united biates august Environmental Protection 1984 Agency • • Lime Handling Systems Problems and Remedies 905R84121 Z30 South Dearbbrti Street ------- Lime Handling Systems - Probims Introduction Lime is one of the most widely-used chemicals for wastewater treatment. It is marketed either as quick- lime (CaO) or hydrated lime (Ca(OH)2). Quicklime is hydrated in a slaking process before it is used as a process chemical. Lime is generally added to treat- ment processes as a slurry. Lime is used in wastewater treatment for chemical coagulation of solids, phosphate precipitation, pH adjustment, and chemical stabilization of sludge. Numerous problems have been experienced with lime handling systems. These problems affect the performance of treatment processes, resulting in poor effluent quality, and increased operation and maintenance costs. A comprehensive evaluation of selected advanced treatment (AT) facilities utilizing lime treatment processes was recently completed with the objective of identifying common problems associated with lime handling systems. This brochure i -ily summarizes the causes and impacts of these problems, and offers suggestions on how to solve them or at least mitigate their impact. The Lime Handling System The lime handling system consists of a series of operations that process raw lime (i.e. quicklime or hydrated lime) into a slurry which is then applied to wastewater in measured portions. A schematic pf a typical lime handling system is shown in Figure 1. Lime handling systems typically include the following components: (1) loading/unloading facility, (2) storage and dry feeder, (3) lime slaker, (4) slurry tanks, (5) slurry transport lines, and (6) slurry feed system. The following discussion of problems and remedies addresses each of these components. The major problem areas for lime handling systems are identified in Figure 1. Vent * Major "Problem" Areas. • Recirculation Loop May Be Found In Intermittent Type Lime Feed Systems Lime Loading -I. pH Indicator/ Recorder ../-, .-:=- :>:c7i '?- •v.-«-:!'v.-"/ VJ Agency Figure! Schem^ipga MHnajHao^g4*»Jet»' ...... f;.--• South Dearborn Street On >;w, fllfnois ------- Lime Loading/unloading Problems associated with the lime loading/unloading operation include generation of lime dust, severe damage of dry lime transport piping due to abrasion at sharp elbows and bends, and rupture of the lime bin due to buildup of excessive pressure inside the bin. To minimize these problems, dust collection baghouses should be installed on lime storage bins and checked after each loading operation; pressure relief valves should be installed on lime bins; and long-radius piping should be used for lime transport. Lime Storage In lime storage bins, the flow of lime to the dry lime feeders is often interrupted by "arching" or "bridging" of the dry lime above the hopper opening. Moisture in the storage bin can cause the lime powder to "cake," thereby preventing it from flowing freely. The lime storage bin should have a minimum 60° bottom slope to facilitate the flow of material into the feed hopper. A vibrating "live bin" bottom helps to minimize "arching" and "bridging" problems. To prevent the entry of moisture into the bin, a rotary ball valve should be installed at the bottom of the bin. In cases where bagged lime is used, the bulk storage area should be adequately ventilated and the humidity controlled to avoid "caking" problems. Lime Slaking Incorrect slaking temperature and water to lime ratios in the slaking operation can result in poor quality hydrated lime. If the slaker is not operated under negative pressure, steam and moisture travels back into the feeder and lime bin and causes "caking" problems. Instrumentation panels located on or adjacent to the slaker are often covered with lime dust and grit resulting in frequent breakdown of equipment. Lime slakers should be airtight and operated under negative pressure. A fan may be used to draw out vapors to help maintain negative pressure in the slaker. Instrumentation panels should be separately housed and located away from the slaker. Lime Slurrying A severe problem of abrasion occurs if fiber rein- forced plastic (FRP) tanks are used for slurry pre- paration. Tanks made of corrosion resistant metal should be used to avoid abrasion problems. Probes used for level control in the slurry tank are often coated with lime solids and rendered ineffective. Sonic-type slurry level sensor systems can be used to mitigate this problem. Lime blurry Transport The clogging of lime slurry lines is one of the most difficult problems in a lime handling system. Scaling in lime slurry piping is caused by the leakage of air into pipes (which leads to formation of calcium carbonate) and settling of solids during off cycles. Use of small diameter slurry lines aggravates this problem Cleaning of scale in pipes can be very labor intensive, particularly in metal pipes where "cleanouts" are not provided. Problems with lime slurry transport systems can be minimized by: continuously recirculating the lime slurry through a recirculation loop (see Figure 1); using flexible hoses for slurry transport lines; mini- mizing the number of sharp bends; using piping at least one and a half to two inches in diameter, and periodically flushing the lines with water. Slaked Lime c D Figure 2 Lime Feed System With Rotary Cup Type Feeder Lime Slurry Feed Common problems of lime slurry feed systems in- clude clogging of metering pumps and valves, and encrustation of pH probes. It is important to locate the take-off point from the slurry line as close as possible to the point of lime slurry application. Rotary cup type feeders or similar slurry feed systems should be used whenever possible. Figure 2 presents a typical lime slurry feed system using a rotary cup type feeder. Feed control valves which are operated in a fully opened or fully closed mode should be used rather than variable rate type valves. The problem of malfunctioning pH probes can only be solved by routinely checking the probe, and cleaning it when needed. One method of preventing probe failure due to fouling is to rotate the use of alternate probes on a regular basis. i ------- Conclusions Based on the performance evaluation of lime han- dling systems, it is clear that these systems are prone to problems of equipment malfunction, and, in general, require frequent maintenance and operator attention. Deficiencies in design and inadequate operation and maintenance of lime handling systems are the major causes of the problems. The inherent nature of lime and its limited solubility in water are also responsible for some of these problems. The performance of existing lime handling systems can be significantly improved by incorporating rem- edial measures at a reasonable cost. A summary of the major problems with lime handling systems and suggested improvements is presented in Table 1. Problem • Lime dust generation • Abrasion of dry lime transport lines • "Arching" of dry lime in feed hopper • "Caking" of lime in feed hopper * Poor quality slaked lime. • Malfunctioning of instrumentation located near slaker. • Abrasion of lime slurrying tanks • Encrustation of probes used for slurry level control • Clogging of lime slurry transport lines Clogging in lime slurry feed system • Encrustation of pH probes Remedy • Install baghouse on lime silos. • Use long radius bends and heavy duty elbows. • Install "live" bin systems. • Operate slaker under negative pressure and install rotary valve under the feeder. • Maintain proper temperature and water content in slaker. • Locate instrumentation away from slaker. • Use corrosion resistant metal tanks (not FRP). • Use sonic-type level sensor systems. • Install lime slurry recirculation loops; flush transport lines with water; use flexible hoses; avoid sharp bends; use minimum "P/2 to 2 inches diameter piping. • Minimize distance between recirculation loop and feeder; use open/close type valves; use rotary cup type feeder. • Rotate the use of alternate pH probes. Table 1 Lime Handling Systems: Summary of Problems and Sug< ad Remedies ------- |