RAi2ii 740R78103
.A69
1978
v. 3
TOXIC SUBSTANCES CONTROL ACT (TSCA)
PL 94-469
CANDIDATE LIST OF
CHEMICAL SUBSTANCES
ADDENDUM III
CHEMICAL SUBSTANCES OF UNKNOWN OR VARIABLE COMPOSITION,
COMPLEX REACTION PRODUCTS AND BIOLOGICAL MATERIALS
MARCH 1978
U.S. ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF TOXIC SUBSTANCES
WASHINGTON, D.C. 20460
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TOXIC SUBSTANCES CONTROL ACT (TSCA)
PL 94-469
CANDIDATE LIST OF
CHEMICAL SUBSTANCES
ADDENDUM III
Chemical Substances of Unknown or Variable Composition,
Complex Reaction Products and Biological Materials
March 1978
U.S. Environmental Protection Agency
Office of Toxic Substances
Washington, DC 20460
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TABLE OF CONTENTS
Page
Introduction 1
Section I : Class 2 Chemical Substances Derived from
Natural Fats and Oils and Synthetic Sub-
stitutes (An Alternate Procedure for Sub-
stance Identification and Reporting for
the Chemical Substance Inventory) 3
Section II : Coke and Selected Coal Chemicals 35
Section III : Chemical Substances Common to the Iron
and Steel Industry 39
Section IV : Wood and Pulp Chemicals 43
Section V : Chemical Substances Manufactured in the
Paper Industry 47
Section VI : Chemical Substances Manufactured in the
Fertilizer Industry 49
Section VII : Natural Oils and Extractives 51
Section VIII: Selected Polymers 63
Section IX : Chemical Substances Manufactured as
Part of Mixtures 77
Section X : Other Class 2 Chemical Substances 81
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INTRODUCTION
The Toxic Substances Control Act (TSCA), Public Law 94-469, re-
quires the U.S. Environmental Protection Agency to compile, keep cur-
rent, and publish a list of each chemical substance which is manufac-
tured, imported, or processed in the United States for commercial
purposes. Under the authority of Section 8 of TSCA, EPA will compile
this inventory from reports prepared and submitted by manufacturers,
importers, and processors of chemical substances in accordance with
Inventory Reporting Regulations (40 CFR 710) . These regulations were
published in the FEDERAL REGISTER on December 23, 1977 (pages 64572 to
64596), and became effective on January 1, 1978.
In April 1977, EPA published the TSCA Candidate List of Chemical
Substances, which identifies over 30,000 chemical substances. The
Candidate List was prepared to assist persons in reporting chemical
substances for the Inventory. In January 1978, EPA published two
addenda to the Candidate List, the first identifying petroleum refinery
intermediate and final process stream chemical substances, and the
second identifying an additional 3,000 Class 1 chemical substances. A
Class 1 chemical substance is one whose composition can be represented
by a definite chemical structure diagram.
This document, addendum III to the Candidate List, identifies
primarily Class 2 chemical substances, and provides a mechanism for
identifying and reporting others. A Class 2 chemical substance is one
whose composition cannot be represented by a definite chemical structure
diagram. Some chemical substances identified in this addendum are
defined, in part, in terms of the processes by which they are manufac-
tured. Other chemical substances are simply identified by names which
are widely recognized and need no further definition.
Certain common materials of commerce, such as inorganic glasses,
are defined by the Inventory Reporting Regulations as mixtures. To
facilitate reporting, this addendum defines certain categories which
encompass the individual chemical substances manufactured in the pro-
duction of these mixtures.
This addendum is organized into ten RPctions, listing terms de-
veloped by EPA in cooperation with various trade associations and other
agents. They represent industries involved in the manufacture of Class
2 chemical substances which are difficult to define, either due to
slight variations of process or because the composition of these sub-
stances is not completely known or is variable. Although this addendum
identifies chemical substances which are common to specific industries,
it does not include all reportable chemical substances manufactured
within these industries. Furthermore, any persons who manufacture such
substances may use the nomenclature presented in this addendum to report
for the Inventory if this nomenclature accurately describes the chemical
substances they manufacture.
-------
All chemical substances identified in this addendum, with the ex-
ception of those in Section I (multi-component Class 2 substances derived
from natural fats and oils or synthetic substitutes), are listed with
CAS Registry Numbers and EPA Code Designations, and may be reported on
Form A. The substances identified in Section I must be reported on Form
C according to the procedures outlined in that section.
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Section I
CLASS 2 CHEMICAL SUBSTANCES DERIVED FROM NATURAL
FATS AND OILS AND SYNTHETIC SUBSTITUTES
An Alternate Procedure for Substance
Identification and Reporting
for the Chemical Substance Inventory
General
This section presents an alternate and relatively simple procedure
for identifying and reporting certain multicomponent Class 2 chemical
substances derived from natural fats and oils and synthetic long-chain
alkyl substitutes. The procedure was developed by The Soap and Detergent
Association in conjunction with the EPA and is intended to standardize
the identification of substances manufactured and used extensively in
the soap and detergent industry. This standardization should provide
for easier and more certain reporting and recording of information for
these substances. Accordingly, the procedure may be used to report
multicomponent soaps and surface active agents (and also their precur-
sors and derivatives) manufactured, imported, or processed for such uses
as wetting agents, emulsifiers, dispersants, and penetrants. Its appli-
cability, however, should extend beyond the soap and detergent industry.
This procedure may not be used to report any single component Class
1 chemical substance (i.e., a substance whose composition may be repre-
sented by a definite chemical structure diagram) or any combination of
such substances prepared by mixing without chemical reaction. Further-
more, it should not be used in those cases where the person reporting
considers its applicability to be marginal or in question. Instead, the
conventional procedures should be followed for chemical substance identi-
fication and reporting, as specified in the EPA publication "Reporting
for the Chemical Substance Inventory" (December 1977).
The Class 2 chemical substances which may be reported following
procedures specified here are complex, multicomponent materials whose
individual components have a common structural feature: one or more
long-chain alkyl groups to which is attached a chemically functional
group or groups. These components differ from one another with respect
to one or more of the following long-chain alkyl group characteristics:
length (carbon number), saturation, structure (linear or branched),
and/or the position of functional group attachment(s).
Before 1950, most of these substances were derived commercially
from natural sources. However, synthetically-derived sources of similar
composition have since been developed and are presently used interchange-
ably with natural sources.
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Substance Identification
According to procedures specified in this section, certain of these
Class 2 chemical substances may be identified by systematically-derived,
chemically-descriptive SDA Substance Names. The proper SPA Substance
Name for each is that which most precisely describes the chemical comp-
osition of the substance. Each substance is reported on Inventory
Report Form C and identified only by the SDA Substance Name and special
SDA Reporting Number, and not in terms of source, blend, process, or
reaction information. During form processing, each substance reported
following this procedure will be assigned, a CAS Registry Number which
will appear on the Inventory with the SDA Substance Name and Reporting
Number and with substance synonyms, if reported.
SDA Substance Names consist of two or, in some cases, three parts.
The two parts common to all SDA Substance Names are: (1) the Alkyl
Descriptor, A, which describes the long-chain alkyl groups of the
substance, and (2) the Functionality Descriptor, F, which identifies the
functional group(s) of the substance. A third part, the Salt Descrip-
tor, S, identifies the cation(s) of any salt.
SDA Substance Names are systematically constructed according to the
following formats:
(A) alkyl (F),
or in the case of salts,
(A) alkyl (F)(S),
where A denotes the Alkyl Descriptor; F, the Func-
tionality Descriptor; and S, the Salt Descriptor.
For example, the SDA Substance Name for a fatty amine which contains
predominantly C _-C1 , saturated alkyl chain-lengths is:
C-.,,-C.., alkyl amine
where the phrase "Cin-C,ft" corresponds to the Alkyl
Descriptor (A), and amine", to the Functionality
Descriptor (F).
Similarly, the SDA Substance Name for the sodium salt of a fatty car-
boxylic acid comprised predominantly of C10 saturated and C.. „ unsatur-
, ,, - , . . lo ±o
ated alkyl chains is:
C, 0 and C,0 unsaturated alkyl carboxylic acid sodium salt
-Lo lo
where the phrase "C,Q and C.. „ unsaturated" corresponds to
the Alkyl Descriptor (A); "carboxylic acid", to the
Functionality Descriptor (F); and "sodium salt", to the
Salt Descriptor (S).
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The Class 2 chemical substances covered by this section are limited
to those whose composition may be described using the Alkyl, Function-
ality, and Salt Descriptors listed in Tables 1, 2, and 3, respectively.
These descriptors, discussed in detail below, may be combined in the SDA
Substance Name format to describe more than 5,000 multicomponent Class 2
chemical substances.
Alkyl Description
Table 1 lists the Alkyl Descriptors covered by this system of sub-
stance identification; assigned to each is a two-digit Alkyl Descriptor
Code used in generating the SDA Reporting Numbers, described later. Each
Descriptor identifies a distribution of alkyl groups in terms of carbon
chainlength, saturation and/or unsaturation, and linear or branched
structure. Alkyl group distributions are inclusive of both even and odd
alkyl chainlengths.
The Descriptors of Table 1 were chosen to cover the predominant
long-chain alkyl group distributions actually present in most commercial
multicomponent Class 2 substances of this type, and to provide for each
as precise a description as practical. Use of this procedure is predicated
on selecting the narrowest alkyl distribution (Alkyl Descriptor) which
describes the predominant long-chain alkyl groups of the substance
reported. In this context, the term "predominant" means that about 80
to 100 percent of all long-chain alkyl groups are included within the
description.
In the Alkyl Descriptor, a saturated, linear long-chain alkyl group
is denoted by "C " where the subscript x indicates the number of carbon
atoms in the alkyl chain. Unsaturated and multiple branched alkyl
groups are denoted by "C unsaturated" and "C branched", respectively.
X X
By convention, the number of carbon atoms in a long-chain alkyl
group includes all long-chain alkyl and functional group carbon atoms,
other than those contained in an aromatic ring, which are connected to
each other in a unbroken chain of carbon-carbon bonds. For example, the
alkyl chainlength, designated by "R" in the representative structural
diagrams found in Table 2, includes the acyl carbon of carboxylic acids
and their derivatives, and the total number of carbon atoms in such
structures as R-CH -OH or R-CH=CH . The alkyl group does not include,
however, functional group carbon atoms which are part of a phenyl ring,
or are separated from the alkyl chain by a phenyl group or an atom other
than carbon, e.g., R-^ , R-N(CH ) , or R-0(CH2) -NH-.
Unless specified otherwise, the alkyl groups identified by each
Alkyl Descriptor are linear, or essentially linear, hydrocarbon chains.
The natural fats and oils listed below provide such alkyl groups:
-------
Vegetable Animal Marine
Avocado Peanut Grease Herring
Babassu Rapeseed Lard Menhaden
Castor Rice Bran Neatsfoot Salmon
Coconut Safflower Poultry Sardine
Corn Safflower Tallow Sperm Body
Cottonseed (high oleic) (whale)
Crambe Sesame Sperm Head
Linseed Sorghum (whale)
Olive Soybean Whale
Oiticica Sunflower
Palm Tung
Palm-kernel Wheat Germ
These sources provide both saturated and unsaturated alkyl groups;
castor oil provides a C R hydroxy substituted alkyl group. Alkyl groups
derived from other natural sources are not covered by this procedure.
Synthetic sources can provide linear or essentially linear alkyl
groups, i.e., chain branching, if any, is limited to no more than one
secondary methyl (CH^-) or ethyl (C^H,--) group per alkyl chain. For
purposes of this section, the latter type of alkyl chain is included
within the designation "linear". Multiple branched alkyl groups, de-
rived exclusively from synthetic sources, have separate Alkyl Descriptors,
Some Class 2 chemical substances covered by this procedure are
comprised of components which have two or more long-chain alkyl groups,
e.g., (dialkyl) amdne, or (dialkyl) dimethyl ammonium chloride. This
procedure may be used to identity such substances provided that each
long-chain alkyl group is describable, in its predominant composition,
by an Alkyl Descriptor found in Table 1 and that none of these long-
chain alkyl groups is a single component structure describable by a
definite chemical structural diagram.
-------
Functionality Description and Substance Definition
Table 2 lists the Functionality Descriptors which may be used in
this procedure of substance identification; assigned to each is a three-
digit Functionality Descriptor Code used in generating SDA Reporting
Numbers. The partial chemical substance nomenclature (Functionality
Descriptors) for each identifies a specific functional group or groups.
Different Descriptors are provided for salts, and for their corresponding
acids.
Associated with each Functionality Descriptor in Table 2 is a
representative structural diagram or diagrams. In many cases, these
diagrams depict only one of several possible isomers of a substance
identified by a given Functionality Descriptor. For example, a C-|/""C]8
alkyl amine reported by this procedure may contain components which have
the amine functional group
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Reporting Instructions
Class 2 chemical substances identified following this procedure may
only be reported on Chemical Substance Inventory Report Form C. Although
substance synonyms may also be provided, the chemical substance need
only be identified by its SPA Substance Name and a systematically-
derived SPA Reporting Number. The SDA Reporting Number indicates that
the substance is being reported according to the procedure described
here and also serves as a redundancy check on the correctness of the
reported SDA Substance Name.
The SDA Reporting dumber is derived using the two- or three-digit
codes associated with each Alkyl, Functionality, or Salt Descriptor
contained in Tables 1 to 3. The SDA Reporting Number is generated by
systematically combining these codes for a given substance in a manner
similar to that used to derive the SDA Substance Name. SDA Reporting
Numbers have the following formats:
SDA aa-fff-ss
or for mixed salts of divalent anions,
SDA aa-fff-ss,s's'
where "aa" denotes the appropriate Alkyl Descriptor Code;
"fff", the appropriate Functionality Descriptor Code; and
"ss" (and "s's"1) the appropriate Salt Descriptor Code(s).
For example, the SDA Reporting Number for C -C.. , alkyl amine is:
SDA 15-029-00
This number was generated using the Descriptor Codes found in Tables 1
to 3. Table 1 identifies the Alkyl Descriptor Code for "C -^,": 15.
Table 2 identifies the Functionality Descriptor Code for "talkyl) amine":
029. Table 3 identifies the Salt Descriptor Code to be used when the
substance is not a salt: 00. Inserting these numbers in the standard
format yields the correct SDA Reporting Number.
A seven step method, described below for a specific example, is
useful in applying the nomenclature of this section to the identifica-
tion and reporting of particular chemical substances. Additional ex-
amples which further illustrate the applicability and limitations of the
procedure immediately follow Table 4.
INTRODUCTORY EXAMPLE
A fatty carboxylic acid is prepared by blending acids from various
sources which contain linear alkyl groups having even and odd carbon
numbers. The fatty acid is then reacted with sodium hydroxide to form
the sodium salt. The composition of the starting fatty acid is listed
below in terms of the percent by weight of each of its components.
-------
Component Alkyl Group % Composition
C0 saturated 0.5
o
C,n saturated 1.5
GI? saturated 7
C-,, saturated 5
14
Ciq. saturated 5
C,, saturated 10
ID
C17 saturated 10
Cno saturated 30
lo
C2n saturated 1.0
Cn, unsaturated 5
ID
C,0 unsaturated 25
lo
Step 1: Identify the Major Component Alkyl Groups
On a worksheet, list in the following format the alkyl groups which
correspond to the alkyl components in the starting ingredients. Include
the actual percentage by weight of each such component. As a practical
consideration, components present at less than two (2) percent by weight
need not be included.
Carbon Chainlength Distribution
% Composition*
7
5
5
10
10
30
5
25
*by weight of starting fatty acid.
NOTE: The C,,, C-,,, and C_» alkyl components of this example were
omitted because each is present at less than two percent by
weight.
Saturated Unsaturated
C12
C14
C15
C16
C17
C18
C16
C18
Branched
No
No
No
No
No
No
No
No
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Step 2: Identify the Most Appropriate Alkyl Descriptor
Select from Table 1 those Alkyl Descriptors which could conceivably
describe the predominant alkyl groups of the substance. Eliminate by
inspection those Alkyl Descriptors which are obviously inadequate for
reasons of alkyl chainlength, saturation and/or unsaturation, or struc-
ture. In this example, the Alkyl Descriptors for solely saturated,
solely unsaturated, or branched alkyl groups are clearly inappropriate
and are not considered. Other Alkyl Descriptors are not considered
because their chainlength distributions are not appropriate.
By such an analysis, the Alkyl Descriptors which correspond to
Alkyl Descriptor Codes 01, 04, and 11 are selected as candidates.
To determine the most appropriate Alkyl Descriptor from among
these candidates, construct the following table:
Alkyl
Desc.
Code
01
04
11
Components
Predominant Carbon Chainlength Within
Saturated Unsaturated Branched Category
Number Number
of Extra of Missing
Components Components
8-18
14-18
16-18
18
16-18
18
No
No
No
93%
90
75
5
1
0
1
1
4
The information entered under the Alkyl Descriptor Code and Predominant
Carbon Chainlength headings are taken from Table 1. The entries under the
other headings were calculated by the following methods:
Components Within Category: For each Alkyl Descriptor, add the
percentages of each alkyl component, listed in Table 1, whose long-
chain alkyl group is included within the specified distribution,
e.g., 90 percent of the components shown in Step 1 fall within
Alkyl Descriptor Code 04.
Number of Extra Components: For each Alkyl Descriptor, subtract
from the total number of long-chain alkyl groups of the specified
distribution those which appear in the actual alkyl composition,
e.g., for Alkyl Descriptor Code 04, only the GI unsaturated
group is absent from the actual alkyl composition.
Number of Missing Cotaponents: For each Alkyl Descriptor, subtract
from the total number of alkyl components in the actual composition
those which are included within the alkyl distribution specified
for the Alkyl Descriptor, e.g., only the C.. „ saturated alkyl compo-
nent of the actual composition is not included within Alkyl Descrip-
tor Code 04.
Analysis: By inspection of the table shown above, it is clear that the
Alkyl Descriptors which correspond to Codes 01 and 04 both adequately
encompass the predominant alkyl composition of the substance, i.e.,
greater than 80 percent of the actual alkyl composition is included
within the range of each of these alkyl distributions. The Alkyl
10
-------
Descriptor corresponding to Code 04 is selected, however, because this
Alkyl Descriptor includes the fewest extra and missing component alkyl
groups.
NOTE: This procedure for determining the most appropriate Alkyl
Descriptor should be followed only once for each unique alkyl
composition reported. It need not be repeated for functionality
variations involving the same alkyl composition.
Step 3: Select the Appropriate Functionality Descriptor
Refer to Table 2 and select the Functionality Descriptor which
identifies the functionality of the substance. In this example, the
appropriate Functionality Descriptor for a salt of a fatty carboxylic
acid corresponds to Code 006 .
Step 4: Select the Appropriate Salt Descriptor
Refer to Table 3 and select the Salt Descriptor (s) which identifies,
if appropriate, the cation (s) of the salt being reported. In this
example, the Salt Descriptor, for the sodium cation, corresponds to
Code 04.
Step 5 : Construct the SPA Reporting Number
Using the prefix SDA, and the Alkyl, Functionality, and Salt De-
scriptor Codes derived from steps 2 through 4, contruct the SDA Reporting
Number using the proper format:
SDA 04-006-04
Step 6: Construct the SDA Substance Name
In the appropriate format, construct the SDA Substance Name for the
chemical substance, using the nomenclature which corresponds to the
appropriate Descriptor Codes found in Tables 1 through 3, respectively.
In this example, the SDA Substance Name is:
^16~^18 unsaturated alkyl
carboxylic acid sodium salt.
Step 7: Complete Form C
Complete Blocks I through IV of Form C following the instructions
provided in the EPA publication "Reporting for the Chemical Substance
Inventory" (December 1977). In Block V, as shown below, enter the SDA
Substance Name in the space provided for the Specific Chemical Name.
Indicate that the substance is a Class 2 substance by checking the
appropriate box. Below the line labeled "Molecular Formula", enter the
SDA Reporting Number. Determine whether any other chemical substances
manufactured at the plant site are encompassed by this particular SDA
Substance Name and Reporting Number. If so, consider them all as a
single substance and enter the appropriate code digit in the box labeled
11
-------
"Production Range" which corresponds to their combined 1977 production
volume. If any of the substances are not site limited, make no check in
the box labeled "site limited". Finally, make all necessary confidentiality
claims by checking the appropriate boxes.
SAMPLE FORM C: BLOCK V
V. CHEMICAL SUBSTANCE WHERE THE IDENTITY IS CONFIDENTIAL (AND/OR) THE CAS REGISTRY NUMBER IS UNKNOWN
c~
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CAS REGISTRY
NUMBER
(IF KNOWN)
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SPECIFIC CHEMICAL _
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NAME
(SEPARATE MULTIPLE NAMES WITH A SEMI-COLON)
Cl4""C]_8 and Cj^-C-^g unsaturated alkyl carboxylic
acid sodium salt
TO
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A
IN THE SPACE PROVIDED BELOW, PROVIDE STRUCTURAL INFORMATION,
MOLECULAR FORMULA, AND OTHER SUPPLEMENTAL INFORMATION TO
AID IN THE SPECIFIC IDENTIFICATION OF THE CHEMICAL SUBSTANCE:
nSEE ATTACHED SHEETS
(WRITE FORM NO ON ALL
NO Of
MOLECULAR FORMULA b*"b ATTACHMENT)
SDA 04-006-04
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ACTIVITY
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-------
TABLE 1
Alkyl Descriptors
Alkyl
Descriptor Code
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
J. L. CUVJU1 XlldlLL.
Carbon Chainlength Distribution
Saturated Unsaturated Branched
8-18
10-16
14-18
14-18
14-18
14-18
14-22
16-22
16
16
16-18
18
6-12
8-26
10-16
12-18
14-18
14-26
16-18
16-18,18*
16-22
8
9
12
11-13
18
12-20
12-20
16-18
16-22
16-26
16-22
18
18
18,18*
18
18
10-16
14-18
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
No
Yes
Yes
Yes
Yes
No
No
Alkyl Descriptor (A) Nomenclature
CQ-C10 and Cno unsaturated
o lo 18
cin~Ci, and C -C- unsaturated
ID lo Iz ZU
C, ,-C
,
ID IZ ZU
-Cj- and Ci2~C20 unsaturated
C ,-Cno and C,,-C 0 unsaturated
14 18 Ib 18
C..-C. 0 and C.,-C-0 unsaturated
14 18 Ib Zz
C..-C „ and C.,-C_. unsaturated
14 18 lo ZD
C14~C22 and C16~C22 unsaturated
ci t~cio an(3 C. 0 unsaturated
ID zz lo
C. . and C1Q unsaturated
Ib 18
C, , plus C, „ unsaturated and
ID lo
hydroxy unsaturated
it
xo
', 0 unsaturated
lo
Cn,-C10 and C,_ unsaturated
lo 18 18
C,_ and C, _ unsaturated
VC12
C8-C26
C10~C16
C12-C18
C14-C18
C14-C26
C16-C18
C. ,-C10 and C. 0
ID lo lo
C16-C22
C0 branched
8
C branched
C branched
branched
Ci /-C,g unsaturated
*Hydroxy substituted alkyl group derived from Castor Oil
13
-------
TABLE 2
Functionality Descriptors
Func.
Desc.
Code
001
002
003
004
005
006
007
008
009
010
Oil
012
013
014
015
Functionality Descriptor (F)
Nomenclature
(trialkyl) glyceride
(alkyl) and (dialkyl) glyceride
(alkyl) and (dialkyl) glyceride
ethoxylate
(alkyl) glyceride
(alkyl) carboxylic acid
(alkyl) carboxylic acid (salt)
(alkyl) dicarboxylic acid
(alkyl) carboxylic acid n-butyl
ester
(alkyl) carboxylic acid 2-
ethylhexyl ester
(alkyl) carboxylic acid methyl
ester
(dialkyl) carboxylic acid
ethylene glycol diester
(alkyl) dicarboxylic acid 2-
ethylhexyl diester
(alkyl) dicarboxylic acid
hexyl diester
(trialkyl) carboxylic acid
trimethylolethane triester
(trialkyl) carboxylic acid
trimethylolpropane triester
Common Name Representative Structural Diagram3
0
II
refined fat or oil R-C-O-CH 0
i ^ ii
0 HC-O-C-R
n t
R-C-0-CH2
0 0
ii M
R-C-O-CH, R-C-O-CH, 0
i ' i l n
HCOH HC-O-C-R
t >
HOCH2 HOCH2
0 0
ti n
R-C-0-CH2 R-C-0-CH2 0
HCO-(CH,CH,0) -H HC-O-C-R
i z. z n ,
0
11
R-C-O-CH
HCOH
i
HOCH2
0
fatty acid R-C-OH
0
soap R-C-ONa
0 0
n ii
fatty dibasic acid HO-C-R-C-OH
0
II
fatty butyl ester R-C-0-(CH,,) ,CH,
0 CH CH,
n t z J
fatty 2- ethylhexyl R-C-O-CH CH(CH ) CH
0
n
fatty methyl ester R-C-O-CH
0 0
II "
fatty ethylene glycol R-C-0-(CH2)2~ 0-C-R
diester
0 CH2CH3
fatty 2-ethylhexyl R-(C-0-CH2-CH-(CH2)3-CH3)2
diester
fatty hexyl diester R-(K-0-(CH2)5-CH3)2
0 CH, 0
n r ^ n
R-C-O-CH CCH -0-C-R
CH -0-C-R
*- H
0
0 CH.CH, 0
M t *• -> n
R-C-0-CH2CCH2-0-C-R
CH, -0-C-R
^ n
0
Substance
Definition
Format^
1
1
2
n
1
1
1
1
1
1
1
1
1
1
1
1
Salts are depicted in terms of sodium cation(s).
Refer to corresponding Substance Definition Format number (1-6) in Table 4.
-------
0
016 (tetraalkyl) carboxylic acid
pentaerythritol tetraester
0 CH--0-C-R
n i z
R-C-O-CH CCH -0-C-R
2, £ n
R-C-0-CH2 0
017
018
019
020
(alkyl) carboxylic acid
ethoxylate
(alkyl) carboxylic acid
propoxylate
(alkyl) carboxylic acid
ethoxylate propoxylate
ethoxylated fatty
acid
propoxylated fatty
acid
ethoxylated propoxyl-
ated fatty acid
R-C-0-(CH CH20)n-H
0 CH,
H i J
R-C-0-(CHCH20)n-H
CH
i J
(alkyl) carboxylic acid amide fatty amide
0
R-C-NH
021 (alkyl) carboxylic acid amide
ethoxylate
ethoxylated fatty
amide
X(CH CH 0) -H
R-C-N
022 (alkyl) carboxylic acid amide
monoethanol
023 (alkyl) carboxylic acid amide
monoisopropanol
024 (alkyl) carboxylic acid amide
diethanol
025 (alkyl) carboxylic acid amide
diisopropanol
026 (alkyl) carboxylic acid amide
(alkyl)
monoethanol fatty
amide
monoisopropanol
fatty amide
diethanol fatty
amide
diisopropanol fatty
amide
^ ^CH CH OH
R-C-NH
° _,CH2CHOH
R-C-NH CH3
° XCH CH OH
R-C-N
CH3
° XCH CHOH
R-C-N
XCH2CHOH
CH,
0
R-C-NH-R
027 N,N'-(dialkyl) ethylene bis
amide
028 N,N'-(dialkyl) propylene bis
amide
R-C-NH(CH2)2-NH-C-R
R-C-NH( CH2 ) 3-NH-C-R
029 (alkyl) amine
fatty amine
R-NH0
030 (alkyl) amine ethoxylate
ethoxylated fatty
amine
R-N .
031 (alkyl) amino ethylene nitrile fatty amine nitrile
R-NH-(CH2)2C«N
032 N-(alkyl) propylene diamine
R-NH-(CH2)3-NH2
033 N-(alkyl) propylene diamine
ethoxylate
/CH CH 0) H
R-N ^ J(CH CH 0) H
X(CH ) -N V
S
034 (alkyl) alkoxy ethylene nitrile fatty ether nitrile
R-0-(CH2)2-C=N
035 (alkyl) alkoxy propylene amine
036 (alkyl) alkoxy propylene amine
ethoxylate
037 (alkyl) alkoxy ethylene amino
nitrile
038 (alkyl) alkoxy propylene amine
propylene amine
R-0-(CH2)3-NH2
R-O-CCH ) -N
/(CH2CH20)nH
X(CH,CH,0) H
22m
fatty ether amino
nitrile
R-0-(CH2)3-NH-(CH2)2-CsN
fatty ether diamine R-0-(CH2)3-NH-(CH2)3~NH2
-------
039 (alkyl) nitrile
fatty nitrile
R-CSN
040 (alkyl) dimethyl amine
fatty dimethyl amine
041 (alkyl) dimethyl amine oxide
fatty dimethyl amine R-N->0
oxide '
042 (dialkyl) amine
dialkyl amine
NH
043 (dialkyl) methyl amine
044 (trialkyl) amine
dialkyl methyl amine N-CH
trialkyl amine
N-R
045 (alkyl) trimethyl ammonium
chloride
046 (alkyl) trimethyl ammonium
bromide
047 (dialkyl) dimethyl ammonium
chloride
048 (dialkyl) dimethyl ammonium
bromide
alkyl trimethyl
ammonium chloride
alkyl trimethyl
ammonium bromide
CH3
V^
dialkyl dimethyl
ammonium chloride I R'
dialkyl dimethyl
ammonium bromide
Cl
Br
Cl
Br
049 (dialkyl) dimethyl ammonium
methyl sulfate
050 (trialkyl) methyl ammonium
chloride
051 (trialkyl) methyl ammonium
bromide
052 (alkyl) benzyl dimethyl
ammonium chloride
053 (dialkyl) benzyl methyl
ammonium chloride
dialkyl dimethyl am-
monium methyl sul-
fate
j
[R R ]
LRXCH J
Cl
Br
Cl
Cl
054 (trialkyl) benzyl ammonium
chloride
Cl
055 (alkyl) chloride
056 (alkyl) bromide
057 (alkyl) alpha olefin
alkyl chloride
alkyl bromide
alpha olefin
RCH2-C1
RCH -Br
R-CH=CHn
058 (alkyl) alkene and (alkyl)
hydroxy sulfonic acid
059 (alkyl) alkene and (alkyl) olefin sulfonate
hydroxy sulfonic acid (salts)
R(CH ) CH=CH(CH ) -SO-H ,
/ x z y j
R(CH7) CH(CH?) -SO H
^ x( / y j
OH
R(CH2) CH=CH(CH ) -SO Na
R(CH,) CH(CH9) -SO Na
Z X, L y J
OH
-------
060 (alkyl) alcohol fatty alcohol R-CH2-OH 3
061 (alkyl) alcohol sulfuric acid R-CH2-OS03H 3
062 (alkyl) alcohol sulfuric acid alkyl sulfate R-CH,-OSO Na 3
(salt)
063 (alkyl) alcohol phosphoric acid R-CH -OPO.H 3
06A (alkyl) alcohol phosphoric acid alkyl phosphate ester R-CH -OPO Na 3
(salt) l J l
065 (alkyl) alcohol ethoxylate ethoxylated fatty R-CH -0-(CH2CH 0) -H 4
alcohol
066 (alkyl) alcohol ethoxylate R-CH2-0-(CH2CH20) -S03H 4
sulfuric acid
067 (alkyl) ethoxylate sulfuric ethoxylated alkyl R-CH,-0-(CH,CH 0) -SO,Na 4
acid (salt) sulfate Z i n J
068 (alkyl) alcohol ethoxylate R-CH2-0-(CH2CH20)n-P03H2 4
phosphoric acid
069 (alkyl) alcohol ethoxylate ethoxylated alkyl R-CH -0-(CH CH20) -PO Na2 4
phosphoric acid (salt) phosphate ester
™3
070 (alkyl) alcohol ethoxylate ethoxylated propoxy- R-CH -0-(CH2CH20) (CHCH 0) -H 4
propoxylate lated fatty alcohol
<;H3
071 (alkyl) alcohol ethoxylate R-CH0-0-(CH,CH.O) (CHCH.O) -SO,H 4
, , , . . , ^ / z n z m 3
propoxylate sulfuric acid
CH3
072 (alkyl) alcohol ethoxylate pro- ethoxylated propoxy- R-CH -0-(CH2CH 0) (CHCH-O) -SO Na 4
poxylate sulfuric acid (salt) lated alkyl sulfate
f3
073 (alkyl) alcohol ethoxylate pro- R-CH0-0-(CH0CH00) (CHCH.O) -PO.Hn 4
, ..... L z/n/m32
poxylate phosphoric acid
CH.
i J
074 (alkyl) alcohol ethoxylate pro- ethoxylated propoxy- R-CH2~0-(CH CH 0) (CHCH20) -PO Na 4
poxylate phosphoric acid lated alkyl phos-
(salt) phate ester
OH
075 (alkyl) glyceryl ether chloride R-0-CH2CHCH2-C1 3
A
076 (alkyl) glycidyl ether R-0-CH2CHCH 3
OH
077 (alkyl) glyceryl ether sulfonic fatty glycerol sul- R-O-CH CHCH2-SO Na 3
acid (salt) fonate
fl
078 (alkyl) epoxide R-CHCH 1
079 (alkyl) benzene LAB CH3(CH2)xCH(CH2) CH 3
080 (alkyl) benzene sulfonic acid CH (CH ) CH(CH,) CH
o z x i z y o
0
081 (alkyl) benzene sulfonic acid LAS CH (CH.) CH(CH9) CH,
(salt) 3 2 ^ 2 y 3
-------
082 (alkyl) phenol
linear alkyl phenol CH3(CH ) CH(CH.) CH.
2 X, I y 6
083 (alkyl) phenol ethoxylate
i
OH
ethoxylated linear CH,(CH,) CH(CH7) CH
alkyl phenol *• y J
084 (alkyl) phenol ethoxylate
sulfuric acid
085 (alkyl) phenol ethoxylate sul-
furic acid (salt)
0(CH0CH,0) H
2. <• n
CH3(CH2) CH(CH2) CH3
o
0(CH0CH,0) -SO,H
2. I- n j
ethoxylated linear CH -(CH,,) CH(CH ) CH
alkyl phosphate ' y
ester
086 (alkyl) phenol ethoxylate
phosphoric acid
) CH
087 (alkyl) phenol ethoxylate phos-
phoric acid (salt)
ethoxylated linear
alkyl phosphate
ester
0(CH.CH,0) -PO_H_
t Z n J £
CH3(CH2)xCH(CH2) CH3
088 (alkyl) phenol ethoxylate
propoxylate
089 (alkyl) phenol ethoxylate pro-
poxylate sulfuric acid
ethoxylated propoxy- CH,(CH2) CH(CH ) CH
lated linear alkyl ^
phenol (^]1 CH3
0(CH,CH00) (CHCH-0) H
J 2. n 2. m
CH3(CH2)xCH(CH2) CH
0(CH.CH00) (CHCH,0) SO H
2. 2. n ^ m J
090 (alkyl) phenol ethoxylate pro- ethoxylated propoxy- CH3(CH2) CH(CH2) CH
poxylate sulfuric acid (salt) lated alkyl phenol JL
sulfate l^j!
CH3
0(CH0CH00) (CHCH,0) SO,Na
2. £ n £ tn J
091 (alkyl) phenol ethoxylate pro-
poxylate phosphoric acid
092 (alkyl) phenol ethoxylate pro- ethoxylated propoxy-
poxylate phosphoric acid (salt) lated linear alkyl
phenol phosphate
ester
(I!) CH3
i i
0(CH0CH00) (CHCH,0) PO,H
2. 2. n t- m ~> *•
CH(CH-).
2
CH3
093 (dialkyl) phenol
linear dialkyl phenol
i
OH
09A (dialkyl) phenol ethoxylate ethoxylated linear ^j)
dialkyl phenol ,
095 (branched alkyl) benzene
AB
R(branched).
-------
096 (branched alkyl) benzene sul-
fonic acid
R(branched)^fX
097 (branched alkyl) benzene
sulfonic acid (salt)
ABS
R (branched)
"SO Na
098 (branched alkyl) phenol
branched alkyl phenol
R(branched)-I
-------
109 (branched dialkyl) phenol
branched dialkyl phenol
R (branched) -if*j- R (branched)
OH
110 (branched dialkyl) phenol
ethoxylate
ethoxylated branched
dialkyl phenol
R(branched)
0(CH.CH 0) H
2 Z n
111 (alkyl) and (dialkyl) phenoxy
benzene sulfonic acid
SO,H
/ 3
112 (alkyl) and (dialkyl) phenoxy
benzene sulfonic acid (salt)
SO.,Na
/ 3
SO Na
/ J
R-Q-°-G • R-
SO Na
SO Na
113 (branched alkyl) and (branched
dialkyl) phenoxy benzene
sulfonic acid
S03H
SO.H
/ j
114 (branched alkyl) and (branched
dialkyl) phenoxy benzene
sulfonic acid (salt)
R(br.)-Q-0-p , R(br.)-Q-0-p-R(br.)
SO Na
115 (alkyl) alpha and (alkyl)
internal oletin
R-CH=CH2 ,
20
-------
TABLE 3
Salt Descriptors
Salt Salt Descriptor (S)
Descriptor Code nomenclature
00 (none)
01 ammonium salt
02 lithium salt
03 potassium salt
04 sodium salt
05 barium salt
06 calcium salt
07 magnesium salt
08 nickel salt
09 zinc salt
10 aluminum salt
11 titanium salt
12 monoethanol amine salt
13 diethanol amine salt
14 triethanol amine salt
21
-------
TABLE 4
Chemical Substance Identification
with Examples
Substance
Definition Format
SDA
Reporting Number
SDA
Substance Name
Substance Definition
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
The combination of alkyl (F)(S) having
predominantly (A) alkyl chainlengths that
generally conform to the following struc-
tural diagram:
Insert the Representative Struc-
tural Diagram from Table 2 which
corresponds to F; indicate pro-
per salt form(s), if applicable.
EXAMPLES:
SDA 13-006-04
C,-C.. alkyl carboxylic
acid sodium salt
The combination of alkyl carboxylic acid
sodium salts having predominantly C,-C._
alkyl chainlengths that generally conform
to the following structural diagram:
SDA 13-093-00
C,-C.
b i
0
R-C-ONa
dialkyl phenol The combination of dialkyl phenols having
predominantly C,-C „ alkyl chainlengths
that generally conform to the following
structural diagram:
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
The combination of alkyl (F)(S) having pre-
dominantly (A) alkyl chainlengths and ethox-
ylate and/or propoxylate homologues (as ap-
propriate) that generally conform to the
following structural diagram:
Insert the Representative Struc-
tural Diagram from Table 2 which
corresponds to F; indicate pro-
per salt form(s) , if applicable.
EXAMPLE:
SDA 13-017-00
C,-C alkyl carboxylic
acid ethoxylate
The combination of alkyl carboxylic acid
ethoxylates having predominantly C,-C
alkyl chainlengths and ethoxylate homo-
logues that generally conform to the fol-
lowing structural diagram:
R-C-0-(CH2CH20)n-H
22
-------
TABLE 4 (continued)
Substance
Definition Format
SDA
Reporting Number
SDA
Substance Name
Substance Definition
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
EXAMPLE:
SDA 13-060-00
C6~C12
alcohol
The combination of alkyl (F)(S) having
predominantly (A) alkyl chainlengths that
generally conform to, or are positional
isomers of, the following structural dia-
gram:
Insert the Representative Struc-
tural Diagram from Table 2 which
corresponds to F; indicate pro-
per salt form(s), if applicable.
The combination of alkyl alcohols having
predominantly C,-C.,2 alkyl chainlengths
that generally conform to, or are posi-
tional isomers of, the following struc-
tural diagram:
R-CH2-OH
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
EXAMPLE:
SDA 13-030-00
C6~C12 alkyl amine
ethoxylate
The combination of alkyl (F)(S) having
predominantly (A) alkyl chainlengths and
ethoxylate and/or propoxylate homologues
(as appropriate) that generally conform
to, or are positional isomers of, the
following structural diagram:
Insert the Representative Struc-
tural Diagram from Table 2 which
corresponds to F; indicate pro-
per salt form(s), if applicable.
The combination of alkyl amine ethoxylates
having predominantly C.-C^ alkyl chain-
lengths and ethoxylate homologues that
generally conform to, or are positional
isomers of, the following structural dia-
gram:
R-N
(CH2CH20)nH
S
23
-------
TABLE 4 (continued)
Substance
Definition Format
SDA
Reporting Number
SDA 00-000-00
SDA
Substance Name
(A) alkyl (F) (S) or
(A) alkyl (F)
EXAMPLE:
SDA 24-095-00
Cj- branched alkyl
benzene
Substance Definition
The combination of alkyl (F)(S) posi-
tional isomers having predominantly (A)
alkyl chainlengths that generally conform
to the following structural diagram:
Insert the Representative Struc-
tural Diagram from Table 2 which
corresponds to F; indicate pro-
per salt form(s), if applicable.
The combination of alkyl benzene posi-
tional isomers having predominantly C. -
branched alkyl chainlengths that generally
conform to the following structural dia-
gram:
R(branched)
e-g
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
EXAMPLE:
SDA 24-099-00
C.- branched alkyl
phenol ethoxylate
The combination of alkyl (F) (S) having
predominantly (A) alkyl chainlengths and
ethoxylate and/or propoxylate homologues
(as appropriate) that generally conform
to, or are positional isomers of, the
following structural diagram:
Insert the Representative Struc-
tural Diagram from Table 2 which
corresponds to F; indicate pro-
per salt form(s), if applicable.
The combination of alkyl phenol ethoxy-
lates having predominantly C, branched
alkyl chainlengths and ethoxylate homo-
logues that generally conform to, or are
positional isomers of, the following
structural diagram:
R(branched
e-g
24
-------
ILLUSTRATIVE EXAMPLES
The examples listed below illustrate the applicability and limitations
of this method. Where appropriate, the examples are treated by the seven
step procedure outlined in the Reporting Instructions.
EXAMPLE 1
A mixture of synthetically derived saturated C-. „ through C.. „ linear
alcohols is reacted with ethylene oxide to manufacture the ethoxylated
alcohol.
jtep 1: The distribution of alkyl chainlengths in the starting fatty alcohol
is determined to be:
Carbon Chainlength Distribution
Saturated Unsat. Branched
% Composition*
1
No
No
No
No
20
30
30
20
Step 2:
* by weight of starting fatty alcohol
The following table lists those Alkyl Descriptors which should
be considered:
Alkyl
Desc.
_Cpd e
14
15
16
17
18
Predominant Carbon Chainlength
Saturated Unsaturated Branched
8-26
10-16
12-18
14-18
14-26
No
No
No
No
No
Components
Within
Category
100%
80
100
80
80
Number
of Extra
Components
6
1
0
0
4
Number
of Missing
Components
0
1
0
1
1
Since the alcohol contains only even chainlengths, only the possible even
chainlenths are considered.
25
-------
Analysis: Alkyl Descriptors 14 and 16 include the same percentage
of components of the fatty alcohol (100 percent) within the
range of the descriptors. However, Descriptor 16 includes the
highest percentage of components with the fewest additional or
missing components. Therefore, Alkyl Descriptor 16 is most
representative of the alkyl composition.
Step 3: Referring to Table 2, the Functionality Descriptor for an
ethoxylated fatty alcohol is 065.
Step 4: Referring to Table 3, the appropriate Salt Descriptor is 00, since
the substance is not a salt.
Step 5: Construct the SDA Reporting Number by sequentially combining the
codes derived in steps 2, 3 and 4:
SDA 16-065-00
Step 6: Following the standard format, construct the SDA Substance Name
using the descriptor nomenclature, found in Tables 1 through 3,
which corresponds to each descriptor code:
C10-Cno alkyl alcohol ethoxylate
I/ lo
Step 7: Complete Form C, taking into account all the individual chemical
substances which are encompassed by this SDA Substance Name and
Reporting Number.
EXAMPLE 2
A manufacturer reacts a mixture of linear synthetic C1 ?-C, s alcohols
with ethylene oxide and propylene oxide to form the ethoxytatea, propoxylated
alcohol.
Step 1: The distribution of alkyl chainlengths in the starting fatty
alcohol is determined to be:
Carbon Chainlength Distribution
Saturated Unsat. Branched % Composition*
C12 — No 20
C13 — No 30
C, . — No 30
14
C — No 20
* by weight of starting fatty alcohol
Step 2: The following table lists those Alkyl Descriptors which should
be considered:
26
-------
Alkyl
Desc.
Code
14
15
16
Components
Predominant Carbon Chainlength Within
Saturated Unsaturated Branched Category
8-26
10-16
12-18
No
No
No
100
100
100
Number Number
of Extra of Missing
Components Components
15
3
3
0
0
0
Step 6:
Step 7:
Since the alcohol contains both even and odd chainlengths,
all chainlengths are considered.
Analysis: All three Alkyl Descriptors (14, 15, 16) include the
same percentage of components of the starting fatty alcohol.
Alkyl Descriptors 15 and 16, however, both provide the fewest
additional or missing components. Although either descriptor
is applicable based on the previous analysis, Alkyl Descriptor
15 is preferred, since it provides a better technical descrip-
tion of the alkyl composition, i.e., the fatty alcohol composi-
tion is nearer the center of the range provided by Alkyl
Descriptor 15.
Referring to Table 2, the Functionality Descriptor for an ethoxylated
propoxylated fatty alcohol is 070.
Referring to Table 3, the appropriate Salt Descriptor is 00, since
the substance is not a salt.
Construct the SDA Reporting Number by sequentially combining the
codes derived in Steps 2, 3, and 4:
SDA 15-070-00
Following the standard format, construct the SDA Substance Name
using the descriptor nomenclature, found in Tables 1 through 3,
which corresponds to each descriptor code:
C, ft-C-, r alkyl alcohol ethoxylate propoxylate
Complete Form C, taking into account all the individual chemical
substances which are encompassed by this SDA Substance Name and
Reporting Number.
EXAMPLE 3
A manufacturer blends two linear synthetic alcohol mixtures, and then
reacts them with ethylene oxide and propylene oxide, forms the phosphate
acid ester by reaction with polyphosphoric acid and finally neutralizes with
a combination of potassium hydroxide and sodium hydroxide.
Step 1: The distribution of alkyl chainlengths in the starting saturated,
linear fatty alcohol is determined to be:
27
-------
Alkyl Chainlength
C10
C12
C14
C16
C-,0
C10 C14
Alcohol
85
8
6
0
0
C12 C18
Alcohol
0
20
•30
30
20
4:1 Blend
% Composition
68.0
10.4
10.8
6.0
4.0
Step 2:
* by weight of starting fatty alcohols
The following table lists those Alkyl Descriptors which should
be considered:
Alkyl
Desc.
Code
13
14
15
Predominant Carbon Chainlength
Saturated Unsaturated Branched
6-12 — No
8-26 — No
10-16 — No
Components
Within
Category
78.4
99.2
95.2
Number
of Extra
Components
2
5
0
Number
of Missing
Components
3
0
1
Analysis: Alkyl Descriptors 14 and 15 include essentially the same
percentage of alkyl components within the descriptor ranges. Alkyl
Descriptor 15 is selected because it includes the fewest additional
or missing components.
Step 3: Referring to Table 2, the Functionality Descriptor for ethoxylated
propoxylated alkyl phosphate ester is 074.
Step 4: Referring to Table 3, the appropriate Salt Descriptor is 03, 04,
since it is a mixed potassium salt and sodium salt of the
divalent alkyl phosphoric acid anion.
NOTE: Mixed salts should be reported in terms of the indivi-
dual components for salts of monovalent anions. For example,
for the mixed sodium and potassium salts of a C1 n-C-. , alkyl
carboxylic acid, report separately the sodium salt t§DA 15-
006-04) on Form C and the potassium salt (SDA 15-006-03) on
a separate Form C.
Step 5: Construct the SDA Reporting Number by sequentially combining the
codes derived in steps 2, 3, and 4:
SDA 15-074-03,04
Step 6: Following the standard format, construct the SDA Substance Name
using the descriptor nomenclature, found in Tables 1 through 3,
which corresponds to each descriptor code:
Cin-C , alkyl alcohol ethoxylate propoxylate phosphoric acid
potassium and sodium salt
Step 7: Complete Form C, taking into account all the individual chemical
substances which are encompassed by this SDA Substance Name and
Reporting Number.
-------
EXAMPLE 4
As an aid in reporting natural fats and oils, the sources covered
in the addencum are listed below, together with the Alkyl Descriptor
Codes, which, in most instances, should be appropriate;
Source
Avocado
Babassu
Castor
Coconut
Corn
Cottonseed
Crambe
Grease (animal)
Herring
Lard
Linseed
Menhaden
Neatsfoot
Olive
Oiticica
Palm
P.alm-kernal
Peanut
Alkyl
Descriptor
Code
9
1
J.
10
1
11
11
7
4
4
4
11
5
4
11
11
11
1
8
Source
Poultry
Rapeseed
Rice Bran
Safflower
Safflower
(high oleic)
Salmon
Sardine
Sesame
Sorghum
Soybean
Sperm Body
Sperm Head
Sunflower
Tallow
Tung
Whale
Alkyl
Descriptor
Code
4
11
11
11
9
5
5
11
11
11
3
2
11
4
9
5
The indicated Alkyl Descriptors may be used to describe the alkyl chain-
lengths of the natural sources unless they have been fractionated or
combined with other materials.
EXAMPLE 5
Stearyl amine is reacted with fatty acids to form an amide.
Step 1: The distribution of alkyl chainleugths in the fatty acids is
determined to be:
Carbon Chainlength Distribution
Saturated Unsat. Branched
No
No
No
No
No
'16
% Composition*
2.5
25.0
18.0
3.0
50.5
Step 2:
* by weight of starting fatty acids
It is obvious by inspection, without generating a table, that
Alkyl Descriptor Code 04 provides a perfect descriptor.
-------
Step 3 : Because stearyl amine (C „ saturated alkyl amine), a Class 1
chemical substance, is used as one of the reactants, the manufactured
substance in this example must be reported according to the normal
method for reporting Class 2 chemical substances with no known
CAS Registry Number. The SDA method may be used, however, to
define the fatty acid reactant. Referring to Table 2, the
Functionality Descriptor for the fatty acid is 005.
Step 4: Referring to Table 3, the appropriate Salt Descriptor for the
fatty acid is 00, because the substance is not a salt.
Step 5: Construct the SDA Reporting Number by sequentially combining the
codes derived in steps 2, 3 and 4.
SDA 04-005-00
Step 6: Following the standard format, construct the SDA Substance Name
using the descriptor nomenclature, found in Tables 1 through 3,
which corresponds to each descriptor code.
Cn.-C10 and Cn,-C10 unsaturated alkyl carboxylic acid
14 lo ID lo
Step 7 : On Form C, in the space provided for structural and other sup-
plemental information, enter the following reaction description:
Stearyl amine +
124-30-1
(CAS Reg. No.)
and C^g-C^g unsaturated alkyl carboxylic acid
SDA 04-005-00
Cn.-C10 and C., ,-Cn 0 unsaturated alkyl stearyl amide
14 lo lo lo
Note: If the alkyl amine reactant had been a Class 2 chemical
substance repor table using this method, the reaction
product could could be reported using Functionality
Descriptor 026: (alkyl) carboxylic acid amide (alkyl) .
EXAMPLE 6
A manufacturer hydrogenates an alkyl nitrile and then alkylates it
to form a dialkyl amine which is then reacted with methyl chloride to
form a quaternary ammonium chemical substance.
Step 1: The alkyl nitrile and the alkylating agents are separately described
by Alkyl Descriptors found in Table 1. Hence, their alkyl compo-
sitions may be combined and the SDA method may be used. The distri-
bution of alkyl chainlengths in the linear fatty reactants is deter-
mined to be:
30
-------
Alkyl Chainlength
C12
C14
C16
C18
Cn 0 unsaturated
lo
Nitrile
25
40
35
Alkylating Agent
40
30
30
% Composition*
12.5
20
37.5
15
15
"by weight of the combination of alkyl nitrile and alkylating
agent
Step 2: The following table lists those Alkyl Descriptors which should
be considered:
Alkyl
Desc.
Code
01
02
03
04
05
06
07
08
Components
Predominant Carbon Chainlength Within
Saturated Unsaturated Branched Category
8-18
10-16
14-18
14-18
14-18
14-18
14-22
14-22
18
12-20
12-20
16-18
16-22
16-26
16-22
18
No
No
No
No
No
No
No
No
Number Number
of Extra of Missing
Components Components
100
85
87.
87.
87.
87.
87.
87.5
2
5
4
1
3
5
5
2
0
1
1
1
1
1
1
2
Analysis: Alkyl Descriptor 01 includes the highest percentage of
components (100 percent). Alkyl Descriptor 04 includes a somewhat
lower percentage of components, but has the same total number of
additional and missing components as Descriptor 01. Because of
the higher precentage of components, Descriptor 01 is selected.
Step 3 : Referring to Table 2, the Functionality Descriptor for dialkyl
dimethyl ammonium chloride is 047.
Step 4; Referring to Table 3, the appropriate Salt Descriptor is 00,
since the substance is not a salt.
Step 5: Construct the SDA Reporting Number and subsequently combining
the codes derived in steps 2, 3, and 4:
SDA 01-047-00
31
-------
Step 6: Following the standard format, construct the SDA Substance
Name using the descriptor nomenclature found in Table 1 through
3, which corresponds to each descriptor code:
Cg-C-,0 and C-,g unsaturated dialkyl dimethyl ammonium chloride
Step 7: Complete Form C, taking into account all the individual chemical
substances which are encompassed by this SDA Substance Name and
Reporting Number.
EXAMPLE 7
The still bottoms from the distillation of the alcohol described
in Example 2 are sold for use in a lubricant.
Step 1: The composition varies and is not well defined. Therefore, it
cannot be represented in terms of alkyl composition, etc.
Step 2: Referring back to Example 2, Alkyl Descriptor 15 was selected
to describe the alkyl composition.
Step 3: Although this variable composition is not included in Table 2,
the Functionality Descriptor for the fatty alcohol is 060.
Step 4: Although this variable composition is not included in Table 3,
the Salt Descriptor is 00.
Step 5: The Reporting Number for the fatty alcohol is SDA 15-060-00.
Step 6: The Substance Name for the fatty alcohol is C -C , alkyl
alcohol. 10 16
Step 7: On Form C, in the space provided for structural and other sup-
plemental information, enter the following description:
Still bottoms from distillation of SDA 15-060-00,
(C10-C16 alkyl alcohol).
NOTE: Since the chemical substance is distributed in com-
merce, it must be reported. The variable composition of
this material can be reported using the appropriate pre-
cursors as defined by this addendum.
EXAMPLE 8
A manufacturer distills a blend of linear saturated fatty acids to
obtain a relatively pure dodecyl (C „) fatty acid. The fatty acid is re-
acted to form a methyl ester.
32
-------
Step 1: Since the fatty acid is a single chainlength without any isomeric
variations, the Alkyl Descriptors are not appropriate. Instead,
Form A, Form B, or Form C should be considered for reporting
this Class 1 chemical substance, depending on whether the sub-
stance appears on the Candidate List or has a CAS Registry
Number.
NOTE: If the fatty acid reactant had been a complex combination
of chainlengths, this system would have been applicable.
Steps
2 - 7: These steps are not appropriate in view of the conventional re-
reporting which is required.
33
-------
SECTION II
COKE AND SELECTED COAL CHEMICALS
Developed in Conjunction
with the
American Coke and Coal Chemicals Institute
Coke (Coal) [*e599P-77-2] HOOO-0189
The cellular carbonaceous mass resulting from the high
temperature (greater than 700CC) destructive distillation
of coal. Composed primarily of carbon. May contain varying
amounts of sulfur anc ash.
Coke Oven Light Oil (Coal) [*e599G-78-3] HOOO-0205
Synonyms: Light Oil (Coal), Intermediate Light Oil (Coal),
Crude Light Oil (Coal)
The volatile organic liquid extracted from the gas
evolved in the high temperature (greater than 700°C) destructive
distillation of coal. Composed primarily of benzene, toluene,
and xylenes. May contain other minor hydrocarbon constituents.
Solvent Naphtha (Coal) [*C5996-79-4] HOOO-0314
The distillate from either High Temperature Coal Tar,
Coke Oven Light Oil, or Coal Tar Oil Alkaline Extract Residue
having an approximate distillation range of 130°C to 210°C.
Composed primarily of indene and other polycyclic ring systems
containing a single aromatic ring. May contain phenolic compounds
and aromatic nitrogen bases.
Ammonia Liquor (Coal) [*P5996-80-7] HOOO-0422
The dilute aqueous solution extracted from the gas evolved
in the high temperature (greater than 700°C) destructive
distillation of coal. Composed primarily of ammonium carbonate
and other ammonium salts. May contain other water-soluble
substances including phenol.
-------
Coke Oven Gas (Coal) [*65996-81-8] HOOO-0531
The gas evolved from the high temperature (greater than
700CC) destructive distillation of coal after the removal of
High Temperature Coal Tar, Coke Oven Light Oil, and Ammonia
Liquor. Composed primarily of hydrogen and methane. May
contain ammonia, hydrogen sulfide, and low molecular weight
hydrocarbons.
Coal Tar Oil [*65996-82-9] H000-0o55
Synonyms: Chemical Oil (Coal), Tar Acid Oil (Coal)
The distillate from High Temperature Coal Tar having
an approximate distillation range of 130° to 250°C. Composed
primarily of naphthalene, alkylnaphthalenes, phenolic
compounds, and aromatic nitrogen bases.
Coal Tar Oil Alkaline Extract [*G5996-83-0] H000-0?6l
Synonym: Chemical Oil Alkaline Extract (Coal)
The extract from Coal Tar Oil produced by an alkaline
wash such as aqueous sodium hydroxide. Composed primarily
of the alkali salts of various phenolic compounds.
Crude Coal Tar Bases [*65996-84-l] HOOO-0879
The reaction product obtained by neutralizing Coal Tar
Base Extract Oil with an alkaline solution, such as aqueous
sodium hydroxide, to obtain the free bases. Composed primarily
of a complex combination of pyridine, quinoline, and their
alkyl derivatives.
Crude Coal Tar Acids [*65996-85-2] HOOO-0989
The reaction product obtained by neutralizing Coal Tar Oil
Alkaline Extract with an acidic solution, such as aqueous
sulfuric acid, to obtain the free acids. Composed primarily of
phenol, cresols, and xylenols.
Coal Tar Base Extract Oil [*65996-86-3] HOOO-1073
The extract from Coal Tar Oil Alkaline Extract Residue produced
by an acidic wash such as aqueous sulfuric acid after distillation
to remove naphthalene. Composed primarily of the acid salts of
various aromatic nitrogen bases including pyridine, quinoline, and
their alkyl derivatives.
36
-------
Coal Tar Oil Alkaline Extract Residue [*65996->87-4] HOOO-1197
Synonym: Chemical Oil Alkaline Extract Residue
The residue obtained from Coal Tar Oil by an alkaline
wash such as aqueous sodium hydroxide after the removal of
Crude Coal Tar Acids. Composed primarily of naphthalenes and
aromatic nitrogen bases.
Benzol Forerunnings (Coal) [*65996-88-5] HOOO-121^
The distillate from Coke Oven Light Oil having an approximate
distillation range below 100°C. Composed primarily of C4-C6
aliphatic hydrocarbons.
Coal Tar, High Temperature 1*65996-89-6} HOOO-1322
The condensation product obtained by cooling, to approximately
ambient temperature, the gas evolved in the high temperature
(greater than 700°C) destructive distillation of coal. A black
viscous liquid denser than water. Composed primarily of a complex
mixture of condensed ring aromatic hydrocarbons. May contain
minor amounts of phenolic compounds and aromatic nitrogen bases.
Coal Tar, Low Temperature [*e5996-90-9] HOOO-l^^O
The condensation product obtained by cooling, to approximately
ambient temperature, the gas evolved in low temperature (less than
700°C) destructive distillation of coal. A black viscous liquid
denser than water. Composed primarily of condensed ring aromatic
hydrocarbons, phenolic compounds, aromatic nitrogen bases, and
their alkyl derivatives.
Coal Tar Upper Distillate [*65996-91-0] HOOO-15^5
The distillate from High Temperature Coal Tar having an
approximate distillation range of 220°C to 450°C. Composed
primarily of three to four membered condensed ring aromatic
hydrocarbons.
Goal Tar Distillate [*65996-92-1] HOOO-1669
The distillate from High Temperature Coal Tar having an
approximate distillation range of 1^0°C to 450°C. Composed
primarily of two to four membered condensed ring aromatic
hydrocarbons, phenolic compounds, and aromatic nitrogen bases.
-------
Coal Tar Pitch [*65996-93-2] HOOO-1778
The residue from the distillation of High Temperature Coal
Tar. A black solid with a softening point from 40bC to l8o°C.
Composed primarily of a complex combination of three or more
membered condensed ring aromatic hydrocarbons.
38
-------
SECTION III
CHEMICAL SUBSTANCES COMMON
TO THE
IRON AND STEEL INDUSTRY
Developed in Conjunction
with the
American Iron and Steel Institute
Iron Ore Agglomerates [*65996-65-8] HOOO-1886
The product of agglomerating iron ore fines, concentrates,
Iron Sinter, and other iron-bearing materials. Includes pellets,
nodules and briquettes.
Iron Sinter [*65996-60-9] HOOO-1995
The thermally agglomerated substance formed by heating a
variable mixture of finely divided coke, iron ore, Blast
Furnace Dust, Steelmaking Dust, Mill Scale, other miscellaneous
iron-bearing materials, limestone, and dolomite at 2400°F to 2700°F,
Furnace Iron [*65996-6?-0] HOOO-2085
The metallic substance produced in a blast furnace or
direct reduction furnace which contains over 90°/0 iron.
Blast Furnace Gas (Ferrous Metalsj [*65996-68-l] HOOO-2116
The off gas from blast furnaces. Composed primarily of
carbon monoxide, carbon dioxide, nitrogen, and hydrogen.
Blast Furnace Slag (Ferrous Metals) [*65996-69-2] HOOO-2225
The fused substance formed by the action of a flux upon the
gangue of the iron-bearing materials charged to a blast furnace
and upon the oxidized impurities in the iron produced.
Depending upon the particular blast furnace operation, the slag
is composed primarily of oxides of aluminum, calcium, magnesium,
and silicon, with varying amounts of sulfur.
39
-------
Blast Furnace Dust (Ferrous Metals) £65996-70-5] HOOO-2333
The dust generated from the initial cleaning of off gases
from a blast furnace. Composed primarily of iron and carbon.
May contain varying amounts of other elements, oxides, and
trace compounds.
Steelmaking Slag [*65996-71-6] HOOO-2442
The fused substance formed by the action of a flux upon
the gangue of iron-bearing materials charged to a steelmaking
furnace and upon the oxidized impurities in the steel produced.
Depending upon the particular steelmaking operation, the slag
is composed primarily of oxides of aluminum, calcium, iron,
magnesium, manganese, phosphorus, and silicon, with varying
amounts of sulfur.
Steelmaking Dust [*65996-72-7] HOOO-2551
The dust generated during the charging, operation, and
tapping of a steelmaking furnace and from steel conditioning,
including that which is recovered through the use of pollution
abatement equipment. Composed primarily of iron oxides.
May contain varying amounts of other metallic oxides and trace
compounds.
Blast Furnace and Steelmaking Sludge [*65996-7Z-8] HOOO-2675
The wetted particulate matter recovered by wet collection
techniques, including pollution abatement equipment, for the
recovery of materials such as iron sinter dust, Blast Furnace
Dust, Steelmaking Dust, and Mill Scale.
Mill Scale (Ferrous Metals) [^65996-74-9] HOOO-2784
The oxidized surface of steel produced during reheating,
conditioning, hot rolling, and hot forming operations. This
substance is usually removed by process waters used for
descaling, roll and material cooling, and other purposes.
It is subsequently recovered by gravity separation techniques.
Composed primarily of high-purity iron oxides. May contain
varying amounts of other oxides, elements, and trace compounds.
Spent Pickle Liquor (Ferrous Metals) [*65996-75-0] HOOO-2899
The solution of an appropriate pickling acid or combination
of acids containing any of the elements, oxides, or salts present
in steel. Pickling acids include hydrochloric, hydrofluoric,
nitric, phosphoric, and sulfuric acids.
40
-------
Metallic Dross or Spelter (Ferrous Metals) [*65996-76-l] HOOO-2915
The metallic salts and oxides removed from the molten
metals used to coat steel by dip processes. Composed primarily
of salts and oxides of aluminum, lead, tin, and zinc.
Chemical Substances Manufactured
as Part of Steel [*65997-19-5] HOOO-3094
This category includes the chemical substances which are
manufactured as part of steel and alloy steels. The following list
identifies those elements which may exist in steel or which may
comprise compounds present in steel or alloy steels. Aluminum,
Beryllium, Boron, Calcium, Carbon, Cerium, Chromium, Cobalt, Copper,
Hafnium, Iron, Lanthanum, Lead, Magnesium, Manganese, Molybdenum,
Nickel, Niobium, Nitrogen, Oxygen, Phosphorus, Selenium, Silicon
Sulfur, Tantalum, Tin, Titanium, Tungsten, Vanadium, Yttrium, Zinc,
Zirconium.
41
-------
SECTION IV
WOOD AND PULP CHEMICALS
Developed in Conjunction
with the
Pulp Chemicals Association
Oil of Turpentine [*8006-64-2] HOOO-^119
Any of the volatile predominately terpenic fractions or
distillates resulting from the solvent extraction of, gum
collection from, or pulping of softwoods. Composed primarily
of the CioHie terpene hydrocarbons: a-pinene, 3-pinene, limonene,
3-carene, camphene. May contain other acyclic, monocyclic, or
bicyclic terpenes, oxygenated terpenes, and anethole. Exact
composition varies with refining methods and the age, location,
and species of the softwood source.
Oil of Turpentine, a-Pinene Fraction [*65996-96-5] HOOO-323^
The hydrocarbon fraction distilled from Oil of Turpentine.
Contains greater than 8o°/0 a-pinene, the remainder being
other terpene hydrocarbons.
Oil of Turpentine, ^-Pinene Fraction [*65996-97-6] HOOO-33^3
The hydrocarbon fraction distilled from Oil of Turpentine
or produced by the isomerization of a-pinene. Contains
greater than 70°/0 3-pinene. Other major components being
limonene, a-pinene, camphene, myrcene. May contain other acyclic,
monocyclic, and bicyclic terpenes.
Pine Oil [*8002-09-3] HOOO-3^59
A complex combination of terpenes produced by the high
temperature distillation of oil of turpentine residues or by
the catalytic hydration of pinenes. Composed primarily of
isomeric tertiary and secondary cyclic terpene alcohols. May
contain terpene hydrocarbons and ethers. Exact composition
varies with production methods and turpentine source.
43
-------
Terpenes, 8o°/0 or greater Limonene Fraction [*65996-98-7] HOOO-3568
A complex combination of terpenes derived from Oil of
Turpentine or citrus oils by fractionation or isomerization
of other terpene fractions. Contains at least 8o°/o limonene,
the remainder being other terpene hydrocarbons. May contain
trace amounts of alcohols, ethers, aldehydes, or ketones.
Oil of Turpentine, 30°/o or greater Limonene Fraction [*65996-99-8] HOOO-3683
A complex combination of terpenes derived from Oil of
Turpentine. Contains at least 50 /o limonene, the remainder being
phellandrenes, terpinenes, terpinolene, cineoles.
Oil, of Turpentine, 800/0 or greater Terpinolene Fraction [^65997-00-4] HOOO-3705
A complex combination of terpenes derived from Oil of
Turpentine. Contains at least So /o terpinolene, the remainder
being mixed terpene hydrocarbons.
Tall Oil [*8002-26-4] HOOO-^SlS
A complex combination of tall oil rosin and fatty acids
derived from the acidulation of crude tall oil soap and including
that which is further refined. Contains at least 10°/o rosin.
Tall Oil, sodium salt [*65997-01-5] HOOO-3922
Synonyms: Black Liquor Soap, Tall Oil Soap Skimmings,
Crude Tall Oil Soap (Kraft Process)
The sodium salt of Tall Oil formed during the kraft
process where it becomes a component of the spent pulping liquor.
The soap separates when the pulping liquor is concentrated and
can be recovered by skimming the concentrated liquor.
Spent Acid from Crude Tall Oil Soap Acidulation [*65997-02-6] HOOO-4015
The aqueous layer formed by acidulation of tall oil soap with
sulfuric acid during the production of Tall Oil. Composed
primarily of a solution of sodium sulfate, the remainder being
lignin and Tall Oil.
44
-------
Tall Oil Pitch £8016-81-?] HOOO-4122
The residue from the distillation of Tall Oil. Composed
primarily of high-boiling esters of fatty acids and rosin.
May contain neutral materials, free fatty acids and rosin acids.
Tall Oil Heads £65997-03-7} HOOO-42^6
The low boiling fraction obtained by the distillation of
Tall Oil. Contains fatty acids such as palmitic, stearic,
oleic and linoleic as well as neutral materials.
Tall Oil Fatty Acids f 61790-12-3] HOOO-4352
A complex combination obtained by distillation of Tall Oil.
Contains at least 90°/o fatty acids, primarily oleic and
linoleic acids, the remainder being rosin and neutral materials.
Rosin £8050-09-?] HOOO-4463
A complex combination derived from wood, especially pine wood.
Composed primarily of resin acids and modified resin acids such as
dimers and decarboxylated resin acids. Includes rosin stabilized
by catalytic disproportionation.
Tall Oil Fatty Acids, Sodium Salt £61790-45-2] HOOO-^577
Tall Oil Fatty Acids, Potassium Salt $61790-44-1] HOOO-4696
Rosin, Glycerol Ester 18050-31-5] HOOO-4713
Rosin, Pentaerythritol Ester [*8050-26-8] HOOO-4823
Rosin, Maleic Acid Adduct [*80SO-28-0] HOOO-49^1
Rosin, Fumaric Acid Adduct [*65997-0*-8] HOOO-5028
Rosin, Polymerized [*65997-05-9] HOOO-513S
Rosin. Hydrogenated [*6599?-06-0] HOOO-5258
45
-------
Rosin, Reaction Product with Formaldehyde [*65997-07-l] HOOO-5367
Rosin, Maleic Acid Adduct - Glycerol Ester [*65997-08-2] HOOO-5477
Rpsin^ Maleic Acid Adduct - Pentaerythritol Ester [*6599?-09-2] HOOO-5586
Rosinj Fumaric Acid Adduct - Glycerol Ester [*65997-lO-6] HOOO-5615
Rosin, Fumaric Acid Adduct - Pentaerythritol Ester [*65997-21-7] HOOO-5724
Rosin, Polymerized - Glycerol Ester [*9006-47-7] HOOO-5831
Rosin, Polymerized - Pentaerythritol Ester [-^65997-22-8] HOOO-5949
Rosin, Hydrogenated - Glycerol Ester [*65997-13-9] HOOO-6034
Rosin, Hydrogenated - Pentaerythritol Ester [*65997-14-0] H000-6l49
46
-------
SECTION V
CHEMICAL SUBSTANCES MANUFACTURED
IN THE
PAPER INDUSTRY
Developed in Conjunction
with the
American Paper Institute
Cellulose, Chemical Pulp [*65996-61-4] HOOO-6263
The fibrous substance obtained from the treatment of
lignocellulosic substances (wood or other agricultural fiber
sources) with one or more aqueous solutions of pulping and/or
bleaching chemicals. Composed of cellulose, hemi-cellulose,
lignin, and other minor components. The relative amounts of
these components depenfl on the extent of the pulping and
bleaching processes.
Examples: bleached and unbleached kraft, sulfite and
seinichemical pulp and bleached mechanical pulp. Includes
virgin and recycled pulps.
Starch, Oxidized [*65996-62-5] HOOO-6^72
The substance resulting from treatment of starch in aqueous
slurry with an aqueous oxidizing agent such as hydrogen peroxide,
sodium hypochlorite, hypochlorous acid, or ammonium persulfate.
Under controlled conditions of temperature, pressure, and time,
the oxidizing agent reacts with the starch to cleave the polymeric
chains and to oxidize the end groups from aldehyde to carboxylic
acid groups.
S_tarch. Acid Hydrolyzed [*65996-63-6] HOOO-6481
The substance resulting from treatment of starch in aqueous
slurry with small amounts of an acidifying substance, such as
aluminum sulfate, generally at elevated temperature and pressure.
The process is usually continuous with the time of treatment very
short. Degree of hydrolysis is usually determined by measurement
of viscosity and controlled by rate of the slurry through the
reactor, temperature, and acidity.
47
-------
Starch, Enzyme Hydrolyzed [*65996-64-7] HOOO-6591
The substance resulting from treatment of starch in
aqueous slurry with amylase or carbohydrase under controlled
conditions of temperature, pressure, and time. The degree
of hydrolysis is usually determined by measurement of viscosity.
Enzymatic hydrolysis is terminated by destroying the enzyme
by raising the temperature or adjusting the pH.
Magnesium Bisulfite [12774-25-9] HOOO-6^13
£ pe nj_ puIpi ng 1 i qu o r [*6C07l-9?-PJ HOOO-7855
The aqueous solution resulting from the reaction of
lignocellulosic substances (wood or other agricultural fiber
sources) with one or more pulping chemicals including those
used in the kraft, sulfite, semichemical or other pulping
processes. Composition is highly variable and includes
excess pulping chemicals, dissolved and degraded cellulose,
hemicellulose and lignin.
48
-------
SECTION VI
CHEMICAL SUBSTANCES MANUFACTURED
IN THE
FERTILIZER INDUSTRY
Developed in Conjunction
with
The Fertilizer Institute
Phosphate Hock, Calcined [*65996-94-S] H000-o7?f"
Substance obtained by heating naturally occurring phosphate
rock to 732°C to 8l6°c (1350°F to 1500°F) in a fluidized bed or
other suitable device for oxidizing carbonaceous matter.
Characterized by upgraded phosphorus content and reduced hydrocarbon
levels.
Supe rpho s phat e [*8011-76-5] HOOO-6842
Synonyms: Normal Superphosphate, Enriched Superphosphate
Substance obtained by treating phosphate rock with sulfuric
acid or a mixture of sulfuric and phosphoric acids. Composed
primarily o^ calcium phosphates and calcium sulfate.
Superphosphate,_ Concentrated [*G599C-95-4] HOOO-6955
Synonyms: Double Superphosphate, Treble Superphosphate, Triple-
Superphosphate
Substance obtained by acidulating phosphate rock with phosphor'c
acid. Normally characterized as containing 4o°/o or more a.vailable.
phosphoric oxide (PsOs). Composed primarily of calcium phosphate.
Supe rpho sphoric Acid [*8017-16-i] HOOO-7C45
Synonym: Polyphosphoric Acid
Combination of phosphoric acids obtained by dehydration of
orthophosphoric acid or by oxidation of phosphorus in the presence
of water. Composed primarily of polyphosphoric acids whose
molecular structure contains more than one atom of phosphorus.
49
-------
SECTION VII
NATURAL OILS AND EXTRACTIVES
Developed in Conjunction
with the
Essential Oils Association
This section identifies certain chemical substances
which are primarily oils derived from botanical sources
In some instances, a substance is defined to include
the oil, extractives, and physically modified deri-
vatives obtained from the source. In this context,
"physically modified" means the application of cer-
tain processes not involving chemical reactions,
namely: distillation, expression, filtration,
drying, heating, cooling, extraction, and decolor-
ization by adsorption.
51
-------
A jo wan Oil [* 8001-99-8] H002-4966
Ptychotis ajowan or Carum ajowan, Urnbellif erae
Almond 05-1, Bitter [*8012-?6-ll H002-5056
Prunus araygdalus or Prunus armeniacs, Rosaceae
Amber Oil [*8002-67-ZJ H002-5160
Pinus succinifera
Ammoniac Gum [*9000-03-7J H002-5276
Extractives and their physically modified derivatives.
Dorema ammoniac urn, LJmbellif erae
Amyris Oil r*8015-65-4] H002-5391'
Extractives and their physically modified derivatives.
Amyris balsamifera, Rutaceae
Angelica Root Oil [*8015-64-3J H002-5-H14
Extractives and their physically modified derivatives.
Hoot Oil, Seed Oil. Angelica archangellca, Urnbelliferae
Anise Oil 1*8007-70-31
Extractives and, their physically modified derivatives
Pimpinella anisum, Ui-ibc 111 ferae
Apopin Oil [*8022-?8-4] H002-57J4!I
Cinnamonum camphora
Araucaria Oil r*8015-6S-71 rr002-5866
Extractives and their physically modified derivatives
Callitropsis araucarioides, Cupressaceae
Asafoetida Gum [*9000-04-8] H002-5972
Extractives and their physically modified derivatives.
Ferula asafoe or ?. asafoetida L. or F. alliacea Boiss,
Unbelliferae
Basil Oil 1*8018-73-4] H002->'"062
Extractives and their physically modified derivatives.
Ocimura basilicum, Labiatae
Bergamot Oil [*8007-75-8J H002-6175
Extractives and their physically modified derivatives.
Citrus bergamia, Citrus
52
-------
Birch Tar Oil 1*8001-88-5] H002-6288
Extractives and their physically modified derivatives.
3etula pu'oescens, Betulaceae
Bois de Rose Oil [*8015-77-8J H002-6J13
Extractives and their physically modified derivatives.
Anibe, rosaeodora, Lauraceae
Soldo Leaf Oil C*8022-81-9J H002-6428
Peuraus boldus
Boronia Oil r*80S3-33-6J H002-653G
Extractives and their physically modified derivatives.
Boronia megastigma, Rutaceae
Cade Oil 1*8015-10-51 H002-6643
Extractives and their physically modified derivatives.
Juniperus oxycedru.s, Cupressaceae
Cajuput Oil 1*8008-98-8] H002-6756
Melaleuca minor, Myrtaceae
Calamus Oil c*FC]r.-73-0] H002-6873
Acorus calamus, Araceae
Camphor Oil [*8008-C1-3J H002-6984
Extractives and their physically modified derivatives.
Cinnamomum camphora, Lauraceae
Canada Balsam r*r,OD7-47-4i 11002-707^
Extractives and their physically modified derivatives.
Abies balsanea or Tsuga canadiensis, Pinaceae
Cape Oil C*8022-45-5J H002-5529
Popowia capea
Capsicum Olecresin [*802S-77-6J H002-7184
Extractives and their physically modified derivatives.
Capsicum annuum or Capsicum longum, Capsicum Prutescens,
or Capsicum fastigiatum, or Capsicum minimum mill, Solanaceae
Caraway Oil [*8000-42-8J H002-7295
Extractives and their physically modified derivatives.
Carum carvi, Umbelliferae
53
-------
Cherry Laurel Oil [*8000-44-0] H002-8663
Prunus laurocerasus_, Rosaceae
Cognac Oil, Green r*8016-21-5) H002-8776
Extractives and their physically modified derivatives.
Wine lees oil
Coriander Oil [*8008-52-4J H002-8896
Extractives and their physically modified derivatives
Coriandrum sativum, Umbelliferae
Costus Oil 1*8022-88-9] H002-8911
Extractives and their physically modified derivatives
Saussurea lappa, Compositae
Cubeb Oil [*8007-87-2] H002-9C01
Extractives and their physically modified derivatives
Piper cubeba, Piperaceae
Cumin Oil 1*8014-13-9] H002-9H^
Extractives and their physically modified derivatives
Cuminum cyminum, Umbelliferae
Curcuma Oil 1*8024-27-1] H002-9225
Extractives and their physically modified derivatives
Curcuma longa, Zingiberaceae
Cypress Oil r*8013-86-3J H002-93.55 /
Extractives and their physically modified derivatives.
Cypressus sempervirens, Cupresnaceae
Davana Oil 1*8016-02-2] H002-9451
Artemisia pallens, Compositae
Dill Seed Oil, European r*8016-OG-6] H002-9565
Extractives and their physically modified derivatives.
Anethum graveolens, Umbelliferae
Dill Weed Oil [*8006-75-5] H002-9677
Anethum graveolens, Umbelliferae
Estragon (Tarragon) Oil f*8016-88-4] H002-97P-1
Extractives and their physically modified derivatives.
Artemisia dracunculus, Ccmpositae
Fennel Oil, Bitter [*800C-84-€l H002-9819
Poeniculurn vulgare, Umbelliferae
-------
Cardamom Oil 1*8000-66-61 H002-7312
Extractives and their physically modified derivatives
Elettaria cardamomum, Zingiberaceae
Carnation Oil :*8021-4Z-OJ H002-7437
Extractives and their physically modified derivative:
Dianthus caryophyllus, Caryophyllaceae
Carrot Seed Oil C*8015-88-H H002-7543
Daucus corota, Umbelliferae
Cascarilla Oil £*8007-06-5J H002-7659
Croton eluteria, Euphorbiaceae
Cashew Nut Shell Oil 1*8007-24-71 H002-7?6l
Cassia Oil [*8007-80-5] H002-7884
(Chinese Cinnamon Oil)
Extractives and their physically modified derivatives.
Cinnamo^Um cassia, Lauraceae
Catnip Oil [*8023-84-5J H002-7903
Nepata cataria, Labiatae
Cedarleaf Oil 1*8007-20-3] H002-0081
Extractives and their physically modified derivatives
Thuja occidentalis, pinaceae
Cedarwood ''Atlas'1 Oil [*8000-S7-9J H002-8191
Extractives and their physically modified derivatives
Cedrus atlantica, Pinaceae
Celery Seed Oil [*8015-90-5J H002-8219
Extractives and their physically modified derivatives.
Apium graveolens, Umbelliferae
Chamomile Oil, German L*8002-66-21 H002-8322
Extractives and their physically modified derivatives.
Matricaria chamomilla, Compositae
Chamomile Oil, Roman 1*8016-92-71 H002-8442
Anthemis nobilis, Compositae"
Champaca Oil [*8006-7G-6J H002-8555
Extractives and their physically modified derivatives.
Michalea champaca or Michalea longifolia, Magnoliaceae
-------
Fennel Oil, Sweet [*8024-24-61 H002-9925
Extractives and their physically modified derivatives
Poeniculum vulgare, var. dulce, Umbelliferae
Fir Needle Oil, Canadian f*8021-28-H H00"-0062
Extractives and their physically modified derivatives
Tsuga canadensis, Pinaceae
Fir Needle Oil, Siberian r*8021-29-2] H003-0171
Extractives and their physically modified derivatives.
Abies siberica, Pinaceae
Fir Needle Oil, Silver 1*8021-27-01 H00>028^
Extractives and their physically modified derivatives.
Abies alba, Pinaceae
Galangal Oil [*8024-40-61 HOO>0314
Extractives and their physically modified derivatives.
Alpinia officinarum, Zingiberaceae
Galbanum Gum [*9000-24-21 H005-0424
Ferula, Umbelliferae
Galbanum Oil r* 8023-91-41 HOOJ-0535
Extractives and their physJcally modified derivatives.
Ferula, Umoelliferae
Garlic Oil C*8000-78-Oj H003-064?
Extractives and their physically modified derivatives.
Allium sativum, Liliaceae
Geranium Oil L*8000-4G-2l HOO^-0755
Extractives and their physically modified derivatives.
Pelargonium graveolens, Geraniaceae
Ginger Oil [*8007-08-71 H00>08?2
Extractives and their physically modified derivatives.
Zingiber officinale, Zingiberaceae
Gingergrass Oil [*8023-92-5J H005-0989
Extractives and their physically modified derivatives
Cymbopogon martini, var. sofia, Grarnineae
Grapefruit Oil 1*8016-20-41 H00>1075
Extractives and their physically modified derivatives
Citrus paradisi, Citrus
-------
GuaJacwood Oil r*801C-23-7] H00>ll88
Extractives and their physically modified derivatives
Bulnesia sarmienti, Zygophyllaceae
Gum Benzoin 1*9000-05-9] H00>1295
Extractives and their physically modified derivatives.
Styrax tonkinensis, Rosaceae
Hay Oil [*80Zl-00-3: H00>1515
Extractives and their physically modified derivatives.
Hierochlea alpina
Hop Oil C*8007-04-31 HOO>1458
Extractives and their physically modified derivatives.
Humulus lupulus, Moraceae
Huon Pine Wood Oil C*8028-7G-OJ H003-15^7
Dacrydium franklinii
Hyssop Oil [*8006-83-5J HOOJ-1655
Hyssopus officinalis, Labiatae
Iva Oil [*8026-97-9J H00>176l
Achillea moschata, Compositae
Juniperberry Oil 1*8012-91-71 H003-1882
Extractives and their physically modified derivatives.
Juniperus ccmmunis, Cupressaceae
Juniper Wood Oil [*8002-G8-4J H00>1902
Juniperus communis, Cupressaceae
Kuromo.ji Oil C*8026-92-4J H003-2088
Lindera sericea
Labdanum Oil (Cistus Oil) r*8016-26-OJ H005-2191
Extractives and their physically modified derivatives
Cistus ladaniferus, Cistaceae
Laurel Berry Oil f*8002-41-S1 H00>2322
Extractives and their physically modified derivatives.
Lau~."us nooilis, Lauraceae
Laurel Leaf Oil i*8006-78-8] H003-2441
Extractives and their physically modified derivatives.
Laurus nobilis, Lauraceae
-------
Lavandin Oil [*8022-15-9J H00>2558
Extractives and their physically modified derivatives.
Lavandula hydride - Lavandula officinalis + Lavandula
latifolia, Labiatae
Lavender Oil C*8000-28-0] H00>266l
extractives and their physically modified derivatives
Lanandula officinalis, Labiatae
Lawang Oil [*8022-16-01 H00>2?71
Cinnamomum culilawan, Lauraceae
Lemongrass Oil r*8007-02-l] H003-2894
Extractives and their physically modified derivatives
Cymbopogon citratus, Gramineae
Lemon Oil [*8008-56-8J HOOJ5-2916
Extractives and their physically modified derivatives
Citrus lirnonum, Citrus
Lime Oil [*8008-26-2J H00>3001
Extractives and their physically modified derivatives.
Citrus aurantifolia, Citrus
Mace Oil ;*8007-12-3J H003-5H5
Extractives and their physically modified derivatives.
Myrlstica fragrans, Myristlcaceae
Mandarin- Petitgrain Oil f*80S2-30-OJ H003-3228
Extractives and their physically modified derivatives.
Citrus reticulata, Citrus
Marjoram Oil r*8015-01-8J H00>3338
Extractives and their physically modified derivatives.
Origanum majorana, Labiatae
Marjoram Oil, Wild (Spanish) f*8016-33-9]
Extractives and their physically modified derivatives.
Thymus masticina, Labiatae
Mawah Oil [*8000-46-2J H003-5566
Pelargonium radula, Geraniaceae
Melissa Oil [*8024-7l-9] H005-5677
Melissa officinalis, Labiatae
-------
Milfoil Oil 1*8022-07-9] HOO>3?B5
Achillae millefolium, Compositae
Mustard Oil 1*8007-40-7] H00>38ll
Brassica nigra, Cruciferae
Myrrh, Oleo-Gum-Resln [*9000-45-7J H00>~5924
Commiphora, Burseraceae
Myrrh Oil 1*8016-57-5] H00>40l8
Extractives and their physically modified derivatives
Commiphora, Burseraceae
Myrtle Oil C* 8008-46-6] HOO>4124
Myrtus communis, Myrtaceae
Neroli Oil 1*8016-58-4] H003-4235
Extractives and their physically modified derivatives
Citrus aurantium, Citrus
Niaouli Oil i*8014-68-4J H00>4>;4
Melaleuca viridiflora, Myrtaceae
Nutmeg Oil 1*8008-45-5] H00>4467
Extractives and their physically modified derivatives.
Myristica fragrans, Myristicaceae
Olibanum Oil [*80lc-56-2]
Extractives and their physically modified derivatives
Species bosvjellia, Burseraceae
Onion Oil [*8002-??.-OJ H00>468l
Extractives and their physically modified derivatives
A Hi urn cepa, Liliaceae
Opopanax Gum L*9000-78-61 HOO^-4799
Extractives and their physically modified derivatives.
Commiphora erythrea, Burseraceae
Opopanax Oil r*go21-S6-ll H00>^8ll
Extractives and their physically modified derivatives.
Commiphora erythrea, Burseraceae
Origanum Oil C*8007-ll-2] H00>4931
Extractives and their physically modified derivatives.
Thymus capitatus, Labiatae
-------
Palrnarosa Oil [*8014-19-5J H00>5023
Extractives and their physically modified derivatives.
Cymbopogon martini, Gramineae
Patchouli Oil [*8014-09-3J HOO>51J1
Extractives and their physically modified derivatives.
Pogostemon cab11n (Pogosteraon patchouli), Labiatae
Pennyroyal Oil, American r*8007-44-l] H003-5247
Extractives and their physically modified derivatives.
Heieoma pulegioides, Labiatae
Pennyroyal Oil, European (*8013-99-8J H003-5355
Extractives and their physically modified derivatives.
Mentha pulegium, Labiatae
Peppermint Oil [*8006-90-4] H003-5W
Extractives and their physically modified derivatives.
Mentha arvensis, Labiatae
Pimenta Berry Oil 1*8006-77-7] H00>5589
Extractives and their physically modified derivatives.
Pimenta officinalls, Myrtaceae
Pimenta Leaf Oil C*8016-45-3J H005-5697
Extractives and their physically modified derivatives.
Pimenta officinalis, Myrtaceae
Pinus Pumilio Oil [*8000-26-8J HOO>5718
Extractives and their physically modified derivatives.
Pinus pumilio (a.k.a. Pinus montana or Pinus rnugo), Pinaceae
Pinus Sylvestris Oil 1*8023-99-2] HOOJ5-5829
Extractives and their physically modified derivatives.
Pinus sylvestris, Pinaceae
Rapeseed Oil r*8002-l3-9] H00>59^4
Extractives and their physically modified derivatives.
Brassica napus
Rose Oil 1*8007-01-0] H003-6012
Extractives and their physically modified derivatives.
Rosa centifolia, Rosaceae
Rosemary Oil [*8000-25-7] H00>6l42
Extractives and their physically modified derivatives.
Rosmarinum officinalis, Labiatae
-------
Rue Oil [*8014-29-7] H00>6254
Extractives and their physically modified derivatives
Rita graveolens, Rutaceae
Saffron Oil C*8022-19-3J H003-6360
Extractives and their physically modified derivatives
Crocus sativus, Iridaceae
Sage (Clary) Oil [*8016-6Z-5; H00>6485
Extractives and their physically modified derivatives
Salvia sclarea, Labiatae
Sage Oil, Dalmatian [*801(t-64-6] H003-6501
Extractives and their physically modified derivatives
Salvia officinalis, Labiatae
Sage Oil, Spanish [*8026-65-7J H00>66l9
Extractives and their physically modified derivatives,
Salvia lavandulaefolia, Labiatae
Sandalwood Oil, East Indian r*8006-8?-9J H003-6727
Extractives and their physically modified derivatives
Santalum album, Santala.ceae
Sassafras Oil E*8006-80-2J H003-6857
Extractives and their physically modified derivatives,
Sassafras albidum, Lauraceae
Savin Oil L*8024-00-8] H003-6953
Juniperus sabina, Cupressaceae
Siam Wood Oil 1*8022-47-71 H00>?04l
Fokiena hodginsii
Snakeroot (Canadian) Oil 1*8016-69-1] H00>?159
Asarum canadense, Aristolochiaceae
Spearmint Oil C*8008-?9-5J H003-726?
Extractives and their physically modified derivatives
Mentha spicata, Labiatae
Spike Lavender Oil r*80i6-78-2J H003-7379
Extractives and their physically modified derivatives
Lavandula latifolia, Labiatae
61
-------
Spikenard Oil C*8022-22-8J H00>7^95
Nardostachys jatamansi
Tansy Oil [*8016-87-3J H003-75U
Tanacetura vulgare, Compositae
Valerian Oil [*8008-88-6J H00>7622
Extractives and their physically modified derivatives.
Valerian officinalis, Valerianaceae
Verbena Oil r* 8024- 12- 21 H003-7733
Extractives and their physically modified derivatives.
Lippia citriodora, Verbenaceae
Verbena Oil, Spanish 1*8022-79-51
Extractives and their physically modified derivatives.
Thymus hiemalis, Verbenaceae
Vetiver Oil [*8016-96-4l H00>7969
Extractives and their physically modified derivatives.
Vetiveria zizanoides, Gramineae
Wormseed Oil (American) 1*8024-11-11 H003-8051
Extractives and their physically modified derivatives.
Chenopodium ambrosloides, var. anthelminthicum, Compositae
Wormwood Oil 1*8008-93-2] H00>8l63
Extractives and their physically modified derivatives.
Artemisia, absinthium, Compositae
Ylang-Ylang Oil [*8006-8l-3l H003-8271!
Extractives and their physically modified derivatives.
Cananga odorata, Anonaceae
62
-------
SECTION VIII
SELECTED POLYMERS
-------
Adipic acid, phthalic anhydride, trimethylc
olpropane, neopentyl glycol, a-hydro-u.-c;
hydroxypoly[oxy[methyl(2-phenylethyl)c^
silyleae] ], a--hydro-!>/-hydroxypoly[oxyc:
(dimethylsilylene)jpolymer
K6085-51-6]
HOOO-8281
Allyl alcohol-, linoleic acid, maleatecl
styrene polymer
[*66070-57-3] HOOO-8303
Azelaic acid, isophthalic acid, trimethyl;
olethane, trimethylolpropane, a-hydro-6u-c:
hydroxypoly[oxy[methyl(2-phenylethyl)^
silylene] ], a-hydro-u/-hydroxypoly[oxyrr
(dimethylsilylene)Jpolymer
[66085-54-9J HOOO-8417
Benzole ac:'.d, isophthalic acid, pentaeryo
thritol, safflower oil poljmier
[*660?2-38-3J HOOO-8527
Benzoic acid, isophthalic acid, t rime thy Ic;
olethane, dehydrated castor oil fatty acids,
methyl methacrylate polymer
[*66071-52-0] HOOO-8635
Benzole acid, phthalic anhydride, trimethy1:
olethane, coconut oil polymer
[*66071-24-7] HOOO-B751
Bisphenol A bis(2-hydroxypropyl)ether,
isophthalic acid, tall oil fatty acids,
neopentyl glycol, 3-hydroxy-2,2-dimethyi;
propyl 3-hydroxy-2,2-dimethylpropionate
polymer
f*66071-40-7J HOOO-8'°66
Bisphenol A, dicyclopentadiene, epichlorohydc;
rin, maleic anhydride, soybean oil fatty acids
polymer
[*66071-06-5] KOOO-9062
Bisphenol A, epichlorohydrin, butyl glycidyl
ether, polymer acrylate [66085-58-3] HOOO-&973
Bisphenol A, epichlorohydrin, isophthalic
acid polymer
[26284-22-1] HOOO-9171
Bisphenol A, epichlorohydrin polymer stearate 159111-89-6] HOOO-9294
64
-------
Bisphenol A, tall oil fatty acid,
epichlorohydrin polymer
r*CC070-75-5J HOOO-931--
jD-jb-Butylbenzoic acid, phthalic
anhydride, pentaerythritol, soybean
fatty acid polymer
[*66071-26-9J HOOO-9^28
jD-_t-Butylbenzoic acid, phthalic anhydride,
soybean oil, trimethylolethane polymer
[*66071-22-5]
HOOO-9535
2-(N-3utylcarbamoyl)ethyl acrylate and
acrylic acid polymer with maleated
bisphenol A epichlorohydrin copolymer
r*66070-56-2J
Chlorendic acid, glycerin, soybean oil
polymer
[^66070-90-41 HOOO-9763
1-Decene 1-octene polymer
[53G21-22-OJ
HOOO-9870
Dehydrated castor oil fatty acid, bisphenol
A, epichlorohydrin polymer
[*66070-77-7] HOOO-9985
Dehydrated castor oil fatty acid, dimer
fatty acid, bisphenol A, epichlorohydrin
polymer
[*66070-78-8J H001-0033
Dehydrated castor oil fatty acids,
maleated soybean oil, pentaerythritol,
rosin polymer
[*66071-3G-1J H001-0145
Dehydrated castor oil fatty acids, maleic
acid, oiticica oil, soybean oil polymer
[*66071-?8-U H001-0265
Dehydrated castor oil fatty acids, maleic
anhydride, rosin, dicyclopentadiene polymer
[*66071-6S-6] H001-0378
Dehydrated castor oil, rosin, formaldehyde,
phenol polymer
[*66071-49-6] H001-C486
Dicyclopentadiene modified linseed oil,
fatty acids, dehydrated castor oil,
maleic anhydride, safflower oil polymer
65
[*66071-75-8J H001-0591
-------
Dicyclopentadiene, modified tall oil fatty
acids, bisphenol A, epichlorohydrin polymer [*66072-Z9-4.J H001-0617
Dicyclopentadiene, phthalic anhydride,
glycerin, pentaerythritol, tall oil fatty
acids, linseed oil polymer
t*66072-43-01 -I001-0733
Dimer fatty acid, aniline, cyclohexylamine,
bisphenol A, epichlorohydrin polymer
[*66072-0?-81 H001-0842
Dimethyl phthlate, phthalic anhydride,
benzoic acid, glycerin, soybean oil
fatty acids polymer
[*66071-52-lJ H001-0954
Ethylene oxide, styrene, butadiene polymer
[Z1292-96-ZJ
Fatty acids, dehydrated castor oil, maleic
anhydride, rosin, dicyclopentadiene,
gilsonite polymer
1*66072-62-2] 1001-1158
Formaldehyde, phenol, triethylenetetramine
polymer
['62610-77-81 H001-1277
Hydrogenated (l-decene 1-octene polymer)
1*66070-54-01 HOOl-1386
Hydrogenated (styrene-butadiene polymer)
2-Kydroxyethyl acrylate, styrene, butyl
acrylate, methyl metnacrylate polymer
L427r,?-02-02 H001-1512
Isophthalic acid, azeleic acid, trimethylc
olpropane, trimethylolethane, neopentylc:
glyco 1, a- hydro-uJ- hydroxypoly [ oxy[methyld
(2-phenylethyl)silylenel], a-hydro-w-^
hyd roxypoly[oxy(d ime thyls ilylene)]polymer
isophthalic acid, glycerin, linseed oil,
pentaerythritol polymer
[*C6070-36-OJ
Isophthalic acid, glycerin, pentaerythri:
tol, linseed oil, styrene, vinyltoluene
polymer
[*66071-77-OJ H001-1852
66
-------
Isophthalic acid, glycerin, soybean oil
polymer
[*66070-91-51
H001-1969
leophthalic acid, glycerin, tall oil
fatty acid polymer
1*66071-17-8]
H001-2053
Isophthalic acid, pentaerythritol,
soybean oil polymer
[*66071-86-l]
H001-2164
Isophthalic acid, pentaerythritol,
tall oil fatty acid, soybean oil polymer
r*6C070-94-8J
H001-2286
Isophthalic acid, trimellitic anhydride,
trimethylolpropane, tall oil fatty acid
polymer
[*66071-08-7J
H001-230'7
Isophthalic acid, trimethylolethane,
soybean oil polymer
[*66070-63-H
H001-2416
Isophthalic acid, trimethylolethane,
trlinethylolpropane, a- hydro- <*- hydroxyo
poly[oxy[methyl(2-phenylethyl)silylene]],
a- hydro-u) - hyd roxypoly [ oxy (dimet hy la
silylene)]polymer
[66085-53-8J
HOOl-2^20
Itaconic acid, phthallc anhydride,
glycerin, pentaerythritol, safflower
oil polymer
[*660?l-45-2]
HOOl-26^]
Itaconic acid, phthalic anhydride,
glycerin, pentaerythritol, safflower
oil, styrene polymer
[*660?l-48-5]
H001-2752
Itaconic acid, phthalic anhydride,
trimethylolethane, safflower oil,
tung oil polymer
[*66070-67-5J
rIOOl-2867
Itaconic acid, phthalic anhydride,
trimethylolethane, safflower oil,
tung oil, styrene polymer
[*66071-54-3]
H001-2975
Linseed oil fatty acid, soybean oil
fatty acid, bisphenol A, epichloroc;
hydrin polymer
1*66070-79-9]
67
-------
Linseed oil, oiticica oil, formaldehyde,
phenol polymer
Linseed oil polymer with oxygen
[*66071-41-8J
[*66071-03-2]
£001-3171
H001-3291
Linseed oil, tung oil modified formalde:
hyde, phenol polymer
[*66071-31-6J
H001-3316
Maleated styrene, allyl alcohol, linoleic
acid polymer compound with 2- (dime thy Ic:
aminojethanol
[*660?0-5£-l]
H001-3*121
Maleic anhydride, glycerin, pentaerythritol,
polyethylene glycol, tall oil fatty acid
polymer
Maleic anhydride, soya oil polymer
[*660?l-ie-?J
HOOl-3538
H001-3641
Maleic anhydride, styrene, allyl alcohol,
linseed oil fatty acid polymer
L*66071-15-6J
H001-3760
Oiticica oil modified rosin, pentaerythritol
ester polymer
H001-38?!
Phenol, formaldehyde, phthalic anhydride,
glycerin, linseed oil fatty acids, dehydrated
castor oil polymer
HOOl-3981
Phenol, formaldehyde, phthalic anhydride,
glycerin, pentaerythritol, linseed oil,
tall oil fatty acids polymer
[*6C071-Z2-7J
H001-4075
Phenol, formaldehyde, phthalic anhydride,
glycerin, soybean oil, tung oil polymer
r*6607l-35-OJ
H001-4186
jo-Phenylphenol, formaldehyde, phenol,
gilsonite, tung oil polymer
C*66071-64-5J
H001-4219
Phthalic anhydride, benzole acid, glycerin,
linseed oil, soybean oil polymer
C*66070-72-2J
H001-4323
68
-------
Phthalic anhydride, benzole acid,
glycerin, pentaerythritol, tall oil
fatty acid polymer
[*66070-85-7]
Phthalic anhydride, benzoic acid, glycerin,
soybean oil fatty acid polymer
[*66070-73-3]
Phthalic anhydride, benzoic acid,
pentaerythritol, tall oil fatty acid
polymer
[*660?0-84-6]
Phthalic anhydride, benzoic acid,
pentaerythritol, tall oil fatty acid,
tall oil polymer
[*66070-74-42
H001-4779
Phthalic anhydride, JD-J;-butylbenzoic
acid, glycerin, pentaerythritol, linseed
oil, dehydrated castor oil polymer
[*6GO?1-70-Z1
H001-4884
Phthalic anhydride, jo-jb-butylbenzoic
acid, glycerin, pentaerythritol, linseed
oil, dehydrated castor oil, styrene polymer
1*66071-60-11
H001-W2
Phthalic anhydride, p-tert-butylbenzoic
acid, trimethylolethane, dehydrated castor
oil polymer
1*66071-44-1]
H001-5084
Phthalic anhydride, p-tert-butylbenzoic
acid, trimethylolethane, pentaerythritol,
soybean oil fatty acid, castor oil polymer
r*66071-42-91
HOOl-5199
Phthalic anhydride, fatty acids dehydrated
castor oil, pentaerythritcl, trimethylc:
olethane polymer
[*66071-02-1J
H001-5216
Phthalic anhydride, glycerin, bisphenol A
bis(2-hydroxypropyl)ether, safflower oil
polymer
r*66071-66-71
HOOl-5339
Phthalic anhydride, glycerin, castor oil
polymer
[*660?0-88-0]
69
-------
Phthalic anhydride, glycerin, coconut
oil polymer
[^66070-87-9] H001-5556
Phthalic anhydride, glycerin, dehydrated
castor oil polymer
1*66071-50-9] H001-5669
Phthalic anhydride, glycerin, linseed
oil polymer
[*66070-59-5J E001-5782
Phthalic anhydride, glycerin, linseed
oil, tung oil polymer
[*66071-18-91 H001-5806
Phthalic anhydride, glycerin, linseed oil,
vinyltoluene polymer
Phthalic anhydride, glycerin, pentaerythc:
ritol, cottonseed oil polymer
[*60071-76-31 H001-5919
[*6607 0-92-6] H001-6096
Phthalic anhydride, glycerin, pentaerythc:
ritol, linseed oil polymer
[*66070-66-4J H001-6112
Phthalic anhydride, glycerin, pentaerythc
ritol, linseed oil and soybean oil polymer
C*6e070-65-3] H001-6226
Phthalic anhydride, glycerin, pentaeryth:
ritol, linseed oil, styrene polymer
r*6C071-63-4J
Phthalic anhydride, glycerin, pentaeryth:
ritol, safflower oil polymer
[*66071-07-6] H001-6455
Phthalic an?iydride, glycerin, pentaerythc
ritol, soybean oil and dehydrated castor
oil polymer
[*6G071-56-5] H001-6562
Phthalic anhydride, glycerin, pentaerythc:
ritol, soybean oil, dehydrated castor oil,
styrene polymer
L*66071-E>7-6] HOC 1-6671
Phthalic anhydride, glycerin, pentaerythc
ritol, soybean oil polymer
[*66070-93-7] H001-6792
70
-------
Phthalic anhydride, glycerin, pentaerythc
ritol, soybean oil, tall oil fatty acid
polymer
[*66070-97-2] H001-6812
Phthalic anhydride, glycerin, pentaerythc
ritol, tall oil fatty acid polymer
1*66070-62-0] H001-6922
Phthalic anhydride, glycerin, pentaerythc
ritol, tall oil polymer
i'*C6071-30-5] H001-7012
Phthalic anhydride, glycerin, pentaerythritol,
soybean fatty acid polymer [*66Q?0-98-2] H001-7129
Phthalic anhydride, glycerin, soybean oil,
oiticica oil polymer
[*66070-81-31 H001-7233
Phthalic anhydride, glycerin, soybean oil
polymer
[*66070-61-9J H001-7359
Phthalic anhydride, glycerin, soybean oil,
tall oil fatty acid polymer
[*660?0-69-71 H001-7463
Phthalic anhydride, glycerin, tall oil
fatty acid polymer
C*P6070-71-1] H001-7579
Phthalic anhydride, glycerin, tall oil
fatty acid polymer
[*660?0-82-41 H001-7687
Phthalic anhydride, linseed oil, pentaeryo
thritol, dipentaerythi--'. tol polymer
L*660?0-95-9J HOC1-7712
Phthalic anhydride, pentaerythritol,
ethylene glycol, coconut oil polymer
r*66070-89-U H001-78;
Phthalic anhydride, pentaerythritol,
linseed oil polymer
H001-7935
Phthalic anhydride, pentaerythritol,
soybean oil polymer
[*66070-60-8J H001-8021
Phthalic anhydride, pentaerythritol,
soybean oil polymer, ester with
hydrcabietyl alcohol 71
[*66071-S3-2] H001-rl"50
-------
Phthalic anhydride, pentaerythritol,
soybean oil, trimethylolpropane polymer
1*66071-01-01
HO 01- 8
Phthalic anhydride, pentaerythritol,
trimethylolethane, soybean oil, safflower
oil polymer
[*660?l-00-9]
H001-8362
Phthalic anhydride, pentaerythritol,
tung oil, tung oil fatty acid, linseed
oil fatty acid polymer
[*660?1-1Z-41
H001-8471
Phthalic anhydride, trimethylolethane,
cottonseed oil fatty acid polymer
r*66070-99-S]
H001-8582
Phthalic anhydride, trimethylolethane,
pentaerythritol, dehydrated castor oil,
methylmethacrylate, styrene polymer
1*66071-72-6]
H001-8696
Phthalic anhydride, trimethylolethane,
tall oil fatty acid polymer
[*66070-8Z-51
H001-8711
Phthalic anhydride, triraethylolpropane,
tall oil fatty acid polymer
C.*e6070-86-8]
H001-8831
Poly[oxy[methyl(2-phenylethyl)silylene]],
a-hydro-^-hydroxy-, polymer with a-hydro-c:
w-hydroxypoly[oxy(dimethylsilylene],
phthalic anhydride, pentaerythritol, soybean
oil polymer [*66071-34-9J
HOOl-89^7
Rosin, fumaric acid, phthalic anhydride,
glycerin, soybean oil, dehydrated
castor oil polymer
[*6C071-47-41
H001-9032
Eosin, isophthalic acid, pentaerythritol,
linseed oil polymer
i*66071-55-4J
Rosin, isophthalic acid, trimellitic
anhydride, trimethylolpropane, linoleic
acid polymer
f*66072-58-7]
H001-9256
72
-------
Rosin, linseed oil modified gilsonite
polymer
[*66071-37-2] H001-9377
Rosin, methyl abietate, modified menhaden
oil polymer
L*66071-27-01 H001-9485
Rosin modified phthalic anhydride, glycerin,
linseed oil, oiticica oil polymer
1*66071-72-51 H001-9595
Resin modified phthalic anhydride,
glycerin, safflower oil polymer
[*e.6071-68-91 H001-9614
Rosin modified tung oil, linseed oil,
soybean oil, glycerin polymer
[*66071-21-41 H001-9721
Rosin modified tung oil polymer
r*6607l-l9-OJ H001-9846
Rosin, phenol, formaldehyde, phthalic
anhydride, glycerin, linseed oil,
tung oil polymer
L*66070-68-6] H001-9952
Rosin, phthalic anhydride, fatty acids,
dehydrated castor oil, glycerin, linseed
oil polymer
[*66071-28-11 H002-0092
Rosin, phthalic anhydride, glycerin,
linseed oil, soya oil, tung oil
polymer
[*660?0-70-01 H002-0114
Rosin, phthalic anhydride, glycerin,
pentaerythritol, tall oil fatty acids
polymer
r*66071-?9-2J H002-0226
Soya oil, oiticica oil modified tripentaero
ythritol, dicyclopentadiene polymer
[*66071-2S-81
Soybean oil fatty acid, bisphenol A,
epichlorohydrin polymer
^66070-76-61 H002-OH53
Soybean oil fatty acid, dimer fatty
acid, bisphenol A, epichlorohydrin
polymer
[*66070-80-2] H002-0565
-------
Styrene, methylmethacrylate, phthalic
anhydride, pentaerythritol, ethylene
glycol, safflower oil polymer
1*66071-71-41 H002-0672
Sulfur, isobutylene polymer
[66085-57-21 HOOP-0795
Tall oil fatty acid, oiticica oil, rosin,
formaldehyde, phenol, styrene, allyl
alcohol polymer
1*66071-29-?.] H002-0811
Tetraethyl silicate, ethylene glycol
polymer
[28742-72-2}
H002-09°7
Toluene 2,4-diisocyanate, castor oil
polymer
1*66071-12-3] H002-1016
Triethylenetetramine, linoleic acid
dimer polymer
16COS5-55-0] H002-1128
Trimellitic anhydride, adipic acid,
dehydrated castor oil fatty acid,
bisphenol A, epichlorohydrin polymer
1*06071-05-4]
Trimellitic anhydride, adipic acid,
dehydrated castor oil fatty acid,
bjsphenol A, epichlorohydrin polymer,
compound with ammonia
H002-1351
Trimellitic anhydride, azelaic acid,
dehydrated castor oil fatty acid, bisphenol
A, epichlorohydrin polymer
r*CG071-04-31 H002-1463
Trimellitic anhydride, azelaic acid,
dehydrated castor oil fatty acid,
bisphenol A, epichlorohydrin polymer,
compound with 2-(dinethylamino)ethanol
r*6C071-62-3J H002-1577
Tung oil, m-cresol, formaldehyde polymer
r*6C07i-io-ll H002-1686
Tung oil, dicyclopentadiene, formalde:
hyde, phenol polymer
[*G6071-7t-7] H002-1715
74
-------
Tung oil, linseed oil, maleic anhydride,
phenol, formaldehyde polymer
H002-1R23
Tung oil modified formaldehyde, phenol
polymer
L* CCO? 1-1"-?] H002-1933
Tung oil, jD-phenylphenol, formaldehyde,
phenol polymer
r*rcfl?l-G9-01 H002-2021
Tung oil, soybean oil, formaldehyde,
phenol, dicyclopentadiene polymer
75
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SECTION IX
CHEMICAL SUBSTANCES MANUFACTURED
AS PART OF MIXTURES
Developed in Conjunction with:
The Portland Cement Association
The Glass Packaging Institute
Corning Glass Works
Owen-Illinois, Incorporated
The Porcelain Enamel Institute
Chemical Substances Manufactured
in the
Production of Portland Cement [*65997-15-l] HOOO-7151
Portland cement is a mixture of chemical substances produced
by burning or sintering at high temperatures (greater than 1200°C)
raw materials which are predominantly calcium carbonate, aluminum
oxide, silica, and iron oxide. The chemical substances which are
manufactured are confined in a crystalline mass.
This category includes all of the chemical substances specified
below when they are intentionally manufactured in the production of
Portland cement. The primary members of the category are Ca2SiC>4
and CasSi05. Other compounds listed below may also be included in
combination with these primary substances.
CaAl204 Ca2Al2SiOT
CaAl407 Ca4Al6SOi6
CaAlisOie Ca12Ali 4C12032
Ca3Al206 Cai2Ali4F2032
Ca12Ali4033 Ca4Al2Fe2Oio
CaO Ca6Al4Pe2Oi 5
Ca2Fe205 Ca3Ti05
CaS04 K2S04
Na2S04
77
-------
Chemical Substances Manufactured
in the
Production of High-Alumina Cement [*65997-16-2] HOOO-7274
High-Alumina cement is a mixture of chemical substances
produced by burning or sintering at high temperature (greater
than 1200°C) raw materials which are predominantly calcium
carbonate, aluminum oxide, silica, and iron oxide. The
chemical substances which are manufactured are confined in
a crystalline maSs.
This category includes all of the chemical substances
specified below when they are intentionally manufactured in the
production of high-alumina cement. The primary members of
this category are CaAl204, Ca4Al2Fe2Oi 0, Cai2Ali4033, and
Ca2Si04. Other compounds listed below may also be included
in the combination with these primary substances.
CaAl407 Ca2Al2SiOT
CaAli2Oig Ca4Al6SOi6
Ca3Al206 Cai2Ali4Cl2032
CaO Cai2Ali4F2032
Ca3Si05 CasAl4Fe2Oi5
Ca2Fe205 Ca3Ti05
CaS04 K2S04
Na2S04
Chemical Substances Manufactured
in the
Production of Inorganic Glass [*65997-17-3] HOOO-7384
This category encompasses the various chemical substances
manufactured in the production of inorganic glasses by the
glass industry. For purposes of this category, '' glass11
is defined as: ''An amorphous, inorganic, usually transparent
or translucent substance consisting of a mixture of silicates,
or sometimes, borates or phosphates, formed by a fusion of
silica, or of oxides of boron or phosphorous, with a flux and a
stabilizer, into a mass that cools to a rigid condition without
crystallization.'1 This category consists of the various
chemical substances (other than byproducts or impurities)1 which
are (l) formed in melting furnaces during the production of
various glasses and concurrently incorporated into a glass
mixture and (2) reportable for the inventory unless excluded,
e.g., under section 710.4(d) of the EPA regulations. These
are substances whose presence and form are, insofar as identified
herein, known, assumed, or reasonably ascertainable. Any glass
contains one or more of these substances, but few, if any, contain all
of them. In this category description, chemical substances are
generally identified in the conventional nomenclature used by
the glass industry2. The elements listed below are principally
present as oxides but may also be present as halides or sulfides,
78
-------
in multiple oxidation states, or in more complex compounds.
An oxides or other compounds (other than byproducts or im-
purities) which are not identified herein but which are
present in some glasses are neither known nor reasonably
ascertainable, and any such substances probably are present only
in very small proportions, e.g., less than one percent.
The following elements are principally present as oxides
but may also be present as halides (fluorides, chlorides,
bromides, or iodides) or sulfides, in multiple oxidation states,
or in more complex compounds. Oxides of the first seven elements
listed* collectively comprise more than 95 percent, by weight,
of the glass produced in the United States.
Aluminum*
Boron*
Calcium*
Magnesium*
Potassium*
Silicon*
Sodium*
Antimony
Arsenic
Barium
Bismuth
Cadmium
Carbon
Cerium
Cesium
Chromium
Cobalt
Copper
Germanium
Gold
Holmium
Iron
Lanthanum
Lead
Lithium
Manganese
Molybdenum
Neodymium
Nickel
Niobium
Phosphorus
Praseodymium
Rubidium
Selenium
Silver
Strontium
Tin
Titanium
Tungsten
Uranium
Vanadium
Zinc
Zirconium
HO C.F.R. 710.Md) (l)-(2) (42 Federal Register 64577).
2Common references on glass composition and structure include
(l) G.W. Morey, The Properties of Glass, 2nd edition,
Reinhold Publication Corporation (1938).
(2) J.R. Hutchins and R.V. Harrington, ''Glass,11
Encyclopedia of Chemical Technology, 2nd edition,
pages 533-604, John Wiley and Sons, Inc. (1968).
(3) F.V. Tooley, the Handbook of Glass Manufacture,
Ogden Publication Company (Volume 1, 197*0.
79
-------
Chemical Substances Manufactured
in the
Production of Frit [*65997-18-4] HOOO-7493
Frit is a mixture of inorganic chemical substances produced
by rapidly quenching a molten, complex combination of materials,
confining the chemical substances thus manufactured as non-
migratory components of glassy solid flakes or granules.
This category includes all of the chemical substances
specified below when they are intentionally manufactured in
the production of frit. The primary members of this category
are oxides of some or all of the elements listed below.
Fluorides of these elements may also be included in combination
with these primary substances.
Ag Ca K Nb Sn
Al Cd La Nd Sr
As Ce Li Ni Ti
Au Co Mg P V
Ba Cr Mn Pb W
Bi Cu Mo Sb Zn
B Fe Na Si Zr
80
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SECTION X
OTHER CLASS 2 CHEMICAL SUBSTANCES
Developed in Conjunction
with the
Leather Tanners Council
International Technical
Caramel Association
Corn Refiners Association
-------
Hair and Hair Pulp [*65997-21-9] HOOO-7512
A biological material consisting predominantly of partially
hydrolyzed keratin.
Recovered Vegetable Tannins [*6599?-20-8] HOOO-7626
A complex combination of vegetable tanning materials recovered
from the tanning of leather. It consists of natural tannins, which
are predominantly polyphenolic compounds, and/or synthetic tannins,
such as aromatic sulfonic acid derivatives.
Caramel (Color) [*8028-89-5] HOOO-77^3
Substance obtained by controlled heat treatment of food-grade
carbohydrates. Food-grade acids, alkalies, and salts may be used
to assist carmelization. Food-grade antlfoaming agents may be
used in an amount not greater than that required to produce the
intended effect. Consists essentially of colloidal aggregates
that are dispersible in water but only partly dispersible in
alcohol-water solutions. Depending upon the particular
carmelizing agent used, may have a positive or negative colloidal
charge in solution.
Corn Gluten Meal [*66071-96-3] HOOO-7967
The dried residue from corn after the removal cf the larger
part of the starch and germ and the separation of the bran in the
wet-milling manufacture of corn starch or syrup, or by enzymatic
treatment of the endosperm.
Corn S teep w at_er [^66071-94-1] HOOO-805^
Synonym: Condensed Fermented Corn Extractives
Substance obtained b;y the partial removal of water from the
liquid resulting from steeping corn in a water and sulphur dioxide
solution which is allowed to ferment by the action of naturally
occurring lactic acid-producing microorganisms.
Starch Molasses [*8052-91-3] HOOO-8163
A by-product of the manufacture of dextrose from starch derived
from corn or grain sorghum. The starch is hydrolyzed by the use
of enzymes and/or acid.
82
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Castor oil, dehydrated
Castor oil fatty acids, diethanolc:
amine salt
Castor oil fatty acids, isopropylo
arainoethanol salt
Castor oil fatty acids, raonoethano^
lamine salt
Castor oil fatty acids, triethanolo
amine salt
Castor oil, hydrogenated, calcium salt
Coconut oil acids, monoethanolamine salt
Cod oil fatty acids, ammonium salt
Cottonseed fatty acids, potassium salt
Cottonseed fatty acids, sodium salt
Lard oil fatty acids, ammonium salt
Lard oil fatty acids, diethanolamine salt
Lard oil fatty acids, monoethanolamine salt
Lard oil fatty acids, potassium salt
Lard oil fatty acids, sodium salt
Lard oil fatty acids, triethanolamine salt
Naphthenic acids, petroleum, potassium salt
Palm oil fatty acids, diethanolamine salt
Palm oil fatty acids, monoethanolamine salt
Palm oil fatty acids, potassium salt
Palm oil fatty acids, triethanolamine salt
Tall oil acids, cyclohexylamine salt
Tall oil acids, monoethanolamine salt
Tall oil acids, triethanolamine salt
[*64147-40-6]
1*66071-87-22
[*66071-8Z-8]
1*66071-85-0]
[*66071-88-3J
1*66072-09-1]
1*66071-80-5]
1*66071-97-4]
[*66071~93-OJ
[*66071-95-2]
[*66072-01-31
[*66071-99-6J
[*66071-98-5]
:*66072-02-4]
r*66072-OZ-5]
^66072-00-2]
[*66072-08-01
[*66072-05-7]
L*G6072-04-6]
[*66072-07-9]
[*66072-06-8]
[*66071-89-4]
[*66071-90-71
[*66071-91-8]
H002-2243
H002-2368
H002-2470
H002-258?
H002-2692
H002-271J4
H002-2851
H002-2^^:9
H002-3032
H002-3143
H002-5252
H002-3371
H002-3^85
H002-5590
H002-3615
I-I002-3724
H002-3842
H002-3955
;I002-4044
H002-4158
H002-4262
H002-4381
H002-4404
H002-4513
83
-------
Tallow acids, hydrogenated, calcium salt [*66071-81-62 H002-ll621
Tallow acids, hydrogenated, lithium salt [*660?l-P2-?i H002-4731
Tallow acids, hydrogenated, triethanol" [*66071-84-9J H002-4856
amine salt
84
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