United States
              Environmental Protection
              Agency

              Research and Development
              f . ironmental Sciences Research  fc'PA oOO 4 78021
              I 3toratory          M,n 1 978
              Pt--.earch Triangle Park NC 27711
vvEPA
Atmospheric
Dispersion
Parameters  in
Plume Modeling

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U S Environmental
Protection Agency, have been grouped into nine series These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology  Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are

      1   Environmental  Health Effects Research
      2   Environmental  Protection Technology
      3   Ecological Research
      4.  Environmental  Monitoring
      5.  Socioeconomic Environmental Studies
      6   Scientific and Technical Assessment Reports (STAR)
      7   Interagency Energy-Environment Research and Development
      8.  "Special" Reports
      9   Miscellaneous Reports

This report has been assigned to the ENVIRONMENTAL MONITORING series.
This series describes research conducted to develop new or improved methods
and instrumentation for the identification and quantification of  environmental
pollutants at the lowest conceivably significant concentrations. It also includes
studies to determine the ambient concentrations of pollutants in the environment
and/or the variance of pollutants as a function of time or meteorological factors.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia  22161.

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                                              EPA-600/4-78-021
                                              May 1978
ATMOSPHERIC DISPERSION PARAMETERS IN PLUME MODELING
                   F. Pasquill
                Visiting Scientist
        Meteorology and Assessment Division
     Environmental Sciences Research Laboratory
    Research Triangle Park, North Carolina 27711
     ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
         OFFICE OF RESEARCH AND DEVELOPMENT
        U.S. ENVIRONMENTAL PROTECTION AGENCY
    RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711

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                                 DISCLAIMER

     This report has been reviewed by the Environmental  Sciences Research
Laboratorys U.S. Environmental  Protection Agency, and approved for
publication.  Mention of trade names or commercial  products does not
constitute endorsement or recommendation for use.
                                      n

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                                   ABSTRACT
     A brief survey is given of the present position in the specification  of
atmospheric dispersion parameters  for use in estimating pollutant concentra-
tion from a continuous point release.
     The theoretical indications of the distribution to be expected across a
time-mean plume are recalled, with particular reference to the  existence of
the Gaussian form.  Observational  evidence, especially as  regards the  vertical
distribution from a surface release, is also recalled, and the  practical
significance of departure from an  assumed Gaussian form is noted.
     The use of the Taylor statistical  theory in the generalized  estimation
of crosswind spread in quasi-ideal boundary layer flow is  briefly summarized.
Recent considerations of the behaviour of the crosswind component of turbu-
lence in the surface layer and new developments  from laboratory modeling of
horizontal dispersion in convective mixing are noted.
     A brief survey is given of the achievements of gradient-transfer  theory
and Lagrangian similarity theory in calculating  vertical  spread from a surface
release.  New tests against previous dispersion  data underline  inadequacies in
the present approaches in very unstable conditions.  Promising  developments
from the laboratory modeling of a  convectively mixed layer and  from the
2nd-order-closure modeling of the  turbulent fluctuation equations are  summarized,
     The assimulation of theory and experience into practical systems  for  the
specification of a  and o  is briefly reconsidered.  For a  a practical
procedure based on wind direction  fluctuation data is reaffirmed.  For a   a
new format which may be envisaged  for future composite curves is  suggested.
Finally, the inherent limitations  of practical systems for estimating  con-
centration levels are reiterated.

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                                  CONTENTS
Abstract	    iii
Figures	    vii
Tables	viii
List of Symbols	ix-x
     1.  Introduction 	      1
     2.  The Shape of the Distribution of Concentration from a  Source .      3
              Implications of the classical  parabolic equation	      3
              The special case of steady homogeneous  turbulence ....      5
              Conformity to Gaussian distribution in  reality and  the
              significance to estimates of concentrations  	      6
              Value of exponent r	      6
              Non-Gaussian intermediate state 	      8
              Non-Gaussian aspects of instantaneous distribution.  ...      8
     3.  Generalized Estimation of Crosswind Spread in Quasi-Ideal
         Boundary Layer Flow	     10
              The Taylor statistical theory 	     11
              Determination of crosswind spread 	     11
              Fffect of the x-T relationship	     11
              Practical adaptation of the Taylor theory at various  ranges
              of T	     12
              T«tL	     12
              Immediate range of T	     13
              Very large T	     13
              Latest developments relevant to the modeling of crosswind
              dispersion	     14
              Laboratory modeling 	     14
              Second-order closure modeling 	     15
     4.  Generalized Examination of Vertical Spread az in  Ouasi-Ideal
         Boundary Layer Flow	     17

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              The gradient-transfer and similarity treatments  of verti-
              cal spread from a surface release	      17
              Deardorff's mixed-layer similarity approach and  laboratory
              modeling	      21
              Second-order closure models	      24
              Early achievements of the 2nd-order closure technique.  .      25
     5.  The Present Position and Prospects in Practical  Systems ...      29
References	   35-37
Appendices
              A.  Similarity-empirical considerations of vertical spread
                  at short range from a surface release	      38
                       Data from project "prairie grass"  	      38
                       Similarity hypotheses on Monin-Obukhov  lines.  .      40
                       Similarity in terms of the intensity and scale
                       of turbulence	      46
              R.  A simple two-layer model for estimating vertical
                  spread beyond the surface-stress layer in neutral
                  flow	      51
                                      v1

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                                   FIGURES

Number                                                                   Page

  1  Vertical spread from a surface release In a neutral boundary layer   27

  2  Envisaged new format of a  curves	   31

A-l  Vertical diffusion similarity functions	   45

B-l  K-profile in a nuetral boundary layer of depth h	   52

B-2  Vertical spread curves for a neutral boundary layer with Surface-
     Rossby-Number similarity properties as in Table B-l	   56

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                                   TABLES

Number                                                                   Page

  1  Forms of Vertical Distribution and Vertical Spread Implied by
     Solutions of the Classical Parabolic Equation of Diffusion. ...     4

  2  Observational Evidence for Existence of Gaussian Shape in Time-
     Mean Distributions	     7

  3  Values of 2uC(X,0)a /Q for a Two-Dimensional  (Infinite Line

     Source) Model with u" Invariant with height and C(X,z)/C(X,0)

     = exp-bzr 	     9

  4  Wind Speed Conditions for Applicability of the Convective-Limit
     Form for a /u*	    16

  5  Gradient-Transfer and Similarity Calculations of Vertical Spread
     from a Surface Release	    19

  6  Comparison of Calculated Vertical Spread from a Surface Release
     with the Smith-Singer Curve for Height of Release 100 M, in
     Neutral Flow	    32

A-l  Adjustment of Cramer's 1957 Estimates of a  from Prairie Grass
     Data	?	ai-42

A-2  Estimates of (l/ku*)(dl/dt) from Adjusted Vertical Spread
     Estimates in Table 1	43-44

A-3  Magnitudes of Boundary Layer Parameters and Dimensionless
     Dispersion Velocity $(Z./L).  Defined in Eq. (A-9) and (A-10)	     47

B-l  Parameters and Results in the Estimation of Vertical  Spread fro.,.
     a Surface Release, Beyond the Surface-Stress  Layer, in Neutral
     Flow	    55
                                      viii

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                               LIST OF SYMBOLS
     The usual  subscript notation is used to indicate,  for example,  axis  of
reference (x,y,z), velocity component involved  (u,v,w).   A zero  subscript is
used to denote  a ground-level  value or an initial  value.   A subscript  g
denotes a geostrophic value.
     f      Coriolis parameter
     c      specific heat of air at constant pressure
     H      vertical heat flux (H   surface value)
     k      von Karman's constant
     K      eddy diffusivity           3      T
                                      if     n
     L      Mcnin-Obukhov length   -- n-  -^—
            source strength, rate of emission  (point  source)  or  rate  of
            emission per unit length (line source)
            Lagrangian correlation coefficient  for  time-lag  £
     Ri     Richardson number
     Ro     Surface Rossby number  V /fz
     t,      Lagrangian time scale
     T      absolute temperature or time of travel
     v,w    velocity components  along axes y,z
     u*     friction velocity  =(T /p) '
                                                         1/3
     w*     free convective velocity scale   (gH z./pc  T)  '
     x,y,z  rectangular coordinates, x along mean wind  y  across  mean  wind and
            z vertical
     z      roughness length
     X      distance of travel  downwind of release  position
     Z      vertical displacement of particle
     z.     mixing depth
     zr     release height
     e      rate of dissipation  of turbulent kinetic  energy per  unit  mass of
            air

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6      wind direction
A      spectral scale represented by equivalent wavelength at which
       product of frequency and spectral  density is a maximum
p      air density
a2     variance
4>      Monin-Obukhov universal function
T      horizontal shearing stress or duration of sampling or release

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                                 SECTION 1
                               INTRODUCTION
     The purpose of this report is to take  stock of the present position in
the technique of representing, for air quality modeling, the properties  of
crosswind and vertical spread from a single point source, as a function  of
distance downwind and of the conditions of flow.  Reviewing of this  nature
has been continuously in process for many years, and several easily  accessible
earlier accounts will be referenced.  In the present account the concern will
be partly with some brief reminders of well-established features and partly
with a summary of recent developments.
     It should be remembered at the outset  that the reliability of the estimates
which are variously made of the familiar properties c  and a  must be judged
in two respects:
     (a)  The accuracy, reproducibility, and representativeness of the
          available full-scale measurements of dispersion, and
     (b)  The validity of the theoretical frameworks within which the
          results of such measurements may  be understood and from which
          those inevitably incomplete results may be generalized.
     As regards (b) we have long been essentially dependent, for practical
applications, on two classical approaches,  the gradient-transfer theory,
requiring appropriate specifications of the eddy diffusivity field,  and  the
statistical theory as initiated by G. I. Taylor, requiring knowledge of  certain
statistical properties of the flow turbulence.  For details of the background
of these approaches, references 1  and 2 may be consulted.  More recently,
useful and promising theories have been developed in the area of similarity
argument and in the whole sophisticated field of the higher-moment turbulent
fluctuation equations and their solution through 2nd-order-closure assumptions
and hypotheses.

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     We shall  be concerned (specifically in  Sections  3  and  4) with  the guidance
provided by all  the foregoing approaches in  the  prescription of a   and a  .
However, the full  description of dispersion  also requires a knowledge of  the
shapes of the  distribution of concentration  of material  crosswind and ver-
tically, and it  seems appropriate to begin (Section  2)  with some discussion
of this aspect.   Finally, in Section 5,  consideration is given to the assimi-
lation of practical experience and theoretical development  into the working
formulae and graphs which are currently  advocated for estimation of the
dilution of air  pollutants.

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                                 SECTION 2
                     THE SHAPE OF THE DISTRIBUTION OF
                       CONCENTRATION FROM A SOURCE
     One of the most widely used mathematical  models of dispersion from a
continuous point source contains the assumption that the crosswind and verti-
cal distributions are of Gaussian form.  Various theoretical  and empirical
features with bearing on this aspect are now summarized briefly.
IMPLICATIONS OF THE CLASSICAL PARABOLIC EQUATION
     For simplicity, and for consistency with the view followed later in this
discussion, attention is first confined to the vertical spread and to a surface
release, though the implications of this particular subsection will  apply
equally well to elevated release and to crosswind spread if the gradient-
transfer assumption is considered to apply in those respects  also.  The appro-
priate equations, in either the one-dimensional time-dependent form  (relevant
to an instantaneous plane source of infinite extent) or the two-dimensional
steady form (relevant to a continuous line source of infinite extent crosswind),
and the vertical distribution characteristics which follow from these equations,
with certain assumptions about Hand K, are summarized in Table I.
     The first four lines of the table, with steady K, are well-known results,
and the fifth and sixth lines, for arbitrarily time-dependent K, are straight-
forward extensions of the steady-state results.  The format of the results  and
the selection of cases are such as to bring out certain important points as
follows:
     (a)  A Gaussian form follows only when r,  (or r?) = 2.  This includes  as
          a special case (m = n = o) the so-called Fickian case of constant  K
          (and constant u").  It is noteworthy, however, that  generally the
          condition m = n (with n-m * 2 as required for the solution to be
          valid) is sufficient.  Near the ground the K profile index n is
          typically in the region of unity, and falls substantially  below

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          unity only in stable conditions or with  increase in  the depth  of
          layer embraced.  As the corresponding wind profile index n  is
          typically in the range 0.1  to 0.5, the larger values occurring only
          with stable conditions and  at low heights, it is evident that  m =  n  is
          likely to occur only in a combination of the latter  conditions.
          Otherwise, solution of the  diffusion equation for a  surface release
          in the atmospheric boundary layer implies a decidely non-Gaussian
          vertical distribution.
     (b)  With K and u steady, when a Gaussian distribution does  follow  from
          the diffusion equation, it  is necessarily associated with the  magni-
          tude of the spread growing  as T2 or X'2.
     (c)  For a homogeneous time-dependent K or a  steady spatially varying K,
          it appears, from lines 5 and 6 of the Table, that a  Gaussian distri-
                                                       _!'     J'
          bution will not generally be associated  with T2 or X2 forms of
          growth.  Note especially that if K, (T) °= Ta (or Xa), with   positive
          and r = 2, it follows that  the growth of the spread  will  behave as
          T(l+a)/2 (Qr jjl+oO/2^  We  sefi then thflt^ accord1ng  to  the  gradient-
          transfer treatment, it is formally possible to have  a combination  of
          non parabolic growth and Gaussian distribution if there are appropriate
          time or space variations in the eddy diffusivity K,  as  might possibly
          occur in practice from the  diurnal cycle and from systematic changes
          in roughness or surface heating.
THE SPECIAL CASE OF STEADY HOMOGENEOUS TURBULENCE
     A well-known result of the G. I. Taylor statistical  theory,  brought out
                           3
in more detail by Batchelor , is that the spread of particles  released
serially from a point grows linearly  with time of travel  initially, then
progressively less rapidly, tending ultimately to  T2.  Batchelor  concluded
that the particle displacements have  a Gaussian probability distribution at
all values of T, though for reasons which must be  different for different
ranges of T.  With such a universal Gaussian behaviour it then follows that  the
diffusion equation does provide a description of the dispersion process  for
all T (or X), , provided K varies appropriately with T (or X), indeed in a manner
which satisfies

                                      5

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                                      p   	      n
                            'i/ _ 1  d o    u   do
                            K - 2  dT or 2   dT

     Obvious similarities exist between this  result and that  discussed  in
the foregoing subsection, but--it cannot be emphasized  too  strongly—these
are to be regarded only in a formal  sense and not in a  meaningful  physical
sense.  In the foregoing subsection  the variations  in K are to  be  envisaged
as arising from variations in the fluid properties.  On the other  hand,  the
result for steady homogeneous turbulence is (logically) to  be regarded  as a
consequence of a dispersive action that is net gradient-transfer in  nature.
The crucial point is that except at  large enough  T  or X the displacements of
the particles are caused by turbulent motions of  a  scale larger than the whole
cross section of the plume of particles.
     It may be noted that several  workers in  dispersion modeling  (e.g..
Fortak ) have drawn attention to the result that  the conventional  Gaussian
plume formula, with arbitrary variation of a with time  or distance of travel,
is a solution of the diffusion equation with  K defined  as above.   Although
there is no objection to using this  result for homogeneous, steady turbulence
merely as a convenient formality, the important point is that the  apparent
K's (associated with a certain nonparabolic growth  of a), implicitly constant
with height but varying systematically with T or  X, cannot  then simply  be used
as genuine gradient-transfer K's in  some other context, e.g., in the treatment
of the vertical transfer of the particles to  an absorbing ground.   In the
latter case, logically, the appropriate K must increase with  height  and
be quasi-constant in time and space.
CONFORMITY TO GAUSSIAN DISTRIBUTION  IN REALITY AND THE SIGNIFICANCE  TO
ESTIMATES OF CONCENTRATION
     A list of sources of observational evidence  for the existence or absence
of Gaussian shape in the distribution of dispersed  material is  given in Table  2,
     Outstanding departures from the Gaussian forir are as follows:
Value of Exponent r
     For vertical spread at short range from a surface release, the  exponent  r
in the exponential form is near 1.5 irrespective  of thermal stratification.

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              TABLE 2.  OBSERVATIONAL EVIDENCE FOR EXISTENCE OF
                 GAUSSIAN SHAPE IN TIME-MEAN DISTRIBUTIONS


1
2
Nature of Dispersion
Crosswind spread from a continuous point
source
Vertical spread from an elevated continuous
Gaussian?
Yes
Yes
Reference
(Dpp 173
& 2?7
(5)
       source of passive particles (before ground
       becomes effective)

3      Vertical spread in first kilometer downwind
       of a surface release

4      Vertical spread from near-surface release
       in laboratory convectively-mixed layer
       Vertical distribution of power station
       plume
   No
(r = 1.5)

 Only at
very early
  stage

 Only in
lower half
(6)


(7)



(8)

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The significance of the precise value of r to  the magnitude  of the  ground-
level  concentration for specified a , wind speed, and source strength  is
shown in Table 3; Clearly the departure from Gaussian becomes of practical
importance only when r is less than 1.5 or much  larger than  2.
Non-Gaussian Intermediate Stage
     A certain intermediate stage in the mixing  in a  laboratory correctively
mixed layer (even before the distribution is obviously modified by  the
presence of the upper boundary to mixing) exhibits non-Gaussian form.
Deardorff and Willis'  study shows an early-stace Gaussian vertical  distribu-
tion fol.lowed by the appearance of an elevated maximum, which progressively
rises through the mixed layer before the final condition of  uniformity with
height is achieved.  This means that the concentration at ground level
transiently "undershoots" the value which would  be calculated (given a )  on the
existence and degree of this effect in the real  atmospheric  mixed layer has yet
to be provided.
Non-Gaussian Aspects of Instantaneous Distribution
               g
     Hamilton's  lidar observations of the time-mean  vertical distribution
of a power-station plume apparently ir-ay be fitted to  a Gaussian shape  over
the lower half of the distribution, which, of course, is the significant  half
as regards the development of the ground-level concentration to is  maximum
value.  It is, however, highly questionable whether such an  approximation
obtains in the instantaneous distribution, the property that will determind
short-term concentrations in the path of the elevated plume.  The fact that
the growth of a rising hot plume is initially dominated by an induced  internal
circulation leads one to expect a tendency to a  flat  rather  than a  peaked
distribution in the cross section of the plume,  but evidence for this  is  net
immediately available.

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TABLE 3.  VALUES OF 2uC(X,0)a /Q FOR_A TWO-DIMENSIONAL
  (INFINITE LINE SOURCE) MODEt WITH ii INVARIANT WITH
	HEIGHT AND C(X.z)/C(X,0) = exp-bzr	

          r           1.0     1.5     2.0     2.5

    2HC(X,0)az/Q      1.37    0.96    0.8     0.73


    N.B.  These figures are for unbounded vertical
    diffusion; for a source at ground-level  they
    should be doubled.  They may be taken as equiva-
    lent to   f   C(x,y,o)dy from a point source.*


    *See p. 350, Ref. 1 for further details

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                                  SECTION 3
                 GENERALIZED ESTIMATION OF CROSSWIND  SPREAD
                     IN QUASI-IDEAL BOUNDARY LAYER  FLOW
     In the atmospheric boundary  layer  both the  magnitude and scale of the
crosswird component (v) of turbulence are found  to  change only slowly with
height (in contrast to the pronounced increase with height of the scale of the
vertical  component).  Accordingly, when also there  are no sharp changes with
time or position, we may treat the flow as quasi-homogeneous as regards the
lateral dispersive action of the  turbulence.
     For the lateral spread of a  continuous point source  (and indeed the verti-
cal  spread when the plume is elevated), the physical  irrelevance of gradient-
transfer action has been discussed on many occasions, and the purely formal
quality of the representation in  terms  of the parabolic diffusion equation
has  been noted in the previous section.  The Lagrangian form of Monin-Obukhov
similarity argument, although originally including  lateral as well as vertical
spread, has been seriously questioned for the former  aspect of dispersion
(p.  119 of Ref. 1).  In an Eulerian sense it has become evident that the v-
component is not a simple function of z/L (where L  is the Monin-Obukhov
length), and it would be most surprising if the  Lagrangian v-properties dif-
fered from the Eulerian in this respect.  A possible  rationalization cf the
behaviour of the v-component in the surface layer in  convective conditions
                                             g
has  recently been proposed by Panofsky  et al. .  Their analysis of several
sets of data on a /u* over uniform surfaces with friction velocity u* demon-
strates a universal dependence, not on  z/L, but  on  Z../L, where z.. is the
effective convective mixing depth.  We  will be noting the special significance
of their result to lateral spread later in this  section.  More generally,  i.e.
including neutral and stable flows, there are complexities in ^-properties
to be expected from synoptic-scale changes in the flow and from mesoscale
topographical influences, the latter especially  in  stable conditions and even
in unstable conditions in light winds.

                                     10

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THE TAYLOR STATISTICAL THEORY
     Of the three working theories hitherto available to us,  the practical
adaptation of the famous Taylor theory of diffusion by continuous movements  is
the one most clearly suited to the estimation of a  for a continuous  point
source.  The developments to date have already been extensively reviewed
(p. 123 et seq, p. 185 et seq, Ref. 1, and p. 6 et. seq of Ref.  2), and only
the main points need to be emphasized here.
Determination of Crosswind Spread
     In accordance with the assumption of quasi-homogeneous  conditicns,
the spread c  is related to o  and time of travel  downwind of the source
in the forms
                               tL = f(T/V                              (i)
                  with f(T/tL) + T/tL as T + 0                           (2)

                    or ay(T) + ovT as T -> 0                              (3)

                   and f(T/tL) + (2T/tL)J* as T + »                       (4)

                    or ay(T) + av(2TtL)% as T -> »                        (5)


tL being the Lagrangian integral  time scale.  This  means  that  in  principle,
neglecting wind direction turning with height (to which reference will  be
made later), crosswind spread is  determined by a  (which  is measurable, and
to some extent describable in boundary-layer climatological terms), and by
tL (which is not easily measurable and for which the  theoretical  and observa-
tional  background is only partially helpful).
Effect  of the T-T Relationship
     Rigorously, the adaptation of the Taylor treatment requires  that a
have the limiting value associated with effectively infinite sampling time
(of the turbulence) and corresponding effectively infinite release or
sampling time of the material. Or a  qualitative argument, however, (p. 136,
Ref. 1) the result may be expected to be valid for  sampling (or release)

                                      11

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time T and time of travel  T when T < T.   As  T increases  beyond  T, the  argument
is that the different properties of cluster  growth  (as distinct from time-mean
plume growth) become increasingly relevant and ultimately  dominant.
Inadequacy of the X-T Relationship
     In strictly homogeneous conditions,  including  uniformity of wind  speed,
the foregoing a , T relations may be converted to a ,  X  form by substituting
X = lit.  However, for real  boundary layer flow,  even though an  assumption of
quasi-homogeneity may be acceptable as  regards the  properties of the v-component,
the variation of mean wind speed with height makes  the simple X, T relation
inadequate.  A practical  solution is to  replace  u" by an  equivalent advecting
speed, u , which increases with T (as vertical spread  increases), and  with
certain assumptions a rough estimate of u is derivable  in terms of the wind
profile  .
PRACTICAL ADAPTATION OF THE TAYLOR THEORY AT VARIOUS RANGES OF  T
     In principle, and qualifications including  those  noted in  Determination
cf Crosswind Spread and Effect of the -r-TRelationship above, the method
provides for estimates of c  in a way that takes into  account the properties
cf turbulence for any surface roughness  and  any  thermal  stratification.  The
practical utility and limitations are most conveniently  considered in  well-
defined ranges of T/t. .
T«tL.

     It has been demonstrated that in this range a  approaches  the simple
limit in Eq. 3, i.e.
                     oy(T) - V                          .              (6)
or approximately
                     ay(X) = •-  X - a0X                                (6a)

noting that c?, which is the standard deviation  of  wind  direction fluctuation,
             9
should strictly be taken as a function of vertical  spread, in accordance with
the definition of u .  Thus at short enough  time or distance the only  require-
ment is an estimate of a_.  Abundant evidence supports rough agreement with
                        o
the very simple form in Eq. (6a), but in more precise  terms the crucial  point
                                      12

-------
is the behaviour of f(T/t.) in Eq. (1) at small  T/t, ;  this will  be apparent
in the more general considerations which follow.
Intermediate Range of T
     For this range the form of f(T/t, ) needs to be specified, basically from
the form of the Lagrangian auto-correlation function R(£)» and earlier
considerations (p. 130 of REf. 1) had led to the impression that f(T/t, ) was
insensitive to such variations of the shape of R(£) as were originally con-
sidered likely.  A recent analysis of dispersion data  by Draxler   has reopened
this question, and it now has to be considered that the initial  reduction of
                                                                 210
R(£) with time-lag £ may be considerably more rapid than exp-5/t.  '  , which
was the sharpest fall hitherto considered.  It is noteworthy that a form which
has a sharper fall and fits selected dispersion  data is provided by
     (a)  The Hay-Pasquill hypothesis of a simple scale relation between
          Lagrangian (moving particle and Eulerian fixed point)  turbulent
          fluctuations (see p. 135 of Ref. 1), and
     (b)  An empirical form of the shape of the  (Eulerian) v-spectrum (see
          p. 70 of Ref. 1).
     Full  application on the foregoing lines, in terms of a specification
of the actual  v-spectrum,  is considered to be the most satisfactory approach,
but the requirement for a  relatively sophisticated measurement and analysis
of the time-lapse fluctuation of v or 6 is obviously a practical  difficulty.
One reasonable practical  solution would appear to be the use of an empirical
generalizaticn cf good quality a  data accompanied by  a  data, and a collection
                                y            no         y
of such data has  been assembled by the writer  .  According to this data,
ay/XaQ follows a  simple function of X, largely irrespective of roughness  and
thermal stratification, with departures (for individual  samples  of data)
which are within  a factor  of 1.5 at short range  (< 1  km) and 2.0 at longer
range (10 km).  With reference to the remark at  the end  of the paragraph  or
T  t. , note that  according to the various U.S. tests a /aQX is on average
    L.                                                 y  o
detectably below  unity even at a distance as short as  100 m.
Very Large T
     If the flow  were ideally homogeneous, the specification of a  at very
large T (or corresponding  X) would require only  an estimate of t.'1- in
                                     13

-------
addition to aQ.  Unfortunately, another aspect  of departure  from  homogeneity
then becomes effective—namely,-the turning of  mean  wind  direction with height--
as a result of which there is, through the process of vertical  spreading, a
contribution to the crosswind spread additional  to that directly  associated
with a .  Certain more or less elaborate theoretical  treatments of this
hear effect are already available (see pp. 156  and 229 of Ref.  1).  With
these and some empirical guidance, first impressions  are  that the additional
contribution becomes important only for distances of travel  exceeding  5-10 km.
LATEST DEVELOPMENTS RELEVANT TO THE MODELING OF CROSSWIND DISPERSION
Laboratory Modeling
     Discussion of the laboratory model  of Deardorff and  Willis for dispersion
in a convectively mixed planetary boundary layer is  considered  in more detail in
relation to vertical dispersion in the next section.   In  one of the latest reports
            13
of this work   , the implication of the model in respect to horizontal  dispersion
is also considered.  From an ensemble of seven  experiments with the water tank
having side-dimension/mixing depth z. ratio 4.0, and with the convective
                                _i  '
scaling velocity w* near 1 m sec  , Willis and  Deardorff  derive statistics of
lateral displacement of nonbuoyant particles released on  a line near the bottom
of the tank.  As in the work on vertical dispersion, these are  expressed in
similarity terms, a /z  versus t* = w*t/z.), identification  with  distance
of travel in a wind being achieved through the  relation X =  Ut  with U  constant.
They compare their laboratory results with field data obtained  in Idaho for
distances of travel up to 3200 m from a continuous point  source,  making
plausible estimates of the likely magnitudes of w* and z.  during  the field
tests.  A remarkable degree of agreement—within about 10% in the ensemble
averages—is found.  In noting this very encouraging initial success in
verification of the full-scale applicability of laboratory modeling in
convective conditions, two qualifications deserve special  mention.
     The a  t curves found in the laboratory tank contain a  distinct inflection,
tion, with da /dt temporarily reduced and then  restored.   In full scale
             y                                                           ] 3
distance terms this appears in the 3- to 4-km range.   Willis and  Deardorff
ascribe the feature to the delayed appearance of horizontal  spread from thermal
outflows at the top of the mixed layer.  It is  noteworthy that  this effect
has not yet been detected in full-scale measurements.
                                      14

-------
     The second point concerns the stipulation of the full-scale conditions,
especially of wind speed, for which the laboratory (windless)  results  may  be
reliably adopted.  In this connection Willis  and Deardorff prescribe an
upper limit cf 12 m sec" .  For all lower wind speeds the  implication  is
that the horizontal dispersive action is essentially controlled  by  buoyancy
forces and not by the mean shear, and in this respect some further  guidance
is now available from the recent generalizations about the behaviour of
the magnitude of the surface layer v-component in convective conditions.
                 Q
Panofsky et al.'s  form for av, in terms of u^.L and z^, m$y be  used to
prescribe the combinations of wind speed and  heat flux which,  for given z
and z., result in a a  which is dominantly (say to the extent  of 90%)  a
consequence of the heat flux.  Details are set out in Table 4  for z 20 cm (a
moderate roughness intermediate between smooth plains and  urban  complexes)
and for z. = 1500 m (a mixing depth typical of afternoon conditions).  Note
         1                                                    _i
that in such circumstances a surface wind speed of even 4  m sec   requires a
vertical heat flux near 500 w m~  to meet the foregoing criterion of dominance
of the buoyancy contribution to a .  This is  a very strong sensible heat
flux, unlikely to occur except over dry terrain and with the highest sun in
low latitudes.  From this standpoint it seems that the 12  m sec" limit pre-
                               17
scribed by Willis and Deardorff "" may require unrealistically  high  heat fluxes,
or, alternatively, a very much smoother surface or much larger z..
SECOND-ORDER CLOSURE MODELING
     A growing effort is being devoted to the use of 2nd-moment  equations,
in which the gradient-transfer assumption is  avoided, at least in the  1st-
moment equations such as those considered in  Table 1.  The  progress of the
technique is more comprehensive in relation to vertical transfer as will
be discussed in Section 4.  The writer is unaware of any crucial  examinations
of the success of the technique in relation to crosswind spread  per se.
                                     15

-------
TABLE 4.  WIND SPEED CONDITIONS  FOR APPLICABILITY  OF
          THE CONVECTIVE-LIMIT FORM FOR  a/u
Taking   ay/u*  =  (12 - z./2L)1/3            Ref.  9

                +  (-z./2L)1/3  for large (-z./L)
it follows that
                       >_  0.9 when -z^L  >_  65
       Associated values of surface heat flux

HQ and if(10m) for -z^L = 65,  zi = 1500m, ZQ = 0.2m


iT(lOm) m sec"1        2     2.5      3    3.5      4

HQ  wrrf2             67     130    220    350    520
                        16

-------
                                  SECTION 4
                GENERALIZED EXAMINATION OF VERTICAL SPREAD  a
                     IN QUASI-IDEAL BOUNDARY LAYER FLOW     Z

THE GRADIENT-TRANSFER AND SIMILARITY TREATMENTS OF VERTICAL SPREAD FROM A
SURFACE RELEASE
     The fundamental acceptability of the gradient-transfer relation  for
turbulent transfer is often seriously questioned (e.g., see Corrsins's
discussion,  ).  Empirically, however, the method is undoubtedly successful
in certain applications, a success which Corrsin refers to  as "largely
fortuitous and certainly surprising."
    It is now a familiar notion that time-mean spread from  a continuous
point source is initially dominated by turbulent motions of scale that  are
large compared to the cross section of the plume of particles,  when the
concern is with lateral spread or even with vertical spread when the  plume
is clear of the ground.  This type of scale relation, which in  an obvious
physical sense is the very opposite of that implied in a gradient-transfer
process, does not exist, however, in the vertical spread action when  passive
particles originate at the boundary.  The point is simply that  at any stage
in the vertical growth of the plume the effective turbulent motions are
constrained in scale by the presence of the underlying boundary, the  effective
scale being dependent on height.  This presumably is the essential  reason for
some success in the K-treatment of the ground-level infinite crosswind  line
source.
     Also noteworthy at this point is the formal  consistency between  the K-
treatment, using the familiar momentum-transfer analogy, and the Lagrangian
similarity treatment, for vertical spread as a function of  time in  the  surface-
stress region of the neutral boundary layer (p. 117 of Ref. 1).  Associated
with this is a simple relation between the rate of vertical spread  and  the
eddy diffusivity, in the form

                                     17

-------
                              dZ/dt  =  K(Z)/Z                           (7)
where Z is the mean displacement of particles at a given time after release
at the surface.  The result is exact for the neutral  surface-stress layer
(p. 118 of Ref. 1) and has been found to be a good approximation, in other
                                              215
thermal stratifications and at greater heights *  .
     In Table 5 a list is given of applications of the mutually consistent
gradient-transfer and similarity approaches that have led to useful  explicit
formulations of the growth of a  with time or distance.  Unfortunately,
observational data for the critical testing of the theoretical  results are  still
largely confined to short range, notably the early Porton-Cardington data
at 100 and 229 m (neutral conditions) and the Prairie Grass  data at distances
up to 800 m (for a wide range of stratification).   Note, however, that in the
latter observations only those at 100 m include measurement  of the vertical
distribution of condentration.  Those at other distances are confined to
ground level and provide only indirect estimates of a .
     A  reexamination of the Prairie Grass data in relation  to some of the
foregoing methods has recently been attempted by the  writer, using the
indirect estimates of a. derived from the concentration measurements at
                                             16
ground level (basically those given by Cramer  , but  with an adjustment
allowing for the variation of wind speed with height  neglected in Cramer's
analysis).  Full details are assembled in Appendix A, and a  summary of the
principal results follows:
     (a)  The magnitudes of dZ/dt implied by the Cramer-type analysis of  the
          Prairie Grass data do not exactly support a similarity relation with
          —                                                   22
          Z and the Monin-Obukhov L, as conjectured by Gifford  , though
          systematic discrepancies from such a relation are  not large.
     (b)  Predicted curves which follow from the assumption  that K = ku*z/<|>H
          with the different estimates available for  <(>M, embrace the range
          of the data on dZ/dt in unstable conditions.  In stable conditions
          the one predicted curve presented tends  to  be a slight overestimate.
     (c)  A predicted curve based on a similarity hypothesis consistent
          with K = aa X  , and evaluated using latest  estimate of the
                     w m
                                      18

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-------
          properties aw and Xm>  provides  a rough  fit  in  unstable  conditions
          though with a curve shape which in  detail differs  from  that  based
          on K = ku*z/£u.   For stable conditions  the  K = aa  X   prediction
                       ri                                  w m
          is a gross overestimate.   In the latter connection it may  be  sig-
          nificant that the present evaluation  uses an empirical  generali-
                23
          zation   in which a /u* increases with  increasing  z/L.
                             W          ' "
     (d)  At large X/-L the data show a tendency  to a growth more rapid than
               _    1/2
          the (Z/-L)    form predicted on simple  similarity  grounds, assuming
          a regime of free convection with the  determining parameters  height
          and surface heat flux.
    ' Clearly, several interesting features still  need more satisfactory
interpretation, but in the meantime the foregoing results provide at
least a useful empirical  step in that, for example, the  observed  stability
dependence of the function (Z/L) = (l/ku*)(dZ/dt) may now plausibly
be applied to a surface roughness different from  that of the Prairie
Grass site.  In principle  this $ may be converted to  the function dZ/dX
by recombining it with the functional form for  dX/dt  as  determined by
the wind profile (see note (c) of Table A-2,  Appendix A). Integration  may
then be carried out, if necessary numerically,  to give I as  a function  of
distance X" for any specified z  and L.
     For the consideration of the growth of spread at much longer range from
the source (several kilometres and beyond), no  definitive direct  measurements
of o  are yet available.  In any case, the knowledge  of  the  flow  characteris-
tics in the upper part of the boundary layer, required for proper interpreta-
tion and generalization of such dispersion measurements, has only recently
begun to accumulate.  As noted in Table 5 (Methods 5  and 6)  some  of  these
new data have recently been applied in constructing new  estimates of c^.
     In nonconvective conditions, for which the gradient-transfer assumption
seems least open to objection, the characteristics of the boundary layer
(including its depth) should be seen within the framework of surface Rossby
Number similarity.  This aspect, which has been brought  out  specifically in
2nd-order closure treatments  , was not incorporated  in  Method  5  of  Table  5.
An examination of the implications of simplified assumptions about the neutral

                                      20

-------
K-profile, within the framework of Surface Rossby Number similarity (Method  7
of Table 5) is reported in Appendix B.   With the existing uncertainties  about
the K-profile in the upper nine-tenths  of the boundary layer,  this  type  of
analysis, even if carried out with complete mathematical  rigor,  can at present
provide no more than an interim solution.  However,  in one example  which will
be noted later in this section, the results are encouraging in being remark-
ably consistent with a completely independent 2nd-order closure  calculation.
Furthermore, they do bring out the schematic way in  which any  extension  of the
a  curve (beyond the well-established short-range Lagrangian-similarity  form)
must reflect the important control exerted on boundary-layer depth  by geo-
strophic wind and surface roughness.
     In principle the procedure of Appendix B may also be considered for the
stable boundary layer.  However, at first sight the  shape of the K-profile
                                                                 25
(as suggested, for example, by the analysis of Businger and Arya,   ) seems
unlikely to be suitably approximated by the simple two-layer form adopted in
Appendix B.  Instead, the numerically more demanding finite-difference
solution of the diffusion equation would probably be desirable.
DEARDORFF'S MIXED-LAYER SIMILARITY APPROACH AND LABORATORY MODELING
     Deardorff's approach  is that the  structure and transfer  properties in a
capped convectively mixed layer are determined completely £y the surface heat
flux H  and the depth of mixing z..  The latter parameter is the obvious
characteristic length scale, and on dimensional  grounds Deardorff defines a
characteristic velocity scale
                                          1/3
                        w* =  (gH0z./pc T)                               (8)
From these considerations Deardorff argues  that the  properties  of dispersion
of nc
form
of non buoyant particles,  say,  the a  growth with  time,  should  obey a universal
where t* is a dimensionless time w*t/z..   The  form of the  function  f  has  been
estimated from both numerical  modeling and from  the laboratory measurements in
                                     21

-------
 a  heated water  tank referred  to  briefly  in Section 2.
                                 1 ^
     Thejnosjt recent  publication  J of the tank data provides a vertical spread
           2
 curve,  (Z1)   against t* where Z1 is the displacement from heights of release
 z> for the following conditions:
                                 zr   = 0.067 z.
                                 z.   =  28.7 cm
                      tank width/z.
                                 W*       -i       -1
                                  *   -   1 cm sec


and with the following properties

                                       /)
    0  Slight acceleration up to   (ZT /z. - 0.4, t* - 0.75,

                                       O
    0  Bending over to a maximum   (Z1)   near 0.6, t* - 1.5,


    0  Slow descent to the asymptotic value of 0.5 at t^ near 3.
For the range 0.2 <_ t* <_ 0.8 Willis and Deardorff13 give (Z1)2 /z.. * tj'15

     In the equivalent Gaussian plume form with idealized reflection of the
distribution at the lower boundary, the familiar a  is equal to
	h                                            2
(Z1)2   only at small and large values of crz/zr> and Willis and Deardorff
include a graph of the general relation between these two specifications of
the vertical spread.  Usi'ng this graph their vertical spread has been converted
to a  and found to fit a linear form


                        az/z1 = 0.61 t*                                (10)

with a discrepancy less than 3% over the range 0.2 < t* < 0.8 or 0.1 < az/z^ < 0.5,
Adopting an effective advecting speed ye this may be written in distance
(X) terms as

                    oz/z. = 0.61(w*/ue)(X/z.)                          (11)
                                      22

-------
     Reference has already been made to a striking feature in  Willis  and
Deardorff's13 dispersion data, namely, the appearance of a non-gaussian
distribution with a progressively elevated maximum.   It is interesting to
note, however, that this departure from Gaussian shape of vertical  profile
does not appear at t* values below 0.5 or GZ/Z^  < 0.3);  As an essentially
uniform vertical distribution is achieved at t*  = 3, it follows that  the
'undershoot' in surface concentration (compared  with that for  a Gaussian
shape and idealized reflection from the upper boundary) is within  the range
0.5 < t* < 3.  Also, it appears from their Figure 10 that the  surface concen-
tration at t* = 1.56 is roughly one-half the magnitude appropriate to a
uniform vertical distribution.
     One important feature which remains to be settled is the  sensitivity of
                                                                              13
the vertical spread properties to the height of release.  Willis and  Deardorff
are careful to emphasize that their result applies to a specific value of z^.
Naturally, one would expect the distribution to  be insensitive to  zr  when
a /z  is sufficiently large, and they estimate this  condition  to be satisfied
for t*<00.5.  On this basis we may expect the Gaussian-type vertical spread,
ifor all zr/z.  (0.067).
               az/z. = = 0.61 t* = 0.61(w*/ue)(X/z.), 0.5 < t* < 0.8      (12)
For t* < 0.5 seme dependence on z z. is to be suspected but has yet to be
specified.

     Another  important  feature to be  kept in mind (as in the brief discussion
'relating to crosswind spread) is the  condition under which the laboratory
results may be  considered directly applicable to an atmospheric mixed layer
                                                                         1 O
with wind, with  full-scale magnitudes of z. and w*.  Willis and Deardorff
plausibly take  the view that the upper limit of wind speed for such direct
scaling should  be associated with a sufficiently large magnitude of z.-L and
for this they adopt 10.  In ether words, the stimulation is that when the
negative Mcnin-Obukhov  length is less than one-tenth of the mixing depth,  the
mixed layer properties  are controlled by the similarity laws we have  just
                                        13
discussed.  On  this basis, they estimate   an upper-limit wind speed  of  12  m
sec" , but this  does need qualification in respect to roughness and heat
flux.  Thus with z. = 1000 m, hence L < 100 m, the criterion is met at
                                      23

-------
U(10)m = 12 m sec  , over a relatively smooth surface (say z  = 3 cm)  only
                  -2
when H  > 550 mw m  , an unusually large heat flux.   The wind  condition  must,
of course, be even more restrictive over the rough surfaces more likely  to  be
of interest in urban pollution.  If for this case we take z  = 1  m,  and  take
                       -2
a heat flux of 300 mw m   as more typical  of the range of conditions of
interest, even allowing for artificial heating, the  wind speed limit, is
3.7 m sec~ !  In general, of course, the limit depends on the  roughness  and
intensity of surface heating, but the foregoing example leaves no doubt  that
the 12 m sec"  value limit constitutes an overstatement of the applicability
of the laboratory results.
SECOND-ORDER CLOSURE MODELS
    In the gradient-transfer models which have been  considered so far, the
continuity equation relating rate of change of concentration to turbulent
flux divergence is put into the "mean quantity forms appearing in Table  1
by substituting
                            Flux = K x gradient.
Second moments which represent this flux (e.g.,  w'C1  where w1  and  C1  have the
usual meaning—turbulent fluctuations from the mean  values)  can, however be
expressed in full, without the gradient-transfer assumption,  for the  momentum,
heat, and material content properties.   Solution of  these equations requires
"closure," by making certain assumptions for simplifying  (modeling) the more
complex terms, including 3rd moments.  The idea  is that such  assumptions,
which may or may not be of the gradient-transfer type, should  not  introduce
errors as large as might arise from making the gradient-transfer assumption
in the simple equations for dC/dt, etc.
    Considerable literature has accumulated on the evolution  of this  approach,
application of which entails a large effort in numerical  solution.  The
necessity for such a development, as well  as its potential,  have been
                                        pc
discussed in a general  article by Lumley  .  The main areas  of failure which
must be expected in the simple gradient-transfer model and  for which  we may
expect the 2nd-order-closure system to  provide more  correct  treatment are
as follows:
                                     24

-------
     (a)  Violation of scale-relation requirements,  in a more subtle fashion
          than that already noted as regards  relative scales  of turbulence
          and plume, for example, as a consequence of time-dependent changes
          in the turbulence characteristics.
     (b)  The special action of buoyancy-driven vertical mixing.   This  point
          is taken up in detail in Lumley's  article.   One of  the  distortions
          which this imposes on the vertical  distribution expected from
                                                                             1 o
          gradient-transfer condition has  emerged in  the Willis and Deardorff
          laboratory data discussed in the foregoing  subsection,  namely,  the
          appearance of a markedly non-Gaussian distribution  (obviously asso-
          ciated with a counter-gradient transfer) after the  vertical spread-
          ing has progressed to a certain  state.   However, on this last specific
          point note that the "certain stage" corresponds to  a  substantial
          magnitude of a /z.., about 0.3!
     (c)  The vertical  spread from an elevated source as distinct  from  a
          surface release.  This is the vertical  analog of the  crosswind
          dispersion problem, though with  the additional complication of  a
          variation (in the vertical) of the  scale of turbulence.   This means
          that neither the statistical  theory nor the gradient-transfer theory
          is applicable for vertical spread  from  an elevated  source,  though
          for a surface-release the second theory has been provided with  some
          empirical verification and will  be  given some further support.
EARLY ACHIEVEMENTS OF THE 2ND-ORDER CLOSURE  TECHNIQUE
     Some specific achievements in the context of predicting  dispersion from
sources have already been reported in the  literature.  The first  and  most
                                                   24 27 28
extensive application is that by Lewellen  and Teske   '  '  using  the
                                                   29
2nd-order closure assumptions advocated by Donaldson   .  These  latter assump-
tions provide expression of unknown terms  in  relation to characteristic
velocity and length scales and in some respects seem  tantamount to a  gradient-
transfer assumption, but, of course, then  only at the 2nd-order.   A brief
summary of the achievements of the Lewellen-Teske work especially  relevant to
the present discussion  follows:
                                     25

-------
     (a)   For a  ground  release  the  vertical  spread  growth with distance in a
          neutral  atmosphere  is included  in  Figure  1  in comparison with
          curves which  follow from  methods 5 and 7  of Table 5.  There is
          a very reasonable degree  of agreement which adds support to the
          validity of the  simple gradient-transfer  method, for distances of
          travel (> 1 km)  for which no observational  test has so far been
          developed.
                                         27
     (b)   In a free-convection  mixed layer   the vertical distributions
          exhibit  a remarkable  similarity to those  observed in the laboratory
                                 13
          by Willis and Deardorff  .  The progressive elevation of the level of
          the concentration maximum is well  reproduced, but the "undershooting"
          of the surface concentration is not  so obvious as in the laboratory
          data.
     (c)   Although the  expected reduction in a with  stability is reproduced,
          the particular conditions adopted  do not  exhibit any significant
          change from the  spread in neutral  flow at distances in the region
          of 0.1 km,  and the  result cannot yet be confirmed in terms of the
          Prairie  Grass data, which do show  a  substantial reduction of the
          vertical spread  at  0.1 km downwind.
     (d)   The potential of the  approach in the treatment of the elevated source
          is displayed  in  a limited way.  Interestingly, for a neutral atmos-
          phere  the 2nd-order closure calculations  show that vertical spread
          is smaller from  a source  elevated  at some hundreds of metres than
          from a surface release, by a factor  near  two at the range correspond-
          ing to a  - z /2.   The reduction is  (not  surprisingly) associated
          with a fall in a with height.
                                                          30
     Another recent application is  that of Zeman and  Lumley    (using a closure
scheme differing from that of Donaldson)  for the case of the surface input of
pollution into a mixing layer growing as  a result of  surface heating.  From
their calculations they derive  effective  eddy  diffusivities which have a
vertical  profile broadly resembling those derived empirically by Crane and
Panofsky   from observations  of a morning buildup of  carbon monoxide pol-
lution in Los Angeles.   In these particular  calculations, although the

                                     26

-------
loco
 100  .   _
                                      ^H;~-:;r-"'!3v cl' PV-T"? '.1*'"
     r.i
1
ice
            Figure 1.  Vertical spread from a surface release in a
                       neutral boundary layer-
                                         21

-------
effective values of K became large in  the middle  of  the mixed layer, they do
not become effectively infinite (as implied  by  Crane and  Panofsky's analysis)
                                             32
or negative as found in Deardorff and  Willis'   laboratory study of dispersion
from an instanteous release.
                                     28

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                                 SECTION 5
           THE PRESENT POSITION AND PROSPECTS IN PRACTICAL SYSTEMS
     For the practical estimation of pollutant concentration arising from a
single continuous point source, two systems in particular have been in popu-
lar use for many years—the Pasquill-Gifford (PG) curves incorporated in the
               33
Turner Workbook  , and the Smith-Singer (SS) curves incorporated in the
           34
publication   by the American Society of Mechanical Engineers.
     The PG curves were based on the understanding and experience accumulated
by the late 1950's on dispersion from surface releases, but they have been
adopted as practical approximations for elevated releases also.  Their most
popular feature is the presentation of the a ,a , estimates in terms of
stability categories prescribed in terms of routine meteorological data.  The
method has been reviev/ed in the general context of dispersion-estimate
                  3K
systems by Gifford " and in the specific context of the conventional Gaussian-
plume model by Weber  .  The need for improvement and updating has been under
consideration for some time, and this was the motivation for Weber's review
                                          12
and for the companion report by the writer   on specific requirements for
modification of the parameters and procedure in the Turner Workbook.
     The Smith-Singer curves are based on observations of ground-level
concentration from an elevated (z  =100 m) release of passive material  at
the Brookhaven National Laboratory.  Estimates of c  and a  are given in
groups designated by the width of the wind direction trace and also in
formulae in terms of a. and 0^, the standard deviations of the direction and
inclination of the wind.
     It is evident from the progress discussed in the foregoing sections that
the basis for revision of the practical systems is still far from complete.
However, certain obvious evidence points to desirable changes in the PG
curves.
                                     29

-------
                                                    12
      One  interim  revision  has already  been suggested   for the estimation of
 a  .   The  main  points  of this are  firstly the reminder of the applicability of
 the  Workbook a parameter  to a  sampling (or release) time of 3 minutes;
 secondly, the  reaffirmation of  the value of wind direction fluctuation data; and
 thirdly,  a plausible  generalization  for variation with distance.  Recent pro-
 gress in  generalizing about the behaviour of a   (or the corresponding wind
 direction fluctuation OQ)  in the  atmospheric boundary layer is directly rele-
                        6
 vant to prospects  of  a climatological  basis for o  , but certain features of
 wind direction variation are not  readily included in such a climatology
 (notably  synoptic  and topographically  induced variations).
      As regards o,, certain details  cannot immediately be settled, but the
 essentials of  a new emerging pattern are already clear enough to suggest
 a  new format along lines indicated in  Figure 2.  Explanatory notes are
 included  with  the  diagram.  At  this  stage the determining "flow parameters"
 are  all in their  basic form: z  ,  L,  w*, z..  For the future, not only is
 there the task of  confirming and  completing the detail of the a ,X curves
 branching off  the  basic neutral form,  but also a parallel requirement
 for  updating the  representation of the second and third of those parameters
 in more convenient meteorological terms.
      Note that the sections of  curve given for unstable conditions are in
 fact based on  elevated source  (laboratory) data, using the principle that
 the  distinction between the concentration distributions from surface and
 elevated  releases  must progressively diminish to a negligible amount as
                                       32
 a  /z  increases.   Deardorff and Willis  suggest that the approximation
"is adequate at a  /z   =5,  and this means that the curves in rigure 2 are
 appropriate -"or -a1,! 7. /z.  less  than  about 0.07.  Not only is confirmation o*
 this estimate  needed, but  also  the effect of z  at shorter distances and in
 other stabilities  has yet  to be convincingly evaluated.  One immediate
 assurance that the use of  surface-release predictions is not severely mis-
 leading for moderate  elevations of source in neutral conditions is contained
 in Table  6. This  compares the  similarity prediction for ZQ = 1 m with the
 Smith-Singer estimates for a release at 100 m, at downwind distances of
 0.1-10.   Note  also that for the unstable conditions Willis and Deardorff
 have demonstrated  good agreement  between their tank values of a  and the

                                       30

-------
                                                                                                                               o
                                                                                                                               o
                                                                                                                              o
                                                                                                                              H
                                                                                                                                          00
                                                                                                                                          
-------
          TABLE 6.   COMPARISON OF CALCULATED  VERTICAL  SPREAD  FROM
          A SURFACE RELEASE WITH  THE  SMITH-SINGER  CURVE  FOR HEIGHT
          OF RELEASE 100 M. IN NEUTRAL  FLOW

Distance downwind (km) 0.1
a (Smith -Singer) m 8
a (calculation by method 7 of 18
Table 5, with z 1 m
1 10
50 280
79 302*

*  At this distance the calculated az increases  slowly  with  the  geostrophic
   wind speed V , and the value given is  for V   =10  m/sec.
                                    32

-------
Smith-Singer estimates, when the data  are  scaled  in  terms  of  z.  and w*.
     Even when the idealized relations for a  are settled, the  calculation of
concentration distribution will  always be  subject to a whole  chain of
uncertainties:
     (a)  Source strength and position,
     (b)  Departure from the idealized relations  between a ,a  and the  basic
          flow parameters, and
     (c)  Uncertainties in the basic flow  parameter  values implied  by  routine
          meteorological data.
Features especially relevant to (b) are the controls exerted  by topography on
the flow pattern and the effects of site geometry on the  behaviour  of  a plume
near the release point.  Discussion of such features will  be  found  in  recent
                   or 07         op
articles by Gifford  '   and Egan  .  An important component  of (c)  is  the
mean wind direction specification, especially as  regards  individual  short-
term averages of concentration when the plume is  narrow.
     Errors in the ground-level  position and magnitude  of  the maximum
concentration from an elevated source  arise especially  from uncertainties
in the effective height of source, the estimated  growth of vertical  spread,
and the wind direction.  As a consequence, individual estimates of  concentra-
tion at a particular receptor near the ensemble-average position of  the
maximum may be grossly in error (see discussion p. 303 of Ref. 1).
     Generally, the error statistics for concentration  estimates must  be
expected to vary widely, according to  the  particular conditions of  source,
site geometry, terrain, and airflow characteristics. From the  experience
accumulated in dispersion studies and  air  pollution  surveys,  it is  possible
to make realistic estimates of the best levels of accuracy which may be
achieved even in the simplest conditions likely to be encountered in practice.
An early exercise OP these lines has been  described  by  the writer (p. 398 of
Ref. 1).  It is scarcely necessary to  emphasize that laboratory-type accuracy
cannot be expected.  Accuracies  in the region of +_ 10 percent may be possible
in the most ideal circumstances  of source, terrain,  and airflow, but for many
circumstances of practical interest there  seems at present no basis  for
                                      33

-------
expecting uncertainties less than several  ten's  of percent  statistically or
factors of twc individually.
                                      34

-------
                                  REFERENCES
 1.  Pasquill, F.  Atmospheric Diffusion.   2nd Ed.  John Wiley & Sons,  New York,
     N. Y., 1974.

 2.  Pasqirill, F.  The Dispersion of Material  in the Atmospheric Boundary
     Layer—The Basis for Generalization.   In: Lectures on Air Pollution and
     Environmental Impact Analyses.   Am. Met.  Soc., 1975, pp. 1-34.

 3.  Batchelor, G. K.  Diffusion in  Field of Homogeneous Turbulence.  I.
     Eulerian Analysis.  Aust. J. Sci.  Res., 2:437, 1949.

 4,  Fortak, H. G.  Numerical Simulation of Temporal and Spatial Distributions
     of Urban Air Pollution Concentration.   In:   Proceedings of Symposium on
     Multiple-Source Urban Diffusion Models.  AP-86, U. S. Air Pollution
     Control Office, Research Triangel  Park, N.  C., 1970.

 5.  Hay, J. S., and F. Pasquill.  Diffusion from a Fixed Source at  a  Height
     of a Few Hundred Feet in the Atmosphere..   J.  Fluid Mech., 2:299,  1957.

 6.  Elliot, W. P.  The Vertical Diffusion  of Gas  from a Continuous  Source.
     Q. J. Air Water Pollut., 4:33,  1961.

 7.  Deardorff, J. W., and G. E. Willis.  Computer  and Laboratory Modeling of
     the Vertical Diffusion of Non-Buoyant  Particles in the Mixed Layer.  Adv.
     Geophy., 186:187-200, 1974.

 8.  Hamilton, P. M.  The Application  of a  Pulsed-Light Rangefinder  (Lidar)  to
     the Study of Chimney Plumes.  Philos.  Trans.  R. Soc. London, (A),  265:
     153-172, 1969.

 9.  Panofsky, H. A., H.  Tennekes, D.  H. Lenschow,  And J. C. Wyngaard.   The
     Characteristics of Turbulent Velocity  Components in the Surface  Layer
     under Convective Conditions.  Boundary Layer Meteorol., 11:355-362, 1977.

10.  Pasquill, F.  Some Topics Relating to  the Modeling of Dispersion  in the
     Boundary Layer.  EPA-650/4-75-015, U.  S.  Environmental  Protection Agency,
     Research Triangle Park,  N.  C.,  1975.

11.  Draxler, R.  R.   Determination of  Atmospheric Diffusion  Parameters.   Atmos.
     Environ., 10:99-105, 1976.

12.  Pasquill, R.  Atmospheric Dispersion  Parameters in Gaussian Plume Modeling,
     Part II.  EPA-600/4-76-030b, U. S. Environmental  Protection Agency,

                                       35

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    Research Triangle Park,  N.  C.,  1975.

13.   Willis, G.  E.,  and J. W.  Deardorff.   A  Laboratory  Model of  Diffusion into
     the Convective  Planetary  Boundary Layer.   Q.  j.  R. Meteorol.  Soc.,  102:
     427-446, 1976.

14.   Corrsin, S.   Limitation of Gradient  Transport Models  in Random Walks and
     in Turbulence.   Advances  in Geophysics, 18A:25-60, 1974.

15.   Chaudrey, F.  H., and R. N. Meroney.   Similarity  Theory of Diffusion and
     the Observed  Vertical  Spread in the  Diabatic  Surface  Layer.   Boundary
     Layer Meteorol, 3:405-415, 1973.

16.   Cramer. H.  E.   A practical Method for Estimating the  Dispersal of
     Atmospheric Contaminants.   In: Proceeding  of  the Conference on App. Met.,
     Am. Met. Soc.,  1957.

17.   Calder, K.  L.   Eddy Diffusion  and Evaporation in Flow over  Aerodynamical -
     ly Smooth and  Rough Surfaces.   Q. J. R. Meteorol.  Soc., 11:153,  1949.

18.   Batchelor,  G.  K.  Diffusion from Sources in a Turbulent Boundary Layer.
     Archiv. Mechanike Stosowanej,  3:661, 1964.

19.   Pasquill, F.   Lagrangian  Similarity  and Vertical Diffusion  from  a Source
     at Ground Level.  Q. J. R. Meteorol., 92:185, 1966.

20.   Tyldesley,  J.  B.  Contribution to Discussion  on  "Short Range  Vertical
     Diffusion in  Stable Conditions."  Q. J. R. ,1eteorol.  Soc.,  93-383-385,
     1967.

21.   Smith, F. B.   A Scheme  for Estimating the  Vertical  Dispersion of a  Plume
     from a Source  near Ground  Level.  In: Proceedings  of  the Third Meeting
     of the Expert  Panel on  Air Pollution Modeling, NATO/CCMS Report  No. 14,
     1972.  (See also Ref.  1,  p. 374 and  Ref. 2, p. 16.)

22.   Gifford, F.  A.   Diffusion  in the Diabatic  Surface  Layer. .J.  Geophys.
     Res. , 67:3207,  1962.

23.   Merry, M.,  and  H. A. Panofsky.  Statistics of Vertical Motion over  Land
     and Water.   Q.  J. R. Meteorol. Soc., 102:255-259,  1976.

24.   Lewellen, W.  S., and M. E. Teske. Second-Order  Closure Modeling of
     Diffusion in  the Atmospheric Boundary Layer.   Boundary Layer  Meteorol.
     10:69-90, 1976.

25.   Businger, J.  A., and S. P. S.  Arya.   Height of the Mixed Layer in the
     Stably Stratified Planetary Boundary Layer.   Adv.  Geophy.,  18A:73-92,
     1974.

26.   Lumley, J.  L.   Simulating  Turbulent  Transport in Urban Air  Pollution
     Models.  (Unpublished Manuscript 1976.)

                                     36

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27.  Lewellen, W. S., and M. E.  Teske.   Atmospheric Pollutant  Dispersion
     Using Second-Order Closure  Modeling of the Turbulence.  Environmental
     Modeling and Simulation.  EPA-600/9-76-016, U. S.  Environmental  Protection
     Agency. Research Triangle Park, N.  C., 1975, pp.  714-718.

28.  Teske, M.< E., and W. S. Lewellen.   Example Calculations of Atmospheric
     Dispersion Using Second-Order Closure Modeling.  In:  Third Symposium  on
     Atmospheric Turbulence, Diffusion,  and Air Quality.  Am. Met.  Soc.,  1973,
     pp. 149-154.

29.  Donaldson, C. duP.  Construction of a Dynamic Model  of  the Production of
     Atmospheric Turbulence and  the Dispersal  of Atmospheric Pollutants.   In:
     Workshop on Micrometeorology,  Am.  Met. Soc., 1973,  pp. 313-392.

30.  Zeman, 0., and J. L. Lumley.  Turbulence and Diffusion  Modeling  in
     Buoyancy Driven Mixed Layers.  In:  Third Symposium on Atmospheric
     Turbulence, Diffusion, and  Air Quality.  Am. Met.  Soc., 1976, pp. 38-45.

31  Crane, G., and H. A. Panofsky.  A Dispersion Model  for Los  Angeles.  In:
    Third Symposium on Atmospheric Turbulence, Diffusion,  and  Air Quality.
    Am. Met. Soc., 1976, pp. 122-123.

32.  Deardorff, J. W., and G. E. Willis.  A Parameterization of Diffusion  in-
     to the Mixed Layer.   \ Appl. Meteorol., 14:1451-1458,  1975.

33.  Turner, D. Bruce.  Workbook of Atmospheric Dispersion Estimates.  Offict
     of Air Programs Publication No.  AP-26.   U.S.  Environmental  Protection
     Agency, Research Triangle Park,  NC, 84 p,  1970.

34.  American Society of Mechanical Engineers.   Recommended  Guide  for  the
     Prediction of the Dispersion of Airborne Effluents,  New York, 1973.

35.  Gifford, F. A.   Atmospheric Dispersion Models  for  Environmental
     Pollution Applications.  In: Lectures on  Air Pollution  and Environmental
     Impact Analyses, Am. Met. Soc., 1975, pp.  35-58.

36.  Weber, A.  Atmospheric Dispersion  Parameters in Gaussian Plume Modeling.
     Part I. Review  of Current Systems and Possible Future Developments.
     EPA-600/4-76-030a, U.  S.  Environmental  Protection  Agency,  Research
     Triangle Park,  N. C.,  1976.

37.  Gifford, F.  A.   Turbulent Diffusion-Typing Schemes:   A  Review.  Nucl.
     Saf.,  17:68-86,  1976.

38.  Egan,  B. A.   Turbulent Diffusion in Complex Terrain.  In:  Lectures on
     Air Pollution and Environmental  Impact  Analyses.   Am. Met.  Soc.,  1975,
     pp. 112-135.
                                    37

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                                APPENDIX A
            SIMILARITY-EMPIRICAL CONSIDERATIONS OF VERTICAL  SPREAD
                   AT SHORT RANGE FROM A SURFACE RELEASE
DATA FROM PROJECT 1:PRAIRIE GRASS"
    The "Prairie Crass" measurements included measurements of vertical  distri-
bution at a distance of 100 m from the source.  Magnitudes of a   derived  from
these data have been put together with additional  measurements in stable  con-
ditions in England by Pasquill  (Ref. 1, p 207, Fig. 4.14).
                                                             p
    Indirect estimates of a  have also been derived by Cramer at greater
distances, up to 800 m, from the "Prairie Grass" data by  using the  measure-
ments of peak concentration and crosswind spread,  and substituting  these  in
the conventional Gaussian plume formula.  Also, from this Gaussian  formula
(in which implicitly the wind is invariant with height)

                     C(x,o,o)   or   l/tfao2                          (A-l)

and if C, o  are measured as a  function of distance the relative  variation of
a  automatically follows and may be converted into absolute  values  of a  by
adopting the directly measured  value at 100 m.  The results  for a  are given
as a function of distance, for  various magnitudes  of the  standard deviation
of wind direction fluctuation a., in Figure 11 of Cramer's paper, and corre-
sponding exponents in the power-law variation of C, a , and  a with distance
over distance intervals 50-100, 10C-200, 200-400,  and 400-800 m are given in
Tables 4a and 4b of that paper.
    The foregoing procedure is  questionable on account of the variation of
wind with height, and a more acceptable form of Eq. (A-l) is

           C(x.o.o)   «   I/ ue ay az                                 (A-2)
                                     38

-------
where u   is an effective wind speed, increasing with a  and therefore with
distance.  An expression for u  may be obtained by correctly writing the con-
servation equation with u a function of height (« zn for convenience).
    With  CIC(x,0) denoting the crosswind integrated concentration at the sur-
face, and assuming a Gaussian distribution in the vertical, the conservation
equation  for a rate cf release Q is

                            f_M
           Q  =  CIC(x.O)    u(z)  exp (-z2/2az2)dz .                     (A-3)
                           •'o
Taking           u~(z)  =  U"(z()(z/z,)n                                   (A-4)
           Q  =  2-azz,-    (         CIC(x.O)            (A-5)

which with z, = az is of the form corresponding' to Eq.(A-2),  i.e.,

           Q  =  (ir/2)%az ue CIC(x.O)                                   (A-6)

if we take
           up =  (27    2-       (l+n)/2  u(oj .                      (A-7)
„    V— » II /   —         |V I  II /, ._  «" \>J
The ratio  u /u(a  ) is of course unity for the case of wind constant with
height  (n = 0).  As n is increased to unity (which embraces the range found
in practice), the  ratio falls to 0.798.
      For the present purpose of adjusting the original Cramer estimates of
a  , the essential  point is that we may now take u  directly proportional to
u"(a ),  i.e., to a   , for a giver wind profile and neglecting the (slow)
variation of n with height in practice.  Accordingly, if in Eq. (A-2) we take
C(x,0,0) cr x"c and a  « xa, it follows that

                 x'2 -l/(xaaznaz)
and therefore
                 oz « xb  with b  =   (c - a)/l+n)                      (A-8)

                                      39

-------
 instead  of b  =  c  -  a  as  given  by Cramer.  Starting with the directly measured
 values of az(100  m) and  Cramer's values of b, the foregoing result has
 been  used to  derive adjusted values of a  in a step-by-step procedure set out
 in  Table A-l.   Note that the original estimates at 800 m are reduced by a
 fraction ranging  froir only  0.02 in the most unstable conditions to nearly
 0.6 in the most stable conditions.
      The adjusted  empirical values of a  have been used to derive a dimension-
 less  dispersion-velocity function
                    $(Z/L)   =   ( l/ku*)( dZ/dt)                        (A-9)
 in  which Z is the mean height  reached by particles at a given time after leaving
 the surface.  This  form  was first postulated by Gifford , with a constant b
 in  place of the von Karman  constant k, and identity of b and k was first
 argued by Ellison (see Ref. 1, p 117).  Details of the derivation of $(Z~/L)
 are summarized  in Table  A-2, and the results are shown graphically in Figure A-l,
       In accordance with the setting of b = k = 0.4 in earlier considerations
 of  Lagrangian similarity (see  Ref. 1, pp. 118 and 206), $(1/1) tends to unity
 as  I/I tends  to zero, and this is reaffirmed in the trend of the empirical
 values presented  here.  However, as the function departs from unity, increas-
 ing in unstable flow  and decreasing in stable flow, similarity in terms of u*
 and L is not  entirely supported, in that the set of points for different
 magnitudes of L/z  do not collapse onto a single curve.  Although the depar-
 tures from a  single curve are  not large, compared say with the scatter in
 the empirical specification of the Monin-Obukhov velocity profile function
 $> , it may be significant that a systematic effect of L/zn is clearly evident.
  n                                                       0
 SIMILARITY HYPOTHESES ON MONIN-OBUKHOV LINES
      Form of $  have already been suggested in terms of the Monin-Obukhov
 functions for transfer of momentum and heat  (see Table 5 of the text), either
 explicitly, or  implicitly through gradient transfer considerations.  These
 forms are reproduced  graphically in Figure A-l.  Note that the form in terms of
 *M  seriously underestimates the effect of stable flow, a result which is
 partly to be expected from  the fact that Tyldesley's setting of the constant
 ^was determined  by fitting to Thompson  data, and these data  (see Ref 1,
•p 207)  do show  a  smaller reduction in a  than do the "Prairie Grass" data.
                                      40

-------
TABLE A-1.  ADJUSTMENT OF CRAMER'S 1957  E?TIMATES OF az FROM PRAIRIE GMSS DATA
Lengths in

az(100m)
•R1(2m)
L
Cramer's
Cramer's
b (100-200)
Est. n
Corrd. b
Adjusted
az(200)
b (200-400)
Est. n
Corrd. b
Adjusted
az(400)
b (400-800)
i
Est. n
Corrd. b
Adjusted
az(800)
Cramer ' s
Original
oz(800)
metres, z
0
10
-0.5
-4
21.5
1.43
0.1
1.30
24.6
1.93
0.1
1.75
82.8
2.46
0.1
2.24
391

400
= 0.008

8
-0.27
-7.4
16
1.24
0.1
1.13
17.5
1.66
0.1
1.51
49.9
2.08
0.1
1.89
185

200


6
-0.09
-22.2
11.5
1.07
0.1
0.97
11.8
1.47
0.1
1.34
29.8
1.75
0.1
1.59
89.7

110


4.5
0

8
1.0
0.16
0.86
8.16
1.20
0.13
1.06
17.0
1.30
0.12
1.16
38.0

50


3
0.06
23.5
5
0.9
0.24
0.73
4.97
0.90
0.29
0.70
8.1
0.80
0.35
0.59
12.2

23


2
0.12
7.1
3
0.8
0.34
0.60
3.03
0.90
0.42
0.63
4.7
0.40
0.45
0.28
5.7

14



(1)
(2)
(3)
(4)
(5)
(6)
(7)











                                     41

-------
TABLE A-I.  ADJUSTMENT OF CRAMER-S L(%& ESTIMATES  OF az FROM  PRAIRIE  GRASS  DATA

 Explanatory Notes
   (1)   From "eye fit" curve, Fig. 4.14, p 207 of Pasquill1
   (2)   Taking Ri(z) = z/L in unstable conditions
              Ri(z) = (z/L)(l  +  4.8Z/L)"1   in stable conditions
   (3)   Interpolating for  a (100) on Fig. 11  of Cramer"
   (4)   Interpolating in accordance with  aft in Cramer's Tables  4a  and 4b
   (5)   In u •* zn, for unstable conditions n = C.I is taken  as  a reasonable
        approximation.  In stable conditions a power law was  fitted to the
        similarity form specified in Table A-3, for z  = 0.8  cm,  over  the
        height interval  corresponding to Cramer's  Z values,  where  1= 0.776
        a,, the latter relation being appropriate  to a vertical  distribution
        form exp-(bzs) with s = 1.5.
   (6)   Estimated corrected b is b/(l+n) as  argued in text
   (7)   Adjusted az(200)  = "directly" measured a (100) x 2b
        Adjusted az(400)  =  Adjusted az(200)  x 2
       . etc.
                                      42

-------
        TABLE  A-2.  ESTIMATES OF (l/kuJ^Z/cit) FROM ADJUSTED VERTICAL
	SPREAD ESTIMATES IN TABLE 1	


  x            Z          dl/dx*        kU"/uxt     (l/kuj(ol/dt)*    I/I

                       (L      -4,    L/zo      -500)

141.4         12.17        0.1119         5.505          3.85         - 3.04

282.2         35.03        0.2168         6.1i8          8.29         - 8.76
565.7       139.7         0.5532         7.026         24.29         -34.9


                       (L      -7.4,  L/z       -925)
141. 4
282.8
565.7

141.4
282.3
:ec,.7

141.4
2S2.8
565.7

141.4
282.8
565.7
9.17
22.93
74.52

6.52
14.53
"O^O

3.00
4.92
7.71

1.91
2.92
4.01
0.0733
0.1225
0.2490
(L -22.2,
0.0447
0.0688
0.1127
(L 23.5,
0.0155
0.0122
0.00804
(L 7.1,
0.00810
0.00651
0.00199
5.62
6.169
6.9*1
L/Zo
5.85
G . 36
6.S5?
L/2o
5.78
G.46
7.18
L/Zo
5.70
6.52
7.26
2.57
4.72
10.80
-2775)
1.63
2.73
4.90
2937.5)
0.56
0.49
'.2L
387.5)
0.29
0.27
0.090
- 1.24
-• 3.10
-10.07

- 0.29
- 0.65
- 1.81

0.128
0.209
0.328

0.269
0.412
0.565
Explanatory Notes:
*    In accordance with the analysis of Table A-l, assume over 2:1 intervals
     of distance that

                         Z~(x)/Z|   = (x/x-j)
and that Z = 0.776 a .   Considering I and d7/dx at the geometric mean of the
distances x1 and 2x1f it fellows  that

                         d7/dx  = bZ/2?i x1
                         T  -  ob/2^-
                         L  -  c.    L-> •

                                    43

-------
        TABLE  A-2.   ESTIMATES  OF  (lkuJ(dZ/dt)  FROM ADJUSTED VERTICAL
	SPREAD  ESTIMATES  IN  TABLE L	

 }     For 0.6  Z/L,  evaluated from the wind  profile equation given in Table 3,
      and assuming  u «  z0-1 for -z/L  greater than 1.0.

 I    Invoking the  similarity  assumption

                              dT/dt   =  "(cZ)

 with  c  = 0.6  (see  item 2 of Table 5  of  main text for reference).
                                      44

-------
            0.2
0.5
5
10
                                   (- VL)
  1C
                                                 a  r-3),  O
0 F
\j t <~>
0.2
C.I j
                                                      1 ft
                                            12
                                                                        1
                                                                      -' '
                                                      I/"
                                                     ,1  14
                  ( -I- Z/L)
                Figure A-l.   Vertical diffusion similarity  functions.
                                       45

-------
The form $ = l/H advocated by Chaudrey and Meroney  does provide an encouraging
fit, though there is ambiquity as to the precise numerical  values to be adopted
for (f>H in unstable flow, and the one set of values considered in stable flow
overestimates $ somewhat.
SIMILARITY IN TERMS OF THE INTENSITY AND SCALE OF TURBULENCE
     As an alternative to the original  form of Lagrangian siirilarity treatment,
the writer *  has suggested a simple local  similarity approach in terms of
the intensity and scale of the vertical component of turbulence, both regarded
as functions of height.
     In the practical form to be considered here, the dispersion velocity is
written as follows:
                      dZ/dt  =  a
L°wVz
in which X  is the equivalent wavelength at which the product cf frequency
and spectral density of the vertical component is a maximum.  It turns out
that to a useful approximation the foregoing relation is the same as that
which follows from the assumption of a gradient-transfer relation with
                      K  =  ao^  .                                   (A-ll)
On identifying Eq. (A-ll) with the Monin-Obukhov form of KM in the special case
of neutral flofc, and inserting the latest estimates of 0 /u and X /z (see later)
                                                        w        m
the magnitude of the constant a is 0.154.  (Alternatively, note that this mag-
nitude is consistent with the result dT/dt = 0.4 u*.)
     The latest estimates of the boundary layer parameters a /u* and X /a* as
                                                            w         HI
a function of z/L are listed in Table A-3, with the magnitude of the dispersion
function $ which then follows from a combination of Eq. (A-9) and A-10).  Also
included are values of the velocity profile function \|>, from which dZ/dt may
be converted to dZ/dX", where X" is the mean distance of travel of the particles.
     As can be seen from Figure A-l, the function $ derived in Table A-3 shows
a growth in unstable flow which, over the total range of Z/L covered, is similar
to that found in the "Prairie Grass" measurements of dispersion.  However,
there are differences in detail, notably the very sharp increase in the

                                     46

-------
  TABLE A-3.  MAGNITUDES OF  BOUNDARY  LAYER PARAMETERS AND  DIMENSIONLESS
              DISPERSION VELOCITY $(Z/L)  DEFINED  IN EQ..(A-9)  AND  (A-10)

z/L
-10
- 5
- 2
- 1
- 0.5
- 0.2
- 0.1
- 0.05
- 0.02
- 0.01
0
0.01
0.02
O.Q5
0.1
0.3
0.5
1
2
^



-1.032
-0.707
-0.354
-0.185
-0.082
-0.024
-0.009
0
0.047
0.094
0.235
0.47
1.41
2.35
4.7
(9.4)
aw/U*
4.084
3.276
2.487
2.064
1.764
1.520
1.419
1.362
1.325
1.313
1.3
1.32
1.34
1.37
1.40
1.57
1.70
1.97
2.36
Vz
6.0
6.0
6.0
6.0
3.5
2.0
2.0
2.0
2.0
2.0
o n
L . \j
(1.97)
(1.94)
(1.90)
1.8
1.25
1.0
0.67
0.45
*U/L)
9.423
7.557
5.737
4.763
2.373
1.170
1.093
1.047
1.017
1.010
1.000
(1.000)
(1.000)
(1.000)
0.970
0.755
0.653
0.507
0.407

ku/u*  =  ln(z/zn)  +  iM
                                         9
\p  for -ve values of z/L,  Dyer and Hicks

t>  for +ve values of z/L,  4.7z/L, Merry and  Panofsky8
aw/u*  =  1>3   L1-0  +  3.0(z/-L)J        for -ve values of z/L,  Panofsky
                                                        et al10 published
                r                 11/3
       =1.3   [1.0+  2.5(z/L) J        for +ve values of z/L,  based on   •
                                                        Iierry arid Pc.nofsky°
A /z  Based on Kaimal et a!   1972.   The "refined" estimates in parentheses
  'are consistent with the general shape of the Am, z curve Baking the neutral
  value as 2.0, and are used rather than rounded values of 2.0 to avoid values
  greater than 1.0 for  $.
                                     47

-------
"similarity theory" value fof Z/L in the region  of -0.5,  which  does  not  appear
in the empirical  values.  This sharp increase is associated  with  the sharp
increase of \m with height in that range of z/L.  On the  other  hand, in  the
most unstable conditions the empirical  values show a much greater rate of
growth than the "similarity theory" values, the  latter necessarily tending to
                      —    1 / ^
a limiting growth as (Z/-L) '   in accordance with the limits of a /u* and
                                         —   i /"^
A /z in Table A-3.  Note also that this (Z-L)    limiting growth  also follows
from the similarity hypothesis that in  free-convective transfer the  dispersion
velocity is determined uniquely by the  surface heat flux  and the  height  (7),
so something is clearly calling for explanation  in the observed growth of
$ at large values of (Z"-L).
     In stable conditions the "similarity theory" function falls  away from
unity much more slowly than is found empirically.  It may be significant here
that a determining factor in the similarity function is the  increase of  a/u*
                                           p                            w
with z/L, now claimed by Merry and Panofsky  and included in Table A-3.
                                     48

-------
                                 REFERENCES

 1.   Pasquill, F.   Atmospheric Diffusion, 2nd Ed.   John Wiley & Sons,  New
     York, N.  Y.,  1974.

 2.   Cramer, H.  E.  A Practical  Method for Estimating the Dispersal  of
     Atmospheric Contaminants, Proceedings of the  Conference on App.  Met.,
     Am.  Met.  Soc., 1957.

 3.   Gifford,  F. A.  Diffusion in the Diabatic Surface Layer. J.  Geophys.
     Res., 67:3207, 1962.

 4.   Thompson, N.   Short-Range Vertical  Diffusion  in Stable Conditions.   Q.
     J.  R. Meteorol.  Soc., 91:175, 1965.

 5.   Chaudrey, F.  H., and R.  N.  Meroney.   Similarity Theory of Diffusion
     and the Observed Vertical Spread in  the Diabatic Surface Layer.  Boundary
     Layer Meteorol., 3:405-415, 1973.

 6.   Pasquill, F.   The Dispersion of Material in  the Atmospheric  Boundary
     Layer—The  Basis for Generalization.  In:  Lectures on Air Pollution and
     Environmental Impact Analyses, Am.  Met. Soc.,  1975, pp. 1-34.

 7.   Pasquill, F.   Some Topics Relating  to the Modeling of Dispersion  in  the
     Boundary  Layer,  EPA-650/4-75-015, U. S. Environmental  Protection  Agency,
     Research  Triangle Park,  N.  C., 1975.

 8.   Merry, M.,  and H. A. Panofsky.  Statistics of Vertical Motion  over
     Land and  Water.   Q.  J.  R. Meteorol.  Soc., 102:255-259, 1976.

 9.   Dyer, A.  J.,  and B.  B.  Hicks.  Flux-Gradient  Relationships in  the
     Constant  Flux Layer. Q.  J.  R. Meteorol. Soc.,  96:715-721, 1970.

10.   Panofsky, H.  A., H.  Tennekes, D. H.  Lenschow,  and J.  C. '..'yngaard.  The
     Characteristics  of Turbulent Velocity Components in the Surface  Layer
     under Convective Conditions. Boundary Layer  Meteorol., 11:355-362, 1977.

11.   Kaimal. J.  C., J. C. Wyngaard, Y. Izumi, and  0. R. Cote.  Spectral
     Characteristics  of Surface  Layer Turbulence.  Q. J. R.  Meteorol.  Soc.,
     98:563-589, 1972.

12.   Dyer. A.  J.  The Turbulaent Transport of Heat  and Water Vapour in an
     Unstable  Atmosphere. Q.  J.  R. Meteorol. Soc.,  93:501-508, 1967.
                                     49

-------
13.   Businger.  J.  A.   Transfer of Momentum and Heat  in  the  Planetary  Boundary
     Layer.  In:  Proceedings  of the Symposium on  Artie  Heat Budget  and
     Atmospheric Circulation  (The Rand Corp.), 1966,  pp.  305-332.

14.   Businger,  J.  A.,  J.  C.  Wyngaard,  Y.  Izumi,  and  E.  F.  Bradley.   Flux-
     Profile Relationships in the Atmospheric Surface Layer.  J.  Atmos.  Sci.,
     28:181-189, 1971.

15.   Tyldesley, J. B.   Contribution to Discussion on  "Short-Range"  Vertical
     Diffusion  in  Stable Conditions. Q.  J. R. Meteorol. Soc.,  93:383-385,  1967.
                                    50

-------
                                 APPENDIX B
           A SIMPLE TWO-LAYER MODEL FOR ESTIMATING VERTICAL SPREAD
               BEYOND THE SURFACE-STRESS LAYER IN NEUTRAL FLOW
     The equivalence of the Lagrangian similarity result, dT/dt = ku*.  and
gradient-transfer with K = ku*z has already been noted.   These laws,  however,
apply only over a shallow surface layer (the surface-stress layer) and  for the
higher parts cf the boundary layer a different form of K-profile must apply.
There have been several guides to the form of this profile, and one of  the
latest, due to Businger and Arya , is shown in Figure E-l in the dimensionless
form K/u*h versus z/h where h is the depth of the boundary layer.  This profile
was derived in a treatment in which von Karman's constant was taken to  be  0.35;
bearing this figure in mind the reader can observe that  the profile follows the
surface-stress layer form very closely up to z/h = 0.05  and to a reasonable
approximation even up to z/h = 0.1.  Thereafter, there is the non familiar
bending of the curve to form a maximum K, in this case with K/u* = 0.033 at
z/h = 0.25, and then a continuous falloff at greater heights.  Note also,  as
an indication of the present uncertainties, that this maximum K is only about
                                          p
half that previously estimated by Townsend  (K/u*h = 0.067).
     Notwithstanding the uncertainties it is now suggested that a useful
general guide to the a  growth curve throughout a substantial depth of  the
atmospheric neutral boundary layer may be obtained from  a simple model  with
the following properties:
     (a)  The surface-stress-layer result for d_Z_ and K is taken to apply to
          Z1  = h/12.                         dt
     (b)  K is taken to be constant at the surface-stress-layer value K(Z") for
          h/12 
-------

                                         m
                                         "i_L
     -tr—r
                                                          -pr
                                                      w+i H-tf
              £*HI
                     +-)-r —
                                  :~ ,-, \. .
                ur
                ~ '-i
                                             -t~t
                                                  -H-4
                                                           ";i
                                                      HH
                                                                 :,t
                                         :ra
. -.  , __.,„, „
   i_i»^-, T.
                                     The continuous curve is from
                                     Businger and Arya's analysis
                                     (Ref. 1) - the y* = 0 curve of
                                     their Fig. 5 combined with
                                     fh/u* = 0.7 as given in their
                                     Fig. 11.
                                     The broken line is the simpli-
                                     fied two-layer form used in
                                     the present analysis.
                         •F
                         I
                                   •i.l  U!
                                                                    rt-f
                                                                    14+
                                                     ^
                                      _i..
                                                          -r
                                                 ir^rn'r
                                                  !- '4- , J   -•  I
3   466
             f b'.'oi
                             3   4   5  6  7  a
                                                              4   5  6  7  8 9 10
Figure B-l.   K-profile in a neutral  boundary layer of depth h.

                           52

-------
     A general solution of the two-dimensional  equation of diffusion with this
two-layer form of K cculd be obtained numerically, but a short-cut calculation
adequate for bringing out the essential properties of the a  growth may be
carried out as follows:  For the lower layer (Z <_I.}

                    dT/dt  =  ku*                                      (B-l)
                    dX/dt  =  u"(cZ~)                                    (B-2)
                 kF(z)/u*  =  ln(z/zo).                                (B-3)
These equations may be integrated to give X~as  a function of 7,  and the
solution which follows from taking the lower limit of integration at I = z  is
                 kV  =  Z    Inz'  - (1  - lnc)(l  - iz')
                                                                       (B-4)
where X  = X/z  and Z  = Z/z  (see Ref. 4, p. 117).  This result is physically
              0    i         0
unacceptable when Z  is near 1.0, since with c less than 1.0 (approximately
0.6) dX/dt actually becomes negative.  This unacceptable result may be
eliminated simply by making the lower limit of integration z /c, in which the
result is
                    k2 X"'   =  Z"'(ln cZ~' - 1)  +  1/c.                  (B-5)
     If K were everywhere constant (= K ) we could write
                    I2  =  2(//az)2 KJ                                (B-6)
or                  dl/dt  =  (Z/az)2 |
-------
     From Eq. (B-6), substituting K  = ku*Z.  and writing (Z/a )2  = r,
                                   C       1                  Z
                      72 - Z2.   =  2r2k u*Z.  (T - T^                   (B-9)
with T. and T the travel times  corresponding  to 7.  and 7,  applicable for 7 up
to say 67. in accordance with (b) above.  For conversion to a I,  X" relation
Eq. (B-9) should be combined with Eq. (B-2) and an appropriate value of c.   How-
ever, since a large proportion  of the total change of wind speed  with  height
occurs in the bottom one-tenth  of the boundary layer, it will be  adequate for
present purposes to take with Eq. (B-9) a constant value of X/T equal  to the wind
speed at say z/h =1/6.  This constant "effective wind speed" u  may be repre-
sented as a fraction p of the geotrophic wind speed, p being drivable  as a func-
tion of Ro from F. B. Smith's  model.  Writing 7 and X" in  the dimensionless forms
above, Eq. (B-9) then becomes
                                           - x,)/pV
and at large I/I,
                    7'2
Given r and k Eqs. (E-10) and (B-ll) are determined by a2> u*/V ,  p, and V  /fz
the first three of these all being functions of the last (the Surface Rossby
Number) and determinable from Smith's model.  Table B-l  gives, for a practical
range of the Surface Rossby Number, the magnitudes of the foregoing parameters,
of 7,, JC,, and of the coefficients A and B in the 7, X~ relations  are specified
in the notes below the table.
     The resulting data for 7/z  as a function of X/z  are shown  graphically
in Figure B-2.  There is a sharp discontinuity at the junctions of the surface-
stress-layer curve (Eq. (B-5) with the Ro-dependent sections (Eq.  (B-10), at
7=7,.  This is a consequence of the discontinuity in d7/dt according to
Eq. (B-8) and Eq. (B-7).  Note also that the limiting form in Eq.  (B-ll) is an
adequate approximation to Eq. (B-10) except near the discontinuity for the
smaller values of Ro.  Finally, it is emphasized that the curves  are taken
only to 7 = h/2, and even at this stage there will be some error  (overestima-
ting 7) if, as expected, there is a reduction of K in the top part of the
boundary layer.
                                     54

-------
TABLE B-l.  PARAMETERS  AND  RESULTS  IN  THE ESTIMATION OF VERTICAL SPREAD FROM A
            SURFACE  RELEASE,  BEYOND THE  SURFACE-STRESS LAYER,  IN NEUTRAL FLOW
1
2
3
4
5
6
7
8
Ro
a2
U*/Vg
Ue/Vg
ZJ
X!
A
B
104
0.320
0.080
0.717
21.33
207.6
3.775
xlO2
1.098
3xl04
0.308
0.070
G.790
53.9
835.2
1.200
xlO3
1.555
105
0.290
0.062
0.858
149.8
3.277
xlO3
4.093
xlO3
2.341
3xl05
0.275
0.054
0.870
371.3
1.023
xlO4
1.180
xlO4
3.416
106
0.260
0.0475
0.886
1029
3.490
xlO4
3.790
xlO4
5.285
3xl06
0.247
0.043
0.904
2655
1.058
xlO5
1.102
xlO5
7.996
107
0.236
0.0385
0.910
7572
3.512
xlO5
3.534
xlO5
12.73
Notes
1.  Ro = Surface Rossby No. = V /fzQ
2.  a« = hf/u*. where h  1s depth of boundary layer
4.  u  = dX/dt, taken to be u at z = h/6, = pV . evaluated from the interpolation
     e                                        9
    form ku(z)/u* = In(z/z0) - z/h
5.  ZJ = h/12zo
6.  7| = value of X1 for Z1 = ^ in Eq. (B-5)
7.  Coefficient A in X' - X| =  A  [(Z'2/ Z,'2) - l]  (see Eq. (B-10))
8.  Coefficient B in Z1 = B X1'2    (see Eq. (B-ll)) (for both A and B, k = 0.4 and
    f/o  = 0.796, the latter figure being appropriate to a Gaussian distribution)
2,3,4.  Data all in accordance with F. B. Smith's3 neutral boundary layer model,
with unpublished minor adjustments.
                                        55

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                                 REFERENCES

1.  Businger, J.  A.,  and S.  P.  S. Arya.  Height of the Mixed Layer in the
    Stably Stratified Planetary Boundary Layer.  Adv. Gecphy., 18A:73-92, 1974,

2.  Townsend, A.  A.   The Structure of  Shear Flow.  Cambridge University Press,
    Cambridge, England,  1956.

3.  Smith, F. B.   Turbulence in the Atmospheric Boundary Layer.  Sci. Prog.,
    62:127-151, 1975.

4.  Pasquill, F.   Atmospheric  Diffusion, 2nd Ed., John Wiley & Sons, New York,
    N. Y., 1974.
                                     57

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
1. REPORT NO.
  EPA-600/4-78-021
             3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE

  ATMOSPHERIC  DISPERSION PARAMETERS  IN  PLUME MODELING
             5. REPORT DATE
               May 1978
                                                           6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                           8. PERFORMING ORGANIZATION REPORT NO.
  F. Pasquill
9. PERFORMING ORGANIZATION NAME AND ADDRESS
  Environmental  Sciences Research  Laboratory
  Office  of  Research and Development
  U.S.  Environmental Protection  Agency
  Research Triangle Park, North  Carolina 27711
             10. PROGRAM ELEMENT NO.

               1AA603 AB-02 (FY-78)
             11. CONTRACT/GRANT NO.
12. SPONSORING AGENCY NAME AND ADDRESS
  Environmental  Sciences Research  Laboratory - RTP,  NC
  Office  of Research and Development
  U.S.  Environmental Protection  Agency
  Research  Triangle Park, North  Carolina 27711
             13. TYPE OF REPORT AND PERIOD COVFRFD
               Inhouse  1/77-8/77
             14. SPONSORING AGENCY CODE
                  EPA/600/09
15. SUPPLEMENTARY NOTES
 *Visiting Scientist from  United Kingdom
16. ABSTRACT
        A survey of the underlying foundations of  the  present systems for  specifi-
  cation of the atmospheric  dispersion parameters  for a  continuous point  source
  leads to the conclusion  that the basis for revision of the current systems  is
  still far from complete, but certain obvious evidence  points to desirable
  changes.  The author's previous recommendations  on  the crosswind spread are
  reiterated, and a suggested revision for vertical  spread as a function  of
  surface roughness, stability, and for the unstable  case, the convective velocity
  scale and mixing depth,  is offered.
17.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS  C. COSATI Field/Group
   Air pollution
  *Atmospheric diffusion
  *Plumes
  *Meteorology
  *Mathematical models
                                13B
                                04A
                                21B
                                04B
                                12A
18. DISTRIBUTION STATEMENT
                       RELEASE TO  PUBLIC
19. SECURITY CLASS (ThisReport)

     UNCLASSIFIED
                                                                         21. NO. OF PAGES
                                                                             68
20. SECURITY CLASS (Thispage)
     UNCLASSIFIED
                                                                         22. PRICE
EPA Form 2220-1 (9-73)
                                             58

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