RESULTS OF 196? SAMPLING PROGRAM
DETROIT PROGRAM OFFICE
U.S. DEPARTMENT OF THE INTERIOR
Federal Water Pollution Control Administration
Great Lakes Region
Detroit Program Office
U.S. Naval Air Station
Groese He, Michigan
-------
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Pinconning
Quanicassee
Pigeon
Pinnebog
Bird Creek
Mill Creek
Table 5
1967 Stream Gaging Results
Lake Huron Tributaries
Date Operation Location
6-5 W900
7-11 ¥900
7-18 Mackinaw Road Br. (l)
8-10 W900
7-12 W530
7-18 W620
7-12 W530
7-18 Russel St. Br. (2)
8-11 W530
7-17 W520
7-17 W510
8-11 W510
5-17 W500
7-17 W500
7-17 Y600
Discharge (CFS)
reverse
61
56
8
0
60
1
0
Uo
0
2
reverse
0
(l) Located approximately 3 miles upstream from W900.
How was not measurable at W900.
(2) Located approximately 3 miles upstream from W530.
Flow was not measurable at W530.
18
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FIGURE 9
DETROIT PROGRAM OFFICE
SAMPLING RANGES
ST. CLAIR RIVER
U.S. DEPARTMENT OF THE INTERIOR
FEDERAL WATER POLLUTION CONTROL ADMINISTRATION
9REAT LAKES RESIGN 9ROSSE ILE, MICHIGAN
SR 39.C
SCA LE IN MILES
10 I 23486789
PORT HURON ) // SARNfA
PORT LAMBTON
SR 13.7
LAKE
5 T CLAIR
-------
Range; SR 39» 0
Station:
Ft. from
Shore
Table 7
1967 Sample Analysis Results
St. Clair River
P30 P31
100 800
FWPCA, DK)
Date
Analysis; Temperature ( C)
4-18
5-2 -
6-1
6-22
8-15
9-25
10-24
n-i3
Average
Analysis:
4-18
5-2
6-1
6-22
Average
Analysis:
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
. 8.5
7-0
12.0
16.5
20.0
15-5
11.5
5-5
12.0
Conductivity (umhos/cm)
210
200
220
220
210
Chloride (ag/l)
6
7
6
7
7
7
6
6
4.5
6.5
11.0
16.5
20.0
16.0
11.5
7.0
4.5
7.0
n.o
15-5
20.0
16.0
11.5
8.0
11.5
200
200
210
220
210
4
6
9
7
4
6
11.5
210
200
210
220
210
6
6
5
7
4
6
Average
23
-------
Table 7
1967 Sample Analysis Results
St. dair River
Range: SR 39.0
Station:
Fb. from W. Shore
Date
Analysis; Phenol (ug/l)
4-18
5-2
6-1
6-22
8-15
9-25
10- 2k
11-13
Average
Analysis: P.O. (mg/l)
5-2
6-1
6-22
8-15
Average
Analysis;
5-2
6-1
6-22
8-15
9-25
10- 2k
11-13
Total PO). (mg/l)
P30
100
6
3
< 1
6
k
6
5
3
10.8
12.3
10.6
9-7
10.5
.1*8
< .01
• 03
.01
.02
.09
.26
.10
3
9
< 1
3
3
9
5
5
10.8
FHPCA, DPO
P32
1500
3
5
< 1
10
3
9
8
3
11.5
12.3
11.1
10.1
9.1
12.0
11.1*
10.8
10.5
8.8
10.7
.08
.01
.07
.02
.02
.08
.13
.Olf
.06
< .01
.01
.01
.03
.06
.07
.06
Average
.12
.06
-------
Table 7
1967 Sample Analysis Results
St. Clair River
Range; SR 39«0
Station:
Ft. from W. Shore
Date
Analysis; Total Sol* PO) (mg/l)
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average
Analysis;
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average
Analysis;
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average
Nitrate (mg/l)
Ammonia-N (mg/l)
.29
< .01
.01
.01
.02
.02
.22
.07
.08
.8
< .1
.1
.1
.2
.2
< .1
.2
.2
.59
.15
.08
.08
.05
.26
.09
.07
.17
P31
800
.02
< .01
• 07
.01
.02
.04
.08
.03
.04
.2
.17
< .05
.16
.06
.11
.15
.11
.06
.11
FWPCA, DPO
.01
< .01
.01
.01
.02
.05
.06
.06
.03
< .1
< .1
.1
.1
.2
.2
.1
.3
.1
< .1
.1
< .1
.2
.1
.2
.1
.1
.11
.07
.05
.07
.09
< .05
.12
.11
.08
25
-------
Table 7
1967 Sample Analysis Results
St. Clair River
Range; SR 35?.Q
Station:
Ft. from W. Shore
Date
Analysis; Organic-N (mg/l)
P30
100
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average
Analysis:
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Median
Analysis:
4-18
5-2
6-1
6-22
8-15
.10
< .05
.08
.11
.12
< .05
< .05
.07
.08
Total Coliform (MF/100 ml)
1600
< 10
< 10
< 10
< 10
170
< 10
7
< 10
Total Solids (ms/l)
270
140
160
160
160
P31
800
.08
Average
180
< 10
20
< 10
< 10
500
10
48
< 10
110
160
140
150
160
i4o
FWPCA, DPO
P32
1500
.10
< .05
.08
.11
.12
< .05
< .05
.07
.18
< .05
.05
.08
.09
< .05
.09
.06
< .05
.06
< .05
.11
.08
< .05
.07
< .05
.06
20
< 10
< 10
< 10
<10
260
< 10
28
< 10
130
130
140
i4o
150
l4o
26
-------
Table 7
1967 Sample Analysis Results
St. Clair River
Range; SR 39-0
Station:
Ft. from W. Shore
Date
Analysis; Dissolved Solids (mg/l)
4-18
5-2
6-1
6-22
8-15 '
P30
100
120
i4o
Average
Analysis:
Suspended Solids (mg/l)
4-18
5-2
6-1
6-22
8-15
Average
Analysis;
4-18
6-22
9-25
11-13
Average
Sulfate (mg/l)
160
150
140
150
1
22
2
5
36
17
16
12
14
15
P31
800
100
130
150
150
130
16
n
16
2
6
10
Ik
16
11
Ik
FWPCA, DPO
100
120
120
130
iko
120
27
11
17
1
7
13
Ik
17
11
Ik
Ik
27
-------
Table 7
1967 Sample Analysis Results
St. Clair River
Range; SR 13.7 "
Station:
Ft. from W. Shore
Date
/
Analysis; Temperature (
FtfPCA, DPO
P56
100
P57
TOO
Average
Analysis; Chloride (mg/l)
4-lS
5-2
6-1
6-22
8-15
9-25
10-24
n-13
Average
230
220
9
7
7
16
8
6
8
10
8
6
6
7
8
4
7
7
210
220
P60
1900
4-18
5-2
6-1
6-22
8-15
9-25
10- 2^
n-13
Average
Analysis:
4-18
5-2
6-1
6-22
7.0
8.0
12.5
17.5
20.5
15-5
12.0
6.5
12.5
Conductivity (umhos/cm)
240
220
220
240
6.0
7.0
12.0
16.5
20.0
15.5
11.5
8.0
12.0
240
200
210
230
*-5
7-0
11.5
16.5
20.0
15-5
11.5
8.0
12.0
210
200
210
220
4.5
7.0
11.5
16.5
20.0
15.5
11.5
7-5
12.0
210
220
220
230
*-5
7.0
12.0
16.5
20.0
15-5
n.5
8.0
12.0
230
260
240
240
240
5
7
6
6
8
3
6
6
3
10
8
8
n
8
7
6
13
20
13
13
13
11
16
n
8
14
28
-------
5
4
1
< 1
7
5
3
5
1
5
< 1
< 1
3
4
5
5
1
6
< 1
< 1
1
6
5
2
2
9
< 1
1
3
4
4
7
2
8
< 1
2
4
7
6
5
Table 7
1967 Sample Analysis Results
St. Clair Elver
Range: SR 13.7 FWPCA, DPO
Station: P56 P57 P58 P59 PoO
Ft. from W. Shore 100 700 1000 l400 1900
Date
Analysis; Phenol (ug/l)
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average
Analysis; P.O. (mg/l)
5-2
6-1
6-22
8-15
Average 10.4 10.5 10.8 10.6 10.3
Analysis: Total PP. (tng/l)
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average .10 .07 .05 .05 .07
10.7
11.8
10.8
9-7
8.9
11.2
11.8
10.7
9-9
9.0
12.0
11.8
10.9
10.0
9.0
11.9
11.7
10.7
10.0
8.9
11.3
11.1
10.8
9.8
8.8
.20
.02
.03
.03
.04
.32
.11
.09
.11
.01
.02
.02
.04
.11
.12
.10
.09
.02
.02
.01
.03
.09
.06
.05
.04
.01
.02
.05
.04
.08
.08
.04
.08
.02
.02
.07
.08
.09
.10
.07
29
-------
Table 7
1967 Sample Analysis Renults
St. Clair River
Station:
Ft. from W. Shore
Date
Analysis; Total Sol. POj,
6-22
8-15
0-25
10-24
11-13
Average
Analysis:
5-2
6-22
8-15
9-25
10-24
11-13
4-18
5-2
•'-22
d-15
9-25
10-24
11-13
Nitrate (ing/l)
Analysis; Ammonia-N (mg/l)
100
- Oo
• •'; i
.03
,29
,07
,07
• 5
< .1
.2
.1
.2
.2
.1
.2
.18
.13
,09
.11
.10
,08
-09
.05
FWPCA, DPO
P57
700
.01
,01
,02
,02
.07
,03
.09
.04
.3
.1
.1
.1
,2
s2
.1
,4
,2
.-6
!l6
.15
.09
.10
• 1 0
- "'
?58
1000
.04
.01
< ,01
. 01
.OP
,0^
.04
.Oil
.OH
.1
.1
.1
< .1
.2
.1
.2
.2
.1
,08
< ,,05
,08
,12
»05
.14
.10
< .05
P59
Ij400
,01
< .01
.01
.03
.03
.04
.,04
o04
.03
.1
< .1
.2
.1
.2
.2
.1
• 5
.2
.11
.26
.08
.10
.10
< • ";>
--13
.10
P60
1900
i •
, • j
.05
•.07
,05
.04
.05
.04
.1
•: .1
.2
.1
.2
.2
.2
.3
.2
.07
• 39
.39
.16
.36
.20
.18
.11
Average
.08
.12
.23
-------
Range; SR 13.7
Station:
Ft. from W. Shore
Date
Table 7
1967 Sample Analysis Results
St. Glair River
P56
100
FWPCA, DPO
Analysis; Organic-N (mg/l)
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Average
.06
Analysis; Total Coliform (MF/100 ml)
4-18
5-2
6-1
6-22
8-15
9-25
10-24
11-13
Median
Analysis; Total Solids(rog/l)
4-18
5-2
6-1
6-22
8-15
Average
650
180
.07
560
160
.08
390
140
.06
320
< .05
< .05
.05
.07
.05
.06
.10
< .05
< .05
< .05
•05
.07
.08
.08
.08
.09
< .05
< .05
.05
.14
.09
.11
.08
.10
< .05
< .05
-
.09
< .05
.09
.06
< .05
.07
.08
.06
.12
.08
.08
< .05
< .05
.07
4200
700
200
3100
100
560
600
740
2900
780
40
1700
190
500
no
610
900
300
< 10
450
720
1000
no
330
100
590
30
820
510
2500
no
120
500
740
120
2500
2700
5000
770
320
760
250
150
160
190
160
180
140
170
160
160
130
100
150
150
160
no
i4o
150
160
170
120
170
160
160
170
150
160
31
-------
Table 7
1967 Sample Analysis Results
St. Clair River
Range; SR 13.7
Station:
Ft. from W. Shore
Date
Analysis: Dissolved Solids
P56
100
P57
700
Average 150
Analysis; Suspended Solids (mg/l)
Average
20
140
4-18
5-2
6-1
6-22
8-15
Average
Analysis: Sulfate (mg/l)
4-18
6-22
9-25
11-13
110
10
20
1
11
30
2k
17
21
20
59
8
2k
9
9
22
22
16
31
17
22
130
12
14
FWPCA, DPO
130
13
P60
1900
4-18
5-2
6-1
6-22
8-15
i4o
l4o
l4o
190
150
120
130
150
150
150
120
90
130
140
150
100
130
130
150
160
no
160
150
160
160
150
16
13
18
7
8
3
11
20
6
7
7
11
16
6
7
17
15
11
16
11
13
15
16
24
14
17
32
-------
FIGURE 6
LOCATION OF SAMPLING STATIONS
LAKE ST. CLAIR
-------
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Station: EL
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO-
Total Sol. P0k
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: E2
Parameter
Lab Number
Temperature (°C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total FO.
Total Sol. POi^
Nitrate-N
Aomonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Date
4-25
17426
8.5
220
11
2
10.9
.06
< .01
.3
.13
.08
< 10
54
11+
5-10
19422
8.0
220
16
4
11.6
.03
.02
.1
1.10
•15
2
11
13
6-6
23425
18.5
230
7
3
9-8
.02
.02
.1
< .05
.10
< 21
16
9
6-27
26421
21.5
220
11
2
9.4
.02
.02
.1
< .05
.07
10
2
15
Date
4-25
17425
8.5
330
15
2
10.8
.16
.04
1.2
•15
.10
60
59
3k
5-1Q
19423
10.0
370
16
4
11.3
.11
• 05
1.1
• 25
.07
3*
48
38
6-6
23426
18.5
240
13
4
11.0
.03
.02
< .1
.06
.10
< 2
12
15
6-27
26422
22.0
260
13
2
8.9
.04
.03
.1
< .05
.08
640
4
18
Average
14.0
220
11
3
10.4
•03
.02
.2
.33
.10
21
13
Average
15.0
300
14
3
10.5
.08
.04
.6
.13
.09
31
26
33
-------
Station: E3
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
Parameter
Lab Number Q
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: E4
Parameter
Lab Number
Temperature (°C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Conform (MF/100 ml)
Suspended Solids
Sulfate
is.
17427
10.5
290
14
< 1
10.3
.11
.07
.9
.17
.08
10
70
26
4-^
17424
8.0
320
15
2
10.5
.16
.10
1.1
-
_
10
61
31
Jhi2
19428
8.0
220
11
7
11.2
.05
.02
.1
.17
< .05
< 2
12
14
Date
—
19429
10.0
320
15
5
11.1
.06
.03
.6
.18
.07
8
23
3'2
6-6
23424
17.5
220
9
4
9-7
.04
.03
.1
.11
.10
< 2
15
9
6-6
23427
18.5
240
11
5
10.0
.02
.02
< .1
.16
.14
< 2
7
11
6-27
26423
20.0
230
12
5
9.0
.03
.02
.1
< .05
< .05
< 1
2
15
6-27
26427
23.0
270
13
-
9-3
.07
.04
.2
.09
.08
540
6
20
Average
14.0
240
12
4
10.0
.06
.04
.3
.12
.0?
25
16
Average
15.0
290
14
4
10.2
.08
.05
.5
.14
.10
24
24
-------
Station: E5
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/1)
D.O.
Total PO,
Total Sol. PO.
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: B6
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
4-25
17432
6.5
210
9
6
11.9
.02
.01
.1
.11
.07
< 10
20
12
^w
19424
6.5
210
10
6
12.2
.24
.02
.1
.14
.07
18
7
14
6-6
23411
19-5
230
12
3
11.8
.05
.04
.1
.12
.08
< 10
19
10
6-27
26431
19.0
220
11
-
10.0
.04
.03
.1
.06
.07
> 12
9
15
Date
4-25
17428
9.0
220
11
<1
10.9
.06
.02
• 3
.14
.06
< 10
48
Ik
5-10
19430
7.5
220
10
6
11.5
< .01
< .01
.2
.12
.05
4
12
14
6-6
23423
16.5
230
9
5
10.1
.09
.08
.1
•15
.10
2
15
9
6-27
26428
20.0
220
7
.
9-1
.04
.03
.1
.16
< .05
28
2
15
Average
13.0
220
10
5
11.5
.09
.02
.1
.11
.07
14
13
Average
13-5
220
9
4
10.4
. .05
.04
.2
.14
.06
19
13
35
-------
Station: E7
Table 8
196T Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO.
Total Sol. PO.
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: ELO
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
^-.25.
17423
7.5
280
12
< 1
10.3
.16
.05
.9
• 36
.08
) 10
86
19
4-2>
17^09
5.0
210
7
< 1
11.3
.02
.01
.2
.21
.12
30
26
17
5-lQ
19431
10.0
290
13
4
11.6
.04
.01
.6
-
.05
6
30
27
Date
5-9
19408
6.0
200
6
2
12.3
.01
< .01
.1
.12
.10
20
7
14
6-6
23428
17.5
230
10
3
10.3
.19
.17
< .1
.09
.21
< 2
10
10
6-5
23409
15-5
220
3
1
10.6
.02
.02
< .1
.10
.05
< 10
15
10
6-27
26429
a. 5
220
9
.
9.0
.03
.03
. 1
< .05
< .05
160
2
15
6-26
26409
19.0
210
6
4
9-3
.03
.03
.2
.06
.06
_
11
16
Average
14.0
260
11
3
10.3
.10
.06
.4
.17
.10
32
18
Average
11.5
210
6
2
10.9
.02
.02
.2
.12
.08
15
14
-------
Table 8
196T Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Station: Ell
Date
Parameter
4-24
2=2
Lab Number 17408 19409
Temperature (°C) 5-0 7-0
Conductivity (umhos/cm) 21° 200
Chloride 6 6
Phenol (ug/l)
D.O.
Total POU
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: EL2
< 1
11.2
.05
• v J
.01
.2
.10
.08
130
26
cJj
17
*•* |
i
12.3
.01
< .01
.1
.10
.06
<10
7
14
6-5
23408
14.5
220
3
4
10.9
.03
.02
< .1
.10
.08
<10
19
10
6-26
26408
19.0
220
7
< 1
9.1
.03
.02
.2
.10
.07
«•
11
15
Date
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO^
Total Sol. PO,
Nitrate-N
Ajnmonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
4-24
17404
5-5
220
6
<1
10.8
.07
• •** |
.02
• x/C.
0
• j
.11
• iJialp
.05
.
-------
Table 8
1967 Sample Analysis Results
Lake St. Glair
(mg/1 unless noted)
Station: EL 3
Parameter
Lab Number
Temperature (°C)
Conductivity (umhos/cm)
Chloride
Fnenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Colifona (MF/100 ml)
Suspended Solids
Sulfate
Station: El4
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Colifona (MF/100 ml)
Suspended Solids
Sulfate
Date
4-25
17429
9.0
220
7
< 1
10.6
.06
.02
.2
_
.06
4o
42
16
4-25_
17422
7.0
250
10
< 1
10.9
.21
.03
.6
.16
.10
50
90
21
5-10
19425
8.0
210
8
5
11.8
• 03
.01
.1
.10
.05
< 2
10
14
Date
5^10
19426
10.6
320
14
4
11.7
.08
.06
.8
.16
.06
8
28
2!j
M.
23422
17.0
220
7
3
10.1
• 59
• 53
.1
.06
.11
< 2
16
9
6-6
23429
16.5
230
9
4
10.2
.04
.03
.1
.06
.13
2
18
10
£i£L
26423
20.0
220
7
4
9.0
.03
.03
.2
< .05
.06
56
1
15
6-27
26424
21.0
230
10
3
8.8
.03
• 03
.1
.09
.09
10
2
15
Average
13.5
220
7
3
10.4
.18
.16
.2
.07
.07
17
14
Average
14.0
260
11
3
10.4
.09
.04
.04
.12
.10
18
34
19
38
-------
Station: P8
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
Parameter
Lab Number
/O \
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organlc-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: PI 5
4-25
17421
5-0
210
7
< 1
10.8
.31
.22
.3
.12
.08
10
70
15
5-10
19427
10.0
310
14
5
11.8
.10
.04
• 7
.15
.05
4
27
28
6-6
23^30
15.0
220
8
3
10.9
.02
.01
.1
.08
.08
6
19
9
6-27
26425
21.5
*~4. • ^
220
10
4
8.6
.03
.03
.1
< .05
< .05
* ^ X
20
2
14
Date
Parameter
Lab Number
/O
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic -N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
•
17^10
8.0
450
33
1
8.6
.68
.35
.6
.38
.10
8000
78
49
5-9
19^03
10.0
420
29
2
8.5
.68
M
.4
• 93
.18
3800
46
J>
6-5
23410
19.5
310
17
< 1
9.1
.67
.62
.1
.47
.08
< 100
28
20
6-26
26410
22.0
310
18
4
6.5
• 53
.41
.3
.10
.25
>£-x
34
23
Average
13-0
220
10
3
10.5
.12
.08
.3
.10
.06
30
16
Average
15.0
370
24
2
8.2
.64
•15
46
32
39
-------
Station: PIT
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
Parameter
PO,
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total P<\
Total Sol.
Nitrate-N **
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: Pl8
_l£l
.7407
8.5
450
30
< 1
10.3
• 51
.32
• 7
.36
_
4300
60
47
23.
19402
9-5
210
7
2
11.0
.05
.02
.2
.12
.08
60
22
15
6-5
23407
20.5
260
9
< 1
12.4
.34
.21
.2
.14
.08
30
30
16
6-26
26407
22.0
270
15
3
10.0
.30
.20
.2
.10
.08
-
30
20
4-24
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO^
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Date
6-2
Average
15-0
300
15
2
10.9
.30
.19
•3
.18
.08
24
6-26 Average
17406
8.5
300
16
< 1
n.o
.14
.07
• 3
.12
.12
700
51
29
19406
9.0
270
13
8
10.8
.27
.13
.3
.24
.11
510
44
22
' 23406
21.5
260
10
1
12.9
.29
.18
.1
.14
.19
30
20
18
26405
21.0
250
12
2
10.4
.16
.07
.2
.10
.13
-
20
17
15.0
270
13
3
11.3
.22
.11
.2
.15
.14
34
22
4o
-------
Station: P20
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO
'4
PO,
Total Sol,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: P22
4-24
17405
7.5
280
14
< 1
11.8
.17
.03
• 3
.50
.05
1070
51
26
5-9
19407
10.5
34o
21
3
11.9
.34
.21
.3
.38
.13
120
34
32
6-5
23403
19.0
230
4
2
11.3
.09
.07
< .1
.16
.19
<10
30
16
6-26
26404
21.0
240
11
5
10.5
.17
.08
.1
.10
.11
-
21
21
4-24
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. POr
Nitrate-N
Amtaonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Date
Average
14.5
270
12
3
11.4
.19
.10
.2
.28
.12
34
24
6-26 Average
17402
8.0
270
14
< 1
10.8
.27
.12
.3
.16
.16
52000
45
26
19401
10.0
260
13
3
10.5
.13
.04
.2
.10
.12
4500
37
22.
23402
19.0
230
8
3
10.1
.23
.11
.1,
.16
• 09
100
37
16
26402
21.0
240
9
5
7-5
.15
.08
.3
.10
.08
_
16
17
14.5
250
11
3
9-7
.20
.09
.2
.13
.11
34
20
41
-------
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Station: P23
Date
Parameter
Lab Number
Temperature (°C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
ABnaonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: P24
Parameter
Lab Number
Temperature (°C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO.
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MP/100 ml)
Suspended Solids
Sulfate
4-24
17401
7.5
240
9
< 1
10.8
.15
.02
.2
.19
.14
600
52
20
4-24
17400
7.0
230
8
< 1
10.3
.12
.03
.3
.14
.10
800
57
20
5=2
194o4
10.0
280
13
2
11.5
.15
.05
• 3
.13
.10
170
32
24
Date
5-9
19405
10.0
270
13
< 1
11.2
.13
.03
.5
.16
.20
4900
30
24
6-5
23401
18.5
220
3
2
12.1
.07
.06
< .1
.12
.07
30
26
16
££
234oo
17.5
220
6
3
11.8
.05
.04
< .1
.22
.08
40
17
14
6-26
26401
20.0
230
9
5
8.6
.10
.05
.1
.08
.09
7
19
6-26
26400
20.0
220
9
5
8.9
.07
.03
.1
.07
.12
6
18
Average
14.0
240
8
2
10.8
.12
.04
.2
.13
.10
29
20
Average
13.6
240
9
2
10.6
.09
.03
.2
.15
.12
28
19
42
-------
Station: P26
Parameter
Table 8
1967 Sample Analysis Results
Lake St. Clair
(mg/1 unless noted)
Date
4-24V25 5-9
6-5
6-2$ . Average
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO,
Total Sol. PO,
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: P27
17403
6.0
220
7
1
10.3
.07
.02
.2
.12
.07
150
47
17
17431
6.5
210
7
< 1
11.6
.01
< .01
.1
.10
.07
30
27
13
I94oo
7.0
220
9
4
11.9
.03
< .01
.1
.10
.07
l4o
l4
• 13
23405
15-5
220
9
10.2
.08
.07
< .1
.15
.10
< 10
13
14
26403
19.0
210
7
4
8.8
.03
.02
.2
.08
.07
.
1
20
Date
4-24 4-25 5-9 6-5 6-26
Parameter
Lat> Number
Temperature (°C)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
Total PO^
Total Sol. POr
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
11.0
220
8
2
10.6
.04
.03
.1
.11
.08
20
15
i74n
6.0
220
9
<1
10.4
.09
.03
• 3
.11
.09
L) -
55
-
17430 19421 23421 26430
8.5 8.0 17.5 20.5
240 210 220 220
10 8 6 8
143-
10.9 11.9 10.1 9.3
.11 .04 .03 .07
.05 .02 .03 .05
.3 .1 .1 .1
.10 .21 .13 < .05
.06 .09 .08 .09
130 60 < 21 30
47 17 17 17
19 13 10 15
Average
12.0
220
8
2
10.5
.07
.04
.2
.12
.08
31
14
43
-------
FIGURE 7
MICHIGAN
Ford
Turning
Basin
DT 3.9
DT 14.6W
WYANDOTTE
Monguagon Cr.
TRENTON
Elizabeth
Park Canal
DT 8.7W
Gibraltar
Monitor
Intake
DETROIT PROGRAM OFFICE
SAMPLING RANGES
DETROIT RIVER
U.S. DEPARTMENT OF THE INTERIOR
FEDERAL WATER POLLUTION CONTROL ADMINISTRATION
GREAT LAKES REGION SROSSE ILE, MICHIGAN
-------
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-------
TABLE OF CONTENTS
Page No.
PURPOSE 1
SCOPE 1
ORGANIZATION 1
ACTIVITY 1
SAMPLING AREAS
St. Marys River Following 3
St. Marys Tributaries 12
Lake Huron Following 12
Lower Lake Huron Tributaries Following 14
Saginaw River & Tributaries 19
St. Clair River Following 22
Lake St. Clair Following 32
Detroit River Following k$
Lake Erie Following 80
SPECIAL STUDIES
Dissolved Oxygen Surveys 95
Automatic Monitor Results 101
Detroit Sewage Treatment Plant Outfalls 105
Self ridge Air Force Base 106
Proposed Dredging Sites Sampled by FWPCA, DPO Following 107
Observation Runs 113
LABORATORY METEDDS 122
-------
List of Tables
Page No,
1967 Sample Analysis Results
1. St. Marys River k
2. St. Marys Tributaries 12
3. Lake Huron 13
k. Lake Huron Tributaries 15
5. 1967 Stream Gaging Results - Lake Huron Tributaries 18
1967 Sample Analysis Results
6. Saginaw River & Tributaries 19
7. St. Clair River 23
8. Lake St. Clair 33
9. Detroit River DT 30.8W & DT 30.7E kk
DT 20.6 52
DT 17.UW & DT 17.0E 5U
DT lk.6U 57
DT 9«3E 59
DT 8.7W 62
DT 3.9 (U.S. waters) 65
DT 3-9 (Canadian vaters) 73
10. Lake Erie 8l
11. Dissolved Oxygen Surveys 95
12. Automatic Monitor Results 101
13. Detroit Sewage Treatment Plant Outfalls 105
ib. Selfridge Air Force Base 106
15. Qualitative Description of Odors 109
16. Proposed Dredging Sites Sampled by IWPCA, DPO 110
17. Proposed Dredging Site - Harbor Beach - Water Samples 112
18. Summary of Laboratory Procedure 123
-------
List of Figures
Following Page Ho.
1. Sampling Area 3
2. Sampling Ranges - St. Marys River 3
3. Sampling Station - Lake Huron , 12
4. Sampling Station - Lower Lake Huron Tributaries Ik
5. Sampling Ranges - St. Clair River 22
6. Sampling Stations - Lake St. Clair 32
7« Sampling Ranges - Detroit River k$
8. Sampling Stations - Lake Erie (Western) 80
9. Sampling Stations - Lake Erie (Pelee Island) 80
Proposed Dredging Sites - Sampling Points
10. Harbor Beach 107
11. Rouge River Old Channel 107
12. Saginav River - Saginaw Bay 107
-------
PURPOSE
The report presents data resulting from the field and laboratory
operations of the Detroit Program Office (FWPCA) in 1967.
SCOPE
This report includes the results of analysis of samples collected
by the Detroit Program Office in 1967. Averages of data groups con-
taining more than two or three individual measurements are also included.
Data from analysis of vater and "bottom sediment samples collected at
the Rouge River and seventeen other harbors and navigation channels
throughout the state are given in separate reports entitled: "Pilot
Study of Rouge River Dredging, 1967" and "Michigan Harbors and Navi-
gation Channels: Bottom Sediment Analysis, 1967*"
ORGANIZATION
The Detroit Program Office of Federal Water Pollution Control
Administration is located at the U.S. Naval Air Station at Grosse He,
Michigan and represents the Great Lakes Region Federal Water Pollution
Control Administration in the Lake Huron Drainage Basin as veil as the
Southeastern Michigan drainage basin to Lake Erie. The staff of 20
people include engineers, chemists, microbiologiste, biologists and a
supporting staff of field and office personnel.
ACTIVITY
As a combined Federal Water Pollution Control Administration
surveillance and International Joint Commission activity, samples vere
collected from the St. Marys River, Lake Huron, St. Glair River, Lake
-------
St. dair, Detroit River, Lake Erie and their tributaries. The majority
of the physical, chemical, and "bacteriological analyses were performed
at the Grosse He laboratory. Temporary laboratory facilities were set
up at Saulte Ste Marie, Ontario for the St. Marys Biver survey and
aboard the U.S. Coast Guard Cutter ACACIA for the Lake Huron sampling
run. The sampling ranges and/or stations are shovn on the maps in-
cluded with each section.
In addition to routine sampling operations, the data from several
special studies are included. On August 8, 9, 17 and 18 intensive D.O.
surveys was run at Detroit River Station R66. Several lake stations
were included in the study on the latter two days. The results are
shown in Table 11 .
The Detroit Program Office also maintains and operates an auto-
matic monitor at Gibraltar, Michigan. The weekly average, maximum
and minimum of the parameters measured (temperature, conductivity & D.O.)
are given in Table 12 .
Water Samples were also collected at the Detroit Sewage Treatment
Plant outfalls and Selfridge Air Force Base. These results are shovn
in Tables 13 and I1* .
Bottom sediment samples from Harbor Beach*, Rouge River Old Channel,
the Saginaw River, and Saginaw Bay were collected and analyzed for the
parameters shown in Table 17 .
During 19&7, several observation runs of the Detroit River, Lake
Erie, and their tributaries were made by field personnel of the Detroit
Program Office. The general river conditions and outfall discharges •
*Two water samples were also collected at Harbor Beach (Table 17)
2
-------
were described and recorded by the boat -.••}.>•-r^'ors and aquatic samplers
involved in the regular sampling operetloi.-fe, 'f*1'..* recorded field observa-
tions shovn on pages 113 to 3,21 clc-^let the ge^- ° -• * r-ppe^rance of several
municipal and industrial outfalls find jbe:-.Jr recel „ i; ?i t . :ra (on the
dates Indicated), Lei-«,!,icH_ a t,ha outfa^le, oj'e indio.-nd Iry the
point designation. Kiese milt; points can be related to the eamp.t
ranges (shown in Figure 7 ) which are Isased on the same system,
!nstfcui.-..-,j 'range PT 20«
at the mouth of the Detroit" R1 *=->--
-------
FIGURE I
DETROIT PROGRAM OFFICE
SAMPLING AREA
SCALE IN MILES
U.S. DEPARTMENT Of TNE INTERIOR
FEDERAL WATER POLLUTION CONTROL ADMINISTRATION
SREAT LAKES REGION OROSSE I I E , MICH I 6 AN
-------
FIGURE 2
-------
Table 1
1967 Sample Analysis Results
St. Marys River
Range; SMU $.6
Station:
Ft. from W. Shore
7-26
7-27
7-30
8-1
8-2
Average
Analysis;
7-26
7-27
7-30
8-1
8-2
Average
Analysis;
7-26
7-30
8-1
8-2
Average
Analysis;
7-26
7-27
7-30
8-1
8-2
Temperature
Chloride (mg/l)
Phenols (ug/l)
Nitrate (mg/l)
M075
1000
18.0
1.2
.1
.2
.1
.1
.2
M076
1300
17-5
1.3
.1
.2
.2
.2
.1
FWPCA, DFO
MD77
1600
MD78
1900
17-5
1.2
17-0
1.2
1
1
< 1
1
1
< 1
1
< 1
1
1
1
2
< 1
1
1
1
2
< 1
< 1
1
M079
2200
17.0
16.0
18.5
19.5
18.5
16.5
16.0
18.0
19-5
18.5
16.5
16.5
18.0
18.5
18.5
16.5
16.5
17-0
17.0
18.0
16.0
16.5
16.5
17.0
17-5
16.5
1.3
1.1
.7
1-9
1.2
1.3
1.2
• 9
2.0
1.1
1.3
1.1
1.1
1.2
1.1
1.3
1.0
1.2
1.2
1.2
1.3
1.1
1.1
1.1
1.3
1.2
1
1
1
1
.1
• 3
.1
.2
.1
.2
.2
.2
.1
.1
.2
.2
.2
< .1
.1
Average
.1
.2
.2
.2
-------
Table 1
1967 Sample Analysis Results
St. Marys River
Range; SMU $.6
Average
Analysis; P.O. (mg/l)
01
< .01
< .01
FWPCA, DPO
Station:
Ft. from W.
Date
Analysis:
7-26
7-27
7-30
8-1
8-2
Median
Analysis:
7-26
7-27
7-30
8-1
8-2
M075
Shore 1000
Total Coliform (MF/100 ml)
<10
< 10
< 10
10
280
< 10
Total PO,. (mg/l)
.01
< .01
.01
< .01
.01
M076
1300
<10
10
20
<10
60
10
.01
< .01
< .01
< .01
< .01
M077
1600
10
<10
< 10
<10
<10
< 10
.01
< .01
< .01
< .01
< .01
M078
1900
< 10
< 10
10
30
10
10
.01
< .01
< .01
.01
< .01
MQ79
2200
10
< 10
< 10
< 10
< 10
< 10
.01
< .01
.01
.01
< .01
< .01
.01
7-26
7-30
8-1
Analysis:
7-26
7-27
7-30
8-1
8-2
Average
Analysis:
7-26
7-30
9.8
9.0
8.9
Total Sol. K)|, (mg/l)
.01
< .01
.01
< .01
.01
.01
Sulfate (mg/l)
7
5
10.0
9.4
9.3
.01
< .01
< .01
< .01
< .01
< .01
4
3
10.1
9.5
9.4
.01
< .01
< .01
< .01
< .01
< .01
7
3
10.0
9.8
9.8
.01
< .01
< .01
< .01
< .01
< .01
3
3
9.9
9-7
9-7
.01
< .01
.01
.01
< .01
.01
6
3
-------
Table 1
1967 Sample Analysis Results
St. Maiys River
Range; SMD 2.0E
Station:
Fb. from W. Shore
Date
FWPCA, DPO
KL09
100
MU1
1500
M112
2100
M113
3000
Analysis; Temperature (°c)
M115
4ooo
7-25
7-26
7-27
7-30
7-31
8-1
8-2
Average
Analysis:
7-25
7-26
7-27
7-30
7-31
8-1
8-2
Average
Analysis:
7-25
7-26
7-27
7-30
7-31
8-1
8-2
17.0
17.0
16.5
17.0
18.5
17-5
18.0
17.5
Chloride (ag/1)
1.2
1.2
1.0
1.2
1.6
1.3
1.3
1.3
Phenols (ug/l)
5
<1
_
<1
<1
1
1
16.0
17.0
16.5
17.0
18.0
17.5
18.0
17.0
1-3
1.2
.8
1.2
1-3
1.3
1.1
1.2
3
1
4
< 1
<1
< 1
2
16.0
17.0
16.5
17-0
17-5
17.5
18.0
17.0
1.2
3.5
• 9
1.0
1.3
1.7
1.3
1.6
3
3
6
2
<1
< 1
3
16.0
16.5
16.5
17-0
17-5
17-5
17-5
17.0
1.2
1.1
1.0
.8
1.1
1.1
.9
1.0
4
2
9
4
<1
1
3
16.0
17.0
17.0
17.0
17-5
17-5
18.0
17.0
1.9
1.1
.9
1.0
• 9
1.6
1.1*
1.3
33
6
31
16
<1
24
33
16.0
17.0
17.0
17.5
17.5
18.0
18.0
17-5
2.2
1.5
1.3
1.3
.9
1.7
1.8
1.5
86
^7
55
35
1
55
59
17.0
17.0
17.0
18.0
18.0
18.0
18.0
17-5
1.7
1.6
1-7
1.0
1.4
1.4
1.3
1.4
86
71
51
50
a
48
54
Average
20
48
54
-------
Table 1
1968 Sample Analysis Results
St. Marys River
Range; SMD 2.0E FWPCA, DPO
Station: M109 M110 Mill M112 M113 Mll4 ML15
Ft. from W. Shore IQQ 500 1500 2100 3000 3500 4000
Date
Analysis; Total Coliform (MF/100 ml)
7-25 730 2,900 50 10 140 2,100 3,600
7-26 3,100 1,500 10 30 60 420 1,800
7-27 2,300 10 40 40 50 380 2,200
7-30 700 620 100 50 170 150 780
7-31 120 190 < 10 10 20 30 150
8-1 790 740 50 120 2,800 3,500 7,300
8-2 > 16,000 7,000 no 220 2,600 > 15,000> 13,000
Median 790 740 50 40 140 420 2,200
-------
Table 1
1967 Sample Analysis Results
St. Marys River
Range; SMD 8.5E Range; SMD
Station: ML40~M142Mpi3" M129M130
Ft. from W. Shore 100 500 "Boo" "l5o
Analysis; Temperature ( C)
16.0 16.0 16.0
16.5 16.5 16.0
17.0 17.0 17.0
18.0 17.5 17.5
17.0 • 17.0 17.0
18.0 17.5 18.0
18.0 17.5 18.0
17.0 17.0 17.0
1.5 .9 1.1
1.2 1.1 1.1
.9 1.1 .9
1.1 1.1 .9
1.0 l.l .9
1.1 1.4 1.1
1.3 1.3 1.2
1.1 1.1 1.0
121
17 2 U
336
< 1 < 1 2
8
-------
Station:
Ft. from W. Shore
Table 1
1967 Sample Analysis Results
St. Marys Eiver
Range; SMD 8.5E
m42.
500
100
800
Date
Analysis:
7-25
7-26
7-27
7-30
7-31
8-1
8-2
Average
Analysis:
7-25
7-26
7-27
7-30
7-31
8-1
8-2
Average
Analysis:
7-25
7-26
7-27
7-30
7-31
8-1
8-2
Total K>,. (mg/l)
.01
.01
< .01
< .01
< .01
.01
.01
.01
Total Sol. PO,, (i
.01
.01
< .01
< .01
< .01
.01
.01
< .01
Nitrate (mg/l)
.1
.3
< -.1
.2
.2
< .1
.1
.01
< .01
.01
.01
< .01
.01
.01
.01
ng/1)
.01
< .01
.01
.01
< .01
.01
.01
.01
.1
.2
.2
.2
• 3
.1
< .1
.01
.01
.01
< .01
< .01
.01
.01
.01
.01
.01
< .01
< .01
< .01
.01
.01
.01
.1
.3
.1
.2
.3
.1
< .1
Range; SMD 5.3W
.01
.01
< .01
.01
< .01
.01
< .01
.01
< .01
< .01
.01
< .01
< .01
< .01
.2
.2
.2
.2
.1
< .1
.2
.01
.01
< .01
.01
< .01
< .01
< .01
.01 < .01
.01
.01
< .01
< .01
< .01
< .01
< .01
< .01 < .01
.1
.3
.2
.1
.2
< .1
.1
Ml 31
900
.01
< .01
< .01
< .01
< .01
.01
.01
< .01
.01
< .01
< .01
< .01
< .01
< .01
.01
< .01
.2
.2
.2
.2
• 3
< .1
.1
Average
.2
.2
.2
.2
.2
.2
-------
Table 1
1967 Sample Analysis Results
St. Marys River
Range; SMD 8.5E Range; SMD 5*3W
Station: MlSo ML42 MPfS Ml 29 M130 M131
Date
Analysis; Total ColUorm (MF/100 ml)
7-25 50 150 260 1,900 140 kO
7-26 280 k2Q 560 490 30 ' 10
7-27 120 360 530 lUO 160 10
7-30 190 370 650 900 90 400
7-31 1,000 9,000 9,000 10 120 1,000
8-1 9,600 > 13,000 > 22,000 950 310 20
8-2 6,800 1,800 5,800 1,900 3,100 880
Median 280 ^20 650 900 1^0 kO
10
-------
Range:
Station:
Ft. from W. Shore
Date
Table 1
1967 Sample Analysis Results
St. Marys River
SMD l6.£M SMD 18.1W
Ml65
600
Analysis; Temperature (°C)
T-25
7-31
16.0
17.0
Analysis; Chloride (ag/l)
T-25 1.2
T-31 1.0
Analysis; Phenols (ug/l)
T-25 5
T-31 <1
Analysis; P.O. (ag/l)
T-25 9.6
T-31 9.1
Analysis; Total PO) (ag/l)
T-25
T-31
< .01
< .01
MITT
150
Analysis; Total Sol. P0j (mg/l)
T-25 < .01
T-31 < .01
Analysis; Nitrate (mg/l)
T-25 .2
T-31 .1
Analysis; Total Coliform (MF/100 ml)
T-25
T-31
130
120
16.0
1T.O
1.1
.9
3
< 1
10.0
9.3
.01
.01
< .01
.01
.1
.2
10
90
SMD 25. OE
Ml89 ML90 M191
$00 nOO 1TOO
18.0 19.0 18.5
21. 0 20.5 21.0
1.4 1..2 1.1
1.2 1.3 1-3
134
< 1 <1 <1
8.T 8.9 9.0
8.8 8.8 T.8
.01 .01 .01
.01 .01 < .01
< .61 .01 .01
< .01 .01 < .01
.1 .2 .1
.2 .2 .2
30 10 10
40 10 20
11
-------
Table 2
1967 Sample Analysis Results
St. Marys Tributaries
(mg/1 unless noted)
River:
Station:
Date:
Parameter
Lab Number
Temperature ( C)
pH (standard units)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
BOD
Total PO.
Total Sol PO,
NO--N
Ammonia-N
Organic-N
Total Coliform (MP/100 ml)
Total Solids
Dissolved Solids
Suspended Solids
River:
Station:
Date:
Parameter
Lab Number
Temperature ( C)
pH (standard units)
Conductivity (umhos/cm)
Chloride
Phenol (ug/l)
D.O.
BOD
Total POi^
Total Sol. POr
HO.-N
Ammonia-W
Organic-N
Total Coliform (MF/100 ml)
Total Solids
Dissolved Solids
Suspended Solids
Waiska
M780
II2!
30019
20.5
7-5
110
1.4
2
6.9
4
.12
.08
.2
.11
.18
1,500
85
69
16
Charlotte
M750
1=52
30021
21.0
7.6
200
12
6
4.8
2
.21
.15
.4
.15
.46
100
180
l4o
36
7-29
30059
20.5
7.6
150
2.2
1
6.7
3
.14
.11
.2
.16
.18
700
120
100
13
7-29
30061
21.0
7-3
230
' 13
< 1
4.5
4
.17
.14
.3
.10
< .05
100
200
180
24
Munuscong
M735
JtS
30020
20.0
8.1
380
5-8
6.7
1
.32
.18
• 3
*18
< .05
20,000
280
210
70
30060
20.5
8.1
430
5.5
< 1
6.9
2
.24
.15
.2
.16
.10
10,200
300
24o
53
Pover Canal
KL05
7-25
30022
16.5
7.6
92
1.3
3
10.0
1
.01
.01
.1
.16
.06
10
4o
39
1
30062
17.0
7.9
110
1.4
2
9.9
1
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.21
.13
30
67
66
1
12
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FIGURt o
i . L4 eDctro,f River Lt.
.•.•.TROiT PROGRAM OFFICE
LCC-":G,v< OF SAMPLING STATIONS
L A K Z ERIE
u.S. DEPARTMENT OF THE INTERIOR
FEDERAL WATER POLLUTION CONTROL ADMINISTRATION
GREAT LAK£S REGiON GROSSE ILE, MICHIGAN
-------
FIGURE 9
-------
Station: 16
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(xng/1 unless noted)
Date
Parameter 4-20 6-7 6-20
Lab Number 16521 23500 25531
Temperature (°C) 7.5 18.5 19..0
Conductivity (unhos/on) 220 280 240
Chlorides 9 25 13
Phenols (ug/l) 8 1 8
D.O. n.2 7-7 8.0
Total PO, .09 .48 *SL
Total Sol. PO, .01 .44 .14
Nitrate-N .6 . .3 «3
Ammonia-N .41 .32 . .32
Organic-N .05 . - < .05
Total Coliform (MF/100 ml) 490 5400 2200
Suspended Solids 11 2 26
Sulfate - 19 17
Station: 1*8
Depth: Surface
Date
Parameter . 4-20 6-7 6-20
Lab Number 16522 23501 23532
Temperature ( C) 9-5 19.0 19-0
Conductivity (umhos/cm) 380 260 '2^0
Chlorides 39 19 13
Phenols (ug/l) 556
D.O. 11.3 9.2 10.8
Total PO, .17 .32 .20
Total Sol. PO, .Ik .2k .Ik
Nitrate-N 4 1.6 .2 .3
Ammonia-N 1.12 - .24
Organic-N .25 .36 < .05
Total Coliform (MF/100 ml) 3^0 130 1900
Suspended Solids 14 1 16
Sulfate 19 17
81
-------
Station: 19
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter 14-20_._ 6-7 6-20
Lab Number 16523 23502 25533
Temperature (C) 8.5 18.0 20.0
Conductivity (umhos/cm) 320 220 26°
Chlorides 32 10 . 17
Phenols (ug/l) 61 6
D.O. 11.4 9.4 7.6
Total PO. .18 .29 , .21
Total Sol. PO. .04 .14 .17
Nitrate-N .7 . .2 .2
Ammonia-N .35 - *31
Organic-N .05 .27 < .05
Total Coliform (MF/100 ml) 13000 120 300
Suspended Solids 14 2 20
Sulfate - 17 17
Station: UU
Depth: Surface
Date
Parameter . 4-20 6-7 6-20
Lat Number / 1652^ 23503 2553^
Temperature ( C) 8.5 20.0 20.5
Conductivity (umhos/cm) 2oO 270 320
Chlorides 19 21 24
Phenols (ug/l) 7 21 9
D.O. 11.5 10.6 7.0
Total FO, .11 .43 .39
Total Sol. PO. .06 .22 .25
Nitrate-N 1.3 .2 .2
Aomonia-N .23 .23 .41
Organic-N < .05 .36 < .05
Total Coliform (MF/100 ml) 110 94 490
Suspended Solids 8 4 27
Sulfate 19 24
82
-------
Station:
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(ing/1 unless noted)
Date
Parameter 4-20 6-7 6-20
Lab Number 16531 235<* 25535
Temperature ( C) 11.5 21.0 21.0
Conductivity (umhos/cm) 5^0 320 300
Chlorides 28 25 20
Phenols (ug/l) 5 10 . 1
D.O. 10.3 9-9 7.5
Total PO, .21 .25 .31
Total Sol. PO. .Ok .17 .21
Nitrate-N 3.6 . .9 .6
Ammonia-N •& .Vf .32
Organic-N .18 .23 < .05
Total Coliform (MP/100 ml) 10000 36 320C
Suspended Solids 70 k 26
Sulfate - 31 2l|
Station: L17
Depth: Surface
Date
Parameter . k-20 6-7 6-20
Lab Number 16525 23505 25536
Temperature ( C) 8.0 20.0 21.5
Conductivity (umhos/ca) 230 290 ?8o
Chlorides
Phenols (ug/l)
D.O.
Total PO. -05. .23
Total Sol. PO.
Nitrate-N *
Ammonia-N
Organic-N < -05 -31
Total Coliform (MP/100 ml)
Suspended Solids 0
Sulfate . 25
83
-------
Station: L21
Depth: Surface
Parameter
Table 10
1967 Sample Analysis Re stilts
Lake Erie
(mg/1 unless noted)
Date
fr- 20
Lab Number
Temperature (°C)
Conductivity (umhos/cm)
Chlorides
Phenols (ug/l)
D.O.
Total PO,
Total Sol. PO.
Nitrate-N
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate
Station: L23
Depth: Surface
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chlorides
Phenols (ug/l)
D.O.
Total POj
Total Sol. PO,
Nitrate-N *
Ammonia-N
Organic-N
Total Coliform (MF/100 ml)
Suspended Solids
Sulfate .
23506
19.0
320
35
8
7-7
.65
.49
• 3
.49
1800
9
20
Date
4-20
16533
10.5
350
34
6
10.8
.15
.06
1.6
.26-
.21
720
10
-
fcl
23507
21.0
310
29
6
9.6
.33
.28
.1
.26
.
390
6
25
6-20
25538
20.5
360
33
4
7.6
.69
• 37
•7
.75
.14
480
31
31
84
-------
Station: 1*26
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter If. 20 6-\ 6-20
Lab Number 16530 23508 25539
Temperature ( C) 10.5 20.5 21.5
Conductivity (umhos/cm) ^50 360 3^0
Chlorides 26 23 22
Phenols (ug/l) 4 1 < 1
D.O. 10.6 9*9 7.0
Total PO, .22 .28 .39
Total Sol. PO. .12 .22 .28
Nitrate-N 3-3 1.6 1.3
/orjnonia-N .60 .1 .33
Organic-N .25 .23 .19
Total Coliform (MF/100 ml) 1^0 20 82
Suspended Solids 42 20 58
Sulfate - 42 39
Station:
Depth: Surface
Date
Parameter 4-20 6-7 6-20
Lab Number 16526 23509 25540
Temperature ( C) 8.0 20.0 21.0
Conductivity (umhos/cm) 240 260 260
Chlorides 21 16 17
Phenols (ug/l) 731
D.O. 12.0 10.6 8.6
Total PO, .06 .15 .ill-
Total Sol. PO, .03 .09 .13
Nitrate-N .9 .4 .2
Ammonia-N .09- .13 .13
Organic-H .05 .36 .16
Total Coliform (MP/100 ml) > 68 < 2 l4
Suspended Solids 5 3 12
Sulfate -19 19
-------
Station:
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter k-20 6-7 6-20
Lab Number 16527 23510 2551*!
Temperature (°C) 8.5 20.5 2L.5
Conductivity (umhos/cm) 290 320 260
Chlorides 27 2k 17
Phenols (ug/l) 6 < 1 8
D.O. 12.4 10.6 7.1+
Total PO, .06 .26 .27
Total Sol. PO. .06 .Ik .21
Nitrate-N .8 1.2 .k
Ammonia-N .10 .13 .1^
Organic-N .09 .3^ .16
Total Coliform (MF/100 ml) 30 < 2 2k
Suspended Solids 13 2 39
Sulfate - 31 20
Station:
Depth: Surface
Date
Parameter k-20 6-7 6-20
Lab Number 16528 23511 255^2
Temperature ( C) 8.5 20.0 22.0
Conductivity (umhos/cm) '230 3^0 320
Chlorides 15 22 20
Phenols (ug/l) 8 3 < 1
D.O. 11.7 10.3 6.3
Total PO, .03 .19 .6k
Total Sol. PO, .03 .12 .35
Nitrate-N H .9 l.fc .9
Ammonia-N .kl - .16
Organic-N .27 .^5 .06
Total Coliform (MP/100 ml) 130 2 20
Suspended Solids 12 5 68
Sulfate - 35 27
86
-------
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Station:
Depth: Surface
Date
Parameter 4-20 6-7 6-20
Lab Number 16529 23512 255^3
Temperature ( C) 9.0 20.0 22.0
Conductivity (umhos/cm) 280 330 3^0
Chlorides 22 23 21
Phenols (ug/l) 10 1 k
D.O. 11.8 10.9 6.7
Total PO, .11 .21 .95
Total Sol. PO. .06 .15 .36
Nitrate-N 1.0 1.1 1.2
Ammonia-N 1*35 »l4
Organlc-N .27 »92 .13
Total Coliform (MP/100 al) 100 2 130
Suspended Solids 16 7 65
Sulfate - 32 35
87
-------
Station: L50
Depth: Surface
Parameter
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
6-13 7-10 8-i6
Lab Number 16500 24561 28500 33561
Temperature ( C) fie 21.5 23,. 0 21.5
Conductivity (umhos/cm) 280 .. 2oO 3^9
Chlorides !8 26 23 M
Phenols (ug/l) 5 3 8
D-°- 11.9 9-5 9.8 9-k
Total PO, .06 .06 .1*8 .10
Total Sol. PO^ .02 .03 .31 .Ok
Nitrate-N Itl .2 - < .1
Ammonia-N .26 .22 .18 .11
Organic-N .10 .13 .n .16
Total Coliform (MP/100 ml) 1300 l80 58 730
Suspended Solids 17 5 3 5
Sulfate 19 17 20
Station: L51
Depth: Surface
Date
Parameter If.jj 6-13 7-10 8-16
Lab Number 16501 21*562 28501 33562
Temperature ( C) 7.5 20.0 22.0 21.0
Conductivity (umhos/cm) 270 2^0 280
Chlorides 19 25 15 28
Phenols (ug/l) 6 4 - 1*
D-°- 12.0 9-7 11.8 9.5
Total PO, . .02 .o4 .35 .03
Total Sol. PO^ .02 .Ql* .28 .02
Nitrate-N .T .x . .!
Ammonia-N .26' .16 .12 .12
Organic-N .21 .1*1 - .17
Total Coliform (MF/100 ml) 2 6 26 150
Suspended Solids 4 1* 1 If
Sulfate . 17 !8 16
88
-------
Station: L52
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter . **-17 6-13 7-10 8-l6
Lab Number 16502 24563 28502 33563
Temperature ( C) 6.5 22.0 23*0 22.0
Conductivity (umhos/on) 290 . 280 270
Chlorides 2k 22 20 27
Phenols (ug/l) 8 3 5
D.O. 12.5 9-5 10.9 9-6
Total POj .06 .06 .69 .03
Total Soi. PO, .05 .04 .39 .02
Nitrate-N .3 -2 - .1
Ammonia-N .19 .28 .07 .09
Organic-N .16 .14 .14 .14
Total Coliform (MP/100 ml) 1 3 1 H
Suspended Solids 202 8
Sulfate - 20 19 16
Station: L53
Depth: Surface
Date
Parameter 4-17 6-13 7-10 8-l6
Lab Number 16503 24564 28503 33564
Temperature (°C) 6.0 20.0 22.0 22.0
Conductivity (umbos/cm) 290 - 280 260
Chlorides 23 20 19 22
Phenols (ug/l) 5 1 - 16
D.O. 12.4 9-5 9-9 10.4
Total PO, .08 .06 .76 .07
Total Sol. PO. .02 .01 .37 .02
Nitrate-N .2 .1 - .3
Ammonia-N .17. .13 »26 .32
Organic-H .13 .09 .22
Total Coliform (MP/100 nl) < 1 15 20 < 1
Suspended Solids 1 11 6
Sulfate. - 19 19 18
89
-------
Station:
Depth: Surface
Parameter
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter
Lab Number
Temperature ( C)
Conductivity (umhos/cm)
Chlorides
Phenols (ug/l)
D.O.
Total PO,
Total Sol. PO.
Nitrate-N H
Ammonia-N
Organic-N
Total Coliform (MP/100 ml)
Suspended Solids
Sulfate
6-13 7-10 8-16
Lab Number 2^565
Temperature ( C) 20.0
Conductivity (umhos/cm)
Chlorides 19
Phenols (ug/l)
D.O. 9-7
Total PO, .07
Total Sol. PO. .08
Nitrate-N .2
Ammonia-N • 21
Organic-N .1^
Total Coliform (MF/100 ml) < 1
Suspended Solids k
Sulfate 22
Station: L55
Depth: Surface
Date
6-13 7-10 8-16
90
-------
Station: 1,56
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter 6-13 7-10 8-l6
Lab Number 2^567 28506 33567
Temperature (c) 21.5 22-5 22-0
Conductivity (umhos/cm) . 320 300
Chlorides 17 21 27
Phenols (ug/l) 2 3
P.O. 9.6 9-6 9.9
Total PO. .06 .51 .05
Total Sol. POjL .05 .29 .0^
Nitrate-N .2 - < .1
Amraonia-N ,U7 .18 .07
Organic-N .11 .14 .20
Total Coliform (MF/100 ml) k < 1 70
Suspended Solids 03 k
Sulfate 20 22 21
Station: 1,57
Depth: Surface
Date
Parameter 6-13 7-10 8-l6
Lab Number 2^568 28507 33568
Temperature ( C) 22.0 22.5 22.0
Conductivity (umhos/cm) _ 320 320
Chlorides 21 21 28
Phenols (ug/l) ± Q
D-0. 9.2 9.0 9.8
Total PO, .06 .1*3 .02
Total Sol. HV .01 .2k .01
Nitrate-N -3 _ < .1
Ammonia-N - .68 .21 .18
Organic-N .13 .34 .16
Total Coliform (MF/100 ml) 2 Uo 1
Suspended Solids 19 9
Sulfate 22 2k 2k
91
-------
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Station: L58
Depth: Surface
Parameter k-lj 6-13 7-10 8-16
Lab Number Q 16508 24569 28508 33569
Temperature ( C) 7.5 23.0 23.0 23.0
Conductivity (umhos/cm) 280 _ 330 330
Chlorides 20 21 23 31
Phenols (ug/l) 7 - - 4
D-0. 12.4 8.4 9.0 10.1
Total PO, .05 .09 .43 .04
Total Sol. PO, .02 .07 .25 .01
Nitrate-N .4 .4 . < .!
Ammonia-N .17 _ ,IQ .05
Organic-N .18 - . .16
Total Coliform (MF/100 BO.) < 2 6 40 < 1
Suspended Solids 1023
Sulfate - 24 23 23
Station: L59
Depth: Surface
Date
Parameter 4-17 6-13 J-1Q 8-16
Lab Number 16509 24570 88509 33570
Temperature ( C) 8.0 24.5 23.0 24.0
Conductivity (umhos/cm) 260 - 280 320
Chlorides 18 19 21 24
Phenols (ug/l) 65-3
D.O. 11.9 9.9 9.5 10.0
Total PO, .04 .04 .43 .10
Total Sol. PO^ .04 .03 .28 .01
Nitrate-N H .3 1.1 < .1
Ammonia-N .23 .15 .09 .4l
Organic-N .11 .09 .13 .06
Total Coliform (MF/100 ml) 2 < 2 1 < 1
Suspended Solids 1311
Sulfate. - 29 17 20
92
-------
Station:
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter 4-17 6-13 7-10 8-16
Lab Number 1*510 24571 28510 33571
Temperature (°C) 8.5 25.0 - 24.0
Conductivity (umhos/cm) 270 - 280 300
Chlorides 20 20 18 20
Phenols (ug/l) 8 < 1 - 5
D.o. 12.4 9.6 11.9 12.0
Total PO, .08 .03 .40 .12
Total Soi. PO, -03 -02 .32 .03
Nitrate-N -8 .7 - < .1
Ammonla-N -27 .18 .10 .06
Organic-N -13 .27 .13 -I1*
Total Coliform (MF/100 ml) 22 < 2 50 2
Suspended Solids 502 5
Sulfate • 23 16 17
Station:
Depth: Surface
Date
Parameter 4-17 6-13 7-10 8-l6
Lab Number 16511 24572 28511 33572
Temperature ( C) 8.5 24.5 - 24.0
Conductivity (umhos/cm) 310 - 290 28o
Chlorides 18 20 19 18
Phenols (ug/l) 6 21 5
D.O. 12.8 9.9 9.8 11.5
Total PO, .08 .07 .46 .21
Total Sol. PO. .03 .05 .26 .13
Hitrate-N 1.3 .3 - .2
Ammonia-N < .05 . .41 .08 .07
Organic-N .59 .22 .10 .18
Total Coliform (MF/100 ml) 360 < 2 11 90
Suspended Solids 902 5
Sulfate 20 15 l£
93
-------
Station: L62
Depth: Surface
Table 10
1967 Sample Analysis Results
Lake Erie
(mg/1 unless noted)
Date
Parameter 4-17 6-13 7-10 8-16
Lab Number 16512 24573 28512 33573
Temperature ( C) 9.5 22.0 21.5 24.0
Conductivity (umnos/cm) 310 - 320 300
Chlorides 18 25 23 15
Phenols (ug/l) < 1 < 1 - 4
D.O. 12.3 9-7 8.9 9.0
Total PO, .12 .02 - .04
Total Sol. PO, .Ok .01 - .04
Nitrate-N 1.4 .3 - A
Ammonia-N .18 .08 .06 .07
Organic-N .14 .23 .08 .15
Total Colifoim (MP/100 ail) 320 6 420 68
Suspended Solids 2k 3 5 6
Sulfate 15 17 16
-------
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Table 12
Detroit River
at Gibraltar, Michigan
FWPCA, DPO Automatic Monitor Results
1967
Week No. ' Date
1
2
3
t
5
6
7
8
9
10
1/4-
1/8-
1/15
1/22
1/29
2/5-
2/12
2/21
2/26
3/5-
1/7
1/14
- 1/21
- 1/28
- 2/4
2/n
- 2/18
- 2/25
- 3/4
3/n
Temp Dissolved Oxygen
f°Fl (Wl)
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Mln.
^•M-MW •
37
38.5
34.5
37
39-0
34.5
36
37-5
33-5
38
40.5
34.5
37
38.5
34.5
35
38.5
32.0
36
to.o
33.5
37
39-5
33-5
37
40.0
33-5
37
4l.o
35-0
-
-
_
-
-
15.5
15-9
14.6
15.4
16.0
lt.8
it. 7
15-8
13-6
15-5
16.5
it. 2
15.2
15-5
It. 9
14. t
It. 7
14.1
14.5
14.9
14.1
it.t
lt.8
14.0
Conductivity
(uahos/cm)
360
t30
320
380
440
350
370
430
320
390
480
340
400
480
370
400
480
360
400
450
370
400
450
350
380
470
360
390
440
350
101
-------
Table 12
Detroit River
at Gibraltar, Michigan
FWPCA, DPO Automatic Monitor Results
196?
Week No.
12
13
15
16
17
20
29
31
Date
3/12
3/19
3/22
4/2 -
- 3/18
- 3/25
-4/1
- 4/8
4/9 - 4/15
4/16
4/23
5/16
7/16
7/30
- 4/22
- 4/29
- 5/20
- 7/22
-8/5
3?emp Dissolved Oxygen
(°F) (ng/i)
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
37
40.0
33-5
37
4o.o
33-0
42
49.0
34.0
49
51.5
46.0
49
52.0
46.0
52
54.0
48.0
50
52.0
47.0
54
56.5
52.0
71
73.5
68.5
75
77-5
74.0
14.2
14.7
13.8
14.2
14.5
13.7
13-3
14.1
12.3
12.3
13-7
11.1
11.8
13-1
10.8
10.9
11.8
9.7
10.3
11.3
9.9
10.7
11.2
9-8
6.9
7.7
6.4
6,2
6.9
4.9
Conductivity
(umhos/cm)
400
430
360
420
520
370
430
470
400
440
500
400
430
490
410
430
490
390
4lO
440
385
390
420
370
380
44o
310
370
430
340
102
-------
Table 12
Detroit River
at Gibraltar, Michigan
FWPCA, DPO Automatic Monitor Re stilts
1967
Week No. Date Tern Dissolved Oxygen Conductivity
(as/1) (•nmhos/cm)
370
430
320
380
415
335
370
380
365
370
410
345
380
4oo
350
4oo
420
350
420
48o
370
4io
435
385
4io
455
380
11/5 - ll/H Ave. 50 8,6 420
Max. 52 j.3 455
Min. 47 -.3 390
103
32
33
34
39
40
41
42
43
44
8/6 -
8/13
8/20
9/24
10/1
10/8
10/15
10/22
10/29
8/12
- 8/19
- 8/26
- 9/30
- 10/7
- 10/14
- 10/21
- 10/28
- n/4
^
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
Ave.
Max.
Min.
74
77.5
72.0
74
75.6
70.5
74
75.0
69.0
63
66.5
57.0
61
63.5
57.0
60
61.0
58.0
58
61.5
55.5
55
58.0
51.0
54
56.0
51.0
6.9
7-9
5-9
7.0
7-7
5-9
6.6
6.7
5-8
7.6
8.2
7-3
7.8
8.3
7-3
7-5
7.8
6.3
7-9
8.4
6.6
8.2
8.8
8.0
8.4
8.8
7.7
-------
Table 12
Detroit River
at Gibraltar, Michigan
FWPCA, DPQ Automatic Monitor Results
1967
Week No. Date Temp Dissolved Oxygen Conductivity
(mg/l) (umhos/cm)
1*6 11/12 - 11/18 Ave. 48 8.9 4lO
445
380
47 11/19 - H/25 Ave. 44 9-5 410
425
370
48 11/26 - 12/2 Ave. 43 11.6 400
430
350
49 12/3 - 12/9 Ave. 42 12.8 400
425
360
50 12/10 - 12/16 Ave. 44 11.5 420
470
370
51 12/17 - 12/23 Ave. 43 11.8 440
580
370
52 12/24 - 12/30 Ave. 38 13-4 400
415
380
11/12
11/19
11/26
12/3 -
12/10
12/17
12/24
- 11/18 Ave.
Max.
Min.
- 11/25 Ave.
Max.
Min.
- 12/2 Ave.
Max.
Min.
12/9 Ave.
Max.
Min.
- 12/16 Ave.
Max.
Min.
- 12/23 Ave.
Max.
Min.
- 12/30 Ave.
Max.
Min.
48
51-5
46.0
44
46.0
42.0
43
46.0
40.0
42
43.5
38.0
44
45.5
42.0
43
46.0
40.0
38
42.0
34.0
8.9
9-5
8.0
9-5
11.0
8.5
11.6
12.0
10.8
12.8
14.5
9.0
11.5
12.5
10.6
11.8
13-3
10.9
13-4
14.6
11.3
104
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FIGURE 10
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FIGURE
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/ ^ii/trY \
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/19 '/ / ' '^
-Lai^ / / • I 19
T-FTROIT PROGRAM OFFICE
;.:,'^OSED DREDGING SITE
SAMPLING POINTS
v! i S; IfiMAW RIVER-SAG I MAW SAY i
U.S. DEPARTMENT OF Tnt'lNTcRICS
FEDERAL WATER POLLUTION CONTr-OL A3,>i,% 3TRA7,C,\ !.
GREAT LAKES REGION GrtCSSE IL£ C-. ,j-,\ |
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Description of Bottom Material
The descriptions of "bottom materials are listed in Table 2.
The sediments were classified as follows:
Ooze: soft, fine, decaying organic material.
Sludge: (clay, silt, mud or organic material): non-gritty
material of natural or unnatural origin.
Sand: gritty particles up to 1/25" to 1/V
Gravel: 1/25" to 1/4"
Pebbles: 1/V to 2"
Stones: 2" to 10"
108
-------
2able 15
Qualitative Descriptions of Odors*
FrfPCA, L?0^ 1$6T
Code
Nature of Odor
'.-3i.e:i cs Odors of: )
A Aromatic (spicy)
Ac cucumber
B Balsamic (flowery)
Bg geranium
Bn nasturtium
Bs sweetish
Bv violet
C Chemical
Cc chlorinous
Ch hydrocarbon
Cm medicinal
Cs sulfuretted
D Disagreeable
Df fishy
Dp pigpen
Ds septic
E Earthy
Ep peaty
G Grassy
M Musty
Mm moldy
V Vegetable
*Standard Methods of Examination
coBiphoar, cloves, lavender, lemon
Synura
geranium, violet, vanilla
Asterionella
Aphanizomenon
Coelo sphaerium
Mallomonas
industrial wastes or treatment chemicals
free chlorine
oil refinery wastes
phenol and iodoform
hydrogen sulfide
(pronounced, unpleasant)
Uroglenopsis, Dinobryon
Anabaena
stale sewage
damp earth
peat
crushed grass
decomposing straw
daznp cellar
re-- - *•--,••,«i
Wastewater, llth Edition, p. 255
109
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Table 16 (con't.)
Proposed Dredging Sites Samples "by FWPCA, DPO 1967
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-------
OBSERVATION RUNS
General Observations - Detroit and Rouge Rivers
Date; June 16, _ 1967
Coal dust and oil film on west side of the Detroit River in the
Trenton Channel south of the County Bridge. (Range DT 8.?W)
Oil film and debris in the vicinity of Wyandotte Water Intake
(Range DT l4.6¥)
Traces of oil near Wyandotte Chemical North Plant. &•'
Heavy iron oxide and oil extending south from Great Lakes Steel
(Ecorse Plant) to the Ecorse River.
Heavy scum and oil with light coal dust extending over the northern
quarter mile of the Old Channel.
(a)
Heavy debris extending from the Ambassador Bridge "north for one
mile. The refuse included beer bottles, cans, and paper cups.
Scum covered an area extending out to 500 feet from shore nearly 1/2
mile in length near DT 30.8w.
Date; June 22, 1967
Heavy yellow - brown oil film near DT 17.4W.
Traces of oil on the Rouge River Old Channel
Heavy debris floating on the Rouge River. River is reddish brown
(•2\
color in the turning basin downstream to the Dix Ave bridge.
Some oil leaking through the oil sktomer at the Ford Boat Slip.
Date; June 29, 1967
Light oil film west of Grassy Island.,
Light oil film along shore ner.v '.sres-i Lakes Steel (Ecorse)
113
-------
Large areas of soap suds near the aouth of the Rouge.
Light oil on the Rouge upstream from the turning basin.
Black oil and debris on the Rouge near Dix Ave bridge.
Water near Belle Isle covered with mayflies.
Date; July 6, 195?
Mayfly skins observed on the river from the north end of Grosse He
to Lake St. Clair.
Iron oxide in Kouge turning basin extending dovn to Fort St. "bridge.
Light oil outside skinner in 7ord boat slip.
Turbid water with light spots of oil upstream from. Rouge turning
basin.
Light traces of oil and mayfly skins on the Old Channel of the Rouge.
Date; July 20,
Light oil and some sewage on the Detroit River from the south end
of Grosse lie north to the Rouge River.
Some white foam observed on Detroit River from Grosse He Toll
bridge (north end of island) to Vyandotte.
Light trace of oil near the mouth of Ecorse Creek. Bubbles observed
rising from river bottom.
Oil observed upstream of Rouge turning basin.
Reddish brown color in turning basin. Heavy debris along the north
(3)
shore at the Dix Avenue bridge. '
Heavy oil along south bank at Fort Street bridge.
Light oil and debris on Rouge River Old Channel.
114
-------
Date; July 27 > 19oT
Traces of oil near the mouth of Ecorse Creek. Bubbles observed
rising from river bottom.
(l>\
Oil observed in northwest portion of Nicholson Boat Slip.*- '
Traces of oil along the entire length of the Rouge River.
Debris and oil along the north bank at Jefferson and Fort Street
bridges. Same condition at the upstream side of the Dix Avenue bridge
Some oil (heavy in spots) observed for one mile upstream from the
Rouge turning basin. •
Traces of light oil along the entire length of the Rouge River
Old Channel.
Date: August 8, 1967
(L\
Traces of oil observed in the south side of Nicholson Boat Slip.^ '
Light traces of oil on both the main Rouge and Old Channel.
Date: August IT, 19o7
Elizabeth Park Canal observed flowing northeast into the Detroit
River.
Bubbling observed rising from a large area of river bottom north
of Great Lakes Steel $3 skimmer. (Scorse) '^'
Traces of oil at the mouth of the Rouge Rivers. The river is
reddish brown in color.
(3)
Some light oil in theItord boat slip.
Light traces of oil on the Rouge Old Channel
Light oil and coal dust in the let roll. .River about one mile north
of range DT 20.6.
Mouth of the Detroit River near '2 3«9 very turbid, possible due
to southwest wind from Lake Erie.
-------
Date: .u^ust 25, 19&7
Sccae oil observed near range HP 3.7W-
Acidic odor detected near Ecorse Creek.
Notes:
(l) v'yandotte Chemical North Plant is located approximately 1/4 mile
:-iorth of range K? 14.6W.
(2) Ambassador Bridge is located approximately 1-1/2 mile upstream
free; range K? 20.6.
(3) V'iiese stations are located on the Rouge River as follovs:
Jefferson St. at mile point 1.09 (upstream from mouth of the Rouge)
Port St. at uile point 2.19
Six Ave at nile point 2.75
Ford Boat Slip at mile point 3-^1
(4) Nicholson Boat Slip is located approximately 3/4 mile upstream
from range HT 17.VvJ.
(5) Great Lakes Steel (Ecorse Plant) is located in the vicinity of
range D2 17.4W.
116
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General Observations - Western Lake Erie
The Detroit Program Office field crew made observation runs on
Western Lake Erie on June 30, July 13, and August 22. On all three
occasions, Lake Erie was free of oil and debris. No swimmers were
seen at Sterling State Park*. Bubbles were observed rising from the
River Raisin bottom (turning basin to Lake Erie). Patches of sewage
(trace of oil) having a strong odor were also found along the lower
stretch of this river.
^Located on Lake Erie immediately north of the mouth of the River Raisin
120
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*
LABORATORY METHODS
The analytical methods used "by the laboratory for physical and
chemical analyses were the procedures published in "Standard Methods
for the Examination of Water and TJastevater," 12th Edition, 19^5-
Additional analytical procedures and modifications developed "by the
Chicago Program Office, Federal Water Pollution Control Administration
were employed as required in the analysis of bottom sediment material.
Modifications have been node on some of the methods to improve the
sensitivity or to expedite a systematic analytical scheme. Before
adopting any modification a thorough study was made to evaluate the
affect of the chare o.
To assure continually re-liable data, reference standards of known
composition and blc.nl;s were analyzed simultaneously with all tests.
A siCEration of x,he analyses performed is shown on Table 18 .
Specific occhniouis or modifications ~c.o "Standard Methods" procedure
are shown where applicable.
-------
Table 18
Detroit Program Office
Summary of Laboratory Procedure
Analysis
pH
Conductivity
Alkalinity
Chloride
Phenol
Dissolved Oxygen
Biochemical Oxygen Demand (BOD)
Chemical Osygen Demand (COD)
Total Phosphate
Total Soluble Phosphate
Nitrate
Nitrite
Ammonia
Organic Nitrogen
Total Coliform
Fecal Coliform
Fecal Strep
Total Solids
Suspended Solids
Total Volatile Solids
Volatile Suspended Solids
Iron
Sulfate
Oil & Grease
Technique or Modification
Glass Electrode Method
Specific Conductance Cell
Potent ioiaetric pH 4.5 & pH 8.3
Mercuric Nitrate
Arainoantipyrine
Method A - Alstezfeerg (Azide)
Modification of Winkler Method
No modifications
Silver Sulfate Catalyst
Autoclaved with Sulfuric acid on
unfaltered sample
Ascorbic acid method (not in "Standard
Methods")
Brucine sulfate method
No modification
Minor modification to "Standard Methods"
Minor modification to"Standard Methods"
Mezibrane filter
Membrane filter
Membrane filter (M-enterococcus agar)
Total Residue, porcelain dish
Filtrable residue, Gooch crucible
No modifications
No modifications
1, 10 pheaanthroline
Barium sulfate
Petroleum, ether extraction
123
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|