EPA-600/2-80-148
                                             August 1980
EFFECT OF PRETREATMENT ON THE FILTRATION OF
      LOW TURBIDITY SECONDARY EFFLUENT
                      by
                Leon S. Directo
                 Ching-lin Chen
                Robert P. Miele
  Los Angeles County Sanitation Districts
         Whittier, California 90607
           Contract No. 14-12-150
              Project Officer

             Irwin J. Kugelman
        Wastewater Research Division
Municipal Environmental Research Laboratory
         Cincinnati, Ohio 45268
MUNICIPAL ENVIRONMENTAL RESEARCH LABORATORY
     OFFICE OF RESEARCH AND DEVELOPMENT
   U.S. ENVIRONMENTAL PROTECTION AGENCY
         CINCINNATI, OHIO 45268

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                                 DISCLAIMER
     This report has been reviewed by the Municipal Environmental Research
Laboratory, U.S. Environmental Protection Agency, and approved for
publication.  Approval does not signify that the contents necessarily
reflect the views and policies of the U.S. Environmental Protection Agency,
nor does mention of trade names or commercial products constitute endorsement
or recommendation for use.

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                                  FOREWORD


     The Environmental Protection Agency was created because of increasing
public and government concern about the dangers of pollution to the health
and welfare of the American people.  Noxious air, foul  water, and spoiled
land are tragic testimony to the deterioration of our natural environment.
The complexity of that environment and the interplay between its components
require a concentrated and integrated attack on the problem.

     Research and development is that necessary first step in problem
solution and it involves defining the problem, measuring its impact, and
searching for solutions.  The Municipal Environmental Research Laboratory
develops new and improved technology and systems for the prevention, treat-
ment, and management of wastewater and solid and hazardous waste pollutant
discharges from municipal and community sources, for the preservation and
treatment of public drinking water supplies, and for minimizing the adverse
economic, social, health, and aesthetic effects of pollution.  This publi-
cation is one of the products of that research; a most vital communications
link between the researcher and the user community.

     Removal of residual suspended solids after biological treatment is one
of the proven procedures for upgrading wastewater treatment plant performance.
This report details studies on filtration of secondary effluent after either
conventional coagulation flocculation sedimentation or in-line coagulation.
                                          Francis T. Mayo, Director
                                          Municipal Environmental Research
                                          Laboratory

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                               ABSTRACT
     A 17-month pilot plant study dealing with inert media filtration of an
activated sludge plant effluent was conducted at Pomona, California, under
the auspices of the U.S. Environmental Protection Agency and the Los Angeles
County Sanitation Districts.  The pilot plant consisted of two pressure fil-
ters operated at surface loading rates of 3.4 1/sec/m2 (5 gpm/ft2) and 6.8
1/sec/m2 (10 gpm/ft2).  During the study, two types of filter media configu-
rations were evaluated; namely, a specially designed dual-media filter and
a Neptune Microfloc, Inc., mixed-media filter.  Two types of filter pretreat-
ment schemes were evaluated.  The first scheme was a conventional chemical
coagulation-sedimentation system and the second scheme was an in-line coagu-
lation system.  In both pretreatment schemes, alum and polymer were used.

     The primary objectives of the study were to evaluate the relative effec-
tiveness of the two types of pretreatment schemes on the performance of mul-
timedia pressure filters in the removal of turbidity, suspended solids, and
other associated pollutants from an activated sludge plant effluent.

     The comparative evaluation of the dual-media and the mixed-media pres-
sure filters showed that the turbidity removal performance was essentially
the same in both types of filters.  The headloss levels across the mixed-
media filter, however, were consistently higher than those observed in the
dual media filter.

     The study demonstrated that for a low turbidity secondary effluent, an
in-line coagulation pretreatment is feasible and results in significantly
lower overall capital and operating costs than that of a conventional chemi-
cal coagulation-sedimentation pretreatment system.  Moreover, it was ob-
served from a limited filtration data that without chemical addition, the
resulting filter effluent turbidity levels were comparable to those ob-
tained in filters with an inline coagulation pretreatment system operated
at optimum doses of alum and polymer.  The lengths of filter run with an
in-line coagulation pretreatment were consistently shorter than those ob-
served without chemical addition or with a chemical coagulation-sedimenta-
tion pretreatment.  It should be pointed out, however, that the effluent
discharge requirements of California mandates the addition of chemical
prior to filtration.  This, therefore, precludes the operation of the fil-
ters without some semblance of chemical pretreatment.

      This  report was  submitted in fulfillment of Contract  No.  14-12-150
by the Los  Angeles Sanitation Districts .under the sponsorship  of  the  U.S.
Environmental  Protection Agency.
                                       IV

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                                 CONTENTS
Foreword	    ^            1-1-1-
Abstract  	  ..........        	iv
Figures	!!.'."."!!''"	vi
Tables .  .  .  .	.  „  .	viii
Acknowledgments.	....!.'   ix

     1.   Introduction	   1
     2.   Conclusions . ,	..I.*.'!!!!   2
     3.   Recommendations . .	!.'•."!!!!!.'!!   4
     4.   Experimental Program	..............' 5
            Pilot Plant Description and Operation   	  ......   5
            Sampling and Testing Program  ... 	  '   10
     5.   Discussion of Experimental Results	       '  '  "   12
            Phase I Test Results	'.."*'*   13
            Phase II Test Results.	20
            Phase III Test Results	   50
     6.   Economic Analysis	!.'!.'!.'   67

References	   73

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                                   FIGURES
Number                                                                    'ฃงS
  1  Schematic flow diagrams of filter pretreatment schemes .......  .   ~6
  2  Pressure filter detail with dual-media ................    8
  3  Pressure filter detail with mixed-media ,  ..............    9
  4  Effect of type of auxiliary backwash on headless  ........  .  .   18
  5  Effect of alum and polymer addition on headless ...........   19
  6  Effect of alum addition on headless .................   21
  7  Performance of filters with chemical coagulation-
     sedimentation pretreatment  ........... • .........   24
  8  Effect of alum dose on turbidity removal with non-nitrified
     secondary effluent feed    ....... ...............  21
  9  Effect of alum dose on turbidity removal with nitrified
     secondary effluent feed  ............... ...... •  •  35
 10  Dual -media filter performance with 110 mg/1 alum and 0.2
     mg/1  polymer in the clarification system   ...... ...... •  •  38
 11  Dual-media filter performance with 155 mg/1 alum and 0.2
     mg/1  polymer in the clarification system   .....  . .  .......  39
 12  Dual -media filter performance with 225 mg/1 alum and 0.2
     mg/1  polymer in the clarification system   ..............  40
 13  Effect of alum dose in the clarification system on the
     dual-media filter performance  ................  ....  42
 14  Dual -media filter performance with in-line coagulation
     pretreatment .................  ............  43
 15  Effect of  alum dose  in the in-line coagulation system on
     the dual -media filter performance  ...............  •  •  •  44
 16  Dual -media  filter  performance with direct  cationic  polymer
      injection  ......... .  ....................  46
                                      vi

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                             FIGURES (Cont'd)
Number
                                                                          Paqe
 17  Effect of cationic polymer dose on the dual-media filter
     performance	     47
 18  Effect of high alum and  polymer doses  on  the dual-media
     filter performance 	'
 19  Turbidity removal  through the filter with  Scheme A  pre-
     treatment  	
 20  Turbidity removal  through  the  filter  with  Scheme  B  pre-
     treatment  .  .	
 21   Turbidity  removal  through  the  filter with Scheme C  pre-
     treatment   ....  	
 22   Frequency distributions of filter  influent and effluent
     turbidity levels    	
 23   Frequency distributions of filter influent and effluent
     suspended solids levels 	
 24  Correlation between filter influent and effluent suspended
    solids	f

 25  Correlation between filter influent and effluent turbidities  .

 26  Correlation between filter influent suspended solids and
    headloss	
27  Effect of pretreatment on headloss  ...

28  Frequency distribution of filter headloss
 48



 54



 56



 57



 58



 59





62



62

65

66
29  Schematic diagram of proposed tertiary filtration system  ......   70
                                    vn

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                                  TABLES
Number
Page
  1  Filter Media Specifications ...................   11
  2  Dual -Media Filter Performance with Direct Chemical
     Injection (without auxiliary mixing)  ...... ........   14
  3  Effect of Chemical Injection and Backwash on Dual -Media
     Filter Performance  .......................   16
  4  Dual -Media Filter Performance with Direct Chemical
     Injection (with static mixer)   ........... . .....   22
  5  Dual-Media Filter Performance with Coagulation-Sedimentation
     Pretreatment  .......... ................   35
  6  Summary of Filter Performance with Scheme A Pretreatment
  7  Summary of Filter Performance with Scheme B Pretreatment
  8  Summary of Filter Performance with Scheme C Pretreatment
  9  Filtration System Design Data	
 10  Unit Costs for Operation and Maintenance Estimate  .  .  .  .
 11  Estimated Filtration System Costs  .  	  •  •  •
 51
 52
 53
 68
 69
 71
                                    vm

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                              ACKNOWLEDGMENTS

     This project was undertaken through a cooperative effort of the U.S.
Environmental Protection Agency and the Los Angeles County Sanitation
Districts.  The pilot plant evaluation was conducted at the Sanitation
Districts' Advanced Waste Treatment Research Facility in Pomona, California,

     The untiring efforts and assistance of both the Laboratory and the
pilot plant operating personnel of the Pomona Advanced Waste Treatment
Research Facility are gratefully acknowledged.
                                   IX

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                                  SECTION 1

                                 INTRODUCTION
     In recent years there has been a growing interest in wastewater filtra-
tion largely because of the need to meet the increasingly more stringent
effluent discharge standards.  For instance, some effluent discharge stand-
ards now require limit not only on coliforms but also on viruses (1,2).  It
is generally recognized, however, that in order to achieve an effective bac-
terial and/or viral kill, the wastewater effluent stream must be essentially
free of suspended matter prior to the terminal disinfection step.  There-
fore, some form of filtration must follow the secondary treatment process.
Moreover, the filtration step is usually preceded by a suitable pretreat-
ment in order to bring about more effective suspended solids removal.

     Although there are a number of filtration processes possible, the in-
ert media filtration process was evaluated in the current study.  In the
course pf the pilot plant study, two types of inert media filter configura-
tions were evaluated; namely, a specially designed dual-media filter and a
mixed-media filter specified by Neptune-Microfloc, Inc.  Two types of fil-
ter pretreatment schemes were evaluated.  The first scheme (Scheme A) was
a conventional chemical coagulation-sedimentation system and the second
scheme (Scheme B for non-nitrified effluent feedwater and Scheme C for
nitrified effluent feedwater) was the direct chemical injection of polymer
or alum and polymer.  The latter pretreatment scheme is referred to in
this report as in-line coagulation.  In addition, some runs with plain fil-
tration were conducted.

     The data presented in this report cover the results of seventeen months
of pilot plant study.  The pilot plant study, which was a joint undertaking
by the Los Angeles County Sanitation Districts and the Environmental
Protection Agency, was conducted at the Districts' Advanced Waste Treatment
Research Facility in Pomona, California.

     The primary objective of the study was to evaluate the relative effec-
tiveness of two different pretreatment schemes;  namely, in-line coagulation
and chemical  coagulation-sedimentation on the performance of multi-media
pressure filters in the removal  of turbidity, suspended solids, and other
associated pollutants from an activated sludge plant effluent.   In this
study, turbidity removal  and headless were used  as the principal parameters
for evaluating the filter performance.

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                                  SECTION 2

                                 CONCLUSIONS
     1.  For low-turbidity secondary effluent, such as that obtained in
Pomona, an in-line coagulation pretreatment is feasible and results in sig-
nificantly lower overall capital and operating costs than that of a conven-
tional chemical coagulation-sedimentation pretreatment system.  With an in-
line coagulation pretreatment, 'however, it is very important to provide the
necessary instrumentation to automatically adjust the chemical dosage in re-
sponse to the diurnal flow variations as the filter performance was very
sensitive to alum dose.

     2.  From limited filtration data, it was observed that without chemical
addition, filter performance was essentially the same at filtration rates of
3.4 1/sec/m2 (5 gpm/ft2) and 6.8 1/sec/m2 (10 gpm/ft2).  Moreover, the ob-
served filter effluent turbidity levels were comparable to those obtained in
filteTs with an in-line coagulation pretreatment system using the optimum
dose of alum and polymer.

     3.  With both in-line coagulation and chemical coagulation-sedimentation
pretreatments, the headless levels through the filters were higher at higher
concentration of polymer filter aid.  This observation suggests that while
the use of polymer filter aid is desirable in enhancing the attachment of
solids on the media surface thereby precluding premature solids breakthrough,
higher levels of polymers could cause rapid headless buildup across the filter.

     4.  Of the two filter backwash auxiliaries evaluated, surface wash and
air scours the latter proved to be more effective in cleaning the filter bed.

     5.  The results of the comparative evaluation of the dual-media and
mixed-media filters showed that the turbidity removal performance was essen-
tially the same in both types of inert media filters.  The headless levels
through the mixed-media filters, however, were consistently higher than those
observed in the dual-media filter.

     6.  During the long-term filter evaluation, the chemical coagulation
system (Scheme A) was operated at an alum dose of 150 mg/1 and an anionic
polymer dose of 0.2 mg/1.  At this dosage in the pretreatment system, the
average removal efficiency through the filter was 90.6 percent for suspected
solids and 83.3 percent for turbidity.  This corresponds to an average filter
effluent suspended solids and turbidity of 1.3 mg/1 and 0.7 FTU, respectively.

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Total phosphate was reduced about 89 percent, resulting in a filter effluent
with total phosphate concentration of 0.9 mg/1.  Total COD and color were re-
duced 48 percent and 38 percent9 respectively.

     7.  The optimum chemical dosage in the in-line coagulation pretreatment
system (Schemes B and C) was 5.5 mg/1 alum and 0.06 mg/1 anionic polymer.
At this dosage, the filter removed 80 percent of the suspended solids and
turbidity, resulting tn a filter effluent with an average suspended solids
of 2.7 mg/1 and turbidity of 1.2 FTU.                                  .

     8.  The estimated total treatment cost for a 379850 cu m/day (10 mgd)
dual-media filtration system is 4.02<ฃ/cu m (15.07^/1000 gallons) with
coagulation-sedimentation pretreatment and 2.19^/cu m (8*.2ฃ/1000 gallons)
with an in-line coagulation pretreatment.  Therefore, from economic and
operation point of view, filtration with an in-line coagulation pretreatment
system is the choice particularly for secondary effluents with low but ob-
jectionable concentrations of colloidal  and suspended materials.

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                             SECTION 3

                          RECOMMENDATIONS
1.
         In the filtration of secondary effluents with low but objectionable
concentrations of colloidal and suspended particles,  in-line coagulation  pre-
treatment should be considered thereby permitting an  appreciable reduction in
operating costs.  While this pretreatment process is  expected to permit the
filters to achieve the desired effluent quality objective, it is imperative
to have the necessary instrumentation to provide feedback control of the  re-
quired chemicals.

     2.  Batch coagulation tests (laboratory jar tests) may be used for the
preliminary screening of chemicals for filter pretreatment, especially in the  ,
filtration of secondary effluents with relatively high levels of suspended
solids.  For secondary effluents with low levels of suspended solids, however,
optimum chemical dosage is rather difficult to obtain by jar tests.  Conse-
quently, the final selection of the type and dosage of the pretreatment
chemicals should be obtained from pilot filtration experiments.

     3.  Additional work on plain filtration should be conducted.
                                 4 '


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                                   SECTION  4

                             EXPERIMENTAL PROGRAM
 PILOT  PLANT  DESCRIPTION AND  OPERATION

 Filter Pretreatment Schemes

     In Figure  1  are presented the schematic flow diagrams of the two types
 of  pretreatment schemes evaluated.  The first type, shown as Scheme A, is a
 conventional chemical  coagulation-sedimentation system.  The system con-
 sisted of  a  rapid mixing unit 0.76 m square (2.5 ft square) with 1.07 m (3,5
 ft)  liquid depth  followed by a three-compartment flocculation unit 1,37 m
 (4.5 ft) wide and 4.11 m (13.5 ft) long with 1.67 m (5.5 ft) liquid depth.
 The  flocculation  unit  was equipped with three variable speed paddle-type
 flocculators.   The secondary effluent was pumped at a constant rate of 3.47
 I/sec  (55  gpm)  to the  rapid mixing chamber where alum was added.  After 3
 minutes of rapid  mixing at 140 rpm, the coagulated secondary effluent flowed
 into the flocculation.unit where slow stirring for about 45 minutes was pro-
 vided.  An anionic polymer (Calgon WT-3000) at an average dosage of 0.2 mg/1
 was added  as a  coagulant aid to the first compartment of the flocculation
 unit.

     The flocculated secondary effluent flowed into a rectangular clarifier
 where  it was settled for about 92 minutes.  At the flow rate of 3.47 I/sec
 (55 gpm),  the clarifier overflow ratejmd weir rate were 44 cu m/day/.m2
 (1080  gpd/ft2)  and 1.91 1/sec/m (9.2 gpm/ft),  respectively.  The clarified
 effluent discharged into a 1.9 cu m (500 gallon) surge tank from which 3.16  .
 I/sec  (50 gpm) was pumped to the inert media pressure filters.  The excess
 clarified effluent flow was diverted to waste.   The chemical  sludge was
 withdrawn intermittently from the clarifier sludge hopper by means  of a
 timer-controlled  sludge pump.

     The second type of filter pretreatment is  shown as Scheme B or C in
 Figure 1.  Scheme B used feedwater from a conventional activated sludge plant
while Scheme C  used feedwater from a two-stage  nitrification  system.   Schemes
A and B used the same type of feedwater.   For  both Schemes  B  and C, a cylin-
 drical  mixing tank 0.61 m (2 ft)  diameter and  1.22 m (4 ft) high was  installed
ahead of the filters.   The mixing tank was provided with a  variable-speed
 propeller mixer.  Alum was injected into the secondary effluent line feeding
the mixing tank.  After 1.5 minutes rapid mixing the alum-coagulated  secon-
dary effluent was pumped to the filters.   An anionic polymer  filter aid
 (either Calgon WT-3000 or WT-2700)  was injected into the influent line of  each

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 filter.   This  second  pretreatment  scheme was  selected to determine the possi-
 bility of replacing the  conventional  coagulation-sedimentation system with a
 much  simpler in-line  coagulation system, which  if successful, could provide
 some  savings both  in  capital  investment and in  operating costs.

 Filtration System

      The  pilot plant  filtration study was  carried out using two identical
 76,2  cm (30 in.) diameter  pressure  filters shown in detail in Figures 2 and
 3.  Each  filter was provided  with an automatic  control panel with the capa-
 bility to  perform  four separate operating  sequences; namely, filtration, sur-
 face  wash,  air scour, and  water backwash.  The  duration of each operating
 step  was  field-adjustable  in  the range of  0 to  30 hours for filtration and 0
 to  30 minutes  each for surface wash, air scour, and water backwash.  The back-
 wash  sequence  was  triggered either  by a predetermined headloss level or dura-
 tion  of filter run.   During the entire period of filter evaluation, the fil-
 ters  were  operated in such a  way as to automatically backwash every 24 to 30
 hours of  filter run or whenever a 1.41 Kg/cm2 (20 psi) pressure drop was
 attained.   Two filter bed  cleaning  procedures were evaluated.  In the first
 two months  of  the  study, the  surface wash-waster backwash procedure was used.
 The backwash sequence consisted of  a surface wash at the rate of 1.7 1/sec/m2
 (2.5  gpm/ft2)  for  3 minutes followed by a water backwash of 13.6 1/sec/m2
 (20 gpm/ft2) for five minutes.  From the second through the fourth month of
 the study,  both surface wash  and air-assisted backwash procedures were
 evaluated.  Thereafter, the air scour-water backwash procedure was used.   In
 the air-assisted backwash, the filter backwash sequence consisted of an air
 scour at the rate  of 20.3  1/sec/m2  (4 scfm/ft2) for three minutes followed
 by a  water  backwash of 13.6 1/sec/m2 (20 gpm/ft2 for 5 minutes.

      In the course of the filter run, the influent and effluent turbidities
were  continuously monitored using in-line turbidimeters (Hach Model  1720 Low
 Range Turbidimeter) each equipped with a Rustrak recorder.

      In Figure 2 is shown the pressure filter detail  with dual-media config-
 uration.  The  filter media consisted of 61  cm (24 in.)  of anthracite coal
 (effective size of 1.1 mm and uniformity coefficient of 1.37)  over 30,5 cm
 (12 in.) of silica sand (effective size of 0.57 .mm and uniformity coefficient
of 1.2).  The  filter media were supported by a 50.8 cm (20  in.)  layer of
graded gravel.  In the design of the media, size range was  restricted,  as  in-
dicated by the low uniformity coefficient,  in  an effort to  provide as  uniform
a size as possible.  The literature on filtration indicate  that  more uniform
media size not only reduces the backwash water flow rate  required to fluidize
the coarser bottom layers of each component of the  filter media,  but also  may
have some beneficial  effect on the  filter performance.  The media cost, how-
ever,  will be  increased by the size restriction  specified.

     The mixed-media  filter,  shown  in detail  in  Figure  3, used a  configura-
tion specified by Neptune-Microfloc, Inc.   The media  consisted of 57.2  cm

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                           30"*
                                        SHOWER HEADS

                                        . —— INFLUENT
                                        1 —ป• BACKWASH
                                          SIGHT GLASS

                                          SURFACE WASH

                                          •SIGHT GLASS
          -  -^
    Q_J  4x6
    UJLU HANDHOLE
                                         12 - I   PERFORATED PVC
                                             PIPE LATERAL
                                              EFFLUENT
                                               I  =2.54 cm
                               AIR SCOUR
Figure 2.  Pressure  filter detail with dual-media.

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                            30"*
                                         SHOWER HEADS

                                         , •*- INFLUENT
                                         J -*• BACKWASH
                                           SIGHT GLASS

                                           SURFACE WASH

                                           SIGHT GLASS
                                                 PERFORATED PVC
                                             PIPE LATERAL
                                               EFFLUENT
                                                |s2.54cm
                               AIR SCOUR
Figure 3.  Pressure  filter  detail  with mixed-r media.

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 22.5 in.) of anthracite coal over 22.9 cm (9 in.) of silica sand and 11.4 cm
 .4.5 in.) of garnet sand.  The filter media were supported by a 7.6 cm (3 in.)
layer of coarse garnet sand support media and 43.2 cm (17 in.) layer of graded
gravel.  The filter media specifications for both dual-media and mixed-media
filters are presented in Table 1.

SAMPLING AND TESTING PROGRAM

     In this study, refrigerated 24-hour composite samples of influent and
effluent from each treatment unit of Schemes A, B, and C were automatically
collected five days a week using timer-controlled solenoid valves.   Starting
from the 9th month of the study, 16-hour composite samples were collected in-
stead of 24-hour composites.  This change in sampling duration was  necessary
in order to meet the sampling schedule of another project dealing with virus
removal.

     The composite samples were analyzed daily for suspended solids, tur-
bidity, color, and two to three times a week for total  chemical oxygen de-
mand (TCOD), dissolved chemical oxygen demand (DCOD), total aluminum, and
total phosphate.  The samples were also analyzed periodically for total dis-
solved solids (TDS) and alkalinity.  Tests for pH and temperature were per-
formed two to three times a week on grab samples.

Analytical Methods

     All physical and chemical analyses were performed in accordance with the
13th edition of Standard Methods (3) or the FWPCA Methods for Chemical
Analysis (4) unless otherwise specified.  Turbidity tests for composite
samples were conducted using a Hach Mode,! 2100 Turbidimeter,
                                      10

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                                 SECTION 5

                     DISCUSSION  OF EXPERIMENTAL RESULTS
     For convenience in the discussion of experimental results, the pilot
plant evaluation is divided into three phases.  In the first phase of the
study, which covered about four months, the two dual-media filters were
operated at flow rates of 3.4 and 6.8 1/sec/m2 (5 and 10 gpm/ft2) with or
without chemical addition'.  During this phase of the study, two filter bed
cleaning procedures; namely, surface wash-water backwash and air scour-water
backwash, were evaluated.  The second phase of the study covered approximately
four months during which time three experimental  test series were conducted.
It should be pointed out that each test series consists of several filter
runs. The first test series entailed the comparative evaluation of a dual-
media filter with two types of pretreatments; namely, a chemical coagulation-
sedimentation pretreatment (Scheme A) and an in-line coagulation pretreatment
(Scheme B or C).  After the completion of the first test series, the mixed-
media filter was converted into a dual-media filter.  In the second test
series the two dual-media filters were operated in parallel with one filter
operated with Scheme A pretreatment and the other filter with Scheme B pre-
treatment.  This test series was performed for the purpose of selecting the
optimum chemical dosage to be used in subsequent long-term filter'evaluation.
During the third test series, a number of special short-term filter runs were
conducted using Scheme B pretreatment at various levels of polymers alone and
in combination with high levels of alum.  The third and final phase of the
filtration study dealt with the long-term evaluation of the effect of type of
pretreatment on the dual-media filter performance.  In this phase of the
study, the filter pretreatment systems were operated at the optimum chemical
dosage obtained in the second phase.

      It should be pointed out that during the entire second and third phases
of the study, the filters were operated at a filtration rate of 3.41 1/sec/m2
(5 gpm/ft2) and they were automatically air scoured-water backwashed once
every 24 hours or whenever a preset terminal headloss of 1.41 Kg/cm2 (20 psi)
was reached.  Moreover, in the course of each filter run, the filter influent
and effluent turbidities were continuously monitored using in-line turbidi-
meters (Hach Model 1720 Low Range Turbidimeter) each equipped with a Rustrak
recorder.  The turbidity data used in evaluating the performance of the dual-
media and the mixed-media filters during the second phase of the study were
taken from the turbidity recorders.  During the first and third, phases, how-
ever, the turbidity data used for evaluating the filters were based on the
laboratory tests (Hach Model 2100 turbidimeter) of composite samples (24-hour
                                      12

-------
composite for the first phase and 16-hour composite for the third phase)
rather than those from the in-line turbidity recorders.  This change was made
in order to be on the same basis as the test results of other parameters, such
as suspended solids, color, chemical oxygen demand (COD), total dissolved
solids (IDS), alkalinity, and total phosphate, which were based on composite
samples.

PHASE I TEST RESULTS

Test Series I - Effect of Filtration Rate and Chemical  Injection on Filter
Performance.

     During the first test series, four different sets  of runs of about one to
two weeks duration per set, were conducted.  In the first two sets of runs,
both dual-media filters were operated without chemical  addition, with one fil-
ter operated at 6.8 1/sec/m2 (10 gpm/ft2) and the other.at 3.4 1/sec/m2 (5
gpm/ft2).  For the third and fourth sets of run, the filters were operated at
an identical flow rate of 6.8 1/sec/m2 (10 gpm/ft2) with  direct injection of
10 mg/1 alum.  An anionic polymer (Calgon WT-3000) was  also fed as a filter
aid to the filter influent lines at a dosage of 0.1 mg/1  to one filter and
0.2 mg/1  to the other.

     Throughout the first test series, both dual-media  filters were automatic-
ally -backwashed at the end of a 30-hr filter run or whenever a preset terminal
headloss  of 1.40 Kg/cm2 (20 psi) was reached.  The filter backwash sequence
consisted of three minutes surface wash at 1.7 1/sec/m2 (2.5 gpm/ft2)
followed  by five minutes of water backwash at 13.6 1/sec/m2 (20 gpm/ft2).

     Table 2 presents a summary of the filter performance during the first
test series.  In evaluating the data in Table 2, the following observations
can be made:

     1. Without chemical addition, filter performance was essentially
        the same at filtration rates of 3.4 1/sec/m2 (5 gpm/ft2)
       and 6.8 1/sec/m2 (10 gpm/ft2).

     2. At filtration rate of 6.8 1/sec/m2 (10 gpm/ft2) with direct
       chemical injection of 10 mg/1  alum, the filter  performance
       with polymer dosage at 0.1 mg/1  was about the same as that
       with polymer dosage at 0.2 mg/1.

     3. Based on filter effluent quality and filter run length, the
       filter performance with plain filtration (no chemicals)
       was markedly better than that with direct chemical in-
       jection of alum and polymer.   Moreover, headloss  levels
       were lower with terminal headloss of 1.4 Kg/sq  cm not
       reached even after 30 hours filter run.  This observation
       was anticipated because of the low levels of turbidity
       and suspended solids in the filter feedwater.  It must be
       pointed out, however, that changes in the concentration and/
       or characteristics of the filter influent could bring about
       a significant change in the filter performance„

                                     13

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                                                                             V
 Test Series  II  -  Effect  of Type  of  Backwash Auxiliary on  Filter Performance

      During  the second test series, which  covered approximately six weeks, the
 filters  were operated at an identical  filtration rate of  6.8 1/sec/m2  (10 gpm/
 ft2).  Both  filters were operated with  direct  injection of alum at a dosage
 of 5 and 10  mg/1.  An anionic  polymer  (Calgon  WT-3000) was also injected di-
 rectly into  the filter influent  lines  at three levels of  concentrations;
 namely,  0, 0.1, and 0.2  mg/1.

      As  in the  first test series, the  filters  were automatically backwashed
 every 30 hours  of filter run or  whenever a preset terminal headless of 1.4
 Kg/cm2 (20 psi) was reached.   In an effort to  determine the effect of back-
 washing  procedure on headless  development and  filter effluent quality, two
 filter bed cleaning procedures were evaluated.  These two bed cleaning pro-
 cedures  were surface wash-water  backwash and air scour-water backwash.

      Table'3 presents a  summary  of the  average performance of the filters in
 terms of the removal of  turbidity, suspended solids, COD and color. .The
 range and average lengths  of filter run are also included in Table 3.  The
 data show that  in general  the  filter effluent  quality parameters for the
 various  experimental runs  were about the same  level when alum at 5 mg/1 was
 used in  combination with  polymer at dosages of 0.1 and 0.2 mg/1.  The filter
 effluent quality, however,  was poor when alum  alone at a dosage of 9.7 mg/1
 was  used for filter pretreatment.  The data in Table 3 further show that at
 5 mg/1 alum  and polymer  at  either 0.1 or 0.2 mg/1, the average filter run
 length with  air scour-water backwash procedure was longer compared to that
 with surface wash-water  backwash procedure.  Moreover, in comparing run,No, 1
 with run  No.  3  and run No.  2 with run No. 4, it is apparent that at an alum
 dose of  5 mg/1, the,filter  run length with polymer at 0.1  mg/1  was about
 three times  longer than  that observed with polymer at 0.2 mq/1.   It is also
 apparent  in  comparing runs  No.  1, 3, and 6 that at alum dose of 5.2-5.3 mg/1,
 the  average  filter run length with no polymer filter aid was longer than >
 those with polymer additi.on.  Additional filtration data which  are not in-
 cluded in Table 3 indicate  that  at an alum dose of 5 mg/1, the  filter efflu-
 ent quality with polymer at 0.02 mg/1  was about the same as that observed
with polymer at 0.2 mg/1.  The average filter run length,  however, was
 longer at the lower polymer dose.

     Figure 4 presents the effect of chemical  dosage and type of filter bed:
 cleaning procedure on the headless buildup through the dual-media filters.
 Each test run shown in the figure covered a period of one  week.   The data
 show that for all  test runs evaluated, headlosses across the filters with
surface wash auxiliary were higher than those observed with an  air scour aux-
 iliary.   These  results were in  accord with the findings  of other investiga-
tors (5,6).   Thus, it was decided to use the air  scour-water backwash proce-
dure in all  subsequent filtration runs starting from the fourth  month  of the
pilot plant  study.

     In Figure  5 are presented  the effect of alum and polymer additions on
the headless buildup across the filter.  The figure shows  that with  5  mg/1
alum, the headless levels were  generally higher with higher concentrations  of
                                    15

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                             UNIT CONVERSIONS •
                                  gpm/ft* x 0.68=l/sec/rrf
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                             OPERATING CONDITIONS

                           FILTRATION RATE-IOgpm/ft.2
                           AIR-ASSISTED BACKWASH   -I
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                      FILTER RUN, hours
Figure 5. Effect of alum and polymer addition on headless.
                             19

-------
polymer.  This is clearly indicated by comparing the headless obtained at 0.5
mg/1 polymer with that obtained without polymer addition.  This observation is
significant in that while the use of polymer filter aid is desirable in enhanc-
ing the attachment of solids on the media surface thereby precluding premature
solids breakthrough, higher levels of polymers could cause rapid headless
buildup across the filter.  This phenomenon had been observed by a number of
investigators (7,8,9,10).  Therefore, a judicious choice of polymer type and
concentration must be made in an effort to effect relatively long filter runs
consistent with the production of a good quality filter effluent.

     The headloss data for test runs No. 1 and 2 (with an air scour auxiliary)
in Figure 4 is replotted in Figure 6 and compared with data obtained with plain
filtration.  As indicated in Figure 6, the range of headloss across the filter
with 5 mg/1 alum was essentially the same as that with 10 mg/1 alum.  Never-
theless, the data clearly demonstrate the relatively much lower headloss ob-
tained without chemical addition.

     It should be pointed out that during the first two months of pilot plant
study alum was injected directly into the suction line of the filter feed
pump without any other auxiliary pre-mixing.  In an effort to provide improved
mixing condition a static mixer was installed and used during the last month
of Phase I.  Starting with the second phase of the study, the static mixer was
replaced with a rapid mixer, which was installed ahead of the filter feed pump
and this rapid mixing set-up was used in all subsequent experimental runs for
Schemes B and C.

     The results of selected test runs with the use of static mixer are sum-
marized in Table 4.  The data show that there appears to be no significant
difference in filter performance with or without the use of static mixer.
Nevertheless, in comparing run No. 2 in Table.4 with run No. 5 in Table 3, it
is  apparent that the average filter run length was longer when a static mixer
was used.  Direct comparison of the results, however, is limited by the fact
that the runs were not conducted in parallel and consequently, factors other
than the type of pre-mixing could have caused the difference in the average
length  of the filter run.

PHASE  II TEST RESULTS

Test Series  I -  Comparison of Dual-Media and Mixed-Media Filter Performance

A.  With Scheme A Pretreatment

     During  the  parallel  filtration run, the  chemical clarification system
was operated  at  a constant flow  rate of 3.47  I/sec  (55 gpm).  Alum was added
at  two  levels of dosages; namely, 55 and 110 mg/1, with  0.20 mg/1 of  artiomc
polymer (Calgon  WT-3000)  added-as a coagulant aid.  An anionic polymer at  a
dosage  varying from 0  to 0.20 mg/1 was  injected as  a filter aid to the in-
fluent  line  of each  filter.  Both filters were operated  at an  identical  fil-
tration rate  of  3.4 l/sec/m2>(5  gpm/ft2).
                                       20

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        0  2 4  6  8  10 12 14 16  18 20 22 24 26 28 30

                      FILTER RUN, hours
Figure  6. Effect of alum addition on headloss.
                         21

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      Figure 7 presents the results  of the parallel  filtration  runs.   The first
 seven runs represent the data with  alum dose of 55  mg/1  in  the clarification
 system.   In comparing runs No.  1  through 3 with runs  No.  4  through  7, it is
 apparent that the turbidity removals  by the filters were  essentially the same
 at polymer filter aid dosages ranging from 0 to 0.2 mg/1.   The headlosses, how-
 ever, at filter aid levels of 0.10  to 0.20 mg/1, were definitely  higher  than
 those at 0 to 0.08 mg/1.   The effect  of polymer filter aid  dosages  on the head-
 loss  buildup is further shown by  comparing runs No. 8 through  No. 11  and run
 No. 14 with runs No.  12 and 13.   These observations suggest that while polymer
 filter aids are desirable in strengthening weak chemical  floe  thus  preventing
 premature solids breakthrough,  the  polymer filter aid doses must be  kept as low
 as possible to avoid excessive  headless buildup.

      In  evaluating the performance  of the filters as  shown  by  the data in
 Figure 7, two conclusions could be  drawn.   First, the turbidity removal  per-
 formance of the dual-media filter was consistently  better than that  of mixed-
 media filter.   The data also indicate patterns  of improved  turbidity  removal
 during the early part of the filter run.   Secondly, the headless buildup
 through  the mixed-media filter was  definitely and consistently higher than
 that  observed in the  dual-media filter.   Moreover,  the data show, that with
 the exception  of run  No.  1,  the headless  buildup  through the filter varied
 linearly with  filtration  time which is  indicative of  an in-depth filtration.

 B. With  Scheme B Pretreatment

      In  the comparative evaluation  of the  filters with in-line coagulation
 pretreatment,  the  alum solution was added  to a  rapid  mixing  unit where mixing
 for approximately  1.5 minutes was provided.  The  alum-coagulated secondary
 effluent was  then  pumped  directly to  both  multi-media pressure  filters at a
 flow  rate to maintain  a filtration  rate of 3.4  1/sec/m2 (5  gpm/ft2).  An
 anionic  polymer (Calgon WT-2700 or  WT-3000) was injected directly into the in-
 fluent line of each filter.   In evaluating  the  filters, the turbidity  removal
 in the course  of the  filter  run was used as the primary parameter for  compar-
 ing the  filter performance.

      The comparative  performance of the filters with  an in-line coagulation
 pretreatment using various levels of  alum and polymer, .is presented in Figure
 8.  .It is  apparent from the  data that for the secondary effluent being
 treated,  high  alum dose definitely  caused poor filter effluent quality.  The
 response of the  filters with  an increase or a decrease in alum dose is clearly
 shown  in  the figure..  The data show that at zero and  low alum doses the tur-
 bidity removal  performance of the dual-media filter was slightly better than
 that  of  the mixed-media filter.  Moreover,  in the absence of alum, turbidity
 removal  with or without polymer appears to be the same.  The results also
 show  that  the  performance of  the filters with direct chemical injection of an
anionic  polymer WT-2700 was about the same as that obtained with an anionic
polymer  WT-3000.

      In  the course of the evaluation, the filters were also operated using a^
nitrified  secondary effluent feedwater  (Scheme C) in an effort to determine
what effect, if any, different type of feedwater would have on the perform-
ance of  the filters.  Figure 9 presents the performance of* the filters with

                                     23                   ,

-------
ID
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3
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 U-
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 CD
 tr
 ID
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 CO

 3
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 X
     0
     15
10
     0
10
       OPERATING CONDITIONS:
       FEED SOURCE-*NON-NITRIFIED SECONDARY EFFLUENT
       FILTRATION RATE-*-5gpm/ft.*
       TYPE OF POLYMER-* ANIONIC WT-3000
       T= MRS. RUN TO 20 PSI  HEADLOSS
       (a) ALUM FOR COAGULATION       O--O  FILTER INFLUENT
       (b) POLYMER COAGULANT AID      &—&  MIXED-MEDIA FILTER
       (C)POLYMER FILTER AID	D—D  DUAL-MEDIA FILTER
              T
          p-o-o-oN
                  T
T
T	T
                            UNIT CONVERSIONS:
                               gpm/ftz x 0.68 = l/sec/m2
                               psi x 0.0703= kg/cm*
     RUN NO. I

(a) 55 mg/l ALUM
(b)0.20 mg/l POLYMER
(c)0.2 mg/l POLYMER
T=8'/2hrs.for DM
      hrs.for MM
         o-o-
              -o-'
                  .o	o
                           o	ฐ—o.
                                                •-o
                                                 a
                        JL
                            J_
       0
                   468
                     FILTER RUN, hours
     RUN NO. 2

 (0)55 mg/l ALUM
 (b)0.20 mg/l POLYMER
 (c)0.20 mg/l POLYMER
 T=23'/2hrs.for DM
  = 7'/2hrs. for MM


     —t-tti
         10  "22
             24
Figure 7.  Performance of filters with chemical coagulation-
          sedimentation pretreatment.
                               24

-------
    4



V 3


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2  5
         0-0-0,
                                      '00
                       X>-0—O	O
                                                RUN NO. 3

                                           (a) 55 mg/l

                                           (b) 0.20 mg/l

                                           (c) 0.10 mg/l

                                            T = 23'/2 hrs. for DM
                                              = 7 hrs. for MM

                                                 RUN NO. 4

                                            (a) 55 mg/l

                                            (b) 0.20 mg/l

                                            (c) O mg/l

                                             T = 23'/2 hrs. for DM

                                            ,   ?23'/2hrs.for MM
                          4        6        8

                           FILTER  RUN, hours
                                                    10
                                                                 24
Figure 7. Continued.
                                  25

-------
 li-
 fe
 CD
 0r
 u>
 a.

 CO
 CO

 3
 o

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 X
 U.
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  en
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  4

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                                                   -tt-

o
                                    RUN NO. 5

                                (a) 55 mg/l

                                (b) 0.20 mg/l

                                (c) 0 mg/l

                                J=24hrs.for DM
                                   and MM
                             \
                                        00	O
         ฃ~3&53S3ZE===8
                           a—m-
-D
                                    RUN NO. 6

                                (a) 55 mg/l

                                (b) 0.20 mg/l

                                (c) 0.08 mg/l

                                  = 24 hrs. for DM
                                   and MM
                                          I
                   468

                    FILTER RUN, hours
                                         ^H^
                                                      /v
                                        10   22
                                                              24
Figure 7. Continued.
                                26

-------
  u_
  5
  CD
  or
  ID
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 4


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        - o'
               4.4
                       4.1  4.2
                                          '""o—o-
                                               RUN NO,  7

                                           (a) 55 mg/l

                                           (b)0.20 mg/l
                                           ,(c) 0.08 mg/l
                                              23^4hrs. for DM
                                              and MM
                               — O	n—
                                               RUN NO. 8

                                           (a) 110 mg/l

                                           (b) 0.20 mg/l

                                           (c) O.08 mg/l

                                           T=24hrs.for DM
                                            = 22hrs.for MM
                                                          I
                         4       68
                           FILTER RUN, hours
                                                    10 '22
                                                            24
Figure  7.  Continued.
                                  27

-------
u_
5
CD
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  •ป



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 0
           o-o I
              \
               \
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                           RUN NO. 9

                       (a) 110 mg/l

                       (b) 0.20 mg/l

                       (c) 0.08 mg/l

                       T-*- DM and MM
                    SHUTDOWN AT  71/2 hrs. DUE
                    TO INFLOW INTERRUPTION
                           RUN NO. 10

                       (a) 110 mg/l

                       (b) 0.20 mg/l

                       (c) 0.08 mg/l

                        T= 12 hrs. for DM
                         = 9 hrs. for MM
                                           _L
                         468

                          FILTER RUN, hours
                                                10   22
                                             24
Figure 7. Continued.
                                 28

-------

ID
t
H,
m
oe
h-
8.
ง
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UJ
X

ID
1-
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1 | | 	 1 	

- ' .
-
*^ ^** ^ป • S
"™ ^"Q"™" ™^Q—™™ IHH ~f\^
^F" ^P rf3 — -Q — p^ — A-4 	 n 	 rp 	



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M
	 o
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	 [JL_
/y RUN NO. II
s'^ ^^"^ (a) HO mg/l ~
„./' r^^ (b) Q2ฐ m9/l
J-* ^^ (c) 0.08 mg/l
/^r^^ T = 24
hrs. for DM
-^y^^-^^ =5'/2 hrs. for MM
tr^"^

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/
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RUN NO. 12
(a) 110
mg/l
(b) 0.20 mg/l
(c) 0 mg/l ~
_f^_&= 23*/2 hrs. for DM
/V" ฃj — i"f
cr i
i
O2 4 6 8



10 U22 24
                       FILTER RUN, hours
Figure 7. Continued.
                             29

-------
u.
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CC
1

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CO
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 to
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         O	O	CL
                                          RUN NO. 13

                                      (a) 110 mg/l
                                      (b)0.20mg/l

                                      (c) 0 mg/l
                                      T=20hrs.forDM

                                         and MM
                                           RUN NO. 14

                                       (a) 110 mg/l

                                       (b) 0.20 mg/l
                                       (c) 0.08 mg/l

                                       T=l3'/2 hrs.forDM
                                         ll'/2hrs.forMM
                         468
                          FILTER RUN, hours
                                               10   22
                                                             24
Figure 7.  Continued.
                                 30

-------
13
H
U.
 •ป

Q
CO
a:
      10
      8
      6
      4
      2
      0
      10
      8
      6
      4
      2
      0
      15
      10
      5
         OPERATING CONDITIONS:
          FEED SOURCE—NON-NITRIFIED SECONDARY EFF
          FILTRATION RATE—5 gpm/ft.*
          POLYMER DOSE*0.23 ma/I WT-3000 (ANIONIC)
           0--0  FILTER INFLUENT
           &—&  MIXED-MEDIA FILTER.EFFLUENT
           D	D  DUAL-MEDIA FILTER EFFLUENT
              I
    59 mg/l ALUM
                                     I    i   r   r
                                     RUN NO. I
                           94 mg/l
                        -O
O	ฃ&
                  UNIT CONVERSIONS:
                     gpm/ft2 x 0.68= I /see/m2
                            RUN NO. 2
65 mg/l
   IM
   +ซi— 21 mg/l	>•
  r65rr
:/ALU
   ALUM
                       0 mg/l
  o-
                            RUN NO. 3
                ALUM: a) 166 mg/l
                      b) 18.7 mg/l
                             _L
                                    1	L
                      46       8   22
                      FILTER RUN, hours
                                       24
Figure 8. Effect of alum dose on turbidity removal with
         non-nitrified secondary effluent feed.
                          31

-------
TURBIDITY, FTU
4
3
2
1
0
4
3
2
1
0
10
8
6
4
2(
0
C
OPERATING CONDITIONS:
FEED SOURCE-^NON-NITRIFIED SECONDARY EFF
FILTRATION RATE-ป-5gpm/ft.z
POLYMER DOSE-*- 0.23 mg/l WT.-3000 (ANIONIC)
0--0 FILTER INFLUENT
&— & MIXED-MEDIA FILTER EFFLUENT
D — D DUAL- MEDIA FILTER EFFLUENT
RUN NO. 4
NO ALUM OR
POLYMER
^ o — ฐ''ฐ^'X
o 	 o- ^ 	 0
ฃ==ฃ 	 r&&-T-fr=&3&=&=&
	 p 	 1 — y — | — ui TIY Y — 4—
RUN NO. 5
o^ ^^ฐ~~ฐ-ON
V -^^-.o^0 X
"S? 	 0
Do 	 tt 	 S 	 — SS- — D- — i>S — li— tf 	 r-Q I
RUN NO. 6
^ 	 	 |=: o mn/l Al 1 IM -• . .to*
^o
o- -o^ ^QJO 	 o- -o- -o"
1
) 2 4 6 8 22 24

-
-
-

                   FILTER RUN, hours
Figure 8. Continued.
                       32


-------
z>
h-
u_
>
Q
CD
CC
Z>
I-
    4
    3
    2
    1
    0
    3
    2
     1
    0
    3
    2
     1
    0
    3
    2
     1
       OPERATING CONDITIONS:
        FEED SOURCE -"NON-NITRIFIED SECONDARY EFFLUENT
        FILTRATION RATE— 5gpm/ft.2
        TYPE OF POLYMER-* ANIONIC, WT.-2700
         0 --- 0 FILTER INFLUENT
         ฃป - & MIXED-MEDIA FILTER EFFLUENT
         D— D DUAL MEDIA FILTER EFFLUENT
    ALUM = 6.1 mg/l
 >   POLYMER = 0.36 mg/l
   ^O--O -- O— O--O-'
                                - -O - O- -6 - -6
                                      RUN NO, 7
 V— A— A — ฃj — A — A— A — A—A — &— A-ฃrf
       +
                                            •*
    ALUM = 6.1 mg/l                 RUN NO. 8
    POLYMER = 0.22 mg/l
                 ^o - -o - o-o-o- -o — QN
    ALUM = 18.4 mg/l
    POLYMER = 0.25 mg/l
 O- O - ^- -o- -O-O - O -O-O- -O--
	^-Hitf
RUN NO. 9
     -O
     ALUM = 18.4 mg/l
     POLYMER =0.34 mg/l
                             _        RUN NO. 10
                            /ฐ-ฐ-O--O-.o-o
0
                    468
                    FILTER RUN, hours
                                          10  22
              24
Figure 8. Continued.
                          33

-------
 I-
 u.
 o
 00
 o:
4
3
2
 I
0
3
 2
 I
 0
 3
 2
     0
        OPERATING CONDITIONS:
         FEED SOURCE-ป-NON-NITRIFIED SECONDARY EFFLUENT
         FILTRATION RATE-*5 gpm/ft.2
         TYPE OF POLYMER-*- ANIONIC,WT.-3000
         O	O  FILTER INFLUENT
         A	A  MIXED-MEDIA FILTER EFFLUENT
         D	'-D  DUAL-MEDIA FILTER EFFLUENT
           ALUM= Omg/l
           POLYMER = 0.2 mg/l
                             RUN NO. II
ALUM = 9.5 mg/l
POLYMER=0.26 mg/l
          ซ~-0--0-o
                                        RUN NO. 12
ALUM = 18.4 mg/l
POLYMER = 0.23mg/l^Q	Q_
     RUN NO. 13
-O—O-
        O-O.
       ALUM = 24.5 mg/l
       POLYMER =0.12 mg/l
           X>--O--O--O-O

                                 P	O	O—O
                     468
                     FILTER RUN, hours
                                      10  22
Figure 8. Continued.
                          34

-------
 Q
 OQ
 CC
8
6
4
2
0
8
6
4
2
0
8
6
4
2
0
15
10
5
       OPERATING CONDITIONS--
        FEED SOURCE-* NITRIFIED SECONDARY EFFLUENT
        FILTRATION RATE—5gpm/ft.*
        POLYMER DOSE•*• 0.23 mg/l WT-3000 (ANIONIC)
         O- --O FILTER INFLUENT
         ฃs	& MIXED-MEDIA FILTER EFFLUENT
         D	D DUAL MEDIA FILTER EFFLUENT
                                        RUN NO. I   _
                •6.1 mg/l ALUM-
       J—0--
I •-.1-1—p_r   t-l-J-t-H-i   I	   I
UNIT CONVERSIONS:         RUN NO. 2
   gpm/ft2 x 0.68= l/sec/m*
O-O-"ฐ~-O	O	-O--O--O--O
                    21 mg/l ALUM
                   45 mg/l ALUM -*k 21 mg/l
                  58 mg/l ALUM-4*- 6.1 mg/l
                   ^            I
                                       RUN NO. 4
                     4      68      10
                     FILTER RUN, hours
                                              12
Figure 9. Effect of alum dose on turbidity removal
          with nitrified secondary effluent feed.
                        '35

-------
 nitrified  secondary  effluent  feedwater.  The results shown in the figure dem-
 onstrate similar  trend  as  in  Figure 8, that is, high effluent turbidity at
 high alum  dose.

     Based on the above observations, which show that the overall performance
 of the dual-media filter was.equal to or better than that of the mixed-media
 filter, all subsequent  filter evaluations were confined to the use of the
 dual-media configuration.

 Test Series II -  Dual Media Filter Performance

 A. With Scheme A  Pretreatment

     As discussed in the Test Series I-A, when the dual-media filter was
 evaluated  in parallel with the mixed-media filter, the chemical clarification
 system was operated at  a flow rate of 3.47 I/sec (55 gpm).'  After the com-
 pletion of the comparative filter evaluation, the flow through the clarifica-
 tion system was reduced to 2.42 I/sec (40 gpm) thus providing mean hydraulic
 residence  times of 4.1, 62.5  and 126 minutes in the rapid mixing, flocculation
 and sedimentation tanks, respectively.  Alum was continuously added to the
 rapid mixing tank at a  dosage ranging from 55 to 225 mg/1.   An anionic polymer
 (Calgon WT-3000)  at an  average dosage of 0.20 mg/1  was added as a coagulant
 aid to the flocculation tank.  The .chemically clarified secondary effluent
 was pumped to the dual-media  filter at a flow rate of 1.58 I/sec (25 gpm)
 which was  equivalent to a filtration rate of 3.41  1/sec/m2 (5 gpm/ft2).   The
 remaining  clarified effluent  flow was then diverted to waste.

     The experimental data presented in this section include all  the results
 obtained with the clarification system operated at 3.47 I/sec (55 gpm) and
 2.52 I/sec  (40 gpm).  Thus, the dual-media filter performance data presented
 in Test Series I-A with alum  dosage of 55 and 110 mg/1  in the clarification
 system are also included in the summary data in this section.

     Table 5 presents a summary of the dual-media filter performance with
 chemical coagulation-sedimentation pretreatment.   In the operation of the
 filters, an anionic polymer (Calgon WT-3000) at a dosage varying from 0  to
 0.20 mg/1  was injected  as a filter aid to the filter influent line.   As. in-
 dicated by the data, the turbidity removal  at a given alum dose remains
 essentially the same with or without polymer filter aid.   The headloss data
 across the filter, however, is definitely higher with the use of a polymer
 filter aid.

     In Figure 10 is shown a number of dual-media filter runs with the clari-
 fication system operated at an alum dose of 110 mg/1  and polymer at 0.20.
mg/1.   The figure shows the fluctuation in  the effluent turbidity in the
 course of the first 7.5 to 10 hours of filter run.   Although  in most runs
 effluent turbidity of 0.5 FTU or less  was attained, there were days  when
 higher effluent turbidity levels were  observed.   Moreover,  the headloss  level
also varied from run to run with an observed range  of 0.55  to 1.1  Kg/cm2
 (7.8 to 15.6 psi) at the end of the first 7.5  hours of filter run.   Figures
 11 and 12 show a similar plot to Figure 10  except  at higher  alum doses in  the
                                     36

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                                  WT. 3000
UNIT CONVERSIONS:

   gpm/ft2 x 0.68 = I /sec/m2
   psi x 0.0703 = kg/cmz
                          4       68

                         FILTER RUN, hours
                                   10
Figure 10. Dual-media filter performance with 110mg/l
         alum and 0.2 mg/i polymer in the clarification
         system.

                         38

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- o
               WITHOUT FILTER AID
         UNIT CONVERSIONS-'
            gpm/ft2 x 0.68= l/sec/m2
            psi x 0.0703 = kg/cm*
                       4       6
                    FILTER RUN, hours
                              8
10
Figure II. Dual-media filter performance with  155 mg/l
         alum and 0.2 mg/l polymer in the clarification
         system.
                        39

-------
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 OPERATING CONDITIONS:
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  A]WITHOUT FILTER^-^
  OJAID        ^   /
             /    /
        s     x
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^     X
  -x
             UNIT CONVERSIONS:
                        gpm/ftax0.68= l/sec/m2
                        psi x 0.0703 = kg/cm*
                      468
                    FILTER RUN, hours
                                        10
Figure 12. Dual-media filter performance with 225
          mg/l alum and 0.2 mg/l polymer in the
          clarification system
                      40


-------
clarification system.  The data in these figures also include the runs with-
out the use of polymer filter aid.  The results presented in Figures 10
through 12 show that effluent turbidities ranging from 0.1  to 0.5 FTU were
obtained in all the three alum doses evaluated.  It is evident from the
figures, however, that except at the alum dose of 155 mg/1, the filter efflu-
ent turbidities varied from run to run.  The data shown in Figures 11 and 12
indicate that the turbidity removal performance of the dual-media filter was
about the same with or without the use of a polymer filter aid.  Moreover, it
is apparent that the headless buildup was markedly higher with the use of a
polymer filter aid.

     Figure 13 presents the effect of alum dose in the clarification system
on the performance of dual-media filter.  Each headloss data point in this
figure represents the observed headloss at the end of the first 7.5 hours of
each filter run.  The effluent turbidity and percent turbidity removal data
are the average of hourly values obtained during the course of the first 7.5
to 7.8 hours of each filter run.  Based on the experimental data summarized
in Figure 13 along with those presented in Table 5, the following conclusions
about filter performance with Scheme A pretreatment were drawn:

     1. A filter effluent turbidity of 0.2-0.4 FTU was achieved at
        an optimum alum dose of 150 mg/1 and an anionic polymer
        coagulant aid of 0.20 mg/1 (Calgon WT-3000) in the chemical
        clarification system.

     2. The turbidity removal- efficiency in the dual-media filter
        was essentially the same with or without the use of a poly-
        mer filter aid.

     3. With the use of a polymer filter aid, the headloss across
        the filter was higher at higher alum dose in the clarifica-
        tion system.  In addition, at a given alum dose, the head-
        loss across the filter with the use of 0.06 to 0.08 rng/1
        polymer filter aid (Calgon WT-3000) was higher than that
        without filter aid.

     On the basis of the above findings, all subsequent filtration runs' were
conducted with the clarification system operated at an alum and polymer dos-
ages of 150 mg/1 and 0.20 mg/1, respectively.  In addition, no polymer fil-
ter aid was used.

B. With Scheme B Pretreatment

     In the evaluation of the dual-media filter with an in-line coagulation
pretreatment, a number of experimental test runs were conducted using various
levels of alum in combination with an anionic polymer (Calgon WT-3000).  Fig-
ure 14 presents the results of selected filtration runswith alum levels rang-
ing from 0 to 18.4 mg/1 and with an anionic polymer from 0 to 0.23 mg/1.  The
test results shown in Figure 14 along with the summary data presented in
Figure 15 showthatwith in-line coagulation pretreatment, filter effluent tur-
bidity levels obtained were greater than 0.5 FTU for all the glum and polymer
                                      41

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  OPERATING CONDITIONS:
   FEED SOURCE-*-NON-NITRIFIED SEC. EFF
   FILTRATION RATE-*-5gpm/ft*
-  POLYMER COAGULANT AID—0.20mg/l   -
     WT. 3000 (ANIONIC)             *
  • —WITH 0.07-.08 mg/l WT.-3000
     FILTER AID
  o-^WITHOUT FILTER AID
                UNIT CONVERSIONS:
                  gpm/f t2 x 0.68 = I /sec/m2
                  psi x 0.0703 = kg/cm*
               50      100     150    200
                      ALUM DOSE, mg/l
                                     250
Figure 13. Effect of alum dose in the clarification system
         on the dual-media filter performance.
                        42

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          OPERATING CONDITIONS:
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            FILTRATION RATE-—5  gpm/ft.2
          SYMBOL  mo/1 ALUM  mq/i POLYMER
                              (WT. 3000, ANIONIC)
UNIT CONVERSIONS:
  gpm/ft* x 0.68= I /sec/m*
  psi x 0.0703= kg/cm*
                        468
                      FILTER RUN, hours
                                    10
Figure 14. Dual-media filter performance with in-line
         coagulation pretreatment.
                       43

-------
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       OPERATING CONDITIONS^
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-------
doses evaluated.  The average filter effluent turbidity in the first 7.5 to
7.8 hours of filter run varied from 0.6 to 1;2 FTU.  In the absence of alum,
however, filter effluent turbidities ranging from 0.2 to 0.8 FTU were ob-
served.  Moreover, in the absence of alum, turbidity removal with or without
polymer injection was about the same.   These results confirmed previous
Pomona filtration data which showed that based on filter effluent quality and
fflter run length, the filter performance with plain filtration (no chemical)
was equal to or better than that with the addition of alum and polymer.

Test Series III - Special Short-Term Filtration Runs with Scheme B
Pretreatment.

     In the course of the dual-media filter evaluation with an in-line coagu-
lation pretreatment, two sets of special filtration runs were conducted.  In
the first set of runs, the dual-media filter was operated with the use of a
cationic polymer (Calgon Cat-Floe T) alone for pretreatment.  Figure 16 pre-
sents the results of selected filtration runs with the cationic polymer dos-
age as high as 2.4 mg/1.  A summary of the effects of cationic polymer dose
on the dual-media filter performance is presented in Figure 17.  Each head-
loss data in this figure represents the observed headloss at the end of the
first 7.5 hours of each filter run.  The effluent turbidity .and percent tur-
bidity removal data represent the average of hourly observations obtained
during the first 7.7 to 8 hours of filter run.  As indicated by the data
in Figure 17 the apparent optimum polymer dosage ranged from 0.05 to 0.5
mg/1.  At this range of polymer dose, the average filter effluent turbidity
in the first 7.8 to 8 hours of run varied from 0.8 to 0.9 FTU.  For the dos-
age range evaluated, the headloss at,the end of 7.5 hours of run was low and
ranged from 0.09 to 0.23 Kg/cm2 (1.3 to 3.3 psi).

     The second set of the special filtration runs entailed the use of high
alum dose (40.5 to 182 mg/1) in the in-line coagulation system in combination
with a non-ionic polymer (American Cyanamid Magnifloc 985 N) filter aid at a
dosage of 0.7 to 2.1 mg/1.  The results of the filtration runs are presented
in Figure 18.   As shown in the figure, for the alum dose of 160 to 182 mg/1
in combination with 1.2 to 2.1 mg/1 non-jonic polymer (Test No. 1  to 4),
filter effluent turbidity levels of 0.3 to 0.4 FTU were attained.   At this
high chemical  dose, however, the length of the filter run to a terminal
headloss of 1.4 Kg/cm2 was very short and ranged only from 20 to 75 minutes.
Moreover, it required a period of about 15 to 20 minutes (so-called "ripen-
ing period") from the start of the filtration run to. reach the stable filter
effluent turbidity level of 0.3 to 0.4 FTU.  Although this ripening period
is short, it constitutes a significant portion of the total filter run.
Thus, the test results show that although low filter effluent turbidity
could be achieved at very high alum and polymer doses in the in-line coagula-
tion pretreatment, the resulting run length was too short to be economically
feasible.  The last three runs (Test Nos. 5 to 7) in Figure 18 show the tur-
bidity removal data at alum dose of 40.5 to 111 mg/1 and non-ionic polymer
dose of 0.7 to 1.3 mg/1.  As indicated in the figure, the filter effluent
turbidity was high throughout the filter run.
                                      45

-------
      OPERATING CONDITIONS^
       FEED SOURCE-*NON-NITRIFIED SEC. EFF
       FILTRATION RATE-*5gpm/ft.ซ
                CAT-FLOG T. mq/l

           •	•    0.08
           o	o    0.25
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                 46

               FILTER RUN, hours
                                    8
10
Figure 16. Dual-media filter performance with direct

          cationic polymer injection.
                      46

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               i   i i  mm
UNIT CONVERSIONS:
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  i   11  Mini—H-++
                                  +-H-+T
  2 34 6  0.1   2346  1.0  2346

             mg/l CAT-FLOG T
                                    10
Figure 17. Effect of cationic polymer dose on the dual-
        media filter performance.
                      47

-------
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        OPERATING CONDITIONS:
         FEED SOURCE — NON-NITRIFIED SECONDARY EFFLUENT
         FILTRATION RATE—5 gpm/ft*
         TYPE OF POLYMER-*-MAGNIFLOC 985N  (NON-IONIC)
         TERMINAL HEADLOSS-* 20 psi
                                 TEST NO.
                                  AVG. INF. TURB.—5.8 FTU
                                  ALUM —182 mg/l
                                  POLYMER-"-1.7 mg/l
                                  FILTER RUN—20-30 min.
                                     UNIT CONVERSIONS:
                                      gpm/ft* x0.68= I /sec/mz
                                      psi x 0.0703 = kg /cm *
                                 TEST NO. 2
          AVG. INF TURB.--3.4 FTU
          ALUM-^174 mg/l
          POLYMER—2.1 mg/l
          FILTER RUN-ซ-60-77min.
          NO. OF RUNS—4
          TEST NO. 3
           AVG. INF TURB.-^4.6 FTU
           ALUM-*-163 mg/l
           POLYMER—2 mg/l
           FILTER RUN—22-50 min.
           NO. OF RUNS —6
                                 TEST NO. 4
                                  AVG. INF TURB.—3.5 FTU
                                  ALUM-*-160 mg/l
                                  POLYMER—-1.2 mg/l
                                  FILTER RUN —45-57min.
                                  NO. OF RUNS—7
               20
40      60      80

 FILTER RUN, minutes
100
120
Figure 18. Effect of high alum and polymer doses on the dual-
          media filter performance.

-------
   10
      OPERATING CONDITIONS:
       FEED SOURCE -—NON-NITRIFIED SEC. EFR
       FILTRATION RATE—5 gpm/ft*
       TYPE OF POLYMER --MAGNIFLOC 985N (NON-IONIC)
            T
T
                 -o-o-o
           TEST NO. 5
            AVG. INF TURB.~3.5FTU
            ALUM— III mg/l
            POLYMER-H.2 mg/l -
            FILTER RUN-*2.5 hrs-
                       3.3 hrs. _
            HEADLOSS—20 psi
                               TEST NO. 6
                               AVG. INF TURBH.7 FTU
                               ALUM-* 40.5 mg/l
                               POLYMER-^0.7 mg/l  -
                               HEADLOSS-H3.3 psi
                                         after 6 hrs.
       TEST NO. 7
        AVG. INF TURB.-2.I FTU
        ALUM—86 mg/l
        POLYMER -H.3 mg/l
        HEADLOSS-HQ.I psi
                  after 5 hrs.
                           I
               I
                    2      3'     4
                     FILTER RUN, hours
Figure 18. Continued.
                         49

-------
 PHASE  III TEST  RESULTS

     The data presented  in this section of the report include the results of
 a  long-term  filtration run encompassing a total period of about eight months.
 During this  period, the  dual-media pressure filters were operated continuous-
 ly in  parallel  at an  identical filtration rate of 3.41 1/sec/m2 (5 gpm/ft2).
 One filter was  operated  with a chemical coagulation-sedimentation pretreat-
 ment (Scheme A)  using about 150 mg/1 alum and 0.20 mg/1 anionic polymer
 (Calgon WT-3000) in the  chemical clarification system.  The other filter was
 operated with an in-line coagulation pretreatment (Scheme B or C) in which
 approximately 5 mg/1  alum was added to the rapid mixing unit and 0.05 to 0.08
 mg/1 anionic polymer  (Calgon WT-3000) injected into the filter influent line
 as a filter  aid.

 Filter Effluent Quality

     The average water"quality parameters for each treatment unit of Scheme A
 are presented in Table 6.  The test results in Table 6 show that the sus-
 pended solids level in the clarified effluent was higher than those in the
 secondary effluent.  This was due to poor solids-liquid separation in the
 sedimentation tank resulting in chemical floe being carried-over with the
 clarified effluent.  Nevertheless, as indicated by the data, solids removal
 by the filter was excellent.  The average filter effluent suspended solids
 and turbidity were 1.3 mg/1 and 0.7 FTU, respectively.  This corresponds to
 an average removal efficiency of 90.6 percent for suspended solids and 83.3
 percent for  turbidity.   Moreover, in the course of chemical .clarification
 and subsequent filtration, total phosphate was reduced about 89 percent, re-
 sulting in a filter effluent with total phosphate concentration of 0.9 mg/1 P.
 Total  COD and color were  reduced 48 percent and 38 percent, respectively.
 The total dissolved solids (TDS) was slightly increased in the filter efflu-
 ent as a result of the,high alum dosage in the chemical  clarification sys-
 tem.

     Tables  7 and 8 present the summary of the average water quality parame-
 ters for Schemes B and C.  As shown by the data in Table 7, the filter re-
moved  80 percent of the  suspended solids and turbidity, resulting in a fil-
 ter effluent with average suspended solids of 2.7 mg/1 and turbidity of 1,2
 FTU. The suspended solids removal  efficiency in Scheme C was about the same
 as  that in Scheme B.  In  addition to turbidity and suspended solids removal,
 color, total  COD and total phosphate were also slightly reduced by the filter
 in  both Schemes B and C.                                   •

     In Figure 19 is presented a plot of the filter effluent turbidity and
 percent turbidity removal as a function of experimental  run for Scheme A.
The turbidity data presented in this figure are based on 113 days run.   The
figure shows that the filter effluent turbidity levels remained stable through-
out the pilot plant study.  Analysis of the filter effluent turbidity data
show that the median and mean values of the filter effluent turbidity were
0.6 to 0.7 FTU, respectively.
                                      50

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            54

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     The daily variations in the filter effluent turbidity and turbidity re-
moval are shown in Figure 20, for Scheme B and Figure 21  for Scheme C.   The
turbidity data presented in the figures are based on 112 observations  for
Scheme B and 38 observations for Scheme C.  The median and mean values of the
filter effluent turbidity for Scheme B were 1.1 and 1.2 FTU, respectively.
For Scheme C, the median and mean filter effluent turbidity values were 1.3
and 1.4 FTU, respectively.  The results presented show that for the pretreat-
ment Schemes A, B, and C, the filter operations remained quite stable  during
the entire period of pilot plant study.

     The daily variations in the filter effluent and effluent turbidity
levels for pretreatment Schemes A, B, and C are presented as frequency curves
in Figure 22.  The observed turbidity data are fitted approximately by a geo-
metrically normal distribution and thus the line of best fit is plotted as a
straight line in log-probability paper.  The turbidity data in Figure  22 are
based on 113 days run for Scheme A, 112 days run for Scheme B, and 38  days
run for Scheme C.  As the frequency curves indicate, the turbidity levels of
the filter influent and effluent with Scheme A pretreatment were consistently
lower than those with Schemes B and C pretreatments.  The filter influent
turbidity ranged from 1.0 to 15 FTU for Scheme A, 1.5 to 16 FTU for Scheme B,
and 2.8,to 32 FTU for Scheme C.  Turbidity of the filter effluent ranged from
0.2 to 2.4 FTU for Scheme A, 0.3 to 3.7 FTU for Scheme B, and 016 to 3.7 FTU
For Scheme C.  Moreoever, the frequency curves show that 50 percent of the
time the filter effluent turbidities were equal to .or less than 0,6, 1.1, and
1.3 FTU for Schemes A, B, and C, respectively.  The observed median values'o'f
the filter effluent were about the,same as the geometric means (50 percent
observations) indicated above.  The log standard deviations of the filter
effluent were 1.7, 1.6, and 1.4 FTU for Schemes, A, B, and C, respectively.

     Figure 23 presents a log-probability plot of suspended solids removal
data through the dual-media filter for the three pretreatment Schemes  A, B,
and C.  The frequency curves show that although the filter influent suspended
solids concentrations were approximately of the same level in the three pre-
treatment schemes, the filter with a chemical coagulation-sedimentation pre-
treatment (Scheme A) consistently showed lower levels of effluent suspended
solids than those with an in-line coagulation pretreatment (Schemes B  and C).
Moreover,  the frequency curves show that 50 percent of the time the filter
effluent suspended solids concentrations were equal to or less than 0.95,
2.3, and 2.5 mg/1 for Schemes A, B, and C, respectively.  The median values
of the filter effluent suspended solids were approximately the same as the
geometric means indicated above.  The log standard deviation of the filter
effluent suspended solids was 2.3 mg/1 for Scheme A, 2.0 mg/1 for Scheme B,
and 1.8 mg/1 for Scheme C.

     It is recognized that of the many variables in filtration, the concentra-
tion as well as the physicochemical nature of the influent solids are  the pri-
mary determining factors that influence the overall filter performance.  Thus,
any pretreatment could drastically alter the physicochemical make-up of the
influent solids which could cause a corresponding change in the filter per-
formance.  With this in mind, a regression analysis was performed to determine
                                     55

-------




















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                  OPERATING PERIOD, DAYS
40
50
Figure 21. Turbidity removal through the filter with  Scheme C
          pretreatment.
                           57

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                                         58

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OPERATING CONDITIONS:
FILTRATION RATE	*- 5 gpm/ff *
AVG. ALUM DOSE, mg/l
  SCHEME A SCHEME B SCHEME C
    148.5      5.6       6.1
AVG. POLYMER DOSE, mg/\
  SCHEME A SCHEME B SCHEME C
    0.20      0.06      0.06
       •SCHEME
       .   B
                                               I   8       i
                                                  FILTER-
                                                INFLUENT
        SCHEME
                                                    FILTER-
                                                  EFFLUENT
                                    UNIT CONVERSIONS;
                                       gpm/ft2 x0.68= l/sec/m*
                       •SCHEME A
     .1 .2 .5  I  2  5  10  20   40   60   80  90 95  98       99.9
      PER CENT OF OBSERVATIONS EQUAL TO OR LESS THAN PLOTTED
                              VALUE
Figure 23. Frequency distributions of filter  influent and effluent
           suspended solids.
                               59

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 the  relationship  between  the  filter  influent and effluent suspended solids for
 the  three  types of  pretreatment schemes.   Figure 24 presents the straight line'
 of best  fit  obtained  by least squares  linear regression analysis.  In ex-
 amining  the  plots in  Figure 24, two  observations are evident.  First, for any
 of the three pretreatment schemes, the filter effluent suspended solids levels
 increase with increasing  influent suspended solids concentration.  Secondly,
 the  plots  demonstrate the effect of  type of filter pretreatment on the filter
 performance.   For instance, for any  given  filter influent suspended solids
 concentration, the  Scheme A pretreatment show consistently better filter per-
 formance than those of Schemes B and C.  Moreover, for the three pretreatment
 schemes, the correlation  coefficients exceed the 95 percent confidence coeffi-
 cient.   This  would  indicate that, with 5 percent chance of error,,effluent
 suspended  solids  is dependent on influent  suspended solids levels.

     In  Figure 25 are presented the relationship between filter effluent and
 effluent turbidities  similar  to those  shown in Figure 24.  The'straight line
 plots in this figure, which were determined by least square analysis, show
 similar  trends as those with  suspended solids.  The results of the regres-
 sion analysis indicate that at the 95  percent confidence levels, only Schemes
 A  and B  show  significant  correlation.  Scheme C did not show significant
 correlation  even at the 90 percent confidence level and this is clearly in-
 dicated  by the regression line with almost zero slope.

 Head!oss Data

     The headloss buildup through a granular filter media is influenced by
 several  factors, the  more significant of which are hydraulic surface loading
 rate, the  nature and  concentration of  influent solids, media size and fre-
 quency and type of  filter backwash.  In the course of the long-term filter
 evaluation, the two dual-media pressure filters were operated in parallel
 under identical conditions of hydraulic surface loading rate and backwash
 procedure.  Thus, the magnitude of pressure drop across the inert media
 filters would depend  primarily on the nature and concentration of influent
 suspended  solids.  Cognizant of this, a linear regression analysis  was per-
 formed in  an  attempt  to determine the relationship between the influent
 solids concentration  and the headloss buildup.   In performing the regres-
 sion analysis, the influent solids concentration was expressed in three
 different parameters; namely, turbidity in FTU, suspended solids in mg/1,  and
 solids capture in Ibs/ft2/run.  For the three pretreatment schemes, attempts
were made to  correlate each of the three influent solids  parameters with
 the total headloss across the filter after 16 hours of filter run.   The re-
 sults of the  regression analysis indicate that only Scheme A showed signi-
ficant correlation,  at 95 percent confidence level,of all  the three influent
 solids parameters with total  headloss.   In Schemes B and  C there was no
 correlation found between the headloss  and any of the three influent solids
parameters.   Figure  26 presents  the correlation between filter influent sus-
pended solids and total  headloss.   A plausible explanation for the  absence
of correlation in Schemes B and  C between the influent solids parameters
and total headloss could be attributed  to the variability of the physico-
chemical  characteristics and concentration of the influent solids during
the course of the filter runs.  It is important to recognize that because
                                      60

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                                      63

-------
of this influent solids variability, a major portion of the resulting headless
buildup could have been triggered by high solid input to the filter during  a
certain period in the course of the filter run.  The influent solids parame-
ters used in the regression analysis were based on the test of 16-hour com-
posite samples which in effect reflected the average solids concentration
during the 16-hour period.  With Scheme A pretreatment, variations  in the
secondary influent suspended solids were reduced by the equalizing  effect of
the chemical clarification-sedimentation system.  Therefore, the influent
solids concentration applied to the filter during the filter run was essen-
tially constant and could be appropriately represented by the test  of the
16-hour composite samples.

     Figure 27 presents a plot of headless buildup across the dual-media fil-
ter during the course of several selected filter runs for pretreatment
Schemes A, B, and C.  As shown in the figure, the headless levels with
coagulation-sedimentation'pretreatment (Scheme A) were considerably lower
than those of in-line coagulation pretreatment (Schemes B and C).  For in-
stance, at the end of 16 hours of filter run, the headless across the dual-
media filter ranged from 0.056 to 0.37 Kg/cm2 (0.8 to 5.3 psi) for  Scheme A,
and 0.44 to 0.86" Kg/cm2 (6.2 to 12.2 psi) for Schemes B and C.  It  is inter-
esting to note that the range of headless in Scheme B was essentially the
same as that in Scheme C.

     In Figure 28 are presented arithmetic-probability plots of total head-
loss across the filter after 16 hours of filter run.  The headloss  data pre-
sented in this figure are based on 103 days data for Scheme A, 93 days data
for Scheme B, and 34 days data for Scheme C.  As indicated by the frequency
curves, the headloss levels in the filter with Scheme A pretreatment were
appreciably lower than those observed in the filter with Schemes B  and C
pretreatments.  The headloss across the filter ranged from 0.03 to  0.37
Kg/cm2 (0.4 to 5.3 psi) for Scheme A, 0.32 to 0.99 Kg/cm2 (4.5 to 14.1 psi)
for Scheme B, and 0.32 to 0.93 Kg/cm2 (4.5 to 13.3 psi) for Scheme  C.  More-  .
over, the frequency curves indicate that 50 percent of the time the headloss
levels were equal to or less than 0.13 Kg/cm2 (1.9 psi), 0.6 Kg/cm2 (8.5 psi)
and 0.62 Kg/cm2  (8.5 psi) and 0.62 Kg/cm2 (8.8 psi) for Schemes A,  B, and C,
respectively.  The median filter headloss was 0.12 Kg/cm2 (1.8 psi) for
Scheme A, 0.58 Kg/cm2 (8.3 psi) for Scheme B, and 0.62 Kg/cm2 (8.8  psi) for
Scheme C.
                                     64

-------
  28
  24-
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FILTRATION RATE-


   o  SCHEME A-
   A  SCHEME B--
   D  SCHEME C —
— 5gpm/ft.s
 ALUM
 (mg/1)
 148.5
  5.6
  6.1
POLYMER
 (mg/l)
  0.20
  0.06
  0.06
UNIT CONVERSIONS:
   gpm/ft*x I/sec/ma
   psi x 0.0703s kg/cma
                   8       12      16     20
                      FILTER RUN, hours
                                        24
 Figure 27. Effect of pretreatment on headless.
                         65

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                                    SECTION  6

                                ECONOMIC ANALYSIS


     The  cost  estimate presented  in this  section  is  based on the treatment of
 Pomona  activated,  sludge  plant effluent for  an average design flow of 37,850
 cu m/day  (10 MGD)  and a  peak design flow  of 52,990' cu m/day (14 MGD}.  The
 process design parameters for sizing the  various  treatment components are pre-
 sented  in Table 9.  THe  unit costs  for chemicals  and other direct costs for
 estimating operation and maintenance (0/M)  costs  are summarized in Table 10.
 In Figure 29 is presented the schematic layout of the proposed filtration sys-
 tem with two types of filter pretreatment schemes.  The various treatment
 units of the overall tertiary system, which are included in the cost estimate,
 are indicated ,in  the figure.  The capital cost estimates include the cost'of
 all equipment, installation and construction costs, startup and testing, and a
 20 percent allowance for contingencies, plus a 15 percent allowance for engi-
 neering costs.  The cost of land, sludge treatment facility, chlorination sys-
.tern and interest  during  construction are not included in the cost estimate.
 In addition, the  cost of unusual construction requirements such as rock ex-
 cavation, site dewatering and extensive demolition work are not included in
 the cost estimate.

     It must be recognized that the cost estimates presented in this report
 are preliminary in nature and are used only as basis to reflect the relative
 cost of the filtration system with two types of pretreatment schemes.   The
 actual  construction bid  costs of three Sanitation Districts inert media fil-
 tration systems varying  in size from 47,312 to 141,938 cu m/day (12.5 to 37.5
 MGD) as well as data from literature (11,12,13)  have served as  a major basis
 in the preparation of the cost estimate.   The estimate of construction costs
 presented are based on ENR construction cost index of 2584 for  July, 1977.

     In Table 11  is shown the complete cost breakdown of the inert media fil-
 tration system.  The total  treatment cost to produce filter effluent with
 characteristics similar  to those presented in Tables 6 and 7 from a 37,850 cu
m/day (10 MGD) plant is  estimated at 4.27<ฃ/m3 (15.99(^/1000 gallons) for Scheme
A, and 2.29<ฃ/m3 (8.58^/1000 gallons) for Scheme  B.  The capital  costs  of the
 pretreatment system represent about 29 percent of the overall  capital  cost for
Scheme A compared to only 6 percent for Scheme B.   Moreover, in evaluating the
 0/M of each scheme, it is shown that,  for Scheme A,  the chemical  cost  alone
 represents about 63 percent of the 0/M cost and  about 36 percent of the total
 treatment cost.  For Scheme B,  on the  other hand,  the chemical  cost represents
 only 9 percent of the 0/M cost and about 3 percent of the total  treatment
 cost.   Thus, in comparing the effluent quality from the two schemes in
                                       67

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                    TABLE 9.  FILTRATION SYSTEM DESIGN DATA
PRETREATMENT SYSTEM

    1. Rapid Mixing:

         Detention time, minutes                               1.0
         Chemical Dosage
             Alum,     mg/1                                  150.0* (5.0)+
             Polymer,  mg/1                                    0.3* (0.06)+


    2. Flpeculation:

         Detention time, minutes         ,                     45.0


    3. Sedimentation:

         Detention time, hours                                 1.5
         Overflow rate, m3/day/m2                             36.6


INERT MEDIA FILTRATION SYSTEM

    1. Filtration:

         Hydraulic Surface Loading, 1/sec/m2                   2.7-4.1
         Backwash Flow Rate,        1/sec/m2                  12.2-13.6
         Backwash Volume, % of plant flow                      2.5* (5)+
         Air scour,                 1/sec/m2           '       15.2-25.4


* for Scheme A     + for Scheme B
                                      68

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TABLE 10.  UNIT COST FOR OPERATION AND MAINTENANCE ESTIMATE
 CHEMICALS

    Alum, $/Kg Al
    Polymer, $/Kg
  1.00
  4.40
 OPERATING COSTS

    Power, $/Kwh
    Backwash Water, <ฃ/m3 (Backwash/day =
     1 for Scheme A and 2 for Scheme B)
    Operating and Maintenance Labor,
     $/person-yr (4 for Scheme A and
     3 for Scheme B)
    Laboratory Personel, $/person-yr
    Maintenance Materials, $/yr
  2.50

  0.80,
12,000
15,000
20,000
 CAPITAL COSTS

    Capital costs were amortized at 7% for 25 years
                             69

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             TABLE 11.   ESTIMATED FILTRATION SYSTEM COST*
CAPITAL COSTS, (1000 of $)
Scheme A
Scheme B
1. PRETREATMENT SYSTEM
Chemical Feeding System
Chemical Coagulation-Sedimentation
System
Sub-Total
Contingencies (20%)
Sub-total
Engineering (15%)
Total Pretreatment System Costs
Amortized Cost, (tf/m3)
2. FILTRATION SYSTEM
Pumping Station
Inert Media Filtration System
i Sub^-total
Contingencies (20%)
Sub-total
Engineering (15%)
Total Filtration System Costs
Amortized Cost, (<ฃ/m3)
OPERATING AND MAINTENANCE COSTS (ซฃ/m3)
Chemicals (Alum and Polymer)
Power
Backwash Water
Operating and Maintenance Labor
Maintenance Materials
Total Operating and Maintenance Costs
Total Treatment Cost (<ฃ/m3)

113.70

506.00
619.70
123.90
743.60
111.50
855.10
0.54

171.00
1,330.00
1 ,501 .00
300.20
1,801.20
270.20
2,071.40
1.30

1.54
0.27
0.02
0.46
0.14
2.43
4.27

102.00

—
102.00
20.40
122.40
18.40
140.80
0.09

171.00
1,330,00
1,501.00
300.20
1 ,801.20
270.20
2,071.40
1 .30

0.08
0.27
0.04
0.37
0.14
0.90
2.29
*   Based on ENR construction cost index of 2584 (July, 1977) for a 37,850
    cu m/day (10 MGD-) plant.
                                  , 71

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addition to the economic analysis, it is apparent that an inert media filtra-
tion system with Scheme B pretreatment is the most practical  and economically
feasible choice for the removal of suspended and colloidal  materials from an
activated sludge plant effluent.
                                      72

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                                 REFERENCES

 1. Cookson, J.T., "The Use of Temporary Wastewater Treatment Plants:
    Standards and Procedures for Elimination of Health Hazards," report pre-
    pared for Montgomery County Council, State of Maryland (Dec. 1972).

 2. Melnick, J.L., "Detection of Virus Spread by Water Route," 13th Water
    Quality Conference, University of Illinois (1971).

 3. "Standard Methods for the Examination of Water and Wastewater," 13th Ed.,
    American Public Health Association, New York (1971).

 4. "FWPCA Methods for Chemical Analysis of Water and Wastes," Federal  Water
    Quality Administration, Cincinnati, Ohio (Nov. 1969).

 5. Cleasby, J.L., Strangl, E.W., and Rice, G.A., "Developments in Backwashing
    of Granular Filters," Proceedings of the American Society of Civil
    Engineers, Journal of the Environmental Engineering Division, Vol.  101,
    No. EE5, pp 713 (Oct. 1975).

 6. Amirtharajah, A., and Cleasby, J.L., "Predicting Expansion of Filters
    During Backwashing," Journal  of American Water Works Association, Vol.
    64, pp 52-59 (1972).

 7. O'Welia, C.R., "The Role of Polyelectrolytes in Filtration Process,"
    EPA 670/2-74-032, U.S. Environmental Protection Agency (April 1974).

 8. Hutchison, W., and Foley, P.O., "Operational and Experimental Results of
    Direct Filtration," Journal of American Water Works Association, Vol. 66,
    No. 2, pp. 79-87 (Feb. 1974).

 9. Adin, A., and Rebhun, M., "High Rate Contact Flocculation-Filtration with
    Cationic Polyelectrolytes," Journal of American Water  Works Association,
    Vol. 66, No. 2, pp 109-117 (Feb.  1974).

10. Robeck, G.G., and Kreissl, J.F.,  "Multi-media Filtration:  Principles and
    Pilot Experiments," U.S. Dept. of Interior, FWPCA, Cincinnati, Ohio
    ,(1967).

11. "Process Design Manual for Suspended Solids Removal,"  EPA 625/1-75-003a,
    U.S. Environmental Protection Agency (Jan.  1975).
                                     73

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12. Smith, R., "Electrical Power Consumption for Municipal Wastewater
    Treatment," Environmental Protection Agency Technology Series, EPA-
    R2-73-281, U.S. Environmental Protection Agency (July, 1973).
13. Patterson, W.L., and Banker, R.F..
    Requirements for Conventional Wastewater Treatment
    Pollution Control Research Series, 17090 DAN 10/71
    Protection Agency (Oct. 1971).
"Estimating Cost and Manpower
                Facilities," Hater
                  U.S.  Environmental
                                       74


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                                    TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
1. REPORT NO.
   EPA-600/2-80-148
                                                            3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
    EFFECT OF PRETREATMENT ON THE  FILTRATION OF
    LOW TURBIDITY  SECONDARY EFFLUENT
                                                            5. REPORT DATE
                                                             August  1980 (Issuing  Date)
            6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
    Leon  S.  Directo, Ching-Tin  Chen
    and Robert P.  Miele
            8. PERFORMING ORGANIZATION REPORT NO
9. PERFORMING ORGANIZATION NAME AND ADDRESS
    County Sanitation Districts  of Los Angeles  County
    Whittier,  California  90607
            10. PROGRAM ELEMENT NO.
              1BC611   SOS#5
            11. CONTRACT/GRANT NO.
                                                               14-12-150
12. SPONSORING AGENCY NAME AND ADDRESS
    Municipal  Environmental  Research Laboratory
    Office of  Research and Development
    U.S. Environmental Protection Agency
    Cincinnati,  Ohio  45268
            13. TYPE OF REPORT AND PERIOD COVERED
             Final  -  4/74-5/76
            14. SPONSORING AGENCY CODE


              EPA/600/14
15. SUPPLEMENTARY NOTES
    Project  Officer:  Irwin J.  Kugelman  (513)  684-7633
16. ABSTRACT
        A pilot study  of  filtration of  secondary effluent was  conducted.  Turbidity
   and  solids  removal were  similar for dual vs.  trimedia filters,  but headless
   was  higher  across the latter.   Coagulation-flocculation and sedimentation
   pretreatment resulted in  a  filter effluent  superior to that when  in-line
   coagulation alone was used  and a lower rate of  head loss build  up.  However,
   the  latter  produced acceptable results (s.s = 2.7 mg/1, FTU = 1.2) at much
   lower  cost.  Filtration  rate  in the range 5-10  gpm/ft2 (3.4-6.8 1/sec/m2)
   had  no effect on performance  except rate of headless build up.
17.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                              b.IDENTIFIERS/OPEN ENDED TERMS  C. COSATl Field/Group
   Sewage Treatment
   Filtration
   Coagulation
Filter Media
Suspended  Solids
Activated  Sludge
Effluent
138
18. DISTRIBUTION STATEMENT
   RELEASE TO  PUBLIC
                                               19. SECURITY CLASS (ThisReport)

                                                 UNCLASSIFIED
                                                                          21. NO. OF PAGES
                              85
                                               20. SECURITY CLASS (This page)

                                                 UNCLASSIFIED
                                                                          22. PRICE
EPA Form 2220-1 (9-73)
                                             75
                                                                   U.S. GOVERNMENT PRINTING OFFICE; 1980—657-165/0132

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