vvEPA
             United States
             Environmental Protection
             Agency
             Municipal Environmental Research  EPA-600/2-79-050a
             Laboratory          Ju|y -, 97g
             Cincinnati OH 45268       y
             Research and Development
Maximum
Utilization of Water
Resources in  a
Planned Community
             Executive Summary

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology.  Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.  Environmental  Health Effects Research
      2,  Environmental  Protection Technology
      3.  Ecological Research
      4.  Environmental  Monitoring
      5.  Socioeconomic Environmental Studies
      6.  Scientific and Technical Assessment Reports (STAR)
      7.  Interagency Energy-Environment Research and Development
      8.  "Special" Reports
      9.  Miscellaneous Reports

This report has been assigned to the  ENVIRONMENTAL PROTECTION TECH-
NOLOGY series. This series describes research performed to develop and dem-
onstrate instrumentation, equipment, and methodology to repair or prevent en-
vironmental degradation from point and non-point sources of pollution. This work
provides the new or improved technology required for the control and treatment
of pollution sources to meet environmental quality standards.
 This document is available to the public through the National Technical Informa-
 tion Service, Springfield, Virginia 22161.

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                                             EPA-600/2-79-050a
                                             July 1979
         MAXIMUM UTILIZATION OF WATER  RESOURCES
                 IN A PLANNED COMMUNITY

                    Executive Summary
                           by
         William G. Characklis, Frank J. Gaudet
           Frank L. Roe and Philip B. Bedient
   Department of Environmental Science and Engineering
                     Rice University
                  Houston, Texas  77001
                    Grant No. 802433
                    Project Officers

                      Richard Field
                    Anthony N. Tafuri
            Storm and Combined Sewer Section
              Wastewater Research Division
Municipal Environmental Research Laboratory (Cincinnati)
                Edison, New Jersey  08817
       MUNICIPAL ENVIRONMENTAL RESEARCH LABORATORY
           OFFICE OF RESEARCH AND DEVELOPMENT
          U.S. ENVIRONMENTAL PROTECTION AGENCY
                 CINCINNATI, OHIO  45268

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                       DISCLAIMER
     This report has been reviewed by the Municipal
Environmental Research Laboratory, U.S. Environmental
Protection Agency, and approved for publication.
Approval does not signify that the contents necessarily
reflect the views and policies of the U.S. Environmental
Protection Agency, nor does mention of trade names or
commercial products constitute endorsement or recommen-
dation for use.

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                          FOREWORD
      The Environmental Protection Agency was created
 because of increasing public and government concern about
 the dangers of pollution to the health and welfare of the
 American people.  Noxious air, foul water, and spoiled
 land are tragic testimony to the deterioration of our
 natural environment.  The complexity of that environment
 and the interplay between its components requires a con-
 centrated and integrated attack on the problem.
      Research and development is that necessary first step
 in problem solution and it involves defining the problem,
 measuring its impact, and searching for solutions.  The
' Municipal Environmental Research Laboratory develops new
 and improved technology and systems for the prevention,
 treatment, and management of wastewater and solid and
 hazardous waste pollutant discharges' from municipal and
 community sources, for the preservation and treatment of"
 public drinking water supplies,  and to minimize the ad-
 verse economic, social, health,  and aesthetic effects of
'pollution.  This publication is  one of the products of
 that:; research; a most vital communications link between
 the researcher and the user community.
      This project.focuses on methods maximizing the use of
 water resources in a planned urban environment, while
 minimizing,their degradation.  Particular attention is
 being directed towards determining the biological, chemical,
 hydrological and physical characteristics of stormwater
 runoff and its corresponding role, in the urban water cycle.
                               Francis T. Mayo
                               Director
                               Municipal Environmental Research
                               Laboratory
                            111

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                         ABSTRACT
     An ecologically planned community (The Woodlands,
Texas) has adopted a unique water management plan designed
to avoid adverse water quality and hydrologic effects due
to urbanization while benefiting from the existing natural
drainage.  The water quantity and quality were monitored
by a comprehensive sampling and analytical program to
evaluate the physical, chemical and biological effects of
its implementation.
     Chemical parameters monitored include oxygen demand,
organic carbon, nitrogenous compounds, phosphate compounds,
dissolved oxygen, pH, specific conductance and pesticides.
Numerous indicator bacterial organisms and pathogenic bac-
teria were enumerated as were various aquatic and edaphic
algal species.  Disinfectant demand and algal bioassays
were also conducted on stormwater runoff.
     Relationships were developed between stormwater run-
off quality, land use and runoff quantities in an effort
to predict pollutant loads.  The load-runoff relationships
were utilized in a modified version of the EPA Stormwater
Management Model (SWMM) to simulate stormwater runoff
quantity and quality for watersheds using the "natural
drainage" concepts at The Woodlands.
     This report was submitted in fulfillment of Grant No.
802433 between the U.S. Environmental Protection Agency
and Rice University, Department of Environmental Science
and Engineering.  This report covers the period July 16,
1973, to May 31, 1976, and work was completed as of
December 31, 1976.
                            IV

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                           CONTENTS
Foreword.  .  .  ,
Abstract.  .  .  ,
Figures  .  .  .  ,
Tables.  .  .  .  ,
Abbreviations  .
Acknowledgment.
                                                      . 111
                                                      . iv
                                                      . vi
                                                      . ix
                                                      . xi
                                                      .xii
   1.
   2.
   3.
   4.
   5.
   6.
Introduction	• t                ,
Conclusions	.*.".'!!!!."	4
Recommendations	! ! ! !	8
Site Descriptions	.....!!	n
Sampling and Monitoring Programs ...!!!!*""" 23
Results and Discussion 	 !!!!"""" 31
References,
                                                             130

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FIGURES
1
2
3
4
5
6

7

8
9

10

11

12

13

14

15

16

Location of study sites 	 ...
Existing drainage network for The Woodlands ....
Schematic water balance for The Woodlands . . . t .
Hunting Bayou watershed land use 	 . . , . t
Westbury Square watershed 	 ....,
Location of sampling sites and rain ge.uges within
the Panther Branch watershed. ... 	
The Woodlands man-made lake system with locations
of stormwater monitoring sites 	 	 . . . t
Site plan for the porous pavement parking lot . . ,
Temporal distribution of polychlorinated biphenyls
in The Woodlands 	 . . »
Temporal distribution of polychlorinated biphenyls
in aquatic fauna in The Woodlands 	
Temporal distribution of Mir ex in The Woodlands

Temporal distribution of Mir ex in the Conference
Center Lakes (A and B) 	
Temporal distribution of chlordane in The Woodlands

Seasonal algal standing crops at P^IO in panther
Branch 	 	
Seasonal algal standing crops at p-30 xn panther
Branch 	 	
Generalized pollutographs observed for stormwater
parameters 	 '....„....,.
12
15
17
21
22

25

28
30

46

47

49

50

51

61

62

67

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Number
                       FIGURES (continued)
 17   Load-runoff relationships for Kjeldahl nitrogen
        and total phosphorus. . .
                                      " *
 18

 19


 20


 21



 22



 23


 24


 25
27


28

29


30
32
                                                            Page


                                                             69

                                                             7Q


                                                             71
Load-runoff relationships  for nitrate and  ammonia

Load-runoff relationships  for total  suspended  solids
  and total COD as related to the watersheds studied.

Load-runoff relationships for soluble chemical  oxygen
  demand (COD) and soluble  organic carbon.  .....    72

Comparison of P-10 and P-30 temporal distribution of
  streamflow, total suspended solids and total COD
  for the storm event of April 8, 1975. ......    77

Comparison of p-10 and p-30 temporal distribution
  of streamflow,  total Kjeldahl nitrogen and total
  phosphorous for the storm event of April 8, 1975.

The Woodlands construction activity in relation to
  the p-10 and p-30 sampling sites	
      Scalar approach to FC/FS patterns  in different
        land use areas .  .  .
      Hydrograph and predicted solids loads for the p-30
        hydrograph period of 10/28/74 to 4/12/75
 26   Hydrographs and observed and simulated mass flow
        curves for P-30 storm events.  .
      Fitted curves for storm runoff and pollutant mass
        flows observed at p-10 on 4/8/75
      Hydrograph and cumulative hyetograph at the Lake B
        gauging station for the April 8,  1975 storm
        event
78


79


81


85
                                                            89
      Master programming routine in the SWMM. ......   91

      Subcatchments and drainage network in Hunting
        Bayou ........
          *
                                                            94
      Predicted hydrographs for suspended solids concen-
        trations at Hunting Bayou (5/8/75) ........   96

 31   predicted pollutograph and mass flow for suspended
        solids at Hunting Bayou (5/8/75) .........   97
                                                           107

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                       FIGURES (continued)
Number

  33   Reduction of total suspended solids through The
         Woodlands lake system	109

  34   Comparison of survival-mortality characteristics
         of fingerling catfish to chlorine exposure in a
         static bioassay and in a flow through bioassay. .  113

  35   Survival-mortality characteristics of fingerling
         catfish to ozone exposure in a flow through
         bioassay	  115

  36   Effect of short term chlorine exposure on the up-
         take of 22Na by the gills of Ictalurus puneta-
         tus	  117

  37   Effect of short term ozone exposure on the uptake
         of ^Na by the gills of Ictalurus punctatus . . .  118
  38   Optical densities of Selenastrum capricornutum
         after incubation in water from Panther Branch and
         Spring Creek	119

  39   Growth of Selenastrum in stormwater runoff in re-
         lation to hydrograph position at P-30	121

  40   Growth of Selenastrum in stormwater runoff from
         Hunting Bayou 	
                         	122
  41   Growth of Selenastrum in stormwater runoff from
         Westbury Square	123

  42   Water depth and rainfall for storm event of
         3/6/76 to 3/8/76.	124
                              Vlll

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TABLES
Number
I
2
3
4
5
6
7
8

9

10

11
12

13
14
15

16

17

Hunting Bayou Watershed Characteristics. ......
Westbury Square Watershed Characteristics. .....
Watershed Characteristics 	 	
Summary of LowHFlow Water Quality Parameters ....
Storm Event Hydrology Summary. ...........
Hydrological Definitions and Calculations 	
Rainwater Quality Analysis .... 	 	
Comparison of Rainwater and Runoff Quality in
Houston and at The Woodlands 	
Comparison of Groundwater Quality After Rainfall to
Runoff Water Quality 	
Runoff Water Quality Summary — Mass Flow and Weighted
Average 	 	 	
Summary of Westbury Runoff Bacterial Quality ....
Summary of Indicator and Pathogen Base Levels, Peak
Levels and Mean Levels at The Woodlands 	
Summary of Panther Branch Aquatic Algae 	
Summary of Edaphic Algae in The Woodlands 	
Water Quality for Stormwater Runoff, Untreated
Sewage, and Treated Sewage 	
Comparison of Stormwater and Wastewater Micro-
biological Analysis 	
Pollutant Load Ranking of the Pour Study Area


Page
21
22
26
32
34
36
37

38

39

41
5.2

54
60
63

64

66

73

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                        TABLES  (continued)
Number
  18

  19
Annual Mass Loads from P-10 and P-30 Watersheds. r

Comparison of Stormwater Quality at P-10, p-30 and
  Developing Areas During Storm #10. .......
Page

 75


 80
  20   Comparison of simulated and Observed Results for

21
22

23

24

25

26
27
28

29
Tnree storms 	 	
Modeling Requirements by SWMM 	 	
Comparison of SWMM Predicted Results with Observed
Flow Measurements for Hunting Bayou Storm Events .
Water Quality Modeling Results for panther Branch
for Storm Event of 12/5/74 	
Modeling Results for Future Development Upstream
for Lake B 	 	
Summary of Water Quality Parameters for sites Lake A
and Lake B During the April 8, 1975 Storm Event. . .
Stormwater Sediment Removal at Lake Harrison ....
Coefficient of Friction 	 	
Summary of Stormwater Quality for Porous Pavement
Storm on 2/20/76 	 	 	
Noise Levels 	
87
92

95

101

103

110
111
125

126
127

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                     LIST OF ABBREVIATIONS
 BOD       Biochemical  Oxygen Demand
 COD       Chemical Oxygen Demand
 DDE       2,2-bis-(p-chlorophenyl)-l,l-dichloro ethylene
 DO        Dissolved  Oxygen
 FC        Fecal Coliforms
 FS        Fecal Streptococci
 g         mass flow  rate
 HB        Hunting Bayou watershed
 LC50      Concentration of toxicant that  is lethal to exactly 50%
          of the test  organism during.continuous exposure for a
          specified  period of time.
 ortho P   Orthophosphate
 P         mass of pollutant
 PCB       polychlorinated biphenyls
 PDS       slope of the load-runoff curve  at some point in time
 PS        Pseudomonas  aeruginosa
 PVC       Polyvinyl  Chloride
 Q         volumetric flow rate
 r         rate of runoff
 S         total storage
 SA        Salmonella sp.
 SOC       Soluble Organic  Carbon
 ST        Staphylococcus  sp.
 SWMM      EPA Stormwater Management Model
 TC        Total Coliforms
 TKN       Total Kjeldahl Nitrogen
 TOG       Total Organic Carbon
 TP        Total Phosphate
 TSS       Total Suspended Solids
 tp        time to peak flow  in a hydrograph
WB        Westbury watershed
                               xi

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                        ACKNOWLEDGMENTS
     This project was supported by the U. S. Environmental
Protection Agency, The Woodlands Development Corporation and
Rice University.

     The Project Director expresses his sincere gratitude to
the EPA Project Officers, Anthony Tafuri and Richard Field and
to James Blackburn, Skip Christy, Peter D'Alessandro, Ralph
Everhart, Bill Kendricks, Ken Kirribrough, Robert Heineman, Plato
Pappas and James Veltman of The Woodlands Development Corpora-
tion for their time and valuable contributions .

     Acknowledgments also go to Robert Gabrysch, Jim Hutchinson,
Steve Johnson, Emil Kamanski, and Robert Smith of the Water
Resources Division, U. S. Geological Survey, for collecting and
compiling essential hydrologic data at The Woodlands.

     Credit is also due to the members of this multidisciplinary
project.  They are as follows:
Rice University

P. B. Bedient
E. Birch
J. Bishop
K. Carter
W. G. Characklis
J. Coffey
j. A. Conner
M. Curtis
S. Davis
J. Delia
F. M. Fisher
G. Fortenberry
F. J. Gaudet
D. Gee
P. Graves
J. H. Hall
B. Hammond
T. D. Hayes
D. Harned
J. D. John
M. A. Kessick
J. M. King
J. LeBlanc
M. Lee
H. M. Liljestrand
W. L. Lloyd
K. Manchen
D. C. Marks
R. Morrison
L. P. Metzgar -
T. Miller
P. MeSherry
L. Price
F, L. Roe
J. B. Smith
C. Stagg
M. Walker
C, H. Ward
J. C. Weismiller
L. Wong
A. Yarletts
J. S, Zogorski
                               XII

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               ACKNOWLEDGMENTS  (continued)


University of Texas School of Public Health - Houston, Tx,

              D. Casserly           p. Mittlemark
              E. M. Davis           D. Moore
              J. Greene             H. Tamashiro
              P. Mattox

Espey, Huston and Associates, inc. - Houston, Tx.

              W. H. Espey, Jr.      T. Remaley
              E. Diniz              F. Sofka
              D. Holloway           D. E. Winslow

S and B Engineers  - Houston, Tx.

   L. Chandler
   W. Davis
   J. Matson

Franklin Institute Research Laboratory - Philadelphia, Pa,

   R. Hoilinger
   E. Thelen
                          Kill

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                            SECTION 1

                          INTRODUCTION

     Non-point source pollution has become of greater concern
due to increasingly stringent point source effluent standards
and rapid development of urban areas.  Urban stormwater runoff
is one of the major non-point pollution sources and innovative
methods must be developed to minimize the impact of stormwater
runoff on receiving waters.  One such imaginative water resource
plan has been developed for The Woodlands, a planned community in
southeast Texas.  The U.S. Environmental Protection Agency,
Woodlands Development Corporation and Rice University have com-
pleted a three year research/demonstration project to evaluate
the water resource system at The Woodlands and develop strategies
for maximizing the benefits to the community while minimizing the
effect on receiving waters.

     The hydrological characteristics of a natural watershed
change with urbanization.  Replacement of flow-retarding vegeta-
tion with impervious surfaces,  such as roads and buildings, in-
creases the rate and amount of stormwater runoff.  Removal of
the water is traditionally implemented by the use of an urban
drainage system consisting of storm sewers and/or deep, concrete-
lined drainage ditches, designed specifically for rapid drainage.
Increased runoff volumes and peak flow rates result,  creating
problems of downstream flooding and channel erosion.

     Infiltration of stormwater is a major groundwater recharge
source, however emphasis on surface removal minimizes the in-
filtration rate,  resulting .in a lowered water table and possible
urban land subsidence problems.  Water quality deteriorates be-
cause natural purification provided by infiltration is compro-
mised.

     The urban environment,  typified by high population density,
provides a major pollutant source for runoff waters (1).  Recent
investigations recognize the significance and magnitude of pollu-
tion problems from urban stormwater runoff.  In terms of specific
pollutants,  the sediment yield problem is the most dramatic.  Due
primarily to urban construction,  urban sediment loads were found
to be as much as 75 times greater than loads in agricultural
regions (2,  3).  Other runoff pollutants reported higher in urban
regions include dissolved solids (4), coliforms (5),  biochemical
oxygen demand and chemical oxygen demand (BOD and COD), poly-
chlorinated biphenyls, heavy metals, pesticides and fer-

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tilizers  (6-9).  An increase in bacterial content is also re-
ported.  Claudon  (10) stated that agricultural and urban runoff
regularly contribute Salmonella sp. to recreational waters.
High fecal coliform an3fecal streptococcus numbers have been
found in urban runoff  (11).  Snowmelt and related agricultural
runoff in far northern climes in the continental U.S. have been
shown to contribute high densities of indicator bacteria and
pathogens to runoff  (12, 13).
     The addition of large quantities of inorganic nutrients,
particularly nitrogen and phosphorous, to freshwater lakes poses
a serious problem in lake management.  Municipal sewage  (14, 15,
16), agricultural drainage  (17), managed forestland drainage (18)
and fertilization often accelerate the natural process of eutro-
phication, thus enhancing the growth of bacteria, algae and aqua-
tic vascular plants.  Population densities of these organisms of-^
ten reach nuisance proportions and interfere with the aesthetic
qualities and recreational values of lakes.  These  "blooms" may
discolor, impart unsatisfactory tastes  (19, 20) and excrete toxins
into the water  (21, 22, 23).  They can also clog treatment plant
filters  (24),  and, upon decomposition, produce foul odors  (14).
Late summer  "blooms"'can create anoxic conditions and cause the
death of  fish.  Accordingly, value of lake properties may depre-
ciate and there may be  increased burdens on municipal water sys-
tems due  to added costs of  filtration and deodorization of the
water.

     Although literature on eutrophication is extensive  (25-29),
most limnological studies were conducted on lakes that were
^either eutrophic, or non-eutrophic at the time of study, and few
studies were continued long enough to follow changes in the
trophic status of lakes.  Even fewer studies have been initiated
on a drainage system before the construction of lakes.  Thus,
complete developmental histories of the water resources of par-
ticular areas are lacking.  Also, it is evident that information
on more effective methods of removing mineral nutrients from ef-
fluents prior to release into natural waters is badly needed
(30).

OBJECTIVES

     The overall goal of this research project was to evaluate
the water resource plan for The Woodlands and to make recommenda-
tions as necessary to maximize its effective utilization through
alterations in design or management.

     One of the major objectives was to modify and expand the
capabilities of the EPA Storm Water Management Model (SWMM) to
apply to the "natural drainage" system designed for The Wood-
lands.  SWMM has been expanded to include the following addi-
tional water quality parameters:  total COD, total Kjeldahl
nitrogen  (TKN), nitrates and phosphates.  The model has been
used to evaluate the effectiveness of the "natural drainage"

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system in minimizing changes in storm runoff quantity and quality
and to assist engineers and planners in designing the drainage
system for future development phases at The Woodlands.

     Since urban areas are typified by a variety of land uses,
including residential, commercial and industrial as the broadest
categories, determining effects of land use on stormwater quality
was conceived as another major project objective.  The Woodlands
development plan could not provide sufficiently diverse study
areas during the project period.  Consequently, urban watersheds
of similar physiographic and drainage characteristics in Houston
were studied to further relate storm runoff water quality to
urban land use.

     In order to accomplish these two primary objectives, a mas-
sive sampling and monitoring program was established.  Rainfall,
streamflow and over twenty-five water quality parameters were
monitored on a regular basis.  Included in the water quality_
program were intensive programs concentrating on bacteriological
water quality, chlorinated hydrocarbons and phytoplankton identi-
fication and enumeration.

     The sampling program included bacteriological tests to eval-
uate the traditional relationship between indicator organisms
 (e.g. fecal coliform, fecal streptococcus) and pathogens in
stormwater runoff.  Disinfection experiments were conducted to
determine relative effectiveness of Cl^, Br2 and 03 in untreated
stormwater runoff.  Toxicological testing determined maximum
tolerable concentrations of disinfectant in the receiving stream
for maintenance of fish populations.  Algal bioassays were con-
ducted to experimentally determine conditions, including nutrient
concentrations, necessary to prevent eutrophication in The Wood-
lands ' lakes.

     Finally, the performance of a porous pavement was compared
to a conventional pavement with regard to runoff amount and
quality, wet skid resistance, hydroplaning and other charac-
teristics related to driveability.

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                             SECTION 2

                            CONCLUSIONS

Runoff Quality
     From January 1975 to April 1976, seventeen storms were moni'-
tored at six different watersheds in the Houston metropolitan
area.  The intensive sampling and analytical effort resulted in
the following conclusions:

     1.  Stormwater runoff from an undeveloped, forested watershed
is relatively low in pollutants and pollutant indicators.  Typical
values are:  total phosphorous  (TP) 0.06 mg/1, total Kjeldahl ni-
trogen (TKN) 1.24 mg/1, total suspended solids  (TSS) 36 mg/1,
total COD 42 mg/1, and dissolved oxygen  (DO) 6 mg/1.

     2.  Development in forested watersheds significantly increases
suspended solids and nutrients in runoff.  COD and other organic
parameters are not affected.  Development increases surface water
turbidity.  Increased nutrient loads from developed areas will
create algal and macrophyte growth problems in urban lakes.

     3.  Urban runoff contains higher nutrient and solids loads
than forest runoff.  Nutrient concentrations  (ammonia, TKN,
nitrate, nitrite, TP, ortho phosphates) are as much as 10 times
greater in urban areas.  TSS concentrations are 4 times greater.
Higher concentrations, combined with increased runoff coefficients
 (the amount of runoff for a given amount of rainfall), provide
receiving waters with heavy pollutant  loads in urban areas.  Sedi-
ment buildup and algal growth problems result.

     4.  A man-made lake serves as an  effective trap for excessive
sediments transported by construction  site runoff.  During seven
separate storm events totaling 10.2 in.  (26 cm) of rainfall, 180
tons  (1.6 x 105kg) of sediment entering 110 ac-ft  (13.56 ha-m)
Lake Harrison was reduced to 34 tons  (3.08 x 104 kg) in the
effluent.  This was an 81% reduction in sediment load.

     5.  A definite first flush is observed for urban and undevel-
ped watershed runoff, most commonly for TSS and turbidity para-
meters.  The flush is related to transport of streambed sediments.
Urban drainage systems have increased  transport potential and
therefore exhibit higher flush concentrations.

     6.  Rainwaters contain phosphates, nitrogen and COD which ac-
count for a significant portion of runoff pollutant loads.

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     7.  Undisturbed soils are capable of removing nutrients
found in rainwater.  Disturbed soils in developing areas lose
this capability.

     8.  Municipal wastewater would require advanced treatment
to compare with nitrogen and phosphorous concentrations in storm-
water runoff.  Secondary treatment of wastewater will lower TSS
and COD concentrations below that in stormwater runoff.

     9.  A linear relationship exists between total pollutant
loads and total stormwater runoff, which is useful in comparison
between watersheds and analytical prediction of stormwater pollu-
tant loads.

    10.  A statistical ranking of four watersheds, on a Ib/ac/in
of runoff basis, indicates that urban watersheds are clearly the
greatest producers of suspended solids and nutrient loads. Loads
from forested and developing watersheds are lower by as much as
an order of magnitude.

    11.  Load-runoff curves may be used to sequentially simulate
mass flow curves.  Simulation of a six-month period, containing
three measured storm events, produced, reasonable comparisons of
of observed and simulated curves.

Eutrophication Potential

     1.  Algal associations encountered at The Woodlands were indi-
cative of oligotrophic or slightly mesotrophic waters.

     2.  Phosphorous is the limiting nutrient for algal growth in
the Conference Center Lakes and Panther Branch during low flow,
while nitrogen is more limiting in stormwater runoff samples.
Consequently, operation of the phosphorous removal process for the
treated sewage effluent entering the lakes is not necessary during
rainy periods.  The savings could amount to $50,000/year.

     3.  Surface runoff from fertilized soilds serves as a source
of nutrients and troublesome algae.  Fertilization of the golf
course, with subsequent increase in soil pH, results in larger
standing crops of blue-green algae and diatoms in the soil.

     4.  Urban stormwater runoff contains higher bacterial concen-
trations than runoff from forested areas.  Substantial numbers of
bacteria, including pathogenic species, were found.   Stormwater
runoff generally exceeded state recreational standards for fecal
coliforms (200 cells/100 ml).

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Disinfection

     1.  Excessive doses of chlorine or ozone are required for
effective disinfection of stormwater runoff.  Chlorine and ozone
demands greater than 8 mg/1 and 32 mg/1, respectively, were mea-
sured, primarily a result of high TSS concentration.

     2.  Toxicity studies using channel catfish  (Ictalarus punctalus)
in a flow-through bioassay system have established maximum safe
surface water concentrations at 7 yg/1 and 3 yg/1 for chlorine
and ozone, respectively.

Porous Pavement

     A porous pavement parking lot was installed at The Woodlands,
Texas and its performance compared to a conventional, dense pave-
ment parking lot.  The following conclusions resulted from the study:

     1.  Porous paving may be used effectively to store and release
stormwater which would otherwise cause erosion or flash flooding.
The quality of the released water is generally better than that
of runoff from standard paving.

     2.  Unacceptable lead concentrations suggest that stored
water under porous pavement should be prevented  from contacting
drinking water supplies.

     3.  Porous pavement is comparable to conventional paving in
terms of driveability and safety.  Mud and dirt  from construction
activities in the vicinity can clog porous paving.

     4.  Periodic maintenance of the paving  should be performed by
brush sweepers with vacuum followed by high  pressure water washing.

     5.  A more durable porous pavement can  be produced by using
lower penetration or stiffer asphalt than that at The Woodlands.

Stormwater Management Model

     The SWMM release of February 1975, referred to in this report
as the original SWMM version, was extensively modified.   The capa-
bilities of the modified version have been expanded to model run-
off and water quality from natural drainage  areas.  The study areas
where the new capabilities were tested  are The Woodlands  and
Houston, Texas.  During the course of this  study the  following con-
clusions were reached:

      1.  After correction of errors in  infiltration rate  computation,
the modified SWMM predictions of observed peak and  total  discharge
were relatively accurate but the pollutant  concentration  predic-
tions, which are dependent on exact hydrograph replication, could
not be modeled for the  study area.

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     _ 2.   Although runoff from natural drainage areas is of better
 qualzty than that from areas with conventional storm sewer drain-
 age,  the effect of construction activity in both types of areas
 could not be determined by the original SWMM version.   The pre-
 dicted values were always too low.   But, modeling of erosion from
 construction activities is now possibile by use of the modified
 SWMM  version.

      3.   Biochemical oxygen demand  (BOD) data produced inconsis-
 tent  results and,  therefore, BOD modeling proved unsatisfactory
 Data  for COD were  consistent and were used to model oxygen demand.

      4.   The functional relationship between pollutant mass and
 runoff volume can  be linearized by  the use of logarithmic trans-
 froms.   Resultant  linear equations  can be used to determine loading
 rates  and total pollutant transport from a watershed.

      5.   The exponential pollutant  removal or decay coefficient
 can be considered  as a  contstant in all geographical areas.   The
 modified SWMM allows for selection  of the value of this coeffi-
 cient  by the user.

     6.   The modified SWMM can  transport flow through  natural
 channels with a minimum of input data requirements.  Each natural
 channel  is described by a  Series of coordinates,  and the  program
 now calculates  the area-discharge curves which formerly had  to
 be input for each natural, channel.

     7.   The  modified SWMM can  determine the  cost  efficiencies  in
 the use  of_natural drainage  systems  relative  to  those  for  conven-
 tional drainage  systems  using either  user  supplied  or  default unit
 cost estimates.

     8.   The modified SWMM can  provide a detailed analysis of
 storage_and  flow into and  out of porous  (pervious) pavement  systems.
 The drain outflow, surface runoff, and storage volumes can be deter-
mined; but the lack of comprehensive data precluded the modeling
 of water quality in porous pavements.

     9.  The modeling schemes developed during this study require
 considerable input data preparation and, consequently,  the modi-
 fied SWMM, when applied to natural drainage systems, is more user

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                            SECTION 3

                         RECOMMENDATIONS
     Sediment discharge from construction area stormwater runoff
should be controlled by sedimentation basins or more sophisti-
cated methods.

     Research is needed to establish the relationship of air
quality to rainwater and stormwater runoff quality.  Special
attention should be focused on effects of projected ambient air
quality criteria.
                               N
     More standardized methods should be instituted to describe
storm events and watershed characteristics and to reduce data
resulting from a stormwater management program.

     A water quality management program should be instituted to
ensure proper maintenance of the aquatic ecosy:3tems in The Wood-
lands.  The first flush nutrients during storm events should be
captured or diverted and treated before release into the Con-
ference Center Lakes.  Homeowners and golf cou::se managers
should be encouraged to select and apply fertilizers with cau-
tion, since excessive, long-term fertilization could result in
nutrient buildups in aquatic systems of The Woodlands.

     The wet weather ponds and marshes in The Woodlands should be
managed since they often overflow into Panther Branch.  Excessive
concentrations of algae and nutrients in these habitats would
ultimately affect the water quality of Panther Branch and its
downstream receiving waters, especially if Panther Branch water
is utilized to control water levels in preexisting and future
lakes.

     Nutrient concentrations and detention times in the Confer-
ence Center Lakes should be controlled in order to prevent ex-.
cessive concentrations of algae.  Treated sewage effluent and/or
well water could be used to periodically flush these lakes and
dilute algal nutrients.

     The aquatic vascular plants should be managed in order to
prevent them from totally encompassing the Coniference Center
Lakes.  This might be accomplished by increasing the slopes of
the littoral zones and/or by harvesting and reridval of the
plants.

                                 8

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      Future investigations on water resources for bacterial as-
 sessment and management of stormwater runoff should establish
 basef low _ diurnal variability in indicator bacteria concentra-
 tions prior to evaluating storm events.

      Further investigations should determine the effect of land
 use on fecal coliform/fecal streptococci ratio.

  •u-i Alternative methods must be developed to yield greater reli-
 ability for bacterial indicator and pathogen quantification.
 wif-Ti         i            Patterns of bacteria in impoundments
 with relatively short detention times suggest that if disinfec-
 tion is to be applied to a particular stormwater source,  if at
 aio J|aSlble' the equivalent of stilling basins should be em-


      Examination of bacterial data for comparison with other
 water quality parameters for analysis or resource management
 purposes should not be accomplished using a simple arithmetic
 approach because non-linear relationships exist between vari-
 ables.   Bacterial data should be transformed to Iog10 basis.

      Before porous pavements are used for stored water release
 to aquifers,  the fate of lead salts in the percolated water
 should  be determined.

     _ Studies  are required for the design of porous  pavement
 parking lots  in other than flat areas in order  to avoid flood-
 ing of  low areas in a lot.

      The water  quality relationships  developed  in this  study
 should  be verified with data from other  watersheds  across the
 country to determine the possibility  of  data transfer.  New or
 revised coefficients may be  developed for  nonhomogeneous water-
 sheds or different climatological regions.   If  linearization of
 the log transforms of water  quality data is  found to be univer-
 sally applicable,  the prediction  of water  quality will  be faci-
 litated .

     The use  of  the  modified SWMM should be  promoted so that
 other users may  utilize  the  vastly  improved  capabilities and
 flexibility of the model.  The use  of baseflow recessions in de-
 signing for low  frequency or  dry weather flows should be con-
 sidered.   Porous pavements should be  evaluated, by means of the
modified  SWMM, as  urban runoff control facilities.  The reduction
 of data requirements  for modeling natural streams should be em-
phasized  and  the use  of the modified SWMM in modeling natural
drainage  systems should be encouraged.

     Water quantity and quality sampling at The Woodlands should
be continued at least until the watersheds have stablilized and

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erosion rates are reduced to pre-development or uniform levels.

     Records of all construction activity should be maintained
so that the location and total area under construction during
a storm event will be known.  This record will prove very helpful
in modeling water quality from that watershed.

     The modeling or erosion in the SWMM needs to be refined.
The coefficients of the Universal Soil Loss Equation were de-
rived for agricultural areas and their applicability to urban
and forested areas is limited.  Possibly, a new approach may
have to be considered.  The significance of pollution from
construction activity has generally been underestimated.
                                10

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                            SECTION 4

                        SITE DESCRIPTIONS
     Several sites in the Houston Metropolitan Area were chosen
to determine if stormwater runoff quality is dependent on land
use and development activities.  The primary study site is The
Woodlands, Texas, a planned satellite city selected for a com-
prehensive investigation of runoff quality during all phases of
development.  Two other watersheds were chosen to supplement data
collected from The Woodlands.  Hunting Bayou is a developed
watershed with strong industrial influences and deteriorating
residential areas.  Westbury Square is a middle class residential
area chosen because of the absence of construction in the water-
shed.  .The locations of these study sites are shown in Figure 1.
Each watershed is comprehensively described in the following
text.

THE WOODLANDS

General Description

     The Woodlands is a planned community being developed in
southern Montgomery County, Texas.  The community is situated in
a heavily forested tract about 35 miles (56 km)  north of Houston,
directly west of Interstate 45 (see Figure 1).   The Woodlands en-
compasses 17,776 acres (7194 ha)  and will be developed over a
twenty-year period beginning September, 1972.   In contrast to a
residential subdivision, The Woodlands will contain all services
of a modern city, including facilities for social, recreational,
educational, commercial, institutional,  business and industrial
pursuits.  The community concept is committed to high standards
for environmental and lifestyle quality.   The phased, long range
development places priority on ecological preservation and balance,
as well as social and habitational quality.  This objective is to
be accomplished through a comprehensive environmental preservation
and management program, including planning and design controls.
The water resource system in The Woodlands, including its drain-
age system, is a good example of such planning and was the pri-
mary subject of this research.

Development Plan

     The prime objective of The Woodlands is to provide the
finest urban environment in the Houston metropolitan area in

                               11

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                              INTERCONTINENTAL
                                 AIRPORT
                                 HUNTING  I3AYOU
WESTSURY
  SQUARE
   Figure 1.  Location of study sites.
              (1 mi = 1.6 km)
                     12

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 terms of physical setting and quality of human life and community
 services.  The basis for all aspects of development in The Wood-
 lands is a unique ecological inventory conducted from 1971-1973
 The geology, soils, drainage, water resources, weather, vegetation,
 and wildlife endemic to The Woodlands were critically evaluated
 for determining the most desirable location of roads, streets,
 homes, offices, and other physical structures.

      Land use allocation for The Woodlands provides for undevel-
 oped areas.  Residential areas will occupy 6,820 acres (2760 ha)
 of The Woodlands site, while 1,699 acres  (688 ha)  are designated
 for restricted industrial use.  Additional area has been allocated
 for retail, commerical, office, open space,  and other land sales.
 Approximately one-third (30.2%) of The Woodlands has been desig-
 nated as open space.  The majority of the' open space will be
 located within the floodplain of Panther Branch and its ma-jor tri-
 butary, Bear Branch.

 Climate

      The macroclimate of the Houston metropolitan area is domi-
 nated by the Gulf of Mexico.  Winters in the region are normally
 mild, while summers are hot and humid.   The  daily winter tempera-

 turl is
 711_  Avfra9e yearly rainfall in The Woodlands totals about 46 in
 (117  cm)  and is  evenly distributed throughout the year.   April
 May,  November and  December are usually the wettest months, while
 March is  the driest month.   The quantity variation of rainfall for
 specific  storm events  can  be significant especially during summer
 months.   Most rainfall occurring during June,  July,  August,  and
 September is associated with thunderstorms.   Precipitation during
 these months is  unpredictable and erratic.   Frequenty an  inch or
 more  (a few  centimeters or more)  of rainfall can  be recorded in
 one part  of  a watershed, while a very  short distance away no pre-
 cipitation occurs.

 Plant Ecology and Wildlife

      The _ tract of land  upon which The  Woodlands will be constructed
 is comprised,  almost completely,  of forest.  Eight major  forest
 ecosystems exist within the development.   Some of these ecosystems,
 including wet weather ponds,  marshes,  and  grasslands,  are  extremely
 unique and differentiated.   The  trees  which  are indigenous to  the

 PCS?  c-ak
     Because of the diversity of vegetation and varied food
     oS/-?°St £f the £auna endemic to southern watersheds are found
   the site.  Common birds include blue jays,  red-headed wood-
peckers, cardinals, Carolina chickadees, Carolina wrens and pink
warblers.  Mammals frequently encountered are whitetail deerT

                                 13

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raccoon, armadillo and ringtail cat.  Numerous snakes and
other reptiles are also frequently observed on the site.  The _
environmental impact of the development upon the wildlie and
vegetation has been estimated to be minimum (31-33) .

Soils

     A comprehensive soil survey was performed at The Woodlands
development site by the USDA Soil Conservation Service, from
March 1972 to June 1973.  The results of this survey are published
in a report entitled "Soil Survey of The Woodlands"  (34).  The
survey describes a total of 22 soil types in the area.

     The soils on The Woodlands site characteristically contain a
zone of clay accumulation.  The clay zone, which generally occurs
at a depth of from 18 in. (46 cm) to 6 ft (1.83 m) below the ground
surface, is relatively impermeable and creates a seasonal perched
water table.  The high water table is an important 'factor in
maintaining the diverse vegetaion which occurs on the site.  Of
major concern in the impact that development could have in re-
ducing recharge to this shallow reservoir due to soil compaction
and construction of impervious surfaces.  If recharge is signi-
ficantly decreased, it could have a detrimental effect on the more
sensitive plant species on the site.  Also, a reduced recharge
could have a significant effect on the base flow characteristics
of the streams draining The Woodlands site.

Existing Drainage

     The natural drainage for The Woodlands community is shown in
Figure 2.  Approximately 80% of the development is drained by
Panther Branch, a tributary of Spring Creek.  The remaining portion
of the development drains directly into Spring Creek, which has a
total drainage area of 750 sq mi  (1942.5 sq km).  Because Panther
Branch and its major tributary, Bear Branch, represent the major
existing drainage for the development site, the hydrologic, morpho-
logic and transport characteristics of this stream are of extreme
importance.

     Both Bear Branch and Panther Branch meander extensively along
well-defined, and low-flow channels, respectively, 9.0  (14.48 km)
and 14.6 mi  (23.5 km) in length.  Alluvial sediments, small
riffles, and slow moving pools are commonplace  within Panther
Branch and Bear Branch.  The width of the low-flow channel is highly
variable but is normally between 5 and 20 ft  (1.5 and 6.1 m).  When
the capacity of the defined channel is exceeded, storm runoff dis-
charges into a very broad, flat flood plain, presently covered
with heavy brush.  Flood runoff is characterized by  low velocities
and shallow depth because (a) a large land area is inundated,
(b) flow resistance is high, and  (c) hydraulic slope is low.
Excluding those areas presently under construction, essentially no
evidence of any serious erosion can be found anywhere in Panther
Branch watershed.
                                 14

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                                      PANTHER BRANCH
                                       DRAINAGE AREA
                                         OUTLINE
                SCALE  IN  MltES
                                                      SAWDUST ROAD
Figure  2.  Existing drainage network for The Woodlands (numbers
            shown indicate elevation above mean sea level).
            1  mi = .1.6 km
                                15

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     Flow rate measurements in Panther Branch indicate that water
velocities as low as 0.04 to 0.10 ft/sec  (.012 to  .03 m/s) are
typical for low-flow conditions.  The slow travel  rate is a
result of low channel slopes present throughout the drainage net-
work.  The total change in channel elevation across the drainage
basin is about 120 ft (36.5m m), with an  average rate of change
of 5 to 7 ft/mi  (.95 to 1.33 m/km).

     The impact of low channel and land slopes within The Wood-
lands is reflected in an extremely low stormwater  runoff coeffi-
cient.  USGS data for the 1973 and 1974 water years show that
only 23% of total rainfall resulted in surface runoff.  The re-
maining 77% either evaporated, transpired or infiltrated into the
ground.  It should be noted that rainfall was heavy during the 1973
and 1974 water years, respectively 77 in.  (195.(i cm) and 51 in.
(129.5 cm).  It is estimated that only 10 to 15% of rainfall will
run off during a year of average rainfall, 45 in.  (114.3 cm)  (35).

     Runoff from the Panther Branch watershed is not evenly dis-
tributed throughout the year.  During the summer months of May
through September little discharge occurs, exce:pt  immediately
following an intense and prolonged rainfall.  The  average daily
low flow discharge at Sawdust Road, including summer months, is
1 to 2 cfs (.028 to .056 m3/sec).  An average daily discharge of
100 cfs (2.8 m3/sec) at this site is exceeded only 5% of the time.

WATER RESOURCE SYSTEM OF THE WOODLANDS

     The annual rainfall at The Woodlands is partitioned as run-
off into existing lakes and streams and infiltration into the
ground.  Losses result from evapotranspiration, evaporation and
subsurface transport to streams (Figure 3).

     The maintenance of a satisfactory groundwa.ter reservoir
above the perched water table is critical for the  continued
growth of vegetation.  Any drainage system for The Woodlands must
consider the detrimental consequences of disrupting the movement
of water within this shallow aquifer.  Deeper a.quifers (1800 ft)
(549 m) are used for community water supply.

     A series of wet weather ponds and variable volume lakes will
serve as recreational centers, wildlife preserves  and, more im-
portantaly, storage for stormwater runoff.  This system of water
reservoirs contributes to the maintenance of an adequate perched
water table for plant life.  Lake water will be lost primarily
through surface evaporation and irrigation.  Inflow to the lake
system will result primarily from stormwater runoff and reclaimed
water water from 2 or 3 sewage treatment plants.   The projected
volume of waste water is 20 mgd (0.88 m^/sec).  If necessary,
treated sewage effluents can be discharged directly into Panther
Branch.
                                16

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TOTAL
     9 USD
CONSUMPTIVE USES
      ft
                                          WATER DEMAND OF
                                          THE  WOODLANDS
                                             J20M6DJ
                                          TRANSPORT AND
                                           TREATMENT OF
                                         SEWAGE (15-20 MGO)
                               EVAPORATION
                                       IRRIGATION
       SURFACE RUNOFF
                       PANTHER BRANCH
                            OR
                        SPRING. CREEK
       Figure  3.   Schematic water balance for The Woodlands.
                                      17

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"Natural prainacre  System"
     The Woodlands Development Corporation has specified  that tne
basic drainage  system for their new community will utilize   natu-
ral drainage" concepts.   These design principles have been  re-
ported in  "Natural Drainage Systems:  An Alternative to Conven-
tional Drainage Systems" by Winslow, Veltman and Espey  (36)  and
will not be  described in detail herein.  Rather, a brief  summary
is presented on the "natural drainage" concept and reasons  for
its selection in The Woodlands.

     The normal procedure for disposing of stormwater runoff
within the Houston Metropolitan Area is to enlarge the  natural
drainageways by deepening and widening existing stream  channels
and providing supplementary lateral drains.  In the City  of
ISuston, thiS approach generally results in stormwater  sewers for
the lateral  drainage and deep, wide, concrete-lined ditches for
the major  drainage.  This solution to stormwater disposal,  al-
though widely used and approved by the City of Houston, was in-
compatible with one of thS major criteria used  in  developing The
Woodlands— preserving and enhancing the natural  environment.
 "Natural drainage" cbncepts adopted by WDC are  envisioned as a
method  of  providing ade
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stormwater runoff and serve as a sedimentation basin for the 337
acre (136.4 ha) watershed under construction at this time.  Upon
completion it will include an 18 hole golf course meandering
through a residential area.

      Lake A is a variable volume lake to be used for non-contact
recreation.  Lake discharge is controlled by an outlet box at an
elevation of 121.8 ft (37.1 m) above sea level.  Water from Lake A
irrigates The Woodlands Gold Course bordering the lake's eastern
and northern shores.  In dry weather, the water level drops due
to evaporation and groundwater is pumped into the lake to com-
pensate.  Lake water is not lost to groundwater recharge due to
a clay bottom which serves as an effective seal.

Porous  Pavement

     An experimental porous pavement parking lot has been con-
structed  at  The Woodlands  as  a possible  solution to the problem
of  excess runoff  from impervious urban surfaces.   The  lot con-
sists of  a permeable asphalt-concrete topping,  overlaying a coarse
base and  fill  material.  The  pavement is  designed to allow rain-
water to  percolate  through the asphalt and  infiltrate  into an ex-
isting  groundwater  reservoir.  Besides reducing urban  stormwater
runoff  volumes, porous pavement has  other benefits  such as anti-
skid properties and better visibility of  road markings.

HUNTING BAYOU  WATERSHED

     The  Hunting  Bayou watershed is  located  in  northeast Houston
near the  intersection of Highways 50 and  610.   The  1,976 acre  (800 ha)
watershed  is characterized by low land slopes and impermeable
soils with high clay content.  Primary drainage channels are
trapezoidal  in shape and lined with  vegetation  which varies in
density from moderate to very heavy  depending upon  the  season
and maintenance schedules.  The majority  of  the secondary drain-
age is  provided by roadside,  grass-lined  swales comparable to
the drainage design at The Woodlands.  A  fourth of  the  area is
drained by storm  sewers.   There are  no known effluents  entering
the drainage system, however, point  sources  are probable due to
the age of the residential districts (illicit sanitary  sewer
connections  to the storm system and  the presence  of industrial
influences).   The area is poorly maintained  and  stream  channels
are sometimes  used as dumping areas  for waste materials  such as
oil and grease, old tires, and other refuse.

     Land  use  in  the watershed is mixed  (Figure  4) with  resi-
dential areas  comprising the  largest segment.   Residences  are
mostly  single  family dwellings of low value.  Table 1 gives demo-
graphic information regarding the indigent population.
                                19

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      Industrial  activity in  the watershed  includes  meat  packing
 and rendering plants, wrecking yards  and mechanical contractors.
 Various  commercial  establishments  in  the watershed  support  the
 residential population.   Construction in the watershed is cen-
 tered around  completion  of Interstate Highway  610.

 WESTBURY SQUARE  WATERSHED

      The "natural drainage"  system utilized by The  Woodlands  is
 an innovative method  for controlling  stormwater runoff  and
 preventing water quality deterioration.  A Houston  watershed
 with  a conventional drainage system was selected as a compara-
 tive  study site.  The residential  land use of  Westbury is simi-
 lar to that being constructed at The  Woodlands.

      The 210  acre  (85 ha) watershed is located in Southwest
 Houston  and is comprised exclusively  of single-family residen-
 tial  dwellings.  No commercial or  industrial influences  are
 present  in this  area.  The watershed  is completely  developed  and
 contains no construction sites, empty lots, and no  undeveloped
 land.  Figure 5  and Table 2  provide watershed  information.

      Demographic information  from the  1970 census presents the
 area  as  upper-middle  class, median annual  income of  $19,000.
 Population density  is approximately 11 persons/acre  (27 persons/ha),
 or 4  persons/household.

      The separate stormwater  drainage  system consists of lateral
 drainage provided by  concrete pipe, 18 in.  to  54 in. (45.72 cm to
 137.16 cm) diameter,  connecting with  a main collecting channel at
 roadway  intersections.   The  channel is a 10 ft  (3 m) deep open
 grass-lined ditch,  often  choked with vegetation in  the summer
months.  The  ditch  passes through culverts beneath  roadways, and
 at these points, ponding  occurs upstream and downstream providing
 slight storage of runoff  and  a reduction of flow velocity.  Low
 runoff coefficients can be expected due to the  low  land slope of
 only  0.8%.  Impervious cover  is estimated  at 35.4%.   No dry weather
 flow  is  present  in  this watershed.

      Soils in the area are predominately dark  clays  and loams,
 characterized by low  permeability and high available water
 capacity.  The soils  tend to be mildly alkaline or  neutral.
Rainfall in the  area  averages 39.5 in/yr (1.0  m/yr).
                                20

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                                                                                                                                         0)
          CO
          o
                                                              to
                                                              B
                                                              O
                                                              10
                               to

                               §
                               to
                               H
                               o
                               a
                                            in
                                            o
            to
            4J
            U
            a
                                                                                                           n
                                                                                                           9
                                                                                                           to
                                                                                                           e
                                                                                                           
                                                         ni    m
                                                                                         s
                                                                                         i
                          •S
c
o
to
H

&
                                                                      21

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        TABLE  2.   WESTBURY SQUARE WATERSHED
                     CHARACTERISTICS -
        Total Drainage Area
        Single Family Residential Areas
        Impervious Cover
        •Population Density
        Family Median Income
        Median School Years Completed
        Home Values - Mean
        Persons/Household
        Rooms/Housing Unit
210 acres (SISha)
          10054
          35.4*5
7,040 persons/mile2  (2718 pers/km2)
$19,000/year
 14.7 years
$29,000.00
 3.8 persons
 7.5 Rooms
        * Data derived from 1970 Census:  Census  tracts 427 and
          428 are averaged.
             N
       1 in.  = 2.54
                     cm
Figure  5.   Westbury Square watershed
               (scale 1 in.  = 1000  ft) .
                                22

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                             SECTION 5

                 SAMPLING AND MONITORING PROGRAMS


      This section summarizes the field sampling and monitoring
 programs initiated in September 1973.  The sampling programs were
 divided into two distinct segments.   First,  selected terrestrial
 and aquatic environments within The  Woodlands  were sampled during
 periods of no overland runoff (low-flow conditions)  for the oc-
 currence and concentration of selected physical,  chemical and
 biological constituents.  These measurements comprise a low-flow
 data bank from which (a) the effect  of urbanization on the water
 resources of The Woodlands can be quantified,  and (b)  the water
 quality criteria of the lakes within The Woodlands can be estab-
 lished  to insure their usage for recreational  and aesthetic pur-
 poses.   Sampling points were located for the comparison of un-
 developed and developing areas within The  Woodlands.   Sampling
 sites downstream in the drainage area of Panther  Branch provide
 data to establish the impact of The  Woodlands  development upon
 the water quality of the receiving body (Spring creek).

      The second phase of the sampling program  concerned itself
 with quantifying the chemical,  physical, hydrological  and bio-
 logical characteristics of overland  runoff and its subsequent
 impact  on the water  resources  of The Woodlands.   The stormwater
 sampling program involved  the  development  of pollutographs for at
 least 25 different water quality parameters  per storm  event.   Not
 every storm  event was  evaluated  but,  rather, selected  storms  were
 monitored to define  various  hydrolog'ic and seasonal conditions.

      A  comprehensive hydrologic  network was  established within
 the  study area,  focused around continuous discharge recording
 stations  operated and maintained by  the Water  Resources Division,
 U.  S. Geological Survey, Houston,  Texas  at the request  of  The
 Woodlands  Development Corporation.   The  purpose of this network
 was  to  accurately delineate  the  movement of water, especially
 surface flows, within the  new  community.  For  this purpose, a
 weather  station,  rain gauges,  streamflow stations and groundwater
 observation wells  were  established.

 DRY WEATHER  PROGRAM

     Dry weather  field  sampling  programs were  conducted within
 the Panther Branch watershed,  in the  immediate vicinity of The
Woodlands  development.  These programs were directed toward

                                23

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gathering a basic data bank on the algal, bactezial, chemical,
hydrological and physical characteristics of thi.s area's surface
water resources.  Water, soil, plant and animal samples were
collected on a regular basis for analysis.

     The locations of aquatic sampling sites are*, shown in Figure
6   Stream water samples were collected at sites located from the
headwaters of Bear Branch and panther Branch downstream to Spring
Creek.  Several ponds and marshes within the watershed were also
sampled.  Sampling frequency was about once per month.

     Specific analysis performed on water samplers included
temperature, dissolved oxygen  (DO), pH, turbidity,  total sus-
pended solids  (TSS), soluble COD, total COD, soluble organic
carbon  (SOC), total Kjeldahl nitrogen  (TKN), total  phosphorous
 (TP), orthophosphate  (ortho P), ammonia  (NH3), nitrite  (NO2),
nitrate  (NO3), BOD, and  specific conductance.  The  presence of
specific pesticides and  chlorinated hydrocarbons; was also deter-
mined   In addition, the following bacterial emimerations were
conducted: fecal coliforra,  fecal streptococcus, total coliform,
total bacteria, Salmonella-Shigella sp., Pseudononas sp., and
Staphylococcus  sp.  Algae  and macrophyte enumerations were also
conducted.

      Other water samples were collected for experimental purposes
 to determine limiting nutrients for algal growth and bacterial
 disinfection characteristics.

      Soil samples were collected from 21 sites located in the
 study area and analyzed for bacterial and algal content.
 Leachates from these samples were tested for pesticides and
 nutrients.

      Plant and animal samples were collected on a  regular basis
 and examined for the presence of pesticides and chlorinated
 hydrocarbons.  Aquatic  animals collected include fish, shrimp
 and crayfish.

 STORM EVENT PROGRAM

      The stormwater monitoring program used a hydrologic network
 combined with  intensive sampling to characterize runoff quality.
 Runoff samples were collected at six  sites  foi:r _ locate^ within
 The Woodlands, a fifth  in  Hunting Bayou, and a sixth at Westbury.
 Characteristics of each watershed are summarized in Table 3.

 The Woodlands

      The Woodlands sampling  locations and  their designations  are
  listed below:

       1.   panther Branch at the  Confluence

                                 24

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          with Bear Branch
      2.  Panther Branch at Sawdust Road
      3.  Outflow of Lake Harrison
      4.  Inflow of Lake Harrison
P-10
P-30
Lake A
Lake B
 A U.S.G.S. gauging station measured streamflow at each of these
 sites .

      Station P-10 is located on Panther Branch 200yds (182.9m) down-
 stream  of the confluence with Bear Branch (see Figure 6)    The
 watershed at this point measures 16,050 acres (6,495 ha)  of pre-
 dominantly undeveloped pine-oak forest.  Data collected  from P-10
 represents runoff from a natural area devoid of urban influences
 and,  when compared to other sites,  serves to determine the ef-
  rS Of4.urba2, inf luences on r^noff quality.  U.S.G.S. establish-
 ed the  streamflow gauging station at p-10 in July 1974.

 4,-u   P7?0.is located downstream on Panther Branch and includes
 the P-10 drainage area in its 21,606 acre (8,744 ha)  watershed
 (Figure 6).   The  sampling site is in an advantageous  position for
 monitoring runoff quality from development areas immediately up-
 ™^?™ U.S.G.S.  has operated a streamflow gauging and monthl?
 sampling station  at this site since April 1972.   Because  con-
 struct ion at The  Woodlands  was a continuing process,  water cmal-
 ity changes  were  expected.                                  H

      Two stormwater sampling stations,  shown in  Figure 7   were
 located at Lake Harrison to measure stormwater inflow and out-
 flow.   The upper  station, situated  in a swale at the  head of
 Lake  B,  sampled runoff from the  major source of  stormwater flow
 into  the lake system.   During dry weather, no flow occurs  in the
 swale.   The  337 acre  (136 ha)  watershed was  under extensive con-
 struction  at the time  of study.   The  Lake A  gauging station
 adjacent to  the lake  outflow box, was  sampled to assess effects
 of detention on runoff quality.   The drainage area at Lake Harri-
 son outflow  is 483  acres  (196  ha) .

     Rainfall data was  available  at five locations in, or  near
 The Woodlands (see Figure 6) .  The precipitation data collected
 at these sites determined the  average hyetograph  for the Panther
 Branch watershed during  each storm event and defined the in-
 tensity, duration, time period and total amount of rainfall
 The rainfall network provided data on the spatial and temporal
 characteristics of rainfall within the study basin.
•   ^       samPles were analyzed for the same parameters listed
in the dry weather flow program.  Chemical data were used in con
junct ion with flow data to derive mass flow relationships for
each constituent during each storm.
                                27

-------
                                 4.1 ac (1.66 ha)
                                 20 ac ft (2.47 ha-m)
                                 Normal Water Level
                                   el. 128 (39 m)
                                 Average Depth
                                   6 ft (1.83 m)
AREA SHOWN IN DETAIL
                                     j.2.5 ac (54 ha)
                                     90 ac ft (11.1 ha-m)
                                     Normal Water Level
                                       el. 122  (37.2 m)
                                     Average Depth
                                       8  ft  (2.438 m)
                                   •  LOCATIONS OF U.S.G.S.  GAUGING STATIONS

                                               O    400   800 feet
                                                   SCALE

                                                1 ft = .305 m

                                                1 ac = .405 ha
            Figure  7,
The Woodlands man-made  lake system with
locations  of stormwater monitoring sites.
                                   28

-------
Hunting Bayou

     The stormwater sampling program at Hunting Bayou was similar
to The Woodlands, except that only one sampling site was monitor-
ed.  Stormwater samples were collected from the U.S.G.S. Hunting
Bayou at Falls Street gauging station  (see Figure 4).  precipita-
tion data were available from two recorders located south of the
drainage basin.

Westbury

     Runoff from this watershed was sampled above the Atwell'
Street bridge crossing the primary drainage channel (see Figure
5).  Flow measurements were determined using a pygmy f f ow meter, and
precipitation measurements were made using a portable volumetric
gauge located at the sampling site.

Porous Pavement

     The porous pavement parking lot at The Woodlands Conference
Leisure and Commercial Center was finished October  1974.  The
pavement consists  of a porous asphalt-concrete topping  overlaying a
gravel reservoir.   Porous  topping is produced  from  an asphalt  bound
aggregate deficient in fine  sizes.  In comparison to conventional
toppings, increased amounts  of  asphalt are required to  compensate
for  loss of  strength resulting  from the  lower  contact area  between
discrete particles of aggregate.

     Soil permeability is  poor  at The  Woodlands, so to  simulate
a  reasonably permeable subsoil, the site of the porous  pavement
lot  was excavated  to a depth of 4 ft  (1.2 m) and a  permeable
soil/sand mixture  was filled into the  excavation to a depth of
33.5 in.  (85 cm).   Open aggregate base course,  12 in.  (30.5 cm)
in depth was placed over the simulated subbase and  2.5  in.  (6.6  cm)
of porous topping  was put  down.  A  French drain was constructed
to drain water  from the soil/sand subbase.

     The site  plan for the experimental  parking lot is  shown in
Figure  8.  Stormwater samples were  collected from the_water depth
wells  in both  conventional and  porous  lots.  The quality of
stormwater percolating through  porous  pavement was  assessed and
compared to  conventional pavement runoff for the following  chemi-
cal  parameters:  TP, orthophosphate,  NH3, N02, TKN, pH, conduc-
tance,  soluble COD, lead,  zinc, and total organic carbon (TOC).
                                  29

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                             SECTION 6

                      RESULTS AMD DISCUSSION
 DATA SUMMARY

 Dry Weather Monitoring
                            within The Woodlands was determined
       m   -K        Periods to establish a baseline water qual-
    .   The baselme will be useful for determining (a) the effect
 of urbanization on the water resources of The Woodlands over the
 ^no4° Yea^'  ^ ^b) inmediate comparisons betweeSsLJmwater
 Ji?ef ar^aindicaSfd    ?10W ^ ^ity.  Woodlands sampling
 .sites are indicated in Figure 6.  Dry weather, or low flow  re-
 fers  to time periods when the stream stage is essentially COn-
 f?ti •  ?hf t1?? Peri°d foll™i*9 * storm event rJquiSdto
 establish low-flow conditions depends on factors s2ch as antece-
 dent  moisture conditions,  time since last storm, rainfall Surl-
 tion  and intensity,  and groundwater elevation.  in the Panther

                              '^1'™
      Low  flow water quality data  for  Panther  Branch, Bear Branch
and  Spring Creek  are presented  in Table  4.  The headwaters  in
the  stream system are  low  in inorganic nutrients but signifi-
cant contributions from developing areas increase concentrations
below P-10.  The  primary nutrient input  is from the golf course
^e^la^L?PStream °? P~30'   Or9anic concentrations are high
nnm  ?7   COD)  consisting  of relatively  non-biodegradable  (2 mg/1
BOD)  leachate from decaying vegetation in the forest.  COD  dilu-
tion occurred downstream and the lowest concentrations were
observed  in Spring Creek.  TSS  changed drastically as the
stream passed through developing  areas where construction activity
af hiShr?W ?Jnn W^? located in the floodplain.  Low flow TSS    Y
as high as 1600 mg/1 were  observed at P-30.

Storm Events
aSneA             hydrolo*i<»l. Physical, and chemical
aspects of 43 distinct runoff events resulted from 17 selected
one fS L^ri? d^Wlth streamflow being sampled simultaneously at
v2rsi?v ?rL^ £he '!l°nitorin? stations established by Rice Uni-
versity (refer to Site Description, Section 4).  The number of
                               31

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runoff events monitored at each sampling site were as follows

          Sampling Site              Number of Runoff Events
            P-30
            P-10
            Lake' A
            Lake B
            Hunting Bayou
            Westbury Square
12
 8
 8
 8
 5
 2
Hydrological Observations—
     A summary of the hydrological data is presented in Table 5.
Hydrological parameters are specifically defined in Table 6.
Note that Total Streamflow is the sum of Baseflow and Runoff.
The number of storm events monitored was limited by two drought
periods, each of six month duration during the project.

Rainwater Quality—
     Previous investigations indicate air pollution may contri-
bute to surface water pollution through rainfall and/or dry fall-
out, even to the extent of pollutants traveling via air from in-
dustrial and agricultural regions to be deposited in undeveloped
areas  (37, 38).  Samples collected in the Houston area and at
The Woodlands assessed relative contributions of rainwater qual-
ity to stream pollution.  Results presented in Table 7 indicate
a substantial nutrient and COD content in rainwater at both sites.
A statistically significant increase exists between Houston and
The Woodlands rainwater in regard to NH3 and NO3 content.  The
rainwater data are compared to stormwater data in Table 8.  A
study of air quality at The Woodlands indicated high levels of
hydrocarbons, 7.6 ppm non-methane hydrocarbons, whose source was
attributable to vegetative emissions.  These ambient air hydro-
carbons may contribute to the soluble COD in rainwater.  The study
also found an absence of NOX at The Woodlands in contrast to
serious NOX air pollution problems in the Houston urban area (39).


     At The Woodlands, rainwater nutrient concentrations were
greater than runoff water, while the opposite relationship pre-
valied  in the urban watershed.  Experiments were conducted to
determine the capacity of soils for stormwater nutrient removal.
Four samples of soil from various locations  in The Woodlands
 (see below) were dried and weighed.  The samples were extracted
with demineralized water until no further NH3 was measured in the
extract, and then equilibrated with 30 ml portions of 1 mg N/l
 (ammonium sulfate).  After centrifugation, the supernatant was
analyzed for NH3 and then discarded.  This was repeated until no
further adsorption was measured.  Findings indicate  low levels
of  NH3  are definitely adsorbed by soils, with the greatest
                                33

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               HYDROLOGICAL DEFINITIONS AND CALCULATIONS
Storm Event:
Total Rainfall;
Duration of
      Rainfall;

Rainfall Intensity;

Type of Storm
          Event:
Antecedent
   Rainfall
       Condition;

Total Discharge
          or  Flow;

Runoff;
 Peak Flow;
 Base Flow or
  Groundwater Flow;
 Time of Passage
Discrete period of rainfall producing
runoff monitored during the study.

Calculated via Thiessen method using total
precipitation data recorded over 2 separate
drainage areas, P-10 and P-30.  The co-
efficients are calculated using these rain
gauges: Porous Pavement, Egypt, Confluence
and W. G. Jones.
                       P-30 Drainage Area
                        Porous P. - .125
                        Confluence- .328
                        Jones     - .075
                        Egypt     - .472
                       p—10 Drainage Area
                        Confluence- .258
                        Jones     - .100
                        Egypt     - .642
 Time of
   Concentrat ion;
Shortest time period during which 85% of
total precipitation occurred.

Total rainfall divided by duration.

Described  type of rainfall - e.g. one
period  of  rainfall, 2 periods of rainfall,
etc.
Total precipitation in 1 week period prior
to storm event.   Calculate same way as
Total Rainfall  (see above).

Volume  of  storm  event hydrograph.
                                          4-
Overland  flow volume.  Equal to total dis-
 charge  minus base flow.

Maximum stream discharge.
 Calculated by multiplying the  instantaneous
 discharge prior  to the storm event by the
 time of passage.
 Time from first rise in stream to 0.1 of
 the peak flow.   If the hydrograph does  not
 return to this level due to  successive
 rainfall a hydrograph separation technique
 is used to extend the recession limb to 0.1
 of the peak.  When runoff is minimal and
 base flow greater than 0.1 of peak flow,
 then the inflection point on the hydrograph
 tail is assumed the end of passage.

 Time from first rise in stream to peak
 flow.
                                36

-------

































4J
j;
(1)
r
4!
•r
X
W
c

r

































3

^

(D
,_j
42
p

o
to







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o
cu
o
.d

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o
•a
















*4*
tti
3










fl)
jJJ
CO








01






1 X


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t*



fi




01







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c





01





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rH









Q> O
VO CM


t^
r» o
• •
co r-




rH . TJ<
« to •
rj< .in
rH S H

CM Q\
in «H



^j. VO
rH UTi
0 0



CM • a\
rH CO CO
o • o
53

rH O
rH CM
rH



vo r-
in rH
i •
0 0
in
o

CM " rH
in v co
• *
C3 O-i ^^


in en
00 rH



CM er»
rH O

^3 *5j* CD
m
o
*
rH CM
CO v CM

' o a o
CO
01
CM tJ
ss. g
O "8
01 - t3
3 0
O 0
(U
o
c -o
a) d
. • O «J
01 m -H
3) r^ iw H
rH \ iH IS
CUCM C O
grH &> -H
ta\ -H 01
01 CO 01 O
rH
l| | ^ t| | Q
O "I O -H
M\VO H m
O co r*^ c) 0)
g ^s.0 Q) -4-*
3 r* CM rH
G \ O
••CM in -P
II in »o
r- in • w
C\r^ C
rH\ 11 O
*r-t 0\ -H
c \rH cm -p
O r*» "v.  >«o o a
i2 jj
01 'O nJ X<
TJ H C g -P
^ 0) T« -H -H
flj >rH X >
•O *H n3 O
C fi O ^ 01
 <8 
rH

^
•
•
52
*
02
IM
m
H
rH
O
•d
o
0
5
Q)
rH
en
fi
w
v
d
c
H
»,
H
rH
 W C O
rH 01 01  rH rH 4J O C -H
04 04* COO
C! g g -P CQ
n^ RJ (0 -P II CP
fl) 01 01 C C 43
g 
-------
     TABLE 8.   COMPARISON OF RAINWATER AND RUNOFF QUALITY
                IN HOUSTON AND AT THE WOODLANDS
                (ALL UNITS lN..mg/l)	
Constituent
soluble COD
NH3
•N03
ortho P
Houston
Rain
14
.31
.52
.01
Runoff1
20
2.1
.38
.57
The Woodlands
Rain
15
.22
.31
.04
Runoff
44
.08
.05
.005
1 Avg. of stormwater data collected at Hunting Bayou

2 Avg. of stonrtwater data collected at p-10



adsorption occurring in undisturbed forest soil:

          Soil Sample          Total mg N/g Adsorbed
          Golf Course
          Roadside
          Swale
          Woods
0.027
0.022
0.017
0.043
           1 mg N/g dry soil adsorbed in equilibrium with
             1 mg N/l solution of ammonium sulfate.

     The data suggest that ammonia nitrogen in rainwater is ad-
sorbed to a large extent in undisturbed forest soils where it is
metabolized by plants or nitrified and possibly denitrified by
soil microorganisms.  In an urban area receiving the same am-
monia rainwater load, there is more impervious area resulting in
higher ammonia in the runoff.  In addition, soils in an urban
area have a lower NH3 adsorption capacity and lower NH3 utilization
rate.

     Of greatest significance is the effect of nutrient wash off
on lake eutrophication at The Woodlands.  Ward and King  (40)
have shown nitrogen  to be the limiting nutrient for algal growth
in The Woodlands lakes during wet weather.  As development con-
tinues, increasing nitrogen input from stormwater runoff can be
expected and lake enrichment may result.
                                38

-------
 Groundwater Quality—
      Surface water quality at The Woodlands is influenced by in-
 filtration from the perched water table.  To determine ground-
 water quality, samples were collected from 17 wells located with-
 in the watershed 3 days after a 2.8 in.  (7.1 cm) rainfall.  The
 wells consist of 2 in. (5 cm) I.D. PVC pipe driven 2 to 5 ft,(0.6
  to  1.5 m) into the soil.  Results presented in Table  9  indi-
 cate The Woodlands groundwater contains greater amounts of
 nutrients but less organic material than runoff.  Low pH values
 are consistent with the naturally acid soil due to the presence
 of humic and tannic components,  high clay and low carbonate con-
 tent.
        TABLE  "9.   COMPARISON OF GROUNDWATER QUALITY AFTER
       	RAINFALL TO RUNOFF WATER QUALITY
                               Gr oundw a t er'
      Constituent
                  Runoff
TKN
NHg
TP
Ortho P
pH
2.1
1.4
0.09
0.02
5.1
1.37
0.08
0.06
0.003
5.9
       Specific
        Conductance
       Total COD

       SOC
200

 22

 10
110

 59

 22
 I       m                                        	     ^"•"™™-^""*™™
   Data in mg/1 except specific conductance as micromhos/cm and
   pH in pH units.
 2
   Mean concentrations of samples collected within 3 days of
   2.8 inch rainfall on April 14, 1975.

   Mean concentrations for runoff samples collected at P-10
   during April 8, 1975 storm event.


Stormwater Runoff Quality—
     Discrete water samples were collected for the purpose of
      n   *1"*0*?1 stormwater quality during a storm.  Over 850
           samples were collected and over 12,000 separate water
quality analyses were performed.  A summary of the water qualify
f^\i%PreSented ** Table 10' inclu<3ing mass load and flow
weighted mean concentrations for each parameter.  Mean concen-
trations are calculated from discrete sample results weighted

                               39

-------
according to instantaneous stream discharge at the time of col-
lection.  Mass load represents total amount of constituent pass-
ing the monitoring site during the runoff event.  Mass load is
incalculable where no discharge occurred, as with lake storage
of stormwater.

     All water quality samples collected are representative of
the total streamflow volume  (including baseflow) which is re-
ported in Table 10.  In the majority of events, overland runoff
is approximately equal to total streamflow and samples can be
considered representative of runoff.  For storm events producing
low runoff, water quality is influenced by bassflow.

Chlorinated Hydrocarbons

     During the two-and-one-half-year study some 2500 biotic and
abiotic samples were collected in The Woodlands and analyzed for
halogenated hydrocarbon compounds.  The major sampling emphasis
was directed toward surface waters and aquatic fauna, however
soil-sediment and plant samples were also analyzed.

Polychlorinated Biphenyls—
     The major class of chlorinated compounds detected during the
study was the polychlorinated biphenyls  (PCBs ) .  These formula-
tions are used in a variety of industrial applications such as
varnishes, paints, inks, waxes, flooring tile, synthetic rubber
and asphalt; however, greatest usage is in the electronics indus-
try in the production of capacitors and transformers.  PCBs have
been produced for over 40 years but only recently have they been
observed as a pollutant in the environment.

     The temporal distribution of PCBs in The Woodlands surface
waters and soils is presented in Figure 9.  In January 1974 a
sudden increase in PCB concentrations in soils was observed which
was followed by a rise in surface water concentrations some four
months later.  The rates of decline of both of these peak concen-
trations resemble a first order curve.  No further increase in
PCBs in water was observed throughout the remainder of the study.
By extracting larger amounts of soil and concentrating the com-
pounds on activated charcoal followed by elution and subsequent
analysis, a second minor peak, three orders of magnitude lower,
was observed in soil samples during the spring of 1975.  Several
plant samples were found to contain trace amounts of PCBs, but
the minute amounts could have been due to surfcice contamination
since they coincided with the highest values observed in water
and soil samples.  The level of PCBs in aquatic: animal samples
started rising in late 1973 and reached a peak in April of 1974
(Figure 10), which is coincident with the highest concentrations
in the water samples (Figure 9).  The concentration in the
aquatic organisms is about 10 times that in the; water samples
but 1/10 that observed in the soil samples (Figure 9).
                               40

-------
TABLE 10.  RUNOFF WATER QUALITY SUMMARY—
            MASS FLOW AND WEIGHTED AVERAGE
Storm
»
I
2
3
4
5
6
7

S


9



10



11

Date
01/18/74
03/20/74
03/26/74
04/11/74
04/22/74
10/28/74
12/05/74

03/04/75


03/13/75



04/08/75



05/08/75

Site
The Woodlands P-30
Hunting Bayou
Hunting Bayou
Hunting Bayou
The Woodlands P-30
The Woodlands P-30
The Woodlands P-30
The Woodlands P-10
The Woodlands P-30
Lake A
Lake B
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
Hunting Bayou
Westbury
Streamflow
acre— feet
2334
2.51
42.1
12.4
5.80
937.
1267
833.
3.32
Stored
.135
119.
79.1
2.38
1.77
2829
1614
93.4
93.2
28.9
7.16
Ortho-PO4
x cone
Ib mg/1
7.73 .001
2.96 .437
45.1 .395
16.9 .503
0.70 .044
43.0 .017
33.7 .010
14.1 .006
0.23 .025
MA .008
.012 .033
3.15 .010
1.15 .005
.043 .006
.102 .021
85.2 .011
15.0 .003
3.75 .015
1.25 .005
40.4 .516
13.8 .710
TP
x cone
Ib mg/1
No Data
No Data
46.4 .407
30.3 .899
7.53 .478
256. .101
328. .096
171. .076
1.14 .127
NA .097
.077 .210
52.3 .162
19.7 .092
.893 .137
2.54 .530
675. .088
264. .060
26.2 .103
27.9 .110
84.2 1.08
14.2 .730
NH3
x cone
Ib mg/1
215. .034
16.5 2.44
287. 2.51
24.6 .732
5.27 .334
236. .093
355. .103
199. .088
.880 .100
NA .062
.238 .650
22.2 .069
19.2 .089
.760 .117
1.06 .221
1144 .149
339. ,077
39.6 .156
28.1 .110
94.4* 1.20
17.3 .890
        NA - Not applicable - a mass loading was not calculable.
     Stored - No discharge of atormwater from the lake system.

      Notes  ac-ft = .123 ha-m

              Ib =  .4536  kg                  (continued)
                         41

-------
TABLE 10  (continued)
N02
x cone
Ib mg/J
5.30 .001
.353 .052
7.42 .065
2.18 .065
.170 .011
12.5 .005
18.5 .005
.280 .000
.055 .006
MA .008
.016 .04*
1.08 .003
.750 .003
.065 .010
.113 .024
73.1 .009
27.1 .004
8.24 .032
2.18 .009
4.52 .058
.754 .039
N03
x cone
Ib rag/1
181. .029
2.96 .438
58.1 .509
11.4 .338
3.71 .235
94.2 .037
79.9 .023
27.6 .012.
.960 .107
NA .189
.131 .357
35.9 .111 -
22.1 .103
1.32 .203
1.74 .362
1181 .154
284. .065
70.4 .280
37.6 .150
40.1 .511
7.20 .371
TKM
Ib x cone
xlo mg/1
Ho Data
No Data
40.1 3.52
5.25 1.56
2.11 1.34
Ho Data
311. .905
187. .826
1.50 1.66
NA .829
.066 1.79
35.1 1.09
34.5 1.61
.401 .620
1.99 4.14
1065 1.39
600. 1.37
33.3 1.31
.47.1 1.86
25.5 3.25*
4.25 2.19
TSS
Ib x cone
xlO3 mg/1
1492 236.
.480 70.9
22.5 197.
4.10 122.
14.8 939.
775. 305.
296. 86.2
60.5 26.8
.426 47.0
NA 166.
.104 283.
28.8 90.0
14.4 67.0
.991 152.
13.8 2877
1312 171.
168. 38.5
61.9 245.
322. 1273
16.2 207.
.474 24.4
soc
Ib , x cone
xlO2 mg/1
No Data
2.59 38.3
18.5 16.3
18.6 55.3
2.74 17.4
455. 17.9
No Data
No Data
.802 9.00
NA 14.0
.027 7.35
69.8 21.6
48.2 22.5
.900 13.8
.705 14.7
1563 20.4
962. 22.0
34.4 13.6
40.8 16.2
13.7 17.5
3.13 16.1
Total_COD
Ib - x cone
xlO2 mg/1
No Data
5.18 76.6
114. 99.8
34.3 102.
14.7 93.1
No Data
1962 57.1
1400 62.0
3.02 33.4
NA 47.0
.181 49.2
192. 59.3
136. 63.4
2.47 38.0
5.90 123.
4037 52.6
2572 58.8
106. 41.8
161. 63.7
140.. 179.
10.4 53.8
Soluble COD
Ib , x cone
xlO1* mg/1
No Data
No Data
No Data
10.8 32.0
8.53 54.2
859. 33.8
1405 40.9
988. 43.7
2.88 32.0
NA 32.5
.120 32.6
143. 44.2
111. 51. 9
1.87 28.8
1.37 28.5
2981 38.8
1888 43.1
66.8 26.4
82.0 32.0
27.5 35.1
6.09 31.4
                                                (continued)
                             42

-------
TABLE 10  (continued)
Storra
1
12

13



14



15



16



17



Date
06/30/75

09/05/75



10/25/75



03/07/76



03/08/76



04/04/76



Site
Hunting Bayou
Westbury
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
The Woodlands P-30
The Woodlands P-10
Lake A
Lake B
Streamf low
acre— feet
116.
11.2
9.82
.918
Stored
1.51
117.
57.1
18.9
No Data
14.9
11.2
Stored
.884
99.3
58.3
6.78
2.71
45.9
2.83
14.5
5.10
Ortho^PO^
x cone
Ib mg/1
212. .677
17.1 .560
1.67 .063
.051 .021
NA .011
.148 .035
12.0 .038
.342 .002
.068 .001
NA .027
1.18 .029
.039 .003
NA .005
.124 .052
7.92 .029
.217 .001
.131 .007
^.088 .012
5.38 .043
.027 .003
.148 .004
.077 .006
TP
,. x cane
Ib mg/1
403. 1.28
34.6 1.14
4.75 .180
.082 .033
NA . 050
.608 .148
46.7 .147
7.32 .047
1.35 .026
NA .081
No Data
No Data
No Data
No Data
No Data
No Data
No Data
No Data
18.7 .149
.468 .061
2.49 .063
1.07 .078
NH^
x cone
Ib mg/1
660. 2.10
4.40 .145
5.36 .201
.075 .030
NA .069
.567 .138
26.1 .082
8.34 .054
2.27 .044
NA . 108
2.58 .064
1.67 .055
NA .063
.089 .037
46.8 .174
3.61 .023
.723 .039
.247 .034
48.9 .390
1.21 .158
4.79 .121
1.66 .120
                    NA - Not applicable - a mass loading was not calculable.
                 Stored - No Discharge of stormwater from the lake system.

                 Note:  ac-f t = .123 ha-m
                          Ib = .4536  kg
(cont inued)
                                      43

-------
TABLE LO (continued)
N02
x cone
Ib mg/1
14.0 .044
.803 .026
.480 .018
.007 .002
NA .009
.047 .012
1.56 .005
.690 .005
.143 .003
NA .010
.593 .015
.321 .010
NA .011
.035 .014
3.70 .014
1.66 .011
.225 .012
.328 .045
2.13 .017
.052 .007
.205 .005
.163 .012
N03
x cone
Ib rag/1
117. .373
11.8 .388
8.13 .305
.075 .030
NA .009
.955 .233
47.0 .147
4.67 .030
1.19 .023
NA .113
10.2 .252
1.43 .047
NA .076
.393 .164
48.0 .178
3.69 .023
1.64 .089
1.31 .141
52.9 .420
1.04 .135
4.53 .112
4.92 .355
TKN
Ibs x cone
xlO mg/1
124. 3.94
4.51 1.48
1.16 .435
.024 .097
NA .172
.168 .410
9.69 .305
4.04 .261
.942 .184
NA .280
No Data
No Data
No Data
No Data
No Data
No Data
No Data ,
No Data
25.5 2.04
.516 .672
2.90 .735
1.29 .929
TSS
Ib x cone
xlO3 jag/1
51.0 182.
2,13 69.8
2.67 100.
.016 6.54
NA 24.0
6.70 1633
53.8 169.
1.18 7.60
1.85 36.2
NA 421.
9.55 237.
6.47 212.
NA 184.
1.77 738.
78.1 290.
20.6 130.
3.27 177.
3.07 419.
No Data
No Data
Mo Data
No Data
SOC
Ib , x cone
xlO^ mg/1
71.6 22.8
5.09 16.7
No Data
No Data
No Data
No Data
66.0 20.7
37.8 24.4
2.38 4.66
NA 20.6
5.55 13.7
6.72 22.0
NA 8.00
.322 13.4
42.4 16.0
41.4 26.0
t.ll 6.05
.962 13.1
18.5 14.8
1.27 16.5
3.98 10.1
•1.94 13.3
Total_COD
Ib _ x cone
xlO^ mg/1
252. 80.4
11.8 38.9
No Data
No Data
No Data
No Data
135. 42.4
70.0 45.1
10.9 21.2
NA 48.9
No Data
No Data
No Data
No Data
No Data
No Data
No Data
No Data
61.7 49.3
3.08 40.0
7.88 20.0
6.00 43.3
Soluble COD
Ib x cone
xlO2 mg/1
61.2 19.5
4.36 14.3
9.40 35.2
.852 34.5
NA 19.5
.878 21.4
77.0 24.2
58.9 38.0
7.21 14.1
NA 24.2
12.2 30.2
14.2 46.6
NA 15.4
.631 26.3
88.3 32.8
86.6 54.7
2.73 14.8
1.78 24.3
43.3 34.6
2.97 38.7
9.20 23.3
5.15 37.2
                                                  (continued)
                              44

-------
TABLE 10  (continued)
Storn
1 Date
1
2
3
4
5
6
7
8


9


10


11
12
13


14


15


16


17



01/18/74
03/20/74
03/26/74
04/11/74
04/22/74
10/28/74
12/05/74
03/04/75


09/13/75


04/08/75


05/08/75
06/30/75
09/05/75


10/25/75


03/07/76


03/08/76


04/04/76



Site
The Woodlands P-30
Hunting Bayou
Hunting Bayou
Hunting Bayou
The Woodlands P-30
The Woodlands P-30
The Woodlands P-30
P-10
The Woodlands P-30
Lake A
Lake B
The Woodlands P-30
P-10
Lake A
Lake B
The Woodlands P-30
P-10
Lake A
Lake B
Hunting Bayou
westbury Square
Hunting Bayou •
Westbury Square
The Woodlands P-30
P-10
Lake A
Lake B
The Woodlands P-30
P-10
Lake A
Lake B
The Woodlands P-30
P-10
Lake A
Lake D
The Woodlands P-30
P-10
Lake. A
Lake B
The Woodlands P-30
P-10
Lake A
Lake B
Turbidity pH
150
135
100
305
250
65
20
35
121
184
50
30
105
1200
130
28
165
330
110
18
140
14
100
7
19
830
120
12
24
325
74
12

137
138
S
-
120
70
7
53
110
6.5

6.5
6.5
5.7
6.0
5.2
7.5
7.5
8.1
6.6
6.1
7.5
7.8
6.8
5.9
7.54
6.9
7.6
7.3
7.2
7.3
7.05
6.6
8.01
7.6
7.4
5.8
8.1
7.4
_
_
-
_
_
7.3
6.9
7.9
7.2
Temp.
14.7
20
15
22
22

14
16

13.5
13.3
17
11.5
19
20
20
24
27

_
_
18.5
18
22
19
_
_
-
_
—
-
_
_
-
Spec.
Cond.

-
545
200
110
58
56
375
115
415
280
290
160
185
103
110
140
80
460
175
360
125
208
280
336
135
275
247
536
167
281
410

155
365
410
115
318
284
363
125
Total
DO Solids
9
2.5
4.6
2.25
3.5

8.3
7.8
7 6
6.4
7.2
7.7
7.4
7.8
6
7.65
7.1
3.2
3.34
3.3
4.6
_
_
7.5
6.6
8.2
7.6


-
_
_
-

_
-

-
-
450
• 385
110
_

~
^ .
_
-
_
_
-
-
-
_
_
-
_
—
-


-

_
-


_
BOD

17
22
6.1
-
_


_
_
-
_
_
-
-
-


-
—
—
-


-


'-


_
 All measurements in rog/1 except:
                                 Turbidity  in JTU; pH in pH  units, Temperature in
                                   Centigrade and Specific Conductance In micromh,
                                                                         .cromhos/cm.
                                      45

-------
                                    GO  O
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    m  The source of the PCBs in The Woodlands is not known.  It is
 of interest that the peak of PCBs in all components of the eco-
 system appeared during a period- of intense ct.t and fill opera-
 tions as well as utility installations.  An abandoned land fill
 with disposed capacitors or other electronic materials could have
 affected the increase in concentration as could the use of road
 oil contaminated with PCBs.  Neither of these possibilities were
 verified by observation.

 Chlorinated Hydrocarbon Pesticides—
      In the first year of investigation trace levels of DDE were
 observed in samples of crayfish,  mosquito and bluegills obtained
 from  The Woodlands aquatic ecosystem.  After completion of The
 Woodlands Golf course, the surface waters and soils in ponds and
 adjacent ditches were examined for halogenatei compounds.

      In the spring of 1975 Mirex,  a chlorinated camphene,  was
 detected in water,  soil and some  aquatic organisms  (Figure 11).
 The highest values were found  in  mosquitofish and  the lowest in
 water samples  with the residues in soil being intermediate be-
 tween the fish and water,   if  there was any biological amplifi-
 cation _ in the  fish from this aquatic system it was  limited to
 approximately*a four-fold  increase (Figure  11).

      Water  from the Conference Center Lakes  (A and  B)  was  used
 for irrigation of portions  of  the  golf  course,   since these man-
 made  impoundments were the  potential  recipients  of  both irriga-
 tion  and stormwater runoff,  the lake  water  sediments  and the
 mosquito fish  were  examined for Mirex.   The  results are shown in
 Figure 12.   The highest  level  of pesticide was  observed in raid-
 to  late summer (1975)  and thereafter  concentration  in all  these
 components  of  the pond ecosystem diminished  rapidly with the  soil
 residues  showing the  slowest rate  of  decline.  Mirex  concentra-
 tion  in Lake Harrison was at least one  order  of magnitude  lower
 than  concentrations observed on The Woodlands Golf  Course.  The
 lower  concentration due  to  lake water dilutior. by groundwater
 pumpage,  runoff and treated  wastewater.

     During  August  of 1974  chlordane  was also detected  in  the
 golf  course  study.  Residues were  found  in soil, water  and  aqua-
 tic organisms  (Figure 13).   The highest  levels of chlordane were
 found  in  the crayfish from golf course ponds.  Somewhat less was
 observed  in  the  same  organisms  from ditches adjacent to the
 course.   Similar, although not as pronounced, results were  ob-
 served in the  concentration  of  chlordane in the waters from the
 same areas  (Figure 13).

Bacteriological Enumerations

Surface Water Characteristics—
     Bacterial counts during dry weather were determined in
                               48

-------
         60
         50
         40
MiREX
 (PPB)
30
         20
          10-
          0
                                        o
             ASONDJ FMAMJJASOND
               1974          1975
        Figure 11.
        Temporal distribution of Mirex in
        The Woodlands gold course.
        •-• mosquitofish  (Gambusia sp.);
        O-O soil; o-o water.
                      49

-------
          40 -
          30
Ml REX
  (PPB)
           10
                 n n
              ASONDJFMAMJJ A~S 0 N D
                  1974                1975
          Figure 12.
Temporal distribution of Mirex in the
Conference Center Lakes (A&B).
d-D soils;  •-• mosquitofish  (Gambusia sp.)/
o-o water.
                            50

-------
            40 -
            30 h

CHLORDANE
    (PPB)
            20
            10 -
  Figure 13 .
  ASONDJ FMAMJ JASOND

     1974                1975


Temporal distribution of chlordane in The Woodlands
gold  course   A-A crayfish  (Carribarus sp.)from pond^
A-A crayfish (Cambarus sp.) from ditch? o-o pond
water; .-. ditch water;    mosouitofish (Gambusia sp  )
from  pond; a-O soil from pond.          —       sp';
                            51

-------
Panther Branch.  Indicator bacteria numbers varied widely as
indicated below:
          Total Coliform  (TC)
          Fecal Coliform  (FC)
          Fecal Streptococci  (FS)
          pseudomonas aeruginosa  (PS)
          Staphvlococcus  sp.  (ST)
          Salmonella sp_.  (SA)
                     Range (number/I00 ml)

                      200-10,000,000
                       10-214,000
                       10-1,580
                       10-53,600
                        1-23,400
                        1-5,800
The maximum values are comparatively high for a rural, forested
area receiving no direct sewage discharges.

     Storm events monitored for water quality were also monitored
for microbiological content.  The range and mean bacterial counts
observed during each storm event at The Woodlands are presented
in Table 12.  All bacterial counts are reported as logarithms to
base 10.  Substantial numbers of bacteria were observed in The
Woodlands storm runoff, including runoff from the undeveloped
watershed, site P-10.  pathogenic species were identified at all
Woodlands monitoring sites in relatively high numbers.  For ex-
ample,  Salmonella sp_.were identified at a mean count of 77/100 ml
for storm event #10 at site P-10.  In the majority of events the
maximum bacterial count occurred before or  coincidental to the
hydrograph crest.

     A  summary of the three storm events monitored at Westbury
Square  is presented in Table  11 (the storm  event of 11/75 was
not monitored for water quality).
      TABLE 1.1.   SUMMARY OF WESTBURY RUNOFF BACTERIAL QUALITY
     Storm
     5/75
     6/75
     (n=12
TC
FC
FS
PS
ST
SA
TC
FC
FS
PS
ST
SA
             log No./lOO ml
        Min.       Max.
8.70
4.60
4.61
4.40
4.30
                                               Mean
7.48
4.34
4.12
3.88
3.91
                                                    (continued)
                                 52

-------
TABLE  11  ("continued-!
                                log No./lOO ml
Storm
11/75
(n=5)




1

TC
FC
FS
PS
ST
SA
Number of
Min.
6.26
3.96
4.39
4.31
TNTC
2.00
Samples
Max.
6.67
4.50
4.68
TNTC2
TNTC
4.17
Mean
6.49
4.28
4.51
4.54

3.19
2
Too Numerous to Count
      Stormwater bacterial counts at Westbury were aen«*r*Ti
 greater than or equal to counts observed  at^hJ WoolKSs
 sample variations were common for P
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       TABLE 13.  SUMMARY OF PANTHER BEANCH AQUATIC ALGAE
    Division
     Number of Species
Identified in Panther Branch
Chlorophyta
Cyanophyta
Chrysophyta
Euglenophyta
Pyrrophyta
92 a
15
16
1
1
43
8
12
15
1
                                        79 Total number
    a number of taxonomic species/division

     Standing crops of algae at site P-10 and P-30 are presented
in Figures 14 and 15, respectively.  On a seasonal basis, algal
cell numbers fluctuated more at site p-30 than at p-10.  The
algal standing crops at both sites were dominated primarily by
members of the euglenoids (Euglenophyta), and green algae
(Chlorophyta) were minor components of the total algal popula-
tions.  Numbers of blue-green algae (Cyanophyta) were compara-
tively low at both sites, even though they were more numerous at
site P-30.  A survey of various collection sites along Panther
Branch (May, 1974) also indicated that standing crops in this
stream were dominated by euglenoids and/or diatoms (Chrysophyta),
while numbers of green algae and blue-green algae were compara-
tively low.  Dominance of this type is indicative of slightly,
acid streams with high organic carbon content.

Soil Algae—
     Fifty-two genera of algae were identified in soils collected
from disturbed and undisturbed sites in The Woodlands  (see Table
14).  Undisturbed soils had larger algal species diversities and
fewer algal numbers than disturbed soils.  Green algae (Chloro-
phyta) genera were most numerous in soils from the forest, while
disturbance of soils favored the development of a more diverse
blue-green  (Cyanophyta) flora and inhibited green algae diver-
sity.

     The change in algae characteristics is probably a result of
increases in soil pH and nutrient content which accompanied soil
disturbance and fertilization.  Undisturbed soils had the lowest
pH  (6.1), compared to high pH values of 6.7 to 7.8 in disturbed
soils.  The results confirm floristic surveys in other regions
of the United States which show that alkaline soils favor the
development of more luxuriant blue-green algal flora than do
acid soils  (41, 42, 43).  Higher algal numbers in disturbed soils
corresponded to the greater concentrations of nitrogen and phos-
                               60

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               CHLOROPHYTA
               CYANOPHYTA
               CHRYSOPHYTA
               EUGLENOPHYTA
               TOTAL
      NDJFMAMJJASO
                  MONTHS
Figure  14. ^Seasonal  algal  standing crops at P-10
            in Panther  Branch.
                      61

-------
           I   I   I  I   I   I  I   I   I   I  I   I

                  	Chiorophyta
                  —— Cyanophyta
                  —x— Chrysophyta
                  	Euglenophyta

           NOJFMAMJJASO

                     TIME  (mo)
Figure  15. Seasonal algal  standing crops at
            P-30  in panther Branch.
                      62

-------
phorus found in these soils.  The increase in soil nutrient con-
centration is due primarily to fertilization.


      TABLE  14.  SUMMARY OF EDAPHIC ALGAE IN THE WOODLAEIDS	
                   Undisturbed
Disturbed Soils
Division Forest Soil Golf Course Lawn
Chlorophyta
Cyanophyta

Chrysophyta

Euglenophyta
Total

27a
3853b

586
{' 11
1297
3
46
5736
7
39629
4
1446
4
13084
1
16
54159
4
17400
4
7195
3
12790
— —
11
37385

a numbers of
determined)
b , -
genera identified
(species
were not
     Since terrestrial and aquatic ecosystems are connected
hydrologically, they cannot be considered as totally disjuncted
units.  Surface drainage serves as a major component in this
hydrologic linkage and is thus an important ecological parameter.
Land usage in a watershed can determine the quality, as well as
the quantity, of surface runoff, thus  influencing aquatic
habitats  in the watershed.  In addition to providing potential
nutrients for algal growth, surface drainage probably transports
algal cells to aquatic habitats from surrounding soils.  Since
land use  affects edaphic algal populations, it must also influ-
ence the  diversity of algae which could be transported by  sur-
face runoff.  For example, a more diverse assemblage of blue-
green algae could potentially enter lakes in the study area by
surface drainage from disturbed, rather than undisturbed,•
soils.

 Stormwater Comparison with Sewage

   Table  15  compares  stormwater  runoff  and  sanitary  wastewater  qual-
 ity.   Stormwater  constituents  are  lower  than  raw  sewage  with  the
 exception of  suspended  solids  in  runoff  from  Hunting  Bayou and The

                                63

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64

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 Woodlands developing areas.   Advanced wastewater treatment yields
 lower GODandTSS values than stormwater, however nutrients remain
 higher.  AS a result, sophisticated nutrient removal processes
 would be necessary to achieve low concentrations observed in
 stormwater runoff.

     Ten samples of untreated and chlorinated secondary waste-
 water effluent were obtained from two large, well-operated
 sewage plants in Houston for bacteriological examination.  The
 data obtained is compared to the bacteriological quality of
 stormwater runoff in Table 16.   Bacterial numbers were lowest in
 chlorinated effluent, higher in runoff and highest in untreated
 wastewater.  Urban runoff contained higher numbers than forest
 runoff.

 OBSERVED TEMPORAL AND SPATIAL VARIATIONS IN STORMWATER RUNOFF
 QUALITY

 Pollutograph Analysis

      A pollutograph is defined  as a plot of pollutant concentra-
 tion versus time.   In this sub-section it is plotted for storm-
 f!6w quality.   Temporal changes of water quality during runoff
 events are important to the  understanding of the impact of these
 non-point sources on stream  quality.   The time-concentration  rela-
 tionship _ is also critical in consideration of stormwater treatment
 alternatives.   Pollutographs observed during the study exhibited
 the  five generalized patterns shown in Figure 16.   These concentra-
 tion patterns  were common to all watersheds,  although levels  of a
 particular parameter were site  dependent.

     Specific conductance  of  groundwater  which feeds  streamflow
 is high due  to dissolved  minerals  and  as  a  result  stormwater  in-
 flow decreases stream conductance  similar  to  the second  polluto-
 graph  shown  in Figure 16.2.   This  dilution  pattern applies to
 other  streamwater  constituents,  including7 some found  in  waste-
water  effluents, which  are concentrated  in  dry-weather  flow.   The
 concentrations of  SOC,  soluble COD  and total  COD often  increased
as runoff progressed, with highest  concentrations observed at  the
end  of  the runoff  (Figure 16.4).   Streamflow  contributions from
interstitial and bank storage flow  is greatest late in runoff
and  could account  for the pattern  if enriched by contact with
soils serving as an organic  carbon  source.  DO concentrations
in stormwater increased proportional to  flow  and assumed a
hydrograph-shaped pollutograph  (Figure 16.5).  Increased re-
aeration at greater streamflows accounts for  this phenomena.
Several parameters observed at site p-10 remained at a constant
level throughout the hydrograph, including pH, NHo, NO, and
soluble COD  (Figure 16.3).  This pattern was not commonly ob-
served at the other watersheds where land use is diversified.
                                65

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                          DILUTION
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                          HYDROGRAPH
               TJME INTO  STORM   EVENT


Figure 16.  Generalized  pollutographs observed

            for storntwater  parameters.
                      67

-------
     The "first flush" pollutograph pattern is characterized by
an abrupt rise in concentration early in the runoff event.  At
Hunting Bayou, the "first flush" was observed for the greatest
number of runoff constituents including TSS, turbidity, ortho P,
TKN, TP, NH3, NO2 and N03.  The Hunting Bayou watershed has a frac-
tion of impervious surface area and includes a diverse land use
mix including industrial and commercial activities.  Turbidity and
TSS parameters exhibited the highest peak values over baseline,
while peak values for other constituents were,less pronounced.

Effect of Land Use on Stormwater Runoff Quality

Pollutant Load-Runoff Relationships—
     Total pollutant loads were plotted against total runoff of
each storm event and regression lines were fitted to correspond
to Hunting Bayou, Westbury, P-10 and P-30 watersheds.  Fitted lines
and associated correlation coefficients are shown in Figures 17-20
for the constituents TSS, total COD, TKN, TP, NC>3, NH3, soluble COD
and SOC.  Correlation coefficients for a majority of the parameters
were greater than r = 0.8 (r = correlation coeff.), however, three
cases showed fair to poor correlation; P-30, NO3 (r =0.775),
Westbury, NH3 (r= 0.397), and Hunting Bayou, SOC (r =0.161).

     N03, NH3, TKN and TP relationships, shown in Figures 17-18,
indicated that the urban watersheds produce nutrient loads greater
than the forested watersheds.  In all cases Hunting Bayou nutrient
loadings are highest, followed in order by Westbury, P-30 and P-10.

     TSS loads are highest in P-30 as a result of construction
activities in the watershed and urban runoff solids loading is
greater than forest runoff  (Figure 19).

    Runoff loads for nonspecific parameters ftota]  COD,.soluble COD
and SOC are shown in Figures 19-20) are higher in forested water-
sheds than urban watersheds, with the exception of high total COD
loads from Hunting Bayou.  The data suggest organic material in
runoff decreases with urbanization, however, insoluble pollutants,
sediments and oils will increase.

     A ranking of the four watersheds, on a Ib/ac/in of runoff
basis, illustrates the relative conditions for each site and pollu-
tant.  Table 17 shows these rankings for mean regression values
at one inch (2.54 cm) of runoff for all parameters and sites.
Confidence intervals (95%)  are included in Table 17 to indicate
significant differences in pollutant loads at one inch (2.54 cm)
runoff.  Confidence limits for Westbury show a particularly large
spread due to the small number (2) of storms monitored for that
watershed.  Significant differences for the total COD, soluble COD
and SOC cases are indicated, with some overlap in the TSS case.
The patterns of nutrient response for the urban developing and
forested watersheds is distinctive, with the urban response pro-
ducing loads up to an order of magnitude larger.  Hunting Bayou
ranks as the producer of the largest pollutant  loads.
                                68

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     TABLE 17.  POLLUTANT LOAD  RANKING OF THE  FOUR STUDY
                AREA WATERSHEDS
                                        RANK
                                   2            3
ss
ECOD
3COD
soc
NO3
NH3
TKN
TP
Area
Upper CL*
1" Value
Lower CL
Area
Upper Cl
1" Value
Lower CL
Area
Upper CL
1" Value
Lower CL
Area
Upper CL
1" Value
Lower CL
Area
Upper CL
1" Value
Lower CL
Area
Upper CL
1" Value
Lower CL
Area
Upper CL
1" Value
Lower CL
Area
Upper CL
1" Value
Lower CL
P30
61.59
43.48
25.36
HB
25.62
18.88
12.14
P10
-10.01
9.86
9.70
P10
5.045
5.00
4.95
WB
0.12
0.088
0.057
HB
0.58
0.48
0.38
HB
1.049
0.95
0.85
HB
0.40
0.28
0.16
HB
42.30
37.73
33.15
P10
14.13
13.50
1-2.87
P30
9.27
8.76
8.25
P30
4.78
4.54
4.30
HB
0.10
0.087
0.072
WB
1.28
0.069
-1.14
WB
1.50
0.40
-0.76
WB
0.90
0.24
-0.43
WB
88.02
13.66
-60.70
P30
12.72
12.09
11.46
HB
6.64
4.44
2.24
WB
4.48
3.75
2.66
P30
0.038
0.020
0.0031
P30
0.037
0.031
0.025
P30
0.36
0.30
0.24
P30
0.028
0.021
0.014
P10
10.16
8.19
6.21
WB
33.13
9.48
-14.17
WB
31.56
4.06
-23.45
HB
2.64
0.70
-1.25
P10
0.020
0.012
0.0051
P10
0 .020
0.018
0 .016
P10
0.38
0.28
0.18
P10
0 .017
0 .014
0 .011
* 95% Confidence Level.  All  confidence
  gression values at 1  inch  (2,. 54 cm)  of
  in Ib/ac.
      P30 = Woodlands   P30 Watershed
      P10 = Woodlands   P10 Watershed
      HB  = Hunting Bayou Watershed
      WB-  = Westbury Watershed
  Note:  inch x 2.54 = cm,  Ib/ac  x  .184  =  kg/ha
levels are for mean re-
 runoff.   All loads are
                                73

-------
      The  load-runoff relations  developed  from several  storm
 events  can be  extended in a  useful  way  to estimate  total  annual
 loads for selected  pollutants.   A measured or predicted annual
 streamflow hydrograph is  required along with  average low-flow
 concentration  values.   During storm events, the  load-runoff re-
 lation  is used to predict the mass  flow,  while during  intermit-
 tent  low  flows, mass flow is estimated  by the product  of  stream-
 flow  and  concentration.

      A  comparison of annual  loads for TSS, TP, NC>3  and total COD
 is  shown  in Table 18 for  the P-10 forested site  and P-30  urbanizing
 site  at The Woodlands.  The  developed load-runoff relations were
 used  to calculate the storm  generated mass flows.   The urbanizing
 watershed appears to be contributing greater  loads  of  TSS on an
 .annual  basis compared to  the forested site.

      The  procedure  allows direct comparison of storm generated
 pollutant loads from non-point  sources  with the  low-flow  contri-
 butions,  which are  primarily of natural background  or  point source
 origin.   Consequently,  non-point loads  can be quantitatively deter-
 mined as  a function of  land  use patterns  as more storm data becomes
 available from other urbanizing watersheds.

      The  annual load calculation can be used  in  conjunction with
 the U.S.  Geological Survey grab sample  method to calculate  annual
 sediment  loads.  Relative accuracy  of the two techniques  remains
 undetermined.

 Effects of Land Development  on  Runoff Quality—
      Storm event #10—Stormwater quality  monitored  at  site  P-10
 represents runoff from  a  forested,  undeveloped watershed  and ac-
 cordingly serves as  a baseline  for  assessing  changes due  to
 urbanization.  The  P-30 sampling site,  located 6.8  miles  (11 km)
 below P-10, monitors runoff  from 5,500  acreas (2250 ha),  in addi-
 tion  to the area monitored by the P-10  site.   The additonal area
 includes  construction activity  of The Woodlands  Developed Corpora-
 tion.  A  comparison  of  these  two sites  during storm event #10
 illustrates the effects of construction activity on runoff  quality.

      Heavy rainfall  over  the  Panther Branch watershed  on April 8,
 1975  produced  large  amounts of  runoff sampled at P-10  and P-30.
 Precipitation  associated  with the storm event began 'shortly after
midnight  on April 8, 1975  and continued till  noon the  same  day.
 The storm featured  3 periods  of intense rainfall at 4:30,  8:30
 and 10:00  A.M. with  interposing pauses  of  drizzle.  The area rain
gages measured 2.00, 2.65, 3.42  and  3.97  in.  (5.08, 6.73,  8.64
and 10.1  cm) of rainfall,  upper  to lower watershed gages,  respec-
tively,  with the Thiessen  adjusted rainfall calculated to be
 2.43  in.  (6.17 cm)  on the  P-10 watershed,  and  2.76 in.  (7.01 cm)
on the P-30 watershed.  Average  rainfall  intensity was 0.76  in/hr
 (1.83 cm/hr) and antecedent soil moisture  conditions were dry with
no rain recorded 7 days prior to  the storm and 2.5 in.  (6.35 cm)
the preceding month.  Watershed  runoff began  after midnight April

 8'                               74

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and ended three days later.  As shown below, the volume of runoff
observed at site P-30 was greater than P-10 but peak discharge
was essentially the same.
Site
P-10
P-30
Streamflow Volume
acre ft. ha-m
1614
2829
(199)
(349)
•Runoff
in. (cm)
1 . 2
1.57
(3.05)
(4)
Peak Plow
cfs (m3/s)
1170
1100
(33.1)
(31.1)
Runoff
Coeff .
50%
57%
The greater runoff volume for P-30, almost twice that of P-10,
was a result of three factors:   (1) larger drainage area,  (2)
heavier rainfall in the lower basin, and  (3) impervious areas in
The Woodlands development.

    Figures 21 and 22 compare P-10 and P-30 pollutographs  for TSS,
total COD, TP and TKN.  Hydrographs are also presented in  the
figures for flow rate and time references.  Pollutograph analysis
should consider the following:

    1.  Those areas of The Woodlands developed or under
        construction encompassed only 10% of the total
        watershed.  The majority of stormwater runoff
        originated in undeveloped  forest  lands.

    2.  Developed or construction  areas were located
        adjacent to P-30, as shown in Figure 23.  As
        a result, runoff originating in these areas was
        observed early in the storm event.

    The pollutographs indicate high TSS loads at P-30  (Figure 21),
a result of sediments washed from  easily  eroded construction sites.
Although the developing area comprised 10% of the watershed, it
contributed as much as 80% of the  TSS load at P-30.  Total COD
 (Figure 21) exhibited a "first flush" at  P-30, probably due to asso-
ciated high TSS.  The major portion  (70%) of the total COD was
soluble.  Significant increases  in TKN and TP at P-30 resulted
from wash-off of ammoniated phosphate and urea based fertilizers
applied to the golf course in the  developing area  (Figure  22).

    Development within the Panther Branch watershed has resulted
in  stormwater runoff quality changes.  TSS and nutrients have in-
creased although no significant  change has been observed for
oxygen demand.  Results for storm  event #10 are summarized in
Table 19.
                                 76

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  Figure  22.   Comparison of  P-10  and P-30 temporal distribution

               of streamflow,  TKN  and TP for the storm event  of

               April 8, 1975.




               1 Ib. =  .4536  kg

               1 ac-ft  =  .123 ha-m

               1 cfs =  .028 m /sec
                               78

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       CONSTRUCTION  AREAS


       PROPERTY   BOUNDARIES
1 mi = 1.6  km

1 ft = .305 km
                        FEET
 Figure  23,
The Woodlands construction  activity in
relation  to the P-10 and  P-30 sampling
sites.
                        79

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    TABLE 19.  COMPARISON OF STORMWATER QUALITY AT P-10, P-30
              AND DEVELOPING AREAS DURING STORM #10
                            Forest
                            with
                            Development,
                            P-30
         The Woodlands
Forest   Development
P-10     (P-30) - (P-10)
Drainage Area  (acres)         21,606
               (ha)             8,750
Streamflow Volume  (ac-ft)      2,829
                  (ha-m)          349
16,050
 6,SCO
 1,614
   199
5,556
2,250
1,215
  150
Average Concentration of Water Quality Parameters  (mg/1)
Ortho-phosphate
Total Phosphorous
Ammonia
Nitrite
Nitrate
Total Kjeldahl Nitrogen
Total Suspended Solids
Soluble Organic Carbon
Total COD
Soluble COD
0.011
0.088
0.15
0.009
0.154
1.39
171
20.4
52.6
38.8
0.003
0.06
0.08
0.004
0.065
1.37
38.5
22.0
58.7
43.0
0.021
0.125
0.244
0.017
0.272
1.41
347
18.2
44.5
33.2
     FC/FS bacteriological ratios and land use--An important com-
parison employed  in examining data is the relationship between
FC and FS concentrations.  A FC/FS ratio > 4 suggests the present
of human wastes.  Between 2 and 4, the FC/FS ra.tio may suggest
human wastes mixed with  other source materials, and 1 < FC/FS <
2 value represents an area of uncertainty.  If values fall be-
tween 0.7 and  1.0, a predominance of livestock or warm-blooded
animal waste may  be suggested.  Following the latter range, FC/
FS values less than or equal to 0.7 strongly suggest a predomi-
nance of warm-blooded animal waste other than human wastes.

     Mean FC/FS ratios for storm events, low flow and sewage de-
terminations are  plotted in Figure 24.  Note that FC and FS
bacterial numbers in The Woodlands stormwaters are greater than
low-flow waters,  however the ratio remains the same.  Urban run-
off at Westbury also exhibited a similar ratio although the
bacterial numbers were much greater.  High ratios for the sewage
determinations confirm human waste contamination.  Lake B runoff
contained the  lowest ratios indicating stormwater impoundment
may have beneficial effects or that organisms attached to sus-
pended sediment.  TC, FC, FS and ST bacterial species were all
observed to settle in quiescent water.  Additional data have been
reported by Olivieri, et al., (44).
                                80

-------
81

-------
     A least significant difference statistical analysis was ap-
plied to FC/FS ratios from all stations resulting in the follow-
ing sequence:
                    Location             FG/FS  (Geo. Mean)
               Storms, Lake A
               Storms, Lake B
               Low Flow, Lake A
               Chlorinated Secondary Sewage
               Low Flow, P-10
               Storms, P-30
               Low Flow, Lake B
               Low Flow, P-30
               Storms, Westbury
               Low Flow, Woodlands
               Storms, P-10
               Raw  Sewage
               Secondary Treated Sewage
 0.17
 0.53
 0.58
 0.73
 0.92
 0.97
 0.99
 1.26
 1.47
 1.68
 2.11
 2.42
13.30
          Those groups which demonstrated no significant  dif-
          ferences between subsets are indicated by the verti-
          cal lines on the side.

STORMWATER QUALITY MODELING

    Several techniques are available for the prediction of water
quality responses in a watershed.  The SWMM model has been
adapted for natural drainage conditions at The Woodlands in an
effort to simulate stormwater quality response.  The model oper-
ates from a relation between runoff rate and pollutant load, but
the prediction of hydrographs. has been more successful than pol-
lutant response.  The water quality procedure in the model is not
designed to simulate the response from natural drainage,  and has
been updated for The Woodlands.  New relationships between cumu-
lative load  (Ib)  and cumulative runoff volume  (ft-*) have been
incorporated into SWMM for various parameters at The Woodlands.
In this way, concentrations can be predicted as a  function of
runoff  (45).  Another water quality modeling approach  is dis-
cussed below.

pollutant Load Modeling for Multiple Events

     The load-runoff relationships presented above (Figures  17-
20) provide  the'foundation  for an uncomplicated, yet satisfac-
torvT model  for runoff pollutant  load simulation of multiple  or
individual storm  events.  Given time  increment  values  for runoff,
the model consults  time-varying load-runoff relationships to
calculate mass  flows  during storm events.
                                82

-------
     Variation in the average pollutant, concentration over time
is approximated by variation of the load-runoff line slopes
(Figures 17-20).  These slopes represent the ratio of mass of
                          an.
  kech watershed.  Initially three parameters are defined for each
load-runoff relationship: the average slope, the initial slope, and
a factor which sets the range within which the slope can vary.  The
average elope can be roughly determined from the cumulative rela-
tionship produced from field data.  The initial slope value depends
primarily on initial conditions, and the range variable is deter-
mined by the spread in observed pollutant concentrations.

     During dry periods the slopes are incrementally increased up
to but not above the pre-defined maximum.  This corresponds to
the buildup of available pollutants on a watershed between storm
events.  An increment chosen to increase the slopes is required as
input and is obtained primarily by calibration.  During a storm
event the value of the slope decays exponentially by the same
means employed in both the SWMM  (46) and the Storage, Treament, and
Overflow Model '(STORM, (47).
           libs pollutant
           washed off  in
           any time  interval
             Lbs
             remaining on
             the ground
 or:
                      -dP
                       dt
= kP
                               (1)
 which when integrated  takes the form:

                      P0-P = PQ (l-e-kt)
                               (2)
 Where P -P =  Ibs washed away in time,  t,  and k is assumed to
 vary in°direct proportion to the rate of runoff,  r:
                              k = br
                               (3)
 b can be  evaluated  given the assumption that 0.5  in. (!•.27 cm)
 of runoff uniformly  delivered  in  1 hour washes  away 90% of  the
 pollutants  (22).  As a. result  the equation  can  be written:

                                                         (4)
                                   83

-------
The equation used  to  decay the load-runoff line slopes is:

                              -4.6 rt
                    PDS  = 1-e
(PDS),
                                   (5)
Where PDS is  the  load-runoff curve slope at some point in time
during the storm  event  and  (PDS)   is the initial value.

     A six month  period of  streamflow at site P-30 was chosen for
sequential simulation.   This period dating from October 28,  1974
to April 8, 1975  includes storm events 5,  1 and 10 monitored
during the study.   Storm events 8 and 9 were considered too small
for use in the simulation.   Predicted  solids  loads  and  the ob-
served streamflow hydrographs are  presented in Figure 25.  Slope
parameters used were derived  from  the  load-runoff relationship,
with the upper limit values  found  by trial  and error.

     Simulation results  can be  evaluated by comparing observed
and simulated mass  flows for  individual  storm events.  As shown
in Figure 26, the simulated  curves compare  satisfactorily to  the
observed mass flow  curves.   Table  20 gives  comparisons of simu-
lated to observed values for  total pounds TSS, and peak magnitudes
for each of the three storms.
                                                                 t
Unit Loadoqraph for Single Event Simulation

     The form of  the stormwater mass flow  curves, obtained from
the product of instantaneous  concentration  and discharge, re-
semble the general  shape of  the streamflow  hydrograph and provide
a more useful measure of runoff loadings than the concentration
curves.  For  a given watershed, it is  possible to generate a  unit
hydrograph based  on the incomplete gamma distribution.  Using the
theory of linear  reservoirs,  the resulting  equation for the unit
hydrograph becomes  (48)
Qn = kr(n)
                               (I) ^
 exp(-tA)
                  (6)
where  S = total  storage  (one  inch (2. 54 cm)of  runoff); k = constant;
n = outflow from n^*1 reservoir.   The watershed  is  considered  as n
serially  arranged linear reservoirs,  and  it  is possible to fit an
observed  hydrograph by  varying  k and  n.

     The  theory of linear reservoirs  can  be  extended for mass
flow curves in  order to develop a  corresponding unit pollutoqraph
or  unit loadograph for  application to urban  storm runoff.  In
this way,  mass  flow curves can  be  generated  in a  similar fashion
to  the hydrograph by varying appropriate  constants.  The water-
shed is considered as n serially arranged tanks with first order
decay, and the  mass balance  becomes
                                84

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                    ~dt~
                                                           (7)
where MI = total mass; go = mass inflow; g1 = mass outflow;
ki = linear decay coefficient.  By solving the equation for n reser-
voirs in series, assuming outflow from one is inflow to the next,
and assuming M = kg  (analogous to S = kQ), the final resulting
equation for the unit loadograph, .de-fined as the ::nass flow in kg/sec
plotted vs time, becomes
                        M
                  gn =
                                                            (8)
The similarities of equation 8 and equation  6 are obvious, where
gn is mass flow  (kg/sec), a equals  (1 + kk1)/k, cind M is total
mass.

     Hydrograph and mass  flow simulations  for Storm 10 on the
P-10 site are  shown in Figure 27.  The timing of the hydrograph
peak and the total volume compare well, but  the recession rate
is predicted lower than the observed.  The simulation of TSS and
TP mass flow curves  (g/sec) yielded  similar  results, with good
peak and total mass definition,  but  a predicted recession rate
lower than observed.  This storm yielded  1.2 in  (3.05 cm) _of runoff,
and the unit response can be ovtained by  dividing all ordinates by
1.2.

     The application  of this approach is  in  a preliminary stage
due to  lack of significant storm runoff data (1 inch, 2.54  cm, or
greater) on Hunting Bayou of The Woodlands watersheds.  As  more
storm event data are  collected  from other watersheds  in the area, it
will be possible to  investigate relationships between the gamma
distribution  shape parameters  (n,  k) and  land USB or  physiographic
factors in the watershed.  In  general,  the time  of  peak of  the unit
loadograph is  related to  n and k by the equation
                          t  =
(9)
 Urbanizing watersheds should have lower values of n and k than
 undeveloped  watersheds of the same size.  As n is increased,  k
 must be correspondingly decreased in order to yield the same tp
 value  for  a  given watershed.

      The unit loadograph can be used in the same manner as the
 unit hydrograph.   Once the unit response has been determined for
 a watershed,  storms of varying intensity can be analyzed by lagr
 ging and superposition of the unit graphs.  A unit pollutograph
  (concentration vs time) is found by dividing the ordinates of the
                                  88

-------
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1.2.




0.6.
          0.0.
                 20   28   36   44   52   60   68

                      HOURS  INTO  STORM

                 	  OBSERVED     	FITTED
Figure 27.
  Fitted curves for storm runoff and pollutant

  mass flows observed at P-10 on 4/8/75.

  1 cfs = .028 m3/sec
                          89

-------
  unit  loadograph by corresponding hydrograph flows.   Because  of
  the linear load-runoff relationships  which have been developed
  tne linear assumption of unit  response  is  further justified    '
                load°9raph  approach  suffers  the  same limitations as
          hYfr°g^a?h1 method with  re^rd  to  assumptions of uniform
          and  initial  conditions, but  it does offer a relatively
 simple and useful technique  for  analyzing  stormwater pollution
 response as a  function of land use, watershed  characteristics
 and hydrologic conditions.

 Storm Water Management Model

      SWMM is composed of  five integral  computation blocks as
 shown in Figure 28.  The Executive Block controls all activity
 within the model because all input-output functions for other
 blocks are programmed into the Executive Block.  The Runoff
 Block computes quantity and quality of runoff for a given storm
 and _ stores results in the form of hydrographs and pollutographs
 i*-J?«?t?1t° th| ?ain sewer system.  The Transport Block sets up
 initial flow and infiltration conditions and performs flow
 quantity and quality routing to produce combined flow hydrographs
 and pollutographs for the total drainage basin and at selected
 ^Jfm;diate PO1^3'  Quantitv a^d quality of flow are stored and
 SSS*  ? Si6*?"1?3 criteria in the Storage Block.   Diapers ioT
 effects of the discharge in receiving waters are computed  in the
 JTXr-S* ^M^ B^°Ck-  A m°re detailed description is available
 in the User Manual - Volume in (46).

 4.1, ~In ^eneral  only one  or  two  computational  blocks,  as well as
 the Executive  Block,  are used in  a  run.   However,  all  blocks may
 be run together.   The use  of  independent computation blocks
 allows for  examination of  intermediate results.  The necessity
 for at least 35 OK bytes  of core storage  in  SWMM leads  to hiqh
 run costs and  limits  the number of  options  to be analyzed.

     The SWMM  release  of February 1975,  referred to in this  re-
 port as the original  SWMM  version,  was extensively modified    The
 capabilities of the modified  version have been  expanded  to model
 runoff and water  quality from natural  drainage  areas.  Study
Model Application —
     Specific data required as input to the original SWMM are de-
scribed in Table 21.  A quantified description of the watershed
provides a computational basis for the model and includes the
rainfall hyetograph for the storm to be modeled, a physical de-
scription of each subcatchment to be modeled including the drain-
age area, percent of impervious cover, ground slope, Manning's
roughness factors,  estimated retention storage for both the per-
vious and impervious surfaces, and the coefficients to define
                               90

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            TABLE  21.  MODELING REQUIREMENTS  BY
Item  3.
 Item 4.
Item 1.   Define the Study Area

          Land use, topography,
          tract data, aerial photos, area boundaries.


Item 2.   Define the System
tions of inlet structures.


Define System Specialties

Flow diversions, regulators, storage basins,


Define System Maintenance

Street sweeping  (description and  frequency).  Catch-
basin cleaning.  Trouble  spots  (flooding).
 Item 5.    Define the Receiving Waters

           General description (estuary, river, or lak «>
           sured data (flow, tides, topography, water quality).


 Item 6.    Define the Base Flow  (DWF)

           Measured directly or  through sewerage facility °Pfr-
           a?ing data   Hourly variation and weekday vs. weekend.
           ^characteristics  (composited BOD and TSSr results >.
           Industrial flows  (locations, average quantities,
           quality) .

 Item 7.   Define the Storm Flow

           nailv rainfall  totals over an extended period (6  months
           SrionqSr) encompassing the study  events.   Continuous



                                                            '
                                 92

-------
Horton's soil infiltration equation.  Input data also define
hydraulics for the storm sewer system in each subcatchment and
the main sewers or open channels in terms of gutter length,
slope, bottom width, and roughness coefficient, cross-sectional
area, side slopes, channel slope, and roughness factor.  For
water quality modeling, a code defining the specific land use in
each subcatchment as well as the street-cleaning frequency, the
number of dry days prior to the storm event, the number of catch-
basins per unit area and the quality of their contents must also
be specified.

     Horton's infiltration equation is used to calculate the in-
filtration rate of rainfall into the soil as a function of time
by Horton's relationship (49).

     Manning's roughness coefficients were necessary for each
drainage element to describe the hydraulics of the drainage sys-
tem.  Gutters and open channels were assigned an initial value
of 0.10, while a value of 0.03 was used for sewers.  These
values were adjusted during model calibration to accommodate
higher peak flows.  Combined sewers are not used in any of the
study areas and therefore all initial flows were zero.

     A 10 minute time interval was the limit for modeling ac-
curacy at minimum cost, and all SWMM runs were made with regard
to this condition.

Hunting Bayou Modeling—
     Input data for the Hunting Bayou drainage system were ob-
tained from existing engineering maps and site inspection.  The
subcatchments and drainage network used as input data are shown
in Figure 29.  The total drainage area of 1976.8 acres (499.86 ha)
is divided into 24 subcatchments ranging in area from 25 acres
(10.11 ha) to 138 acres (55.85 ha).  Each subcatchment was
assigned a land use class for modeling water quality in SWMM.
The drainage system includes 23 gutters and pipes in the Runoff
Block and 44 manholes and conduits in the Transport Block.
Infiltration rates were originally estimated and then calibrated
by consecutive modeling runs.

     Five storms were modeled initially.  The rainfall data for
these storms were obtained from reports published by the U.S.
Geological Survey.  All five storms occurred during 1968 and
1970, prior to the initiation of this project.  Consequently,
only water quantity was modeled and no water quality data were
available.  Comparisons of observed and computed hydrographs for
these five events, presented in'Table 22, indicate reasonable agree-
ment.  The average absolute error in runoff volume was 26% (see
Table 22) of the observed value,  while the average error in peak
flow prediction was 20% of the observed.  The temporal agreement of
the hydrographs was very good.  For instance, the times of peak
flow agreed within ten minutes in four of the five instances and
                                93

-------
                     LEGEND.
                        STUOV AREA BOUNDARY
                        SUBCATCHMENT DIVIDE
                        SEWER  PIPE
                        OPEN DITCH
                        MANHOLE
                        MANHOLE NUMBER
                    1 ft = .305  m
Figure 29
•«*>*« *•    ----
Subcatohments  and drainage network in Hunting  Bayou,

                      94

-------
average error was twenty-two minutes.  However, computed values
tended to predict faster returns to low-flow conditions than were
actually observed.
        TABLE 22.  COMPARISON OP SWMM PREDICTED RESULTS
                   WITH OBSERVED FLOW MEASUREMENTS FOR
                   HUNTING BAYOU STORM EVENTS
Date of Storm
09/08/68
09/17/68
11/05/68
10/22/70
11/09/70
Total Runoff
(ft3 x 106)
Measured
4.84
9.06
4.40
12.69
1.52
Predicted
4.50
4.98
5.07
12.84
2.46
Peak Flow Rate
(cfs)
Measured
325
330
282
665
160
Predicted
303
302
337
549
205

    NOTE:   1 cfs = .028 m3/sec
     Three more recent Hunting Bayou storms on  3/26/74, 4/11/74
and 5/8/75 were sampled and the water quality and flow prediction
capability of the SWMM was tested.  The 5/8/75  storm event will
be presented here as an example.  Figure 30 shows the observed
and SWMM predicted hydrographs for this event.

     Original SWMM predictive capabilities are  based upon
dust and dirt accumulation data acquired in Chicago, and the
extrapolation of these data to natural drainage areas is a
limitation of the model, which resulted in poor water quality
predictions for this watershed.  Consequently,  a simplified
approach to water quality prediction in SWMM was developed
which does not consider pollutant buildup or input data on
dry days, street cleaning frequency, land use,  or curb length.
Instead, pollutant availability loading rate at the beginning
of the storm is input.  This information was produced by The
Woodlands project stormwater monitoring program.  The user
determines effects of dry days, street cleaning frequency
and land use external to the model.

     The new SWMM version was also run for the  5/8/75 storm event,
and the resulting predicted TSS pollutograph is shown in Figure 31
(left-hand figure).   The loading rates used for this pollutograph
prediction are as follows:
                               95

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STREAM
FLOW
DISCHARGE

STATION
Ji-20



     21 22 23 24  1  23456  7  8  9  10  M  12.

                       TIME (hrs.)
   STORM  OF  5/08/75
ui
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                 	^OMPUTEl)
                                                    SUSPENDED
                                                    SOLilDS  BY
                                                    ORIGINAL SWWM
                                                    VERSION
     200 22 23 24  I
23  4567
   TIME  (hrs.)
                  8  9 D   1
                                                     STATION
                                                       M-20
       Figure  30.
Predicted hydrographs for T55S concentratioinis
at Hunting Bayou ((5/8/75) ,

1 cfs  = ,028 m3/sec
                                 96

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       Pollutograph
       Prediction
  TSS Loading Rate According to Land Use
     m	(Ib/acre)	
  Residential  Construction  Undeveloped
     1-85          2.31          0.23
      A removal coefficient of 21.2  min"
 4.6 in the SWMM.
                    was used,  as compared to
 =T^T  A_tr^l and error procedure was followed to determine the
 above loading rates and removal coefficient combination that
 would reproduce the observed pollutograph.  Loading rate and
 removal coefficients derived are valid only forttS s£rm Ssed
                  nd aPPlic*tion of results to othe? stSSL Is
                  Prevailing antecedent conditions and raXfall-
 ™ •s are similar for both storms and if study areas
 are identical or at least homogeneous.                ^uay areas

     Although simulated pollutographs were curve-fit to
 observed pollutographs,  actual andcomputed masl ^ans^
 *X2 not correspond.  As shown in Figure 31 (right-hand fiou
 SSFVi11^ P°°r reSUltS WSre outlined usingthe product o?'the
 thJf Sn^^ograph -and pollutograph.   it wa2 determined  that
 this condition resulted from a failure to properly predict the
 timing of the peak of concentration.                P-^UJ-C-C -cne


 4-a«4- 5° improve the modeling of total mass loading of  a pollu-
 tant the new version was used to model  pollutant  mass  flow rates
 Again  the loading rate and decay factor were adjusted  to repro-
 duce mass flow rates,  using the following values:
                                    TSS  Loading Rate According
                                to Land Use (Ib/acre)
     Mass Flow
     Prediction
Residential
   4.0
Construction
    5.0
Undeveloped
    0.5
     A removal  coefficient of  35 min-1 was used for this case.


Results, shown  in Figure  31  (right-hand  figure), indicate mass
flow rates can  be accurately predicted using this method  (dashed
line).  The method was applied to other  stormwater quality para-
meters, COD, N03, TP, with similar results.

Panther Branch  Modeling—
     The data input to the SWMM for the  Panther Branch drainage
system was developed from existing engineering maps and numerous
site inspections of the watershed.  The  total drainage area for
Panther Branch  of 21607 acres  (874.40 ha) was divided into
57 subcatchments ranging from 21 acres (815 ha) to 1366 acres
(552.80 ha).  The input parameter called "width ©f sub-
catchment" is defined as the width over which overland flow oc-
                               98

-------
curs.  Values for this parameter were f-irst estimated by the
method described in the SWMM User's Manual (46).  These values
were subsequently reduced by approximately 40% to achieve cali-
bration.  The Panther Branch drainage system is made up of 57
"gutters" and 61 transport elements of varying characteristics.

     A major drawback of SWMM at The Woodlands is that the area
below P-10 was in a transient state due to development.  Con-
tinually changing land use affects the quality of runoff and
consequently P-10 is regarded as a control point.  The area above
this gage is in a relatively stable condition and will give a
more accurate measurement of the pollutant loading due to the
land use rather than from a construction area.  Stormwater runoff
from a construction area can vary in quality from storm to storm
depending on the stage of construction, and modeling proved diffi-
cult.  Consequently, it is presumed that several construction
areas where the natural ground had been disturbed and stripped
of the protective vegetative cover contributed more TSS than SWMM
could predict from available input data.

     Five storm events on Panther Branch have been modeled.
Similar to the data for Hunting Bayou, all subcatchment, gutter
and transport element data for Panther Branch were identical for
all runs.   Infiltration rates were determined similar to
Hunting Bayou.  The original SWMM was used to model both water
quantity and quality for two storm events on 10/28/74 and 12/5/74
and only quantity of flow for the remaining events  (1/18/74,
4/8/75 and 11/24/75).  Computed flow peaks and volumes agreed well
with the observed flows; the average absolute error in the volume
of runoff between observed and computed hydrographs was good
except for the storm events of 10/20/74 and 11/25/74 when the flow-
peaks between observed and computed hydrographs were approximately
three hours apart.  Water quality modeling at P-30 was not
acceptable using the original SWMM.  The 10/28/74 storm event at
P-30 was a multi-peaked hydrograph, and TSS modeling by the ori-
ginal SWMM was not accurate.  The maximum observed TSS concentra-
tion of 1000 mg/1 during the second peak in streamflow was com-
puted to be 273 mg/1, a much lower concentration.  Runoff quality
modeling of the 12/5/74 storm event was similarly too low in
concentration and total load.

     The 12/5/74 storm event was modeled for both the upstream
gage, P-10, and the downstream gage, P-30.  Since the entire
drainage area had the same land use before development began, most
differences between the upstream gage and the downstream gage can
be attributed to the changing land use in the developing area.
Using the original SWMM version, the computed peak concentration
of 142 mg/1 TSS at Station P-10 was in good temporal agreement with
the  observed value of 130 mg/1.  The falling  limb of the observed
pollutograph occurred more rapidly than the simulation  pollutograph,
resulting in'a difference of 11,330 kg  (25,000  Ib)  or  a 40% error
                                99

-------
in computed total load.  Observed TSS production at Station P-10
was about one-third that at Station P-30.

     The modified water quality version of SWMM was also used to
model the 12/5/74 storm on Panther Branch for TSS, COD, N03 and
TP parameters.  The pollutographs and mass flow curves were sepa-
rately computed using loading rates obtained by trial and error.
Simulation results are summarized in Table 23.  Optimized polluto-
graph and mass flow curves corresponded well with the observed
data.  However, mass flow rates calculated from the optimized pol-
lutographs were not as accurate as computed optimized mass flow
rates.  TSS predictions at Station P-30 were compatible to observed
data with slight differences for occurrence of peak flow rates.
Modeling of TP at both P-10 and P-30 and NO3 at P-30 not entirely
satisfactory.

Swale 8 Modeling, Existing and Future Development—
     Existing drainage and planning maps were used to develop the
input data for Swale 8, the watershed above Lake Harrison.  Site
inspections to determine drainage area boundaries and extent of
construction were conducted on a periodic basis because this
watershed was in a transitional stage.  During the project, the
channel was enlarged and construction of Lake C was underway
whiles Lakes A and B had already been filled.

      The total drainage area  for Swale  8 of  459.3 acres  (185.87
hectares) was divided  into  10  subcatchments  ranging from  23 acres
 (9.30 ha) to  66  acres  (26.71  ha).  Land uses, for  the upstream
subcatchments were classified as open space,  whereas the  last
three downstream subcatchments  were designated as multi-family,
residential and  commercial.   Seventeen  drainage system elements
were used to model the entire area.  Of these, two elements were
storage units, Lakes A and  B,  and  all six channels were trape-
zoidal in shape  as a result of channel  enlargement.

      Swale 8  storm even on  4/8/75  was modeled because  the only
other observed storm event, 3/13/75, had a peak inflow into Lake
B  of 0.06 m3/sec (2.0  cfs)  from 0.81 in.  (2.06 cm) of  rainfall.


      The transitional  phase of development in Swale 8  gave rise
to several problems in modeling runoff. The most severe  problem
is the lack of lake volume  data.   The topographic maps prior to
lake construction show the  natural ground contours, but the
reservoir areas  were used as  borrow pits for fill material for
the dams as well as other construction  at The Woodlands.   Conse-
quently, the  original  storage capacity  of the reservoirs  was not
known and no  subsequent reservoir  surveys have been conducted;
therefore, the elevation-area-capacity  data  for these  lakes were
                                100

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only approximate.  Also, groundwater was being pumped in Lake A
and pumpage rate was not recorded.

     The outflow structure for Lake A is controlled by different
outlets at different water surface elevations.  The outflow rat-
ing curve  (discharge as a function of water surface elevation)
is composed of three segments, one controlled by the low-flow
orifice, the second controlled by weir flow through the flood
discharge outlet which in turn is limited at extreme flows by
the capacity of the outfall conduit and resulting in the third
segment of the rating curve.  The SWMM is not capable of model-
ing this complex outflow scheme.

     Under the conditions described above, the modeling of runoff
storage in the lakes proved to be difficult.  Several attempts to
model the outflow from Lake A for the storm of 4/8/75 were un-
successful.  The extent of assumed data was too large in magni-
tude to approximate the correct operation of Lakes A and B.  As
a result, additional modeling of the watershed was conducted
only on that drainage area of Swale 8 upstream from Lake Harrison
at point £>-10 (Lake B gaging station) .  The results of this
modeling effort are discussed in the following paragraphs.

     Due to various external influences, urban development at The
Woodlands did not proceed as rapidly as expected.  Site develop-
ment plans were available for Phase I, and in early 1976 a major
portion of the Swale 8 watershed was being planned for develop-
ment.  Using these plans for the watershed, three development
scenarios were evaluated for modeling:   (1) existing conditions,
(2) immediately developing conditions, and (3) future but not
ultimate conditions.
                                                               i

     Water quality predictions by the modified version of SWMM
were attempted.  Changes in land use and increase in impervious-
ness were computed from plat maps provided by The Woodlands De-
velopment Corporation and input to the SWMM.  As described
earlier, the modified quality prediction version required the
input of loading rates for each pollutant.  The initial loading
rates used were derived from the p-30 watershed modeling experi-
ence.  Based on previously described experience with pollutograph
differences resulting from computed hydrographs, it was decided
that only mass, flow rates would be modeled.  Runoff from the
storm on 4/8/75 was chosen for modeling; however, due to its
multi-peak complexity, only the first hydrograph peak was model-
ed.  Results from the first computer run indicated that the load-
ing rates determined from the results of modeling at Station P-30
were too low.  Observed peak mass flowof.TSS was three times the
peak mass flow computed from loading rates derived at Station
P-30.  These differences are a result of the extreme effects of
lake and golf course construction, as well as channel improvement
concentrated in the Swale 8 watershed.  Also the freshly sodded,
                               102

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 developed areas severely eroded during the intense rainfall of
 tnis period.  Loading rates were revised for both construction
 and developed areas.  For Swale 8 the  TSS loading rates from de-
 veloped areas were 82% of the rate from construction areas.  In
 contrast, the same ratio at Station P-30 was 78%.

      The modified version of SWMM was run for two future water-
 shed development conditions described earlier,  using the rainfall
 on 4/8/75 to provide a basis for comparison between existing and
 future conditions.  AS anticipated, the larger proportion of area
 under construction changes the pollutant loads: considerably; the
 changes range from an increase of 77% for TSS to a decrease of 8%
 for nitrates.                                                  '

      After the construction phase of development has been com-
 pleted, peak pollutant loads do not decrease as may be expected
 but_the total mass   of pollutant do decrease.   These dramatic '
 environmental effects of construction activities are listed in
 "?abf^ 24C  One reason for the increase in peak  mass flow rates
 is the change in the runoff hydrograph.   After  construction the
 hydrograph peak is increased by approximately 40%.   Another
 reason is the increase in the input loading rates  for developed
 areas,  which results in a doubling of peak mass flow rates  for
 the parameters N03,  COD and TP.   The 20%  increase  in the TSS
 mass  flow rate is  a result of hydrograph  modification due to
 urbanization.

      In summary,  the modified water quality modeling version
 greatly improved  the capabilities  of the  SWMM.   Water quality
 modeling results  are much more dependable,  and  observed  events
 can be  adequately  simulated.   Each of the  stores used to test
 the new SWMM version was  selected  to present  a  range of  flow
 water quality and  land use data; thus, the  modal was  tested over
 a  range of different conditions.

 STORMWATER ALTERATIONS AT THE  WOODLANDS

 Water Quality  Needs

 Irrigation—
    t Collected stormwaters are to be used for golf course irri-
 gation  at  The Woodlands to supplement natural precipitation   The
 critical water quality parameter for  irrigation is salinity.  Ex-
 cessive salinity affects plants by  increasing osmotic pressure in
 the soil which limits uptake of water by plants).  However, this
 is not the case at The Woodlands and, therefore, salinity will
not be a problem.  Electrical conductivity measurements in storm-
water runoff is less than 3000 micromhos at Th<> Woodlands and is
 excellent to good for most plants"  (50).  The presence of nutri-
ents in stormwaters slated for irrigation is not high and in this
case considered an asset rather than a pollutant.   TSS concentra-
 tion  or large particulates could cause mechanical problems  such

                               104

-------
 as pump  damage  or  clogging of  sprinkler  heads, but careful
 placement of  the intake  structure  will avoid  these difficul-
 ties.  TSS concentration in Lake Harrison  during low-flow
 conditions is about 100  mg/1 and average particulate  size is
 estimated between  25 and 250 mg/1,  levels  acceptable  for
 pumping  requirements.  The velocity in the distribution system
 will keep the solids in  suspension.   Particulate size criteria
 will be  set by  the orifice size of the irrigation system.

 Aesthetics—
     The water  quality level for aesthetics is presently met without
 any stormwater  treatment.   The lake  is devoid of  floating debris or
 objectionable odors  and  promises to  support a wide  variety of  life-
 forms.   Superficially, it  resembles  early  stages  of other local
 man-made lakes.  High nutrient levels may  promote macrophyte growth
 and algal blooms,  but macrophytes  can be controlled by a regular
 lake maintenance program and algal blooms  can be  prevented by
 reducing the  lake  detention times  and nutrient levels  (40).

 Recreation—
     In  a discussion of  recreational water uses,  two divisions must
 be considered:  contact  and noncontact.  The water  quality require-
 ment for contact recreation, which involves substantial risk of
 ingestion,  is more stringent than  that of  noncontact  (51).  Swimming
 is the primary  example of  contact  recreation and  is prohibited in
 The Woodlands'  lakes.

     A water  quality criteria designed strictly for boating would
 be similar  to that for aesthetics, with the added requirement  for
 fecal coliform  levels.   It  is recommended  that fecal coliform
 levels of  2000/100 ml average and  4000/100 ml maximum be observed
 for "unofficial recreation"  waters.  Levels of 1000/100 ml average
 arid 2000/100  ml maximum were suggested for official noncontact
 waters (52).  Fishing water criteria invoke an additional require-
 ment that harvested species  be fit for human consumption.   Edible
 fish species  should be free  of toxic chemicals and pathogenic bac-
 teria or viruses.  The data  to determine the fulfillment of this
 requirement is not presently available.  The consumption of fish
 from such waters has been practiced without harmful results.
 Coliforms in  the digestive  systems of fish caught at Woodlands are
 in higher concentrations than from other lakes but presumably do
 not reach the edible portions of the fish  (52).

Water Supply  Uses—
     Lake Harrison ranks as  a poor raw drinking water source
because it would require a high level of treatment before  use  (50).
With groundwater, a less expensive and more reliable source is
 easily obtained.   Its use for this function is to be restricted to
 emergencies.
                                105

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The Lake System

     The man-made lakes at The Woodlands will  serve as recrea-
tional centers, wildlife preserves and  storage for stormwater
runoff.  The lakes will contribute to the maintenance of a
perched water table necessary for plant life.   The lake water
will also be used for  irrigation of adjacent golf courses.  In-
puts to the lake system are  limited to  stormwater runoff and
treated wastewater from The  Woodlands Wastewater Reclamation
Plant with ultimate capacity of 6 mgd (..26 m3/sec>.  Eor a
year of average rainfall, treated wastewater will comprise  75% of
the flow through the lake system.  Design effluent quality  for
the plant is indicated in Table 15 and  suggests that the lakes
will contain clear waters with somewhat elevated nutrient con-
centrations as compared to existing surface waters.  Lake de-
tention time during dry weather will be approximately six days.
Consequently, treated  wastewater will be the dominant influence
on lake water quality  at The Woodlands.

     The lakes will serve as stormwater storage reservoirs  and, in
so doing, will remove  significant amounts of pollutants, primari-
ly due to sedimentation.
Lake Harrison Sedimentation—
     Eight storm events were monitored at the lake system, ranging
from 0.26 in. (0.66 cm) to 3.97 in.  (10 cm) of rainfall.  In the
following paragraphs, the largest storm indicates the usefulness
of reservoirs for preventing release of construction site sedi-
ment washoff.

     Rainfall associated with the storm event began shortly
after midnight on April 8, 1975 and  continued until noon the
same day.  An early morning cloudburst was followed after a four
hour pause by less intense rainfall  totaling 3.97 in. (10 cm).
The hyetograph is shown in Figure 32.  Runoff passing the Lake B -
gaging  station, the major inflow to  Lake Harrison, originated in
a watershed undergoing intense development at this time.  Much
of the  drainage system itself was being constructed under speci-
fications of the  "natural drainage"  system including Lake C,
656.2 ft (200 m) upstream of Lake B.  Lake C was constructed to
serve as a wet weather pond and golf course water hazard.
Unfortunately, its low earthen spillway had yet to be sodded and
provided an  erosion source within the drainage channel.

     Lake Harrison inflow and outflow hydrographs are compared in
Figure  33.  Characteristic of runoff response in a small water-
shed, the multi-peaked inflow hydrograph was a product of the
sporadic hyetograph  (Figure 32).  Intense stormwater flow deepen-
ed the  inflow channel by 6 in.  (15 cm) and obliterated bales of
                               106

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001        08       09

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                                                      .  8
                                                        8
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hay placed in the  channel  to act as flow c°^rol deviceJ-  Storm-
water flow crested shortly before noon on April 8 at a recora
discharge of 123 cfs  (3.48 m3/s).  Bank storage and ponding
helped to prolong  minimum  flow in the channel for two days, con-
tributing to the total inflow runoff volume of 93 acre ft  (114 m^).
TnelakegsyStem effectively damped inflow fluctuations   The
hydrograph peak traveled through the lakes in a half hour.





 «._*>_ _.  —,—.*..•»—»—»v* *i ^r*\n o i  TnS3.ri GOIlC"J.l L.J- d. L. A.\jj.+*y »  x^-*-                m    _
 ticie  comparison ua- luccai* ^      *->,« outflow was nutrient enriched as

 a'rSultNol ont o^a^omSinStion of two sources:
      (1)  unmeasured  runoff from the fertilized --._-  ---_
      1    to the  lakes and/or direct precipitation  on the
           lakes,

           The  ouality of water held in the  lakes  prior to
           SS  storm event.   (Water impounded  in the lake
           prior to the storm event approximated the runoff
           volume.)


 ai£fe^=





 proximated maximum concentrations.
sedimentation is a
                                                 of 2660 mg/1 at
                                  a
(117 t)
                               the voume of the
                                                       assume<1.
                 mass

               215  S
  ing Panther  Branch by the lake system.
       Table 26  shows  the reduction in stormwaterseaiment^oad by

                                   ^lete1^^!,  100,,  is a
                                   108

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2800 r  '40
CO
Q

8
o
a
  800
<
o
  400
                             /  \
    TOTAL
	SUSPENDED SOLIDS
    DISCHARGE
2800 r
 ,800
o
f-
  400
        100
       (O
     -  UJ
       o
       CO
       Q
                                                    OUTFLOW
          J          4          8         12

                         HOURS  INTO  STORM
           Figure 33.  Reduction of  TSS through The
                       Woodlands lake system.

                       1 cfs  =  .028  m3/sec
      16
20
                                109

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 TABLE 25.   SUMMARY OF WATER QUALITY PARAMETERS FOR SITES
            LAKE A AMD LAKE B DURING THE APRIL 8, 1975
            STORM EVENT



Drainage Area (acres)
Runoff Volume (ac-ft)
Rainfall (inches)
OUTFLOW
Lake A
483
93.4
3.97
INFLOW
Lake B *
337
93.2
3.97
Concentration of Water
Quality Parameters:*
Ortho-P

TP

NH3

N02

NO3

TKN


TSS

SOC

Total COD

Soluble COD

Specific Conduc-
tance (micromhos)

Turbidity  (JTU)
Avg.
0.015
0.10
0.16
0.032
0.28
1.3
245.
13.6
41.8
26.4
130.
Max.
0.048
0.19
0.26
0.046
0.32
2.
356.
19.
45
31.
215.
Avg.
0.005
0.11
0.11
0.009
0.15
1.86
1273.
16.2
63.7
32.
85.
Max.
0.013
0.36
0.15
0.054
2.1
3.1
2660.
22.
87.
45.
304.
160.
210,
375.
900,
                    1 ac =  .405 ha
                    1 ac ft =  .123 ha-m
                    1 in = 2.54 cm

     *all concentrations in mg/1 except where indicated

                            110

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result of total stormwater storage by Lake Harrison and does not
preclude discharge at a later time.
      TABLE 26.  STORMWATER SEDIMENT REMOVAL AT LAKE  HARRISON
                          TSS Load During Storm Event
Storm #
8
9
10
13
14
15 & 16
Ibs Input
(Lake B)
104
13800
322000
6700
115302
4840
Ib Discharged
(Lake A)
Flow stored
within lake
991
61900
Flow stored
1850
3270
% Load
Reduction
100%
93%
80%
100%
84%
32%
           1 Ib =  .453 6 kg

        2
           Estimated value  (Lake B gage inoperative) calculated
           using estimated 10.1 ac-ft  (1.24 ha-m)inflow times
           sample  average concentration, 421 mg/1.

 Disinfection—
      The  FC standard adopted by the  State  of Texas  for contact
 recreation is  200/100 ml  (Iog10 = 2.3)  (53).  For noncontact
 recreation the figures are one order of magnitude higher,  i.e.,
 2,000/100 ml  (Iog10 = 3.3).  Sixteen of 27 storms,  considering
 all  stations,  exceeded the noncontact  recreation standard.  All
 the  Westbury storm events exceeded the standard.  Contact
 recreation standards were met only for Lake A stormwater sampled
 on 3/4/75 and  3/12/75.

      Dry  weather flow in Panther Branch met the contact recre-
 ational standard at site P-10 but not  at site p-30.  The mean
 FC value  for p-10  low-flow data was  2.13  (log1Q basis) indicat-
 ing  that,  on the average, the criteria for contact  recreation is
 satisfied.  However, the value for stream  water at  P-30 was 2.38
 and  therefore  unacceptable.
                               Ill

-------
     Disinfection of stormwater is feasible, and it is generally
agreed that large dosages will be required to achieve adequate
reduction in indicator and pathogen densities.  Chlorine or
chlorine dioxide has been reported to be the most effective dis-
infectant, and in many cases the least expensive (54,  55, 56).
Davis et al. (57, 58) discussed current disinfection research
and practices along with encountered problems which occur in
combined sewer disinfection and stormwater disinfection.

     Samples were obtained from different locations during storm
events to determine disinfectant demand and effectiveness of
ozone and chlorine.  Chlorine demand of Lake A stormwaters on
3/13/75 and 4/7/75 was 10 mg/1, and the ozone demand was in ex-
cess of 32 mg/1.  These elevated demands were partially due to
suspended solids and oxidizable materials competing for the dis-
infectant.  As a result, stormwater disinfection will be costly.

     Chlorine and ozone toxicity—Water quality standards often
state that the final concentration of any waste in a receiving
water should not exceed 1/10 of the 96 hour LC5;) value  (59).  To
assume that 1/10 of even a true 96 hour LC^Q would not have
severe physiological effects and truly impair natural propagation
of all species is unrealistic.  Tsai (60) reported that species
shifts occurred following the introduction of chlorine into a
Maryland river.  Also, Arthur and Eaton  (61) show that the re-
production of fathead minnows is drastically affected by exposure
to sublethal concentrations of chlorine.  This evidence suggests
that sublethal concentration of chlorine is capable of producing
significant physiological impairment.

     The approach taken herein was to establish a chlorine stand-
ard based on physiological responses of the test animal.  The ef-
fect of chlorine and ozone exposure on the phys Lological function
of Ictalurus punctatus  (the channel catfish) has been examined.
The physiological parameters evaluated were heart rate, blood
pressure, sodium uptake, ion excretion, and glomerular filtra-
tion.  In addition, typical LC5Q bioassay tests were completed
for comparative purposes.  Significant results are presented in
the following paragraphs.

     Survival-mortality characteristics—The survival-mortality
characteristics of fingerling channel catfish to chlorine were,
examined and results are shown in Figure 34.  A flow through
bioassay compared to a static bioassay results in a lower 96 hour
LC5Q.  The LCcQ concentrations of 0.07 mg/1 for the flow through
bioassay and 0.45 mg/1 for the static bioassay were read directly
from the figure.  A flow through or continuous ::low bioassay is
a more accurate measurement for 96 hour LC5Q of a highly reacting
toxicant like chlorine  (62) .  The chlorine concentrations in
Figure 34 are based on the measured amounts of total residual
chlorine added to the inflow and do not represent concentrations
during tests with fish.  Thus the chlorine concentrations shown

                                112

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      l      v   £       b? rePrese*tative at treatment outfalls
  Samples taken from receiving waters should show chlorine concen-
      X<    s^lflcantly lower.  Based on a 96 hour ie*ZfToT
                and USing the "Aquatic Life Water Qualfgy criteria"
               ^^
  noted  that this concentration is below the liSit of Analysis?
      The flow through bioassay was  also used for ozone and the
  survival-mortality characteristics  of fingerling catfish are
                                                          ,      t.

 reactive,  it was decomposed  in  the presence  of  organics  (fish).

      In the presence of fish, ozone could not be detected in the
                     insensitivity of the analytical technique
                      ^entrations were estimated from
                                    by its odor  (detectable odor
                                                          exceeds
 chlorine^into the 10 liter recirculating system.  Upon

              ??fe WaS a dr°P ±n bl°°d P^ssure, duS to   ga
              Following escapement from vagal inhibition, there
       m;an.in=rease m blood pressure which in turn decreased
          mmutes of exposure.  This is thought to be due to an
        e X       vascular resistance,  changes in heart rate
 r               be secondary compensations for the gill vascular
 resistance   chlorine ^xposure at levels approaching the 96 hour
 LC50 (0.7 mg/1)  were immediately detected as shown by a pro-
   1111      °  in.blood Pressure.   Continued exposure for 5 hours
                increase in heart rate fr°ni 22 beats/minute to
                   At an exposure of 0.03 mg/1 chlorine there was
           ,.react:LOn shown b^ the bl°od pressure or heart rate
 After  two hours  the fish appeared normal with no apparent SiJl
 function.   Thus,  it is  likely that with exposure to a chlorine
 concentration of 0.007  mg/1 chlorine (1/10 of 96 hour LC  I
 fish will shown  no .physiological response.               50

     Tests  to determine the effects  of ozone on blood pressure
 pulse pressure and heart rate indicate that  ozone levels from
 0.1  to 0.5  mg/1  for 10  hours  had no  apparent effect.

4-T,   GJ1,1 S0d:i?m transPort~The  influence of chlorine  exposure on
the uptake  of 22Na by gills of fish  is  shown in Figure  36.  The
disappearance of 22Na from  agueous phase  (ordinateyaxis  in Figure
                              114

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                                                     115

-------
36) is a measure of the removal of 22Na by the gills of the fish.
The addition of 0.1 mg/1 of chlorine at the start of the experi-
ment markedly reduced the ability of the gills to remove sodium
from aqueous solution.  This reduction in uptake rate following
chlorine exposure suggests an impairment of normal physiological
function in the sodium transport system.
                                                      o p
     The influence of ozone exposure on the uptake of   Na by the
gills of fish is shown in Figure 37.  Phase one of the experiment
utilized the fish as its own control.  A one day recovery period
followed.  The addition of 0.1 mg/1 ozone in the second phase of
the experiment markedly reduced the ability of the gills to re-
move sodium from the aqueous solution.  This reduction in uptake
following ozone exposure also suggests an impairment of normal
physiological functions.

Eutrophicat ion—
     The development of standing crops of phytoplankton in pan-
ther Branch is influenced to a large extent by streamflow rates.
High flow rates do not provide adequate detention times for de-
velopment of large standing crops at any given point along the
stream.  However, reductions of flow rates and/or pooling in the
stream allow detention times suitable for standing crop develop-
ment, provided nutrients are not limiting for algal growth.  De-
velopment of algal populations in this stream, as in other aquat-
ic ecosystems, is influenced by concentrations and availability
of various algal nutrients.  This point is not only pertinent to
development of phytoplankton in Panther Branch but also to
aquatic systems which might receive water from this stream.
Thus, it is imperative to have some knowledge of which nutrients
stimulate algal growth in Panther Branch water.  Therefore, algal
bioassays were conducted to determine whether nitrogen and/or
phosphorus were limiting for algal growth.

     Low-flow water samples collected from sites on Panther
Branch and Spring Creek were used to determine the limiting-
nutrient for algal growth.  Aliquots of stream water were inocu-
lated with the algae Selanastrum and spiked with nitrogen and/or
phosphorus as nutrients.  The results presented in Figure 38 in-
dicate algal growth was increased by additions of both nitrogen
and phosphorus to water samples and phosphorus was the most im-
portant single limiting nutrient along Panther Branch.  The in-
troduction of treated sewage effluent and agricultural runoff
into Spring Creek was probably responsible for the comparatively
larger algal yields in water from this stream.  These findings
are in contrast to results derived from bioassays of stormwater.

     Algal bioassays were also conducted with water collected
from Panther Branch at various time intervals during the course
of storm events.  The stormwater runoff collected below the major
area of construction in The Woodlands  (site P-^-30) seemed to
fluctuate in its ability to support the growth of algae  (Figure

                               116

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                           I-WATER SAMPLES - SPIKES
                           2-WATER SAMPLES * 1.0 ppm N
                           3-WATER SAMPLES * O.O5 ppm P
                           4-WATER SAMPLES * 1.0 N * 0.05 P
             P-IO
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Figure 38,
Optical densities of  Selenastrum capricornutum
after incubation in v/ater  from panther Branch.
and Spring Creek  (May,  1974).
                            119

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39).  Test samples collected early in runoff at P-30 demonstrated
the greatest growth in both control and spiked aliquots.  These
samples corresponded to high nutrient stormwaters from the fer-
tilized areas of The Woodlands, not present at site p~10.  As
runoff at P-30 progressed there was a decrease in algal cell
yields to similar levels observed for P-10 test samples.  Algal
growth was increased by enrichment of stormwater samples with
both nitrogen and phosphorus; however, nitrogen was consistently
limiting for algal growth in stormwater runoff from The Woodlands.

     Data from storm events at Hunting Bayou were similar to
those described above, indicating a stimulation of algal growth
with additions of nitrogen or both nitrogen and phosphorus to the
majority of water samples and slight or no stimulation with only
phosphorus spikes (Figure 40).  The marked reduction in algal
growth, even with combined nitrogen and phosphorus, in the 4:30
sample could have been due to the presence of some toxic agent or
the absence of some essential trace element.  Additional data ob-
tained from bioassays of stromwater from Westbury Square  (Figure
41) also indicated that nitrogen was the limiting nutrient for
algal growth in stormwater runoff.

Porous Pavement

Rainwater Storage and Quality—
     The water depth under the porous pavement in both the sand
subbase and the general storage layer during a period of rainfall
from 3/6/76 to 3/8/76 is shown graphically in Figure 42.  The
depth of the sand layer is 33 in-     (84 cm),, and the layer shows
saturation resulting from failure of the French drain to remove
water from the lower levels.  The gravel layer responded to rain-
fall by storing water as shown by the increased water depth in
the gravel layer followed by a gradual decrease in depth as the
water was drained from the top of the sand layer.  The height of
the stored water and the time to reach the peak height depend on
the quantity and intensity of the rainfall.  This is best illus-
trated in Figure 42 in which seven separate rainfall events oc-
curred over a 60 hour time span.  The first three events, total-
ing 1116 ft3 (31.6 m3), were spread over approximately five hours
and produced an even response with a peak of approximately six in.
The subsequent event at 21 hours involved only 283 ft3  (8m3) of
rainfall and increase in stored water height of 1.8 in.  (4.6 cm).
For the two major storm events occurring at 28 and 48 hours, the
water level had not drained sufficiently and the increase in
stored water height exceeded the measuring probe length.  The
time required for the majority of stored water to drain away was
approximately 10 hours.

     The quality of the water in runoff from the standard pave-
ment and in the gravel and sand layers beneath the porous pave-
ment was monitored during six storm events.  As expected, there
was a general flushing effect for the runoff water with initially
                               120

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              2115-2215 , 2300-0045, OII5-O215, 0245-0315

               WESTBURY    SQUARE

              TIME   OF   COLLECTION (hrs)
Figure  41.   Growth of Selenastrum in stornwater
             runoff from Westbury Square (May 8,
             1975).
                       123

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high concentrations of contaminants which then rapidly decreased.
The rapidity if change is not evident in the water underlying the
porous lot.  Table 28 presents a summary of stormwater quality
data collected during a 0.44 in. (1.12 cm) rainfall on 2/20/76,
which is exemplary of the monitroing effort.  SOC and soluble COD
are generally lower in the water under the porous lot than in the
runoff from the standard pavement, but the reverse is true for
conductivity, TKN, and NH3.  This is apparently a result of the
failure of the French drain to completely drain the sand layer
beneath the porous lot.  The lower COD and TOC values, together
with the high Kjeldahl and ammonia nitrogen, indicate than an
anaerobic digestion process is occurring in the standing water.
Lead values are generally lower in the water under the porous lot
and, in most cases, would be acceptable in aquifers.  The few
cases where high lead values were found in the underlying layers
do indicate that before porous paving is used for recharge of
aquifers by percolation information must be obtained on the ability
of soils to remove lead from leachates.
Wet Skid Resistance—
     A modification of the locked wheel test was used to deter-
mine the coefficient of sliding friction between a standard
passenger vehicle tire (size 6.50 x 13) and the test pavements,
both wet and dry.  In the case of the porous pavement, tests were
made on a section of the original paving and on a repaired section.
Test results for three series are shown in Table 27,

	TABLE 27.  COEFFICIENT OF FRICTION
  Test  Date    Paving and Condition
                     Reaction Force
                          (Ibs)
             Coefficient
             of Sliding
             Friction  (u,)
   12-3-75
    2-5-76
  4-28-76
Old porous - dry
Old porous - wet
New porous - dry
New porous - wet
Standard - dry
Standard - wet

Old porous - dry
Old porous - wet
New porous - dry
New porous - wet
Standard - dry
Standard - wet

Old porous - dry
Old porous - wet
New porous - dry
New porous - wet
Standard - dry
Standard - wet
43.2
60.8
47.2
52.8
52.0
42.4

58.4
68.0
59.2
64.0
71.2
57.6

52.5
60.0
57.0
60.0
55.5
51.0
.605
.851
.661
.739
.728
.594

.818
.952
.829
.896
.997
.806

.735
.840
.798
.840
.777
.714
                            1 Ib . = .138 nt
                               125

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    TABLE 28.  SUMMARY OF STORMWATER QUALITY FOR POROUS
              PAVEMENT STORM ON 2/20/76
Conventional

1
Constituent
pH
Sp . Cond .
Soluble COD
SOC
TKN
NH3
NO3
N02
TP
ortho P
Pb
Zn

Gravel
X
8.1
457
35.
15.
2.5
1.5
.12
.014
.10
.06
.05
.18
Porous
Layer
s
0.2
14.
5.8
4.4
.42
.41
.14
.017
.02
.02
.03
.39
Pavement
Sand
3c
8.0
542
35.
13.
2.7
1.33
.03
.004
.50
.48
.03
.27
Layer
s
.04
12.
3.7
2.8
.46
.28
.01
.002
.08
.06
.01
.18
Pavement Runoff

x
7.8
108
60.
30.
1.2
.15
.36
.013
.11
.06
.31
.34

s
.23
54.
35.
16.
.42
.09
.17
.009
.04
.02
.43
.21
              n = 11
                                n = 11
n = 10
  all measurements in mg/1 except
  specific conductance in
2  _
                                   in pH units and
  = mean

s = standard deviation

n = number of samples
                            126

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    In most cases the standard,  dense paving exhibited dry skid
resistance better than or equal to the two porous pavements.  The
reverse was true when wet paving was tested with the porous pave-
ments being clearly superior.  For standard pavement, the coef-
ficient of friction under wet conditions was, as expected, lower
than under dry conditions.  However, a consistent behavior pat-
tern for the porous pavements, for which there is currently no
verified explanation, is the increase of the coefficient of
friction on wet pavement over that on the dry pavement.  One
possible explanation is that in the case of the wetted pavement
surface dust layers have been washed through the pavement and
the rougher surface .then comes into full play.

Noise Levels

     Traffic noise levels  (Table 29) were determined using two
different vehicles, both equipped with standard steel belted
radial tires.  Measurements were made early  in the morning to
avoid external noise interference.
                     TABLE  29.  NOISE LEVELS   1 mi = 1.6 km	
  paving
Vehicle
Speed (mph)
Noise Level!(dB)
Old porous
New porous
Standard
Old porous
New porous
Standard
Old porous
New porous
Standard
1
1
1
2
2
2
2
2
2
15
15
15
15
15
15
20
20
20
A62
A57
A64
B68
B68
B71
B69
B69
B73
     The porous pavings are less noisy than standard paving.

     1 A scale consistent with human ear.  B scale filters to
       accentuate lower frequency sound.
Porosity

     In situ porosity was determined on the porous pavements_by
grouting in place a 6 in. diameter tube having two scribed lines
5 in. apart.  Water was placed in the tube and the time required
for the water level to pass the marks was measured.  Results are
calculated in in./sec of water transmission.  The section of new
porous pavement gave the best water transmission than that in the
original pavement.  Water transmission rates in the new pavement
were normally 0.55 in./sec  (1.4 cm/sec) while the original sec-
tions exhibited a normal porosity of 0.38 in./sec  (0.96 cm/sec).
Sections of original paving were found to be clogged.  These sec-


                                127

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tions were primarily near the curb or near the curbing at the
upper side of the lot opposite the curb.  The clogging near the
curb resulted from mud and dirt from the wheels; of contractors'
trucks, while the clogging of the upper lot was; chiefly from
cement dust from curb construction and find sand and silt washed
from the grass plot before the grass gave adequate cover.  The
partially clogged or completely clogged areas were marked for
studies of cleanability.

Cleaning and Maintenance

     It was recognized early in the program that maintenance and
cleaning of porous pavement to prevent or alleviate clogging
would be a factor in the application of such peivements.  Sections
of the porous pavement which were clogged were cleaned by various
methods.  No method was satisfactory on fully clogged pavement
and only a superficially clogged section, showing a water penetra-
tion of 0.38 in/sec  (0.96 cm/sec), could be restored to normal
operation.  The best method for cleaning was brush and vacuum
sweeping followed by high pressure water washing of the pavement.
Vacuum cleaning alone, once the pavement is clogged, was found to
have no effect.  The oils in the asphalt bind c'.irt and only
abrading and washing techniques are effective in removal.  By
removing fractional thicknesses of paving, it was observed
the clogging to a depth of 0.5 in  (1.3 cm) was sufficient to
prevent water penetration.

     Damage to pavement porosity results chiefly from abuse dur-
ing the early life of the paving.  Normally, pa.ving is carried
out while heavy construction and earth moving is continuing in
the area and is subjected to mud and dirt from contractor ve-
hicles for up to several months.  Continual passage of these
vehicles serves to compact dirt into the pores.  Porosity can be
retained only if the paving is cleaned daily by sweeping and high
pressure water washing.

     Once a large area of porous pavement is fully clogged it
cannot be adequately cleaned and the paving must be removed to a
depth where the clogging is not evident and new porous paving
filled in.  In extreme cases, the affected area of the porous
topping must be removed and new topping put down.

     Both the standard and porous pavements showed signs of the
effect of heavy vehicle passage and of power steering damage.
Heavy vehicles tended to leave tire depressions in either lot on
hot days while power steering damage was evidenced by small cir-
cular depressions in the lot surface.  The latter damage occurs
when wheels are turned when a vehicle is not in motion.  The use
of a lower penetration asphalt for pavements should offset the
damage to paving in warm climates.
                               128

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 Pavement Deflection

     Pavement deflections  in porous and  standard  surface  lots
 were measured on  four different occasions.  Measurements  were
 made of pavement  acceleration  and time duration of acceleration
 as  it deflected on passage of  the test vehicle.   Test results
 indicate there are no real differences in the magnitude of the
 deflections, but  the time  duration of the deflection was  always
 longer for the porous pavement than for  the standard pavement
 with correspondingly lower "g" levels.   This long response may be
 responsible for the lessened tire noise  observed  in the sound
 level tests.

 Pavement Survey

     Visits were  made to four  locations  where porous paving is in
 use.  The locations at the University of Delaware, Newark, Dela-
 ware, Bryn Mawr Hospital,  Bryn Mawr, Pennsylvania, and at The
 Marine Sciences Consortium, Lewes, Delaware  were in good con-
 dition with little or no indication of pavement clogging.  The
 paving at a Travelodge in  Tampa, Florida showed considerable
 clogging from sand and silt caused by passage of  trucks on the
 nearby road and inadequate curbing to prevent surrounding soil
 from washing onto the lot.  Degradation  of the surface was evi-
 dent in the form  of patches of loose stone and gravel.

     It is evident from the damage at the Tampa lot and in the
 lot at The Woodlands that  a lower penetration asphalt should be
 used in the topping, especially in warm  areas.  Again, it is felt
 that clogging can be minimized by proper use of curbing to pre-
 vent surrounding  soil from washing onto  the lot surface.  Recent
 installation of porous paving  at The Franklin Institute parking
 lot in Philadelphia, Pennsylvania has further pointed up  the need
 for close control of contractor vehicles on a newly installed
 lot.  It was necessary to  sweep away caked mud from vehicle
 wheels and then wash the affected area with high pressure water.

 Traffic Paint Visibility

     Two colors of traffic paint,  white and yellow,  with and
 without addition of glass beads,  were applied to the pavements.
 They were photographed under equal incident lighting intensities
 at night'under wet and dry conditions and the reflected light in-
 tensity was determined from image densities on the negatives.
 The white marking paint showed a slight superiority in visibility
 over the yellow whether or not glass beads were added.  No real
 difference in the reflected light intensity from either pavement,
wet or dry,  was evident.   The test,  however,  did not evaluate
 glare from oncoming vehicle lights which may obscure reflected
 light from paint on a wet,  non-porous pavement.
                               129

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  1.


  2.


  3.
                             REFERENCES
Field, Richard, and Pauline Weigel.  Urban Runoff and Com-
bined Sewer Overflow.   JWPCF, 6,: 1108, 1973.

Wolman, M. G., and A. P. Schick.  Effects of Construction on
Fluvial Sediment, Urban and Suburban Areas of Maryland.
Water Resources Research, _3_: 451, 1967.

Guy, H. P., and G. E. Ferguson.  Sediment in Small Reser-
voirs Due to Urbanization.  j. Hydraulic Div., ASCE, 88,
HY2; 27, 1962.                                       	
  4.  Anderson,  D.  W.,  and S.  D.  Faust.   Changes in Quality of
     Water in the  passaic River  at Little Falls,  New Jersey.
     USGS  Professional Paper  525-D,  1965.

  5.  Geldreich,  E. E.,  L. C.  Best,  B. A.  Keener,'and O.  J.  Van
     Donsel.   The  Bacteriological Aspects of Storm Water Pollu-
     tion.  JWPCF, 40;  1861,  1968.

  6.  Storm and Combined Sewer Overflows Section,   Environmental
     Impact of Highway Deicing,   U.S. EPA Report  #  11040GKK06/71.,.
     1971


  7.  Bryan, E. H.   Quality of Stormwater  Drainage 'from Urban
     Land.  Paper  presented at 7th American  Water  Resources Con-
     ference, Washington,  D. C.,  1971.

  8.  Heaney,  J.  p., and R.  H. Sullivan.   Source Control  of Urban
     Water Pollution.  JWPCF, 43: 571, 1971.

  9.  Sartor,  J.D.  and  G.B.  Boyd.   Water  Pollution Aspects of
     Street Surface Contaminants. U.S. EPA Report # EPA-R2-72-081,
     1972.

10.  Claudon,  D. G., D. I.  Thompson, E. H. Christenson,.  G. W.
     Lawton, and E. C. Dick.  Prolonged Salmonella Contamination
     of a Recreational Lake by Runoff Waters, Appl. Microbiol.,
     21. (5): 875-877, May,  1971.

11.  Tafuri, Anthony N.  Pollution from Urban Land Runoff.  News
     of Environmental Research in Cincinnati, U.S. Environmental
                               130

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      Protection Agency, Cincinnati, Ohio, April 11, 1975.

 12.  Harms, L. L., P. Middaugh, J. N. Dornbush, and.j. R. Ander-
      sen.  Bacteriological Quality of Surface Runoff from Agri-
      culture Land - Part II.  Water and Sew. Works, 122  (11)-
      71-73, November, 1975.                         ~r~~~

 13.  Harms, L. L., P. Middaugh, J. N. Dornbush, and J. R. Ander-
      sen.  Agricultural Runoff Pollutes Surface Waters - Part I
      Water and Sew. Works,  122 (10): 84-85,  October, 1975.

 14.  Edmondson,  W. T.  Eutrophication in North America,  in:
      Eutrophication:  Causes,  Consequences,  Correctives,  Anon
      (ed.).  Proceedings of NAS-NRC Symposium,  Washington, D. C.,
      1969 -

 15.  Sylvester,  R. O.  An Engineering and Ecological Study for
      the Rehabilitation of Green  Lake.  University of Washington
      Seattle,  Washington,  I960.                     '            '

 16.  Hasler, A.  W.  Eutrophication of Lakes  by  Domestic Drainacre
      Ecology,  28;  383,  1947.

 17.  Biggar, j.  w,,  and R.  B.  Corey.   Agricultural Drainage and
      Eutrophication.   In:   Eutrophication:   Causes,  Consequences
      Correctives,  Anon (ed.).   proceedings of NAS-NRC  Symposium,
      Washington, p.  c.,  1969.                                  *

 18.  Cooper, C.  P.   Nutrient Output  from Managed Forests.   In:
      Eutrophication  Causes, Consequences, Correctives, Anon (ed  )
      proceedings of  NAS-NRC Symposium, Washington, p.  C.,  1969.

 19.   Jackson, D. P.,  and H. F.  A. Meier.  Variations  in Summer
      Phytoplankton Populations  of Skaneateles Lakes, New York
     Assoc. Theor. Appl. Liranol., proa.,  16: 173,  1966.

 20.   palmer, M. C.  Algae in Water Supplies of  the United  States
      In:  Algae and Man, Jackson, D, F.  (ed.).  Plenum press.
     New York, 1964.

 21.  Schwimmer, D., and M.  Schwimmer.  Algae and Medicine,  in-
     Algae and Man, Jackson, D. F,  (ed.), Plenum Press, New York,
22.  Rose, E. T.  Toxic Algae in Iowa Lakes.  Iowa Acad. Sci
     Proc., 60.: 738, 1953.                                   '

23.  Olson, T. A.  Water Poisoning - A Study of Poisonous Algae
     Blooms in Minnesota.  Am. J. Health, 50: 883, ij.960.

24.  Moore, G.. T., and K. F. Kellerman.  A Method of Destroying
     or Preventing the Growth of Algae and Certain Pathogenic

                               131

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25.



26.




27.


28.



29.


30.



31.




32.




33.




34.



35.



36.
 Bacteria in Water  Supplies.  US.DA Bureau Plant Indus-
 tries  Bulletin  64,  1904.

 Anon (ed.).   Eutrophication:  Causes, Consequences, Cor-
 rectives.   Proceedings  of NAS-NRC Symposium, Washington,
 D.  C.,  1969.

 Kerr,  P.  C.,  et al_.  The Interrelation of Carbon and Phos-
 phorous in  Regulating Heterotrophic and Autotrophic Popula-
 tions  in Aquatic Ecosystems.  Proceedings of 25th1Purdue
 Industrial  Waste Conference, West Lafayette, Indiana, 1970.

 Keuntzel, L.  E.  Bacteria, Carbon Dioxide, and Algal Blooms.
 JWPCF,  41:  1737, 1969.

 Lee, F.   An Approach to the Assessment of the Role of Phos-
 phorous  in  Eutrophication.  Paper presented at American
 Chemical  Society, Los Angeles, California, 1970.
Shapiro, j.
1970.
A Statement on Phosphorous.  JWPCF, 42 ; 772,
American Chemical Society.
Chemical Basis for Action.
D. C., 1969.
               Cleaning Our Environment:  The
               Amer. Chem. Soc., Washington,
Poche, R. M.  A Baseline Census and Development of a Monitor-
ing System for Important Animal Species on the Proposed
Woodlands Site,'Montgomery County, Texas.  Consultant's Re-
port to The Woodlands Development Corp., April, 1973.

Maestro, R.  Criteria for Residential Wildlife planning in
the New Community of The Woodlands, Montgomery County,
Texas.  Consultant's Report to The Woodlands Development
Corp., Mary, 1973.

Hass, R. H., and M. C. McCaskill.  Use of Large-Scale
Aerial Photography in Obtaining Vegetation Information for
Urban Planning.  Consultant's Report to The Woodlands Deve-
lopment Corp., July, 1972.

Kendrick, W. W., and D. Williams.  Soil Survey of The Wood-
lands.  Consultant's Report to The Woodlands Development
Corp., July, 1973.

Water Resources Data for Texas,  part 1 Surface Water Re-
cords, 1973 and 1974.  U.S. Dept. of the Interior publica-
tion, prepared in cooperation with the State of Texas.

Winslow, D. E., J. A. Veltman, and W. H. Espey, Jr.  Natural
Drainage Systems.  Paper presented at Spring Session of the
Texas Section of the ASCE, Beaumont, Texas,  March 29, 1974.
                               132

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37.  Dugan, G. L., and P. H. McGauhey.  Protecting Our Lakes:
     Wastewater Treatment is Not Enough.  Paper presented at
     46th Annual Conference of W.p.c.F., Cleveland, Ohio,
     September 30-October 5, 1973.

38.  Schicht, R. j., and p. A. Huff,  The Effects of Precipita-
     tion Scavenging of Airborne and Surface Pollutants on Sur-
     face and Groundwater Quality in Urban Areas. , Part II.
     NSF # GK-38329, National Science Foundation, Engineering
     Division, Washington, D. C., July, 197$.

39.  Whitehead, L. W.  Some Microclimate and Air Quality Impli-
     cations of Urbanization in a Southern Coastal Forest.  Dis-
     sertation, University of Texas School of Public Health,
     Houston, Texas, 1976*

40.  Ward,  C.H.,  and J. King. "Eutrophication Potential of Surface
     Waters in a Developing Community, " Draft Final Report fpr
     Maximum Utilization of Water Resources in a Planned Community,
     EPA Research Grant #802433, October,  1976.
41.
42.
43.
44.
45.
46.
47.
     MacEntee,  F. J.  A Preliminary Investigation of the Soil
     Algae of Northeastern Pennsylvania.  Soil Sci., 110s 313-
     317,  1970.                                      - ".

     Hofstetter,  A. M.  A Preliminary Report of the Algal Flora
     from Selected Areas of Shelby County.  Jour. Tenn. Acad. of
     Sci., 43;  20-21,  1968.

     MacEntee,  F. J.,  G. Schreckenberg,  and H. C. Bold.  Some
     Observations on the Distribution of Edaphic Algae.  Soil
     Sci., 114; 717-719, 1972.

     Olivieri,  V.,  C.  Kruse,  K.  Kawata,  J. Smith.  "Microorganisms
     in Urban Stormwater, " EPA^600/2-77-087,  MERL,  Cincinnati,
     July, 1977.

     Diniz,  E.  V. and  W. H. Espey,  Jr.  "Maximum Utilization  of
     Water Resources in a Planned  Community;  Application of  the
     Storm Water  Management Model:   Volume I,"  EPA-600/2-79-050c,  1979.

     Metcalf & Eddy,  Inc.,  et al.,  Storm Water Management Model,  in
     four  volumes,   "Final Report," (Vol. I:  USEPA Report No. 11024
     DOC 07/71, p.  352);  "Verification and Testing," (Vol.  II:
     USEPA Report No.  11024 DOC  8/71,  p. 172;)  "Users Manual,"
     (Vol. Ill: USEPA Report  No. 11024 DOC 10/71,  p. 249).

     U.S.  Corps of Engineers. Urban Runoff:  .Storage and Treatment
     and Overflow Model "STORM." Hydrologic Engineering Center
     Computer Program 723-58-L2520,  U.S. Army,  Davis,  California,
     May,  1974.                                           ^
                               133

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48.  Nash, J. G.  The Form of the Instantaneous Unit Hydrograph.
     Int. Assoc. of Sc. Hydrol., Pub. 45, Vol. 3_: 114-121, 1957.

49.  Horton, R. E.  An Approach Towards a Physical Interpretation
     of Infiltration Capacity.  Soil Sc. Soc. of America, Proc.,
     5.: 399-417, 1940.

50.  McKee, J. E., and H. W. Wolf.  Water Quality Criteria.
     May, 1963.

51.  Davis, Ernst.  "Microbiological Quality of Stormwater Runoff
     in The Woodlands," Draft Final Report for Maximum Utilization
     of Water Resources in a Planned Community, EPA Research
     Grant #802433, October, 1976.

52.  Report of the Commission on Water Quality Criteria.  FWPCA,
     April, 1968.

53.  Texas Water Quality Standards.  Texas Water Quality  Board,
     Austin, Texas, February, 1976.

54.  Bender, R. J.  Ozonation, Next Step to Water purification.
     Power, 114  (8):  58-60, August, 1970 (Abs.).

55.  Glover, G.E. and Herbert, G.R.  Microstaining and Disinfection
     of Combined Sewer Overflows.  U.S.  EPA Report f 11023EVO
     06/70, June, 1970.

56.  Moffa, P.E., et  al. Bench-Scale High-Rate Disinfection of
     Combined Sewer Overflows:  With Chlorine and Chlorine
     Dioxide.  U.S. EPA Report #670/2-75-021, June, 1970.

57.  Davis, E.M., L.W. Whiteheard, and J.D. Moore.  Disinfection.
     Jour. Water Poll. Control Fedn., 46  (6): 1181-1191,
     June,  1974.

58.  Davis, E.M., J.D. Moore, D.  Casserly, J. Petros, and W.
     DiPietro.  Disinfection.  Jour. Water Poll. Control  Fedn.,
     47^  (6): 1323-1334, June, 1975.

59.  Horton, R.K.  Aquatic  Life Water Quality Criteria.   Envirn.
     Sci.  and Tech.,  11; 888, 1967.

60.  Tsai,  Chu-fa.  Effects of Chlorinated Sewage Effluents on
     Fish in Upper Patument River, Maryland.  Chesapeake  Sci. 9,
     2_:  83,  1968.

61.  Arthur, J.W., and J.G. Eaton.  Chloramine Toxicity  to the
     Amphiphod,  Gammarus Pseudolimneaus  and  the  Fathead Minnow,
     Pimepephales promelas. Jour.  Fish  Res.  Bd.  Can., 28: 1841,
     1971.
                                134

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62'
          Los Angeles,  California,  June 27-28,  1972
                           135

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
  REPORT NO.
 EPA-600/2-79-050a
                                                           3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
MAXIMUM UTILIZATION OF WATER RESOURCES IN A PLANNED
COMMUNITY
Executive Summary
             5. REPORT DATE
              July 1979  (Issuing Date)
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 William G. Characklis, Frank J.  Gaudet, Frank L. Roe,
 and Philip B. Bedient                            	
                                                           8. PERFORMING ORGANIZATION REPORT NO.
 I. PERFORMING ORGANIZATION NAME AND ADDRESS
 Department of Environmental  Science & Engineering
 Rice University
 P.O. Box 1892
 Houston, Texas  77001
             1O. PROGRAM ELEMENT NO.
              1BC822      SOS 2    Task 02
             11. CONTRACT/GRANT NO.
                        802433
12. SPONSORING AGENCY NAME AND ADDRESS
Municipal Environmental  Research Laboratory—Gin, OH
Office of Research and Development
U.S. Environmental Protection Agency
Cincinnati, Ohio  45268
             13. TYPE OF REPORT AND PERIOD COVERED
              Final       7/73-12/76
             14. SPONSORING AGENCY CODE
                       EPA/600/14
15. SUPPLEMENTARY NOTES one  in a series of volumes of one report.   Project Officers:
 Richard Field and Anthony N.  Tafuri, Storm and Combined  Sewer Section, FTS 340-6674,
 (201) 321-6674	'	
16. ABSTRACTgtormwater £rom four watersheds in the Houston  area was monitored over a three
year period.  Land use in the watershed included undeveloped forest, developing forest,
iully-developed residential and mixed commercial-residential.
Chemical parameters monitored included suspended solids,  oxygen demand, organic carbon,
 .itrogen, phosphorous, dissolved oxygen, pH, specific conductance and chlorinated hydro-
carbons.  Indicator and pathogenic bacterial species  were enumerated as well as aquatic
and edaphic algae species.  Disinfectant demand and algal bioassays were also conducted.

Relationships have been developed between stormwater  runoff quality, quantity and4land
use in an effort  to predict pollutant loads.  The  appearance of a "first flush"' is depen
dent on the parameter  measured and watershed characteristics.  Rainwater quality contri-
mtes significantly to stormwater pollutant loads, especially in urbanized areas.  Modi-
Eying effects of  natural biological processes on nitrogen content in the runoff and  ef-
fects of the hydrological regime on nutrient limitations  were observed.  The effective-
less of storage lakes, very positive in the case of suspended solids, were also observed
Ehe Storm Water Management Model (SWMM) was modified  to describe the processes occurring
in the watersheds and  allowed for (1) separate sewer  systems, (2) effects of urbaniza-
tion on base flows,  (3) performance efficiency and cost effectiveness of natural drain-
age systems,  (4)  four  additional water quality parameters (COD, Kjeldahl nitrogen,
 vibrates, phosphates), (5) hyduologie effects  of
17.
                                KEY WORDS AND DOCUMENT ANALYSIS
a.
                  DESCRIPTORS
                                              b.lDENTIFIERS/OPEN ENDED TERMS
                           c. COSATI Field/Group
 Water quality,  Pesticides, Pavements,
 Disinfection, Urbanization, Chemical
 analysis
Demonstration watersheds,
Hydrologic data, Hydrologi
models, Overland flow,
Fish toxins, Eutrophicatioi
Water sampling, Porous  pav J
nent, The Woodlands,  Storm
Water Management Model
13B
 18. DISTRIBUTION STATEMENT


           RELEASE  TO PUBLIC
19. SECURITY CLASS (ThisReport)

       TTNfTLASSTFIED
                                                                         21. NO. OF PAG.ES
150
20. SECURITY CLASS (Thispage)

       UNCLASSIFIED
                           22. PRICE
 EPA Form 2220-1 (Rev. 4-77)
                                            136
                                                                  4 U.S. GOVERNMENT PBINIINO OFFICE: 1080 -657-060/5430

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