EPA 903/B-99-001
              DISPOSAL
            HANDBOOK
A Guide to Managing Classification and Disposal
     of Hazardous Waste at Superfund Sites
                   Prepared by
               The Roy F. Western, Inc.
         Site Assessment Technical Assistance Team
                     for the
          U. S. Environmental Protection Agency
          Region III, Superfund Removal Branch
             Under Contract # 68-S5-3002
                  December 1998
                                  EPA Report Collection
                                  Regional Center for Environmental Information
                                  U.S. EPA Region III
                                  Philadelphia, PA 19103

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al Center for F.mnoui icrit^-l IiiloriTidtion
          1650 \rc\\St
     Philadelphia, PA 19103

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                                    DISCLAIMER

Environmental regulations and technologies are dynamic. The U.S. EPA makes no guarantee of
the timeliness of the materials published in this guidance manual. The U.S. EPA and the
contractors assisting in the development of the manual will not assume responsibility for
omissions, errors, misprints, or ambiguities, and shall not be liable for any loss or injury caused by
such. Private industries and corporations are only mentioned as references regarding technological
information and are not endorsed or recommended in any way by the U.S. EPA. This handbook is
not intended to take the place of direct discussions with the appropriate agency about potentially
relevant federal and/or state regulations. The appropriate personnel should always be contacted'if
there is any question as to the applicability of certain regulations.
                                                             U.S. EPA Region III
                                                             Regional Center for Environmental
                                                              information
                                                             1650 Arch Street (3PM52)
                                                             A mladeJphia, PA 19103

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                             TABLE OF CONTENTS


Disclaimer	i

Table of Contents	ii

Introduction	v

Acknowledgments	vi

Chapter 1: Federal RCRA Requirements	1

       Subchapter I: Identification of Wastes (RCRA Classifications)	1

       Table 1-1: Toxicity Characteristic Wastes	3

       Subchapter II: Pre-transport Requirements, RCRA Land Disposal Restriction
       Notifications and Manifest Requirements	5.

       Subchapter HI: Post Transportation Requirements	6

       Subchapter IV: Summary of RCRA Hazardous Waste Management	7

       Figure 1-1: RCRA Waste Code Flowchart	8

       Figure 1-2: Manifest Flow Chart	 9

       Table 1 -2: Hazardous Constituents	10

Chapter 2: Federal DOT Regulations for the Highway Transportation of Hazardous
Substances and Hazardous Waste	: ..20

       Subchapter I: Introduction to the DOT Hazardous Materials Regulations	20

       Subchapter II: DOT Hazardous Materials Descriptions and Hazard Classifications	20

       Subchapter III: General DOT Hazardous Materials Packaging Requirements	23

       Subchapter IV: DOT Hazardous Materials Shipping Descriptions, Container Labeling
       and Marking, Vehicle Placarding and Material Segregation Requirements	27

       Subchapter V: Shipping Papers	29

       Subchapter VI: Emergency Removal Exemption	29

       Subchapter VII: Summary of DOT Requirements for the Highway Transportation of
       Hazardous Materials and Hazardous Wastes	30

       Table 2-1: Segregation Table for Hazardous Materials	31
                                         ii

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Chapter 3: Conventional Hazardous Waste Treatment and Disposal Methods	33

       Subchapter I: Introduction to Conventional Hazardous Waste Treatment and
       Disposal Methods	33

       Subchapter II: Recycling and Recovery	33

       Subchapter ED: Incineration	34

       Subchapter IV: Conventional Wastewater Treatment Technologies	35

       Subchapter V: Deactivation/Stabilization Waste Treatment Technologies	37

       Subchapter VI: Contaminated Soils	37

Chapter 4: Disposal Facility Waste Evaluation and Acceptance Procedures	40

       Subchapter I: The Waste Profile	40

       Table 4-1: Treatment-Specific Information (usually required on waste profiles)	40

       Subchapter II: The Disposal Facility's Process and Considerations	41

       Subchapter III: Summary of Commercial Disposal Wastestream Evaluation and
       Considerations	42

Chapter 5: Introduction to Sampling and Analysis Methodologies	43

       Subchapter I: Environmental Assessment Methodologies Versus Waste
       Characterization Needs	43

       Subchapter II: Factors to Consider in Determining the Information Needed to
       Characterize a Wastestream	44

       Table 5-1: Contract Laboratory Program Hazardous Substance Reference List	46

Chapter 6: Unknown Drum Wastes: Characterization for Disposal	52

       Subchapter I: Introduction to Waste Characterization Needs	52

       Subchapter II: RCRA Hazard and Compatibility Testing of Unknown Substances for
       Disposal	52

       Subchapter III: Haz-Cat Test Procedures	53

       Subchapter IV: Determination of Treatment Options Based on RCRA Hazard and
       Compatibility	57

       Subchapter V: Compositing Wastestream Samples and Determining the Appropriate
       Disposal Analysis	59
                                          iii

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       Subchapter VI: Summary of Disposal Evaluation Procedures for Unknown Drums,
       Utilizing Wastestreams Developed by RCRA Hazard and Compatibility
       Testing and Available Treatment Options	61

Chapter 7: Waste Characterization of Tanks, Vats, Lagoons, Effluent, and Soil	63

Chapter 8: Specialty Wastes	65

       Subchapter I: Lab Packs	65

       Subchapter II: Dioxins and Dibenzofurans	67

       Figure 8-1: Dioxin Chemical Structure	68

       Figure 8-2: 2,3,7,8-Tetrachlorodibenzo-p-dioxin	68

       Figure 8-3: Dibenzofuran Chemical Structure	68

       Subchapter HI: Polychlorinated Biphenyls (PCBs)	68

       Figure 8-4: Polychlorinated Biphenyl Molecule	69

       Figure 8-5 :PCB Marking Label ML	73

       Figure 8-6: PCB Marking Label Ms	73

       Subchapter IV: Explosive and Shock Sensitive Substances	74

       Subchapter V: Radioactive Wastes	.75

Appendix 1: Example of Disposal Evaluation and Handling Procedures for Unknown
Drum Wastes	77
                                          IV

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INTRODUCTION

This book is the second edition of a handbook designed to form the basis for understanding
regulatory and technical references needed to plan a removal response so that hazardous wastes
may be disposed of in the most efficient, cost effective manner. Planning and coordinating a
CERCLA removal action requires considering and implementing a variety of statutes and EPA,
OSHA, and DOT regulations, policies, guidance, and directives as they apply to investigating
technological assessment, treatment, and disposal alternatives.  The relevant statutory and
regulatory documents are convoluted at best and at worst create a labyrinth where the twin
minotaurs of high costs and delays lie in wait for the unwary. While the Emergency Rapid  Support
Services contractor actually arranges for disposal of the hazardous substances generated from a
Superfund removal action, the OSC needs to understand the disposal process and its ramifications
to contain the cost of the removal response and to ensure compliance with the statutes and
regulations.

This manual may be viewed as a companion piece to the Hazard Evaluation Handbook: A Guide to
Removal Actions, also published by the U.S. Environmental Protection Agency, Region III,
Superfund Removal Branch. The Hazard Evaluation Handbook presents a qualitative approach to
assessing a hazardous waste site; in it are discussions of where to look for the threats presented by
a site and how to recognize them. Once a threat is recognized as existing, it must be quantified so
that the best alternatives can be selected for eliminating it.  This manual discusses the steps
involved in quantifying the threat effectively and in selecting appropriate disposal options.

In Chapters 1 and 2, evaluation and disposal of hazardous waste streams are discussed within the
context of complying with RCRA and applicable DOT regulations. In Chapters 3 and 4, hazardous
waste disposal is discussed from the perspective of commercial disposal facilities and their
specifications. Discussions in Chapters 5, 6, and 7 are focussed on technical applications to meet
both regulatory and commercial requirements. Various specialty wastes are discussed briefly in
Chapter 8. The information presented in Chapters 1 through 6 is put into practice in the example
hazardous waste site problem presented in the Appendix. This example goes from initial
assessment, through determining waste streams and preparing waste profiles, to final transport,
disposal, and record-keeping.

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                             ACKNOWLEDGMENTS

    This book was prepared by the Roy F. Weston, Inc. Site Assessment Technical Assistance
(SATA) team under the coordination of Joan Henry, U.S. EPA Region HI Deputy Project Officer.
Many SATA members contributed directly and indirectly to this project.  The project would not
have been successfully completed, however, without the assistance of all of the EPA and SATA
personnel involved.
                                         VI

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                                          CHAPTER 1
                            FEDERAL RCRA REQUIREMENTS
                                      (40 CFR references 7/1/97 revision)
Subchapter I:  Identification of Wastes (RCRA Classifications)

In the event of a response action at a Superfund site, the Superfund Amendments and
Reauthorization Act (SARA), Section 121(d)(3), requires that off-site disposal of
substances defined as being hazardous pursuant to the Comprehensive Environmental
Response, Compensation, and Liability Act (CERCLA) comply with the Resource
Conservation and Recovery Act (RCRA) to ensure disposal in the most
environmentally sound manner.  RCRA governs the disposal of all wastes which are
referred to in the statue as "solid wastes." "Solid wastes" can be gaseous, liquid, or
solid in physical state. In RCRA these physical states are labeled as "gaseous,"
"liquid," and "non-liquid," respectively.

Regulations to govern the identification, handling, and proper disposal of hazardous
wastes were established by RCRA as amended by the Hazardous and Solid Waste
Amendments (HSWA). These regulations are based on the hazardous constituents in a
waste, the hazardous  characteristics of a waste and/or the conditions under which the
waste was derived.

Step 1: Exclusions and Exemptions  Exclusions and exemptions to all or part of the
solid and hazardous waste regulations are listed in 40 CFR 261.4. These exclusions
and exemptions should be examined as the first step in the evaluation of a substance
for disposal. The exclusions listed are for specific waste products and include, but are
not limited to: domestic sewage, irrigation return flows, household hazardous wastes,
and samples collected for the sole purpose of characterization. Many additional
process specific exemptions are listed in 40 CFR261.4

Step 2: Is the waste a RCRA Hazardous Waste?  If a substance to be disposed of is
not excluded from solid and/or hazardous waste regulations, then the generator of the
waste further applies  federal statutes and regulations to establish whether the waste is
hazardous.  A solid waste that contains any regulated hazardous constituents may be
considered hazardous. The concentration of the hazardous constituents or the source
from which the hazardous constituents were derived will affect the classification of the
waste.  A list of RCRA hazardous constituents is provided in Table 1-2.  Other
hazardous wastes, which may not appear on the hazardous constituents list, include
materials which demonstrate the characteristics of ignitability, corrosivity or reactivity
as defined by RCRA.

The EPA has established sampling and test procedures to quantitatively determine if a
waste is hazardous. These procedures are described in the "Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods" section of EPA publication SW-
846 and will be discussed in Chapter 5 of this manual.

Once a waste has been determined to be hazardous, the third step in evaluating it for
disposal is to apply RCRA hazardous waste codes to the waste and/or determine if the
40 CFR 261
Identification and
Listing of
Hazardous Waste

Subpart A -
General 261.2
Definition of solid
waste
Subpart A -
General 261.3
Definition of
hazardous waste

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Federal RCRA Requirements
waste requires special handling as a California-listed waste.  This part of the process
requires exploring the RCRA code lists and the California list.

RCRA waste codes are divided into five categories, each category identified with a
letter of the alphabet.  These categories are the "U", "P", "K", "F", and "D" codes.  The
"U" and "P" list of waste codes are found in 40 CFR 261.33 and pertain to discarded
commercial chemical product, off-specification species, container residues and
spill residues.  "U" indicates that the compound is listed due to its toxicity,
while "P" indicates that the compound is listed due to its acute toxicity. "U" and "P"
listed wastes fall into the following six groups.

     1.  Unused commercial chemical products,
    2.  Unused materials which were meant to be commercial chemical products but
        which were not made correctly,
    3.  Unused chemical manufacturing intermediates which are essentially technical
        grade chemicals,
    4.  Unused chemical manufacturing intermediates which would have been
        essentially technical grade chemicals if they had been made correctly.
    5.  Container residues of the first four items,
     6.  Spill residues and spill cleanup residues of the first five items.,

It is unlikely that the OSC, who assumes the role of generator at a CERCLA removal
action, will be able to verify the history of any container contents or spills, making it
unlikely that "U" or "P" codes will be used on a Superfund site.

The "K" list of waste codes is found in 40 CFR 261.32 and pertains to hazardous
wastes from specific sources. K-listed wastes are generated by specific processes
involving wood preservation, inorganic pigments, organic chemicals, inorganic
chemicals, pesticides, petroleum refining, iron and steel, primary copper, primary lead,
primary zinc, primary aluminum, ferroalloys, secondary lead, veterinary
Pharmaceuticals, ink formulation, and coking. K-listings are also unlikely to be used
at a Superfund site unless the site is a chemical processing plant.

The "F" list of waste codes is found in 40 CFR 261.31 and pertains to hazardous
wastes from non-specific sources, which include generic processes.  F-listed wastes
fall into the following eight groups.

     1.  Spent (.used) halogenated solvents or non-halogenated solvents (F001 - F005).
    2.  Spent baths or other wastes from electroplating operations (F006 - F012).
    3.  Certain metal finishing wastes (F019).
    4.  Waste solvents from the production of chlorinated hydrocarbons or dioxin
        precursors (F020 - F026).
    5.  Unused and incinerator residues of dioxin and dioxin precursor wastes (FO27
        and F028).
     6.  Wood treating wastes (F032 - F035).
     7.  Petroleum refinery wastes (oil/water/sludge separation wastes) (F037- F038).
     8.  Land fill leachate (F039).

("Spent" means used material that can no longer be used for its original purpose
without being cleaned.)
                                                2
40 CFR 261
Identification and
Listing of
Hazardous Waste

Subpart C -
Characteristics
of Hazardous
Waste
261.33 Discarded
commercial
chemical
products, off-
i pacification
species, container
residues, and spill
residues
thereof
Subpart D - Lists
of Hazardous
Wastes
261.32 Hazardous
wastes from
specific
sources
Subpart D - Lists
of
Hazardous Wastes
261.31 Hazardous
wastes from non-
specific
sources

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Federal RCRA Requirements
"D" codes pertain to characteristic wastes as defined in 40 CFR 261.21- 261.24 and are
divided into the following four groups:

1.   D001 code for the characteristic of ignitability includes the following:
     -  liquids with a flash point of less than 140°F;
     -  solids that can cause fire and burn vigorously and persistently when ignited
        (includes Department of Transportation (DOT) flammable solids,
        spontaneously combustible, and dangerous when wet hazard classes);
     -  ignitable compressed gases (DOT flammable gases);
     -  DOT oxidizers.
2.   D002 code for the characteristic of corrosivity includes the following:
     - liquids with a pH below 2 or above 12.5 and
     - liquids which corrode steel faster than 0.25 inches per year.
3.   D003 code for the characteristic of reactivity includes the following:
     -  any waste that undergoes violent change without detonating;
     -  any waste that when mixed with water reacts violently, forms explosive
        mixtures, or generates toxic gases, vapors, or fumes;
     -  any waste that gives off cyanide or sulfide gases in sufficient quantity to
        present a danger to human health  or the environment when the pH is between
        2 and  12.5; and
     -  any waste that may spontaneously explode, or is a DOT defined explosive.
4.  Codes D004 through D043 apply to metal, pesticide and organic contaminants in a
    waste at concentrations above the regulatory level as determined by the Toxicity
    Characteristic Leachate Procedure (TCLP). Such wastes are referred to as the
    toxicity characteristic wastes. The code for each contaminant and its regulatory
    limit are as follows in Table 1-1:
40 CFR 261
Identification and
Lbting
of Hazardous
Watte

Subpart C -
Characteristics
of Hazardous
Wastes
261.21
Characteristic of
ignitability


Subpart C -
Characteristic!
of Hazardous
Wastes
261.22
Characteristics of
corrosivity

Subpart C -
Characteristics
of Hazardous
Wastes
261.23
Characteristics of
reactivity
Subpart C -
Characteristics
of Hazardous
Wastes
261.24 Toxicity
characteristic
                              Table 1-1 Toxicity Characteristic Wastes
                                (40 CFR 261.24,1 July 1997 Edition)
Waste Code
D004
D005
D018
D006
D019
D020
D021
D022
D007
D023
D024
D025
D026
D016
D027
D028
D029
D030
D012
D031
Contaminant
Arsenic
Barium
Benzene
Cadmium
Carbon tetrachloride
Chlordane
Chlorobenzene
Chloroform
Chromium
o-Cresol
m-Cresol
p-Cresol
Cresol
2,4-D
1 ,4-Dichlorobenzene
1 ,2-Dichloroethane
1, 1 -Dichloroethylene
2,4-Dinitrotoluene
Endrin
Heptachlor (and its hydroxide)
All materials with leachable levels
greater than or equal to (ppm)
5.0
100.0
0.5
1.0
0.5
0.03
100.0
6.0
5.0
200.0
200.0
200.0
200.0
10.0
7.5
0.5
0.7
0.13
0.02
0.008

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Federal RCRA Requirements
Waste Code
D032
D033
D034
D008
0013
D009
D014
D035
D036
D037
D038
D010
D01 1
D039
D015
D040
D041
D042
D017
D043
Contaminant
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Lead
Lindane
Mercury
Methoxychlor
Methyl ethyl ketone
Nitrobenzene
Pentachlorophenol
Pyridine
Selenium
Silver
Tetrachloroethylene
Toxaphene
Trichloroethylene
2,4,5- Trichlorophenol
2,4,6-Trichlorophenol
2,4,5-TP (Silvex)
Vinyl chloride
All materials with leachable levels
greater than or equal to (ppm)
0.13
0.5
3.0
5.0
0.4
0.2
10.0
200.0
2.0
1100.0
5.0
1.0
5.0
0.7
0.5
0.5
400.0
2.0
1.0
0.2
California List Wastes:

California-listed wastes are wastes adopted by federal RCRA from the state of
California to avoid any loopholes in the identification and subsequent disposal of
materials which may be hazardous. RCRA requires the appropriate disposal of the
following California-listed wastes per 40 CFR 268.42 (a):

     1. Hazardous wastes containing nickel greater than or equal to 134 mg/L;
     2. Hazardous liquid wastes with PCBs greater than or equal to 50 ppm;
     3. Hazardous wastes with halogenated organic compounds (HOC's) greater
         than 1,000 mg/kg;
     4. Hazardous wastes containing thallium, greater than or equal to 130 mg/L.

Handling and disposal of PCB waste are governed under the Toxic Substances
Control Act (TSCA), 40 CFR 761. It is important to note that with the exception of
PCBs, the other California-listed wastes will probably have an associated RCRA
waste code. Regulations which relate to a waste code take precedence over
California lists with the exception of PCBs.

A flow chart is provided in Figure 1-1 to assist with the applicability of a waste code
to a waste.

The regulations concerning the hazardous waste identification system currently
regard a waste as hazardous under the "mixed-waste" rule or the "derived-from" rule.
The mixed-waste rule defines a waste as hazardous if a listed or a characteristic waste
has been mixed with a non-hazardous waste, even if the final mixture does not
demonstrate levels or characteristics of hazardous waste.  The derived-from rule
defines a waste as hazardous if at any time the waste contained or was defined as a
listed hazardous waste (U-, P-, K-, or F-listed wastes), even after it has been treated
according to existing regulations.

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 Federal RCRA Requirements
 Snbchapter II: Pre-transport Requirements, RCRA Land Disposal Restriction
 Notifications and Manifest Requirements

 Besides regulating the disposal of hazardous waste, RCRA regulates the handling and
 storage of hazardous waste prior to disposal. The generator of hazardous waste must
 first obtain an EPA identification number, then package, label, and mark waste
 containers of 110 gallons or less in accordance with 40 CFR 262 and 49 CFR 172,
 173,178 and 179 (DOT) prior to offering hazardous waste for transport off site. EPA
 ID numbers are assigned to removal sites through the Comprehensive Environmental
 Response, Compensation, and Liability Information System (CERCLIS).
 Regulations pertaining to actual transport are discussed in detail in Chapter 2 (DOT).

 Several forms of documentation must accompany each shipment of waste to an
 authorized, designated disposal facility.  Among these documents are land disposal
 restriction (LDR) notifications, which state that a particular waste must be treated by
 a specific technology (treatment technologies) or that the regulated hazardous
 constituents must be reduced to levels below a set concentration value (treatment
 standards). The LDR notification from the generator to the disposal facility must
 include the following:

 •   The generator's EPA ID number;
 •   The manifest umber of the shipment;
 •   The applicable LDR references for the waste codes from the 40 CFR 268.41,
    268.42 and/or 268.43; and
 •   The treatment standard (concentration value) for each hazardous constituent in
    F001, F002, F003, F004, F005, F039 and California-listed wastes.

 The purpose of the LDR notifications is to provide the disposal facility with the
 information needed to determine the extent of treatment and the test method used to
 make that determination.

 In 40 CFR 268.41, treatment standards are listed as Constituent Concentrations of a
 Waste Extract (CCWE). Regulated constituents with concentration values are listed
 for specific waste codes. The concentration values are based on leachability test
 results, which means the treatment, storage and disposal facility (TSD) must run
 TCLP analysis on the waste after treatment. All constituent concentrations must be
 below regulated TCLP values before the waste can be landfilled.

 In 40 CFR 268.43, treatment standards are listed as Constituent Concentrations of
 Waste (CCW). Regulated constituents with concentration values are listed for
 specific waste  codes. The concentration values are based on total results, not on
TCLP results.  All constituent concentrations must be below regulated total values
before the waste can be landfilled.
 40 CFR 268
 Land Disposal
 Restrictions
 Subpart A -
 Genera] 268.7
 Waste analysis
 and record-
 keeping
40 CFR 268
Land Disposal
Restrictions
Subpart D -
Treatment
Standards

268.41 Treatment
standards
expressed as
concentrations in
waste extract
268.43 Treatment
standards
expressed as
waste
concentrations
Treatment technologies are listed in 40 CFR 268.42, Table 2. Wastes with codes that
are not listed as CCW or CCWE are disposed of according to specified treatment
technologies, not according to concentration values. The treatment required for a
California-listed waste is defined in 40 CFR 268.42 (a).
268 42 Treatment
standards
expressed as
specified
technologies

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Federal RCRA Requirements
The first step to referencing LDRs is to determine if the waste is wastewater or non-
wastewater.  Wastewater is waste consisting primarily of water with less than one
percent total organic carbon (TOC) and less than one percent total suspended solids
(TSS). Non-wastewater is water that does not meet the definition of waste water.
The second step to referencing LDRs is to look up each waste code in 40 CFR
268.41,268.42, and 268.43 and note where each code is listed. For F codes and
California-listed wastes, also note the concentration values for the hazardous
constituents in the waste. Finally, if the constituents of a U-, P-, K-, or F-listed waste
exhibit D-listed characteristics, causing a D-code to be assigned also, the generator
does not have to provide the treatment technology for the D-code as long as the
treatment standard under U, P, K, or F meets or exceeds the treatment standard for the
D characteristic (i.e., destroys the D characteristic).

In addition to LDR notifications, a manifest must accompany each shipment of
hazardous waste. The manifest is a modified bill of lading for the purpose of
transporting, documenting, and reporting hazardous waste shipments. The manifest
meets the bill of lading requirements for  hazardous material transportation under the
DOT. Directions on the completion of a manifest are  usually printed on the back of
the document. The federal requirements for the completion of a uniform hazardous
waste manifest are provided in the appendix of 40 CFR 262.

Individual states may also print and require the use of state-specific manifests with
additional requirements. If the receiving state prints a manifest (i.e., the state in
which the designated disposal facility is located), the generator is required to use the
manifest for that state. If the receiving state does not print a manifest, the  generator
uses the generator state's manifest, if available. If neither state prints a manifest, the
generator can use a federal uniform hazardous waste manifest. Details on  particular
transportation requirements on the uniform manifest are covered in Chapter 2 (DOT).

Subchapter HI:  Post Transportation Requirements

Copies of the manifest are used in the "cradle to grave" waste tracking system
established by RCRA. The flow chart in Figure 1-2 depicts the use of manifest
copies in the tracking system. Individual states may or may not require the generator
to submit a copy of the manifest. If the receiving state (receiving facility's state)
provides a manifest, refer to copy distribution  directions on the back of the manifest.
If the receiving state does not supply a manifest, it is unlikely that the state has a
tracking system in place. Always check  generator state requirements at the onset of a
project.

It is important to note that the generator is responsible for ensuring that a shipment of
waste has reached its destination. A copy of each manifest signed by the receiving
facility is returned to the generator as a "certification of receipt." If the generator does
not receive the returned, signed manifest within 35 days of the shipment, he or she
must determine the location and status of the waste. Certifications of receipt must be
maintained by the generator for three years.

Biennial Report and Notification of Waste Activity Reports

In addition to maintaining manifest records, the generator must also file a biennial
40 CFR 268
Land Disposal
Restrictions
Subpart A -
General 268.2
Definitions
applicable in this
part
40 CFR 262
Standards
Applicable to
Generators of
Hazardous
Waste
Subpart B - The
Manifest
262.20 General
requirements
40 CFR 262
Standards
Applicable to
Generators of
Hazardous
Waste
Subpart B - The
Manifest
262.21
Acquisition of
manifests
40 CFR 262
262.42 Exception
reporting

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Federal RCRA Requirements
report with the Regional Administrator or the generator's state (if the state has an
authorized waste program) by March 1 of each even numbered year. The report,
filed on EPA Form 8700-13 A, tells how wastes were classified, the quantities
removed, and disposal method for the reporting period. The form provides space to
report activities of the previous year and changes in activities since the previous
year. Some state programs require a similar report to be filed annually instead of
biennially. Detailed instructions for completion are available with the biennial
report forms and thus are not detailed in this manual.

Last, but not least, when a site is completed and no additional waste disposal is
anticipated, the OSC should file a Notification of Regulated Waste Activity Report
with the generator's state. The submission of this report notifies the state that no
additional waste generation and disposal are anticipated at the site and completes the
record-keeping process.

Subchapter IV: Summary of RCRA Hazardous Waste Management
Requirements

1.   To determine if a substance to be disposed of is regulated as a hazardous waste,
     the generator must determine if the substance is or was derived from a U-, P-, K,
     or F-listed, characteristic, or California-listed waste. Changes to the hazardous
     waste identification system have been proposed.

2.   The Department of Transportation (DOT) governs hazardous waste packaging
     and labeling requirements.

3.   Land disposal restriction notifications and manifests must accompany each
     shipment of waste.

4.   Generators are required to  obtain a certification of receipt for each shipment of
     waste to a disposal facility and must submit biennially a report to the EPA by
     March '1 of even-numbered years.  This report details the classification of wastes
     generated, quantities removed, and disposal method.
 40CFR262
 262.40
 Record-
 keeping
 262.41
 Biennial report
 40 CFR 261
 Identification and
 Listing
 of Hazardous
 Waste

 40 CFR 262
 Standards
' Applicable to
 Generators of
 Hazardous
 Waste

 40 CFR 268
 Land Disposal
 Restrictions
40 CFR 262
Standards
Applicable to
Generators of
Hazardous
Waste

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Federal RCRA Requirements
                                    Is the waste an unused
                              commercial chemical product ?
                                          I
                                                          N
 Is the material or the
 active ingredient U or P
 listed?
            N
Does the waste have a
D-listed characteristic?
N
  Assign the U or P
  number.
           Assign only the
            D number(s).
Does the waste have a
D-listed characteristic?
                N
Also assign
the D number.
Assign only
thePorU
number.
                                             N
Is the waste K-listed
(specific source) or F-listed
(non-specific source)?
                                  Assign the K or F
                                   number.
                 Is the waste a California-listed
                 Waste subject to LDRs?
                                Does the waste have a
                                D -listed characteristic?
                         N
                                              N
Non-RCRA haz waste.
CERCLA disposal only.
  Also assign
  the D number.
            Assign only
            the K or F
            number.
                         Reference the Land Disposal Restrictions
                                        (LDRs).
                         Figure 1-1 RCRA Waste Code Flow Chart

-------
Federal RCRA Requirements
      Copy to
      Generator's State
Copy to Disposal
Facility's State
Copy to
Generator's State
Copy to Disposal
Facility's State
                   Generator
                                     Completed copy
                                     (within 35 days)
                          Transporter
                                         Completed copy (immediately)
* If disposal facility's copy is not received in 35 days.
                                Figure 1-2 Manifest Flow Chart

-------
Federal RCRA Requirements
                                 Table 1-2 Constituents
                      (40 CFR 261, Append.-Vm, 1 July 1997 Edition)
Common Name
A2213
Acetonitrile
Acetophenone
2-Acetylaminefluarone
Acetyl chloride
1 -Acetyl-2-thiourea
Acrolein
Acrylamide
Acrylonitrile
Aflatoxins
Aldicarb
Aldicarb sulfone
Aldrin
Allyl alcohol
Allyl chloride
Aluminum phosphide
4-Ammobiphenyl
5-(Aminomethyl)-3-isoxazolol
4-Ammopyridine
Amitrole
Ammonium vanadale
Aniline
Antimony
Antimony compounds, N.O.S.
Aramite
Arsenic
Arsenic compounds, N.O.S.
Arsenic acid
Arsenic pentoxide
Arsenic trioxide
Auramme
Azasenne
Barban
Banum
Barium compounds, N.O.S.
Banum cyanide
Bendiocarb
Bendiocarb phenol
Benomyl
Benzfclacridine
Benz[alanthracene
Benzal chloride
Benzene
Benzenearsonic acid
Benzidine
Benzofblfluoranthene
Benzofj Ifluoranthene
Benzo(k)fluoranthene
p-Benzoquinone
Chemical Abstract Name
Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-
oxo-methyl ester.
Same
Ethanone, 1 -phenyl-
Acetamide, N-9H-fluoren-2-yl-
same
Acetamide, N-(aminothioxomethyl)-
2-Propenal
2-Propenamide
2-Propenenitrile
Same
Propanal, 2-methyl-2- (methylthio)-O-[(methylamino)
carbonyll oxime
Propanal, 2-methyl-2-(rnethylsulfonyl)-O-[(methylamino)
carbonylloxime.
1,4,5,8- Dimethanonaphthalene, 1,2,3,4,10,10-10-
hexachloro-l,4,4a,5,8,8a-hexahydro -, (lalpha,4alpha,
4abeta,5alpha, 8alpha,8abeta)-.
2-Propen-l-ol
1 -Propane,3-chloro
Same
f 1 .1 '-Biphenyll-4-amine
3(2HHsoxazolone,5-(aminomethyl)-
4-Pyridinamme
1 H-l,2,4,-Triazol-3-amine
Vanadic acid, ammonium salt
Benzenamine
Same

Sulfurous acid, 2-chloroethyl 2-[4- (1,1-dimethylethyl)
phenoxyl-1-methylethyl ester.
Same

Arsenic acid H3AsO<
Arsenic oxide AszOs
Arsenic oxide AS2O3
Benzenamine, 4,4'-carbommidoylbisrN,N-dimethyl
L-Senne, diazoacetate (ester)
Carbamic acid,(3-chlorophenyl)-,4-chloro-2-butynyl ester
Same

Same
l,3-Benzodioxol-4-ol, 2,2 -dimethyl-, methyl carbamate
1 ,3-Benzodioxol-4-ol, 2,2-dimethyl-,
Carbamic acid, [l-[(butylamino)carbonyl]- 1 H-benzimidazo
-2-yl]-,methyl ester.
Same
Same
Benzene, (dichloromethyl)-
Same
Arsonic acid, phenyl
n,r-Biphenyll-4,4i-diamme
Benzfelacephenanthrylene
Same
Same
2,5-Cyclohexadiene-l ,4-dione
Chemical
Abstract No.
30558-43-1
75-05-8
98-86-2
53-96-3
75-36-5
591-08-2
107-02-8
79-06-1
107-13-1
1402-68-2
116-06-3
1646-88-4
309-00-2
107-18-6
107-18-6
20859-73-8
92-67-1
2763-96-4
504-24-5
61-82-5
7803-55-6
62-53-3
7440-36-0

140-57-8
7440-38-2

7778-39-4
1303-28-2
1327-53-3
492-80-8
115-02-6
101-27-9
7440-39-3

542-62-1
22781-23-3
22961-82-6
17804-35-2
225-51-4
56-55-3
98-87-3
71-43-2
98-05-5
92-87-5
205-99-2
205-82-3
207-08-9
106-51-4
Hazardous
Waste No.
U394
U003
U004
U005
U006
P002
P003
U007
U009

P070
P203
P004
POOS

P006

P007
POOS
U011
P119
U012





P010
P011
P012
U014
U015
U280


P013
U278
U364
U271
U016
U018
U017
U019

U021



U197
                                         10

-------
Federal RCRA Requirements
Common Name
Benzotrichloride
Benzyl chloride
Bis (pentamethyleneHhiuram tetrasulfide
Beryllium powder
Beryllium compounds, N.O.S.
Benzofafpyrene
Bromoacetone
Bromoform
4-Bromophenyl phenyl ether
Brucine
Butyl benzyl phthalate
Butylate
Cacodylic acid
Cadmium
Cadmium compounds, N.O.S.
Calcium chromate
Calcium cyanide
Carbaryl
Carbendazim
Carbofuran
Carbofuran phenol
Carbon disulfide
Carbon oxyfluoride
Carbon tetrachloride
Carbosulfan
Chloral
Chlorambucil
Chlordane
Chlordane (alpha and gamma isomers)
Chlonnated benzenes, N.O.S.
Chlorinated ethane, N.O.S.
Chlorinated fluorocarbons, N.O.S.
Chlonnated naphthalene, N.O.S.
Chlorinated phenol, N.O.S.
Chlomaphazin
Chloroacetaldehyde
Chloroalkyl ethers, N.O.S.
p-Chloroanilme
Chlorobenzene
Chlorobenzilate
p-Chloro-m-cresol
2-Chloroethyl vinyl ether
Chloroform
Chloromethyl methyl ether
beta-Chloronaphthalene
o-Chlorophenol
1 -(o-Chlorophenyl)thiourea
Chloroprene
3-Chloropropiomtrile
Chromium
Chromium compounds, N.O.S.
Chrysene
Citrus red No.2
Coal tar creosote
Copper cyanide
Copper dimethyldithiocarbamate
Creosote
Cresol (Cresyhc acid)
Chemical Abstract Name
Benzene, (trichloromethyl)-
Benzene, (chloromethyl)-
Piperidine,l-r-tetrathiodicarbonothioyl)-bis-
Same

Same
2-Propanone, 1 -bromo-
Methane, tribromo
Benzene, 1 -bromo-4-phenoxy-
Strychnidin-10-one,2,3-dimethoxy-
1 ,2-Benzenedicarboxylic acid, butyl phenylmethyl ester.
Carbamothioic acid, bis(2-methylpropyl)-,S-ethyl ester.
Arsinic acid, dimethyl-
Same

Chromic and H2GO4, calcium salt
Calcium cyanide Ca(CN)2
1-Naphthalenol, methylcarbamate
Carbamic acid, lH-benzimidazol-2-yl, methyl ester.
7-Benzofuranol, 2,3-dihydro-2,2 -dimethyl-, methylcarbamat
7-Benzofuranol, 2,3-dihydro-2,2 -dimethyl-
Same
Carbonic difluoride
Methane, tetrachloro-
Carbamic acid[(dibutylamino) thio] methyl-2,3-dihydro-2,2-
dimethyl-7-benzofuranyl ester.
Acetaldehyde, trichloro-
Benzenebutanoic acid, 4-[bis(2-chlaroethyl)amino]-
4,7-Methano-lH-indene,l,2,4,5,6,7,8,8-octachloro-2,3,3a,4,
7,7a-hexahydro-.






Naphthalenamine,N,N-bis(2-chloroethyl)-
Acetaldehyde, chloro-

Benzenamine,4-chloro-
Benzene, chloro-
Benzeneacetic acid,4-chloro-alpha- (4-chlorophenyl)-alpha-
hydroxy-,ethyl ester.
Phenol,4-chloro-3-methyl-
Ethene, (2-chloroethoxy)-
Methane,tnchloro-
Methane, chloromethoxy-
Naphthalene, 2-chloro-
Phenol,2-chloro-
Thiourea, (2-chlorophenyl)-
1 ,3-Butadiene,2-chloro-
Propanemtrile,3-chloro-
Same

Same
2-Naphthalenol, 1 -[2,5-dimethoxyphenyl)azo]-
Same
Copper cyanide CuCN
Copper, bis(dimethylcarbamodithioato-S,S')-,
Same
Phenol, methyl -
Chemical
Abstract No.
98-07-7
100-44-7
120-54-7
7440-41-7

50-32-8
598-31-2
75-25-2
101-55-3
357-57-3
85-68-7
2008-41-5
75-50-5
7440^3-9

13765-19-0
592-01-8
63-25-2
10605-21-7
. 1563-66-2
1563-38-8
75-15-0
353-50^
56-23-5
55285-14-8
75-87-6
305-03-3
57-74-9






494-03-1
107-20-0

106-47-8
108-90-7
510-15-6
59-50-7
110-75-8
67-66-3
107-30-2
91-58-7
95-57-8
5344-82-1
126-99-8
542-76-7
7440-47-3

218-01-9
6358-53-8
8007-45-2
544-92-3
137-29-1

1319-77-3
Hazardous
Waste No.
U023
P028

P015

U022
P017
U225
U030
P018


U136


U032
P021
U279
U372
P127
U367
P022
U033
U211
PI 89
U034
U035
U036
U036





U026
P023

P024
U037
U038
U039
U042
U044
U046
U047
U048
P026

P027


U050


P029

U051
U052
                                       11

-------
Federal RCRA Requirements
Common Name
Crotonaldehyde
m-Cumenylmethyl carbamate
Cyanides (soluble salts and complexes),
N.O.S.
Cyanogen
Cyanogen bromide
Cyanogen chloride
Cycasin
Cycloate
2-Cyclohexyl-4,6-dinitrophenol
Cyclophosphamide
2,4-D
2,4-D,salts,esters
Daunomycin
Dazomet
ODD
DDE
DDT
Diallate
Dibenzfa,h]acridine
Dibenzfajlacridine
Dibenzo[a,h]anthracene
7H-Dibenzo[c,glcarbazole
Dibenzofa.elpyrene
Dibenzofa.hlpyrene
Dibenzofa.ilpyrene
1 ,2-Dibromo-3-chloropropane
Dibutyl phthalate
o-Dichlorobenzene
m-Dichlorobenzene
p-Dichlorobenzene
Dichlorobenzene, N.O.S.
3,3'-Dichlorobenzidme
1 ,4-dichloro-2-butene
Dichlorodifluoromethane
Dichloroethylene, N.O.S.
1,1-Dichloroethylene
1 ,2-Dichloroethylene
Dichloroethyl ether
Dichloroisopropyl ether
Dichloromethoxy ethane
Dichloromethyl ether
2,4-Dichlorophenol
2,6-Dichlorophenol
Dichlororphenylarsme
Dichloropropane, N.O.S.
Dichloropropanol, N.O.S.
Dichloropropene, N.O.S.
1,3-Dichloropropene
Dieldnn
1 ,2:3,4-Diepoxybutane
Diethylarsme
Diethylene glycol, dicarbamate
1 ,4-Diethyleneoxide
Diethylhexyl phthalate
N,N '-Diethylhydrazme
Chemical Abstract Name
2-Butenal
Phenol, 3-(methylethyl>,methyl carbamate

Ethanedinitrile
Cyanogen bromide (CN)Br
Cyanogen chloride (CN)CI
beta-D-Glucopyranoside, (methyl- ONN-azoxy)methyl.
Carbamothioic acid, cyclohexylethyl-,S-ethyl ester.
Phenol,2-cyclohexyl-4,6-dinitro.
2H-1 ,3,2-Oxazaphosphorin-2-am.ine, bis(2-chloroethyl)
tetrahydro-,2 -oxide
Acetic acid, (2,4-dicholrophenoxy)-

5,12-Naphthacenedione,8-acetyl-10-[(3-amino-2,3,6-
trideoxy-alpha-L-lyxo-hexopyranosyl)oxyl-7,8,9,10-
tetrahydro-6,8,1 1 -trihydroxy-l-methoxy-,(8S-cis>
2H-1 ,3,5-thiadiazine-2-thione, tetrahydro-3,5-dimethyl.
Benzene, 1, r-(2,2-dichloroethylidene)bisf4-chloro-.
Benzene, 1,1'- (dichloroethenylidene)bisf4-chloro-.
Benzene 1 ,1 '-(2,2,2 -trichloroethylidene)bis[4-chloro-.
Carbamothioic acid, bis(l-methylethyl)-,S-(2,3-dichloro-2-
propenyl) ester.
Same
Same
Same
Same
Naphthofl ,2,3,4-def]chrysene
Dibenzo[b,def]chrysene
Benzo frst]pentaphene
Propane, l,2-dibromo-3-chloro-
1,2-Benzenedicarboxylic acid, dibutyl ester
Benzene, 1 ,2-dichloro-
Benzene, 1 ,3-dichloro-
Benzene, 1 ,4-dichloro-
Benzene.dichloro
[1,1 '-Biphenyll-4,4'-diamine,3 ,3 '-dichloro-
2-Butene, 1 ,4-dichloro-
Methane, dichlorofluor-o
Dichloroethylene
Ethene, 1,1-dichloro
Ethene, 1 ,2-dichlorol-,(E)-
Ethane, 1,1' oxybis[2-chloro-
Propane, 2,2'-oxybis[2-chloro-
Ethane, 1,1 '-[methylenebis(oxy)lbis2-chloro-
Methane, oxybisfchloro-
Phenol-2,4-dichloro-
Phenol,2,6-dichloro-
Arsonous dichlonde phenyl-
Propane, dichloro-
Propanol, dichloro-
1-Propene, dichloro-
1-Propene, 1 ,3-dichloro-
2,7:3,6-Dimethanonaphth[2,3-b]oxirene,3,4,5,6,9,9-
hexachloro-la^^a,3,6,6a,7,7a-octahydro-(laalpha,2beta,
2aalpha,3beta,6beta,6aalpha,7beta,7aalpha)-
2,2'-Bioxirane
Arsine, diethyl-
Ethanol, 2,2'-oxybis-,dicarbamate
1 ,4-Dioxane
1^-Benzenedicarboxyhc acid, bis(2-ethylhexyl) ester.
Hydrazine, 1,2-diethyl-
Chemical
Abstract No.
4170-30-3
64-00-6

460-19-5
506-68-3
506-77-4
14901-08-7
1134-23-2
131-89-5
50-18-0
94-75-7

20830-81-3
533-74-4
72-54-8
72-55-9
50-29-3
2303-16-4
226-36-8
224-24-0
53-70-3
194-59-2
192-65-4
189-64-0
189-55-9
96-12-8
84-74-2
95-50-1
541-73-1
106-46-7
25321-22-6
91-94-1
>64-41-0
75-71-8
25323-30-2
75-35-4
156-60-5
111-44-4
108-60-1
111-91-1
542-88-1
120-83-2
87-65-0
696-28-6
26638-19-7
26545-73-3
26952-23-8
542-75-6
60-57-1
1464-53-5
692^2-2
5952-26-1
123-91-1
117-81-7
1615-80-1
Hazardous
Waste No.
U053
P202
P030
P031
U246
P033


P034
U058
U240
U240
U059

U060

U061
U062


U063



U064
U066
U069
U070
U071
U072

U073
U074
U075

U078
U079
U025
U027
U024
P016
U081
U082
P036



U084
P037
U085
P038
U395
U108
U028
U086
                                      12

-------
Federal RCRA Requirements
Common Name
O,O-Diethyl S-methyl dithiophosphate
Diethyl-p-nitrophenyl phosphate
Diethyl phthalate
O,O-Diethyl O-pyrazinyl phosphoro-thioa
Diethylstilbesterol
Dihydrosafrole
Diisopropylfluorophosphate (DFP)
Dimethoate
3,3'-Dimethoxybenzidine
p-Dimethylaminoazobenzene
7,12-Dimethylbenz[alanthracene
3,3'-Dimethylbenzidine
Dimethylcarbamoyl chloride
1, 1-Dimethylhydrazine
1 ,2-Dimethylhydrazine
alpha,alpha-Dimethylphenethylainine
2 ,4-Dimethylphenol
Dimethyl phthalate
Dimethyl sulfate
Dimetilan
Dinitrobenzene, N.O.S
4,6-Dinitro-o-cresol
4,6-Dinitro-o-cresol salts
2 ,4-Dinitrophenol
2,4-Dmitrotoluene
2,6-Dinitro toluene
Dinoseb
Di-n-octyTphthalate
Diphenylamme
1 ,2-Diphenylhydrazme
Di-n-propylmtrosamine
Disulfiram
Disulfoton
Duhiobiuret
Endosulfan
Endothall
Endnn
Endnn metabolites
Epichlorohydrin
Epinephnne
EPTC
Ethyl carbamate (urethane)
Ethyl cyanide
Ethyl ziram
Ethylenebisdithiocarbamic acid
Ethylenebisdithiocarbamic acid, salts, and
esters
Ethylene dibromide
Ethylene dichlonde
Ethylene glycol monoethyl ether
Ethyleneimine
Ethylene oxide
Ethylenethiourea
Ethylidene dichloride
Ethyl methacrylate
Ethyl methanesulfonate
Chemical Abstract Name
Phosphorodithioic acid, O,O-diethyl S-methyl ester.
Phosphoric acid, diethyl 4-nitrophenyl ester
1,2-Benzenedicarboxylic acid, diethyl ester
: Ehosphorothioic acid, O,O-diethyl O- pyrazinyl ester.
Phenol, 4,4'-(U-diethyl-l^-ethenediyl)bis-, (E)-
1,3-Benzodioxole, 5-propyl-
Phosphorofluoridic acid, bisfl-methylethyl) ester.
Phophorodithioic acid, O,O-dimethyl S-[2-(methylamino)-2
oxoethyl ester.
[l,l'-Biphenyl]-4,4'-diamine,3,3-dimethoxy-
Benzenamine,N,N-dimethyl-4-{phenylazo>
Benzfalanthracene, 7,12-dimethyl
[1, l-Biphenyll-4,4-diamine,3,3'- dimethyl-
Carbamic chloride, dimethyl-
Hydrazine, 1,1-dimethyl-
Hydrazine, 1,2-dimethyl-
Benzeneethanamine,alpha,alpha-dimethyl-
Phenol,2,4-dimethyl-
1,2-Benzenedicarboxylic acid, dimethyl ester
Sulfuric acid, dimethyl ester
Carbamic acid, dimethyl-, l-[(dimethylamino) carbonyl]-5-
methyl-lH-pyrazol-3-yl ester
Benzene, dinitro-
Phenol, 2-methyl-4,6-dinitro-

Phenol, 2,4-dinitro-
Benzene, 1 -methyl-2,4-dinitro-
Benzene, 2-methyl-l,3-dimtro-
Phenol,2-(l-methylpropyl)-4,6-dinitro-
1 ,2-Benzenedicarboxylic acid, dioctyl ester.
Benzenamine, N-phenyl-
Hydrazine, 1 ,2-diphenyl-
1 -Propanamine,N-nitroso-N-propyl-
Thioperoxydicarbonic diamide, tetraethyl
Phosphorodithioic acid, O,O-diethyl S-[2-(ethylthio)ethyll
ester
Thioimidodicarbonic diamide [(H2N)C(S)1 2NH
6,9-Methano-2,4,3-benzodioxathiepm,6,7,8,9,10-hexachloro
1 ,5,5a,6,9,9a-hexhydro-,3-oxide.
7-Oxabicyclo[2.2.1 lheptane-2,3-dicarboxylic acid.
2,7:3,6-Dimethanonaphth[2,3-b]oxirene,3,4,5,6,9,9-hexa-
chloro-la,2,2a,3,6,6a,7,7a,octa-hydro-(laalpha,2beta,2abeta,
3alpha,6alpha,6abeta,7beta,7aalpha)-.

Oxirane, (chloromethyl)-
l,2-Benzenediol,4-fl -hydroxy-2- (methylamino)ethyl]-,(R)-
Carbamothioic acid, dipropyl-, S-ethyl ester
Carbamic acid, ethyl ester
Propanemtrile
Zinc, bis(diethylcarbamodithioato-S,S')-
Carbamodithioic acid, 1 ,2-ethanediylbis-

Ethane, 1,2-dibromo-
Ethane, 1 ,2-dichloro-
Ethanol, 2-ethoxy-
Aziridme
Oxirine
2-Imidazohdinethione
Ehtane, 1,1-dichloro-
2-Propenoic acid, 2-methyl-,ethyl ester
Methanesulfonic acid, ethyl ester
Chemical
Abstract No.
3288-58-2
311-45-5
84-66-2
297-97-2
56-53-1
94-58-6
55-9 1-4
60-51-5
119-90-4
60-11-7
57-97-6
119-93-7
79-44-7
57-14-7
540-73-8
122-09-8
105-67-9
131-11-3
77-78-1
644-64-4
25154-54-5
534-52-1

51-28-5
121-14-2
606-20-2
88-85-7
117-84-0
122-39-4
122-66-7
621-64-7
97-77-8
298-04-4
541-53-7
115-29-7
145-73-3
72-20-8

106-89-8
51-43-1
759-94-4
51-79-6
107-12-0
14324-55-1
111-54-6

106-93-4
107-06-2
110-80-5
151-56-4
75-21-8
96-45-7
75-34-3
97-63-2
62-50-0
Hazardous
Waste No.
U087
P041
U088
P040
U089
U090
P043
P044
U091
U093
U094
U095
U097
U098
U099
P046
U101
U102
U103
P191

P047
P047
P048
U105
U106
P020
U017

U109
Ulll

P039
P049
P050
P088
P051
P051
U041
P042

U238
P101

U114
U114
U067
U077
U359
P054
U115
U116
U076
U118
U119
                                      13

-------
Federal RCRA Requirements
Common Name
Famphur
Ferbam
Fluoranthene
Fluorine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Formaldehyde
Formetanate hydrochloride
Fonnic acid
Formparanate
Glycidylaldehyde
Halomethanes, N.O.S.
Heptachlor
Heptachlor epoxide
Heptachlor epoxide (alpha, beta,
and gamma isomers)
Heptachlorodibenzofurans
Heptachlorodibenzo-p-dioxins
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachlorodibenzo-p-dioxins
Hexachlorodibenzofurans
Hexachloroe thane
Hexachlorophene
Hexachloropropene
Hexaethyl tetraphosphate
Hydrazine
Hydrogen cyanide
Hydrogen fluoride
Hydrogen sulfide
Indenofl,2,3-cdlpyrene
3-lodo-2-propynyl n-butylcarbamate
Isobutyl alcohol
Isodnn
Isolan
Isosafrole
Kepone
Lasiocarpme
Uad
Lead compounds, N.O.S.
Lead acetate
Lead phosphate
Lead subacetate
Lmdane
Maleic anhydride
Maleic hydrazide
Malonomtrile
Manganese dimethyldithiocarbamate
Chemical Abstract Name
Phosphorothioic acid, O-[4-[(dimethylamino)sulfonyl]pheny
O,O-di-methyl ester.
Iron, tris(dimethylcarbamodithioato-S-S')-
Same
Same
Acetamide, 2-fluoro-
Acetic acid, fluoro-, sodium salt
Same
Methanimidamide, NN-dimethyl-N'-(3-[[(methylamino)
carbonylloxylphenyll-, monohydrochloride
Same
Methanimidamide, N,N-dimethyl-N'-[2-rnethyl-4-[[(me!hyl
amino) carbonyl]oxy]phenyll-
Oxiranecarboxyaldehyde

4,7-Methano-l H-indene, 1 ,4,5,6,7,8,8-heptachloro-3a,4,7,7a
tetrahydro-
2,5-Methano-2H-indeno[l,2-b]oxirene,2 ,3,4,5,6,7 ,7-hepta
chloro-la, lb,5,5a,6,6a-hexa-hydro-,(laalpha,lbbeta,2alpha,
Salpha, 5abeta,6beta,6aalpha)-



Benzene.hexachloro-
1 ,3-Butadiene, 1 ,1 ,2,3,4,4-hexachloro-
1 ,3-Cyclopentadiene, 1 ,2,3,4,5,5-hexachloro-


Ethane, hexachloro-
Phenol,2,2'-methylenebisr3,4,6-trichloro-
1-Propene, 1,1 ,2,3,3,3 -hexachloro-
Tetraphosphoric acid, hexaethyl ester
Same
Hydrocyanic acid
Hydrofluoric acid
Hydrogen sulfide H2S
Same
Carbamic acid, butyl-, 3-iodo-2-propynyl ester.
1 -Propaiiol,2-methyl-
1 ,4,5,8-Dimethanonaphthalene, 1 ,2,3,4,1 0,10-hexachloro-
l,4,4a,5,8,8a,- hexahydro- (1 alpha,4alpha,4abeta,5beta,
Sbeta, 8abeta)-.
Carbamic acid, dimethyl-, 3-methyl-l-(l-methylethyl)-lH-
pyrazol-5-yl ester
1 ,3-Benzodioxole,5-(l -propenyl)-
l,3,4-Metheno-2H-cyclobuta[cd)pentalen-2-one, 1, 1
a,3,3a,4,5,5a,5b,6-decachlorooctahydro-,
2-Butenoic acid,2-methyl-,7-[[2,3-dihyd roxy-2-(l -methoxy-
ethyl)-3-methyl-l-oxobutoxy]methyl]2,3,5,7a-tetrahydro-l
H-pyrrolizin-1 -yl-ester,f 1 S-[ 1 alpha(Z),7(2S*,3R*),7aalphall.
Same

Acetic acid, lead(2 +)salt
Phosphonc acid, lead(2 +) salt (2:3)
Lead, bis(acetato-O)tetrahydroxtn
Cyclohexane, 1,2,3,4,5,6-hexachloro-, (1 alpha,2alpha,
3beta,4alpha,5alpha, 6beta)-
2,5-Furandione
3,6-Pyridazinedione, 1,2-dihydro-
Propanedmitrile
Manganese, bis(dimethylcarbamodithioato-S,S')-
Chemical
Abstract No.
] 52-85-7
14484-64-1
206-44-0
7782-41-4
640-19-7
62-74-8
50-00-0
23422-53-9
64-18-6
17702-57-7
765-34-4

76-44-8
1024-57-3



118-74-1
87-68-3
77-47-4


67-72-1
70-30-4
1888-71-7
757-58-4
302-01-2
74-90-8
7664-39-3
7783-06-4
193-39-5
55406-53-6
78-83-1
465-73-6
119-38-0
120-58-1
143-50-0
303-34-1
7439-92-1

301-04-2
7446-27-7
1335-32-6
58-89-9
108-31-6
123-33-1
109-77-3
15339-36-3
Hazardous
Waste No.
P097

U120
P056
P057
P058
U122
P198
U123
P197
U126

P059




U127
U128
U130


U131
U132
U243
P062
U133
P063
Ul 34
U135
U137

U140
P060
PI 92
U141
U142
4143


U144
UI45
U146
U129
U147
U148
U149
PI 96
                                      14

-------
Federal RCRA Requirements
Common Name
Melphalan
Mercury
Mercury compounds, N.O.S.
Mercury fulminate
Metam sodium
Methacrylonitrile
Methapyrilene
Methiocarb
Methomyl
Methoxychlor
Methyl bromide
Methyl chloride
Methyl chlorocarbonate
Methyl chloroform
3-Methylcholanthrene
4,4-Methylenebis(2-chloroaniline)
Methylene bromide
Methylene chloride
Methyl ethyl ketone (MEK)
Methyl ethyl ketone peroxide
Methyl hydrazine
Methyl iodide
Methyl isocyanate
2-Methyllactomtrile
Methyl methacrylate
Methyl methanesulfonate
Methyl parathion
Methylthiouracil
Metolcarb
Mexacarbate
Mitomycin C
MNNG
Mohnate
Mustard gas
Naphthalene
1 ,4-Naphthoquinone
alpha-Naphthylamine
beta-Naphthylamme
alpha-Naphthylthiourea
Nickel
Nickel compounds, N.O.S.
Nickel carbonyl
Nickel cyanide
Nicotine
Nicotine salts
Nitnc oxide
p-Nitroanihne
Nitrobenzene
Nitrogen dioxide
Nitrogen mustard
Nitrogen mOstard, hydrochlonde salt
Nitrogen mustard N-oxide
Nitrogen mustard, N-oxide, hydro-chloridf
salt
Nitroglycenn
p-Nitrophenol
2-Nitropropane
Chemical Abstract Name
L-Phenylalanine, 4-[bis(2-chloroethyl)aminoll-
Same

Fulminic acid, mercury(2+)salt
Carbamodithioic acid, methyl-, monosodium salt.
2-Propenenitrile,2-methyl-
l,2-Ethanediamine,N)N-dirnethyl-N'-2-pyridinyl-N'-(2-
thienylmethyl)-
Phenol, (3,5-dimethyl-4-(methylthio)-,methylcarbamate.
Ethanimidothioic acid, N- [[(methylamino)carbonyl]oxy]-
methyl ester.
Benzene, 1 ,1 ' -(2,2,2 -trichloroethylidene)bis[4-methoxy-
Methane, bromo-
Methane, chloro-
Carbonochloridic acid, methyl ester
Ethane , 1 , 1 , 1 -trichloro-
Benzfilaceanthrylene, 1 ,2-dihydro-3-methyl-
Benzenamine,4,4'-methylenebisf2-chloro-
Methane, dibromo-
Methane, dichloro
2-Butanone
2-Butanone,peroxide
Hydrazine, methyl-
Methane, iodo-
Methane, isocyanato-
Propanenitrile,2-hydroxy-2-methyl-
2-Propenoic acid,2-methyl,methyl ester
Methanesulfonic acid, methyl ester
Phosphorothioic acid, O,O-dimethyl O-(4-mtrophenyl)ester.
4(1 H)-Pyrimidinone,2,3-dihydro-6-methyl-2-thioxo-
Carbamic acid, methyl-, 3-methylphenyl
Phenol, 4-(dimethylamino)-3,5-dimethl-) methylcarbamate
(ester).
Azinno[2 ' ,3 ' :3,4]pyrrolo[ 1 ,2-a]indole-4,7-dione,6-ammo-8-
[[(arranocarbonyl)oxy]methyl]-l, 1 a,2,8,8a,8b-hexahydro-
8a-methoxy-5-methyl-,(laalpha,8beta,8balpha)l-
Guanidine,N-methyl-N'-nitro-N-nitroso-
IH-Azepme-l-carbothioic acid, hexahydro,-S-ethyl ester.
Ethane, l,l'-thiobis[2-chloro-
Same
1 ,4-Naphthalenedione
1 -Naphthalenamme
2- Naphthalenamine
Thiourea, 1 -naphthalenyl-
Same

Nickel carbonyl Ni(COK(T-4)-
Nickel cyanide Ni(CN)2
Pyridine,3-(l-methyl-2-pyrrolidinyl)-, (S)-

Nitrogen oxide NO
Benzenamine, 4-nitro-
Benzene, nitro-
Nitrogen oxide N02
Ethanamme, 2-chloro-N-(2-chloroethyl)-N-methyl

Ethanamine,2-chloro-N-(2-chloroethyl)-N-methyl, N-oxide

1,2,3-Propanetnol, tnnitrate
Phenol ,4-nitro-
Propane, 2-nitro-
Chemical
Abstract No.
148-82-3
7439-97-6

628-86-4
137-42-8
126-98-7
91-80-5
2032-65-7
16752-77-5
72-43-5
74-83-9
74-87-3
79-22-1
71-55-6
56-49-5
101-14-4
74-95-3
75-09-2
78-93-3
1338-23-4
60-34-4
74-88^t
624-83-9
75-86-5
80-62-6
66-27-3
298-00-0
56-04-2
1129-41-5
315-13-4
50-07-7
70-25-7
2212-67-1
505-60-2
91-20-3
130-15-4
134-32-7
91-59-8
86-88-4
7440-02-0

13463-39-3
557-19-7
54-11-5

10102-43-9
100-01-6
98-95-3
10102-44-0
51-75-2

126-85-2

55-63-0
100-02-7
79-46-9
Hazardous
Waste No.
U150
U151

P065

U152
U155
PI 99
P066
U247
U029
U045
U156
U226
U157
U158
U068
U080
U159
U160
P068
UBS
P064
P069
U162

P071
U164
P190
P128
U010
U163


U165
U166
U167
U168
P072


P073
P074
P075
P075
P076
P077
U169
P078




P081
U170
U171
                                      15

-------
Federal RCRA Requirements
Common Name
Nitrosamines, N.O.S.
N-Nitrosodi-n-butylamine
N-Nitrosodiethanolamine
N-Nitrosodiethylamine
N-Nitrosodirnethylarnine
N-Nitroso-N-ethylurea
N-Nitrosomethylethylamine
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosomethylvinylamine
N-Nitrosomorpholine
N-Nitrosonornicotine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
N-Nitrososarcosine
5-Nitro-o-toluidine
Octamethylpyrophosphoramide
Osmium tetroxide
Oxamyl
Paraldehyde
Parathion
Pebulate
Pentachlorobenzene
Pentachlorodibenzo-p-dioxins
Pentachlorodibenzofurans
Pentachloroethane
Pentachloronitrobenzene (PCNB)
Pentachlorophenol
Phenacetin
Phenol
Phenylenediamine
Phenylmercury acetate
Phenylthiourea
Phosgene
Phosphme •
Phorate
Phthahc acid esters, N.O.S.
Phthalic anhydnde
Physostigmine
Physostigmine salicylate
2-Picohne
Polychlonnated biphenyls, N.O.S.
Potassium cyanide
Potassium dimethyldithiocarbamate
Potassium n-hydroxymethyl-n-methyl-
dithiocarbamate
Potassium n-methyldithiocarbamate
Potassium pentachlorophenate "
Potassium stiver cyanide
Promecarb
Pronamide
1 ,3-Propane sultone
n-Propylamme
Propargyl alcohol
Propham
Propoxur
Propylene dichloride
Chemical Abstract Name

l-Butanamine, N-butyl-N-nitroso-
Ethanol,2,2'-(nitrosoimino)bis-
Ethananrine,N-ethyl-N-nitroso-
Methanamine, N-methyl-N-nitroso-
Urea, N-ethyl-N-nitroso-
Ethanamine, N-methyl-N-nitroso-
Urea, N-methyl-N-nitroso-
Carbamic acid, methylnitroso-, ethyl ester
Vinylairrine, N-methyl-N-nitroso-
Morpholine, 4-nitroso-
Pyridine,3-(l-nitroso-2-pyrrolidiyl)-,(S)-
Piperidine, 1-nitroso-
Pyrrolidine, 1-nitroso-
Glycine, N-methyl-N-nitroso-
Benzenamine^-methyl-5-nitro-
Diphosphoramide, octamethyl-
Osmium oxide OsO4 (T-4>
Ethanimidothioic acid, 2-(dimethylamino)-N-[[(methyl-
amino)carbonylloxyl-2-oxo-, methyl ester.
1,3,5-Trioxane, 2,4,6-trimethyl-
Phosphorothioic acid, O,O-diethyl O- (4-nitrophenyl) ester.
Carbamothioic acid, butylethyl-, S-propyl ester.
Benzene, pentachloro-


Ethane, pentachloro-
Benzene, pentachloronitro-
Phenol, pentachloro-
Acetamide, N-(4-ethoxyphenyl)-
Same
Benzenediamine
Mercury, (acetato-O) phenyl
Thiourea, phenyl
Carbonic dichloride
Same
Phosphorodithioic acid, O,O-diethyl S-[(ethylthio)methyl
ester.

1 , 3-lsobenzofurandione
Pyrrolo [2,3-b]indol-5-01 , l,2,3,3a,8,8a-hexahydro-l,3a,8-
trimethyl-.methylcarbamate (ester), (3aS-cis)-
Benzoic acid, 2-hydroxy-, compd. with (3aS-cis)
-l,2,3,3a,8,8a-hexahydro-l ,3a,8-trimethylpyrrolo [2,3-
b]indol-5-yl methylcarbamate ester (1:1).
Pyridine, 2-methyl-

Potassium cyanide K(CN)
Carbamodithioic acid, dimethyl, potassium salt
Carbamodithioic acid, (hydroxymethyl)methyl-,mono-
potassium salt.
Carbamodithioic acid, methyl-monopotassium salt
Pentachlorophenol, potassium salt
Argentate (1-), bis(cyano-C),^potassium
Phenol, 3-methyl-5-(l-methylethyl)-, methyl carbamate.
Benzamide, 3,5-dichloro-N-(l ,1 -dimethyl-2-propynyl)-
1,2-Oxathiolane, 2,2 -dioxide
1 -Propanamine
2-Propyn-l-ol
Carbamic acid, phenyl-, 1-methylethyl ester
Phenol, 2-(l-methylethoxy)-, methylcarbamate.
Propane, 1 ,2-dichloro-
Chemical
Abstract No.
35576-91-1D
924-16-3
111 6-54-7
55-18-5
62-75-9
759-73-9
10595-95-6
684-93-5
615-53-2
4549-40-0
59-89-2
16543-55-8
100-75-4
930-55-2
13256-22-9
99-55-8
152-1 6-9
20816-12-0
23135-22-0
123-63-7
56-38-2
1114-71-2
608-93-5


76-01-7
82-68-8
87-86-5
62-44-2
108-95-2
25265-76-3
62-38^
103-85-5
75-44-5
7803-51-2
298-02-2

85-44-9
57-47-6
57-64-7
109-06-8

151-50-8
128-03-0
51026-28-9
137-41-7
7778736
506-61-6
2631-37-0
23950-58-5
1120-71-4
107-10-8
107-19-7
122-42-9
114-26-1
78-87-5
Hazardous
Waste No.

U172
U173
U174
P082
U176

U177
U178
P084


U179
U180

U181
P085
P087
PI 94
U182
P089

U183


U184
U185
See F027
U187
U188

P092
P093
P095
P096
P094

U190
P204
PI 88
U191

P098



None
P099
P201
U192
U193
U194
P102
U373
U411
U083
                                      16

-------
Federal RCRA Requirements
Common Name
1 ,2-Propylenimine
Propylthiouracil
Prosulfocarb
Pyridine
Reseipine
Resoreinol *
Saccharin
Saccharin salts
Safrole
Selenium
Selenium compounds, N.O.S.
Selenium dioxide
Selenium sulfide
Selenium, tetrakis (dimethyl-dithio-
carbamate)
Selenourea
Silver
Silver compounds, N.O.S.
Silver cyanide
Silvex (2,4,5-TP)
Sodium cyanide
Sodium dibutyldithiocarbamate
Sodium diethyldithiocarbamate
Sodium dimethyldithiocarbamate
Sodium pentachlorophenate
Strep tozotocin
Strychnine
Strychnine salts
Sulfallate
TCDD
Tetrabutylthiuram disulfide
1 ,2,4,5-Tetrachlorobenzene
Tetrachlorodibenzo-p-dioxins
Tetrachlorodibenzofurans
Tetrachloroethane,N.O.S
1,1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethylene
2,3,4,6-Tetrachlorophenol
2,3,4,6-Tetrachlorophenol, potassium salt
2,3,4,6-Tetrachlorophenol, sodium salt
Tetraethylduhiopyrophosphate
Tetraethyl lead
Tetraethyl pyrophosphate
Tetramethylthiuram monosulfide
Tetramtrome thane
Thallium
Thallium compounds, N.O.S.
Thallic oxide
Thallmm(l)acetate
Thallium(l) carbonate
Thallium(l) chloride
Thallium(l) nitrate
Thallium selenite
Thalhum(l) sulfate
Thioacetamide
Thiodicarb
Thiofanox
Chemical Abstract Name
Aziridine, 2-methyl-
4(1 HVPvrimidinone, 2,3-dihydro-6-propyl-2-thioxo-
Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester.
Same
Yohimban-16-carboxylic acid, 11, 17-dimethoxy-18-[(3,4,5
trimethoxybenzoyl)oxy]-smethyl ester (3beta, 16beta,
17alpha, ISbeta, 20alpha>-
1 ,3-Benzenediol
1 ,2-Benzisothiazol-3(2H>one, 1 , 1 -dioxide

1 ,3-Benzodioxole, 5-(2-propenyl)-
Same

Selenious acid
Selenium sulfide SeSz
Carbamodithioic acid, dimethyl-, tetraanhydrosulfide with
orthothioselenious acid.
Same
Same

Silver cyanide Ag(CN)
Propanoic acid, 2-(2,4,5-trichlorophenoxy>
Sodium cyanide Na(CN)
Carbamodithioic acid, dibutyl, sodium salt
Carbamodithioic acid, diethyl-, sodium salt
Carbamodithioic acid, dimethyl-, sodium salt '
Pentachlorophenol, sodium salt
D-Glucose,2-deoxy-2-[[(meihylnitrosoamino)carbonyl]-
amino]-
Strychnidin-1 0-one

Carbamodithioic acid, diethyl-, 2-chloro-2-propenyl ester.
Dibenzo[b,e1f 1 ,41dioxin, 2,3,7 ,8-tetrachloro-
Thioperoxydicarbonic diamide, tetrabutyl
Benzene, 1,2,4,5-tetrachloro-


Ethane, tetrachloro-, N.O.S.
Ethane, 1,1, 1 ,2-tetrachloro-
Ethane, 1, 1,2,2-tetrachloro-
Ethene, tetrachloro-
Phenol,2,3,4,6-tetrachloro-
same
same
Thiodiphosphoric acid, tetraethyl ester
Plumbane, tetraethyl
Diphosphonc acid, tetraethyl ester
Bis(dimethylthiocarbamoyl) sulfide
Methane, tetramtro-
Same

Thallium oxide ThOs
Acetic acid, thallium(l +) salt
Carbonic acid, dithallium(l +) salt
Thallium chloride TIC1
Nitric acid, thallium(l +) salt
Selenious acid, dithallium(l +) salt
Sulfuric acid, dithallium(l +) salt
Ethanethioamide
Ethanomidothioic acid, N,N'-[thiobis [(methyhmmo)
carbonyloxyJlbis-, dimethyl ester.
2-Butanone,3,3-dimethyl-l-(methylthio)-,0-[(methylamino)
Chemical
Abstract No.
75-55-8
51-52-5
52888-80-9.
110-86-1
50-55-5
108-46-3
81-07-2

94-59-7
7782-49-2

7783-00-8
7488-56-4
144-34-3
630-10-4
7440-22-4

506-64-9
93-72-1
143-33-9
136-30-1
148-18-5
128-04-1
131522
18883-66-4
57-24-9

95-06-7
1 746-0 r-6
1634-02-2
95-94-3


25322-20-7
630-20-6
79-34-5
127-18-4
58-90-2
53535276
25567559
3689-24-5
78-00-2
107-49-3
97-74-5
509-14-8
7440-28-0

1314-32-5
563-68-8
6533-73-9
7791-12-0
10102-45-1
12039-52-0
7446-18-6
62-55-5
59669-26-0
39196-18-4
Hazardous
Waste No.
P067

U387
U196
U200
U201
U202
U202
U203


U204
U205

P103


P104
See F027
P106



None
U206
P108
P108



U207



U208
U209
U210
See F027
None
None
P109
P110
Pill

P112


P113
U214
U215
U216
U217
P114
P115
U218
U410
P045
                                      17

-------
Federal RCRA Requirements
Common Name

Thiomethanol
Thiophanate-methyl
Thiophenol
Thiosetrticarbazide
Thiourea
Thiram
Tirpate
Toluene
Toluenediamine
Toluene-2,4-diamine
Toluene-2,6-diamine
Toluene-3,4-diamine
Toluene diisocyanate
o-Toluidine
o-Toluidine hydrochloride
p-Toluidine
Toxaphene
Triallate
1 ,2,4-Tnchlorobenzene
1 ,1 ,2-Trichloroethane
Trichloroethylene
Trichloromethanethiol
Trichloromonofluoromethane
2,4,5-Tnchlorophenol
2,4,6-Trichlorophenol
2,4,5-T
Trichloropropane, N.O.S.
1 ,2,3-Tnchloropropane
Triethylamine
O,O,O-Triethyl phosphorothioate
1 ,3,5-Trinitrobenzene
Tris(l-aziridinyl)phosphine sulfide
Tns(2,3-dibromopropyl)phosphate
Trypan blue
Uracil mustard
Vanadium pentoxide
Vemolate
Vinyl chloride
Warfarin
Warfarin
Warfarin salts, when present at
concentrations less than 0.3%
Warfarin salts, when present at
concentrations greater than 0.3%
Zinc cyanide
Zinc phosphide
Zinc phosphide
Ziram
Chemical Abstract Name
carbonylloxime.
Methanethiol
Carbamic acid, [1,2-phenylenebis (iminocarbonothioyl)] bis-
dimethyl ester
Benzenethiol
Hydrazinecarbothioamide
Same
Thioperoxydicarbonic diamider(H2N)C(S)]2S 2, tetramethyl-
l^-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O-
f(methylamino)carbonyll oxime.
Benzene, methyl-
Benzenediamine, ar-methyl-
1 ,3-Benzenediamine, 4-methyl-
1 ,3-Benzenediamine, 2-methyl-
1,2-Benzenediamine, 4-methyl-
Benzene, 1,3-diisocyanatomethyl-
Benzenamine, 2-methyl-
Benzenamine, 2-methyl-, hydrochloride
Benzenamine, 4-methyl-
Same
Carbamothioic acid, bis(l-methylethyl)-, S-(2,3,3-trichloro-2
propenyl) ester
Benzene, 1,2,4-trichloro-
E thane, 1,1,2-trichloro-
Ethene, trichloro-
Methanethiol, trichloro-
Methane, trichlorofluoro-
Phenol, 2,4,5-trichloro-
Phenol, 2,4,6-trichloro-
Acetic acid, (2,4,5-trichlorophenoxy)-

Propane, 1,2,3-trichloro-
Ethanarmne, N,N-diethyl-
Phosphorothioic acid, O,O,O-triethyl ester
Benzene, 1,3,5-tnnitro-
Aziridine, 1,1 ',1 "-phosphinothioylidynetris-
1 -Propanol, 2,3-dibromo- .phosphate (3:1)
2,7-Naphthlenedisulfonic acid, 3,3'-[3,3'-dimethyl[l,r-
biphenyl]-4,4'diyl)bis(azo)]bis[-5-amino-4-hydroxy-,
tetrasodium salt.
2,4-(l H,3H)-Pyrimidinedione, 5- rbis(2-chloroethyl)aminol-
Vanadium oxide V2Os
Carbamothioic acid, dipropyl-, S-propyl ester
Ethene, chloro
2H-l-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-l-phenylbutyl)-
when present at concentrations less than 0.3%
2H-l-Benzlopyran-2-one,4-hydroxy-3-(3-oxo-l-phenylbutyl)
when present at concentrations greater than 0.3%.


Zinc cyanide Zn(CN)2
Zinc phosphide Zn3P2 when present at concentrations
greater than 10%.
Zinc phosphide Zn3P2 when present at concentrations of
10% or less.
Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)-
Chemical
Abstract No.

74-93-1
23564-05-8
108-98-5
79-19-6
62-56-6
137-26-8
26419-73-8
108-88-3
25376-4-8
95-80-7
823-40-5
496-72-0
26471-62-5
95-53-4
636-21-5
106-49-0
8001-35-2
2303-17-5
120-82-1
79-00-5
79-01-6
75-70-7
75-69-4
95-95-4
88-06-2
93-76-5
25735-29-9
96-18-4
121-M-8
126-68-1
99-35-4
52-24^
126-72-7
72-57-1
66-75-1
1314-62-1
1929-77-7
75-01-4
81-81-2
81-81-2


557-21-1
1314-84-7
1314-84-7
137-30-4
Hazardous
Waste No.

U153
U409
P014
P116
U219
U244
P185
U220
U221



U223
U328
U222
U353
P123
U389

U227
U228
P118
U121
See F027
See F027
See F027


U404

U234

U235
U236
U237
P120

U043
U248.
P001
U248
PO01
P121
P122
U249
P205
                                      18

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Federal RCRA Requirements
                                 [TfflS PAGE INTENTIONALLY LEFT BLANK]
                                19

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                                        CHAPTER 2
     FEDERAL DOT REGULATIONS FOR THE HIGHWAY TRANSPORTATION
            OF HAZARDOUS SUBSTANCES AND HAZARDOUS WASTE
Subchapter I: Introduction to the DOT Hazardous Materials Transportation
Regulations

Transportation requirements are specific to the mode of transportation, such as air,
water or ground. Ground transportation can be further divided into highway,
passenger, and rail. This manual will concentrate on highway transportation of
hazardous materials, which is the normal mode of hazardous waste transportation from
a removal site.
49 CFR Department
of Transportation
Subchapter C Hazardous
Materials Regulations
Part 171 General
Information,
Regulations, and
Definitions
Subchapter II: DOT Hazardous Materials Descriptions and Hazard  '
Classifications

Hazardous wastes and hazardous substances transported off site for treatment and/or
disposal must comply with the DOT hazardous materials requirements. The DOT
defines a hazardous material as a substance or material that is capable of posing an
unreasonable risk to health, safety, and property when transported in commerce.  DOT
hazardous materials include all hazardous substances as defined by CERCLA and
hazardous wastes as defined by RCRA.

The DOT Hazardous Materials Table (HMT) in 49 CFR Part 172. 101 provides
references to other sections of 49 CFR from which may be obtained proper
packaging guidelines for both bulk and non-bulk transportation of hazardous
materials, special provisions or exemptions, and container labeling requirements, all
according to shipping names. Thus, the proper shipping name must be assigned to a
waste to determine all other applicable DOT requirements. The HMT lists possible
shipping names in column 2 in alphabetical order.  The majority of the shipping
names are chemical compounds and mixtures. The numerical code listed in column
3 of the HMT represents the hazard class division of the particular material. The
DOT hazard class definitions and references to 49 CFR follow.
Part 171 General
Information,
Regulations, and
Definitions
171.8 Definitions and
abbreviations
Part 172 Hazardous
Materials Table,
Special Provisions,
Hazardous Materials
Communications
Requirements and
Emergency Response
Information
Requirements
Subpart 8 Table of
Hazardous Materials
and Special
Provisions
172.01 Purpose and
use of hazardous
materials table
Hazard Class:

A.  Class 1 - Explosives (49 CFR 173.50)

     Any material which functions by explosion (extremely rapid release of gas and
     heat) either from design or from inherent chemical characteristics, unless
     otherwise classed.  Divisions 1.1, 1.2, 1.3,  1.4, 1.5, and 1.6 are in this class.

B.   Class 2-Gases .(49 CFR 173.115)

     2.1 Flammable gases
     2.2  Non-flammable, non-poisonous compressed gases (including compressed
Part 173 Shippers-
General
Requirements for
Shipments and
Packaging

173.21 Forbidden
materials and packages

-------
Federal DOT Regulations
        gas, liquefied gas, pressurized cryogenic gas, compressed gas in solution,
        asphyxiant gas, and oxidizing gas)
     2.3 Gas poisonous by inhalation (see 173.116 for required assignment of hazard
        zone)

C.  Class 3 - Ignitable Liquids (49 CFR 173.120)

    Flammable liquids: flash point (FP) < 141°F
    Combustible liquids: 141°F < FP < 200°F
    (Note: Flammable liquids with a flash point of 100°F to 141°F may also be
    classed as combustible.)

D.  Class 4 - Ignitable Solids (49 CFR 173.124)

     4.1 Flammable solids: Desensitized explosives (wetted with an appropriate
        media to suppress explosive properties), self-reactive materials (undergo
        strong exothermic decomposition at normal or elevated temperatures),
        readily combustible solids (matches, powdered metals).
     4.2 Spontaneously combustible materials: Pyrophoric materials (materials that
        without an external source of ignition can ignite within 5 minutes after
        coming in contact with air), self-heating materials (self heat when reacting
        with air).
     4.3 Dangerous When Wet Materials: Materials that either are spontaneously
        flammable or give off flammable or toxic gases when in contact with water.

E.   Class 5 - Oxidizing Materials (49 CFR 173.127)

     5.1 Oxidizers: Materials that may cause or enhance the combustion of other
        materials, generally by yielding oxygen.
     5.2 Organic peroxides: Organic compounds containing oxygen in a bivalent 0-0
        structure, which may be considered a derivative of hydrogen peroxide (an
      - organic peroxide). If the DOT lists a particular peroxide as an explosive,
        then it is classed for transportation purposes as an explosive, not as an
        oxidizer. Note: The table in 49 CFR 173.225 (b) lists organic peroxides
        by technical name.

F.   Class 6 - Toxic Materials (49 CFR 173.132 -  173.134)

     6.1 Poisonous materials: A material other than a gas which is known to be so
        toxic to humans as to afford a hazard to health during transportation.
        Poison inhalation hazards: 49CFR173.133 establishes hazard zone criteria
        for materials which pose a poison inhalation hazard to humans. The hazard
        zone ranking system starts with the letter  "A" for the most severe hazards
        and extends to the letter "D"  for the least  severe hazards. Certain materials
        which are not defined as Class 6.1 are defined by the DOT as "poison
        inhalation hazards." Likewise, not all Class 6.1 materials meet the criteria
        of a "poison inhalation hazard."
     6.2 Infectious substances or etiologic agents:  Diagnostic specimens (human or
        animal material), biological product (investigational drugs) and regulated
        medical wastes containing an infectious or potentially infectious substance.
                                              21

-------
Federal DOT Regulations
        This category includes agents listed in 42 CFR 72.3 (Department of Health
        and Human Services or DHHS).

G.   Class 7 - Radioactive Materials (49 CFR 173.401 -173.478)

     Any material having a specific activity greater than 70Bq per gram.
     Radioactive materials constitute a special case, and will not be covered in detail
     in this manual.  In addition to 49 CFR, 10 CFR Part 71 must also be consulted
     prior to packaging and transportation of radioactive materials.

H.  Class8-CorrosiveMaterials(49CFR 173.136)

     Liquids or solids that cause full thickness destruction to human skin at the site
    of contact, or liquids that rapidly corrode steel or aluminum.

I.   Class 9 - Miscellaneous Hazardous Materials (49 CFR 173.140)

    Includes hazardous substances and  hazardous wastes that do not meet any other
    DOT hazard classification and elevated temperature materials (e.g., hot tar).

Packing Group:

The packing group for each description is depicted in column 5 of the HMT as I, n
or III and represents the degree of hazard associated with each hazard classification.
Packing group I represents a high hazard, n is a medium hazard and m is a low
hazard.  The packing group must be determined for materials that are described with
a generic hazard classification. The determination of the packing group for a
mixture can best be done by evaluating the listing in the HMT for the constituent(s)
that causes the material to be assigned to a particular hazard class.  The packing
group for a flammable liquid can be assigned from data on the material's flash point
and boiling point as follows:
                              Boiling Point
                               <95°F
                               >95°F
                               >95°F
49 CFR
Department of
Transportaaon
SubchipttrC
Hazardous
Materials Regulations

Pan 173 Shippers
Geneiil
Requirements for
Shipment! and
Packaging Subpan B
Preparation of
Hazardous Materials
for Transportation I
GROUP
I
n
III
Flash Point

<73°F
73 to 141°F
Special Provisions:

Column 7 of the Hazardous Materials Table (49 CFR172.101) provides special
provisions for the shipping description. The special provisions are listed according to
numerical/alphabetical codes.  Definitions and specific directives are presented in 49
CFR172.102 Special Provisions, for each code represented. A code in Column 7
should be a flag to the generator that special handling may be required for the listed
material.  For example, codes "1" through "6" represent materials which are poisonous
by inhalation.
                                               22

-------
 Federal DOT Regulations'
 Waste Mixtures:

 If the waste mixture to be transported can be assigned to more than one hazard
 classification, the material must be classed according to the highest applicable
 hazard. A material that meets the definition of Class I (explosives), Division 5.2
 (organic peroxides), Division 4.1 (wetted explosives), or Division 6.2 (infectious
 substances) is always classed as such regardless of any other hazards associated with
 the material, due to the unique properties associated with these categories. The
 following hazard classes take precedence over the remaining hazard classes in the
 order listed:

 Radioactives  (Class 7)
 Poisonous gases (Division 2.3)
 Flammable gases (Division 2.1)
 Non-flammable gases (Division 2.2)
 Poisonous liquids, PGI, poisonous by inhalation (Division 6.1)
 Pyrophorics (Division 4.2)
 Self-reactives (Division 4.1)

 The Precedence of Hazard Table in 49 CFR 173.2a must be consulted to determine
 the highest applicable hazard for mixtures that meet more than one of the following
 classes:
 49 CFR
 Department of
 Transportation
 Subchapter C
 Hazardous
 Materials Regulations

 Part 173 Shippers
 General Requirements
 for Shipments and
 Packagings 173.2a
 Classifications of a
 material having more
 than one hazard
Dangerous when wet (Division 4.3)
Flammable liquids (Class 3)
Oxidizers (Division 5. 1)
Flammable solids (Division 4. 1) other than wetted explosives and self-reactives
Spontaneously combustible (Division 4.2)
Corrosive materials (Class 8)
Poisonous liquids and solids, II & III (Class 6)

The precedence of the above classifications depends on the packaging group of the
material. The classifications "combustible liquids" (Class 3) and "miscellaneous
hazardous materials" (Class 9) are only used when no other hazard class can be
applied.

Subchapter HI: General DOT Hazardous Materials Packaging Requirements

All hazardous materials must be packaged according to DOT specifications prior to
shipment. The process of determining the proper packaging specifications has several
steps.

As with most regulations, gaining an understanding of regulatory definitions and the
application of general exemptions to the regulations is the first step in evaluating
hazardous waste packaging requirements. Hazardous material packagings for highway
transportation are subdivided into bulk and non-bulk containers. Bulk containers have
a capacity of greater than 119 gallons (450 liters) for liquids and greater than 883
pounds (400 kilograms) for solids, and have no intermediate form of containment.
Non-bulk containers have a capacity of less than 119 gallons or 882 pounds.
9 CFR
Department of
Transportation
Subchapter C
Hazardous
Materials Regulations
Part 171 General
Information,
Regulations,
and Definitions

171.8 Definitions and
abbreviations
                                                23

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Federal DOT Regulations
Packaging Exemptions:

The DOT requires all packages used for a particular hazardous material or hazard
class to pass DOT tests to ensure that the containers will not allow the release of the
hazardous material under normal transportation conditions or during a typical
transportation incident.  General requirements for non-bulk packages are listed in 49
CFR 173.24a and include the following: inner packaging to be contained with the
closures upright, inner packaging to be cushioned to prevent friction and breakage,
and proper filling of the containers to be based on specific gravity and vapor
pressure of the material. General requirements for bulk packages are listed in 49
CFR 132.24b and relate to filling limits and methods, and to container structural
requirements.

The use of salvage drums (incorrectly referred to as "overpacks") is common on
removal sites. DOT-defined "salvage drums" are used to contain damaged, defective
or leaking packages for transport for disposal or repackaging. A salvage drum
manufactured prior to October 1, 1993, is subject to provisions brought into effect on
September 30,1992. These provisions allow for the use of any drum that has
structural integrity equal to or greater than that required for the hazardous material to
be contained, and that does not exceed a maximum capacity of 110 gallons.  Salvage
drums manufactured after October 1,1993; must meet DOT specifications and testing
requirements and may not exceed 119 gallons in capacity. The new. salvage drum
provisions still require cushioning and absorbent to prevent movement of the interior
package and to eliminate the release of any free flowing liquids.  "Overpack" refers to
an enclosure that is used to provide protection for a package or packages; it can only
be used if the requirements of 49 CFR 173.25 are met.

DOT drum packaging specifications for many hazardous materials only allow closed
head drums (drums with bung openings instead of a removable lid) to be used for
transport. However, DOT provides for exemption to this rule for hazardous waste.
Under this exemption, open head drums may be used if the waste substance cannot
be physically placed into a  closed head drum.

Previously-used containers may be reused once to transport waste without being
subject to the reconditioning and testing requirements established in 49 CFR 173.28
and 178.

Two or more different waste materials, which are chemically compatible, and are
less than 4 liters (1 gallon)  each, may be packed in the same shipping container as a
"lab pack."  The "lab pack" exemption for the transportation of laboratory wastes is
discussed in further detail in Chapter 8.

Packaging Selection:

The second step in determining DOT packing specifications for a specific waste is to
reference the HMT (49 CFR 172. 1 0 1). Each hazardous material's shipping name
listed in column 2 of the table has applicable packaging regulations  (CFR sections)
referenced in column 7 (special provisions) and in column 8 (packaging
authorizations).  Column 8 is further divided into column 8A (exemptions), column
8B (non-bulk packagings),  and column 8C (bulk packagings).
Part 173 Shipper
General
Requirements for
Shipments and
Packaging

SubpartB
Preparation of
Hazardous Materials
for
Transportation
173.24 General
requirements for
packagings and
packages
Subpart A General
173.3 Packing and
exceptions
173.12 Exceptions for
shipment of waste
materials
49 CFR
Department of
Transportation
Part 172 Hazardous
Materials Table
Special Provisions
172.101 Purpose and
use of hazardous
materials table
                                                24

-------
 Federal DOT Regulations
 The special provision references listed in column 7 of the HMT are coded according
 to the applicable mode of transportation and bulk and non-bulk packaging. Special
 provision codes referenced in column 7 of the HMT are defined as follows:

 Numbers-only codes refer to bulk and non-bulk packaging.
 •  "A"  refers to transportation by aircraft.
 •  "B" refers to bulk packages only.
         refers to transportation by highway.
         refers to non-bulk packages only.
         refers to transportation by rail.
         refers to intermodal* portable tanks (intermodal (IM) portable tanks are
         freight containers designed to be used in several modes of transportation
         such as highway and rail.)
          refers to transportation by water.
"H"
"N"
"R"
ll'T'll
"W"
The provisions in column 7 impose limitations or additional requirements on
package specifications referenced in column 8 of the HMT. The word "none" in
column 8A, 8B, or 8C of the HMT indicates that no exemptions, non-bulk
packaging, or bulk packaging, respectively, are authorized, except as may be
provided for under special provisions (column 7).

The final step in determining the proper packaging for a hazardous material is to
apply the references obtained in the hazardous materials table. The packaging
specifications referenced in column 8 of the HMT are detailed in 49 CFR 173.
Special provisions can be referenced by code in 49 CFR 172.102.

Section 173 of 49 CFR contains the DOT specifications for packagings that may be
used to transport a material within a particular hazard class and packing group.
Again, an understanding of the regulatory definitions and codings is needed to apply
the packaging specifications to a hazardous material to be shipped.

The DOT defines authorized combination packagings and authorized single
packagings. Combination packaging consists of one or more inner packages secured
in a non-bulk outer package. Single packaging is non-bulk packaging other than
combination packaging, and includes composite packaging. Composite packaging
consists of an outer packaging and an inner receptacle and is constructed so that the
total package forms an integrated whole.  Once a composite package is constructed,
it is always handled as a single unit.

DOT standards for packaging hazardous materials are based on United Nations (UN)
recommendations. Identification codes are assigned to types of authorized
packaging and are referred to as "DOT packaging specifications." The identification
code system for non-bulk packages involves a series of numbers and capital letters.
The number preceding a capital letter identifies the type of container (drum, box,
composite package, etc.). The capital letter refers to the construction material of the
container (steel, wood, plastic, etc.). The number appearing after a capital letter
indicates whether a drum has a removable head (code number "1") or non-removable
head (code number "2").  A composite package is coded with a "6" to identify the
type of container and with two capital letters together to identify the construction
materials. The first capital letter in the composite package identification code refers
                                               25
                                                                               49 CFR
                                                                               Department of
                                                                               Transportation
                                                                               Pan 172 Hazardous
                                                                               Materials Table
                                                                               Special Provisions
                                                                               172.102 Special
                                                                               provisions
                                                                               172.1 01 Purpose and
                                                                               use of hazardous
                                                                               materials table
                                                                              49 CFR
                                                                              Department of
                                                                              Transportation
                                                                              Subchapter C
                                                                              Hazardous
                                                                              Matenals Regulations
                                                                              Part 178
                                                                              Specifications
                                                                              for Packagings
                                                                              Subpart L Non-bulk
                                                                              Performance-oriented
                                                                              Packaging Standards
                                                                              178.502
                                                                              Identification
                                                                              code for packagings

-------
Federal DOT Regulations
to the inner package and the second capital letter refers to the outer package.
Combination packages are designated with the outer code number only.
Identification codes are defined as follows:

1 - drum                     A - steel
2 - wooden box               B - aluminum
3 - jerrican                   C - natural wood
4 - box                      D - plywood
5 - bag                      F - reconstituted wood
6 - composite package         G - fiberboard
7 - pressure receptacle         H - plastic
                             L - textile
                             M - multi-wall paper
                             N - metal other than steel or aluminum
                             P - glass, porcelain or stoneware

Under this system, a steel drum with an open head would be designated " 1 Al." A
composite packaging consisting of a plastic bag inside of a steel, non-removable head
drum would be designated "6HA.2" A combination package of plastic bags inside of a
steel, removable head drum would be designated "1A1."

DOT packaging regulations are cumbersome and thus difficult to decipher.
Nevertheless, determining the proper transportation packaging for a hazardous
material can be made easier if several steps are followed.  The first step is to become
familiar with  the general provisions and exemptions of the DOT packaging
regulations. The general provisions, based for the most part on common sense,
include using a package that is capable of containing the hazardous material during
transport. Exemptions generally apply to specific cases, such as waste and small
quantities.

The second step in determining the proper packaging for a hazardous material is to
look up the specific packaging regulation and special provision references in the
DOT Hazardous Materials Table in 49 CFR  172. 101.  The third step is to review the
specific packaging regulations referred to in the HMT (column 8A, 8B, or 8C) and
to determine which authorized package or packaging can be utilized for your
particular situation. The final step is to ensure that no special provisions affect the
packaging selected. References to special provisions are found in column 7 of the
HMT, with codes that apply to specific types of packages and/or modes of
transportation. Checking CFR special provisions for details is not necessary unless a
code is present that can be applied to the particular transportation mode and
container type selected.

Once the proper packaging has been determined, the shipping description must be
prepared, the container must be labeled and marked, and the transport vehicle must
be placarded  in accordance with DOT specifications.  The information used to
determine packaging is also used to determine shipping description, labels and
markings, and placarding.
                                               26

-------
 Federal DOT Regulations
 Subchapter IV: DOT Hazardous Materials Shipping Descriptions, Container
 Labeling and Marking, Vehicle Placarding and Material Segregation
 Requirements

 Packaging Labels:

 A DOT-authorized shipping description must be assigned to every hazardous
 material package prior to transportation.  The shipping description consists of the
 shipping name, hazard class or division, identification number, packaging group,
 and possibly a technical description and/or CERCLA reportable quantity (RQ)
 reference. All authorized shipping names with the associated identification number
 (UN number), hazard class, and packaging group are listed alphabetically in the
 Hazardous Materials Table of 49 CFR 172.101. When the hazardous material is
 a RCRA hazardous waste, the word "waste" must precede the shipping
 description. Shipping names that do not include specific chemical or common
 names will include the "Not Otherwise Specified" (n.o.s.) ending. When the n.o.s
 designation is used, additional technical descriptions are required in parentheses
 between the shipping name and the hazard class or following the basic description.
 The DOT allows the use of RCRA codes as a substitute for technical descriptions in
 the transportation of hazardous wastes. For clarity and emergency response
 purposes, the authors of this manual recommend the use of both technical
 descriptions and RCRA codes when using generic hazardous waste shipping
 descriptions. If a package contains a CERCLA reportable quantity of a hazardous
 substance, the letters "RQ" and the name of the substance to which the RQ pertains
 must be included as part of the  shipping description. CERCLA hazardous
 substances and the associated reportable quantities are listed in the appendix of 49
 CFR 172. 101; reportable quantities of hazardous wastes are reported at the end of
 this appendix and are referenced according to the applicable RCRA waste code.

 The format recommended for shipping descriptions of hazardous waste from
 removal sites is as follows:
 49 CFR
 Department of
 Transportation
 Subpart C Hazardous
 Materials Regulations
 Part 172 Hazardous
 Materials Table,
 Special Provisions,
 Hazardous Materials
 Communications
 Requirements and
 Emergency Response
 Information
 Requirements

 171.203 Additional
 description requirements
RQ, Waste Hazard Classification, NOS (technical description), Hazard Class or
Division, UN number, packaging group, (each RQ reference)

An example of a shipping description for a container of a waste mixture containing
xylene and benzene is as follows:

RQ, Waste Flammable Liquid, n.o.s (Contains Xylene and Benzene), 3, UN1993, II,
(D001)

DOT package labeling, marking and placarding requirements depend on the type of
material and the size of the container. DOT labels identify the primary hazard of the
material and must conform to DOT specifications as listed in 49 CFR 172. All non-
bulk containers must be labeled as specified in column 6 of the HMT. Bulk containers
of less than 1,000 gallons must also be labeled according to the HMT unless placarded
in accordance with 49 CFR 172.

DOT markings are descriptive information that may be required for particular
packages and/or for particular hazardous materials.  DOT regulations require all

                                              27
49 CFR
Department of
Transportation
Subpart C Hazardous
Materials Regulations
Part 172 Hazardous
Materials Table

Subpart E Labeling

-------
Federal DOT Regulations
non-bulk containers of hazardous waste to be marked with the following
information:
•   "Hazardous Waste - Federal law prohibits improper disposal.  If found, contact
    the nearest police or public safety authority or the U.S. Environmental
    Protection Agency."
•   The generator's name and address.
•   The manifest document number.
•   The proper shipping description.

The corresponding EPA regulations in 40 CFR still stipulate that containers of 110
gallons or less be marked according to the above information.
Placarding:

Bulk packages with a capacity of 1,000 gallons or more must be marked with the
hazardous material identification number (UN number) on each side and on each
end. A package with a capacity of less than 1,000 gallons must be marked on two
opposing sides.  Additional information on container-specific marking requirements
can be referenced in 49 CFR as follows:

•   Liquid hazardous materials in non-bulk packages - 49 CFR 172.312
•   Poisonous hazardous materials - 49 CFR 172.313
•   Explosive hazardous materials - 49 CFR 172.320
•   Elevated temperature materials  - 49 CFR 172.325
•   Portable tanks - 49 CFR 172.326
49 CFR
Department of
Transportation
172.400 General
labeling
requirements
SubpartD
Markingl72.301
Applicability

40 CFR 262
Standards Applicable
to Generators of
Hazardous
Waste
Subpart C Pre-
Transport
Requirements
262.32 Marking
49 CFR
Department of
Transportation
SubchapterC
Hazardous
Material Regulations
Part 172 Hazardous
Materials Table
Subpart D Marking
172.302 General
marking requirements
for bulk packaging
Placards provide hazard identification information on a transportation vehicle that
contains hazardous materials.  Placards must conform to DOT specifications as
listed in 49 CFR 172. Use of placards depends on the types and quantities of
hazardous materials in the transport vehicle. Placards are always required for the
following:
•   Any vehicle transporting an explosive (1. 1, 1.2 or 1.3), poisonous by inhalation
    (6.1-Hazard Zone A, B, C or D), dangerous when wet (4.3), or radioactive
    material (7), must always be placarded as such.
•   Any vehicle transporting over 1,000 pounds of any other hazardous material
    must be placarded according to the hazard classification of the material carried.
•   A "dangerous" placard is required on a vehicle containing a combined total of
    over 1,000 pounds of materials from different hazard classes. Specific placards
    are  still required in conjunction with the dangerous placard if over 5,000 pounds
    of a material from one hazard class is loaded on the vehicle, or if any amount of:
    explosive (1. 1, 1.2 or 1.3), poisonous by inhalation (6.1-Hazard Zone A, B, C or
    D), dangerous when wet (4.3), or radioactive material (7) are loaded on the
    vehicle.

Load Segregation Requirements:

DOT requires that certain hazardous materials be  segregated from each other for
storage and transportation. Consult the "Segregation Table for Hazardous Materials"
in 49 CFR 177.848 to determine the proper segregation of hazardous materials. The
                                                28
Subpart F Placarding
172.504 General
placarding requirements
49 CFR
Subchapter C
Part 177 Carriage by
Public Highway
SubpartC
Segregation
and Separation Chart

-------
 Federal DOT Regulations
 Segregation Table is represented here in Table 2-1.
 Subchapter V:  Shipping Papers

 Each shipment of hazardous materials must be accompanied by shipping papers.
 Shipping papers describe the quantity and types of materials to be shipped, the
 addresses of the consignor (shipper) and the consignee (designated receiver), safety
 information and, possibly, additional regulatory information.  A hazardous waste
 manifest (manifest) is required to be used as the shipping paper for hazardous waste
 transportation.

 The following information is always required on a manifest:
 •  Generator's EPA ID Number and unique five-digit document number.
 •  Generator's mailing address (the mailing address may be different from the site
    address).
 •  Generator's phone number.
 •  Name and EPA ID number of the transporter.
 •  Name, address and EPA ID number of the designated receiving facility.
 •  Complete DOT shipping description for each hazardous material for each type
    of container.
 •  Container type, number of containers, and total quantity of each shipping
    description.
 •  Generator's certification.

 DOT regulations also require that emergency response information accompany a
 shipment of hazardous materials.  A 24-hour emergency phone number for a contact
 who is capable of accepting responsibility and providing detailed information is
 required on shipping papers. The following basic information must also accompany
 the shipping papers for each hazardous material shipping description:
 •  Immediate hazards to health.
 •  Risks of fire or explosion.
 •  Immediate precautions to be taken in the event of an accident or incident.
 •  Immediate methods for handling a fire involving the material; Initial methods
    for handling spills or leaks in the absence of fire,
 •  Preliminary first aid measures.

 The appropriate section of the DOT Emergency Response Guidebook  should be
 referenced on a manifest to fulfill the basic emergency response information
 requirements. The preparers of this handbook recommend attaching a copy of the
 ERG  Guidebook page to the shipment paperwork.

 Subchapter VI: Emergency Removal Exemption

The DOT regulations and RCRA provide an emergency exemption for discharges of
hazardous materials during transportation.  A federal, state, or local official may
authorize the removal of waste without the preparation of a manifest if immediate
removal is necessary to prevent further adverse consequences. The transporter in an
emergency transportation removal is not required to have an EPA ID Number.
                                                29
 of Hazardous Waste
 177.848 Segregation
 of hazardous
 materials

 49CFR
 Part 172 Hazardous
 Materials Table,
 Special Provisions,
 Hazardous Materials
 Communications
 Requirements, and
 Emergency Response
 Information
 Requirements
 Subpart C Shipping
 Papers
 49CFR
 172.201 Description
 of hazardous material
 on shipping papers
 172.205 Hazardous
 waste manifest

 40CFR262
 Standard Applicable
 to Generator of
 Hazardous Waste
 Appendix to Part 262
 Uniform Hazardous
 Waste Manifest and
 Instructions
 49CFR
 Subchapter C
 Hazardous
 Materials Regulations
 Part 172
 Subpart G
 Emergency Response
 Information
 172.602 Emergency
 response information
 172.604 Emergency
 response telephone
 number
Part 171 General
Information,
Regulations,
and definitions

171.3 Hazardous waste

-------
Federal DOT Regulations
Subchapter VII:  Summary of DOT Requirements for the Highway
Transportation of Hazardous Materials and Hazardous Wastes

1.   Determine the best shipping name from those listed in the HMT.  Generic
    shipping names may be used as shipping names for waste mixtures and, if so,
    are assigned an NOS ending.

2.   Determine the appropriate authorized packaging for the material and the
    volume being transported.

3.   Complete a shipping label for each container and affix the label to the side of
    the container. Review the HMT for labeling of non-bulk packages and 49
    CFR173.02, Subpart D for placarding requirements for bulk and non-bulk
    packages.

4.   Reference the proper segregation of the materials and determine the appropriate
    placards for packages of materials to be shipped together in a transportation
    vehicle.

5.   Manifest the shipment and include all emergency response information.
                                             30

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 Federal DOT Regulations
                                                      Table 2-1
                                  Segregation Table for Hazardous Materials
                                    49CFR 177.848 (October 1997 Edition)
Class or
Division
1.1 and 1.2
Explosives
1.3
Explosives
1.4
Explosives
1.5 Very
Insensitive
Explosives
1.6
Extremely
•Insensitive
Explosives
2.1
Flammable
Gases
2.2 Non-
flammable
Gases
2 3 Zone A
Poisonous
Gases
2.3 Zone B
Poisonous
Gases
3Flammable
Liquids
4.1
Flammable
Solids
4.2 Spontan-
eously
Combustible
43
Dangerous
When Wet
5.1
Oxidizers
5.2 Organic
Peroxides
6.1 Zone A
Poisonous
Liquids
7
Radioactive
8 Corrosive
Liquids
1.1
1.2

*
*
*
*
X
X
X
X
X
X
X
X
X
X
X
X
X
1.3

*
*
*
*
X

X
X
X

X
X
X
X
X

X
1.4

*
*
*
*
o

o
o
o

o



o

o
1.5

*
*
*
*
X
X
X
X
X
X
X
X
X
X
X
X
X
1.6

*
*
*
*













2.1
X
X
O
X



X
o






o
o

2.2
X


X














23
Zone A
X
X
O
X

X



X
X
X
X
X
X


X
23
ZoneB
X
X
o
X

o



0
o
o
0
o
o


o
3
X
X
o
X



X
o




o

X


4.1
X


X



X
o






X

o
4.2
X
X
o
X



X
o






X

X
43
X
X

X



X
0






X

o
S.1
X
X

X



X
o
o





X

o
5.2
X
X

X



X
o






X

o
6.1
liquid PGI
Zone A
X
X
O
X

O



X
X
X
• X
X
X


X
7
X


X

o












8
liquid
only
X
X
O
X



X
O

o
X
o
o
o
X


"X" - These materials may not be loaded, transported or stored together in the same transport vehicle or storage facility during the course of
transport.
"O" - These materials may not be loaded, transported or stored together in the same transport vehicle or storage facility during the course of
transport, unless separated in a manner that in the event of leakage from packages under conditions normally incident to transportation,
commingling of hazardous materials would not occur.
"*" - Indicates that segregation among Class 1 (explosive) materials is governed by the compatibility of those materials as outlined in
49CFR177.848, para. f.
                                                         31

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Federal DOT Regulations
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                                  32

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                                        CHAPTER 3
                CONVENTIONAL HAZARDOUS WASTE TREATMENT
                               AND DISPOSAL METHODS
Subchapter 1:  Introduction to Conventional Hazardous Waste Treatment and Disposal Methods

Regulations under RCRA detail requirements for hazardous waste classification, handling, and record-
keeping. RCRA further specifies treatment standards or land disposal restrictions for all hazardous
wastes. Land disposal restrictions dictate the extent of treatment or destruction of a waste prior to
landfilling. Several commercial treatment options that meet the regulatory treatment standards may be
available for a specific wastestream. Understanding conventional waste treatment processes allows the
generator to select the most environmentally beneficial and cost effective means of disposal for a
particular wastestream.  This chapter briefly describes the processes of typical commercial, RCRA-
permitted, waste treatment options. In particular, the capabilities of resource recovery, incineration,
wastewater treatment, and stabilization options are summarized. The selection of disposal options based
on waste characterizations and the method for characterizing wastes and wastestreams are outlined in
Chapter 6.

Subchapter II: Recycling and Recovery

RCRA has authorized a number of waste treatment methods that promote resource recovery from several
types of wastes. Recovery methods are available for concentrated solvent or metal wastes. Solvent
recovery involves the distillation of a waste mixture to separate and purify the components. The distilled
solvents can then be reused in many commercial manufacturing processes. Solvent F001, F002, F003,
and F005 wastes without sulfide or cyanide contamination and with limited inorganic contamination are
often recyclable.

Fuels blending is a means of promoting resource recovery from hazardous wastes.  In 1991, RCRA
promulgated the Boiler and Industrial Furnace (BIF) rule to promote blending of many organic
wastestreams with fuel.  In the past, cement kilns were authorized to utilize pumpable organic liquid
wastes with a fuel value of greater than 5,000 BTU/pound as a fuel supplement in the cement process.
The new BIF rule will allow many cement kilns to explore the use of low fuel value organic liquid
wastes as well as solids and sludges (ITTze Hazardous Waste Consultant, March/April 1992).

The process of using organic wastes as fuel substitutes in cement kilns thermally destroys the organic
constituents of the waste. Ash recpvered from the burning of fuels and fuel substitutes is also used in
cement production, rendering immobile the inorganic contaminants from fuels blended wastes.

The fuels blending process is currently less expensive than commercial treatment, storage and disposal
(TSD) incineration processes due to the limited types of wastestreams acceptable and the permitting and
waste processing requirements associated with fuels blending.  Thus, fuels blending by cement kilns
should be explored prior to conventional waste treatment technologies at commercial TSDs for the
disposal of organic liquid wastestreams.

Recycling of chlorinated fluorocarbons (CFCs) may present the generator with a highly cost effective
disposal alternative. Disposal facilities establish strict guidelines for acceptance of CFCs for recycling.
These guidelines include reclaim value of the CFC, product contamination, and re-sale value of the

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Waste Treatment and Disposal Methods
reclaimed product. However, the disposal facility may actually provide the generator with a refund for
the sometimes valuable reclaimed CFC solvent.

Metal recovery from a wastestream may involve chemical reactions and/or thermal treatment to remove
and recover valuable metals from waste mixtures. Metals can be recovered from liquids, solids, sludges,
acids and alkalies. Typical criteria for metals recovery from inorganic solid (non-liquid) wastes follow
in Table 3-1:

                                          Table 3-1
                            Approximate Waste Feed Specifications

                     Nickel                              >       1.3  %
                     Chromium                          >       5.0 %
                     Phosphorus                         <      0.05%
                     Iron                                       no limit
                     Sodium, chloride, potassium          <      20.0  %
                     Copper                             <       2.0  %
                     Tin                                <      0.03  %
                     Cadmium   .                        <      20.0  %
                     Sulfur                              <       5.0  %
                     Lead                               <      10.0  %
                     Zinc                                <      15.0  %
                     Alumina                            <      15.0  %
                     Silica                               <       2.0  %
                     Cobalt                              <      10.0  %
                     Molybdenum                        <      10.0  %

Reference:     Approximate Waste Feed Specifications INMETCO, Ellwood City, PA

Subchapter III:  Incineration

In 1988, regulations under RCRA restricted land disposal of liquid, solvent, dioxin and 157 high hazard,
high volume wastes. The 1988 restrictions were referred to as the "soft hammer" and required waste
treatment by a method that provided the greatest environmental benefit if a concentration-based
treatment standard had not been established for the particular waste. As a result, thermal destruction of
hazardous wastes through RCRA-permitted incinerators became a popular means of compliance with the
soft hammer.  Today, land disposal restrictions require each type of waste to be treated to achieve
concentrations below a specified level or to be treated by a specific treatment technology prior to
landfilling.  Incineration is one method of treatment listed under RCRA land disposal restrictions for a
variety of wastes.  Incineration is also a common method of treatment to achieve the concentration-based
standards.

A RCRA-permitted incinerator is an enclosed device that uses flame combustion  at temperatures of 1200
to 1500°C and that is not a boiler or furnace. Flame  combustion is the thermal destruction of wastes by
oxidation, which reduces the volume of the waste and creates less harmful chemical components.
Carbon dioxide and water are the end products of the combustion of organic materials. Oxides are the
end products of the combustion of inorganic materials.
                                             34

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 Waste Treatment and Disposal Methods
 In general, the incineration process is required to achieve a Destruction Removal Efficiency (DRE) of at
 least 99.99 percent of Principal Organic Hazardous Constituents (POHC) of a waste.  Some specific
 POHCs, such as dioxins, require a DRE of greater than 99.9999 percent.  Rotary kilns are the most
 widely used incinerators because of their versatility in accepting variations in wastestreams. A rotary
 kiln consists of a refractory-lined cylindrical reactor lying on its side. One end of the kiln is elevated and
 is designed to accept the waste feed. The waste can be solid, liquid or sludge. The kiln rotates around its
 horizontal axis to move the waste from the elevated end to the lower end.  The speed of rotation can be
 manipulated to ensure the desired combustion of the waste feed.

 Combustion products (carbon dioxide, elemental oxides, particulates, and acid gases from combustion of
 sulfur and halogenated compounds) flow from the kiln to an afterburner chamber, which operates at a
 lower temperature than the rotary kiln. Low BTU wastes, such as contaminated water, are often
 introduced into the afterburner chamber. Water is vaporized while organic contaminants are thermally
 destroyed in this part of the process. Cooling combustion products then flow from the afterburner to a
 quench and scrub unit.  Water is sprayed into the quench and scrub unit with the combustion products.
 This aspect of the waste incineration process serves to cool combustion gases and then to scrub or
 remove particulates and acid gases. Scrub water is reused after neutralization and precipitation
 treatments. Precipitated particles from scrub water as well as any kiln ash are tested to assure
 compliance with LDRs and are usually further treated with chemical bonding or stabilization techniques
 prior to landfill.

 Wastestreams that contain more than 10 percent organic constituents are usually treated with thermal
 destruction techniques. Incineration is the most likely treatment technique for any organic solid or
 sludge wastestream. Important factors to consider for wastes to be incinerated are fuel value (BTU) and
 ash, halogen and sulfur content.

 The ash content of a waste dictates the reduction in volume the waste will undergo when it is incinerated.
 Since the ash from incineration is usually treated and is always disposed of at a RCRA hazardous waste
 landfill, ash content is directly related to price of disposal. Most flammable liquids and organic
polymers have a high BTU value (10,000 to  20,000 BTUs per pound) and a low ash value (less than one
percent ash).  Thus, flammable liquid and polymer wastes are generally the least expensive to incinerate.
Halogenated solvents and organic solids are  usually moderately priced with fuel values of 3,000 to
 10,000 BTUs per pound and ash content of less than ten percent. Aqueous liquids have a low to negative
fuel value and usually an ash content of less  than 25 percent.  Inorganic solids may have a positive fuel
value but normally have a high ash value. Thus, other forms of disposal should be considered for
aqueous and inorganic solid wastestreams for both cost and environmental effectiveness.

The use of wastes as fuels is the most cost effective means of disposal of organic liquids. Whereas
boilers and furnaces are generally restricted to high energy (greater than 5,000 BTUs per pound) and
limited halogen content wastes for use as fuel substitutes, RCRA-permitted incinerators blend both high
and low fuel value organic liquids, even with halogens, to achieve the desirable fuel value for kiln
operations. Thus, for a site with low and high fuel value organic wastes and/or halogenated organic
waste, incineration of all organic wastestreams may be more cost effective than fuels blending of high
BTU wastes at a cement kiln and incineration of low BTU and halogenated wastes at an incinerator
facility.

Subchapter IV:  Conventional Wastewater Treatment Technologies

RCRA-permitted commercial wastewater treatment facilities are capable of treating a variety of aqueous
wastes as well as water-soluble solids and sludges. The facilities utilize biological, chemical and/or

                                              35

-------
Waste Treatment and Disposal Methods
physical techniques throughout the wastewater treatment system to reduce the hazardous properties
and/or constituents of a wastestream. A facility's ability to treat a wastestream using one or more
techniques in the process allows multi-contaminant wastestreams to be treated environmentally safely
and cost effectively.

     Aqueous wastes with organic contaminants are usually treated by biological processes or carbon
absorption, or a combination of the two, within the commercial wastewater treatment facility. Biological
treatments, which include aerobic and anaerobic systems, utilize the metabolism of microorganisms to
degrade organic  chemicals into less harmful compounds or into a cellular mass.  The organic constituents
of a waste in effect become food for a population of microorganisms.

Aerobic biological processes require oxygen as well as a carbon source for the microorganisms to thrive.
Some aerobic systems contain organisms in a liquid suspension, or activated sludge.  The sludge  is
supplied with oxygen by agitation and sparging.  When hazardous waste is introduced into the sludge,
the organisms consume the organic contaminants and build cellular mass. The enlarged biological cells
are removed when the degradation of the organic contaminants in the waste has been completed.
Aerobic treatment techniques effectively process wastewaters with less than one percent organic
contamination.

Anaerobic processes occur in the absence of oxygen. Anaerobic microorganisms, catalyzed by enzymes,
break down organic contaminants into cellular mass and gaseous products. These organisms can tolerate
higher levels of organic contaminants than can aerobic organisms. A disadvantage of the process is that
anaerobic systems lack flexibility in responding to a change in organic concentrations in the waste feed.

The physical process of carbon adsorption is also effective in the removal of organic contaminants from
wastewater. Activated carbon has a greater affinity than water for organic contaminants. Thus, organic
wastes are removed from an aqueous matrix and are adsorbed or fixed onto the carbon surfaces in this
process. When the carbon has become saturated with organic contaminants, it must be regenerated.
Thermal regeneration of carbon reactivates the carbon surface while destroying the organic constituents.
Both carbon adsorption and biological processes are often utilized in commercial wastewater treatment
systems to process aqueous wastes with generally up to 10 percent organic constituents.

Inorganic contamination in wastewater as well as water soluble inorganic hazardous wastes can be
processed in commercial wastewater facilities through a variety of physical and chemical treatments.
Precipitation involves changing the solubility of an aqueous inorganic contaminant, causing it to become
solid and fall out of solution.  One method of precipitation is achieved by introducing a chemical  into the
wastewater that causes a reaction with the water soluble inorganic compound.  The chemical reaction
creates a new, water insoluble component that precipitates. Another method of precipitation involves the
manipulation of the original solvent (water) to create a new matrix in which the contaminant is less
soluble. The precipitated solids are stabilized with solidification techniques prior to landfill.
Precipitation reactions are used frequently to treat wastewaters that contain regulated levels of metals in
the form of salts.

Neutralization is the removal of the RCRA characteristic of corrosivity by the addition of an acid or base
to an aqueous waste material of the opposite pH.  The result of the typically exothermic reaction is an
aqueous solution containing a salt.  If the resulting salt contains regulated metals, precipitation can then
be utilized in the treatment process.

Oxidation/reduction (redox) reactions are used in wastewater treatment processes to destroy the
oxidizing properties of a waste and to reduce the toxicity of metal, sulfide or cyanide compounds.

                                               36

-------
 Waste Treatment and Disposal Methods
 Phenols, pesticides, and sulfur-containing organic compounds can also be treated with redox reactions.
 This process involves the addition of a chemical capable of oxidizing (removing an electron) or reducing
 (adding an electron) to the contaminant of concern. The redox reaction may render the contaminant less
 toxic or may cause it to precipitate out of the aqueous solution.

 Regardless of the particular processes or combination of processes used in the wastewater treatment
 system, the resultant "cleaned" water must be tested to ensure the effectiveness of the treatment and
 compliance with RCRA treatment standards. The discharge of the "cleaned" water is also regulated
 under the National Pollutant Discharge Elimination System (NPDES).

 Chapter 6 of this manual outlines the appropriateness of wastewater treatment for field characterized
 wastes. In addition, RCRA-permitted wastewater treatment facilities should be considered for
 wastewater from the decontamination of site personnel and equipment, drum rinsate, and leachate
 collection, corrosive wastes from electroplating facilities, and aqueous wood treating solutions.

 Subchapter V: Deactivation/Stabilization Waste Treatment Technologies

 Deactivation is the elimination of the RCRA characteristic that causes  a waste to be classified as
 hazardous. Technologies for aqueous wastes can also be applied to inorganic solid and sludge
 wastestreams without the introduction of water as a solvent. The addition of other chemical components
 to a wastestream that result in neutralization or redox reactions destroys corrosivity and oxidizer
 characteristics, respectively.  Redox reactions can also be used to reduce the toxicity of many metal,
 sulfide, and cyanide compounds.  The treated waste must be tested to assure compliance with LDRs prior
 to landfill.

 In addition to these chemical reactions, solidification and encapsulation (S&E) techniques are used to
 eliminate free liquids and encapsulate hazardous contaminants of inorganic solid and sludge
 wastestreams.  S&E processes do not destroy the hazardous constituents in the waste, instead, they
 stabilize the hazardous constituents to prevent mobility when landfilled. S&E is achieved through the
 addition of cement, lime, thermoplastic materials or organic polymers to the wastestream. The S&E
process substantially increases the volume of waste to be landfilled. Thus, alternate treatment and
recovery methods should be considered prior to deactivation/stabilization disposal methods.

Subchapter VI:  Contaminated Soils

Hazardous soils are subject to LDRs when the soils are generated and removed to a land disposal unit,
and either "contain" a characteristic of a hazardous waste (D001-D040 waste codes) and/or "contain"
listed hazardous wastes.  Soils contaminated with a listed waste material, requiring a specified treatment
technology, must be disposed of in accordance with the specified technology. Two options exist for the
disposal of contaminated soils, which are not limited to a specified disposal technology:

 1)  The generator may apply the universal treatment standards (UTS),  (40 CFR268.40 and .41) to the
    soil and dispose of the soil accordingly.
2)  On 26 May 1998, the USEPA published the Phase IV Land Disposal Restrictions Supplemental Final
    Rule. This ruling includes two regulations which may affect disposal operations at Superfund sites:
       a)  The EPA established new UTS for metal bearing wastes for both wastewaters and non-
           wastewaters, these treatment standards for a given metal may vary between wastewaters and
           non-wastewaters. This ruling went into effect on 24 August 1998 in those states which are
           not authorized to enforce their own LDRs.


                                              37

-------
Waste Treatment and Disposal Methods
       b)  The EPA established alternative treatment standards for contaminated soil disposal. This
           ruling is summarized by the phrase "90% capped by 10 X UTS".  This rule establishes
           alternative soil treatment standards. Soils contaminated with hazardous constituents, that are
           subject to treatment standards, must be treated to reduce the contamination level by 90%, for
           all constituents.  The treatment levels are capped by 10 times the UTS. Contaminated soils
           subject to the LDRs must also be treated to meet the soil treatment standards for all
           reasonably expected Underlying Hazardous Constituents (UHCs). UHCs initially present at
           a level less than  10 times the applicable UTS, do not require further treatment. The rulings
           regarding contaminated soils went into effect on 26 May 1998 in those states which are not
           authorized to enforce their own LDRs.

Two examples of application of the alternative treatment standards for contaminated soils:

       A soil is characteristically hazardous for lead at 10 mg/L TCLP (UTS of 0.75 mg/1 TCLP), the
       new soil treatment standard would require treatment to 1 mg/L (90% the contaminant level).
       However,  applying the cap of 10 times the UTS, a treatment standard of 7.5 mg/L is required.
       This is greater than the 90% standard of 1 mg/L. Therefore, the soil would only require treatment
       to 7.5 mg/L, or a 25% contamination reduction. Note, after treatment, the soil may still be
       characteristically hazardous for lead (D008, 5.0 mg/L TCLP) and will require disposal at a
       Subtitle C Landfill. However, if the lead concentration can be lowered to less than 5.0 mg/L
       TCLP, the soil has been de-characterized and can go to a Subtitle D Landfill.

       A soil is characteristically hazardous for chromium at 5.5 mg/L TCLP (UTS of 0.6 mg/L TCLP).
       Analytical testing detected the following underlying hazardous constituent is present at a
       detectable level: toluene at 90 mg/kg (UTS of 10 mg/kg). Since the toluene is present at less than
       100 mg/kg (10 X UTS), it already meets the alternative treatment standard. The chromium
       should be  treated to 0.55 mg/L TCLP (90% reduction) or to less than 6.0 mg/L TCLP (10 X
       UTS).  The soil can go for land disposal without further treatment. However, it is still a
       characteristically hazardous waste for chromium (D007, 5.0 mg/L TCLP) and will require
       disposal at a Subtitle C landfill.

References:

      1.   Standard Handbook of Hazardous Waste Treatment and Disposal. Harry M. Freeman, Editor
          in Chief, McGraw-Hill Book Co. New York. 1989.
      2.  Commercial literature from TSDs.
                                             38

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Waste Treatment and Disposal Methods
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                                 39

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                                       CHAPTER 4
                      DISPOSAL FACILITY WASTE EVALUATION
                           AND ACCEPTANCE PROCEDURES
Subchapter I: The Waste Profile

A wastestream comprises all site wastes that have the same physical, chemical and hazard
characteristics, the same RCRA-regulated hazardous constituents and waste codes, and that will be
treated using the same disposal technology. Prior to approving the wastestream for disposal, commercial
treatment, storage and disposal (TSD) facilities require each wastestream to be profiled, that is, to be
fully characterized. The profile information is completed on the particular TSD's profile form. Profile
forms may also be known as waste characterization forms, or waste safety data forms. The following
information is usually required on a profile for all wastestreams:
•   Generator's name, address, phone number and EPA ID number.
•   General description of the waste and the process from which it was derived.
•   Physical state of the waste (solid, sludge, liquid) with percent liquid and percent solid.
•   The composition of the waste totaling 100 percent (this includes hazardous and non-regulated
    constituents).
•   The shipment method, quantity and frequency anticipated (one 5,000 gallon tank truck, one time).
•   All applicable RCRA waste codes.
•   Hazardous characteristics of the waste (flammable, oxidizer, corrosive).
•   Chemical data such as pH, estimated total organic carbon content, and estimated total halogenated
    organic compounds.

                                         Table 4-1
                              Treatment-Specific Information
                              (usually required on waste profiles)
Parameter
BTU
Flash Point
Boiling Point
RCRA
metals
pesticides & herbicides
volatile organics
semi-volatiles
cyanide
sulfide
Thermal
yes
yes
yes

totals
totals
totals
total
total

Wastewater
no
>140°F
no

totals
totals
totals
total
total

Deact/Stab/LF
no
>140°F
no

TCLP
TCLP
TCLP
reactive
reactive

Specialty hazards of a waste must also be noted on a profile. Chapter 8 of this manual addresses
specialty wastes such as explosives, radioactives, PCBs, dioxins and labpacks.

Conventional disposal processes and RCRA. regulations were developed on the assumption that the
generator possesses knowledge of the waste. Most chemical users and manufacturers typically generate
large quantities of any one wastestream and have knowledge of the presence or absence of RCRA

-------
 Disposal Facility Waste Evaluation and Acceptance Procedures
 regulated constituents.  Thus, the commercial generator may complete a profile based on "generator's
 knowledge" of the waste.

 Unfortunately, the generator's (OSC's) knowledge of wastes at Superfund removal sites is limited.  The
 OSC must rely heavily on analysis to profile each waste.  Many variables exist in laboratory analytical
 data due to the heterogeneous nature of wastes, choices made in compositing samples, and
 inconsistencies in sample collecting and handling techniques. Chapters 5 and 6 of this manual discuss
 waste sampling and analysis options for a variety of waste streams to maintain financial feasibility and
 reduce data variability.

 Regardless of the manner in which profile information is  obtained, regulated and non-regulated
 constituent values as well as chemical and physical properties should be reported as reasonable ranges.
 Most TSDs have set ranges for significant parameters that will affect the treatability and/or the cost of
 the treatment. Thus, analysis variability may cause a wastestream to be redefined.  To avoid unexpected
 costs and possible rejection of a wastestream from a TSD, the OSC should profile site wastestreams
 based on the worst-case scenario possible using the data available.

 Subchapter II: The Disposal Facility's Process and Considerations

 In addition to a waste profile form, which provides a detailed description of the waste stream, a
 representative sample of the wastestream must be submitted to the proposed disposal facility. The TSD
 analyzes the sample and compares the results to the profile form.  If the analysis and profile information
 are congruent, the TSD assigns an approval number to the profile and accepts the waste for treatment.
 This facility review process is normally associated with a profile approval fee of $100 to $300.

 Once the TSD has approved the wastestream, the disposal price can be confirmed and a schedule for
 shipment can be arranged. The approval number (profile  number) must be noted for each line of a
 manifest, and marked on each container of non-bulk waste (containers of less than 119 gallons).

 All waste shipped to a facility under a profile number is sampled and analyzed upon arrival at the
 designated facility.  If the waste matches the profile data within the acceptable ranges, a representative of
 the facility will sign the receipt section of the manifest and mail copies to the generator and to applicable
 states.  The signed, returned copy of the manifest is the "certification of receipt" required by RCRA.

 A word of caution, the CERCLA off-site disposal policy [SARA 121 (d) (3)] requires  RCRA compliance
 for off-site disposal of CERCLA hazardous substances during a CERCLA-funded response action.
 Facilities should be informed that the waste to be treated was derived from a CERCLA-funded response
action and that compliance with the CERCLA off-site policy must be maintained. Many facilities have a
line on their profile dedicated to this issue (i.e., "Is this waste generated from a CERCLA Superfund
Removal Action?"). If the profile does not address this question, the authorized agent at a CERCLA site
should note the waste as the result of a Superfund activity  and state the site name in the remarks section
of the profile. The certification of disposal should be requested from the facility at the time of the
contract agreement for documentation of CERCLA compliance. TSDs often accept and then broker
wastes to alternate facilities.  If a certification of disposal  and compliance with the CERCLA off-site
disposal policy are not stipulated in the disposal contract,  the waste could be subcontracted to a facility
that is not currently in compliance or that does not provide the treatment method specified by the OSC.
Some CERCLA wastes are not RCRA regulated; thus, a TSD could dispose of a non-RCRA regulated
waste stream at another facility that is not RCRA permitted, unless RCRA compliance is specified.
If waste received at a facility does not match the profile information, the waste is referred to as off-
specification (off-spec). Several options are generally considered for off-specification wastes. The TSD

                                              41

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Disposal Facility Waste Evaluation and Acceptance Procedures
may determine that the off-spec waste can still be treated at its facility; if so, treatment of off-spec waste
is accompanied by a second profile fee and/or waste handling surcharges. Transportation and storage
charges accrued to investigate an alternate facility are usually higher than the additional charges
requested by the originally designated facility to process the waste. If the designated facility is not
permitted for, or is not capable of, treating the off-specification waste, the waste will be rejected for
treatment by the facility.  The wastes should be returned to the generation location while alternate
disposal options are explored and coordinated

Subchapter HI:  Summary of Commercial Disposal Waste Stream Evaluation and Considerations

1.   Sampling and analysis variables must be considered for waste profile information.  See Chapter 5
     for further detail.

2.   Treatment technology for a waste stream should be determined prior to contracting with a TSD.

3.   Waste profile forms  should £e completed with the  "worst case scenario" in mind to account for
     analysis variability and to ensure acceptance by the designated facility.

4.   Proper waste profile information is essential to ensure proper disposal.

5.   Compliance with the CERCLA off-site disposal policy and provision of certifications of disposal
     should be stipulated  in the contract with the TSD.
                                               42

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                                        CHAPTER 5
                         INTRODUCTION TO SAMPLING AND
                             ANALYSIS METHODOLOGIES
Subchapter I: Environmental Assessment Methodologies Versus Waste
Characterization Needs

CERCLA hazardous substances include any substance which has been determined to
be hazardous under the Clean Ah- Act (CAA), Clean Water Act (CWA), RCRA,
TSCA, or CERCLA. CERCLA pollutants and contaminants are defined as any
substance that when released into the environment is determined to present an
imminent and substantial danger to the public health or welfare.

Analysis parameters are the substances and physical characteristics to be tested for in a
laboratory.  Analysis parameters and associated laboratory test methods for each
environmental regulation are published in 40 CFR.  The parameters of concern and the
corresponding test methods established for particular substances are typically
organized according to the matrix regulated by a specific environmental act.
Parameters of concern under the CAA (air emissions) and the associated analysis test
methods are listed in 40 CFR 60; parameters of concern under the CWA (effluent
discharges into surface waters) and the associated approved test methods are listed in
40 CFR 136; parameters of concern under the Public Health Service Act as amended
by the Safe Drinking Water Act (ground water) with the associated action levels and
Maximum Contaminant Levels (MCLS) are listed in 40 CFR 141. Parameters of
concern under RCRA as amended by the Hazardous and Solid Waste Amendments
(HSWA) are listed in 40 CFR 261 (hazardous waste constituents in containers and
soil).

Sample collection and handling procedures are unique to the matrix of the sample
and the contaminants of concern. Several EPA publications are available for
guidance as to proper sampling and sample handling techniques. The publication
Solid  Waste 846 (SW-846), "Test Methods for Evaluating Solid Waste" was
developed under HSWA to provide uniform sampling, sample handling and analysis
methods to  determine if a waste contains hazardous constituents in a concentration
that would make the waste subject to hazardous waste regulations. The EPA-600
publication was developed under the CWA to provide uniform sampling, sample
handling and analysis methods  for determining if wastewater can be discharged
under the National Pollutant Discharge Elimination System (NPDES) permitting
process. The EPA Office of Solid Waste and Emergency Response (OSWER) has
published standard sampling procedures established by the EPA Environmental
Response Team (ERT) for a variety of environmental sampling  efforts as follows:
OSWER DIRECTIVE
9360.4-02 1/91

9360.4-03 1/91
Compendium of ERT Soil Sampling and Surface Geophysics
Procedures
Compendium of ERT Surface Water and Sediment Sampling
Procedures
                                                            40 CFR 60
                                                            Standards of
                                                            Performance for
                                                            New Stationary
                                                            Sources

                                                            40 CFR 136
                                                            Guidelines
                                                            Establishing
                                                            Test Procedures
                                                            for the Analysis
                                                            of Pollutants

                                                            40 CFR 141
                                                            National
                                                            Primary
                                                            Drinking Water
                                                            Regulations

                                                            40 CFR 261
                                                            Identification and
                                                            Listing of
                                                            Hazardous Waste

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Introduction to Sampling and Analysis Methodologies
9360.4-05 5/92      Compendium of ERT Air Sampling Procedures
9360.4-06 1/91      Compendium of ERT Groundwater Sampling Procedures
9360.4-07 1/91      Compendium of ERT Waste Sampling Procedures

These EPA guidance publications were not established as regulation.  Rather, the
publications establish tangible sample handling procedures that provide a legal basis
for verification of analytical results obtained from the sampling effort.

In addition to producing sample and analysis guidance publications to ensure
uniformity, EPA has established the Contract Laboratory Program (CLP) to
assist with consistency and verification of laboratory results. EPA-contracted
labs must comply with statements of work and approved sample handling and
analysis procedures to participate in the program.  CLP statements of work
and laboratory procedures are consistent with SW-846 and EPA-600
publications.

Most removal assessments involve sampling and analysis for hazardous substances
that have established, verifiable sample collection and handling procedures and
analysis methodologies. The commonly used assessment parameters are priority
pollutants (PP), CLP target analyte list (TAL) and/or CLP target compound list
(TCL) compounds. These assessment parameter lists can be subdivided according to
chemical properties as follows:
Priority Pollutants
Volatile organics
Semi-volatile organics (or base,
neutral &acid extractables)
Pesticides & PCBs
Metals
Cyanides
Target Analyte List



Metals
Cyanides
Target Compound List
Volatile organics
Semi-volatile organics (or base,
neutral & acid extractables)
Pesticides & PCBs


The compounds in each list and the associated environmental regulations governing
the compound can be found in Table 5-1.

The normal CLP data obtained from a removal assessment provides the OSC
information with which to evaluate the site threat. In disposal terms, assessment
data provides generator knowledge of the waste. However, the normal CLP data
does not supply the OSC with sufficient information to determine the proper
technique to mitigate the threat or to arrange proper treatment or disposal of the
evaluated site hazardous substances.

Subchapter II: Factors to Consider in Determining the Information Needed to
Characterize a Wastestream

As described in Chapter I of this manual, hazardous waste is a sub-classification of
solid waste.  A generator of any type of waste is required under RCRA regulations to
determine if a generated waste is hazardous. A waste can be defined as hazardous
based on the conditions under which it was derived, based on its hazardous
characteristics, or based on the concentrations of regulated hazardous constituents in
the waste.
                                             44

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Introduction to Sampling and Analysis Methodologies
During an assessment, an OSC must consider the threat caused by any hazardous
substance on a site.  The OSC must also consider the means of mitigating the threat
and complying with regulations. Not all CERCLA hazardous substances are
regulated under RCRA as hazardous waste; however, the CERCLA off-site disposal
policy requires that the disposal of all hazardous substances at CERCLA responses
be consistent with RCRA regulations regarding hazardous waste disposal. Thus, it is
important that an OSC acquire knowledge of all site wastes with regard to disposal
regulations.

The extent of analysis needed to define substances for waste disposal depends upon
the OSC's knowledge of the waste, the chemical and physical characteristics of the
waste, the treatment technologies to be explored for disposal of the waste, and the
facility where the waste will be treated.  It-is not possible to know which facility will
treat the waste until the removal action has begun. However, qualitative information
about the characteristics of a substance can be easily obtained, and waste treatment
technology options can be explored based on the physical and chemical
characteristics of a waste. Waste analysis parameters can then be selected based
upon the generator's knowledge of the waste, general characteristics of the waste,
and available treatment options for the waste to complete regulatory classification
requirements. Chapter 6 of this manual addresses waste characterization and
analysis options for typical unknown drum wastes found at Superfund removal sites.
The Appendix provides an example of the evaluation of unknown drum wastes and
the requirements of the disposal process. Chapter 7 addresses typical bulk wastes,
such as tanks and vats from manufacturing and process facilities, soil contamination
and hazardous debris. Chapter 8 addresses specialty wastes.
                                              45

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Introduction to Sampling and Analysis Methodologies
                                              Table 5-1
                                    Contract Laboratory Program
                                Hazardous Substances Reference List

                                     Base/Neutral and Acid Compounds
Hazardous Substance
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
2-Methylphenol
bis(2-Chloroisopropyl)ether
4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2,6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dmitrotoluene
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
4,6-Dmitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Carbazole
Di-n-butylphthalate
Fluoranthene
Pyrene
Statutory Source for
Designation as Hazardous
Substance under CERCLA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
RCRA/TSCA/CWA
CWA/RCRA
RCRA/TSCA/CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA/RCRA
RCRA
CWA/RCRA
CWA/RCRA

CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
TSCA
CWA/RCRA
CWA
CWA/RCRA
TSCA
CWA
CWA/RCRA
CWA/RCRA
CAA
CWA/RCRA
CWA/RCRA
CWA
CWA
RCRA
CWA/RCRA
CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA
TSCA
CWA/RCRA
CWA/RCRA
CWA
                                                   46

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Introduction to Sampling and Analysis Methodologies
                                 Base/Neutral and Acid Compounds (cont'd.)

                                                                Statutory Source for
                                                                Designation as Hazardous
Hazardous Substance                                             Substance under CERCLA
Butylbenzylphthalate                                               CWA
3,3-Dichlorobenzidine                                              CWA/RCRA
Benzo(a)anthracene                                                CWA/RCRA
Chrysene                                                        CWA/RCRA
bis(2-ethylhexyl)phthalate                                           CWA/RCRA
Di-n-octylphthalate                                                CWA/RCRA
Benzo(b)fluoranthene                                               CWA
Benzo(k)fluoranthene                                               CWA
Benzo(a)pyrene                                                   CWA/RCRA
Indeno(l,2,3-cd)pyrene                                             CWA/RCRA
Dibenz(a,h)anthracene                                              CWA/RCRA
Benzo(g,h,i)pyrene                                                CWA
                                                  47

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Introduction to Sampling and Analysis Methodologies
                                      Volatile Organic Compounds
Hazardous Substance
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon Disulfide
1,1-Dichloroethene
1,1-Dichloroethane
Total 1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
2-Butanone
1,1,1 -Trichloroethane
Carbon Tetrachloride
Vinyl Acetate
Bromodichloromethane
1,2-Dichloropropane
Cis-1,3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1,2-Trichloroethane
Benzene
Trans-1,3-Dichloropropene
Bromoform
4-Methyl-2-pentanone
2-Hexanone
Tetrachloroethene
1,1,2,2-Tetrachloroethane
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Total Xylenes
Statutory Source for
Designation as Hazardous
Substance  under CERCLA
CWA/RCRA
CWA/RCRA
CWA/CAA/RCRA
CWA
CWA/RCRA
RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
RCRA
CWA/RCRA
CWA/RCRA
CWA
TSCA
CWA/RCRA
CWA/RCRA
CWA/RCRA
TSCA
CWA/RCRA
CWA/CAA/RCRA
CWA/RCRA
CWA/RCRA
RCRA
TSCA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA
CWA/RCRA
                                                  48

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Introduction to Sampling and Analysis Methodologies
                                         Pesticides and PCBs
Hazardous Substance
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Aldrin
Heptachlor Epoxide
Endosulfan I
Dieldrin
4,4-DDE
Endrin
Endosulfan II
4,4-DDD
Endosulfan Sulfate
4,4-DDT
Methoxychlor
Endrin Ketone
Endrin Aldehyde
alpha-Chlordane
gamma-Chlordane
Toxaphene
Aroclor-101 6
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
Statutory Source for
Designation as Hazardous
Substance  under CERCLA
CWA
CWA
CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA/RCRA
CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA
CWA/RCRA
CWA/RCRA
CWA/RCRA
CWA/TSCA
CWA/TSCA
CWAATSCA
CWAyTSCA
CWA/TSCA
CWA/TSCA
CWA/TSCA
                                                49

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Introduction to Sampling and Analysis Methodologies
                                          Inorganic Metals
Hazardous Substance
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Statutory Source for
Designation as Hazardous
Substance under CERCLA
SOW
CWA
CWA/CAA/RCRA
RCRA
CWA
CWA/RCRA

CWA/RCRA

CWA
SOW
CWA/RCRA

SOW
CWA/RCRA
CWA

CWA/RCRA
CWA/RCRA
CWA
CWA

CWA
                                                50

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Introduction to Sampling and Analysis Methodologies
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                                   51

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                                         CHAPTER 6
                               UNKNOWN DRUM WASTES:
                          CHARACTERIZATION FOR DISPOSAL
Subchapter I: Introduction to Waste Characterization Needs

This chapter is dedicated to the techniques and general criteria needed to evaluate the unknown drum
wastes (for example, those often found from "midnight dumping") for treatment and disposal. As is
described in Chapter I of this manual, hazardous waste is a sub-classification of solid waste.  A generator
of any type of waste is required under RCRA regulations to determine whether a generated waste is
hazardous. A waste can be defined as hazardous based on the situation from which it was derived, based
on its hazardous characteristics, or based on the concentrations of regulated hazardous constituents in the
waste. The EPA Office of Solid Waste and Emergency Response (OSWER) has established sampling
and analysis methodologies to be used to determine if a hazardous constituent is present in a waste at a
regulated concentration. The OSWER sampling and analysis procedures are published in Solid Waste
846 (SW-846).

The extent of analysis needed to define substances for waste disposal depends upon the OSC's
knowledge of the waste, the chemical and physical characteristics of the waste, the treatment
technologies to be explored for the disposal of the waste, and the facility where the waste will be treated.
It is not possible to know which facility will treat the waste until the removal action has begun.
However, qualitative information or information about the RCRA characteristics of a substance can be
easily obtained. Waste treatment technology options can be explored based on the physical and chemical
characteristics of a waste. Waste analysis parameters can then be selected based upon the generator's
knowledge of the waste, general characteristics of the waste, and treatment options available for the
waste to complete regulatory classification requirements.

Solvent recycling, metals recovery, and fuels blending waste treatments provide resource recovery, while
eliminating the environmental threats posed by the hazardous waste. Unfortunately, resource recovery
options are only available for a few types of wastestreams. Conventional commercial disposal methods
include wastewater treatment, thermal  destruction, chemical stabilization, and landfilling. Wastewater
treatment is the conventional method for wastestreams that consist of water soluble liquids with limited
organic contamination.  Thermal destruction is the conventional treatment method for most organic
liquids and solids.  Chemical stabilization is the conventional treatment method for non-ignitable,
inorganic solids and sludges.  Both resource recovery and conventional commercial disposal methods
and a description of the types of wastestreams capable of being treated by each method are described in
detail in Chapter 3. The Appendix of this manual outlines an example of the evaluation and disposal
process of unknown drum waste. Chapter 7 describes the requirements for the evaluation of bulk waste
such as tanks, vats, soil  and debris. The evaluation of bulk wastes may only involve limited analysis and
conformation data or a process similar to that for unknown drum waste. Handling and disposal options
for specialty wastes such as dioxins, PCBs, explosives and radioactives are discussed in Chapter 8.

Subchapter II: RCRA Hazard and Compatibility Testing of Unknown Substances for Disposal

Chapter 1 of this manual explains the application of RCRA waste identification requirements as defined
in 40 CFR Part 261. The characteristic of ignitability applies to wastes with a flash point of less than
140°F, solids that cause fire and bum vigorously, and DOT-regulated ignitable compressed gases and
oxidizers. The characteristic of corrosivity applies to wastes with a pH of less than 2 or greater than

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 Unknown Drum Wastes:  Characterization for Disposal
 12.5. The characteristic of reactivity applies to wastes that react violently with air or water, contain
 reactive cyanides or sulfides, or are explosive.

 A wastestream comprises all wastes with the same hazardous, chemical, and physical characteristics, and
 which are compatible and will be treated with the same disposal method. Field testing methods have
 been developed to easily obtain the following information on a sample: physical description of the
 substance, including all phases, and the ignitability, corrosivity, water reactivity, oxidizing properties,
 the presence of sulfides or cyanides, water solubility, and hexane solubility for each phase. All samples
 with the same results from the field testing are most likely physically and chemically compatible. An
 additional test of sample compatibility should be made by mixing together small quantities of separate
 samples and observing any reaction. If any type of physical or chemical reaction such as fuming, heat
 generation, or chemical precipitation occurs during the mixing operation, the samples are not compatible.
 All samples that have the same test results and are compatible will most likely be treated with the same
 method of disposal. The field testing methods used to make site wastestream determinations are referred
 to as RCRA hazard characteristic and compatibility testing or "haz-cat" testing.

 The foregoing description of haz-cat testing and wastestream determination may sound simple, but
 determining wastestreams can be complex.  Consider the sample matrix: generally, samples with similar
 matrices are considered as one wastestream. For disposal purposes, a matrix that contains @ free-
 flowing liquids is classified as "liquid." However, while several samples may be classified as "liquid" on
 the basis of their matrices, they may not constitute one wastestream because of variation between
 samples in the amount of liquid versus solid and because of differences in disposal based on this
 variation.  For example, a flammable sludge with a small amount of liquid should be considered a
 separate wastestream from a sample containing a large amount of liquid and a small percentage of
 flammable sludge, even though both wastes would be classified as flammable "liquid." An aqueous
 mixture containing less than 10 percent flammable organics is considered flammable. This mixture can
 be treated under wastewater treatment technologies. However, an aqueous mixture containing 11 percent
 flammable organics must be incinerated under RCRA LDRs. Thus, the percentage of constituents that
 produce a RCRA characteristic may affect the wastestream classification. Judgments such as these
 should only be made by an experienced disposal chemist to avoid misclassification of wastestreams.

 An example of the application of field testing to wastestreams and disposal technologies is provided in
 the Appendix of this manual. The following is a discussion of typical haz-cat procedures for determining
 wastestreams in the field.

 Subchapter HI:  Haz-Cat Test Procedures

 Sampling techniques may affect the accuracy of wastestream determinations, whether based on field
 testing or laboratory analysis, a representative sample of the container contents to be evaluated is
 essential. If sampling is performed incorrectly, all field testing and analysis data may be invalid.
 Sample collection procedures as such are outside the scope of this manual and are not discussed here.
 Guidance on sampling hazardous substances may be found in the "Compendium of ERT Waste Sampling
Procedures" (EPA/540/P-91/008, OSWER Directive 9360.40-7, January 1991) and in Volume 4,
 "Waste," of the Superfund Program Representative Sampling Guidance (EPA/540/R-93/060, OSWER
Directive 9360.4-14, May 1993).  Observations made during sample collection may contribute
 significantly to haz-cat testing, so types of useful observations are discussed here.
                                              53

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Unknown Drum Wastes: Characterization for Disposal
Materials Needed

EQUIPMENT               REAGENTS                          TEST STRIPS
matches                    hexane                                pH paper
propane torch               deionized/distilled water                oxidizer (potassium iodide)
cotton swabs                hydrochloric acid, 3 normal (3N)         sulfide (lead acetate)
glass rod                    iron citrate                            peroxide test strips
spatula                      ferrous ammonium sulfide
pipettes
test tubes
watch glasses
test tube clamp
copper wire

Sample  Observations

1 .   Before sampling, note the type, size, and condition (i.e., the physical properties) of the container and
    the visible characteristics of the contents, as these characteristics are clues to the nature of the
    contents. Include any label information.
      Crystals on the container may indicate explosive peroxides. If possible, test crystals directly
      with oxidizer and peroxide indicators. If positive oxidizer and peroxide results are obtained,
      contact reactives/explosive specialists. DO NOT OPEN OR MOVE THE CONTAINER.
      Organic peroxides are powerful, unstable explosives. Friction and/or heat can detonate
      organic peroxides.

2.  Note visible properties of the representative sample after it  is collected. Be sure to document the
    percent of the total composition and test results for each layer and/or phase of a  sample.

3.  Review air monitoring results obtained from the container prior to sampling and note possible
    explanations for readings. Combustible gas indicators can assist with the identification of ignitable
    hazards. Flame-ionization and photo-ionization detector readings may indicate the possibility of
    volatile organics.

4.  Note any distinct odors such as the odor of rotten eggs,  which indicates sulfides.

Haz-cat Field Tests

Water Reactivity - Place a pea-sized amount of a solid or a dime-sized pool of a liquid substance on a
watch glass. Wet pH test paper with water and touch the wetted paper to the substance. (Heat, fumes, or
fire indicate a water reactive sample.  Stop field tests and refer to specialty wastes.)

Corrosivity - Compare colors on the pH test strip with the pH indicator chart. Note the actual pH and
assign one of the following descriptions:
•   pH 0-3 = corrosive acid, solid or liquid
•   pH 3-5 =acidic solid or liquid
•   pH 5-9 = neutral solid or liquid
•   pH 9-1 1 = basic solid or liquid
•   pH 1 1 - 1 4 = corrosive base, solid or liquid
                                              54

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 Unknown Drum Wastes: Characterization for Disposal
 Oxidizer - Wet an oxidizer test strip (potassium iodide) with hydrochloric acid (HCI) and apply to the
 substance. A change in color of the entire wetted area of the test strip to blue, black or purple indicates
 the substance is an oxidizer.  If the oxidizer test is positive, perform the peroxide test. If the oxidizer test
 is negative, proceed with the solubility tests.

 Peroxide - Put a drop of water to the peroxide test strip and apply the strip to the substance - whether
 liquid or solid. Remove the strip  and wait at least 15 seconds.  A blue color indicates the presence of
 peroxides. A color indicator chart can be used to  estimate the peroxide concentration.  If the substance
 may be an organic liquid and the first peroxide test is negative, dip a dry test strip into the substance.
 Allow the solvent to evaporate from the test strip  and then apply a drop of water. Wait 15 seconds and
 note any color change which indicates the presence of peroxides. Describe the substance as one of the
 following: Organic peroxide, liquid or solid, or Oxidizer, liquid or solid.

 Water Solubility - Add a pea-sized amount of a solid or 1 milliliter of liquid being tested to 1 milliliter
 of water in a test tube. Always add an unknown substance to water, slowly. Never add water to an
 unknown. Note any reaction with the water such as dissolving, floating, sinking, fuming, or boiling.
 Dissolving indicates the substance is a water soluble inorganic or polar organic substance (such as salts
 or alcohols).  Emulsification indicates a slightly polar organic (such as a pesticide). Floating of liquids
 indicates a non-halogenated non-polar organic substance (such as an alkane like  hexane). Sinking of
 liquids indicates a halogenated non-polar organic  (such as carbon tetrachloride or trichloroethene).
 White curdling is typical of a liquid plastic resin.  Fuming and/or a temperature change is typical of acids
 or bases (see corrosivity test).

 Proceed with the hexane solubility test.

 Hexane Solubility - Add a small amount of the substance being tested to an equal amount of hexane in a
 test tube and note the solubility. Hexane solubility indicates  an organic substance. Hexane insolubility
 indicates an inorganic substance.

 Proceed with the halogen test.

 Halogen Test - Clean the copper wire by heating it in a torch flame until the wire glows red and there is
no green color in the flame. When the cleaned wire has cooled, dip the wire into the sample for 10
seconds. Apply the wire coated with the substance to the torch flame and note flame color. A green
 flame indicates a halogenated substance, amine (also basic) or nitrate (also an oxidizer).

If an organic  substance tests positive for halogens, the sample should be tested for PCBs.  Commercial
kits are available to test for PCBs  in liquids (oils) and in solids (soils). I Directions are available with
each kit.

Use the data gained from the halogen test along with data obtained from the water solubility and hexane
solubility tests to classify the substance according to the following list:

•  Inorganic, liquid, aqueous (water soluble and hexane insoluble liquid)
•  Inorganic, solid (water soluble, hexane insoluble or water and hexane insoluble)
•  Organic, non-halogenated, liquid or solid (hexane soluble, may be water soluble, float on water, or
   emulsify  with water, negative halogen test)
•  Organic, halogenated, liquid or solid, negative PCB (hexane soluble, sinks in water or is water
   soluble, positive halogen test,  negative PCB test)
                                               55

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Unknown Dram Wastes: Characterization for Disposal
•   Organic, halogenated, liquid or solid, PCB (hexane soluble, sinks in water, positive halogen test,
    positive PCB test)

Reactive Sulfide or Cyanide - Dilute the 3N hydrochloric acid by slowly adding equal amounts of the
3N HC1 to water in a test tube.  With a pipette slowly add, one drop at a time, the dilute HC1 to a small
amount of the substance being tested in another test tube. (Do not add more than 6 drops of dilute HC1 to
1/2 test tube of substance.)

A yellow color (accompanied by a rotten egg odor) indicates toxic hydrogen sulfide. Touch a sulfide
indicator paper (lead acetate) to the mixture of acid and unknown. A change in color of the test paper to
brown or black is positive for sulfides.

Bubbling or effervescing from a reaction with the dilute HC1 may indicate the presence of highly toxic
cyanides. Dissolve unknown solids in water. If the unknown solid is not water soluble, do not continue
with this test. In a separate test tube, mix iron citrate (about 1/4 of the test tube) and a pinch of ferrous
ammonium sulfide.  Add the unknown liquid substance to the test tube to bring the total volume of the
test to 1/2 to 3/4 full. Shake the mixture for  1 minute. Slowly add 5 to 6 drops of 3N HC1.  A dark
Prussian blue color indicates cyanides.

Class the substance from the following list:

•   Non-sulfide or non-cyanide reactive, solid or liquid
•   Sulfide reactive solid or liquid
•   Cyanide reactive solid or liquid

Ignitability - Place a pea-sized amount of a solid or a quarter-sized pool of liquid onto a watch glass.

Touch a lighted match to the surface of the substance. If the match goes out and the substance does not
burn, the unknown is not ignitable. If the flame jumps from the match to the substance or the substance
continues to burn when the match is removed, the unknown is ignitable.

Ignitable liquids are classed as flammable or combustible.:

•   Combustible liquids take longer to ignite than flammables.
•   Flammables will ignite quickly and continue to burn.  The match must be held to a combustible to
    ignite and may require constant heat to continue to burn.

Solids are classified as flammable or non-flammable. Flammable solids bum vigorously upon ignition.

Classify the ignitability of the substance as follows:

•   Non-ignitable liquid or solid
•   Flammable solid
•   Flammable liquid
•   Combustible liquid

Compatibility Testing - Combine individual sample test classifications into one description for each
sample. This sample description will be a preliminary wastestream description. Be sure to indicate the
characteristics of separate phases and/or layers of the sample. Multi-phased samples and single-phased

                                               56

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 Unknown Dram Wastes:  Characterization for Disposal
 samples represent separate wastestreams.  Mix equal amounts of all samples with the same wastestream
 classification, adding one sample at a time. If the addition of a given sample causes a reaction in the
 mixture, the sample is incompatible with the mixture and must be eliminated from this wastestream. The
 compatibility mixing must be restarted at the first sample once the incompatible sample has been
 eliminated.

 Preliminary Wastestreams - All samples with similar phases and field testing descriptions, which are
 compatible, constitute a preliminary wastestream.

 Subchapter IV:  Determination of Treatment Options Based on RCRA Hazard and Compatibility
 Testing

 The general characterization descriptions obtained from field testing can be used to determine an
 appropriate disposal method for each phase of an unknown substance. A precedence of treatment
 options for multi-phased wastes can be developed based on an understanding of the results of each
 treatment option and an understanding of RCRA-regulated treatment requirements. Possible waste
 classifications from field testing and the likely treatment option are summarized below. A list of
 treatment options for multi-phased waste immediately follows the wastestream summaries.
 Conventional waste treatment and disposal options are discussed in detail in Chapter 3 of this manual.
 General wastestream properties and characteristics capable of being treated by a particular method are
 also discussed in Chapter 3.

 Organic Liquids and Solids

 Thermal destruction is the only method capable of destroying concentrated organic constituents in a
 waste. Several types of thermal destruction are available: incineration and fuels blending.  Fuels
 blending at cement kilns is the most cost effective means of thermal destruction. Currently, only
 pumpable organic liquids are acceptable for fuels blending. Substances exhibiting the RCRA
 characteristics of corrosivity and ignitability, metals and oxidizers are usually acceptable in an organic
 liquid wastestream for fuels blenders.  Sludges, halogens, pesticides, sulfides and cyanides in organic
 liquid wastestreams are usually not acceptable for cement kilns.

 Commercial incineration is the treatment option of choice for organic liquid wastestreams which are not
 fuels blendable (i.e., the waste contains sludges, halogens, pesticides, sulfides or cyanides).

 All wastes with greater than 50 ppm of PCBs must be incinerated at a TSCA-permitted facility. PCBs
 are covered further in Chapter 8.

Inorganic Solids

Corrosive acid or acidic or neutral, or basic or corrosive base, plus
      •  water soluble or non-water soluble,
      •  oxidizer or non-oxidizer,
      •  sulfide or non-sulfide,
      •  cyanide or non-cyanide, or
      •  flammable solid.

Incineration for disposal.
                                              57

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Unknown Drum Wastes:  Characterization for Disposal
Inorganic Solids

Corrosive acid or acidic or neutral, or basic or corrosive base, plus

      •   water soluble,
      •   oxidizer or non-oxidizer,
      •   sulfide or non-sulfide,
      •   cyanide or non-cyanide, or
      •   non-flammable solid.

Stabilization or waste-water treatment.

Corrosive acid or acidic or neutral, or basic or corrosive base, plus

      •   non-water soluble,
      •   oxidizer or non-oxidizer,
      •   sulfide or non-sulfide,
      •   cyanide or non-cyanide, or
      •   non-flammable solid.

Stabilization treatment.

Inorganic Liquids

Corrosive acid or acidic or neutral, or basic or corrosive base, plus

      •   water soluble,
      •   oxidizer or non-oxidizer,
      •   sulfide or non-sulfide,
      •   cyanide or non-cyanide, or
      •   non-flammable solid.

Wastewater treatment.

Multi-phased Waste - Precedence of Treatment Options

1.    Any phase that is ignitable - thermal destruction (with the exception of aqueous wastes with less
     than 10 percent organic constituents wastewater treatment).
2.    Any waste that contains more than 10 percent organic constituents - thermal destruction.
3.    Any waste that contains more than 5 percent halogenated organic carbon - thermal destruction.
4.    Aqueous waste that contains less than 10 percent organics and/or less than 5 percent halogenated
     organics - wastewater treatment.
5.    Inorganic sludge that contains less than 20 percent water and no regulated organics - stabilization
     and landfilling.
6.    Inorganic sludge that contains greater than 20 percent water and no regulated organics; separate
     solids from liquids - wastewater treatment for liquids and stabilization and landfilling of the
     remaining sludge.
7.   Inorganic sludge and regulated organics - thermal destruction.


                                               58

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 Unknown Drum Wastes:  Characterization for Disposal
 NOTE: Wastestreams are determined by combining similar preliminary wastestream classification
 samples according to the appropriately determined treatment method.  For example, field testing results
 may have indicated an aqueous sample with an organic sheen and less than 10 percent organics is a
 separate wastestream from an aqueous sample with no sheen and less than 10 percent organics.
 However, the treatment precedence above indicates these wastes will be disposed of in the same manner.
 Thus, the wastes may be combined into a new final wastestream classified as aqueous with less than 10
 percent organic constituents.

 Subchapter V: Compositing Wastestream Samples and Determining the Appropriate Disposal
 Analysis

 Once wastestream classifications have been established according to physical properties, hazard
 characteristics, and chemical compatibility, and once appropriate treatment options have been
 established, additional laboratory analysis may be needed to determine the presence of regulated
 constituents and the feasibility of recovery disposal options. Compositing wastestream samples for
 detailed laboratory analysis is commonly used to minimize costs.  The following factors must be
 considered when compositing wastestream samples for laboratory analysis:

 1.  Possible treatment methods and required analysis for each treatment method.
 2.  The number of individual samples to be combined.
 3.  Possible PCB contamination.
 4.  The amount of sample needed to perform the anticipated analysis.
 5.  The amount of individual samples to be maintained for future analysis or disposal approval.

 Analysis Parameters Based on Characteristics of the Waste and Possible Treatment Options

 Several inexpensive laboratory tests can be performed to rule out the possibility of certain contaminants
 or to determine the applicability of a particular treatment method.  Additional, more expensive analyses
 for concentrations of particular constituents can then be chosen.

 If thermal destruction is the treatment option of choice for a determined wastestream, then values for
 percent water, percent solids, total organic carbon (TOC), total organic halogens (TOX), also known as
 halogenated organic carbon (HOC), flash point, boiling point, British thermal units (BTU), cyanides,
 sulfides, percent ash, and PCBs are required to determine the practicability of fuels blending versus
 incineration.  These parameters will also be required by the disposal facility for calculating cost of
 disposal. For thermal destruction, generator's knowledge or total values for volatile organic compounds
 (VOC), base-neutral and acid extractables (BNA), and metals are sufficient to determine the regulated
 constituents.  Values for TCLP-regulated constituents can be assigned based on the results. The
 application of RCRA waste codes based on total dry weight results rarely affects the pricing for thermal
 destruction. Pricing is based on the general parameters that dictate the energy needed to destroy the
 waste to the required extent.
 If wastewater treatment is the treatment option of choice for a determined wastestream, then values for
percent water, percent solids, TOC, TOX, cyanides, sulfides, pH, and PCBs are usually required by the
disposal facility to determine the practicability of treatment at the particular plant and to determine
pricing. Total metals quantities are usually required for disposal. If the TOC value times the number of
 samples composited is less then 0.01 percent, there is probably no need to perform further organic
analysis. If the TOC value is greater than 0.01 percent dry weight, then VOC and BNAs analyses may be
required. Remember, for the assignment of RCRA codes in an aqueous matrix, dry weight analysis
results are equivalent to TCLP results.


                                              59

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Unknown Drum Wastes: Characterization for Disposal
If stabilization techniques or landfill are the treatment options of choice for a determined wastestream,
then values for percent water, percent solids, cyanides, sulfides, pH, and PCBs are required by the
disposal facility for applicability of the treatment or disposal as well as for pricing. TCLP analysis is
required for RCRA-regulated organics and metals unless information is available that indicates the
contaminants of concern are not present. For example, if Contract Laboratory Program (CLP) analyses
indicate that regulated VOC and BNA compounds are not present, the OSC has generator's knowledge
and analytical results to prove the constituents are not present at TCLP regulatory levels.  Waste codes
may be .applied from dry weight results, but pricing for disposal will most likely be affected.

Sample Compositing

Descriptions, or profiles, of wastestreams required by disposal facilities are general. Therefore, all data
obtained for a wastestream should be reported on a profile as ranges, not as exact figures. The general
profile descriptions of wastestreams allow for separate container samples of the same wastestream to be
composited for laboratory analysis. Sample composites provide the necessary data at the least cost.
However, it is important to understand the effect of compositing samples in relation to the results
obtained and the interpretation of the results as applied to the wastestream. If a contaminant is present at
a regulated level in only one of several samples composited, dilution of the particular contaminant must
be considered in the interpretation of the analysis of the composite. When a particular analysis
parameter is known, the formula used to determine the maximum number (n) of samples per composite
is:

                                          n =mcl/dl

Where mcl = maximum concentration limit of the method, and dl = detection limit of the analysis
parameter.

For example,  the regulatory limit for PCBs is 50 ppm (MCL). If the analysis method detection limit for
PCBs is 1 ppm, the number of samples that can be composited is 50. However, if 50 samples are
composited and the analytical result for the composite sample is 1  ppm, there is no way to know whether
one sample of the 50 contains 50 ppm of PCBs while the others contain 0 ppm, or whether the opposite
extreme has occurred, each of the 50 samples contains 1 ppm of PCBs. Thus, it is prudent to limit the
number of samples composited for wastestream analysis to 10. It is also prudent to maintain the  separate
individual samples.  If the composite sample indicates a possible contaminant that may significantly
affect disposal, then the individual samples can be analyzed for the contaminant of concern.

Consider a wastestream determined to be an organic halogenated liquid with possible PCB
contamination. Ten samples are composited, and analysis indicates 10 ppm of PCBs. That is:

       10 ppm (composite) = (Ci+C2+C3+C4+cs+C6+C7+C8+C9+cioyio

Where Cn result is the concentration in a particular individual sample of the 10 samples
composited. In this case, the maximum concentration possible for any one sample is 100 ppm, which is
the analytical result multiplied by the total number of samples composited. The minimum concentration
possible for the remaining nine samples is 0 ppm, assuming the maximum concentration is contained in
one sample (i.e., one sample contains 100 ppm while  the remaining nine contain 0 ppm). The proper
disposal profile information, based on the data, is the range PCBs 0 to 100 ppm.  If the cost of drum
disposal of PCB waste (exceeding 50 ppm) is $100/drum more than for non-PCB waste and PCB
analysis can be obtained for approximately $50/sample, an OSC may chose to reevaluate the contents of
the individual drum rather than dispose of all drums as PCB waste.
                                             60

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 Unknown Drum Wastes: Characterization for Disposal
 Consider a wastestream determined to be aqueous and 10 samples are composited.  The analysis of the
 composite sample shows 0.01 percent (100 ppm) TOC and 99.99 percent water. This information is
 sufficient to determine that none of the 10 samples exceeds the definition of RCRA wastewater (water
 containing less than 1,000 ppm TOC). Thus, further analysis to identify trace organic contaminants may
 not be needed.

     Once the analysis parameters have been chosen and the number of samples to be composited per
 wastestream has been determined, the amount of sample needed from each container in the wastestream
 must be considered. CLP lists are available that give the type of container and quantity of sample needed
 to analyze particular parameters. When possible, a duplicate of each composite should be maintained on
 site for evaluation (tre'atability study, approval study) by the TSD, when determined.  A minimum of one
 8-ounce sample from each individual container should also be maintained in the event additional analysis
 may be required (16-ounce samples should be maintained if less than 10 samples per wastestream are
 composited).

     It should also be noted, that sampling techniques may affect the accuracy of wastestream
 determinations from any kind of testing.  A representative sample of the container contents to be
 evaluated  is essential. If sampling is performed incorrectly, all field testing and analysis data may be
 invalid.

 Subchapter VI: Summary of Disposal Evaluation Procedures for Unknown Drums, Utilizing
 Wastestreams Developed by RCRA Hazard and Compatibility Testing and Available Treatment
 Options

 1 .  Perform field testing of samples of drum contents.

 2.   Develop preliminary wastestreams from physical characteristics, hazard characteristics and
     chemical compatibility.

 3.   Determine potential treatment technologies for each preliminary wastestream.

4.   Complete wastestream determinations based on field testing results and treatment technologies.

 5.   Determine appropriate analysis parameters  from generator's knowledge and potential treatment
     options. Use hierarchy of parameters to rule out expensive analysis where possible.

6.   Composite samples based on wastestream determinations and acceptable contaminant concentration
    ranges for the proposed treatment option. Maintain individual container samples and a duplicate
    wastestream composite sample for future use.
                                             61

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Unknown Drum Wastes: Characterization for Disposal
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                                    62

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                                         CHAPTER 7
                     WASTE CHARACTERIZATION OF TANKS, VATS,
                             LAGOONS, EFFLUENT, AND SOIL
As is discussed throughout this manual, a waste is regulated by RCRA as a hazardous waste if it is
specifically listed as a hazardous waste, if it contains regulated hazardous constituents above a specified
concentration, or if it has been derived from, mixed with or contained in a hazardous waste. These
principles apply to bulk quantities of wastes found in tanks, vats and lagoons, and soil, just as they apply
to smaller, non-bulk quantities found in drums. Because these same principles apply, bulk wastes are
characterized for disposal along essentially the same lines as drummed wastes.

In the case of a bulk container of an unknown substance from an unknown source, the contents are
characterized for disposal utilizing the same process as is described in Chapter 6 for drum wastes.
However, the initial steps in properly sampling a bulk waste tend to be more elaborate and critical than in
sampling a non-bulk, drummed waste.

The sample or samples collected from any waste must be representative of the waste and account for any
variability in the waste. A drum containing a liquid can be sampled with a glass tube in such a manner
that the sample obtained is representative of the entire contents of the drum.  Unfortunately, sampling
devices are not usually designed to obtain a single representative sample of a large quantity of waste
such as is  found in tanks, vats, lagoons, effluent, or soil piles. Thus, several samples from different
locations within a bulk waste must be collected and composited to obtain a representative sample and to
account for variability in the waste. Just as with drums, different layers of contaminants and physical
phases in a bulk quantity of waste must be recognized and sampled to determine proper treatment and/or
disposal. Different physical phases, such as a sludge and a liquid, within a container must initially be
evaluated  as separate wastestreams. All contaminant layers in a bulk quantity of waste can usually be
composited for disposal analysis. Interpretation of results obtained from a composite sample is discussed
in detail in Chapter 6. An example of analysis data interpretation for composited waste samples is
available in the example outlined in the Appendix.

The OSWER publication Solid Waste 846 (SW-846) "Test Methods for Evaluation of Solid Waste"
provides guidance to both the method and number of samples to collect from tanks, effluent, lagoons and
soils in order to obtain verifiable representative waste analysis results.

In the case of bulk quantities of wastes in tanks, vats, lagoons and effluent generated in process
manufacturing facilities, RCRA regulatory classifications for manufacturing process waste can usually
be assigned without sample characterization and analysis. The initial step in  evaluating bulk quantities
of waste from manufacturing facilities for disposal (see Chapter I - RCRA) is review of the "U" and "P"
waste codes assigned to discarded commercial chemical products, off-specification species, and
container residues, the "K" codes assigned to specific source wastes, and the  "F" codes assigned to
general process, non-specific source wastes.

RCRA land disposal restrictions and available waste treatment technologies can be evaluated based on
the RCRA hazardous waste classification. It  is important to note that regardless of how the waste is
classified and the amount of information known about the source of the waste, representative samples of
a RCRA-classified waste are still needed to profile the waste properly for treatment and disposal. The
type of analysis required to profile a RCRA-classified waste depends on the classification and the
treatment technologies available for the waste. Often, representative samples of RCRA-classified waste

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Waste Characterization of Tanks, Vats, Lagoons, Effluent and Soil
can be analyzed by the TSDs considered for disposal as part of the treatability study included in the
profile fee. These TSD treatability studies usually include general analysis parameters such as percent
water and solids, total organic carbon, total halogenated organic carbon, flash point, and fuel value as
discussed in Chapter 6 for specific characterized wastestreams and treatment methods. The need for
more elaborate and expensive analyses to determine the concentration of specific contaminants should be
based upon the RCRA classification, treatment standards, the type of treatment selected, and the results
of the general parameter analyses.

Soil contamination resulting from a spill or release of a hazardous substance can be classified under
RCRA regulations as a "derived from" waste. Thus, all waste codes and associated treatment standards
that would have applied to the released substance or waste are applied to the area of contamination.
Since the transportation and off-site treatment of large volumes of contaminated soil are expensive, the
feasibility of on-site treatment options to mitigate the threat should be explored. With on-site treatment
of soil, CERCLA cleanup standards defined for the site by Regional EPA officials take precedence over
RCRA off-site disposal regulations. Proper sampling and analysis for the treatability study to determine
effectiveness of an on-site treatment option is essential. Again, the EPA guidance SW-846 should be
consulted to determine the procedures and methods to obtain representative samples for the waste
evaluation and treatability study.
                                               64

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                                          CHAPTER 8
                                    SPECIALTY WASTES
 Subchapterl: Lab Packs

 The term lab pack refers to specific exemptions to the DOT hazardous materials
 transportation requirements and the RCRA hazardous waste treatment standard
 requirements for laboratory-sized containers of waste. "Laboratory-sized containers"
 means glass containers not exceeding a one-gallon capacity (4 liters) and metal or
 plastic containers not exceeding a 5.3-gallon capacity (20 liters).

 The DOT lab pack exemption allows specified laboratory-sized containers of
 chemically compatible waste materials with the same hazard class to be placed in
 combination packagings.  The combination package or lab pack can be described
 with the generic hazard class description for highway transportation only.  The waste
 must be classed as 3, 4.1,4.2,4.3, 5.1, 6.1, 8, or 9 and segregated as such to be
 considered for lab pack. Wastes meeting the definition of 6.1 packing group I or
 Division 4.3 packing group I, bromine pentafluoride, bromine trifluoride, chloric
 acid, and oleum (fuming sulfuric acid), are specifically prohibited from lab packs.

 The outer packaging of a DOT lab pack must be one of the following DOT-specified
 containers:
1A2 - open head steel drum
1B2 - open head metal drum
ID- plywood drum
1G-fiber drum
1H2 - open head plastic drum
Inner packagings of a lab pack (laboratory-sized containers) holding liquids must be
surrounded by chemically compatible absorbent material in sufficient quantity to
absorb the total liquid content. The gross weight of a lab pack cannot exceed 452
pounds (205 kilograms). All other DOT hazardous materials requirements such as
labeling, manifesting, and emergency information as described in Chapter 2 of this
manual apply to the lab packs.

In order to achieve the chemically compatible requirements, lab wastes of the same
DOT hazard class may need to be segregated according to additional physical and
chemical properties.  Following is a list of potential sub-segregation criteria for lab
packs:

Class 3 Flammable liquids: organic or inorganic

Class 4.1 Flammable solids: organic or inorganic

Class 4.2 Spontaneously combustible materials
         Solids: organic or inorganic
         Liquids: organic or inorganic
                                                49CFR
                                                Department of
                                                Transportation
                                                Hazardous  .
                                                Materials
                                                Regulations
                                                Part 173
                                                Shippers
                                                General
                                                Requirements
                                                for Shipments
                                                and Packaging

                                                173.12
                                                Exceptions for
                                                shipment of waste
                                                materials
Class 4.3 Dangerous when wet

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Specialty Wastes
         Packing group I: lab pack forbidden
         Solids:  organic or inorganic
         Liquids: organic or inorganic

Class 5.1 Oxidizers: solid or liquid

Class 6.1 Poisonous materials
        Packing group I: lab pack forbidden
        Solids: organic or inorganic
        Liquids: organic or inorganic

Class 8 Corrosive materials
       Solid organic: acid or base
       Solid inorganic: acid or base
       Liquid organic: acid or base
       Liquid inorganic : acid or base

Class 9 Miscellaneous hazardous materials
       Liquids: organic or inorganic
       Solids: organic or inorganic

As an alternative to otherwise applicable RCRA hazardous waste treatment
standards or land disposal restrictions, lab packs are eligible to be incinerated at a
RCRA-approved facility. The ash from the incineration of authorized lab packs is
only subject to D004, D005, D006, D007,  D008, D010, and D011 (TCLP metal
wastes) land disposal restrictions. Hazardous wastes eligible for this exemption
must be placed in an organometallic or an  organic lab pack. Appendix IV of 40 CFR
268 lists RCRA codes for wastes that are authorized to be placed in an
organometallic lab pack; Appendix V of 40 CFR 268 lists RCRA codes for wastes
that are authorized to be placed in an organic lab pack. Thus, laboratory wastes
must be segregated according to the DOT-authorized hazard class, chemical
compatibility and the applicable RCRA hazardous waste classifications to be
considered for both DOT and RCRA lab pack exemptions.

The final consideration for the proper segregation and packaging of laboratory-sized
waste containers is TSD-specific requirements. The TSD's RCRA permit for
treatment and disposal of hazardous wastes affects the types of wastes the facility
may accept. Although waste may be packaged properly for DOT and RCRA lab
pack exemptions, the facility may not be permitted to treat a particular container
within a lab pack drum.  Such a situation would result in the rejection of the entire
lab pack drum from the TSD.

The standard operating procedures at a TSD may also affect lab pack procedures.
Most facilities have developed special packaging requirements for wastes with
hazard characteristics that are difficult to handle. Examples of wastes that often
require special packaging requirements include sulfur and cyanide compounds,
ethers, oxidizers, alkali metals, bromine and iodine, silanes, air or water reactive
materials, lacrymators and other dangerous fire or explosion risk materials. Thus, to
ensure compliance with both regulatory and facility lab pack requirements, TSDs
generally require their own personnel to package laboratory wastes at a customer

                                              66

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 Specialty Wastes
 site.

 If a TSD cannot be contracted to perform lab pack operations at a site in the time-
 frame needed, site personnel could segregate lab wastes according to lab pack
 regulatory standards. Segregation of wastes according to lab pack standards would
 reduce the threat of adverse reactions between incompatible wastes and would
 reduce the time and costs associated with final lab pack by a commercial TSD.

 Subchapter U: Dioxins and Dibenzofurans

 Dioxins are any chemical compound with the molecular structure where X
 represents possible hydrogen, bromine, or chlorine substitution positions, see Figure
 8-1 for an example.

 2,3,7,8-Tetra chloro dibenzo-p-dioxin, or TCDD, has the chemical structure seen in
 Figure 8-2.

 Halogenated dibenzo-p-dioxins, HDDS, are any dioxins that have the 2, 3, 7, and 8
 positions occupied by chlorine or bromine.  Other positions may be occupied by
 chlorine or bromine as well.

 Dibenzofurans are any chemical compound with the molecular structure shown in
 Figure 8-3 where X represents possible hydrogen, bromine, or chlorine substitution
 positions.

 Halogenated dibenzofurans, HDFS, are any dibenzofurans that have the 2, 3, 7, and
 8 positions occupied by chlorine or bromine. Other positions may be occupied by
 chlorine or bromine as well.

 RCRA regulates dioxins and dibenzofurans under waste codes F020, F021, F023,
 F026, F027, and F028. The codes are specific to wastes generated from the
production and manufacturing use of chlorophenols and chlorobenzenes, to wastes
 generated from discarded unused formulations of chlorophenols, and to residues
 from the treatment of soil contaminated with F020, F021,  F023, F026 and F027
 wastes.

 Specifically listed hazardous constituents of these wastes include tetra-, penta-, and
 hexa-chlorodibenzo-p-dioxins and dibenzofurans, and tri-, tetra- and penta-
 chlorophenols and their chlorophenoxy derivative acids, esters, ethers, amines and
other salts.

RCRA treatment standards or land disposal restrictions for dioxin bearing wastes are
as follows:
 40CFR
 Toxic
 Substances'
 Control Act
 Part 766
 Dibenzc-para-
 dioxins/
 dibenzofurans

 766.3 Definitions
40 CFR 268
Land Disposal
Restrictions
Subpart C-
Prohibitions on
Land Disposal
268.31 Waste
specific
prohibitions -
Dioxin-
containmg
wastes

40 CFR 261
Identification
and Listing of
Hazardous
Waste
Appendix VII -
Basis for Listing
Hazardous
Waste

40 CFR 268
Land Disposal
Restrictions
Subpart D -
Treatment
Standards
12641
Treatment
standards
expressed as
concentrations in
waste extract
Constituent
tetra-, penta- and hexa-chloro dibenzo-p-dioxins
tetra-, penta- and hexa-chlorodibenzofurans
2,4,5 and 2,4,6 trichlorophenol
2,3,4,6 tetra-chlorophenol
Pentachlorophenol
Treatment Standard for Waste Extract (TCLP)
< 1.0 ppb
<1.0ppb
< 1.0 ppb
< 1.0 ppb
<0.01 ppm
                                                67

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Specialty Wastes
RCRA further requires incinerators to achieve a 99.9999 percent destruction removal
efficiency for the principle organic hazardous constituents of dioxin-bearing wastes.
Within the past few years, one commercial incinerator in the United States was
permitted to bum dioxin and dibenzofuran bearing wastes. Unfortunately, in
September 1997, this incinerator notified clients that until further notice, they would
no longer accept dioxin and dibenzofuran bearing wastes for incineration. At this
time, there are no commercial incineration options available for the disposal of dioxin
and dibenxofuran bearing wastes.

On-site chemical reaction, photodegradation, bioremediation, and incineration with an
EPA-approved mobile incinerator have been used on Superfund sites to reduce HDD
and HDF contamination of soil and debris.
40 CFR 264.342
Principal organic
hazardous
constituents
                     Figure 8-1 Dioxin Chemical Structure
                 Figure 8-2 2,3,7,8-Tetrachlorodibenzo-p-dioxin

                                x
                  Figure 8-3 Dibenzofuran Chemical Structure

Subchapter III: Poh chlorinated Biphenyls (PCBs)

Regulatory Definitions and Disposal Requirements of PCBs and PCB Items

Polychlorinated biphenyls (PCBs) are chemical compounds that consist of a
chlorinated biphenyl molecule as pictured in Figure 8-4.

"X" indicates possible chlorine or hydrogen positions on the biphenyl molecule.
                                              68

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 Specialty Wastes
Aroclor
Aroclor B
Asbestol
Askarel
Chlorextol
Chlorphen
Diaclor
Dykanol
Elemex
Eucarel
Fenchlor
Hyvol
                 Figure 8-4 Polychlorinated biphenyl Molecule

PCBs were manufactured primarily as an insulating substance for electrical
transformers and capacitors. The generic name for electrical equipment insulating
substances is "askarel." Some trade names and common names of PCB askarel
substances include:
                            Inerteen
                            Kanechlor
                            Phenochlor
                            Pyralene
                            Pyrochlor
                            Santotherm

PCBs are regulated as a chemical substance under the Toxic Substances Control Act
(TSCA). TSCA banned the manufacturing of PCBs in the United States in 1976 and
currently regulates the handling, storage and disposal of PCB substances and wastes.
TSCA defines specific handling, storage and disposal procedures for PCBs and PCB
items.  TSCA definitions of types of PCB wastes that are commonly found at
Superfund removal projects are as follows:

•   PCB substances include but are not limited to, dielectric fluids, contaminated
    solvent,  oils, waste oils, heat transfer fluids, hydraulic fluids, paints, sludges,
    slurries, dredge spoils, soils, materials contaminated as a result of a spill, and
    other chemical substances or a combination of substances that  contain PCBs.

•   PCB articles are manufactured articles that contain PCBs and  whose surfaces
    have been in direct contact with PCBs.  PCB articles may include capacitors,
    transformers, electrical motors, pumps and pipes.

•   PCB containers are packages that contain PCBs or PCB articles,
•   but whose surface has not been in direct contact with PCBs.

•   PCB-contaminated electrical equipment (also called a PCB article) includes
    any electrical equipment that contains between 50 to 500 ppm PCBs. Examples
    are transformers, capacitors, circuit breakers, reclosures, voltage regulators,
    switches, electromagnets and cable.

•   PCB equipment means manufactured items, not including containers, that
    contain a PCB article  such as microwave ovens or fluorescent light ballasts and
    fixtures.

•   PCB transformers (also called PCB articles) are transformers that
•   contain greater than 500 ppm PCBs.
40CFR
Toxic
Substances
Control Act
Part 761
Polychlorinated
biphenyls
(PCBs)
Manufacturing,
processing,
distribution in
commerce, and use
prohibitions
761.1 Applicability

761.3 Definitions
                                              69

-------
Specialty Wastes
•   Non-PCB transformers are transformers that contain less than 50 ppm PCBs.
    (Note: Transformers that contain 50 to 500 ppm PCBs are regulated as PCB-
    contaminated electrical equipment.)

Authorized disposal of PCBs depends on the type of PCB waste, the physical state of
the waste (solid or liquid) and the concentration of PCBs in the waste. The terms
"chemical landfill," "incinerator" and "boiler" used in this chapter refer to disposal
options at TSCA-permitted facilities. Disposal options for specific PCB wastes are
described as follows:

Disposal of PCB substances:

1.   Liquid hazardous wastes, as defined by RCRA and described in Chapter I of this
    manual, that contain PCBs at a concentration of greater than 500 ppm must be
    incinerated at a facility that is permitted under both RCRA and TSCA. Liquid
    hazardous wastes that contain 50 to 500 ppm of PCBs must be thermally
    destroyed at a RCRA- and TSCA-permitted boiler or incinerator.
2.  Mineral oil dielectric fluid (from PCB-contaminated electrical equipment)
    containing 50 to 500 ppm PCBs may be disposed of at an incinerator, chemical
    waste landfill, or high efficiency boiler.

3.  Other PCB liquids that contain 50 to 500 ppm PCBs may be disposed of at an
    incinerator, chemical waste landfill, or high efficiency boiler.

4.  Non-liquid PCBs in a concentration greater than 50 ppm in the form of
    contaminated soil, rags or debris may be disposed of at an incinerator or
    chemical waste landfill. (Note: It is illegal to process liquid PCBs into non-
    liquid PCBs to circumvent high temperature incineration requirements.)

5.  Dredged materials containing PCBs greater than 50 ppm may be disposed of at
    an incinerator or a chemical waste landfill.

6.  All other PCB substances with a concentration exceeding 50 ppm must be
    incinerated.  This includes all liquids containing greater than 500 ppm PCBs.

Disposal of PCB transformers (greater than 500 ppm PCBs

1.  Emptied and rinsed PCB transformers may be disposed of at a chemical waste
    landfill. "Emptied" means drained of all free flowing liquids. "Rinsed" means
    filled with a solvent (kerosene, toluene, xylene) in which PCBs are readily
    soluble, allowed to stand for at least 18 hours, and then drained thoroughly. All
    PCB liquids, including  rinsate, removed from  a transformer must be disposed of
    as PCB substances.

2.  PCB transformers that have not been emptied and rinsed must be disposed of at
    an incinerator.
40CFR
Toxic
Substances
Control Act
Part 268 Land
Disposal
Restrictions
                                              70

-------
 Specialty Wastes
 PCB-contaminated electrical equipment

 1.   Transformers containing 50 to 500 ppm PCBs must be drained of all free
     flowing liquids. The liquids must be disposed of as PCB substances. The
     disposal of the emptied transformer carcass is not regulated.

 2.   Capacitors

     a) With the exception of capacitors at PCB capacitor manufacturing facilities,
        small capacitors, (containing less than three pounds of dielectric fluid,
        generally less than ten pounds gross weight) may be disposed of as
        municipal solid waste.
     b) Manufacturers of small PCB capacitors must dispose of them by
        incineration.
     c) All other capacitors (containing greater than three pounds of dielectric
        fluid) must be disposed of at an incinerator.

 3.   All other PCB-contaminated electrical equipment must be drained of free
     flowing liquids. The liquids must be disposed of as PCB substances. The
     disposal of the emptied equipment is not regulated.

 Disposal of other PCB articles

 1.   PCB hydraulic machines  containing greater than 1000 ppm PCBs must be
     drained and flushed with  a solvent. The liquids, including rinsate, must be
     disposed of as PCB substances.  The emptied and flushed carcass may be
     disposed of as municipal  solid waste.

 2.   PCB hydraulic machines  containing between 50 and 1000 ppm PCBs must be
     drained of all free flowing liquids. The liquids must be disposed of as  PCB
     substances.  The emptied machines may be disposed of as municipal solid
     waste.

 3.  All other PCB articles with concentrations of greater than 500 ppm may be:

     a) Disposed of at an incinerator, or
     b) Drained and disposed of at a chemical waste landfill. Drained liquids must
        be incinerated.

4.   All other PCB articles  with concentrations of 50 to 500 ppm must be disposed
     of by  draining all free-flowing  liquids and  disposing  of the liquids as PCB
     substances.  The disposal of the drained article is not regulated.

Disposal of PCB containers

 1.   Any PCB container that  held PCBs in a  concentration greater  than  500 ppm
     must be:

     a) Disposed of at an incinerator or chemical waste landfill, or
     b) Decontaminated by flushing the internal surfaces three times with a solvent

                                              71

-------
Specialty Wastes
         capable of 5 percent or more PCB solubility. Each rinse shall comprise 10
         percent of the volume of the container. The solvent may be reused until it
         contains 50 ppm PCB. The rinsate, when no longer useful, is disposed of
         as a PCB substance.

2.  Any PCB container that held PCBs in a concentration of less than 500 ppm is
    disposed of as a municipal solid waste, provided any free-flowing liquids have
    been drained and disposed of as PCB substances.

Disposal of PCB spills

1.  Spills and other uncontrolled discharges of PCBs at concentrations greater than
    50 ppm constitute unlawful disposal.

2.  PCBs  resulting  from the  cleanup or  removal  of  spills,  leaks, or  other
    uncontrolled discharges must be disposed of as PCB substances.

Note:  TSCA established a PCB Spill Clean-Up Policy as a guidance for
Responsible Parties in the event of a PCB release. The EPA determines the extent
and adequacy of a PCB cleanup. Additional information on the PCB Clean-Up
Policy can be referenced in 40 CFR sections 761.120 through 761.135.

Proper packaging, marking, labeling, manifesting, and record-keeping requirements
for the transportation  of PCBs and PCB items off site for storage and disposal

TSCA, DOT and OSHA regulations govern the types of containers that may
properly be used for the transportation and storage of PCB wastes. TSCA packaging
regulations for PCBs are specified in 40 CFR 761.65 (c). TSCA packaging
regulations also reference OSHA packaging regulations specified in 29 CFR
1910.106, "Flammable and Combustible Liquids."  DOT packaging regulations for
PCBs are specified in 49 CFR sections 172.102 (9), 172.102 (N81), 173.155,
173.202, and 173.241. In general, PCB liquids should be packaged in DOT-approved
steel drums with a closed head (UN 1A1) and PCB solids (such as contaminated soil
or debris) should be packaged in DOT-approved steel drums with an open head (UN
IA2). All PCB packaging regulations provide for the use of alternate containers, if
necessary, that protect against leaks and exposure to the environment. In some
cases, a PCB article may itself be used as a transportation and storage package. If
DOT-specified drums for PCB liquids and solids are impractical, the DOT and
TSCA regulations must be referenced for further guidance.

All PCB articles and containers, storage areas, and transportation vehicles, which have
been loaded with one or more  PCB transformers or with more than 45 kilograms of
PCBs in the liquid phase, must be properly marked according to TSCA regulations.
Two types of PCB markings are defined by TSCA.  The large PCB mark is referred to
as ML and is depicted in Figure 8-5. ML must be 6 inches by 6 inches if the item can
accommodate the size. ML may be reduced to a minimum of 2 inches by 2 inches.  If
the PCB item can not accommodate the 2 square inch ML, the small PCB mark, Ms,
must be used.  Ms is depicted in Figure 8-6.  The standard Ms is 1 inch by 2 inches. Ms
may be reduced to 0.4 inches by 0.8 inches if necessary.
40 CFR
Toxic
Substances
Control Act
Part 761
Polychlonnated
biphenyls
(PCBs)
manufacturing,
processing,
distribution in
commerce, and
use prohibitions
Subpart D -
Storage and
Disposal

761.65 Storage
for disposal
                                              72

-------
 Specialty Wastes

                                      CONTAINS
                                PCBs
                                
-------
Specialty Wastes
Certificate of Disposal within 30 days of the date the PCB waste was actually
disposed of.  The Certificates of Disposal indicate the date and disposal process used
for each waste manifested to the facility.
Subchapter IV: Explosive and Shock Sensitive Substances

An explosive substance is any material that undergoes change such as to cause the
extremely rapid release of gas and heat. A mass explosion is a blast that affects
almost the entire load instantaneously. Shock waves generated by the blast,
fragment projectiles and fire are the hazards associated with explosive substances.

A large variety of chemical compounds present explosion hazards.  Many organic
nitro, nitroso and nitroamine compounds, nitrates, fulminates, azides, chlorates,
perchlorates, picrates, picryl, picric compounds, and organic peroxides are
explosive. A large variety of other chemicals form unstable, shock sensitive,
explosives upon exposure to air and/or light.  Some examples of compounds that
form unstable explosives are isopropyl ether, ethyl ether, vinyl ethers, dioxanes,
tetrahydrofuran, cyclohexene, butadiene, styrene monomer, vinyl acetate monomer,
potassium amide and sodium amide.

The hazardous properties of all substances discovered on a site must be researched
before the onset of site operations.  The handling of explosive and shock sensitive
wastes is extremely dangerous and should only be attempted by trained specialists
with the appropriate equipment.

Upon discovery of suspected explosive wastes on a  site, the local bomb squad
should be contacted to evaluate the situation. Local bomb squads are often capable
of transporting small quantities of explosives to a detonation site for disposal. If the
local bomb squad is unable to properly handle and dispose of the material, the
feasibility of on-site treatment or on-site detonation can be evaluated. DOT
regulations forbid the transportation of many unstable explosive materials. Thus,
the option of off-site disposal of explosive wastes at a commercial TSD is limited.

On-site detonation is complicated by the need for proper geographical and
environmental conditions, safety concerns, pre-detonation and post-detonation
sampling and analysis to evaluate decomposition products, and permit requirements.
On-site detonations can only be performed by specialists with a blasting license.

On-site treatment involves the stabilization of the material for transportation and off-
site disposal. Most explosive compounds can be stabilized by dissolving the
substance in a suitable  solvent. The resulting mixture can then be safely  transported
to a RCRA-permitted TSD  for incineration. On-site treatment should only be
performed by specialists with remote opening equipment. Opening a container of an
explosive material generates friction; friction can detonate unstable explosive
compounds.
761.207
The manifest -
general
requirements
761.218
Certificate of
Disposal
                                               74

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 Specialty Wastes
 Subchapter V: Radioactive Wastes

 Radioactive substances emit three types of atomic energy: alpha particles, beta
 particles and gamma rays.  Alpha particles are identical to the nucleus of a helium
 atom and are considered to be large atomic particles. Alpha particles travel less than
 one inch from the source and can be blocked with a sheet of paper. Beta particles,
 which are electrons from an atom, travel a few inches and can be blocked with a
 sheet of aluminum foil. Gamma rays are electromagnetic waves that travel large
 distances and can penetrate even dense material.

 Survey instruments available to screen for radiation on a site measure milli-
 Roentgens/hour (mR/hr). A Roentgen is a radiation dose unit in air. Typical
 background gamma radiation is 0.02 mR/hr. EPA protocol dictates that when
 radiation levels exceed three to five times background level, personnel must leave
 the area and the Regional Radiation Safety Officer must be contacted to evaluate the
 site conditions and determine proper employee protection and monitoring
 requirements to comply with worker safety regulations. The Nuclear Regulatory
 Commission (NRC) regulates worker exposure to radiation on a short-term basis
 (less than a day), a yearly basis, and a lifetime exposure basis.

 RCRA regulations under the EPA specifically exclude radioactive source, special
 nuclear and by-product materials as defined by the Atomic Energy Act (AEA) of
 1954, as amended, from solid and hazardous waste regulations.  The NRC regulates
 radioactive wastes under the AEA.  However, both the EPA under RCRA and the
 NRC under AEA regulate "mixed wastes." Mixed wastes are defined as radioactive
 wastes that contain a RCRA-regulated hazardous waste component.  The radioactive
 component within a mixed waste is subject to AEA regulations, while the hazardous
 waste components are subject to RCRA regulations. RCRA regulations of the
 hazardous waste component of a mixed waste also include land disposal restrictions.
 If RCRA and AEA regulations are inconsistent, AEA regulations under the NRC
 take precedence. NRC regulations under the AEA can be referenced in 10 CFR.

 Several commercial TSDs are authorized under both RCRA and AEA to treat and
 dispose of low level mixed  wastes.  The Regional Radiation Safety Officer and
 radioactive wastes specialists must be consulted prior to treatment and disposal of
 radioactive or mixed wastes.

Reference:

     1.  Low-Level Mixed Wastes: A RCRA Perspective for NRC Licensees;
     EPA/530-SW 90-47, August 1990, Office of Solid Waste and Emergency
     Response.
                                             75

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Specialty Wastes
                                  [THIS PAGE INTENTIONALLY LEFT BLANK]
                                    76

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                                      APPENDIX 1
     EXAMPLE OF DISPOSAL EVALUATION AND HANDLING PROCEDURES
                           FOR UNKNOWN DRUM WASTES
 Site Waste Evaluations, Characterizations and Classifications

 In this example, nine drums are discovered near mile marker 555 on Route 621 in Superfund,
 Philadelphia County, VA. Drum numbers are assigned and container information is documented. A
 representative sample is collected from each drum (see Chapter 5 for proper sampling guidance). The
 drum samples are men evaluated using field haz-cat testing procedures (see Chapter 6, Subchapter TO).
 Container information, sample testing results and haz-cat descriptions for each drum are as follows:

 Drum Number: 01
 Container description:                       55-gallon poly drum
 Air monitoring data:                        no readings above background
 Sample description:                         single phase, light yellow liquid
 Water reactive/pH:                         pH = 2
 Oxidizer:                                 negative
 Water soluble:                             yes
 Hexane soluble:                           no
 Halogens:                                not applicable
 CN:                                     negative
 S:                                       negative
 Ignitability:                               non-ignitable

 Haz-cat waste classification: single phase, inorganic, corrosive acid, liquid

 Drum Number: 02
 Container description:                      55-gallon poly drum
 Air monitoring data:                        no readings above background
 Sample description:                        single phase, light yellow liquid
 Water reactive/pH:                         pH = 2
 Oxidizer:                                 negative
 Water soluble:                             yes
 Hexane soluble:                           no
 Halogens:                                not applicable
 CN:                                      negative
 S:                                       negative
Ignitability:                               non-ignitable

Haz-cat waste classification: single phase, inorganic, corrosive acid, liquid

Drum Number: 03
Container description:                      55-gallon poly drum
Air monitoring data:                        no  readings above background
Sample description:                        single phase, light yellow liquid

-------
Appendix 1
Water reactive/pH:                          pH = 2
Oxidizer:                                   positive
Peroxide:                                   negative
Water soluble:                              yes
Hexane soluble:                             no
Halogens:       '                           not applicable
CN:                                       negative
S:                                         negative
Ignitability:                                 non-ignitable

Haz-cat waste classification: single phase, inorganic, corrosive acid, oxidizer, liquid

Drum Number: 04
Container description:                        55-gallon steel, open head drum
Air monitoring data:                         PID 5 units
Sample description:                          bilayer: 80% top gray liquid
                                                  20% bottom gray sludge
Phases/layers:                               top (liquid)            bottom (solid)
Water reactive/pH:                          pH= 12               pH=14
Oxidizer:                                   negative              negative
Water soluble:                              yes                   no
Hexane soluble:                             no                   yes
Halogens:                                  negative              negative
CN:                                       negative              negative
S:                                         negative              negative
Ignitability:                                 non-ignitable          non-ignitable

Haz-cat waste classification: inorganic, corrosive base, sludge (80% liquid, 20% solid)

Drum Number: 05
Container description:                        55-gallon steel, open head drum
Air monitoring data:                         PID 5 units
Sample description:                          bilayer: 50% top gray liquid
                                                  50% bottom gray sludge
Phases/layers:                               top(liquid)            bottom (solid)
Water reactive/pH:                          pH=12               pH=14
Oxidizer:                                   negative              negative
Water soluble:                              yes                   no
Hexane soluble:                             no                   yes
Halogens:                                  negative              negative
CN:                                       negative              negative
S:                                         negative              negative
Ignitability:                                 non-ignitable          non-ignitable

Haz-cat waste classification: inorganic, corrosive base, liquid/sludge (50% liquid, 50 % solid)

Drum Number: 06
Container description:                        55-gallon steel, closed head drum
Air monitoring data:                         LEL 25%, PID 500 units
Sample description:                         single phase, yellow liquid
                                             78

-------
Appendix 1
Water reactive/pH:                         pH=7
Oxidizer:                                  negative
Water soluble:                             no
Hexane soluble:                            yes
Halogens:                                 negative
CN:                                      negative
S:                                        negative
Ignitability:                                flammable

Haz-cat waste classification: single phase, organic, flammable liquid

Drum Number: 07
Container description:                       55-gallon steel, closed head drum
Air monitoring data:                        LEL 20%, PID 700 units
Sample description:                         single phase yellow liquid
Water reactive/pH:                         pH=7
Oxidizer:                                  negative
Water soluble:                             no
Hexane soluble:                            yes
Halogens:                                 negative
CN:                                      negative
S:                                        negative
Ignitability:                                flammable

Haz-cat waste classification: single phase, organic, flammable liquid

Drum Number: 08
Container description:                       55-gallon steel, closed head drum
Air monitoring data:                        LEL 15%, PID 300 units
Sample description:                         bilayer: 80% top yellow liquid
                                                 20% bottom brown liquid
Phases/layers:                              top (liquid)            bottom (liquid)
Water reactive/pH:                         pH=7                 pH=7
Oxidizer:                                  negative              negative
Water soluble:                             no                   no
Hexane soluble:                            yes                  yes
Halogens:                                 negative              negative
CN:                                      negative              negative
S:                                        negative              negative
Ignitability:                                flammable            combustible

Haz-cat waste classification: bilayer organic, 80% flammable liquid, 20% combustible liquid

Drum Number: 09
Container description:                       55-gallon steel, closed head drum
Air monitoring data:                        LEL 17%, PID 200 units
Sample description:                         bilayer:  80% top viscous brown liquid
                                                  20% bottom yellow liquid1
Phases/layers:                              top liquid)            bottom (liquid)
Water reactive/pH:  .                       pH=7                 pH=6
                                           . 79

-------
Appendix 1
Oxidizer:
Water soluble:
Hexane soluble:
Halogens:
PCBs:
CN:
S:
Ignitability:
negative
no
yes
negative
negative
negative
negative
combustible
negative
no (sinks)
no (sinks)
positive
positive
negative
negative
non-ignitable
Haz-cat waste classification: bilayer organic liquid, 80% combustible liquid, 20% halogenated liquid
                          (possible PCB)

Determination of Preliminary Wastestreams

Small quantities of samples having the same haz-cat waste classification are mixed to determine chemical
compatibility and preliminary wastestreams (see Chapter 6, Subchapter IE). All samples with the same
haz-cat classifications that are chemically compatible are assigned to a preliminary wastestream.

•   Single phase, inorganic, corrosive acid liquid samples (drums 01 and 02) are determined to be .
    compatible, and the preliminary wastestream description single phase, inorganic corrosive acid liquid
    100% is assigned to drums 01 and 02.

•   Inorganic corrosive acid oxidizer. liquid 100% is the preliminary wastestream description for drum
    03; none of the other drums meet this classification.

•   Inorganic, corrosive base, liquid/sludge samples (drums 04 and 05) are determined to be compatible,
    and the preliminary waste stream description inorganic, corrosive base liquid-/sludize (50 - 80%
    liquids 20 - 50% solids') is assigned to drums 04 and 05.

•   Organic, flammable liquid samples (drums 06 and 07) are determined to be compatible,  and
•   the preliminary wastestream description single phase, organic, flammable liquid. 100% is
•   assigned to drums 06 and 07.

•   Oreanic. 80% flammable liquid. 20% combustible liquid is the preliminary wastestream
•   description for drum 08; none of the other drums meet this classification.

•   Bi-laver organic liquid. 80% combustible liquid. 20% halogenated liquid - (possible PCS') is the
    preliminary wastestream description for drum 09; none of the other drums meet this classification.

Treatment Options Based on Preliminary Wastestream Determinations

Treatment options are evaluated for each preliminary wastestream description (see Chapter 6, Subchapter
IV) for treatment option selections. Preliminary wastestream descriptions and associated treatments for
this site are as follows:

•   Inorganic, corrosive acid, liquid, 100%
       drums 01 and 02
       wastewater treatment

                                              80

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 Appendix 1
 •  Inorganic, corrosive acid, oxidizer, liquid, 100%
        drum 03
        wastewater treatment

 •  Inorganic, corrosive base, sludge
        50 - 80% liquid, 20 - 50% solid
        drums 04 and 05
        liquid: wastewater treatment
        solid: stabilization

 •  Organic flammable liquid, 100%
        drums 06 and 07
        thermal destruction: possible fuels blending

 •  Bilayer organic liquid
        80% flammable liquid, 20% combustible liquid
        drum 08
        thermal destruction (possible fuels blending)

 •  Bilayer organic liquid
        80% combustible liquid, 20% halogenated liquid
        drum 09
        thermal destruction: incineration

 Determination of Final Waste Stream Descriptions Based on Treatment Technologies (see
 Chapter 6, Subchapter IV.)

Because the  descriptions of drums 06,07, and 08 are similar for disposal purposes and because they will
each undergo the same treatment, samples of drums 06, 07, and 08 are tested for compatibility. The tests
show that these samples are chemically compatible, and so the preliminary wastestream descriptions for
these samples are combined into a new wastesteam description: Organic flammable/combustible liquids
(80 - 100% flammable liquid. 0 - 20% combustible liquid). No other preliminary wastestream
descriptions  can be combined based on treatment standard, thus all other preliminary wastestream
descriptions become final wastestream descriptions.

Selection of Disposal Analysis Parameters

Analysis parameter are selected based on the waste stream description, the treatment option for the waste
stream description and characteristics of the waste (see Chapter 6, Subchapter V).  Analysis parameters
for the wastes in this example are as follows:

•   Inorganic, corrosive acid, liquid, 100%
       Sample SC001 (drums 01 and 02)
       Wastewater treatment
       Analysis  parameters: % water, % solids, TOC, TOX, CN-, S-, pH, PCBs, total metals,
       halogen ions (optional).
       If TOX < 0.05, no additional analysis.
       If TOX > 0.05, analyze for VOCs and BNAS.
                                             81

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Appendix 1
•   Inorganic, corrosive, oxidizer, liquid, 100%
       Sample SC002 (drum 03)
       Wastewater treatment
       Analysis parameters: % water, % solids, TOC, TOX, CN-, S-, pH, PCBs, total metals, nitrogen
       and phosphorous ions (optional).
       If TOX < 0.05, no additional analysis.
       If TOX > 0.05, analyze for VOC and BNAS.

•   Inorganic, corrosive base, liquid/sludge
    Separate solids from liquids
       Composite SC003A solids (solids from drums 04 and 05)
              Stabilization
              Analysis parameters: % solid, TOC, TOX, pH, PCBs, TCLP RCRA list.
       Composite SC003B liquids (liquids from drums 04 and 05)
              Waste water treatment
              Analysis parameters: % water, % solids, TOC, and TOX. Metals and organic
              contamination can be assigned from sludge results (SC003A).

•   Organic, flammable/combustible liquid
       80 - 100% flammable liquid
       0 - 20% combustible liquid
       SC004 (drums 06, 07, and 08)
       Fuels blending
       Analysis parameters: % water, % solids, TOC, TOX, CN-, S-, pH, PCBs, BTU, Fp, Bp, % ash,
       total metals, VOC and BNAS.

•   Halogenated organic liquid
       80% combustible liquid
       20% halogenated liquid
       SC005 (drums 09)
       Incineration
       Analysis parameters: % water, % solids, TOC, TOX, CN-, S-, pH, PCBs, BTU, Fp, Bp, % ash,
       total metals, VOC and BNAS.

Enough sample from each drum is then collected to obtain one 16-ounce sample and two 8-ounce
samples for each wastestream. The 16-ounce wastestream sample (a composite sample for wastestreams
containing several drums) is sent to a laboratory to obtain the needed analysis results.  The 8-ounce
wastestream samples are maintained to meet future facility treatability study and/or additional laboratory
analysis requirements.

Interpretation of Disposal Analysis Results

The results from laboratory analysis of the wastestream samples and the interpretation of
the results to account for sample compositing (see Chapter 6, Subchapter V) are listed as follows:
                                             82

-------
Appendix 1
Sample SC001 (composite of drums 01 and 02): Inorganic, corrosive acid liquids
       Parameter
       % water
       % solids
       TOC
       TOX
       Cyanide (CN-)
       Sulfide (S-)
       PH
       PCBs
       Halogen ions:

             Chlorine
             Fluorine
             Bromine
             Iodine

       Total metals:
             Antimony
             Arsenic
             Beryllium
             Cadmium
             Chromium
             Copper
             Lead
             Mercury
             Nickel
             Selenium
             Silver
             Zinc
Results
90%
 - V/*W J. / V
< 0.01%
< Ippm
25 ppm
1.6
< 1 ppm


50,000 ppm
< 100 ppm
< 100 ppm
< 100 ppm


< 0.5 ppm
0. 8 ppm
< 0.5 ppm
0.2 ppm
200 ppm
30 ppm
 1,300 ppm
< 0.02 ppm
< 25 ppm
< 0.5 ppm
 < 0.5 ppm
900 ppm
Possible/drum
80 to 100%
<2%
< 0.02%
< 0.02%
<2ppm
0 to 50 ppm
Ito3
<2ppm
                   0 - 100,000 ppm
                   < 200 ppm
                   < 200 ppm
                   < 200 ppm
                   < 1.0 ppm
                   < 1. 6 ppm
                   <  1.0 ppm
                   <  0.4 ppm
                   <  400 ppm
                   < 60 ppm
                   < 2,600 ppm
                   < 0.04 ppm
                   < 50 ppm
                   < 1. 0 ppm
                   < 1. 0 ppm
                   < 1,800 ppm
                                          83

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Appendix 1
Sample SC002 (sample of drum 3) Inorganic, corrosive oxidizer liquid
       Parameter
       % water
       % solids
       TOC
       TOX
       Cyanide
       Sulfide
       PH
       PCBs
       Nitrogen
       Phosphorous
       Total Metals:
             Antimony
             Arsenic
             Beryllium
             Cadmium
             Chromium
             Copper
             Lead
             Mercury
             Nickel
             Selenium
             Silver
             Zinc
Results
88%
< 1.2%
< 0.02%
< 1 ppm
120 ppm
1.1
< 1 ppm
88,000 ppm
7, 587 ppm

< 0.5 ppm
6.4 ppm
< 0.5 ppm
0.7 ppm
56 ppm
71 ppm
2, 857 ppm
< 0.02 ppm
< 25 ppm
< 0.5 ppm
< 0.5 ppm
530 ppm
Possible/drum
same, only one sample
                                          84

-------
--ft 	
Sample SC003A (composite of solids from drums 04 and 05) Inorganic, corrosive base, sludge
Parameter
% water
% solids
TOC
TOX
Cyanide
Sulfide
pH
PCBs
TCLP RCRA VGA compounds:
Vinyl chloride
1 , 1 -Dichloroethene
Chloroform
1 ,2-Dichloroethane
Carbon tetrachloride
Trichloroethene
Benzene
2-Butanone
Tetrachloroethene
Chlorobenzene
BNA Compounds:
Pyridine
1 ,4-Dichlorobenzene
Hexachloroethane
2-Methylphenol0.08 ppm
3&4 Methylphenol
Hexachlorobutadiene
Nitrobenzene < 0.01 ppm
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2,4-Dinitrotoluene
Hexachlorobenzene
Pentachlorobenzene
Pesticide compounds:
Lindane
Heptachlor
Heptachlor epoxide
Endrin
Chlordane
Toxaphene
Methoxychlor
Herbicide compounds:
2,4-D
2,4,5 TP (Silvex)
Metals:
Arsenic
Barium
Cadmium
Results
11%
< 89%
1.2%
< 0.01 %
< 1 ppm
3 ppm
13.2
< 1 ppm

< 0.01 ppm
< 0.01 ppm
< 0.01 ppm
0.6 ppm
< 0.01 ppm
1.8 ppm
2.4 ppm
0.8 ppm
5.2 ppm
0.3 ppm

< 0.01 ppm
0.07 ppm
< O.Olppm
< 0.1 6 ppm
0.03 ppm
< 0.01 ppm
< 0.02 ppm
< 0.01 ppm
< 0.01 ppm
< 0.01 ppm
< 0.01 ppm
< 0.01 ppm

< 0.01 ppm
< 0.0001 ppm
< 0.0001 ppm
< 0.01 ppm
< 0.01 ppm
<0.01 ppm
< 0. 1 ppm

< 1.0 ppm
<0.1 ppm

< 0. 1 ppm
20 ppm
8.0 ppm
Possible/drum
0-22 %
• 78 - 100%
< 2.4 %
< 0.02%
<2ppm
< 6 ppm
13- 14
<2ppm

< 0.02 ppm
< 0.02 ppm
< 0.02 ppm
< 1.2 ppm
< 0.02 ppm
< 3. 6 ppm
< 4.8 ppm
< 1 .6 ppm
< 10.4 ppm
< 0.6 ppm

< 0.02 ppm
< 0. 14 ppm
< 0.02 ppm

< 0.06 ppm
< 0.02 ppm

< 0.02 ppm
< 0.02 ppm
< 0.02 ppm
< 0.02 ppm
< 0.02 ppm

< 0.02 ppm
< 0.0002 ppm
< 0.0002 ppm
.^ /\ f\ 1
< 0.0 1 ppm
< 0.02 ppm
< 0.02 ppm

-------
Appendix 1
Sample SC003A (composite of solids from drums 04 and 05) Inorganic, corrosive base, sludge

      Parameter                       Results             Possible/drum
      Metals (cont'd.):
             Chromium                 6.3 ppm             < 12.6 ppm
             Lead                      12.4 ppm            < 24.8 ppm
             Mercury                   < 0.1 ppm           < 0.2 ppm
             Selenium                  < 0.1 ppm           < 0.2 ppm
             Silver                     < 0.1 ppm           < 0.2 ppm

Sample SC003B (composite of solids from drums 04 and 05) Inorganic, corrosive base, liquid

      Parameter                       Results             Possible/drum
      % Water                         81%               70-90%
      % Solids                         < 6%               < 12%
      TOC                            4.6%               < 9.2 %
      TOX                            0.02%              < 0.04%
      pH                              13.2                13 -14
      PCBs                            < 1 ppm             < 2 ppm
      Flashpoint                       > 140°F             > 140°F
      Boiling point                      > 120°F             > 120°F

NOTE: Refer to SC003A for TCLP results for specific compounds
                                          86

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Appendix 1
Sample SC004 (composite of solids from drums 06,07, and 08) Flammable/combustible liquid
(NOTE: For this example, assume all pesticide values are below the detection limit.)

      Parameter                       Results              Possible/drum
      % water                          2%                 < 6%
      % solids                          <1%                <3%
      TOC                             96%                90 -100%
      TOX                             2.3%                < 6.9 %
      pH                              7                   6-8
      PCBs                            < 1 ppm             < 3 ppm
      Flashpoint                       80°F                70-90°F
      Boiling point                      100°F               100 - 120°F
      BTU                             21,756 BTU/P         15,000-25,000
      Ash                             4%                 < 10%
      VOA Compounds:
             1,1,1 -Trichloroethane         3.6 ppm             < 11 ppm
             Benzene                   360 ppm             < 1000 ppm
             Tetrachloroethene           46 ppm              < 150 ppm
             Toluene                   14,000 ppm          1 - 4 %
             Ethylbenzene               8,700 ppm           0.9 - 3 %
             Xylenes (total)              38,000 ppm          3 -10%
             n-Propylbenzene            980 ppm             < 3000 ppm
             1,3,5-Trimethylbenzene       3,500 ppm           < 1%
             Naphthalene                76 ppm              < 250 ppm
      (NOTE: For this example, assume VOA compounds that are not listed have values below the
      detection limit.)
      BNA Compounds:
             Naphthalene                85 ppm              < 250 ppm
             Fluorene                   130 ppm             < 400 ppm
             Phenanthrene               140 ppm             < 400 ppm
             Anthracene                86 ppm              < 250 ppm
             Fluoranthene               230 ppm             < 700 ppm
             Pyridine                   410 ppm             < 1300 ppm
             Chrysene                  95 ppm              < 300 ppm
             Phenol                    330 ppm             < 1000 ppm
      (NOTE: For this example, assume BNA compounds that are not listed have values below the
      detection limit.)
      Metals:
             Antimony                 < 0.5 ppm           < 1.5 ppm
             Arsenic                   1.2 ppm             < 3.6 ppm
             Beryllium                 < 0.5 ppm           < 1.0 ppm
             Cadmium                 4.2 ppm             < 12.6 ppm
             Chromium                 85 ppm              < 250 ppm
             Copper                   40 ppm              < 120 ppm
             Lead                      800 ppm             < 2,400 ppm
             Mercury                   < 0.02 ppm          < 0.06 ppm
             Nickel                    < 25 ppm            < 150 ppm
             Selenium                  < 0.5 ppm           < 1.5 ppm
             Silver                     < 0.5 ppm           < 1.5 ppm
             Zinc                      250 ppm             < 750 ppm

                                          87

-------
Appendix 1
Sample SC005 (sample of drum 09) Combustible/halogenated liquids
       Parameter
       % water
       Solids
       TOC
       TOX
       PH
       PCBs
       Flashpoint
       Boiling point
       BTU
       Ash
       VOA Compounds:
              Methylene chloride.
              1,1,1 -Trichloroethane
              1,1 -Dichloroethene
              1,1 -Dichloroethane
              2,2-Dichloropropane
              1,2-Dichloroethane
              Carbon tetrachloride
              Trichloroethene
              1,1,2-Trichloroethane
              1,1,1,2-Tetrachloroethane
              1,1,2,2-Tetrachloroethane
              Benzene
              Tetrachloroethene
              Toluene
              Ethylbenzene
              Xylenes (total)
              n-Propylbenzene
              Naphthalene
       (NOTE: For this example, assume
       detection limit.)
       BNA Compounds:
              Hexachloroethane
              1,2,4-Trichlorobenzene
              Naphthalene
              Fluorene
              Phenanthrene
              Anthracene
              Fluoranthene
              Pyridine
              Chrysene
              Phenol 90ppm
       (NOTE: For this example, assume
       detection limit.)
                         Possible/drum
                         same, only one sample
Results
5%
1.3%
93%
15%
7
26ppfn
120°F
150°F
7,000 BTU/P
9%
     8000 ppm
     6000 ppm
     800 ppm
     700 ppm
     600 ppm
     3000 ppm
     900 ppm
     400 ppm
     4000 ppm
     2000 ppm
     1500 ppm
     120 ppm
     889 ppm
     145 ppm
     34 ppm
     255 ppm
     10 ppm
     988 ppm
VOA compounds that are not listed have values below the
     700 ppm
     400 ppm
     822 ppm
     340 ppm
     966 ppm
     555 ppm
     860 ppm
     300 ppm
     120 ppm

BNA compounds that are not listed have values below the
                                           88

-------
Appendix 1
Sample SC005 (sample of drum 09) Combustible/halogenated liquids

       Parameter                        Results             Possible/drum
       Metals:
              Antimony                  < 0.5 ppm           same, only one sample
              Arsenic                    < 0.5 ppm
              Beryllium                  < 0.5 ppm
              Cadmium                  < 0.5 ppm
              Chromium                 < 0.5 ppm
              Copper                    43 ppm
              Lead                      560 ppm
              Mercury                   < 0.02 ppm
              Nickel                     < 25 ppm
              Selenium                   < 0.5 ppm
              Silver                     < 0.5 ppm
              Zinc                      12 ppm
       (NOTE: Pesticide compounds - For this example, assume all pesticide values are
       below the detection limit.)
RCRA Hazardous Waste Classifications (See Chapter 1, Subchapter I)

RCRA hazardous waste classifications (codes) are assigned to each wastestream according
to the properties of the waste and the hazardous constituents in the waste as follows:

Inorganic corrosive liquids, sample SC001, drums 01 and 02
       D002  pH < 2
       D007  Chromium > 5 ppm
       D008  Lead > 5 ppm

Inorganic corrosive oxidizer liquid, sample SC002, drum 03
       D001  Oxidizer
       D002  Corrosive acid
       D004  Arsenic > 5 ppm
       D007  Chromium > 5 ppm
       D008  Lead > 5 ppm

Inorganic corrosive base, liquid/sludge, sample SC003A and SC003B, drums 04 and 05
       D002  Corrosive base
       D006  Cadmium > 1 ppm
       D007  Chromium > 5 ppm
       D008  Lead > 5 ppm
       DO 18  Benzene > 0.5 ppm
       D028  1,2-Dichloroethane > 0.5 ppm
       D039  Tetrachloroethylene > 0.7 ppm
       D040  Trichloroethylene > 0.5 ppm

Organic, flammable/combustible liquids, sample SC004, drums 06, 07, and 08.
       D001  Flash point <140°F
       D006  Cadmium > 1 ppm
                                           89

-------
Appendix 1
       D007  Chromium > 5 ppm
       D008  Lead > 5 ppm
       DO 10  Selenium > 1 ppm
       DO 18  Benzene > 0.5 ppm
       D039  Tetrachloroethene > 0. 7 ppm
       F002  1,1,1 -Trichloroethane, tetrachloroethane and F005 solvents
       F003  Ethylbenzene, xylene, and F002 and F005 solvents
       F005  Benzene, toluene, pyridine and F002 solvents

Organic combustible/halogenated liquid, sample SC005, drum 09
       D001  Flash point <140°F
       D008  Lead > 5 ppm
       DO 18  Benzene > 0.5 ppm
       D019  Carbon tetrachloride > 0.5 ppm
       D028  l,2,Dichloroethane>0.5ppm
       D034  Hexachloroethane > 3.0 ppm
       D039  Tetrachloroethene > 0.7 ppm
       D040  Trichloroethylene > 0.5 ppm
       F002  Tetrachloroethylene, methylene chloride, trichloroethene, 1,1,1 -trichloroethane,
       1,1,2-trichloroethane and F005 solvents
       F003  Xylene, ethylbenzene and F002 and F005 solvents
       F005  Toluene, pyridine, benzene and F002 solvents

NOTE: As of this writing, none of the states in Region III require the use of state hazardous waste codes.
       However, the state in which the designated treatment and disposal facility is located may require
       the use of state hazardous waste codes. Always check with the receiving state for additional
       state requirements.

RCRA Land Disposal Restrictions Notifications (LDRS) - See Chapter 1, Subchapter D

The following LDR references must be supplied to the TSD for each shipment of waste.

Inorganic corrosive liquids, sample SC001, drums 01 and 02 (wastewater)
       D002  Acid pH < 2                               40 CFR 268.42, Table 2
       D007  Chromium > 5 ppm                        40 CFR 268.43, Table CCW
       D008  Lead > 5 ppm                             40 CFR 268.43, Table CCW

Inorganic corrosive oxidizer liquid, sample SC002, drum 03  (nonwastewater)
       D001  Oxidizer                                  40 CFR 268.42, Table 2
       D002  Corrosive acid                             40 CFR 268.42, Table 2
       D004  ArseniOSppm                           40 CFR 268.42, Table CCWE
       D007  Chromium > 5 ppm                        40 CFR 268.42, Table CCWE
       D008  Lead > 5 ppm                             40 CFR 268.42, Table CCWE

Inorganic corrosive base, liquid/sludge, sample SC003A and SC003B, drums 04 and 05 (nonwastewater)
       D002  Corrosive base 40 CFR 268.42, Table 2
       D006  Cadmium > 1 ppm                         40 CFR 268.42, Table CCWE
       D007  Chromium > 5 ppm                        40 CFR 268.42, Table CCWE
       D008  Lead > 5 ppm                             40 CFR 268.42, Table CCWE
       DO 18  Benzene > 0.5 ppm                        none

                                            90

-------
Appendix 1
       D028  l,2-Dichloroethane>0.5ppm               none
       D039  Tetrachloroethylene > 0.7 ppm               none
       D040  Trichloroethylene > 0.5 ppm                none

Organic, flammable/combustible liquids, sample SCO04, drums 06, 07, and 08 (nonwastewater)
       D001        Flashpoint < 140°F               40 CFR 268.42, Table 2
       D006        Cadmium > 1 ppm               40 CFR 268.41, Table CCWE
       D007        Chromium > 5 ppm              40 CFR 268.41, Table CCWE
     .  D008        Lead > 5 ppm                   40 CFR 268.41, Table CCWE
       DO 10        Selenium > 1  ppm                none
       DO 18        Benzene > 0.5 ppm               none
       D039        Tetrachloroethene > 0.7 ppm       none
       F002        1,1,1-Trichloroethane             0.41 ppm
                    Tetrachloroethane                0.05 ppm
       F003        Ethylbenzene                    0.053 ppm
                    Xylene                         0.15 ppm
       F005        Benzene                        3.7 ppm
                    Toluene                         0.33 ppm
                    Pyridine                         0.33 ppm

Organic combustible/halogenated liquid, sample SC005, drum 09 (nonwastewater)
             D001           Flash point < 140°F           40.CFR 268.42, Table 2
             D008           Lead > 5 ppm               40 CFR 268.42, Table CCWE
             DO 18           Benzene > 0.5 ppm           none
             DO 19           Carbon tetrachloride > 0.5 ppm none
             D028           1,2,  Dichloroethane > 0.5 ppm  none
             D034           Hexachloroethane>3.0ppm   none
             D039           Tetrachloroethene > 0.7 ppm   none
             D040           Trichloroethylene > 0.5 ppm   none
             F002           Tetrachloroethylene           0.05 ppm
                            Methylene chloride           0.96 ppm
                            Trichloroethene              0.091 ppm
                            1,1,1-Trichloroethane         0.41 ppm
                            1,1,2-Trichloroethane         7.6 ppm
             F003           Xylene                     0.15 ppm
                            Ethylbenzene           .     0.053 ppm
             F005           Toluene                    0.33 ppm
                            Pyridine                    0.33 ppm
                            Benzene                    3.7 ppm

DOT Shipping Descriptions, Labels, Markings, and Packaging (See Chapter 2)

The DOT Hazardous Materials Table (HMT) in 49 CFR 172. 101 is consulted to determine the proper
shipping name, labels, and packaging references for each wastestream (See Chapter 2, Subchapter II for
shipping names and use the HMT; see Chapter 2 Subchapter III for packaging regulations). Additional
container marking requirements for each wastestream are also listed below (See Chapter 2, Subchapter
IV).
                                            91

-------
Appendix 1
Wastestream: Inorganic corrosive liquids, Drums 01 and 02
       RQ, Waste Corrosive Liquid, n.o.s. (contains spent hydrochloric acid), 8, UN 1760, PGn (D002)
       Labels: Corrosive
       Markings:   Hazardous waste label and "this end up"
       Packagings: 49 CFR 173.202

Wastestream: Inorganic corrosive oxidizer liquid, Drum 03
       RQ, Waste Corrosive Liquid, Oxidizing, n.o.s. (contains dilute, spent nitric and phosphoric
       acids), 8, UN3093, PGH, (D002) (D001)
       Labels: Corrosive, oxidizer
       Markings: Hazardous waste label and "this end up"
       Packaging: 40 CFR 173.202

Wastestream: Inorganic corrosive base, liquid/sludge, drums 04 and 05
       RQ, Waste Corrosive Liquid, n.o.s. (contains spent sodium hydroxide solution and sludge), 8,
       UNI760, PGII (DO02)
       Labels: Corrosive
       Markings: Hazardous waste label and "this end up"
       Packaging: 49 CFR 173.202

Wastestream: Organic, flammable/combustible liquids, Drums 06, 07, and 08
       RQ, Waste Flammable Liquid, n.o.s. (spent solvents including benzene and toluene), 3,
       UN1993,PGII,(D001)
       Labels: Flammable liquid
       Markings: Hazardous waste label and "this end up"
       Packagings: 409 CFR 173.202

Wastestream: Organic combustible/halogenated liquid, Drum 09
       RQ, Waste Flammable Liquid, n.o.s. (contains petroleum hydrocarbons and halogenated
       solvents), 3, UN1993, PG HI, (DO01)
       Labels: Flammable liquid
       Markings: Hazardous waste label and "this end up"
       Packagings: 49 CFR 173.203

The Waste Profile

Once all regulatory information is obtained for each Wastestream and the RCRA permitted disposal
facility has been contracted, all information which describes the waste is completed on the designated
facility's waste profile form.  The designated facility will then assign a profile number or waste approval
number to each profile (see Chapter 4, Subchapter I).  The profile number must then be added to each
drum to be shipped. A commercial TSD's profile form is used in this manual to provide the user with an
example of a waste profile. It should be noted that each facility's form is unique, but all such forms
generally require the same information.  The specific profile form in  this manual is used solely to provide
an example and is based on a randomly selected form from a variety  of commercial TSD waste profile
forms. The use of this form in this example in no way endorses or recommends the use of the TSD that
actually developed it.

      See the following completed waste profile forms for this example. A blank waste profile form,
along with a blank manifest and LDR notification form are attached at the end of the Appendix for those
persons who want practice filling them out using the example data.

                                             92

-------
Appendix 1
        UNIFORM HAZARDOUS

          WASTE MANIFEST
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                                                                93

-------
Appendix 1
t
     UNIFORM HAZARDOUS
       WASTE MANIFEST
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                                                                 94

-------
Appendix 1
                                INSTRUCTIONS FOR THE UNIFORM HAZARDOUS WASTE MANIFEST
          Federal nfuUiioM require generator! tnd iramporler of btztrdain wuu tod owMn or optnmn aTluandanwuM raiment, MOM, ud
          ditpottl fecililie. to complete Uu following infonwtion:

          DISTRIBUTION
          The hutrdoue wute menifea cooiiu of «U (6) copies. A. DM Muifeet u compieied die copie. an removed from beek to bat.
                  White Copy I               Mailed by TSDFlo dw Situ
                  Green Copy 2               Mtikd by T3DF to Generator
                  YUnunU>«™>l^
                  TtbU 1 (below).
                  Item O • Eimr tfM total quuaky of buiidou VMU, dxciibcd on oek line.
         TABLE I TYTCS OF CONTAINERS
         DM - M«u) dium, bamlt, l»f i                                        DW - Woodn ckunu, bwnU, luys
         DF - FibwboMd or pbttie dtuou, bamli, luft                              TP - T«fa portibte
         TT-Cw|oTiok.
-------
Appendix 1
                                                               f Tool
                                          Gmraur Lud Dfenoul Itatifcti.. NotifldtkM for
                                       llmrdBM VVaflae. Srijim lo «• EffiOiT* FraMtttfoa Da
Gcneraior Nairn:

Addnu:



Signature:
                                     Zaa/pi/ZZI
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                                                          EPA ID NO.
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Tin hmntou WHIM idenrinad on Ibe actoeupanyim aaaltm
below in nnieMd wtaua wrack are praUblud from land dupoca)
40 CFR 26«.7(iX3>. DM EPA
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                  WaetaGv
                                          Numerical Tn
                                                               id. Technology Coda aad/or Reference
                        •bl*
                               id Wai
        DOOl
        ill**
        11 Igncabla Liquid < IOHTOC
        | ] IgMablcuouids > or - IOXTOC
        nigniuelcCompreseedGa,
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        ( lOxiauen
        D002
        0t Acid. pH < or - 2.0
        11 Alkaline. pH > or - 12.5
                  r,
        D003
        II Reactive  SulSdea
        11 Reactive Cyanides
        IIElploerves
        I 1 Waur ReacnVca
        [| Otttcr (per |ttl.23(aXI>
        D004-Arsenic
        D005 - Barium
        D006
        I | Cadmium
        11 Cadmium Containing Beaches
        D007 - Chromium
        DOOl
            ILead
          - Lead Acid Balurics
        DOW-Mercury
        I I Low Hf. < 260 mf /*« H«
        I I High Hf. > or • 260 mg/*g Hf.
          mercury and orfamca and an
          not incinerator residue*
        I I High Hf. > «• - 260 mf/ki Hf.
          inorganics including
          incineratnr e< RMERC  residues
        DOIO - Selenium
        DO! I - Silver
        D0!2-Endriii
        DOI3-Lindinc
        DOI4-Mcuoxychlor
        DOIS - Toiaphnene
        P016 - 2.4-D
        DOI7 - 2.4.5-TP (SUvex)
                                        l)Ref2-l
                                        NA
                                        NA
                                        NA
                                        NA
                                        II Ref 2-DEACT

                                        (t Ref 2 - DEACT
                                        I I Raf 2 - DEACT
                                        II Ref2-DEACT

                                        (1 Ref 2-DEACT
                                        II Ref 3
                                        II Ref 2-DEACT
                                        NA
                                        11 Ref 2 - DEACT

                                        II Ref 3
                                                  II NA
                                                  II I
                                                  NA
                                                  NA
                                                                                  NA
                                                                                  II
                                                                                  II
                                                                                  II
                                                                                  II
   Ref 2-DEACT
   Ref 2 - FSUBS; RORCS; or INCIN
   Ref2 - DEACT
   Raf 2-DEACT
   Ref 2 - DEACT
      t-DEACT
I) Ref 2-DEACT
[] Ref2-DEACT

U Ref 2-DEACT
I) Ref3
II Ref 2-DEACT
11 Ref 2 - DEACT
|| Ref 2-DEACT
|| Ref 1
II Refl
                                                                                  II  Refl
                                                                                         -RTHRM
                                                                        II Ref 1

                                                                        11 Refl
                                                                        I | Ref2-ULEAD

                                                                        I) Ref!
                                                                        II Ref2 - [MERC: or RMEXC
                                                                                  I |  Ref 2 - RMERC
                                                  I I Ref3                         I)  Refl
                                                  II Ref3                         I ]  Refl
                                                  I I Rtf2 - BrODG:orINC[N         | ]  Ref 3
                                                  || Ref 2 - CARBN: or INCIN        II  Ref 3
                                                  I I Ref 2- WETOX; or INCfN        I I  Ref 3
                                                  I ] Ref 2 - BIODC: or INCIN         ( |  R.f 5
                                                  II Ref 2 - ChOXD: BIODO: or INCIN  ( |  Ref 3
                                                  II Ref 2 - CHOXD: or INCIN        I )  R.f 3
             11
          References
          Ref 1:  See numerical maurai* lunoardd) in 40 CFR 26S .41. Tabl* CCWE - Comtiuen ConunUMioaa in Wuu Exmci
          Ref 2:  See technology-owed aUMlard(i) in 40 CFR 261.42. Table 2 • tecbnoiof y-bawd Slandard By RCRA Wa>e Codes
          Ref 3.  See numnical unumnt •andardO). 40 CFR 26S.43. Table CCW . CooaUnicm Cooceatraiioni in Waau
          I |      CHECK HERE IF SPENT SOLVENT. CALIFORNIA LIST. OR F-. K-. P-. OR U-CODE WASTE, if CHECKED. COMPLETE
                  PACE 2.
                                                                    96

-------
Appendix 1
         01.
                 SpmSolvralWuuCod*(i)rClMCk*U*faich«pply|| F001 (I  FOOT [| F003 [| F004  I] FOQ5    /
                         ronnimtnt                               Coaettaamk (agO. unUu a&ttvim nncifittf)

                         n-Bwyl4lcobol
                         Cufcoaduul&b
                         Cutxxiutrachlorid*
                         ChtoiDbOTMO.
                         Craali and (ad cmylia •«*>
                         CyctobuuoM
                        Bkyl
                        MMhytMH chiorid. -
                        laden? WuunurOriy
                        Pyri*ae
                        T«rachlonMhylm>
                        TakMm
                        1.1,1-TrichloKMhtm
                        1,1.2-TricUanMhne
                        I.1.2-Triehkm-1.2J-T or- |}4mg/U
                        Liquid* «xh PCS'. >r 50 ppm
Wuuwuw
[] 0.05
[I 0.070
0 S.O
(1 1.05
1)0.05 -»,
[ ] O.IS \J/
[12.IJ **?/
(] 0.125 / •
1 1 0.6S /
[] R.fa-B»DO-.AlNCJN
( 1 0.05 /
1 1 0.05 /
I J 0.05 /
tl 5.0 /
11 OJS /
[) 0.20 /
tJ 0.«4
II *ns
i\/>M
Ul 0.46
«(] R*r2-(WBTOXor
CHOXD) ft CABBN; or
INCIN
11 1.12
II 0.079
II 1.12
(1 1.05
(1 0.0)0
II 1.05
1 1 0.062
11 0.05
11 0.05
• of UK following eooniuau.
.. _/.....
rmnraMvwMiT
(1 OJ*
(J/7««*,
1/s.o
Kl 4J1
1l 0,96
11 0.05
11 0.75
1 1 0.75
11 0.125
[] tall ~WCK
1 1 0.75
I] O.OS3
1 1 0.75
(1 SA
11 0.75
Jl 0.96
NA
II 0.75
[J OJ3
(1 0.125
[] R*f2- INCIN


(1 OJ3
M 0.05
[1 OJ3
LI 0.41
t) Ltagnv
LI 0-M
(1 0.091
(1 0.96
11 0.15
                         [ I  ThiUium > or . 130 raf/L
                         [ J  Wuu toatiaaif HOC'i > or » 1,000 mf/kf
                OUur Uiud Haartfoui W
         EFAIUunloiu
         Wuu Co*.
((F006-F012.F019-F02S.K-, U-. nt F^odu)

      5-Uur Ttchoolofy Codt
                                                                               OUf 1. k*f 2. rad/ot lUf 3)
                CHECK HERE IF ADDITIONAL LISTED WASTE CODES ARE PRESENT. IF CHECKED. USE LDR1 CONTINUATION
                SHEET.
             : Set numnml Iraumni UadudO) in 40 CFR 26S.41. Tlbk CCWE . CanBtaim C
           f2 SoVKhaolo()'4inMiiuad>rd(t)in4OCFR26142. Tabte 2 - T
-------
Appendix 1
Generator Neme:

Addrau:



Sifnuun:
                                         Oewnur Lad Dbpul Rathe** NoUficadui for
                                       ItanrdMi WMM Sibjcct ID am EOktir* Protobide. Dalt
        EPA ID No.

        Contract (Prim)

       ;

        DIM:
                            Liqiiid WUUWUMI
                  1 1 Ipunbh Liquid < IO%TOC
                  1 1 Ifnittbta liquidl >or - 10* TOC
                  1 1 Ifniubte Rwciivc.
                  D002
                  M Acid. pH < or - 1.0
                  (|AIWi».pH> or- 12 J
        D003
        [IRnaiv. Sulfidu
        1 1 RMCUV* Cyioidu
        UExpkMiVM
        I ) Wmt Rnctivm
        |]Otf»r(p«r|261.2}(tXI)
        D004- Arwuo
        DOOS-Biiiuai
        D006
        I ICtdmum
        1 1 Cidmhim CoMumif Buumi
        D007 ' Chfooiium
        DOM
        ^4-Lud
        I 1 - Lud Acid BMUnci
        D009 - M.reury
        I I Law H|, < 260 mt/kf Hf
        [ I Hifh Hf . > or » 260 mf'kf H».
          nufvury tnd off •»!» ftnd IN
          nal incinnvtar rtsiduM
        I 1 Hirh Hj. > or - 160 nf/kf Hf .
          inoryaflicf including
          incmenutr A RMERC mtdu«i
        D010 - Selenium
        DOt I • Silver
        DOI2-Eadfin
        D013 • Undine
        DOM - Mrthoxychlor
        DOI5 • Toxiphnm
        DOI6 - 2.4-D
        DOI7-2.43-TP(SUv<»)
(lluri-DEACT
NA
NA
NA
NA
I) lUfl-DEACT

I ) lUf J - DEACT
() lUfJ-DEACT
1 1 tofl - DEACT

I ] iuri - DEACT
II IUf3
|| lUfl- DEACT
NA
(I Rcfl- DEACT
II IUf3
                                                 II IUf3
                                                 II NA
                                                 |J R«f3

                                                 II »t(J
                                                 NA
                                                  NA
                                                  NA
NA
|| R.r 1- DEACT
1 1 Rtf 2 - FSUBSl RORCS; or D4CIN
II R«f 1- DEACT
|| Ref2- DEACT
1)4 JUfl- DEACT

WR.fl- DEACT
f] IUf2- DEACT
I) IUfJ- DEACT

(] IUf2- DEACT
I) R.f3
|| Refl- DEACT
II R»f2- DEACT
I ) Rtf2 - DEACT
N R*"
II JUf!

I) Rcfl
|| Rcfl-RTHRM
                               |] Rcfl-RLEAD

                               II Rcfl
                               II Rcf 1 - IMERC; or RMERC
                                                                                I I Refl- RMERC
                                                  ! I R.f 3                        || Refl
                                                  II R«f3                        II Rcf I
                                                  I I Rtf2-BIODC:of INCIN        I I Ref 3
                                                  I I Rtf2-CARBN:or 1NC1N        I I Ref 3
                                                  I) Rcf 1-WETOX: or INCIN       I I Rcf 3
                                                  I I Rcf 1-BIODC: or INCIN        II Ref 3
                                                  II Rcf 2 - ChOXD; BIODQ: or INCIN I I Rcf 3
             (I    DOI7-2.43-TP(SUv«n)              I I R.f J - CHOXD: or INCIN       I I Rcf3
           Rclcniicci                            	
           Ref I: S
-------
Appendix 1
Spent Sotvm WUIM F001 dwMfh F005

Sp«» Sotv«ot W.«. Ccxkd) - Ch«k mil wbiclupply 1 1  F001
        _ — : -----
                                                                    [| F002  [ I  F003 (1 F004 II POOS
                                                                    CootiMnuoo (m»/L un*«l odMcw

                            Carbon duulfid*
                            CaitoawncUorid*
                            Cblono*BM»
                            Omota u4 (ud cmylk Mid)
                            CyelaknnaM
                            1.2-DkhkxobmM
                            2-Elhaxywluaol ffOOS)
                            Bbjrt
                            fctafcrlmcfclorld*
                            MMhyteao chloride -
                            lodmry Wiiuwitir Only
                            M«hyl «thyl IMOM
                            Mdkyl uobutyl kMoai
                            TMnckloiwitiylMM
                            Tokwiw
                             l.l
                            TricUonMhylMM
                            TricUonnuofDOMihaiii
                            Xykm
             ID.
                     Cilifocnu Lin Wtui - H«
1 1 0.05
(] 0.070
(1 5-0
11 1.05
[1 0.05
1 1 0.15
(1 1.12
1 1 0.125
II 0.65
11 Mi-
ll 0.05
(1 0.05
II 0.05
11 5.0
11 0.25
I) 0.20 /
II 0.4/
11 0/5
11/05
1/0.66
Y\ JUf2-
n oj»
ii yh***t
UAO
M 4.11
/] 9.96
/[) 0.05
NW 0 0.75
•^y 110.75
V 1 1 0.125
MODOio/lNCrNn Rrf2-lNClW
/ 11 0.75
/ [ J 0.053
/ 11 0.75
/ 1 1 S-0
/ 1 1 0.75
f t) 0.96
NA
1 1 0.75
1 1 0.33
I] 0.125
(WETOXor [] R«f2- INCIN
' CHOXD) Ot CARBN; or
INCIN
11 1.12
|| 0.079
11 1.12
(S 1-05
I) 0.030
11 1.05
[| 0.062
11 0.05
11 0.05
nofUufoUo

(1 OJ3
(1 0.05
11 OJ3
(1 0.4t
| | 7^Kfft(
tl 0.96
[] 0.091
[) 0.96
11 0.15
wmt eonwnuau.
             IV
                     I I      NicM > or - 1341
                     ( 1      Liquid! with PCB-i > <

                     Oilwr Litud Haardout Wai
                                               (| TtuUiura > or - !30mg/L
                                               (1 Wuu eoouiaiot HOC'i > or » l.000m»/k»
                                                )-FOI2. FOI9-F02S. K-. U-. ind P-eod*i)

                                                 5-Ua*r Ttehioloty Cod*
                                                 Gf«pplic«M>-M.R>f2)
                                                                                    OUf 1. lUfl. ud/orlUf 3)
                       ECK HERE IF ADDmONAL LISTED WASTE CODES ABE PRESENT.
                     SHEET.
                                                                                IF CHECKED. USE LORI CONTINUATION
                  Su niuncra*! iruinM iitadinKi) ia 40 CFR 261.41. T«bU CCWE - CoaMMac CoGcadniioat a WUH Ennci
                  S« uduolof H>u m 40 CFR 241.42. Tibb 2 • TKhnolo|y-BubU CCW . ronahmm COOMMMIOIU ia Wun
                                                                     99

-------
Appendix 1
           Generator Name:
           Addnw:
           Signature:
                           I/.6-
                                           Generator Land Dboaaal sUatttafaTNetfincatRM tar
                                        Uaaardout Wastes SMtjttt u *• Effectm PnUbUwDM*
                                                           EPA ID NO.
                            /{.So ft CCH Steep
                                                                OSC
           tin hazardous WUIM identified oo DM accompanying t
           40 CFR 161.7(t)(n. Hi* EPA wast. tack. waste mb
           reference*, u applicable. u* provide* btJow.
           1.       rhiracurinVi Wanes D001 uuouth D017
                                                                . and bnriat *a EPA Haaidouc Waal* Coda* Uaud
                                                                leJ Restrictions, 40 CFR Pan 26S. In accordance with
                                                                ttnaat auusdnnb. technology code*, and appmnnasj
             I]
              11
           Ref 2:
           I I
DOOI
11 ItniUBle Liouid Wastewatan
I ] Ifnaable Liatiid < IOSTOC
I 1 Unstable liquids :> or- IOSTOC
11 IfmtsbloCompreseedaas
I) IfnkakW Raaeuves
11 Ondiun
D002
I I Acid. pH < or - 1.0
Ift Alkaline. pH > or - 12.3
                                                           StudMd, T«chnolofy Cod* ud/or Rt
                                                          -DEACT
                                                           - DEACT
                   DOQJ
                   1 1 RMCtiv. SulfUo
                   1 1 BMCtiv* Cyuida
                   1 1 Wucr RcMii
             II
             []    DOW-Arsenic
             []    D005-Barium
             M    D006
              11
        1 1 CxlmiuiD CoMiinicf BMttmi
        D007 - Chromium
        DOM
        Dd-Lttd
        I 1 - U*d Acid Dannies
        D009-Mmny
        HLowHf. <260m»/k|H,
        I I Hifil H». > or » 260 of/kf Hf .
          mercury and or§ arnea and are
                                        I)  lUfl-
                                        ti  *ai-

                                        II  RrfJ-
                                        II  Ref3
                                        U  «efZ-
                                        NA
                                        II  RefJ-
                                        II  R«r3
                                        tl  Raf)
                                U NA
                                I] RtO

                                II Rtri
                                NA

                                H Ref3
                                NA
-DEACT
•DEACT
-DEACT

-DEACT

•DEACT

•DEACT
                                                                                   NA
                                                                                   [| Raf2-DEACT
                                                                                          t - FSUBS: ROROS; or INCIN
                                                                                          t-DEACT
                                                                                          t-DEACT
                                                                                   II Ref 2-DEACT
                                                                                   II Ref 2-DEACT
                                                                                   k4 Rafl-DEACT
                                                                                   1) Ref 2-DEACT
                                                                I) Refl-DEACT
                                                                M Raf 3
                                                                II Refl-DEACT
                                                                I I Refl- DEACT
                                                                || Refl-DEACT
                                                                II Ref 1
                                                                II Ref I
                                                                                   II tUfJ-RTHRM
                   I | Hifh Kg. > or . 260 m»/kf He.
                      inoiranki iadudinf
                      inetfwraior A RMERC residues
                   DOIO - Selenium
                   DO)I-Silver
                   DOI2 - Endria
                   DOI3 • Undine
                   DOla • Metboxvchloc
                   DOIS • Tonapluiene
                   DOI6 - 2.4-D
                   DOI7 -1.4. S-TP(Silve»)
                                -RLEAD

                        II Refl
                        (I Ref 2 - IMEXC: or RMERC
                                                                                   I I Refl- RMERC
                                        I I Ref3                         I I  (Uf 1
                                        1 | Ref3                         | |  Ref I
                                        ( I Raf 2 - BIODC: or 1NCIN         I I  Ref3
                                        [) Refl - CARBN: or INCIN        ( |  Ref 3
                                        I ) Rafl - WETOX: or INCIN        | I  Ref 3
                                        11 Ref 2 - BIODC: or INCIN         11  Ref 3
                                        |] Ref 1 - ChOXD: BIODG: or INCIN  | I  Ref 3
                                        II Refl - CHOXD: or INCIN        I I  Ref3
References
Ref I:  See numerical treatment atandardd) in 40 CFR 261.41. Table CCWE - Conniiucm Concentrations in Watte Enract
      See technolof y-baied tundanUs) in 40 CFR 268.42, Table 2 • ucbnoiofy.to.sed Standard By RCRA Waaie Codes
      See numeTwal ireaunem pundardli). 40 CFR 261.43. Table CCW • Consliluem Cooccntralioni in Waau
        CHECK HERE D= SPENT SOLVENT. CALIFORNIA LIST. OR F-. K-. P-. OR U-CODE WASTE, if CHECKED. COMPLETE
        PACE 2.
                                                                    100

-------
Appendix 1
                    Span Sot v«mWMU.FOOHhroBIbF005
            IU.
                    (I
                    II
                    II
                    II
                    I)
                    II
                    I)
                    II
                    II
                    II
                    II
                    II
                    II
                    tl
                    M
                            Conaliuux
                                          - Cluck all which apply 1 1  FQOI || 1=002 [] W03 I I F004 (1 F005
                                                                    Coocaantieo or - 1)4 mf/L
                            Uquidi wild PCB'i > or 50 ppm
                                                        11 Thallium > or - 130 m|/L
                                                        11 WMU covuimnt HOC» > or • 1.000 mf/k|
IV      Other Lined Hazanfcxit Watua (P006-F012. FOI9-F02I. K-. U-. and P-codaa)

EPAHazankxu    Waauwateror          5-LattaTTachnolot]iCo4a
                Noowaauwaur         fit applitabk - aca Raf 2)
                                                                                     OUT I. Rrf2, ud/orR«f3)
            I |      CHECK HERE IF ADDITIONAL LISTED WASTE CODES ARE PRESENT. IF CHECKED. USE LDR1 CONTINUATION
                    SHEET.
            Rtfenncn
            R«f I:  S.« nimmul irtunnu iludMdU) in 40 CFR 261.41. TabU COVE • ConUtuau Conxmntiou in Wan* Enncl
            Rcf 2:  Sec uchaoU>fy-ku«
-------
Appendix 1
            Sifnuun:
                                            Ga-antor Lud D-ponl Rtttrfatitt N«_Hc-l_« for
                                         Ha-r-«u WotM _.kjt-t la an Effactirt ProUUfea Da
                                                            EPA ID No.

                                                            Conuma (Prim)



                                                            Dau:
                           i Idantifiad onlh« irrommiyiiur imnifcn matttt
                                                                              and bearim lb« EPA Hmrfou. Waaa rnrlii Baal
                                  ich«Mprohibilidfa>mlind», tcutam uaomte. uduMloty eodu. tad tppreprim
            nCncacM. tupplicifcto. M pi
            1.
                                 MM 0001 Ibroufh DOIT
              |J
              11
              I I
              I |
              I)
            Ror - 10* TOC
I I If luttbW Reacuv..
I I Oxidian
D002
11 Acid. pH < or - 2.0
I) Ala-ttoa. pH > or • 12 J
()0lher
D003
[ I Reactive Sulfidcl
11 Reactive Cyenidej
I lExploaive*
I I Water Raaciivai
I|OUier or - 260 mf/kf Hf.
  mercury and organic* and ar«
  not  iacintntar reuuuei
I I Hifh Hf. > or - 260 mffkf Hf.
  inorf anica mciuduif
  incinerator & RMERC residue!
DO 10 - Selenium
DO 11 - Silver
DOI2 - Endrin
DO 13 - Lindam
0014 - Metboxychlor
0015-Tuxaphnaae
DO 16 - 2.4-0
DOI7.2.4.5-TP(SUvex)
                                                           > Suadud. TKtealafjr Cod* ud/er Rtftnae*
                                  (I R«f 3 - DEACT
                                  NA
                                  NA
                                  NA
                                  NA
                                  I I R*r2 - DEACT
I) R*f2
|] R.f2
II lUfJ

I) RefJ
[] Ref3
[] R«f2
NA
II R«f2
                                                    II NA
                                                    II R) in 40 CFR 268.41. Table CCWE - Comuoum Concennlkwi in Watla Extract
See technolofy-baaed etandardd) in 40 CFR 268 42. Table 2 • lechaoUify-feeMd Standard By RCRA Waale Codei
            Ref 3.  See numerical inaumm -indardd). 40 CFR 268.43. Table CCW - Conautucru Coacemnlioiu in Waale
            tfl      CHECK HERE IF SPENT SOLVENT. CALIFORNIA LIST. OR F-. K-. P-. OR U-CODE WASTE, if CHECKED. COMPLETE
                    PAGE 2.
                                                                      102

-------
Appendix 1
            It.
           IV
        •-Butyl WMUC<>4e<»)-Quc* ill which apply ||  R»l  ^ W02  tf  F003 II F004 &( F005

                            " — •'• -----                                  CaacMmuaa (mf/L unlut oifaeiwiM ^•etfiad)
                    IJ

                    I!
                    0
                    I)
                    n
                    II
                    il
                    II
                    n
                    n

                    fi
                    (I
                    u
                    n
                    M
                    n
                    ii
                    n
                    il
                    I
                    04
                    II
                    II
                    11
                    II
                    M
        M«hyleneehlaride

        laduiay Wutmw Only
        Methyl ethyl keue.

        Methyl aobulyl keione
                            2-NkfoproB«m(F005)
        Pyrkfae

        Tetnchkxaelhyleae

        Toluene

        l.l.l-Triohlocoetheiie

        1.1.2-TricliloroettMoe

        I.lj-Trichloro- l.2.2-TriOuoroe or - 134 mt/L

I !      Liquid! wuli PCB-i > or 50 ppm
                                                                       I I  Thallium > or - 130 mg/L

                                                                       ft  Wuu conuauBf HOC't > or - 1.000 raf/kf
                    Other Laud Hazardous Want* (F006-F012. F019-F028. K-. V-. and l>-codw)
           EPAHuudoui

           . Wuu Coda
        Watimuror

        NOBWaoewater
                               iJAr
5-Lxur Techooloty Cod*

(if appliubU - >M R»f 2)
                                                                                       (Rtf I. R«f 2, ind/or lUf 3)
           | 1       CHECK HERE IF AODmONAL LISTED WASTE CODES ARE PRESENT.  IF CHECKED. USE LDR1 CONTINUATION

                    SHEET.

           Reference*

           Kef 1   See numenul tfeelmeol iuodardd) in 40 CFR 26S.4I. Table CCWE - Coruutuent Concewnliow in W.«u Extncl

           Ref 1.  S« uchnolofr-oued aandtRlli) in 40 CFR 261.42. T«bU 2 • Teehnalof ;-B*Md Sundird By RCltA Wuu Code.

           R*r }   See omnencel ireMaeni euaderd(i). 40 CFR 241.43. T.bk CCW • ComuueM conceatnuaiu m Wene
                                                                         103

-------
Appendix 1
Generator Name:

Addroa:



Siftunura:
                            IbSO  ARCH
                                           GtMtuor ImA Dttpgol RMrictiM NmUkadoo for
                                         lUurdMet WMU* Subject w to EflMnt PnhibMM OMt
        EPA ID No.

        Contract (Print)
                                                                                             JO ft
                                                                CKC
                                            PA  HUB
                            identified oa die
                                                     aiba
                                                                            ud kotisi UK EPA mantau Wou CodM bud
                                                                                                     Ini
40 CFR 26I.7(eX3). Ik* EPA waata code, waate auteatefory. I
nimacea. aa applicable, an piovided below:
I.       OuraetatiauceWealeeDOOl through DOI7
                                                                       ». Uwmm uulaidi. uehiulety eodo, ud
              I I
              II
              (I
              II
              (1
              ( )
              [ 1
R.f I:
Ref 2
Ref 3;
                   0001
                   [ | If oueble Liquid WeetHraun
                   [ 11fniukle Liquid < lOKTOC
                                 i >or- IOXTOC
                   ( | If niubto RacavM
        0002
        ( | Aeld. pH <« - 2.0
        ( | AltoiM. pH > or • 12 J
        [)OdKr(ptr|2«1.22(iXD
        0003
        1 1 lUutiw Sulffdti
        I | Ruelivi Cyuuda
I) Water Reactive.
I ) Other (per 1261.23(.X1)
D004-Araenic
DOOS-Barium
D006
[) Cadmium
[ I Cadmium Containing Bauerici
D007 • Chromium
D00>

( 1 - Lead Acid Batumi
DOW- Mercury
I I Low HI. < 260mf/kf Hf
[ | Hifh Hf. > or - 260 mf/kf Hf.
  mercury and orfanica and are
  not incinerator reaidiMs
I | High H|. > or - 260 mf/kf H|.
  taorfaniet includinf
  tncinentnr & RMERC reuduaa
DO 10 • Selenium
DOM -Silver
0012-Endiu
DOI3 - Lindanc
DOI4 . Mclboivchlor
0015 - Touphncne
DOI6-2.4-D
DOI7-2.-U-TP(SiIv«iO
                                        Olurj-DEACT
                                        NA
                                        NA
                                        NA
                                        NA
                                        { 1 R«f2 - DEACT
(] R.f J
(] IUf2
( ) R«f 2

U R«f2
(] R«f3
U IUf2
NA
[| Reft
                                        II  NA
                                        II  Ref 3

                                        1)  Ref 3
                                        NA

                                        II  Ref3
                                        NA
                                        |] Ref 3
                                        II Ref 3
                                        II Ref2-
                                        I] Ref 2-
                                        II Ref 2-
                                        11 RDa:orlNCIN
                                                 CARBN;orlNCIN
                                                 WETOX; or INCIN
                                                 B10DO:orINCm
NA
I I  Ref 2-DEACT
hi Ref 2 - FSUBS: ROROS: or INCIN
II  Ref 2-DEACT
(I  Ref 2-DEACT
I I  R.f 2-DEACT

II  Ref 2-DEACT
(I  Ref 2-DEACT
I)  Ref2-DEACT

{]  Ref 2-DEACT
I]  R«f3
I |  Ref 2-DEACT
I)  Ref 2-DEACT
I)  Ref 2-DEACT
II  Refl
II  Refl

II  Refl
II  RefZ-RTHRM
II  Refl

t4R.fl
II  RcfZ-RLEAD

tl  Refl
II  Refl - DXfERC; or RMERC
                                                                                   I | R.f 2-RMERC
                                                                                   ||  R.f I
                                                                                   ||  Refl
                                                                                   I I  Ref 3
                                                                                   I I  Ref 3
                                                                                   I I  Ref 3
                                                                                   ||  Ref 3
                                                            CbOXD:BIODO:orlNCIN  II  Ref 3
                                                            CHOXD: or INCIN        []  R.f 3
      See numerical treatment uandardta) in 40 CFR 261.41. Tabk CCWE •
      S«e lecnnolofy-baaed aundard(a) in 40 CFR 268.42. Table 2 - I
                                                                     Coimicueni Coocentniioni in Win. Extract
                                                                     Dfy-be*ed Standard By RCRA Waate Codee
                  See numerical treatment eundard(i), 40 CFR 26S.43. Table CCW - CoMuuent Concentrationi in Wane
                    CHECK HERE IF SPENT SOLVENT. CALIFORNIA LIST. OR F-. K-. P-. OR U-CODE WASTE, if CHECKED. COMPLETE
                    PAGE 2.
                                                                    104

-------
Appendix 1
                       T
Waejmear
I) 0.05
I] 0.070
U 5.0
t) 1-05
[J 0.05
1 1 0.15
U 2.12
U 0.125
(1 0.65
NoBWaumar
(I 0.59
Pt3.7B^k(
II 5.0
1 1 4.11
0*0.96
II 0.05
1 1 0.75
1 1 0.75
1) 0.125
[] JUf 1 - WODO; or WON ( I «W2-MCIN
(1 0.05
(1 0.05
(1 0.05
t] 5.0
11 0.25
II 0.20
II 0.44
{] 0.05
II 0.05
U 0.66
|| taf2-(WETOXof
CHOXD) ft CABIN; or
mciN
II 1.12
(1 0.079
(1 1-12
(J 1.05
() 0.030
II 1.05
1 1 0.062
11 0.05
II 0.05
1 J 0.75
() 0.053
(1 0.75
(1 *-o
I! 0.75
M 0.96
NA
( } 0.75
(1 OJ3
M 0.125
[) bn-lNCni


M OJ3
M 0.05
M OJ3
M 0.41
p 7.6nt/kf
(J 0.96
M 0.091
1) 0.96
M 0.15
                           Ni<*el > or - 134 miIL
                           Liqiudi wi* PCB'l > or 50 ppm
                                                      I) ThiUium > of - 130 mg/L
                                                      pi Won conuniaf HOC-i >« -
                    OUw Luud Hiuidoui WMU (F006-F011. F019-F02S, K-. U-. and P-coda)
            EPAHiunkxu
            w>u Cadi
Wumnuror
NonMtuwiur
                                    5-LM«rT«cluK>ic»yCobb CCWE • CO
                  S« uchiiolo(y-bu«d iUndu4(M in 40 CFR 2«S .42. Table 1 • T
-------
Appendix 1
                                         XYZ CORPORATION*                      Profle Numtaar
                                   WASTE MATERIAL PROFILE SHEET                  Pag* 1 of 2
      A. GENERAL INFORMATION
      GENERATOR    	  BILL TO:
      FACILITY ADDRESS       __^___^__^^^^^__  BILL TO ADDRESS
      SIC NUMBER    	  XYZ CORP CONTACT PERSON    	
      GENERATOR U.S. EPA IDf  ^^__^^_____  XYZ CORP SERVICE CENTER LOCATION
      GENERATOR STATE ID*   	  SAMPLE APPROVAL P.O.f       	
      TECHNICAL CONTACT     	  CUSTOMER CONTACT      	
      TECHNICAL CONTACTS PHONE     ____^^___  CUSTOMER CONTACT'S PHONE  	
      a. WASTE MSCMPTION
      COMMON NAME FOR WASTE
      PROCESS GENERATING THE WASTE
      C.
      PH  Q <2            O2-4          DM         D 10-12.8             d >12.S    ACTUAL	
      * TOC	                  BTUi/POUND	                     COLOR	
      % ORGANIC HALOGEN	                  ODOR	
      FLASHPOINT CF1    D < 73«     O 73-»»«      D 100-139*      Q 14O-200*      D >200*          O NONE
      BOILING POINT (*FI              D < OR - »S«         Q > »S»
      PHYSICAL STATE
      D LIQUID WITH NO SOLIDS                     O SOLID WITHOUT FREE LIQUID                     O MONOUTH
      D THICK VISCOUS LIQUID                      O POWDER
      D LIQUID/SOUP MIXTURE	             % FREE LIQUID	            % SOUPS

      D. COMPOSITION
      MSDS'« ATTACHED  D YES   O NO
      E. DEPARTMENT OF TRANSPORTATION MFOMMATON
      D.O.T. SHIPPING NAME    	
      D.O.T. HAZARD CLASS OR DIVISION	
      UN/NAf         	PACKING CROUP        	HAZARD ZONE        	RO

      F. SHIPMENT METHOD
      D BULK LIQUID  D BULK SOUD  3 DRUM (SIZE)  	
      g OTHER (SPECIFY!

      G. ANTICIPATED VOLUME
      	      D GALS.              Q DRUMS               D CUBIC YARDS
      FREQUENCY     a ONE TIME	D WEEK	O MONTH	D QUARTER	D YEAR

      H. WASTE DISPOSAL STATUS
      U.S. EPA HAZARDOUS WASTE     3 YES     D NO
      U.S. EPA HAZARDOUS WASTE NUMBERIS)   	
      STATE HAZARDOUS WASTE     2 YES     O NO
      STATE HAZARDOUS WASTE NUMBERIS)     	
      IS THIS RESTRICTED WASTE UNDER THE LAND BAN REGULATIONS?   G YES     O NO
      THIS WASTE IS A  O WASTEWATER  D NON-WASTEWATER   PER U.S. EPA DEFINITION IN 4O CFR 268.2.
      DOES TREATMENT OP THIS WASTE GENERATE A F006 OR F019 SLUDGE?   D YES     O NO
      IS THIS WASTE SUBJECT TO CATEGORICAL PRETREATMENT DISCHARGE STANDARDS?   D YES     D NO
      IF YES SPECIFY POINT SOURCE CATEGORY LISTED IN 4O CFR PART 401

1. OTHER HAZARDS
YES
DIOXIN O
INFECTIOUS C
OXIDIZER G
WATER REACTIVE 0

NO
2
*-.
D
~

YES
EXPLOSIVE 2
PESTICIDE r
RADIOACTIVE Z


NO
a
D
a


YES
HERBICIDE C
PYROPHORIC ~
SHOCK SENSITIVE C


NO
a
a
a

                                                           106

-------
Appendix 1
                                                                                            Profile Number
   j.  roxicmr cHARACTBwnc COMPOUNDS CONCENTRATION REPORTED M a TOTAL (ppM)  a TCLP (ppM)  Pag* 2 of 2
      COMPLETED IASED ON K - QENEKATORS KNOWLEDGE  T - TESTING
  WASTE    COMPOUND                          REGULATORY      COMPLETED
NO.
METALS
0004 ARSENIC
DOOS BARIUM
0004 CADMIUM
DOOS CHROMIUM
CHROMIUM CR +6
0008 LEAD
DOOS SELENIUM
D0 10 MERCURY
DO11 SILVER
PESTICIDES AND HERBICIDES
0012 ENDMN
0013 UNDANE
0014 METHOXYCHLOR
001 S TOXAPHENE
DO1B 2.4-O
0017 2.4.S-TP (SILVEX)
D020 CHLORDANE
DQ31 HEPTACHLOR (AND ITS EPOMDEI
VOLATILE OROANIC COMPOUNDS
0018 BENZENE
0018 CARBON TETRACHLORIDE
002 1 CHLOROBENZENE
0022 CHLOROFORM
0028 1,2-DICHLOROETHANE
0029 1,1-OCHLOROETHYLENE
0036 METHYL ETHYL KETONE
0039 TETRACHLOROETHYLENE
0040 TRICHLOROETHYLENE
DC* 3 VINYL CHLORIDE
SEMI-VOLATILE OROANIC COMPOUNDS
0023 o-CRESOL
0024 m-CRESOL
0025 p-CSESOL
O02« CRESOL (TOTAL)
O02 7 1 ,4-DICHLOROBENZENE
O030 2.4-OINITROTOLUENE
0032 HEXACHLOROBENZENE
0033 HEXACHLOROBUTADIENE
0034 HEXACHLOROETHANE
0036 NITROBENZENE
D037 PENTACHLOROPHENOL
DO38 PYRIDINE
0041 2.4.B TRICHLOROPHENOL
DO42 2,4.6-TRICHLOROPHENOL
K. OTHER COMPOUNDS Ippfn)
AMMONIA
CYANIDES
BERYLLIUM
THALLIUM
LEVEL (ppm)
8.0
100.0
1.0
6.0
5.0
0.2
1.0
S.O
0.02
0.4
1O.O
0.6
1OJ3
1.0
O.03
0.008
O.B
0.5
100 a
8.0
0.5
0.7
200.0
0.7
O.B
0.2
200.0
200 JO
200.0
200.0
7.6
0.13
0.13
O.S
3.0
2.0
100.0
S.O
400.0
2.0
HOCt
PCB<
COPPER .
TIN
BASED ON
(CHECK ONE] CONCENTRATION (ppm)
1C T
D D
Q
a
D
a
a
a
a
D
K
a
a
a
a
a
o
o
a
K
a
a
a
o
0
a
D
D
n
D
K
D
D
a
a
a
a
a
a
n
D
D
D
n
D




a
D
a
a
n
n
n
a
T
D
D
a
a
a
n
a
D
T
D
D
a
a
o
D
o
a
D
a
T
0
a
a
D
a
a
n
c
a
n
a
D
a
D
P001-F005 SOLVENTS
SULPIOES
NICKEL
ZINC
   L. SAMPLE STATUS
          A REPRESENTATIVE SAMPLE HAS BEEN SUPPLIED
                                                  a YES   a NO
  M. SPECIFIC GENERATOR REQUEST FOR DISPOSAL ANOKDR COMMENTS
   ran XYZ CORP USE ONLY
  i ta**bv o«ft*tv th*n *ll tnform*tli
  «• rnpr*Mfiwbv« of th« actual WMU.
                                           GENERATOR'S CERTIFICATION
                             ttttd ki thii «nd «n«ch*d 4oaum««u to comet to tht v«tt o
                                                                               I *lto 0*nfty th«t «ny
      AUTHORIZED SIGNATURE
                                        NAME (PRINT)
                                                                         TITLE
                                                                                                DATE
                                                             107

-------
Appendix 1
                                     112-etaH Mp»«iMM.t
                                                                                                 Ota** tofimm.Saintt-X-tt
1
G
E
N
e
R
A
T
O
R
,


UNIFORM HAZARDOUS
WASTE MANIFEST
3 Oanerator'a
4. OenereWe

Phone | )
I.Gonai
|
pVdd •

«oi'> US EP/i
| |

S. Traneporter 1 Company Name
7. Traneporter 2 Company Name
». Oeaunatad FecOty Name end SKe Addreee
ID No. Menifeet. Doeume
No.
1 1 1 1 1 1 II
nt

6. US EPA D Number
1 1 1 1 1 1 1 1
8. US EPA D Number
1 1 1 1 1 1 1
10. US EPA ID Number
1 1 1 1 1 1 1



11 US POT Peicitctton Unetottly »le»w SHx*lt Hmxt. Hatfd daet. o»aT4P AVaateri tl.Contalner
a.
b.
c.
d.








No.





MUte ttetavd Abow
Type



2.
Pa0g
1 of
A-Suea
NUhtfeor
«•««*•
IniurmaUoo In Hie
required by Federal law.

".^j^i'-1....'
&tTrare«x>rl«^*.«»iar»A= .. -
fi Tianepo«eii««ior» •• .
: "- •- ,v, .' -
' •_'• 5- • '^ ; • *' ••
»?^«**:^^:
u.
Ouaan



14. .- ''.!*--
«** WeaceHo. ..
WWel



Above ' - ., ,.,
• - *«, ' '~-
IS. Special Handing nemiooona end Additional ntormetJon
16 GENERATOR'S CERTFICATON: 1 hereby declare that t
proper ahlppmcj nemo end are claiilfied. peeked, marked
according to applicable intemationel and national govern*
If I em e large ouantrty generator. 1 eeRHy that 1 have a
determined to be economicaly practicable and that 1 how
mmnMwe the praeent and future threat to human health
mMmiia my waata generation and lalact the beat weata
PnntedfTyped name
1 7. Tranipom




Printed/Typed name
ha contenta of thti oonelgniMnl era fuay end accurately *
and labeled, and are In el reapacta In proper condition tor
irogrem In place to reduce the volume and toiiaitv of weal

trenapc
aganer
diapoai
management method that la aiieilatli to ma and that 1 eon effort.
Signature
U
above by
•t by highway
tied to the degree 1 have
ll ounenOv evoilabb to ma which
made e good faHn effort to
with
O«Y Veer
aipta of Metenala
Signature
Mi
jntfi
Day Vear
IB Traneponer 1 Acknowledgement of PIMeioti of Matariala
Pmted/Typad name
Signature
M
DMh
Day Year
1 9 FeeMy Owner or Operator. CanHfcetaHi of recent of haiaMoua metenala covered by thki menHeet e«eept aa noted in Ham 1 1.
Printed/Typed name
Signature '
M>
>nth
Day Veer
                                                  OPJOtHAl . HTUMN TO OCNCIUTOP.
                                                                                    CM Farm g70O->2 »av.
                                                                 108

-------
Appendix 1
                                           Counter Lend Dbponl RwrictMB Nodflcrioo lor
                                                 i V/utu Sityict to *a EfTtttfoFraUbiiiaa Dm
           Generator Name:

           Addraa:
                                           EPA ID No.

                                           Cottna (PriM)
           SifMUrc:
           The htmdouawuut ideoU6td on DM tecoapanyiDf; nuufitt mat** ^^______
           below in mtufcud want* which an praUMMd from land diapoeal under the Und DUp
                                                             and betriot tbe EPA Hnardeua WaHa Codaa Kurt
                                                           >eelRel«ricooot,40CrTt Part 241. Inaccordanoawilh
                                              uu
           40 CFR 26«.7(a)<3), toe EPA
           nfereacee. it applicable, an provided below
           I.      aitraciariaueaWaateaDOOIihrouihDOl?
                                  ^category, uuttbility troupe, maunta atudtrde, Mctaaalotjr coda, tod appropriate
              (I
              il
              I)
             [1
             II
             I)
             II
              [I
             I)
             n
             []
             II
             I)
             11
             II
           Refcrei
           Refl:
           Ref 2;
           Ref 3:
           n
                           N«merit»lT
                           WtBtwner
                                                           Sundud. Ttdmology Cod. Mid/or Mono*
                                                                     .       NonwMUwtler
   D001
   11 ItnUabU Liquid W«
   I ] Ifiuunla Liquid < IO«TOC
   I llfniubb liquid! > or- 10HTOC
   1J Ifniuble Conpreeied Gat
   11 Igaiubk Reaciivet
   11 Oxidixen
   D002
   I) Acid, pH < or - 2.0
   11 Alkaline, pH > or - 12 J
  D003
  [ | Rttttiw SulfidM
  I ] Retctive Cyiaidti
  I | Exploiivti
  I ] Wtur Rociivu
  II Otter (pet 1161.23(1X1)
  D004- Aiwaie
  DOQS-Btrium
  D006
  [ ) Cadmium
  [ 1 Ctdmium Coouining Buuriu
  D007 - Cbraoiium
  D008
  I|-Utd
  1 1 - Utd Acid Bltwmi
  0009 - Mercury
  I I Low H|.  < 2«Omt/k*Hf
  I ) Hifh Hg. > or - 260 mf/kf H(.
     imrcury tnd orjtnki and tn
  I | Hiffa HI. > or - 260 mf/k| Ht.
     ioorstnic* including
     incinerator A RMERC rcsidueii
  DOIO - Selenium
  DO 1 1 - Silver
  D012 • Eadiu
  D013 • Undine
  D014 - Melboir/elilor
  DOI5 - Tonphneae
  D016 • 2.4-D
  DOI7-2,O-TPrSUvex)
                                                    DRtfl-DEACT
                                                    NA
                                                    NA
                                                    NA
                                                    NA
                                                    [ I Ref 2 - DEACT
II Ref 2
II Ref 2
t) Ret 2

(] Ref 2
U *•«
I) Ref 2
NA
() Ref 2
[| RrfS
I) »«f3

[) Ref 3
tl NA
tl Ref 3

t) «ef3
NA

[I Ref 3
NA
II Ref 3
II Ref 3
(  | Ref 2
I) Ref J
I) Ref2
|] Rcf2
|| Ref 2
[I Ref2
DEACT
DEACT
DEACT

DEACT

DEACT

DEACT
BIODO; or INCIN
CARBN: or INCIN
WETOX;orWCIN
BIODC: or INCIN
CbOXD; BIODG: or INCIN
CHOXD;orINCIN
NA
(I Ref 2- DEACT
I I Ref 2 - RUBS; RORGS; or INCIN
11 Ref 2 - DEACT
I | Ref 2 - DEACT
I I Ref2 - DEACT

(1 Ref 2-DEACT
[J RefJ- DEACT
I) Ref 2-DEACT

I ] Ref 2 - DEACT
II R«f 3
[I Ref 2-DEACT
I ] Ref 2 - DEACT
(] Ref 2-DEACT
II Refl
[) lUTI

tl R«fl
I) Ref2-RTHRM
II Rtfl

(1 R«fl
II Ref2-RLEAD

I) Refl
II Ref 2 - MERC; or RMERC
                                                                                   I I Ref 2 - RMERC
(I Refl
I) Refl
II Ref3
11 Ref 3
(I Ref3
[] Ref 3
[| Ref 3
II Ref3
See numerical iretunent nandird(t) In 40 CFR 261.41, Ttbh CCWE - CoariiBMnt Concenuuioai ia Wule Eared
See uchnotofy-bued iundird(>) in 40 CFR 26S .42, Table 2 - lecbootofy-bucd Standard By RCRA Wule Coda
See numerical Irulmem Baodard(t). 40 CFR 26S.43. Table CCW - ConeUuieB Con:eMration> ia Wtau
  CHECK HERE IF SPENT SOLVENT. CALIFORNIA LIST. OR F-. K-. P-. OR U-CODE WASTE, if CHECKED, COMPLETE
  PAGE 2.
                                                                  109

-------
Appendix 1
           n.      Spaat Solvent Wuu» F001 through F005

                   Spaa SolvaniWaeiaCode<<)-Check aD which apply (| F001 (|  F002 I] F003  11  F004 U F005
           m.
           IV.
                   0
                   1)
                   11
                   (1
                   II
                   I)
                   (1
                   I)
                   11
                   n
                   (i
                   n
                   (j
                   n
                   n
                   n
                   ti
                   ii
                   n
                   n
                   11
                    n
                    n
                    n
                    n
                    ii
                    n
                    (i
                    n
                    ii
o-Buryl alcohol
Carbon dimlfUc
Crceoli tad (and cretylic arid)
l,2-Dttaloroben»ene
2-Bhoxyedia«i>l or - 134 m»/L
Liquidl with PCB'i > or 50 ppm
                    I) Thallium > or - 130 mj/L
                    11 W.necoouinimHOC'1 > or - 1.000m»/kt
                    OUm taut Hiz»rdou4 Wuu> (F006-P012, F019-P02S. K-. U-. ud P^odti)
           EPA Hrardoui
            Watte Code
Wuuwucf or
NoowtiuwMer
5.UwrT*chaoU>tyCod«
fifippiic.bk-»t.R«f2)
R»f«r«oc«<»)
(Kef I. Rcf 2, and/or lUf 3)
           I I       CHECK HERE IF ADDITIONAL USTED WASTE CODES ARE PRESENT.  IF CHECKED. USE LDK1 CONTINUATION
                    SHEET.
           Reference!
           R« f 1:  See ouimric*) ireaUMai nandinKi) in 40 CFR 26S.4I, Table CCWE • Coaoiuant Coneemraiiaae in W«u Extract
           lUf 2:  Se. lechnolofy^aaad aundard(i) in 40 CFR 2M.42. Table 2 - Tecliaalofy-BaaedSuiidud By RCRA Wane Cooei
           Ref 3.  See numerical treaincm nandanld), 40 CFR 26S.43. Table CCW . Coaatituad ettetmuieat in Want
                                                                     no

-------