EPA-600/2-77-217
                                          December 1977
             URBAN RUNOFF TREATMENT METHODS

       Volume I - Non-Structural Wetland Treatment
                           by

        Eugene A. Hickok, Marcus C. Hannaman and
                     Norman C. Wenck
             Eugene A. Hickok and Associates
                Wayzata, Minnesota  55391
                   Grant No. S-802535
                     Project Officer

                      Hugh Masters
            Storm and Combined Sewer Section
              Wastewater Research Division
Municipal Environmental Research Laboratory (Cincinnati)
                Edison, New Jersey  08817
                This study was conducted
                   in cooperation with
           Minnehaha Creek Watershed District
                Wayzata, Minnesota  55391
       MUNICIPAL ENVIRONMENTAL RESEARCH LABORATORY
            OFFICE OF RESEARCH AND DEVELOPMENT
           U.S.  ENVIRONMENTAL PROTECTION AGENCY
                 CINCINNATI,  OHIO  45268

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                          DISCLAIMER

     This report has been reviewed by the Municipal Environmen-
tal Research Laboratory/ Cincinnati, U.S. Environmental Protec-
tion Agency, and approved for publication.  Approval does not
signify that the contents necessarily reflect the views and
policies of the U.S. Environmental Protection Agency, nor does
mention of trade names or commercial products constitute en-
dorsement or recommendation for use.
                              11

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                           FOREWORD

     The Environmental Protection Agency was created because of
increasing public and government concern about the dangers of
pollution to the health and welfare of the American people.
Noxious air, foul water, and spoiled land are tragic testimony
to the deterioration of our natural environment.  The complexity
of that environment and the interplay between its components
require a concentrated and integrated attack on the problem.

     Research and development is that necessary first step in
problem solution and it involves defining the problem, measuring
its impact, and searching for solutions.  The Municipal Environ-
mental Research Laboratory develops new and improved technology
and systems for the prevention, treatment, and management of
wastewater and solid and hazardous waste pollutant discharges
from municipal and community sources, for the preservation and
treatment of public drinking water supplies, and to minimize
the adverse economic, social, health, and aesthetic effects of
pollution.  This publication is one of the products of that re-
search; a most vital communications link between the researcher
and the user community.

     This report defines the role that wetlands play in the hydro-
logic cycle, the character and impact of urban runoff on wetlands
and the expected water quality changes by supporting wetland
biota with organics and nutrients inherent in the runoff as pollu-
tants.  Biological assessments detected no environmental impacts
on the wildlife or vegetation as a result of this project.
                                Francis T. Mayo
                                    Director
                   Municipal Environmental Research Laboratory
                               111

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                            ABSTRACT

      A major  concern  of  the Minnehaha Creek Watershed  District,
 a natural  watershed basin  encompassing the area  that drains
 into  the Lake Minnetonka - Minnehaha  Creek system,  near Wayzata,
 Minnesota,  is the water  quality  of its lakes.  A significant
 impact on  lake waters is known to be  caused by stormwater  run-
 off;  providing control and treatment  methods  from this pollu-
 tion  source is a large and complex problem.   The methods de-
 veloped by  this project  may be implemented as an urban storm-
 water runoff  control  practice in many of  the  urban  centers of
 the country that have unused adjacent wetlands.

      This project has demonstrated the treatability and effec-
 tiveness of non-structural methods to improve the quality of
 stormwater  runoff from urban areas using  natural wetlands.

      The wetland used in the study retained 77 percent of all
 phosphorus  and 94 percent  of the total suspended solids entering
 the site during the evaluation period.

      It has been shown that the  mechanism utilized  by  organic
 soils  in the  removal  of  nutrients and contaminants  is  the re-
 sult  of physical, biological and chemical mechanisms.

      The physical trapping of contaminants by organic  soils is
 the result  of  the characteristic fine  texture of  the material.
 The fine textures permit physical screening of sediment trans-
 ported to the  marsh and  also tend to  reduce the  velocity of
 groundwater movement.  The relatively  slow velocity increases
 the non-structural wetland treatment  methods.  This report can
 be used as  a guide in  the wise and prudent use and management
 of wetlands, especially  in urban and  developing  areas.   A de-
 tailed environmental  assessment indicated that no impacts were
 detected on the wildlife or vegetation as a result of  this
 project.

 This report was submitted in fulfillment of Grant No.  S-802535
 by the Minnehaha Creek Watershed District and their consultant,
Eugene A.  Hickok and Associates under the sponsorship of the
 U.S. Environmental Protection Agency.   This report covers the
period November,  1974 to October, 1975 and work was completed
 as of November, 1976.
                               IV

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                            CONTENTS

Foreword	iii
Abstract	iv
Figures	vi
Tables	viii
Abbreviations 	  ix
Acknowledgments	   x

     1.  Introduction 	   1
     2.  Conclusions	   3
     3.  Recommendations	   5
     4.  Background	   6
     5.  Site Description	13
     6.  Site Development and Instrumentation	26
     7.  Methodology	35
     8.  Results	38
     9.  Discussion	94

References	96
Appendices

     A.  Ecology Report - Phase I	99
     B.  Ecology Report - Phase II	108
     C.  Methods of Sample Collection and Analysis	115
     D.  Penman Method for Calculation of Evapotranspiration. 118

Glossary	120
                               v

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                            FIGURES

Number
   1    Location Map - Minnehaha Creek Watershed District. .   7
   2    Photographic Views of Lake Minnetonka and the
          Wayzata Wetland	   8
   3    Location Map - Wayzata Wetland 	  12
   4    Soils Map	14
   5    Stratigraphic Log of Wetland Soils 	  16
   6    Wayzata Wetland Watershed Boundaries 	  18
   7    Typical Photographic Views of Drainage Groups I - IV  19
   8    Groundwater Contour Map	  22
   9    Hydrologic Cycle 	  23
  10    Monthly Precipitation Distribution Minneapolis-
          St. Paul Area (1936-1975)	24
  11    Instrumentation of Watershed 	  27
  12    Instrumentation of Wetland 	  29
  13    Photographs of Instrumentation of Wetland	32
  14    Hydrograph - Wetland Discharge 	  43
  15    Evaporation Pan Data - Wetland vs. University of
          Minnesota, St.  Paul	44
  16    Pollutograph of May, 1975 Storm - Drainage Group II,
          Subwatershed II	  50
  17    Relationship of Wetland Outflow,  Ammonia Nitrogen
          Concentrations and Total Phosphorus Concentrations  54
  18    Groundwater Fluctuation - Observation Well 1 ....  57
  19    Carbon Dioxide Production -  Control Area, Stations
          7-12	61
  20    Carbon Dioxide Production -  24 Hours vs. 72 Hours,
          Station 7. .  .	62
  21    Microbial Counts vs.  Rainfall/Runoff Events -
          Stations 7 and 13.	64
  22    Depth to Groundwater - Stations 4 and 10	67
  23    Depth to Groundwater - Stations 2 and 8	68
  24    Carbon Dioxide Production -  Stations 4  and 10,
          24  Hour	69
  25    Carbon Dioxide Production -  Stations 4  and 10,
          72  Hour	70
  26    Surface Microbial Counts  - Stations 4 and 10 ....   71
  27    Subsurface Microbial  Counts  - Stations  4 and 10.  ..   72
  28    Carbon Dioxide  Production -  Stations 2  and 8,
          24  Hour	73
  29     Carbon Dioxide  Production -  Stations 2  and 8,
          72  Hour	74
                               VI

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                      FIGURES (continued)

Number                                                       Page

  30    Surface Microbial Counts - Stations 2 and 3	  75
  31    Surface and Subsurface Microbial Counts vs. Total
          Phosphorus Concentration in Soil Water - Station 6  77
  32    Surface and Subsurface Microbial Counts vs. Total
          Phosphorus Concentration in Soil Water -
          Station 10	78
  33    Surface and Subsurface Microbial Counts vs. Total
          Phosphorus Concentration in Soil Water -
          Station 5	79
  34    Phosphorus Adsorption Isotherms -  Stations 4 and 10.  82
  35    Total Coliform,  Total Suspended Solids and Bio-
          chemical Oxygen Demand Concentrations in Sump
          Discharge Water	84
  36    Total Coliform,  Total Suspended Solids and Bio-
          chemical Oxygen Demand in Outlet Discharge Water .  86
  37    Ammonia Concentration and Oxidation Reduction Po-
          tential in Sump Discharge.  .  . . . ,	87
  38    Ammonia Concentration in Soil Water - Stations
          3 and 9	, .	89
  39    Ammonia Concentration in Outlet Discharge	90
  40    Total Phosphorus Concentration  in  Sump Discharge . .  92
  41    Total Phosphorus Concentration  in  Outlet Discharge
          Water	93
                              vii

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                             TABLES

Number                                                       Pag(

   1    Watershed Characteristics - Impermeable Area	21
   2    Precipitation, November 1, 1974 - October 31,
          1975, centimeters	~q
   3    Runoff Coefficients	•  •  •  • 40
   4    Empirical Coefficient - Penman Equation 	  [45
   5    Evapotranspiration - Wayzata Wetland	46
   6    Wetland Flow Discharge	47
   7    Comparison of Stormwater Runoff Quality ..!!!!! 49
   8    Comparison of Annual Pollutant Loads	!  ! 51
   9    Annual Nutrient Inflows	!  !  ! 52
  10    Discharge Quantities From Wayzata Wetland
          November, 1974 - October,  1975	53
  11    Comparison of Average Heavy Metal Concentrations.  !  ! 55
  12    Comparison of Nutrient Concentrations  in the
          Groundwater	59
  13    Comparison of Heavy Metal  Concentrations in the
          Groundwater	59
  14    Vegetative Mass Production - Wayzata Wetland!  !  !  !  ! 80
  15    Phosphorus Adsorption Characteristics  - Wayzata
          Wetland Soils
                             Vlll

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                    LIST OF ABBREVIATIONS

ha        — hectare
ha-m      — hectare meter
ac        — acre
ac-ft     — acre foot
kg        — kilogram
yr        — year
Ibs       — pounds
cm        — centimeter
sq mi     — square mile
m         — meter
ft        — foot
cm/sec    — centimeters per second
gpd/sq ft — gallons per day per square foot
F         — Fahrenheit
C         — Celsius
in        — inch
1         — liter
gpm       — gallons per minute
mis       — milliliters
gal       — gallon
km        — kilometer
FITC      — fluoriscene isothiocyanate
                              IX

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                       ACKNOWLEDGMENTS

     The authors wish to acknowledge the support of the Board of
Managers of the Minnehaha Creek Watershed District including
Lawrence Kelley, President, David Cochran, Vice President,
H. Dale Palmatier, Secretary, James Russell, Treasurer and
Albert Lehman, Manager.  Special thanks are due Mr. Kelley who
spent numerous hours with the planning and fund raising ac-
tivities for the project.

     Appreciation is extended to those numerous private citizens
and foundations who supported the project financially and poli-
tically.  The cooperation of personnel and city council members
of the City of Wayzata made the acquisition and use of the pro-
ject site possible and is greatly appreciated.  The property
owners surrounding the site permitted access across their pro-
perty which is gratefully appreciated.  The assistance of Dr.
Edwin L. Schmit, Department of Soils Science, University of
Minnesota, St. Paul and Dr. James A. Jones, Department of
Biology, Macalester College, St. Paul, in the areas of micro-
biology and ecology are greatly appreciated.

     The suggestions, comments, encouragement and guidance pro-
vided by Mr. Richard Field, Chief Storm and Combined Sewer Sec-
tion, United States Environmental Protection Agency and Mr. Hugh
Masters, Project Officer, were invaluable.  The support of Mr.
Darwin R. Wright and Mr. William A. Rosenkranz during the de-
velopment stage of the project is also appreciated.

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                           SECTION  1

                          INTRODUCTION


      Wetlands  have been  identified as  having  a  certain  capacity
 for  the  renovation of  polluted waters.   Urban stormwater  runoff
 contributes  significant  pollution  loads  to  urban  lakes  and  an
 economically and ecologically acceptable method of  control  is
 required.  This study  was  designated to  evaluate  the  effective-
 ness  of  wetlands for water renovation  and to  identify the mech-
 anisms and processes which take place.

      A wetlands is a complex hydrologic, chemical and biologi-
 cal  system which can result in the transformation of  various
 elements in  runoff water into compounds  which may improve the
 quality  of the discharge water or,  to  the contrary, have  a
 significant  deleterious  effect on  the  quality of  the  water  be-
 ing  discharged.

      The wetland selected  for this  study has  a  total  watershed
 size  of  approximately  28.3 ha (70  ac) with  a  wetland  area of
 approximately 2.8 ha  (7  ac).  This  conforms to  the  10:1 ratio
 typical of many land-surface to water-surface relationships in
 the region.  The watershed has a well  developed drainage
 system with  much of the  area being  drained by storm sewers.
 Several types of urban land use exist.

      An environmental  inventory was taken before  and  after  the
 project and  observations of the wildlife and  vegetation have
 been  made.

      Flows into and from the wetland and groundwater  monitoring
 wells were analyzed for  a  variety of parameters from  November,
 1974  through May, 1976.

      The study included  intensive microbial monitoring to deter-
 mine  the microbiological activity of the wetland  and  its  impor-
 tance to the nutrient cycle.  A unique staining method called
 "fluoriscene isothiocyanate total count" (FITC)  was used which
 gives a one-step method of  counting the bacteria  population in
 soil  and water samples.  Microbial numbers together with nutri-
 ent loads and carbon dioxide production were  utilized to deter-
mine  the capacity of the microbial community  to utilize storm-
water loads.

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     The primary benefits from this study are the identification
and determination of the feasibility of improving the quality of
stormwater runoff by utilizing natural wetlands.  Scientific
data required to help justify the protection of natural wet-
lands were also obtained.

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                           SECTION 2

                          CONCLUSIONS
 1.  The mechanism for the renovation of stormwater by non-struc-
     tural wetlands appears to be a combination of physical en-
     trapment, microbial transformation and biological utiliza-
     tion.

 2.  The annual runoff coefficients ranged from 0.07 for the open
     space and single family drainage group to 0.32 for the shop-
     ping center and traffic corridor drainage group.

 3.  Groundwater discharge provides 18 percent of the total water
     runoff input to the Wayzata wetland.

 4.  The tributary phosphorus loading ranged from 0.11 kg/ha/yr
     (0.60 Ibs/ac/yr)  to 0.39 kg/ha/yr (2.1 Ibs/ac/yr)  from the
     undeveloped and single family drainage group to the shop-
     ping center and traffic corridor drainage group respective-
     ly.

 5.  Evaporation rates in the wetland are greatly reduced during
     periods when the vegetation is dense.

 6.  The Wayzata wetland retained 78 percent of all total phos-
     phorus and 94 percent of the total suspended solids enter-
     ing the site during the study period.

 7.  The Wayzata wetlands organic soil contained approximately
     2,868 kg/ha-m (780 Ibs/ac-ft) of phosphorus,  5.5 times
     the phosphorus holding capacity indicated by phosphorus
     isotherms for the soil.

 8.  There appears to be a net loss of ammonia from the wetland
     which is caused by the transformation of nitrogen  compounds.

 9.  Phosphorus and ammonia nitrogen concentrations of  the dis-
     charge water do not correlate for short term, day  to day,
     comparisons but do correlate seasonally.

10.  Discharge of nutrients from the wetlands is related to the
     seasons.

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11.  The water level management technique, where effective, did
     appreciably increase the surface microbial activity.

12.  Microbial activity decreased dramatically when wetland soils
     were submerged and become anaerobic.

13.  Microbial activity is significantly affected by soil temp-
     erature with higher activity during warmer temperatures.

14.  Surface bacteria counts appear very responsive to runoff
     events, possibly due to the phosphorus load, with counts
     increasing in  number after each event.

15.  The population of anaerobic organisms deep in the organic
     soils  [76 cm  (30  in)]  (76 cm)  illustrate a direct relation-
     ship to phosphorus  concentration.

16.  The microbial  activity in the wetland appears to be the
     initial and most important mechanism for removing phos-
     phorus from the soil water solution.

17.  Phosphorus appears to be the limiting nutrient during the
     summer when microbial growth conditions are optimum.

18.  Dewatering of  the  pilot zone produced approximately 2.4
     times the vegetative mass produced in the control zone.

19.  The biological assessments detected no environmental im-
     pacts on the wildlife or vegetation type and abundance as
     a result of this project.

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                           SECTION 3

                        RECOMMENDATIONS


1.  A general policy of wetland preservation and phosphorus re-
    moval with non-structural treatment methods should be adopt-
    ed.

2.  The drainage from selected wetlands should be managed and
    possibly be aerated before allowed to discharge to the re-
    ceiving body.

3.  Careful consideration must be given to the distribution of
    stormwater to wetlands.

4.  The Wayzata wetland study should be continued to determine
    nutrient transformations, ammonia to nitrate conversion, the
    phosphorus capture mechanisms and the hydrologic balances.

5.  Additional research and uniform procedures are required in
    the following areas:

    a.  Define the various factors of the hydrologic budget of
        wetlands including evapotranspiration rates, evapora-
        tion rates and groundwater movement.

    b.  Define the microbial activity during  aerobic and anaerobic
        conditions for typical wetland types.

    c.  Define the importance of the plant growth cycle and water
        level management techniques or changes in effluent water
        quality.

    d.  Define the treatment life expectancy  of the wetland and
        its benefits  and costs in stormwater  treatment.

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                           SECTION 4

                           BACKGROUND
      During the calendar years of  1974 and  1975 the Minnehaha
Creek Watershed District, in cooperation with the Environmental
Protection Agency, implemented a rigorous study designed to de-
termine the impacts of urban stormwater runoff on the wetlands
of the District.

      A wetland has been defined in the new  "Interim Classifica-
tion of Wetland and Aquatic Habitats of the  United States", by
the United States Fish and Wildlife Service  (1), as... "land
where the water table is at, near or above the land surface
long enough each year to promote the formation of hydric soils
and to support the growth of hydrophytes, as long as other en-
vironmental conditions are favorable".

      The specific wetland site was selected because it, in the
opinion of the researchers, best approximated a typical wetland.
See Figure 1, Location Map - Minnehaha Creek Watershed District,
for the location of the watershed in reference to the Minne-
apolis - St. Paul Metropolitan area and Figure 2, Photographic
Views of Lake Minnetonka and the Wayzata wetland.

      The Minnehaha Creek Watershed District encloses 47,760 ha
(184 sq mi) on the western edge of the Twin Cities Metropolitan
area and, since its formation, has been charged with the pro-
tection of the resources of the watershed.  Consequently, it
would naturally follow that the Minnehaha Creek Watershed Dis-
trict Board of Managers would seek definitive answers to the
following questions:

      1.   What role do wetlands play in the watershed's hydro-
          logic cycle?

      2.   What is the character of the runoff entering the wet-
          lands?

      3.   What impact does the runoff have on the wetlands?

      4.   What impact do the wetlands have on the quality of
          the runoff  waters?

      5.   Can wetlands be managed in order to enhance the quality

                                6

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  MOUND FILTE
  PLANT
                                     	j	ti	
Figure 1.  Location Map  -  Minnehaha Creek Watershed District

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a.  Lake Minnetonka
b.  Wayzata Wetland

Figure 2.  Photographic Views of Lake Minne-
           tonka and the Wayzata Wetland

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           of discharge waters?

       It was the objective of this project to provide answers to
 the above questions as completely as  possible and in a form that
 would assist others in the wise and prudent use of wetlands.

 OBJECTIVES

       The wetland project had three specific objectives that
 would dictate the wetland selected and formulate the study ap-
 proach.   Those objectives focused in  these principal areas:

       1.   Identification  and  characterization of the watershed
           ecosystems  including  the hydrologic balance and  the
           nutrient balance.

       2.   Interaction of  hydrologic and nutrient balances  with
           the wetland ecosystem including  water level,  microbial
           activity and nutrient discharge.

       3.   Implementation  and  evaluation of a controlled wetland
           ecosystem including microbial activity,  nutrient bal-
           ance and impacts.

 METHOD OF APPROACH

       The above  objectives were  accomplished in six  major  tasks,
 as  follows:

       Task I.   Develop  a  planning  and  control  technique  for the
       entire  project.

       Task II.   Select  a  wetland  for the project and acquire  ac-
       cess rights.

       Task III.   Design,  purchase,  construct and install the  in-
       strumentation and modifications  to acquire the  required
       data.

       Task IV.   Collect and analyze data, perform environmental
       assessments, modify data acquisition systems,  review data
       for  completeness and collect  additional data.

      Task V.  Data evaluation, statistical  data analyses and
      development of hydrologic and nutrient balances and models.

      Task VI.  Prepare a final report.

      These task breakdowns were used to develop a comprehensive
work plan which was used and refined as the project progressed.

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SITE SELECTION

      In view of the project scope, selection of a suitable wet-
land was critical.  It was paramount that all parameters in the
watershed ecosystem be identified and controlled.

      A program dealing with the implementation and evaluation of
a controlled ecosystem and a wetland is defined in the previous-
ly mentioned interim classification.  Therefore, an extensive
preliminary survey was made for several wetlands to select an
ideal wetland for the project.

      Four wetland sites were evaluated as potential sites.  The
final selection was based on 15 criteria.  These criteria in-
cluded:

      A.  Essential Characteristics:

          1.  Defined wetland.

          2.  Variety of urban  runoff quality (highway,  shopping
              center, commercial, residential, etc.).

          3.  Well defined watershed.

          4.  Well defined inlets.

          5.  Well defined outlets.

          6.  Public ownership.

          7.  Availability.

      B.  Desirable Characteristics:

          1.  Management size.

          2.  Accessibility.

          3.  Representative  wetland for  region  (10:1  ratio).

          4.  Availability of suitable  sampling  points.

          5.  Groundwater level  above lake level.

          6.  Sanitary  sewered region.

          7.  Suitable  wetland configuration  for management and
              control area.

          8.   Near laboratory facilities.
                               10

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      The selection was based upon the highest composite score.
The scoring was as follows:  Items 1 through 7 were given a value
range between 1 and 10 and items 8 through 15 were given a value
range between 1 and 5.

      Major faults encountered in evaluation of the four wetlands
were:  private ownership and poorly defined inlets and outlets.
Such wetlands were not acceptable for the project.  The Wayzata
wetland site, which had the highest composite score, was chosen
for the study.  See Figure 3, Location Map - Wayzata Wetland.

      The Wayzata wetland is located in the heart of the City of
Wayzata (population 4,500) a suburb in the Minneapolis - St.
Paul Metropolitan area.

      The wetland site is also located within the legal boundar-
ies of the Minnehaha Creek Watershed District and its drainage
is tributary to Lake Minnetonka.
                                11

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'%/jwATERSHiD
      BOUNDARY
**)/*
**
                                   WAYZATA
                                   WETLANO
      LAKE
      MINNETONKA
Figure  3.  Location Map - Wayzata Wetland
                      12

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                           SECTION 5

                        SITE DESCRIPTION
      The total watershed system utilized in the Wayzata wetland
project consists of an area of 29.4 ha (72.6 ac).  The total
sub-basin consists of 3.06 ha (7.55 ac) of wetland and 26.3 ha
(65.1 ac) of upland or tributary watershed.

SOILS AND GEOLOGY

      The area of the wetland project is covered by glacial drift
deposited by the Grantsberg sublobe of the late Mankato Glacia-
tion.  This drift is composed of relatively recent materials
derived through the rewashing of older deposits.  The parent
material for soils of the wetland watershed is glacial till,
glaciolacustrine deposits and organic material.

      Two major soils make up the wetland watershed, they are the
Hayden loam and the Cordova silty clay loam.  The remainder of
the soils in the watershed consist of either hydric soils or
areas of cut and fill.  See Figure 4, Soils Map, for the location
of the specific soils.

      The Hayden series consists of deep, well drained, loamy
soils that formed in loamy glacial till.  These gently sloping
to very steep soils are convex areas on knolls and hillsides as
shown in Figure 4.

      The native vegetation was mixed hardwood forest.  Much of
this forest has given to urbanization, however, several areas of
the watershed along the periphery of the wetland harbor trees
that appear to be remnants of the original hardwood forest.

      Hayden soils have high available moisture capacity and
moderate permeability.  The water table is at a depth below
1.5 m (5 ft) in all seasons.  Hayden soils have low organic
matter content and medium fertility.  The subsoil is generally
high in phosphorus.

      The Cordova series consist of deep, poorly drained soils
that formed in loam glacial till.  These soils are on broad
flats and in drainageways.  As illustrated in Figure 4, the
native vegetation is mixed hardwood forest.


                               13

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LEGEND

CO
Cu
HbB
HBC
H1B
Ma
                   Data from Soil Conservation Service
Cordorva silty clay loam
Cut and fill land
Hayden loam, 2 to 6 percent slopes
Hayden loam, 6 to 12 percent slopes
Heyder complex, 2 to 6 percent slopes
Marsh
Figure 4.  Soils Map
                             14

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       Cordova  soils have  high  available  moisture  capacity,  inter-
 nal  drainage is  slow,  and the  permeability  is  moderately slow.
 During the wet periods, the water  table  is  at  a depth of 30.5  to
 91 cm  (1  to 3  ft).  Fertility  and  organic matter  content are
 high.

       The remainder of the soils in  the  wetland watershed are  or-
 ganic  soils.   At this particular site  these soils are formed on
 Glaciolacustrine deposits.  The mineral  soils  underlying the
 organic soils  sediments are silty  clay in the  upper  61 to 150
 cm (2  to  5 ft) and silt loam below that  depth.  The  peat or or-
 ganic  soils of the wetland range in  thickness  from 15.0 cm
 (0.5 ft)  to over 6 m  (19.7 ft).  Values  for the percent of  or-
 ganic  matter of  each separate  soil profile  are also  shown.  See
 Figure 5, Stratigraphic Log of Wetland Soils,  for a  representa-
 tive log  of the  organic soils.

       The maximum percent organic  matter occurs at a depth  of
 approximately  50 cm  (1.7  ft).  It  is also interesting to note
 that the  percentage of organic matter  at the 400  cm  (13 ft)
 depth  is  32 percent.  The peat is  well supplied with calcium,
 but  it is low  in content  of available  potassium and  phosphorus.

       The importance of the above  information on  soils will be-
 come apparent  when groundwater quality and  quantity  is related
 to the soils.

 TOPOGRAPHY

       The topography of the area is a  result of a melting gla-
 cier.   The depression forming  the  wetland is probably the re-
 sult of stagnated ice.  The actual wetland  is centrally located
 and surrounded by moderately rolling terrain.  The maximum  re-
 lief is approximately 18.3 m (60 ft).

 VEGETATION

       The vegetation of the upland portion  of the  watershed
 basically consist of natural wooded areas with oak,  elm,  bass-
 wood,  maple and  ash as the main species.  Urbanization  has  re-
 placed most of the woods  with  lawns;  however, with the  excep-
 tion of the fertilizer applied, the change  in vegetation  has
 had little effect on the  underlying soil.

       The wetland has a dense  growth of natural vegetation  as
 high as eight  feet through the summer  season which produces a
 thick  vegetative cover.   See Appendix A  for  ecology  evaluations.
 Lush and varied,  this vegetation is comprised of  38  species.
 Reed canary grass, willows and dogwoods are most  conspicuous.
 Distribution of various other plant types is related  to soil
moisture conditions within the wetland.
                               15

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Depth
Centimeters

        50 —
       100 —
       150 —
       200 —
       250 —
       300 —
       350 —
       400
       450 —
       500 —
     Material
                          Peat, dark brown,  fibrous
                                   (Percent Organic
                                   (Matter
                                        69.4
Peat, orange -brown,
very fibrous
	 Muck, grayish, little  fiber


    Muck, black

    Peat, brownish, fibrous, becomes
    darker  & less fibrous with depth

__ Muck, black

    Muck, brown, trace of sand


__ Muck, light brown, silty
                          Silt, gray, some orange -brown
                          fibers
Clay, light gray, some sand
                                                                 88.2
                                        52.1


                                        39.3

                                        42.6


                                        3.4
                                                                 13.7
                                        32.0
       Figure 5.   Stratigraphic Log of Wetland Soils
                                  16

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      Predominant vegetation in the wetlands include:

      Grasses:  Phlaris  (reed canary);

      Cattails:  Typha latifolia;

      Forbes:  Equatorium pupureum  (purple boneset),
               Lythrum salicaria  (purple loosestrife);

      Trees and shrubs:  Cprnus (dogwood), Salix  (willows)
                         Ribes (black currant), and Sambucus
                         canadensis  (elderberry)

DRAINAGE

      The wetland is directly tributary to Lake Minnetonka and
has a total watershed area of 29.4 ha (72.6 ac).  The subwater-
shed boundaries and drainage system are generally well defined
with rolling topography  and urban development.

      The watershed was  divided into five drainage groups based
upon the degree of similarity of the various subwatersheds.  A
total of 13 subwatersheds made up the five groups.  See Figure 6,
Wayzata Wetland Watershed Boundaries.

      Drainage Group I includes subwatersheds 1, 2, 5 and 7.  It
has a total area of 8.57 ha (21.17 ac) or 29.9 percent of the
total watershed area.  The watersheds are typically undeveloped
or have single family homes on large lots, and are heavily wood-
ed.  A typical photographic view of Drainage Groups I - IV is
shown in Figure 7.  This group has very low population density.

      Drainage Group II  includes subwatersheds 3, 4 and 11 and
has a total area of 5.03 ha (12.44 ac), 17.1 percent of the
total watershed.  This group consists of single family homes on
small lots.  See Figure  7.  This group has the highest popula-
tion density of the wetland watershed.

      Drainage Group III includes subwatersheds 6, 8 and 9 and
has a total area of 4.66 ha (11.52 ac), 15.9 percent of the
total watershed.  This area is characterized by having approxi-
mately 50 percent occupied by small businesses located along a
major traffic corridor.  See Figure 7.  The remaining portion
consists of a very sparsely developed, heavily wooded area.  A
total of 44 percent of this drainage group consists of impervious
cover material such as roofs, parking lots or highways.

      Drainage Group IV  includes subwatersheds 10 and 12 and has
a total area of 8.05 ha  (19.88 ac), 27.4 percent of the total
watershed.  The area is  characterized by a major traffic corridor
(U.S. Highway 12).  See  Figure 7.   A total of 55 percent of the
area in Group IV has an  impervious cover.

                               17

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                                          Source:  Mark Kurd
Drainage Group

       I
      II
     III
      IV
       V
Subwatersheds

 1, 2, 5 & 7
  3, 4 & 11
   6, 8 & 9
   10 & 12
      13
Figure 6.  Wayzata Wetland Watershed Boundaries
                             18

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a.  Drainage Group I
b.  Drainage Group II

Figure 7.  Typical Photographic Views of
           Drainage Groups I - IV
                      19

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c.  Drainage Group III
d.  Drainage Group IV



Figure 7.  Continued
                     20

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      Drainage Group V includes subwatershed  13, the wetland it-
self, and has an area of 3.06 ha  (7.55 ac), 10.4 percent of the
total watershed.

      Each drainage group has an  associated runoff value at which
rate the subwatershed supplies runoff to the  wetland.

      Table 1 tabulates the amount of impermeable surface area in
each drainage group.  Drainage Group I has the least amount of
impermeable area, 3 percent, and  Drainage Group IV has the great-
est percent impermeable area with 55 percent.  Approximately 26
percent of the total wetland watershed has impermeable surfaces,
either in private drives, roof tops, highways or shopping cen-
ters.

    TABLE 1.  WATERSHED CHARACTERISTICS - IMPERMEABLE AREA
                           Total     Impermeable
Drainage        Sub-       Area         Area
 Group	Watershed	ha	    ha	
                                         Percent
                                       Impermeable
    I
   II
  III
   IV
    V
1,2,5&7
 3,4&11
 6,8&9
 10&12
  13
8.57
5.03
4.66
8.05
3.06
                    TOTAL  29.37
                          7.52
 3
17
43
55
                     AVERAGE  26
GROUNDWATER

      In the vast majority of wetlands, groundwater is the most
important physical and chemical factor of a particular wetland
ecosystem.  It will be illustrated later in this report that the
local groundwater table is in intimate contact with the Wayzata
wetland.

      The groundwater regime for the Lake Minnetonka area and
the wetland specifically is very complex in that the lake and
surrounding wetlands are hydraulically connected to the glacial
till aquifer.  The groundwater gradient in the glacial drift of
the wetland watershed is toward the wetland, consequently, the
wetland is a point of groundwater discharge.  See Figure 8,
Groundwater Contour Map.

      The glacial till aquifer is also a source of a limited
amount of groundwater recharge for underlying artesian aquifers.
It has been estimated that vertical permeability of the glacial
till is in the order of 4.0 x (10)~7 to 3.6 x (10)~6 cm/sec
(0.01 to 0.08 gpd/sq ft) with an average value in the order of
1.3 x (10)~6 cm/sec (0.03 gpd/sq ft) (2).  See Figure 9, Hydro-
logic Cycle.
                               21

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                               096.33
                               FLUME 4
   96.61
   FLUME
     -^
       \
                                                            O96.}|
                                                             FLUME 3
                                                  -A
                                                  PERIMETER OF WETLAND
        X
                          \   _^
                      ^-^:i1«*
NOTE:  GROUNDWATER ELEVATIONS
      ARE BASED ON LOCAL DATUM AND
      ON APRIL 1975  MEASUREMENTS
      QWATER EiEVA
                                       /
       WELl NUMBE

         DIRECTION OF FLOW
 Figure  8.  Groundwater Contour Map
                                 22

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A    06
                                         I
                                         1
                                         
                                        \
                                     3

                                     (0

                                     c
                                     <0
                                     'to
                                     0>
                                     *-<
                                     k.
                                     (0

                                     O)


                                     l_
                                     0)

                                     c
                                     3
                                                      0
                                                      •H
                                                      O
                                                      >i
                                                      u

                                                      o
                                                      •H
                                                      t^
                                                      O
                                                      rH
                                                      O
                                                      M
                                                      Tl
                                           (U
                                           Cn
                                           •H
23

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CLIMATOLOGY

      The study area is close to the geographical center of  the
continent; thus, the climate is predominantly the continental
type characterized by generally mild subhumid summers and rela-
tively long, severe winters.  All climate features tend to ex-
tremes.  Temperatures ranged from -36°C  (-34°F) in January,  1936
and January, 1970 to 42°C (108°F) in July, 1936.  Monthly pre-
cipitation ranged from a trace in December, 1943 to 20.4 cm
(8.03 in) in May, 1962.  Abrupt changes  in temperature and pre-
cipitation are common and are caused by  the pressure systems
that cross from west to east.  Because relief is low, topographic
influence on climate patterns is insignificant.  Rainfall is
greatest during the summer, when it is most favorable for vege-
tative growth.  The average growing season is 166 days.  About
55 percent of the annual precipitation is during the period May
through August.

      The seasonal areal distribution of precipitation is shown
in Figure 10, Monthly Precipitation Distribution Minneapolis -
St. Paul Area  (1936-1975).  The annual precipitation over the
wetland watershed area was computed to be 72 cm (28.3 in) during
the study period.
        20 r—
        10
                                                   I    I    I
           JAN  FEB MAR APR MAY JUN JUL  AUG SEP OCT NOV DEC

                             Time-Months

    Figure  10.  Monthly Precipitation Distribution Minne-
                apolis-St. Paul Area  (1936-1975)
                               24

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      Evapotranspiration is highly dependent on climatic events
and is an important factor in the water resources of an area.
The United States Geological Survey utilized two methods to ob-
tain evapotranspiration values for use in a water budget for
the metropolitan area.  Two methods were used, the Thornthwaite
and Manther method (3) and the energy balance  (4).

      The average annual evapotranspiration calculated for the
area was approximately 57.15 cm/yr (22.5 in/yr); the potential
evapotranspiration was approximately 62.23 cm/yr  (24.5 in/yr).

      The energy-balance method for determining evapotranspira-
tion yields a value of 57.15 cm/yr (22.5 in/yr) of evapotrans-
piration.

      Because these values represent a substantial portion of
the total water budget, a complete climatological station was
installed in the marsh in order to determine if the micro-climate
of the marsh ecosystem was of the same order of magnitude as the
previously calculated volumes.  The results of this climatologi-
cal station will be discussed in detail in the section on water
balance.
                              25

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                           SECTION 6

              SITE DEVELOPMENT AND INSTRUMENTATION
      Site development and instrumentation centered around ob-
taining quantitative data to establish the characteristics of
runoff and to construct a detailed nutrient and hydrologic bal-
ance for the wetland ecosystem.

      The second aspect of site development and instrumentation
was to determine the effectiveness of the wetland management
area.

TRIBUTARY WATERSHED

      A total of five 15.2 cm  (6 in) parshall flumes were in-
stalled in the watershed.  Four flumes were installed in repre-
sentative drainage systems that flow into the wetland.  The par-
shall flumes were capable of gaging the flow from as low as
0.063 I/sec (1 gpm) to as high as 12.6 I/sec (200 gpm) and is
shown in Figure 11, Instrumentation of Watershed.  The fifth
flume was installed at the outlet.  Each of the inlet flumes were
equipped with automatic samplers and flow recorders so as to
record as many runoff events as possible.  Preceding each flume
was a roughing filter of coarse gravel utilized to remove coarse
sediment from the runoff.

      For pre-selected runoff events, the inlet flumes were
equipped with automatic water quality samplers set to sample
every 15 minutes with a one hour composite and a 28-hour capa-
city.  A total of 33 runoff events were monitored.  A flume
was installed at the outlet of the wetland area and was equip-
ped with a continuous water level recorder.

      Sixteen 3.5 cm (1.4 in) outside diameter polyvinylchlo-
ride observation wells were installed in the wetland area and
ten observation wells were installed in the upland areas around
the wetland.  A typical observation well is shown on Figure 11.
The depth of well installation varied between 1.2 m (3.9 ft)
and 5.5 m (18 ft)  below land surface.  The wells were sealed
with sheet plastic at the soil surface to prevent surface
seepage from entering the well.  See Figure 12, Instrumenta-
tion of Wetland, for location of the observation wells within
                               26

-------
 a.   Inlet  Flume  -  Drainage  Group  II
b.  Typical Flume




Figure 11.  Instrumentation of Watershed
                        27

-------
 c.  Observation Well  14
                               d.  Wetland Weather
                                   Station
Figure 11.  Continued
                          28

-------
                   DIVIDER BOX
     PILOT
        II
      ZONE 4
                                         200 FT
                                         61.0M
CONTROL
    II
10  ZONE
                                 11
        o
 100 FT
  30.5M
       	 200 FT 	
              61.OM
       OBSERVATION WELL
              12
                                     100 FT
                                     30.5M
     QCLIMATOLOGICAL STATION
    =  UNDER DRAIN
      • OXIDATION REDUCTION PROBES
Figure 12.  Instrumentation of Wetland
                     29

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 the wetland area.

      A complete weather station was installed in the wetland at
 the transition of  grasses  to cattails and sedges to measure all
 climatological parameters.   Recording instrumentation included:
 temperature-humidity recorder,  precipitation gage,  two U.S. Wea-
 ther Bureau evaporation pans and two anemometers.   See Figure 11.

      Research indicates little  is known about the micro-climate
 of  wetlands.   The  dense vegetation shades the underlying soil
 and stifles the wind.   The  wetland is located in a  depression
 near Lake  Minnetonka,  a 5,700 ha (14,000 ac)  water  body.   These
 are important factors  in determining evapotranspiration rates in
 wetlands.

      A unique climatological monitoring system was  installed
 utilizing  two evaporation pans,  one in the wetland  and one in the
 adjacent uplands.   The wetland  pan was installed in such a man-
 ner that the  bottom of the  pan  was always in contact with the
 water table so that the temperature of the water in the evapora-
 tion pan would approximate  the  wetland soil water temperature.
 Two anemometers were installed  at this site.   A critical  low
 speed anemometer was placed at  a height of 0.5 m (1.6 ft)  and a
 second anemometer  at a height of 5.5  m (18 ft)  above the  wetland
 soil surface.

      Temperature and relative humidity recording devices  were
 also installed near the wetland  evaporation pan.

      The second evaporation pan  was  installed  in a  typical U.S.
 Weather Bureau fashion  in the uplands.   A time driven automatic
 precipitation  recorder  was  maintained  in the upland  site  and
 precipitation  was  recorded  in the wetland evaporation pan.

 WETLAND MANAGEMENT  AREA

      The perimeter  of  the Wayzata wetland is subject to aerobic
 states as the  water level drops  below  soil  surface between run-
 off  events  and therefore suitable  for  the  control of water
 levels.  Two inlets supply  runoff to this  area.  This  area is
 sufficiently isolated  so that slight modifications only were
 needed to establish a controlled surface water  system which  could
 be closely monitored.

     Approximately one  acre was  designated  as  the study area.
A pentagon configuration was  chosen for  the study area to  con-
 form with the natural geography of the area.  The area was sur-
veyed to establish water flow boundaries.

     Half of the area was designated the pilot  zone  to be  used
in the dewatering study, the other half to be used as a con-
trol zone.   Water tables, soils  and vegetation of the two  areas

                              30

-------
are similar.

      The study area was subdivided into twelve stations to ob-
tain more detailed observations of the water table and soil
activity.  Eight stations each were designated for the control
and the pilot area.  Four stations were located immediately
outside the perimeter of the study area to monitor the effects
of the water management process on the area outside.  Figure 12
shows the layout of the control and monitoring instrumentation.

      Oxidation-reduction potentials were determined by install-
ing five electrodes at 15 cm (0.5 ft) intervals at a depth of
2.5 m (8.2 ft) below the soil surface in the pilot station 3 and
control station 9.

      Chambers to monitor carbon dioxide generated by the soil
bacteria were installed at twelve stations within the study
area.  In situ chambers were constructed from 3.8 1 (1 gal)
glass jars with the bottoms removed.  The jars were inserted
5 cm (2 in)  into the soil.  Surface vegetation was removed from
within the chambers to minimize the influence of carbon dioxide
assimilation by plants.

MODIFICATIONS

      A system suitable for the programming of controlled water
levels was installed within the wetland.  All construction was
performed manually so as to minimize the impact on the natural
wetland.  Identical systems and methods were used to prepare
the control and the pilot zone.

      The modifications included:

      1.  A polyethylene barrier was used to line the channels
          from the parshall flumes to the wetland perimeter to
          prevent water penetration into the ground so that all
          recorded water volumes would enter the wetland as sur-
          face water.

      2.  A polyethylene barrier was buried to a depth of 91 cm
          (3 ft)  surrounding the perimeter of the control and
          pilot zone to prevent seepage from surrounding ground-
          water.

      3.  A divider box constructed of untreated redwood was in-
          stalled at the junction of the inlet with the wetland
          to equally split water volumes to the control and pi-
          lot zone or to direct the water flow as desired.   See
          Figure 13, Photographs of Instrumentation of Wetland.

      4.  An underdrain system of perforated plastic tiles was
          installed 91 cm (3 ft)  below the soil surface to

                               31

-------
          a.  Divider box
b.  Perforated Plastic Underdrain •*
Figure 13.  Photographs of Instrumentation of Wetland
                                32

-------
c.  Sump
d.  Sump Installed



Figure 3.3.  Continued

                                      \  *
                           33

-------
    direct water to the control sump.

5.  A sump constructed of 122 cm (48 in) corrugated pipe,
    152 cm (5 ft) deep with a sealed bottom was placed
    vertically in the ground to which the drain tiles were
    connected through control valves.  See Figure 13.

6.  An electrical sump pump was installed in the sump to
    pump water out of the dewatered area to a peripheral
    wetland area.  See Figure 13.
                         34

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                           SECTION 7

                          METHODOLOGY
MONITORING

Overview

      Sampling and analysis was performed periodically to deter-
mine the water quality in various parts of the wetland system
from November, 1974 to October, 1975.  The frequency of sampl-
ing and analytical parameters were determined from preliminary
sampling.  Water quality and volumes were monitored for all water
flowing into the wetland, out of the wetland as well as the
groundwater within and around the wetland.  Precipitation, evap-
oration, temperature, relative humidity and wind were monitored
during the study period.

      An intensive evaluation of the soil activity and soil en-
vironment in the wetland was performed for a six month period,
June, 1975 through November, 1975.  Parameters used to evaluate
the soil activity included direct counts of soil bacteria and
measurement of the generation of carbon dioxide by the soil
bacteria.

      Special emphasis was placed on data collection during the
summer months of June, July and August, 1975, when the wetland
system is most active, and the sampling frequency was increased
during this period.  The following paragraphs describe the moni-
toring which took place during the project.

Surface Water Quality

      Discrete and flow composited samples of four wetland in-
lets during runoff events were collected and analyzed for total
coliform, total suspended solids, ammonia nitrogen, total
phosphorus, biochemical oxygen demand and oxidation reduction
potential (list A).  A total of 130 runoff samples were col-
lected from 17 separate runoff events during the year November,
1974 - October, 1975.  Selected composite samples of the runoff
were analyzed for iron, copper, lead, zinc and nickel (list B).

      Samples of the discharge from the wetland were collected
and analyzed for the parameters in list A, November through
                               35

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 freeze-up on December 7, 1974 on a daily basis.  Daily sampling
 was resumed April 7, 1975, spring thaw, and continued until
 June 12,  1975.   Six-hour composite samples were taken from June
 12, 1975  through June 27, 1976 and twice daily (morning and
 afternoon)  samples were collected from July through October,
 1975.   Weekly composite samples from the wetland discharge were
 analyzed  for the list B parameters from April, 1975 to October,


       Samples were collected from the sump of the pilot zone on
 an hourly basis  from June 16 through July 12, 1975 (dewatering
 cycle  I)  and analyzed for the list A parameters.   During (de-
 watering  cycle  II)  July, 1975 through November, 1975  two samples
 were collected  daily and were analyzed for the list A parameters.
 Weekly composite samples from the sump were analyzed  for the
 list B parameters from June  16,  1975 through October, 1975.

 Surface Water Quantity

       Flows  were recorded at the wetland inlets during 19 separ-
 ate runoff events from May,  1975 to September, 1975.

       Flow from  the  wetland  outlet was recorded on a  daily  basis
 during November  and  December,  1974 and April and  May, 1975.
 The flow  was recorded continuously from June,  1975 to October,
 1975.

       The electrical consumption of the sump pumping  system was
 recorded  on  a daily  basis  during the month of July, 1975  to  de-
 termine the  volume pumped  during the dewatering process.

 Groundwater

       The observation wells  in the pilot and control  zones were
 sampled and  analyzed for the  list  A parameters 18  times.  The
 observation  wells were  sampled monthly from November,  1974
 through April, 1975,  twice per month during May and June, 1975
 and weekly during July  and August,  1975.

       Groundwater levels were measured at  the  observation wells
 in  the  pilot  and  control zones twice  a month from  November,  1974
 to June,  1975, daily during June,  1975  and  three times a week
 from July, 1975 to August  13, 1975.   The groundwater  level of
 the peripheral observation wells was  measured  during  Julv and
August, 1975.                                      ^    *

Soil Activity and Environment

      Carbon dioxide generation was monitored  at 12 stations four
days per week by 24-hour periods from  June,  1975 to September,
1975.  During October and November,  1975 carbon dioxide genera-


                               36

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tion was measured twice a week.

      Weekly, carbon dioxide generation was measured by 72-hour
periods from July, 1975 to September, 1975.

      Soil bacteria counts of surface soil samples were perform-
ed weekly from June, 1975 to mid-September, 1975.  Two soil
bacteria counts were performed per month from mid-September, 1975
to October, 1975.  Each of 15 stations was monitored 20 times.

      Soil bacteria counts of subsurface soils were performed at
stations 4, 5, 6 and 10 from June 16, 1975 to September 11, 1975
on a weekly basis.

      Soil temperatures were monitored at 12 stations on a daily
basis from July 7 to July 18, 1975.  Twice per week soil tempera-
tures were measured during the period from July 21, 1975 to
September 25, 1975.  During October and November, 1975 soil
temperatures were recorded weekly.

      Oxidation reduction potential of soils was monitored for
stations 3 and 9  (see Figure 12) at five depths from July 7 to
July 21, 1975 on a daily basis.  During the period from July 23
to August 13, 1975 the oxidation reduction potential was re-
corded three times per week.

Other Measurements

      Precipitation, air temperature, relative humidity and wind
velocity data were recorded continuously from November, 1974
to October, 1975.

      Pan evaporation data was continuously recorded from June,
1975 to October, 1975.   Daily manual measurements were also
taken during July and August, 1975.
                               37

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                            SECTION 8

                             RESULTS


 IDENTIFICATION AND  CHARACTERIZATION OF THE  WATERSHED

      The  identification  and characterization  of  the watershed
 can best be  analyzed  in three separate but  related categories,
 the hydrologic or water balance,  the nutrient  balance and the
 resulting  impacts on  the  wetland.

 Water Balance

      The  water balance of  the ecosystem  consists of the  follow-
 ing parameters:

      Water  Inflows (Gains)

           A-L = Precipitation directly on wetland
           B-L = Runoff from the tributary watershed
           Ci = Groundwater inflow

      Water  Outflow (Losses)

           AQ = Evapotranspiration (transpiration and evapora-
                tion)  from  the wetland
           B0 = Discharge at  outlet  of the wetland
           C0 = Groundwater seepage

      If the above terms  are  arranged  in  the following equation,
 the change in storage (AS)  of water  in the wetland can be de-
 scribed:

      (Ai + Bi + Cj.} - {AO  + B0 +  C0>  = AS  	  Eq.  1

      It can be stated that the value  for AS will  approximate
 zero because the water level in the wetland was the  same at the
end of the study as at the  start.

      It must be pointed out that  the  long term AS  for a particu-
lar wetland ecosystem will not be at equilibrium  because re-
search has shown that a wetland in the region accumulates or-
ganic matter at a rate of approximately 1 cm (0.4  in)  per year
(7), although the literature states a wide range of values
                               38

-------
-p
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-------
 (8,  9,  10).   Assuming that the  organic soil contains 80 percent
 moisture  it  can be  seen that the system will not be at equili-
 brium but will  actually be storing water.

      The three water inputs to the wetland are  direct precipita-
 tion, runoff and groundwater inflow and will be  discussed in the
 following paragraphs.

 Direct  Precipitation—

      During the period from November  1,  1974  to October 31, 1975
 a  total of 77.7 cm  (30.6  in)  of precipitation  fell  directly  on
 the  wetland  as  shown  on Table 2.   This is  5.8  cm (2.3  in)  above
 the  31  year  normal.   Of the  total  precipitation,  78 percent  fell
 during  the period April through August.

      The precipitation falling directly on the  wetland,  3.06  ha
 (7.55 ac)  contributed  a total of 2.38  ha-m (19.3 ac-ft)  of
 water to  the water balance.

 Runoff—

      The average runoff  coefficient for the entire watershed
 tributary to the wetland  was  0.156.

      The runoff coefficients ranged from  0.071  for Group  I  to
 a high  of 0.32  for Group  IV.  See  Figure 5  for the  location  of
 each drainage group and also  Table  3 for areas and  average run-
 off  coefficients.

                 TABLE  3.   RUNOFF COEFFICIENTS

Drainage
Group
I
II
III
IV


ha
8.57
5.03
4.66
8.05

Area
ac
21.17
12.44
11.52
19.88
Percent of
Tributary
Watershed
33
19
18
31

Runoff
Coefficient
0.07
0.09
0.09
0.32
Average for total tributary watershed - 0.156	

      Utilizing these general coefficients of runoff, a total of
3.19 ha-m (25.9 ac-ft) of water was added to the wetland water
balance equation via surface runoff.

Groundwater Inflow—

      The groundwater inflow into the wetland comes from basin
storage and remains relatively constant.
                               40

-------
     In order to determine the groundwater contribution to the
wetland area a flow net analysis was conducted using the follow-
ing equation:

     Q = KiA	Eq. 2

     Q = Flow, I/day  (gpd)
     K = Coefficient of permeability cm/sec  (gpd/ft )
     i = Hydraulic gradient
     A = Cross sectional area through which  flow occurs

     Permeability tests were conducted on two representative
groundwater monitoring wells.  The results of these tests indi-
cate that permeability of till was in the order of 5 x 10"4
cm/sec (10.64 gpd/ft^).

     A review of the groundwater levels recorded at the monitor-
ing locations during the study period illustrates that the
groundwater gradient tributary to the wetland remained relative-
ly stable at approximately one percent.  See Figures , page 22.

     Using these values in equation 2, the average daily ground-
water contribution to the wetland is approximately 0.38 - 0.50
I/sec (6-8 gpm) or 1.20 ha-m (9.7 ac-ft) annually.

     The permeability of the organic soils was not considered as
a factor in the groundwater contribution because much of the or-
ganic soils consisted of very fibrous peat which was extremely
permeable typical to those values reported by Boelter (11).

     Using a method developed by Kunkle (12) it is possible to
separate basin storage discharge or groundwater inflow from the
annual hydrograph.  Two assumptions are made in constructing the
line separating basin-storage discharge from the other runoff
components.  First, the minimum discharge values at the beginning
and end of the groundwater year are assumed to represent ground-
water discharge from basin storage.  This assumption is based on
the premise that at the beginning and end of the groundwater
year, groundwater storage is at a minimum.  Therefore, bank
storage has been depleted and, provided that there has been no
recent precipitation, all the discharge is coming from basin
storage.   The second assumption is that groundwater discharge
from basin storage varies only to a minor extent throughout the
groundwater year and that fluctuations tend to cancel one
another.

     The second assumption is most valid for the typical ground-
water year.  During a typical groundwater year the amount of dis-
charge is closely balanced by an equal amount of recharge.  This
phenomenon is observed when the minimum discharge values at the
beginning and end of the groundwater year are very nearly equal.
This fact is also exhibited by the relatively constant ground-

                               41

-------
water gradient in the till tributary to the wetland.

     Figure  14, Hydrograph - Wetland Discharge, illustrates  the
daily discharge plotted on a semi-logarithmic  scale.  This il-
lustration was used to evaluate the groundwater inflow  and wet-
land responsiveness to precipitation.

     The dashed line connecting the low flow at each end of  the
study period represents the groundwater discharge into  the wet-
land.  This value is approximately 0.38 I/sec  (6 gpm) or 1.19
ha-m (9.7 ac-ft) annually and agrees well with the groundwater
contribution calculated from the flow net analysis.

     The study period, November 1, 1974 - October 31, 1975,  was
chosen because it represented a groundwater year as illustrated
by Figure 14.  During November, 1974, September, 1975 and Octo-
ber, 1975 the discharge from the wetland stabilized at  approxi-
mately 0.38 I/sec (6 gpm).

     In summary the total water inputs to the  wetland ecosystem
water budget for the groundwater year is as follows:

     Precipitation          2.38 ha-m     19.3 ac-ft
     Surface Runoff         3.19 ha-m     25.9 ac-ft
     Groundwater Inflow     1.20 ha-m      9.7 ac-ft

                            6.77 ha-m     54.9 ac-ft

     Therefore, the total water input equalled approximately
6.77 ha-m (54.9 ac-ft) from November 1, 1974 through October
31, 1975.

     The second portion of the water balance consists of deter-
mining the water losses from the wetland.  These losses occur as
evapotranspiration,  groundwater seepage and discharge from the
wetland outlet.

Evapotranspiration Losses—

     Since the wetland is located in a depression, it was decided
to instrument the watershed with data collection equipment that
would provide the necessary input to calculate the evapotrans-
piration rate using the Penman method (13).

     The Penman equation is based on a complete theoretical ap-
proach,  showing that evapotranspiration is inseparably connected
to the amount of radiative energy gained by the surface.  See
Appendix D for equation.

     Results of the  wetland evaporation pan were somewhat star-
tling in the fact that the evaporation values during the height
of the growing season departed substantially from evaporation

                               42

-------
                                                   (1)
                                                  .a
                                                   o
                                                   w
                                                  •H
                                                   Q
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                                                   St
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MOld
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         43

-------
rates  recorded  by the University of Minnesota, St. Paul,  some
55 km  (34  mi) away.

     The values recorded during the entire year show little  ag-
reement with  the exception of a general decline during the sea-
son.   The  University  of Minnesota values were substantially
higher.  Figure 15, Evaporation Pan Data - Wetland vs. Univer-
sity of Minnesota, St.  Paul,  illustrates the difference in
evaporation rates.  It  is of  interest to note that the two
stations responded almost the opposite to the wet period  during
May and June, 1975 with wet periods tending to reduce the
University values for this period,  whereas the values for the
wetland increased.  The increase in the rate of evaporation  in
the wetland may be due  to a general warming as a result of the
runoff entering the wetland.   During the period July to mid-
September both  stations showed the  same response to the climatic
conditions.  However, a sharp increase in the rate of evapora-
tion was recorded at  the University of Minnesota station  from
mid-September through October,  whereas the wetland pan con-
tinued to decline.  There is  no apparent explanation for
this difference  in response to climatic conditions.
         20
         15
         10
      o
      c
      o
     +•>
      03
      I
      to
     111
      c
      to
     a.
                             / Climatological Year
                               1975 University of
                               Minnesota Pan,
                               St. Paul Campus
                               Wayzata
                               Wetland Pan
              _L
_L
                      _L
                             _L
                JL
                                     _L
                                                    JL
                                      J
           JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC
                            Time-Months

     Figure 15.  Evaporation  Pan Data - Wetland vs. University
                 of Minnesota,  St.  Paul
                               44

-------
     The total evaporation from the wetland during the period
November 1, 1974 to October 31, 1975 was 64.3 cm (25.3 in).  It
was not possible to compare this value directly with the Univer-
sity of Minnesota station because many of the months used in
this study were not recorded at the University of Minnesota
station.  At the end of May the vegetation was approximately
30 cm  (12 in)  in height, consequently, the vegetation probably
had less effect on the rate of evaporation; however, as the
season progressed, the height of vegetation has an apparent in-
verse effect on the rate of evaporation from the wetland.

     Utilizing the Penman equation (see Appendix D), the calcu-
lated rate of evapotranspiration for the wetland was approximate-
ly 58.59 cm (23.06 in) during the 1975 growing season.  Table 4
gives a complete list of coefficients utilized to calculate the
rate of evapotranspiration for the wetland.

      TABLE 4.  EMPIRICAL COEFFICIENT - PENMAN EQUATION
 Time
(month)
Radiation
(cal/cm~l
  day-2)*
 Relative
 Humidity
(percent)
Maximum
Possible
Sunshine
(hours)*
 Average
 Wind
 Velocity
(MPH-18ft)
  Average
  Monthly
Temperature
April
May
June
July
Aug.
Sept.
Oct.
  807.5
  913.3
  997.1
  928.4
  810.8
  663.8
  467.1
   70.0
   60.0
   68.9
   58.7
   66.6
   69.8
   58.0
  13.5
  14.9
  15.6
  15.3
  14.1
  12.6
  11.0
   11.2
    9.7
    8.9
    9.0
    7.8
    8.4
    9.4
    3.8
   15.5
   20.4
   24.6
   22.0
   14.3
   12.1
*Source;  U.S. Weather Bureau - Minneapolis-St. Paul Airport	

     Table 5 indicates the values of evapotranspiration at the
Wayzata wetland.  This value agrees with the values (55.9 - 59.4
cm) estimated for the area by the United States Geological Sur-
vey.  As a result of this work and work by Lawrence (14), it
should be pointed out that there is a need for research in this
aspect of a wetland water budget.  It was apparent to workers
in the wetland that noticeable differences in relative humidity
existed within the wetland depending upon the type of vegeta-
tion present.  The wetland area appeared to contain hot spots.
These observations were also made by Lawrence.  Empirical for-
mulas utilized to calculate the rate of evapotranspiration can
vary as much as 100 percent depending upon where and how the
data is gathered in a given wetland.  Daily pan evaporation
values for the wetland indicated stable conditions in that there
was little day to day fluctuation.  The wetland evaporation ap-
peared to respond more to seasonal warming and cooling.  The
wetland evaporation pan was in contact with the soil water sys-
tem and closely approximates the actual role of evaporation.
                               45

-------
          TABLE 5.   EVAPOTRANSPIRATION - WAYZATA WETLAND
                   Evapotranspiration         Evapotranspiration
   Month	(centime te r s)
April
May
June
July
August
September
October

5.10
9.78
11.38
14.04
9.17
5.36
3.76
58.59
2.01
3.85
4.48
5.53
3.61
2. 11
1.48
23.07
      Given  an  evapotranspiration rate  of 58.59  cm (23.07 in)  from
 a wetland area of  3.06  ha  (7.55  ac)  a  total of  1.79  ha-m (14.52
 ac-ft)  of water was  lost from the wetland through evapotranspira-
 tion  during the growing season,  April  1,  1975 to  October,  1975.

 Groundwater Losses—

      It can be assumed  that  there are  no  significant groundwater
 losses  from the wetland because  groundwater contour  maps pre-
 pared from  monitoring well data  indicate  that the wetland  area
 is a point  of  discharge for  the  local  glacial till.   Figure  8,
 page  22, illustrates the direction of  flow.  Consequently, the
 groundwater losses are  considered zero in the water  balance
 equation.

 Surface  Discharge—

     A  parshall flume with a  continuous water level  recorder was
 installed at the outlet of the wetland.   A total  of  5.44 ha-m/yr
 (44.17  ac-ft/yr) of water was discharged  from the  wetland  through
 the outlet.   See Table  6 for  monthly totals, and  Figure  10, page
 24, for daily  variations in discharge.

     It is  of  interest  to note the impact  the hot, dry summer had
on the discharge for the wetland.  As  can be seen  from Figure 14,
page 43, periods during early June, July  and August,  1975 the
evapotranspiration rate exceeded  the groundwater recharge rate
consequently reducing the  minimum  flow to less than  the esti-
mated base  flow of approximately  0.33 I/sec  (6 gpm).

     The total water losses from  the wetland ecosystem are as
tollows:

     Evapotranspiration (E.T.)      1.79  ha-m   14.52 ac-ft
     Discharged at Wetland  Outlet   5.44  ha-m   44.17 ac-ft

                                    7.23  ha-m   58.69 ac-ft

                               46

-------
                TABLE 6.  WETLAND FLOW DISCHARGE

Discharge
Year
1974
1974
1975
1975
1975
1975
1975
1975
1975
1975
1975
1975

*0utlet
some
Hectare-meter
Month (ha-m)
November
*December
* January
*February
*March
April
May
June
July
August
September
October

either completely frozen or
portion of the above months
0.13
0.002
—
—
0.015
1.69
1.19
1.48
0.43
0.33
0.09
0.08
5.437
frozen for

Acre-feet
(ac-ft)
1.06
0.02
—
—
0.12
13.70
9.69
11.98
3.49
2.69
0.75
0.67
44.17



Storage—

     Utilizing water balance Equation 1, page 38 /

Precipitation + Runoff + Groundwater - Outflow = Balance  (AS)

     {2.38 + 3.19 + 1.20} - {1.79 + 5.44} = 0.46 ha-m

it appears that 0.46 ha-m (3.45 ac-ft) was removed from wetland
storage during the study period.

Nutrient Balance

     The same basic equation utilized in the water balance is
also applicable to use in the nutrient balance.

     The following factors are considered part of the wetland
nutrient balance.

     Nutrient Inflows (Gains)

          Aj[ = Nutrients in the precipitation directly on wet-
               land
          Bi = Nutrients in the runoff from tributary watersheds
          Ci = Nutrients in the groundwater inflow
                               47

-------
     Nutrient Outflow  (Losses)

          A0 = Nutrients in the evapotranspiration  from  the
               wetland
          B0 = Nutrients in the discharge at the outlet  of the
               wetland
          Co = Nutrients in the groundwater seepage
          DO = Nutrients in materials removed from  the wetland

     Unlike the water balance, nutrient losses from evapotrans-
piration and groundwater seepage are not factors in the  total
nutrient budget.  No known nutrients are lost from  the wetland
as a result of evapotranspiration and no materials were  removed
from the study wetland.  Groundwater discharges to  the wetland,
therefore, there is no groundwater seepage from the wetland.
Consequently, the nutrient balance would be as follows:

     {Ai + Bi + Gil - B0 = AS 	 Eq. 3

     It is one of the primary objectives of this report  to de-
termine the relative value of AS.  It has been assumed simply
because of the accumulation of organic matter that AS will show
a net gain in nutrients in the wetland.  However, the relative
magnitude of change in AS is the important aspect of the study.

Precipitation—

     Research has indicated that precipitation contains  small but
finite amounts of potential nutrients.

     A number of studies (15,  16, 17, 18)  indicates that the
total phosphorus occurring in precipitation varies between 0.002
mg/1 to 0.03 mg/1.   With the exception of the data collected by
Krupa (18), the above results were obtained from relatively un-
developed areas.

     Assuming a mean concentration of 0.03 mg/1 for phosphorus,
0.75 mg/1 for ammonia nitrogen concentration and 1 mg/1 for
total suspended solids, the following nutrients were added to
the wetland nutrient budget by precipitation:

     phosphorus, 0.7 kg/yr (1.6  Ibs/yr);
     ammonia nitrogen concentration,  17.8 kg/yr (39.3 Ibs/yr);
     and total suspended solids,  24 kg/yr (52 Ibs/yr)

Runoff Quality—

     The quality of the runoff water which reaches the wetland
from the area tributary is variable,  and appears to be a func-
tion of land use (impermeable  area)  and season of the year.

     In terms of land use,  drainage group  II consists of single

                              48

-------
family, small lots and the highest average concentration of
total phosphorus and ammonia nitrogen concentration of the four
drainage groups tributary to the wetland area.  Whereas drainage
group IV, shopping centers, etc. (56 percent impermeable) had the
lowest average concentration as shown in Table 7.

	TABLE 7.  COMPARISON OF STORMWATER RUNOFF QUALITY
            SPRING, 1975
SUMMER, 1975
FALL, 1975
Drainage   TP   NH3-N  TSS   TP   NH3-N  TSS   TP   NH3~N   TSS
 Group    mg/1  mg/1  mg/1  mg/1  mg/1  mg/1  mg/1  mg/1   mg/1
I 2.2 3.33
II 2.4 3.87
III 2.0 2.85
IV 1.9 2.55
Average 2.1 3.15
780
559
580
614
633
NOTE: Above concentrations
0.
0.
0.
0.
0.
37
73
22
09
35
are
4.
5.
5.
2.
4.
13
44
13
86
39
1200
3800
374
200
1394
0.
0.
0.
0.
0.
30
42
22
25
30
4.
4.
4.
3.
4.
33
97
00
81
28
70
60
68
100
75
based on weighted values
       calculated from specific runoff events that occurred
       during the study period.

       TP    = Total phosphorus
       NH3-N = Ammonia nitrogen
	TSS   = Total suspended solids	

     Because of the weather that was experienced during the win-
ter of 1974-1975, no runoff occurred from December until April,
consequently, quality values were not assigned for a winter
period but were included in the spring values.

     As can be seen from Table 7, a great deal of variation
occurs in the quality of runoff water as a result of seasonal
ranges.  The highest phosphorus values were recorded during the
April runoff which included the time period December through
May, with the greatest concentration running off with early
rains and snow melt.  However, as illustrated by Figure 16,
Pollutograph of May, 1975 Storm Drainage Group II Subwatershed
II, high levels of phosphorus still occurred late in May.

     During the summer months, June through August, the level of
phosphorus in the runoff dropped substantially.  However, the
relative position of the various drainage groups in respect to
total concentration remained the same with Group II still showing
the highest values.

     The phosphorus values during the fall months, September
through November, generally equalized for all of the drainage
groups.

     Drainage Group II recorded the highest average concentra-
                               49

-------
 000
                       TOTAL SUSPENDED SOLIDS (TSS)
               i    N.   I	I	1
                           50   60    70   80   90   100
                                      AMMONIA NITROGEN (NH3)
           ,0   20   30    40    50   60   70   80   90   100
20 2  2 20
 10  1 1 10
 0000
Figure 16.   Pollutograph of May,  1975 Storm -
             Drainage Group II,  Subwatershed II
                        50

-------
tion for ammonia nitrogen concentration, during the spring  sea-
son, however, during the summer and fall season, this correla-
tion did not exist.

     A comparison of annual quantities of pollutants delivered
to the wetland by the various drainage groups is presented  in
Table 8.

	TABLE 8.  COMPARISON OF ANNUAL POLLUTANT LOADS	
                  TotalAmmoniaTotal Suspended
Drainage        Phosphorus        Nitrogen             Solids
 Group	(kg/ha/yr)	(kg/ha/yr)	(kg/ha/yr)

    I              0.11             0.34                84
   II              0.17             0.54               241
  III              0.13             0.47                54
   IV              0.39             1.13               163

Weighted Average   0.21	0.64	133. 8	

     Drainage Group IV, shopping centers, has the highest annual
contribution of nutrients followed by Drainage Groups III,  II and
I, respectively.

     Keup  (19) reviewed the sources of phosphorus in flowing
water based on the contributing watershed area, and found the
areal contribution to vary between 0.001 and 0.026 kg/ha/yr
(0.006 and 0.14 Ibs/ac/yr).  In general, the more densely popu-
lated agricultural areas of the Midwest were highest.

     The average phosphorus value of the runoff from the study
area is 0.21 kg/ha/yr (1.13 Ibs/ac/yr).  This agrees with the
findings by Keup and also results by Sorenson (20).  Sorenson's
findings indicate that the average annual contribution to French
Lake, a drainage area approximately 5.6 km  (3.5 mi) west of the
project area, was approximately 0.21 kg/ha/yr (1.13 Ibs/ac/yr).
The French Lake watershed is similar to the Wayzata wetland
watershed.

Groundwater Contribution—

     As illustrated earlier, the groundwater contribution to the
wetland area remained relatively constant during the entire
period of investigation.  However, the values for phosphorus and
ammonia nitrogen concentration were variable.

     Groundwater quality tributary to the wetland was establish-
ed from observation wells located up gradient from the wetland
and in mineral soils.  See Figure 12, page 29, for location of
the observation wells.
                                51

-------
      The phosphorus values recorded in the observation wells
 varied from a low of 0.06 mg/1 to a high of 18.0 mg/1 with an
 average value of 2.2 mg/1.

      As mentioned earlier, the soils that make up the tributary
 watershed were deposited by the Grantsberg sublobe, a material
 naturally high in phosphorus.

      Routine groundwater sampling of shallow wells in the Lake
 Minnetonka area commonly encounter wells having phosphorus values
 in this range (21).

      The ammonia nitrogen concentrations in the observation
 wells varied from 1.9 mg/1 to 30.0 mg/1 with an average value of
 8.3 mg/1.

      As a result of those observations it has been calculated
 that the groundwater inflow supplied 26.6 kg (58.7 Ibs)  phos-
 phorus and 100.5 kg (221.6 Ibs)  ammonia to the wetland during
 the period of study.

      Total suspended solids were not determined for the ground-
 water contribution  because the observation well screen (slotted
 pipe)  would not effectively screen the organic soil out during
 pumping.   The normal contribution from this source is low.  The
 total nutrient inflow into the wetland as a result of direct
 precipitation, stormwater runoff and groundwater discharge for
 ammonia,  phosphorus and total suspended solids is shown in
 Table 9.
               TABLE  9.  ANNUAL NUTRIENT  INFLOWS
                   Phosphorus
           Ammonia-N
                Total Suspended
                     Solids

Precipitation
Surface Runoff
Groundwater
kg/yr
0.7
33.8
26.6
Ibs/yr
1.6
74.6
58.7
kg/yr
17.8
103.3
100.5
Ibs/yr
39.3
227.8
221.6
kg/yr
24
17010

Ibs/yr
52
37500

Total Inflow      61.1
Nutrient Outflow—
134.9
221.6
                                           488.7   17034   37552
     As expressed in the nutrient balance equation, the only
means by which nutrients leave the wetland is in the discharge
water passing through the outlet.

     Discharge flows were recorded and water quality sampling
and analyses were performed.  Nutrient quantities have been de-
termined from composite samples as shown in Table 10.
                               52

-------
       TABLE  10.   DISCHARGE  QUANTITIES FROM WAYZATA WETLAND
                        NOVEMBER,  1974 -  OCTOBER/  1975
Month
NOV
DEC
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
Total
Phosphorus
(kg)
0.29
0.004
0.02
3.28
2.56
4.38
2.09
0.38
0.05
0.14
13.19
Ammonia
Nitrogen
(kg)
1.36
0.04
1.00
73.95
85.47
103.01
44.20
6.91
2.01
1.31
319.26
Total Suspended
Solids
(kg)
36.48
1.33
0.47
209.31
213.19
176.90
240.41
120.75
8.48
17.65
1024.97
Water
(kg(10)6)
1.31
0.03
0.15
16.84
11.96
14.77
4.30
3.32
0.93
0.82
54.43
     The table illustrates the monthly discharge of phosphorus,
ammonia nitrogen concentration and total suspended solids  from
the Wayzata wetland.  The seasonal variations are very similar
to those exhibited in runoff quality.  Figure 17, Relationship
of Wetland Outflow, Ammonia Nitrogen Concentrations and Total
Phosphorus Concentrations, shows the relationship to outflow,
ammonia nitrogen concentration and total phosphorus to time.

Removal—

     Completing the nutrient balance for phosphorus it can be
illustrated that for the study year, November, 1974 through
October, 1975, 78 percent of all phosphorus entering the wetland
was retained in some form.  Net gain in wetland is calculated to
be 47.9 kg/yr.

     The ammonia nitrogen balance indicates that greater quan-
tities of ammonia nitrogen left the wetland than entered the
system.  Net loss from the wetland would be 97.3 kg/yr.

     The results of the ammonia nitrogen values will be dis-
cussed in greater detail in the following section, however, it
appears that the increased ammonia nitrogen in the discharge
water is the result of the transformation of nitrogen compounds.

     Completing the balance for total suspended solids shows
that 94 percent of the total suspended solids entering the wet-
land system are retained, i.e., 16,009 kg/yr.

     The total suspended solids component of urban stormwater
runoff is often the parameter which exceeds effluent limitations,

                               53

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                                                                         •H
                                 54

-------
 therefore,  the  removal  efficiency  is  an important aspect of the
 wetland  system.

 Heavy  Metals—

     The average  concentrations  of heavy metals;  zinc,  lead,
 copper and  cadmium for  the  stormwater runoff  and  the  outlet from
 the wetland are shown in  Table  11.  The table shows that the
 runoff from highway and shopping center land  use  has  signifi-
 cantly higher concentrations  of  all the metals than the unde-
 veloped  and large  residential land use.   The  table also shows
 the average concentrations  of the  metals in discharge from the
 wetland.  The reduction in  concentration of all the metals but
 cadmium  appears significant.

   TABLE 11.  COMPARISON  OF AVERAGE HEAVY METAL CONCENTRATIONS
Drainage
Group
Zinc
yg/i
Lead
yg/i
Copper
yg/i
Cadmium
yg/i
I - Undeveloped and resi-
dential large lots
II - Single family on
small lots
III & IV - Highway and
shopping center
Wetland Outlet

10

11

15
2.2

26

26

71
2.5

12

19

19
3.3

0.4

0.9

1.4
0.3

Wetland Ecosystem

     The interactions of the water and nutrient balances within
the wetland ecosystem including water level, water quality, nu-
trient discharge and microbial activity are discussed in this
section.

     The Wayzata wetland exists because the rate of deposition
of organic matter exceeds the rate of decomposition.

     It has been established (7)  that the rate of accumulation of
organic matter in a wetland at a similar stage of development
was approximately 1.3 cm/yr (0.5 in/yr).

     It should be recognized that the rate of peat accumulation
is not a uniform process but rather depends on many factors,
each of which influences the rate and amount of accumulation.

     Soper (22) concluded that in the lake states region of the
United States, organic deposits which accumulate in ponds or
lakes generally go through the following succession stages:

     1.  Stonewort-waterweed stage (Chara-Philotria associes),
     2.  Pondweed-water lily stage (Potamogenton-Nymphaea

                               55

-------
          associes),
      3.   Rush-wild rice  stage  (Scirpus-Zizania associes),
      4.   Bog-meadow  stage  (Carex associes),
      5.   Sphagnum-bog heath  stage (Andromeda-Ledum associes),
      6.   Tamarack-spruce stage (Larix-Picea  associes).

      The  rate  of  deposition  of organic matter  is  considerably
 slower in the  first  three  pond stages  than in  the latter  three
 bog  stages.  Accumulation  of organic matter  reaches its great-
 est  rate  in  the sphagnum-bog heath stage.  The Wayzata wetland
 is nearing the end of the  bog-meadow stage.

      Groundwater  or  saturated  soil conditions  and the resulting
 control they have on the microbial activity  and the decomposi-
 tion of the  organic  matter is  in part  the cause for the exist-
 ence of the  wetland.

      With increased  activities of man,  the wetland condition has
 been altered by a restriction  that has  been  formed by the  con-
 struction of LaSalle Avenue  along the  southern boundary with an
 outlet consisting of 25  cm (10 in)  clay tile.   The result  of
 these alterations is to  generally lower the  normal seasonal
 water level, resulting in  greater stormwater storage capacity.
 To some degree, this increases the retention time of the  storm-
 water in  the wetland,  however,  resulting water level fluctuation
 is in excess of those that occurred naturally.  The fluctuation
 is illustrated in Figure 18, Groundwater Fluctuation - Observa-
 tion Well  1.

      Groundwater  observation well  1 is  located near the entrance
 of the pilot zone and has  a  ground elevation of 29.2 m  (95.80
 ft).  This is  approximately  0.70  m (2.3  ft)  above  the invert
 elevation of the  outlet  flume.

      As illustrated  in Figure  18,  the groundwater  levels in the
 wetland are  very  responsive to precipitation and  runoff events.
 The  maximum  fluctuation  recorded  during  the  study  period was
 0.46  m (1.5  ft) from a low elevation on  December  30, 1974  to a
 high  elevation on June 17,  1975.   The water  level  elevations re-
 corded at observation well 1 were  generally  0.31 m (1 ft)   above
 those recorded at the outlet,  indicating a hydraulic gradient of
 approximately  0.0014.

     The wetland or organic soils  are the result of  the deposi-
 tion of plant and other  organic material at  a  rate  greater than
 the  decomposition rate.  These plant materials when  first de-
posited contain substances  readily used and  hence  rapidly de-
 composed by microorganisms  to meet demands for  the  carbon and
energy needed in their growth.   With the readily available
 components used up in a  few days to a few weeks, the bulk of the
residues are degraded or partially degraded  at  a slower rate.
Cellulose components, for example, are  broken down  relatively

                               56

-------
          9aoo r-

L»
^^
LU
UJ
LL
_J
UJ
UJ
_J
DC
UJ
5
£
95.80
95.60

95.40
9520


95.00


94.80


                                               *
          94.60 -
          94.40 -
          94.20  -
          94.00
                  Ill
I    I   I    i
               NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP OCT
                             Time -Months
         Figure 18.  Groundwater Fluctuation - Observation
                     Well 1
completely and rapidly, whereas  lignin  and  lignified  material  is
modified slowly over periods of  months  and  years.   The  more  re-
sistant organic matter which thus slowly accumulates  serves  as
not only the nutrient base for microorganisms, but  a  physical
base as well.  Root penetration  into the accumulating organic
matter provides microorganisms with more available  organic
materials than leak out of the roots or are contributed when
roots die.  Roots also serve to  introduce oxygen into the or-
ganic environment close to the root surfaces.

     The high moisture content and the compact structure of  the
organic soil allow surface layers to become slowly  aerated as
the water table drops.  Under these conditions fresh  organic
matter is utilized by aerobic microorganisms with concomitant
consumption of oxygen, leading to the depletion of  oxygen in the
saturated organic soil.  With oxygen consumed and respiratory
carbon dioxide released, the saturated organic soil becomes
anaerobic, and the microbiological activity is continued only
by those forms that can grow in  the absence of oxygen.
                               57

-------
      Anaerobic metabolism results in only partial decomposition
 of the organic environment, and it follows that the fresh resi-
 dues of one year become deposited on the still only partially
 degraded remnants of previous years.

      The microbial population of the wetland is in equilibrium
 with the organic soil environment.  The equilibrium is manifest-
 ed in terms of population density, the magnitude of which is de-
 termined largely by the nutritional availability of the organic
 matter.  A change in the environment in the form of fresh plant
 residue additions (autumn leaf fall, frost-die-back)  will be re-
 flected in a sharp increase with population density.   A less pro-
 nounced change occurs with slow aeration and will be more evi-
 dent as a change in the nature of the microbial population than
 as a marked population increase.

      The quality of the groundwater in the wetland was extremely
 variable for all parameters analyzed.   Table 12 presents the
 concentration of ammonia nitrogen and total phosphorus measured
 in observation wells  1,  5  and 9.   The ammonia nitrogen concentra-
 tion in observation well 1 varied from a low of 1.61  mg/1 to 15
 mg/1.   Observation well 5,  located in the pilot section, has the
 smallest range of concentration,  from 7.19 mg/1 to 24.29 mg/1,
 but had the  highest average concentration of ammonia  nitrogen,
 15.19  mg/1.   Observation well 9  showed the greatest range in
 concentration of ammonia nitrogen from 5.7 mg/1 to 28.5 mg/1.
 Observation  well 9  is  located in  the control section.   Observa-
 tion wells  1 and 9  averaged 5.78  mg/1  ammonia nitrogen concen-
 tration and  11.95  mg/1,  respectively.

     Observation well  1 recorded  the lowest total  phosphorus
 concentration range from 0.01 mg/1  to  0.76  mg/1 with  an average
 concentration of 0.23  mg/1.   Observation  well 5 had the highest
 average total phosphorus concentration,  0.85  mg/1  with a range
 of  0.07 to 2.63  mg/1.  The  total  phosphorus  concentration
 in  observation well 9  ranged  from 0.09  mg/1  to  1.66 mg/1 with
 an  average concentration of  0.62  mg/1.

     A  statistical analysis did not  reveal  any  correlation be-
 tween the total  phosphorus and ammonia  nitrogen values  recorded
 in  the  groundwater.

     Table 13 indicates little change in heavy  metal concentra-
 tions during  the study period in  the groundwater of the  wet-
 land.  The lead  concentration ranged from <0.1  yg/1 to  0.8 yg/1
 and  zinc concentrations ranged from 0.01 yg/1 to 5.0 yg/1.

     The importance of the microorganisms as agents of mineral-
ization and degradation, in natural environments is amply recog-
nized  (23).  When it becomes of interest to define these  func-
tions in relation to a particular environmental situation, cer-
tain inherent difficulties must be recognized.  Microorganisms
                               58

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        TABLE 12.  COMPARISON OF NUTRIENT CONCENTRATIONS
                            IN THE GROUNDWATER

Observation
Well 1
Date
11-5-74
12-13-74
12-30-74
1-29-75
2-17-75
3-3-75
3-11-75
4-1-75
5-15-75
5-27-75
6-6-75
6-16-75
7-2-75
7-11-75
7-18-75
8-7-75
11-4-75
Average
NOTE: TP
TP
mg/1
0.18
0.01
0.01
0.01
0.76
0.37
0.06
0.26
0.22
0.62
0.02
0.67
0.13
0.10
0.16
0.07
0.19
0.23
= Total
NH3
mg/1
10.13
1.61
2.76
2.19
4.30
4.76
1.94
5.50
4.50
14.02
7.77
3.10
15.00
4.95
9.19
5.17
3.03
5.88
phosphorus
Observation
Well 5
TP
mg/1
0.26
0.81
2.63
0.30
2.05
—
—
—
0.87
0.29
0.53
1.34
0.97
0.32
0.28
0.07
1.17
0.85

NH3
mg/1
7.19
20.31
13.68
15.31
17.09
—
—
--
11.0
21.03
24.29
7.62
23.31
13.00
15.91
10.25
8.28
14.88

Observation
Well 9
TP
mg/1
0.28
0.66
1.66
0.68
0.33
—
—
—
0.50
0.09
0.15
1.50
0.42
0.19
0.72
0.11
1.34
0.62

NH3
mg/1
8.17
6.67
8.90
12.19
11.96
—
—
—
10.00
28.50
11.77
5.71
16.31
14.38
16.38
6.50
7.83
11.81

NH^ = Ammonia nitrogen

      TABLE 13.  COMPARISON OF HEAVY METAL CONCENTRATIONS
                            IN THE GROUNDWATER

Observation


Date
1-29-75
2-17-75
3-3-75
4-17-75
5-15-75
5-27-75
7-11-75
Average
Well
Lead
yg/i
0.20
<0.20
0.40
<0.10
<0.20
0.10
<0.10
0.19
1
Zinc
yg/i
0.60
1.70
5.00
0.02
1.70
0.05
0.06
1.30
Observation
Well
Lead
yg/i
__
<0.20
—
0.10
0.10
—
<0.10
0.12
5
Zinc
yg/i
_ _
0.40
—
0.75
0.04
—
0.01
0.30
Observation
Well
Lead
yg/i
<0.20
0.20
__
0.80
<0.10
—
—
0.32
9
Zinc
yg/i
0.70
0.80
—
0.24
0.03
—
--
0.44

are nondescript morphologically, but extremely diverse,  flexible,
and responsive in their metabolic activities.  These properties
combined with the extremely small size of the microorganisms  and
                               59

-------
 the extreme complexities of natural environments sharply limit
 the analytical approaches which are both feasible and practical.

      A significant indicator of microbial activity in natural
 environments is the amount of carbon dioxide evolved per unit
 time and the number of bacteria in the microbial environment.
 These parameters are especially useful because they reflect an
 overall summation of metabolic rates of a diverse population,
 and provides an indication of the amount and degradability of
 the major organic materials.  Because the usual routine measure-
 ment of carbon dioxide evolution is subject to many shortcomings,
 close attention was paid to the design of the carbon dioxide ex-
 periment and to analysis of the resulting data.

      The carbon dioxide evolved from the soils ranged from 7 to
 310 mg per day for the 24-hour trials to 260 mg per day for the
 72-hour trials.  The daily average levels were lower for the 72-
 hour trial than the 24-hour trial.  This indicates  that atmos-
 pheric carbon dioxide made significant contributions to measure-
 ments.   The 72-hour chambers were exposed one time,  in the ini-
 tial preparation for a sampling,  to the atmosphere  at which time
 air filled the chamber before it  was sealed.  Values obtained
 over the 72-hour period were averaged and divided by three to
 obtain the 24-hour value.   The atmospheric contribution would
 thus be one-third the amount as for the 24-hour samplings.   The
 longer trial  period should,  therefore,  be a more accurate mea-
 sure of the actual carbon  dioxide production by the  micro-flora.
 The 24-hour samplings are  important in  monitoring short-term
 fluctuations  in activity and are  important in that  the daily
 fluctuations  are  illustrated.   Unfortunately the actual fluc-
 tuation is somewhat dampened by the atmospheric contribution.

      Microbial activity as  reflected by carbon dioxide was  moni-
 tored at 12  stations  which  are all located in and around the
 management area.   Microbial  activity as reflected by carbon
 dioxide evolved did differ  substantially in  carbon dioxide  pro-
 duction between stations 7  and 12,  however,  the response to en-
 vironmental conditions  were  very  similar.  Data based on 24-hour
 periods,  for  samples  measured  daily at  these stations  are  shown
 in  Figure  19,  Carbon  Dioxide Production -  Control Area,  Stations
 7-12.   The  carbon  dioxide evolved  at  station 7  was significantly
 greater  than  that  at  station 12, however,  this  probably  is  the
 result  of  the higher water table.   Data from these stations
were  compared because both were outside  the  management  area
 and  are  intended to reflect natural conditions.

     Also plotted on Figure 19 are  the  41 rainfall/runoff events
that occurred during the sampling period.  As is illustrated,
there generally was a sharp decrease in  the  rate of carbon di-
oxide evolution following major rainfall/runoff events.  Figure
20, Carbon Dioxide Production - 24 hours vs.  72 hours, Station  7,
shows the degree of variation between the 24-hour and 72-hour

                               60

-------
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                                           STATION 7
                                    	STATION 12
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                       Time-Months



Figure  19.   Carbon Dioxide Production - Control

             Area, Stations 7-12
                         61

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Figure 20.   Carbon Dioxide Production - 24 Hours vs

             72  hours, Station 7
                           62

-------
 carbon dioxide evolution  at  station  7.   These  values  are  not  ad-
 justed for  the atmospheric contribution  to  carbon  dioxide and
 consequently  the 24-hour  carbon dioxide  values are uniformly
 higher than those  for the 72-hour run.   However, the  response to
 environmental conditions  is  very similar.

     Estimation of microbial number  is feasible and is a  useful
 indicator to  compliment carbon dioxide evolution studies.

     Direct counts of bacteria for surface  soils overall  ranged
 from 9 x 10°  to 164 x 10° bacteria per gram of dry soil.   Largest
 populations were observed during the month  of  July for most sta-
 tions.  Conditions favorable for growth  were optimum  in the
 latter half of July; water was absent from  the soil surface and
 ground temperature peaked.  Fluctuating  populations of slightly
 decreased size were observed during  the  fall samplings.

     Direct microscopic enumeration  of total bacteria per gram
 of marsh soil was carried out throughout the sampling period.

     Counts taken at stations 7 and  13 served  as controls  to
 monitor sample variability and the basic reproducibility  of the
 methodology used for direct microscopic  counts.

     Station 7 was located near the management area and conse-
 quently subjected to some degree of  alteration, whereas station
 13 was located in a relatively undisturbed  area of the wetland.
 These two sites are located in areas that are  similar in  vegeta-
 tion and micro-relief.  The data are presented in  Figure  21,  Mi-
 crobial Counts vs. Rainfall/Runoff Events,  Stations 7 and  13.
 Population  densities ranged from approximately 30  x 10°" to 100 x
 10° bacteria per gram of  dry soil.  The  bacteria population were
 cyclic with some degree of regularity.   Figure 17, page 54, il-
 lustrates that the lowest values were recorded during early June
 and late July, whereas the highest values were also recorded
 June and July.

     The microbial activity is expected  to  be  related to  soil
 temperature, however, during late July a sharp decline in or-
 ganisms was recorded, not only at stations  7 and 13 but at
 virtually all stations monitored.   The soil temperature peaked
 during July and August and values up to  25°C (77°F) were record-
 ed which are just within  the optimal range of mesophilic growth.
 Soil temperatures were very stable and no abrupt changes were
 recorded, consequently,  it is apparent that some factor other
 than soil temperature was responsible for the decrease in soil
bacteria.

     Comparing the soil bacteria counts  for both stations 7 and
 13 with rainfall/runoff events,  it is apparent that surface bac-
 terial counts respond to rainfall/runoff as indicated in Figure
 21.

                               63

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                          DEWATERED
     120 H
           JUN
JUL
                                AUG

                             Time -Months
                    SEP
OCT
  Figure 21.   Microbial  Counts  vs.  Rainfall/Runoff Events -
              Stations  7 and  13
     Episodes of high rainfall caused sharp decreases  in  the
rates of carbon dioxide evolution,  as levels dropped to half  the
pre-precipitation value or even more than that.   Return to pre-
vious carbon dioxide release rates  occurred three to four days
after a rainstorm in both the control and dewatered areas.  The
effect of the heavy rainfall on carbon dioxide evolution  was
probably due to the increased moisture content of the  surface
zones.  With the pre-rainfall equilibrium of dissolved/gaseous
carbon dioxide altered by soil saturation,  a greater proportion
of the carbon dioxide was dissolved until a new equilibrium was
attained.   Microbial activity may also have slowed somewhat with
sudden saturation of the habitat, but this  probably was less im-
portant than the carbon dioxide solution  effects.
                              64

-------
     The basic agreement between the two stations is obvious,
attesting to the validity of the counting procedures and to the
reliability of the fluctuations observed.

Wetland Management

     One of the main objectives of the wetland study was to
evaluate possible methods or techniques in which the nutrient
removal capacity of a wetland could be enhanced.  With this
objective in mind, a management area was set up consisting of
two individual test plots.

     It was theorized that by regulating the water level in the
wetland the microbial activity could be increased and consequent-
ly the nutrient removal capacity of the wetland enhanced.  The
specific objectives were to determine that if by regulating the
water level, could the microbial activity be stimulated, and if
so, what would be the resulting impact on water quality changes?

     The data collection stations associated with the pilot zone
and those associated with the control zone were located as shown
in Figure 12, page 29.

     The pilot zone was dewatered twice during the summer of
1975.  The first dewatering occurred during the period June 16
through August 1 and the second period was August 26 through
November 11.

     Pumping at a rate of 120 gpm, approximately 36 hours of
pumping was required before maximum dewatering of the pilot zone
was attained.

     A continuous pumping rate of 15 gpm was required to keep
the area dewatered.

     Comparisons were made on paired sets of stations with one
member of the pair in the control zone and the other member lo-
cated in the pilot zone.  The pilot zone was subject to manipu-
lation of the water table, while counterpart stations in the
control zones were subjected to the normal water table of the
marsh.

     When the data was analyzed for all stations, it became evi-
dent that water table changes did cause substantial changes in
the microbial system where water level management was effective.

     The water table of the pilot zone was lower than the control
zone by several inches for most stations and three feet for
station 4.  Thus, station 4 was the driest location within the
                               65

-------
wetland.  The highest water table was consistently found at
station 10, often this area was covered by standing water.  Com-
parison of these two stations would be expected to show the
greatest microbial differences because soil conditions of the dry
station 4 would greatly differ from the wetter station 10.

     Stations 4 and 10 demonstrate the distinct differences in
water table expected of pilot versus control zone stations.
Pumping capacity at station 4 was obviously adequate to lower the
water table significantly and hence allow for substantially
better aeration than occurred in the more nearly saturated soil
of station 10.

     A summary of the data derived from measurements of the depth
of water table below the soil surface for paired stations 4 and
10 is shown on Figure 22, Depth to Groundwater - Stations 4 and
10.

     Located in the pilot zone and subjected to pumping, site 2
can be seen to be virtually identical to the unpumped counter-
part site 8 in terms of water level.

     The corresponding data for paired stations 2 and 8 is pre-
sented similarly on Figure 23, Depth to Groundwater - Stations
2 and 8.

     The course of carbon dioxide evolution at stations 4 and 10,
based on 24-hour periods of carbon dioxide absorption, is summar-
ized on Figure 24, Carbon Dioxide Production - Stations 4 and 10,
24-hour.  Although some variations are evident, the trend is
clearly in the direction of higher respiratory activity at the
well drained station 4 than at the counterpart station 10 where
the water table remained within 25.4 cm (10 in) of the surface.
It is of interest to point out the difference in response of
carbon dioxide production at stations 4 and 10 following the
rainfall events of July 1 and August 1, 1975 during which
5.59 cm (2.20 in)  and 5.72 cm (2.25 in) of precipitation were
recorded, respectively.  Carbon dioxide production at station
4 shows a gradual response as a result of the rainfall events
whereas station 10 responded with almost an immediate drop in
carbon dioxide production following the July rainstorm event.
It appears that the carbon dioxide production at station 10 was
much more responsive to rainfall events, however, there was
little correlation.   This can partially be explained by the fact
that runoff did not occur with each rainfall event, consequently
the magnitude and intensity of the rainfall event had some
bearing.  Results for the 72-hour absorption experiments are
similar but disclose greater differences in carbon dioxide evolu-
tion between stations 4 and 10 as shown on Figure 25, Carbon Di-
oxide Production - Stations 4 and 10, 72 hour.   Respiratory ac-
tivity remained at high and relatively stable rates from late
July through mid-September.

                               66

-------
            DEWATERING CYCLE  I
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                     15

                     JULY
31
  15

AUGUST
 Figure 22.   Depth  to Groundwater - Stations 4  and  10
                            67

-------
         DEWATERING CYCLE [
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oc
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    20
   40
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                    15

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 Figure 23.  Depth to Groundwater - Stations 2 and 8
                           68

-------
                STATION 4
            JUL    AUG    SEP   OCT
            JUL    AUG    SEP    OCT
Figure 24.  Carbon  Dioxide Production •
            Stations  4  and 10, 24 Hour
                   69

-------
                               DEWATERED
   o
   •^.
   0
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   D
   Q
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        150
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        //
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                  JULY
                                        STATION 4
                                    \ STATION 10
                          AUGUST
SEPTEMBER
   Figure 25.   Carbon Dioxide  Production  - Stations  4 and  10,
               72 Hour


     Enumeration data for paired stations 4  and 10  are  given  in
Figure 26, Surface Microbial Counts,  Stations  4 and 10.  These
data are for surface samples.   Populations ranged from  about  15
x lOVgram in early spring to  approximately  10 times that  as  the
maximal population occurring in mid-summer.  Bacterial  numbers
increased from early June through early August,  with generally
lower numbers through September and October.   There  were clearly
greater numbers of bacteria per gram  at surface station 4  (well
drained) than at surface station 10 (high water table).  Addi-
tional counts were made at stations 4 and 10 from subsurface
samples taken at a depth of 76 cm (30 in).   These data  are sum-
marized in Figure 27, Subsurface Microbial Counts Stations 4
                               70

-------
                                DEWATERED
    150 -
    100
    50
             STATION 10
             FROZEN
       OCT
       1974
                  MAY   JUNE
              JUL
                    AUG
                    1975
                         SEP
                              OCT
NOV
                                DEWATERED
   150
   100
    50
             STATION 4
             FROZEN
       OCT
       1974
                  MAY  JUNE
              JUL
                   AUG
                   1975
                        SEP
                              OCT
NOV
Figure  26.
Surface  Microbial Counts -
Stations 4  and  10
                           71

-------
and 10.  In contrast to the surface samples, the two subsurface
stations were very similar with respect to population density
and seasonal patterns.  These findings are consistent with the
concept that surface populations are more diverse and numerous
than subsurface populations.  The high population recorded for
the subsurface stations 4 and 10 during early June is difficult
to interpret.  Hydrologically the wetland was very active and
significant flows in the order of 200 gpm were occurring at the
outlet.  Consequently, the soil water system was actively moving
and the high early counts may be in response to the availability
of nutrients.
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     Figure 27.   Subsurface Microbial Counts - Stations 4
                 and 10
                              72

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 Figure 28.   Carbon Dioxide Production

               Stations  2  and 8,  24 Hour
                     73

-------
     Microbial activity as reflected by carbon dioxide evolved
did not differ substantially between stations 2 and 8.  Data,
based on 24-hour periods, for samples measured daily at these
stations are shown on Figure 28, Carbon Dioxide Production  -
Stations 2 and 8, 24 hour.  Periods during which the pumps  were
operative in the pilot zone are also shown in the figure, appear-
ing as horizontal lines near the top of the graph.   Pumping was
relatively ineffective and microbial activity (carbon dioxide
evolved)  was only slightly lower at unpumped, control station  8
than at pilot station 2.   Stations 2 and 8 must be  treated  as
duplicate samples since they were chosen originally for similari-
ties in vegetation and location, and since the expected variable,
water level, proved to be similar in each.   Agreement between
these duplicate samples were good.   Carbon dioxide  evolution
over a 72 hour period in  the vicinity of stations 2  and 8 is
shown on  Figure 29,  Carbon Dioxide  Production - Stations 2  and
8, 72 hour.
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                         AUGUST
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        Carbon  Dioxide Production - Stations 2 and 8,
        72  hour
                              74

-------
     Results of counts on paired stations 2 and 8, which varied
only slightly in depth of water table, showed general agreement
in total numbers.  The data are summarized in Figure 30, Sur-
face Microbial Counts, Stations 2 and 8.  Population densities
ranged from about 20 x 108/gram to 100 x lOVgram.  Numbers were
lowest in early June/ increasing throughout June, and high dur-
ing July.  After a decline in the second half of August, num-
bers were steady through much of September and October.
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1 1 1 1 i 1
         JUNE
JULY   AUGUST  SEPT   OCTOBER  NOV
Figure 30.  Surface Microbial Counts - Stations 2 and 8
     One of the main objectives of the Wayzata wetland project
was to determine the impacts the wetland has on the quality of
stormwater passing through the wetland and also if any water
quality improvement that occurs in the wetland can be enhanced.

     As mentioned earlier, the pilot and control management area
was set up and regulated in order to determine if water level
management in the wetland would stimulate microbial activity
and consequently enhance the water quality passing through the
wetland ecosystem.

     Figures 31, 32 and 33 were constructed utilizing the data
phosphorus levels in the soil water, surface and subsurface mi-
crobial populations.
                               75

-------
      Figure  31,  Surface  and Subsurface  Microbial Counts  vs.  Total
 Phosphorus Concentration in Soil  Water  -  Station 6,  is  con-
 structed  from data  obtained at monitoring station 6  and  obser-
 vation well  6.   Monitoring  station  6  is located outside  the
 management area  approximately  2 m (6.6  ft)  from monitoring sta-
 tion  5.

      The  most vivid feature of Figure 31  is the apparent rela-
 tionship  between soil water phosphorus  levels  and subsurface
 microbial populations during the  month  of June and early July.
 Figure 31 also indicates that  when  the  level of phosphorus drops
 below some given value,  the phosphorus  level ceases  to have  an
 effect on the population of subsurface  microbes.   However, Fig-
 ure 32, Surface  and Subsurface Microbial  Counts vs.  Total Phos-
 phorus Concentration in  Soil Water  -  Station 10,  does not illu-
 strate this  relationship.   This may be  due  to  the high water
 table condition  at  site  10  resulting  in less variation in the
 type  of microbes  present.

      There appears  to be an almost  inverse  relationship  between
 surface microbes  and subsurface microbes  and surface microbes
 and phosphorus.

      The  same relationship  between  subsurface  microbes and total
 phosphorus is well  illustrated at monitoring stations 5  and  10.
 Also, there  appears  to be an inverse  relationship between sur-
 face  microbes and subsurface microbes and total phosphorus.  How-
 ever, this relationship  is  not as apparent  as  is  illustrated
 on Figure 31 of monitoring  station  6.

      There does not  appear  to  be  any  relationship between ammonia
 nitrogen  and biochemical oxygen demand  parameters  monitored  at
 the sites and the surface and  subsurface  microbe  population.

      The  apparent inverse relationship  between  aerobic microbes
 and total phosphorus could be  the result  of  microbial immobili-
 zation of phosphorus resulting  in lower equilibrium  - solution
 levels.   These results appear  to agree with  results  obtained by
 B.B.  Singh (24).

      The most visible and the  ultimate  impact of  the management
program was  the vegetative response to dewatering.  A one  meter
square area was selected in both the pilot and  control zone.
The selection process required that these areas be as vegetative-
ly similar as possible.   The dominate vegetation was reed  canary
grass (Phalaris arundenacea).  The vegetation was clipped  ap-
proximately every ten days and immediately weighed.  The  first
clipping occurred on July 10, 1975 and the final clipping oc-
curred on August  12, 1975.

     The results  of the  clipping are presented in Table  14.


                               76

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 Figure 31.
      Jul
Aug
                                     Sep
                                  Oct
Surface and Subsurface Microbial Counts vs. Total

Phosphorus Concentration in Soil Water - Station 6
                            77

-------
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Figure 32.
Surface and Subsurface Microbial Counts vs. Total
Phosphorus Concentration in Soil Water -
Station 10
                         78

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 Figure  33.
     JULY
AUG
SEPT
OCT
Surface and Subsurface  Microbial Counts vs. Total
Phosphorus Concentration in  Soil Water - Station 5
                             79

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      TABLE 14.  VEGETATIVE MASS PRODUCTION - WAYZATA WETLAND
                                    Vegetative Mass, kg/rn^
                              Pilot Zone             Control  Zone
 July 10, 1975                   2.04                    0  749
 July 21, 1975                   0.518                   0*269
 August 1, 1975                  0.173                   0*084
 August 12, 1975                 0 . 110                   0*087
 Total         	           2.84
1.19
      The results of this relatively brief monitoring of vegeta-
 tive mass indicates that the vegetative growth in the dewatered
 zone produced approximately 2.84 kg/m2 during the test period,
 whereas the control zone produced 1.19 kg/m2.  On a one term
 basis it appears that the dewatered pilot zone produced approxi-
 mately 2.4 times the vegetative mass produced in the control
 *-7S*\ T"\ y—\
 zone.
      Phosphorus sorption and desorption characteristics of soil
 is  affected by organic residues (24) .

      Phosphorus has been shown to be  the limiting nutrient in
 the lake eutrophication cycle and therefore,  has a special sig-
 nificance to the Lake Minnetonka area.   Consequently,  an in-
 depth study was conducted on the marsh  soils  in order  to estab-
 lish the ultimate fate of phosphorus  in the wetland.   A total of
 18  organic soil samples were collected  in the vicinity of sta-
 tions 4  and 10 for phosphorus analysis.

      In  order to check the validity of  the results,  three core
 samples  were  taken at stations  4  and  10.   Three soil samples
 were selected from each individual core.   The first  sample was
 taken at approximately the 5  cm ( 2 in)  depth,  the  second at ap-
 proximately the 30 cm (17  in) depth and  the third  at approximate
 ly  the 60  cm  (24 in)  depth.
n «*cThe results of these analysis indicate that  approximately
0.045 percent of the wetlands organic soil is phorphorus.

     The average bulk density of the organic soil has been es-
tablished at approximately 641 kg/cu-m  (40 Ibs/cu-ft) . This value
agrees well with the values reported in United States Department
of Agriculture Circular 290  (R) .

     Assuming a bulk density of 641 kg/cu-m (40 Ibs/cu-ft) and an
nV9QQ^ Concentration of 0.045 percent phosphorus, approximately
0.288 kg/cu-m (0.018 Ibs/cu-ft) of phosphorus is present in the
organic soil.

     In order to add more insight into the complex nature of the

                               80

-------
phosphorus cycle, phosphorus adsorption isotherms were construct-
ed for the wetland soils.  A method developed by A. W. Taylor and
H. Kieuishi (25) for constructing phosphorus adsorption isotherms
was utilized.

     The results are calculated in terms of the ratio x/(1.0 +
log c), where x is the weight of phosphorus adsorbed in the soil
in mg/kg (ppm) and c is the final phosphorus concentration in
mg/1.  This ratio provides an index of the adsorption capacity
of the soils.   Together with data on the bulk density of the
soil, the relative depth of the soil horizons and the anticipated
composition of the influent water, this ratio may be used to
calculate the adsorption capacity of the soil.

     To determine the phosphorus adsorption, a five gram sample
of each soil was added to a 100 ml volume of a solution contain-
ing 30 ppm phosphorus and 0.13 percent KCl and shaken for 18
hours on a reciprocating shaker.  The suspension was then fil-
tered and an aliquot of clear solution removed for analysis.
The final phosphorus concentration was determined colorimetri-
cally using the ammonium molybdate-ascorbic acid procedure.

     Table 15 indicates that at a phosphorus concentration of
1 mg/1, the range in phosphorus adsorption isotherm at stations
4 and 10 illustrates the shape of the isotherm for the various
soils.

       TABLE 15.  PHOSPHORUS ADSORPTION CHARACTERISTICS -
                         WAYZATA WETLAND SOILS



Sample
1
2
3
4
5
6



Station
4
4
4
10
10
10


Depth
(cm)
5
30
60
5
30
60
Phosphorus
Adsorption
(ppm)
(1 mg/1)
81.3
28.5
35.8

35.6
26.5
Phosphorus
Adsorption
(ppm)
(30 mg/1)
232
269
431
264
251
339
     The average measured value for phosphorus in solution at
stations 4 and 10 was approximately 0.9 mg/1.  Consequently, one
would assume that the amount of phosphorus present in the wetland
soils would be in the order of 26 to 81 ppm or 165 to 518 kg/ha-m
(45 to 141 Ibs/ac-ft).  However, the digestive results indicated
that approximately 2,868 kg/ha-m  (780 Ibs/ac-ft) of phosphorus
was present in the organic soil.  Consequently, the organic soil
in the Wayzata wetland presently contains from 5 to 17 times the
amount of phosphorus that the isotherm indicates that it should
hold as indicated in Figure 34, Phosphorus Adsorption Isotherms -


                               81

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Stations 4 and 10.

     These values are high for an organic soil, however, they
appear reasonable when considering the relatively larger percent
of inorganic material present in the soil profile as shown in
Figure 5, page 16.

     It is apparent that the phosphorus is fixed in some organic
form, possibly as part of the vegetative fiber.

     If this additional phosphorus is organically based, stimula-
tion of the biological system will remove greater quantities of
phosphorus.  The results of the vegetative plots indicate that
significant quantities of organic matter were produced.  Research
(26) has shown that by the time a plant has obtained approximate-
ly 25 percent of its total dry weight it has acquired 75 percent
of its total phosphorus needs.  Experimental results by Spangler
et al. (27) indicate that frequent harvesting of bulrushes re-
moved greater quantities of phosphorus than a single harvest
even though the total organic matter removal was not substan-
tially greater.

Sump Water Quality

     The frequent analysis of water quality for the sump pumping
station provides a detailed picture of nutrient concentrations.
The control of water elevations within the pilot area would be
expected to alter the water quality at the sump, the result of
changing environmental conditions and thus biological activity.
A comparison of water quality for sump versus outlet would be
comparable to pilot zone versus control zone.  Pilot zone versus
control zone comparisons yielded significantly different water
quality for three parameters:  ammonia nitrogen, phosphorus and
total suspended solids.  Biochemical oxygen demand, total coli-
form and oxidation reduction potential appear to be minimally
affected by manipulation of water levels.  The effect of dewater-
ing upon the pilot zone was distinctly different for the two de-
watering cycles, I and II, studied attesting to the pronounced
effect uncontrollable parameters have upon the pilot zone.

Sump Water Quality - Total Coliform—

     Total coliform counts of the sump follow an erratic pattern,
ranging from 0-322 colonies per 100 mis.  See Figure 35, Total
Coliform, Total Suspended Solids and Biochemical Oxygen Demand
Concentrations in Sump Discharge Water.  The standard mean was
59.  The appearance of the occasional high counts does not
appear to be related to any monitored parameter.  Such fluctua-
tions in total coliform counts are common.  The source of the
coliform are natural soil inhabitants and animal fecal contamina-
tion.  It is considered that within these observed ranges for
total coliform contaminated water would not be a problem.

                                83

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                  DEWATERED
   16

   14

   12

   10

    Q 	

    6 -
                  BOD,
       JUN
 JUL
AUG
                 DEWATERED
                          SEP
                   OCT   NOV
       JUN
JUL   AUG    SEP   OCT   NOV
  300
  200-
o 100-
      JUN
Figure  35
JUL
AUG
                         SEP
                  OCT
                                     NOV
Total  Coliform, Total Suspend-
ed Solids  and Biochemical Oxygen
Demand Concentrations in Sump
Discharge  Water
                      84

-------
     Total coliform of the sump and outlet were similar but no
distinct patterns were observed.  See Figures 35 and 36.  The
mean value was slightly lower for the sump.  The outlet ranged
0-240 colonies per 100 mis, the mean was 71 over the same period.

Sump Water Quality - Biochemical Oxygen Demand—

     Biochemical oxygen demand values of the sump ranged from
0-16 mg/1 fluctuating greatly  (see Figure 35).  Values were
slightly higher through September.  Outlet values of biochemi-
cal oxygen demand ranged 0-14 over the same period.  See Figure
36, Total Coliform, Total Suspended Solids and Biochemical Oxy-
gen Demand in Outlet Discharge Water.  The value of comparing
biochemical oxygen demand over time and location is highly
questionable, the nature of oxidizable material is unknown and
variable.  However, within the restriction of the wetland a
comparison of biochemical oxygen demand may be fairly accurate.
There does not appear to be a significant difference in bio-
chemical oxygen demand for sump and control zones.

Sump Water Quality - Total Suspended Solids—

     Total suspended solids of the sump showed a definite pattern
(Figure 35).  Highest values were found during dewatering cycle
I, significantly lower values were seen during dewatering cycle
II.  Preceding and through the first two weeks of dewatering
cycle I the wetland was infiltrated with stormwaters as a result
of the excessive precipitation in June.  The high volume of water
stirs up the wetland soils as a result of increased flow rate and
increases the suspended solids concentration.

     Total suspended solids concentration values were greatly re-
duced through dewatering cycle II during which less precipitation
fell.  The wetland soils received smaller increments of inflow
resulting in lower flow rates such that suspended solids settle
out.  The need for controlled flow rates is seen as a means of
reducing total suspended solids.

     Total suspended solids values of the outlet were subject to
larger fluctuations than the sump.  See Figure 36.  Outlet
values ranged 0-270 mg/1, sump values ranged 0-104 mg/1 over the
same period.  The high peaks observed at the outlet were due to
disturbance of sediments in the bed of the outlet channel.  These
high peaks were reduced or absent for the sump due to the dif-
ference in manner of discharge for the outlet and sump.

Sump Water Quality - Ammonia Nitrogen—

     Ammonia values in sump discharge ranged from 0.1-15 ppm,
with concentrations fluctuating greatly June through July but
remaining almost constant from September through November.  See
Figure 37, Ammonia Concentration and Oxidation Reduction Poten-

                               85

-------
  125
                                   BOD
      NOV   DEC
        1974
APR
MAY
JUN    JUL
   1975
 300
0200
a
Q
                                TSS
      NOV   DEC
        1974
APR    MAY
      JUN   JJL
       1975
                          AUG    SEP
                          OCT
 f 300
 ;ioo
                                   TC
     NOV    DEC     APR    MAY   JUN    JUL
         1974                    1975
                           AUG    SEP
                                OCT
Figure  36.   Total  Coliform, Total Suspended Solids  and
             Biochemical Oxygen  Demand in  Outlet Dis-
             charge Water
                              86

-------
    500
    400
   300
    200
    14 r—
                 DEWATERED
       JUN    JUL    AUG   SEP    OCT    NOV
Figure 37.   Ammonia Concentration and
             Oxidation Reduction  Potential
             in Sump Discharge
                     87

-------
 tial in Sump Discharge.   The fluctuating ammonia nitrogen concen-
 trations observed in July were quite mysterious in light of the
 constant water levels over this period.   It appears that the
 fluctuations observed are the result of  nitrification and deni-
 trification by bacteria.   Nitrates were  not measured but nitrifi-
 cation could occur as indicated by the oxidation reduction poten-
 tial.   Patrick found that an oxidation reduction potential of 300
 or  greater was necessary  for nitrification (28).  Through July
 this potential was exceeded several times corresponding to de-
 creased ammonia nitrogen  values.   The fluctuating observed for
 oxidation reduction potential and ammonia nitrogen values may be
 due to the depletion of oxygen within the environment by the ni-
 trifying bacteria followed by a replenishment of oxygen as the
 water  aerates.

     Water quality pumped from the pilot zone and sampled at the
 sump differed significantly from water quality sampled at the
 piezometers.   The source  of the sump is  groundwater pumped from
 the upper three feet of soil.   Ammonia nitrogen concentration ap-
 pears  to be affected most as can  be seen by comparing Figures 37
 and 38,  Ammonia Concentration in  Soil Water - Stations 3 and 9.
 Ammonia nitrogen concentration at the sump were generally half
 the ammonia concentrations of groundwater at the piezometer
 sump.   This appears  to point out  the importance of aerating to
 improve  the water quality.   Further evidence of the pronounced
 effect of aeration was seen in August.   The lysimeter was not
 pumped,  groundwater was left standing in the holding tank over a
 three  week period and sampled daily.   Ammonia nitrogen concentra-
 tions  were extremely low,  1-2  ppm,  as this  water was exposed to
 air.   Upon exposure  to air the ammonia nitrogen concentrations
 present  as  the  dissolved  ammonium ion may be volatized and lost
 as  the  gaseous  form ammonia nitrogen to  the atmosphere.

     Dewatering  of the pilot zone  was done  two  times as  indicated
 by  the black  bars  on Figure  37.   Through dewatering cycle I,
 ammonia  nitrogen  of  the outlet and  sump  are within  similar
 ranges and  both  fluctuate  greatly.   See  Figure  37,  page  87,  and
 Figure  39,  Ammonia Concentration  in  Outlet  Discharge,  for ammonia
 concentrations of  sump and  outlet.   Peak  concentrations  of the
 sump and  outlet  correlate with the highest  ammonia  values  occur-
 ring on  the  same  day.  The  two  cycles  of  dewatering differed  sig-
 nificantly  in resultant ammonia nitrogen  concentrations.

     During dewatering cycle  II the  ammonia  nitrogen  values of
 the sump  are  twice the concentration  of  the  outlet.   The  higher
 ammonia values observed for  dewatering cycle  II  in  the pilot
 zone may  be due to the increased activity of  the  soils microbes
 at  station 4  in the pilot  zone, as seen  in  carbon dioxide  pro-
 duction,  Figure 24, page 69.  Less new cell  synthesis was  ob-
 served through the fall months but maintenance metabolism would
be  continuing.  With less new growth or microbes, less nitrogen
would be  required but an energy source would  still be needed,


                               88

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               90

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producing carbon dioxide.

     The greater quantity of organic material used by the mi-
crobes of the pilot zone, as observed in high carbon dioxide
evolution over dewatering cycle II results in the subsequent re-
lease of ammonia nitrogen concentrations through deamination of
the organic matter used as an energy source.  The higher soil
activity of the pilot zone consequently produces higher ammonia
nitrogen in the sump.

Sump Water Quality - Total Phosphorus—

     Total phosphorus concentrations of the sump ranged from 0.01
to 1.24 mg/1 as shown in Figure 40, Total Phosphorus Concentra-
tion in Sump Discharge Water.  A fluctuating pattern was seen,
concentrations increased and decreased by a factor greater than
two within a short period, one to two days.  The phosphorus
concentrations appear to be highly unpredictable.  Through the
period of July and September through October, water elevations
were constant and phosphorus continued to fluctuate greatly in-
dicating no direct relationship between water elevation and
phosphorus.

     Comparison of total phosphorus, pilot zone to control zone
during dewatering cycle I shows similar ranges, however, peak
concentrations for sump and outlet do not coincide.  The outlet
peaks lag the sump peaks by several days.  See Figure 40 and
Figure 41, Total Phosphorus Concentration in Outlet Discharge
Water.  This appears to indicate a mass movement of phosphorus
carried by the groundwater through the wetland.

     Through dewatering cycle II, higher concentrations of phos-
phorus were seen in the pilot zone over the control zone.  It is
uncertain as to whether this is related to the biological ac-
tivity phenomena described for ammonia.  Whereas ammonia is
relatively constant over this period, phosphorus fluctuates
greatly.

Phosphorus Ammonia Nitrogen Correlation—

     There does not appear to be a direct relationship between
phosphorus and ammonia nitrogen within the pilot zone for short
term comparisons.  This is best exemplified in the month of
September, ammonia nitrogen concentrations are constant whereas
phosphorus concentrations fluctuated.  June through July both
ammonia and phosphorus are fluctuating, however, the fluctua-
tions do not appear to coincide.

     Seasonally phosphorus and ammonia nitrogen concentrations
do follow a similar pattern, higher concentrations were observed
June through July, lower concentrations were observed September
through November.

                                91

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   0.0
                        DEWATERED
        JUN
JUL
                        AUQ
               SEP
                                       OCT
                               NOV
Figure 40.  Total Phosphorus Concentration in Sump Dis-
            charge
                            92

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1.4

1.3

1.2

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0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1
0.0
                   FROZEN

                I    I     I
        NOV  DEC  JAN   FEB  MAR  APR  MAY  JUN   JUL  AUG  SEP  OCT
           1874                            1878
                                                        NOV
  Figure 41.
         Total Phosphorus Concentration in Outlet
         Discharge Water
     The ranges for samples  taken throughout the year are in a
ratio of nine ammonia to one total phosphorus, the accepted ra-
tio of nitrogen to phosphorus in a biological system.  This in-
dicates that the majority  of the nitrogen is of the ammonia form.
The failure of ammonia nitrogen and phosphorus to correlate,
short term, is probably due  to the alteration of nitrogen states.

     Where the wetland system is a contributing watershed to a
recreational lake, it is desirable to reduce the nutrient flow
to the lake.  As the groundwater flows to the lake it carries
this large load of nutrients to the lake.  For an undisturbed
system the inflow of nutrients would be desirable as a constant
supply of nutrients in an  equilibrium necessary to primary pro-
duction and thus beneficial  to fish and other aquatic life.
However, many recreational lakes are out of equilibrium from
poor sewage practices and  thus unstable and unable to handle the
nutrient load of groundwater.
                                93

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                            SECTION 9

                            DISCUSSION


  •14-u Thu hydrologic balance of the project watershed and wetland,
 although typical, present very complex problems relative to
 groundwater movement and losses from evaporation and evapotrans-
 piration.   The biological and chemical aspects of the ecosystem
 are closely related to the water level.   High water levels
 create an  anaerobic environment; an aerobic system is estab-
 lished with continuing low water levels.   The state of the wet-
 lands, aerobic or anaerobic,  ultimately  determines the type and
 amount of  activity.

      The wetland  received water from the  following three sources,
 with the percentage  from each source shown in parenthesis;  direct
 precipitation  (35 percent),  surface runoff (47 percent)  and
 groundwater inflow (18 percent).

      The losses from the wetland were by  means of evapotranspira-
 tion (25 percent)  and surface discharge  (75  percent).

      The sources  of  phosphorus,  the major nutrient of  interest,
 f?othe-,wetland ™fre  surface runoff  (55 percent),  groundwater in-
 flow (44 percent)  and precipitation (1 percent).   Based  on  the
 waS-S.  A     e equation'  78  Percent of  the  phosphorus entering the
 wetland  was removed,  while 94 percent of  the  suspended solids
 were  removed.

      Review of the detailed environmental  assessments, presented
 in Appendices A and B,  indicate that  no impacts were detected on
 the wildlife or vegetation as  a result of  this project.

     The microbial activity within  the wetland appears to be the
most important mechanism influencing  the improvement of  the
quality of the water passing  through the site.  The detailed in-
vestigations correlating microbial activity with water levels
and total phosphorus concentration indicate that a rapid increase
in microbial population follows the runoff events.       increase

          ?r°cess  aPPears to follow the classic growth pattern
          in microorganisms in a batch culture.  Initially, all
          ********** in excess of the requirement of the micro-
           and  growth is unrestricted.  During this period,
                               94

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called the constant growth phase, the concentration of microor-
ganisms increases at an exponential rate.  At some concentration,
one of the nutrients becomes growth limiting and the culture
proceeds into the declining growth phase.  In response to the
increasing competition of the microorganisms for the remaining
limiting nutrient, the rate of growth decreases until growth
finally halts.  At this point, the limiting nutrient has been
depleted and the replacement of those organisms that die is not
possible.  Consequently, the microorganism concentration de-
creases in what is termed the endogenous or auto-oxidation phase.
When microorganisms are introduced to a growth medium to which
they are unacclimated, there occurs prior to the constant growth
phase, a lag phase in which the microorganisms become adjusted
to the culture environment.

     Modifications of the classic pattern occur as the results of
varying ratios of nutrients to microorganisms in the culture
medium.

     After an initial lag phase, growth proceeds in the constant
growth phase with the concentration of microorganisms increasing
expotentially.  The microorganisms remove from the culture nutri-
ents required for growth, and the concentrations of the latter
will decrease.

     Organic material assimilated by a microorganism furnishes
both the elements out of which protoplasm is constructed and the
energy necessary for its synthesis.

     The process found in the wetland appears to be one which
involves an initial lag period, with a rapid growth period, fol-
lowed by a declining growth period caused either by limited
quantity of nutrients or by physical removal (by falling water
levels) of the nutrients from the microorganisms activity sites.

     Additional work in the area of optimizing the microbial
processes is being performed, as part of the second portion of
this grant, in organic soil filtration units and development of
support data is anticipated.

     The relative ineffectiveness of dewatering the wetland may
be caused by the fact that additional acclimation is required
once the stormwater is added to the system.
                                95

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                            REFERENCES

 1.   U.S.  Fish and Wildlife  Service,  "Interim Classification of
     Wetland and Aquatic Habitats  of  the United States",  U.S.
     Department of the  Interior, March,  1976.

 2.   Norvich,  R.F.,  Ross,  T.G.  and Brietkrietz, Alex,  "Water Re-
     sources Outlook for the Minneapolis-St.  Paul  Metropolitan
     Area",  U.S.  Geological  Survey, 1973.

 3.   Thornthwaite,  C.W.  and  Mather, J.R.,  "Instructions  and Tables
     for Computing Potential Evapotranspiration and  the Water  Bal-
     ance",  Drexel  Institute of Technology, Publication  in  Clima-
     tology",  Volume X,  No.  3,  1957.

 4.   Blad, Elaine  L.  and Baker, Donald G.,  "A  Three-Year  Study of
     Net Radiation  at St.  Paul, Minnesota:  Jour.  Applied Meteor-
     ology", Volume  10,  1971.

 5.   U.S. Environmental  Protection Agency,  "Methods  for Chemical
     Analysis  of Water and Wastes", 1974 Edition.

 6.   APHA, AWWA and  WPCF,  "Standard Methods for the  Examination of
     Waste and Wastewater",  13th Edition.

 7.   Sears,  P.B. and  Janson, E., "The  Rate of  Peat Growth in the
     Erie Basin", Ecology, 1933.

 8.   Olson,  J.S., "Energy, Storage and the Balance of Producers
     and Decomposers  in Ecological Systems", Ecology, 1963.

 9.   Reader, R.J. and Stewart, J.M., "The Realtionship Between
    Net Primary Production and Accumulations  for a  Peatland in
     Southeastern Manitoba", Ecology,   1972.

 10. Lusman, G.A., "The Rate of Organic Matter Accumulation on the
    Sedge Mat Zone of Bogs in the Itasca State Park Region of
    Minnesota", Ecology, January,  1953.

 11. Boelter, D.H., "Hydraulic Conductivity of Peats",  Soil
    Science, 1965.

12. Kunkle,  G.K., "The Baseflow Duration Curve, A Technique for
    the Study of Groundwater Discharge From a Drainage Basin".
    Jour.  Geophysical Research, Volume 76, No. 4.


                               96

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13.   Schwab,  Frevert,  Edminster and Barnes, "Soil and Water Con-
     servation Engineering",  John Wiley & Sons, New York, 1966.
     p. 80.

14.   Lawrence, D.B., Bonde, A.N. and Ives, J.D., "Ecosystem
     Studies  at Cedar Creek Natural History Area", III Water Use
     Study Proceedings, Minnesota Academy of Sciences, 1961.

15.   Voight,  G.K.,  "Amer.  Midi. Natur.", 1960.

16.   Chalupa, J., "Sb Ved. Pr. Vys. Sk. Chemickotechnol. Par-
     dubice  (Prague)", Fac. Technol. Fuel. Wat. Vol. 4, Pt. 1
     (English Summary, "Water Pollution Abstract, Volume 35
     No. 5, Abs. No. 660) .

17.   Tamm, C.O., "Physiol. Plant", 1951.

18.   Krupa, Sagar,  University of Minnesota, Unpublished.

19.   Keup, L.E., Water Research", Volume 2, Pergamon Press,
     Great Britain, 1968.

20.   Sorenson, K.E., "A Program for Preserving the Quality of
     Lake Minnetonka", 1971.

21.   E.  A. Hickok and Associates, "Minnehaha Creek Watershed Dis-
     trict Hydrologic Report", 1971.

22.   Soper, E.K., "The Peat Deposits of Minnesota", Minnesota
     Geological Survey Bulletin 16, 1919.

23.   Waksman, S.A., "Principles of Soil Microbiology", Williams
     and Wilkins Co., Baltimore, Md., 2nd Edition. 1932.

24.   Singh, B.B. and Jones, J.P., "Phosphorus Sorption and De-
     sorption Characteristics of Soil as Affected by Organic
     Residues", Soil Science Society of America Journal, Volume
     40, No.  3, May-June,  1976.

25.   Taylor,  A.W. and Kieuishi, "Journal of Soil Water Conserva-
     tion", 1967.

26.   Seatz, Lloyd F. and Stanberry, Chauncy O., "Advances in
     Phosphate Fertilization", 1960, Soil Science Society of
     America Journal.

27.   Spangler, Frederic L., Sloey, William E. and Fetter, C.W.,
     Jr., "Artificial and Natural Marshes as Wastewater Treat-
     ment Systems in Wisconsin", Presented at Freshwater Wet-
     lands and Sewage Effluent Disposal: Ecosystem Impacts,
     Economics, and Feasibility, May, 1976.
                                97

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28.  Patrick,  W.H.,  Jr.  and Tusneem,  M.E.,  "Nitrogen Loss from
     Flooded Soil",  Soil Science Society of America Journal,
     1960.
                             98

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                           APPENDIX A

                   ECOLOGY REPORT - PHASE I
     (Status of the Biota at the Beginning of the Project)
                               by
                   James A. Jones, Ecologist
GENERAL COMMENTS

     For some time it has been widely accepted that the wetland
plays an important role in conditioning water which comes as
runoff from the hard surfaces such as streets and parking lots.
In some situations part of this water may be derived as surface
drainage from highly fertilized lawns.  Runoff water has been
shown to be enriched with dissolved chemicals and it has the
potential of carrying toxic agents.  When this water flows dir-
ectly into lakes the lakes tend to become overenriched result-
ing in undesirably heavy blooms of blue-green algae.  It is pro-
posed that the marsh functions as a biological filter system in-
corporating the undesirable agents from the water as it slowly
filters through before entering the lake.

     The present study is concerned with establishing specific
values for the effects of the marsh on the drainage water; exam-
ining the feasibility of increasing the effectiveness of the
marsh; and identifying the impact of the experimental procedures
on the life of the marsh.

OBJECTIVES OF THE ECOLOGICAL STUDY

     The specific objectives of the ecological portion of the
study relate to measuring the biological effects on the marsh
of the various controlled alterations of the environment.  The
study will include a vegetative analysis of the control and ex-
perimental plots and a faunal and floral analysis of the open-
water marsh outside the plots to establish the original biologi-
cal status and to identify any alterations in the biota accom-
panying and possibly induced by the experimental techniques.

THE EXPERIMENTAL AND CONTROL PLOTS

Description

     The plots chosen for study meet  the dictionary definition


                                99

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of  "wetland" —  "a  track of low, wet,  soft  land".   The water
level during this,  a rather "normal",  season  (1974) has  varied
from a  shallow covering in the early spring to  about  three  feet
below the surface in late July.  Several  showers in early August
returned the water  table to about  six  inches  below  the surface.

     The substrate  of the plots is of  plant material  in  various
stages  of decomposition and preservation  (as  peat)  with  seeming-
ly  negligible but as yet undetermined  siltation from  runoff.

     The vegetation of the plots is dense and represented by a
variety of species  which characterize  the ecological  age of the
wetland.  By growth form, species were identified as  two trees,
nine shrubs, three  grasses, three  sedges, and seventeen  forbes.
In  initial appearance one is impressed by the predominance  of
willows, dogwoods,  and reed canary grass.

     The two plots  are similar in  species composition and in the
relative abundance  of the species.  The homogeneity of the  vege-
tation of the plots is further accentuated  by the lack of marked
zonation in species distribution although there is  some  clumping
due to vegetative reproduction.

     In general, the species are those common and widespread
over central Minnesota.  They are  tolerant  of the varied mois-
ture conditions  to  which they are  subjected in  this habitat.
Two species, Typha  latifolia  (cattail) and  Sagittaria sp.
(arrowleaf)  are  characteristic, and tolerant  of higher water
levels and may be near their dry-tolerance  limit in this habitat
partly because of the low water table  at  certain times and
partly because of the severe competition  provided by  the reed
canary grass and the various shrubs.

     From the viewpoint of succession, the  appearance of two
species of trees on the plots, Acer negundo (box elder) and
Fraxians pennsylvanica (green ash), and one species just off
the plots, Populus deltoides (cottonwood) give  evidence of  the
late stage of wetland succession.  Poa sp.  (bluegrass), Eupa-
torium perfoliatum  (white boneset), and Urtica  gracilis  (sting-
ing nettle)  are tolerant of more dry conditions and are perhaps
near the limit of their moisture tolerance  in this  habitat.

     It should be noted that all species considered are hardy,
tolerant, perennials and will be altered only by marked water-
level alteration over an extended period of time.

Methods

     Initial work on the vegetation analysis was begun in early
July before I knew exactly the limits of the study plots.  At
that time plants were collected and identified  from an extensive
                               100

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area of the wetland much of it lying outside the plots as they
came to be surveyed and marked out later.  All of the plants
now found in the plots occur extensively outside the plots;
only a couple of species found outside the plots do not occur
within them.  This indicates the representative nature of the
study*

     Several techniques for vegetation analysis were considered
including the line transect, a one-meter wide transect, and
random one square meter quadrants.  When the study plots were
designated their relatively small size, compared to viewing
the entire marsh, made detailed mapping of conspicuous features
seem the most functional.  This was facilitated by the sub-
division of the study plots into 25-feet wide subplots with
the installation of tile for water level control.

     Since the dense stand of the several species provides
more than 100 percent cover it was impossibly confusing to place
all plants on the same chart.  Thus one chart includes trees
and shrubs; a second includes reed canary grass and cattails;
and a third includes conspicuous forbes and minor grasses and
sedges.

Findings

     The vegetation of the study plots is lush and varied.
Thirty-eight species of plants have been identified as com-
prising the vegetative complex  (see species list).  No species
has attained exclusive dominance over any extensive area al-
though reed canary grass and the larger bush willows have suc-
ceeded in so doing to a limited extent.  The distribution pat-
tern for several species is to grow as a dense clone in one or
more limited areas then as scattered individuals over a wider
area.  This pattern is exhibited by cattails, dogwoods, sedges,
reed canary grass, purple loosestrife, black currant, purple
bonest, and white boneset.  Because these are the large and
conspicuous forms, the distribution was most impressive.  The
herbs of lower growth forms undoubtedly display somewhat the
same pattern in some cases but I was more impressed by their
more scattered distribution under the overstory of the larger
forms.

     Black ash and box elder occur sparsely over the plots as
young trees mostly less than four feet tall.  Either the con-
ditions are becoming more suitable for their germination and
growth and they are about to take over as the next stage of
succession or they are perpetually starting seedlings which
grow for a couple of years than die out because of the en-
vironment.  I believe the latter to be the case but it will
be interesting to watch their response in relation to the
experimental procedures to be carried out.
                               101

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      All species  give  the appearance of health and vigor.   All
 are undergoing flowering and seed production (exclude two  ferns
 and two trees).

      Trampling, slashing, and ditching, as  necessary activities
 of  the  project, are  having an undetermined  and unpredictable
 effect  on about 15 percent of the marsh.  Already,  within  two
 weeks from the time  of disturbance due  to slashing and trampl-
 ing,  recovery  is  apparent in some areas;  the ditching effects
 may be  longer  lasting.   In any event development on these  dis-
 turbed  areas will be observed and recorded.

      See the accompanying list of species for plant composition
 and for plant  distribution.   The  expressions for abundance,
 abundant (A),  common (C),  and rate (R)  are  subjective values and
 expressed on the  basis  of frequency of  observation  in relation to
 other species.  If a species is present as  isolated individuals
 but occurs  widely over  the plots  it is  classed as  common.   To
 be  abundant the species occurs in dense stands and  then as  in-
 dividuals over a  wide  area.

 THE OPEN-WATER PORTION  OF THE WETLAND

 Description

      The open-water  area of  the wetland is  restricted to about
 one acre located  near the  center  of the marsh.   It  was  about
 eight inches deep when  measured on August 16,  1974.   Although
 the bottom  at eight  inches was capable  of supporting the weight
 used  for sampling (1 3/4  inch pipe  coupling)  it  really  repre-
 sents the top of  several  feet of  unconsolidated  ooze  and plant
 fragments.

      The  open-water  is  being reduced around  the  perifery by  bog-
 like  encroachment of surrounding  vegetation.   It was  possible
 to  approach the open-water within  about ten  feet by walking  on
 the quaking roots.  However,  between these clusters of  roots
 it  was possible to thrust  a  lathe  down  five  feet without con-
 tacting  any firm  bottom.  By  laying  4x8 sheets of  1/4-inch
 plywood  on  the quaking  rooted plants it was possible  to  get  to
 the very edge of  the open water to  take samples with  dip nets
 and to dip samples for plankton analysis.

Methods

     Sampling was  performed  from the edge of the open water.
After much experimentation two techniques were established for
 sampling.  Plankton was taken by holding a one-gallon plastic
bucket on the end  of a stick and allowing it to fill very
 slowly and carefully to avoid disturbance of the bottom ooze.
This sample was then poured through a coarse-mesh insect net
                               102

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into the plankton net.  The coarse-mesh net removed most of
the duckweed and other floating material while the small plank-
ters, it is felt, passed through relatively unaffected.  The
same technique will be used for the follow-up study.

     Larger organisms including snails, fingernail clams, and
insects, were collected by random thrusts with the insect net
among the roots, bottom ooze, plant fragments and floating
duckweed.  This material was then worked over manually and the
organisms picked out in the laboratory.

     Finally life forms and activity on and about the marsh were
observed and recorded.

Findings

     The examination of the open-water portion of the marsh
demonstrated conclusively that it is a healthful, living habi-
tat.  The limited span (season) of time over which the investi-
gation was conducted  (late July and early August) limit the
organisms to those which were in "bloom" at that time.  The
highly organic quality of the environment further limits the
species to those of special tolerance also.  However, in spite
of the limiting factors, great diversity of life forms is ap-
parent.

     At least two broods of ducks were reared on the marsh.  One
brood of five young woodducks with the mother and one brood
of five young mallards with their mother were observed.  Green
herons, four at one time, were observed in July and August sug-
gesting that they were reared there.

     Many young toads, very recently metamorphosed, were ob-
served on the higher marsh suggesting that they passed the tad-
pole stage in the marsh water.  Leopard frogs are present near
the water and over the marsh.

     Anthropods were broadly represented in the collections.
Back-swimmers, water scavenger beetles of two species, damsel-
fly naiads, mosquito larvae and other diptera larvae were ab-
undant.  Cladocera were represented by Ceriodaphnia and Simo-
cephalus.  Copepods were represented by two cyclopid types
identified to the genera Cyclops and Eucyclops.  No live ostra-
cods were collected although fossil shells occurred in the
plankton collections suggesting their recent demise.

     Mollusks were represented by three species of snails in-
cluding Helisoma trivolvis, a small species of Stagnicola, and
a Planorbula, and one species of fingernail clam in the genus
Musculium.

     Annelids were represented by at least three species; flat-

                               103

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worms, one species; rotifers, seven species; porifera, one spe-
cies; protozoa by fifteen species identified to genus and many
species not identified; algae, by eight species identified to
genus and many species of diatoms not identified.

     The surface of the open water was completely covered by
duckweed including Lemna minor, Lemna trisulca, and Wolffia sp.
No submerged or floating leaved aquatic plants were observed in
the open water.

     Encroachment around the perifery is being accomplished by
several species of plants including cattails, purple loosestrife,
arrowleaf, smartweed, a mint, an umbelliferae, and a spike rush.

     Quantitative determinations are restricted to the forms
collected by straining a measured volume of water through the
plankton net.  The name "plankton" has been advisedly applied
to thise category.  Because of the few sexually mature adults
(needed for species identification) and the many developing
stages the two species of copeponds are simply referred to as
cyclopids.  Counts are as follows:

                    Number                         Number
     Organism      per liter       Organism       per liter

     Phacus           150        Nauplius           1920
     Monostyla        960        Cyclopidae          750
     Lecane           420        Ceriodaphnia      Present
     Lepadella        300        Simocephalus      Present
     Platyias         340
     Salphina         300
     Diaschiza         30

     See the attached list of identified species.  All in all I
conclude that this is a healthy late-stage marsh community of a
type found in abundance in the metropolitan area and over much
of the state.  Adequate evidence is available to evaluate any
marked alteration in the quality of the environment caused by
the experimental techniques of the marsh evaluation study.
                               104

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      REPRESENTATIVE LIST OF THE FLORA OF THE STUDY PLOTS
    SCIENTIFIC NAME
    (or genus only)

Acer negundo
Fraxinus pennsylvanica

Salix (2 spp.)
Cornus sp.
Ribes
Sambucus canadensis
Rubus pubescens
Vitis vulpina
Rhamnus catharticus
Viburnum opulus

Dryopteris thelypteris
Onoclea sensibilis
Phalaris arundinacea
Calamagrostis canadensis
Poa sp.
Carex (3 spp.)
Scirpus atrovirens
Typha latifolia
Sagittaria sp.
Caltha palustrius
Mentha arvensis
Lycopus asper
Lycopus americanus
Rumex sp.
Urtica gracilis
Lysimachia thyrsiflora
Eupatorium purpureum
Eupatorium perfoliatum
Impatiens capensis
Lythrum salicaria
Asclepias incarnata
Stellaria longifolia
Campanula aparinoides
Solidago sp.
Polygonum sagittatum
Epilobium sp.
Chelonia glabra
Cirsium sp.
Aster sp.
Aster sp.
  COMMON NAME

Box Elder
Green Ash

Willows
Dogwood
Black Currant
Elderberry
Swamp Raspberry
Wild Grape
Buckthorne
Highbush Cranberry

Marsh Shield Fern
Sensitive Fern
Reed Canary Grass
Blue-joint Grass
Blue Grass
Sedges
Leafy Bulrush
Cattail
Arrowleaf
Marsh Marigold
Peppermint
Water Horehound
Water Horehound
Dock
Stinging Nettle
Tufted Loosestrife
Purple Boneset
White Boneset
Spotted Jewelweed
Purple Loosestrife
Swamp Milkweed
Long-leaf Chickweed
Marsh Bellflower
Goldenrod
Tear-thumb
Willowherb
Turtlehead
Thistle
White Aster
Purple Aster
 ABUNDANCE
(R,  C,  or A)

     C
     C

     C
     C
     C
     C
     R
     R
     R
     R

     R
     R
     A
     C
     R
  R to  C
     R
     A
     C
     R
     C
     R
     R
     R
     R
     C
     C
     R
     C
     A
     R
     R
     R
     R
     C
     R
     R
     R
     R
     R
                               105

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               REPRESENTATIVE
               THE OPEN-WATER
Algae, Blue-Greens

  Oscillatoria

Algae, Greens

  Cosmerium
  Closterium
  Euglena
  TracheImonas
  Phacus
  Mougeotia
  Oedogonium
  Ulothrix

Algae, Diatoms (Many)

Protozoa, Amoeboid

  Arcella
  Centropyxis
  Difflugia

Protozoa, Ciliates

  Stentor
  Stylonichia
  Spirostomum
  Chilodonella
  HalterTa
  Frontonia
  Cyclidium
  Vorticella
  Trachelophyllum
  Paramecium
  Coleps
  Urocentrum

Protozoa, Flagellates

  Peranema
  Anthrophysa
  Oikomonas
  Monas
  Bodo
OF ORGANISMS FROM
PORTION OF WETLAND

  Porifera

    Spongilla fragillis
      (Spicules only)

  Flowering Plants on Water

    Lemna minor
    Lemna trisulca
    Wolffia sp.

  Flowering Plants in Water (None)

  Rotifers

    Rotaria
    Platyi
las
    Salpina
    Monostyla
    Diaschiza
    Lecane
    Lepadella

  Platyhelminthes

    Stenostomum

  Annelida

    Chaetogaster
    Pristina
    Another unidentified

  Mollusca, Gastrapods

    Helisoma trivolvis
    Stagnicola
    Planorbula

  Mollusca, Pelecypoda

    Musculium
                              106

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               REPRESENTATIVE OF ORGANISMS FROM
          THE OPEN-WATER PORTION OF WETLAND  (cont.)
Crustacea, Cladocera

  Simocephalus
  CeriodaphnTa

Crustaces, Copepods

  Cyclops
  Eucyclops

Crustacea, Amphipods

  Hyalella
                              107

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                           APPENDIX B

                   ECOLOGY REPORT - PHASE II
              (Status of the Biota After One Year)
                               by
                  James A. Jones, Ecologist

GENERAL COMMENTS

     One year has elapsed since the initial examination of the
vegetation of control and experimental plots and the faunal and
floral analysis of the open-water portion of the wetland outside
the plots.  During this period the hydrolegists, biologists,
chemists and engineers of E. A. Hickok and Associates have com-
pleted installation of a superb array of water control and water
monitoring devices and developed mechanisms for monitoring the
activity of the microorganisms of the wetland substrate (and
other) .

     Significant to the ecology portion of the study there has
been a difference in the treatment given the experimental and
control plots of the study area.  The water level in the experi-
mental plot has been lowered by pumping then allowed to fill
again several times during the course of the year.

     Significant also have been the fact that the spring and
early summer have been exceedingly wet maintaining a somewhat
greater amount of water over the whole wetland than normal.  The
relative effect of the natural phenomenon and the artificial con-
trols will not be assessable.  The effort of this portion of the
study will be to identify any differences between the experiment-
al and the control plots and to compare the present biota of the
open-water wetland with that of one year ago.

THE EXPERIMENTAL AND CONTROL PLOTS

Methods for Reassessment

     Plot maps of the 1974 survey were used to determine the
lines followed in that survey.  This was necessary because re-
growth and recovery of the vegetation has been sufficient to
obliterate the paths established in the installation of the
tile and the plastic sheeting.  However, conspicuous forms of
vegetation such as trees,  willow clumps and the larger herbs
made it possible to orient myself at all times.  Many specific
                               108

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plants on the lines and at points of intersection were identi-
fiable.  Using this technique for orientation I traced each of
the trails three times—once for trees and shrubs, once for
grasses, sedges and cattails, and once for other herbs.  Many
of the trails were covered additional times to double check and
confirm impressions (see Figures 1, 2 and 3 for distribution of
vegetation).

     Vegetation of the wetland outside the control and experi-
mental plots was examined also, especially as it pertained to
willows.

Findings

     Two generalizations can be made:

     1.  There are noticeable changes in the wetland.

     2.  There are no detectable differences in the changes
         between the test and control plots.

     The larger willows have suffered the death of some major
stems as well as of lesser branches.  Careful examination shows
that this is not a unique occurrence of this year but that major
stems have died in years past not only on the study plots but
over the wetland outside the plots.  Older dead stems are on the
ground by the willow clumps and overgrown with grasses of pre-
vious years.  Dead and dying stems are found outside the study
area in this wetland and in other wetlands in the metropolitan
area.  Vital young growth is apparent in most clumps.

     There is an increase in the amount of touch-me-not  (Impat-
iens capensis) in both the test and the control plots.

     There is an increase in the number and vitality of the cat-
tails in both plots; this is especially noticeable in the test
plot because of the greater abundance of cattails there.  Many
more stems are producing seeds this year than last.  New stems
one to two feet tall are present in both plots.

     There is an increase in the amount of mint (Mentha arvensis)
related especially to the paths formed last summer.  The slight-
ly reduced competition of the previously well established cover
due to last summer's disturbance probably gave the mint a better
chance.

     The several small (seedlings and saplings) ash  (Fraxinus
sp.) and box elder (Acer negundo) apparent last summer could not
be found and no new ones were found this summer.

     The reed canary grass appears to be acquiring even a great-
er dominance over the western half of the plot although this is

                               109

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 difficult to establish.   (Perhaps the clipping data will give
 some indication.)   My impression may be prejudiced by the fact
 that no trails were established over most of the area this sum-
 mer requiring me  to break new trails through it.

      Two other plants,  though still rare are definitely more
 abundant, the wetland marigold (Caltha palustris)  and the arrow-
 head (Sagittaria  sp.).

 Conclusions

      Based on the  information that I can bring to  bear on the
 question I conclude that  there is no difference in the response
 of  the  vegetation  of the  control and experimental  plots result-
 ing from the "difference  in  treatment" afforded them over the
 past year.

      However,  there are changes in both plots.   While I am re-
 luctant to hypothesize on the causes of the  changes,  the summa-
 tion of the  observations  strengthens my feeling that the changes
 are definitely toward  the direction of a greater amount of water.
 The woody plants  (willows and trees and to some extent the red-
 ozier dogwood)  are under  stress while the more  typically aquatic
 herbacious plants  are  thriving and increasing.   The great major-
 ity of  the species have a wide tolerance and are not noticeably
 affected,  however.

      Further,  since both  sides of the study  area are  similarly
 affected,  I  am confident  that any effect on  the vegetation that
 might have been apparent  due  to the experimental activity has
 been overridden by natural forces  over the whole wetland.

 THE OPEN-WATER PORTION OF THE WETLAND

 Method  of  Reassessment

      Sampling  was  performed from the  edge of  the open  water as
 was  done previously.  It  was  necessary  to place  a  new  piece of
 plywood at the edge of the wetland  for  support.  (Anyone  ap-
 proaching  the  open-water  edge  should  be  warned  of  the  lack of any
 solid support  for  several feet  into  the  bottom  once  the  support-
 ing  root structure  of the  sedges  and  cattails is passed.)

     The sample was taken using  a dip net and a  plankton  net  as
was  done for the original samples last summer.   They were  taken
 to  the  laboratory  and examined  under  the dissecting scope  then
 under the compound microscope  as was  done previously.

 Findings

     I  can detect no significant difference in  the open-water
wetland in the two examinations.  No ducks were observed on my

                               110

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single visitation but that is not to say there are none in the
wetland.  Last summer they were only seen once in several visits
then only after a prolonged period of quiet observation.

     No leopard frogs were observed.

     More toads than last year were observed which indicates
that conditions were satisfactory for amphibian reproduction.

     The same anthropods, mollusks, and lesser animal phyla were
observed in flourishing numbers, many of them in reproductive
phases and developmental stages.

     The surface of the open water is again covered by  the three
species of duckweed.  Again no submerged or emergent rooted
aquatics were apparent.  The bottom is probably just too un-
stable to support rooted aquatics.  Succession into the open
water is from the periphery with the same formation as  last year
apparent.

     No attempt is made at quantitative determinations  this time
but in scanning the microscope fields it is apparent that the
same species are present.  There are less nauplius stage cope-
pods at this time but the adults of Cyclopidae are carrying
egg sacs which will be developing into nauplius larvae  shortly.
Comparing the species list of 1974 with a list that might be
prepared now, there is no significant difference.  One  addition-
al algae (Spirogyra) is noted; one rotifer  (Rotaria) was not ob-
served; an additional cladoceran  (Pleuroxisj  and an additional
copepod  (Ectocyclops) were observed this year.  It is apparent
that the diversity index is high indicating a healthful com-
munity.  Once this is established the number  of species listed
is directly proportional to the amount of time spent looking
and the number of samples examined.  Thus the deletion  or ad-
dition  of a few examples is not meaningful  for our purpose here.

Conclusions

     I  conclude that the activity on the wetland over the past
year has had no measurable effect on the life and vitality of
the open-water portion of the wetland as measured by the  composi-
tion of the biota of the plants and  animals of the open water.
                                Ill

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                      NORTH
                    25'
      GRASSES,  SEDGES  AND  CATTAIL
      LEGEND
      3 GRASSES  (90% POA)             o	
      SEDGES
      CATTAILS
Figure 1.   Distribution of Grasses, Sedges and Cattails
50'
112

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                  TREES AND SHRUBS
TW-SALIX SP.
A- FRAXINUS PENNSYLVANICA
B - ACER NEGUNDO
C^CORNUS SP.
E-SAMBUCUS  CANADENSIS
G-VITIS VULPINA
R=RIBES SP
HC = VIBURNUM  OPULUS
Bu=*  R. CATHARTICUS
BW= SALIX  SP.
 Figure 2.  Distribution of Trees and Shrubs
                          113

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                           114

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                           APPENDIX C

           METHODS OF SAMPLE COLLECTION AND ANALYSIS

OVERVIEW

     All methods used in the performance of this project were in
accordance with accepted methods specified by various agencies
and organizations including the Environmental Protection Agency,
U.S. Weather Bureau, U.S. Geological Survey, American Society of
Testing Materials, University of Minnesota, American Public
Health Association and the American Water Well Association.

SURFACE WATER QUALITY

     All water samples were collected in 500 ml  (0.13 gal)
"whirl-pak" bags sterilized with ethylene oxide.  Discrete
samples of stormwater runoff were collected using automatic
samplers, equipped with automatic starters, at 15 minute inter-
vals.

     Composite samples of stormwater runoff, where required,
were prepared from the discrete samples.  The volume of flow
passing through each flume was used to prepare the composite
samples.

     Samples of water from the wetland pilot zone were collect-
ed at the sump both automatically and manually.

     The analysis of all chemical parameters were performed in
accordance with Methods for Chemical Analysis of Water and
Wastes, U.S. Environmental Protection Agency  (1974 Edition)  (5)
and Standard Methods for the Examination of Waste and Wastewater
(13th Edition) (6) .

     TABLE 1.  METHODS FOR ANALYSIS OF CHEMICAL PARAMETERS	

Total Suspended Solids - Filtered through glass filter paper,
     dried at 103UC and weighed.
Ammonia Nitrogen  - Nesslerization colorimetric analysis.
Total Phosphorus  - Ammonia persulfate digestion with ammonium-
     mo lybate-ascorbic acid colorimetric analysis.
Biochemical Oxygen Demand - Dissolved oxygen change over  five day
     incubation.
                               115

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                         TABLE  1  (continued)

  Total  Coliform  -  Plate  count  on m-f  Endo-Broth  differential
      medium.
  Oxidation Reduction Potential - Redox meter measurement.
 SURFACE WATER QUANTITY
      The quantities of water flowing into and out of the wetland
 were determined using auto-start Stevens Type F flow recorders
 mounted on parshall flumes.  The flumes were calibrated and a
 stage-discharge relationship was used to determine the flow
 rates from stage measurements.  The time factor was determined
 rrom the flow record.

 GROUNDWATER

      Groundwater levels were measured in the observation wells
 and expressed as centimeters below the soil surface.   The top of
 the casings were determined from local benchmarks.

      The observation wells were sampled by pumping the standing
 water from the well and allowing the wells to refill.   A tyqon
 tube was inserted through the top of the well and the  sample
 pumped directly into the sampling container.

 SOIL ACTIVITY AND ENVIRONMENT

      Direct counts of  microorganisms were taken  from fresh soil
 suspensions stained with FITC and expressed  as number of  bacteria
 per gram of dry soil.   Direct microscopy method  utilized  a sam-
 ple taken from the natural environment,  diluted  quantitatively,
 and a known volume placed over  a given  area of microscope  slide
 Following appropriate  staining,  the  preparation  is examined under
 the microscope and all microorganisms in a given field  of  the
 microscope  are counted.   Recent  improvements  in  the staining of
 microorganisms have  greatly  facilitated  the detection and  the
 ditferention  of microorganisms  from  inert particles.  Of par-
 ticular _ usefulness  is the  method of  staining with FITC  followed
 by  examination and  enumeration by fluorescent microscopy,   with
 this  system,  microbial cells react with  the FITC and are visible
 due  to the  fluorescence subsequently emitted from those cells;
 inert and background particles do not react with the FITC and
 are not seen  under  the microscope.  Both surface and subsurface
 soils were sampled.

 mu  KC?fb°n dioxide evolution from the soil was measured in situ.
 The bottoms of one gal glass jars were removed and the jar¥ IH=~
 serted 5 cm (2 in) into the soil.  When capped this created a
closed chamber of fixed area to which the soil surface  was ex-
                              116

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posed.  A crucible was suspended from the lid, 10 mis of one
normal (five normal over 72-hour period) solution sodium hydrox-
ide was placed in the crucible and the lid screwed tight, after
24 hours, or 72-hours, the sodium hydroxide was quantitatively
collected and carbonate ions precipitated with barium chloride.
The sodium hydroxide was back titrated with standard hydro-
chloric acid and the milligrams of carbon dioxide absorbed was
computed.

     Soil temperatures were monitored throughout the sampling
period at 12 stations.  Soil temperatures at all stations were
found to be the same on a given day within the wetland.  A bi-
metallic thermometer was inserted 5 cm  (2 in) into the soil and
the temperatures recorded to the nearest Celsius degree.

     The oxidation reduction potential of the soils was deter-
mined using platinum probes and a Corning AG3 portable pH meter.

OTHER

     Precipitation data were collected using a Stevens Type SR
and a Stevens Type QR recording precipitation gage.

     Air temperature and relative humidity were recorded con-
tinuously using a Science Associates Model 257 hygrothermograph.

     Wind velocity data were recorded continuously using Science
Associates Model 436 and 442 anemometers with strip chart record-
ers.

     Pan evaporation values were determined manually using  a
U.S. Weather Bureau hook gage  and continuously using a Stevens
Type F level recorder.
                                117

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                            APPENDIX D

       PENMAN METHOD FOR CALCULATION OF EVAPOTRANSPIRATION

                        H = E + A + S+C

 where H = net radiant energy available at the earth's surface,
       E - energy used in evaporating water,
       A = energy used in hearing air,
       S = energy used in hearing the water, and
       C = energy used in heating the surroundings of the water.

      He reasoned that energy used in heating the water and its
 container could be neglected and that the evaporation of water
 could be predicted from the equation.

                             E = H - A

      Combination of this equation with Dalton's law results in
 an expression for E in which all needed values  are available from
 meteorological data.   The  Penman equation is:
                              _  AH  +  EaY
                            E  "   A  +
where E = evaporation  from  a  free-water  surface  in mm/day,

     A_ de    _
        dT Ta ~ sl°Pe  of  the  curve of vapor pressure at

                saturation  versus air temperature, Ta, in
                mm Hg/°F,

           Ea = 0.35(es - ed) 0'51+QV2

     es = saturation vapor  pressure at air temperature T=, in
          mm Hg,

     63 = actual vapor pressure of the air in mm Hg,
                             =     6.6
                           2   logh     n
where V2 = average wind velocity in mpd at a height of 2 meters,
      Vh = observed wind velocity at a height of h feet, and
                               118

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      H = net radiant energy available at the surface expressed
          in ram of water evaporated per day by that energy.

H is calculated from

H = Ra(l - r)0.18 + °'55n - aTa4(0.56 - 0.092/ed)
                      N
                                 0.10
where Ra = mean extraterrestial radiation in mm of water per day,
      r  = radiation reflection coefficient  (0.05 for water
           surface) ,
     n/N = ratio of actual to possible hours of sunshine,
      a  = Stef an-Boltzmann constant  (2.01 x 10~9 mm day""l °K~^),
      Ta = air temperature °K (°C, absolute) ,
      eci = actual vapor pressure of air, mm Hg, and
      y  = constant in wet and dry bulk hygrometer equation
           (0.27 for temperature in °F and vapor pressure in
            mm Hg) .
                               119

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                             GLOSSARY

 aerobic:   describes an environment containing oxygen and microbes
      which grow in the presence of oxygen

 anaerobic:  describes  an environment lacking in oxygen or
      microbes  which grow in lack of oxygen

 ecosystem:  all interacting parts of the  biological  and non-
      biological community

 eutrophication:  the process of nutrient  enrichment  of a body  of
      water in  which an inbalance is created  as  nutrient concen-
      trations  increase at a faster rate than utilized  by the
      biological community

 evaporation:   the  physical  process of water  loss by  heat energy
      conversion of water from the liquid  to  the gaseous state

 evapotranspiration:  the combined process  of physical  loss
      (evaporation)  and biological loss, transpiration,  of water
      from  a  system

 fluorescene  isothiocyanate  total  count (FITC):  a staining pro-
      cedure  utilizing  fluorescent and direct microscopic  counts
      for differentiation and  enumeration of  bacteria in  a soil
      suspension

mesophillic:  describes  the class of microorganisms which grow in
      the temperature range of 16-46°C, most  soil microorganisms
      are of the mesophillic class

nitrification:   the process of oxidation of nitrogenous compounds
      to nitrate in a soil system by a class of microorganisms
     known as nitrifying bacteria

phosphorus isotherm:  the equilibrium curve of phosphorus in
     solution versus phosphorus sorbed to soil particles, over
     a range of concentrations.   Each soil type has a charac-
     teristic phosphorus isotherm

sorbtion:   the  process  by which nutrients  are bound to  soil
     particles  by an ionic charge
                              120

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                             TECHNICAL REPORT DATA
                       (Please read Instructions on the reverse before completing)
 . REPORT NO.
 EPA-600/2-77-217
                                                 3. RECIPIENT'S ACCESSION«NO.
 , TITLE AND SUBTITLE
 URBAN RUNOFF  TREATMENT METHODS
 Volume  I  -  Non-Structural Wetland Treatment
           5. REPORT DATE
           December 1977  (Issuing Date)
           6. PERFORMING ORGANIZATION CODE
 , AUTHOR(S)
 Eugene A.  Hickok,  Marcus C. Hannaman and
 Norman C.  Wenck                 	
                                                 8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORG \NIZATION NAME AND ADDRESS
 Eugene A.  Hickok and Associates,  Engineers for
 the Minnehaha Creek Watershed  District
 P.O.  Box 387
 Wayzata,  Minnesota  55391	
           10. PROGRAM ELEMENT NO. ]_BC611
            ROAP: SOS 2; Task:  03
           11. CONTRACT/GRANT NO.

             S-802535
12. SPONSORING AGENCY NAME AND ADDRESS              Cin. / OH
 Municipal Environmental Research Laboratory--
 Office  of Research and Development
 U.S. Environmental Protection Agency
 Cincinnati.  Ohio  45268	
           13. TYPE OF REPORT AND PERIOD COVERED
            Final  1974-1976
           14. SPONSORING AGENCY CODE
            EPA/600/14
15. SUPPLEMENTARY NOTES

  P.O.  Hugh E. Masters  (201)-321-6678  FTS  340-6678
16. ABSTRACT
  A  significant impact  on lake waters is known  to be caused by storm-
  water runoff; providing control and treatment methods from this  pollu-
  tion source is a  large  and complex problem.   The methods developed by
  this project may  be implemented as an urban  stormwater runoff  control
  practice in many  of the urban centers of  the  country that have adjacent
  wetlands.

  The wetland used  in the study retained  77 percent of all phosphorus
  and 94 percent of the total suspended solids  entering the site during
  the evaluation period.

  It has been shown that the mechanism utilized by organic soils in the
  removal of nutrients  and contaminants is  the result of physical, bio-
  logical and chemical  mechanisms.

  This report was  submitted in fulfillment  of Grant No. S-802535 by the
  Minnehaha Creek  Watershed District and  their consultant, Eugene A
  Hickok and Associates under the sponsorship of the U.S. Environmental
  Protection Agency.	
17.

a.
                           KEY WORDS AND DOCUMENT ANALYSIS
               DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS C.  COSATI Field/Group
  Swamps,  Surface water  runoff,
  Material balance, Treatment,
  Filtration, Water pollution
Non-structural, Treat
ment  system,  Wetland
utilization,  Runoff
control,  Wetland eco-
system, Water balance
Nutrient  balance,
Microbial immobiliza-
tiorL
19. SECUI
     13B
13. DISTRIBUTION STATEMENT

  RELEASE UNLIMITED
19. SECURITY CLASS (This Report)
UNCLASSIFIED
21. NO. OF PAGES
   131
                                       20. SECURITY CLASS (This page)
                                       UNCLASSIFIED
                                                             22. PRICE
EPA Form 2220-1 (9-73)
                                     121
                                                          «U.S. GOVERNMENT PRINTING OFFICE: 1978— 757-140/6650

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