What Is EPA's Design for the
 Environment Program?

 EPA's  Design for the Environment (DfE)
 Program works in partnership with a broad
 range of stakeholders to reduce risk to
 people and the environment by preventing
 pollution. Partnerships focus on industries
 that combine the potential for chemical risk
 reduction with a strong motivation to make
 lasting, positive changes.  DfE convenes
 partners,  including industry representatives
 and environmental groups, who develop
 goals  and guide the work of the
 partnership.

 As incentives for participation and driving
 change, DfE offers unique technical tools,
 methodologies, and expertise. Partnerships
 evaluate the human health and
 environmental risks, performance, and cost
 of traditional and alternative technologies,
 materials, and processes.

 DfE has formed partnerships with a range of
 industries including:
     •  Auto refinishing
     •  Chemical product formulators
     •  Electronics
       • Printed wiring board manufacturing
       • Lead-free solder
       • Computer displays
     •  Furniture
     •  Garment and textile care
     •  Industrial and institutional laundry
     •  Printing
     •  Wire and cable
                US. ERA
                                               Lead-Free Solder Partnership
Solders  in  Electronics: A

Life-Cycle Assessment

Why Did the Partnership Evaluate Solders?

Solder composed of tin and lead is a fundamental
material joining electronic components to circuit
boards in the assembly of almost every type of
electronic  product.  The electronics industry,
however, is facing significant international legislative
and market pressures to phase out the use of tin-lead  I            I
solders and switch to lead-free alternatives.  Such a switch will require
significant capital expenditures and may have a broad impact on
public health and the environment.  The electronics industry, as well as
public interest and governmental organizations, are concerned about
the lack of research  to date  on the potential environmental effects of
the alternatives to tin-lead (SnPb) solder.

Approximately 176  million pounds of tin-lead solder was used
worldwide in 2002. Lead, a chemical known to be toxic, can be
released into the air and groundwater throughout its life cycle, from
mining and use to waste treatment and disposal. Once in the
environment, lead is persistent (as are all metals) and bioaccumulates
in the food chain.

Concerns about potential risks have led to initiatives by several nations
(e.g.,  European Union and Japan) to mandate or encourage the
electronics industry  to replace lead solder with lead-free alternatives.
Industry experts estimate that U.S. industry could lose approximately
$240 billion over only three years if the United States does not
respond to these initiatives quickly and competitively by identifying
viable alternative solders that perform well, are cost effective, and
pose fewer environmental risks.

Virtually all research about potential substitutes for lead  in solder,
however, has focused strictly on performance.  Although U.S. industry
needs to move ahead with alternative products to remain competitive,
information about life-cycle impacts and risks of the alternatives is
lacking.  This  has raised concerns for both industry and the public
about the  possible future business and environmental risks of making a
wholesale switch from lead  to other metals.

What Were the Partnership's Goals?

To address the information gap on the impacts of leaded and lead-free
solders, EPA's Design for the Environment (DfE) Program entered into
a voluntary partnership with representatives of the electronics industry
August 2005
   www.epa.gov/dfe
EPA 744-F-05-003

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and other interested parties to evaluate the life-cycle
environmental impacts of tin-lead solder and four
alternative lead-free solder compositions.

Project partners included electronics manufacturers and
assemblers, trade associations (the Electronic Industries
Alliance and 1PC—Association Connecting Electronics
Industries), academic and research organizations (e.g.,
University of Tennessee), and public interest groups.
Contributing industry partners included Agilent, Cookson
Electronics, Delphi Delco, Hewlett-Packard, IBM, Intel,
Pitney Bowes, Rockwell Collins, Sematech, and Thomson
Multimedia.

Specific goals of the project included:

       • Evaluating the environmental impacts of tin/lead
         solder and selected lead-free alternative solders;
       • Evaluating the effects of lead-free solders on
         recycling and reclamation at the end of the
         electronic product life-cycle; and
       • Assessing the leachability of lead-free solders and
         their potential environmental effects.

What Solders Were Evaluated by the
Partnership?

The partnership examined life-cycle impacts of tin-lead
solder and the following lead-free solders:

       • 95.5% tin, 3.9% silver, and 0.6% copper;
       • 57.0% bismuth, 42.0% tin, and 1.0% silver;
       • 96.0% tin, 2.5% silver, 1.0% bismuth, and 0.5%
         copper; and
       • 99.2% tin and 0.8% copper.

These solder alternatives were selected by the industry
partners because they have shown promising
performance as substitutes for tin-lead solder. Solders
were evaluated in both paste form, used in "reflow"
soldering, and bar form, used in "wave" soldering.
Wave soldering is used mostly in low-tech, low-cost
applications, and reflow soldering is usually used for
higher-tech applications.  Using a life-cycle assessment
(LCA) approach, the study has generated data to help
manufacturers, users, and suppliers of solder incorporate
environmental considerations into their decision-making
processes.

What Were  the Project's Results?

A life-cycle assesment examines the full life cycle of a
product, and estimates environmental impacts from each
of the following life cycle stages:  raw material
           extraction or acquisition and material processing; solder
           manufacture; solder application; and end-of-life
           disposition.

           The LCA results can be used by industry to select lead-
           free solders that work well for reflow or wave
           soldering applications and that may have fewer impacts
           on public health and the environment.

                  • For paste solders, bismuth/tin/silver had the lowest
                    (best) impact scores among the lead-free
                    alternatives in every category except
                    non-renewable  resource consumption.
                  • For bar solders, when only lead-free solders were
                    considered, the tin/copper alternative had the
                    lowest (best)  scores.
                  • Three major contributors to overall life-cycle
                    impacts include energy consumption during solder
                    application, silver mining and extraction for
                    silver-bearing alloys, and potential leachate from
                    landfilling the SnPb alloy.

           A detailed discussion and presentation of the  results can
           be found at www.epa.gov/dfe.
             How Can I Get More Information?

             To learn more about the DfE Program or the Lead-Free
             Solder Partnership, or to obtain an electronic version of
             this fact sheet (document #EPA 744-F-05-003), visit the
             Office of Pollution Prevention and Toxics' DfE Program
             Web site: www.epa.gov/dfe.

             To obtain hard copies of DfE Program technical reports,
             pollution prevention case studies,  and project
             summaries, contact:

             National Service Center for Environmental Publications
             U.S. Environmental Protection Agency
             P.O. Box 42419
             Cincinnati,  OH 45242
             Phone: (513) 489-8190, (800) 490-9198
             Fax: (513) 489-8695
             E-mail: ncepimal@one.net
EPA 744-F-05-003
www.epa.gov/dfe
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