2 0.13 UGM. /M-t-3
METHYL BENZOIC ISOMERS EST. 0.26 UGM . -•'M-t-3
ETHYL EEHZO::C ISOMERS EST. 0.092 UGM. /M-t-3
TRI METHYL BEINZOIC ISOM. EST 0.861 UGM /M-t-3
PENT AND I QIC ACID EST. 4.5 UGM./M-t3
HEXANDIOIC nCID 4
METHYLHEXAHUIOIC ACID 1
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC: ACID) EST
7. 6
3. 3
1. 3
2. 6
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t-3
CPD. F::LE 0055, DATE
CH2CN FRAGMEINT ('RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5H2 FRAGMENT fRELATIVE)
CH2HG3 FRAGMENT (RELATIVE*
C4HSH2 FRAGMENT (RELATIVE:.'
082575, NITROGEN COMPOUNDS
2. 6 UGM. /M-t-3
8. 4 UGM. /M-t-3
0. 70 UGM. .-'M-t-3
16 UGM. /M-t-3
15 UGM. .--M-t-3
C4H9N2 FRAGMENT (RELATIVE) 0.36 UGM..'M-t-3
P Y R I D I H E + P Y R I D Y L C P D S L 0 . 0 1 6 U G M ,-' M -t- 3
PI PER I DINES (+ISOMERS' EST 0.033 UGM. /M-t-3
CARBAZOLE L 0.041 UGM. /M-t-3
QU INCLINE (--INTERFER?-:' L 0.022 UGM /M-t-3
PYRIDINE SULFATE
CPD. F::LE 0055,
C8H503 (PHTHALATES)
C7H1403 ISOMERS
C7H1203 ISOMERS EST 0.73 UGM.
C6H1203 ISOMERS EST 0.30 UGM.
EST 0. 40 UGM. .'M-t-3
DATE 082575, POSSIBLE
7. 4 UGM. /M-t-3
EST 0. 36 UGM. /M-t-3
- M-t-3
'M-t-3
C5H304 (GLU'"ARIC ACID?) EST 6. 1 UGM. /M-t-3
C6H1003 ISOMERS
C7H1202 ISOMERS
C5H1003 ISOMERS
C5H1002 ISOMEP'3
HOOC(CH2)50N02
HOOC 4 0 N13 2 + I S 0 M E R S
HOOC(CH2)3COOM02
H C0(C H 2)5 C0 0H 0 2+1S0M E R S
EST 0. 67 UGM. /M-t-3
EST 0.15 UGM. /M-t-3
EST 0. 24 UGM. .'M-t-3
EST 0. IS UGM. /M-t-3
EST 0. 79 UGM. /M-t-3
EST 0. 30 UGM. .'M-t-3
EST 8. 39 UGM. /M-t-3
EST 0. 46 UGM. /M-t-3
EST 0. IS UGM. /M-t-3
EST 0. 83 UGM. /M-t-3
SEC. DIFUNCTIONALS
H C 0 ( C H 2 > 3 C 0 0 M 0 2 + I S 0 M E P. S E S T 0.1 2 U G M . .' M -t- 3
105
-------
PAGE 803.
HCOCCH2MCOONO
EST 0. 33 UGM. /Mt-3
CPD. F::LE 0057.
C6H602 ISOMfIRS
C6H802 ISQMEIRS
C7H10Q2 ISOMERS
C5H803 ISOME:RS
C6H804 ISOME:RS
C7H7H04 ISOMERS
NITROCRESOL8?
DATE 882575, TENTATIVE: TOLUENE PRODUCTS
EST 4. 5 UGM.
EST 2. 7 UGM. /M-r-3
EST 0. 46 UGM. .-'Mt-3
EST 0. 46 UGM. /
EST 0.15 UGM.
EST 6.015 UGM /M-t-3
L 0.018 UGM. /Mt-3
CPD. F::LE 0058,
C9H1402 ISOMERS
C10H1602 ISOMERS
C10H1403 ISOMERS
HATE 002575,
EST 0.33
EST 0. 12
EST 0.39
C10H1603 CP::HONIC AC ID?) EST 0.43
TENTATIVE:
UGM. /M-t-3
UGM. /fit3
UGM. .--M-t-3
UGM. ••'M-t-3
TERRENE PRODUCES
CPU. F::LE 0059,
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM HI"RATE
SODIUM NITRATE
CPD. F::LE 0060,
LIHDANE
C5H5CL CHEP"ACHLOR?>
DATE 092575, INORGANIC
ACID 4 37. UGM. /M-t-3
3 0. 90 UGM. /M-t-3
2 0. 98 UGM. .--M-t-3
1 0. 68 UGM. .--M-t-3
DATE 082575, CHLOPIHA"
EST 0. 096 UGM. /M-t-3
EST 0.61 UGM. .'M-t-3
COMPOUNDS
'ED COMPOUND;
106
-------
WEST COVIHA 1928 TO 2220 PD" 7/24/73
TB0204RV 1 FILTER
FILE HO. 9001, FIT TOL. 903 , SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANE-S
ALKAHES LOW MW
ALKAHES MED. MW
ALKAHES HI MW
TOTAL ALKEHEIS
CL 1. 6 UGM. /M-t-3
CL 0. 15 UGM. /M-t-3
CL 1.0 UGM. /M-t-3
CL 0. 36 UGM. /M-t-3
2. 2 UGM. /M-t-3
ALKENES LOW MW
ALKEHES MED. MW
ALKENES HI MU
ALPHA PIHENE:
TERPEHES AS PIHEME
CL 0.15 UGM. /M-t-3
CL 1.1 UGM. /M-t-3
CL 0. 99 UGM. /M-t-3
2. 0 UGM. /M-t-3
CL 0. 92 UGM. /M-t-3
X Y L E H E S, M 0 H S U E B E H Z E H E S C L 0.92 U G M . / M -t- 3
XYLENES, ETHYL BENZENE CL 9.16 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 2.4 UGM./Mt-3
ALKYL BEHZENES C10H14 CL 0.076 UGM. /M-t-3
BIPHEHYL 1 1.5 UGM. /M-t-3
DIP H E H Y L ETHANE & IS 0 M E R S L 0. 0 2 7 U G M . / M -t- 3
CPU. F::LE 0052, DATE 0532575,
NAPHTHALENE 1 0.
METHYL NAPH"HALENES+INT. L 0.
ALKYL NAPHTHALENES C12H12 L 0.
AHTHRACENE-F'HEHANTHP.EHE 2 0.
PYREHE & ISOMERS C16H10 L 0.
POLYCYCL::C
19 UGM. /M-t-3
035 UGM /M-t-3
013 UGM /M-t-3
0069 UGM. /M-t-3
017 UGM. /M-t-3
HYDROCARBOHS
BENZOPERYLENE+IHTERFER.
E 0. 052 UGM /M-t-3
CPD. F::LE 0053, DATE 0532575, AROMATIC
CRESOLS ''.BENZYL ALCOHOL? > CL 0.087 UGM /M-t-3
PHENOL + N02., CHO, C02H?
TRIMETHYLPHE:HOL+ISOMERS
DIHYDROXYBEHZENES
BENZOQUINONE:
NAPHTHOQUIHOHE?
BENZALDEHYDE-: < + I NTERF
PHENOL
EST
ES
EST
T
1
L
L
1
0.
0.
0.
0.
0
0.
0.
30
15
15
02
02
07
15
.-,
4
8
UGM.
UGM.
UGM.
UGM
UGM
UGM
UGM.
.--M-t-3
/Mt-3
.-- M-t-3
/M-t-3
. /M-t-3
/M-t-3
/ M-t-3
OXYGEHATED CPDS
CPD. F::LE 0054, DATE 002575, CARBOXYL::C
B E N Z 0 I C A C I n 20.10 U G M . / M -t- 3
M E T H Y LEE N Z 0 I C I S 0 M E R S EST. 0.04 0 U G M / M -t- 3
ACIDS
107
-------
PAGE 602.
ETHYL BEHZO::C ISOMERS EST. Q.
TRI METHYL BE-INZOIC I SOU. EST 9.
PENTANDIOIC ACID EST. 3.
HEXANDIOIC ACID 43.
METHYLHEXANDIOIC ACID 12.
026 UGM./Mt3
634 UGM./M-t 3
4 UGM. /M-t-3
1 UGM./M-t3
1 UGM./M-t3
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID)
EST
0. SB UGM. /M-t-3
1. 3 UGM. /M-t-3
CPD. F::LE 0055, DATE
CH2CN FRAGMENT tRELATIVE)
COHH FRAGMENT
-------
PAGE 993.
CPU.
SULFATES
HfinONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
HI"RATE
SODIUM HITRATE
DATE 682575, INORGANIC
ACID 4 23. UGM. /M-t-3
3 0. 54 UGM. /M-t-3
21.8 UGM. /M-t-3
1 0. 27 UGM. /M-t-3
COMPOUHDS
CPD, F::LE 0060, DATE 002575., CHLORIHA"ED COMPOUHDS
C5H5CL
-------
POMONA 2110 3/16/73 TO 8120 8/17/73 PDT
LAP 289 2UGM
FILE HO. 0901,
DATE 831075,
TOTAL SAt1PLE: =
BBA MPY 406
FIT TOL. 003 ( 11 1 LL I MASS > RUN 0061 TO RUN
ASS3 ERROR 10 CL
PHENOL+N02,CHO,COSH? EST.
TR I METHYLPHEINOL+ ISOMERS EST
DIHYDROXYBENZENES 1
BENZQQUINOHE: L
AROMATIC
0. 048 UGM /M-t-3
0. 10 UGM. /M-t-3
0. 037 UGM. /M-t-3
0. 021 UGM /M-t-3
0. 0095 UGM. /M-t-3
OXYGENATED CPDS
BENZALDEHYDE;
PHENOL
(+INTERF )
L
1
0.016
0. 655
UGM
UGM
/ M-t-3
/M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXVL::C ACIDS
BENZOIC ACID 2 0
ETHYL BENZO.iC ISOMERS EST. 0
TR I METHYL BEINZOIC ISOM. EST 6
PENTAHDIOIC ACID EST. 0
HEXANDIOIC HCID 4 1
75 UGM. /M-t-3
029 UGM /M-t-3
8074 UGM. /M-t-3
13 UGM. /M-t-3
6 UGM. /M-t-3
METHYLHEXANDIOIC ACID 1 0.
B E N Z0 Y L I 0 N (ARBITRARY> 1.
ACIDS (AS ACETIC ACID.> EST 0.
36 UGM. /M-i-3
7 UGM. ..-M-t-3
16 UGM. .-• M-t-3
110
-------
PAGE 862.
CPD. F"LE 0955, DATE 0S32575, NITROGEN COMPOUNDS
CH2CN FRAGMEINT (RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT
-------
POMONA 8129 8/17/73 TO 0629 3x17/73 PDT
LAP 290 --2 UG BBA 8220-0720
FILE NO. 0902, FIT TOL. 003 (MILL I MASS) RUN 0096 TO RUN 0130
DATE 031075, PASS3 ERROR 10 3
CL @. £3 UGM. /M-t-3
CL 8.16 UGM. /M-t-3
CL 0. 023 UGM. /M-t-3
8. 45 UGM. /Mt-3
CL 0. 068 UGM. /M-t-3
CL 0. 24 UGM. /M-t3
CL 0.12 UGM. /M-t-3
8. 32 UGM. /M-t-3
CL 0.18 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.17 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.037 UGM /M-t-3
ALKYL BENZENES C9H12 CL 0.55 UGM./M-t-3
ALKYL BENZENES C1QH14 CL 0.019 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.018 UGM /M-t-3
METHYL NAPH"HALEHES+INT. L 0.0860 UGM. /M-t-3
2 0. 0026 UGM. /M-t-3
L 8.010 UGM. /M-t-3
ANTHRACENE-PHENANTHRENE
PYRENE & ISOMERS C16H10
CPD. F::LE 0053, DATE 002575, AROMATIC
PHENOL + N02, CHO, C02H? EST. 6.038 UGM./M-t-3
DIHYDROXYBEUZENES 1 0.013 UGM./M-t-3
BENZALDEHYDE- C+INTERF.) L 0.012 UGM. /M-t-3
PHENOL 1 0.035 UGM./M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL:C ACIDS
OXYGENATED CPDS
BENZOIC ACID 2 8.
PENTAHDIOIC ACID EST. 0.
HEXAND I 01C ACID 4 0.
BENZOYL ION (ARBITRARY) 1.
ACIDS CAS ACETIC ACID> EST 0.
66 UGM. /M-t-3
33 UGM. /M-t-3
83 UGM. /M-t-3
5 UGM. /M-t-3
14 UGM. /M-t-3
CPD. F::LE 0055, DATE 002575,
NITROGEN COMPOUNDS
CONH FRAGMENT .:--IHTERFER0 ' L
PYRIDINE SULFATE EST
2. 1 UGM. /M-t-3
O. 14 UGM. .--M-t-3
0. 0049 UGM. /M-t-3
8. 05B UGM /M-t-3
112
-------
PAGE 802.
CPD. F::LE 0056, DATE 0:32575, POSSIBLE SEC. DIFUNCTION^LS
CSH503 '.:PHTHALATES> 2.2 UGM./M+S
CPD. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUCES
C6H602 ISOME:RS EST 0.16 UGM. .'M-t3
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERPENE PRODUCES
CPD. F:LE 0053, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 4.9 UGM . /M-t-3
AMMONIUM CHLORIDE 3 0.093 UGM /M-t-3
AMMONIUM N I "RATE 2 0.28 UGM . .'
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
C5H5CL
-------
POMONA 0729 3-'17/73 TO 9918 8/17/73 PDT
LAP 231 -- 2UG BBA 9720-^5)10
FILE HO. 8002, FIT TOL. 003 (MILLIMASS) RUN 0071 TO RUN 0103
DATE 031175, PASS3 ERROR 10 (MILLIMASS)
TOTAL SAMPLE[=0. 840E -1 CUB"C METERS, ALIQUOT = 0. 999E
INST. SENSI"IVITY=0. 800E +55
CHECK HEIGH" RAT 10 = 0. 500
-------
PAGE 082.
CPU. F::LE 8858, DATE 002575, TENTATIVE: TERRENE PRODUCTS
C10H1403 ISOMERS EST 0.23 UGM. .'(1*3
CPD. F::LE mess, DATE 0*32575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 5.8 UGM. -'M-t-3
AMMONIUM CHLORIDE 3 8.12 UGM..'M*3
AMMONIUM NT'RATE 2 0.42 UGM..'M-t-3
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
C5H5CL (HEP"ACHLOR?) EST 0.21 UGM..-'M-t-3
115
-------
POMONA 9918 8x17/73 TO 1110 8/17/73 PDT
LAP 292 .9/17/74 091 0-1:
FILE NO. 0002, FIT TOL. 003
DATE Q31175, PASS3 ERROR 10
TOTAL SAMPLE[ = 0. 870E -1 CUBi
INST. SENSI"IVITY=0. 800E + 1)
CHECK HEIGH" RATIO = 6. 500 < TRACT ION > , SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCAREJONS
10
RUN 0110 TO RUN 0144
O1ILLIMASS>
C METERS. ALIQUOT=©. 999E +0
TOTAL ALKANE-S
ALKANES LOU MU
ALKAHES MED. MW
TOTAL ALKENE-IS
ALKENES LOW MU
ALKENES MED. MU
ALKENES HI MW
ALPHA PINENE-
TERPEHES AS PINENE
CL 1. 0 UGM. /M-t-3
CL 8. 15 UGM. -'M-r-3
CL 0.55 UGM./M*3
1.2 UGM./M+3
CL 8. 067 UGM. /Mf-3
CL 9.62 UGM./M + 3
CL 0. 25 UGM. /Mt-3
0. 88 UGM. /M-t-3
CL 0. 37 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.39 UGM./M-t-3
XYLEHES, ETHYL BENZENE
ALKYL BENZENES C9H12
CL 0. 039 UGM. /M-t-3
CL 1. 2 UGM. /Mt-3
CPD. F::LE 0052, DATE 082575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.023 UGM. /M-t-3
METHYL NAPH"HALENES+IHT. L 0.013 UGM /Mt-3
CPD. F::LE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.052 UGM./M*3
PHENOL + N02, CHO, C02H? EST. 0.29 UGM.xMt-3
PHENOL 1 0.10 UGM./M-t3
CPD. F::LE 0054, DATE
BENZOIC ACID
PENTAHDIOIC ACID EST.
HEXAND I 01C ACID 4
BENZOYL ION (.'ARBITRARY?
ACIDS INTERFER?> L
PYRIDINE SUL.FATE EST
0. 83 UGM. .
0.073 UGM
0.029 UGM
0.610 UGM
•-M-t-3
/M-t-3
.--M-t-3
/ M-t-3
0. 096 UGM. /M-t-3
CPD. F::LE 0056,
C8H503 ''PHTHALATES:-'
C7H1202 ISOMERS
DATE 902575. POSSIBLE SEC. DIFUNCTI ONflLS
3. 5 UGH. /Mt-3
EST 0. 33 UGM. --71 + 3
116
-------
PAGE 002.
CPD. F::LE 0057, DATE 092575. TENTATIVE: TOLUENE PRODUCT'S
CSH802 ISOME:RS EST 0.30 UGH. .-'Mt-3
C5H803 ISQME-RS EST 0.17 UGM./M+3
CPD. F::LE ease, DATE 002575, TENTATIVE: TERPENE PRODUC"S
.CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES A3 SULFURIC ACID 4 7.5 UGM. xM-t-3
A M M 0 N I U M C H L. 0 RIDE 3 0.085 UGM. -* M -t 3
AMMONIUM NI "RATE 2 1.5 UGM . /M-t-3
CPD. F::LE a0se, DATE 002575, CHLORINA~ED COMPOUNDS
117
-------
POMONA 1110 8/17/73 TO 1310 8/17/73 PDT
LAP 293 --2 IJG BBA 1110-1310
FILE HO. 0092, FIT TOL. 003 (MILLIMASS) RUN 0145 TO RUN 01 SO
DATE Q31175, PASS3 ERROR 10 (MILLIMASS)
TOTAL SAMPLE: = 0. 870E -1 CUB"C METERS, ALIQUOT = 0. 999E +0
IHST. SENSI"IVITY = 0. 800E +55
CHECK HEIGH" RAT 10 = 0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARESONS
TOTAL ALKANEIS
ALKANES LOU MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 1. 1 UGM. /Mt-3
CL 0. 38 UGM. /M-t-3
CL 0. 43 UGM. /M-t-3
CL 0. 035 UGM. /M-t-3
1.2 UGM./M-t-3
ALKENES LOW MW
ALKEHES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERPEHES AS PINENE
CL 0. 19 UGM. /M-t-3
CL 0. 49 UGM. /M-t-3
CL 0. 35 UGM. /M-t-3
0. 85 UGM. /M-t-3
CL 0. 54 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.51 UGM. /Mt-3
XYLENES, ETHYL BENZENE CL 0.073 UGM /M-t-3
ALKYL BENZENES C9H12 CL 1.3 UGM. /M-t-3
ALKYL BENZENES C10H14 CL 0.851 UGM /M-t-3
CPD. F::LE 0052, DATE 082575, POLYCYCL::C HYDROCARBON;
NAPHTHALENE 1 0.085 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.018 UGM /M-t-3
EST. 0. 40 UGM. /M-t-3
1 0. 055 UGM. /M-t-3
L 0.022 UGM /M*3
1 0. 031 UGM. /M-t-3
PHENOL+H02,CHO,C02H?
DIHYDROXYBENZENES
BENZALDEHYDt: (+INTERF
PHENOL
CPD. F:LE 0054, DATE
BENZOIC ACID
METHYLHEXANDIOIC ACID
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID>
0B2575, CARBOXYL::C ACIDS
21.2 UGM. /M-t-3
1 1.7 UGM. /M-t-3
2. 8 UGM. /M-t-3
EST 0. 60 UGM. /M-t-3
CPD. F::LE 0055, DATE 902575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE':' 3.5 UGM./M + 3
C3H5N2 FRAGMENT (RELATIVE) 0.14 UGM. /M't-3
C4H8N2 FRAGMENT (RELATIVE) 0.15 UGM./M+3
QU INCLINE (--INTERFER?? L 0.015 UGM /Mt-3
CPD. F::LE 0056, DATE 002
C8H503 (PHTHALATES) 6
C6H1003 ISOMERS E
H C 0(C H 2)4 0N02 +IS0M E R S EST
75, POSSIBLE
. 7 UGM. /M-t-3
0. 55 UGM. /M-t-3
9. 34 UGM. /M-t-3
>EC. DIFUHCTIONALS
118
-------
PAGE Q02.
CPD. F::LE 0057,
C6H6Q2 ISOMEERS
C6H302 ISOMEIRS
C7H1002 ISOMERS
HITROCRE30LG?
CPD. F::LE 0053, DATE 082575, TENTATIVE: TERPENE PROHUC-S
CPD. F::LE 0059, HATE 0*32575, INORGANIC COMPOUNDS
DATE 0*32575, TENTATIVE: TOLUENE PRODUCES
EST 0.46 UGM..'M-t-3
EST 1.3 UGM. .••'M + 3
EST 0.69 UGM./M-t-3
L 0.014 UGM
SULFATES AS SULFUR 1C ACID 4
AMMONIUM CHLORIDE 3
AMMONIUM N I "RATE 2
SODIUM NITRflTE 1
13. UGM./ri-t-3
0.29 UGM./M-t-3
1.3 UGM./Mt-3
0.031 UGM xM + 3
CPU. F::LE 0050, DATE 002575, CHLORINA-ED COMPOUNDS
119
-------
POMONA 1319 8x17/73 TO 1519 8/17/73 PDT
LAP 234 --2 IJG BBA 1319-1 SI 6
FILE HO. 0002, FIT TOL. 003 (. MILL I MASS) RUN 0181 TO RUN 0215
DATE 031175, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLERS. 870E -1 CUBilC METERS, ALIQUOT = 6. 999E +0
IHST. SENSI"IVITY=0. 809E +S
CHECK HEIGH" RAT I 0 = 0. 500 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDPOCARESOHS
TOTAL ALKANEIS
ALKAHES LOW MW
ALKANES MED. MW
TOTAL ALKENE-S
ALKENES LOW MW
CL 0. 86 UGM. /Mt-3
CL 0. 39 UGM. /Mt-3
CL 0.16 UGM. /Mt-3
0. 79 UGM. /M-t-3
CL 9.14 UGM. /Mt-3
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERPENES AS PINENE
CL 0. 23 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
0. 48 UGM. /M-t-3
CL 0. 34 UGM. /M-t-3
XYLENES,MON SUB BENZENES CL 0.30 UGM./M+3
XYLENES, ETHYL
ALKYL BENZENES
ALKYL BENZENES
BENZENE
C9H12
C10H14
CL
CL
CL
0
050 UGM. /M-t-3
60 UGM. /M-t-3
12 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.021 UGM. /Mt-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPUS
CRESOLS (BENZYL ALCOHOL?)CL 8.653 UGM./M-t-3
PHENOL+H02,OHO,C02H?
DIHYDROXYBENZENES
BENZALDEHYDE: (+INTERF. >
EST. 0. 23 UGM. /M-t-3
1 0. 079 UGM. /Mt-3
L 0. 020 UGM /M-t-3
PHENOL
CPD. F::LE 0054, DATE
BENZOIC ACID
HEXANDIOIC RCID
METHYLHEXANDIOIC ACID
BENZOYL ION (ARBITRARY)
1 0. 023 UGM. /M-t-3
002575, CARBOXYL::C ACIDS
2 0. 94 UGM. /M-t-3
42.4 UGM. /M-t-3
1 0. 88 UGM. /Mt-3
2. 3 UGM. /Mt-3
ACIDS CAS ACETIC ACID;' EST 9. 52' UGM. .-'M-t-3
CPD. F::LE 0055, DATE
CH2CN FRAGMENT (RELATIVE)
CONH FRAGMENT (RELATIVE!:'
C3H5H2 FRAGMENT (RELATIVE)
C4H9N2 FRAGMENT (RELATIVE)
PIPERIDINES C+ISOMERS? EST
002575, NITROGEN
0. 18 UGM. /M-t-3
2.5 UGM. /M-t-3
0.17 UGM. /M-t-3
0.21 LI GM./ M-t-3
0. 034 UGM /Mt-3
COMPOUNDS
ACRID I HE £ ::SOMERS
L 0.014 UGM /M-t-3
120
-------
PAGE 082.
CPD. F::LE eess, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
C8H503 6.4 UGM./M+3
C6H1803 ISOMERS EST 8.24 UGM./M-t-3
HCO
-------
POMONA 1510 8/17/73 TO 171© 8/17/73 PDT
LAP 295 -- 2UG BEA 1510-1710
FILE HO. 0002, FIT TOL. 003 (MILLIMASS) RUN 6216 TO RUN 0250
DATE 831175, PAS33 ERROR 10 CM ILL I MASS)
TOTAL SAMPLED. 876E -1 CUBT.C METERS, ALIQUOT = 6. 999E + 0
INST. SENSI"IVITY=S. 300E + 5
CHECK HEIGH" RAT 10 = 0. 500 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARESONS
TOTAL ALKANE-:S
ALKANES LOW MW
ALKANES MED. MM
TOTAL ALKENEIS
ALKEHES LOW MW
CL 0. 63 UGM. /M-t-3
CL 9. 26 UGM. /M-t-3
CL 0. 24 UGM. /M-t-3
0. 85 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
ALKENES MED. MW
ALKEHES HI MW
ALPHA PINENE:
TERPENES AS PINENE
CL S. 36 UGM. /M-t-3
CL 9.16 UGM./M* 3
0.81 UGM. /M-t-3
CL 0. 44 UGM. /M-t-3
XYLENE3, MON SUE BENZENES CL 0.38 UGM. /M-t-3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
CL 0.10 UGM. .''M't-3
CL 0. 93 UGM. /M-t-3
CPD. F:LE 0052, DATE 082575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.025 UGM. /M-t-3
METHYL NAPH"HALENES+INT. L 0.018 UGM /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS CBENZYL ALCOHOL? )CL 0.025 UGM /M-t-3
0.11 UGM. /M-t-3
0.18 UGM. /M-t-3
0.013 UGM. /M-t-3
0. 049 UGM. /M-t-3
PHENOL+H02,CHO,C02H? EST.
TRIMETHYLPHENOL+ISOMERS EST
DIHYDROXYBENZENES 1
PHENOL 1
CPD. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
BENZOIC ACID 2
PENTANDIOIC ACID EST.
HEXANDIOIC ACID 4
METHYLHEXANDIOIC ACID 1
BENZOYL ION (ARBITRARY)
0. 92 UGM. /M-t-3
0. 32 UGM. /M-t-3
1. 4 UGM. /M't-3
0. 99 UGM. /M-t-3
2. 6 UGM. /M-t-3
ACIDS (AS ACETIC ACID:' EST 0.42 UGM. /M-t-3
CPD. F::LE 0055, DATE 082575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 4.6 UGM./M-t3
PIPERIDIHES ( + ISOMERS5 EST 0.011 UGM ,-M-t3
A C P I D I N E & ." S 0 M E R S L 0.015 U G M / M -t- 3
P Y R I D I N E S U L F A T E E S T O . 0 9 6 U G M / M -t- 3
CPD. F::LE 0056,
C8H503 (PHTHALATES)
DATE 682575, POSSIBLE SEC.
2. 9 UGM. /M-t-3
DIFUNCTIONRLS
122
-------
PAGE 802.
HCO
-------
POMOHA 1710 3x17x73 TO 1918 8/17/73 PDT
LAP 296 + 2 UG BBA 1710-19:.0
FILE HO. 8002, FIT TOL. 003 CM ILL I MASS) RUN 0251 TO RUN 0285
DATE Q31275, PASS3 ERROR 19 0. 128E +0 CUB"C METERS, ALIQUOT=0. 999E +Q
INST. SENSI"IVITY=0. 800E + 5
CHECK HEIGH" RATIO=0. 500 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 0*52575, HYDROCAREJONS
TOTAL ALKAHE:S
ALKANES LOW MW
ALKANES MED. MW
ALP-CANES HI MW
TOTAL ALKENEiS
CL 0.67 UGM./M*3
CL 0.15 UGM. /M-t3
CL 0. 40 UGM. /M*3
CL 0. 040 UGM. /M-t-3
0. 93 UGM. /M-t-3
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENEI
TERPENES AS PINENE
CL 0.052 UGM./M+3
CL 0.41 UGM. .-'M-t-3
CL 0.19 UGM. /M-t3
0. 95 UGM. /Mt-3
CL 0. 28 UGM. /M-t-3
XYLENES, MOM SUB BENZENES CL 0.37 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.088 UGM /M-t-3
ALKYL BENZENES C9H12 CL 1.1 UGM. /M-t-3
ALKYL BENZENES C1QH14 CL 0.099 UGM. /M-t-3
CPD. F::LE 0052, DATE 082575,
NAPHTHALENE 1 0.011
METHYL HAPH"HALEHES+INT. L 0.016
DIBENZANTHRACENES C22H14 E 0.021
POLYCYCL::C
UGM. /M-t-3
UGM. /M-t-3
UGM./M+3
HYDROCARBONS
CPD. F::LE 0053, DATE 092575,
CRESOLS f,BENZYL ALCOHOL?)CL
PHEHOL+N02,CHO,C02H? EST.
TRIMETHYLPHEIHOL+ISOMERS EST
DIHYDROXYBENZEHES 1
BENZOQUINONE L
AROMATIC
0. 033 UGM /M-t'3
0.16 UGM. /M-t-3
0 19 UGM. /M-t-3
0. 093 UGM. /M-t-3
0.014 UGM. /Mt-3
OXYGENATED CPUS
PHENOL
1 0. 055 UGM. /M-t-3
CPD. F:LE 0054, DA
BEHZOIC ACID
PENTAHDIOIC ACID
HEXANDIOIC ACID
METHYLHEXANI! I 0 I C ACID
BENZOYL ION CARBITRARY)
ACIDS CAS ACETIC ACID:'
TE 082575
E
2
ST.
4
1
EST
0.
1.
1.
1 .
1 .
0.
77
5
2
•-'
6
47
CARBOXYL::C
UGM
UGM.
UGM.
UGM.
UGM.
UGM
. /M-t-3
/M-t-
/M-t-
/M-t-
/ M -t-
..•• M
>i
3
•i
T
•_'
•t
•i
ACIDS
CPU. F::LE 0055. DATE 082575, NITROGEN
CONH FRAGMENT C RELATIVE) 1.5 UGM. /M-t-3
C3H5N2 FRAGMENT ^RELATIVE) 0.23 UGM. /M-t-3
COMPOUNDS
124
-------
PAGE 692.
PI PER I DINES <+ISQMERS) EST 0.611 UGM./M-T-3
CARBAZOLE L 0.018 UGM
CPU. F::LE 0056, SATE 0x2575, POSSIBLE SEC. BIFUNCTIONHLS
C8H503 2.7 UGM.xM-t-3
C7H1202 ISOHERS EST 8.49 UGM..'M*3
CPU. F::LE 0057, DATE 082575, TENTATIVE: TOLUENE PRODUCTS
CSH602 ISOMEERS EST 0.78 UGM./M-t-3
C6H302 ISOMEIRS EST 0.17 UGH. /M-t-3
C7H1002 ISOMERS EST 0.11 UGM. .'M*3
CPD. F::LE 0053, DATE 002575, TENTATIVE TERRENE PRODUCTS
CPU. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 5.9 UGM./f1 + 3
AMMONIUM CHLORIDE 3 0.032 UGM /M-t-3
AMMONIUM N I "RATE 2 0.11 U G M . / M -t- 3
CPD. F::LE 0050, DATE 002575, CHLORINA~ED COMPOUNDS
125
-------
POMONA 1319 8/17x73 TO 2209 8/17/73 PUT
LAP 297 + 2UGM BBA 1910-2209
FILE HO. 0901, FIT TOL. 093 < MILL I MASS) RUN 0131 TO RUN 01655
DATE 831975, PASS3 ERROR 19 L 0.013 UGM /M-t-3
PHEHOL 1 9.039 UGM /M-t-3
CPD. F:LE 0054, DATE 902575, CARBOXYL::C ACIDS
BENZOIC ACID
ETHYL BEHZO::C ISOMERS
PENTAHDIOIC ACID
HEXAHDIOIC ACID
BENZOYL ION (ARBITRARY)
2 9. 89 UGM. /M-t-3
EST. 0. 045 UGM /M-t-3
EST. 0. 74 UGM. /M-t-3
41.1 UGM. /Mt-3
1 . 9 UGM. /M-t-3
ACIDS (AS ACETIC: ACID) EST 9.39 UGM./M-t-3
CPD. F::LE 0055, DATE 082575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 4.1 UGM./M-t3
C 3 H 5 N 2 F R A G M E N T ( R E L A T IV E ) 0 . 9 9 3 'J G M / M -t- 3
PYRIDINE SULFATE EST 0.12 UGM. /M-t-3
CPU. F::LE oose, DATE 082575, POSSIBLE SEC. DIFUNCTIONAL:;
C8H503 CPHTHALATES) 2.1 UGM. /M-t-3
126
-------
PAGE 062.
C6H1803 ISOHERS EST 0.21 UGM. .'M-t-3
C7H1202 ISOMERS EST 0.11 UGM.
C5H1003 ISOMERS EST 0.10 UGM.
CPD. F::LE 0057, DATE 002575, TENTATIVE TOLUENE PRODUCES
C6H802 ISQME-IRS EST 0.65 UGM..'M*3
C7H1002 ISOMERS EST 0.17 UGM . .•"M*3
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERRENE PRODUCTS
CPU. F::LE 0055, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 7.7 U G M. / H-t-3
AMMONIUM CHLORIDE 3 0.27 UGM./M-t-3
AMMONIUM NI"RATE 2 1.0 UGM./Mt-3
CPD. F::LE 0060, DATE 032575, CHLORINA"ED COMPOUNDS
127
-------
BOMINGUEZ H::LLS 2200 10/4/7:5 TO 2200, 10/5x7;;
LAD 239 2200-2203 24 MRS
FILE HO. 0002, FIT TOL. 005 RUN 0586 TO RUN 0620
DATE 880875, PASS3 ERROR 10
-------
PAGE ©02.
C3H5N2 FRAGMENT 0.20 UGM./M+3
QUINOLIHE <--INTERFER?> L 0.031 UGM /M + 3
CPD. F::LE 0056, DATE 092575, POSSIBLE SEC.
C7H1204 EST 0.083 UGM./M-t-3
CPD. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 33. UGM. /M-t-3
AMMONIUM CHLORIDE 3 0.060 UGM /M-t-3
2 0. 60 UGM. /M-t-3
1 0. 29 UGM. /M-t-3
AMMONIUM NI"RATE
SODIUM NITRHTE
CPD. F::LE
LINDANE
C5H5CL
DATE 082575, CHLORINA"ED COMPOUNDS
EST 6. 44 UGM. /M-t-3
EST 0. 038 UGM. /M-t-3
129
-------
DOMINGUEZ H::LLS 1110 10/5/7;; TO 1310 10/5/7:;
LAD 244 DOMIGUES HILLS 2HF>
FILE NO. 00C12, FIT TOL. 003 (MILL I MASS) RUN 0286 TO RUN 0320
DATE Q31275, PASS3 ERROR 10
TOTAL SAMPLEI = 0. 860E -1 CU&'.'.C METERS, ALIQUOT = 0. 999E + Q
IHST. SENSI"IVITY=0. 850E + 5
CHECK HEIGH" RAT 10 = 0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARESONS
TOTAL ALKANEIS
ALKANES LOW MI..J
ALKANES MED. MW
TOTAL ALKENE:S
ALKENES LOW MW
CL 0. 63 UGM. /M-t-3
CL 0. 33 UGM. /M-t-3
CL 0. 28 UGM. /M-t-3
0. 69 UGM. /M-t-3
CL 0.072 UGM./M+3
ALKEHES MED. MW CL 0.29 UGM./M-t-3
ALKEHES HI MW CL 0.19 UGM. /M't-3
TERRENES AS PINENE CL 0.12 UGM./M+3
XYLENES,MON SUB BENZENES CL 0.20 UGM./M+3
XYLENES, ETHYL BENZENE CL 0.024 UGM. /M-t-3
ALKYL BENZENES C9H12
CL 0.15 UGM./M + 3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.039 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPUS
PHENOL + H02, CHO, C02H? EST. 0.34 UGM./M-t-3
DIHYDROXYBENZENES 1 0. 082 UGM /M-t-3
CPD. F::LE 0054, DATE 0025^5, CARBOXYL:C ACIDS
EENZOIC ACID 2
PENTAHDIOIC ACID EST.
HEXANDIOIC ACID 4
METHYLHEXANIHOIC ACID 1
BENZOYL ION ( ARBITRARY)
74 UGM. /M-t-3
30 UGM. /M-t-3
36 UGNi^.--M-t-3
37
0
0
0
0
1. 8 UGM. /M-t3
ACIDS
-------
PAGE 902.
CPD. F::LE 0053, DATE 082575, TENTATIVE; TERRENE PRODUCTS
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 10. UGM./M-t-3
AMMONIUM CHLORIDE 3 0. 20 UGM. .'M*3
2 1.1 UGM.xM-t-3
1 0.073 UGM. -'M-t-3
AMMONIUM NI"RATE
SODIUM NITRATE
CPD. F:LE 0060, DATE 0532575, CHLORINA"ED COMPOUNDS
C5H5CL EST 0.59 UGM. /M-t-3
1.31
-------
DOMINGUEZ H"LLS 1318 10/5/73 TO 1510 10/5/73
LAD 245 :. 212-1409
FILE HO. 0602, FIT TOL. 003
-------
PAGE 992.
GUI NOLI HE <--INTERFER?> L 0.011 UGM
PYRIDINE SUL.FATE EST 0.10 UGM./M*3
CPU. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
CQH503 3.4 UGM./M-t3
CPD. F:LE 0057, DATE 002575, TENTATIVE; TOLUENE PRODUCE'S
C6H602 ISOMEIRS EST 0.16 UGM..'M-t-3
C6H802 ISOMEIRS EST 0.25 UGM. .-'M-t-3
CPD. F::LE 0059, DATE 002575, TENTATIVE: TERRENE PRODUCES
CPD. F::LE 0053, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 8.3 UGM. /H-t-3
AMMONIUM CHLORIDE 3 0.10 UGM./M-t-3
AMMONIUM NI"RATE 2 0.43 UGfL/M-t-S
SODIUM NITRHTE 1 0.14 UGM.xM-t3
CPD. F:LE 0060, DATE 002575, CHLORINA"ED COMPOUNDS
133
-------
DENVER REGENCY 1339 6/11/73 TO 1200 7/11/73
DER 1 193 0 6x11x73 -1206
FILE HO. 6003, FIT TOL. 003 CM ILL I MASS) RUN 0456 TO RUN 0490
DATE 756820, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLE-=Q. 170E +2 CUBiiC METERS, ALIQUOT=0. 930E -1
INST. SENSI"IVITY=0. 550E +4
CHECK HEIGH" RATIO=0. 500 (TRACTION), SMOOTHED
CPU. F::LE 0051, DATE 082575.. HYDROCARBONS
TOTAL ALKANKS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE:S
CL 2. 6 UGM. /M-t-3
CL 0. 36 UGM. /M-t-3
CL 1. 0 UGM. /M-t3
CL 1.6 UGM./M + 3
3.1 UGM./M + 3
ALKENES LOU MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENEI
TERRENES AS PINENE
CL 0. 22 UGM. /M + 3
CL 1.3 UGM./M + 3
CL 1.5 UGM./M-t-3
2. 2 UGM. /M*3
CL 0. 97 UGM. /M-t-3
XYLEHES,MON SUB BENZENES CL 0.52 UGM. /M-t-3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 24 UGM. /M-t-3
CL 3. 7 UGM. /M-t-3
CL 0.16 UGM. /M-t-3
1 0.013 UGM. /M-t-3
DIPHEHYL ME"HANE+ISOMERS CL 8.610 UGM. /M-t-3
DIPHENYL ETHANE & ISOMERS L 0.066 UGM./Mf-3
CPD. F::LE 0052, DATE 082575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE
METHYL NAPH"HALENES+INT.
ALKYL NAPHTHALENES C12H12
PYRENE & ISOMERS C16H10
CHRYSENE, ISOMERS C18H12
PERYLENE, ISOMERS C20H12
BENZOPERYLENE+INTERFER.
DIBENZANTHRACENES C22H14
CPU. F::LE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
PHENOL + N02, CHO, C02H? EST. 0.061 UGM /M-t-3
TRIMETHYLPHEIHOL+I30MERS EST 0.036 UGM. .--M-t-3
CPD. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
0825
1 0.
L 0.
L 0.
L 0.
L 0.
L 0.
E 0.
E 0.
75,
030
098
020
083
054
048
16
065
POLYCYCL:
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t-3
UGM. /M*3
UGM. /M*3
UGM. /M-t3
UGM. /M-t-3
UGM. /M-t-3
C
BENZOIC ACID 2 0
METHYL BENZOIC: ISOMERS EST. 0
HEXANDIOIC RCID 4 1
BENZOYL ION (ARBITRARY) 0
ACIDS
-------
PAGE 902.
CPD. F::LE 0055, DATE
CONH FRAGMENT EST 0.32 UGM. /M-t-3
135
-------
DENVER REGENCY 1210 7x11/73 TO 0860 8/11x73
DER 2 165 » 7/11/73 -1630
FILE HO. 9003, FIT TOL. 005 CM ILL I MASS) RUN 0491 TO RUN 0525
DATE 750828, PASS3 ERROR 18 CM ILL I MASS)
TOTAL SAMPLE-=0. 190E +2 CUB"C METERS, ALIQUOT = 0. 930E -1
INST. SENSI"IVITY=0. 550E +4
CHECK HEIGH" RAT I 0=0. 500 CTRACT I ON), SMOOTHED
CPD. F::LE 0051, DATE 0*32575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 1. 5 UGM. xM-t-3
CL 0. 30 UGM. /M-t-3
CL 8. 52 UGM. XM-t-3
CL 8. 63 UGM. XM-t-3
1.9 UGM.XM+3
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERRENES AS PINENE
CL 0. 24 UGM. xM-t-3
CL 0. 69 UGM. xM-t-3
CL 1. 1 UGM.xM + 3
1. 1 UGM. XM-t-3
CL 0. 46 UGM. XM-t-3
XYLENES,MON SUB BENZENES CL 6.
XYLENES, ETHYL BENZENE CL 0.
ALKYL BENZENES C9H12 CL 2.
ALKYL BENZENES C16H14 CL 0.
DIPHEHYL ME"HANE+ISOMERS CL 0.
40 UGM. xMf-3
17 UGM. XM-t-3
6 UGM. xM-t-3
073 UGM xM-t-3
014 UGM. xM-t-3
CPD. F::LE 0052,
NAPHTHALENE
METHYL NAPH"HALENES+INT.
AHTHRACENE-PHENANTHRENE
PYRENE & ISOMERS C16H10
DIBEHZAHTHRACENES C22H14
CORONENE?
DATE 082575, POI.YCYCL'.iC HYDROCARBONS
1 0. 037 UGM. XM-t-3
L 0. 0094 UGM. xM-t-3
2 0. 0053 UGM. XM-t-3
L 0. 063 UGM. XM-t-3
E 0.016 UGM. xMt-3
E 0. 945 UGM. xM-t-3
CPD. F::LE 0053, DATE
DIHYDROXYBENZENES
BENZOQUINONE:
BENZALDEHYDE: C + INTERF. :>
PHENOL
082575,
1 0.019
L 0.017
L 0.011
1 0.020
AROMATIC
UGM. xM-t-3
UGM. xM-t-3
UGM xM-i-3
UGM xM-t-3
OXYGENATEH CPUS
CPD. F:LE 0054, DATE 082575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0.
METHYL BENZOIC ISOMERS EST. 0.
PENTANDIOIC ACID EST. 0.
HEXANDIOIC ACID 4 1.
BENZOYL ION CARBITRARY) 0.
018 UGM XM-t-3
065 UGM xM't-3
20 UGM. xn-t-3
2 UGM. xM-t-3
30 UGM. xM-t-3
ACIDS CAS ACETIC ACID:' EST 1.2 UGM.xM-t-3
136
-------
PAGE 00;
CPD. F::LE 0055,
CH2CN FRAGME:NT <:RELATIVE:.'
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT '.: RELAT IVE )
C4H9N2 FRAGMENT (RELATIVE)
PI PER I DINES C + ISOMER3J EST
DATE 002575, NITROGEN COMPOUNDS
0. 083 UGM /M-t-3
0. 86 UGM. /M-t-3
0. 38 UGM. /M-t3
0. 983 UGM /M-t-3
0.16 UGM. -• M-t-3
QUINOL INE <• •-1 HTERFER?
L 0.013 UGM /M-t-3
CPU. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
C8H503 (PHTHALATES) 2.0 UGM./M*3
C6H1004 < AD "PIC ACID) DUP 2.2 UGM. /M-t-3
C6H1203 ISOMERS EST 0.083 UGM /M-t-3
C6H1003 ISOMERS EST 0.093 U G M . / M -t- 3
C7H1202 ISOMERS EST 0.083 UGM
C5H1003 ISOMERS
HOOCOI:H2)40N02
EST 0.21 UGM. xM-t-3
EST 0. 083 UGM. /M-t-3
CPD. F::LE 0057, DATE 002575, TENTATIVE; TOLUENE PRODUCES
C6H602 ISOME:RS EST 0.16 UGM./M^S
C6H802 ISOMEIRS EST 0.27 UGM..''M-t3
CPD. F::LE 0058, DATE 002575, TENTATIVE: TERRENE PRODUCES
CPD
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
MIGRATE
SODIUM NITRHTE
DATE 002575, INORGANIC
ACID 4 18. UGM. .-"M-t-3
31.4 UGM. /M-t-3
2 9.0 UGM. ..•'M-t-3
1 6. 35 UGM. /M-t-3
COMPOUNDS
CPD. F::LE 0060,
LINDANE
C5H5CL
-------
DENVER REGENCY 0819 3/11/73 TO 1820 8.'11/73
DER 3 681 O 8/11/73 - 1820
FILE HO. 0903, FIT TOL. 965 (MILL I MASS) RUN 0526 TO RUN 0560
DATE 750820, PASS3 ERROR 16 (MILL I MASS)
TOTAL SAMPLEi>0. 164E +2 CUB::C METERS, ALIQUOT = 0. 190E +6
INST. SENSI"IVITV=0. 556E + 4
CHECK HEIGH" RAT 10 = 0. 500 CFRACTION), SMOOTHED
CPD. F::LE 0051, DATE 0*52575, HYDROCARESONS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 2. 3 UGM./M + 3
CL 8. 43 UGM. /M-t-3
CL 0. 97 UGM. /M-t-3
CL 1 . 0 UGM. /M-t-3
3. 8 UGM. /M-t-3
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINEHE-:
TERPEHES AS PIHENE
CL 0. 40 UGM. /M-t-3
CL 1 . 1 UGM. /M-t-3
CL 2. 1 UGM. /M-t-3
2. 8 UGM. /M-t-3
CL 0.91 UGM. /M-t-3
XYLENES, MON SUE BENZENES CL 0.63 UGM.
XYLENE3, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 39 UGM. /M-t-3
CL 4.3 UGM. /M-t-3
CL 0. 46 UGM. /M-t-3
1 0.011 UGM /M-t-3
DIPHEHYL ME~HAHE+ISOMERS CL 0.012 UGM./M-t-3
CPD. F::LE 0052, DATE 082575, POLYCYCL:
NAPHTHALENE 1 0.057 UGM. /M-t-3
METHYL NAPH"HALENES+INT. L 0.010 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.020 UGM. /M-t-3
ANTHRACENE-PHENAHTHRENE 2 0.8889 UGM. /M-t-3
PYRENE & I30MERS C16H10 L 0.064 UGM. /M-t-3
1C HYDROCARBONS
CHRYSEHE, I80MERS C18H12 L
BEHZOPERYLENE+INTERFER. E
DIBENZANTHRACENES C22H14 E
0. 832 UGM /M-t-3
0. 043 UGM. /M-t-3
0.10 UGM. /M-t-3
CPD. F::LE 0053, DATE 082575,
CRESOLS (BENZYL ALCOHOL?)CL 8.052
PHENOL+N02,CHO,C02H? EST. 0.
TRIMETHYLPHEINOL+ISOMERS EST 0.
DIHYDROXYBENZENES 1 0.
PHENOL 1
AROMATIC:
UGM / M-t-3
10 UGM. /M-t-3
039 UGM. /M-t-3
068 UGM. /M-t-3
OXYGENATED CPUS
8. 828 UGM /M-t-
CPD. F::LE
BENZOIC AC IH
PENTAHDIOIC ACID
HEXAND 10 1C ACID
8054, DATE 082575, CARBOXYLTC ACIDS
2 8. 833 UGM .--M-t-3
EST. 8. 98 UGM. /M-t-3
42.4 UGM. /M-t-3
METHYLHEXANIi 10 I C AC ID
1 1.1 UGM. /M-t3
138
-------
PAGE 002.
BENZOYL ION
-------
DENVER REGENCY 1840 8/11.-'73 TO 0810 9/ 11/73
DER 4 1S4 » 8/11/73 - 9810
FILE NO. 0903, FIT TOL. 905 (MILL I MASS) RUN 0141 TO RUN 01755
DATE 759822, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLEI = 0. 138E +2 CUB:C METERS, ALIGUQT=0. 198E +0
INST. SEHSI"IVITY=0. 415E +4
CHECK HEIGH" RAT 10 = 0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANEIS
ALKAHES LOU MW
ALKAHES MED. HI..J
ALKAHES HI MW
TOTAL ALKENES
CL 2. 4 UGM. /M-t-3
CL 0. 63 UGM. /M-t-3
CL 1.0 UGM. /M-t-3
CL 9. 44 UGM. /M-t-3
2. B UGM. /M-t-3
ALKEHES LOU MI..J
ALKEHES MED. MW
ALKENES HI riU
ALPHA PINENE:
TERRENES AS PINENE
CL 9. 54 UGM. /M-t-3
CL 1.3 UGM./M + 3
CL 0. 60 UGM. /M-t-3
1. 9 UGM. /M-t-3
CL 9. 65 UGM. /M-t-3
XYLENE3, MON SUB BENZENES CL 9.45 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 9.21 UGM./M+3
ALKYL BENZENES C9H12 CL 2.9 UGM. /M-t-3
ALKYL BENZENES C10H14 CL 0.33 UGM./M-t-3
DIPHEHYL ME"HANE+ISOMERS CL 0.017 UGM. /M-t-3
DIPHENYL ETHANE & ISOMERS L 9.950 UGM /M + 3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
1 9. 054 UGM. /M-t-3
L 0.10 UGM./M+3
NAPHTHALENE
METHYL NAPH"HALENES+IHT. L 0.
ALKYL NAPHTHALENES C12H12 L 0.945 UGM. /M-t-3
PYRENE & ISOMERS C16H10 L 0.064 UGM./M-t-3
CHRYSENE, ISOMERS C18H12 L 0.943 UGM. /M-t-3
PERYLENE, ISOMERS C20H12 L
BENZOPERYLENE+INTERFER. E
DIBENZANTHRHCENES C22H14 E
0. 924 UGM. /M-t-3
0. 049 UGM. /M-t3
0. 19 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC
CRESOLS < BENZYL ALCOHOL? )CL 0.0058 UGM..--M-t-3
TRiMETHYLPHE:NOL+ISOMERS EST 0.026 UGM. .--M-t-3
DI H Y D R 0 X Y B E N Z E N E S 10.079 U G M . / M -t- 3
BENZALDEHYDE: C+INTERF. > L 0.015 UGM /M-t-3
PHENOL 1 0.039 UGM..--M-t-3
OXYGENATEH CPUS
CPD. F::LE
BENZOIC ACID
METHYL BENZOIC ISOMERS
PENTANDIOIC ACID
HEXANDIOIC mi: ID
0954, HATE 082575, CARBOXYL"C
2 0. 092 UGM. /M-t-3
EST. 9. 021 UGM. /M-t-3
EST. 0. 82 UGM. / M-t-3
4 0. 49 UGM. -•- M-t-3
ACIDS
-------
PAGE 892.
METHYLHEXAND 101C ACID
BEHZOYL ION
-------
MONTBELLO 0950 3/11x73 TO 1950 8/11x73
DEM 1
FILE HO. 00»3, FIT TOL. 095 0. 960E +1 CUB"C METERS, ALIQUOT=0. 280E +0
INST. SENSI"IVITY=0. 550E +4
CHECK HEIGH" RAT 10 = 0. 500
PHENOL
1.013 UGM. xM + 3
082575,
L
T
1
L
1
0.
0.
0.
0.
0.
045
025
070
013
044
AROMATIC
UGM
UGM.
UGM.
UGM
UGM.
XM-t-3
XM-t-3
xMt-3
x M -t- 3
xM-t-3
OXYGENATED CPDS
CPD. F::LE 0054, HATE 082575,
CARBOXYL::C ACIDS
BENZOIC ACID 2
ETHYL BENZO::C ISOMERS EST.
PENTANDIOIC ACID EST.
HEXANDIOIC ACID 4
METHYLHEXAHDIOIC ACID 1
BENZOYL I OH (ARBITRARY)
ACIDS
-------
PAGE 802.
CPD. F::LE 0055, DATE 082575. NITROGEN COMPOUNDS
CH2CN FRAGMENT (RELATIVE) 0.061 UGM./M+3
COHH FRAGMENT (RELATIVE) 0.36 UGM./M+3
C3H5N2 FRAGMENT (RELATIVE) 0.083 UGM./M+3
C4H3N2 FRAGMENT (RELATIVE) 0.088 UGM./M+3
PIPERIDINES C+ISQMERS) EST 0.15 UGM./M+3
QUINCLINE <-INTERFER?>
i. 035 UGM /M + 3
DATE 982575, POSSIBLE SEC.
1. 9 UGM. /M + 3
DUP 1. 3 UGM. /M + 3
EST 0. 081 UGM. /M + 3
EST 0. 081 UGM. /M + 3
EST 0. 088 UGM. /M + 3
CPD. F:LE 0055,
C8H503 (PHTHALATES)
C6H1004
C6H1203 ISOMERS
C6H1003 ISOMERS
C5H1003 ISOMERS
C5H1602 ISOMERS
HOQC(CH2)40H02
HCO4COONO
EST 0.061 UGM.
CPD. F:LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUC-S
C6H602 ISOME:RS
C6H802 ISOMERS
C7H1002 ISOMERS
EST 0. 59 UGM. /M-t-3
EST 0. 39 UGM. /M-T-3
EST 0.21 UGM. .-'Mf-3
CPD. F::LE 0058, DATE 002575, TENTATIVE: TERPENE PRODUC"S
C9H1402 ISOHERS EST 0.081 UGM./M-t-3
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 8.3 UGM./M-t-S
AMMONIUM CHLORIDE 3 0.82 UGM./M+3
AMMONIUM NI"RATE 2 4.7 UGM. /M-t-3
SODIUM NITRHTE 1 0.039 UGM./M+3
CPD. F::LE eese, DATE 002575, CHLORINA"ED COMPOUNDS
C5H5CL EST 0.027 UGM./M+3
-------
MONTBELLO 2805 8/11/73 TO 0050 9/11x73
DEM 2 2005-0:350
FILE NO. 0902, FIT TOL. 005 EST 9.044 UGM /Mt-3
QU INCLINE C--INTERFER? J L 0.015 UGM /Mt-3
-------
PAGE 902.
CPD. F::LE 0056, DATE 082575, POSSIBLE SEC. DIFUHCTIONALS
C3H503 0.99 UGM. /M-t-3
CPD. F::LE 0057, DATE 0*32575, TENTATIVE: TOLUENE PRODUCES
C6H602 ISOME:RS EST 8. 13 UGM. /M-r3
.CPD. F::LE 0053, DATE 002575, TENTATIVE: TERPEHE PRODUC"S
CPD. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 0.68 UGM./M-t-3
AMMONIUM CHLORIDE 3 0.18 UGM./M-t-3
AMMONIUM NI"RATE 2 0.39 UGM. /M-t-3
SODIUM NITRATE 1 0.088 UGM. /M-t-3
CPD. F::LE 0060, DATE 082575, CHLORINA-ED COMPOUNDS
LINDANE EST 0.059 UGM .-'M-t-3
C5H5CL
-------
HCAR BOULDER 1800 6x11/73 TO 1640 7/11x73
DEN 1 189 0-1640 11 X06X73
FILE HO. 0002. FIT TOL. 003 O1 ILL I MASS) RUN 0316 TO RUN 0350
DATE 750820, PASS3 ERROR 10
-------
PAGE 082.
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUHCTIONHLS
C8H503 CPHTHALATES) 1.5 UGM.
C7H1202 ISOMERS EST 0.038 UGM
HCO5CQONQ2+ISOMERS EST 0.033 UGM./M*3
CPD. F:LE 0057, DATE 002575, TENTATIVE; TOLUENE PRODUC"S
C6H602 ISOMEIRS EST 0.23 UGM./M't-S
C6H802 ISOME-RS EST 0.23 UGM..'11*3
C7H1002 ISOMERS EST 0.054 UGM./M-t-3
C5H803 ISQME:RS EST 0.046 UGM./M-T-S
CPD. F.".LE.0058, DATE 002575, TENTATIVE TERPENE PRODUC"S
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 1.4 UGM. -T-l-tS
AMMONIUM CHLORIDE 3 0.18 UGM./M+3
AMMONIUM NI"RATE 2 4.4 UGM./M+3
SODIUM NITRATE 1 0.10 UGM.,'M + 3
CPD. FT.LE 0060, DATE 002575, CHLORINA"ED COMPOUNDS
C5H5CL EST 0.13
147
-------
NCAR BOULDER 1649 8/11x73 TO 0950 9/11/73
DEH 3
FILE HO.
9003. FIT TOL. 005 RUN 0386 TO RUN 0420
DATE 758820, PASS3 ERROR 10
TOTAL SAMPLED. 175E +2 CUB"C METERS, ALIQUOT = 0. 190E +0
INST. SENSI"IVITY=0. 550E +4
CHECK HEIGH" RATIO=0. 500 ^FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANE-S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE-S
ALKENES LOU MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERPENES AS PINENE
CL 0. 40 UGM. .'M-t-3
CL 0. 098 UGM. /M-t-3
CL 0.19 UGM. /M-t-3
CL 0. 043 UGM /M-t-3
0.51 UGM./M-t-3
CL 0.082 UGM /M-t-3
CL 0.£5 UGM./M-t-3
CL 0. 18 UGM. /M-t-3
0.51 UGM. /M-t-3
CL 0.14 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.12 UGM./M-t-3
XYLEHES, ETHYL BENZENE CL 0.015 UGM /M-t-3
ALKYL BENZENES C9H12 CL 0.65 UGM.."71 + 3
ALKYL BENZENES C10H14 CL 0.046 UGM. /M-t-3
BIPHENYL 1 0.0031 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.0096 UGM. /M-t-3
METHYL NAPH"HALENES+IHT. L 0.0060 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.022 UGM. /M-t-3
L 0.013 UGM. /Mt-3
L 0. 0077 UGM. /M-t-3
PYRENE & ISOMERS C16H10
PERYLENE, ISOMERS C20H12
BENZOPERYLEUE+INTERFER.
DIBENZANTHRACENES C22H14
E 0. 020 UGM. /M-t-3
E 0.012 UGM. /Mt-3
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
PHENOL + N02, CHO, C02H? EST. 0.044 UGM. /M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0.022 UGM. /M-t-3
PENTANDIOIC ACID EST. 0.22 UGM. -"M-t-3
BENZOYL ION < ARB I TRARY ) 0.13 UGM..-'M-t-3
ACIDS CAS ACETIC ACID.J EST 0.23 UGM. .-'M-t-3
CPD. F::LE 0055, DATE 002575,
CONH FRAGMENT
-------
PAGE 882.
CPD. F::LE 0055, BATE 002575, POSSIBLE SEC. DIFUNCTIOHALS
C8H503 1.5 UGM./M+3
C7H1203 ISOHERS EST 0.877 UGM /M + 3
HCO3COON02+ISOMERS EST 8.855 UGM./M+3
CPD. F::LE 0057,
C6H302 ISOMEiRS
DATE 002575, TENTATIVE; TOLUENE PRODUCE'S
EST 8. 88S UGM./'M*3
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERPENE PRODUC"S
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 4.4 UGM. /M + 3
AMMONIUM CHLORIDE 3 0.25 UGM.-'M-r3
AMMONIUM NI"RATE 2 2.0 UGM.
SODIUM NITRATE 1 8.043 UGM
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
C5H5CL
-------
WASHINGTON UNIV. 1739 9/05/73 TO 2336 CUT
SLW14F
FILE HO. 0901, FIT TOL. 003 (MILL I MASS) RUN 0102 TO RUM 0132
DATE 123073, PASS3 ERROR 26 < MILL I MASS)
702E +1 CUBiiC METERS, ALIQUOT=0. 100E +0
TOTAL SAMPLE- =0.
INST. SENSI"IVITY=0.
177E
CHECK HEIGH" RAT 1 0 = 0. 590 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANE:S
ALKANES LOU MW
ALKANES MED. MW
ALKAHES HI MW
TOTAL ALKENE-S
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE;
TERRENES AS PINENE
CL 1
UGM. /M-t-3
CL 0.10 UGM. /M-t-3
CL 0. 78 UGM. /M-t-3
CL 0. 23 UGM. /M-t-3
1.8 UGM./M + 3
CL 0. S54 UGM. /M-t-3
CL 0. 53 UGM. .-'M-t-3
CL 0. 64 UGM. /M-t-3
1. S UGM. /Mt-3
CL 0. 76 UGM. /M-t-3
XYLENES, MOH SUB BENZENES CL 9.61 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.13 UGM./M-t-3
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 2.7 UGM. /Mt-3
CL 0.14 UGM. /M-t-3
1. 8 UGM. /Mt-3
1
DIPHENYL ME~HANE+ISOMERS CL 0.023 UGM /M*3
DIPHEHYL ETHANE &. ISOMERS L 0.026 UGM./M-t-3
CPD. F::LE 0052, DATE 082575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.18 UGM. /M-t-3
METHYL NAPH"HALENES + INT. L 0.083 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.095 UGM /M-t-3
ANTHRACENE-PHENANTHRENE 2 0.022 UGM. /M-t-3
PYRENE & ISOMERS C16H18 L 0.066 UGM. /M-t-3
CHRYSENE, ISOMERS C18H12
PERYLENE, ISOMERS C20H12
BENZOPERYLENE+INTERFER.
CORONENE?
L 0. 0040 UGM. /M-t-3
L 0. 0040 UGM. /M-t-3
E 0. 027 UGM. /M-t-3
E 0. 054 UGM. /M-t-3
CPD. F::LE 0053, DATE 982575,
CRESOLS CL 9.967
PHENOL+N02,CHO,C02H? EST.
TRiMETHYLPHE:NOL+ISOMERS EST
DIHYDROXYBEHZENES 1
BENZOQUINONE: L
AROMATIC
UGM /M-t-3
0. 48 UGM. /M-t-3
0.17 UGM. /Mt-3
9. 10 UGM. /M-t-3
0.013 UGM. /M-t-3
NAPHTHOQUINONE? EST.
BEHZALDEHYDEI C + IHTERF ) L
PHENOL 1
9.9064 UGM. /M-t-3
0.047 UGM /M-t-3
0.084 UGM /M-t-3
OXYGENATED CPDS
150
-------
PAGE 902.
CPU. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
BEHZOIC ACID 2 0.
METHYL BENZOIC ISOMER3 EST. 0.
ETHYL BEHZO::C ISOMERS EST. 0.
TRIMETHYL BEIHZOIC ISOM. EST 8.
PENTAHDIOIC ACID EST. 1.
13 UGM. /M-t-3
083 UGM. /M-t-3
040 UGM /M-t-3
0034 UGM. /M-t-3
2 UGM. /M-t-3
HEXANDIOIC ACID 4 0.77 IJGM./M + 3
METHYLHEXANttlOIC ACID 1 0.86 UGM. /M-t-3
BEHZOYL ION (ARBITRARY) 0.62 UGM. /M-t-3
ACIDS -CAS ACETIC ACID; EST 8.52 UGM./M + 3
CPD. F::LE 0055, DATE
CH2CH FRAGMENT (RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
C4HSN2 FRAGMENT (RELATIVE)
C4H9N2 FRAGMENT (RELATIVE)
882575, NITROGEN COMPOUNDS
8.91 UGM. .--M-t-3
2. 2 UGM. /M-t-3
0.16 UGM. /M-t-3
0. 25 UGM. /M-t-3
0. 032 UGM /M-t-3
PYRIDINE + F:'YRIDYL CPDS
PI PER I DINES ( +ISOMERSJ
CARBAZOLE
ACRID I HE & "SOWERS
PIPERAZINE?
NITROHAPHTHALENE
L 9. 0032 UGM. /M-t-3
EST 0. 12 UGM. /M-t-3
L 0. 026 UGM. /M-t-3
L 8. 8035 UGM. /M-t-3
EST 0. 0040 UGM. /M-t-3
EST 0. 0836 UGM. /M-t-3
CPD. F::LE 0055, DATE
C8H503 (PHTHALATES)
C7H1403 ISOHERS
C6H1004 (AD::PIC ACID)
C7H1203 ISOMERS
C6H1203 ISOMERS
082575., POSSIBLE
25. UGM./M*3
EST 0. 031 UGM /M-t-3
DUP 1. 4 UGM. /M-t-3
EST 0. 065 UGM /M-t-3
EST 0.21 UGM. /Mt-3
C5H804
-------
PAGE 003.
HCQ4COONO EST 0.10 UGM./M-t-3
CPD. F::LE 0057, DATE 082575, TENTATIVE: TOLUENE PRODUC-S
C6H602 ISOMF.RS EST 0.91 UGM. /M-t-3
C6H802 ISOMEIRS EST 0.60 UGM./
C7H1002 ISOMERS EST 0.30 UGM.
C5H803 ISOMEIRS EST 0.065 UGM.
C5H604 ISOMEIRS EST 0.032 UGM. /M-t-3
C6H804 ISOMEIRS
C7H7H04 ISOMERS
EST 0.11 UGM. /M-t-3
EST 0. 0040 UGM. /M-t-3
CPD. F::LE 0053,
C9H1402 ISOMERS
C10H1403 ISOMERS
DATE 082575. TENTATIVE! TERPENE PRODUCT'S
EST 0. 897 UGM /M-t-3
EST 0. 056 UGM /M-t-3
CPU. F::LE 0053, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 7.7 UGM. /M-t-3
AMMONIUM CHLORIDE 3 0.75 UGM. /M-t-3
AMMONIUM NI "RATE 2 1.3 UGM. /M-t-3
SODIUM NITRATE 1 0.42 UGM. /M-t-3
CPD. F::LE 0068, DATE 032575, CHI.ORINA~ED COMPOUNDS
C5H5CL EST 0.075 UGM./M-t-3
152
-------
WASHINGTON UNIV. 0025 9x06x73 TO 6715 CDT
SLW15F
FILE NO. 0901* FIT TOL. 003 CM ILL I MASS) RUN 8966 TO RUN 619:
DATE 123973, PASS3 ERROR 26 CHILLI MASS)
TOTAL SAMPLE:. = 0. 820E +1 CUB"C METERS, AHQUOT = 0. 100E +0
INST. SENSI"IVITY=0. 177E +5
CHECK HEIGH" RAT 10 = 9. 500 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANE:S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 0. 56 UGM. /M-t-3
CL 0. 029 UGM. /M-t-3
CL 0. 14 UGM. /M-t-3
CL 0.17 UGM. /M-t-3
0. 57 UGM. /M-t-3
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI t1W
ALPHA PINENE
TERPEHES AS PINENE
CL 0. 925 UGM. /M-t-3
CL 0. 23 UGM. /M-t-3
CL 0. 33 UGM. /M-t-3
0. 96 UGM. /M-t-3
CL 0. 45 UGM. /M-t-3
V. Y L E N E S, M 0 H S U B B E N Z E H E S C L 0.37 U G M . / M -t- 3
XYLENES, ETHYL BENZENE CL 0.10 UGM./M-t-3
ALKYL BENZENES C9H12 CL 1. 2 UGM./Mt-3
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 086 UGM. /M-t-3
1 0. 20 UGM. /M-t-3
DIPHEHYL ME"HANE+ISOMERS CL 0.0095 UGM./M-t-3
DIPHEHYL ETHANE & ISOMERS L 0.013 UGM. /M-t-3
CPD. F::LE 0052, DATE 082575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.080 UGM /M-t-3
METHYL NAPH"HALEHES+INT. L 0.040 UGM /M-t3
ALKYL NAPHTHALENES C12H12 L 0.012 UGM /M-t-3
ANTHRACENE-PHENANTHREHE 2 0.0092 UGM./M-t3
PYRENE & ISOMERS C16H10 L 0.029 UGM /M-t-3
CHRYSENE, ISOMERS C19H12 L 0.0092 UGM. /M-t-3
PERYLENE, ISOMERS C20H12 L 0.0027 UGM./M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS CBENZYL ALCOHOL?>CL 0.031 UGM. /M-t-3
PHENOL + N02, CHO,C02H? EST. 0.61 UGM. /M-t-3
TRIMETHYLPHEINOL + ISOMERS EST 0.080 UGM. /M-t-3
DIH Y D R 0 X Y BENZENES 1 0 . 0 6 9 U G M . / M -t- 3
B E N Z 0 Q UIN 0 N El L 0 . 0 0 7 5 U G M. / M -t- 3
BEHZALDEHYDE: OINTERF >
PHENOL
L 0.016 UGM /M-t-3
1 0. 072 UGM /M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0.11 UGM./M*3
153
-------
PAGE 082.
METHYL BEHZOIC ISOMERS EST.
ETHYL EENZO::C ISOMERS EST.
TRI METHYL EEENZOIC ISOM. EST
PENTAUDIO 1C ACID EST.
HEXANDIOIC ACID 4
0. 037 UGH. /M-t-3
0.019 UGM. /Mt-3
0.011 UGM /M-t3
0. 83 UCM. /M-t-3
0. 73 UGM. /M + 3
METHYLHEXANHIQIC ACID 1 9.49 UGM./Mt-3
BENZOYL ION < ARBITRARY) 8.49 UGM. /M-t-3
ACIDS
-------
PAGE 883.
C6HQ04 ISOME:RS
EST 8. 034 UGM.
CPD. F::LE eess, DATE 002575, TENTATIVE:
C9H1402 ISOMERS EST 0.848 UGM /Mt-3
C10H1602 I50MERS EST 0.876 UGM xn-T-3
C10H1603
HATE 0B2575.. INORGANIC COMPOUNDS
ACID 4 5.1 UGM. xM-t-3
3 0. 24 UGM. /Mt-3
2 0. 42 UGM. .'M^3
1 0.41 UGM. xM-t-3
DATE 082575, CHLORIHA"ED COMPOUNDS
EST 0.617 UGM /Mt-3
EST 0. 027 UGM /Mt-3
155
-------
WASHINGTON UNIV. 0755 9/Q6/~,'3 TO 1215 CDT
SLW16F
FILE NO. 0001, FIT TOL. 003 < MILLI MASS > RUN 0030 TO RUN 00S55
DATE 123073, PASS3 ERROR 26
-------
PAGE 802.
CPD. F:LE 0054, DATE 0
BENZOIC ACID 2
METHYL BENZOIC ISOMERS EST.
ETHYL BENZO::C ISOMERS EST.
TRIMETHYL BMNZOIC ISOM. EST
PENTAHDIOIC ACID EST.
HEXAHDIOIC ACID 4
METHYLHEXANMOIC ACID 1
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID* EST
CARBOXYL::C ACIDS
8.16 UGM. /M-t-3
0. 059 UGM /M-t-3
0. 031 UGM. .-TH3
0.031 UGM./M-t-3
0. 86 UGM. /M-t-3
1.9 UGM./M+3
0. 48 UGM. /M-t-3
0. 80 UGM. /M-t-3
0. 73 UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMENT (RELATIVE) 1.2 UGM. /M-t-3
3. 1 UGM./M*3
0. 59 UGM. /M-t-3
0. ©87 UGM /M-t-3
0.13 UGM. /M-t-3
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
C4H8H2 FRAGMENT (RELATIVE)
C4H9N2 FRAGMENT (RELATIVE)
PYRIDINE + PVR IDYL CPUS
PI PER IDINES ( + ISOMERS J
CARBAZOLE
ACRIDINE & :: SOMERS-
ET INCLINE (--INTERFER?)
PIPERAZINE?
PYRIDINE SULFATE
L 0.014 UGM. /M-t-3
EST 0. 028 UGM /M-t-3
L @. 025 UGM /M-t-3
L 0. 0047 UGM. /M-t-3
L 0. 0097 UGM. /M-t-3
EST 0. 8043 UGM. /M-t-3
EST 0. 043 UGM /M-t-3
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC.
C7H1204 (ME"HYL ADIPIC) DUP ©.87 UGM./M+3
C8H503 (PHTHALATES) 34. UGM./M-t-3
C7H1403 ISOMERS EST 0.054 UGM /M-t-3
C6H1004
-------
PAGE 003.
HCCXCH2MQN02+ISOMERS EST 0.087 UGM.'M*3
HCQ5COON02+ISOMERS EST 0.09S UGM.xM.t3
HCQEST 0.098 UGM
TERPENE PRODUC"S
CPU. F::LE 0059,
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM NI"RATE
SODIUM NITRATE
DATE
ACID
982575, INORGANIC
4 15. UGM. /M+3
3 0. 77 UGM. xM'T-S
21.0 UGM. xM-t-3
1 0. 76 UGM. /Mt-3
COMPOUND;:
CPD. F::LE 0060, DATE 002575, CHLORINA~ED COMPOUNDS
C5H5CL CHEP"ACHLOR?) EST 8.29 UGM..'M*3
158
-------
WASHINGTON UNIV. 1249 9/86/73 TO 1625 CDT
SLW17F
FILE NO. 8001.. FIT TOL. 003 RUN 0801 TO RUN 0036
DATE 123073, PASS3 ERROR 26
TOTAL SAMPLE_r = 0. 416E +1 CUBiiC METERS, ALIQUOT = 0. 100E +0
INST. SENSI"IVITY=0. 237E +S
CHECK HEIGH" RATIO=0. 509 , SMOOTHED
CPD. F::LE 0051, DATE 0^2575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE:S
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI f1W
ALPHA PINEHE-
TERRENES AS PINEHE
CL @. 99 UGM. /M-t-3
CL 0.13 UGM. /M + 3
CL 0. 47 UGM. /M-t-3
CL 0.13 UGM. /M-t-3
1. 1 UGM. /Mf-3
CL 0.13 UGM. /M +3
CL 0. 52 UGM. /M-t-3
CL 9. 46 UGM. /M-t-3
1. 4 UGM. /M-r-3
CL 6. 64 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.65 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.21 UGM./M-t-3
ALKYL BENZENES C9H12 CL
ALKYL BENZENES C10H14 CL
2 UGM. /M-t-3
17 UGM, /M-t-3
BIPHEHYL
1 2.4 UGM.
DIPHENYL ME"HANE+ISOMERS CL 0.051 UGM./M-t-3
DIPHENYL ETHANE & ISOMERS L 8.011 UGM./Mt-3
CPD. F:LE 0052, DATE 0*52575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.25 UGM./M-t-3
METHYL NAPH"HALENES+INT. L 0.085 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 0.083 UGM./M-t-3
2 0.017 UGM. /M-t-3
L 0.012 UGM /M*3
ANTHRACENE-PHEHAHTHRENE
PYRENE & ISOMERS C16H10
CHRYSENE, ISOMERS C18H12 L 0.0068 UGM. /M-t-3
CPD. F::LE 0053, DATE 0532575, AROMATIC OXYGENATED CPUS
CRESOLS (BENZYL ALCOHOL?)CL 0.063 UGM /M-t-3
PHENOL+N02,CHO,COSH? EST. 0.
TRiMETHYLPHE:NOL+ISOMERS EST 0.
DIHYDROXYBEHZENES 1 0.
BENZOQUIHONE: L 0.
69 UGM./M+3
11 UGM./M-t-3
12 UGM. .--M-t-3
011 UGM. /Mi-3
BENZALDEHYDE:
PHENOL
>INTERF. > L 0.015 UGM /Mi-3
1 0.10 UGM. /M-t-3
CPD. F::LE
BENZOIC ACID
METHYL BENZOIC
0054, DATE 082575, CARBOXYL"C ACIDS
2 0.14 UGM. /M-t-3
ISOMERS EST. 0.036 UGM /M-t-3
159
-------
PAGE 092.
ETHYL BENZO:C ISOMERS EST. 0
TRIMETHYL BEINZOIC ISOM. EST 0
PEHTAHDIOIC ACID EST. 1
HEXANDIOIC ACID 4 1
METHYLHEXANDIOIC ACID 11
081 UGM./f1't-3
055 UGM.
0 UGM. /-Mt-3
0 UGM. /M + 3
1 UGM./M+3
BEH20YL ION (ARBITRARY) 0.68 UGM./Mt-S
ACIDS CAS ACETIC ACID) EST 0.54 UGM./M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMEINT (RELATIVES
CONH FRAGMENT
-------
PAGE @03.
CPU. F::LE 0057,
C6H602 ISOME:RS
C6H802 ISOME:RS
C7H1002 ISOMERS
C5H803 ISOME-IRS
C5H604 ISOMEIRS
C7H7H04 ISOHERS
HITROCRESOLS?
DATE 802575, TENTATIVE: TOLUENE PRODUCES
EST 1. 0 UGM. /M-t-3
EST 0. 19 UGH. /M-t-3
EST 0.13 UGM. /M-t-3
EST 0. 46 UGM. .-71-1-3
EST 0. 061 UGM. /M-r3
EST 0. 0041 UGM. /M-t-3
L 0. 0051 UGM. .-'M-t-3
CPD. F::LE 0059, DATE 002575, TENTATIVE: TERPEHE PRODUCES
C9H1402 ISOriERS EST 0.10 UGM./M-t-3
C10H1602 ISOMERS EST 0.040 UGM./M+3
C8H1204 CNOF5PINIC ACID?>EST 0.051 UGM.xM-t-3
CPU. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 13. UGM. /M-t-3
AMMONIUM CHLORIDE 3 0.35 UGM./Mt-3
AMMONIUM NI "RATE 2 0.90 UGM. /M-t-3
SODIUM HITRnTE 1 0.64 UGM. /M-t-3
CPD. F::LE 0060, DATE 002575, CHLORIHA"ED COMPOUNDS
C5H5CL CHEP"ACHLOR?> EST 0.097 UGM /t'>3
161
-------
WASHINGTON UNIV. 1645 9/06/73 TO 2305 CDT
SI_yi8F
FILE HO. 9001, FIT TOL. 003 CMILL IMASS) RUN 0001 TO RUN 0029
DATE 123073, PASS3 ERROR 26 CM ILL I MASS>
TOTAL SAMPLE[ = 0. 760E +1 CUB"C METERS, ALIQUOT = 6. 100E +0
INST. SENSI"IVITY = 0. 177E +1)
CHECK HEIGH" RATIO = 0. 500 CL 6. 076
PHENOL+N02,CHO.C02H? EST.
TRiMETHYLPHE:NOL+ISOMERS EST
DIH Y D R 0M YBENZENES 1
BENZOQUINONE-: L
AROMATIC
UGM /M-t-3
81 UGM. .--M-t3
087 UGM /M-t-3
13 UGM. /M-t-3
0. 016 UGM /M-t-3
OXYGENATETJ CPDS
NAPHTHOQUINOi-IE? EST.
BENZALDEHYDE; OINTERF ;• L
PHENOL i
0. 0059 UGM. /M-t;
0. 061 UGM /M-t-3
0.10 UGM./Mt3
162
-------
PAGE @02.
CPD. F::LE 0054, DATE 092575, CARBOXYL::C ACIDS
BEHZOIC ACID 2 0.13 UGM. /M+3
METHYL BEHZOIC ISOMERS EST. 0.044 UGM /M + 3
ETHYL BENZO'.'.C ISOMERS EST. 0.064 UGM. /M+3
TRIMETHYL BE-INZOIC ISOM. EST 0.070 UGM. /M+3
PENTANDIOIC ACID EST. 0.86 UGM. /M+3
HEXANDIOIC HCID 4
METHYLHEHANDIOIC ACID 1
BEHZOYL I OH (ARBITRARY)
ACIDS CAS ACETIC ACID.:- EST
1.2 UGM./M + 3
0. 89 UGM. /M + 3
©. 66 UGM. /M + 3
0.71 UGM. /M + 3
CPU. F::LE 0055, DATE
CH2CH FRAGMENT (RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5H2 FRAGMENT (RELATIVE)
CH2H03 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
982575, NITROGEN
0. 38 UGM. /M + 3
1. 6 UGM. /M + 3
0. 27 UGM. /M + 3
0.014 UGM /M + 3
6.15 UGM. .'M + 3
COMPOUNDS
C4H9N2 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPUS L
PI PER I DINES ( +ISOMERSJ EST
CARBAZOLE L
QUINCLINE (-IHTEF.FER? > L
NITRONAPHTHRLEHE
PYRIDINE SUL.FATE
0. 075 UGM /M + 3
0. 6029 UGM. /M-t-3
0. 0059 UGM. .--M-t-3
0.010 UGM. /M-t-3
0. 0044 UGM. /M-t-3
EST 0. 0645 UGM. /M-t-3
EST 0. 0099 UGM. /M-t-3
CPD. F::LE eose, DATE 002575, POSSIBLE SEC. DIFUHCTIONHLS
C7H1204 (ME"HYL ttDIPIC) DUP 8.74 UGM./M+3
C8H503 (PHTHALATES) 15. UGM./M+3
C7H1403 ISOMERS EST 0.10 UGM./M+3
C6H1004 (AD::PIC ACID) DUP 5.0 UGM./M+S
C7H1203 ISOMERS EST 0.10 UGM./M+3
C6H1203 ISOMERS EST 0.
C5H804 (GLU"ARIC ACID?) EST 1.
C6H1803 ISOMERS EST 0.
C7H1202 ISOMERS EST 0.
C5H1003 ISOMERS EST 0.
14 UGM./M+3
6 UGM./M+3
35 UGM./M+3
21 UGM./M+3
20 UGM./M+3
C6H1202 ISOMERS
C5H1B02 ISOMERS
HOOC(CH2)50H02
HOOC(CH2)40N02
HCOCCH2)6 0 N0 2 +1S 0ME R S
EST 0.037 UGM /M+3
EST 0.11 UGM./M+3
EST 0.075 UGM /M+3
EST 0.14 UGM./M+3
EST 0.037 UGM /M+3
163
-------
PAGE Q03.
HCO C CH2 >50N02+ISONERS
HCO >', CH2 ::< 40N02+1SOMERS
HCO < CH2 :> 5COON02+ I SOMERS
H C 0 < C H 2 ::• 4 C 0 0 H 02+1 S 0 M EPS
HCO < CH2 > 3COOH02+ISOMERS
HCCKCH2MCOONO
EST 0.059 UGM./M-t-3
EST 0. 067 UGM. /M-t-3
EST 0.19 UGM. /M-t-3 '
EST 0. 059 UGM. /M-t>3
EST 0.10 UGM. /M-t-3
EST 0. 029 UGM. /M-t-3
CPU. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUCES
CSH6Q2 ISOMEIRS
C6H802 ISOME-:RS
C7H1802 ISOHERS
C5H803 ISOME:RS
C5H604 ISOMEIRS
C6H804 ISOMEIRS
NITROCRESOLS?
CPD. F::LE 0053,
C3H1402 ISOHERS
C10H1602 ISOMERS
C16H1403 ISOMERS
C10H1603 CP::NONIC
C8H1204 CHOFJPIHIC
EST 1 . 1 UGM. /M-t-3
EST 0. 70 UGM. .'M-t-3
EST 0. 48 UGM. xM-t-3
EST 0. 059 UGM. xM + 3
EST 0. 089 UGM. /M-t-3
EST 0. 059 UGM. /M-t-3
L 0. 0074 UGM. /M-t-3
DATE 082575, TENTATIVE!
EST 0. 029 UGM. /M-t-3
EST 0. 022 UGM. /M-t-3
EST 0.11 UGM. /M-t-3
ACID?>EST 0.029 UGM /Mt-3
ACID?)EST 0.022 UGM /M-t-3
TERRENE PRODUCT'S
C9H1404 CPI NIC ACID?)
EST 0. 059 UGM. /M-t-3
CPD. F::LE 0059, DATE
SULFATES AS SULFUR 1C ACID
AMMONIUM CHLORIDE
AMMONIUM HI ""RATE
SODIUM NITRATE
082575, INORGANIC COMPOUNDS
43.6 UGM. /M-t-3
3 0. 53 UGM. .'M-t-3
2 0. 56 UGM. /M-t-3
1 0.41 UGM. /M-t-3
CPD. F::LE 0060,
DDT, 3DD
C5H5CL CHEP""ACHLOR?)
DATE 082575, CHLORINATED COMPOUNDS
EST 0.011 UGM /M-t-3
EST 0. 22 UGM. /M-t-3
164
-------
WASHINGTON UNIV. 2340 9/86/73 TO 8848 CDT
SLW19F
FILE NO. 0001, FIT TOL1. 603
TOTAL SAMPLE->8. 108E +2 CUBiiC METERS, ALIQUOT = 0 100E +0
INST. SENSI"IVITY = 8. 177E +Ji
CHECK HEIGH" RAT 10 = 8. 500 L 0.033 UGM /M-t-3
PHENOL 1 0.071 UGM. /M-t-3
165
-------
PAGE 802.
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2 6.074 UGM. /M-t-3
METHYL BENZOIC ISOMERS EST. 0.930 UGM /M-t-3
ETHYL BENZO"C ISOMERS EST. 0.033 UGM./M-t-3
TRIMETHYL BEINZOIC ISOM. EST 0.013 UGM./M*3
PENTAHDIOIC ACID EST. 0.62 UGM./M-t-3
HEXANDIOIC ACID 4 S.96 UGM./M-t-3
METHYLHEKANMOIC ACID 1 0.55 UGM. /M-t-3
BENZOYL ION (ARBITRARY) 0.36 UGM../M-t-3
ACIDS
NITRONAPHTHALENE
L
EST
.0051 UGM./M + 3
0.0043
0.0026
UGM. /M-t-3
UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, POSSIBLE
C7H1204 (ME"HYL ADIPIC) DUP 1.4 UGM./M-t-3
C8H503 (PHTHALATES) 14. UGM./M+3
C7H1403 ISQMERS EST 0.057 UGM./fH3
C6H1904 (AD::PIC ACID) DUP 0.42 UGM./Mt-3
C7H1203 ISOMERS EST 0.668 UGM. /M-t-3
SEC. DIFUHCTIONALS
C6H1203
C5H804 -
C7H1402
C6H1003
C7H1202
ISOMERS
GLU"ARIC
ISOMERS
I SOHERS
ISOMERS
ACID?)
EST 0.
EST 0.
EST 0.
EST 0.
EST 0.
052 UGM
52 UGM..
021 UGM.
20 UGM..
026 UGM
/M-t-3
M-t-3
/M-t-3
M-t-3
/M-t-3
C5H1003 ISOMERS
C6H1202 ISOMERS
HOOC(CH2)50N02
HOOC(CH2)40N02
HCO(CH2)60H02+ISOMER!
EST 0.13 UGM. /M-t-3
EST 0.079 UGM /Mt3
EST 0. 079 UGM. /M-t-3
EST 0. 079 UGM /M-t-3
EST O. 052 UGM /M-t-3
166
-------
PAGE 003.
HCO40N02+ISOMERS
HOQCCCH2MCOON02
HCOCCH2:>4COON02+ISQMERS
HCO3COOH02+ISOMERS
HCOCCH2MCOOHO
HCO3COONO
EST
EST
EST
EST
EST
0. 031
0. 021
0. 021
0. 026
0. 021
UGH.
UGM.
UGM.
UGM.
/M-t-3
/Mt-3
/M + 3
/M-t-3
UGM. /M-t-3
EST 0. 052 UGM. /M-t-3
EST 0.063 UGM./M + 3
CPD. F::LE 0057, DATE 092575, TENTATIVE TOLUENE PRODUCT
C6H602 ISOMERS
C6HS02 ISOMERS
C7H1002 ISOMERS
C5HS03 ISOMERS
C5H604 ISOMERS
C6H804 ISOMERS
C7H7N04 ISOMERS
NITROCRESOL8?
CPD. F:LE 0058,
C9H1402 ISOMERS
C16H1602 ISOMERS
C10H1403 ISOMERS
EST 0. 59 UGM. /M-t-3
EST 0. 46 UGM. /M-t-3
EST 0.14 UGM. /M-t-3
EST 0.14 UGM. ."-M-rS
EST 0. 026 UGH. /Mf-3
EST 0.13 UGM. .--M-t-3
EST 0. 0015 UGM. /M-t-3
L 0. 0031 UGM. /Mt-3
DATE 082575, TENTATIVE
EST 0.068 UGM /M*3
EST 0. 626 UGM. /M-t-3
EST 0.10 UGM. /M-t-3
TERPENE PRODUCTS
C8H1204 (NORPINIC ACID?)EST 0.047 UGM
C9H1404 EST 0.046 UGM. /M-t-3
167
-------
WASHINGTON UNIV. 1350 8x19/74 TO 0115 CDT
SLW62
FILE NO. 0002, FIT TOL. 905 CM ILL I MASS) RUN 0036 TO RUN 0070
'DATE 632075, PASS3 ERROR 10 (MILL I MASS)
TOTAL tSAMPLEI = 0. 920E +1 CUB"C METERS, ALIQUOT = 0. 930E -1
INST. SENSI"IVITY=0. 230E + 5
CHECK HEIGH" RAT 10 = 0. 508 (.'FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCAREJONS
TOTAL ALKAHEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE:S
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE-:
TERRENES AS PINENE
CL 0. 39 UGM. /M-t-3
CL 0.16 UGM. /M-t-3
CL 0.10 UGM. /M-t-3
CL 0.0084 UGM./M +
0. 40 UGM. /M-t-3
CL 0. 027 UGM /M-t-3
CL 0.15 UGM. /M-t-3
CL 0.12 UGM. /M-t-3
0. 29 UGM. /M-t-3
CL 0.14 UGM. /M-t-3
X Y L E N E S, M 0 H S U B BENZENE S C L 0.12 U G M . / M -t- 3
XYLENES, ETHYL BENZENE CL 0.031 UGM /M-K
ALKYL BENZENES C9H12 CL 0.39 UGM./M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.0071 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.014 UGM./M-t-3
CPU. F:.LE 0053, HATE 002575, AROMATIC OXYGENATED CPUS
CRESOLS (BENZYL ALCOHOL?)CL 0.016 UGM /M-t-3
DIHYDROXYBENZEHES 1 0.017 UGM./M+3 -
BENZOQUINONE: L 0.0046 UGM./M-t-3
PHENOL 1 9.031 UGM /M+3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BEHZOIC ACID
METHYL BENZOIC ISOMERS
ETHYL BENZO::C ISOMERS
TRI METHYL BEINZOIC ISOM.
PENTAHDIOIC ACID
HEXANIHOIC ACID
METHYLHEXANUIOIC ACID
BEN20YL ION CARBITRARY)
ACIDS (AS ACETIC ACID.:>
2
EST.
EST.
EST
EST.
4
1
EST
0.
0.
0.
0.
0.
0.
0.
0.
0 .
030 UGM /M-t-3
0080 UGM. /M-t-3
014 UGM. /M-t-3
014 UGM. /M-t-3
71 UGM. /M-t-3
96 UGM. .-• M-t-3
27 UGM. /M-t-3
20 UGM. /M-t-3
21 UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN
CONH FRAGMENT (RELATIVE) 0.69 UGM./M-t-3
C3H5N2 FRAGMENT (RELATIVE) 9.11 UGM. /M-t-3
C4H8N2 FRAGMENT (RELATIVE) 0.051 UGM /Mt-3
PI PER I DINES ( + ISOMERSJ EST 0.010 UGM .--M-t3
COMPOUNDS
168
-------
PAGE 002.
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONHLS
C3H503 CPHTHALATES) 2.8 UGM./M+3
C7H1202 ISOMERS EST 0.43 UGM. /M-t-3
CPD. F::LE 0057,
C6H602 ISOMERS
C6H802 ISOMERS
C7H1002 ISOMERS
C5H803 ISOME:RS
HATE 082575, TENTATIVE TOLUENE PRODUC"S
EST 0. 14 UGM. /M-t-3
EST 0.17 UGM. .'M-t-3
EST 0.16 UGM. /M-t-3
EST 0.21 UGM. .-'M-t-3
CPD. F::LE 0053, DATE 082575, TENTATIVE: TERPENE PRODUC"S
C8H1204 O'JORPINIC ACI3?)EST 9.077 UGM /M-T-3
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 15. UGM./M+3
AMMONIUM CHLORIDE 3 0.34 UGM. /M-t-3
AMMONIUM NI"RATE 2 1.0 UGM. /M-t-3
CPD. F::LE 0060, DATE 002575, CHLORINA"ED COMPOUNDS
LINDANE . EST 0.28 UGM. /M-t-3
C5H5CL (HEP"ACHLOR?> EST 0.26 UGM. /M-t-3
169
-------
WASHINGTON UNIV. 0130 8/20x74 TO 0345 CUT
SLW63
FILE HO. 0902, FIT TOL. 605 CM ILL I MASS) RUN 0176 TO RUN 9210
DATE 032975, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLERS. 320E +1 CUBiiC METERS, ALIQUOT = 0. 190E +0
INST. SENSI"IVITY = 0. 230E +?.5
CHECK HEIGH" RAT 10 = 0. 509 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANEIS
ALKAHES LOW MW
ALKAHES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 0. 28 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
CL 0. 081 UGM. /M-t-3
CL 0.012 UGM /M-t-3
0. 36 UGM. /M-t-3
ALKENES LOW MW
ALKEHES MED. MW
ALKENES HI MW
ALPHA PIHENE:
TERRENES AS PINENE
CL 0.015 UGM.
CL 0.11 UGM. /M-t-3
CL 0. 053 UGM /M-t-3
0. 28 UGM. /M-t-3
CL 0.15 UGM. /M-t-3
XYLEHES, MON SUB BENZENES CL 0.15 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.028 UGM /M-t-3
ALKYL BENZENES C9H12 CL 8.58 UGM./M-t-3
CPU. F::LE 0052, HATE 082575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.013 UGM./M-t-3
METHYL HAPH"HALENES+INT. L 0.0039 UGM./M-t-3
PERYLENE, ISOMERS C28H12 L 0.0672 UGM./M-t-3
CPD. F::LE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?>CL 0.013 UGM /M-t-3
DIHYDROXYBENZEHES 1 0.068 UGM /Mf-3
PHENOL 1 8.020 UGM /M-t-3
CPD. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
BENZOIC ACID
ETHYL BENZOIC ISOMERS EST.
PENTAHDIOIC ACID EST.
HEXANDIOIC ACID 4
METHYLHEXANDIOIC ACID 1
2 8. 839 UGM. /M-K
8. 855 UGM. /M-r3
8. 92 UGM. /M-t-3
8. 45 UGM. /M-t-3
8. 23 UGM. /M-t-3
BENZOYL ION (ARBITRARY) 0.23 UGM. /M-t-3
ACIDS CAS ACETIC ACID) EST 0.19 UGM./M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN
CH2CN FRAGME-INT (RELATIVE) 0.15 UGM./M-t-3
CONH FRAGMENT (RELATIVE) 0.42 UGM./M-T3
C3H5H2 FRAGMENT (RELATIVE:' 0.27 UGM. /M-t-3
PIPERIDINES C + I S 0 M E R S :• E S T 8.019 U G M -' M -t- 3
COMPOUNDS
170
-------
PAGE 082.
CPD. F::LE 0056, DATE 082575, POSSIBLE SEC. DIFUHCTIONRLS
C8H503 CPHTHALATES) 8.8 UGM./M*3
C6H1203 ISOMERS EST 0.20 UGM..'IH-3
CPU. F::LE 0057, DATE 082575, TENTATIVE: TOLUENE PRODUCES
C6H602 ISOMEIRS EST 0.57 UGM..'M*3
censor ISOME:RS EST 0.10 UGM. .-11+3
C7H1002 ISOriERS EST 0.073 UGM
CPD. F::LE 0058, DATE 002575, TENTATIVE: TERPENE PRODUCES
CPU. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 14. UGM.xM-t-3
AMMONIUM CHLORIDE 3 0.18 UGM..-TH3
AMMONIUM N I "RATE 2 0.82 UGM./M+3
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
171
-------
WASHINGTON UNIV. 9409 8/26/74 TO 0739 CDT
SLW64
FILE NO. 9002, FIT TOL. 003 SMOOTHED
CPU. F::LE 0051, DATE 082575, HYDROCAREJQNS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI HW
TOTAL ALKENEIS
CL 9.41 UGM. /M-t3
CL 9.11 UGM. /M-t-3
CL 0.17 UGM. /M-t-3
CL 9. 031 UGM /M-t-3
0. 49 UGM. /M + 3
ALKENES LOW MW
ALKEHES MED. MW
ALKENES HI HW
ALPHA PINENE:
TERRENES AS PINENE
CL 9. 068 UGM. /M-t-3
CL 9. 22 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
0. 39 UGM. /M-t-3
CL 0.18 UGM. /M-t-3
XYLEHES, MOH SUB BENZENES CL 0.12 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.919 UGM /M-t-3
ALKYL BENZENES C9H12 CL 0.46 UGM./M-t-3
ALKYL BENZENES C19H14 CL 9.019 UGM /M-t-3
CPU. F::LE 0052, DATE
NAPHTHALENE
METHYL NAPH"HALENES+IHT.
ALKYL NAPHTHALENES C12H12
ANTHRACENE-PHEHANTHRENE
PYREHE & ISOMERS C16H19
PERYLENE, ISOMERS C20H12
BENZOPERYLENE+INTERFER.
082575,
1 0.911
L 0.013
L 0.017
L
L
E
POI_YCYCL::C
UGM. /M-t-3
UGM. /M-t-3
UGM /M-t-3
HYDROCARBONS
0. 0015 UGM. /M-t-3
0.013 UGM. /M-t-3
i. 651
i. 042
UGM /M-t-3
UGM /M-t-3
CPD. F::LE 0053, DATE 082575..
CRESOLS (. BENZYL ALCOHOL? )CL 0.011
TR IMETHYLPHEINOL+ I SOMERS EST
DIHYDROXYBENZENES 1
BEHZALDEHYDE: C + INTERF. > L
PHENOL 1
AROMATIC
UGM /M-t-3
9. 10 UGM. /M-t-3
0. 022 UGM /M-t-3
0. 9058 UGM. /M-t-3
0. 017 UGM. /M-t-3
OXYGENATE.? CPDS
CPD. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0.
PENTANDIOIC ACID EST. 1.
HEXANDIOIC ACID 4 0.
METHYLHEXANDIOIC ACID 1 0.
BENZOYL ION (ARBITRARY) 9.
0090 UGM. /M-t-3
0 UGM. /M-t-3
61
49
10
UGM.
UGM.
UGM.
.-'M-t-3
/ M -t- 3
/Mt-3
ACIDS CAS ACETIC ACID
EST 0. 24 UGM. /M-t-3
172
-------
PAGE 002.
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMEINT (RELATIVE) 0.090 UGM /M-t-3
CONH FRAGMENT (RELATIVE) 0.93 UGM. /M-t-3
C3H5N2 FRAGMENT (RELATIVE) 0.045 UGM./M-t-3
C4H8N2 FRAGMENT (RELATIVE) 0.63 UGM. /M-t-3
PYRIDINE + PVRIDYL CPDS L 0.00090 UGM.
ACRID INE & ::SOMERS
PYRIDINE SULFATE
L 0. 9078 UGM. /Mf-3
EST 0. 036 UGM /M-t-3
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
C8H503 (PHTHALATES) 1.2 UGM./M+3
C7H1202 ISOMERS EST 0.18 UGM. /M-t-3
C5H1003 ISOMERS EST 0.26 UGM..'
CPD. F::LE 0057,
C6H602 ISOME:RS
C6HS02 ISOMERS
DATE 082575, TENTATIVE: TOLUENE PRODUCE'S
EST 0.18 UGM. /M-t-3
EST 9. 30 UGM. /M-t-3
CPD. F::LE 0058,
C10H1602 ISOMERS
C10H1403 ISOMERS
DATE 082575, TENTATIVE! TERRENE PRODUCES
EST 0.063 UGM /M + 3
EST 0. 036 UGM. /M-t-3
CPD. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 27. UGM. /M-t-3
AMMONIUM CHLORIDE 3 0.19 UGM. /M-t-3
AMMONIUM NT'RATE 2 1.4 UGM. /M-t-3
CPD. F::LE 0060, DATE 002575, CHLORINATED COMPOUNDS
C5H5CL (HEP"ACHLOR?) EST 0.20 UGM. /M-t-3
173.
-------
WASHINGTON UNIV. 9809 8/20/74 TO 0956 CDT
SLW 65 2 PUNCHES 0800-9950
FILE NO. 0902, FIT TOL. 803 < MILL I MASS) RUN 0211 TO RUN 0245
DATE Q32075, PASS3 ERROR 19 CM ILL I MASS)
TOTAL SAMPLE[ = 0. 289E +1 CUB'.'.C METERS, ALIQUOT = 0. 199E + 9
INST. SEHSr"IVITY = 0. 239E + 5
CHECK HEIGH" RAT 10 = 0. 590
-------
PAGE 002.
CPD. F::LE 0055, DATE 002575, POSSIBLE SEC. BIFUNCTIONRLS
C8H503 EST 0.15 UGM.
175
-------
WASHINGTON UNIV. 1000 8/20/74 TO 1239 CDT
SLW 66
FILE NO. 8002, FIT TOL. 005 CM ILL I MASS) RUN 0246 TO RUN 828(5
DATE 932075, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLE[ = 0. 360E +1 CUBiiC METERS, ALIQUOT=0. 1S0E +0
IN ST. SENSI"IVITY = 0. 23QE +55
CHECK HEIGH" RAT 10 = 0. 500
-------
PAGE 092.
C5H1003 ISONERS
HOOC40H02+ISOMERS
CPD. F::LE 0057,
C6H602 ISOMEIRS
C6H802 isoMERs
C7H 10.02 ISOMERS
EST 0. 32 UGM. xM + 3
EST 0. 070 UGM. xM-t-3
EST 0. 47 UGM.
BATE 882575, TENTATIVE-: TOLUENE PRODUCTS
EST 0.71 UGM.
EST 0. 48 UGM. .''
EST 0.17 UGM. xMt-3
CPD. F::LE 0053, DATE 002575, TENTATIVE TERPENE PRODUCT'S
CPD. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 22. UGM./M*3
AMMONIUM CHLORIDE 3 0.15 UGM./M-t-3
AMMONIUM NI"RATE 2 0.70 UGM./M-t-S
SODIUM NITRATE 1 0.19 UGM./M+3
CPU. F::LE 0060, DATE 002575, CHLQRINA~ED COMPOUNDS
C5H5CL
-------
WASHINGTON UNIV. 1248 3/20/74 TO 143© CUT
SLW 67
FILE NO. 0002, FIT TOL. 005 CM ILL I MASS) RUN 028 1 TO RUN
DATE 932075, PASS3 ERROR 10 (MILL I MASS)
TOTAL SAMPLEI = 0. 210E +1 CUB"C METERS, ALIQUOT=0. 190E +0
INST. SENSI"1VITY = 0. 230E +?.:>
CHECK HEIGH" RAT 1 0 = 0. 500 < FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANEIS
A L K A N E 8 L 0 W M W
ALKANES MED. MW
TOTAL ALKENEIS
ALKEHES LOU MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PIHENE:
TERPENES A-3 PINENE
CL 0.38 UGM. /M-t-3
C L 0.16 U G M . / M 1- 3
CL 0.038 UGM. /M-t-3
0.40 UGM. /M-t-3
CL 0.069 UGM./M-t-3
CL 0.18 UGM. /M-t-3
CL 0.087 UGM. /M-t-3
0.19 UGM. /M-t-3
CL 0.13 UGM. /M-t-3
XYLENES, MOH SUB BENZENES CL 0.16 UGM. /M-t-3
ALKYL BENZENES C9H12
CL 0.24 UGM./M-t-3
CPU. F:LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
CPD. F"LE 0953, DATE 082575, AROMATIC OXYGENATED CPD3
CRESOLS (BENZYL ALCOHOL? ) CL 0.017 UGM /M-t-3
T R I M E T H Y L P H El N 0 L + I S 0 M E R S E S T 0.0 3 4 U G M / M -t- 3
DIHYDRDXYBEHZENES 1 0.091 UGM. /M-t-3
PHENOL
1 0.016 UGM. /M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYLT.C ACIDS
BEHZOIC AC I])
PENTANDIOIC ACID
HEXANDIOIC ACID
METHYLHEXANDIOIC ACID
BENZOYL ION < ARBITRARY)
2 0.028 UGM./M*3
EST. 0.26 UGM . . --M-t-3
4 1.5 UGM. /M-t-3
1 0.39 UGM./M-t-3
0.087 UGM /M-t-3
ACIDS CAS ACETIC ACID') EST 0.25 UGM./Mt-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
COHH FRAGMENT (RELATIVE)
8.40 UGM . /M-t-3
C3H5H2 FRAGMENT (RELATIVE) 0.33 UGM. /M-t-3
C4H8N2 FRAGMENT (RELATIVE) 1.1 UGM./Mt-3
P Y R I D I H E + F:I Y R I D Y L C P D S L 0 . 0 0 8 8 U G M . / M -t- 3
PI PER I DINES ( + I30MER3 :' EST 0.037 UGM /M-t-3
PYRIDINE SLU.FATE
EST O.I 4 UGM. /M-t-3
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIOHALS
C8H503 (PHTHALATES) 1.3 UGM. /M-t-3
H 0 0 C ( C H 2 ) 4 0 N 0 2 E S T 0 . 2 5 U G M . / M -t 3
178
-------
PAGE 802.
HCOCCH2MON02+ISOMERS
EST 0.0S7 UGM./M-tS
CPD. F::LE 0057, DATE 0552575, TENTATIVE- TOLUENE PRODUCT'S
C6H602 ISOMEIRS
C6H802 ISOME-RS
C7H1802 ISOflERS
EST 0.76 UGM..'M-t-3
EST 0.39 UGM./M-tS
EST 0.29 UGM..'M*3
CPD. F::LE 0059, HATE 0432575, TENTATIVE: TERRENE PRODUCTS
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 14. UGM. .'M-t-3
AMMONIUM CHLORIDE 3 0.21 UGH.. '11*3
AMMONIUM NI"RATE 2 0.63 UGM..'M + 3
SODIUM NITRATE 1 0.039
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
LINDANE EST 1.2 UGM. /Mt-3
C5H5CL CHEP'-ACHLOR?) EST 0.51 UGM..'M>3
179
-------
WASHINGTON UN IV. 1445 8.-'20.-'74 TO ly0Q CDT
SLW 6B 4.3 MRS BBA
FILE NO. 00fi2, FIT TOL. 003 aiILLIMASS> PUN 9351 TO RUN QSS'.j
DATE 032075. PASS3 ERROR 10
TOTAL SAMPLERS. SIOE +1 CUE-:C METERS, ALIQUOT=S. 190E +e
IHST. SEN'S I "IV IT V-O. 230E +^
CHECK HEIGH"" RAT 10 = 0. 500 a"P ACTION;', SMOOTHED
CPL. F::LE 0051, DATE 8B2575, HYDROCAREJONS
TOT A 1.. A L K A N El S C L 0.1 8 U G M . .-' M + 3
ALKANE3 LCn.i MM CL 0.07S UGH xM-t-3
A L i-: A r \ L s M E D . n w CL 0. 0 s 6 u G M / n -t- 3
A L K H N l£ S HI M!..! C L O . 0 1 6 U G M . .••' M -t- 3
TCTAL HLi-'ENEIS 0.26 UGM. .••71 + 3
A L K E N E S L 0 M M I.I C L O . 0 1 2 U G M .-- M -t 3
H L K E '--i E S M Ft M U C L 0.15 U G M . / M t- 3
HLKENES HI m.J CL O 057 UGM xM-t-3
ALPHA PINENE-. 0.049 UGM xM-t-3
TERRENES AS PINENE CL 8 087 UGM /M-r-3
KVLENES-HON SUE BENZENES CL O.OSt UGM ^Mt-3
ALKYL BENZENES C9H12 CL 0. ? t UGH 'Mt"?
C-'L. t.LE 0052, ;in"F Mi'2'575 fCl •YC,..:.0. HYDROCARBONS
NHPHTHALENE 1 ^ an?9 UG;I. •iit-3
C P D F . L E O 053, J. i T P. U 5': J' 5 7 5, H P 0 M H T I C 0 >, Y G E N A T E .I ' P D S
LIHYLPOXYEENZENES 1 0.041 UGM ,-M*3
P HEN 0 i_ i '3 8 0 6 0 !J G h . ,' M -t 3
CPD. F:LE 0054- HATE o::32575, CARBOXYL::C ACIDS
FFNTANDIOIC HCID EST a. 76 UGM..M-t3
HCMAilDIOIC AL ID 4 1 0 UGM .- M13
METHYL HE:,'A!JiUij:i: M:MD t e. ?s UGM. nt3
B E N Z 0 Y L [ 0 N '' H R D 1 T P A R Y '' 0 £ 11 U G N / M -T- 3
A!:iCS ',AS Hi'ETIC ACID.' EST 0.17 UGM /Mr-3
CPD C.:LE eoio, JHTE Oo,?:1???, KITPOGEH COMPOUNDS
COMH !"RHGnENT '.RELATIVE:- 0.12 UGM..-M13
PYRIDINE t PYPIDYL CPJ'S L 0 052 UGM ,-H.T-3
PIPERTDP'ES '•: + ISOf'iEPS ' E:fT 0 (Hi": 3 UGH... M-t3
CARBAZOLE L 0.0041 UGM. 'M-t-3
CPD. ' L!-: OOSb, JHTE 0::::25" ?, POSSIBLE SEC. DIFUHCTI OHfiL!
CSHjO? .. PL : HH! uTES'' , 6 UGM. •'M-r3
f 7 H 1 2 0 2 ( £. U n E. P S E c. T 0 2 0 U G M . •" M -t 3
rpr r:.LE 0057. HATE of'2'5Titj. TENTHTIVE: TOLUENE PPODUC-S
C6H602 i '.ijiirR1: e-.T y 34 UCN. --Mf-3
r: 6 H 8 0 2 S 0:1 E: P S ESI U 11 11C M . h t 3
C 7 H 1 0IJ 2 I S ONE R S E G T 0 . 0 ? 0 U G M •• M f 3
18-0
-------
PAGE 802.
CPD. F::LE QQSS, DATE 002575, 'TENTATIVE: TERRENE PRODUCTS
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 19. UGM./M+3
AMMONIUM CHLORIDE 3 0.069 UGM.xM*3
2 8.46 UGM./M-t-3
1 6.0074 U G M . .-' M-t- 3
AMMONIUM NI"RATE
SODIUM NITRttTE
CPD. F::LE 0060,
LINDAHE
C5H5CL
DATE 002575, CHLORINA"ED COMPOUNDS
EST 0.48 UGM./M+3
EST 0. 35 UGM. /M-t-3
181
-------
WASHINGTON UNIV. 1318 8/20/74 TO £215 CDT
SLW 69 :?
FILE NO. 090
DATE 032075.
TOTAL SAMPLE:
INST. SENS I"
CHECK HEIGH"
.1 HRS BBA
2, FIT TOL. 003 '. Y L E N E S.. M 0 N S U B BENZENE S C L O.I 8 U G M. / M -t- 3
XYLEHES, ETHYL BENZENE CL 0.016 UGM /MK
A L K Y L BENZENE S C 9 H 1 2 C I 0 . -1 S U G M. / It 3
ALKYL BENZENES C10H14 C L ij , U L 6 UGM - hh :
CPU. F :LE 0052, DATE
NAPHTHHLENE
METHYL NAPH"HALENES+IHT
ALKYL NHPHTHALENES c
PYRENE i- ISUMERS C 16
CPD F::LE 0053,
CRESOLS '"BENZYL ALCO
P HEN 0 L -t M 0 2 . r H n , r. o 2 H "
T R I M E T H Y L F' H E; N 0 L +• I S 0 M E P S E S T
DIHYDROXYBENZENES
PHENOL
CPD F .' L. E O 0 5 4 .
BENZOIC ML III
M E T H Y L B E N Z r 11 C I S 0 M E P. S
ETHYL BENZO.iC ISOMERS
PENTANDIOIC ACID
HEXANDIOIC ACID
METHYLHEXANniOIC HCID
B E N Z 0 Y L ION •. H P B I T P A P Y '.'
HLIDS 'in'!. Af'ETIC ACID
P 0 L Y L Y C L :: C H Y P R 0 C A - *. 0 N S
:NT
. 2H
no
i
ti
DATE
iOL
IPS
*y
p
';i
i~
E
DATE
? C;
'.'
)
:'Y'.'
j i
E
E
E
i^-
i~
S
E
1
I
L
L
08
CL
T
ST
1
1
09
2.
J .
T
T
4
1
ST
0.
0 .
0 .
0 .
25
0 .
n
0
0
0.
~' ^i
0
n.
0.
1 .
1 .
0.
o ,
O .
0
1
0 0
0
1
5
r
0
UGM
6 UGM
UGM
..-
M
t-3
. /M-t-3
f
M
0040 UGM ..-
7
0
0
1
0
0
7
0
0
0
1
0
g
1
L^!
S
"7
1
2
5
•-i
5
1
-i
ii!
•t 3
M-t-3
AROMATIC OXYGENATED
6
3
q
1
UGM
UGM
UGM •'
UGM
UGM
/
/
M
.--
M
M
•t-
M
*T' """I
t 3
3
•t-3
/ M -t 3
CAP BO
1
tl
4
UGM
UGM
UGM
UGM. /M
UGM. ,-M
8
L!
"7
UGM /
UGM •'
UGM. .-
..-'
.••
/
•t-
•T
M
M
M
M
M
M
-?
3
•t
t
1-
XYLVC ACIDS
•t-3
•t-3
•t-3
;?,
•7
^
CPDS
C P D F L E 0 O 55. DATE 0 0 2 5 75, N I T R 0 G E N C 0 M P 0 U N D S
C H 2 C N F P H G M L N T ' P E L A T I V E ,< O . 3 0 U G M . .•' M -t 3
182
-------
PAGE 082.
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT EST
QU I NOLI HE C--INTERFER?) L
8.S UGM./M*3
0.073 UGM.
0.12 UGM. /M-t-3
0. 0869 UGM. /M + 3
CPD. F::LE 0055,
C8H503 CPHTHALATES)
C7H 12.02 ISOMERS
HCO
-------
WASHINGTON UNI'
2225 8/20/74-020© 3/21 CUT
SLM 78 ;;. bHRS
FILE HO. 8802, FIT TOL 803 O1 ILL I MASS) RUN 8386 TO RUN 0420
DATE 032075, PASS3 ERROR 10 < M I LL I MASS)
TOTAL SAMPLE:=O. 430E +1 CUE::C METERS. ALn?uoT=0. ISOE +0
IN ST. SENS I" IV IT V = 0. 23QE + 5
CHECK HEIGH" F'HTIO = 0. 500 < TRACT I OH > , SMOOTHED
CPD. F.LE 0051. DATE 082575, HY3ROCAREJOHS
TOTAL HLKANF.S
A L K A H E S L 0 l.J M l.l
ft L K A N E S M E D M t..!
ALP:AHES HI MM
TOTAL HLKENL'S
CL 6.37 UGH . /M-t 3
C L 6 . 1 0 U G M . / M -t- 3
C L 0.19 U G M . .••' M f 3
CL 0.011 UGM /H-t-3
0.48 UGM. /M-t-3
ALKENES LOI.I MM
MLKEHES MEL. MM
A L K E H E S H I H '.I
ALPHA PINENE:
TERPEHES ri3 PINENE
CL 6.033 UCM /M-t-3
CL 0.24 UGM. /M-t- 3
C L 8 . 1 2 U G M . / M -t- 3
0.43 UGM. /M-t-3
CL 0.17 UGM. /M-t-3
:••: V L E H E S , M 0 N S U E B E H 2 E H E S C L 0 . 1 b U C, M . / M -t- 3
X Y L E N E S . E T H Y LEE H .T E H F. C L 0.016 U G f1 ••" M -t- 3
ALKYL BENZENES C'3H1:"J .:.!. > t / iJCf1 I + 3
DTP'IEMYL ETHnNF .;:. ISGPL'Po !. . 0 1 ? !jr,M ' r-3
.: r L . i :: L e o o ^ 2 . j n ~
NAPHTHnLtNE
HHTHRACENE-PHEHrtNTHFEiJ£
n .' . ;• 5 7 -< , p o L Y c Y c L. " c H Y n R o c ^ ? B o H s
1 1 . '"1 i 5 u G M / M -t- 3
,2 -5.0C25 UGM./M-T-3
cpi'. F::LE 0053, DATE 00^575. AROMATIC OXYGENATED CPDS
C P E -; 0 L S -BENZYL H L C 0 H 0 L '' .:• C L 8.824 U G M / M -t- 3
P ri E H 0 L H N 0 2 • r. H 0 , r 0 2 H 7' E S T . 0 . 8 8 3 U G M . -' M -t- 3
TSlMETHYLPriFIMOL+ISOMEP.:: EST 0.019 UGM /lltj
DlHYHRO;-":"3Fi:ZFNE:. 1 0-98^3 UGM ." M-t 7-
B C N Z ^ L D E H Y G II • - I N T L £• F .• L £ . 6 n 7 5 U G H . / M "" 3
P H E N 0 L
10.013 U G M / M t- 3
CPD. ^.iLE 0054, DrtTF 002575, CAPBOXYL"C ACIDS
E E !-•! Z 0 I C H C I ]} 20. 0 2 4 U G M . ' M « 7
METHYL BENCU1C I 50MER5 EST P 013 UGM .--M-vc
ETHYL BENZn"C ISOMERS EST 0 83b UGM.,- M-t- 3
T P I M E T H Y L E' II i ! Z 0 I C I S 0 M . E S T 0 . 0 1 8 U G M . ,- M -t- 3
P E N T A H D I 0 I r A L ID E S T . 1 . 0 U G M / M t 3
METHYLREXHi-iMOIO ACID i u 73 UGM . Mt3
B E N Z 0 Y L ION ' n p E1 1 T P A P Y .' 0 . 12 U i, M ' M T 3
A C I D S '" H S H i'" E T 3 C ACID' E S T 0 . 4 1 U G M / M -t- 3
C P D F .' L E 0055, DATE U 0 2575, HIT P G U, F N C 0 M P 0 U N D S
C H 2 L N F P i- d i'l [I NT >' F' E L H T I V E .:< 0 0 3 5 U G M • H -f- 3
184
-------
PAGE
COHH FRAGMENT (RELATIVE) 0.
PYRIDIHE + PVR IDYL CPDS L 0.
PIPERIDINES <+ISOMERS> EST 0.
QU INCLINE <--INTERFER?J L 0.
PYRIDINE SULFATE EST 0.
45 UGM.
0035 UGM./M + 3
12 UGM. /M-t-3
8047 UGM.
039 UGM.
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONHLS
C8H503 5.3 UGM./M*3
C7H1203 ISOHERS EST 0.17 UGM.xM-t-3
C7H1202 ISOMERS EST 0.33 UGM./M*3
DATE 002575, TENTATIVE!
EST 0.053 UGM./M+3
EST 0. 17 UGM. /M-t-3
EST 0.042 UGM. /M + 3
EST 0.075 UGM.
TOLUENE PRODUCTS
CPD. F::LE 0057,
C6H602 ISQMEiRS
C6H802 ISOMEIRS
C7H1002 ISOMERS
C5H803 ISOMIERS
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERRENE PRODUCTS
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 11. UGM. /M't-3
AMMONIUM CHLORIDE
AMMONIUM HI"RATE
SODIUM NITRRTE
3 0. 28 UGM. .'M*3
21.2 UGM. /M-t-3
1 0. 049 UGM. /Mf-3
CPD. F::LE 0060,
LINDAHE
C5H5CL (HEP"ACHLOR?)
DATE 002575, CHLORINA"ED COMPOUNDS
EST 0. 45 UGM. ,-'M-t-3
EST 0. 23 UGM. /M-t-3
185
-------
WASHINGTON UNIV. 0219 8/21/74 TO C745 CDT
SLW 71 5.6 MRS
FILE NO. 00(?2, FIT TOL. 003 < MILL I MASS) RUN 8421 TO RUN 045^5
DATE 832875, PASS3 ERROR 10
-------
PAGE 092.
CPU. F::LE 0055, DATE 002575.. NITROGEN'COMPOUNDS
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H9N2 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPDS L
0. 65 UGM. /M-t-3 •
0. 53 UGM. .-'M-t-3
0. 028 UGM. /M +3
0.046 UGM./M*3
0.010 UGM /M-t-3
PI PER IDINtS ( + ISOMERS >
CARBAZOLE
ACRID I HE & :: SOMERS
QU INCLINE (--INTERFER?)
PYRIDINE SULFATE
EST 0. 056 UGM /M + 3
L 0. 0038 UGM. /M-t-3
L 0. 0093 UGM. /M-t-3
L 0.012 UGM /M*3
EST 0. 045 UGM. /M-t-3
CPU. F::LE 0056,
C8H503 (PHTHALATES)
C6H1203 ISOMERS
C7H1202 ISOMERS
HOOC(CH2)40N02
DATE 092575, POSSIBLE
2. 2 UGM. /Mt-3
EST 0. 45 UGM. /M-t-3
EST 0. 48 UGM. /M-r-3
EST 0. 15 UGM. /M-t-3
SEC. DIFUHCTIOHnLS
CPD. F::LE 0057,
C6H602 ISOME:RS
C6H802 ISOME:RS
C7H1002 ISOMERS
C5H803 ISOMEIRS
DATE 002575, TENTATIVE TOLUENE PRODUCT'S
EST 8. 54 UGM. /M-t-3
EST 0. 27 UGM. /M-t-3
EST 0. 29 UGM. /M-t-3
EST 0. 051 UGM /Mt-3
CPD. F::LE 0058, DATE 002575, TENTATIVE: TERPENE PRODUC"S
CPD.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
NI"RATE
SODIUM NITRATE
DATE 082575, INORGANIC
ACID 4 34. UGM. /M-t-3
3 0.17 UGM. /M-t-3
21.3 UGM. /M-t-3
1 0.012 UGM. /M-t-3
COMPOUNDS
CPU. F::LE 0060, DATE 002575, CHLORINA"ED COMPOUNDS
LINDANE EST 0.70 UGM./M-t-3
C5H5CL (HEP-'ACHLOR?) EST 0.26 UGM./M-t-3
187
-------
HOLIDAY INN 1696 9/5x73 TO 2360 9/5/73 CDT
SLH8F
FILE NO. 0881, FIT TOL. 803 •. + INTEPF. > L
PHENOL i
0. 01 1 UGM /M-t-3
O. 87S UGM /M-t3
0.18 UGM. /M-t-3
188
-------
PAGE 802.
CPD. F::LE 0054, DA
BENZOIC AC in
METHYL BENZOIC ISOMERS
ETHYL BENZOIC ISOMERS
TRI METHYL BE:'NZOIC ISOM.
PENTANDIOIC ACID
HEXANDIOIC ACID
METHYLHEXAH])10 1C ACID
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC: ACID)
TE 0532575, CARBOXYL
2
EST.
EST.
EST
EST.
4
1
EST
0
0
0
0
1
1
1
0
0
..071 UGM. /M-t-3
. 076 UGM /M-t-3
. 060 UGM. /M-t-3
. 042 UGM. /M-t-3
. 4 UGM. /M+3
. 5 UGM. /M*3
. 0 UGM. /Mt-3
. 57 UGM. /M-t-3
. 80 UGM. /M-t-3
:c ACIDS
CPD. F::LE 0055, DATE 002575..
NITROGEN COMPOUNDS
CH2CN FRAGMENT
-------
PAGE 003.
H C 0 (C H 2 ) 6 0 H Ci 2 + IS 0 M E R S
HCOCCH2MON02+I SOMERS
HCOC.CH2 >5CODH02+ISOMERS
HCOCCH2MCOUH02+ISOMERS
HCO3COOH02+I SOMERS
EST
EST
EST
EST
EST
0.
0.
0.
0.
0.
042
821
678
042
021
UGM.
UGM.
UGM.
UGM.
UGM
/M-t-3
/M-t-3
/•M-t-3
/Mt-3
/M + 3
CPU. F"LE 0057, DATE d82575, TENTATIVE! TOLUENE PRODUCES
CSH602 ISOMEIRS
C6HS02 ISOMEIRS
C7H1Q02 ISCiriER:;
C5H803 ISOMEIRS
C5H604 ISOMEIRS
EST 0. 99 UGM. .-'Mt-3
EST 0. 63 UGM. .-'M-t-3
EST 0. 35 UGM. /M-t-3
EST 0. 34 UGM. ,-"M-t3
EST 0. 023 UGM. /M-t-3
C6HS04 ISOMEIRS
NITROCRESOLO?
EST 0. 028 UGM. /M-t-3
L 0. 0028 UGM. .-'M-t-3
CPU. F::LE 00
C9H1402 ISOHEPS
C10H1403 ISOMERS
C10H1603 '. P::NONIC
C8H1204 CNOPPINIC
58, DATE 082575..
EST
EST
ACID?>EST
ACIB?>EST
TENTATIVFI
0.14 UGM. xM-t-3
0.035 UGM.xM*3
0. 19 UGM. ."• M-t-3
O. 023 UGM. xM-t-3
TERPENE PRODUC"S
C9H1404
-------
HOLIDAY INN 2319 9/5/73 TO 0646 9/6/73 CDT
SLH9F
FILE NO. 0901, FIT TOL. 663 CM ILL I MASS) RUN 0001 TO RUN 0033
DATE 122973, PASS3 ERROR 26
TOTAL SAMPLEI = 0. 845E +1 CUBiiC METERS, ALIQUOT = 0. 100E +9
INST. SENSI"IVITY=0. 264E + 5
CHECK HEIGH" RATIO=0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARESONS
TOTAL ALKANE:S
ALKANES LOI..I MW
ALKAHES MED. MW
ALKANES HI f1W
TOTAL ALKENE-S
CL 0.51 UGM. /M-t-3
CL 0.10 UGM. /M-t-3
CL 0. 20 UGM. /M-t-3
CL 0.089 UGM./M + 3
0. 56 UGM. /M-t-3
ALKEHES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE!
TERPENES AS PINENE
CL 0.946 UGM./M + 3
CL 8.19 UGM. /M-t-3
CL 0.21 UGM. /M-t-3
0. 58 UGM. /M-t-3
CL 0. 29 UGM. /M-t-3
XYLENES,MOM SUB BENZENES CL 8.32 UGM./M+3
XYLENES, ETHYL BENZENE CL 0.12 UGM./M*3
ALKYL BENZENES C9H12 CL 0.94 UGM./M-t-3
ALKYL BENZENES C10H14 CL 0.086 UGM./M-t-3
BIPHENYL 1 9.82 UGM./M-t-3
DIPHENYL ME"HAHE+ISOMERS CL
DIPHENYL ETHANE & ISOMERS L
0020 UGM./M+3
013 UGM. /M*3
CPD. F:LE 0052, DATE 002575, POLYCYCLIC HYDROCARBONS
NAPHTHALENE 1 0.095 UGM./M-t-3
METHYL NAPH"HALENES+INT. L 0.038 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 0.017 UGM./M+3
2 0. 0099 UGM. /Mt-3
L 0. 029 UGM. /M-t3
ANTHRACENE-PHEHANTHREHE
PYRENE £ ISOMERS C16H10
CPD. F::LE. 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.048 UGM./M1-3
PHENOL + N02, CHO, C02H? EST. 0.22 UGM./M-t-3
i. 036 UGM. /M*3
1 0. 075 UGM. /M-t-3
L 0. 020 UGM. /M-t-3
EST.
TR I METHYLPHEENOL+ISOMERS EST
DIHYDROXYBENZENES
BENZOQUINONE;
BENZ ALDEHYDE:
PHENOL
<+INTERF.
L 0.610 UGM /M-t-3
1 0. 060 UGM. /Mt-3
CPD. F::LE
BENZOIC ACID
METHYL BENZOIC ISOJ1ERS
ETHYL BENZO."C ISOMERS
PENTANDIOIC ACID
0054, HATE 082575, CARBOXYL::C ACIDS
2 0. 048 UGM /M-t-3
EST. 0. 0038 UGM. /M-t-3
EST. 0. 0051 UGM. /M-t-3
EST. 0.71 UGM. /M-t-3
191
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PAGE 082.
HEHANDIOIC ACID
METHYLHE/IANIiIOIC AC 111
BEHZOVL I OH (ARBITRARY)
ACIDS (AS ACETIC ACID.)
4
1
EST
9.
0.
0.
0.
57
18
17
51
UGM.
UGM.
UGM.
UGM.
.'M-t-3
xM-t-3
-'•M-T-3
--71-t- 3
CPU F.:LE 0055, HATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMENT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT ( RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT ''.RELATIVE)
C4H9H2 FRAGMENT (RELATIVE)
PYPIDINE + F'YPIDYL CPUS L
PIFERIDINES '' + ISOMERS3 EST
CARBAZOLE L
ACPI DINE $•• "SONERS L
0. 58 UGM. .-"Mt-3
1 . 6 UGM. /M-t-3
0.15 UGM. .-'N't-3
0. 0090 UGM. /Mt-3
0 . 0 3 6 U G M . -•' M -t- 3
0.13 UGM. .•-M-t-3
0 Oil UGM .--M-t-3
O. 014 UGM ••'M-t-3
8. 0037 UGM. .--M-t-3
0.010 UGM. .--M-t-3
PIPERAZINE?
PYRIDINE SULFATE
EST O. 9031 UGM. .--M-t-3
EST 0. 0090 UGM. .--M-t-3
CPU. F::LE oose, DATE 0
C7H1204 (ME"HYL ADIPIC) DUP
C8H503 (PHTHALATES)
C7H1403 ISOMERS
C6H100- '. nil. PIC ACID)
C7H12U3 If.OMEPS
EST
HUP
EST
02575. POSSIBLE
0. 36" UGM. .--Mt-3
1 . 5 UGM. /M-t-3
O. 04? UGM. -Mt-3
1 7 UGM. .--Mi-3
SEC. DIFUNCTIONALS
O. 13 UGM. 'Mt-3
C6H1203 ISOMEPS
C 5 H 8 0 4 (. G L U " A P I C
C7H1402 ISOMEPS
CtHlOO-3 ISOMEPS
r 7 H 1 2 0 2 I S 0 r ! E P S
EST 0. 040 UGM /M-t-3
:ID?) EST 1 . 9 UGM. -'Mr 3
EST O. 018 UGM .- Mt-3
EST 0.17 UGM. .-'Mt-3
EST 0 063 UGM --M-t-3
C5H1003 ISOMEPS
C5H 100? ISOMEPS
HOOC > Ch2 '' 50N02
HOOC f CH2 •' 40N02
H C 0 •: C H 2 ) 6 0 N f 3 2 + I S 0 M EPS
H C 0 < C H 2 %' 5 0 1 -1 1 1 2 + I 3 0 M E P. S
H C 0 < C H 2 ' 4 0 N ( 1 2 + I S 0 M E P S
HOOC'-. CH2) 3CUON02
H C 0 '" C H 2 •' 5 C 0 r i N 0 2 + I S 0 M E P S
HCO '.' CH2 '4 C Oi IN02+ I SOMEPS
EST
EST
EST
EST
EST
0.
0.
C
0.
0 .
O 9 9
0 8 1
0 1 8
031
027
UGM
UGM
UGM
UGM
UGM.
--'M-t 3
•'M-t-3
.••M-t 3
-- M -t- 3
.--M-t-3
EST 0. 072 UGM.
EST 6. 054 UGM
EST 0. 013 UGM.
EST 0 067 UGM
EST 0. 067 UGM
-M-t-3
-M-t-3
--M-t-3
" M-t-3
CPU. F"LE 0057
C6H602 ISOMEIPS
'DATE Of"12575, TENTATIVE: TOLUENE PPODUi!
EST 0. 63 UGM. .-'Mt-3
192
-------
PAGE 803.
C6H802 ISOMKRS
C7H1002 ISOMERS
C5HS03 ISOMEIRS
CPD. F::LE 0053,
C9H1402 ISOMERS
C10H1602 ISOMERS
C10H 1.403 ISOMERS
EST 0.24 UGM. /M + 3
EST 0.11 UGM. /-M-t-3
EST 0. 24 UGM. /M-t-3
DATE 002575, TENTATIVE-
EST 0. 031 UGM. /M-t-3
EST 0.11 UGM. .-"M'T-3
EST 0. 049 UGM. /M-t-3
TERRENE PRODUC"S
C10H1603 EST 0.013 UGM .-"M-t-3
CPD.
SULFATES
AMMONIUM
AMMONIUM
F:LE 0059,
AS SULFUR 1C
CHLORIDE
NI"RATE
SODIUM NITRATE
?HATE 082575, INORGANIC COMPOUNDS
ACID 4 5.1 UGM. xM-t-3
31.1 UGM. .''M-r-3
2 0. 80 UGM. .-'M't-3
1 0.13 UGM. .--M't-3
CPU. F::LE 0060, DATE 002575, CHLORINA~ED COMPOUNDS
C5H5CL EST 0.036 UGM. /M-t-3
193
-------
HOLIDAY INN 01-550 9/6/73 TO :. 130 9/6/73 CDT
SLH10F
FILE NO. 0001, FIT TOL. 003 RUN 0001 TO RUN 0030
DATE 122873, PASS3 ERROR 26 CM ILLI MASS>
TOTAL SAMPLE:=O. 532E +1 CUB::C METERS, ALT01101=0. 100E +0
INST. SENSI"IVITY = 0. 375E +?.i
CHECK HEIGH" PAT 10 = 0. 509 < FRACT I ON V. SMOOTHED
CPD. F.:LE 0051, DATE 002575. HYDROCAREJONS
TOTAL ALKANEIS
ALKANES LOU MW
ALKANES MED. Ml.. I
ALKAHES HI MW
TOTAL ALKEHEIS
CL 1.3 UGM. /Mt-3
CL 8.11 UGM. /M-t-3
CL 0. 54 UGM. /Mt-3
CL 8. 43 UGM. /M-t-3
1. 4 UGM. /M-t-3
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI tlW
ALPHA PINENE:
TERRENES fnS PINEHE
CL 8. 856 UGM.
CL 8. 46 UGM. / M-t-3
CL 8. 83 UGM. .-- M-t-3
1 . 5 UGM. /M-t-3
CL 8. 66 UGM. /M-t3
XYL E H E S, M 0 N S UB B E NZ EN E S CL 0.62 U G M. /M + 3
XYLEHES, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHEHYL
CL 8. 18 UGM. /M-t-3
CL 2.2 UGM. /M-t-3
CL O. 14 UGM. /Mt-3
1 8. 27 UGM. /M-t-3
D I P H E N Y L M E " H A N E + I S 0 M E P S C L 0 . 0 6 7 U G M .- M t- 3
BIPHEHYL ETHANE />• ISOMERS L 0 059 UGM /M-t-3
CPD. F::LE 0052. HATE 002575. POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 8.18 UGM./Mt3
METHYL NAPH"HALEHES+IHT. L 8.868 UGM -'M-t-3
ALKYL NAPHTHALENES C12H12 L 0.825 UGM ,-M-t-3
AHTHPHCENE-PHENAHTHREHE 2 8. 823 UGM /M-t3
P Y P E H E ••• I 3 0 M E P S C 1 6 H 1 0 L 0. 8 2 3 U G M . / M -t- 3
C H R Y S E N E . I ?:, 0 M E P S C 1 8 H 12
PERYLENE. ISOMEPS C28H12
BENZOPEPYLENE+INTEPFEP.
L 0. 8071 UGM. /M-t-3
L 8.014 UGM. /Mt-3
E O. 816 UGM .--M-t-3
CPU. F7.LE 9053, DATE OB2575, AROMATIC OXYGENATED CPUS
CPESOLS (BENZYL HLCOHOL ? "> CL 8.856 UGM •-M-t-3
P H E N 0 L + H 0 2 , i.. H 0 . C 0 2 H ? E S T . 8.2 5 U G M . / M -t- 3
TPIMETHYLPHEIHOL+ISOMEFS EST 8.874 UGM. /M-t 3
DIHYDROi'i'i'BENZENES 1 8.18 UGM. Tit 3
BENZOQUINONE: L 0. 022 UGM --M-t-3
NAPHTHOOUTNONE-'
BENZALDEHYDE: • +IHTEPF
PHENOL
EST O. 8058 UGM. /M-t-3
• L O . 8 1 5 U G M .-- M t- 3
1 0. 074 UGM /M-t-3
194
-------
PAGE 092.
CPD. F:LE 0054, DATE 082575, CARBOXYL::C ACIDS
BENZOIC AC IB 2
METHYL BENZOIC ISOMERS EST.
TRI METHYL BE:HZOIC ISOM. EST
PENTANDIOIi:: ACID EST.
HEXANDIOIC ACID 4
METHYLHEXANDIOIC ACID 1
BEMZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID) EST
0.079 UGM./M-t-3
0. 076 UGM. /M-t-3
0.612 UGM. /M + 3
1. 0 UGM. /M-t-3
1. 7 UGM. /M-t-3
0. 52
0. 34
0. 51
UGM. /M-t-3
UGM. /M*3
UGM. /M-t-3
CPD. F::LE 0055, DATE 082575, NITROGEN COMPOUNDS
CH2CN FRAGME:NT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
PYRIDINE + F:'YRIDYL CPUS L
0. 79 UGM. .•-M-t-3
2. 3 UGM. /M-t-3
8. 096 UGM. .""M-t-3
0. 22 UGM. .-"M-t-3
0. 0043 UGM. .---M-t-3
CARBAZOLE
NITRONAPHTHHLENE
L 0.015 UGM. /Mt-3
EST 0. 8030 UGM. .'-M-t-3
CPD. F:LE 0056, HATE 082575, POSSIBLE SEC.
C7H1204 (ME"HYL ADIPIC) DUP 2.2 UGM. /M-t-3
C8H503 (PHTHALATES) 3.
C7H1403 ISOHERS EST 0.
C7H1203 ISOMERS EST 0.
C6H1203 ISOMERS EST 0.
DIFUNCTIONRLS
1 UGM. /M-t-3
091 UGM.
44 UGM. /M-t-3
37 UGM. /M-t-3
C5H804 (GLU"ARIC ACID?)
C7H1202 ISOHERS
C5H1003 ISOHERS
C5H1002 ISDMERS
HOOC(CH2)50N02
HOOC(CH2)40H02
HCOCCH2)40H02+ISOMERS
HCO(CH2)4COONO
EST 2. 1 UGM. /M-t-3
EST 0. 080 UGM. /M't-3
EST 0.11 UGM. /M-t-3
EST 0.15 UGM. /M-t-3
EST 0. 045 UGM. /M-t-3
EST 0. 36 UGM. /M-t-3
EST 0. 035 UGM. /M-t-3
EST 0. 091 UGM. /M-t-3
CPD. F::LE 0057,
C6H602 ISOMEiRS
C6H802 ISOMEIRS
C7H1002 ISQMERS
C5HS03 ISOME:RS.
CPD. F::LE 0053,
C9H1402 ISOnEPS
C18H1403 ISOMERS
DATE 982575, TENTATIVE
EST 0. 88 UGM. /M-t-3
EST 0.12 UGM. /M-t-3
EST 0. 075 UGM. /M-t-3
EST 0. 27 UGM. /M-t-3
DATE 082575, TENTATIVE!
EST 0. 070 UGM /M-t-3
EST 0. 065 UGM /M-t-3
TOLUENE PRODUC'
TERPENE PRODUCE'S
195
-------
PAGE 003.
C3H1204 'CNOF'PINIC ACID?>EST 0.055
C9H1404 ''.PINIC ACID?) EST 0.955
UGM
UGM./M't
CPD.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
NI"RATE
SODIUM NITRATE
DATE 682575, INORGANIC
ACID 4 20. UGM. /M-t3
31.7 UGM. ''M-t-3
21.8 UGM. .-'M-t-3
1 0. 24 UGM. .-'M't-3
COMPOUNDS
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
196
-------
HOLIDAY INN 1145 9/6/73 TO 1.545 9/6/73 CDT
SLH11F 1-32
FILE HO. 8001, FIT TOL. 883
CHECK HEIGH" RAT 10 = 0. 500 ('.FRACTION), SMOOTHED
CPD. F:LE 0051, DATE 0*32575,
HYDROCARBONS
TOTAL ALKANEES
ALKAHES LOU MW
ALKANES MED. MW
ALKANES HI HW
TOTAL ALKENEES
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI riW
ALPHA PINENEE
TERRENES AS PINENE
CL 1.1 UGM. /M*3
CL 0.20 UGM. /M + 3
CL 0. 36 UGM. /M-t-3
CL 0.18 UGM./M+3
1. 1 UGM. /M-t-3
CL 8.19 UGM. /M + 3
CL 0. 48 UGM. /M-t-3
CL 0. 33 UGM. /M-t-3
1.0 UGM./M*3
CL 0.67 UGM./M+3
XYLENES, MOH SUB BENZENES CL 0.55 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.13 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 1.5 UGM./M-t3
ALKYL BENZENES C18H14 CL 8.19 UGM. /M-t-3
BIPHENYL 1 0.41 UGM. /M-t-3
DIPHENYL ME"HANE+ISOMERS CL 8.057 UGM./M+3
CPD. F::LE 0052, DATE 902575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 8.13 UGM. /M-t-3
METHYL NAPH"HALENES+INT. L 0.071 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.014 UGM./M*3
ANTHRACENE-F:'HENANTHRENE
PYRENE & ISOMERS C16H18
2 0.821 UGM./M+3
L 8.0066 UGM./M*3
CHRYSENE, ISOMERS C1SH12
PERYLEHE, ISOMERS C28H12
BENZOPERYLEHE+INTERFER.
DIBENZANTHRACENES C22H14
L 8.015 UGM /M + 3
L 0. 8873 UGM. /Mt-3
E 8. 8855 UGM. /M-t-3
E 0.018 UGM /M-t-3
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATED CPUS
CRESOLS (BENZYL ALCOHOL?)CL 8.870 UGM /M-t-3
PHENOL + N02, CHO, C02H? EST. 8.34 UGM. /M-t-3
TRIMETHYLPHEIHOLH-ISOMERS EST 8.28 UGM. /M-t-3
DI H Y D R 0 X Y B E N Z E N E S 1 8.881 U G M . / M -t- 3
NAPHTHOQUINGNE? EST. 8.012 UGM. /M-t-3
BENZALDEHYDEE < + INTERF .
PHENOL
L 8. 837 UGM /M-t-3
1 8.12 UGM. /M-t-3
197
-------
PAGE 802.
CPD. F::LE 0054, BATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2
METHYL BENZOIC ISOMER3 EST.
ETHYL BENZOIC ISOMERS EST.
TRI METHYL BENZOIC ISOM. EST
PENTAND I QIC ACID EST.
0. 093
9. 066
0. 028
O. 038
UGM /M-t-3
UGM /M-t-3
UGM./M*3
UGM. /M-t-3
1 . 3 UGM. /M-t-3
HEXANDIOIC ACID 4
METHYLHEXAHDIOIC ACID 1
BENZOYL ION (ARBITRARY)
ACIDS '.:A3 ACETIC ACID) EST
1 . 3 UGM. /M-t-3
1 . 0 UGM. /M-t-3
0. 27 UGM. /M-t3
0. 60 UGM. /M-t-3
CPD. F:LE 0055, DATE
CH2CH FPAGMEINT ('RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5H2 FRAGMENT (RELATIVE)
CH2H03 FRAGMENT EST
CARBAZOLE L
0. 093
0. 021
0. 036
0. 01 1
UGM. /M-t-3
UGM. /M-t-3
UGM ''M-t-3
UGM. /M-t-3
ACRID I HE & :30MEPS
L 8. 9065 UGM. /M-t-3
NITRQHHPHTHHLENE
PYRIDINE 3ULFATE
EST 0. 0016 UGM /M-t-3
EST 0. 026 UGM. /M-t-3
CPD. F"LE 0056, HATE 802575, POSSIBLE SEC. DIFUHCTI ONflLS
C8H503 40N02
H C 0 < C H 2)6 0 H02 +I 30 HERS
H C 0 f. CHS ) 5 0 N f 12 + I 3 0 M E R S
H C 0 •:. C H 2 ) 4 0 N H 2 + I S 0 M E R S
EST 0.13 UGM. /M-t-3
EST 0. 50 UGM. /Mr3
EST 0. 23 UGM. /Mt-3
EST 8. 88 UGM. .'M-t-3
EST 0. 66 UGM. /M-t-3
EST 0.15 UGM. /M-t-3
EST O. 067 UGM /M-t-3
EST 0. 20 UGM. .'Mt-3
EST O. 087 UGM. /M-t-3
198
-------
PAGE
HCO5COON02+ISOMERS EST
HCCKCH2>3COONQ2+ISOMERS EST
HCO3COONO EST
9.14 UGM. /M + 3
0. 073 UGM. /M-T-3
0. 033 UGM. /M-r-3
0. 080 UGM. /M-r-3
CPD. F::LE 0057,
C6H602 ISOMEIRS
C6H8Q2 ISOMEIRS
C7H1002 ISOMERS
C5H803 ISOMEIRS
C7H7H04 ISOriERS
DATE 082575, TENTATIVE!
EST 0. 68 UGM. /M-T-3
EST 9. 67 UGM. /M-T-3
EST 0. 093 UGM. /M-r-3
EST 0. 46 UGM. /M-T-3
EST 0. 0073 UGM. .-"Mt-3
TOLUENE PRODUCES
CPU.
C10H1602
C10H1403
C18H1603
F::LE 0058, DATE 002575, TENTATIVE: TERPENE PRODUC'
ISOMERS EST 0.14 UGM. /M-t-3
ISOMERS EST 0.033 UGM. /M-T-3
EST 0.040 UGM /M-t-3
C8H1204 CNOFJPINIC AC ID?) EST 0.046 UGM. /M-T-3
CPU.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0053,
AS SULFUR 1C
CHLORIDE
HT'RATE
SODIUM NITRATE
DATE 082575, INORGANIC COMPOUNDS
ACID 4 6.0 UGM. /M-T-3
3 0. 64 UGM. /M-T-3
2 0. 67 UGM. /M-T-3
1 0.41 UGM. /M-T-3
CPU. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
C5H5CL
-------
HOLIDAY INN 1550 9-'6.--73 TO 2230 9.-'b.''73 GET
SLH12F 1-30
FILE NO. 00 Hi.- FIT TOL. 003 ','M I LL I MASS > PUN 6001 TO PUN 0070
EmTE 122873, PnSS3 ERROR 26 •' M ILL I MASS >
TOTAL SnNFL[>0. 720E +1 CU3"C METERS. AL IG1UOT--0. 1POE +0
IHST. SEHSI"IVITY=G. 375E +*:>
CHECK HEIGH" PAT 10 = 0. 580 •'. FPAl T I ON .'•, SMOOTHED
C P H F : L E 0 051, D H T E 0 f; 2575. H V 3 R 0 C A R E3 01J £
TOTAL ALKm-IEIS CL 1.0 UGM. •'l-l-t.3
ALKuNES LOU MM CL 0 12 UGM. -'M-t3
H L f- M N11S MED. II '0 C L 0.47 U G M . • M t- 3
H L f- H N E S HI f! M C L 0 . 2 S U G M . -' M t- 3
TOTAL H!_! ENE.S 1 . 4 UGM --Tit 3
ft L. f. E N E S L 0 U M U C L 0. 0 4 4 U G M ••• M t- 3
HLKENES MED. MM CL 0.53 UGM..-Mr 3
HL^ENES HI M''1 CL 0.60 UGM. /M t-3
ALPHA PINENi; 1.2 UGM .--Mt3
TERPENE3 PS PIMENE CL 0.59 UGM./M-t3
XVLEHES. MON SUB BENZENES C L 0 54 UGM..-'Mr-.3
HYLENES. ETHYL BENZENE CL 0 13 UGM . Mt-3
HLKYL BENZENES :?H12 CL 1.7 UGM. ,- M13
ri L \"f L BENZENE S C 1 0 H 1 4 C L 0 1 7 U G M . . M -t- 3
BIPHENYL 1 0.13 UGM. ."Mt-3
BTPHENYL ME'"HHNE+1SOMEPS CL 0 034 UGM •T'U3
DIPHENYL ETHANE ': I SOMEPS L 0 014 UGM -'Mt-3
CPU. F"LE 0052, JnTE '3::'i2575. POLYCYCL iiC HYDROCARBONS
H A P H T H H L t N E 10. 0 8 5 U G M ••- M t- 3
METHYL NriPH""HALENES+IHT. L 0.025 UGM /Mt-3
HLM'L NnPHTH^LE'iZS C12H12 L 0 014 UGM -Mt-3
ANTHRHCENE-f'HENi-i-ITHREIIE 2 0 012 UGM -'Mt-.S
P Y P E N E i'- I S H M E F'S C 1 6 H I 0 L 0 .034 U G M - • M -t- 3
C H P Y S E N E . !'•• 0 M E P S C 1 S H 1 2 L 0 . 0 1 9 U G M -• M -t- 3
PEP'i'LENE.. I'.CMEPS C20H12 L 6.6067 UGM. M13
B E N 2 0 P E P Y L1NE+INTERFEP E 0 . 0 0 3 1 U G11. .- M -t 3
C 0 R 0 N E N E - E O . 0 0 4 4 U Gil. -•" M t 3
CPD F..LE 0053, HATE 0^2575. AROMATIC OXYGEHrnTE.'.! CPUS
CPESOLS (BENZYL :iLC OHOL ?) CL 0.050 UGM -"Mt-S
PHENOL i U02. ( '-10. C'DzH"5 EST. 0.2^ U-1M. "Mt-3
T R I M E T H Y L F1 H f i -' '•'}!_ '-1 S 0 M E R 5 E S T 0 . 0'!' 9 U G M •- M t- 3
DIHYBPOXYFOIZENES 1 0.11 UGM . T'1t3
BENZor'UiNiru: L o 0047 UGM -11+3
B E N Z H L n E11',' DI [ '. + I NT E R F .) L 0 . U 2 6 U G M , M t- 3
PHENOL 1 0. 10 UGM .-'Mt.3
200
-------
PAGE 002.
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BEHZOIC AC 13) 2
METHYL BEHZOIC ISOMERS EST.
ETHYL BENZOL ISOMERS EST.
TR I METHYL BEINZQIC I SOU. EST
PENTAND 101C ACID EST.
HEXAND IOIC HCID 4
METHYLHEXANHIOIC ACID 1
BEHZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID) EST
0. 068 UGM /M-t-3
0. 023 UGM /M-t-3
0.023 UGM /M+3
0. 0085 UGM. /M-t-3
1. 1 UGM. /il-t-3
1. 9 UGM. /M-t-3
0. 75 UGM. /M-t-3
0. 26 UGM. .--M-t-3
0. 35 UGM. /M-t-3
CPD. F::LE 0055, DATE
CH2CN FRAGMENT (RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
002575, NITROGEN COMPOUNDS
1 . 1 UGM. /M-t-3
2. 7 UGM. /M-t-3
0.18 UGM. .-'M-t-3
0. 028 UGM. /M-t-3
0.018 UGM. /M-t-3
C4H9N2 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPUS L
PI PER IDINES ( + ISOMERS > EST
CARBAZOLE L
ACRIDINE & ::SOMERS L
QUINCLINE (--INTERFER?:' L
PIPERAZINE? EST
NITRONAPHTHnLENE EST
0.10 UGM. .--M-t-3
0. 0622 UGM. /M-t-3
0. 036 UGM /M-t-3
0.014 UGM. /M + 3
0. 0832 UGM. .--M-t-3
0.0030
0.0018
0.0014
UGM. /Mi-3
UGM. /M-t-3
UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, POSSIBLE SEC.
C7H1204 (ME"HYL ADIPIC) DUP 0.74 UGM. /M-t-3
C8H503 (PHTHALATES) 4.
C7H1403 ISOMERS EST 0.
C6H1004 CAD::PIC ACID) DUP 0.
C7H1203 ISOMERS EST 0.085 UGM./M-t-S
DIFUNCTIONALS
1 UGM. /M-t-3
087 UGM. /Mt-3
85 UGM. /M-t-3
C6H1203 ISOMERS
C5H804 (GLU"'ARIC
C7H1402 ISOMERS
C6H1803 ISOMERS
C7H1202 ISOMERS
C5H1003 ISOMERS
EST 0. 23 UGM. /M-t-3
ACID?) EST 0.37 UGM./M-t-3
EST 0. 089 UGM. /M-t-3
EST O. 063 UGM. /M-t-3
EST 0. 10 UGM. /M-t3
EST 0. 26 UGM. /M-t-3
C 4 H 6 0 4 ( S LI C C I N I C ACID?) EST 0. 5 9 U G M . / M -t- 3
C6H1202 ISOMEPS EST 0.12 UGM./M-t-3
C 5 H 1 0 0 2 I S 0 M E R 3 EST 0.2 9 U G M . / M -t- 3
HOOC(CH2:.'50H02 EST 0.13 UGM. /M-t-3
201
-------
PAGE 003.
HOOCO::H2.:'40N02 EST
HCO < CH2 ':' 50N02+ I SOMER? EST
H C 0 '.: C l-l £ .:' 4 0 N (J £ + I S 0 M E R S EST
H 0 0 C •: C H 2 .:' 4 C 0 0 H 0 2 EST
HCO (. CH2 :' 5C OON02+ I SOMERS EST
0. 059
0. 874
0. 044
0.018
UGM /M-r3
UGM /M-*3
UGM. /M-t3
UGM. /Mt-3
0.14 UGM. /M-t-3
H C 0 < C H 2 > 3 C 0 0 H 0 2 + I S 0 M E R S E S T 0.044 U G M .-" M -t- 3
CPU. F::LE 0057, DATE 082575. TENTATIVE TOLUENE PRODUC
C6H602 ISQMELRS
C6HS02 ISOMEIPS
C7H1002 I SOMERS
C5H303 ISOME:RS
C5H604 I SO HEIRS
EST O. 93 UGM. .'M-t-3
EST 6. 82 UGM. .-"M-t-S
EST 0.19 UGM. .-'Mt-3
EST 0. 46 UGM. .•"M-t-3
EST 0.11 UGM. .--M-t-3
C6H804 ISQMKPS
C7H7H04 I SOMERS
EST 0. 963 UGM. /M-r-3
EST 0.0018 UGM.
CPD. F::LE 00
C3H1402 I SOMERS
C18H1602 ISDMEPS
ClOH 1403 ISOMEPS
C10H1603 '.:P::HONIC:
;8, HATE 082575, TENTATIVE
EST 0. 018 UGM /M-t-3
EST 0. 037 UGM. /M-t-3
EST 0. 12 UGM. /M-t-3
ACID ? ) EST 0.029 U G M / M t- 3
TERPENE PRODUCT'S
C 8 H1 2 0 4 f. N 0 R P I H I C MOID ? ) EST 0.044 U G M / M -t- 3
C P D
SUL.FHTES
AMMONIUM
AMMONIUM
F'.LE 0059.
AS SULFUR 1C
CHLORIDE
NI"RHTE
iODIUM NITRATE
DATE 08Z57T. INORGANIC
ACID 4 9.2 UGM. /M-.-3
3 0. 88 UGM. ,-"M-t3
21.1 UGM. /M-t-3
1 0. 24 UGM. /M-t-3
COMPOUNDS
CFD. F::LE ooeo,
C5H5CL N'HEP"ACHLOP?>
DATE OB2575.,
EST 0.28
CHLORINA"
UGM./M*3
'ED COMPOUNDS
202
-------
HOLIDAY INN 2248 9/6x73 TO 0810 9/7/73 CDT
SLH13F €7-97
FILE HO. 0901, FIT TOL. Q03 (MILL I MASS) RUN 9067 TO RUN 0097
DATE 122973, PASS3 ERROR 26 CM ILL I MASS)
TOTAL SAMPLERS. 188E +2 C\JB"C METERS, ALIQUOT=0. 100E +0
INST. SENSI"IVITY=0. 177E +!5
CHECK HEIGH" RATIO=0. 590 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 0*33575,
HYDROCARE30NS
TOTAL ALKANE:S
ALKAHES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE:S
ALKENES LOW MW
ALKEHES MED. MW
ALKENES HI MW
ALPHA PIHEHE:
TERPEHES A3 PINENE
CL 0. 76 UGM. /M-t-3
CL 0. 065 UGM /M-t-3
CL 0.44 UGM./M + 3
CL 0.11 UGM. /Mt-3
0. 99 UGM. /Mt-3
CL 9. 842 UGM. /M-t-3
CL 0. 53 UGM. /M + 3
CL 0. 32 UGM. /Mt-3
1 . 1 UGM. /Mt3
CL 0. 43 UGM. /Mt-3
XYLENES, MOH SUB BENZENES CL 6.33 UGM. .-'M-t-3
XYLENES, ETHYL BENZENE CL 0.11 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 1 . 4 UGM. /Mt-3
ALKYL BENZENES C10H14 CL 0.050 UGM. /M-t-3
BIPHENYL 1 1.0 UGM. /Mt-3
DIPHENYL ME"HANE + ISOMERS CL 0.046 UGM. /Mt-3
DIPHENYL ETHANE & ISOMERS L 0.015 UGM./Mt-3
CPD. F:LE 0052, DATE 082575, POLYCYCLIC HYDROCARBONS
NAPHTHALENE 1 0.11 UGM./M-t-3
METHYL NAPH~HALENES+INT. L 0.04S UGM /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.011 UGM. /M-t-3
2 0. 020 UGM /M-t-3
L 0.0S2 UGM /M*3
ANTHRACENE-PHENANTHRENE
PYRENE & ISOMERS C16H10
CHRYSENE, ISOMERS C13H12
PERYLENE, ISOMERS C20H12
BENZOPERYLENE+INTERFER.
L 0. 028 UGM. /M-t-3
L 0.027 UGM./M + 3
E 0. 0092 UGM. /Mt-3
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATE:: CPUS
CRESOLS (BENZYL ALCOHOL?>CL 0.026 UGM /M-t-3
PHENOL + N02, OHO, CQ2H? EST. 0.13 UGM. /M-t-3
TRIMETHYLPHEINOL+ISOMERS EST 0.046 UGM. /Mt-3
D I H Y D R 0 X Y BENZENES 10.0 8 3 U G M / M -t 3
BENZOQUIHONE: L 0.0057 UGM./Mt-3
BEHZALDEHYDE:
PHENOL
•INTERF )
L 0.017 UGM /M-t-3
1 0.061 UGM. /Mt-3
203
-------
PAGE 802.
CPD. F::LE 0054, DATE 002575. CARBOXYL::C ACIDS
BEHZOIC ACI]1 2
METHYL BEHZOIC ISOMERS EST.
ETHYL BEHZO"C ISOMERS EST.
TRI METHYL BF-NZOIC ISOM. EST
PENTAHDIOIC ACID EST.
0. 831 UGM. xM-t-3
O. 052 UGM .-'M-t3
0. 0075 UGM. xM-t-3
0. 026 UGM /M-t-3
0. 54 UGM. .-'Mt-3
HEXAHDIOIC ACID 4 0.96 UGM.xM-t-3
METHYLHEXANIHOIC ACID 1 0.11 UGM. xM-t-3
B E N Z 0 '•(' L I 0 H ''I ARBITRARY > 0 . 2 1 U G M . / M + 3
ACIDS CAS ACETIC ACID) EST 0.41 UGM. .--M-T-3
CPD. F::LE 0055.. DATE
CH2CN FRAGMEIHT
PIPERAZINE'1
NITROHAPHTHALENE
PYRIDINE SULFATE
021 UGM x M-t-3
0079 UGM. .--M-t-3
00 S3 UGM xMt-3
0 0 5 2 U G M . .-- M "?• 3
L O 00S4 IIGP .--M-t-3
EST 0 0015 UGH. x M-t-3
E S T 0.0 0 1 0 U G M . -- M t- 3
EST 0. 070 UGM xM-t3
CPD. F::LE oose, DATE 802575, POSSIBLE SEC. DIFUHCTIONALS
CSH503 CPHTHALATES)
C7H1403 ISOHERS EST
C6H1Q04 CAD::PIC ACID) DUP
C7H1203 ISOMERS EST
C6H1203 ISOMERS EST
8 UGM. xM-t-3
042 UGM x M-t-3
7 UGM. x M-t-3
047 UGM x M-t-3
0.12 UGM. x M-t-3
C5H804 :. C H 2 ':< 5 01 U'i 2 + I S 0 M E R S
H C 0 r: C H 2 "' -! 0 N f 12 + I 'E. 0 M E R S
EST 0. 079 UGM x M-t-3
EST 0. 079 UGM xM-t3
EST 0 063 UGM -•' M-t-3
EST 0. 063 UGM x M-t-3
EST 0. 031 UGM.
204
-------
PAGE 0@3.
HOOC4COOH02 EST
HOOCCCH2)3COON02 EST
HCO3COOHO EST
0. 015 UGM. /M-t-3
0.021 UGM./M-t-3
0. 026 UGM. /Mt-3
0.11 UGM. /M-t-3
8. 826 UGM. /Mf-3
CPD. F::LE 0057.
C6H6Q2 ISOMHRS
C6H802 ISOMEIRS
C7H1002 ISOMERS
C5H803 ISOMEERS
C5H604 ISOMEERS
DATE 092575, TENTATIVE! TOLUENE PRODUCTS
EST 0. 69 UGM. /M-t-3
EST 0. 42 UGM. /M-t-3
EST 0. 26 UGM. /M-t-3
EST 0.11 UGM. /M-T-3
EST 0.036 UGM. /M + 3
CPD. F::LE 0053, DATE 0*32575,
C9H1402 ISOMERS EST 9.036
C18H1603 EST 0.615
C9H1404 CPINIC ACID?> EST 0.034
TENTATIVE:
UGM. /M-t-3
UGM /M-t-3
UGM. /M-t-3
UGM /M-t-3
TERPENE PRODUCTS
CPD. F::LE 0059, HATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 5.1 UGM./M+3
AMMONIUM CHLORIDE 3 1.4 UGM. /M-t-3
21.9 UGM. /M-t-3
1 0.11 UGM. /M-t-3
AMMONIUM NI"RATE
SODIUM NITRATE
CPD. F::LE 0060, DATE 002575, CHLQRINA~ED COMPOUNDS
C5H5CL EST 0.023 UGM. /M-t-3
205
-------
HOLIDAY INN 1018 9-'9/73 TO OS 15 9x11x73 CDT
SLH16F 34-69
FILE NO. 0001, FIT TOL. 003
DATE 122973, PASS3 ERROR 26
TOTAL SAMPLE:=@. 216E +2 CUB
IHST. SENSI"IVITY=0. 690E +4
CHECK HEIGH" RAT I 0 = 0. 500 < TRACT I OH ) ,
< MILL I MASS)
-------
PAGE 082.
TRI METHYL BEINZOIC ISOM. EST
PENTANDIOIC ACID EST.
HEXANDIOIC fiCID 4
METHYLHEXANinOIC ACID 1
BENZOYL I OH (ARBITRARY)
0. 0077 UGM. /M*3
0.51 UGM. /Mt-3
0. 85 UGM. .-'M-t-3 .
0. 660 UGM. /M-t-3
0. 24 UGM. /M-t-3
ACIDS
-------
PAGE 1383.
CPD.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
NI"RATE
SODIUM NITRATE
HATE 082575, INORGANIC COMPOUNDS
ACID 4 49. UGM./M-t-3
3 0. 48 UGM. .'"Mt-3
2 0. 54 UGM. .'M't-3
1 9. 24 UGM./M + 3
CPU. F::LE 0060,
DDT, DDD
LINDAHE
C5H5CL
-------
NATIONAL CT(J 1810 3x19x74 - 2420 8x19x74 CD"
SLN 62 4BBA+4BP 1819-2420
FILE HO. 6002, FIT TOL. 805 CM ILL I MASS) RUN 0876 TO RUN 0910
DATE 031475, PASS3 ERROR 10 O1 ILL I MASS)
TOTAL SAMPLE->0. 85IE +1 CUBT.C METERS, ALIQUOT = 0. 930E -1
INST. SENSI"IVITY = 0. 520E + 5
CHECK HEIGH" RAT 10 = 0. 509
PHENOL
1 0.016 UGM xM-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2
PENTANDIOIC ACID EST.
HEXAHDIOIC AC ID 4
METHYLHEXANDIOIC ACID 1
BENZOYL ION
-------
PAGE QQ2.
CPU. F::LE 0055, DATE
CH2CN FRAGMENT CRELATIVE)
CONH FRAGMENT (RELATIVE)
PYRIDINE + F-YRIDYL CPDS
002575, NITROGEN COMPOUNDS
0.11 IJGM. /M-t-3
0. 49 IJGM. .-'M-t-3
L 0. 0070 IJGM. /M-t-3
P I P E R ID I N E S < + I S 0 M E R S > EST 6 . 0 0 8 3 U G M . / M -t- 3
CPD. F::LE 0055, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
C7H1204
-------
NATIONAL CT" 6845 3/20/74.- 0365 8/20x74 CD"
SLN 63 --2BBA + 2BP 0045-0:505
FILE HO. 0902, FIT TOL. 803 CM ILL I MASS) RUN 0491 TO RUN 0521:3
DATE 031475, PASS3 ERROR 10 (MILL I MASS)
TOTAL SAMPLE: = 0. 336E +1 CUBiiC METERS, ALIQUOT = 0. 930E -1
INST. SENSI"IVITY = 0. 520E +'J
CHECK HEIGH" RAT 10 = 0. 590 (TRACT I OH), SMOOTHED
CPU. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANEES
ALKANES LOU MU
ALKANES MED. MW
ALKANES HI ntJ
TOTAL ALKEHE:S
ALKEHES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERPEHES AS PINENE
CL 0. 33 IJGM. /M-t-3
CL 0. 076 UGM. /M-t-3
CL 8.17 UGM. /M-t-3
CL 0. 023 UGM. /M-t-3
0.51 UGM. /M-t-3
CL @.832 UGM./Mt-3
CL 0.21 UGM. /M-t-3
CL 0.15 UGM. /M-t-3
0. 59 UGM. /M-t-3
CL 0. 29 UGM. /M-t-3
XYLEHES, MON SUB BENZENES CL 0.26 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.044 UGM. /Mt-3
ALKYL BENZENES C9H12 CL 0.89 IJGM./M-t-3
ALKYL BENZENES C10H14 CL 0.086 UGM./M+3
BIPHEHYL 1 2.2 UGM. /M-t-3
DIPHEHYL ME"HAHE+ISOMERS CL 0.012 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.17 UGM. /M-t-3
METHYL NAPH"HALENES+INT. L 0.0090 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.032 UGM./M-t-3
2 0. 020 UGM. /M-t-3
L 0. 10 IJGM. /M-t-3
ANTHRACENE-PHEHANTHRENE
PYREHE & ISOMERS C16H10
CHRYSENE, ISOMERS C18H12 L
PERYLEHE, ISOMERS C20H12 L
BENZOPERYLENE+INTEPFER. E
DIBENZANTHRRCENES C22H14 E
0. 089 UGM /M-t-3
0.19 UGM. /M-t-3
0. 084 IJGM. /M-t-3
8. 068 UGM. /M-t-3
CPD. F::LE 005.3, DATE 082575, AROMATIC
CRESOLS (BENZYL ALCOHOL? ) CL 0.012 UGM . .--M-t-3
PHENOL + N02. CHO, C02H? EST. 0.11 UGM..--M-t-3
TRiMETHYLPHE:NOL+ISOMERS EST 0.024 UGM./M-t-3
D I H Y D R 0 X Y B E N Z E N E S 1 0.040 U G M / M -t- 3
PHENOL 1 0.055 UGM / M-t-3
OXYGENATED CPUS
CPD. F::LE 0054,
BENZOIC AC ID
ETHYL BENZO"C ISOMEPS
HEXANDIOIC ACID
DATE 082575, CARBOXYLiiC ACIDS
2 0. 69 UGM. /Mt-3
EST. 0.017 UGM. /Mt-3
4 0.17 UGM. /Mt-3
211
-------
PAGE 092.
BEHZOYL ION (ARBITRARY)
ACIDS CAS ACETIC ACID,''
EST
1. 5 UGM.>M*3
9. 40 UGM. .''Mt-3
CPD. F:LE 0055, HATE 082575.. NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE? 0.11 UGM..-'M + 3
C3H5H2 FRAGMENT 5COON02+ISOMERS EST 0.11 UGM. .-'M-t-3
DIFUNCTIONALS
CPD. F::LE 0057, DATE 002575, TENTATIVE TOLUENE PRODUC.-S
CSHS02 ISOME:RS EST 0.34 UGM. .--M-t-3
C6H302 ISOME-RS EST 0.049 UGM /'M-t-3
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERRENE PRODUC"S
C9H1402 ISOMERS EST 0.061 UGM
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 5.6 UGM . .'"M-t-3
A M M 0 N I U M C H L 0 R I D E 30.043 U C- M ••' M -t- 3
AMMONIUM NT'PATE 2 0 23 UGM..-Mt-3
CPD. F::LE 0050, DATE 002575,
C H L 0 R I N A " E D C 0 M P 0 U N D S
212
-------
NATIONAL CT" 9315 8/20x74
0790 3/29/74 CD'
SLH 64 0/20/74 0315-0700
FILE HO. 0002, FIT TOL. 003 CM ILL I MASS) RUN 0526 TO RUN 0560
DATE 031475, PASS3 ERROR 10
-------
PAGE Q82.
CPD. F::LE 0055, HATE 0:32575, NITROGEN COMPOUNDS
CH2CN FRAGME:NT cRELATIVE)
CONH FRAGMENT (RELATIVE)
CARBAZOLE L
Q.U INOLI HE '". --1NTEPFER? > L
PYRIDINE SUl.FATE EST
9.15 UGM. /Mt-3
0. 24 UGM. .-71*3
9.010 UGM. .--M-t-3
9. 8024 UGM. /M-t-3
0. 021 UGM /-M-t-3
CPD. F:LE 0055, HATE 002575, POSSIBLE SEC.
C8H503 '.'.PHTHALATES::' 0.90 UGM. .-"M-t-3
C5H804 (GLU"ARIC ACID?) EST 1.1 UGM. /M-t-3
C7H1202 ISOMERS EST 0.11 UGM..-'M-t-3
DIFUHCTIOHALS
CPD. F::LE 0057,
C6H602 ISOMEIRS
C6H802 ISOMEIRS
C5H604 ISOME-IRS
DATE 982575, TENTATIVE! TOLUENE PRODUCES
EST 0.16 UGM. .-'M-t-3
EST 0. 872 UGM. /M-t3
EST 0. 04S UGM. /M-t-3
CPU. F::LE 0053, DATE 002575, TENTATIVE TERRENE
CPD. F::LE 0053,
SULFATES AS SULFUR 1C
A M M 0 H I U M CHI. 0 RIDE
AMMONIUM Ml "RATE
DATE 002575, INORGANIC COMPOUNDS
ACID 4 6.0 UGM.-- M-t-3
30.074 U G M . .-" M -t- 3
2 0.58 UGM. -'Mtj
CPD. F::LE eoee. DATE 002575, CHLORIHA"ED COMPOUNDS
C5H5CL
-------
NATIONAL CT'-1 9765 8/28/74 - 0905 8/28/74 CD"
SLH 65 9705-9995 +2UG. EJBA
FILE HO. 00H2, FIT TOL. 605 RUN 6426 TO RUN 0460
DATE Q31275, PASS3 ERROR 10 CHILLI MASS)
TOTAL SAMPLERS. 238E +1 CUBiiC METERS, ALIQUOT = 0. 930E -1
INST. SENSI"IVITV=9. 350E + 5
CHECK HEIGH" RAT I 0 = 0. 500 , SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARESONS
TOTAL ALKANE:S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE:S
ALKEHES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINEHE:
TERRENES AS PIHENE
CL 8. 52 UGM. /M-t-3
CL 8. 097 UGM. /M-t-3
CL 0. 29 UGM. /M-t-3
CL 0. 045 UGM. /M-t-3
8. 64 UGM. /M-t-3
CL 0. 844 UGM. /M-t-3
CL 0. 42 UGM. /M-t-3
CL 0. 22 UGM. /M-t-3
0. 57 UGM. /M-t-3
CL 0. 23 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL
XYLENES, ETHYL BENZENE CL
ALKYL BENZENES C9H12 CL
ALKYL BENZENES C10H14 CL
DIPHENYL ME"HANE+ISOMERS CL
CPD. F::LE 0052, DATE 08
NAPHTHALENE 1
METHYL NAPH"HHLEHES+INT. L
ALKYL NAPHTHALENES C12H12 L
ANTHRACEHE-F:'HENANTHRENE 2
PYRENE & ISDMERS C16H1B L
CHRYSENE, ISOMEPS C18H12 L
PERYLENE, I30MERS C20H12 L
BENZOPERYLENE+INTEPFER. E
DIBENZANTHRRCENES C22H14 E
CPD. F::LE 0053, DATE 08
CRESOLS (BENZYL ALCOHOL? >CL
PHEHOL + N02 . \.\ HO . COSH? EST .
T R I M E T H Y LPHEINOL + I S 0 M E R S E S T
DIHYDROXYBENZENES 1
BEHZALDEHYDM C+INTERF > L
0
0
0
0
0
0
0
0
0
8
0
0
0
0
2
0
0
o
0
0
. 18 UGM. /M-t-3
.094 UGM /Mt-3
. 98 UGM. /M-t-3
. 15 UGM. /M-t-3
.010 UGM /M-t-3
575, POLYCYCL::C HYDROCARBONS
.827 UGM. /M-t-3
.011 UGM.. --M-t-3
. 0083 UGM. /M-t-3
.012 UGM. /M-t-3
0081 UGM.. /M-t-3
.013 UGM. / M-t-3
.053 UGM. /M-t-3
.038 UGM. /M-t-3
.614 UGM. /Mt-3
575, AROMATIC OXYGENATED CPD3
.019 UGM. /M-t-3
.072 UGM. /M-t-3
. 870 UGM /M-t-3
.013 UGM. /M-t-3
.012 UGM .--M-t-3
PHENOL
1 0. 018 UGM .--M-t-3
CPD. F::LE o@54, DATE 082575, CARBOXYL::C ACIDS
B E H Z 01C A CI ] 'i 20.30 U G M . / M t- 3
P E H T A N D I 01 C ACID EST. 0 . 2 8 U G M . / M -t- 3
H E X A N DI 01C d C. ID 40.6 6 U G M . / M -t- 3
215
-------
PAGE 602.
METHYLHEXANDIOIC ACID
BENZOVL ION
-------
NATIONAL CTV 0915 8/20/74 - 1115 8/2.8/74 CD
15
(MILLIMASS) RUN 0561 TO RUN 059S
(MILLIMASS )
C METERS, ALIQUOT = 0. 930E -1
SLN 66 --2BBA + 2BP 0915-1 r
FILE HO. 0902, FIT TOL. 003
DATE 031475, PASS3 ERROR 10
TOTAL S AMPLE- =0. 288E +1 CUBi
INST. SENSI7IVITY=0. 520E + !>
CHECK HEIGHT RAT 1 0 = 0. 500 (FRACTION), SMOOTHED
CPD. FILE 0951, DATE 082575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI HW
TOTAL ALKENEIS
CL 0. 20 UGM. /M-t-3
CL 0. 047 UGM. /M-t-3
CL 6. 097 UGM. /M-t-3
CL 0. 0093 UGM. /M-t-3
0. 30 UGM. /M-t-3
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MM
ALPHA PINENE: .
TERRENES AS PINENE
CL 0. 029 UGM. /M + 3
CL 0.10 UGM. /M-t-3
CL 0. 033 UGM /M-t-3
0.13 UGM. /M-t-3
CL 0. 063 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.10 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.0090 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 0.16 UGM. /M-t-3
BIPHEHYL 12.5 UGM. /M-t-3
CPD. F~LE 0052, DATE 082575, POLYCYCLIC HYDROCARBONS
NAPHTHALENE 1 0.14 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.082 UGM /M-t-3
CPD. F:LE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.010 UGM./M-t-3
PHENOL + N02, CHO, C02H? EST. 0.13 UGM./M-r3
DIHYDROXYBENZENES 1 0.015 UGM./M-t-3
PHENOL 1 0.037 UGM./M-t-3
CPD. FILE' 0054, DATE 082575, CARBOXYLIC ACIDS
BENZOIC ACID 2 0.66 UGM./M-T-3
PENTAHDIOIC ACID EST. 0.16 UGM. /M-t-3
BEHZOYL ION (ARBITRARY) 1.6 UGM. /M-t-3
ACIDS (AS ACETIC: ACID) EST 0.17 UGM. /M-t-3
CPD. F:LE 0055, DATE 082575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 0.30 UGM. /M-t-3
PYRIDINE + PVR IDYL CPUS L 0.013 UGM./M*3
PIPERIDINE S ( + I S 0 M E R S ) EST 0.022 U G M / M -t- 3
CPD. F::LE 0056, DATE 082575, POSSIBLE SEC. DIFUNCTIONAL;
C8H503 (PHTHALATES) 3.6 UGM. /M-t-3
CPD. F::LE 0057, DATE 082575, TENTATIVE TOLUENE PRODUCES
C6H602 ISOME:RS EST 0.13 UGM./M-t-3
217
-------
PAGE 982.
C6H802 ISQME-RS
C7H1802 ISOMERS
NITROCRESOLS?
CPD. F:LE 0053, DATE 082575, TENTATIVE: TERRENE PRODUCT'S
EST 0. 13 UGM. /M-t-3
EST 0.986 UGM./Mt-3
L 0. 0939 UGM.
CPU.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
NI"RATE
DATE 082575, INORGANIC COMPOUNDS
ACID 4 17. UGM. /M-t-3
3 0. 0046 UGM. /M-t-3
20.10 UGM. /M-t-3
CPD. F7.LE 0060, HATE 082575, CHLORINA"ED COMPOUNDS
C5H5CL
-------
NATIONAL CTV 1280 8/20/74 - 1340 8/29/74 CD'
SLN 67 --2BBA + 2BP 1290-1340
FILE NO. 0902, FIT TOL. 003 CM ILL I MASS) RUN 0536 TO RUN 0630
DATE 931475, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLERS. 240E +1 CUBZC METERS, ALIQUOT=0. 190E +0
INST. SENSI"IVITY=0. 529E +55
CHECK HEIGH" RAT 10 = 0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575,
HYDROCARBONS
TOTAL ALKANE-IS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 0. 081 UGM. /M-t-3
CL 0.0047 UGM./M+3
CL 0. 027 UGM. /M-t-3
CL 0. 017 UGM. /M-t-3
0.14 UGM. /M-t-3
ALKENES MED. MW CL 0.042 UGM./M+3
ALKEHES HI MW CL 0.086 UGM /M-t3
TERRENES AS PINENE CL 0.046 UGM./M-t-3
XYLENES, MOH SUB BENZENES CL 0.064 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 0.093 UGM./M-t-3
BIPHENYL
1 1.0 UGM./M+3
CPD. FILE 0052, DATE 082575, PQLYCYCLHC HYDROCARBONS
NAPHTHALENE 1 9.033 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.0094 UGM./M-t-3
CPD. F::LE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?>CL 0.0039 UGM./M+3
PHENOL + N02, CHO, C02H? EST. 0.018 UGM. /M-t-3
DIHYDROXYBENZENES 1 0.0070 UGM./Mt-3
PHENOL 1 9.0072 UGM./M-t-3
CPD. FT.LE
BENZOIC AC in
HEXANDIOIC PC ID
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID)
0054, DATE 082575,
2 9. 18
40.11
9. 47
EST 0.11
CARBOXYL:C ACIDS
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t-3
UGM. /M-t-3
CPD. F:LE 0055, DATE 082575, NITROGEN
CONH FRAGMENT (RELATIVE) 0.959 UGM. /M-t-3
C3H5N2 FRAGMENT (RELATIVE) 0.22 UGM. /M-t-3
PYRIDINE + PYRIDYL CPDS L 0.0042 UGH. /M-t-3
PIPER I DINES OISOMERS) EST 0.0046 UGM./M-t-3
COMPOUNDS
CPD. F::LE 0056,
C8H503 (PHTHALATES)
CPD. F::LE 0057,
C6H602 ISOME:RS
C7H7N04 ISQMERS
DATE 082575, POSSIBLE
4. 1 UGM. /M-t-3
DATE 082575, TENTATIVE!
EST .0. 059 UGM. /M-t-3
EST 0. 0042 UGM. .--M-t-3
SEC. -DIFUNCTIONRLS
TOLUENE PRODUC"S
219
-------
PAGE 902.
CPD. F::LE 01353, DATE 002575. TENTATIVE TERRENE PRODUCTS
C9H1402 ISOHERS EST 0.093 UGM .
CPD. F:LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 6.5 UGM./M+3
AMMONIUM NI"RATE £ 0.31 UGM. .-'M-t-3
SODIUM NITRATE 1 0.021 UGM./M-t-3
CPU. F::LE 0050, HATE 082575, CHLORINA"ED COMPOUNDS
LINDAHE EST 0.026 UGM. /M-t-3
C5H5CL
-------
NATIONAL CT" 1400 8/20/74 - 1820 8/20/74 CD"
SLN 68 8/20/74 1400-1820
FILE NO. 0002, FIT TOL. 003 (MILLIMASS) RUN 0106 TO RUN 0140
DATE 031875, PASS3 ERROR 10 (MILLIMASS)
TOTAL SAMPLE:=0. 624E +1 CUBHC METERS, ALIQUOT = 0. 930E -1
IHST. SENSI"IVITY=0. 200E +3
CHECK HEIGH" RATIO=0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANE:S
ALKANES LOW MW
ALKANES MED. MW
TOTAL ALKENEIS
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERRENES AS PINENE
CL 0. 29 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
CL 0. 639 UGM /M-t-3
0. 36 UGM. /M-t-3
CL 0. 617 UGM. /M-t-3
CL 9. 15 UGM. /M+3
CL 0.11 UGM. /M-t-3
0.069 UGM./M+3
CL 0. 068 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.12 UGM./M-t-3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
CL 0. 633 UGM. /M-t-3
CL 0.10 UGM. /M-t-3
CPD. FILE 0052,
NAPHTHALENE
DATE 082575, POLYCYCL7.C HYDROCARBONS
1 0. 0064 UGM. /M-t-3
CPD. FVLE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?>CL 0.013 UGM./M*3
TRIMETHYLPHEINOL+ISOMERS EST 0.12 UGM./M-t-3
DIHYDROXYBENZENES 1 0.033 UGM. /M-t-3
PHENOL 1 0.024 UGM./M+3
CPD. F:LE 0054, DATE 082575, CARBOXYL::C ACIDS
METHYL BENZOIC ISOMERS EST.
PENTAHDIOIC ACID EST.
HEXANDIOIC (1C.ID 4
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID) EST
0. 019 UGM /M-t-3
0.91 UGM./M*3
0.11 UGM. /M-t-3
0.10 UGM. /M-t-3
0.23 UGM./M*3
CPD. F::LE 0055, DATE 082575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 0.83 UGM./M-t-3
C3H5N2 FRAGtlENT (RELATIVE) 0.20 UGM. /M-t-3
PYRIDINE + PYRIDYL CPUS L 0.015 UGM. /M-t-3
QUINCLINE (--INTERFER?) L 0.0064 UGM./M-t-3
CPD. F::LE 0056,
C8H503 (PHTHALATES)
DATE 082575, POSSIBLE
1. 8 UGM. /M-t-3
SEC. DIFUNCTIOHALS
CPD. F::LE 0057, DATE 082575, TENTATIVE: TOLUENE PRODUC-S
C6H602 ISOME:RS EST 0.27 UGM./M-t-3
C7H1002 ISOMERS EST 0.10 UGM./M-t-3
221
-------
PAGE 002.
C7H7N04 ISOMERS
EST 0.0987 UGM.xM+3
CPD. F::LE 0059, DATE 002575, TENTATIVE: TERRENE PRODUCES
C9H1402 ISOMERS EST 0.10 UGM./M-t-3
CPU. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 37. UGM./M-T-3
AMMONIUM CHLORIDE 3 0.099 UGM. /'M-t-3
2 0. 24 UGM. /M-t-3
1 0. 031 UGM xM-t-3
AMMONIUM HI"RATE
SODIUM NITRATE
CPD. F::LE 0060,
LINDANE
C5H5CL
DATE 082575, CHLORINA"ED COMPOUNDS
EST 0. 076 UGM. .--M-t-3
EST 0. 43 UGM. .'M-t-3
222
-------
NATIONAL CTY 1835 8x20/74 - 2139 8/29x74 CD"
SLN 69 ?. PUNCHES 1835-2:38
FILE NO. 0902, FIT TOL. 803 CHILL I MASS) RUN 0666 TO RUN 0700
DATE 031475, PASS3 ERROR 10 (MILLI MASS)
TOTAL SAMPLE: = 0. 403E +1 CUBilC METERS, ALIQUOT=0. 190E + 0
INST. SENSI"IVITY = 0. 529E +')
CHECK HEIGH" RAT 10 = 9. 568
-------
PAGE 002.
CPD. F:LE 0055.
C3H503 CPHTHALATES)
C5H1002 ISOMER3
DATE 082575, POSSIBLE SEC.
0. 76 UGM. /M-i-3
EST 0. 030 UGM. /M-t-3
DIFUNCTIONALS
CPU. F::LE 0057,
C6H602 ISQMEERS
C6H802 ISQMEIRS
C7H1002 ISOMERS
NITROCRESOLS?
DATE 082575, TENTATIVE:
EST 0. 24 UGM. .-"M-t-3
EST 0. 053 UGM. /M-t-3
EST 0. 020 UGM. /M-t-3
L 0. 0030 UGM. /M-t-3
TOLUENE PRODUCES
CPD. F::LE 0053,
C9H1402 ISOMERS
DATE 082575,
EST 0.027
TENTATIVE!
UGM. xM-t-3
TERRENE PRODUCE'S
CPD.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059, DATE
AS SULFUR 1C ACID
CHLORIDE
HI"PATE
SODIUM NITRATE
082575, INORGANIC COMPOUNDS
45.4 UGM. /M-t-3
3 0. 030 UGM. xM-t-3
2 0.19 UGM. .--M-t-3
1 0.017 UGM. /M-t-3
CPU. F:LE 0060,
C5H5CL (HEP"ACHLOR?>
DATE 082575,
EST 0.015
CHLORINA"ED
UGM. /M-t-3
COMPOUNDS
224
-------
NATIONAL CP-1 2149 3/20/74 - 8128 8/2.1x74 CD"
SLN7S
FILE HO. 80H2, FIT TOL. 005 (MILL I MASS) RUN 9771 TO RUN 03955
DATE 631475, PASS3 ERROR 19 CM ILL I MASS)
528E +1 CUB::C METERS, ALIQUOT=@. 190E +9
TOTAL SAMPLE:=O.
INST. SENSI"IVITY=0.
529E
CHECK HEIGH" RAT 1 0 = 9. 598 < TRACTION), SMOOTHED
CPD. FT.LE 0951, DATE 982575, HYDROCARE30NS
TOTAL ALKANE:S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE-IS
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERRENES AS PINENE
CL 9.17 UGM. /M-t-3
CL 9. 941 UGM. /M-t-3
CL 0. 973 UGM. /M-t-3
CL 9. 0971 UGM. /M-t-3
9. 28 UGM. /M-t-3
CL 0. 036 UGM. /M-t-3
CL 9.936 UGM./M*3
CL 0. 050 UGM. /M-t-3
0. 28 UGM. /M-t-3
CL 0. 088 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 9.052 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.825 UGM./Mt-3
ALKYL BENZENES C9H12 CL 0.25 UGM. /M-t-3
ALKYL BENZENES C10H14 CL 9.031 UGM. /M-t-3
BIPHENYL 1 0.61 UGM./M-t-3
CPD. F::LE 0052, DATE 992575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.848 UGM./M-t-3
METHYL NAPH"HALENES+IHT. L 0.9871 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 9.0064 UGM./M-t-3
PYREHE & ISOMERS C16H19 L 9.814 UGM./M-t-3
PERYLENE, ISOMERS C20H12 L 0.9936 UGM./M+3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 9.0984 UGM. /M-t-3
PHENOL + H02, CHO, C02H? EST. 0.951 UGM. /M-t-3
.011 UGM./M+3
.914 UGM. /M-t-3
EST.
TR I METHYLPHEINOL+ISOMERS EST
DIHYDROXYBENZENE3 1
BENZALDEHYDEI
PHENOL
•IHTERF. ) L 0.8857 UGM./M-t-3
1 0.8865 UGM./M+3
CPD. F:LE 0054, DATE 08257;;
CARBOXYL:C ACIDS
BENZOIC ACID 2
METHYL BEHZOIC ISOMERS EST.
ETHYL BENZOIC ISOMERS EST.
TR I METHYL BEINZOIC ISOM. EST
PENTAND I QIC ACID EST.
HEXANDIOIC HCID 4
METHYLHEXANDIOIC ACID 1
9.11 UGM. /M-t-3
8. 8977 UGM. /M-t-3
8. 019 UGM. /M-t-3
9. 8855 UGM. /M-t-3
9. 977 UGM. /M-t-3
0.13 UGM. /M-t-3
0.951 UGM..--M-t-3
225
-------
PAGE 802.
BEHZOYL ION
(ARBITRARY)
CPU. F:LE 0055, DATE
COHH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGT1EHT (RELATIVE)
C4H8H2 FRAGflEHT (RELATIVE)
PVR I HI HE + PYRIBYL CPUS L
8. 36 UGM.
082575, NITROGEN
0. 22 UGM. /M-t-3
0.12 UGM. .'M-t-3
0. 24 UGM. /M-t-3
0.015 UGM. /M-t-3
020 UGM. /M-t-3
COMPOUNDS
PIPERIDIHES (+ISOMERSJ EST
ACRID I HE & .'iSOMERS L
QUIHOLIHE (--IHTERFER?) L
0.010 UGM /M-t-3
0.0034 UGM./M + 3
0. 0020 UGM. /M-t-3
CPD. F::LE 0055, HATE 002575, POSSIBLE SEC. DIFUNCTIOHALS
CSH503 (PHTHALATES)
C7H1203 ISOMERS
C6H1203 ISOMERS
C6H1003 ISOMERS
C7H1202 ISOMERS
C5H1003 ISOMERS
C6H1202 ISOHEPS
HOOC
-------
NATIONAL CT" 0130 3/21/74"- 0700 3x21/74 CD'
SLN 71 4.5 HRS 0130-0700
FILE HO. 0002, FIT TOL. 005 (MILL I MASS) RUN 0071 TO RUN 0105
DATE Q31875, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLERS. 648E +1 CUB".C METERS, ALIQUOT=0. 930E -1
INST. SENSI"IVITY=0. 200E +5
CHECK HEIGH" RAT 10 = 0. 500 (FRACTION::'.. SMOOTHED
CPD. F::LE 0051, DATE 092575. HYDROCARBONS
TOTAL ALKANKS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 1 . 2 UGM. /M-t-3
CL 0. 23 UGM. .--M-t-3
CL 0. 63 UGM. /M-t-3
CL 0. 052 UGM. /M-t-3
1.6 UGM./M-t-3
ALKEHES LOW MW
ALKENES MED. MU
ALKENES HI MW
ALPHA PINENE-:
TERRENES AS PINENE
CL 0. 14 UGM. /M-t-3
CL 0.97 UGM./M-t-3
CL 0.32 UGM./M+3
1.8 UGM./M*3
CL 0. 58 UGM. .--M-t-3
XYLENES,MON SUB BENZENES CL 0.33 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.19 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 2.0 UGM./M+3
ALKYL BENZENES C10H14 CL 0.21 UGM. /M-t-3
BIPHENYL
1 0.018 UGM. /M-t-3
DIPHENYL ME"HANE+ISOMERS CL 0.019 UGM./M-t3
CPD. F::LE 0052, DATE 002575, POLYCYCLT.C HYDROCARBONS
NAPHTHALENE 1 0.985 UGM./M*3
METHYL NAPH"HALENES+IHT. L 0.10 UGM. /M-t-3
ALKYL NAPHTHALENES C12H12 L 0.097 UGM./M*3
ANTHRACENE-PHENANTHRENE 2 0.014 UGM..-"M^3
PYRENE & ISGMERS C16H10 L 0.091 UGM. /M-t-3
CHRYSENE, I80MER3 C18H12 L
PERYLENE, IGOMERS C20H12 L
BENZOPERYLENE+INTERFER. E
0. 061 UGM. /M-t-3
Q.15 UGM. .'M + 3
0.15 UGM. /M-t-3
CPD. F:LE 0053, DATE 002575, AROMATIC
CRESOLS CBENZYL ALCOHOL?)CL 0.031 UGM /M-t-3
TRIMETHYLPHEZNOL+ISOMERS EST 9.14 UGM. /M-t-3
DIH Y D R 0 ';< Y BENZENES 1 0. 0 2 3 U G M . / M -t 3
PHENOL 1 0.057 UGM /M-t-3
OXYGENATED CPD3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2
METHYL BENZOIC ISOMERS EST.
PENTANDIOIC ACID EST.
HEXANDIOIC ACID 4
METHYLHEXANUIOIC ACID 1
0. 23 UGM. /M-t-3
0. 023 UGM /M-t-3
1 . 5 UGM. /M-t-3
1.1 UGM. /M-t-3
0. 87 UGM. /M-t-3
227
-------
PAGE 002.
BENZOYL ION (ARBITRARY? 0.6? UGM'./M-t-3
ACIDS (AS ACETIC ACID) EST 0.71 UGM./M*3
CPD. F::LE 0055, DATE 082575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
C4H9H2 FRAGMENT (RELATIVE)
PYRIDIHE + PYRIDYL CPUS L
PIPERIDIHES (+ISOMERS) EST
0. 075 UGM. /M-t-3
0. 62 UGM. /M-t-3
0.13 UGM. /M-t-3
0. 0072 UGM. /M-t-3
0. 051 UGM /M-t-3
CARBAZOLE
ACRIDIHE & ::SOMERS
QU INCLINE (--INTERFER?)
L 0. 0069 UGM. /M-t-3
L 0.010 UGM. /M + 3
L 0. 0037 UGM. /M-t-3
CPD. F::LE 0056,
C8H503 (PHTHALATES)
C6H1203 ISOMERS
C7H1202 ISOMERS
C5H1903 ISOMERS
HCO(CH2)5COON02+ISOMERS
DATE 682575, POSSIBLE SEC. DIFUHCTIONALS
3. 2 UGM. /M-t-3
EST 0. 16 UGM. /M-t-3
EST 0. 20 UGM. /M-t-3
EST 0. 092 UGM. /M-t-3
EST 0. 32 UGM. /M-t-3
CPD. F::LE 0057,
C6H602 ISOMEIRS
C6H802 ISOMEIRS
C7H1002 ISOMERS
C5H803 ISOMEIRS
DATE 082575, TENTATIVE TOLUENE PRODUCES
EST 0. 20 UGM. /M-t-3
EST 0. 53 UGM. /M-t-3
EST 0. 29 UGM. /Mf3
EST 0. 16 UGM. /M-1-3
CPD. F::LE eess, DATE 082575, TENTATIVEI TERPENE PRODUC-S
C10H1603
ACID 4 19. UGM. /M-t-3
3 0. 52 UGM. /M-t-3
24.1 UGM. /M-t-3
1 0. 020 UGM /M-t-3
DATE 082575, CHLORINA"ED
EST O. 094 UGM /M-t-3
EST 0.12 UGM. /M-t-3
COMPOUNDS
228
-------
TYSON VALLE" 1990 9x4/73 TO 1735 9x5x73 CDT
SLT1F
FILE NO. 00«1, FIT TOL. 093 CM ILL I MASS) RUN 0061 TO RUN 0090
DATE 122473, PASS3 ERROR 26 CM ILL I MASS)
TOTAL SAMPLE: = 0. 121E +2 CUB"C METERS, ALIQUOT = 0. 100E +0
INST. SENSI"IVITY=0. 268E + 5
CHECK HEIGH" RAT 10 = 0. 500
-------
PAGE 902.
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVES
C4H8H2 FRAGMENT ''RELATIVE)
C4H9H2 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPUS
0. 47 UGM. /M-t-3
0. 974 UGM. /M-t-3
0. 049 UGM /M-t-3
0.037 UGM./M + 3
L 0. 06062 UGM. /M-K3
PI PER I DINES O ISOMERS) EST
CARBAZOLE L
QU INCLINE (--INTERFER?) L
PYRIDINE SULFATE EST
0. 0049 UGM. /M-t-3
0. 0015 UGM. /M-t-3
0. 0013 UGM. .--M-t-3
0.014 UGM. /M-t-3
CPD. F::LE 0056, DATE 082575, POSSIBLE SEC. DIFUNCTIONALS
C6H1004
-------
TYSON VALLE" 1807 9/5/73 TO 0826 9/6/73 CDT
SLT2F
FILE NO. 0001, FIT TOL. 603 (MILLIMASS) RUN 0031 TO RUN 0060
DATE 122473, PASS3 ERROR 26 GIILLIMASS)
TOTAL SAMPLEI = 0. 155E +2 CUBliC METERS, ALIQUOT = 0. 100E +0
INST. SENSI"IVITY=0. 263E +1)
CHECK HEIGH" RAT 10 = 0. 500 CL 0.011 UGM /M-t-3
PHENOL + N02, OHO, C02H? EST. 0.018 UGM./M-t-3
TRIMETHYLPHEINOL+ISOMERS EST 0.0885 UGM. /M-t-3
DIHYDROXYBENZENES 1 0.0095 UGM. /M-t-3
PHENOL 1 0.0014 UGM. /M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2
METHYL BENZOIC ISOMERS EST.
HEXANDIOIC ACID 4
METHYLHEXANHIOIC ACID 1
B E N Z 0 Y L I 0 N < A R B I T R A R Y >
0. 0046 UGM. /M-t-3
0. 0063 UGM. /M-t-3
0. 097 UGM /M-t-3
9. 044 UGM .--M-t3
8.014 UGM. /M-t-3
ACIDS CAS ACETIC ACID) EST 9.080 UGM /M-t-3
231
-------
PAGE 092.
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMENT (RELATIVE)
COHH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
0.14 UGM. /M-t-3
0. 24 UGM. /M-t-3
0. 069 UGM. /M-t-3
0. 0630 UGM. /M-t-3
0. 037 UGM. /M-t-3
C4H9H2 FRAGMENT (RELATIVE)
PVR I DINE + PVR IDYL CPUS L
PI PER I DINES <+ ISOMERS) EST
A C R I D I N E & :. S 0 M E R S L
PYRIDINE SULFATE EST
0.012 UGM /M-t-3
0.00066 UGM. /M-t-3
0.0064 UGM. /M-t-3
0.0016 U G M . / M -t 3
0.811 UGM. /M-t-3
CPU. F::LE 0056, DATE 002575., POSSIBLE SEC. DIFUHCTIONALS
C8H503 (PHTHALATE5)
0. 027 UGM. /M-t-3
C6H1004 (AD::PIC ACID) DUP 0.29 UGM./M+S
C5HS04 (GLIJ"ARIC ACID?) EST 0.24 UGM..'M*3
C6H1003 ISOMERS EST 0.034 UGM./M-t-3
C7H1202 ISOMERS EST 0.034 UGM. .-'M-t-3
C5H1B02 ISOMERS
HCO(CH2)3COONO
EST 0. 032 UGM. /'M-t-3
EST 0. 924 UGM. /M-t-3
CPD. F::LE 0057, HATE 002575, TENTATIVE TOLUENE PRODUCES
C6H602 ISOMEIRS
C6H802 ISOMEIRS
C7H1002 ISOMERS
C5H803 ISOMflPS
C7H7N04 ISOMEPS
EST 0. 0S0 UGM ..'Mt-3
EST 0.12 UGM. .-'M-t3
EST 0. 037 UGM /M-t-3
EST 0.014 UGM /M-t-3
EST 0. 0019 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERPENE PRODUCTS
C9H1402 ISOMERS EST 0.012 UGM. /M-t-3
CPD. F:.LE 0059, DATE 002575.
INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM HI"PATE
SODIUM NITRATE
ACID 4 2 1 UGM. /Mt-3
3 0. 054 UGM /M-t-3
2 0. 065 UGM /Mt-3
1 0. 032 UGM /M-t-3
CPD. F::LE eeee, DATE 002575, CHLORINA"ED COMPOUNDS
232
-------
TYSON VALUE" 9911 9/6/73 TO 1818 9/6/73 CDT
SLT3F
FILE HO. 0901, FIT TOL. 003 RUN 0891 TO RUN 0830
DATE 122473, PASS3 ERROR 26
TOTAL SAMPLE: = 8. 974E +1 CUB^C METERS, ALIQUOT = 8. 188E +8
IHST. SENSI"IVITY=8. 263E +5
CHECK HEIGH" RAT I 0 = 0. 588 (TRACT I ON), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENE:S
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PIHENE:
TERRENES AS PINENE
CL 8. 23 UGM. /M-t-3
CL 8. 060 UGM. /M-t-3
CL 6.077 UGM./M+3
CL 0. 853 UGM. /M-t-3
0. 33 UGM. /M-t-3
CL 8.018 UGM./M*3
CL 8.11 UGM. /M-t-3
CL 0.10 UGM. /M-t-3
0. 14 UGM. /M-t-3
CL 8.13 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 8.12 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 8.835 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 0.10 UGM./M*3
ALKYL BENZENES C18H14 CL 0.010 UGM. /M-t-3
BIPHENYL 1 8.67 UGM. /M-t-3
DIPHENYL ME-HANE+ISOMERS CL 0.8815 UGM./M+3
DIPHENYL ETHANE & ISOMERS L 8.8843 UGM. /M-t-3
CPD. F::LE 8052, DATE 002575, POLYCYCL:.C HYDROCARBONS
NAPHTHALENE 1 8.856 UGM. /M-t-3
METHYL NAPH"HALENES+INT. L 8.0871 UGM./M*3
ALKYL NAPHTHALENES C12H12 L 0.8069 UGM./M+3
ANTHRACENE-PHENANTHRENE 2 8.0016 UGM. /M-t-3
CPU. F:-:LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 8.814 UGM./M+3
PHENQL + H02, OHO, C02H? EST. 0.062 UGM /M-t-3
TRIMETHYLPHE-:NOL+ISOMERS EST 0.022 UGM./M-t-3
DIHYDROXYBENZENES 1 0.073 UGM. /M-t-3
BENZOQUINONE- L 8.8035 UGM. /M-t-3
BENZALDEHYDE: ( + INTERF
PHENOL
L 8. 0825 UGM. /M-t-3
1 0. 8878 UGM. /M-t-3
CPU. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC AC I]) 2
ETHYL BENZOIC ISOMERS EST.
TRI METHYL BEIHZOIC ISOM. EST
PENTAND IOIC ACID EST.
HEXANDIOIC MCID 4
8.812 UGM /M-t-3
8. 0823 UGM. /M-t-3
0. 8045 UGM. /M-t-3
8.51 UGM. /M-t-3
8. 53 UGM. /M-t-3
233
-------
PAGE 802.
BENZOYL ION (ARBITRARY)
ACIDS CAS ACETIC ACIU)
EST
0.955 UGM /M + 3
0. 22 UGM. /M-t-3
CPU. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMENT (RELATIVE) 0
CONH FRAGMENT (RELATIVE) 0
C3H5N2 FRAGMENT (RELATIVE) 0
C4H3N2 FRAGMENT (RELATIVE) 0
PI PER I DINES (+ISQMERSJ EST 0
15 UGM. /M-t-3
77 UGM. .-'M-t-3
10 UGM. /Mt-3
043 UGM. /M-t-3
0023 UGM. --M-T-3
QUI NOLI HE ( •-1NTERFER
L 0.010 UGM /M*3
CPU. F::LE moss, DATE 002575, POSSIBLE SEC. DIFUHCTIOHALS
CSH503 (PHTHALATES
C7H1403 ISOMERS
C7H1203 ISOMEPS
C6H1203 ISOMERS
C6H1003 ISOMERS
0. 65 UGM. .-'M-t-3
EST 0.019 UGM. /M-t-3
EST 0. 023 UGM /M-t-3
EST 0. 047 UGM. /M-t-3
EST 0.019 UGM /M-t-3
C7H1202 ISOMERS
C5H1003 ISOMERS
C6H1202 ISOMERS
C5H1002 ISOMEPS
HOOC(CH2">50N02
EST 0. 092 UGM. /M-t-3
EST 0. 071 UGM. /M-t-3
EST 0. 023 UGM. /M-t-3
EST 0.015 UGM /M-t-3
EST 0. 039 UG'1 /Mt-3
HOOC(CH2':'40N02
HCO(CH2)40N02+ISOMERS
HOOC(CH2"'3CnijN02
HCO(CH2)4COONO
EST O. 035 UGM /M-t-3
EST 0. 023 UGM /M-t-3
EST 0.019 UGM /M-t-3
EST 0.019 UGM. /M-t>3
CPU. F:.LE 0057, DATE 002575.,
TENTATIVE TOLUENE PRODUC"S
C6H602 ISOMEIRS
C6H802 iSOME:PS
C7H1002 ISOMEPS
C5H803 ISQMEIPS
C7H7H04 ISOMERS
CPD. F::LE 0053,
C9H1402 ISOMERS
EST 0.61 UGM. /M-t-3
EST O.023 UGM./M+3
EST 0. 082 UGM. /M-t-3
EST 0. 043 UGM. /M-t-3
EST O. 01 1 UGM. /Mt-3
DATE 002575,
EST 0.019
TENTATIVE TERRENE
UGM. /M-t-3
PRODUC"S
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID
AMMONIUM CHLORIDE
AMMONIUM HI"RATE
SODIUM NITRATE
45.6 UGM. /M-t-3
3 0.12 UGM. /M-t-3
2 0. 26 UGM. /M-t-3
1 0. 038 UGM. /M-t-3
CPD.
LINDAHE
F:'LE 0060, DATE
002575,
T 0.£12
CHLORINA-
UGM. /M-t-3
'ED COMPOUNDS
234
-------
TYSON VALLE" 1828 9/6/73 TO 0856 9/7/73 CDT
SLT4F 1-38
FILE HO. 0801.. FIT TOL. 803 (MILL I MASS) RUN 0091 TO RUN 0830
DATE 122773, PASS3 ERROR 26 (MILLIMASS)
TOTAL SAMPLEI = 0. 166E +2 CUB'.'.C METERS, ALI0UOT=0. 188E +Q
INST. SENSI"IVITY=0. 177E +S
CHECK HEIGH" RAT 10 = 0. 508 (FRACTION), SMOOTHED
CPU. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANEES
ALKANES LOW MW
ALKAHES MED. MU
ALKANES HI MW
TOTAL ALKENES
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENE
TERRENES AS PINEHE
CL 0. 49 UGM. /M-t-3
CL 8. 084 UGM /Mt-3
CL 0. 868 UGM. .-'M-t-3
CL 8. 27 UGM. /M-t-3
8. 48 UGM. /M-t-3
CL 8. 933 UGM. /M-t-3
CL 0. 074 UGM. /M-t-3
CL 0. 42 UGM. /M-t-3
8.53 UGM./M*3
CL 0. 27 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.. 26 UGM.
XYLENES, ETHYL BENZENE CL 0.13 UGM. /M-t-3
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 96 UGM. /M-t-3
CL 8. 10 UGM. /M-t-3
1 0. 020 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 8.836 UGM./M*3
METHYL NAPH"HALEHES+IHT. L 8.831 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 0.0059 UGM./M-t-3
2 0.010 UGM. /M-t-3
L 0. 8033 UGM. /M-t-3
AHTHRACENE-PHENANTHREHE
PYRENE & ISOT1ERS C16H10
CPD. F::LE 0053, DATE 082575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.028 UGM./M-t-3
PHENOL+N02,CHO,C02H? EST. 0.078 UGM./M+3
TRIMETHYLPHE:HOL+ISOMERS EST 0.047 UGM./nt-3
DIHYDROXYBENZENES 1 8.045 UGM. /M-t-3
BENZALDEHYDE: OINTERF.
PHENOL
L 0. 0026 UGM. /M-t-3
L 046 UGM, /M-t-3
CPD. F::LE 0054, DATE
L'57
.J,
CAREOXYL:C ACIDS
BENZOIC ACID
ETHYL BEN20::C ISOMERS
PENTAHDIOIC ACID
HEXANDIOIC HCID
METHYLHEXAND10 IC ACID
2 0.015 UGM. /M-t-3
EST. 0. 0058 UGM. /M-t-3
EST. 0. 33 UGM. /M-t-3
4 0. 45 UGM. /M-t-3
1 8.31 UGM. /M-t-3
BENZOYL ION (ARBITRARY) 0.11 UGM./M*3
ACIDS (AS ACETIC: ACID) EST 8.28 UGM. /M-t-3
23>5
-------
PAGE 062.
CPD. F::LE 0055, DATE
CH2CN FRAGMENT < RELATIVE)
COHH FRAGMENT CRELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
C4H3N2 FRAGMENT
-------
TYSON VALUED 9999 9/7/73 TO 1335 9/3/73 CDT
SLT5F
FILE HO. 9001, FIT TOL. 993 CM ILL I MASS) RUN 9927 TO RUN 095(5
DATE 122373, PASS3 ERROR 26
TOTAL SAMPLERS. 307E + 2 CUBiiC METERS, ALIQUOT = 9. 109E +0
INST. SENSI"IVITY=0. 196E + S
CHECK HEIGH" RAT 10 = 9. 589 (TRACT ION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANEIS
ALKAHES LOU MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKEHEIS
ALKENES LOW MW
ALKENES MED. MW
ALKEHES HI MW
ALPHA PINENE;
TERPEHES AS PIHENE
CL 0.095 UGM./M + 3
CL 0. 9953 UGM. /M-t-3
CL 0. 054 UGM. /M-t-3
CL 0. 022 UGM. /M-r-3
0.17 UGM. /M-t-3
CL 9.0048 UGM./M + 3
CL 0. 064 UGM. /M-t-3
CL 9. 979 UGM. /M-t-3
0.15 UGM. /M-t-3
CL 0. 07S UGM. /M-i-3
XYLENES, MON SUB BENZENES CL 0.095 UGM./M-t-3
XYLEHES, ETHYL BENZENE CL 9.013 UGM./M+3
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 21 UGM. /M-t-3
CL 9. 0996 UGM. /M-t-3
1 0. 38 UGM. /M-t-3
DIPHEHYL ME"HANE+ISOMERS CL 0.0019 UGM./M+3
DIPHEHYL ETHANE & ISOMERS L 9.0959 UGM./M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.031 UGM./M-t-3
METHYL NAPH"HALEHES+INT. L 0.9929 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 9.00092 UGM. /M-t-3
ANTHRACENE-PHENANTHRENE
PYRENE & ISGMERS C16H10
2 8. 00049 UGM. /M-t-3
L 9. 00094 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.012 UGM. /M-t-3
PHENOL + N02, CHO, C02H? EST. 0.920 UGM. /M-t-3
TRIMETHYLPHFiNOL+ISOMERS EST 9.011 UGM./M + 3
DIHYDROXYBENZENES 1 0.023 UGM. /M-t-3
BENZOI3UINOHEE L 0.9930 UGM./M-t-3
NAPHTHOQUINONE?
BEHZALDEHYDE: (+INTERF
PHENOL
EST. 0.0036 UGM./M-t-3
) L 0. 0077 UGM. /M-t-3
1 0. 924 UGM. /M-t-3
CPD. F::LE
BENZOIC AC IK
METHYL BENZOIC ISOMERS
ETHYL BENZO::C ISOMERS
0054, DATE 002575, CARBOXYLiiC ACIDS
2 0. 0041 UGM. /Mt-3
EST. 0. 020 UGM /M-t-3
EST. 0.0081 UGM./M-t-3
237
-------
PAGE 092.
TRI METHYL BE-INZOIC I SOU. EST 0.
PENTAND 10 1C ACID EST. 0.
HEXANDIOIC ACID 4 0.
METHYLHEXANDIOIC ACID 18.
BEHZOYL ION (ARBITRARY? Q.
ACIDS 50N02
DATE 082575, POSSIBLE SEC.
0.22 UGM.XM+3
EST 0.011 UGM. .-'M-t-3.
EST 0.013 UGM.xM+3
EST 0.016 UGM.XM+3
EST 0. 0067 UGM.
DIFUNCTIONALS
HOOC
-------
TYSON VALLE"-' 1345 9x3x73 TO 1145 9x9/73 CDT
SLT6F
FILE HO. 0001, FIT TOL. 003 CM ILL I MASS) RUN 0091 TO RUN 0120
DATE 122473, PASS3 ERROR 26
CHECK HEIGH" RAT 10 = 0. 500 ''.FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 092575,
HYDROCARBONS
TOTAL ALK.ANE:S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI NW
ALPHA PI NEW!
TERRENES AS PINENE
CL 0. 022 UGM. xM-t3
CL 0. 0615 UGM. xM-t-3
CL 0. 017 UGM. xM-t-3
CL 0.012 UGM. XM-t-3
0. 073 UGM. xM-t-3
CL 0.06070 UGM.xM + 3
CL 0.024 UGM.XM+3
CL 9. 020 UGM. XM-t-3
0.018 UGM. XM-t-3
CL 0. 029 UGM. XM-t-3
XYLENES, MON SUB BENZENES CL 0.030 UGM xM-t-3
XYLENES, ETHYL BENZENE CL 0.0058 UGM.xM*3
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 0. 19 UGM. xM-t-3
CL 0. 0051 UGM. xM-t3
1 0.17 UGM. xM-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.015 UGM.xM-t-3
ALKYL NAPHTHALENES C12H12 L 0.0012 UGM./M*3
DIBENZANTHRACENES C22H14 E 0.0012 UGM.xMt-3
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.0024 UGM./M+3
PHENOL + N02, CHO, C02H? EST. 0.011 UGM.xM-t-3
DIH Y D R 0 X Y BENZENES 1 0.0013 U G M . x M -t- 3
PHENOL 1 0.0023 UGM. xM-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC AC IB
ETHYL BENZOIC ISOMERS
PENTAHDIOIC ACID
HEXANDIOIC ACID
B E N Z 0 Y L 10 N ( ft R B IT R A R Y )
2 0.0023 UGM.xM + 3
EST. O. 0049 UGM, xM-t-3
EST. 0. 663 UGM. xM-t-3
4 0.020 UGM.XM + 3
0. 00S0 UGM. xM-t-3
ACIDS (AS ACETIC ACID) EST 0.076 UGM xM-t-3
CPU. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
C H 2 C N F R A G M El H T < R E L A T IV E ) 0 . 13 U G M . •••' M -t- 3
COHH FRAGMENT (RELATIVE) 0.16 UGM./M-t-3
C3H5N2 FRAGMENT (RELATIVE) 0.054 UGM.xM-t-3
C4H8N2 FRAGMENT (RELATIVE) 0.825 UGM XM-t-3
239
-------
PAGE 992.
PYRIDIHE + PYRIDYL CPDS L
PI PER I DINES <+ISOMER3> EST
QUIHOLIHE C--IHTERFER?) L
PYRIDIHE SULFATE EST
0.00073 UGM.xM + 3
0.0041 UGM.xMt-3'
0. 0023 UGM. x M-t-3
0. 0062 UGM. xM-t-3
CPU. F::LE 0056, HATE 082575, POSSIBLE SEC. DIFUNCTIOHALS
C7H1204 EST
C6H1003 I50MERS EST
C7H1202 ISOMERS EST
C5H1002 ISOMERS EST
HOOC50NQ2 EST
HCO5COOH02+1SOMERS EST
0. 18 UGM. .--M-t-3
0.21 UGM. .-"M-t-3
0. 0062 UGM. xn-t-3
0. 028 UGM xM-t-3
0.0078
0.0062
0.0078
UGM. /Mt-3
UGM. .-'M + 3
UGM. xM-t-3
CPD. F::LE 0057, DATE 082575. TENTATIVE TOLUENE PRODUCES
C6H602 ISOMFiRS
C6H802 ISOME:RS
C7H1002 ISOMERS
C7H7N04 ISOMERS
NITROCRESOL':5?
EST 0.011 UGM. xM-t-3
EST 0. 028 UGM. /M-t-3
EST 0. 022 UGM. -"M-t-3
EST 0. 00078 UGM. xM-t-3
L 0. 00094 UGM. .'M-t-.:$
CPU. F::LE 0053, HATE 082575, TENTATIVE: TERPENE PRODUC-S
CPD. F::LE 0059, IIATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 5.
AMMONIUM CHLORIDE 3 0.
AMMONIUM NI"RATE 2 0.
SODIUM NITPNTE 1 0,
7 UGM. .''M-t-3
057 UGM .--M-t-3
14 UGM. .--M-t-3
025 UGM x M-t-3
CPD. F::LE 0060, DATE 032575, CHLORINA-ED COMPOUNDS
240
-------
TYSON VALLE" 1155 9/9/73 TO 1155 9/10/73 CD"
SLT7F
FILE NO. 9001. FIT TOL. 003 EST
QUINCLINE (-INTERFER?) L
PYRIDIHE SULFATE EST
0. 0023 UGM. /M-t-3
0. 0018 UGM. /M-t-3
0.011 UGM. /M-t-3
241
-------
PAGE 092.
CPD. F::LE 0055, DATE 0*32575, POSSIBLE'SEC. DIFUNCTIONALS
C3H503 CPHTHALATES)
C6H1004 < AD:: PIC ACID?
C7H1203 ISOMER3
C6H1203 ISOMERS
C6H1003 ISOMERS
6. 038 UGM. /M-t-3
DUP 0.17 UGM. /M-t-3
EST 0.0086 UGM./M-t-3
EST 0.015 UGM. /M-t-3
EST 0. 043 UGM. /M-t-3
C4H604 CSUCCIHIC ACID?> EST
C5H1002 ISOMEPS EST
HQOC40N02 EST
HCO f. CH2 > 5COON02+ISOMERS EST
HCO
-------
TYSOH VALLE" 1485 9/19/73 TO 1625 9/11 CUT
SLTSF
FILE HO. 9001. FIT TOL. 603 -CM ILL I MASS) RUN 9901 TO RUN 0836
DATE 122773. PASS3 ERROR 26 O11LLI MASS)
TOTAL SAMPLERS. 308E +2 CUBilC METERS, ALIQUOT=8. 188E +0
IHST. SEHSI"IVITY = 8. 177E +«;
CHECK HEIGH" RAT 10 = 0. 500 CL 0.0864 UGM. /M-t-3
PHENOL + H02, OHO, C02H? EST. 0.027 UGM. /M-t-3
TRIMETHYLPHEIHOL+ISOMERS EST 0.8895 UGM. /M-t-3
DIHYDROXYBENZEHES 1 8.038 UGM. /M-t-3
BENZOQUINOHE L 0.8840 UGM. /M-t-3
PHENOL
1 0. 820 UGM. /M-t-3
8854, HATE
CPD. F::LE
BEHZOIC AC IB 2
METHYL BEHZOIC ISOMERS EST.
TRI METHYL BELNZOIC ISOM. EST
PEHTAHDIOIC ACID EST.
HEXANDIOIC ACID 4
802575,
2 8.8885
8.0852
8.
0.
CARBOXYL:
UGM. /M-t-3
UGM. /M-t-3
8831 UGM. /M-t-3
32 UGM. /M-t-3
C ACIDS
8. 18 UGM. .--M-t-3
METHYLHEXANHIOIC ACID 1 0.870
BEHZOYL I OH EST 8.892
UGM./M+3
UGM. /M-t-3
UGM. /M-t-3
2U3
-------
PAGE Q02.
CPD. F::LE 0055, DATE
CH2CN FRAGMENT (RELATIVE)
COHH FRAGMENT (RELATIVE^'
C3H5H2 FRAGMENT (RELATIVE)
C4H8N2 FRAGMENT (RELATIVE)
C4H9N2 FRAGMENT (RELATIVE
9tt2575, NITROGEN
0.17 UGM. .--M-t-3
0. 86 UGM. /M-t-3
0.014 UGM /M-t-3
COMPOUNDS
PI PER I BINES
CARBAZOLE
QUINCLINE (
( +ISOMERS:'
-INTERFER?
CPD. F:LE 0055., DA"
C3H503 (PHTHALATES)
C7H1203 ISOMERS
C6H1003 ISOMERS
C7H1202 ISOMERS
C5H1003 ISOMERS
H C 0 ( C H 2 ) 3 C 0 0 N 0 2 + I S 0 M E R S
E)
£.:•
EST
L
L
0.
0.
0.
0.
0.
E 0825
EST
EST
EST
EST
EST
0.
0.
0.
0.
0.
0.
012 UGM. .-- M-t-3
011 UGM. /M-t-3
0012 UGM. /M-t-3
00092 UGM. /M-t-3
00082 UGM. /M-t-3
75, POSSIBLE
18 UGM. /M-t-3
012 UGM. /M-t-3
022 UGM. /M-t-3
024 UGM. /M-t-3
035 UGM /M-t-3
018 UGM. /M-t-3
SEC. DIFUNCTIONHLS
CPD. F:LE 0057, DATE 092575, TENTATIVE TOLUENE PRODUCES
CSH602 ISOME-IRS
C6HS02 i so ME; PS
C7H1002 ISOMERS
C5H803 ISOMEPS
C6H804 ISOMERS
EST 0. 25 UGM. /M-t-3
EST 9.10 U&M. /M-t-3
EST 0. 024 UGh /M-t-3
EST 0.011 UGM /M-t-3
EST 0.011 UGM. /M-t-3
CPD. F:LE 0053, DATE 082575, TENTATIVE TERPENE PPODUC-S
C 9 H 1 4 0 £ I S 0 f 1E P S EST 0.011 U G M . / M -t- 3
CPD. F::LE 0059,
SULFATES AS SULFUR 1C
AMMONIUM CHLORIDE
AMMONIUM HI ""RATE
SODIUM HITPHTE
HATE
ACID
082575, INORGANIC
4 12. UGM. /M-t-3
3 0. 039 UGM /M-t-3
2 0.12 UGM. /M-t-3
1 0 18 UGM. /M-t-3
COMPOUNDS
CPD. F::LE 0060, DATE 082575, CHLORINA-ED COMPOUNDS
C5H5CL i.-HEF-ACHLOP--') EST 0.018 UGM /M-t-3
244
-------
TYSON VALLE1-' 1890 8/19/74 - 2400 8/19x74 CD'
SLT 62 6 HRS 1806-2488
FILE HO. 8002, FIT TOL. 885 CM ILL I MASS) RUN 0186 TO RUN 8140
DATE 832575.. PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLE: = 8. 465E +1 CUBIIC METERS, ALIQUOT=8. 930E -1
IHST. SEHSI"IVITV=8. 215E +S
CHECK HEIGH" RAT I 0 = 0. 588 CFRACTIOH), SMOOTHED
CPD. F::LE 0051, DATE 002575,
HYDROCARE30NS
TOTAL ALKANEES
ALKAHES LOW MW
ALKANES MED. MW
TOTAL ALKENEES
ALKEHES LOW MW
CL 8.41 UGM. /M-t-3
CL 0. 28 UGM. /M-t-3
CL 8. 853 UGM. /M-t-3
8. 29 UGM. /M-t-3
CL 0.036 UGM./M + 3
ALKENES MED. MW CL 0.13 UGM. /M-t-3
ALKEHES HI MW CL 0.039 UGM./M-t-3
TERPEHES AS PIHEHE CL 0.10 UGM./M-t-3
XYLEHES,MOH SUB BEHZEHES CL 0.15 UGM./M+3
XYLEHES, ETHYL BEHZEHE CL 0.813 UGM./M-t-3
ALKYL BEHZENES C9H12
CL 8.12 UGM. /M-t-3
CPD. F::LE 8052, DATE 002575,
POLYCYCL::C HYDROCARBONS
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPUS
CRESOLS
-------
PAGE 092.
CPU. F::LE 0959, DATE 092575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 33. UGM. /M + 3
AMMONIUM CHLORIDE 3 0.19 UGM. .•'M + S
AMMONIUM NT'RATE 2 0.24 UGM. /M-r-3
CPD. F::LE 0060, DATE 002575, CHLORINA-ED COMPOUNDS
C5H5CL CHEF'-ACHLOR?) EST 0.5S UGM.xM-t-3
2^6
-------
TYSON VALLE1"' 0880 8/28/74 - 0300 8x20/74 CD'
SLT 63 3 HRS 0098-0380
FILE NO. 9002, FIT TOL. 005 (MILLIMASS) RUN 0071 TO RUN 0105
DATE 832575, PASS3 ERROR 18 CMILL I MASS)
TOTAL SAMPLED. 234E +1 CUB:\C METERS, ALIQUOT=S. 130E +0
INST. SENSI"IVITY = 0. 215E + 3
CHECK HEIGH" RAT 10 = 0. 580 (FRACTION), SMOOTHED
CPU. F::LE 0051, DATE
TOTAL ALKANEIS
ALKANES LOW MU
ALKAHES MED. MU
TOTAL ALKEHEIS
ALKENES MED. MU
32575, HYDROCARE30HS
CL 8. 27 UGM. /M-t-3
CL 0. 091 UGM. /M-t-3
CL 0. 068 UGM. /M-t-3
8. 54 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
ALKENES HI HU CL 0.051 UGM /M + 3
ALPHA PIHEHE: 0.31 UGM./M-t-3
TERPENES AS PIHEHE CL 0.20 UGM./M+3
XYLEHES, MON SUB BENZENES CL 8.24 UGM. /M-t-3
XYLENES, ETHYL BENZENE CL 0.045 UGM. /M-t-3
ALKYL BENZENES C9H12
CL 0. 64 UGM. /M-t-3
CPD. F::LE 0052, HATE 082575, POLYCYCLT.C HYDROCARBONS
NAPHTHALENE 1 0.0078 UGM./M-t-3
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL? >CL 0.039 UG':./M*3
TRIMETHYLPHEIHOL+ISOMERS EST 0.093 UGM./M-t-3
DIHYDROXYBENZENES 1 0.622 UGM./M-t-3
PHENOL 1 0.031 UGM./M*3
CPD. F:LE 0054, DATE 002575, CARBOXYLT.C ACIDS
BENZOIC ACID 2
PENTANDIOIC ACID EST.
HEXANDIOIC ACID 4
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID.:' EST
0. 013 UGM. /M-t-3
2. 4 UGM. /M-t-3
1. 5 UGM. /Mt-3
0.14 UGM. /M-t-3
0. 75 UGM. /Mt-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CH2CN FRAGMEINT (RELATIVE) 6.884 UGM./M-t-3
CONH FRAGMENT (RELATIVE) 1.6 UGM. /M-t-3
C3H5N2 FRAGMENT (RELATIVE) 8.11 UGM./M-t-3
CPD. F::LE eoss, DATE 002575, POSSIBLE SEC. DIFUNCTIQNMLS
C8H503 (PHTHALATES) 2.6 UGM. /M-t-3
C7H1203 ISOMERS EST 0.18 UGM./M-t-3
CPD. F::LE
C6H602 ISOMEIRS
C6H802 ISOMEERS
8657, HATE 802575, TENTATIVE!
EST 8. 18 UGM. /M-t-3
EST 6. 33 UGM. /M-t-3
TOLUENE PRODUC
247
-------
PAGE 802.
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERRENE PRODUCT'S
CPD. F::LE 0059.. DATE 002575, INORGANIC; COMPOUNDS
SULFATES AS SULFURIC ACID 4 5.2 UGM. /M-t-3
AMMONIUM CHLORIDE 3 0.17 UGM./M-t-3
AMMONIUM NI"RATE 2 0.38 UGM. /M-t-3
CPD. F::LE 0060, DATE 002575, CHLORINA"ED COMPOUNDS
C5H5CL
-------
TYSOH VALLE" 8300 8/28/74 - 0700 8/28/74 CD"
SLT 64 9300-0708 4 HRS
FILE HO. 0902, FIT TOL. 905 CM ILL I MASS) RUN 0518 TO RUN 0550
DATE 080375, PASS3 ERROR 19 (MILLIMASS)
TOTAL SAMPLEI = 0. 312E +1 CUB::C METERS, ALIQUOT = 8. 280E +0
IHST. SENSI"IVITY=6. 140E +5
CHECK HEIGH" RATIO=8. 500 (FRACTIOH), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCAREHOHS
TOTAL ALKAHE:S
ALKANES LOU MW
ALKANES MED. MW
TOTAL ALKENE:S
ALKEHES LOW MW
CL 0.46 UGM./M-t-3
CL 0. 19 UGM. /M-t-3
CL 0. 11 UGM. /M-t-3
0. 33 UGM. /M-t-3
CL 0. 080 UGM. /M-t-3
ALKENES MED. MW CL 0.11 UGM./M-t-3
ALKEHES HI MW CL 0.049 UGM. /M-t-3
TERRENES AS PINENE CL 0.13 UGM./M-t-3
XYLENES,MOH SUB BENZENES CL 0.16 UGM./M+3
XYLEHES, ETHYL BENZENE CL 0.831 UGM./M+3
ALKYL BENZENES C9H12
ALKYL BENZENES C18H14
CL 0. 63 UGM. /M-t-3
CL 0. 927 UGM. /M-t-3
CPD. FILE 0052, DATE 082575, POLYCYCLIC HYDROCARBONS
NAPHTHALENE 1 0.0053 UGM./M-t-3
METHYL NAPH"HALENES+IHT. L 0.028 UGM./M-t-3
DIBEHZAHTHRACEHES C22H14 E 0.031 UGM /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPUS
CRESOLS (BENZYL ALCOHOL? >CL 0.016 UGM./M-t-3
PHENOL + H02, OHO, C02H? EST. 8 . 19 UGM ./M-t-3
DIHYDROXYBENZENES 1 0.057 UGM./M-t-3
BENZALDEHYDE-I (+IHTERF.) L 0.0863 UGM./M-t-3
PHENOL 1 0.923 UGM./M-t-3
CPD. FILE 8854, DATE 882575, CARBOXYLIC ACIDS
BEHZOIC ACID 2 0
PEHTAHDIOIC ACID EST. 1
HEXAHDIOIC RCID 4 1
BENZOYL ION
-------
PAGE 902.
C7H1202 ISOMERS
C5H1002 ISOMER3
CPU. F::LE 0057,
C6H602 ISQMELRS
C6H802 ISQMEIRS
C5H803 ISOMERS
CPD. F::LE 0053,
C10H1403 ISOMERS
EST 0. 10 UGM. /M-t-3
EST Q. 074 UGM. /M-t-3
DATE 9132575, TENTATIVE: TOLUENE PRODUC"S
EST 0. 48 UGM. /M + 3
EST 0. 074 UGM. /Mt-3
EST 0.10 UGM. /M-r-3
DATE 092575, TENTATIVE TERRENE PRODUCT'S
EST 0. 34 UGM. /M-t-3
CPD. F:LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 1.3 UGM. /M-t-3
AMMONIUM CHLORIDE 3 0.16 UGM. /M-t-3
AMMONIUM NI "RATE 2-0.041 UGM./Mt-3
CPD. F::LE sees,
ISODRIH
LINDANE
C5H5CL
-------
TYSON VALLE'"1 6799 8/20/74 - 6999 8/20/74 CD'
CMILLIMASS) RUN 9176 TO RUN 9210
CM ILL I MASS)
289E +9
SLT 65 2.0 HRS 9789-0996
FILE NO. 0902. FIT TOL. 095
DATE 932575, PASS3 ERROR 19
TOTAL SAMPLE>0. 156E +1 CUBiiC METERS, ALIQUOT = 0.
INST. SENSI"IVITV = 0. 215E +55
CHECK HEIGH" RAT 10 = 8. 590 CTRACT I OH), SMOOTHED
CPU. F::LE 0051, HATE 882575, HYDROCARBONS
TOTAL ALKAHEIS
ALKANES LOW MU
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
ALKENES LOW MW
ALKEHES MED. MW
ALKENES HI MW
ALPHA PINENE:
TERRENES AS PINENE
CL 9. 46 LIGM. /M-t-3
CL 0. 999 UGM. /M-t-3
CL 0.18 UGM. /M-t-3
CL 9. 977 UGM. /M-t-3
0. 60 UGM. /M-t-3
CL 9.015 UGM. /M-t-3
CL 0. 21 UGM. /M-t-3
CL 0.17 UGM. /M-t-3
0. 79 UGM. /M-t-3
CL 0. 32 UGM. /M-t-3
XYLENES, MON SUE BENZENES CL 0.23 UGM./M-t-3
XYLEHES, ETHYL BENZENE CL 0.061 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 1.1 UGM. /M-t-3
CPD. F:LE 0052, DATE 082575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.0074 UGM./M-t-3
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS CBENZYL ALCOHOL?)CL 0.025 UGM. /M-t-3
DIHYDROXYBENZENES 1 0.929 UGM./M+3
BENZOQUINOHE-I L 9.027 UGM./M-t-3
PHENOL 1 0.010 UGM./M-t-3
0054,
CPD. F:LE
BENZOIC ACID
PENTANDIOIC ACID
HEXANDIQIC HCID
BENZOYL ION ''ARBITRARY)
ACIDS CAS ACETIC ACID)
DATE 082575,
2
EST.
4
1
EST
CARBOXYL::C
016 UGM. /M-t-3
1 UGM. /M-t-3
2. 0 UGM. /M-t-3
0. 26 UGM. /M-t-3
0. 66 UGM. /M-t-3
ACIDS
CPD. F::LE 0055, DATE 082575, NITROGEN COMPOUNDS
CONH FRAGMENT CRELATIVE) 1.2 UGM. /M-t-3
C3H5N2 FRAGMENT CRELATIVE) 0.096 UGM. /M-t-3
PIPER I DINES C + ISOMERS) EST 0.940 UGM /M-t-3
PYRIDINE SULFATE EST 9.29 UGM. /M-t-3
CPD. F::LE 0055, DATE 082575, POSSIBLE SEC. DIFUNCTIONALS
C8H503 CPHTHALATES) 7.9 UGM. /M-t-3
C5H1003 ISOflERS EST 0.17 UGM./M-t-3
H 0 0 C C C H 2 > 5 0 N 0 2 E S T 0.6 6 U G M . / M -t- 3
251
-------
PAGE 902.
CPU. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUC.-S
C6HS02 ISONEIRS EST 8.17 UGM. .'M-t-3
C6H802 ISOME:RS EST 0.66 UGM. y M-t-3
CPU. F::LE 0053, HATE 002575, TENTATIVE: TERRENE PRQDUC-S
.CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 2.5 UGM.xM*3
AMM0NI UM CHI.0RIDE 3 0. 14 UGM. yM*• 3
CPU. F::LE 0050, DATE 002575, CHLORINA"ED COMPOUNDS
C5H5CL
-------
TYSON VALLE" 0900 8x29/74 - 1108 S/2.Q/74 CD"
SLT 66 2.0HRS 0909-1100
FILE HO. 0902, FIT TOL. 005
-------
PAGE 092.
CPD. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUCTS
C6H602 ISOME:RS EST 0.61 UGM..'M*3
CPU. F::LE 0053, DATE 002575, TENTATIVE: TERRENE PRODUCES
CPD. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 7.5 UGM. xM-t-3
AMMONIUM CHLORIDE 3 0.15 UGM. xM-t-3
AMMONIUM HI "RATE 2 0.43 UGM. .--M-t-3
CPD. F::LE 0050, DATE 082575, CHLORINA"ED COMPOUNDS
C5H5CL
-------
TYSON VALLE1"1 1H
8/20/74- - 1308 8/20/74 CD'
SLT 67 2. 0 HRS 1100-1360
FILE HO. 0902, FIT TOL. 005 (MILL I MASS) RUN 0246 TO RUN 0280
DATE 032575, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLERS. 156E +1 CUBilC METERS, ALIQUOT = 0. 280E +0
IHST. SENSI"IVITY = 0. 215E + 53
CHECK HEIGH" RAT I 0 = 0. 500 (TRACT I OH), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOU MW
ALKAHES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
ALKEHES LOW MW
ALKEHES MED. MW
ALKEHES HI MW
ALPHA PINEHE;
TERRENES AS PINENE
CL 0.41 UGM. /M-t-3
CL 0.14 UGM. /M-t-3
CL 0.13 UGM. /M-t-3
CL 0. 022 UGM. /M-t-3
0. 60 UGM. /M-t-3
CL 0. 028 UGM. /M-t-3
CL 0. 21 UGM. /M-t-3
CL 0. 039 UGM. /M-t-3
0.19 UGM. /M-t-3
CL 0. 24 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.33 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.034 UGM./M*3
ALKYL BENZENES C9H12 CL 0.65 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
METHYL NAPH""HALEHES+INT. L 0.0097 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.053 UGM./M+3
PHENOL + N02, CHO, C02H? EST. 0.10 UGM. /M-t-3
TRIMETHYLPHEIHOL+ISOMERS EST 0.14 UGM. /M-t-3
DIHYDROXYBENZEHES 1 0.046 UGM./Mt-3
PHENOL 1 0.023 UGM./M*3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
PENTAHDIOIC ACID EST.
HEXANDIOIC nCID 4
METHYLHEXANMOIC ACID 1
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID) EST
1.6 UGM. /M-t-3
2. 1 UGM. /M*3
0.19 UGM. /M-t-3
0. 20 UGM. /M-t-3
0. 74 UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 0.58 UGM./M+3
C3H5N2 FRAGMENT (RELATIVE) 0.23 UGM./M-t-3
P Y R ID I N E + F:' Y R I D Y L C P D S L 0.015 U G M / M -t- 3
PIP E RI D IN E S ( +1S 0 M E R S '.' E S T 0.040 U G M / M -t- 3
CPD. F::LE 0056,
C8H503 (PHTHALATES)
C6H1203 ISOMERS
DATE 002575, POSSIBLE
3. 4 UGM. /M-t-3
EST 0. 16 UGM. /M-t-3
SEC. DIFUNCTIDNHLS
255
-------
PAGE 882.
CPU. F::LE 0057,
C6H602 ISOMEIRS
C6H802 ISOME-IRS
C7H7H04 ISOMEP.S
DATE 982575, TENTATIVE-! TOLUENE PRODUC"S
EST 0. 38 UGM. .-"M-t-3
EST 0. 56 UGM. .'M-t-3
EST 0. 046 UGM. xfl-t-3
CPU. F::LE eess, DATE 082575, TENTATIVE: TERPENE PRODUC"S
CPU. F::LE 0059, DATE 002575, INORGANIC
SULFATES AS SULFUR 1C ACID 4 15. UGM. ,-"M-t-3
A M M 0 H I U M CHI. 0 P IDE 39.671 U G M . / M i- 3
AMMONIUM HI"RATE 2 0.41 UGM. .-'M-t-3
COMPOUND
CPD. F::LE 0060,
ISODRIH
LIHDAHE
C5H5CL
CHLORIHA-ED COMPOUNDS
EST 0.64 UGM . .-"M-t-3
EST 2.2 UGM. /M-t-3
EST 9. 80 UGM . xM-t-3
256
-------
TYSON VALLE" 1386 8/29/74 - 1508 8/20/74 CD"
SLT 68 2.0 HRS 1390-1590
FILE NO. 0002, FIT TOL. 905 CM ILL I MASS) RUN 0281 TO RUN 03155
DATE 932575, PASS3 ERROR 10 (MILLIMASS)
TOTAL SAMPLEI = 0. 156E +1 CUBiiC METERS, ALIQUDT = 9. 280E +0
INST. SENSI"IVITY=0. 215E +55
CHECK HEIGH" RAT I 0 = 0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, HATE 082575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEES
CL 0. 45 UGM. /M-t-3
CL 0.17 UGM. /M-t-3
CL 9. 13 UGM. /M-t-3
CL 0.012 UGM. /M-t-3
0. 44 UGM. /M-t-3
ALKENES LOI.,,1 MW
ALKENES MED. MW
ALKENES HI HU
ALPHA PINENEE
TERPENES AS PINENE
CL 0. 054 UGM. /M-t-3
CL 0.17 UGM. /M-t-3
CL 0. 055 UGM /M-t-3
0. 46 UGM. /M-t-3
CL 0.18 UGM. /M-t-3
X Y L E N E S, M 0 H S U & B E N Z E N E S C L 0.20 U G M . / M -t- 3
XYLENES, ETHYL BENZENE CL 0.060 UGM. /M-t-3
ALKYL BENZENES C3H12 CL 0.81 UGM. /M-t-3
ALKYL BENZENES C10H14 CL 0.060 UGM /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL^C HYDROCARBONS
CPD. F:LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.033 UGM. /M-t-3 •
PHENOL + N02, CHO, C02H? EST. 0.15 UGM. /M-t-3
DIHYDROXYBENZENES 1 0.046 UGM. /M-t-3
BENZALDEHYDE: (+INTERF. ) L 0.019 UGM
CPD. F::LE 0054, DATE 002575,
BEHZOIC ACID 2 0. 024
PENTAHDIOIC ACID EST. 1.
HEXANDIOIC RCID 4 0.
BENZOYL ION (ARBITRARY) 0.
ACIDS (AS ACETIC AC ID. ) EST 0.45 UGM. /M-t-3
CARBOXYL:C
UGM. /M-t-3
3 UGM. /M-t-3
51 UGM./M-t-3
19 UGM. /M-t-3
ACIDS
CPD. F::LE 0055, DATE
CH2CN FRAGMEINT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
PYRIDIHE + PYRIDYL CPDS L
002575, NITROGEN
0.15 UGM. /M-t-3
0. 79 UGM. /M-t-3
0.16 UGM. /M-t-3
010 UGM /M-t-3
COMPOUNDS
P I P E R I D I N E 3 ( + I S 0 M E R S
EST 0.05 5 U G M / M -t- 3
CPD. F::LE 0056,
C8H503 (PHTHALATES)
DATE 002575, POSSIBLE
11. UGM. /M-t-3
SEC. DIFUNCTIOHHLS
257
-------
PAGE 002.
CPD. F::LE 0057,
C6HS02 ISOME:RS
C6H802 ISOME:RS
DATE 082575, TENTATIVE: TOLUENE PRODUCES
EST 8. 38 UGM. .-'M-t-3
EST 0. 30 UGM. .-"M-t-3
CPD. F::LE 0059, DATE 002575, TENTATIVE: TERPENE PRODUC"S
CPU.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059.,
AS SULFUR 1C
CHLORIDE
NI"RATE
>ODIUM NITRATE
DATE 082575. INORGANIC
ACID 49.4 UGM. /M-t-3
3 0.15 UGM. ,--M-t-3
2 0.15 UGM. .--M-t-3
1 0. 953 UGM .--M-t-3
COMPOUNDS
CPD. F::LE 0060,
LINDANE
C5H5CL
-------
TYSON VALLE1-' 1598 8/29/74 - 1899 8/29/74 CD
SLT 69
FILE HO. 0902, FIT TOL. 005 CM ILL I MASS) RUN 0316 TO RUN 9350
DATE Q32575.. PASS3 ERROR 16 CMILLIMASS)
TOTAL SAMPLERS. 234E +1 CUBiiC METERS, ALIQUOT = 9. 280E +0
INST. SENSI"IVITY=8. 215E +55
CHECK HEIGH" RAT 1 0 = 0. 580 < TRACT I ON), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKANE-IS
ALKANES LOW MW
ALKAHES MED. MW
TOTAL ALKEHEIS
ALKENES LOW MW
CL 0. 28 UGM. /M-t-3
CL 0. 089 UGM. /M-t-3
CL 0. 073 UGM. /M-t-3
0. 37 UGM. /M-t-3
CL 9. 021 UGM. /M-t-3
ALKENES MED. MW
ALKENES HI HW
ALPHA PINENE:
TERRENES AS PINENE
CL 9.12 UGM. /M-t-3
CL 0. 064 UGM. /M-t;
0. 28 UGM. /M-t-3
CL 0. 16 UGM. /M-t-3
XYLENES, M0N SUB BENZENES CL 0.17 UGM. /M-t-3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C18H14
CL 0.622 UGM./M+3
CL 0. 48 UGM. /M-t-3
CL 9. 050 UGM. /M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.0043 UGM./M-t-3
METHYL HAPH"HALENES+INT. L 0.0971 UGM./M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL? )CL 9.032 UGM /M-t-3
PHENOL + N02, CHO, C02H? EST.
TRIMETHYLPHEINOL+ISOMERS EST
DIHYDROXYBENZENES 1
BENZALDEHYDE: C+INTERF. > L
0. 19 UGM. /M-t-3
9.14 UGM. /M-t-3
0. 941 UGM. /M-t-3
0.010 UGM./M*3
PHENOL
1 0. 040 UGM. /M-t-3
CPD. F:LE 0054, DATE 002575,
BENZOIC ACID 29.
PENTAND IOIC ACID EST. 2.
HEXANDIOIC ACID 4 2.
METHYLHEXANDIOIC ACID 10.
BENZOYL ION (ARBITRARY) 9.
CARBOXYL::C
026 UGM /M-t-3
1 UGM. /M-t-3
6 UGM. /M-t-3
41 UGM. /M-t-3
11 UGM. /M-t-3
ACIDS CAS ACETIC ACID:- EST 8.47 UGM. /M-t-3
ACIDS
CPD. F::LE 0055, DATE 002575
CONH FRAGMENT (RELATIVE:.' 0.43
C3H5H2 FRAGMENT (RELATIVE) 9
C4H8N2 FRAGMENT '"RELATIVE) 8
PYRIDINE + PYRIDYL CPDS L 8
NITROGEN
UGM. /M-t-3
45 UGM. .--M-t-3
064 UGM./M+3
017 UGM /M-t-3
COMPOUNDS
259
-------
PAGE 092.
PIPERIDINES C+ISOMERS)
EST 9. 051 UGM /M-t-3
CPD. F::LE 0055.
C8H503 CPHTHALATES)
C5H1002 ISOMERS
HOOCCCHSMONOS
HOQCXCH2>3COONQ2
HATE 0*32575, POSSIBLE SEC. DIFUNCTIONALS
4. 1 UGM. /M-t-3
EST 0. 085 UGM. /M-t-3
EST 0.10 UGM. .--M-t-3
EST 0.15 UGM. /M-t-3
HCOCCH2J5COOH02 + ISOMERS EST 0.064 UGM./M-t-3
CPU. F::LE 0057,
C6H602 ISOME:RS
C6HS02 ISOME-:RS
C7H7N04 ISOMERS
DATE 092575, TENTATIVE: TOLUENE PRODUC"S
EST 0. 35 UGM. /M-t-3
EST 0. 22 UGM. /'M-t3
EST 0. 057 UGM. .-"M-t-3
CPD. F:LE 0053, DATE 002575, TENTATIVE: TERPENE PRODUC-S
CPD. F::LE 0059, DATE 002575, iMORGANn
SULFATES AS SULFURIC ACID 4 19. UGM. /M-t-3
AMMONIUM CHLORIDE
COMPOUNDS
AMMONIUM NI"RATE
SODIUM NITRATE
3 0.11 UGM./M+3
2 0. 59 UGM. /M-t-3
1 0.010 UGM. /M-t-3
CPD. F::LE 0060,
LINDAHE
C5H5CL
-------
TYSON VALLE1"1 1889 8x20x74' - 2199 8x20x74 CD"
SLT 79 3.9 MRS 1860-2199
FILE HO. 9902, FIT TOL. 995 0. 234E +1 CUBiiC METERS, ALIQUOT = 0. 280E +0
INST. SENSI"IVITY=0. 215E +5
CHECK HEIGH" RAT 10 = 0. 590 (TRACTION). SMOOTHED
CPD. F::LE 0051, HATE 0^2575,
HYDROCARE30NS
TOTAL ALKANEIS
ALKANES LOW MU
ALKANES MED. MU
TOTAL ALKENEIS
ALKEHES LOW MW
CL 0. 34 UGM. xM-t-3
CL 0.14 UGM. xM-t-3
CL 0. 063 UGM. xM-t3
0. 34 UGM. xM-t-3
CL O. 954 UGM. xM-t-3
ALKENES MED. MW
ALKEHES HI flW
ALPHA PIHENt:
TERRENES AS PINENE
CL 0. 15 UGM. xM-t-3
CL 0. 036 UGM. xM-t-3
0. 30 UGM. xM-t-3
CL 0.16 UGM. xM-t-3
XYLENES, MON SUB BENZENES CL 0.24 UGM.xM-t-3
XYLEHES, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
CL 0. 0089 UGM. xM + 3
CL 0. .30 UGM. /M-t-3
CL 0. 023 UGM. xM-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL:C HYDROCARBONS
NAPHTHALENE 1 0.010 UGM.xM-t-3
AHTHRACENE-F:'HENAHTHRENE 2 0.0036 UGM.xM-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.028 UGM xM-t-3
TRIMETHYLPHEINOL+ISOMERS EST 6.19 UGM.xM-t-3
DIH Y D R 0 X Y BENZENES 1 0. 0 7 6 U G M . x M -t- 3
PHENOL 1 9.0054 UGM.xM-t-3
CPD. F:LE 0054, DATE 0^2575, CARBOXYL::C ACIDS
BENZOIC ACID
PENTANDIOIC ACID
HEXANDIOIC HCID
M E T H Y L H E X A H ]) 101C A CID
BENZOYL ION (ARBITRARY!
2 8. 919 UGM. xM-t-3
EST. 1. 9 UGM. xM-t-3
41.1 UGM. xM-t-3
1 0. 19 UGM. xM-t-3
> 0.080 UGM.xM+3
ACIDS (A3 ACETIC ACID' EST 0.37 UGM.xM-t-3
CPD. F:LE 0055, DATE 082575,
NITROGEN COMPOUNDS
COHH FRAGMENT (RELATIVE'.:' 9.
C3H5N2 FRAGMENT (RELATIVE) 0.
C4H9N2 FRAGMENT (RELATIVE) 0.
PYRIDINE + PYRIDYL CPDS L 0.
PIPERIDIHES (+ISOMER3? EST 0.
085 UGM. xM-t-3
46 UGM. .-'M-t-3
078 UGM. x M-t-3
084 UGM. /M-t-3
10 UGM. xM-t-3
261
-------
PAGE 002.
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
C8H503 EST 0.27 UGM. .-'M-t-3
262
-------
TYSON VALLE1"1 2196 8/29/74. - 2409 8/29/74 CD'
SLT 71 2100-240Q
FILE HO. 0902, FIT TOL. 005 ( MILL I MASS ) RUN 9551 TO RUN 95855
DATE Q80875, PA3S3 ERROR 10 (MILLIMASS)
TOTAL SAMPLERS. 234E +1 CUBiiC METERS, ALIQUOT = 0. 379E +9
INST. SEHSI"IVITY=9. 149E +',i .
CHECK HEIGH" RAT 10 = 0. 500 (TRACTION), SMOOTHED
CPD. F::LE 0051, DATE 082575,
HYDROCARBONS
TOTAL ALKAME;S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
CL 9. 69 UGM. /M-t-3
CL 0. 27 UGM. /M-t-3
CL 9. 16 UGM. /M-t-3
CL 9. 961 UGM. /M-t-3
0.51 UGM. /M-t-3
ALKEHES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINEHEI
TERPEHES AS PINENE
CL 0. 064 UGM. /M-t-3
CL 0.13 UGM. /M-t-3
CL 0. 17 UGM. /M-t-3
0. 48 UGM. /M-t-3
CL 0.19 UGM. /M-t-3
XYLENES, MOM SUB BENZENES CL 0.19 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.016 UGM. /M-t-3
ALKYL BENZENES C9H12 CL 0.62 UGM. /M-t-3
ALKYL BENZENES C10H14 CL 0.019 UGM./M-t-3
CPD. F::LE 0052, DATE 002575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.018 UGM./M-t-3
DIBENZAHTHRV^CENES C22H14 E 0.092 UGM./M+3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPUS
CRESOLS (BENZYL ALCOHOL?)CL 0.0057 UGM. /M-t-3
PHENOL + N02, CHO, C02H? EST. 0.11 UGM./M-t-3
TRIMETHYLPHE:NOL+ISOMERS EST 0.035 UGM./n-t-s
DIHYDROXYBENZEHES 1-0.081 UGM. /M-t-3
PHENOL 1 0.035 UGM./Mt-3
CPD. F::LE 0054, DATE 002575, CARBOXYL:C ACIDS
BENZOIC ACID 2 0.
ETHYL BENZO::C ISOMERS EST. 0.
PENTANDIOIC ACID EST. 2.
HEXANDIOIC PC ID 4 3.
METHYLHEXANDIOIC ACID 10.
36 UGM. /M-t-3
030 UGM. /M-t-3
3 UGM. /M-t-3
0 UGM. /M-t3
23 UGM. /M-t-3
B E H Z 0 Y L I 0 N ( A R B I T R A R Y '.
ACIDS (AS ACETIC ACID':'
EST
0. 65
O. 66
UGM. /M-t-3
UGM. /M-t-3
CPD. F::LE 005^
HATE 082575, NITROGEN COMPOUNDS
CH2CN FRAGME:NT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPUS L
0. 083 UGM /M-t-3
1. 1 UGM. /M-t-3
0. 68 UGM. .--M-t-3
0. 0060 UGM. /M-t3
263
-------
PAGE 802.
PIPERIDIHES <+ISOMERS) EST
PVRIDIHE SULFATE EST
0. 13 UGM. /M-t-3
0. 866 UGM. /M-t-3
CPD. F:LE 0055,
CSH503 3COON02
CPD. F::LE 0057,
C6H602 ISQMEIRS
C6H802 ISOMERS
C7H1002 ISOMERS
SEC. DIFUNCTIONALS
DATE 082575, POSSIBLE
3. 1 UGM. /M-t-3
EST 0. 033 UGM. /M-t-3
EST 0.13 UGM. /M-t-3
EST 0.11 UGM. /M-t-3
EST 0. 083 UGM /M-t-3
DATE 082575, TENTATIVE! TOLUENE PRODUCES
EST 0. 68 UGM. /M-t-3
EST 0. 86 UGM. /M-t-3
EST 0. 099 UGM /M-t-3
CPD. F::LE 0053, DATE 002575, TENTATIVE TERRENE PRODUC~S
CPD. F::LE 0059,
SULFATES AS SULFURic
AMMONIUM CHLORIDE
AMMONIUM HI"RATE
SODIUM NITRATE
DATE 082575, INORGANIC COMPOUNDS
ACID 4 12. UGM. /M-t-3
3 0. 32 UGM. /M-t-3
2 0. 70 UGM. /M-t-3
1 0.051 UGM./M-t-3
CPD.
LINDAHE
F::LE 0050,
DATE 082575, CHLORIHA"
EST 0.12 UGM. 'M-t-3
'ED COMPOUNDS
264
-------
TYSON VALUE" 9866 8/21/74. - 9708 3/21/74 CD"
SLT 72 7.9 HRS 9-700
FILE NO. 0902, FIT TOL. 005 CM ILL I MASS) RUN 0421 TO RUN 045'J
DATE 032575, PASS3 ERROR 10 0. 546E +1 CUBiiC METERS, ALIQUOT=0. 190E + 0
INST. SENSI"IVITY=0. 215E +5> .
CHECK HEIGH" RAT 10 = 0. 599 (FRACTION), SMOOTHED
CPD. F:LE 0051, BATE 0532575, HYDROCAREJONS
TOTAL ALKANE:S
ALKANES LOW MW
ALKANES MED. MW
TOTAL ALKEHEIS
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENEI
TERRENES AS PINENE
CL 0.14 UGM./M-t-3
CL 0. 063 UGM. /M-t-3
CL 0.027 UGM./M*3
0.19 UGM. /M-t-3
CL 9.939 UGM./M + 3
CL 0. 069 UGM. /M-t-3
CL 9.919 UGM. /M + 3
0.11 UGM. /M-T-3
CL 0. 089 UGM. .--M-t-3
XYLENES, MON SUB BENZENES CL 0.097 UGM. /M-t-3
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
CL 0. 0056 UGM. /M-t-3
CL 0. 28 UGM. /M-t-3
CPD. F::LE- 0052, DATE 092575, POLYCYCL:C HYDROCARBONS
CPD. F::LE 0053, HATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 9.912 UGM./M*3
DIHYDROXYBENZENES 1 0.029 UGM./M-t-3
PHENOL 1 8.0936 UGM./M+3
CPD. F::LE 9954,
PENTAHDIOIC ACID
HEXAHDIOIC ACID
METHYLHEXANDIOIC ACID
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID)
DATE 082575, CARBOXYL:C ACIDS
EST. 1.5 UGM./M*3
41.5 UGM. /M-t-3
1 0.12 UGM./M+3
0. 082 UGM. /Mi-3
EST 0.21 UGM. /M-t-3
CPD. F:LE 0055, DATE 0:32575, NITROGEN COMPOUNDS
CH2CN FRAGMEENT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
PI PER I DINES ( + ISOMERS:- EST
QU INCLINE (-INTERFER?-) L
0. 054 UGM. /M-t-3
9. 26 UGM. /M-t-3
9. 045 UGM. /M-t-3
0. 097 UGM /M-t-3
0. 0036 UGM. /M-t-3
CPD. F::LE 0056;
C8H503 (PHTHALATES)
C6H1003 ISOMERS
HOOC(CH2)50N02
CPD. F::LE 0057,
C6H602 ISOMEIRS
DATE 982575, POSSIBLE
3. 5 UGM. /M-t-3
EST 0. 058 UGM /M-t-3
EST 0.13 UGM. /M-t-3
HATE 082575, TENTATIVE:
EST 9.17 UGM. /M-t-3
SEC. DIFUNCTIQNHLS
TOLUENE PRODUCES
265
-------
PAGE 602.
C6H802 ISOME-RS EST 0.26 UGM./M*3
CPD. F::LE 0053, DATE 002575, TENTATIVE; TERRENE PRODUCT'S
CPU. F::LE 0059, DATE 082575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 14. UGM./Hf-3
AMMONIUM CHLORIDE 3 0.053 UGM.xMt-3
AMMONIUM NI"RATE £ 0.47 UGM./M-t-3
SODIUM NITRATE 1 0.012 UGM.
CPD. F::LE 0060, DATE 082575, CHLORINA"ED COMPOUNDS
LIHDANE EST 0.39 UGM. ,-T-1-t-3
C5H5CL EST 0.26 UGM..'M*3
266
-------
SEATTLE 0323 10/17/74 TO 11IJ5 10/17/74 PDT
SEU3 101774 0825-1135
FILE NO. 6002, FIT TOL. 003 (MILL I MASS) RUN 0246 TO RUN 0230
DATE 031875, PASS3 ERROR 10 CL 0.037 UGM /M+3
PHENOL + N02, CHO, C02H? EST. 0.11 UGM. /M-t-3
TRIMETHYLPHE:NOL+ISOMERS EST 0.045 ucM./M*3
DIHYDROXYBENZENES 1 0.093 UGM. /M-t-3
BENZALDEHYDE: OINTERF. > L 0.023 UGM /M*S
PHENOL
1 0. 040 UGM. /M-t-3
0054,
CPD. F::LE
BENZOIC ACID
METHYL BENZOIC ISOMERS
PENTAND IOIC ACID
HEXANDIOIC ACID
M E T H Y L H E X A N1) I 0 1C ACID
DATE 082575, CARBOXYL!
2 0. 024 UGM /M-t-3
0. 023 UGM /M-t-3
0.91 UGM. /M-t-3
1. 0 UGM. /M-t-3
C ACIDS
EST.
EST.
4
1
0. 083 UGM. /M-t-3
267
-------
PAGE 692.
BEHZOYL ION (ARBITRARY)
ACIDS CAS ACETIC ACID)
EST
0. 26 UGM. .-71*3
1.3 UGM./M-t-3
CPU. F::LE 9055, DATE 092575, NITROGEN COMPOUNDS
CH2CN FRAGMENT fRELATIVE)
CQNH FRAGMENT CRELATIVE)
C3H5N2 FRAGMENT (.RELATIVE)
PYRIDIHE + PYRIDYL CPDS L
PI PER I DINES <+ISOMERS) EST
0.11 UGM. /M-t-3
9. 082 UGM. /M-t-3
9.15 UGM. .'11*3
0. 0040 UGM. /M-t-3
0. 051 UGM /M-t-3
CARBAZOLE
QUINOLINE
C--IHTERFER?)
L 0. 8062 UGM. /M-t-3
L 0.011 UGM /M-t-3
CPU. F::LE ease,
C8H503
-------
SEATTLE 1140 10x17/74 TO 16:59 10/17/74 PDT
SEU 4
FILE HO. 0003, FIT TOL. 065 (MILL I MASS) RUN 0826 TO RUN 0860
DATE 750821, PASS3 ERROR 10 CM ILL I MASS)
TOTAL SAMPLt: = 0. 730E +1 CUBIIC METERS, ALIQUOT=0. 800E -1
IHST. SENSI"IVITV=0. 470E +4
CHECK HEIGH" RAT 10=0. 500 EST 1.1 UGM./M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 0.40 UGM./M-t-3
C3H5N2 FRAGMENT (RELATIVE) 0.88 UGM..--M-t-3
PYRIDINE + PYRIDYL CPDS L 0.953 UGM /M-t-3
PIPERIDINES (+ISQMERSJ EST 0.099 UGM./M-t3
CPD. F::LE 0055, DATE 002575, POSSIBLE SEC. DI FUNCTIONAL*
C8H503 (PHTHALATES) 6.9 UGM. /M-t-3
HOOi::(CH2)40H02 EST 0.47 UGM. /M-t-3
CPD. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRODUCES
C5 H 8 0 3 IS 0 M E[ R S EST 0.44 U G M. / M -t- 3
CPD. F::LE 0058, DATE 002575, TENTATIVE: TERRENE PRODUCE'S
269
-------
PAGE 002.
CPD. F::LE 0059, ~ATE 902575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 15. UGM./M-t.3 .
AMMONIUM CHLORIDE 3 0.50 UGM. /M-t-3
AMMONIUM NT'RATE 2 2.5 UGM. /M-t-3
SODIUM NITRATE 1 0.072 UGM./M-t-3
CPD. F::LE 0060, DATE 0:32575, CHLORINA"ED COMPOUNDS
LINDANE . EST 0.93 UGM. /'M-t-3
C5H5CL EST 1.1 UGM. /M-t-3
270
-------
SEATTLE 1640 19/17x74 TO 2200 10/17/74 PDT
SEU 5
FILE HO. 00^3, FIT TOL. 085 CM ILL I MASS) RUN 0861 TO RUN 0895
DATE 750821, 'PASS3 ERROR 10 (MILL I MASS)
TOTAL sAMPLE: ==0. sees +1 cue::c METERS, ALi: +1NTERF.
EST.
i
L
L
20 UGM..
097 UGM
070 UGM
019 UGM
M-t-3
/M + 3
/M-t-3
/M-t-3
PHENOL
1 0. 026 UGM. /M-t-3
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC ACID 2 0
METHYL BENZOIC ISOMERS EST. 0
PENTANDIOIC ACID EST. 0
HEXANDIOIC HCID 4 0
METHYLHEXANDIOIC ACID 11
073 UGM. /M-t-3
062 UGM /M-t-3
48 UGM. .'• M-t-3
96 UGM. .--M-t-3
2 UGM. /M-t-3
271
-------
PAGE 902.
BENZOYL I OH (ARBITRARY;
ACIDS I SOMERS > EST
CARBAZOLE L
ACRIDIHE & ::SOMERS L
0. 57 UGM. /M-t-3
0. 38 UGM. /M-t-3
0. 20 UGM. .•'M-t-3
0. 027 UGM. .-" M-t-3
0.010 UGM /M-t-3
PYRIDINE SULFATE
EST 0. 089 UGM. /M-t-3
CPD. F:LE 0056, DATE
C8H503 CPHTMALATES)
HCO
HATE 0B2575, INORGANIC
ACID 47.4 UGM. /M-t-3
3 0. 93 UGM. .--M-t-3
22.8 UGM. /M-t-3
1 0.21 UGM. /M-t-3
HATE 082575, CHLORINA"
EST 0. 34 UGM. /M-t-3
EST 0. 72 UGM. /M-t-3
COMPOUNDS
'ED COMPOUNDS
272
-------
SEATTLE 2210 19/17/74 TO 09:.0 10/18/74 PDT
SEU 6
FILE HO. 9003, FIT TOL. 005 (MILLIMASS) RUN 0896 TO RUN 0930
DATE 750321, PASS3 ERROR 16 (MILL I MASS)
TOTAL SAMPLERS. 165E +2 CUB'/.C METERS, ALIQUOT = 0. 860E -1
INST. SENSI"IVITY=0. 470E +4
CHECK HEIGH" RAT 10 = 0. 500 (TRACTION), SMOOTHED
CPU. F::LE 0051, DATE 002575, HYDROCARBONS
TOTAL ALKAHtrS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENF.S
ALKENES LOW MW
ALKENES MED. MW
ALKENES HI HW
ALPHA PINENE:
TERRENES AS PINENE
CL 0. 99 UGM. /M-t-3
CL 0. 24 UGM. /M-t-3
CL 0. 39 UGM. .--M-t-3
CL 0. 083 UGM. /M-t-3
1. 3 UGM. /M-t-3
CL 0.16 UGM. /M-t-3
CL 0. 53 UGM. /M-t-3
CL 0.41 UGM. /Mt-3
1.4 UGM./M + 3
CL 0.41 UGM. /M-t-3
XYLENES,MOH SUB BENZENES CL 0.
XYLENES, ETHYL BENZENE CL 0.
ALKYL BENZENES C9H12 CL 1.
ALKYL BENZENES C19H14 CL 0.
DIPHENYL ETHANE & ISOMERS L 0.
38 UGM. /M-t-3
10 UGM. /M-t-3
6 UGM. /f'U-3
15 UGM. /M-t-3
040 UGM. /M-t-3
CPD. F:LE 0052, DATE 082575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 0.054 UGM /M-t-3
METHYL NAPH"HALEHES + INT. L 0.019 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 0.016 UGM. /M-t-3
PERYLENE, ISOMERS C20H12 L 0.026 UGM. /M-t-3
BENZOPERYLENE+INTERFER.
E 0. 043 UGM. /M-t-3
DIBENZANTHRttCENES C22H14 E 0.052 UGM. /M-t-3
CPD. F::LE 0053, DATE 002575, AROMATIC OXYGENATED CPDS
CRESOLS (BENZYL ALCOHOL?)CL 0.0091 UGM./M-t-3
PHENOL + H02, OHO, C02H? EST. 0.070 UGM. /M-t-3
DIHYDROXYBEHZENES 1 0.17 UGM. /M-t-3
PHENOL 1 0.00S1 UGM./M+3
CPD. F:LE 0054, HATE 05
BENZOIC ACID 2
METHYL BENZOIC ISOMERS EST.
TRI METHYL BEINZOIC ISOM. EST
PENTANDIOIC ACID EST.
HEXAHDIOIC HCID 4
:2575, CARBOXYL::C ACIDS
0. 13 UGM. /M-t-3
0. 046 UGM /M-t3
0. 046 UGM /M-t-3
0. 86 UGM. /M-t-3
1.1 UGM. /M-t-3
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC ACID>
0. 65 UGM. /M-t-3
EST 2. 5 UGM. /M-t-3
273
-------
PAGE Q82.
CPD. F::LE 0055, DATE
COHH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
PI PER I DINES C + ISOMERSJ EST
CARBAZOLE L
902575, NITROGEN COMPOUNDS
1 . 1 UGM. /M-t-3 .
0.21 UGM. .'M-t-3
0. 52 UGM. .-'M-t-3
0.11 UGM. .-'M-t-3
0. 842 UGM
QUINOLINE (--1NTERFER? >
PYRIDINE SUL.FATE
L 0. 036 UGM /M-t-3
EST 8. 37 UGM. .-'M-t-3
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC.
CSH503 (PHTHALATES) 1.3 U G M.--• M-t-3
C5H1002 ISOMERS EST 0.21 UGM. /M-i-3
DIFUHCTIOHALS
DATE 082575, TENTATIVE TOLUENE PRODUC"S
EST 1. 4 UGM. /M-t-3
EST 0.14 UGM. /M-t3
EST 0.11 UGM.
CPD. F::LE 0057,
C6H602 ISOME:RS
C6H802 ISOMEIRS
C5H803 ISOMEIRS
CPD. F::LE 0059, DATE 002575, TENTATIVE: TERPENE PRODUC."
CPD
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHI.OP IDE
NI"RATE
SODIUM NITRATE
CPD. F::LE 0060,
C5H5CL (HEP"ACHLOR?)
DATE 002575, INORGANIC COMPOUNDS
ACID 4 6. 2 UGM. .•-M-t-3
3 1.1 UGM. xM-t-3
27.0 UGM. xM-t-3
1 0. 090 UGM. .--M-t-3
DATE 002575, CHLORIHA"ED COMPOUND';
EST 0. 65 UGM. xM-t-3
274
-------
SEATTLE 092« 10/18/74 TO 16:.Q 16/18/74 PUT
SEU 7
FILE HO. 9003, FIT TOL. 895 RUN 0931 TO RUN 0961:5
DATE 750821, PASS3 ERROR 10
TOTAL SAMPLfI = e. 103E +2 CUBiiC METERS, ALIQUOT=0. 160E +0
INST. SENSI"IVITY=0. 470E +4
CHECK HEIGH" RAT 10 = 0. 500 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 002575, HYDROCAREJONS
TOTAL ALKANF.S
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI HW
TOTAL ALKENE:S
ALKENES LOW MW
ALKENES MED. MW
ALKEHES HI MW
ALPHA PINENE:
TERRENES AS PIHENE
CL 0. 89 UGM. /M-t-3
CL 0. 13 UGM. /M-t-3
CL 0. 52 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
1. 6 UGM. /M + 3
CL 0.13 UGM. /M-t-3
CL 0. 73 UGM. /M-t-3
CL 0. 60 UGM. /M-t-3
1. 7 UGM. /M-t-3
CL 0.71 UGM. /M-t-3
XYLENES, MON SUB BENZENES CL 0.54 UGM./M-t-3
XYLENES, ETHYL BENZENE CL 0.11 UGM. /M-t-3
ALKYL BENZENES C9H12
ALKYL BENZENES C10H14
BIPHENYL
CL 2. 1 UGM. /M-t-3
CL 0.11 UGM. /M-t-3
1 0.012 UGM. /M-t-3
CPD. F::LE 0052, DATE 082575,
NAPHTHALENE 1 0.
ALKYL NAPHTHALENES C12H12 L 0,
ANTHRACENE-PHENANTHRENE 2 0.
PYREHE & ISOMERS C16H10 L 0
PERYLENE, ISOMERS C20H12 L 0,
POLYCYCLTC
085 UGM./M + 3
040 UGM /M-t-3
0053 UGM. /M-t-3
11 UGM..-'M-t-3
016 UGM. /M-t-3
HYDROCARBONS
BENZOPERYLENE+IHTERFER.
E 0. 039 UGM. /M-t-3
CPD. F::LE 0053, HATE 0-82575,
CRESOLS (BENZYL ALCOHOL?>CL 0.091
PHENOL+N02,CHO,C02H? EST. 0.
TRIMETHYLPHMNOL+ISOMERS EST 0.
DIHYDROXYBENZENES 1 0.
BENZALDEHYDE: C + INTERF :> L 0.
AROMATIC
UGM /M*3
43 UGM. /M-t-3
044 UGM./M+3
23 UGM. /M-t-3
018 UGM /M-t-3
OXYGENATED CPUS
PHENOL
1 0.10 UGM. /M-t-3
CPD. F::LE 0054, DATE 082575, CARBOXYL::C ACIDS
BENZOIC ACID 2
METHYL BENZOIC ISOMERS EST.
ETHYL BENZOIC ISOMERS EST.
TR I METHYL BELNZOIC ISOM. EST
PENTAND I QIC ACID EST.
0. 12 UGM. /M-t-3
0.11 UGM. .--M-T-3
0.17 UGM. /Mt-3
9. 067 UGM. /M-t-3
3.1 UGM. /M-t-3
275
-------
PAGE 082.
HEXANDIOIC ACID
METHYLHEXAND I 0 I C AC I D
BEHZOVL ION (ARBITRARY)
ACIDS CAS ACETIC ACID'J
44.1 UGM. /M-t-3
1 2.8 UGM./M-t-3
0. 97 UGM. /M-t-3
EST 2. 6 UGM. /M-t-3
CPU. F::LE 0055, DATE
CH2CN FRAGMEINT < RELATIVE)
COHH .FRAGMENT (RELATIVE)
C3H5H2 FRAGMENT (RELATIVE)
CH2H03 FRAGMENT (RELATIVE)
C4H9H2 FRAGMENT (RELATIVE)
002575, NITROGEN COMPOUNDS
0. 40 UGM. /Mt-3
1.3 UGM./M-t-3
O. 29 UGM. / M-t-3
O. 078 UGM /M-t-3
0.15 UGM. /M-t-3
PYRIDINE + PYRIDYL CPDS
PI PER I DINES
CARBAZOLE
QU I NOLI HE (-
ISOMERS:*
IHTERFER?
L 8. 0869 UGM. /Mt-3
EST 0. 13 UGM. /M-t3
L 0.013 UGM /M-t-3
L 0. 049 UGM /M-t-3
CPD. F::LE 0056, DATE
C8H503 (PHTHALATES)
C6H1004 (AD::PIC ACID) DUP
C6H1003 ISOMERS EST
C5H1002 ISOMERS EST
HCO(CH2)50N02+ISOMERS EST
882575, POSSIBLE
4. 3 UGM. /M-t-3
SEC. DIFUHCTIONALS
2. 0 UGM. /M-t-3
0. 57 UGM. /M-t-3
0.16 UGM. /M-t-3
0. 28 UGM. /M-t-3
HCO(CH2)4COONO
EST @. 10 UGM. /M-t-3
CPU. F':LE 0057, DATE ej
C6H602 ISOMEIRS EST
C6H802 ISOMFIRS EST
C7H1002 ISOMERS EST
C5H803 ISOMEERS EST
C6H804 ISOMEIRS EST
2575, TENTATIVE!
1. 9 UGM. /M-t-3
2. 0 UGM. /M-t-3
0. 46 UGM. /M-t'3
0. 50 UGM. /M-t-3
0.10 UGM. /M-t-3
TOLUENE PRODUCE'S
C7H7H04 ISOMERS
HITROCRESOLS?
EST 0.015 UGM, /M-t-3
L 0.015 UGM. /M-t-3
CPU. F::LE 0058, DATE 002575, TENTATIVE: TERPENE PRODUCES
C9H1402 ISOMERS EST 0.11 UGM./M-t-3
CPD. F::LE 0059, DATE 002575,
INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID
AMMONIUM CHLORIDE
AMMONIUM HF'RATE
SODIUM NITRATE
4 10. UGM. /M-t-3
3 0. 60 UGM. .--M-t-3
2 10. UGM. /M-t-3
1 0. 34 UGM. .--M-t-3
CPD. F::LE oeee,
LINDAHE
C5H5CL (HEP"ACHLOP?)
DATE 002575, CHLORINA"
EST 6. 16 UGM. /M-t-3
EST 0. 72 UGM. /M-t-3
ED COMPOUNDS
276
-------
SEATTLE 1620 10/18/74 TO 2300 10/18x74 PDT
SEU 8
FILE HO. 9903, FIT TOL. 695 (MILLIMASS) RUN 8036 TO RUN 0970
DATE 750S21, PASS3 ERROR 10 (MILLI MASS)
TOTAL SAMPLE->@. 999E +1 CUBiiC METERS. ALIQUOT=0. 800E -1
IHST. SEHSI"IVITY=0. 476E +4
CHECK HEIGH" RAT 10 = 0. 509 (TRACTION), SMOOTHED
CPU. F::LE 0051, DATE 082575, HYDROCARBONS
TOTAL ALKANEIS
ALKANES LOU MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKENEIS
ALKEHES LOW MW
ALKEHES MED. MW
ALKEHES HI MW
ALPHA PIHEHE:
TERRENES AS PIHEHE
CL 2.2 UGM. /M-t-3
CL 0.71 UGM. /M-t-3
CL 0. 93 UGM. /M-t-3
CL 0. 28 UGM. /M-t-3
2. 9 UGM. /M-t-3
CL 0. 56 UGM. /M-t-3
CL 1. 3 UGM. /M-t-3
CL 0. 86 UGM. /M-t-3
2. 2 UGM. /M-t-3
CL 0. 99 UGM. /M-t-3
X Y L E N E S.- M 0 H S U B B E N Z E N E S C L 0.76 U G M. / M -t- 3
XYLEHES, ETHYL BEHZEHE CL 0.23 UGM./M-t-3
ALKYL BENZENES C9H12 CL 4.8 UGM. /M-t-3
ALKYL BENZENES C10H14 CL 0.076 UGM./M+3
CPU. F::LE 0052, DATE 082575,
POLYCYCL::C HYDROCARBON:;
NAPHTHALENE 1
ALKYL HAPHTHALEHES C12H12 L
PYREHE & ISOMERS C16H10 L
CHRYSENE, ISOMERS C13H12 L
DIBENZANTHRACENES C22H14 E
0.12 UGM./M + 3
0. 065 UGM /M-t-3
0. 037 UGM /M-t-3
0. 062 UGM. /M-t-3
0. 20 UGM. /M-t-3
CPU. F::LE 0053, DATE 082575, AROMATIC OXYGENATED CPUS
PHENOL + N02, OHO, C02H? EST. 0.34 UGM./M-t-3
DIH Y D R 0 >•-, Y B E N Z E N E S 1 0.079 U G M . / M + 3
PHENOL 1 0. 12 UGM. /M-t-3
CPD. F::LE 0054, DATE 0:32575, CARBOXYL::C ACIDS
BENZOIC ACID
2 0. 090 UGM. /M-t-3
ETHYL BENZO::C ISOMERS EST.
PENTAHDIOIC ACID EST.
HEXANDIOIC ACID 4
BEHZOYL I OH (ARBITRARY)
9.19 UGM. /M-t-3
3.5 UGM. /M-t-3
4.6 UGM. /M-t-3
1.1 UGM. /M-t-3
ACIDS (AS ACETIC ACID:- EST 6.0 UGM. /M-t-3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
CONH FRAGMENT (RELATIVE) 3.0 UGM. /M-t-3
C3H5H2 FRAGMENT (RELATIVE) 0.75 UGM./M-t-3
PIPERIDIHES ( + ISOMERS J EST 9.064 UGM /M-t-3
CARBAZOLE L 0.933 UGM . ,-"M-t-3
277
-------
PAGE 692.
ACRIDINE & ::SOMERS L 9.037 UGM. /M-t-3
QUINOLIHE <--INTERFER?> L 0.017 UGM /M-t-3
NITRONAPHTHALENE EST 0.012 UGM. /M-t-3
CFD. F::LE 0055, DATE
C8H503 CPHTHALATES)
C5H1603 ISQMERS
HCO < CH2 :> 40N02+ I SOMEP.S
HCO < CH2:.' 5COON02+1 SOMERS
882575, POSSIBLE
5. £ UGM. /M-t-3
EST 0. 23 UGM. .'M + 3
EST 0. 16 UGM. /M-t-3
EST 0. 32 UGM. /M-t-3
SEC. DIFUHCTIQNMLS
CPD. F::LE 0057,
C6H602 ISOMEEPS
C6H802 ISOMEIRS
C7H1602 ISOMERS
C5H803 ISOMEERS
DATE 082575, TENTATIVE!
EST 0. 67 UGM. xM-t-3
EST 1. 2 UGM. /M-t-3
EST 0. 64 UGM. /M-t-3
EST 0. 56 UGM. /M-t-3
TOLUENE PRODUCT'S
CPD. F::LE 0053, DATE 002575, TENTATIVE TERPENE PRODUCES
C9H1404 CPINIC ACID?) EST 0.26 UGM. /M-t-3
CPU.
SULFATES
AMMONIUM
AMMONIUM
F::LE 0059,
AS SULFUR 1C
CHLORIDE
NI"RATE
SODIUM NITRATE
DATE 082575, INORGANIC COMPOUNDS
ACID 4 11. UGM. /M-t-3
3 1.8 UGM. /M-t-3
27.1 UGM. /M-t-3
1 0. 095 UGM /M-t-3
CPD. F::LE 0060, DATE 082575,
LIHDANE EST 0.55
C5H5CL EST 0.14
CHLORINA"
UGM. .--M-t-3
UGM. /M-t-3
'ED COMPOUNDS
278
-------
SEATTLE 2310 16/18/74 TO 12S0 10/1
PDT
SEU 9
FILE HO. 6803, FIT TOL. 665 (HILL I MASS) RUN 6671 TO RUN 61655
DATE 756821, PASS3 ERROR 16 (MILL I MASS)
TOTAL SAMPLE'S. 265E +2 CUB'/.C METERS, ALIQUOT=6. 866E -1
IHST. SENSI"IVITV=6. 476E + 4
CHECK HEIGH" RAT 10 = 8. 586 (FRACTION), SMOOTHED
CPD. F::LE 0051, DATE 682575,
HYDROCARE30NS
TOTAL ALKANIIS
ALKANES LOW MW
ALKANES MED. MW
ALKANES HI MW
TOTAL ALKEHEIS
ALKEHES LOW MW
ALKENES MED. MW
ALKENES HI MW
ALPHA PINENi:
TERRENES AS PINENE
XYLENES,MON SUB BENZENES
XYLENES, ETHYL BENZENE
ALKYL BENZENES C9H12
ALKYL BENZENES C18H14
BIPHENYL
CL 1. 5 UGM. /M-t-3
CL 6. 27 UGM. /M-t-3
CL 0. 55 UGM. /M-t-3
CL 6. 37 UGM. /M-t-3
2. 1 UGM. /M-t-3
CL 8. 29 UGM. /M-t-3
CL 8.91 UGM./M+3
CL 0.93 UGM./M+3
2. 1 UGM. /M-t-3
CL 0. 70 UGM. /M-t-3
CL 0. 63 UGM. /M-t-3
CL 6. 18 UGM. /M-t-3
CL 3. 0 UGM. /M-t-3
CL 0. 33 UGM. /M-t-3
1 0.811 UGM. /M-t-3
CPD. F::LE 0552, DATE 682575, POLYCYCL::C HYDROCARBONS
NAPHTHALENE 1 9.18 UGM. /M-t-3
METHYL NAPH"HALENES+INT. L 6.16 UGM./M-t-3
ALKYL NAPHTHALENES C12H12 L 6.813 UGM./M-t-3
PYRENE S-. ISOMERS C16H18 L 8.623 UGM./M-t-3
PERYLENE, ISOMERS C28H12 L 8.666 UGM./M*3
BENZOPERYLENE+INTERFER.
DIBENZANTHP.ACENES C22H14
E 8. 886 UGM. /M-t-3
E 6. 649 UGM. /M-t-3
CPD. F::LE 6853, DATE 882575,
CRESOLS (BENZYL ALCOHOL?)CL 6.611
PHEHOL+N02,OHO,C02H? EST.
DIHYDRQXYBENZENES 1
BENZALDEHYDE: ( + INTERF ) L
PHENOL i
AROMATIC
UGM. /M-t3
6. 29 UGM. /M-t-3
0.23 UGM./M*3
0.016 UGM /M-t-3
0.615 UGM. /M-t-3
OXYGENATED CPD3
CPD. F::LE 0054, DATE 982575, CARBOXYL::C ACIDS
BENZOIC A cm
M E T H Y L B E N Z 01 C I S 0 M E R S
ETHYL BENZO::C ISOMERS
PENTANDIOIC ACID
HEXAND IOIC ACID
M E T H Y L H E X A H ]) 10 I C ACID
28.19 UGM. /M-t-3
EST. 0. 26 UGM. /M-t-3
EST. 6. 082 UGM. /M-t-3
EST. 3. 7 IJGM. /M-t-3
44.0 UGM. /M-t-3
1 2.5 UGM. /M-t-3
279
-------
PAGE 092.
BENZOYL ION (ARBITRARY)
ACIDS (AS ACETIC. ACID
EST
0. 91 UGM. /M + 3
5.1 UGM./M*3
CPD. F::LE 0055, DATE
CH2CN FRAGMENT (RELATIVE)
CONH FRAGMENT (RELATIVE)
C3H5N2 FRAGMENT (RELATIVE)
CH2N03 FRAGMENT (RELATIVE)
PYRIDINE + PYRIDYL CPDS L
002575, NITROGEN
0.18 UGM. /M-t-3
1 . 7 UGM. /M + 3
0. 52 UGM. ."-M-t-3
0.14 UGM. /M-t-3
COMPOUNDS
0. 046 UGM. /M-t-3
PI PER IDINES ( + ISOMERS )
CAREAZOLE
ACRIDINE & "SOMERS
QIJ I NOLI NE •: --1 NTERFER? )
NITRONAPHTHALENE
PYRIDINE SULFATE
EST 0. 23 UGM. /M-t-3
L 0. 16 UGM. /M-t-3
L 0. 022 UGM. /M-t-3
L O. 032 UGM /M-t-3
EST 0. 0065 UGM. /M-t-3
EST 0.19 UGM./M+3
CPU.
C7H1204 <
C8H503 (PHTHALATES)
C6H1003 ISOMERS
C5H1003 ISOMERS
HOOC(CH2)50N02
F::LE 0056, DATE 002575.. POSSIBLE SEC.
ME"HYL ADIPIC) DUP 2.0 UGM./M+3
2. 1 UGM. /M-t-3
EST 0. 078 UGM. /M-t-3
EST 0.15 UGM. /M + 3
EST 0. 20 UGM. /M-t-3
DIFUNCTIONRLS
HOOC(CH2:-40N02
H C 0 ( C H a ) 6 0 H 0 2 + I S 0 M E P S
H C 0 ( C H 2 ) 5 0 NO 2+I'B 0 M E R S
HCO(CH2)40H02+ISOMERS
HOOC(CH2:'3COOH02
EST 0.19 UGM.
EST 0. 68 UGM. xM^3
EST 0. 10 UGM. .--M-t-3
EST 0. 10 UGM. xM-t-3
EST 0. 13 UGM. .---M-t-3
HCO
-------
PAGE 803.
AMMONIUM CHLORIDE 3 1.4 UGM./M*3
AMMONIUM NI"RATE 2 6.3 UGM.xM-t-3
SODIUM NITRATE 1 0.21 UGM. .'M-t-3 .
CPD. F::LE oeee, DATE 002575, CHLORINA-ED COMPOUNDS
LINDANE EST 0.25 UGM. /-M-t-3
C5H5CL
-------
SEA 2 AUTO EIXHAUST, WITHOUT CONVERTER, IDLE
SEA 2 AUTO EXHA UST
FILE HO. 0902, FIT TOL. 005 L 120. UGM. /M-t-3
1 24. UGM. /M-t-3
OXYGENATED CPUS
CPD. F::LE 0054, DATE 002575, CARBOXYL::C ACIDS
BENZOIC AC IH 2 260. UGM./M-t-3
BENZ 0 Y L I 0 N ( ARBITRARY ) 1700. U G M . / M -t- 3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
COHH FRAGMENT < RELATIVE) 340. UGM./M-t-3
P I PER I D I NES < + I SOMERS > EST 4 1 . UGM. /M-t-3
282
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PAGE 902.
ACRIDINE & HSOMERS L 25. UGM./M+3
CPD. F::LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTIONALS
CPD. F::LE 0057, DATE 002575, TENTATIVE; TOLUENE PRODUCE
C5H803 ISOMEIRS EST 97. UGM.xM+3
CPU. F::LE 0058, DATE 002575, TENTATIVE: TERRENE
CPU. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFURIC ACID 4 400. UGM..'M*3
AMMONIUM CHLORIDE 3 250. UGM./M-t-3
CPD. F::LE 0060, DATE 002575, CHLORINATED COMPOUNDS
C5H5CL
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SEA 6 AUTO EXHAUST, WITH CONVERTER, IDLE
SEA 6 C3) AUTO EXHA
FILE NO. 601:12, FIT TOL. 905 CHILL I MASS) RUN 9671 TO RUN 81955
DATE 750819, PASS3 ERROR 10 Y R I D Y L C P D S L 1 . 0 U G M . ,"' M -t- 3
CPD. F::LE 005.5, DATE 002575, POSSIBLE SEC. DIFUHCTIQNMLS
C8H503 CPHTHALATES) 730. UGM..--M-t-3
CPD. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PF:ODU::"S
C 7 H 7 N 0 4 I S 0 M E R S EST 2 . 8 U G M . .••" M -t 3
CPU. F!'LE 0053, DATE 902575, TENTATIVE TERRENE PRODUCTS
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
A M M 0 N I U M CHLORIDE 31.7 U G M . /" M -t- 3
CPD. F::LE 0060, DATE 002575, CHLORINATED COMPOUNDS
C5H5CL CHEP-'ACHLOR?) EST 31. UGM./M-t3
284
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SEA 7 AUTO EIXHAUST, WITH CONVERTER, HI RPM
SEA 7 AUTO EXHA UST
FILE HO. 0002.. FIT TOL. 005 (MILLIMASS) RUH 0106 TO RUN 0140
DATE 750819. PAS33 ERROR 10 EST 47. UGM./M+3
CPD. F::LE 0055, DATE 002575, NITROGEN COMPOUNDS
PI PERI DINES < + ISOMERS) EST 9.0 UGM. ,-"M-t-3
CPD. FT.LE 0056, DATE 002575, POSSIBLE SEC. DIFUNCTI OHfiLS
C8H503 (PHTHALATES) 1500. UGM. .-"M-t-3
CPD. F::LE 0057, DATE 002575, TENTATIVE: TOLUENE PRQBUC-S
CPD. F::LE 0053, DATE 002575, TENTATIVE: TERPENE PRODUC-S
CPD. F::LE 0059, DATE 002575, INORGANIC COMPOUNDS
SULFATES AS SULFUR 1C ACID 4 110. UGM. .-'M-t-3
CPD. F::LE eese, DATE 002575, CHLORINA"ED COMPOUNDS
C5H5CL (HEP"ACHLOR?> EST 146. UGM.xM+3
285
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U A S H I H G I 0 Mil I M P H C T 0 R @ 8 0 0 - 0 ? 5 0 3 .••' 2 0 .-'74 C D ""
SLW 65 I MPACTOP 1.3 HP::5
FILE NO. OOH2. FIT TOL. 003 '" M I LL I MASS '•' RUN 04? 1 TO RUN u52c
DATE 032075. PASS3 EPROP 10 • H I LL INnSC. '.-
TOTAL SAMPLKX3 230E +1 CUS:C METERS. AL. I Q U iM T = C 330F +0
INST. SENSI' IV! TY-O 230E +?."•
CHECK HEIGH" P n T I 0 - 0 . 500 'FPuCTION , SMOOTHED
C P D . F " L E 0 9 51.. D IH T E 0 ::J 2 5 T 5 . H Y D P 0 C H P E : 0 N S
TOTAL. ALfi-n-irS CL 0.044 UCM •• M f 3
Es L0»i ni.l CL U 0074 UGH -Mt3
ES MED MM CL 0 C044 UGM. ••• 11 1 3
TOTHL rtLFEliE::. 0.033 UGM 'M-t-3
CFD F'LE 0652. IiHTE -302575. POLVCVC L "C HVDROCrtPBOrJS
CPU. F'LE 0353, DnTE 0::;257.5.. AROMHTIC 0';','} GEMRTETi CFD=.
C P D F L E 0 0 5 4 , D n T E 0 '•''• 257 5 , C H R B 0 X V L :: C i^i C I D S
HCIDS '!HS HiETIC HCID1 EST 0 012 UGM • M 1 3
C P D . F . LE 0 0 5 5 , "J H T E 9 ;• '; £ 5 7 5 . N I T P 0 G E ,M C 0 N P 0 U H P S
C 3 H 5 H 2 F P A G t i E N T '.' P E L H f I V E :• 0 0 S 5 U G M t 3
CPD. F', LE 0053. ~HTE .Ji.;2575, POSSIBLE SEC D I FUI ICT I 0: \Hl
C8H503 .. PKTH'HLhTES"' 0. 13 UCM . Mt3
CPU F LE 0057, JuTE or>2575, TENTnTIVE: TOI.UEHE Ppn7iu
C P D F'LE 0 0 5 3 . D H T E -3 . .: 2 5 7' -5 , T E i I T H f I V E T E P P E N E I-1 P 0 D IJ
CPD F LE 005?. JnTE 0^2575. INOPGnNir: COMPOUNDS
SULFnTES HE, SULFUPIC nCID -1 . 3 UGM • M 1 3
H M M 0 N I U M C H L 0 P IDE 3 0 1 0 U G M . M t j!
HMMONIUM NI'T'HlE 2 0 4b UGM • M 1 3
CPD F"LE Li-HtSO, HATE 002575, C HI. OP I MM"' ED COMPOUNDS
LIHDAHF EST 0 2? UGM. lit 3
286
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-600/3-76-093
3. RECIPIENT'S ACCESSION>NO.
4. TITLE AND SUBTITLE
ANALYSIS OF ATMOSPHERIC ORGANIC AEROSOLS BY
MASS SPECTROSCOPY
6. REPORT DATE
August 1976
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Alden L. Crittenden
STPERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
University of Washington
Department of Chemistry
Seattle, Washington 98195
10. PROGRAM ELEMENT NO.
1AA003
11. CONTRACT/GRANT NO.
801119
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Sciences Research Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final 6/72 - 10/75
14. SPONSORING AGENCY CODE
EPA-ORD
15. SUPPLEMENTARY NOTES
16. ABSTRACT
High resolution mass spectroscopy has been found to be a useful means of charac-
terizing the organic fraction of urban aerosols. Quantitative accuracy, however,
was limited, particularly for compounds of low abundance. Some ambiguities were
found in the assignment of origins of ions formed in the mass spectrometer.
Compounds that were detected included phenols; aromatic carboxylic acids and,
possibly, esters of these; and aliphatic dibasic acids. Evidence was found of
several other difunctional compounds, including nitrate or nitrite species.
Strong evidence was found for the presence in some urban aerosols of compounds
reported by others as products of the oxidation of toluene in smog chamber reactions.
Less evidence was found for products formed by the oxidation of terpenes.
A few samples of automobile exhaust particulates were analyzed. The occurrence of
benzoic acid and the benzoyl ion in mass spectra appear to be possible indicators
of automotive contribution to the organic components.
Results for a large number of compounds are provided for 88 samples of aerosols
collected at sites located in the greater Los Angeles, Seattle, St. Louis, and
Denver areas.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS C. COS AT I Field/Group
*Air pollution
*Aerosols
*0rganic compounds
*Chemical analysis
*Mass spectroscopy
13B
07D
07C
14B
18. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
19. SECURITY CLASS (This Report)
UNCLASSIFIED
21. NO. OF PAGES
295
20. SECURITY CLASS (This page)
UNCLASSIFIED
22. PRICE
EPA Form 2220-1 (9-73)
287
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