<>EPA
           United States
           Environmental Protection
           Agency
            Environmental Sciences Research
            Laboratory
            Research Triangle Park NC 27711
EPA-600/3-82-036
April 1982
           Research and Development
EPA  Complex
Terrain Model
Development

First  Milestone
Report  -  1981

-------
                 RESEARCH  REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.   Environmental Health Effects Research
      2.   Environmental Protection Technology
      3.   Ecological Research
      4.   Environmental Monitoring
      5.   Socioeconomic  Environmental Studies
      6.   Scientific and Technical Assessment Reports (STAR)
      7.   Interagency Energy-Environment Research and Development
      8.   "Special"  Reports
      9.   Miscellaneous Reports

This report has been assigned to the ECOLOGICAL RESEARCH series. This series
describes research on the effects of pollution on  humans, plant and animal spe-
cies, and materials.  Problems are assessed for their long- and short-term influ-
ences. Investigations include formation, transport, and pathway studies to deter-
mine the fate of pollutants and their effects. This work provides the technical basis
for setting  standards to minimize undesirable changes in living organisms in the
aquatic, terrestrial, and  atmospheric environments.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia  22161.

-------
                                 EPA-600/3-82-036
                                 April 1982
    EPA Complex  Terrain
     Model  Development
First Milestone Report - 1981
                     by

       T.F. Lavery, A.Bass, D.G. Strimaitis, Venkatram,
              B.R. Green, P.J. Drivas,
                     and
                   B.A. Egan
         Environmental Research & Technology, Inc.
                 696 Virginia Road
             Concord, Massachusetts 01742
               Contract No. 68-02-3421

                  Project Officer

                Francis A. Schiermeier
            Meterology and Assessment Division
         Environmental Sciences Research Laboratory
        Research Triangle Park, North Carolina 27711
      ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
         OFFICE OF RESEARCH AND DEVELOPMENT
         U S ENVIRONMENTAL PROTECTION AGENCY
      RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711

                    April 1982

-------
                                 DISCLAIMER

     This report has been reviewed by the Environmental Sciences Research
Laboratory, U.S. Environmental Protection Agency, and approved for
publication.  Approval does not signify that the contents necessarily
reflect the views and policies of the U.S. Environmental Protection Agency,
nor does mention of trade names or commercial products constitute
endorsement or recommendation for use.
                                   ii

-------
                                  FOREWORD
     The Environmental Sciences Research Laboratory (ESRL) conducts an
intramural and extramural research program in the physical sciences to
detect, define, and quantify air pollution and its effects on urban,
regional, and global atmospheres and the subsequent impact on water quality
and land use.  The Laboratory is responsible for planning, implementing, and
managing research and development programs designed to quantitate the
relationships between emissions of pollutants from all types of sources and
air quality and atmospheric effects and to uncover and characterize hitherto
unidentified air pollution problems.  Information from ESRL programs and
from the programs of other Government agencies, private  industry, and the
academic community are integrated by the Laboratory to develop the technical
basis  for air  pollution  control strategies for various pollutants.
     The Complex Terrain Model Development project is designed to develop
reliable atmospheric  dispersion models  that  are  applicable  to  large
pollutant sources  located  in  complex terrain.  The first major field  study
of  this  five-year  program  was conducted during 1980  at Cinder  Cone Butte
near Boise,  Idaho.  Data from this  field  study along with measurements  of
scaled physical  simulations performed  in  the EPA Fluid Modeling  Facility  are
being  used  to quantify the effects  of  terrain obstacles  on  stable plume
dispersion.   This  interim  report  presents the performance evaluations of
 four existing complex terrain models  and  describes the  initial developmental
 stages of  two proposed new models.
                            A. H. Ellison
                            Acting Director
                            Environmental Sciences Research Laboratory
                                      111

-------
                                  ABSTRACT

     The U.S. Environmental Protection Agency  (EPA)  is sponsoring the
Complex Terrain Model Development (CTMD),  a multi-year integrated program to
develop and validate practical plume models of known reliability and
accuracy for simulating 1-hour average ground-level concentrations downwind
of elevated sources during stable atmospheric conditions in complex
terrain.  The first major component of the CTMP was a field program
conducted during the fall of 1980 at Cinder Cone Butte (CCB), a roughly
axisymmetric, isolated 100-meter hill located in the broad Snake River Basin
near Boise, Idaho.  The field program consisted of ten flow visualization
experiments and 18 multi-hour tracer gas experiments conducted during stable
flow conditions.
     The data base compiled at CCB includes the following components:

     •    Source information:   emission rates,  locations, and heights of
          SFg,  CF^Br,  and oil-fog releases.
     •    Meteorological information:  descriptions of the undisturbed
          mesoscale valley flow in the vicinity of CCB as well as
          information  on flow and dispersion on and over CCB itself.
     •    Hill  surface tracer gas concentrations:   data from more than
          14,000 individual bag samples  collected  over the  18 days  of
          experiments  from as  many as 80 sampler locations  in a given
          experiment.
     •     Lidar  data:   characterizing the  plume  trajectory\ and plume  spread
          upwind and over CCB.
     •     Photographic  data:   still  photographs  taken from  fixed  locations
          on  and around CCB,  aerial  photographs  taken from  an aircraft
          flying overhead,  and  16 mm movies and  videotapes.
                                     IV

-------
     This report presents an overview of the CCB experiment and the results
of the modeling analyses completed through June 1, 1981.   The objectives of
the model analyses are to develop and evaluate new models using the CCB data
base and to compare their performance to the following current complex
terrain dispersion models:

     ©    the EPA Valley model worst-case screening algorithm, widely used
          in regulatory practice to screen elevated sources in complex
          terrain;
     •    COMPLEX I and COMPLEX II, two new proposed complex terrain
          screening models issued by EPA for public testing and evaluation;
          and
     9    PFM, a potential flow model for turbulent dispersion of plumes in
          the presence of simple terrain features.

For these comparisons, 45 case study hours were selected from the 18 field
experiment days.  (The PFM model comparisons were made with about half of
these case study hours.)
     Two new modeling approaches suggested by the experimental evidence have
been formulated and tested.   One new model  (called  the Impingement model) is
used to  simulate ground-level concentrations in strongly stable flows  in
which plumes go horizontally  around  the  side of CCB; another  new model
(called  the Neutral model) simulates slightly stable or  neutral flows  in
which plumes rise over CCB.   It must be  emphasized, though, that these new
models—which  thus far represent only a  modest  level of  effort—are
tentative first steps toward  the goal of practical, reliable  complex  terrain
models.  They  are not the desired  end results and are in no way identified
for routine application  at  this  time.
     All models were  evaluated by  comparing 1-hour  average observed
concentrations with 1-hour average calculated concentrations. The results
are encouraging:  the two preliminary models appear to simulate maximum
concentrations and spatial concentration patterns more realistically  than
the current models.
                                  v

-------
     This report was submitted in partial fulfillment of  Contract  68-02-3421
by Environmental Research & Technology, Inc. under the sponsorship of the
U.S. Environmental Protection Agency.  This report covers the period
June 26, 1980 to June 1, 1981, and work was completed as of June 1, 1981.
                                   VI

-------
                               CONTENTS
                                                                Page
_       ,                                       	111
Foreword ... 	
Abstract	•	1V
_.,.                                                  	ix
Figures	
Tables	•	xv
Symbols and Abbreviations	•  xviii
Acknowledgements 	  XX1
1.    Introduction  . . 	
     1.1  Overview of Complex Terrain Model Development   ...    1
     1.2  Basic Concepts of Plume Dispersion in Stable Flows  .    6
2.   Overview of Complex Terrain Field Study 	   10
     2.1  Geographic and"Meteorological Setting   	   10
     2.2  Fluid Modeling of Expected Flow Regimes	   17
     2.3  Experimental Design of Field Study 	  ...   23
     2.4  Field Study Res.ults	   45
3.   Quality Assurance Program  	   70
     3.1  Meteorological Data	. . ;	   71
     3.2  Tracer Data	•  •   95
4.   Air Quality Models  Evaluated   	   103
     4.1  Introduction	•  •   103
     4.2  Valley Model	 104
     4.3  COMPLEX  I  and  COMPLEX II  Models	1°6
     4.4  Potential  Flow Model	109
     4.5  New Experimental Models	   114
5.   Model  Performance  Using  Cindor Cone  Butte Field Data  .  .   128
     5.1  Case  Hours Selected for Model Evaluations   	   128
      5.2  Data  Preparation	129
                                  Vii

-------
                         CONTENTS (Continued)
                                                                Page
     5.3  Model Evaluation Methods 	  132
     5.4  Sample Case Study Results - Case 205, Hour 5 ....  145
     5.5  Summary of Model Performance 	  184
6.   Conclusions and Recommendations for Further Analysis and
     Development	221
     6.1  Accomplishments in Overview	221
     6.2  Comparative Model Performance Evaluations  	  224
     6.3  Recommendations for Further Research 	  227
References	236
Appendices

     A.   Summary of Tracer Data Analyzed for Tests 201-218   .  239
     B.   Laboratory Simulation of Stable Plume Dispersion
          Cinder Cone Butte	249
     C.   Use of Model Performance Statistics  	  302
                                Vlll

-------
                                   FIGURES
Number
Page
1

2
3
4
5
6
7


8

9

10
11
12
13
14
15
Schematic of flow around a three-dimensional obstacle at




Aerial view of Cinder Cone Butte from south 	 	

Distribution of wind speed and direction for September
1965-1969 derived from weather observations at

Composite estimates of plume paths based on towing tank
simulations: wind direction 110°, Fr = 0.4 	 ,
Composite estimates of plume paths based on towing tank
simulations: wind direction 300°, Fr = 0.4 	 ,





Bag sampling and analysis procedures 	 . . ,

9
11
12
13
14
15


16

21

22
25
28
32
34
36
37
                                  IX

-------
FIGURES
JNumbe
16
17
18
19
20
21

22

23

24

25

26

27

28

29
30

31

32
33

34

r
Procedures to obtain tracer gas concentrations 	



Number of samples analyzed for each field experiment ....
Observed SFg concentrations (ppt) for Case 206,
0500-0600 	
Five-minute exposure; camera location 0-15 (Case 206,
0500 MST) 	
One-minute exposure looking from northeast (Case 206,
0508 MST) 	
Five-minute exposure; camera location 0-15 (Case 206,
0530 MST) 	
One-minute exposure looking from North Peak (Case 206,
0540 MST) 	
Five-minute exposure; camera location 0-11 (Case 206,
0546 MST) 	
Observed SFg concentrations (ppt) for Case 211,
0400-0500 	
Observed CF3Br concentrations (ppt) for Case 211,
0400-0500 	
One-minute exposure from southwest (Case 211, 0414 MST). . .
One-minute exposure from lee side of Cinder Cone Butte
(Case 211, 0435 MST) 	
Observed CF3Br concentrations (ppt) for Case 210
0200-0300 	
Observed SF6 concentrations (ppt) for Case 210, 0200-0300.
One-minute exposure looking from South Peak (Case 210,
0209 MST) 	
One-minute exposure looking from southwest (Case 210,
0535 MST) 	
Page
38
40
42
44
49

52

54

55

56

57

58

60

61
62

63

65
66

67

68

-------
                                  FIGURES
Number

 35     Observed SFg concentrations (ppt) for Case 205,
          0400-0500	     69

 36     Example of a data file.	     92

 37     Example of an edited data file	•     93

 38a    PFM geometry for Cinder Cone Butte calculations 	    112

 38b    Illustration of the relationship between the tracer release
        height and important reference surfaces at CCB	    113

 39     Geometry used in formulating Impingement model for low
          Froude number flows 	

 40     Geometry used in formulating Neutral model for high Froude
          number flows	

 41     Dependence of lidir-derived Oz on downwind distance
          for 15 case hours	«	

 42     Relationship between model inputs, single concentration
          observations, and the set of possible concentrations
          described by model inputs 	    138

 43     Relationship between an observed concentration and estimates
          of this concentration from models A and B when these
          models accurately simulate the ensemble mean
          concentration	• •    139

 44     Relative performance of different models. . 	  ...    144

 45     Observed SFg concentrations for  Case 205, 0400-0500  ...     146

 46     COMPLEX I:  calculated SFg concentrations for  Case 205,
          Hour  5, Stability Class D .  .	•	    1*8

 47     COMPLEX I:  calculated SFg concentrations for  Case 205,
          Hour  5, Stability Class E .	    149

 48     COMPLEX I:  calculated SFg concentrations for  Case 205,
          Hour  5, Stability Class F	  ...    150

 49     COMPLEX II:  calculated SFg concentrations  for Case  205,
          Hour  5, Stability Class D	    151

 50     COMPLEX II:. calculated SFg concentrations  for Case  205,
          Hour  5, Stability Class E	   152

                                   xi

-------
                                   FIGURES
Number
Page
 51     COMPLEX II:  calculated SFg concentrations for Case 205,
          Hour 5, Stability Class F	    153

 52     COMPLEX I and II:  calculated SFg concentrations versus
          observed SFg concentrations for Case 205,  Hour 5,
          Stability Class D	    155

 53     COMPLEX I and II:  calculated SFg concentrations versus
          observed SFg concentrations for Case 205,  Hour 5,
          Stability Class E	    156

 54     COMPLEX I and II:  calculated SFg concentrations versus
          observed SFg concentrations for Case 205,  Hour 5,
          Stability Class F	    157

 55     PFM:  calculated SFg concentrations for Case 205,
          Hour 5, Stability Class D	    169

 56     PFM:  calculated SFg concentrations for Case 205,
          Hour 5, Stability Class E	    170

 57     PFM:  calculated SFg concentrations versus observed SFg
          concentrations for Case 205, Hour 5, Stability Class D.  .    172
                                         \
 58     PFM:  calculated SFg concentrations versus observed SFg
          concentrations for Case 205, Hour 5, Stability Class E.  .    173

 59     Neutral model:  calculated SFg concentrations for
           Case 205,  Hour 5	    179

 60     Neutral model:  calculated SFg concentrations versus
          observed SFg concentrations for Case 205,  Hour 5. ...      180

 61     Variation of  modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations calculated
          by Valley	    187

 62     Variation of  modeled—to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated  by Valley (centerline) 	    188

 63     Variation of  modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated  by COMPLEX I (Stability Class D) 	    192

 64     Variation of  modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated  by COMPLEX I (Stability Class E) 	    193

                                  xii

-------
                                   FIGURES
Number
 65     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by COMPLEX I (Stability Class F) .......   194

 66     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by COMPLEX I (Appropriate Stability Class -
          Turner Scheme) .............«•••.••••.••  195

 67     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by COMPLEX II (Stability Class D) .......  196

 68     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by COMPLEX II (Stability Class E) 	  197

 69     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by COMPLEX II (Stability Class F) 	  198

 70     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by COMPLEX II (appropriate stability class -
          Turner Scheme)	1"

 71     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by PFM (Stability Class D)	 ......  202

 72     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by PFM (Stability Class E)	  203

 73     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by the Impingement model	206

 74     Variation of modeled-to-observed ratios of maximum hourly
          SFg concentrations with modeled concentrations
          calculated by the Neutral model	208

 75     Relative performance of mpdels tested with 45 case hours
          of data from CCB with model performance based on ratios
          of maximum calculated and observed hourly SFg
          concentrations	212

 76     Relative performance of models tested with 45 case hours
          of data from CCB with model performance based on residuals
          of maximum calculated and observed concentrations.  . . •  •  213

                                   xiii

-------
Number
 77
 78
 79
                                   FIGURES
Relative performance of models tested with 45 case hours
  of data from CCB with model performance based on residuals
  of calculated and observed hourly SFg concentration
  at all samplers*	214
Relative performance of models tested with 23 case hours
  (release height > Hcr^t) of data at CCB with model
  performance based on ratios of maximum calculated and
  observed SF$ concentrations	
Relative performance of models tested with 23 case hours
  (release height > Hcr£t) of data at CCB with model
  performance based on residuals of maximum calculated
  and observed SFg concentrations	
 80
Relative performance of models tested with 23 case hours
  (release height > Hcrit) of data at CCB with model
  performance based on residuals of calculated and
  observed SFg concentrations at all samplers	
                                                                      217
                                                                      218
                                                                      219
                                  xiv

-------
                                   TABLES
Number
1

2
3
4
5
6
7
8
9
10

11

12
13
14

Prevailing Wind Direction and Frequency at Mountain
Home AFB (October 1964-1970) 	 	

SFg and CF3Br Release Rates. 	 	 » •
Sample Analysis Programs Available Onsite. 	 	
Summary of Tracer Data Analyzed. ... 	
Audit Results: Climatronics Temperature System 	
Audit Results: Climatronics Delta Temperature System. . . •
Audit Results: Climatronics UVW Wind Systems 	
Audit Results: F460 Wind Speed System 	 	
Audit Results: Climatronics F460 Wind Direction

Audit Results: Climatronics F460 Wind Direction
Linearity Test 	 	
Audit Results: Orientation of V Propeller Crossarm 	
Audit Results: F460 Wind Direction Systems Errors 	
Audit Results: Landmark and North Stake Orientation


18
26
31
46
47
74
75
76
78

79

80
81
82

83
                                   XV

-------
                                   TABLES
Number

 15


 16

 17

 18

 19

 20


 21


 22

 23



 24



 25



 26


 27


 28


 29


 30


  31
Classification Criteria and Data Quality Flags for
  Hour-Averages Produced from 5-Minute Data . . .
Recount Statistics	

Co-Located Sampler Statistics

Sample Degradation Test . .  .

TRC Audit Results 	
Comparison of Oz Derived from Lidar Observations with
  Predicted a.
Data Estimated at Source Height for Case Hours Selected
  for Model Comparisons 	
Descriptive Statistics and Associated Analyses.
Frequency Distributions of SFg  Concentrations for
  COMPLEX I and II Models (Case 205, Hour  5, Stability
  Class D). .  .	

Frequency Distributions of SF6  Concentrations for
  COMPLEX I and II Models (Case 205, Hour  5, Stability
  Class E)	

Frequency Distributions of SFg  Concentrations for
  COMPLEX I and II Models (Case 205, Hour  5, Stability
  Class F)	

Observed Versus COMPLEX I Paired Concentrations (Case
  205, Hour 5, Stability Class  D)	<
 Observed  Versus  COMPLEX I Paired Concentrations (Case
   205,  Hour 5, Stability Class  E) 	
 Observed  Versus  COMPLEX I Paired Concentrations (Case
   205,  Hour  5, Stability Class F) 	
 Observed  Versus  COMPLEX II Paired Concentrations (Case
   205,  Hour 5, Stability Class D)	•
 Observed Versus  COMPLEX II Paired Concentrations (Case
   205,  Hour 5, Stability Class E) 	
 Observed Versus COMPLEX II Paired Concentrations (Case
   205,  Hour 5,  Stability Class F)	 .  .  .
 94

 97

 97

 99

100


125


133

136



158



159



160


161


162


163


164


165


166
                                   xvi

-------
                                   TABLES
Number

 32


 33


 34


 35


 36


 37

 38


 39


 40


 41


 42

 43

  44  •

  45

  46

  47

  48
Summary Statistics for COMPLEX I and II (Case 205,
  Hour 5) 	

Frequency Distributions of SF6 Concentrations for
  PFM (Case 205, Hour 5, Stability Class D) . . .
Frequency Distributions of SFg Concentrations for
  PFM (Case 205, Hour 5, Stability Class E) . . .
Observed Versus PFM Paired Concentrations (Case 205,
  Hour 5, Stability Class D)	
Observed Versus PFM Paired Concentrations (Case 205,
  Hour 5, Stability Class E). . . 	
Summary Statistics for PFM (Case 205, Hour 5)
Frequency Distributions of SF6 Concentrations for
  Neutral Model (Case 205, Hour 5)	
Observed Versus Neutral Paired Concentrations (Case 205,
  Hour  5)	•	'	

Summary Statistics  for Neutral Flow Model  (Case  205,
  Hour  5)	'

Summary C/Q Statistics for Valley  and  Centerline Valley
  Calculations	•	

Summary C/Q Statistics for COMPLEX I Calculations ....

Summary C/Q Statistics for COMPLEX II  Calculations.  .  .  .

Summary C/Q Statistics for PFM  Calculations  	

Summary C/Q Statistics for Impingement Model Calculations

 Summary C/Q Statistics for Neutral Model Calculations  .  .

 Summary of Analysis of  C/Q Residuals  - All Case Hours  .  .

 Summary of Analysis of  C/Q Residuals  for Hours  in which
   H > Hcr-[t + 5 m . . •	
                                                                      Page
168


174


175


176


177

178


181


182


183


185

189

190

 201

 204

 207

 210


 216
                                   xvi i

-------
SYMBOL
                      LIST OF SYMBOLS AND ABBREVIATIONS
  scat
  max
 d
 36/3 z
 3p/3z
 D ,  D
  y»   z
 £
 Fr
 g
 h
 H

 Hcrit
 IX, IY, IZ
 A
 m
  g
Horizontal distortion factor
Scattering coefficient
Concentration
Instantaneous concentration
Maximum hourly averaged concentration
Observed concentration
Modeled concentration
Distance of source to receptor
Vertical potential temperature gradient
Vertical density gradient
Ratio of plume spread in complex terrain to plume spread
over flat terrain
Error or residual
Ratio of streamline spacing at the source to that at a
given downwind distance
Hill factor
Froude number
Acceleration caused by gravity
Hill height
Height of the plume centerline above the ground over flat
terrain
Critical dividing streamline height
Turbulence intensities alongwind, crosswind, and vertical
Vertical length scale of turbulence
Geometric mean
                                   xviii

-------
N
n
 r,6,z
 w
a
    '
  ze
 u
  s
 U, u
 X
 x
 x,,
 z.
  1
Brunt-Vaisala frequency.
Height of plume centerline over a, terrain feature
Fractional height of plume centerline over a terrain
feature
Angle between stagnation streamline and U
Instantaneous angular plume spread
Tracer emission rate
Surface heat flux
CCB polar coordinate system coordinates
Geometric standard deviation
Standard deviation of distribution of model errors or
residuals
Standard deviation of horizontal wind direction
Standard deviation of vertical velocity fluctuations
Standard deviation of crosswind tracer distribution
Crosswind and vertical standard deviations of tracer
concentrations in flat terrain setting
Standard deviation of vertical tracer distribution
Effective total hourly standard deviation of vertical
tracer distribution derived from lidar sections
Integral time scale
Average temperature
Wind  speed at source
Uniform wind speed of flow approaching hill
Stream function
Distance downwind from source
Set of known model input variables
Set of unknown variables affecting  plume dispersion
Mixed layer height
Plume release height
ABBREVIATIONS
   CCB
   DBMS
 Cinder Cone Butte
 Data Base Management System
                                    xix

-------
EPA
ERT
FMF
GC
MRI
MST
NAWC
NOAA
NRTS
ppb
ppt
PG
PFM
RTD
TRC
WPL
 U.S.  Environmental  Protection Agency
 Environmental Research  &  Technology
 Fluid Modeling  Facility
 Gas chromatograph
 Meteorology Research, Inc.
 Mountain Standard Time
 North American  Weather  Consultants
 National Oceanographic  and Atmospheric Administration
 National Reactor Testing  Station
 Parts per billion by volume
 Parts per trillion by volume
 Pasquill-Gifford
 Potential Flow Model
 Resistance Thermometric Device
 TRC Environmental Consultants, Inc.
Wave Propagation Laboratory
                                 xx

-------
                               ACKNOWLEDGMENTS

     Many people—far too many, in fact, to acknowledge here individually—
contributed their talents and energies to making a success of the Cinder
Cone Butte (CCB) experiment.  We wish to emphasize the extraordinary efforts
of colleagues without whom the experiment would never have flown.  First,
our colleagues at ERT and WSSI:  Mike Onorato and Bob Ledwith, who both
worked many long days and nights to configure, program, install, and check
out the data base management system; Jim Wallace, who did much of the
scientific software development; Jim Wagner, Robert Lehmann, Paul Shultz,
and Tom Swafford, who labored literally around the clock to install and
check out the tower instrumentation and data communication links; Dan
Godden, who captained the computer command center through many long
experiments; Bob Hatcher, who devoted many weeks to designing, planning, and
supervising the field execution of the CCB experiment; and especially Norm
Ricks, whose mechanical wizardry, resourcefulness, and sheer persistence in
conquering a myriad of mechanical problems was an inspiration to us all.  We
also want to thank Tony Curreri and Jack Beebe, who assembled the modeling
system so quickly; and especially Don DiCristofaro, Jonathan Pleim, and Bill
Adamski, who worked long days and nights to do all the model runs and
analyses, accurately and completely, in truly record time.
     Next, we can thank but a few of many other colleagues who struggled
with us to carry this off:

     9    Tim Spangler and George Taylor of NAWC, our field general and
          deputy field general at CCB, who superbly directed the complicated
          logistics of the field operations.  Their fortitude, energy, and
          unfailing patience throughout many difficulties were crucial to
          the harmonious operation of the field program.
                                    xxi.

-------
     •    Bill Snyder of the EPA Fluid Modeling Facility, the godfather of
          the "small hill" experiment, whose many helpful suggestions in
          calling the shots during both phases of the field program were
          invaluable and whose pyrotechnic and photographic triumphs at CCB
          are truly memorable I
     •    Wynn Eberhard and colleagues from the NOAA Wave Propagation
          Laboratory, who labored with us during Phase II to generate the
          lidar data base.
     •    Julian Hunt, for his many useful suggestions for modeling the flow
          regimes at CCB.

     And finally, our special thanks to Frank Schiermeier and George
Holzworth, whose unflagging enthusiasm, support, and warm encouragement
truly made the difference.
                                    xxii

-------
                                  SECTION 1
                                INTRODUCTION

1.1  Overview of Complex Terrain Model Development

     At a time of growing national pressure to expedite decisions on the
regulatory acceptability of new energy-development facilities and other
major air pollution sources, it is imperative to improve the air quality
models that play critical roles in decision-making—especially when models
in wide regulatory use are regarded as insufficient by many of the modelers
who use them.  In particular, problems of plume transport and dispersion in
complex terrain urgently require more reliable models.
     The Valley model (Burt 1977), widely used for such problems, is
recommended for preliminary screening analyses only.  The U.S. Environmental
Protection Agency (EPA) does not recognize any current model as generally
reliable for refined source analyses in complex terrain.
     Recognizing its special responsibility to encourage the development of
more reliable complex terrain models for regulatory decision making, EPA's
Environmental Sciences Research Laboratory convened an expert technical
workshop in July 1979 to address outstanding problems of dispersion model
development for sources in complex terrain (Hovind et al. 1979).  The
workshop's specific objective was to make recommendations to EPA for the
design of an extensive research program to support the development of more
credible models for regulatory applications.
     The general consensus of the workshop supported EPA's suggested focus
on stable plume impaction and its multiphased approach to progressive model
refinement:
     The Workshop participants agreed in principle that EPA should adopt a
     two-phased field program approach, starting with a controlled
     experiment on a small, isolated hill of simple geometric setting, and

-------
     then proceeding with a large scale program of increased complexity.  It
     was also recommended that the model development program follow multiple
     phases.  The initial effort should be oriented towards improvements in
     Gaussian-based models, while the final effort should be aimed towards
     new model development incorporating complex flow fields in rough
     terrain with either Gaussian-based or "K theory" based models.
     Physical modeling 'programs should be an integral part of the above
     efforts (Hovind et al. 1979).

     Proceeding with the workshop recommendations, EPA undertook the

preliminary conceptual design of such a multi-year integrated program in

which paramount emphasis was placed upon the "production of a useful model
(or models) with demonstrated reliability and prescribed applicability"

(Holzx«>rth 1980).  During the field measurements and laboratory experiments

throughout the program, the observational needs of the modelers were to be

foremost in importance.  The program was perceived as "an integrated and

highly coordinated effort that involves:


     (1)  model evaluation/improvement/development,

     (2)  scaled physical modeling in a fluid modeling laboratory,

     (3)  field measurements/experiments centered on an isolated, simple

          hill, and
     (4)  field measurements/experiments centered on a full-scale
          plant....in terrain with opportunities for plume impaction and

          other types of plume-terrain interactions" (Holzworth 1980).


     In June 1980 a contract was awarded for this program, called the EPA

Complex Terrain Model Development.*  The stated goal of this study is to
 *The prime contractor for the study is Environmental Research and
  Technology, Inc.  (ERT).  Its principal subcontractors are Western
  Scientific Services, Inc.  (WSSI), responsible for fixed meteorological
  data  (towers, instrumentation and data communication), and North American
  Weather Consultants (NAWC), responsible  for the experimental field program
  (tracer and smoke releases, tracer data  collection, photography, mobile
  meteorology, and  field  logistics).   In allied activities, the EPA Fluid
  Modeling Facility (FMF) has provided laboratory fluid modeling support;
  the NOAA Wave Propagation  Laboratory has  supported the field program with
  a manned lidar system;  and TRC,  Inc. has  provided independent data audits.

-------
develop and validate practical plume models of known reliability and
accuracy in order to simulate 1-hour average* ground-level concentrations
during stable atmospheric conditions in complex terrain downwind of elevated
sources.  The models must be reasonably economical and easy to use,
and—most importantly-—their accuracies, limitations, and restrictions must
be well understood.
     In accordance with EPA's preliminary planning to meet this goal, this
study comprises field observations and measurements, laboratory fluid
modeling, data archiving and analysis, and model development and
evaluation.  The primary field measurement data gathered by the contractor
are supplemented by experiments at the EPA Fluid Modeling Facility (FMF),
and the model development and evaluation tasks are guided by complementary
work at the EPA Meteorology and Assessment Division.
     The first major field program was conducted during the fall of 1980 at
Cinder Cone Butte (CCB), a roughly axisymmetric, isolated 100-meter hill
located in the,broad Snake River Basin near Boise, Idaho.  The field program
consisted of a preliminary, learning phase followed by a second, intensive
measurement phase.
     The first phase (September 16-27, 1980) comprised 10 experiments
(performed mostly at night) to check out and refine the field program and to
gain operational and logistical experience.  The objectives of this phase
were:  (1) to practice techniques for generating and photographing oil-fog
plumes and (2) to practice procedures for choosing plume release locations,
release heights, and sampler locations on CCB in order to "capture"
different flow regimes or different aspects of plume-hill behavior.
*Short-term ambient air quality standards and increments for S02 and
 particulates are expressed as maximum 3—hour or 24—hour averages, but the
 ability to estimate 1-hour averages successfully is a necessary first step
 toward models for the longer averaging times.

-------
                                                         If
     The second phase (October 16-November 12, 1980) comprised 18 multihour
experiments conducted in the late evening, night, or early morning hours
during primarily stable flow conditions.  The experimental program
concentrated on measurements of ground-level tracer gas (SF6 and CF^r)
concentrations on the butte as well as lidar sections through the plume and
an intensive set of fixed and mobile meteorological measurements and
photographic documentation.  Most experiments lasted eight hours with tracer
gas releases during at least five or six hours.
     When the project was begun in June 1980, the experimental approach and
methods for such a small hill study appeared promising but were untested.
Looking back, we may conclude that the CCB experiment was largely successful
and fulfilled its basic goal: creating an extensive, well-documented archive
of reliable meteorological, plume trajectory, and tracer concentration data
to illuminate the physics of plume transport and diffusion in the presence
of such a hill under stable nocturnal flow conditions.  This unique data
archive will provide—more effectively than any previous data base—an
empirical foundation for developing models of stable plume impingement on
three-dimensional, nearly axisymmetric hills.
     The data base compiled at CCB includes the following important
components:

     •     Source  information:  emission rates, locations, and heights  of
           SF,, CFoBr, and oil-fog releases.
     •     Meteorological information:   descriptions of  the undisturbed
          mesoscale valley  flow  in the vicinity  of  CCB  as well  as
           information on flow and dispersion  on  and over  CCB  itself.
     •     Hill  surface  tracer gas concentrations:   data from more  than
           14,000  individual bag  samples collected  over  the 18 days  of
           experiments  from as many as 80  sampler locations in a given
           experiment•
      •     Lidar data:   sections  across the plume characterizing the plume
           trajectory and  plume  spread upwind of  CCB.
      •     Photographic  data:  still  photographs  taken from fixed locations
           on and around CCB, aerial  photographs  taken from an aircraft
           flying overhead,  and  (occasional) 16 mm movies  and  videotapes.

-------
     The problems that developed during the field program were caused mainly
by insufficient lead time to procure and successfully install all needed
equipment, data communication outages or instrument failures in the
real-time monitoring network, and failures in gas sampler collection or
processing.  Immediately after the field program ended, a substantial effort
was undertaken to edit, validate, and assess the reliability of all
meteorological and tracer gas data.  Although more remains to be done, the
result to date is an excellent data base for model development.
     The major objectives of the model analyses are to develop and evaluate
the performance of new models against the observational data at CCB and to
compare their performance to the following current complex terrain
dispersion models:

     e    the EPA Valley model worst-case screening algorithm, widely used
          in regulatory practice to screen elevated sources in complex
          terrain;
     «    COMPLEX I and COMPLEX  II, two new proposed complex terrain
          screening models issued by EPA for public testing and evaluation;
          and
     •    PFM, a potential flow model for turbulent dispersion of plumes  in
          the presence of simple terrain features.

For these comparisons, 45 case study hours were  selected  from the 18  field
experiment days.  (The PFM model comparisons were made with about half of
these case study hours.)
     We have begun  to  formulate  and test new modeling approaches suggested
by the experimental evidence  studied to date.  One new model  (called  the
Impingement model)  is  used to simulate grounds-level concentrations  in
strongly  stable  flows  in which plumes go horizontally around  the side of
CCB; another new model  (called the Neutral model)  simulates slightly  stable
or neutral flows in which plumes rise over CCB.   It must  be emphasized,
though,  that these  new models—which thus  far  represent only  a modest level
of effort—are tentative first steps toward the  goal of practical,  reliable

-------
 complex terrain models.  They are not the desired end results and are in no
 way identified for routine application at this time.
      All models were evaluated by comparing 1-hour average observed
 concentrations with 1-hour average predicted concentrations.   The
 descriptive statistical measures used were chosen according to the
 recommendations of a recent American Meteorological Society workshop (Fox
 1981).  These were supplemented with special statistical measures to
 describe the mean and peak concentration ratios that were quite useful  for
 summarizing comparative model performance.
      The early results are encouraging:  the two provisional models appear to
 simulate maximum concentrations and spatial concentration patterns more
 realistically than the screening models.   Much of the data base remains  to
 be analyzed,  however.   In the future,  better model results may be
 achieved—when,  for example,  all of the  lidar data collected  at CCB have
 been analyzed,  or the  existing photographic and meteorological data archives
 have been more  fully used,  in conjunction with fluid modeling experiments,
 to extend the data base for developing and validating complex terrain plume
 models.

 1.2 Basic  Concepts  of Plume  Dispersion  in Stable  Flows

     Throughout  this report,  two  basic concepts are  used  to characterize the
 flow around a hill—the Froude number and  the dividing streamline height.
 Important dynamic  features  of  flow around  an  isolated hill are  characterized
 by the hill Froude number  (Fr), defined by
                               Fr
U/Nh
(1)
where U is the uniform wind speed of the flow approaching the hill, N is the
Brunt-Vaisala frequency, and h is the height of the hill.  The stability of
the flow is described in terms of the Brunt-Vaisala frequency, N, which can
be written as
                                 '  6

-------
                          N  =
                                                       (2)
where 36/3z is the stable potential temperature gradient (assumed to be
uniform over the height of the hill), g is the acceleration caused by
gravity, and T  is the average temperature.
     In physical terms, the hill Froude number is the ratio of the inertia
of the flow to the buoyancy force that suppresses motion in the vertical.
Another physical interpretation of Fr can be obtained by recasting
Equation 1 in terms of the density gradient and squaring both sides:
                           Fr2 =
                       PIT
                                 gh2(-3p/8z)
                                                      (3)
        2
Here, Fr  is the ratio of the kinetic energy of the fluid to the potential
energy gained by the fluid as it rises through the stable density gradient
to the top of the hill.
     A hill Froude number less than unity implies that a fluid parcel at the
bottom of the hill will not have sufficient kinetic energy to rise to the
top of the hill and thus will be forced to go around it.  A hill Froude
number of unity or greater implies that the fluid parcel can rise to the
top.  These concepts can be refined by introducing the dividing streamline
height, H   . , defined by the following integral formula (Snyder 1980a):
- g
                   crit
                          (h-.)  (If
                                                       (4)
where U  is evaluated at z = ^crit and  (3p/3z) is the local
density  gradient.  The left-hand side  of Equation 4 is the kinetic
energy of a  fluid  parcel at this critical height, and the right-hand
side is  the  potential energy gained by the fluid parcel rising through
the height h-H   .  .  The equality in Equation 4 implies that

-------
 is  the height at which  the  fluid  has  just  enough  kinetic  energy  to
 ascend the  hill.   If  the  wind  speed increases with  height,  fluid
 parcels originating below H    are forced to either  stagnate  on the
 hill or flow horizontally around  it.
     For a  constant wind  and density  gradient,  Equation 4 reduces to
                            H
                             crit
(5)
Note  that H   .  embodies  the  physics of  the  hill  Froude number, but  in a
more  flexible manner:   it also accounts  for  nonuniform temperature and
velocity profiles.  For Fr+0, Hh, suggesting that most of the flow
goes around the hill.  When Fr*!, H   • t~*"0,  implying that most of the fluid
goes over the hill.  Under these conditions, the flow pattern away from the
surface on the windward side of the hill can be modeled to a first
approximation as inviscid potential flow (Hunt et al. 1979).
     When Fr is close to zero, the flow around a three-dimensional obstacle
such as CCB is essentially horizontal (Drazin 1961).  Plumes embedded in
such a flow field will not be significantly displaced upward as they
disperse around the hill.  Hunt et al. (1979) show that, given certain
limiting assumptions, this problem of plume impingement can be reduced to
that of two-dimensional diffusion of a line source around a cylinder.  The
axis of the cylinder is parallel to the z-axis, and the cylinder has the
same cross section as the hill at the height of release z .  Figure 1
shows plume behavior under such conditions.  When the hill Froude number is
greater than unity, the flow (and hence a plume embedded in the flow) will
go over the top of the hill.

-------
     0)
 +->  X
 s  o
 (D
 i— I  (U
 a-
 tt)
 pi  CD
 O  O
•H  £-(
 w  3
 f-l  O   •
 CD  W    f-i
 PH    NI

•H  fi  CD

    i—I  rt
m      o
 O  cd i—t
         0)
 S  B  M
 CD  O
rH  (-1 <4H
rQ <+•!  O
 O
 ?-l  S -P
 f^^ O p^
    •H  IX)
 CD  t/) -H
         0)
     PH
 0)
 O   O
Z,   +->

-------
                                  SECTION 2
                   OVERVIEW OF  COMPLEX TERRAIN FIELD  STUDY

2.1  Geographic and Meteorological Setting

     Cinder Cone Butte, Idaho,  the site selected for the flow visualization
and tracer experiments, is an isolated hill in the Snake River Basin,
located about 30 miles south-southeast of Boise and 15 miles northwest of
Mountain Home Air Force Base (AFB) (see Figure 2).  This site was selected
for the following reasons:  (1) the butte is the dominant terrain feature
for many miles; (2) fairly simple meteorological conditions prevail during
the fall months; (3) the area is easily accessible and has available
electric power and telephone lines; (4) the Bureau of Land Management  (which
manages the Bruno Resource Area in which CCB is located) was willing to
grant permission for use of the butte; and (5) the local farmers were
willing to lend or rent their facilities and land for the experiments.
     Cinder Cone Butte is a two-peaked, roughly axisymmetrical hill about
100 meters (m) high.  Its nearly circular base is about 1 kilometer (km) in
diameter (Figure 3).  Figure 4 presents side views of the butte from the
north, northeast, and east; Figures 5 and 6 are aerial views* from the south
and southeast.  Typical side slopes of the upper j?art of the butte are about
25°.  A road paved with cinder provides access to the peaks.  Numerous roads
around the hill provided access for the sampling crews and equipment;
several roads were constructed as part of the project.  The butte could be
easily reached from Boise via Interstate 80.
     Meteorological measurements taken at Mountain Home AFB provide
information on the wind speed and direction for the fall months.  Figure 7
shows two wind roses—one for all stability conditions, the other for stable
conditions only—derived from September weather observations.  During stable
 *The two figures show elevated and ground-level smoke released on
  October 24, 1980 at sunrise.
                                 10

-------
              •i "»t J««iKy
              t: ?i"'i   • 'X ;"'v • #''ifwv3*'^.'
              IliSli;: iSSSliSMttttl
\,: -•• /- V.	j-; -i-Srvd!.,^

" M:--\-f-1  .'
     Figure 2.  Topographic map of Cinder Cone Butte region.
                       11

-------
                                    Elevation in feet above MSL
                                    Contour intervals are 20 feet.
Figure  3.    Topography of  Cinder Cone Butte.

                       12

-------
                     sC^&'^V ^ v'H^f* -*
                     *-/>"'.   -  ,*^   «^  \  •-
                     1*&*•*•* **•• ^   >-
                     K^s»'S»J.»\  sis.
                                   Cinder Cone Butte looking south
Cinder Cone Butte looking southwest
                                   Cinder Cone Butte looking west
      Figure 4.    Side views of Cinder Cone  Butte.



                               13

-------
                                                                     •p
                                                                     M-l
                                                                     CD
                                                                     oa
                                                                     
-------
                                               tn
                                               cd
                                               o
                                               in


                                               o
                                               +J

                                               oa

                                               (D
                                               rt
                                               o
                                               


                                               i—I

                                               OS

                                               •H


                                               0)
                                               •H
                                               PL,
15

-------
                                                   CO
                                                                  en
                                                                  vO
                                                                  C7>
                                                                  LO
                                                                   CD  LL,
                                                                  •P  E
                                                                  co

                                                                  H.5
                                                                  O  oj
                                                                  •Si
                                                                  4->
                                                                  O  -P
                                                                  0)  nj
                                                                  •H  t/)
                                                                  -d -H
                                                                  C •(->
                                                                  rt  rt
                                                                  0  
                                                                 •P -H
                                                                 •H  
-------
conditions, which generally occur at night,  the most frequent wind
directions are east, east-southeast, and west-northwest.  Table 1 lists the
prevailing wind direction and frequency for  every odd hour of the day as
derived  from Mountain  Home AFB data for October.  The data illustrate the
prevailing up-valley flow (approximately 300°) during the day and
down-valley flow  (approximately  110°) after  midnight.  Although the basin
circulation appears to occur regularly, it is quite variable about the most
frequent wind  directions, as may be noted from the wind  rose.  Evidently,
the up-valley  flow, most frequently from the west-northwest, can also come
from the northwest or  west  (even occasionally from the north).  The
down-valley flow  can come east-southeast and southeast as well as the most
frequent easterly direction shown in the wind rose for stable conditions.
      Additional climatological data are available from the National Reactor
Testing  Station (NRTS) at Idaho  Falls, located about 300 km away in the
Snake River Basin (Yanskey et al. 1966).  This information was assumed to be
generally representative of CCB  as both sites are in the basin, although the
valley axis is northeast-southwest at NRTS and northwest-southeast at CCB.
The wind and  temperature profiles were also  assumed to be similar enough for
use in designing  the experiments.  Vertical  temperature  profile data suggest
 the occurrence of. inversion conditions more  than half the time during the
 fall, and strong  inversions  (>3.7°C/100 m) occur approximately 20% of the
 time (Yanskey et  al. 1966).   Typical  positive  temperature gradients and
 light wind  speeds suggest  that Froude numbers  are frequently  less than 1.0
 and occasionally  as  low as  0.2.  For  example, wind  speeds at  75 m are less
 than 2 meters per second  (m/sec) about  20% of  the  time  (Yanskey et al.
 1966).  If  light  winds are  well  correlated with  inversion conditions,
 Fr < 0.5 should occur  about 20%  of  the  time.

 2.2  Fluid Modeling of Expected  Flow Regimes

      During the summer of 1980,  three series of  towing  tank experiments  at
. the EPA Fluid Modeling Facility  (FMF) were  conducted  by William  Snyder  to
 provide input to the design of  the  CCB  field experiment.  The first  series
 of experiments was made to assess  the perturbations to  the  mesoscale  basin
 circulation caused by the presence  of CCB.   The  question specifically
                                   17

-------
 TABLE 1.  PREVAILING WIND DIRECTION AND FREQUENCY AT MOUNTAIN HOME AFB
                          (OCTOBER 1964-1970)
Hour
(MST)
U100
0300
0500
0700
0900
1100
1300
1500
1700
1900
2100
2300
Wind Direction
(degrees)
110
100
100
120
110
120
140
320
310
300
290, 310, 320
300
Average Speed
(knots )
5.4
4.0
4.'9
'3sce«3!«nQ
"*™"/ • y
7.8
10.7
7.5
12.1
10.2
4.8
6.0
6.8
Frequency
(%)
6.5
10.6
14.3
12.0
16.6
13.4
11.1
10.6
14.7
10.6
6.0
6.0
Note:  Direction and frequency determined from all weather conditions.
                                  18

-------
addressed was where to site a 150 m tower relative to CCB so that,  given the ,
range of prevailing southeasterly or northwesterly wind directions  expected
during strongly stable stratification, the flow fields at the proposed tower
site would not be appreciably perturbed by the hill.
     For this series of tows in the FMF stratified towing tank, a model of
CCB was constructed at a scale of 1:1536 (with contours derived from
enlargements of USGS maps) and mounted so as to be easily rotated to change
the wind direction (Snyder I980b).  Twenty-six tows were made for varied
Froude numbers and wind directions.  Rakes of tubes emitted a dyed  solution
for flow visualization.  Vertical rakes were used to obtain centerplane
streamline patterns and semiquantitative information on vertical velocity
profiles (with pulsed releases).  Horizontal rakes were used to obtain
horizontal streamline patterns at different elevations and information on
the horizontal velocity profiles (again, with pulsed releases).  From the
limited number of wind directions (110°, 120°, 300°) and Froude numbers
investigated (Fr = 0.2, 0.4, 0.6) it was estimated that at the proposed
150 m tower site (2 km, 357° relative to hill center), the perturbations in
the flow field were negligible and that the streamline patterns appeared
independent of wind direction except quite close to the hill surface.
     A second series of eleven tow tank experiments was made in the FMF
stratified towing tank to (1) guide the design of the smoke and tracer
experiments for the CCB ;field program, (2) preselect possible tracer gas
sampler and camera.locations, and (3) choose different sampling strategies
to account for the variation in wind flows (Bass 1980).  The experiments
were run using a second model of CCB constructed to a scale of 1:640 and
contoured at 20-foot  (3/8-inch) intervals.  As before, rakes of tubes
emitted a dyed solution for flow visualization.
     Each tow was filmed from the side with the camera moving with the tow
carriage, and from directly below the tow path with the camera held fixed at
two or three stationary points pointed upward at the (inverted) model hill.
The movie films were  viewed with an analyst projector, and the plume
patterns were sketched independently by two analysts who used a plan map of
CCB identical to the  model.  The two sketches were  then reconciled and
smoothed to define the  (apparent) envelope of each  plume path.
                                   19

-------
      Figures 8 and 9 illustrate the composite estimates of the plume paths
 and dispersion for two of the towing tank simulations.  Figure 8 illustrates
 the simulation for a wind direction of 110°, Fr = 0.4, and releases equal to
 0.25, 0.5, 0.75, and 1.25 of the hill height.  Similarly,  Figure 9
 illustrates flows from 300°, Fr = 0.4, and releases equal  to 0.125, 0.25,
 0.375, 0.5, 0.75, and 1.25 of the hill height.   The results corroborate the
 suggestions of Hunt and Snyder (1980) that air  parcels below H      the
                                                               crit'
 dividing streamline height,  tend to impinge upon and pass  around the sides
 of the hill and that air parcels above_the dividing streamline height tend
 to go over the hill.  Note in Figure 8 the uphill-downhill extent of the
 lowest plume as it impinges  in the east "draw"  and is swept around the side
 of CCB; note also that the plumes emitted at one-half and  three-quarters
 hill height (h > Hcrit) are  carried over the hill crest with negligible
 spread before growing on the lee side of the hill.
      The qualitative results of  the second series of towing tank experiments
 are summarized  as follows:
      •     Locally,  CCB perturbs  the  general mesoscale wind  flow in  the Snake
           River  Basin.
      •     A parcel  of  air  below  the  dividing  streamline height may  impinge
           on the upwind side  of  the  butte  if  directed along a stagnation
           streamline and may  tend to flow  around the butte.
      •     A plume released just  above H  .  may produce a maximum
           ground-level  concentration on the upwind side as it passes over
           the top.
      •     A plume released substantially above H  .  may occasionally
           produce a maximum ground-level .concentration on the lee side of
           the hill.
      •     A parcel of air traveling  in a direction off the stagnation
           streamline will tend to pass around CCB without significant impact.

      The final series of tow tank experiments conducted to guide the field
program design was undertaken to establish more adequately the validity of
the general integral expression for the height of the dividing streamline in
stably stratified flow (see Section 1.2).   Twelve tows  of the 1:640 scale
                                  20

-------
Figure 8.    Composite estimates of plume paths based on towing tank
            simulations:   wind direction 110°, Fr = 0.4.
                                21

-------
270
                                                                              75, 1.25
                          wwxfmsmmsxtf
~"-~-.        !
t&satiXAfi&SBlRii* i;****<^e*fc;esiwdtt*."j
           180
                                                   :r^^
     Figure  9.    Composite  estimates  of plume paths  based on towing  tank
                  simulations:   wind direction 300°,  Fr = 0.4.
                                         22

-------
 model were made under different combinations of density profiles,  towing
 speeds, and source heights (Snyder 1980a), with effective Brunt-Vaisala
 frequencies (0.86, 0.089 rad sec  ) very close to those expected at CCB
 under stable nighttime conditions.  A vertical rake of three tubes emitted
 neutrally buoyant colored dyes.  For each set of three source heights,  the
 general formula (see Equation 4) was integrated numerically using  the
 measured density profile and towing speed, and the resulting plume path
 predictions were compared to the observed plume trajectories.
      Overall,  the agreement was excellent.  The validity of the  general
 integral formula (Equation 4)  for predicting the height of  the dividing
 streamline as  a function of wind speed was demonstrated for a  wide range of
 stable  density profiles.   It was therefore recommended  that the  integral
 formula be used as an operational,  real-time decision-making tool  during the
 field study.

 2.3  Experimental Design of Field Study

     The basic program goal required  the measurement of data that,  together
 with information obtained  from fluid modeling  experiments and  recent
 theoretical work,  will be  used  to develop  improved mathematical  simulations
 of plume dispersion and  impingement from elevated sources in complex
 terrain.   The  basic experimental  design involved:  (1) meteorological
 measurements,  (2)  the emission  of tracer gases and a visible plume,
 (3) quantitative measurements of  tracer gas concentrations, and
 (4) photographic  documentation  of plume behavior.  The  variability of the
 wind flow  about the most frequent directions of both up-valley and
 down-valley flows  required  that smoke and  tracer sources be highly mobile.
 The regularity of the basin circulation required sampler placement to
 capture  the prevailing west-northwest and east-southeast winds.
     The expected perturbations of the air flow by the hill implied the
following requirements:
          deployment of samplers to capture plume impacts near the
          stagnation streamline, as plumes go around the side or up and over
          CCB;
                                   23

-------
     •    the need for real—time meteorological measurements and feedback in
          order to locate the source azimuth and choose a source height
          (e.g., release above or below H r-t)5
     •    meteorological measurements of the unperturbed flow as well as
          measurements to characterize dispersion on the hill;
     •    visible elevated and ground-level plumes to capture qualitatively
          the different classes of plume-terrain interaction; and
     •    sufficient vertical resolution of meteorological measurements to
          calculate H  .. and Fr.
                     crit

All of these features were included in the experimental design.
     The first field study of the EPA program was conducted at CCB from
September through November 1980.  The field study encompassed two distinct
phases.  Phase I ran from September 16 to September 27, 1980 and included a
total of 10 experiments.  The purpose of this preliminary phase was to gain
experience working at the CCB site and photograph various smoke releases for
flow visualization.  Phase II, the major experimental phase, ran from
October 16 to November 12, 1980.  Eighteen experiments were run with SF
as a tracer, in addition to the smoke plume releases.  In nine of these
experiments, CF_Br was simultaneously used as a tracer gas.

     2.3.1  Fixed Meteorological Network

     ERT assembled at CCB a meteorological monitoring network to
characterize the unobstructed approach flow and to analyze the wind field as
it encountered the hill.  A series of meteorological towers (a 150 m tower
located approximately 2 km north of CCB, and a 30 m tower and four 10 m
towers located on the hill) documented the local meteorology.  The locations
of the towers (A, B, C, D, E, and F)* are shown in Figure 10, and the direct
measurements and derived parameters at each tower level are given in Table 2.
*0ne other F460 cup-and-vane wind set was on a 10 m mast adjacent to the
 office trailers at Simco Road (ERT Command Post), but its output was
 recorded only on strip charts (see Figure 10).
                                   24

-------
25

-------
        TABLE  2.    TOWER  INSTRUMENTATION  AND  MEASURES
      Site

 Tower A

   Level 0 (1 m)


   I.i-Vtfl I (2 n)



   I.evi-I J (1(1 m)
                      Instruments*
 Pyranomecer
 Net radiometer

 Triaxiat props
 Uup & vane
 KTU

 Triaxial props
 Cup & vaiu*
 Itl'U
 Ka.sl Iu»aiJ llii-rmiscor
 Insolation
 Net radiation

 U, V, W,  IX,  tY,  12
 UX, VX
 T

 U, V, W,  IX,  IY,  IZ
 UX, VX,  U,  a',,
 4T
 T, a.r
                     Cup & vane               UX,  VX
                     KTU                      AT
                     Kast bc'ad tlit-rmistor     T, 0^
                                                 Derived Measures"1"
 WS, WD
 iSP, DR
                                                                          WS, WD
                                                                          SP, UK
                                                                          T
Love I

Level
Levc 1
1,1-Vf I
Ll'V<;l
J

5
b
7
a
do

(bU
(SO
(100
llj<)
m)

m)
n.)
in)
m)
KT1)
Rl'U
RTD
Triaxial props
RID
KTD
Triaxial props
T
U, V, W, IX, IY, li.
4T
T
U, V, W, IX, IY, IZ
AT
T
U, V, W, IX, IY, IZ

WS ,
f

WS,
T

WS,

WD

WD

WD
                                                     SP, DR
                                                     r
 Towr  B
   JO m



Towers C, D, E, F

  2 a


  10 m
 Triaxial props
 KTU

 Triaxial props
 Ctip & vane
 K'I'D

 Triaxial props
 Cup tt vane
 RID
Triaxial props
RTD

Triaxial props
Cup & vane
RTD
 U, V, W, IX, IY, IZ
 T

 U, V, W, IX, IY, IZ
 UX, VX
 AT

 U, V, W, IX, IY, IZ
 UX, VX
 AT
U, V,  W,  IX,  IY,  IZ
T

U, V,  W,  IX,  IY,  IZ
UX, VX
                                                                          WS,  WD
WS, WD
SP, DR
T

WS, WU
SP, DR
T
WS, WD
                                                                         WS, WD
                                                                         SP, DR
                                                                         T
 *A11 temperature sensors were mounted in aspirated radiation shields; an RTD is a
  Resistance Thermometric Device.

**"Dlrect" measures  are  those calculated by the data station microprocessors from the
  outputs of Che  Instrument translators.  The turbulence  data (IX,  IY, IZ, 09,
  OT) were calculated  for both 5-min and 1-hr data periods.   All direct measures
  were updated once  per  minute by the data stations.  UX  and VX are  the westerly and
  southerly components of the wind calculated from the cup and vane  outputs at the 4 Hz
  saapling frequency.

  "Derived" measures are those calculated by the data collector computer from the
  5-stn averages  provided by the data stations.  These derived measures comprise 5-min
  average values  of  the measures Indicated as well as 1-hr averages  of all direct and
  derived measures except the turbulence data, 1-hr averages of which were calculated by
  the data stations.
                                         26

-------
     The 150 m tower was instrumented at eight levels to characterize the
approach flow for the experiments.  This tower had an unobstructed view of
the wind for almost all wind directions.  The 30 m tower, mounted on the
southern peak of CCB, was instrumented at 2, 10, and 30 m.  The four 10 m
towers were located in the northeast, southeast, southwest, and northwest
quadrants of the hill, each tower at a height approximately 65 m above the
plain.

     2.3.2  Photography Program

     A primary objective of the CCB experiment was to document
photographically the behavior of the plume' as it encountered the hill.  This
objective was achieved only in part, because most of the experiments were
conducted during hours of darkness, and lighting of the smoke plume was a
problem.  During both Phase I and Phase II, several photographic media were
used, including black-and-white as well as color still photographs (35 mm),
motion-picture film (16 mm), and videotape.
     Five 35 mm cameras were operated simultaneously during the field
experiments.  Locations were chosen on the basis of the climatological data,
the towing tank results, and previous experience with the aid of a
professional photographer.  Cameras were operated manually at the desired
exposure.  Exposure times at night were generally 3-5 minutes.  Each camera
operator was in continuous contact with the lead photographer to synchronize
shots.   Figure 11 shows the preselected camera locations.
     When lighting allowed, a 16 mm motion picture camera was used in a
time—lapse mode.   This camera, operated by a professional photographer, was
generally located at the top of CCB looking toward the plume.  The videotape
camera was a valuable management tool, especially during debriefing and
planning sessions, for near—real-time review of visual experimental evidence.
     Lighting of the plume proved to be extremely difficult.  Under clear
conditions and a full moon, no lighting was required.  For other conditions,
a carbon arc lamp was invaluable.   The arc lamp was generally placed
approximately 2 miles away so that the light beam and the plume were nearly
perpendicular.   The lamp was put in an automatic sweep mode that passed
along the plume at 30—second intervals.
                                  27

-------
                                                               O
                                                               O
                                                               O
                                                               rt
                                                               I.
                                                               O
                                                               0
                                                               O
                                                               CD
                                                               CD
                                                               W
                                                               0
                                                               r-l

                                                               CD

                                                               3
                                                              .. tx>
                                                               •H
28

-------
      Aerial  photographs  were  taken  with  a  still  35  mm camera  from  a
 single-engine  airplane  flying as  slowly  as safety allowed.  ASA 400
 black-and-white  film was normally used at  night, and  ASA 64 color  film was
 used when sufficient sunlight was available.   The plane  flew  at a  range  of
 heights  between  250 and  1,500 feet  above the  local  basin level.
 Light-gathering  power at night was  increased  by  a "Starscope"  borrowed from
 the  Army,  but  the  images obtained were not very  satisfactory.   In  the later
 experiments, aerial photographs were attempted only when there  was
 sufficient natural light.

      2.3.3  Tracer Release, Sampling, and  Analysis

      Tracer  Release System

      Two  tracer  gases, SF, and  CF^Br, were  released at different heights
 from the  boom  of a  mobile crane.  The mobility of the release system
 resulted  in a  high  number of  successful hours per test (normally six or
 seven hours out  of  eight) in which  significant tracer concentrations were
 recorded on the  hill.  In only  one  experiment (Test 212) were the wind
 patterns so variable  that it was not possible to align the release system
 upwind of the  hill.
      The SF^ and CF^Br tracer gases were stored in individual compressed
 gas  cylinders  kept  at ground level; flexible Tygon tubing, approximately
 100 m long, led  from  the gas cylinders to different release heights on the
 crane boom.  For the  first nine experiments (Cases 201-209), the tracer
 release tube was attached to the smoke generator platform at the smoke
 release height but  from 0.5 m to 1m away,  horizontally.  For the last nine
experiments (Cases  210-218), the tracer release tube was on a separate
 pulley system independent of the smoke generator platform and about 1 m
away, horizontally, from the smoke release.  The gas flow was monitored by
 separate rotameters on the SFg and CF3Br cylinders,  and the weight  loss
of each cylinder was monitored by a separate electronic digital scale.
     Because of the difficulty in calibrating rotameters with 100 m of
tubing attached,  the rotameters were used simply to  monitor a constant flow
rate of tracer; the weight loss of the cylinders (as recorded by the digital
                                  29

-------
scales) was used to determine the emission rate of each tracer.  The scales
could be read accurately only to the nearest 0.05 Ib, hoyever, and because
the SF, flow rate was initially as low as 0.06 g/sec (0.5 Ib/hr), the
possible uncertainty in the hourly emission rate determination could be up
to 10%.  This problem was alleviated in the later experiments by increasing
the SF  flow rate to about 0.18 g/sec (1.5 Ib/hr), thus reducing the
emission rate uncertainty to about 3%.  Table 3 presents the average tracer
release rates in each experiment; release rates ranged from 0.06 g/sec to
0.20 g/sec for SF, and from 0.86 g/sec to 0.98 g/sec for CF-jBr.*

     Tracer Sampling System

     Tracer sampling was accomplished by means of approximately
90 individual battery-operated samplers capable of either 10-minute or
1-hour sequential operation.  Each sampler contained 12 individual pumps,
each of which intermittently** filled a Tedlar bag over the time period of
interest.  Thus, each sampler could take sequential 1-hour samples over a
12-hour period or sequential 10-minute samples over a 2-hour period.
Normally, 1-liter bags were used for both hourly and 10-minute samples.
Except for samples taken from reflection masts (described below), all
samples were taken at 1 m above ground level.
     Figure 12 shows the locations of the 70 fixed samplers and also the
10 movable samplers that were placed on either the northwest or southeast
side of the hill, depending on the prevailing wind direction.  Of these
80 samplers, typically 60 were used for 1-hour average samples and 20 were
used for 10-minute average samples.  Another 10 samplers were used for
reflection masts, for background ambient air samples, and for co-located
samplers.
 *In analysis by electron-capture gas chromatography,,CF3Br is about
  20 times less sensitive than SFg.
**For a 1-hour average sample, a pump sampled intermittently for
  about 1 second every 15 seconds.
                                   30

-------
             TABLE  3.   SF6  AND CF-jBr RELEASE RATES (g/sec)
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
                          SF6 Average
                          Release Rate
0.09
0.08
0.08
0.09
0.09
0.06
0.16
0.19
0.16
0.17
0.17
0.16
0.20
0. 17
0.20
0.18
0.16
0. 15
                                 Average
                           Release Rate
0.97

0.97
0.97

0.96
0.94
0.96
0.96
0.98
0.86
                                  31

-------
                                                           O
                                                           
-------
      The design of a reflection mast is shown in Figure  13.   Air samples
 were drawn in from 3 m and 6 m (in addition to the  normal  1  m height) and
 also at an uphill site equal in elevation to the 6  m height.   The purpose  of
 this sampling strategy was to determine if tracer concentrations would
 "reflect" off the surface as predicted by some dispersion  models. Four of
 these reflection masts were used during Cases 203-218.   Normally, the 3 m
 height was sampled on only one of the reflection masts;  the  other masts were
 sampled at 6 m and 1 m,  in addition to the uphill site-
      Background air was sampled during each experiment by  at  least one
 sampler upwind of the tracer release point.   At  two  locations  during each
 test,  an extra sampler was placed next to the normal sampler and set to
 sample at the same time.   These co-located samplers  were used  to assess the
 variability  in the sampling  technique;  the results from  the co-located
 samplers are discussed in Section 3.2.
      The mechanical  reliability of the  samplers was  relatively poor, with  a
 typical pump breakdown rate  of  about 20%  during each test.  During the
 earlier experiments,  the  mechanical  breakdown problems, when combined with
 sampler crew mistakes  in  setting  the sampler  times,  resulted in  fairly low
 data capture for  some  of  the  experiments.   However,  as the sampler crew
 gained  experience, the data capture  during  the later experiments was limited
 mainly  by mechanical  problems.
     The  design of the sampling system proved to be a good compromise
 between total flexibility of  the system and personnel endurance.  For
 example,  it  was not possible  to operate many more 10-minute samplers because
 bags had  to  be manually changed by the sampler crew every two hours for  each
 10-minute sampler.  The utility of the reflection mast system cannot be
 properly assessed at present because a more detailed study of the results  is
 necessary.

     Tracer Analysis System

     The analysis of the bag samples by electron-capture  gas  chromatography
was accomplished in the NAWC laboratory in Boise.  Six gas  chromatographs
were used to analyze for the SFg tracer; however, because of  problems in
obtaining adequate column packing material, only one of the chromatographs
                                   33

-------
I
                                                                                   •H
                                                                                    t/)
                                                                                    (D
                                                                                   13
                                                                                    oj


                                                                                    fi
                                                                                    O
                                                                                   •H
                                                                                   •M
                                                                                    O
                                                                                    0)
                                                                                    CD
                                                                                    w>
                                                                                   •H

-------
could analyze for the CF-Br tracer as well as SFg.  The detection limit
of the chromatographs was about 5 parts per trillon (ppt) for SF,. and
about 100 ppt for CF3Br.
     A chromatogram showing a good separation of the tracer gases using a
5A molecular sieve column is illustrated in Figure 14.   The SF  and
CF»Br* elute before the large oxygen peak, with a total analysis time of
about 4 minutes per sample.  The SF  areas were calculated by an
electronic digital integrator (the area under the peaks is directly
proportional to concentration).  With six chromatographs and an average of
4 minutes per sample, a total of 90 samples per hour could be analyzed.
     For quality assurance, about 5% of the samples were analyzed twice on
different gas chromatographs.  The results of these recounts are discussed
in Section 3.2.  Most analyzed bags were then flushed two times with
nitrogen and returned to the field.  The exceptions were bags that contained
high tracer concentrations (>1 part per billion (ppb) SF,;
>10 ppb CF Br).  These bags were discarded to prevent any possible
contamination caused by tracer desorption from the bag walls.  Figure 15
illustrates the flow of procedures followed in bag sampling and analysis.
     Calibrations were performed on each gas chromatograph at the start and
finish of each analysis day.  Nine calibration gases, ranging from about
10 ppt to 40 ppb SF, and from about 200 ppt to 800 ppb CF^Br, were used
to calibrate each chromatograph in the early experiments.  The calibration
points were reduced to seven (10 ppt to 10 ppb SFg) in later experiments
because no SFg tracer concentration greater than 10 ppb was ever detected
in the field studies.  A check with one calibration gas (usually
100 ppt SF, ) was performed every four hours on every chromatograph; if
this span check showed a greater than 5% difference from the last
calibration, that chromatograph was completely recalibrated with all of the
calibration gases.
     Figure 16 presents the procedures followed to obtain tracer gas
concentrations as a function of time and location.  The data sheets from
each field sampler location that contained times and bag numbers were
transferred to the laboratory in Boise along with the bags, and the analysis

*0n the remaining five columns, the CFgBr peak could not be separated from
 the oxygen peak.
                                   35

-------
                                        eg
                                       O
                                                                                                                  8
                                                                                                                  c
cd
(4
bfl
O
•P
oj

O
M

O

t/1
nS
bfl
                                                                                                                            0

                                                                                                                            O

                                                                                                                            Cti
                                                                                 O
                                                                                                                            bO
                                                                                                                            •H
CO

CO
o
                                                                                                              o
                                                                                                                  I
                                                            36

-------
                            Field
                          Samplers
 GC Analysis
     1
    High
Concentrations
Recounts
Bag Flushing
      Figure  15.    Bag sampling and analysis procedures.
                              37

-------
   I

Field
Sampler
Data Sheets





QA

GC Analysis

i

QA
\
r

Raw
Data Entry



Recounts


                          Computer
                             }
                        Concentrations
                                                  GC Calibrations
                                                        i r
                                                    Calibration
                                                    Data Entry
Figure  16.    Procedures to obtain tracer gas  concentrations.
                             38

-------
 information (date,  time,  and integrator area)  was then written on the same
 data sheet.  These  data were then entered into the ERT data base  during  the
 field study from a  console at the Boise laboratory.
      Calibration data for each chromatograph were also entered separately
 into the ERT data base.  At first,  a cubic spline interpolation was  used to
 fit a continuous curve to the calibration points.  However,  this  cubic
 spline technique resulted in too many degrees  of freedom for some
 calibration curves  and produced inaccurate results for high concentrations,
 as shown in Figure  17. Another function was selected  to provide  a better
 fit to the  calibration data:
               y   =  ax  (1  - e-b/X),
(6)
where y  is the area or peak height and x is the concentration.,. This
function is based on the response of the electron-capture detector.at low
and high concentrations (Maggs et al. 1971) and fits the calibration data
quite well, as shown in Figure 17.  Tracer concentrations of SF, and
CF3Br were then calculated by computer from a linear interpolation in time
between  the two closest calibrations before and after the analysis time of
each sample.
     In  view of the huge number of tracer samples and the operation of the
gas chromatographs for 16 hours per day, the tracer analysis system worked
quite well.  All samples were analyzed within 48 hours of sample
collection.  The main deficiency was that only one chromatograph could
analyze  both SF& and CF3Br.  The only major instrument problem occurred
during the early experiments when it was difficult to obtain reproducible
results  from three of the chromatographs.  These chromatographs were
subsequently replaced,  and the analysis proceeded quite smoothly
thereafter.  The preliminary recount statistics, as discussed in
Section  3.2, showed good reproducibility of the tracer analysis system.

     2.3.4  Lidar Measurements
     Under funding through an EPA/NOAA Interagency Agreement,  the NOAA Wave
Propagation Laboratory (WPL) operated a lidar to measure the back scattering
                                   39

-------
                                                          CO
                                                         u.
                                                                  I/) -
                                                                  CD

                                                                  f-t
                                                                  3
                                                                  o


                                                                  o
                                                                  rt
                                                                  XI
                                                                  'H
                                                                  cti
                                                                  O
                                                                   \O
                                                                  txO
                                                                  •H
                                                                  p-
40

-------
 of  the  oil-fog  plume.   The  basic  purpose  of  the  lidar measurements was to
 determine  plume dimensions  and  to locate  the plume centerline before it
 reached the  hill.  A sampling protocol was developed so  that WPL took
 regularly  scheduled  measurements  at three locations upwind of CCB.  The
 lidar proved to be also useful  for operations management.  The WPL crew
 frequently provided  sketches of the plume (see Figure 18), providing nearly
 real-time  feedback of plume location.

     2.3.5  Other Measurements

     To obtain  katabatic wind information, cup-and-vane wind sensors and
 temperature  sensors  were arranged at about 1 m above the axis of the east
 draw at five locations separated  by about 50 m.  Three hot-wire anemometers
 were located in a vertical  array  in the draw near the base of the butte.
 These instruments were set  out  to, quantify the flow character as a function
 of height  on the hill and longitudinal position down the east draw.  A field
 of orange  and white  fluorescent streamers was constructed and located across
 the bottom of both the east and northwest draws to qualitatively assess the
 depth and  extent of  downhill flows.  The  cup-and-vane sets and temperature
 sensors were connected to a tape  recorder and the hot-wire anemometers to a
 chart recorder.
     To define  the plume before it interacted with the hill, nephelometer
measurements of b     were  taken  by instruments suspended from a crane
                 SO 3. L
 that was driven across the  plume  path.  A 10 m tower with three
 nephelometers was located near the top of the east draw on CCB.  Also, one
 nephelometer was located at the top of each peak of the butte and one at
 Tower D.
     Supplementing the measurements from  the six main meteorological towers
were various sounding devices operated by NAWC and WPL (see Figure 10).
NAWC operated a tethersonde from  the more upwind of two locations about
1.3 km from the center of the butte.  These sites were therefore usually '
within  700 m of the primary release point.  An ascent-descent sequence
yielding profiles of temperature,  pressure,  and wind speed and direction was
normally performed once an hour (or more  frequently) to heights at least
 200 m above the local terrain.
                                  41

-------
                                                                CO
                                                                I

                                                                h

                                                                cti
                                                                e
                                                                o
                                                               •H
                                                               •M



                                                               3
                                                               CX)

                                                               1—I



                                                                CD
                                                               •H

                                                               PH
42

-------
      When this tethered balloon system was not available because wind speeds
 were too high to allow tethersonde operation, the supplementary profiles
 were obtained from minisonde flights.   (The minisonde profiles were less
 frequent than the tethersonde profiles.)  Wind profiles were also derived
 from pilot balloons (pibals) released  approximately once an hour.  The pilot
 balloon flights were tracked by two theodolites for 10 minutes,  if possible,
 and the balloons rose at approximately 200 m/min;  thus,  many of  the pibal
 profiles extended as high as 2,000 m above the surface.   (The azimuth and
 elevation angles taken during the balloon flights  have not  as yet been
 transformed by NAWC into heights and wind speed and direction profiles.)
      WPL operated its frequency-modulated, continuous-wave  (FM/CW) radar
 from a  point south of the butte as well as two monostatic acoustic radars,
 one to  the east and one to the west of the butte,  to provide information on
 the atmospheric boundary layer in the  vicinity of  the butte.   Information
 from these instruments  has not yet been received by ERT.

      2.3.6  Data Base Management

      To  house  the enormous amount  of data  that  was  collected,  ERT utilized a
 Data Base  Management  System (DBMS)  that  was  designed for  efficient handling
 of  data  at all  levels of  input,  validation,  reduction, processing,  and
 archiving.   A Data  General Nova minicomputer was located  on-site  to serve as
 the prime  data  collector.   This minicomputer provided maintenance
 information, automatic calibration  support,  automatic screening of  status
 and  value,  hourly system  summary reports,  and data  communications  in
 addition to data  collection.  An on-site hardcopy output printer and three
 CRT terminals gave  scientists direct access  to  the meteorological data in
 real time.  Data were permanently archived as both  5-minute and 1-hour
 averages.
     Figure 19  illustrates  the configuration of the data collector system
and  the ERT central data processing system.  Measurements taken at the 150 m
 tower were initially  processed and averaged at a transponding data station,
telemetered to a shelter at the top of CCB, and transmitted to the data
collector.  Similarly, meteorological data collected from instruments
located on the butte were first processed at the data stations there and
                                   43

-------
 cd

 I
 •H
 •a
 o
 o
.
 o
•H
 4J
 O
 O
 O
 •P
 rt
 Q
 
-------
 then transmitted to the data collector located at the field headquarters.
 Data were displayed in real time at the data collector for analysis and
 operations management purposes.  Data were transmitted to the ERT office in
 Fort Collins, Colorado, and sent to the ERT central computer in Concord,
 Massachusetts, via a dedicated telephone line.  A computer terminal was
 available at the NAWC Boise laboratory to allow entry of the SF, and
 CF-jBr data into the data base.  In addition to data analysis efforts at
 CCB, meteorological data were analyzed at the ERT central data processing
 facilities, and selected analysis results were sent back to the field
 headquarters for use during the experiment.  Table 4 lists examples of the
 analysis programs used during the experiment.

 2.4  Field Study Results

     2.4.1  Summary of Field Data

     When the project began in June 1980, the experimental methods to be
used in the small hill study were untested and unproven.   We can now
 conclude that the CCB dispersion experiment was successful.  Extensive data
sets of meteorological conditions and ground-level tracer gas concentrations
have been assembled which will permit the development of models of plume
interaction with three-dimensional,  approximately axisymmetric hills in
 stable flows.  Problems in the field occurred primarily because of
insufficient lead time,  communications failure in the real—time
meteorological monitoring system,  and tracer gas sampler failure.  However,
the end result is an excellent data base for model development purposes.
     A summary of the total number of tracer data samples analyzed for each
case (both 1-hour and 10-minute samples) is presented in Table 5.  More
detailed data summaries presenting hour-by-hour data capture for each case
are tabulated in Appendix A.  Table 5 shows a total of over 14,000 data
points for the 18 cases,  or roughly 800 tracer samples analyzed per case.
Overall, 33% of the samples were 1-hour averages and 67% were 10-minute
averages.  Two tracers (SF, and CF-Br) were released at different
                          D       _5
heights in nine of the experiments (Cases 208, 210-211, and 213-218).  The
                                   45

-------
          TABLE 4.  SAMPLE ANALYSIS PROGRAMS AVAILABLE ONSITE
     GRAD

     Tabulates local temperature, potential temperature gradient,
gradient Richardson number, Froude number, and square of Brunt-Vaisala
frequency as a function of height for a specified tower and time.

     TOWR

     Tabulates U, V wind components, mean wind, and wind shear
profiles as a function of height for a specified tower and time.

     FDIF

     Computes the gradient Richardson number, square of Brunt-Vaisala
frequency, potential temperature gradient, and Froude number in finite
difference form as a function of selected heights for Z;L and Z2
for a specified tower and time.

     SURF

     Computes the Bulk Richardson number, Monin-Obuhkov length,
surface friction velocity, surface heat flux, and surface temperature
scale as a function of roughness height (ZQ), Z^ and Z2 for a
specified tower and time.

     ZJD

     Computes the roughness height from data from the 150 m tower for
a specified time.  Heights used are 40, 10, and 2 m.

     HCRIT

     Calculates the dividing streamline height using data collected at
all eight levels of Tower A or from data collected at the other five
(B-F) towers.
                                  46

-------
              TABLE 5.  SUMMARY OF TRACER DATA ANALYZED
Case

201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218

TOTAL
  Number of 1-hr
  Average Samples
  SF6       CFsBr

   73
  169
   79
  222
  225
  228
  150
  173         64
  240
  251        109
  291        149
   86
  216         62
  233         61
  278         64
  368         98
  339         95
  382         74
                                        Number of 10-min
                                        Average Samples
                                                   CFBr
4,003
776
  292
  404
  440
  507
  422
  446
  469
  461
  368
  471
  596
  202
  352
  478
  567
  693
  664
  713

8,545
   89
   81

   93
  194
  341
  167
   88
  169

1,365
  Total

   365
   573
   519
   729
   647
   619
   841
   608
   608
   920
 1,117
   288 "
   723
   966
 1,250
 1,326
 1,186
 1,338

14,689
                                  47

-------
CF,Br data account for only 15% of the total because only one of the six
chromatographs could analyze for CF~Br.
     It should be noted that Table 5 presents only the number of samples
that were analyzed.  In most experiments, a number of presumably valid
samples were never analyzed because of assumed zero tracer concentrations
(e.g., the plume missed the hill for one or two hours).  Figure 20 shows the
total number of samples analyzed for each case.  The severe drop in number
for Case 212 was not caused by system failures but rather by a decision to
analyze only a few samples; the variable wind patterns during this
experiment made it impossible to align the release system upwind of the hill.
     These are some of the specific achievements of the CCB experiment:

     •    Demonstration that the small-hill design concepts successfully
          generated new knowledge of stable plume dispersion around an
          isolated, three-dimensional, roughly axisymmetric hill.
     •    Assembly of a meteorological data base that adequately
          characterizes the wind and temperature fields around CCB.
     •    Assembly of a SF  and CF Br tracer concentration data base
                          o       J
          that will assist in the development of sound models of stable
          plume impact on elevated terrain.
     •    Design, implementation, and operation of a data base management
          system that generated useful real-time feedback for field
          operations management and that subsequently will allow users to
          combine the source, meteorological, and tracer concentration data
          in a variety of useful formats to aid in developing models.
     •    Demonstration of the utility of a photographic record of plume
          behavior in understanding the physics of flows.
     •    Corroboration of the utility of fluid modeling experiments in
          understanding flows and dispersion in complex terrain and in
          designing the CCB experiment.
     •    Demonstration of the utility of the lidar measurements—both in
          managing operations and in providing information on plume behavior
          upwind of CCB.
                                   48

-------
                                                               CD
                                                               W
                                                               CO
                                                               O
                                                                   CD

                                                                   •H
                                                                   M
                                                                   CO
                                                                   co
                                                                   •H
                                                                   o
                                                                   cd
                                                                   CO
13
CO
                                                                   s
                                                                   <0
                                                                   o

                                                                   M
                                                                   <0
                                                                   O
                                                                   CN]
                                                                   W)
                                                                   •H
sajdiueg |BIOJ_
          49

-------
     •    Confirmation in part that the concept of a dividing streamline
          usefully describes flows around isolated, three-dimensional hills.*

     Because we have not yet examined the nephelometer data, FM/CW radar
measurements, sampling mast SF, data, acoustic sounder data, and katabatic
wind measurements,** we cannot assess their usefulness for model development
at this time.  Most of the 35 mm pictures (especially the nighttime aerial
photographs) provided little information and the formal fixed-location
photography program was too inflexible from a scientific viewpoint.  Many of
the most valuable pictures were taken from arbitrary vantage points by
interested scientists free to change viewing position in order to best
capture the plume dynamics.

     2.4.2  Example Results from Specific Experiments

     To illustrate some of the experimental results, the remainder of this
section will describe four case study hours:
          Case 206 (10/24/80)
          Case 211 (10/31/80)
          Case 210 (10/30/80)
          Case 205 (10/23/80)
0500-0600
0400-0500
0200-0300
0400-0500
Case 206 represents a situation in which the plume remained basically
horizontal but quite unsteady throughout the hour.  Case 211 illustrates an
 *During the field experiments Hcrit appeared to distinguish instantaneous
  plume behavior reasonably well for averaging times short enough that  •
  Hcrit remained approximately constant; however, fluctuations primarily
  in wind speed rendered the 1-hour average Hcr£t value less useful in
  determining hourly-averaged maximum ground-level concentrations.
**Much of the information was lost when the katabatic wind sensors,
  recorders, and tapes were stolen near the end of the experiment.
 +A11 times are in Mountain Standard Time (MST).
                                   50

-------
 experiment with the emission of both SF. and CF0Br.  The smoke and
                                        o       J
 CF3Br were released at an elevation above the dividing streamline height;
 SFg was emitted below it.  Case 210 is an example of a situation in which
 the higher concentrations occurred on the lee side of CCB.   Case 205 is  the
 hour used to illustrate the model evaluations described in  the next two
 sections.

      Case 206 (0500-0600)

      The morning of October 24,  1980 exemplifies a situation with light
 east-southeasterly  (126°) drainage winds  down the Snake River  Basin.   The
 source crane was located about  595 m from the hill center at an orientation
 of  123.5°.   The  hourly  average wind direction and speed (estimated  for the
 source height) were 126°  and  2.0 m/sec, respectively.   The SF^  was
                                                             6
 released 35  m above the local ground elevation.   H  .   was estimated as
                                                   crit
 40  m.   On the average,  therefore,  the SFg was emitted at a level  slightly
 below the dividing  streamline height,  suggesting  flow around and  toward the
 north side of CCB during  most of  the  hour  (the average  wind  direction being
 more  southerly than the source orientation).
      Figure  21 shows the  observed  SFg concentrations for the hour 0500 -
 0600.  All concentration  labels are  placed so  that the  lower left-hand
 corner of  the right-most  digit lies at the sample  location.   Height contours
 are presented at 10 m intervals, beginning with the 5 m height contour.  The
 zero  height  coincides with  945 m  (3,100 ft) above  sea level.  The grid marks
 radial distance increments  of 100 m and angular increments of 22.5°.  (The
 numbers  in parentheses  represent averages of 10-minute average
 concentrations; the number  of 10-minute averages used to construct the value
 is  the subscript listed at  the right.  All other values in the figure are
 hourly average concentrations.*)
     Hcrit values calculated from the archived 5-minute meteorological
data range from 29 m to 45 m.  Local Fr (calculated at 35 m) ranged from 0.3
 to 0.8, and the wind direction varied from 81° to 157°.   Most of the plume
*Subscripts greater than 6 indicate sampling mast results,  which are
 averaged over all heights sampled (1,  3,  and 6m).   A subscript of 2 can
 also indicate two co-located,  hourly averaged samples.
                                   51

-------
 CASE 206 HR 6 SF6
Figure 21.   Observed SFg  concentrations (ppt) for Case 206, 0500-0600.
             Source:  r  =  595  m,  6 = 123.5°,  relative height =  29.5 ra,
             Q = 0.06 g/sec.
                                   52

-------
 material could be expected to be transported toward or along the north side
 of the butte,  at elevations close to the release height.   With the changing
 Hcrit an<* w:i-n^ direction,  some SF, could be transported through the draw
 and up the north peak.   The hill concentration pattern confirms the
 transport pattern suggested by the meteorological observations.  The higher
 concentrations (879,  957,  and 687 ppt)  were measured north of the mean
 incident wind  trajectory at contour heights of between 30 m and 45 m.   (Note
 that a contour height of zero lies approximately 5 m above the local terrain
 at the release location.)   High concentrations were also  measured further up
 in the draw (730 ppt) and  on the north  peak (606 and 438  ppt),  and also
 towards the base of  the  draw (1,248 ppt).
      Figure 22 is a  photograph (5-minute exposure)  of the plume taken  from
 the north peak (camera location 0-15) at 0505.   The photograph shows the
 plume bending  toward  the north and staying  at  an elevation below the top of
 the butte.   Figure 23, a photograph (1-minute  exposure) of the  experimental
 setting taken  from the northeast three  minutes  later (0508),  shows  a
 continuous  plume going up  the  north peak and some  plume material  going
 around the  north side (indicative  of the observed  concentration pattern).
 Two photographs,  Figures 24  and  25,  taken near  the  middle of  the  hour—at
 0530 and  0540—from the  north  peak,  show the initial  plume trajectory  toward
 the butte with subsequent  deflection toward  the  north  side.   These  two
 photographs  suggest substantial  crosswind plume  diffusion  and indicate that
 the plume path stayed below  the  top of  CCB.  Figure  26, shot  from the
 southeast (camera location 0-11) at 0546, shows  plume material moving up the
 draw toward  the  north peak (but  below its top) and around  to  the north.
      Case 206  is a good  example  of plume transport and diffusion when the
 release height  is near or below  the dividing streamline height during most
 of  the hour.  Most plume material went toward and around the north side of
 the  butte, although the  plume path varied with changes in meteorological
 conditions.

      Case 211  (0400-0500)

      Halloween morning 1980 also experienced an east-southeasterly (119°)
drainage flow.   During the  experiment the source crane was located about
1,156 m from the hill center at an orientation of 120.5°.   SF, was
                                                             6
                                   53

-------
                                                          LO
                                                          o
                                                          LO
                                                          CN
                                                          
-------
                                                    oo
                                                    o
                                                    LO
                                                    o
                                                    O
                                                    CM
                                                     CD
                                                     tn
                                                     O


                                                     6
                                                     o
                                                     Wl
                                                     c
                                                    •H
                                                     O
                                                     o
                                                     X
                                                     CD
                                                    •H
                                                     S

                                                     CD
                                                    trj
                                                    CM
                                                     bO
55

-------
                                                            co
                                                             CD
                                                             w
                                                             nJ
                                                             t_3
                                                             (D
                                                             O
                                                             
-------
                                               LO
                                               O
                                                CD
                                                to
                                                oj
                                                CD




                                                •P


                                                O
                                                O
                                               •H
                                               ^
                                                O
                                                O
                                                (D

                                                £
                                                w
                                                o

                                                &
                                                CD
                                                •H


                                                 I
                                                
-------
                                                         E-
                                                         c/D
                                                         S
                                                         LO
                                                         o
                                                         O
                                                         CM

                                                          
-------
released at a local height of 20 m; smoke and CF«Br were released at
58 m.  The average dividing streamline height was 28 m.  The Tower A wind
direction near the height of the SF, source varied from 88° to 165°
(5-minute averages) during the hour; the direction near the height of the
smoke plume was steadier, ranging from 115° to. 142°.
     Figures 27 and 28 show plots of the SF  and CF.,Br concentration,
respectively.  The low-level release is below Hcrit and the resulting
SF, plume spread all over the hill, with the maximum hourly concentration
(2,936 ppt) above the relative release height (i.e., approximately 30 m
elevation on CCB compared with a release height of 11 m relative to the 0 m
elevation contour).  High concentrations were measured throughout an area
generally between the 15 m and 35 m contour lines extending from the
measured value of 2,936 ppt to values around 1,300 ppt on the northeast
slope.  SF, concentrations above 1,000 ppt were measured in the draw on
both the windward and lee sides of CCB.  The smoke and CF^Br plume are
transported over the hill, producing essentially zero CF^Br concentrations
on the hill surface.  (The two nonzero values are near the detectable limit
of CF Br.)
     Figure 29 shows a photograph of the smoke plume looking from the
southwest of 0414.  The plume apparently goes up and over CCB with virtually
no ground-level impact.  As shown in Figure 30 (0435), the plume stays
elevated as it is transported over the lee side of CCB.
     Case 211 is a good example of plume transport and diffusion when the
SF, was released below the average dividing streamline height.  The SF
plume apparently impinged on the hill at levels near and 10-20 m above the
relative release height and subsequently spread over and around the hill.
The case also shows the difference between releases below and above the
dividing streamline.  SF  released below H     produced significant
ground-level concentrations almost everywhere on CCB whereas the CF^Br
plume, which was emitted well above H    , went up and over the hill and
produced virtually no ground-level concentrations.
                                  59

-------
  CftSE 211 HR S SF6
Figure 27.   Observed SF6  concentrations (ppt)  for Case 211, 0400-0500.
             Source:  r  =  1156  m,  9 = 120.5°,  relative height =  11.1 m,
             Q = 0.18 g/sec.
                                    60

-------
  CASE 811 HR 5 CF3BR
Figure 28.   Observed CF3Br  concentrations (ppt) for Case 211, 0400-0500.
             Source:  r  =  1156  m,  Q = 120.5°, relative height =  49.1  m,
             Q = 1.02 g/sec.
                                    61

-------
                                                  **
                                                  1—I

                                                  o
                                                   0
                                                   to
                                                   cd
                                                  U
                                                   tO
                                                   CD
                                                   o
                                                   0)
                                                   to
                                                   o
                                                   3
                                                   •H
                                                   B

                                                   
-------
                                                    LO
                                                    to
                                                    CN

                                                     0
                                                     
-------
     Case 210 (0200-0300)

     Both SF, and CF0Br were emitted during this period of stable
            o       J
easterly down-valley winds.  The SF, and oil-fog were released at 57 m;
CFoBr was emitted at 30 m above the surface.  The release crane
orientation was 114° with an average wind direction of 110° at 5.5 m/sec
(estimated for the SF, release height).  The wind measured at the 40 m
level of Tower A varied from 82° to 132°.  The average Hcrifc was 30 m.
     As expected, the CF-Br was transported around the sides (principally
the north side) of CCB (see Figure 31), and the SF& generally went up and
over the hill (see Figure 32).  Evidently there was sufficient turbulence in
the lee of CCB to diffuse the SF, to ground level, thereby producing the
highest concentrations on the northwest lee side.  Figure 33 shows the plume
going up and over the north peak at 0209.  Figure 34, which was taken later
in the experiment at 0535, illustrates a plume trajectory typical of
Case 210.

     Case 205 (0400-0500)

     This case is presented because it was used to illustrate the model
evaluation techniques in Sections 4 and 5.  It is representative of a
near-neutral, east-southeast (118°) flow with a wind speed of 6.0 m/sec at
the SF, local release height of 50 m.  The release crane was located at an
orientation of 120.5° at a distance of 1,156 m from the center of CCB.
     Figure 35 presents the sampled ground-level SF^ concentrations.
Values are relatively low; the maximum occurs well below the relative height
of the release (41 m).  The observed variability of wind direction and
concentrations suggest that the plume covers almost the entire hill during
the hour.
                                   64

-------
                                                                  • 9
  CASE 210 HR 3 CF3BR
Figure 31.   Observed CF3Br  concentrations (ppt) for Case 210, 0200-0300
             Source:  r  =  1085  m,  6  = 114.0°, relative height  =  22  8 m
             Q = 0.95 g/sec.                                            '
                                   65

-------
  CASE 210 HR 3 SF6
Figure 32.   Observed SFe  concentrations (ppt)  for Case 210, 0200-0300.
             Source:  r =  1085  m,  9  = 114.0°,  relative height = 49.8 m,
             Q = 0.16 g/sec.
                                    66

-------
                                            E-
                                            CO
                                            s

                                            Ol
                                            o
                                            CM
                                            O
                                            3
                                            O
                                            co


                                            o
                                            bO

                                            •H
                                            ^!
                                            O
                                            O
                                            
-------
                                        CO
                                        to
                                        LO
                                        bO
68

-------
  CASE 205 HR 5 SF6
Figure 35.   Observed SF6 concentrations (ppt)  for Case 205, 0400-0500.
             Source:  r = 1156  m,  6  = 120.5°,  relative height = 41.1 m,
             Q = 0.09 g/sec.
                                   69

-------
                                  SECTION 3
                          QUALITY ASSURANCE PROGRAM

     A comprehensive program plan provided quality assurance procedures
relating to all aspects of the meteorological and tracer measurements taken
during the field experiments.  This section presents a summary of the
procedures followed during the field study, external audits, data validation
procedures, and a preliminary estimate of data quality.
     All meteorological instrument calibration data have not yet been
received from WSSI, nor have the preformance experiments been performed with
sample wind instruments in a wind tunnel.  Similarly, the results of some of
the tests and experiments relating to tracer gas measurements have not yet
been received by ERT from NAWC.  These missing data and experiments include
the following:

     •    sample degradation with time in the Tedlar sample bags after the
          bags were filled with known gases from the calibration cylinders
          (some data on sample degradation of actual experimental samples,
          however, are reported here);
     •    performance tests of the sequential bag samplers in an
          environmental chamber prior to the tracer experiments;
     •    experiments with flushing the sample bags with nitrogen to clean
          them of tracer gas in order to establish an effective procedure
          for cleaning the bags for reuse in the field experiments; and
     •    chromatograms from bags exposed to large dosages of particulates
          from orange smoke candles and smoke generators.

A final quality assurance program report will be produced when the full
complement of inputs has been assembled and analyzed.
                                   70

-------
     In general, the meteorological data are of excellent quality.  Problems
with UVW propeller transmitters seizing, propellers breaking, and
communications failure between the data collector and the data stations
resulted in a loss of about 18% to 20% of real-time meteorological data
during the experiments.  (Final data-capture statistics are not yet
available.)  This estimate of data loss is by measure, not by instrument;
the failure of one U or V propeller transmitter results in the loss of all
six of the measures that use its input.  Pibal, tethersonde, and minisonde
data may be used to fill in gaps in the definition of the flow approaching
the hill, should a measurement from Tower A be missing or intermediate
measurements be required.
     The audit of the gas chromatographs by TRC indicates excellent accuracy
of the tracer data.  All gas chromatograph responses were within +8% of the
designated concentrations specified by the supplier of the audit gases.
Nineteen of the 25 gas chromatograph audit points were within the +5%
accuracy range of concentrations specified by the supplier for the audit
cylinders.
     Preliminary precision information of the tracer measurements is
presented in Section 3.2.  In general, the precision statistics were very
good for both the SF  and CF^Br tracers.

3.1  Meteorological Data

     3.1.1 Quality Assurance of Meteorological Data

     The basic quality assurance program for meteorological data comprised
the following procedures with appropriate documentation:

     *    performance and calibration checks of the DS-00 microprocessor
          data stations prior to start-up;
     a    mechanical checks and calibrations of all instruments at
          installation and before the tracer experiments;
     e    calibration checks (and, if necessary, recalibrations) of
          replacement instruments during the course of the field, program;
                                     71

-------
      •     two  independent  audits  of  instrument  accuracy  and  data  system
           performance;
      •     calibration checks  at system takedown;  and
      •     real-time  automated screening by  the  data collector computer  for
           values  out of  range.

Although all of these procedures  were  implemented, some  of the documentation
has not yet been  received  by  ERT.
      The major quality assurance  problems with  the meteorological data  were
the result of  unforeseen difficulties with  equipment.  The triaxial
propeller  (UVW) sensors, of which 48 were deployed in the network,
occasionally became  unresponsive.  Sometimes they would  stop turning almost
completely, in x^hich case  the fault was easy to identify.  More frequently,
however, the failure was more subtle—a slight  "stiffening" of the
instrument.  This could  be identified only  by the low ratio of crosswind
intensity of turbulence  (IY)  to downwind intensity of turbulence (IX) if a U
or V  transmitter  failed, or by changes  in the relative values of U or V
components with respect  to an adjacent cup-and-vane wind set in similar flow
conditions but separated by one hour or more.  When a U  or V propeller
failed, it affected  the values of WS, WD, IX, IY, and IZ.*  If a W propeller
failed, it affected  only IZ.  The data have been flagged accordingly.
      The second piece of equipment that failed to perform well was the
unshielded cable used for transmission of data between the shelters (located
on the butte and at  Tower A)  and the data collector computer (in the
operations trailer at Simco Road).  Although ERT had specified shielded
cable for this purpose,  it could not be obtained from vendors in time for
system start-up.  These failures necessitated an unplanned requirement for
detailed value-by-value examination of the measurements taken during the
experiments.
*Measure codes are listed in Table 2; hourly average measures have the
 same code as the 5-minute measures with a "1" suffix added.
                                     72

-------
      3.1.2   External  Audits

      Two  independent  audits  of the real-time  meteorological instruments  and
 data  system  were  performed during  the  first week of  November 1980.   TRC,
 under contract  to ERT,  audited the wind  and temperature systems  at  every
 level of  the six  towers using  conventional techniques  including  Haake
 temperature  baths and synchronous  motors.  Meteorology Research,  Inc.
 (MRI),  represented by Thomas J.  Lockhart and  under contract to EPA,  audited
 an  easily accessible  subset  of temperature and  UVW propellor systems using
 techniques devised by Mr. Lockhart.  TRC audited the instruments'
 performance  by  checking the  voltage  output of the translator cards.   The
 calibration  of  the data stations was audited  separately by  imposing  a
 fixed,  constant voltage on the inputs  to the  microprocessors for  10  minutes
 or  more and  checking  the 5-minute  averages archived  in the  data  system
 against the  measure values corresponding to the  voltage applied.  MRI's
 audit  checked the 5-minute averages  received  by  the data collector directly
 against the  audit values.  Cup-and-vane wind  sets (Climatronics  F460) and
 the orientation of the  wind  instruments were  checked only by TRC.
      The  results  of the audits are shown in Tables 6 through 14.  The data
 for the temperature systems  (Table 6)  indicate that the errors found  in
 TRC's  audit  are often of opposite  sign from those found in  MRI's  audit.
 The largest  error found by MRI, +0.40°C (at 2 m  on Tower B  near the  ice
 point), corresponds to  -0.15°C in  TRC's audit.   Conversely,  the largest
 error  found  by TRC in a system also  audited by MRI was  -0.16°C (near  the
 ice point at 2 m  on Tower A),  for which MRI reported an error of +0.12°C.
     The TRC audit  results of  the nine resistance thermometric device (RTD)
 temperature  systems indicate that the maximum measurement error was  0.20°C
 in magnitude.  The errors at six of  the 18 audit  points  lay within the
 resolution of the  data  system.   The  problem with  the auditing of the
 fast-response bead  thermistors  at 10 m and 150 m on Tower A has been  traced
 to an error in the color-coding of the wiring diagram supplied by
 Climatronics.  This error was corrected in the actual wiring of the sensors
but not on the diagrams  in the  system documentation left in the shelter.
Consequently, the wrong wires were jumpered during the audit.  This error
                                    73

-------
        TABLE 6.   AUDIT RESULTS:   CLIMATRONICS  TEMPERATURE  SYSTEM
   A

   A

   A
                 Level
                (meters)
 20


 60

100

 10

150
                                  Audit Temp.
                                          Error
                                      Response-Audit
 TRC

29.39
 0.38

29.39
 0.38

29.39
 0.38
29.39
 0.38
29.39
 0.38
29.39
 0.38
 MR!

32.54
 0.65
15.89
32.54
 0.65
15.89
 TRC

 0.08
-0.16

 0.10
-0.12

 0.13
-0.11
 0.10
-0.11
-8.75*
-8.59*
-8.64*
-8.49*
 MRI

-0.08
 0.12
 0.04
 0.09
-0.14
 0.10
   B
               30.06
               -0.01
         35.41
          1.16
         19.68
                                                        0.07
                                                       -0.15
                        -0.16
                         0.40
                         0.02
                                30.06
                                -0.01
                                       0.05
                                      -0.15
  D
               30.06
                0.02
                                                        0.07
                                                       -0.13
                               30.06
                               -0.01
                        33.15
                         3.20
                        18.60
                        0.07
                       -0.13
                       -0.14
                        0.00
                        0.04
                               30.06
                                0.02
                                       0.20
                                      -0.07
*The fast-response bead thermistors were audited incorrectly because
 of an error in the manufacturer's wiring diagram that had been
 corrected in the instruments' wiring but not in the diagrams kept in
 the shelter at Tower A.
                                  74

-------
    TABLE  7.   AUDIT RESULTS:   CLIMATRONICS DELTA TEMPERATURE SYSTEM
Tower
  A
  A
 Level
(meters)

   10
   40
                                 Bath  Temp.
     Error
 Response-Audit
      (bc)
TRC
29.4
0.4
29.4
0.4
MRI
32.54
0.65
15.89
0.00
0.65
15.89
TRC
0.032
0.024
0.032
0.012
MRI
0.08
0.16
0.06
. 0.00
-0.09
0.06
  A
   80
                 150
                  10
                  30
                  10
                  10
                  10
29.4
0.4
29.4
0.4
29.6 35.41
-0.01 1.16
19.68
29.6
-0.01
29.6
-0.01
29.6
0.02
29.6 33.15
-0.01 3.20
18.60
Not working
0.092
0.076
0.044 -0
0.000 0
0
-0.044
-0.008
-0.012
-0.004
0.048
-0.012
. -0.084 -0
-0.080 0
0

-
.02
.32
.00
-
-
-
.13
.06
.06
                  10
                29.6
                 0.02
-0.056
-0.120
                                 75

-------



co
S
W
H
CO
CO


g
J_l
I*
>
CO
o
M
5S
Q
H
M
O
co
H
co
3

f-l
M


"^
co
9
1
H




^>
u
u
JI
4J
•M
•o

<
1
U
13
i
14
O
JJ
w






•o
0. U
CO V
•** "is
3



Of
5














>







3










meters j

3 i , $3 , , 3
Z 00 0
A»? On
LJJ OOO OOO OO
r*j OOO OOO OO






M O O O
05 1 I • - II- II
£ oo o


g OOO OOO OO
H OOO OOO OO




fM CM CM CM
il • • |2 • • ||
U| OOO OOO OO
H| OOO OOO OO


, O ir» O o
l-ll O (-4 O -4
g 1 1 . . 11.. II
=2| oo oo



O coeoo co co o co co o
H CO CO O CO CO O CO CO O
1 > 1

CM O O

i— 1 i-H U"l IO
, I .1 , . °° I I °° . I
00 00
i-iO OO OOO OOO »-* »-4
OO OO OOO OOO OO
,





CM <
0 0
It II 1 1 • * II II
o o


I*» rt OO CO^-ICM ^2 CM—t
OO ^*O OOO t— -" ^JO
oo oo ooo ooo- do


it ii i i t • i i r * 111
0 0



CO CO 0 00 CO O CO 00 O 00 CO O CO OO O
co co o oo co o co co o co co o coeoo
III 1 1

O O CM O O

76

-------



o
0)
i
4J
•H
•a
3
,
OJ
1

C£ O •-< O OOO OOO
H OOO OOO OOO
III 1

g III III III
y o^o ooo ooo
H OOO OOO OOO

III 11^ III III III
o o
OOO t-*OO fiOO OOO OOO
OOO tnOO OOO OOO OOO


cso
•-t m
III 1 1 o m ill ill I)'
1

§r--,-« e*jfOf^ oomcsi e^jOeM S^S
OO \£>.-to — < O --t OOO OO^
ooo ooo ooo ooo °^>?

CM CO
III 11^. ! 1 | ° 111 1 1 '
O 0
O-HO --too 2o^4 ooo o--
-------
           TABLE 9.  AUDIT RESULTS:  F460 WIND SPEED SYSTEM
Tower
 Level
(meters)
Audit Speed
  (m/sec)
    Error
Respons e-Aud i t
   (m/sec)
                   2
                  LO
                 150
                    8,6-9
                    8.69
                    8.69
                           0.16
                           0.16
                           0.15
  B
   10
   30
   8.69
   8.69
     0.15
     0.26
                  10
                    8.69
                                                          -0.16
                  10
                    8.69
                                                          -0.14
                  10
                    8.69
                                                          -0.13
  F
                  10
                    8.69
                                                          -0.15
                                 78

-------
   T3
    co
 !-<
wo
        M
        cu
   a-a
   CO v_x
   0)
               oo
                                    o  o
                                        CM
                                         I
O
vO
o-
fn
CO

KH
2
O
#
n
r •»

H
CO
H

^
Q
S
^
O





4J
•M'
T3
3





c
o
recti
•H
Q




/"™N
co
a)
01
S-l
oo
V
-o



o o o
r~ r^ i —


                                   O  O
                                                   O

                                                   CO
                                                   m
                                                   ro
                                                               CO
                                                                                 CO

                                                                                 CT\
                                                                                 r~^
                                                                                 Csl
                                      ON
                                      r~-
                                      CN
ESULTS
PJ
H
Q
O
, — i
W
t-J
<-l
o
 4J
 CU  Q)
nJ  6
              CM  O  O
                                  o  o
                                  r-l  CO
O
                                    O
    o
   H
                                                             Q
                                                                             W
                                                 79

-------
 TABLE 11.  AUDIT RESULTS:  CLIMATRONICS F460 WIND DIRECTION LINEARITY TEST
Tower
 Level
(meters)
  Audit
Direction
(degrees)

  356
   86
  176
  266
Response
(degrees)

   356
    85
   177
   266
    Error
Response-Audit
   (degrees)

      0
     -1
      1
      0
                 10
                    357
                     87
                    177
                    267
                      357
                       87
                      179
                      268
                          0
                          0
                          2
                          1
                 150
                    359
                     89
                    179
                    269
                      359
                       88
                      179
                      270
                 10
                    356
                     86
                    176
                    266
                      356
                       88
                      178
                      266
                          0
                          2
                          2
                          0
                 30
                    359
                     89
                    179
                    269
                      359
                       90
                      180
                      270
  C.
                  10
                    349
                     79
                    169
                    259
                      349
                       82
                      170
                      260
                         0
                         3
                         1
                         1
                  10
                    360
                     90
                    180
                    270
                      360
                       90
                      182
                      271
                          0
                          0
                          2
                          1
                  10
                    359
                     89
                    179
                    269
                      359
                       91
                      182
                      270
                  10
                    364
                     94'
                    184
                    274
                      364
                       93
                      184
                      272
                                          80

-------
TABLE 12.  AUDIT RESULTS:   ORIENTATION OF V PROPELLOR CROSSARM
  Tower
                 Level
              Error  Relative  to True North
                    2
                   10
                   30
                   80
                   150
                      1°42' West
                      2°47' East
                      2°47' East
                      8°14' East
                      6°47' East
                    2
                   10
                   30
                      2°54'  East
                      1°28'  East
                      2°54!  East
                    2
                   10
                      1°58'  East
                      2°22'  East
     D
 2
10
56'  East
14'  East
     E
 2
10
12'  West
19'  East
                    2
                   10
                      1°56'  East
                      1°56'  East
                               81

-------
 td

 CO
to
                              o o  o
                                                 CN1 OO


                                                 O C3
                                                               o
                              o o o
                                                 I   i
CO
>1
CO
                     00
                    •r4
                    PC
                 Q)
                              t-<  O r-<
                                                CM
                                                O  O
                 e  c
                                                o  o
                T3  C
                (3  
-------
TABLE 14.  AUDIT RESULTS:  LANDMARK AND NORTH



          STAKE ORIENTATION ERRORS







                    Landmark Orientation Errors
Tower
A
A
B
C
D
E
F

Audit Audit ERT
Landmark Measurement Measurement
Tower B 177°3' 177°
Tower C 173°22' 173°24'
Tower A 358°46' 357°
Tower A 353°50' 353°24'
None done 	 	
Center of Butte^ 279°43' 279°48'
Tower A, 18' 1°
NORTH STAKE ORIENTATION ERRORS
Tower North Stake Error
Error
-3'
2'
-!•«••
-26'
	
5'
42'

                            2°43!
                            1°36'
                              47'
              D
                     83

-------
was discovered and duplicated by WSSI technicians after the instruments had
been returned to Fort Collins.  When properly wired and audited, the bead
thermistors gave satisfactory responses.  Because these probes were used
only to calculate cr , however, their actual accuracy is not of primary
concern.
     The results of the auditing of the RTD AT systems are shown in
Table 7.  (TRC reported the 80 m AT to be "not functioning," but the data
from Case 213, which began at midnight after the audit, show the 80 m AT
do be working satisfactorily.  In any case, there are no audit data for
this instrument.)  Twelve of the 18 good audits points taken by TRC on the
AT systems lay, within the performance goal of 0.05°C; ten of the points
lay within the PSD guideline criterion of 0.003°C error per meter of
vertical separation; and 14 of the points lay within the union of the two
goals, that is, the larger of 0.05°C or 0.003°C/m.  The only points outside
this criterion were the 2-to-10 m AT'S on Towers E and F.
     Again, the TRC results were not generally duplicated by the MRI
audit.  Eight AT audit points, two on each of four different systems,
were done at comparable temperatures by both MRI and TRC.  Of these, three
of MRI's results showed errors of opposite sign to those in the TRC
results, one showed no error where TRC had found one, and the largest error
(4O.32°C) found by MRI corresponds to an error-free point in TRC's audit.
     TRC audited the 48 Climatronics UVW propellers by coupling the
propeller shafts to a synchronous motor running at 1,800 rpm (equivalent to
8.81 m/sec wind speed), checking the voltage response of the translator
cards, and converting it to meters per second.  The propellers were spun in
both positive and negative directions.  The voltage output of the systems
was also checked x?hen the shafts were held stationary.  The UVW audit data
are shown in Table 8.  An accurate but intermittent response was measured
from the 150 m U component when it was spun in the negative (easterly)
direction.  Large negative errors were found in the V and W components at
2 m on Tower E when spun in the positive directions (southerly and upward,
respectively); these errors were -0.62 m/sec for V and -5.72 m/sec for W.
Other than these anomalous readings, the largest error for any of the
propeller instruments was 0.19 m/sec at Tower C's 2 m V component when spun
negatively.

                                    84

-------
      According to Climatronics'  technical staff, the calibration of a W€-ll
 propeller sensor and translator  is practically linear from the bottom of
 the signal range at maximum negative speed (-25 m/sec or 0 volts) across
 the zero speed point (2.5 volts) to maximum positive speed (+25 m/sec or
 5 volts.)  Consequently, if a large error occurs at a positive speed of
 8.8 m/sec and a small error at a negative speed of -8.8 m/sec, there should
 be a substantial error near zero approximately equal to the mean of the
 errors at +8.8 and -8.8 m/sec.  This was not the case for the audit data
 from the V and W transmitters at 2 m on Tower E.  Furthermore, an error of
 -5.72 m/sec such as that indicated by TRC for the 2 m W prop on Tower E
 would be apparent in the data collected as either strongly negative W's or
 very large IZ's when the propeller changed its direction of rotation.
 Neither of these discrepancies appears in the data, however.
      MRI examined a small sample of the UVW instruments at the 2 and 10 m
 levels of Towers A and B and the 2 and 10 m levels of Tower E, which ERT's
 quality assurance officer requested that MRI examine after TRC's anomalous
 results.  MRI spun the propellor shafts with a small motor that gave a low
 equivalent wind speed of about 0.15 m/sec,  which is close to the instrument
 threshold.  The MRI audit did not find the anomaly in the 2 m W component
 of  Tower E when it  was spun  in the negative direction,  the error being
 +0.04 m/sec at  an imposed speed  of -0.15 m/sec,  but it  did turn up  an even
 more  extreme  anomaly of  -15.51 m/sec  in the V component  when it Was  spun at
 -0.16 m/sec.  This  error was  due to a communication problem in which the
 request  for this  measure value from the data  collector was  received  by the
 data  station  DS-00  as  requested  for the along-wind  intensity of turbulence,
 which was  returned  to  the  data collector in integer form and  interpreted as
 a V-component value.   Other than the  Tower  E  2 m errors,  the  largest  error
 found  by MRI when spinning the transmitters at low  speed  was  -0.12 m/sec  at
 the 2  m  U-component  of the 150 m tower.   This  instrument  had  given a
 positive error of 0.09 m/sec when  spun  at -8.81 m/sec by  TRC.
      Both MRI and TRC  checked  the  instrument  output when  the  UVW shafts
were held  stationary.  Of  the  15 transmitters checked by  both at this  zero
wind-speed  point, four of  the  errors were of opposite sign in the two
audits;  these four errors were also associated with the largest differences
                                    85

-------
In voltage response of the translator cards, the largest such difference
being 0.012 volts, or 0.25% of the instrument range of 5 volts.  The
largest zero offset found by TRC among these 15 instruments was 0.12 m/sec
for the 10 m U on Tower B, for which MR! found an offset of 0.07 m/sec; the
largest zero offset found by MRI (checking the system all the way through
to the data archive) was 0.12 m/sec in the 2 m U-component on Tower E, for
which TRC found an offset of 0.08 m/sec.
     TRC's audit of the nine F460 wind speed systems (see Table 9) showed a
maximum error of 0.26 m/sec at a cup speed corresponding to approximately
8.7 m/sec.  The maximum misalignment of the F460 wind vanes with respect to
ERT's landmarks (see Table 10) was 2° except for the 2 m level of the 150 m
tower, which was mounted on a steel post about 4 m southwest of the tower
to keep it somewhat removed from the disruptive effects of the junction
box, tower elevator, and structural reinforcements of the tower's bottom
end.  The boom at this level could be rotated fairly easily by any
passerby.  The maximum nonlinearity of the F460 vane outputs was 3° (see
Table 11).  TRC's calculations of the errors in ERT's directions to
landmarks and north stakes are tabulated in Table 12, and the total errors
of the F460 wind vanes are shown in Table 13.  The maximum total error was
estimated to be 7° to 9° at the 2 m level of Tower A.  All other vane
systems were judged to be accurate to within approximately 3°.
     The orientation of the UVW systems was audited by TRC by checking the
axis of the V-component transmitter with respect to true north (see
Table 14).  The 80 m and 150 m systems at Tower A were oriented
approximately 8° and 7° east of true north, respectively; these
misalignments were clear to an observer looking up the tower from the
ground.  The 16 other UVWs were judged to be aligned within 3° of true
north.
     Finally, the vertical orientation of the W propellers and the
cup-and-vane transmitters was checked by TRC by sighting with a transit
from two directions approximately 90° apart.  The results of this test were
not quantified, but the audit report states that the worst misalignment was
less than 2°.
                                    86

-------
      3.1.3  Data Validation Procedures

      No changes have been made to the values of the measurements in the
 data base in response to the results of the audits for several reasons.
 First,  the audits are not generally consistent with each other,  so that it
 is not  clear what to do to improve the accuracy of most of the data.
 Second, the calibration history of all the instrumentation has not been
 systematically studied for consistency.   Third,  for those instruments  for
 which an error was demonstrated in an audit,  is  discernible in the data,
 and was perhaps even visible to the naked eye (such as the misorientation
 of the  80 and 150 m UVW sets),  it may not be prudent to make adjustments"
 until more information is available.
      The direct measures from misaligned  propellor sets,  for example,  are
 the U and V components and the downwind and crosswind intensities  of
 turbulence IX and IY.   On the premise that the wind speeds determined  from
 U and V are independent  of wind direction,  adjustments could  be made to the
 wind directions and  new U and  V components  resolved.   The  magnitude of  wind
 speed is dependent upon  the wind  direction because  of  the  propellorfs
 non-cosine response  to the wind stack angle.   Errors  introduced in U and V,
 and  therefore wind speed  and wind  direction,  by  this deviation from cosine
 response have not yet  been examined  in detail.   When more  conclusive
 information  is  available,  data  derived from propellers  can be corrected for
 instrument response, and  adjustments  for misalignments  can then be made.
      Data  taken during 17  of the 18  tracer  experiments  of  Phase II are
 being validated according  to the procedures described  below.  (Data from
 Case  212 have not yet  been validated because the tracer plumes never hit
 the hill.)  The 5-minute average data were  the basic measurements received
 by the data collector.  All hourly averages except the turbulence
 intensities and standard deviations of wind direction and temperature were
 calculated by the data collector from  the 5-minute data.  Therefore, the
major validation effort was directed to the 5-minute data.
     The communications problems resulting from the unshielded cable caused
two major  types of errors.  The first type was a miscommunication from a
data station to the data collector which was not always picked up by the
                                   87

-------
parity checking on the transmission.  Such an error resulted in a value
that looked peculiar in the time series of values for the measure
affected.  From the redundant wind measurements (both cup-and-vane and UW
propellers), errors of this type could be fairly easily verified for wind
speed and direction except at the 40 and 80 m levels of Tower A, where the
propellers were alone and vertically separated by 30 m or more from the
nearest source of data for comparison.  Because of the strong thermal
layering during many experiments, it was often not feasible to verify a
communications "hit" by comparison at these levels, and the determination
that a value was suspect or in error depended entirely on whether it was
unreasonable or out of place in the time series.  Calculated temperatures
at 10 m and 150 m could be validated by comparison with the values from the
fast-response thermistors at these sites.  Temperatures and temperature
differences at other heights on Tower A were validated by comparison with
the temperatures above and below the height being validated.
     Fortunately, few errors of communication from the data stations to the
data collector resulted in measure values that were in the range of
possible values.  Most were recognized as faulty by the data collector and
identified as missing by an "M" flag.
     A far more common problem of communication occurred in the data
requests from the data collector to the data stations.  A request for a
wind component might be received as a request for a temperature, and the
temperature would therefore be returned to the data collector, which would
put it into the data base as the wind value.  All measure values were
transmitted to the data collector as integers  (called  "counts") between 0
and 1,023 inclusively.  The data collector converted them to proper
engineering units by interpolation  in the range of the measure.  A
temperature transmitted in error as a wind component would therefore not
appear in the data base as the value of the temperature that was sent but
rather as the value of the wind component appropriate  to the number of
counts corresponding to the temperature.  Consequently one could look
through all the data for the 5-minute scan in which the suspect value
occurred for another measure value  that had the same associated counts.   If
such a measure was found, the suspect value was regarded as bad.
                                    88

-------
     Typically, the same error in transmission of data requests to the data
stations occurred more than once during the course of an experiment, and
this recurrence confirmed the fault.  The data collector sometimes
recognized that an error of this sort had occurred and flagged the measure
value in the subsequent scan with an "M."  The data base therefore
contained good values flagged "M" as well as bad values with no error flag.
     To expedite the time-consuming error check through all the
measurements taken during the experiments, the 5-minute data were retrieved
from the data base in time-series files for each experiment.  In general,
each of these files included all the 5-minute measures for one measurement
height on a tower; there are 19 files per experiment in this "edit"
format.  The program quality assurance officer drew up a series of
guidelines for editing these files and a set of data flags for identifying
the quality of the data.  The flags are the following:

          (blank):   Both the editor and the data system concur that the
          value is valid.
     "M"  (missing):   Both the editor and the data system concur that the
          value is invalid.
     "U"  (unavailable):   The value is unavailable because of data
          collector or data station failure.
     "B"  (bad):   The editor believes the value is invalid but the data
          system did not catch the error; this flag is therefore associated
          either with instrument malfunction or communications problems.
     "R"  (restored):   The editor believes the value is valid, although
          the data system had flagged it "M."
     "C"  (calculated):   The editor calculated a derived measure (WD, WS,
          SP, DR, TC), usually from "R" values.
     "S"  (suspect):   The editor believes the data are somewhat in error
          but cannot confirm either an instrument malfunction or
          communications failure.
                                   89

-------
      "L"  (at limit):    The measure is at the upper limit of its range and
           the "true" value exceeds that shown.  The instrument ranges were
           not themselves exceeded during the experiments, and this flag is
           necessary only for the turbulence data (IX,  IY, IZ, SD) in very
           light and variable winds.

 No  data  have  been estimated and  inserted into the data base.
      The program quality assurance officer personally  conducted a final
 quality  check on all of the real-time  meteorological values  before they
 were  released to the EPA.   In this final editing, he tried to maintain a
 balance  between the premise that all data are potentially valid and the
 premise  that  no data are above suspicion.  Consequently,  if  no instrument
 failure  or communications  error  could  be verified,  a value was regarded as
 valid unless  it appeared to be unreasonable with respect  to  comparable
 values adjoining it in  time or space.   This is generally  not a difficult
 judgment to make,  but in some situations a value may look peculiar but not
 completely unreasonable and might  indicate a significant  phenomenon.   Such
 data  were left unflagged if they were  not misleading or were flagged  "S" if
 they  were sufficiently  removed from the general trend  to  substantially
 influence an  hourly average.
      The different characteristics of  propellor wind sets and cup-and-vane
 systems  are well demonstrated in the CCB data.   In  general,  the vector
 resultant wind  speed from  propellers was less  than  the  vector resultant
wind  speed  from a  cup-and-vane set at  the same location.   The ratio of WS
 to  SP decreases  from 0.8 to 0.9  in high-speed,  smooth  flows  down to 0.5 or
less  in  light and  variable  winds.   In  near-calm conditions,  the props  were
observed  to be more responsive to  gentle puffs  than the vanes,  so  that a
5-minute  wind direction and wind speed  resolved  from the  props  might be
175°  at  0.2 m/sec  whereas  the corresponding  cup-and-vane  direction and
speed might be  245° at  0.5  m/sec.   Both  these  pairs  of wind measurements
might appear in  the data without any error  flag  because there was no
indication of instrument malfunction or  communications error.   The
differences between the measurements are  thus  attributable to the
differences in the instruments.
                                    90

-------
     Similarly, the response of propellor sensors is somewhat
direction-dependent.  Often the difference between WD and DR. at a site
changed markedly when WD passed through a cardinal direction such as 0°,
45°, 90°, or 135°.  Again, the measures were both retained as valid in the
data base.  The users of the data should be aware of these instrumental
characteristics.  To invalidate the data from the propellers would require
that WS, WD, IX, IY, and IZ all be flagged "B" or "S."  Such a requirement
would decrease the utility of the data enormously.
     The differences between the speeds and directions from the two kinds
of instruments show quite general consistency with the differences
anticipated as a result of the departure from the cosine response curve.
Furthermore, the horizontal intensities of turbulence IX and IY tend to
become more nearly equal when the average angle of attack of the wind is
approximately equal on both propellers (i.e., directions near 45°, 135°,
225°, 315°), whereas IX tends to exceed IY when the average angles of
attack are substantially different (i.e., directions near 0°, 90°, 180°,
270°).  This consistency suggests that the quality of the UVW data might
significantly improve if corrections were applied similar to those
described by Horst (1973), which were derived from comparisons of propellor'
data and sonic anemometer data.  ERT has been unable to find any similar
comparative analysis of data for the,Climatronlcs system.
     The procedures for data validation were based on common sense,
comparison between neighboring sensors, searching for measures whose
contemporaneous values were associated with the same "counts" as a suspect
measure, reports of malfunctions in the field logs by the instrument
technicians and others, and by a learned feeling for how instruments track
one another when they are working correctly. Examples of an as—taken file
and its edited version are given in Figures 36 and 37.
     When editing and flagging of the 5-minute data were completed,
hour-averages of the direct measures other than the turbulence measures
were calculated by computer from the 5-minute values; hour-averages of the
derived measures were in turn calculated from these.  A set of
classification criteria and data quality flags has been established for the
hour—averages; it is shown in Table 15.
                                    91

-------
\fl -JOY
1*00 303
I7QO 3O3
I^OO 305
|"i8O 303
1-ftflO 303
iveo 30 a
l««rt 303
l«t& 309
l«90 309
1*00 303
IV&O 305
llflO 3O3
1*PO 303
I Mm 303
l«H«t 303
I'ttO 305
1980 305
IVOO 309
1*00 303
IvflO 303
I*S0O 303
I*tt0 305
IW£» 103
I*»tt0 303
1*00 3fl5
|MfW 3O3
I'«JO 105
I«WM% 303
weu MS
!•»»» 303
l-'Ot) 309
I'TO** 305
|9Qt> 305
liHi*> 303
I«*SO 303
HBO 303
I*W 305
1««0 303
l^6t» 303
l*>fri 303
l<-Bt» 305
l»0fl 303
1*00 ?03
I-HW 305
ivjjo ?C3
IVbf* 31»5
I»M 103
IW1 ^'5
l-Mlfi H>9
ITQO 3O3
1900 303
I *«!O 303
1900 309
1980 303
I90O 3O3
I«BO 3O9
1*00 303
1900 309
t«»9U 309
t«W 303
1*00 3O5
I*il0 3O9
HBO 703
I960 309
t ogo 309
19QO 309
] 505
OOOM -3
6 544
5 997 -3
OOOH
7 17O
OOOH -3
OOOH -3
OOOH
6 857
6 735
7 248
7-322
7 326
OOOM
7, 17O -3
7 268
OOOM
6 818
6 073
OOOH
OOOH -3
7 424
5 469
OOOM
5 758
OOOM
3 039
4 433
4 433
4 157
OOOM
4 120
4 003
4 550
4 785
OOOM
OOOM
OOOM
3 371
OOOM
4 883
onoM
DOOM
5 O9B -3
4. BS3 -3
3 000
4 746
3. 254
5. 663
3 347
OOOH
3, 573 '
OOOH '
3 923
4. 238
OOOH -3
4.433
4 374
4 511
4 511
4. 139
: OOOM
OOOM
OOOM
OOOM -3
2 928
OOOH
OOOH
ooon
3. 006
OOOH :
3 297 A
AL5T
B 631
9 413
9 022
"7 257
B 744
0 OOOH
B, OB4
0 OOOM
7 849
B 084
o ooon
D OOOH
7 771
7 458
7 B47
9 162
7, 849
7. 438
7 693
0 OOOH
B. 397
9 788K
B. 377
7 613
7 673
a OOOM
3 006M
£> 442
!> 5?O
i 570
5 773
5 660
3, 503
3 503
3 816
3 66O
3 660
5 B94
!> 051
S 503
5 816
5. 738
J SR2
3.347
5 112
y 347
J 66O
3. OOOM
3 OOOM
5, 303
3. 303
J. 874
S.. 127
Si. 2O7
I. 816
t 487
.800
034
. 112
OOOM
878
078
034
O34
721
407
330
076
OOOH
783
705
705
739
627
737
, 018
AL6TD
9 115
-3 OOOM
8. 920
9. 096
-3 OOOH
8 900
B, 275
9 233
-5. OOOM
4 873
-5 OOOH
8 B42H
B. 685
-5. OOOH
B. 939
-5, OOOH
9, 526
9. 7BO
1O, 093
9, 7BO
-5,000
B 939H
-3 OOOH
11 344
826
11 149H
-5 OOOH
-5 OOOM
B, 822
-S OOOM
1O, 621
4 638
10 171
11 16B
11 285
11 147
10 953
10 582
10. BV4
1O 797M
1O 347
1O. 562
1O. O54
9 448
7 174
-;; 3?2
-3 OOOM
-5 OOOM
-3 OOOM
7. 154M
B 803
-5, OOOM
7, SOS
-3, OOOM
7 336
5. 166
4. 286
4 3B4
4. 638
-5 OOOM
3 715
4. 071
4 286
4 130
-3. OOOM
3, 661
-5. OOOM
4. 580
-5 OOOM
7. 7O3
B, O40
7. S84
7.667
6. 769
-5, OOOM
4. 4B2
AL6TC AL7T
7 927 7. 761
OOOM 7 961
9 B09 9 883
OOOM -30 OOOH
OOOH -30. OOOM
9 397 -30. OOOM
9, 086 7, 413
B 793 9 101
OOOM -30. OOOM
5. 528 -3O OOOM
OOOM -3O OOOM
OOOM -3O OOOM
B. 558 7 1O1
, OOOM -3O OOOM
0 656 7 022
OOOM 7 1O1
8. 617 -30 OOOM
8. 402 0. 066
0. 4SO 0. 866
OOOH B. 866
OOOM 8. 866
OOOM 8. 788
OOOM 8. 710
8715 -3O. OOOM
-1 760 8, 71O
OOOH 0. 700
OOOM 8 553
OOOM -30 OOOH
7 13! -30. OOOH
OOOM -3O OOOM
6 349 6 320
445 6 S9B
6 6B1 8 210
7 O53 -30. OOOM
7 P48 8. 162
7 1
-------
980 305
950 305
980 305
9C>0 3O5
980 3O5
900 305
98G 305
9SG 305
•J80 3O5
«RO 305
980 305
960 3O5
'•'BO 30.5
V30 305
9BO 303
*80 3O5
98O 305
930 305
980 3O5
96O 3O5
9BO 305
980 3O3
*.'80 305
98O 3O5
«HO 3O5
'*BO 3O5
veo 305
9BO 3O5
9(3r, 305
•VRO 3O5
^8O 3O5
980 305
980 3D 3
V0O 3O3
"&<•• r,K>5
"80 305
^a<> 3O5
'-BO 3O 5
"BO 3O5
9(30 305
VI30 3O5
',r,0 JO-,
980 305
98O 3O3
9BO 3O5
980 305
"BO 3O3
980 3O5
980 3O5
980 305
980 3O3
980 303
980 3O5
9BO 305
980 3O5
980 3O5
9BC) 303
9SO 305
980 305
98O 3O3
98O 303
98O 305
9BO 305
9BO 3O5
980 305
980 303
•?B() 3O3
980 3O3
980 3O3
9BO 303
98O 303
900 30D
98O 3O5
980 303
O O
0 600
O 70O
O 150O
O 1POO
O 2400
0 3000
O 3300
I O
1 300
1 600
1 9OO
1 1200
1 1500
1 1800
1 2400
1 270O
1 33OO
2 0
2 600
2 900
2 I2OO
2 1800
2 2100
? 27OO
2 3000
2 3300
3 0
3 300
3 600
3 7OO
3 1500
3 180O
3 2100
3 270O
3 3OOO
3 3300
4 O
4 600
4 9QO
4 120O
4 1500
4 2100
4 2700
4 3000
4 33OO
5 0
3 30O
5 60O
5 70O
5 1500
3 I80O
3 2400
5 3000
6 0
6 60O
6 120O
6 1500
6 2100
6 27OO
6 3300
7 O
7 300
7 600
7 90O
7 I2OO
7 I30O
7 iaoo
7 270O
7 3OOO
7 33OO
8 O
81 1
*. 890
Bit
4?0
QI1C
-30 OOOU
O29C
809C
49BC
34 2C
- 127
- 362
- 283
- 362C
- 909
-I 613C
- 987
029
-1 691
-2 630C
-2 786
-2 331
-3 177
-3 49O
-1 691
-1 222
-I 3'/8
-3 099
-4 27?
-3 0O3C
-3 49O
-4 115
-4 O37
-3 B»1C
-3 /IM
-3 724C
-4 506
-4 507C
-4 8 I'M.
-4 5OT.
-•4 o;j>*
-4 741
-4 272C
-3. 646C
-3, 803
-4 O37
-3. 333
-2 630C
-1 535
-1 37B
-1 300
- 206C
1 202
1 ?Q1
1 20?
1 437C
1 359
1 124
420
- 362
-1 691
-3 49OC
-3 aaiR
-4 113
-3 959
-2 786
-I 222
- 596
- 127
2 331
I, 977
1 704
2 937
3 36O
-5 OOOU
2 429
1 354
1 667
-D OOOM
-5 OOOM
1 413
5 479
7 845
3 426
3 739
5 027
5 518
-5 OOOM
6 867
6 730
7 082
5 850
-5 OOOM
4 091
-5 OOOM
6 300
6 870
D 127
4 775
4 932
5 87O
5 a?on
-5 OOOM
-5 OOOM
4 347
3 974
4 97]
'j OOOM
•r> OOOM
3. 909
6. 163
5. 787
6, 163
5 831
-5, OOOM
4 326
4 013
4 326
3 132
2, 097
1 393*
1 17B
1 784
1 549
1 647
-5 OOOM
-5 OOOM
-5 OOOM
3 O33
4 599
-5 OOOM
5 44O
6 065
3 641
-5 OOOM
2 1 16
-5 OOOM
3 142C
2 867C
2. 595
3 436
4 179
OOOU
2 458
2 243
S 165C
OOOM
OOOM
5 117C
6. 936C
1 813
2 732
5 058C
3. 827C
OOOM
4 081C
4 177C
3 905
2 361
OOOM
3 B67C
OOOM
3 O28
2 067
1 637C
66O
894
1 9B9
2 302C
OOOM
OOOM
- 181
- 333
152
OO.OM
OOOM
1. 168
1 891
2.341C
1 970
1 794C
OOOM
1. 696
2 478
1, 852
1 871
2. 593
2 459C
2. 986
2 986
3 O06
. OOOM
OOOM
OOOM
1 398
1. 1O9
OOOM
1 323
2 1O7
1 09O
OOOM
1 676
OOOM
4
5
5
4
5
-30
5
5
-3D
6
5
6
7
3
4
6
3
4
4
3
5
4
32
4
4
3
3
3
-3O
2
3
3
1
3?
3
4,
4
4
4
3
4
3
3
2
2
2
3
3
3
7
3
3
2
1
2
1
2
1
2
643
582
582
878
816
OOOU
816
423
OOOM
285
347
833
38O
236
252
129
191
487
936
123
816
721
637D
643
878
937
157
236
OOOM
688
001
236
923
766
984
A39B
923
906
in?
096
174
409
O18
783
O18
7O3
861
174
61O
845
923
47O
392
627
693B
548
314
332
828
141
843
9O6
987B
332R
5, 89O
7,023
6 730
-3, OOOM
5 733
-5 OOOU
-5 OOOM
6. 313
-5. OOOM
-5 OOOM
-5, OOOM
7 219
7, 610
B. 431
-3, OOOM
8 137
-3 OOOM
B, 666
-5 OOOM
-3 OOOM
10, 6O1
9 838
-5 OOOM
7 ISO
6 9B4
9 311
B 236
7 923
8. 275
-3 OOOM
7 834
8 1 18
B 509
-5, OOOM
9 330
-3 OOQM
10 3?7H
9 819
9 O76
9 839
-5. OOOM
B, 744
-3. OOOM
8. 920
8 333
7 688
6 789
3, 974
2, 449
3. 035
3 231
2. 996
3, 152
3. 033
-3. OOOM
-3. OOOM
4 619
6 359
7 121
7, 393
-5 OOOM
-5 OOOM
6 7O1
7 913
7 561C
OOOM
6 544
OOOU
OOOM
7 170
OOOM
OOOM
OOOM
7 24B
7 322
OOOM
7 170
OOOM
6 818
OOOM
OOOM
7 424
6 369
OOOM
5 958
5 762
S 371
5 039
4 4U3
4 433
4 159
OOOM
4 003
4 550
4 785
OOOM
4 S24C
OpOM
S 5O8C
I? 391
4 88J
5 098C
. OOOM
3. O98
OOOM
4 883
•5 ODD
4 746
5 2S4
3 768
3 651C
4 238
4 433C
4 433
4 311
4 159
OOOM
OOOM
2 728C
2 869
2 928
3 436C
OOOM
OOOM
8 631
9 022
9 257
-3O OOOM
8 084
-30. OOOU
7 849
B 084
-30 OOOM
-30, OOOM
7 771
7, 43B
7. 849
8 162
7. 849
7 693
-30 OOOM
B. 788R
8 397
7. 693
-30 OOOM
8 006R
7 224
6 520
6 598
6. 442
6 207
5 773
5 66O
5 5O3
5. SO3
3 816
3 66O
5 894
6 O51
5 582
-30 OOOM
5 816
3, 73S
5 582
311?
3.347
3. 66O
-30, OOOM
3. 347
-3O OOOM
3 503
3. 3O3
3 874
4. 643
4 BOO
3 112
-30 OOOM
4,878
5, 034
4, 721
4 330
4, 096
-30. OOOM
-3O OOOM
3, 783
3 703
3 348
3 939
9 115
B. 920
7, 076
8 9OO
8 275
-5 OOOU
3 OOOM
4 87 3D
-5 OOOM
8. B42R
8.685
-5 OOOM
B 93?
-5. OOOM
9 326
O. O73
9. 7BO
9. 9375
-5. OOOM
B26Q
1, 147R
-5, OOOM
-5. OOOM
8 8P2
-5. OOOM
B 177
-5. OOOM
O, 621
4 6380
0 171
1 168
1 283
O 953
O 582
O 894
5 244B
0 62 1
O. 347
O 362
O Ob4
9 171
-2. 3228
-S. OOOM
-5. 000(1
-3. OOOM
-3, QOOM
8 8O3
-3. OOOM
-3. OOOM
4 286
4 638
-5. OOOM
3. 915
4 286
-5. OOOM
-5 OOOM
4 380
-5. OOOM
7, 317
7 9O3
7 884
5, 264
5. OOOM
f 927
9, B09
9. 9O7C
9, 377
7. OQ6
. OOOU
OOOM
5 528 D
OOOM
9. 194C
S. 558
OOOM
, OOOM
B. 617
8. 48O
8. 793C
B. 96BC
. OOOM
-1. 96OD
8. 598C
. OOOM
, OOOM
7. 131
. OOOM
6. 753
OOOM
6 349
445D
6 681
7, 053
7. 24B
7 072C
7 O14C
7 170
OOOM
6 193
3 84OC
3 743C
5 626
5 137
.OOOM
. OOOM
, OOOM
. OOOM
. OOOM
y. BTIC-
6, 173
. OOOM
. OOOM
OOOM
3. 567
5 917C
. OOOM
5. 352
5. 645C
. OOOM
OOOM
4 218
. OOOM
3. 827
4 O22
4. 081
4, 257
4. 277
OOOM
4 35SC
7. 96 L
9. B83
-30. OOOM
-30 OOOM
9 413
-3O OOOU
-30 OOOM
-30 OOOM
-3O OOOM
-30. OOOM
7. 1O1
-3O OOOM
7, 1O1
-30. OOOM
8.866
B. 788
8 710
8. 71O
8, 7BB
8. 553
8. 162
-30 OOOM
-3O OOOM
7 380
-30. OOOM
6. 52O
6. 578
B, 240
-30 OOOM
8. 162
7. 537
-3O. OOOM
7 537
6 833
6. 031
3 738
5 582
-3O OOOM
-3O OOOM
5, 503
3. 660
3. 738
-3O OOOM
-30 OOOM
-30. OOOM
6.285
6, 32O
6. 833

-30. OOOM
6. 676
-30. OOOM
5 773
5.973
-30. OOOM
4. 800
4 365
-3O. OOOM
4 O18
4. O96
4. 096
-30. OOOM
4. 643
-3O. OOOM
9, 643
9.213
9. 154
9 252
8 744
-5. OOOU
9. 154
8, 627
8. 757
9, 096
9. 389
9. 467
9. 897
10. 406
7,995
8.959
10, 875
11 364
1 1 . 97O
12. 028
14. 668
14. 629
11 403
11. 383
11. SS9
11,731
14. 157
13. 727
13, 725
4. 482B
13. 045
12. 713
12. 361
12. 322
1 1 . 657
11. 012
1O, 714
11. IBB
1O. 152
9. 663
10. 758
1O. 523
9.877
1O. 152
1O. 982
10. 073
9,800
B. 683
7. 736
3. 91 SB
6. 867
6. 730
5. 987
6. 574
8.627
5, 362
5. 186
3.440
6. 476
7. 903
B. 4.7O
8. 333R
8. 548
6. 496
6. 32O
10. 454C
10, 103C
9, 763C
7. 751
9, 553
OOOU
9 340
7. 2B2
9 457
9 438
9. 262C
9. 106
9. 535C
9. 477
7 086
B. 988C
9, 027
B, 871
7. 027
9, 477C
11, 491
11. 139
9. 712C
1O. 161
10. 239
10, 553C
9, BBS
9 926C
1O, 200
, 28BB
f, 164
8, 910
B. 793
8. 597
7, 933
6. 384
6. 307C
6 369
5. 723
5. 626
6,017
6. 251
6. 231
6. 349
6. 344
6. 740C
7. 170C
7. 151
7. 952C
, OOOM
7. 463C
8. 069C
a. one
7, 170
8. OtlC
9. 785
6. 486C
5. 606.
5 156
4 394
4 335
4. 511
4 433
OOOM
4, 374 C
5. 137
5. 508
5. 802
Figure 37.   Example of an edited data file.




                     93

-------
TABLE 15.  CLASSIFICATION  CRITERIA AND DATA QUALITY  FLAGS  FOR
              HOUR-AVERAGES  PRODUCED FROM  5-MINUTE DATA
   Definitions:
        •    Invalid  5-minute data are those flagged either M (Missing),
             B (Bad), or U (Unavailable).
        •    Valid 5-minute data are those flagged  either " " (Good),
             C (Calculated) or R (Restored).
        •    Doubtful 5-minute data are those flagged  either S (Suspect)
             or L (at Limit).

         MB - Number  of missing and bad 5-minute values
          U =• Number  of unavailable values
        GCR - Number  of good, calculated, or restored  values
         SL = Number  of suspect or at-limit values
   Cases
        I.    MB + U - 12
             1) U < MB
             2) U >. MB
       II.    6 < MB + U < 12

             1) U < MB   Hr-avg

             2) U > MB   Hr-avg
      III.    MB + U < 6
                         Hr-avg = -999.0; Flag = M
                         Hr-avg = -999.0; Flag = U
                      lyalid + jdoubtful.
                            GCR  + SL
                              Same
                                        ; Flag = M

                                        ; Flag = U
1) GCR >  10   Hr-avg

2) 7 < GCR    Hr-avg
                                        GCR
                                            -; Flag
                                       valid           .          .
                                       • GCR ; Flag - I (Incomplete)
                                            invalid +  doubtful
                                                GCR + SL       :
3) GCR <  6 and SL - 1  Hr-avg
4) GCR <  6 and SL > 1
                               yvalid  + doubtful
   1)  S  > L       1  Hr-avg - ^	GCR + SL	;
                                                -; Flag
                2)  S < L
                      Hr-avg
                                                  Same
                                                ; Flag = L
                                    94

-------
 3.2   Tracer  Data

      3.2.1   Quality  Assurance  Procedures  During  Field  Study

      Strict  quality  assurance  procedures  were  followed during  every  phase
 of the  tracer  sampling and  analysis  field program.   These  procedures
 included:

      •    multipoint calibrations of every gas chromatograph at  the  start
          and  finish of each analysis day;
      •    span checks every four hours on every  gas  chromatograph;
      •    recounts (samples analyzed twice on  different gas chromatographs)
          on 5% of the total samples;
      ®    background air samples upwind of the tracer  release  in every
          experiment;
      «    pairs of co—located  samplers set up  at two locations in every
          experiment;
      e    testing of sample degradation with time in the sample bags up to
          42 hours;
      a    an independent audit on the accuracy of the  SF  analysis system.

Each  of these  quality assurance procedures is discussed below in more
detail.
      Calibrations were performed on  each gas chromatograph at the start and
finish of each analysis day.  However, because a typical analysis day was
16 hours long,  a span check with one calibration gas (usually 100 ppt
SFg) was performed every four hours  on every chromatograph to check any
response drift with  time.   If the span check showed a greater than 5%
difference from the most recent calibration,  that.chromatograph was
completely recalibrated with all of  the calibration gases.  On the average,
one extra calibration during the analysis day was performed for each
chromatograph because of failure to  pass a span check.
                                    95

-------
      Roughly 5% of the samples analyzed in each test were analyzed again,
 usually on a different gas chromatograph.*  The results of these recounts
 are summarized in Table 16.  The results are segregated into low and high
 SF, and CF0Br concentrations because of the higher imprecision inherent
   6       3
 in concentrations near the lower detection limit.  The recount statistics
 on the higher SF, and CFJBr concentrations were very good, with 89% of
 the SF, recounts greater than 50 ppt within +15%, and 95% of the CF~Br
       6                                                            ->
 recounts greater than 1,000 ppt within +10%.  The CF3Br recount
"statistics were somewhat better than the SF, recounts, possibly because
 all CF,Br samples were analyzed on one gas chromatograph.
      Background air samples taken upwind of the tracer release system
 consistently recorded zero concentrations for both SF, and CFJBr.
 Therefore, contamination from sources other than the release was not a
 problem.  Perhaps the best documentation of the lack of background air
 contamination was Case 212, in which the tracer plume missed the hill for
 the entire 8-hour experiment.  No concentrations higher than 5 ppt SF,
 (the detection limit of the gas chromatographs) were recorded during this
 8-hour experiment, indicating no background contamination nor any residual
 contamination in the sampler or the sample bags from previous experiments.
      At two locations during each experiment, two samplers were placed side
 by side and set to sample air during the same time periods.  These
 co-located samplers were used to assess the variability in the sampling
 technique.  The results are shown in Table 17.  Because of random sampler
 failure, the co-located data capture was relatively poor.  The co-located
 statistics were somewhat poorer than the recount statistics, with only 50%
 of the SF- co-located samples (greater than 50 ppt) within +15%.  One
          o
 reason for this relatively poor comparison may have been  the intermittent
 pump sampling; because the samplers took in air for only  one second every
 15 seconds, they were not  sampling the same air parcels because the
 samplers were driven by separate timers.
 *A11 CF3Br analyses were done on gas chromatograph No. 8, the AID
  instrument, since this was the only one that could separate SF5 and
  CF^Br.  Hence, all recounts for CF3Br were also done on this gas chroma-
  tograph.
                                      96

-------
                       TABLE  16.   RECOUNT STATISTICS
Percent
Difference
0-5
5-10
10-15
15-20
20-25
25-30
>30
No. SI
<50 ppt
221
26
28
13
11
15
57
?5 Samples
>50 ppt
140
65
42
16
5
5
4
                                                  No.  CF3Br Samples
Total
371
111
jjlOQO ppt

    11
     9
     2
     2
     0
     1
     1

    26
>1000 ppt

    17
     2
     0
     1
     0
     0
     0

    20
               TABLE 17.  CO-LOCATED SAMPLER STATISTICS
Percent
D if ference
0-5
5-10
10-15
15-20
20-25
25-30
>30
No. SF6
£50 ppt
28
0
0
1
0
1
17
Samples
>50 ppt
3
3
3
1
1
1
6
                                                  No.  CFjBr Samples
Total
 47
 18
£1000 ppt

     7
     1
     1
     0
     1
     0
     3

    13
                                                             >1000 ppt

                                                                  0
                                                                  0
                                                                  0
                                                                  0
                                                                  2
                                                                  0
                                                                  0
                                  97

-------
      During most  experiments,  all  samples  were  analyzed within  24  hours;
 the  longest time  period  between  sampling and analysis  for any experiment was
 48 hours.   A test was  made to  determine if any  sample  degradation  took  place
 in the  Tedlar bags by  analysing  five  test  samples  immediately and  at various
 times up to 42 hours later.  The results are shown in  Table  18.  As shown,
 no sample  degradation  was  apparent for any of the  samples; the  concentration
 variability was well within  that demonstrated by the recounts.

      3.2.2  External Audits          _=,.^..,

      Under subcontract to  ERT, Edmund J. Burke, manager of quality assurance
 at TRC  Environmental Consultants,  supervised an independent  performance
 audit of the four chromatographs that were  operational in the Boise
 laboratory on the audit  day.   The  results,  shown in Table 19, indicate  that
 15 of the  20 audit samples were  within the  +5%  limit of accuracy given by
 the  supplier (+3% for  Gas  3),  and  all samples were  within +8%.
      Because the  calibration gases used by  NAWC and the audit gases used by
 TRC were all supplied  by Scott-Marrin, Inc., of Riverside, California, the
 audit gases  were  subsequently  analyzed by  C. Ray Dickson at  the NOAA Air
 Resources  Laboratory (ARL) in  Idaho Falls to check  the concentrations (and
 hence the  calibrations of  the  GCs  in Boise) against standards other than
 Scott-Marrin's.   The results of  these replicated analyses are also listed in
 Table 19.   If  the  results  for  Gas  5 are disregarded because  the
 concentration was  outside  the  range of calibration  of the ARL system,  the
mean  analysis  for  each of  the  other four audit gases was within 6% of the
 concentration  indicated by Scott-Marrin.

      3.2.3   Data Validation Procedures
     As discussed in Section 2.3, all sampler and analysis data were entered
into the ERT computer during the field study, and concentrations were then
calculated on the basis of the two closest calibrations before and after the
analysis time.  Because of the time constraints during the experiment, it
was not possible to double check the data entry process during the field
study.  All tracer data files were therefore validated after the field
experiment was over.
                                   98

-------
TABLE 18.  SAMPLE DEGRADATION TEST

Sample
1




2




3




4 '




5




Time in
Bag (hr)
0
6
11
18
42
0
6
11
18
42
0
6
11
18
42
0
6
11
18
42
0
6
11
18
42
                 SF6 (ppt)

                    11
                     9
                    13
                    15
                     9

                    23
                    21
                    22
                    22
                    21

                    24
                    21
                    24
                    24
                    22

                    45
                    46
                    51
                    47
                    48

                    68
                    67
                    66
                    72
                    66
   (ppt)
  490
  510
  480
  420
  450

 2,970
 3,030
 3,250
 3,090
 3,130

 5,530
 5,550
 5,670
 5,520
 5,630

 6,270
 6,330
 6,340
 6,400
 6,500

4,100
4,110
4,160
4,110
4,100
               99

-------
            TABLE 19.  RESULTS OF ANALYSES OF TRC'S SF, AUDIT GASES
                                                       o
                            (concentrations in ppt)
                                            SFft Audit Gases
Concentration Analysis
Supplier's Analysis*
GC No. (Make)
5 (S3)
6 (S3)
7 (S3)
7 (S3)**
8 (AID)
Avg/Std Dev
ARL/NOAA Analysis
Std Dev (No. of pts)
Percent Differences
GC 5 - Supplier
GC 6 - Supplier
GC 7 - Supplier
GC 8 - Supplier
Average
GC 5 - ARL
GC 6 - ARL
GC 7 - ARL
GC 8 - ARL
Average
ARL - Supplier
Gas 1
99
105
101
96
96
99
100/3.8
95
2.5(22)
6.1
2.0
-3.0
0.0
1.3
10.5
6.3
1.1
4.2
5.5
-4.0
Gas 2
247
260
244
241
234
264
252/11.4
235
2.6(19)
5.3
-1.2
-2.4
6.9
2.2
10.6
3.8
2.6
12.3
7.3
-4.9
Gas 3
505
518
483
465
471
510
494/24.5
484
5.1(19)
2.6
-4.4
-7.9
1.0
-2.2
7.0
-0.2
-3.9
5.4
2.1
-4.2
Gas 4
1,000
1,000
954
958
950
989
975/22.7
1,060
11.6(10)
0.0
-4.6
-4.2
-1.1
-2.5
-5.7
-10.0
-9.6
-6.7
-8.0
6.0
Gas 5
10,300
10,100
10,400
10,500
10,300
10,700
10,400/250
7,990+
15.6(10)
. -1.9
1.0
1.9
3.9
1.2
__+
—
—
—
—
—
Mean Absolute Percent Differences
NAWC GCs - Supplier 3
NAWC GCs - ARL 6
ARL - Supplier 4
.1%
.2%
.8%
Avg
Avg

NAWC GCs
NAWC GCs

- Supplier
- ARL

1.7%
5.6%

 *Gas supplier certified Gas 3 to +3%, other gases to ^5
**This audit of GC 7 was done with audit gases first injected into Tedlar
  sampler bags and then into the GC; results were not used in the remainder
  of this table.
 4-ARL's GC was not calibrated for SFg concentraitons as high as Gas 5 and
  gave a low response.

                                   100

-------
     The entire tracer data base (over 14,000 data points) was methodically
checked line-by-line against the original data sheets.  This validation
process revealed numerous simple data entry errors, primarily in the sampler
on-off times, which were relatively easy to correct.  Other discrepancies,
such as uncertain sampler locations, were resolved using best judgment.
Questionable data that could not be resolved satisfactorily (such as unknown
sampler times) were deleted from the data base.  Questionable tracer
concentrations, which conceivably could be resolved by reviewing the
original recorder strip charts and integrator tapes, were indicated by a "Q"
in the tracer data files.  These questionable data consisted mainly of
recounts and co—located samples that differed by more than +30%, in addition
to other probable errors in transcription from the integrator tapes to the
data sheets.
     The systematic line-by-line check of the original data sheets was
complemented by a number of computer tests on the data base.  These quality
assurance computer checks included:
          A printout of any sampler on-off times outside the time window of
          the experiment and any times indicating other than 10-minute or
          hourly averages.  In many of the tracer tests, some samples were
          actually taken after the experiment had concluded; these data have
          been kept in the tracer data base for possible use in following
          the tracer decay with time after the release was stopped.
          A printout of all tracer data indicating the same location and
          on—off times.  This check revealed a number of duplicate and
          erroneous entries, as well as the correct co—located sampler data.
          A comparison of all recount data (bags that were analyzed twice on
          a different gas chromatograph).  The recounts are tabulated in the
          data base by the fictitious "75Z" sampler location.
          A printout of all SF  concentrations higher than 1,000 ppt and
          all CF_Br concentrations higher than 10,000 ppt.  These high
          tracer concentrations were then checked again for accuracy against
          the original data sheets.
          A printout of any sampler locations other than those used in the
          field experiments.
                                    101

-------
All obvious discrepancies found by the computer checks were corrected.  The
data sheet verification and computer checking validation procedures
necessitated corrections in roughly 10% of the total number of data points.
                                                                    i
     The tracer data files now contain four different alphabetic codes for
each sample:

     •    G - good sample
     •    B - bad sample (a bag half-full or less but which could still be
              analyzed)
     •    R — recount
     •    Q — questionable concentration (generally, recounts and
              co-located samples that differed by more than + 30%)

It may be possible to resolve the questionable concentrations by reviewing
the original recorder strip charts and integrator tapes.  In the evaluation
and testing of the various air quality models in Sections 4 and 5, only
those tracer concentrations considered good were used in the analyses.
                                     102

-------
                                  SECTION 4
                        AIR QUALITY MODELS EVALUATED

4.1  Introduction

     One key objective for this phase of the program was to evaluate
existing complex terrain models against the CCB field data.  The performance
of the Valley model is of special interest because it is the only complex
terrain screening model recommended for regulatory use by the EPA.
Comparisons of Valley estimates of the peak hourly concentrations with
observed peak hourly concentrations not only test the model's ability to
estimate the peak tracer concentration during the field study but also offer
references of model performance against which to evaluate other complex
terrain models.  Other models chosen with the concurrence of the EPA Project
Officer for evaluation against the CCB observations were COMPLEX I,
COMPLEX II, and PFM.  Two new experimental algorithms—one for flow over the
crest of the hill (Neutral model), the other for stable flow around the hill
(Impingement model)—were developed in this phase of the program.
     None of these more refined models has been validated or accepted for
regulatory use.  COMPLEX I and COMPLEX II have been.issued by EPA only for
public testing and evaluation.  PFM may be made available soon (for the same
purpose) as a modeling system (called COMPLEX/PFM) similar to the COMPLEX
models.  The two new experimental models are very preliminary, contain many
partly tested algorithms, and have no regulatory status.  The following
subsections briefly describe each model and its application to the CCB data.
                                      103

-------
4.2  Valley Model
     4.2.1  Description

     The Valley model (Burt 1977) is recommended by EPA for screening
analyses in support of regulatory decisions (Budney 1977).  Valley is
designed to provide an estimate of the maximum 24-hour pollutant
concentration expected to occur on elevated terrain near a point source of
air pollution in any one-year period.  This concentration is computed with a
steady-state, univariate Gaussian plume dispersion equation, modified to
provide a uniform crosswind distribution over a 22.5° sector, using assumed
worst-case meteorology.
     The model assumes that the plume travels toward nearby terrain with no
vertical deflection until the centerline of the plume comes to within 10 m
of the local terrain surface.  (Thereafter, the centerline is deflected to
maintain a stand-off distance of 10 m from the terrain surface.)  The plume
is considered to impinge upon the terrain at points where terrain height
equals the plume height, and the impingement point used in the calculation
of maximum plume impact is the nearest such topographic point as viewed from
the source, independent of hourly wind direction.
     Worst-case meteorology is that combination of wind speed and
Pasquill-Gifford (PG) dispersion stability class leading  to the highest
concentration at the impingement point.  For most large sources of air
pollution, a stack-top wind speed of 2.5 m/sec and PG stability class F are
recommended for the vertical growth of the plume under inversion conditions
at night when plume impingement  is most likely.
     The model estimate is implied to be a 1-hour average concentration.
The 24-hour average concentration is estimated by dividing this 1-hour
average concentration by four, on the premise that the plume may affect a
specific point for no more than  six hours in any 24-hour  period.
     It should be stressed that  because neither the  tracer source release
heights, crane locations, nor meteorology were equivalently  "persistent"
from hour  to hour during the actual experiment, the  CCB data base is not
appropriate for testing the Valley model as it is used in regulatory
applications.  (The CCB field experiment was not intended specifically  to

                                     104

-------
validate or invalidate the Valley model but rather to assemble a data base
that will support the development and refinement of progressively better
modeling approaches for plume interactions with complex terrain.)

     4.2.2  Application Procedures

     The longest steady averaging period for tracer releases and
concentrations in the CCB field study was four hours.  Most steady averaging
periods were between one and two hours.  Consequently, only 1—hour Valley
estimates were compared with maximum observed hourly tracer concentrations.
     Release crane positions during the experiments ranged from a distance
of 538 m to a distance of 1,452 m from the center of the hill.  The local
release heights of the nonbuoyant tracer gas varied from 15 m to 60 m.  The
distance to the nearest point of impingement was obtained from a contour map
of the hill for each hour of the 45 case hours modeled.  (Section 5.1 lists
those experiment case hours included in the model evaluation.)  These
distances ranged from 213 m to 867 m.  In each instance, the difference
between the local elevation at the crane position and the zero height
contour on the hill was taken into account to maintain the level plume
geometry of the model.  The local elevation at each release location was
interpolated from the nearest survey points and the shape of the local hill
contours.
     Concentration estimates scaled by the emission rate were computed by:
                                                                 (7)
which is derived from Equation 2-1 of the Valley User's Guide (Burt 1977).
                      3
C is in units of  Vg/m , and Q is in units of g/sec.
     The standard deviation of the vertical pollutant distribution (cr )
                                                                     z
is calculated from:
               a  = 0.362 x °"55 - 2.7
                z
(8)
                                     105

-------
 The constants in this equation are taken from Table 2-1 of the Valley User's
 Guide.   They are applicable for PG stability class F over a range of x
 between 100 and 1,000 m, which includes all of the impingement distances
 developed for the 45 test case hours.
      The wind speed was set to 2.5 m/sec, and the stand-off distance (H) was
 fixed at 10 m to be consistent with the regulatory applications of Valley.
 However, because the 10 m value is not based on any theoretical analysis, it
 may not be an appropriate scale for the narrow plume configuration of the
 tracer experiments (compared to plume sizes encountered with large pollutant
 sources).  Therefore,  parallel computations are also presented for the
 centerline (i.e., center of the plume) concentration at the impingement
 point,  not including a surface reflection contribution.

 4.3  COMPLEX I and COMPLEX II Models

      4.3.1  Description
      COMPLEX 1 and  COMPLEX II are  sequential  complex terrain models  designed
to estimate  1-hour,  3-hour,  24-hour,  and  annual  pollutant  concentrations
resulting  from emissions  from many point  sources.   Concentrations  are
estimated  at many receptors  using  hour-by-hour meteorological data.
      Several terrain treatment options  (formulated  by the  Complex  Terrain
Team  at  the  February 1980 Chicago  Workshop  on Air Quality  Models)  are
available  in the COMPLEX  models.   The standard option for  PG stability
classes  E  and F simulates the plume behavior  contained in  the Valley model.
This  was the option  selected  for comparison with the  CCB field data.  (The
COMPLEX models  also  contain a buoyancy-induced dispersion  option,  but this
feature was  not used  in this  modeling because the tracer releases  are not
buoyant.)
      COMPLEX I  is a  univariate Gaussian plume model with 22.5° sector
averaging  in the horizontal.   It uses the PG  stability class  system.
COMPLEX  II differs from COMPLEX I  only in its representation  of crosswind
plume spread.  Whereas COMPLEX I assumes a  22.5° horizontal  sector
averaging, COMPLEX II assumes  the  familiar  crosswind  Gaussian profile.  (In
all other  respects, the two models are identical.)

                                    106

-------
     COMPLEX I is essentially an extension of the direct-impingement Valley
model to hourly averaged wind speed, wind direction, and stability class
instead of the assumed worst-case meteorology; and COMPLEX II merely
replaces Valley's 22.5° horizontal sector averaging with a Gaussian
crosswind profile.  For neutral or unstable conditions, COMPLEX I and
COMPLEX II permit different (nonimpingement) terrain assumptions.  For
stability classes A through D, the terrain treatment allows the plume
centerline to rise over terrain features but at a height less than its
initial height over flat terrain.  Its actual height at any point is
computed from its initial height,^ the local terrain height, and a, plume path
coefficient.

     4.3.2  Application Procedures

     With the concurrence of the EPA Project Officer, it was decided that
for efficiency, the evaluations of COMPLEX I and COMPLEX II with the CCB
data base would actually be carried out by embedding the essential
computational algorithms of these two models within a flexible,
research-oriented computer code.  The COMPLEX algorithms are invoked by
selecting specific options for plume path coefficients, dispersion
parameters, sector averaging, and surface reflection treatment.  The
flexibility inherent in this code structure will allow the testing of
various permutations of the COMPLEX modeling assumptions in future analyses.
     In addition, because this modeling system was developed by ERT
specifically for  the CCB field experiment, it can access any portion of the
CCB data archive.  It retrieves such information as the locations,
elevations, and validated concentrations of all samples recorded, hourly
average winds, and other field data for a given hour.  The predictive
segment of  the code is set up for real-time application via an  interactive
terminal.   It also allows a wide choice of user input and data  override
options, control  over postprocessing, data archiving and file management,
and  statistical and graphical displays.
     Input  data for the models consist of hourly average wind speed and
direction,  source location, source  height, stability class, receptor
location, and receptor height.  Receptor information is provided for all
                                     107

-------
potential (93) sampling locations.  Although the samplers were designed to
measure tracer concentrations no closer to the surface than 1 m, no receptor
height offset was used in the modeling because the overall model resolution
is no more accurate than 1 m.  Source locations are input to the nearest
meter and nearest 0.5 degree (polar coordinates referenced to the center of
the hill).  Release heights relative to the zero height contour on the hill
are input to the nearest 0.1 m.  Average wind speed is input to the nearest
0.5 m/sec, and the wind direction is input to the nearest whole degree.
Data used in the modeling are summarized^in Section 5.2.
     Stability classes used in the modeling required special treatment.  No
attempt was made before the fact to select only the one PG stability class
that is most appropriate for a given hour.  Instead, both models were run
three times for each hour, assuming (in turn) stability classes D, E, and
F.  Thus, for each hour of observational data, six model predictions were
generated—three for COMPLEX 1, three for COMPLEX II—with the following
rationale.
     The PG stability classification scheme, in conjunction with the PG
dispersion coefficients, is strictly applicable only to near-surface
releases; its use to characterize dispersion of plumes at elevations of 30 m
to 40 m in a very stable, layered flow is less justified.  It was therefore
prudent to run COMPLEX I and COMPLEX II with the same range of stability
classes for all of the case hours and compare observed and predicted
concentrations for each hour to judge whether the PG classification scheme
was appropriate.
     We made no attempt to compare COMPLEX I and COMPLEX II to the CCB data
in terms of 3-hour or 24-hour averages because the source position or
release height was often changed during  a field experiment.  The CCB field
experiment does not provide a basis for  evaluating the multiple-hour
(running average) performance of these models; only the 1-hour averages may
be legitimately compared.
                                   108

-------
4.4  Potential Flow Model (PFM)
     4.4.1  Description

     The PFM was developed and refined by ERT under EPA Contract 68-02-2759
(Isaacs et al. 1980; Bass et al. 1981; Strimaitis et al. 1981).  Grounded in
both empirical evidence and theoretical arguments, PFM takes as its starting
point the fact that as air flows over and around terrain features, an
embedded plume will experience regions of acceleration and distortion along
its trajectory.  For flow situations in which vertical density gradients are
unimportant and surface boundary layer effects can be ignored, inviscid
potential flow theory provides an analytical tool for approximating velocity
fields, streamline trajectories, and plume deformation in the presence of
simple, isolated terrain features.
     The model calculations of terrain-modified plume dispersion
coefficients and surface concentrations are based largely on work by Hunt
and Mulhearn  (1973) and Hunt and Snyder (1978) on the theory of turbulent,
Gaussian-like plumes embedded within potential flow fields.  Strimaitis
et al.  (1981) describe additional modifications made to incorporate more
general isolated terrain features.  They present a method for incorporating
PFM computations within the framework of sequential complex terrain models
(such as COMPLEX).
     PFM has  recently undergone final revisions allowing it to operate
within  the framework of the COMPLEX models—specifically, a version called
COMPLEX/PFM (Strimaitis et al. 1981).  The version of PFM used in
comparisons against the CCB field data is fully equivalent to the PFM
algorithm in  COMPLEX/PFM.  However, more data analysis  is required in
running PFM separately, as some required input data are computed within
COMPLEX/PFM.
     The  PFM  code  is used to generate a potential flow  streamline that
defines the path of a plume in neutral flow about an isolated hill or ridge
(modeled as either an ellipsoid or a  bluff).  The code  then alters the path
and velocity  along the  path to approximate changes introduced by
stratification  as  measured by the hill Froude number.   Line integrals from
the source then determine cumulative  distortions  in the plume sigmas.
                                     109

-------
Output from PFM includes a file containing the coordinates of the plume
trajectory and a file containing modification factors (for Cf ,  O ,
                                                            y   z
plume elevation, and centerline concentration) that connect flat terrain
values to values consistent with the computed flow field.
     Other subroutines within COMPLEX/PFM use this information in computing
concentrations at all receptors.  A postprocessor performs this function in
a similar way here.  The postprocessor evaluates plume-receptor geometry,
computes modified plume o  and O  values based on Turner workbook
coefficients (although other functions may be substituted easily),  and uses
the hourly emission rate and wind speed to calculate the field of
concentration estimates in a format consistent with the requirements of the
statistical analysis software.

     4.4.2  Application Procedures

     PFM requires the following information:

     •    hill shape:  along-wind and crosswind aspect ratios,
     •    effective hill height,
     •    distance from source to hill center,
     •    effective source height,
     •    wind angle (zero degrees takes the  plume over the hill center),
     •    effective Froude number, and         ;
     •    downwind receptor resolution.        J

     The CCB-specific postprocessor requires  the following information:
          local source height,
          absolute hill height,
          height of the critical dividing streamline (H  ^f
          actual wind speed and  direction,
          emission rate,
          PG stability class, and
          sampler positions and  heights.
                                  110

-------
     Although some of these quantities are needed to run other models (wind
speed, direction, source height and location, and emission rates are
presented in Section 5.2), several are specific to the PFM computations.
These are highlighted below:

     Hill Height and Shape - CCB is taken to be an axisymmetric ellipsoid.
The aspect ratios are therefore equal and are derived by dividing the mean
radius of the hill at the 40 m contour by the total hill height (the 40 m
contour is about halfway up the hill).  The highest labeled contour on the
hill is 95 m on the south peak; the highest contour that virtually spans the
saddle between the peaks is 85 m.  The 90 m contour, which spans much of
both peaks, is taken to represent the top of the hill for modeling
purposes.  The base of the hill is taken to be the -5 m contour height.
(The contour heights on the hill are referenced to the 945 m (3,100 ft)
height contour above sea level.)  Thus, the total hill height is taken as
95 m.  The average radius at the 40 m height contour is 244 m, which gives a
hill aspect ratio of 2.6.
     H  .   - The concept of the dividing streamline height was presented
in Section 1.2.  H  .  values are computed with a hill height of 95 m for
each case hour.
     Effective Source and Hill Heights - The potential flow is assumed to
take place only above a surface defined by the effective value of Hcrit>
as shown in Figure 38.  The region below H     is considered "dead"
insofar as interaction with the plume is concerned.  The hill height is just
that portion of the hill above H    —that is (in cross-section), the arc
AB.  The model approximates this upper portion of the hill with an
equivalent ellipsoid of the same semimajor axes b and c used to define the
entire hill shape.  (The dashed curve represents this equivalent ellipsoid,
exaggerated for illustration.)  Similarly, the effective source height is
the local source height minus H    .  (This definition implies that the
dividing streamline of the flow is assumed to follow the small undulations
of the terrain up to the base of the hill.)  If any release heights lie
below H    , no PFM computation is performed.  This does not mean that the
       crit'
                                    111  .

-------
                 Q.

                CD
                 o>
                ui
                                       
-------
             CQ
             3
             O

             c
             O
             O
             co
             .c
                                          ro
                                         ID-
                                                             CQ
.:=:•  ro

X  «
£.  DC
              CO
          (0
          OC
          s
          3:
          in
    CD
    GC
    CO
                o
2

O)
'5
CD
CC

IB

§
                                             o
                                       \     I
                                       1     ro

                                       \    9
I
,2
                                                                      m
                                                                      O
                                                                      O
                                                                      a>
                                                                       CQ
                                                                                      C_)
                                                                                     n)
                                                                                    CD CH
                                                                   •H
                                                                   fi CD
                                                                   (/) O
                                                                                    i-l  CD
                                                                                    CD  M
                                                                    CD
                                                                   m  o
                                                                    O  PH

                                                                    g.H

                                                                   • H 13
                                                                    4->  C
                                                                    rt  rt
                                                                                     3 bfl
                                                                                    r-H -H
                                                                                    r-l 
-------
 plume will  impinge somewhere on the hill;  it means only that the flow is
 likely to move  around the hill with more horizontal than vertical deflection
 and  that PFM in its present configuration is not applicable.  Within the
 COMPLEX/PFM system,- a COMPLEX I computation would be performed under these
 circumstances.

      Effective  Froude Number - The Froude  number (Fr) used with PFM is a
 bulk Froude number defined over the layer  extending from H  ..to 150 m
 ~"~~~~*"                                                      cri t
 (the top measurement level on Tower A).   It is  assumed that H  .   caps a
 surface layer of large AT so that  above  H     the temperature gradients
 vary slowly;  hence,  a simple bulk  value  will suffice for the Froude number.
 One  Froude  number is computed for  each hour.

      Receptor Resolution  - PFM is  run for  receptors spaced evenly along the
 trajectory  from the source to ,a point near the  downwind base of CCB.  The
 resolution  varies from 25 m to 36  m along  the direction from the  source
 through the center of the hill. The end receptor is located 600  m beyond
 the  hill center.   Once the PFM computations are made,  the postprocessor
 converts the  plume trajectory and  the plume deformation factors to a field
 of tracer concentrations  for various choices of stability class.

      Following  a  rationale such as that  used to run the COMPLEX models with
 different stability  classes,  the PFM model was  run for each hour  with
 stability classes D  and E to form  two estimates at each receptor  for each
 hour.  (Class F computations have  not been made,  as the class  D and E
 comparisons are thought to form an adequate base  for comparing the relative
 performance of  PFM with the  other  models.)

 4.5   New Experimental  Models

      4.5.1  Overview

      This section describes  initial  progress in the development of new
models to explain 1—hour  average concentration  patterns  observed  on CCB
during the field  study conducted in  the  fall of 1980.   It  must be emphasized

                                     114

-------
that these models are preliminary and subject to change as this study
proceeds.
     A complicated plume dispersion problem such as that presented by CCB
involves a large number of physical processes that together constitute the
relevant physical system.  It is desirable to identify a small number of
essential variables that may control the behavior of the system.  One way of
doing this is to construct a simple model with empirical parameterization of
important effects.*  Testing this type of model against observations can
lead to an understanding of the relative importance of the controlling
physical variables.  This approach to modeling, adopted to guide new model
development, relies heavily on the analysis of concentration observations.
     Two preliminary models are proposed.  One model, the Impingement model,
corresponds to low Froude-number flows in which the plume remains horizontal
as it flows around the hill.  The other model, the Neutral model,
corresponds to moderate or large Froude-number flows and allows the plume to
go over the top of the hill.  The simplicity of these models is deliberate;
it will encourage applications in situations for which input information for
the model is minimal.

     4.5.2  Impingement Model for Low Froude Number Flows

     This preliminary model development effort focused on 1-hour average
concentrations and meteorology to parallel the regulatory use
of existing models.  Visual plume observations made during the field study
indicate that when the flow was stably stratified, there was often
considerable meander of the horizontal wind.  Moreover, horizontal turbulent
intensities averaged over an hour were typically around 20% of the mean
vector average wind speed.  Under these circumstances, it is not physically
realistic to assume that the mean flow can be separated from much smaller
scale turbulence.  This assumption of separability is central to the
theories of Hunt and others (see, for example, Hunt and Mulhearn 1973).  To
be consistent with observations, a distribution of streamlines about a
 *This approach  to modeling  should  be contrasted  to  that which  relies on
  prior assumptions about  the relevant  physics of the  problem in order  to
  assemble  the model by combining detailed mechanistic submodels.
                                      115

-------
"mean" streamline corresponding to the hourly average wind is postulated.
Next, the concentration at a receptor is determined by the probability (the
fraction of time) that the wind blows in the direction of the streamline
that passes close to the receptor.
     Figure 39 is a schematic of the physical situation being considered.
The figure shows that the stagnation streamline is the.only one that hugs
the hill.  If the dispersion caused by small-scale motion (turbulence) is
small compared to the horizontal meandering of the instantaneous plume, the
hill concentration is determined by the probability that the wind blows
along the stagnation streamline.  For a hill with a circular cross section,
the maximum concentration will occur at stagnation point A.  The
instantaneous concentration C. at A can be written as
                            Q/(/2ifu a 6 d)
                                   s z s
                                     (9)
where 6  is the instantaneous angular spread (in radians) of the plume
       s
and d is the distance of the source to the receptor.  The mass per unit
length of the plume is Q/u  where Q is the emission rate and ug is the
mean wind speed at the source.  We can compute u  if we assume that the
flow around the obstacle is described by potential theory.  Then,

                            dw
                            dz
;  z = x + iy
(10)
where w is the complex velocity potential with the argument z given by
                      w
                                                                     (11)
and U is the mean wind speed  far upwind  of  the hill  (Milne-Thompson 1968)
It is assumed that the concentration distribution  is  Gaussian  in  the
vertical.
                                     116

-------
                                                  Instantaneous Streamline
  Stagnation Streamline
Figure 39.    Geometry used in formulating Impingement  model for low
              Froude number flows.
                                  117

-------
     The maximum hourly averaged concentrations, C    at A, can be written
as
                      c    - c.  r
                       max    i J
                                             (12)
where P(0)d6 is the probability that the wind blows in the interval


(6 - d8/2, 6 + d6/2) during the hour.  By assumption, a0>>es and


Equation 12 can be written as
                       max
                                 P(0,)0
                                id  s
                                             (13)
where OQ is the hourly average standard deviation of  the horizontal


wind direction and 0, is the angle between the  stagnation  streamline and
                    d

U.


     With Equation 9, Equation 13 becomes
                       max   /2Tr u O d
                             r    s z
                                                                     (14)
The distribution of P(6d) is assumed to be Gaussian,  so  that  Equation 14


can be written as
max
                               2JTu O crfld
                                 S Z **
                                           exp
                                                                     (15)
Note that in Equation 15, 0 ,  is used  instead  of  the  angular  difference


between u  and the direction  of the stagnation streamline.   This  is
         s

because P(0,) is determined by the upstream flow field  rather  than the
           d

distorted flow close to the obstacle.   In  order  to use  Equation 15,  a


formulation for Cf  is needed; the suggested expression  for a  is
                 z                                           z

presented in Section 4.5.4.
                                    118

-------
     4.5.3  Neutral Model For Moderate to High Froude-Number Flows

     Figure 40 is a schematic of a plume embedded in a neutral flow  (that
is, a flow that can be considered to be a potential flow based upon  the hill
Froude number).  For convenience, an axisymmetric flow is considered.  The
lower figure shows, in cross section, the plume heading towards  the  hill.
As the plume goes over the hill, it is distorted in the vertical and
horizontal directions and its height (the height of the plume centerline
above the hill surface) varies with the distance along the  plume.  These
effects must be parameterized in-a dispersion model.  Based on the model of
Egan (1975), the following formulation for the concentration on  the  hill
surface is proposed:
C(x,y)  =
               2Q
          (2TTuCf CT ) D D
          v    y z'f y z
         exp  -
•
h2
2 -
r
I? / 22
z zf
exp
(By)2
2 2
y yf
(16)
where the subscript f denotes values in the absence of the hill
(e.g., CJ   is the unperturbed horizontal plume spread, and CT   is
the plume spread perturbed .by the hill).  The other terms in Equation 16
are defined as follows:
T| = n /z
     o  r
                                  (See Figure 40)
              D  = a /a   • D  = a  /a
               y    y  yf   z    z  zf
(17)

(18)

(19)
In Equation 18, ^ is the stream function.  The factor C is the ratio of
the streamline spacing at the position of the source to that at a given
distance.  It accounts for the vertical deformation of the plume.  The
justification for using local stream function gradients to account for the
vertical distortion of cr  relies on the fact that O  is relatively
                        Z                          "
small when the flow is stably stratified (that is, when 90/3z is large).
                                     119

-------
                                                   bfl
                                                   0)  (1)
                                                   I"?
                                                   §2
                                                   CD PU
                                                           w  C
                                                             O
O  -H

  f-i



d>  ,^3
e  +->
                                                           O -H
120

-------
     Because of horizontal meandering of the wind, the same assumption
cannot be made to estimate the horizontal distortion factor fi.  To
estimate J3 we use the fact that in axisymmetric flow the angle 4> (see
Figure 40) remains a constant along a streamline.  We next assume that
horizontal plume distortion is uncoupled from turbulent plume spread and
occurs after the plume has spread because of turbulence.  In other words,
the segment AB (in Figure 40), which would describe the plume spread at a
downwind distance x from the source in the absence of the hill, becomes the
plume segment CD at the same downwind distance in the presence of the hill.
In effect, the point ?„ maps onto the point P-j^ on the "flat terrain"
plume.  For a plume directed towards the center of the hill, simple geometry
shows that B> = z /z.*  As a first approximation, it is also assumed that
D  = D  = 1.0.
 y    z
     A hill factor, f,, can be defined as:
                                                                    (20)
Using potential flow theory, Egan (1975) shows that for two-dimensional
flow, fjVL.  On the other hand, ffa is usually smaller than unity for
three-dimensional flows.  The minimum value is close to 1/2.  In
the absence of detailed flow computations, a simple formulation that
interpolates between these two values is suggested:
               fh  =  l-z/2zr; z<
(21)
                   =1/2
When the receptor is not located on elevated terrain (z = 0), f^ =1.0 as
expected.  (Note that Equation 21 does not allow fh to be smaller than
1/2.)
*When the plume direction is not along the radius of the hill, the
 expression for B is slightly less straightforward, although the
 concept behind its derivation is still very simple.
                                     121

-------
      4.5.4  Dispersion Parameters

      Dispersion in stable flows is far from being fully understood, ;although
 some  progress  has  been made in modeling the behavior of surface releases
 (see  Van Ulden 1978).   At the present time, the analysis of lidar data
 collected during the small hill experiment is not complete.  Because  of this
 lack  of adequate theory and data, the suggested expressions for sigmas
 should  be considered very tentative.
      The horizontal meandering of the wind suggests that CT  can be
 expressed as
                    = crX
(22)
where CFg  is measured  at  source  height.   This  equation has  not  yet  been
fully tested.
     For  elevated  releases  in the  stable boundary layer, the vertical  length
scale of  turbulence,  &  ,  can be expressed as
               JL  ^ a  /N
                w    w
(23)
where CT  is the standard deviation  of vertical  velocity  fluctuations and
       w
N is the Brunt—Vaisala frequency.   The  Lagrangian  integral  timescale,  tn,
should be on the order of 1/N.  A typical value of N measured at  source
height during the CCB experiment is  0.05 s   , which translates  to a t,,
of about 20 s.  With a typical wind  speed of  5  ms  , it  is  expected that
d  will approach the large travel time  behavior beyond 200  m from the
 z
source.  Because the source receptor distance was  usually more  than 400 m,
the following equation is tentatively proposed  for cr :
                                                    Z
                         w
                         u¥
(24)
where all of the variables in Equation 24 refer to source height.
                                     122

-------
     A preliminary test of Equation 24 for O  has been made using lidar
data from 15 case hours.  In the course of reducing the raw lidar data, the
Wave Propagation Laboratory (WPL) has computed standard deviations of the
inferred smoke plume density.  These values apply to the nearly
instantaneous distribution of oil fog material in one of several sampling
planes.  Sampling planes lie along rays originating at the lidar location.
Therefore, calculated o  values usually apply to a plane that is not a
                       z
perpendicular slice through the plume.
     An estimate of 1-hour plume sigmas is obtained from these lidar data by
assuming that the effective 1-hour sigma is a combination of the average
instantaneous sigma and the standard deviation of the positions of the
instantaneous centroid of the distribution.  For example, during hour 2 of
Case 202, the plume was sampled five times in a plane approximately 210 m
downwind of the source.  The mean instantaneous sigma () was
                                                         Z
8.6 m.  This average is formed as follows:
                              N
                   = (I   l  a2)172
                    z    VN  1=1  i'
                                  (25)
The standard deviation of the height of the centroid (OH) using N - 1
weighting is 0.9 m.  An effective 1-hour O  is formed according to
                                          Z
                     ze
>2 +
'I
                                                                    (26)
Using the data from Case  202, hour  2, az& = 8.6 m.
     All 1-hour estimates of plume  sigmas .formed in this way from the lidar
should  be viewed as crude estimates only.  Many planes are sampled no more
than three times in an hour, and these may be grouped in the first half-hour
during  some hours.  The results are presented mainly to see if the distance
function proposed in Equation 24 is a reasonable description of plume
development upwind of the hill and  if the magnitudes of the predicted sigmas
are comparable to the observed values.
                                   123

-------
     Table 20 summarizes  the  results  of  the  sigma  comparisons.   In the
table, "R" is the approximate distance of  the  sampling  plane  from  the center
of the hill.  Any distances less  than 300  m  are  likely  to  be  close enough to
the hill to produce significant distortion in  the  instantaneous  plume.
"Calculated O " is the value  of cr  computed  from Equation  24.
             z                    z
Undoubtedly, interpolating measured intensities  of turbulence to the release
height contributes to the imprecision of the estimate.
     There is generally good  agreement between the lidar-derived a
                                                                   z
values and those calculated using Equation 24  in 12 of  the 15 case hours
analyzed.  The mean percentage error  (absolute value of the difference
divided by lidar-derived cr ), assuming all of  the  error is contained in
                          Z
the predicted O  values, is 22% with  a standard  deviation of 17%.
     Agreement was much poorer for the remaining three  case hours.  The
worst comparison is with Case 209, hour 8.
one-third the size of the lidar cr
                                             The calculated O  is about
                                                             z
                                      Calculated cr  for the other two
                                  z               z
hours  differ  from the  lidar sigmas by about a factor of two (100% error).
     Figure 41 'summarizes the behavior of the lidar-derived cr  as a
                                                              z
function  of downwind distance.   Distance is scaled by the length scale u/N,
and CT   is scaled  by the vertical length scale of turbulence in the
     Z
Stable boundary layer,  CTW/N.   Although scatter is certainly evident,
there  appears to  be a  significant growth of cr  with distance.  The curve
of CT   values  calculated with  Equation 24 is also displayed in the
    Z
figure.   Its  square root growth assumption appears to be reasonable.
     Case 209, hour 8,  is plotted separately in Figure 41.  It is the  case
hour with the worst correpondence between lidar observations and predicted
values.   Four of  the five sampling planes show nearly equal plume spread.
This hour, which  has the lowest value of cr /N,  may represent a case in
which  the density stratification inhibits continued plume growth with
distance.
     PG Cf  values are also compared with the lidar observations  in
          Z
Table  20.  In seven of  the 15 case hours,  the best stability class (based  on
0"  alone)  is  class  F; class E appears best in three of the hours.   If
 Z
the same  hours are  classified by the  Turner scheme,  13 hours are classified
class  F,  one  hour class  E, and  one hour class D.   These latter two
designations  agree  with those inferred from the lidar observations.
                                      124

-------
TABLE 20.
COMPARISON OF a  DERIVED FROM LIDAR OBSERVATIONS WITH PREDICTED
              uz
Case Hour
202 1

202 2

204 1


204 8


205 4


205 5


205 6



206 4

206 6
209 1

209 3


209 8




210 3



211 1


211 4


Downwind
Distance
200
520
210
480
225
450
660
130
360
580
555
780
865
350
555
785
350
545
690
800
215
425
225
215
385
485
350
195
95
190
295
510
605
200
295
565
785
210
385
470
445
645
885
R
820
500
810
535
810
585
375
830
600
380
600
375
290
805
600
370
805
610
465
355
380
170
370
775
600
505
640
795
905
810
705
490
395
885
790
520
302
790
615
530
710
510
270
No. of
Lidar
Scans
3
4
5
6
2
3
3
2
1
1
3
3
2
1
3
2
1
3
2
1
5
4
3
3
2
9
2
2
2
2
3
4
3
1
4
5
10
2
2
7
3
3
9
Lidar Derived Calculated
<°,> SH 2ze °z
7.8 2.5 8.2 15.0
12.9
8.6
11.0
3.8
3.4
5.1
7.4
20.3
, 16.6
8.2
7.4
6.9
3.2
8.1
8.8
4.8
6.6
5.8
5.5
3.2
5.2
7.9
8.1
11-2
8.9
7.5
7.4
8.2
9.2
8.6
8.0
6.9
4.3
3.9
6.5
7.2
9.9
8.7
10.6
4.2
5.6
5.9
7.9
0.9
3.2
1.8
2.6
6.3
3.5
-
-
2.6
1.1
8.7
-
4.6
2.6
-
0.8
3.5
-
0.8
4.1
5.8
3.0
8.6
11.9
1.2
7.4
5.0
5.0
7.5
6.6
2.2
-
1.0
1.8
4.2
0.8
0.6
8.2
6.1
3.1
9.0
15.1
. 8.6
11.4
4.2
4.3
8.1
8.2
(20.3)
(16.6)
8.6
7.5
11.1
(3.2)
9.3
9.2
(4.8)
6.6
6.8
(5.5)
3.3
6.6
9.8
8.6
14.1
14.9
7.6
10.5
9.6
10.5
11.4
10.4
7.2
(4.3)
4.0
6.7
8.3
9.9
8.7
13.4
7.4
6.4
10.8
24.2
9.0
13.5
4.1
5.8
7.0
7.5
12.5
15.8
7.7
9.1
9.6
9.2
11.5
13.7
5.6
7.0
7.9
8.5
4.4
6.2
10.9
10.1
13.5
-6.6
5.6
4.2
1.7
2.4
3.0
3.9
4.3
2.3
2.7
3.8
4.5
8.7
11.8
13.0
14.0
16.9
19.8
OW/N
18.6
18.6
7.6
7.6
1.2
1.2
1.2
2.1
2.1
2.1
2.6
2.6
2.6
3.7
3.7
3.7
2.2
2.2
2.2
2.2
2.0
2.0
3.7
6.7
6.7
1.2
1.2
1.2
0.6
0.6
0.6
0.6
0.6
1.3
1.3
1.3
1.3
1.9
1.9
1.9
2.8
2.8
2.8
Pasquill-Gif f ord
g,(D) o,(E) o,(F)
8.5 6.2 4.1
18.9
8.9
17.7
9.4
16.8
22.9
5.8
14.0
20.6
19.9
26.2
28.5
13.7
19.9
26.4
13.7
19.6
23.8
26.8
9.1
16.0
9.4
9.1
14.8
17.9
13.7
8.3
4.4
8.1
11.9
18.6
21.4
8.5
11.9
20.2
26.4
8.9
14.8
17.4
16.6
22.5
29.0
13.2
6.5
12.4
6.9
11.8
15.8
4.4
10.0
14.3
13.9
17.9
19.4
9.8
13.9
18.0
9.8
13.7'
16.3
18.3
6.6
11.3
6.9
6.6
10.5
12.5
9.8
6.1
3^4
6.0
8.6
13.0
14.8
6.2
8.6
14.0
18.0
6.5
10.5
12.2
11.7
15.5
19.7
8.7
4.3
8.1
4.5
7.7
10.4
2.9
6.5
9.4
9.1
11.8
12.6
6'. 3
9.1
11.8
6.3
9.0
10.8
12.0
6.8
7.4
4.5
4.3
6.8
8.2
6.3
4.0
2~.T
3.9
5.6
8.5
9.7
4.1
5.6
9.2
11.8
4.3
6.8
8.0
7.7
10.3
12.8
                                    125

-------
                                                       0  O
                                                       (3  cti
                                                       0)  O
                                                       PM
                                                       0) LO
                                                       0)
                                                       W)
126

-------
     4.5.5  Application Procedures
     The Neutral model was run in much the same way as the COMPLEX models.
The relationship between the source and the receptors on the hill is the
same.  However, several additional meteorological variables are needed:
N (Brunt-Vaisala frequency) and IX, IY, and IZ (turbulence intensities).
N is calculated at release height from the local temperature gradient.  The
intensities of turbulence are linearly interpolated to the release height.
Section 5.2 summarizes these data.
     The Impingement model computes a maximum concentration on the hill
rather than an entire concentration field.  This maximum occurs at the
theoretical stagnation point for a wind flow directed from the source to the
hill center.  The location of this point is approximated in the following
way.
     An average radius for each height contour between 10 m and 60 m is
obtained from a map of the hill.  The contours are evaluated for each 10 m
height change.  Averages are computed from actual north-south and east-west
dimensions.  These radii are then fit with a function of the form
               R  =  A H
                        .B
(27)
where H is the height in meters above the zero height contour, and the
constants A and B are then found to be 970 and -0.38, respectively.  This
function is now included in the modeling system so that the Impingement
model operates from the same input file used to run the Neutral model.
                                      127

-------
                                  SECTION 5
            MODEL  PERFORMANCE  USING CINDER  CONE  BUTTE  FIELD  DATA

5.1  Case Hours Selected for Model Evaluations

     To select case hours for model evaluation, all 120 hours of experimental
data for Cases 201-215 were examined.*  In 21 of these hours, no SFg had
been released.  From the remaining 99 hours, 54 were identified as having
reasonably good SF,. sampling data (i.e., more than trace amounts of SF,
were measured at many samplers on the hill).  These 54 hours are distributed
among Cases 201, 202, 204-211, and 213-215.  Some of the hours removed will
be analyzed at a later date, as they are still considered useful in the model
development and evaluation tasks.
     The final number of case hours selected for model evaluation in this
report was reduced to 45 by removing Cases  207,  208, 213, and 215 from
consideration at this time because quality assurance evaluations of the
meteorological data had not been completed.  The final selection of 45
representative hours was made among Cases 201-202, 204-206,  209-211, and 214.
     Each of the models was evaluated using these 45 case hours except PFM,
which was applied only for hours in which the release height exceeded the
critical dividing streamline height  (Hcrit;) by at least 5 m.  The choice of
a 5 m margin of error in H  .  was included to ensure that the model would
be applied in cases where the plume was higher than the theoretical dividing
streamline height.  A total of 23 of the 45 hours were selected for the PFM
evaluation.  The 45 case hours chosen for the evaluations are described in
more detail in Section 5.2.5.
*Case hour data for Cases 216—218 were not yet fully reduced to be
 included in the comparisons made in this report.
                                     128

-------
 5.2  Data Preparation

      5.2.1  Tracer Release Data

      Release logs maintained during the field  experiment  at  CCB  contain
 information on the release crane position,  the time  and duration of tracer
 releases,  the change in weight  of the  tracer container as the material is
 released,  and the height of the tracer release above the  local surface.  When
 used in conjunction with survey data,  this  information defines the location
 of  the  release point in the hill polar coordinate system  (r, 6,  z) and the
 tracer  emission rate.
      The emission rate  was computed directly from the weight change entries
 for the tracer gas cylinders.   The  weight of the cylinders was recorded
 several times during each hour  and  whenever the tracer was started or
 stopped.   Emission rates were computed for  each hour and  tabulated to the
 nearest 0.01 g/sec for  modeling.  Over the  course of the  experiment,
 characteristic SF& emission rates varied from  0.06 g/sec  to 0.20 g/sec.
      Release  positions  were denoted  by distances from known markers along the
 major roads.   Primary markers were  surveyed for position  as well as height
 with  respect  to  the  zero  height of  the  hill coordinate system (945 m [3,100
 feet] above  sea  level).   Secondary markers were set  out by the tracer release
 crew  and were not  surveyed;  the positions of these secondary markers were
 plotted on the survey map of the hill.  Release locations were described by
 the distance  and direction to the nearest marker.  The coordinates of these
 release points were  then  measured directly on  the map and recorded to the
 nearest meter from the  hill  center and  to the nearest 0.1°.   The angular
 coordinate was later rounded to the nearest 0.5° for input to the models.
      The local elevation  of  the release point was not directly measured but
 rather interpolated from  the elevations of the closest primary markers and
 the general shape  of the  height contours.  In most cases,  bracketing primary
markers existed and the height at an intermediate point could be linearly
 interpolated.  When there was only one primary marker near the release point,
 the shape of  the nearest height contours was used as a guide.  The local
 elevation was  recorded  to the nearest 0.1 m when warranted by the proximity
                                  129

-------
 of the primary markers.   Otherwise,  the elevation was  recorded  to  the  nearest
 0.5 m.
      Release height above the local  surface was measured  by  a calibrated  rope
 hanging from the release system (see Section 2.3.3).   This height  was
 reported to the nearest  meter on the release logs.

      5.2.2  Wind Data
      Wind speeds  and directions  derived  primarily  from  Tower A data  (the
 150 m tower north, of the hill) were  used in the modeling  to represent
 conditions at  the release point.  Meteorology  at the  release height  was
 assumed  to be  equivalent to  the  meteorology at Tower  A  for the same  height
 above the local surface.  If this height corresponded to  a measurement level
 on the tower,  the measurements were  used directly; if the release height fell
 between  two instrumented levels, a linear interpolation was used to  estimate
 the meteorology at the release height.
      At  times, additional guidance was needed  from photographs, tracer
 concentration maps,  tethersonde  data, and data from the instrumented 30 m
 tower on top of CCB (Tower B).   This need arose in cases  in which one of the
 propeller anemometers at the 40 m level  of  Tower A had seized up or when
 there was considerable directional wind  shear  between the instrumented
 levels.   When one  propeller  malfunctioned at 40 m, the wind at that level was
 usually  reconstructed from the good  wind  component at 40 m and the mean wind
 speeds at  the adjacent levels (10 m  and  80 m).  A reasonable interpolation of
 wind speed at 40 m could usually be  corroborated by the derived wind
 direction  (consistent with the good wind component and the inferred mean wind
 speed) and other supporting  evidence (photos,  SFg, and maps).  This was not
 always possible, however;  therefore, the inferred wind speed at 40 m was
 computed  to  be consistent with the most reasonable wind direction in these
 cases.
      For modeling  purposes, wind speeds were rounded to the nearest 0.5 m/sec
 although they are  probably less certain in many cases.  Wind directions were
 rounded to  the nearest 1.0° but the accuracy may be more like ±2°.
 Subjective choices, where they were made, were based mainly on 1-hour average
data.  Later analyses of the 5-minute average meteorology may
                                  130  ,

-------
suggest alternate methods for inferring reasonable wind data for the release
height.                                        v
     Another source of uncertainty in wind data was the problem of
interpreting the 1-hour vector-averaged wind data taken from the propeller
anemometers.  The response of a propeller is less sensitive at large attack
angles.  This loss of sensitivity could be responsible for some
underestimation of wind speed or for several degrees of error in wind
direction, the error magnitudes depending upon both speed and direction.
     Data used in the modeling have not yet been modified for this effect;
moreover, 1-hour vector averages themselves are usually-an underestimation of
actual wind speeds during the hour.  A complete analysis of model sensitivity
to possible underestimation of the wind speed has not been made.*

     5.2.3  Turbulence Intensities

     The 1-hour intensities of turbulence were measured at 2, 10, 40, 80, and
150 m on Tower A.  Linear interpolation was used when the release height did
not coincide with one of these instrumented levels.
     Some horizontal  turbulence intensity data were not available because of
a  seizing propeller anemometer at 40 m.  In such cases, the interpolation was
carried out across the 10 m to 80 m interval.  The vertical turbulence
intensity at 40 m could be corrected in these instances because the vertical
propeller data were good, but the mean horizontal wind was underestimated.
The correction factor was approximately the ratio of the speed from the good
horizontal wind component to the inferred wind speed (see Section 5.2.2).

      5.2.4  Dividing  Streamline Height (Hcrlt)

      Computation of H  .  is based on wind  speed and temperature data from
Tower  A and  the height of CCB.  The effective height of  CCB is taken to be
 *Concentrations from models like COMPLEX,  which use the wind speed
  only for dilution,  are inversely proportional to changes in the wind
  speed.
                                      131

-------
95 m (base at -5 m; "top" at the 90 m contour).  The computation of H   ..
was made from 1-hour averaged data.
     Where valid 1-hour average data were available on Tower A, H   .  was
computed from the data base directly.  In cases where one 40 m wind component
malfunctioned, however, the computation made use of the inferred wind speed
calculated for that height (see Section 5.2.2).

     5.2.5  Summary of Model Input Data

     All of the data used as input to the models evaluated in this report are
listed in Table 21.  The time and date of each of the 45 test case hours is
followed by the SFg emission rate (Q), the relative release height above
the hill zero contour (not the base of the hill), the local release height,
the local height of the critical dividing streamline (H  ^(.)j the release
location, the hourly average wind speed and direction, the turbulence
intensities (IX, IY, IZ), the Brunt-Vaisala frequency (N), and the bulk
Froude number (Fr) of the flow above H  . .  See Figure 38b for a depiction
of the relationship between H  .,., release heights, and the hill coordinate
system.

5.3  Model Evaluation Methods

     The statistical evaluation measures adopted for this report follow the
recommendations of the Woods Hole Workshop on Dispersion Model Performance
(Fox 1981).  Of the broad set of difference measures suggested in the
Workshop report, a subset was judged appropriate for the observed and modeled
concentration data sets.  We routinely calculated and tabulated the following
difference measures:
          the average of the absolute residuals, IC -C I  (the "absolute
the average of the residuals, C -C  (called "the bias" in the
Workshop report);
the average of
gross error");
                               2
the variance of the residual, cr (C -C.) (the "noise"); and
                                  o  p  2
the variance of the absolute residual, CT |C -C |.
                                           o  p
                            132

-------
 co
 o
 CO
 O

 O
                                                         <*i t*S evj e*i «M
 Q

 i

 erf
 o
 Q

 W

 H

 U
 w
 co

 CO
 erf


 1

 w
 CO
 g

 H

 s
 M
   ^1 sssspgssi§sissisillllss§ssslppslsgl|illiii


     Q y
     u ^ ,

     3 g.
0)  B
> fl) ^
*r-l y 4J

•w t-< jr
« 3 M
!-* O *H


£ m x
                                                         4 CQ CD O U1
           §000000000000000001
          __ 000000 000000000001
                                                        \o IA \o o^ o
CM


w
                                133

-------
     In addition, because it is sometimes asserted that observed
concentrations are lognormally distributed, the following relative difference
measures, although not expressly recommended in the Workshop, were routinely
calculated as well:
          the arithmetic and geometric means of the ratio (C /C ) (for
          nonzero observed concentrations) and
          the corresponding variances.
     Data pairings also follow the priority recommendations of the Workshop.
For each data hour, the 1-hour average observed and modeled concentrations
are paired as follows :

     •    The peak observed concentration is paired with the concurrent
          modeled concentration at the same location.
     •    The peak observed concentration is paired with the concurrent peak
          modeled concentration independent of location.
     •    All observed concentrations are paired with the concurrent modeled
          concentrations at the same locations.

     Next, to examine and compare their respective distribution functions,
the concurrent observed concentrations, modeled concentrations, residuals,
and absolute residuals are routinely sorted into frequency histograms so as
to emphasize any gross biases or asymmetries in the distributions.
     In accord with the Workshop recommendations for graphical displays,
concurrent sets of observed and modeled concentrations were also compared in
scatterplots of C  versus C .  Scatterplots of C /C  versus the ratio
                 p         o                    p  o
of release height to critical dividing streamline height (z /H  .  ) were
                                                           IT  CIL It
also generated.  These were done to flag any systematic or clear— cut
differences in how the models performed in the limiting cases of stable
(impingement— type) flow (z «H  . ) or neutral flow (z »H    )
                          i
The form of the scatterplots was chosen to emphasize model relative
performance — for example, to show how many of the 1— hour average model
predictions fall within a factor of 2 (or more) of the observed
concentrations .
                                    134

-------
     Table 22 summarizes the descriptive statistics  (including graphical
displays) used for this report.  In this table,  "paired concentrations" means
sets of 1-hour average observations for the same case hour.  The nomenclature
for "peak values" follows the Workshop report:
          C (1  ,t ) = peak value observed at time t  and location
           o  n  n                                 n
          1 .
           n
          C (1  ,t ) = the corresponding modeled value for the same time
          period at the location of observed peak value.
          C (l..t ) = the peak modeled value for the time t ,
           P  J' n'                                        n
          irrespective of location.
     Finally, in order to compare the overall relative performance of the
different models, statistics for each individual case hour were aggregated
and summarized for the ensemble of 45 case study hours.  Evaluating and
interpreting overall model performance on the basis of these statistics
requires a clear understanding of the relationship between modeled and
observed concentrations.  This relationship is described below.
     Time-averaged concentrations at a single point are governed by complex
phenomena with wide ranges of space and time scales.  Models characteris-
tically use parametric descriptions of many of these phenomena in order to
simplify or reduce the input information and number of computations
required.  Such simplifications introduce many sources of uncertainty and,
therefore, model estimates will usually not agree precisely with observed
concentrations.
     These differences between modeled and observed concentrations result
both from the input data and from the model formulation.  Any discrete set of
model input data is necessarily an incomplete description of the actual flow
field.  Many Gaussian plume models in use today characterize the flow field
by hourly averages of wind speed and direction measured at one point.  This
information is insufficient to resolve the detailed spatial and temporal
structures of the flow field.  Any number of different flow fields may be
described by the same average data, and each distinct realization of the flow
field may produce a different observed concentration at a particular point.
The incomplete model inputs, therefore, lead to an infinite set of possible
                                     135

-------
        TABLE  22.  DESCRIPTIVE  STATISTICS AND ASSOCIATED ANALYSES



    Paired                                           Scatter-   Tabular

Concentrations   Means   Variances   Distributions    plots      Data
                   X
                             X
                                           X
                                                                    X
Peak Values
                   X
                                                     vs. C
                                                 X
C -C
 o  p
X
                             X
                        X
                                                                    X
 C -C
  o  p
X
                             X
                                           X
                                  vs. C
                                                                    X
C /C
 P
X
X
                                                     vs. C
                                                 X
Co(1n> tn)

C  (1  , t  )
 p  n   n
X
X
                        X
                                                 X
 lCo(1n> V-
Cp(1n>
X
X
Co(1n>  tn)

C  (1.,  t  )
 P J   n
X
X
                        X
                                                 X
 lCo(1n>  V-
        '.'
X
X
                                                                    X
 C (1  ,  t )
  on   n
                              X
                                  vs.  Zr/Hcrit   X


                                  vs.  C
                                  136

-------
observed concentrations for each set of input data; or, in other words, the
input data set itself describes an ensemble of possible observed
concentrations .
     The Venn diagram in Figure 42 illustrates the ensembles of observed
concentrations corresponding to two distinct input data sets.  Each input
data set contains the same variables, but their values are different in the
two sets.  In principle, if many more events are observed for the same two
sets of input data, more concentration measurements will be associated with
one or the other of these two data sets.  Eventually, an ensemble of possible
observed concentrations might be described for each set of input data
values.  Ensembles associated with different input data sets may overlap, and
the range of each ensemble will depend, among other things, upon how fully
the input data describes the wind flow's influence on measured concentrations.
     If the input data and concentration measurements contain no measurement
errors, then for a particular input data set the difference between modeled
and observed concentrations will depend upon the standard deviation of the
distribution of possible observed concentrations within the ensemble, and the
difference between the mean of the ensemble and the model estimate.  A highly
accurate model may closely estimate the mean of the ensemble, and may
incorporate enough information so that the standard deviation of the
distribution is a small fraction of the mean concentration in the ensemble.
     A less accurate model that incorporates less input data might also
closely reproduce all ensemble means but with larger standard deviation.  The
performance of these two models will differ because the second model will be
estimating the means of ensembles with broader distributions of possible
observed concentrations.
     Figure 43 illustrates the difference between the two models.  Denote the
less accurate model as model A, with input data set A, and ensemble standard
deviation O .  Model B is the more accurate model.  Suppose an observed
           A.
concentration, C , lies in the region in which the two ensembles overlap.
Model A's estimate of the ensemble mean concentration, C., might not be
useful if o  is large compared to the range of C  over all data sets .
           A                                    O
Model B's estimate of the ensemble mean concentration, that is, C,
provides a more useful estimate of C  because d  is smaller.
                                      137

-------
                                                                      A Single
                                                                      Observed Concentration
                                                                      Corresponding to
                                                                      Inputs I
                                                                     Set of Possible Observed
                                                                     Concentrations Associated
                                                                     with Inputs I
                                                                  A Single
                                                                  Observed Concentration
                                                                  Corresponding to Inputs II
                                                                 Set of Possible Observed
                                                                 Concentrations Associated
                                                                 with Inputs II
             Figure  42.    Relationship  between model inputs,  single  concentration
                           observations,  and the  set of possible concentrations
                           associated with model  inputs.
it
§
                                                   138

-------
                                                                    to
                                                                      1-1
                                                                    cd  CD
                                                                    6  -d
                                                                    •H  o
                                                                    4->  6
                                                                    to
                                                                    (D  CD
                                                                    s
                                                                    O
                                                                        CD  O
                                                                            •P
                                                                            cd
                                                                        0)
                                                                            CD
                                                                            O
td  ^
f-i  pa
•p      o
C  -d  O
CD  fi
O  cd  p!
C      cd
O  <  CD
                                                                    *"Cl  fH  CD
                                                                     <1>  CD  r-H

                                                                     ^  o  "6
                                                                     CD  B  CD
                                                                     CO      CO
                                                                    f>  6  C
                                                                     O  O  CD

                                                                     fi  ^n  CD

                                                                        C  -P
                                                                     C  O
                                                                     CD  -H  CD
                                                                     CD  -P  +->
                                                                     !3  cd  nj

                                                                     
-------
     This way of looking at the relationship between model estimates and
observed concentrations suggests that the performance of a model is
ultimately limited by the amount of input information available.  A good
model will extract and correctly interpret this information so that the
residual between modeled and observed concentrations is reduced to a random
variable.  The observed concentration should actually be treated as a random
variable (Papoulis 1965) because it embodies everything that is "unknown" in
the model.  If two or more models use the same input information, then a
comparison of residuals for each model will show which model is most
successful in interpreting the input data.  Similarly, a comparison of
residuals for models that are formulated in nearly the same way, but that use
different input information, will show the value of incorporating more
information.  The costs of providing more input data and the unavoidable
measurement errors are likely to constrain the benefits of more complicated,
data-intensive models.  Careful analyses of residuals should help in defining
the technical benefits associated with increased modeling costs.
     We will now recast in mathematical terms  the approach to model
comparison.
      Observed Concentration

      Inputs to an air quality model constitute only part  of  the  information
 required to explain concentrations.  If the set of model  inputs  (the "known"
 variables) are denoted by x.. , the concentration C at a specific  location
 can be expressed as
                                                                      (28)
 where f(x , x~) is some function of known variables (the set x^), and
 unknown variables (the set x2).  Because the set x2 can take any values
 for given x,, the concentration C can also assume any of a broad range of
 values.  Therefore, the model inputs x^ define an infinitely large ensemble
 of concentrations.

                                      140

-------
      An observed  concentration C  (x..)  belonging  to  this  ensemble  can  be
 written as  the  sum of  the mean of the  ensemble and  a  random variable  £:
                         
                                                         (29)
       =  0.   In Equation  29,  the angle brackets denote an
ensemble average obtained by keeping x..  fixed.   Therefore, the ensemble
mean  is independent  of x».  If  C  ,is the average over  the ensemble of
concentrations defined by the x.. , then  = C  (x, ) .
                                1         o   1   2.      pi
     The Modeled Concentration
     Equation 29 may be rewritten as:
     .» X2>  "  W
                                                                    (30)
 In this equation only x., is known, so the best a model can do is estimate
 C (x  ).  Because x_ is unknown, we expect any single observation
 corresponding to x  to deviate from the ideal model prediction C (x,).
                                                   2     2      p
 The magnitude of this deviation is determined by <£ > = O .
     Because £ is a random variable, x  should be chosen so that O
 is as  small as possible.  Also, in order to use a model it is necessary to
 know how cr  varies with x .  This means that an air quality model
 should ideally consist of a submodel for C  as well as a submodel for the
 stochastic term £.  While physical principles can help in constructing the
 model  for C , we have to rely on trial-and-error empirical methods to infer
O£.  To simplify the modeling of e, it is convenient to choose the
 model  inputs x1 (and the model itself) so that £ is not a function of the
 inputs x1 .  Equation 30 can then be written as
Co *
                        £(X2)
(31)
Equation 31 then represents the "ideal" relationship between model calcula-
tion and observation.  As described by Box, Hunter, and Hunter (1978), such a
                                  141

-------
model produces e's that have zero mean and constant variance (independent
of x,), and are distributed independently of one another.  The characteris-
tics of an adequate model can then be described in terms of the residual
£ 3 C -C .  With a series of observations and calculations we can
     o  p
calculate the following statistics:
     e «  —
                                                                         (32)
                    - F>
                                                                         (33)
Then, for an adequate model, e should be near zero (i.e., the model should
be accurate) and Cf  should be small (i.e., the model should be precise).

     Model Improvement

     The previous discussion shows that a model can be improved by reducing
0_.  This process is equivalent to expanding x, to include as much of
 £                                            J_
X2 as possible.  If x, included all of x™, a model could in principle
calculate the observed concentration C  precisely.  Because this is
impossible in practice, the observed concentration must be treated as a
random variable.  The formulation of an improved model is subject to several
limitations.  The uncertainty associated with formulating a model to
incorporate added information can lead to errors.  Also, inevitable errors in
model inputs may degrade the utility of increasing the complexity of a model.

     A Method to Test Models
     The previous discussion provides the framework for a method to test
     s.  We have seen that for
have the following properties:
models.  We have seen that for an adequate model, the residuals (C -C )
                                  142

-------
     •    e - 0,
     •    CJ  should be small, and
     •    e should be unrelated to C  or x,.

     The first step in examining a model is to plot e against C  or x .
The plot should show a band-like structure in which e is uncorrelated with C .
Also £ should be randomly distributed about zero.  This visual examination
provides an easy check on residual behavior.  It also indicates the range of C
over which the model can be used.  Clearly, one would like to have as large a
range of C  as possible in which the model behavior is acceptable.
     To use the statistics of e, it is desirable to transform C  and C
so that £ is normally distributed.  This knowledge of the distribution of
£ allows us to estimate confidence intervals for the model prediction.
This procedure is illustrated in Appendix C.
                                                           i
     The relationship between the transformed observation C  and the
transformed prediction C  can be written as
               C  + e
                P
(34)
where e is normally distributed with zero mean and variance 
-------
Figure 44.   The relative performance of different models.
                           144

-------
      For the transformation C  = In C, it  is convenient  to  plot  the
 logarithmic mean m  against the logarithmic standard  deviation s , where
                  °                  "   ,                        8
 m  and  s  are  defined  as  follows:
 g      g
        m
             exp
exp In (Co/Cp)
(36)
        s  = exp  (a  ) = exp a(ln(C  /C  ))
         g         e              op
                                          (37)
When plotted on double log paper, m  and s  figures are equivalent to e
                                   O      &
and cr£ figures.  This labeling allows one to interpret model performance
in terms of multiplicative factors.  For example, an m  of 0.5 implies a
                                                      o
tendency to overestimate by factor of 2.

5.4  Sample Case Study Results - Case 205, Hour 5
     This section provides a representative case study to illustrate the
kinds of analyses available for use in evaluating model performance on an
hour-by-hour basis.  Spatial characteristics of calculated.and observed
concentration fields must be used if we want to know why one model may
estimate the highest observed concentrations better than another.  This
sample case study hour (Case 205, hour 5) has already been described in
Section 2.4.2.  The following discussion presents a synopsis of the meteoro-
logical conditions and the observed distribution of 1-hour average SFfi
concentrations.
     Case 205, hour 5 was an hour with persistent southeast winds averaging
6.0 m/sec at the release height.  The flow regime was observed to be neutral
(flow up the east draw and over the top of CCB) with respect to plume
behavior, although the Turner scheme for estimating dispersion stability
class indicated that class F was appropriate for this hour (1.3 m/sec hourly
average wind speed at 10 m).  The local release height was 50 m, and the
computed dividing streamline height was 25 m.  The observed 1-hour SF,-
                                                                     o
concentration distribution for this hour, shown in Figure 45, confirms the
considerable spatial extent to which the plume contacted the surface of CCB,
although concentrations are relatively low.
                                    145

-------
Figure 45.   Observed SF6 concentrations (ppt) for Case 205, 0400-0500.
             Source:  r = 1156 m, 0 = 120.5°, effective height = 41.1 ra,
             Q = 0.09 g/sec.
                                   146

-------
     The model evaluation products for this case hour are presented for
COMPLEX I and II, PFM, and the Neutral model only.  Estimates from Valley and
the Impingement models are deferred until Section 5.5, as these models
produce an estimate of the maximum concentration only.

     5.4.1  COMPLEX I and COMPLEX II

     The first step in the model evaluation is a quantitative comparison of
the distribution of measured and calculated concentrations.  The 1-hour
average ground-level SF  concentrations calculated by COMPLEX I and COMPLEX
II for stability classes D, E, and F, respectively, are shown in Figures 46
through 51.  (For stability class D, COMPLEX I and COMPLEX II use plume path
coefficient = 0.5; for stability classes E and F, both models use plume path
coefficient =0.)  The calculated concentrations are given as parts per
trillion (ppt).  The model calculations were made at each of the 93 possible
sample locations shown earlier in Figure 12.
     Only in the COMPLEX II runs for E and F stability is the peak
concentration (385 ppt, observed at the base of the southeast draw) equaled
or exceeded elsewhere on the hill.  Qualitatively, though,' the spatial
distribution pattern shown in the COMPLEX II runs is too narrow in the
crosswind direction (compared to the observed concentrations).
     If the peak concentration at the base of the hill is ignored for the
moment*, then COMPLEX II estimates using stability class D dispersion
coefficients show a better agreement with the observations.  It nonetheless
appears that the calculations across the top of the hill and out to the sides
would improve further if the model plume were broader.
     The COMPLEX I results, by comparison, show a horizontal spread that
appears too large, especially with respect to the concentrations on the south
side of the hill.  Nonetheless, if we focus on the higher concentrations near
*These locally large concentrations at the base of the hill were
 observed on several occasions during the experiments; they are
 tentatively attributed to downslope flows driven by horse—shoe
 vortices or drainage.  None of the models addresses this effect, but
 the model statistics reflect these large measured concentrations
 nonetheless.
                                     147

-------
Figure 46.   Complex I:  calculated SFe concentrations  (ppt) for Case
             205, Hour 5, Stability Class D.
                                 148

-------
   38."
Figure 47.   Complex I:  calculated  SFg  concentrations (ppt) for Case
             205,, Hour 5, Stability  Class  E.
                                  149

-------
Figure 48.   Complex I:  calculated SFg concentrations  (ppt) for Case
             205, Hour 5, Stability Class F.
                                 150

-------
80.
Figure 49.   Complex II:  calculated SFg concentrations  (ppt)
             205, Hour 5, Stability Class D.
                                                                Case
                              151

-------
Figure 50.   Complex II:  calculated SFg concentrations  (ppt) for Case
             205, Hour 5, Stability Class E.
                                 152

-------
3S.
Figure 51.   Complex II:  calculated SFg concentrations
             205, Hour 5, Stability Class F.
                                                           for Case
                              153

-------
the top of the hill, COMPLEX I with class E dispersion coefficients does a
fair job of estimating those concentrations.
     A better quantitative idea of the performance of each of the models is
obtained by looking at scatterplots of modeled versus observed
concentrations.  In Figures 52, 53, and 54, the solid triangles indicate
COMPLEX II results and the open squares indicate COMPLEX I results.  For
potential regulatory application, of course, the chief interest is to gauge
how extensively and consistently the models may overestimate or underestimate
concentrations, especially the highest observed concentrations.  Scatterplots
are extremely helpful in identifying such gross tendencies.  As shown in the
second of these scatterplots, for example, the COMPLEX I model run with E
stability tends to overestimate the lower observed concentrations (C  <
80 ppt) but to underestimate the higher concentrations.  By comparison, the
COMPLEX II model both overestimates and underestimates the lower observed
concentrations by much wider margins than COMPLEX I.  COMPLEX II
underestimates the peak observed concentration but overestimates the second
highest, in each case by substantial margins.
     Tables 23 through 25 display frequency histograms for the observed
concentrations, for the concentrations modeled with COMPLEX I and COMPLEX II,
and for the residuals.  (As before, the model calculations are shown
successively for stability classes D, E, and F.)  For example, as Table 24
for class E shows, the COMPLEX I results span a narrow range similar to the
observed concentrations; whereas the COMPLEX II results are broadly
distributed.  From the histograms of the residuals, it can readily be seen
that the COMPLEX II paired results are on average skewed slightly toward
overestimation; that the COMPLEX I results are skewed (very weakly) toward
overestimation; and that for either model most of the residuals are less than
160 ppt.
     The next level of analysis uses the descriptive statistics calculated
from all paired concentrations for the case study hour.  Tables 26 through 31
show these calculations for the six previous combinations of model and
stability class.  The column "ID" refers to individual sampler locations
shown previously in Figure 12.  (For this data hour, a total of 31 valid,
nonzero, full-hour average SF,- concentration samples was obtained.)  The
other table entries are self-explanatory.

                                     154

-------
PREDICTED 
 540.0-
 480.8-
 4S0.0-
 360.0-
 300.0-
 340.0-
 180.0-
 130.0-
  60.0-
           60.0   180.0   180.0   240.0   300.0  36«.0  480.0   480.0   540.0
         LEGEND

         a COMPLEX I
         A COMPLEX II
OBSERVED (PPT)
 Figure  52.    Complex I and  II:   calculated SP^  concentrations versus
               observed SFg concentrations for Case  205, Hour 5,
               Stability Class  D.
                                     155

-------
PREDICTED  CPPT)
 480.0-
 430.0-
 366.0-
 360.0-
 340.0-
 180.0-
 120.0-
  60.8-
        LEGEND
OBSERVED  (PPT)
           COMPLEX
           COMPLEX
 Figure 53.    Complex I and  II:   calculated  SF6 concentrations  versus
               observed SF6 concentrations  for Case 205, Hour  5,
               Stability Class  E.
                                    156

-------
PREDICTED (PPT)
1080.0-
 960.0-
 840.0-
 730.0-
 600.0-
 480.0-
 360.0-
 340.0-
 150.0-
           180.0  a40.0   360.0   480.0   600.0   720.0   840.0   960.0  1080.0
LEGEND
n  COMPLEX I
*  COMPLEX II
                                                                OBSERVED  (PPT)
 Figure  54.    Complex I and  II:   calculated SFg  concentrations versus
               observed SFg concentrations for Case 205, Hour 5,
               Stability Class  F.
                                     157

-------
       TABLE  23.   FREQUENCY DISTRIBUTIONS  OF SF6 CONCENTRATIONS (ppt)
                          FOR COMPLEX I AND  II MODELS
                     (CASE  205,  HOUR  5,  STABILITY CLASS  D)
             CLASS INTERVAL
                                    OBSERVED
                                                COMPLEX I
                                                             COMPLEX II
                  0.
                  5.
                 10.
                 60.
                HO.
                160.
                210.
                260.
                310.
                360.
               5.
              10.
              60.
             110.
             160.
             210.
             260.
             310.
             360.
             410.
                   0
                   O
                   6
                  14
                   7
                   2
                   1
                   0
                   0
                   1
                    6
                    O
                    3
                   17
                    6
                    0
                    0
                    0
                    0
                    0
                    8
                    4
                    2
                    5
                    5
                    5
                    2
                    0
                    0
                    0
#»##»**#*##*********************************************************************
##»»#*»*#«#****#**#**»*************#********************************************
            RESIDUALS (CO-CP)

  CLASS INTERVAL  COMPLEX I  COMPLEX II
                                    ABSOLUTE RESIDUALS !CO-CP!

                               CLASS INTERVAL  COMPLEX I   COMPLEX  II
  -400.
  -32O.
  -240.
  -160.
   -SO.
     0.
    SO.
   160.
   24O.
   320.
-320.
-240.
-160.
 -BO.
   O.
  80.
 160.
 240.
 320.
 400.
 O
 0
 0
 0
12
13
 5
 0
 1
 0
 O
 0
 0
 1
10
16
 3
 O
 1
 0
  0.
 4O.
 80.
120.
160.
200.
240.
2BO.
320.
360.
 40.
 SO.
120.
160.
200.
240.
280.
320.
360.
400.
IS
 7
 3
 2
 O
 O
 0
 1
 0
 0
 9
17
 4
 0
 0
 O
 1
 0
 O
 0
if*******************************************************************************
                                       158

-------
    TABLE 24.   FREQUENCY  DISTRIBUTIONS OF SF6 CONCENTRATIONS (ppt)
                       FOR COMPLEX I AND  II MODELS
                  (CASE 205,  HOUR 5, STABILITY CLASS E)
           CLASS INTERVAL
                                  OBSERVED
                                              COMPLEX  I
                                                           COMPLEX  II
0. -
5. -
1O. -
90. -
170. -
250. -
330. -
41O. -
490. -
570. -
5.
10.
90.
170.
250.
330.
410.
490.
570.
65O.
                                      o
                                      o
                                     IS
                                      9
                                      3
                                      O
                                      1
                                      0
                                      0
                                      0
                                       6
                                       O
                                       3
                                      14
                                       8
                                       0
                                       0
                                       0
                                       0
                                       0
                                           12
                                            1
                                            5
                                            3
                                            2
                                            4
                                            0
                                            3
                                            O
                                            1
          RESIDUALS (CO-CP)

CLASS INTERVAL  COMPLEX I  COMPLEX II
                                   ABSOLUTE RESIDUALS  !CO-CP!

                              CLASS  INTERVAL  COMPLEX  I  COMPLEX II
-400.
-320.
-240.
-16O.
 -80.
   O.
  80.
 160.
 240.
 320.
-32O.
-240.
-160.
 -80.
   0.
  80.
 160.
 240.
 320.
 400.
 O
 0
 0
 6
14
 7
 3
 0
 0
 1
 1
 3
 3
 2
 4
11
 6
 0
 1
 0
  0.
 40.
 80.
12O.
160.
200.
240.
280.
320.
360.
 40.
 80.
120.
16O.
200.
24O.
280.
320.
36O.
400.
 9
12
 7
 2
 0
 O
 O
 0
 1
 0
 2
13
 7
 1
 3
 O
 2
 2
 0
 1
                                    159

-------
     TABLE 25.   FREQUENCY DISTRIBUTIONS OF  SF6 CONCENTRATIONS (ppt)
                         FOR  COMPLEX  I  AND II MODELS
                    (CASE 205,  HOUR 5,  STABILITY CLASS  F)

****»»##»#*##**####**#**#**##«•****#*#**********•*********************************
             CLASS INTERVAL
                                    OBSERVED
                                                COMPLEX  I
                                                             COMPLEX II
                  0.
                  5.
                 10.
                160.
                31O.
                460.
                610.
                760.
                910.
               1060.
               5.
              1O.
             160.
             310.
             460.
             610.
             760.
             910.
            1060.
            1210.
                   0
                   O
                  27
                   3
                   1
                   0
                   0
                   0
                   0
                   0
                    6
                    1
                    4
                   20
                    0
                    0
                    0
                    0
                    0
                    0
                   16
                    2
                    3
                    1
                    5
                    2
                    0
                    1
                    0
                    1
»*#»**#***##**##*»#*»*****»*********#******«•*#**********#**************«•********
            RESIDUALS  (CO-CP)

  CLASS  INTERVAL  COMPLEX  I  COMPLEX  II
                                    ABSOLUTE RESIDUALS !CO-CP!

                               CLASS INTERVAL  COMPLEX I   COMPLEX II
  -10OO.
  -BOO.
  -600.
  -400.
  -200.
     0.
   200.
   400.
   60O.
   BOO.
-BOO.
-600.
-400.
-200.
   0.
 200.
 400.
 600.
 BOO.
1000.
 O
 O
 O
 1
19
10
 1
 O
 0
 0
 1
 1
 0
 6
 3
19
 1
 0
 0
 O
  0.
1OO.
200.
300.
400.
500.
6OO.
7OO.
800.
900.
 100.
 200.
 300.
 400.
 500.
 600.
 700.
 800.
 900.
1000.
17
12
 1
 1
 0
 0
 O
 O
 0
 0
18
 4
 3
 4
 0
 0
 O
 1
 0
 1
 **##*#*#***»***#**#**«•#********************************************************
                                        160

-------
         o
         o
         Q_

         O
               O O
                                                                                                          I- i- H- K
                                                                                                          0.0.0. a.
                                                                                                          o. a. a. a.

                                                                                                          o* o cu oa
                                                                                                          00 O
                                                                                                          •o *
                                                                                                                  CO
                                                                                                                  m
                                                                                                          u  n  n  n
C/D

S

O
cA



W
W
0.  H

    M
          a.
          a.
          a.
          o

          o
          o
•s-'    •*•  o «
OD  i  -rtCD(>
                                o
                                         N ru
                                         i   N N ri &•' i>  to -a
N m N «*•
«t ^ <*• n
><  m
O   „
         a.
         a.
         a.
         o
                  in ru
                  O «H
                                                                                                           n  II  u  II

                                                                                                          0:0:0:0:
 >

 w
                                                                                                          D. DL  a. a.
                                                                                                          a. a.  a. a.
                                                                                                          ru in
                                                                                                          o ru  N ru
                                                                                                          •rn N  n in
W
t-J
          a.
          a.
          o
          o
          Q
                                                                                              u
                                                                                           n   .
                                                                                            .  o     u
                                                                                           o  z
                                                                                           Z  O  II O
                                                                                           oo   .2
                                                                                           o     oo
                                                                                              Q  z o
                                                                                           Q  UJ  O
                                                                                           LU  I-  O —
                                                                                           >  o    a.
                                                                                           D:  M  a. o
                                                                                           LU  Q  o  i
                                                                                           m  LU  i o
                                                                                           C3  DC  O O
                                                                                           O  a.  o —

                                                                                           Z  2  Z Z

                                                                                           LU  LU  111 LU
                                                                                           £  r  2: E
                                                       161

-------
                                                   i •"-! n -i ^ -i    ru ru
                                                                                                   ni  -<
                                                                                                                c*j
                                                                                                                      t- H I- t-
                                                                                                                      0- 0_ Q_ 0-
                                                                                                                      0-0.0.0.


                                                                                                                      o- in o o


                                                                                                                      cri * ni o
                                                                                                                       n  it  n  ii
co
                                                                                                                      111 HI  LU 111
                                                                                                                      Q Q  Q Q
                                                                                                                      a a  Q o
                                                                                                                      I- t-  I- I-
                                                                                                                      tn en  en tn
    w
          o.
    co   o
          O
          o
M


X
    M
                    -  o    <  -   o •*• ir>

                                                            • o o  N a  a  o a in  T ra
                                                                                                   t  ru  o   o-
                                           I   I
                                                       -<  I   I
                                                                        I
                                                                              I
                                                                                           i   i
                                                                                                                  ni ru  ru ni
                                                                                                                  # *  *  *
                                                                                                                  # *  *  *
                                                                                                                  i- i-  H H
                                                                                                                  o. a.  a. a.
                                                                                                                  n. a.  a. a.

                                                                                                                  en -o  ON N

                                                                                                                  N o-'  ri
                                                                                                                          I  0«
                                                                                                                            in
                                                                                                                  «* IT.  03  n
                                                                                                                      N Ift  '
    CO   ^
o    «

                                                                                                        I «i  CD '-i     II  II  II  II
                    03
                                                                          ru
td
CO
CO
H- H I-  H
O. a. Q.  DL
a. DL a.  a.

ra oo o  o

o o o  o
»-< ni 1-1  N
w
          o
                                                                             ^H "i n ru  ^
                                                                                                         ni
                                                                                                                      o ;

                                                                                                                      o O
                                                                                                                      o
                                                                                                                            o o
                                                                                                                      s
                                                                                                                      _ I- O —
                                                                                                                      r> o    a.
                                                                                                                      o: M a. o
                                                                                                                         Q O
                                                                                                                         Ul  I
                                                                                                                  S_     _
                                                                                                                  a ce o  o
                                                                                                                  o o_ o  —

                                                                                                                  z z z  z

                                                                                                                  LU LU LU  UJ
                                                             162

-------
         o
         u
         Q.
         O
                 ni ru
                                    ru ru
                                           -< «*• ru <-< -<   ro n ru -H
                                                                                   ru ru   *•< t
                                                                                                   H- 1- h- H
                                                                                                   a. a. a. a.
                                                                                                   a. a. a. a.

                                                                                                   o- n "^ •**

                                                                                                   co -o o oo
                                                                                                   •4J O 01 -0
                                                                                                    n  n  n  n
o
w
H
                                                                                                    Ul UJUJ Ul
                                                                                                    Q Q Q Q
                                                                                                   Q Q Q Q
                                                                                                   H- h- (- t-
                                                                                                   tn tn in in
w
o
U  CO

Q  3
W  J
£5  O
         o.
         0.
         O
         o
                                                                                   .»i o~ -o o »H
                 oci N o  ni o o  n -o"    in ru o o «t o-
                 oocoo3&-r^Niricuoio£D£hnN-oirin'-iinNr^
                 rt»H              •r-l-^t-li-rH-^lll    ^| f)| ^|  |  {<)
                 II                I   I  I     I  I          III
                                                                         -  t> ri N m o
                                                                                                   ru ru ru ni
                                                                                                   * * * *
                                                                                                   # * * #
                                                                                                   I- I- I- H
                                                                                                   a. a. a. o_
                                                                                                   a. a. a. o.

                                                                                                   n in m o
CM  f-|

>->  !j

x  «

§^
SW    ^
O   „   I-
o  u-,    a.
         Q.
CO  g
«  s
         a.
         u
                 03 -o
                 ru ru
                                      o-O'-oift'H^o-rutDO-mm
                                      ^ ^ ru ni ru ni ^   «-< ru ru ru
                                                                         ru ru
                                                                                                   «*• o
                                                                                                   N n
                                                                                                            n
                                                                                                            «o
                                                                                                    II  II II  II

                                                                                                    EC CC CC Q-
gs
a!  M

i^^
CQ  rj
O s_^
                                                                                                    I- t- t- 1-
                                                                                                    Q. o. a. a.
                                                                                                    D. a. a. a.

                                                                                                    ro t> N o~
00
CM
W
         I-
         D.
         0.
         o
         o
                                                                                                            II
                                                                                                            O
                                                                                                       II
                                                                                                    II  .
                                                                                                     . o
                                                                                                   O 2
                                                                                                   2 O II
                                                                                                   O O   _
                                                                                                   CJ    (JO
                                                                                                      Q 2 O
                                                                                                   Q LU O
                                                                                                   HI I- O —
                                                                                                   > o   n_
                                                                                                   o: M a. o
                                                                                                   ui Q u  i
                                                                                                   tn ui i o
                                                                                                   to ce o o
                                                                                                   o a. u —

                                                                                                   2222
                                                                                                   « «
                                                                                                   LJ UJ 1J 111
                                                                                                   z: s: s: E:
                                                    163

-------
er>
                                                                                                                     K- h- t- H
                                                                                                                     o. a. Q. o.
                                                                                                                     O. CL CL D.


                                                                                                                     0- N CD ru

                                                                                                          —•<  *-i    00 O O "Jj"
                                                                                                 i ru ru    .-<
                                                                                                                        00 N
                                                                                                                     II  II   II   II
                                                                                                                     HI Ul Ul UJ
                                                                                                                     Q Q Q Q



                                                                                                                     Q' Q Q Q
                                                                                                                     K- I- I- I-
                                                                                                                     tn to tn to
O
%  <~*

8°
    CO
Q  CO
M  O
M  M
M  iJ
    l-l
                                                                                i  ru
          o
cu ru ru ni

# * *  *
I- H- I- h-
O. CL D- CL
Q. CL CL CL
                                                                                                                     N o* oo *H
                                                                                                                     «t TH o in
                                                                                                                     N in o o-
                                                                                                                        O.
o  m


CO  B5
SO
CO  O
          t-    'H
                                                                                                              -<     II  II  II  II
                   o «t
                   ru o
                                         ru
                                                         •^ ru co
                                                                               ni ^ cu ru
o: o: a: o:
< <  ru
                                                                                                                    -H  oo  ni -o
a
pa
          o
                                                                                                                    o
                                                                                                                      . u     n
                                                                                                                      i Z
                                                                                                                       o  H  u
                                                                                                                           _  o
                                                                                                                        Q Z O
                                                                                                                    Q Ul O
                                                                                                                    LU I- O —
                                                                                                                    > U    Q.
                                                                                                                    EC M D. O
                                                                                                                    UJ Q O  I
                                                                                                                    CO LU I  O
                                                                                                                    03 K O O
                                                                                                                    O 0. O —


                                                                                                                    zzzz
                                                            164

-------
          o
          o
          a.
          o
                                                       *•«
                                                                                 ru ru    «-<  d •
              n*«otD--i
              <••< ru ni ru ra
ii  n  n  n

oc 0:0:0:
Q  O
OS  W
W  CO

%  <
PQ  tj

o  ^
                                                                                                              t- h- H I-
                                                                                                              a. a. a. a.
                                                                                                              a. a. a. Q.

                                                                                                              ni i> 03 ru

                                                                                                              d in in i-i
                                                                                                              •^ n ni ru
o
CO
w

oa
          a.
          a.
O
o
                                                                                                              II
                                                                                                                 II
                                                                                                                       n
                                                                                                               . o
                                                                                                              t> z
                                                                                                              z a  u o
                                                                                                              o o   .z
                                                                                                              o    o o
                                                                                                                Q z o
                                                                                                              Q ui o
                                                                                                              111 H O —
                                                                                                              > o    a.
                                                                                                              a: M a. o
                                                                                                              ui a u  I
                                                                                                              en ui  i  o
                                                                                                              m o: o o
                                                                                                              o o_ o —

                                                                                                              zzz z

                                                                                                              Ul Ul Ul Ul
                                                                                                              SEES:
                                                         165

-------
                                                           -o  n
                                                                                  ru
                                                                                           »-< -o in •r-i ru
                           h- t- f- I-
                           O. OL O. D_
                           0. 0.0. 0.

                           Ch * n N

                           od ru «t «t
                           *O 00 *>Q O
                              ru ru ru
 o
     CO
 a  co
 M  O
                                                             n
                                                                         «•» o- n n
                                                                                   i   i
         ru ru « ru
          i   i   i   i
                                                                                                                u  ii  ii  it
                                                                                                                ui ui ui ui
                                                                                                                a Q Q o


                                                                                                                ci ci Q Q
                                                                                                                H (- H I-
                                                                                                                cn tn CD en
                                                                                               ru ru ru ru
                                                                                               * * * #

                                                                                               I- I- I- H-
                                                                                               a_ a. a. a.
                                                                                               a. a. a. a.
                                                                                                                n
                                                                                                                      N -o

                                                                                                                      in 6
                                                                                                                   N N
                                                                                                                 " t> O-
CO  OS
                                                       in
                                                          oo
-<    03 -i in i
in       n n i
                                                                                                                II  II  II  II
                                                                                                                cc a: ir tc
Q  o
M  CS

OS  W
u  co
co   o    o.
                                                                                                               o: f a. o
                                                                                                               Ul Q O  I
                                                                                                               to ui  i  o
                                                                                                               a ac a o
                                                                                                               o a. o —


                                                                                                               < < < <
                                                                                                               Ul Ul Ul Ul
                                                                                                               E s: r z:
                                                          166

-------
     To determine which of these six model/stability class combinations best
matches the observed concentrations during Case 205, hour 5, the respective
statistics shown at the bottom of each table should be compared.  Table 32
lists these for side-by-side comparisons.  If all criteria were given equal
weight, the descriptive statistics would seem to suggest that of these six
choices of model and stability class, the COMPLEX I model with E stability is
preferred (note that the maximum is estimated better by two other choices):

     e    the mean modeled value agrees most closely with the mean observed
          value and is somewhat larger (slightly conservative),
     a    the mean residual error  is  smallest  (least bias),
     e    the standard deviation of the residual error is not much larger
          than  the standard deviation of the observed concentrations, and
     e    the standard deviation of the modeled concentrations is only
          marginally greater  than  that of the  observed concentrations.
      5.4.2   PFM

      A similar set  of plots,  tables,  and  figures  is  presented  below for  the
 PFM simulation of Case 205, hour 5.   Stability classes  D and E were both used
 in running  PFM so that comparisons could  be made  with the best-performing
 versions of the COMPLEX computations.
      The 1-hour average ground-level SF&  concentrations calculated by PFM
 are shown in Figures 55 and  56.   The distribution of modeled concentrations
 is qualitatively similar to  that calculated by the COMPLEX II  model for  the
 same stability classes because they use similar horizontal distribution
 functions.   The magnitudes,  however, are  different.
      PFM with stability class E produces  concentrations in excess of the
 observed maximum but tends to overestimate all of the concentrations on  the
 central part of the hill.  If the observed maximum (located at the base  of
 the windward side of the hill) is ignored, PFM with stability  class D does
 better; still, there appears to be too little plume spread to match the
 observations.
                                      167

-------
      TABLE 32.  SUMMARY STATISTICS FOR COMPLEX I AND COMPLEX II

                          (Case 205, Hour 5)
Number of Points
max (C0)
max (C )
 o   p
     -
max  |CQ -Cp|

 'Co  - V

-------
Figure 55.   PFM:  calculated SF6 concentrations for Case 205, Hour 5,
             Stability Class D.
                                 169

-------
   85.
Figure 56.   PFM:  calculated SFg concentrations for  Case  205,  Hour 5,
             Stability Class E.
                                 170

-------
     Scatterplots of modeled versus observed concentrations presented in
Figures 57 and 58 show evident similarities with the scatterplots for
COMPLEX II with stability classes D and E.  Many low concentrations away from
the hill center are underestimated, and most of the concentrations above
60 ppt are overestimated (especially for stability class E).  Frequency
distributions presented in Tables 33 and 34 show that although many
similarities between PFM and COMPLEX II concentrations exist, PFM tends to
produce higher concentrations.  This tendency increases the range in the
distribution of residuals.
     Finally, paired concentrations and a summary table of the PFM statistics
for this case hour are presented in Tables 35 through 37.  The stability
class for which PFM performs better (on the basis of summary statistics)
appears to be class D, even though the mean statistics and the peak
concentration show a tendency toward underestimation.  A comparison of PFM
and COMPLEX summary statistics shows that PFM performs as well as any of the
COMPLEX models for the case hour.

     5.4.3  New Experimental Models

     Figure 59 displays the distribution of concentrations calculated by the
Neutral model (see Section 4.5.3) for Case 205, hour 5.  Concentrations are
presented only at those samplers with good SF, data.  The spread of
concentrations over the hill appears to be reproduced fairly well, but most
concentrations are underestimated.
     These features are evident in the scatterplot of modeled versus observed
concentrations as well (see Figure 60).  The lower concentra- tions are just
as likely to be either over- or underestimated, but few concentrations are
calculated to be less than 5 ppt.  The higher concentrations (>120 ppt) are
underestimated.
     Frequency distributions (see Table 38) and the statistics of paired
concentrations (see Tables 39 and 40) reinforce this description.  Modeled
concentrations populate lower class intervals, and the distribution of
residuals is biased toward underestimation.  One half of the calculations lie
within 40 ppt of the corresponding observations.  The mean of all
calculations is slightly greater than half the mean of all observed
                                     171

-------
PREDICTED (PPT)
 540.0-
 480.0-
 420.0-
 360.0-
 300.0-
 240.0-
 180.0-
 130.©-
  60.0-
            60.0    180.0   180.0   240.0   300.0   360.0   4S0.0   480.0  540.0
                                                                 OBSERVED (PPT)
  Figure 57.    PFM:   calculated SFg  concentrations versus observed SFg
                concentrations for Case 205, Hour 5, Stability  Class D.
                                      172

-------
PREDICTED 
-------
TABLE  33.  FREQUENCY DISTRIBUTIONS OF  SFg CONCENTRATIONS  (ppt)
          FOR PFM  (CASE 205,  HOUR  5,  STABILITY CLASS  D)
            CLASS INTERVAL.
                                  OBSERVED
                                                 PFM
                0.
                5.
               1O.
               6O.
              HO.
              160.
              210.
              260.
              310.
              360.
        5.
       10.
       60.
      110.
      160.
      210.
      260.
      31O.
      360.
      410.
            0
            0
            6
           14
            7
            2
            1
            0
            0
            1
            7
            3
            4
            5
            5
            2
            3
            1
            1
            0
            RESIDUALS (CO-CP)

       CLASS INTERVAL     PFM
                   ABSOLUTE RESIDUALS !CO-CP!

                   CLASS INTERVAL     PFM
       -300.
       -240.
       -ISO.
       -12O.
       -60.
          0.
         60.
       120.
       ISO.
       24O.
-240.
-180.
-120.
 -60.
   0.
  60.
 120.
 ISO.
 240.
 3OO.
 0
 0
 2
 5
 5
 e
10
 o
 i
 o
  o.
 30.
 60.
 90.
120.
150.
ISO.
210.
240.
270.
 30.
 60.
 90.
120.
150.
180.
210.
240.
270.
300.
 5
 8
12
 3
 2
 O
 0
 1
 0
 0
                                174

-------
TABLE 34.   FREQUENCY DISTRIBUTIONS  OF SF6  CONCENTRATIONS  (ppt)
          FOR PFM (CASE  205, HOUR 5, STABILITY  CLASS E)
            CLASS INTERVAL
                                   OBSERVED
                                                  PFM
                0.
                5.
               10.
               80.
              ISO.
              220.
              29O.
              36O.
              43O.
              500.
        5.
       10.
       80.
      150.
      22O.
      290.
      360.
      43O.
      50O.
      57O.
            0
            O
           12
           13
            4
            1
            0
            1
            0
            0
            13
             1
             5
             1
             3
             5
             0
             1
             1
             1
            RESIDUALS 

       CLASS INTERVAL     PFM
                   ABSOLUTE RESIDUALS  ICO-CP!

                   CLASS INTERVAL      PFM
       -400.
       -320.
       -240.
       -16O.
        -SO.
          0.
         80.
        16O.
        240.
        320.
-32O.
-24O.
-160.
 -80.
   0.
  80.
 160.
 240.
 320.
 400.
 2
 1
 1
 3
 6
10
 7
 0
 0
 1
  0.
 4O.
 80.
120.
160.
200.
240.
280.
320.
360.
 40.
 80.
120.
160.
20O.
24O.
280.
32O.
360.
400.
 4
12
 7
 3
 1
 0
 0
 1
 2
 1
     *******#*******«•#***«•**«••»**•»«•***«•*«•##«•*****************###
                                 175

-------
         o
                                                  CM CM
                                                                                     CM
                                                                                                     K- H I- I-
                                                                                                     OL EL D. O.
                                                                                                     o. o. a. Q.


                                                                                                     0" CM CM -i
                                                                                                      ii  ii  ii  ii
co
                                                                                                     LU Ul UJ  LU
                                                                                                     Q Q Q  Q
                                                                                                     Q a a o
                                                                                                     I- H- H- h-
                                                                                                     cn in en tn
   CO    ~

   CO
O
         o
                                                  - TH -.    I
                                                                     •^ ru
                                                                                   I   i   i
                                                                                                     CM CM CM CM
                                                                                                     # # * #

                                                                                                     t- I- I- h-
                                                                                                     OL EL D- 0.
                                                                                                     a. a. a. a.

                                                                                                     C"J in CD n

                                                                                                     N o in -i
                                                                                                     ^" *0 CD C^
                                                                                                     N o in o^
co
CA
   oi    Q.

   o    t
   SG
Id   „
              CMnir)Oonoo«*mNinoc> co

                                                                                                     d ri 
                                                                                                     o z
                                                                                                       : o n o
                                                                                                     o o
                                                                                                     o    o o
                                                                                                        Q 2 o
                                                                                                     a ui a
                                                                                                     LU i- o —
                                                                                                     > o   CL
                                                                                                     a: w o. o
                                                                                                     ID Q o  i
                                                                                                     en u i  o
                                                                                                     ca a: o o
                                                                                                     o a. o —

                                                                                                     222:2
                                                                                                     <<<<
                                                                                                     UJ UJ HI UJ
                                                     176

-------
o
o
v,

Q_
O
i- I- I- H
OL a. a. a.
a. a. a. a.

o «H n ro

oa W ri ri
                                                                                              H  II  ii  II


CO
2
O
H
$
H
:s
w
u
2
O
^
Q
W
OS
n
rt
"
s
En
OH

CO

CO
OS
w
>
Q

^^
03
W
CO
o
.
CO

W
h-3
PQ
*^
H























W
CO
<
, •]
o
H

, "j
M
03
H
CO


"
"1
OS
0
03

"*
O
CN
W
CO
CJ



























1-
o.
O-

Q.
o
1
o
^





_
H
n
Q.

EL
O






Q_
n


0
CJ













Q
l~l

•UJ
a
d
i-
tn

no-o-.i^in^*-.-.innruo3-i'*^rU'*-oo-ooncr-ruo(Mnoro

•^•03ino<3'OOi^'>ooinrur^.-»-iin'-<-ciro'd"ruronh*ruOfcininci3Oi^03 *
i «-*C3ru i nroi-»-< i-^"-*!! i—
III 1 1 II Q.
Q-
ro
N
^f




o*5'isv*^oO'^oh^in^frurii*omosOv*^tnmr*v*orucu^'OsOOs*~'Or>^ 11

ru>-< oo-o -^-oo3 no-o^ruru 


i-
a.
a.
ru
d

nnr~.ruNin-4«s-moo-o-«*-Q3<4-inoo-o--
a:
UJ
CD

0
^^^Km^SN^KNf^S^&SmoaSlnNooon^NNNNW z
UJ

UJ
Q
Q
t-
tn



*
*
t-
a_
Q.
in
in
n
ru



n

a:
^
>


i-
a.
a.
N
03




II

O
Z
O
0

Q
Ul
H
O
*~l
Q
UJ
a:
a.
z
UJ

U!
Q
a
H
cn


ru
*
#
i-
Q.
a.
^.
in
<«•
in
o




II

a:
^
>


\-
a.
a.
in
03








II

(J

o
U

a.
0
I
o
u
z
UJ

UJ
Q
ci
1-
tn


CM
*
*
a.
a.
ro
ri
00




n

a:
^
>


i-
D_
a.
O






II

cJ
z
o
0

— -
Q.
O
1
O
O

Z
Ul
s:
                                            177

-------
                 TABLE  37.  SUMMARY STATISTICS FOR PFM
                          (Case 205,  Hour  5)
                                        OBSERVED
                                                  PFM
                                             Stability Class
                                              D           E
Number of Points
a(co)
max (C )
C
 P
o(Cp)
max (C )
a
-------
Figure 59.   Neutral model:  calculated SF6 concentrations  (ppt)  for Case
             205, Hour 5.
                                   179

-------
PREDICTED (PPT)
 543.0"
 486.0-
 420.0-
 360.0-
 300.0-
 240.0-
 180.0-
 130.0-
  60.0-

            60.0   120.0   180.0   240.0  300.0  360.0  430.0   480.0  540.0

                                                                 OBSERUED (PPT)

  Figure 60.    Neutral model:   calculated SF^ concentrations versus
                 observed SF6  concentrations for Case  205,  Hour  5.
                                      180

-------
TABLE  38.  FREQUENCY DISTRIBUTIONS  OF SFg  CONCENTRATIONS (ppt)
              FOR NEUTRAL  MODEL (CASE 205,  HOUR 5)
           CLASS INTERVAL
                                 OBSERVED   NEUTRAL MODEL
               0.
               5.
              10.
              60.
             110.
             160.'
             21O.
             260.
             310.
             360.
        5.
       10.
       60.
      110.
      16O.
      210.
      26O.
      310.
      360.
      410.
            0
            0
            6
           14
            7
            2
            1
            0
            0
            1
 2
 2
11
14
 2
 0
 0
 O
 0
 0
           RESIDUALS (CO-CP)

      CLASS INTERVAL   NEUTRAL
                   ABSOLUTE RESIDUALS !CO-CP!

                    CLASS INTERVAL   NEUTRAL
      -400.
      -320.
      -240.
      -16O.
       -80.
         0.
        BO.
       160.
       240.
       320.
-320.
-240.
-160.
 -80.
   0.
  80.
 160.
 240.
 320.
 400.
 0
 0
 0
 O
 7
20
 2
 1
 O
 1
0. -
40. -
80. -
12O. -
160. -
200. -
24O. -
280. -
32O. -
36O. -
4O.
SO.
120.
160.
200.
240.
2SO.
320.
36O.
400.
16
11
2
0
1
0
0
0
0
1
                                 181

-------
en  w
erf  w
w  <:
>  o
                                                                                                               H i- H- H-
                                                                                                               Q. O. O. Q.
                                                                                                               0.0.0.0.
           o
                                                                                                               co co n co
                                                                                                               *o c*3 r**- *o
                                                                                                               II  II  II  II
                                                                                                               UJ Ul UJ Ul
                                                                                                               Q Q Q Q



                                                                                                               Q Q a a
                                                                                                               t- I- I- I-
                                                                                                               cn en en en
 Q
CM
CD n  o o- in m n  o -ci od cri K ni ri
                                                             c

                                            i  ni CM CM CM ni CM -o  i  nru-orxo«t-oin  i
                                                                                    ir a c ri -H 1
                                                                                                 I
          o
CM CM CM CM
* * # #
# * * #
l_ (_ H (_

a. o. a. a.
a. a. a. a.


n m<3 o
                                                                                                                  oo  »H
                                                                                                                - -rH  ITl
                                                                                                                        «o
H  ffi

W    -   **
a  "*>    i-
    o    o.
                                                                                               u  u   H  u.
co
to
                                                                                              a. a. o. a.
                                                                                              o. o. a. a.

                                                                                              CM N in «t

                                                                                              d -^i en in
                                                                                              »-< o «»• in
                                                                                                   ru ~<
                                                                                                                 o  n
                                                                                                              o o
                                                                                                              o
                                                                                                                    o o
                                                                                                                      .
                                                                                                              Q UJ O
                                                                                                              iu i- o
                                                                                                              a:      .
                                                                                                              u Q u  i
                                                                                                              en
                                                                                                                     i  o
                                                                                                              a) Q: o o
                                                                                                              o o. o —

                                                                                                              2 Z Z 2
                                                                                                              «r < <
                                                                                                              Ul UJ Ul Ul
                                                                                                              s: r E i:
                                                         182

-------
          TABLE 40.  SUMMARY STATISTICS FOR NEUTRAL FLOW MODEL
                           (Case 205, Hour 5)
                              OBSERVED
                                           NEUTRAL MODEL
Number of Points
a(co)
max (CQ)
r
 p
a(Cp)
max ( C  )
C -C
 o  p
max  C -C
_ p ... p.
 |Co - Cp'
a(|co -cpl)
                         31
                        110
                         69
                        385
                                                62
                                                38
                                               115
                                                49
                                                73
                                               378
                                                55
                                                68
 Note:
SF, concentrations are in ppt.
  D
                               183

-------
concentrations, and the maximum calculated concentration is about one-third
of the maximum observed.

5.5  Summary of Model Performance

     5.5.1  Model Performance Statistics

     Valley

     Valley model estimates of the maximum 1-hour average tracer
concentrations (scaled by the emission rate) are presented in Table 41 for
each of the 45 case hours.  The concentrations are scaled by the emission
rate to facilitate comparisons.  Also included are the associated centerline
concentrations (zero stand-off distance, no surface reflection), observed
concentrations, and ratios of the hourly calculated to observed
concentrations.
     The Valley estimates of C/Q depend only on the distance from the source
to the nearest possible  point of impingement.  With Valley, predicted C/Q
values* range  from 53 to 105.  The maximum possible C/Q  from the Valley model
occurs at  a distance of  366 m.  This value is about 107,  so the calculated
value of 105 is virtually the greatest  C/Q possible from Valley.
     Valley appreciably  underestimated  peak observed  concentrations  in the
four  test  case hours with the highest observed  scaled peak concentrations
 (C/Q), and estimated the fifth and  sixth highest  scaled  peak concentrations
 to within  1%.  All  peak concentrations  in the  remaining  39 case hours were
overestimated  by  Valley. Of  the  four hours  in which  Valley underestimated
 observed concentrations, one was  a  nonimpingement  case in that  the  plume was
 released above the  critical dividing  streamline.   This case hour  occurred  in
 the early  morning as the sun was  rising, and  the  release was very close  to
 the hill  (213-m); so  the class  F  dispersion  rate  for  O^  apparently
 underestimated the  size of  the  plume.   Wind  speeds for the other  three
                     -3
-3
 *Units of 10   sec m  ; 1 yg/m   = 167.5 ppt for
                                      184

-------
TABLE 41.  SUMMARY C/Q STATISTICS FOR VALLEY AND
         CENTERLINE VALLEY CALCULATIONS
Exp.
201
201
201
301
20 1
202
202
2O2
2O2
202
202
204
204
204
204
204
2O4
205
205
205
206
206
206
2O6
206
209
209
209
209
209
210
210
210
210
210
211
211
211
211
211
211
214
214
214
214
Case
Hour
1
2
4
3
6
1
2
3
4
5
6
1
2
5
6
7
S
4
5
6
4
5
6
7
S
1
2
3
7
3
3
4
6
7
S
1
2
3
4
5
6
3
4
7
8
Max Co
32. 2
25. 1
IS. 6
34. 6
18. 7
18. 0
33. 6
67. 2
81. 6
49. 2
11. 8
14. 5
11. 3
4. 8
17. 6
9. 6
16. 1
15. 4
25. 5
15. 5
56. 7
41. 2
124. 2
92. 8
154. 6
3. 8
5. 0
5. 6
7. 6
20. 3
11. 5
4. 6
4. 4
8. 1
17. 9
11. 5
6. 4
3. 9
33. 0
97. 4
53. 1
77. 6
54. 4
119. 1
31. 7
Max Cp
79. 5
79. 5
86. 2
86. 2
86. 2
68. 2
68. 2
81. 4
81. 4
76. 7
71. 9
6B. 9
6S. 9
SI. 3
81. 3
81. 3
81. 3
56. 5
54. 8
60. 9
92. 2
92. 2
92. 2
92. 2
92. 2
7S. 6
75. 6
75. 6
60. 8
60. S
55. 3
55. 3
58. 1
58. 1
64. 1
69. 6
69. 6
69. 6
62. 6
62. 6
62. 6
105. 1
93. 4
53. 4
7O. 1
Max Cp/
Max Co
2. 47
3. 17
4. 63
2. 49
4. 61
3. 79
2. 03
1. 21
1. 00
1. 56
6. 09
4. 75
6. 10
16. 94
4. 62
8. 47
5. 05
3. 67
2. 15
3. 93
1. 63
2. 24
O. 74
0. 99
0. 6O
19. 89
15. 12
13. 50
8. 00
3. 00
4. 31
12. 02 •
13. 20
7. 17
3. 58
6. 05
1O. 83
17. 85
1. 9O
O. 64
1. IS
1. 35
1. 72
0. 45
2. 21
Max CL
67. 5
67. 5
78. 5
78. 5
78. 5
52. 4
52. 4
70. 3
70. 3
63. 4
57. 0
53. 2
53. 2
70. 3
70. 3
70. 3
70. 3
39. 9
38. 2
44. 3
279. 0
279. 0
279. 0
279. 0
279. 0
61. 8
61. 8
61. 3
44. 2
44. 2
38. 7
38. 7
41. 5
41. 5
47. S
54. 2
54. 2
54. 2
46. 2
46. 2
46. 2
139. 7
93. 7
454. 5
376. 4
Max CL/
Max Co
2. 10
2. 69
4. 22
2. 27
4. 2O
2. 91
1. 56
1. 05
. 36
1. 29
4. 83
3. 67
4. 71
14. 64
3. 99
7. 32
4. 37
2. 59
1. SO
2. 86
4. 92
6. 77
2. 25
3. 01
1. 81
16. 27
12. 36
11. 04
5. 82
2. 18
3. 37
8. 42
9. 43
5. 13
2. 67
4. 71
S. 46
13. 89
1. 4O
. 48
. 87
1. SO
1. 72
3. 82
11. 8S
                      185

-------
hours were between 2 and 2.5 m/sec (Case 206, hours 5 and 8; Case 211,
hour 5).  In fact, the highest observed C/Q of 155 occurred with a wind speed
of 2.5 m/sec and PG class F (Case 206, hour 8).
     One possible cause of Valley's failure to estimate the highest observed
hourly SFg concentrations at CCB may be related to the assumed 10 m "miss
distance."  Although this distance may be appropriate for large pollutant
sources in complex terrain where plume QZ values are considerably larger
than 10 m, it may be too large for the scale of the experiment at CCB.
Reducing the miss distance to 8.4m would be sufficient to reproduce the
maximum observed C/Q ratio in Case 206, hours  6 and 8.  However, it would not
be sufficient to reproduce the maximum concentration of 97 ppt observed in
Case 211, hour  5.  If  the average wind speed for this hour were used
(2.0 m/sec instead of  2.5 m/sec), then a  C/Q in excess of 97 would be
produced with a miss distance of  6.5 m.   The use of a lower wind speed as
well as a smaller miss distance at CCB may be  justified again by the  scale of
the experiment: tracer plumes are much closer to  the ground, much closer to
terrain, and much narrower than typical plumes from large sources.
     Figures  61 and  62 are scatterplots of modeled to observed concentration
ratios  versus modeled  concentrations  for  both  Valley and  Valley  centerline
SF,  concentrations.   It is  seen  that  about  one-third of  the 45 observed
   6
concentrations  are within a  factor  of 2 of  the hourly Valley calculations,
whereas about one-fourth are within a factor of  2  of  the Valley  centerline
calculations.   (Note that in these  scatterplots  some data points fell on  top
 of one  another within the resolution of  the plotter,  and some values fell
 below the bottom of  the plot when modeled values were very  small.   Therefore,
 the number of points distinguishable on the plots  may  not be as  large as  the
 number of sample points in the  data set  plotted.)
      COMPLEX I and COMPLEX II

      A complete set of statistical and graphical analyses of COMPLEX model
 calculations, like those illustrated for the example case study hour, was
 assembled for each of the 45 case hours.  (The complete set of analyses is
 available from the EPA Project Office upon request.)  Most of the key
 statistical results are summarized in Tables 42 and 43.  The asterisks that
                                      186

-------
  C(PRED)xCCOBS)

  100.0-



   50.0-




   30.fi-



   le.9-



    5.0-
    2.0'
    i.e-
     .5
     .1
                             C(Um.lEV)/C(OBS) US. C/0
                                  PEftK CONCENTRrtTIONS
                                              ®
      1.0                    10.0   20.0      50.0   100.0   800.0     506.6  1000.0


                                                               C(PRED>/0
Figure  61.    Variation of modeled-to-observed ratios  of maximum hourly
              concentrations with modeled  concentrations calculated by
              Valley.   Circles  identify the five highest observed  SF6
              concentrations CC/Q).
                                       187

-------
                   C(UAU.EV-CENTERLINE>/CCOBS> US. C(UAUEV-CENTERUNE>/0
                                 PEAK CONCENTRATIONS
C(PRED)'CCOBS)
 160.0-
  50.0-
  20.0-
  10.0-
   5.0-
   2.0-
   1.0-
    .5-
    .a-
    .1
      i.e
                                                                  ®
                                                             @
200.0     500.0   1000.0

      C(PRED>'0
Figure 62.   Variation of modeled-to-observed ratios of maximum hourly
              SFg concentrations with modeled concentrations  calculated
              by Valley  (centerline).   Circles identify the  five highest
              observed SF^ concentrations (C/Q).
                                       188

-------
                    ~n»cucu     -I ~
                                                               cu cu tn n n -< cu ni ni ru
                                                                                                   — « -« w -• w -H -]
p*
a
o
0

erf
o
Cn

CO
o
M
H
CO
M
H

^
CO

o-

o

t*
OS
                  d m' ni CD -o *b r « in d o1 CD •
                                                -n*r*Qa}~rir^&-*iT^~**6
                                                                      ^ N -H ni « n n   -«      «- * n n ni v tu   n -o r
                                           CD ni o in" iri o «' «):fa»dniiriNni(D«'«r -« CD ri fid w * -^ ai ri -* ni ni -o t>- N N o-' •* d hi n «
                                                                 •« «s- ni PJ   •- ««              «H        ru^-'-«i
                  ri ri o *t *> i' «t  '  '  ' i* -^  'riricoo'
                     i-4i-4              n   tfsnffin
                       ii               i    i  i  i i
                                                                  i  i  i      lit
W
.-J
                                      mo^tri^rhJ^^w^Qi^t^^virim^^riiriiftmNCDNriru^^iriwtri^vw
                                      —   ^rm^r^o-H—   — «r ^r co o r^- w n «sr n n          -* -o n n n tn n o*<9- o ^
                                                                                                          -^    w *M in «
                                                                                   tDri^ri^niKKth^ri
                                                                                   ^            ru-t-»^w^   cu-oo

                  cu^^j<)NO^ru^nia)«nnoj*^^^ifttnNcucua)-*
                  nicunrucucunincunicuaininrucutucuracucucuncucuoicucunicucurarunicun
                                                                       189

-------
CO
O
M
o
o

M
M


X
p..

§
o

oi

g

en
cj
w
H
CO
M
 co

 o-

 o

 ><
 s
 co
 CO
 -'-«t)*r*-<---'-''-v
                                                 [>o-ruof^o»oinmruon*o^N-«N-ooiD'«-nin   njcjo-oni'^*^r>Joo'O'-*t>'-*-o-oo^roQ)—'-o-otoN   in N ru o- o- N ry
SSSnio-*      ^i     «   «tD«K--iiH finjr^oSnj w   to v —   -«   -o ni   «* n    w«w




V ~° < N ri d ^ t> -4 6 -*" ni ni iri CD 6 -o N o" w d CD «r' ri * ri ^ ni N 6 w th ni ni th iri -^ ni ^o V JHid cp «-; ri
•-t n v o « -» -* •* N -« -4 ^-   o in o ch -* ~* -H m n -< «r « ni ci nl o «r *^   *-•-H   on   n t n *• n -o -o
                                                                                     :  1 «J* O* —« CM -JJ PI O-

                                                                                         i     i        T
                                                                                    *-
                                                                                 CM**   »i «M -< n -« n
                                       " w ^ ri ^ nl m cu « ri frwn«^^ntoNra^r^^o)ChO^r^no3a3th«a'N'OOOC3t>-'S-«HO--«ootnntj-noinin

N U N n ni n s to N <) r> *r ni -** ri -o in o' V  ri ocDv-*-*-<   -*   -*-*ni-«in«rn]Oi-in          w-<        ^-«     ncr-tDh-in^n
                 aicoir>om^->o>or
                                        ^r^rci'Oo*-~*iriifi   ^iw^rii^'CM—'^^^^mnj*^   thnnj^n-^cn
                                               «nwn                                 CM — «-«n
                 rimo^r^vcocQi^«ri-JcM — nj'w<)«Nifiriiriiri — ri  '   'tM-Jrini^ '  n ri *' ni  ' to 
-------
appear in Table 42 denote the stability class for each case hour according to
the Turner scheme for nighttime stability using the observed 10 m wind speed
(assuming no cloud cover, which generally agreed with net radiometer
measurements).  For a given case hour, the appropriate stability class is
signaled by an asterisk in one of the three C  columns.  For example, at
the entries for Case 205, hour 5, the asterisk appears in the C  column
corresponding to stability class F; for this hour, class F stability was the
most appropriate choice according to the Turner scheme because the mean 10 m
wind speed was 1.3 m/s and clear skies prevailed.
     Figures 63 through 70 are scatterplots of modeled maximum-to-observed
maximum concentration ratios versus modeled maximum concentrations.  These
concentrations have been scaled by the emission rate (Q) to facilitate
comparisons from one case hour to the next.  About one-half of the points lie
in the range 0.5 < C /C  < 2 (at least in the COMPLEX I results), and
                 -  p  o —
the other half lie significantly above this range (indicating
overestimation).  As the stability class changes from D to F, both COMPLEX I
and COMPLEX II tend to overestimate more.  Figures 66 and 70 illustrate the
performance of COMPLEX I and COMPLEX II when the stability class is selected
be the Turner scheme.  These figures show that COMPLEX I would be preferable
to COMPLEX II for use at CCB.
     Each of these scatterplots may be interpreted as a plot of the residual
between the modeled and observed concentration versus the modeled
concentration, if the observed concentration is assumed to be lognormally
distributed about the modeled concentration (see Section 5.3).  An excellent
model should produce a scatterplot with the residuals tightly clustered about
zero (C /C  =1) for all C , and the scatter about zero should be equal
throughout the range of C .
   "  Figures 63 through 70 show that the residuals based on maximum
concentrations (for all variants of the COMPLEX models tested) do not exhibit
these characteristics.  The scatter is large at all C , and the mean
increases with C  .
                                     191

-------
 C US. C(COHPLEX I)/0
                                  PEAK CONCENTRATIONS
                                                           ®
   	1	1	1	1	~1        I
i.e                    10.0   20.e      50.0    100.0  200.0    500.0   1000.0

                                                         CCPREDVQ
Figure  63.    Variation of modeled-to-observed ratios  of maximum hourly SF(,
              concentrations with modeled  concentrations calculated by
              Complex I (Stability Class D).   Circles  identify the  five
              highest observed SF6 concentrations  (C/Q).
                                       192

-------
  C(PRED)/C(OBS)
   50.0-
   30.0-
   10.0-
    5.0-
    2.0-
    1.0-
     .5
     .2-
                           C(COMPLEX I)/C(OBS) US. CCCOHPLEX I )/Q
                                  PErtK CONCENTRATIONS
                                                       ®
                                                           ®
                                                ®
     .1
      1.0                   10.0   20.0      50.0   100.0   290.e     500,0   1000.0

                                                               C
-------
 CCPREDVCCOBS)
  ioa.0-
   50.0-
   20.0-
   10.0-
    5.0-
    3.0
    1.0-
     .5
     .s-
     .1
      l.C
                          CCCOMPtEX I)XC(OBS) US. CCCONPLEX IJ/0
                                  PEAK CONCENTRATIONS
                            	1	1	
                             10.e   se.0
50.0   100.0   800.0     500.0   1000.0
Figure  65.    Variation of modeled-to-observed ratios of  maximum hourly
              concentrations with modeled  concentrations  calculated by
              Complex I (Stability Class F).   Circles identify the five
              highest observed  SF6 concentrations (C/Q).
                                       194

-------
                            CJCOHPLEX I)/CCOBS> US. C(COHPLEX IJ/O
                                    PEAK CONCEMTRftTIONS
   C
    100.9-
     50.0-
     30.0-
     10.0-
      5.0-
      3.0
      1.0-
       .5
       .2-
       .1
        1.0
Figure  66.
                              10.0   59.
                                50.0    100.0  S00.0     506.9   1000.0


                                                   CCPREDJ/0
Variation of modeled-to-observed  ratios of maximum hourly
concentrations with  modeled concentrations calculated by
Complex I (appropriate stability  class - Turner scheme).
Circles identify the five highest observed SF6  concentrations (C/Q)
                                        195

-------
                          CCCOMPLEX II)xC(OBS) US. CCCOMPLEX ID/Q
                                  PEAK CONCENTRATIONS
  C(PRED)/CCOBS)
   iee.0-
   se.a-
   so.e-
   10.0-
    5.0-
    E.0'
    1.0-
     .5-
      .1
                                                          ®
       1.0                    10.8    30.0      50.0    100.0   300.0     500.0   1000.0

                                                                C(PRED)/Q

Figure  67.    Variation of modeled-to-observed ratios  of maximum hourly SF6
              concentrations with modeled  concentrations calculated  by
              Complex II (Stability Class  D).   Circles identify the  five
              highest observed SF^ concentrations  (C/Q).
                                       196

-------
CCPRED)XC(OBS)
 100.0-


 50.0-



 ee.0-


 10.0-


  5.0-
  a.0-
  1.0-
   .5-
   .5-
   .1
     1.0
                        C
-------
                         CCCOflPLEX II)/C/CCOBS>
   se.e-
   ae.e-
   ie.8-
    5.0-
    a.e
    i.e-
     .5
     .a-
     .1
      i.e
                            	1	1	
                             ie.e   20.0
                              —i	1	1—
                              50.0   100.8   H00.0
500.0  1000.0
                                                               C(PRED)/Q
Figure  69.
Variation of modeled-to-observed ratios  of maximum hourly SFg
concentrations with modeled  concentrations calculated  by
Complex II (Stability Class  F).   Circles identify the  five
highest observed  SF6 concentrations  (C/Q).
                                        198

-------
                           C(COMPLEX II)/C(OBS) US.  C(COMPLEX ID/Q
                                   PEAK CONCENTRATIONS
   C(PRED)/C
    se.e-
    aa.e-
     s.e-
     2.0
     i.e-
      .5-
      .2-
      .1
        1.0                    ie. e   ae.e      se.o   lee.e   aee.e     see.e

                                                                C(PRED)/G

Figure  70.    Variation  of modeled-to-observed ratios  of maximum hourly SF6
              concentrations with modeled concentrations calculated  by
              Complex  II (appropriate  stability class  - Turner scheme).
              Circles  identify the five highest observed SF6
              concentrations (C/Q).
                                      199

-------
     PFM

     The analysis of PFM model calculations followed the same procedures used
in preparing results from the COMPLEX models.  Differences in tabular data
summaries arise only from the fewer case hours used and the fewer stability
classes tested.
     Table 44 summarizes PFM model performance statistics for the 23 hours in
which the SFg release height exceeded Hcrit by 5 m or more.  All
concentrations have again been scaled by the emission rate.  Figures 71
and 72 present scatterplots of peak calculated concentration ratios.  The
distribution of data in these figures shows some tendency toward
overestimation, and this overestimation increases in going from class D to
class E dispersion rates.  However, in comparing the PFM scatterplots with
the COMPLEX model scatterplots, there appears to be less of a trend toward
increasing the magnitude of the residuals with Cp.  This is apparently more
a function of the case hours selected than the model.   The relationship
between model performance and data classification by H     will be
discussed further in Section 5.5.2.
      Impingement Model

      Impingement model  calculations  are similar to  those  of  Valley—a maximum
 concentration is calculated for each hour.   Unlike  Valley, however,  the
 Impingement  model  simulates the maximum concentrations using actual
 meteorological conditions observed during a particular hour.  The Impingement
 model should better account for the  hour-to-hour variability in the  observed
 maximum concentrations  because it uses dispersion parameters calculated from
 observed turbulence intensities (see Section 4.5.4).   Table  45 summarizes the
 analysis of  the calculated concentrations (scaled by the  emission rate) for
 each of the  45 hours.
      Two consecutive case hours (Case 209,  hours 7  and 8) show conspicuously
 large overestimates, apparently because of differences in the o^
 calculated by the  model and the GZ estimated from lidar data (see
 Section 4.5.4).  In particular, for Case 209, hour 8, the proposed equation
 for O  seriously underestimates the size of the a  derived for this
      z                                           z
                                      200

-------
CO
a
a
t-t


|

u
o
       LU
       en
a. o

J  U


X  X

m  m
           jj  jj
          a>  <-
          ui  3
          rn  o

         o  I
            N  <* • -o o i -o  -o -a *-> o-  « -ci -H I o «* • «j-
         *-< ft        n-i        -<     -< in cu •? *•< ru
                                                                                      -c  o- cri
                                                                                         -i ri
                                                        CM     ru
         o- ci ri -< OD s ri •*• N N  s oi ri od o ri -o ni     -d i -o rJ  o
            ^                               n "< — i     -<                 ^  «
                    OD o  •* -6 oa "S-  in iri N in
                                                                     a  -o  ri « in o  t> o- o o  o o o T  *t

                   OOOOOOOOOOOOOOOO-i-irtrtrt«-i
                   oi oi ro CM rj rii  ni rj r
-------
  CCPRED1/CCOBS)
   iw.e-
   59.6-
   ae.e-
    5.0-
    s.e
    i.e-
     .5-
     .a-
     .1
       i.e
                               C(PFM)/C(OBS) US. CCPFID'O
                                  PEftK CONCENTRATIONS
                                                       ®
                                                        ®
A


A  A
                                                      ®
                                   ae.e
       — i
        59. t>
                                                     1
                                                           1
                                                   100.0   380.
	1	
 500.0  1000.0
                                                               C(PRED)/Q
Figure  71.    Variation of modeled-to-observed  ratios of maximum hourly
              concentrations with  modeled concentrations calculated by PFM
              (Stability Class D).   Circles identify the five highest
              observed SF6 concentrations (C/Q).
                                       202

-------
                                C(PFN)/C/C
   100.0-
    S0.e-
    20.0-
    10.0-
     5.0-
     3.0-
     1.0-
      .5
      .1
       1.0
Figure  72.
                                                      A     ®
                                                           @
                             —i	1—
                              10.0   20.9
                               	,	1	1	1	

                               50.0   100.0  200.0    500.0  1000.0


                                                  CtPREDJ/'Q
Variation of modeled-to-observed ratios of maximum hourly
concentrations with  modeled concentrations calculated by PFM
(Stability Class E).   Circles identify the five highest
observed SF6 concentrations (C/Q).
                                       203

-------
TABLE 45.
SUMMARY C/Q STATISTICS FOR  IMPINGEMENT
     MODEL CALCULATIONS
               Observed
Case
EXR, Hour
20 1
20 1
201
20 1
201
2O2
202
202
2O2
2O2
202
204
204
204
204
204
204
205
2O5
205
206
2O6
206
206
2O6
2O9
209
2O9
209
209
210
21O
210
21O
21O
211
211
211
211
211
211
214
214
214
214
1
2
4
5
6
1
2
3
4
5
6
1
2
5
6
7
8
4
5
6
4
5
6
7
8
1
2
3
7
8
3
4
6
7
8
1
2
3
4
5
6
3
4
7
8
N
16
16
16
1O
11
26
32
28
24
24
21
37
36
3O
34
32
33
33
31
37
35
3O
28
33
7O
47
46
48
46
40
45
39
40
45
15
43
36
34
36
40
37
41
37
43
46
Co
13. 1
8. 3
6. 4
11. 2
7. 9
4. O
B. 4
8. 6
7. 8
5. 2
3. 1
1. 7
2. 0
1. 1
2. 1
2. 5
6. 6
5. 2
7. 3
5. 3
13. 6
5. 7
35. 4
21. 6
38. 6
. 4
. 9
2. 1
1. 6
3. 2
2. 4
1. 6
. 5
. 8
3. 3
4. 3
2. 3
. 5
8. 7
24. 6
12. 3
5. 0
16. 7
25. O
9. 0
rf(Co)
B. 4
8. 1
5. 6
10. 1
5. 7
4. 9
6. 8
16. 9
17. 8
11. 1
3. 2
2. 7
2. 9
1. 0
3. 4
2. 4
4. 3
4. 4
4. 6
3. 6
16. 1
9. 5
31. 5
25. 5
35. 3
. 6
1. 3
1. 3
2. 0
4. 9
2. 7
1. 3
1. 0
1. 5
5. 4
2. 8
1. 4
. 8
9. 2
23. 0
12. 2
14. 9
13. 8
31.7
8. 4
Max
32.
25.
IB.
34.
18.
18.
33.
67.
81.
49.
11.
14.
11.
4.
17.
9.
16.
15.
25.
15.
56.
41.
124.
92.
154.
3.
5.
5.
7.
On
2
1
6
6
7
O
6
2
6
2
B
5
3
8
6
6
1
4
5
5
7
2
2
8
6
8
0
6
6
20. 3
11. 5
4. 6
4. 4
8. 1
17
11
6
3
. 9
. 5
. 4
. 9
33. O
97
53
77
54
119
31
. 4
. 1
. 6
. 4
. 1
. 7
Max Cp
14.
41.
71.
126.
137.
9.
27.
41.
12.
1.
58.
50.
18.
23.
57.
23.
38.
26.
11.
22.
169.
89.
126.
47.
23.
22.
28.
8.
221.
2B1.
44.
14.
3.
B.
40.
14.
15.
9.
11.
22.
28.
24.
55.
128.
12.
1
8
4
5
8
9
4
8
1
6
6
6
5
2
1
O
4
6
O
4
1
9
3
4
7
4
7
1
7
1
2
4
1
7
5
2
6
1
3
6
1
2
0
5
8
Max
Max

1.
3.
3.
7.





4.
3.
1.
4.
3.
2.
2.
1.

1.
2.
2.
1.


5.
5.
1.
29.
13.
3.
3.

1.
2.
1.
2.
2.




1.
1.

Op/
Co
44
66
83
66
39
55
82
62
15
03
96
49
63
88
25
41
39
73
43
44
98
18
02
51
15
94
69
45
17
86
87
16
71
08
26
23
45
34
34
23
53
31
Ol
08
40
Co-Cp
IB. 0
-16. 7
-52. B
-91. 9
-119. 2
B. 1
6. 2
25. 3
69. 6
47. 6
-46. B
-36. 1
-7. 2
-18. 5
-39. 5
-13. 5
-22. 3
-11. 2
14. 6
-6. 9
-112. 3
-48. 6
-2. 1
45. 4
131. 0
-IB. 6
-23. 6
-2. 5
-214. 1
-260. 8
-32. B
-9. 9
1. 3
— . 6
-22. 6
-2. 7
-9. 2
-5. 2
21. 7
74. B
25. 0
53. 4
-. 6
-9. 5
19. 0
                         204

-------
hour from the lidar data.  No other case hour showed so large a discrepancy.
If the turbulent plume spread during the preceding hour was also
underestimated to the same extent, then the consecutive hours of
overestimation are not surprising.  (Hour 7 lidar data are currently
unavailable because only selected hours of lidar data have been processed to
date.)   It is not known if the turbulence measurements, the temperature
measurements, or the functional form for a  are responsible for these
                                          z
discrepancies.
     A scatterplot of the Impingement model calculated-to-observed
concentration ratios versus calculated concentrations (scaled by the emission
rate) is presented in Figure 73.  It shows a general tendency for
overestimation of concentration peaks, although many observations are
underestimated.  The scatter in the residuals is very large,
especially for the lower two-thirds of the data points (as ordered by Cp) .

     Neutral Model

     Neutral model calculations are summarized and the overall statistics are
presented in Table 46.  A scatterplot of calculated-to-observed concentration
ratios versus calculated concentrations is presented in Figure 74.
     The Neutral model calculations underestimated the concentrations
observed during the two case hours singled out above (Case  209, hours 7
and  8).  A third hour  (Case  202,  hour 6) stands out because the model
predicted no SF, anywhere on the  hill.  This clearly results from the
magnitude of the vertical intensity of  turbulence  (IZ) used to compute
0  .  IZ for this hour was extremely small compared to all other hours
  z
tested.  Although  the magnitude of IZ is unusual,  the variation of  IZ and IW
throughout the hour (5-minute averages) indicates  that the  propellor
anemometer was probably  not  seizing.
     The scatterplot for the Neutral model shows a wide variability in model
performance, with  cases  of overestimation and underestimation of the hourly
maximum concentration.   However,  no strong increase in the  residual with Cp
is evident.   The Neutral model may thus have a mean residual close  to zero,
 but it  is  far  from being a good model for estimating maximum hourly
                                   205

-------
                     CUrtPINGEMENT P10DEL)/C(OBS> US.  CariPINCErtENT HODEU/0
                                   PEAK CONCENTRATIONS
  C(PRED)/C(OBS>
   iee.e-
    50.8-
    ae.e-
    ie.0-
     5.0-
     E.e
     i.e-
      .5
      .2-
      .1
        i.e
Figure  73.
                10.0    28.0      50.0   100.0   200.0     500.0   1000.0

                                                   CCPRED)/0

Variation of modeled-to-observed ratios  of maximum hourly SF
concentrations with modeled  concentrations calculated by the
Impingement model.   Circles  identify  the five highest
observed SF6 concentrations  (C/Q).
                                       206

-------
TABLE 46.  SUMMARY C/Q STATISTICS FOR NEUTRAL
             MODEL  CALCULATIONS
     Observed
Exp.
2O1
20 1
201
201
201
202
202
202
2O2
202
202
20-1
2O4
204
204
204
204
2O5
205
205
206
206
206
2O6
206
209
209
2O9
209
2O9
21O
210
210
210
210
211
211
211
211
211
211
214
214
214
214
Case
Hour
1
2
4
5
6
1
2
3
4
5
6
1
2
5
6
7
8
4
5
6
4
5
6
7
B
1
3
3
7
B
3
4
6
7
B
1
2
3
4
5
6
3
4
7
3
N
16
16
16
10
11
26
32
28
24
24
21
37
36
3O
34
32
33
33
31
37
35
30
23
33
70
47
46
48
46
40
45
39
40
45
15
43
36
34
36
4O
37
41
37
43
46
Co
13. 1
8. 3
6. 4
11.2
7. 9
4. O
B. 4
8. 6
7. B
5. 2
3. 1
1. 7
2. O
1. 1
2. 1
2. 5
6. 6
5. 2
7. 3
5. 3
13. 6
5. 7
35. 4
21. 6
38. 6
. 4
. 9
2. 1
1. 6
3. 2
2. 4
1. 6
. 5
. 8
3. 3
4. 3
2. 3
. 5
B. 7
24. 6
12. 3
5. O
16. 7
25. 0
9. 0
ff(Co)
B. 4
B. 1
5. 6
1O. 1
5. 7
4. 9
6. B
16. 9
17. B
11. 1
3. 2
2. 7
2. 9
1. O
3. 4
2. 4
4. 3
4. 4
4. 6
3. 6
16. 1
9. 5
31. 5
25. 5
35. 3
. 6
1. 3
1. 3
2. 0
4. 9
2. 7
1. 3
1. O
1. 5
5. 4
2. 8
1. 4
. S
9. 2
23. 0
12. 2
14. 9
13. 8
31. 7
8. 4
Max Co
32. 2
25. 1
18. 6
34. 6
18. 7
18. 0
33. 6
67. 2
81. 6
49. 2
11.8
14. 5
11. 3
4. B
17. 6
9. 6
16. 1
15. 4
25. 5
15. 5
56, 7
41. 2
124. 2
92. B
154. 6
3. B
5. 0
5. 6
7. 6
20. 3
11. 5
4. 6
4. 4
B. 1
17. 9
11.5
6. 4
3. 9
33. O
97. 4
53. 1
77. 6
54. 4
119. 1
31. 7
Cp
12. 4
1O. 0
22. 0
17. 0
2. 4
6. 4
4. 9
22.2
11. 5
4. 9
. O
20. 6
B. 7
21. 0
30. 9
2O. 4
33. 0
8. 7
4. 1
12. 7
6. 4
1O. 2
42. 6
17. 9
11.4
13. 6
9. 7
2. 9
. 5
1. 3
1. O
2. 9
. 7
3. B
8. 2
11. 1
13. 3
6. 6
1O. 5
19. O
21. 5
11.9
25. 7
29. 9
7. 1
(T
-------
                        CCNEUTRAL riODEL)/C(OBS> US. CtNEUTRAL flODEL >/0
                                  PEAK CONCENTRATIONS
 C/-C(01S)
  100.0-
   se.0-
   20.0-
   10.0-
    5.0-
    a.0
    1.0-
     .5
     .2-
     .1
       1.0
Figure  74.
                                       *  9
                                      ®
               10.0    20.0      50.0    100.0  200.0    500.0  1000.0

                                                  C(PRED)/0

Variation of modeled-to-observed ratios of maximum hourly  SFg
concentrations with modeled concentrations calculated by the
Neutral model.   Circles  identify the  five highest  observed
     concentrations (C/Q).
                                       208

-------
concentrations at CCB because of the scatter in the residuals and because it
underestimates the highest observations.
     5.5.2  Performance Evaluation

     Overall model error statistics for Valley, COMPLEX I, COMPLEX II, PFM,
and the new experimental models have been assembled in Table 47 for the
following measures related to e and cr£:

     e    m , s :  lognormal statistics (geometric mean and geometric
               gp1
               o
          standard deviation) of the residual errors in maximum computed and
          maximum observed concentrations.
          Max C  - Max C , O(Max C  - Max C ):  statistics of the
               o        p         o        p
          residuals in maximum computed and maximum observed concentrations.
          C -C , CJ(C -C ):  statistics of the residuals in computed
           o  p'    o  p'
          and observed concentrations paired by sampling location.
The first two sets of statistics summarize the errors in estimating 1-hour
maximum concentrations, regardless of location, over the hours included in
this analysis.  The third set summarizes the mean errors in estimating
observed concentrations at all sampling points.  Plots of £ versus cre
based on the data in Table 47 are displayed in Figures 75 through 77.
     Not all model statistics summarized in Table 47 are based on 45 case
hours.  The geometric statistics include only those hours with maximum
estimated concentrations greater than zero.  Several models produced an
estimate of zero for one hour, and so the geometric statistics for these are
based on 44 hours.  Furthermore, PFM was run for only those 23 hours in which
the release height exceeded  the calculated dividing streamline height by 5 m.
     Table 47 also contains  statistics for a "hybrid" model made up of
Neutral and Impingement model estimates.  Neutral model results are taken for
those 23 cases  where the release height exceeds ^clc±t by 5 m or more and
the Impingement model results are taken for the remaining 22 hours.  However,
geometric  statistics for this Neutral-Impingement combination model are based
on only 44 case hours because one of  the  23 Neutral model estimates is zero.
                                   209

-------
  TABLE  47.    SUMMARY  OF ANALYSIS  OF  C/Q  RESIDUALS - ALL  CASE HOURS
Model
Valley
Valley
COMPLEX
COMPLEX
COMPLEX
COMPLEX


(CD
I D
I E
I F
I T*
N
45
45
45
45
45
45
i
0
0
0
0
0
0

.29
.28
.66
.40
.37
.39
s
2
2
3
3
3
3

g
.64
.27
.10
.09
.18
.37
Max C -Max
-38
-64
-11
-37
-36
-37
C
.9
.9
.5
.8
.1
.6
COMPLEX II D
COMPLEX II E
COMPLEX II F
COMPLEX II T*
45
45
44
44
0.41
0.23
0.13
0.16
3.16
3.87
3.29
3.85
PFM** D
PFM** E

Neutral

Impingement
23
23
44

45
0.68    2.43
0.52    2.49

0.97    2.81

0.72    3.56
 -40.9
-109.9
-178.9
-165.3

 -11.7
 -29.4

   6.5

 -15.5
                                                         o(Hax Co - Max C )
 33.2
 80.0

 43.4
 52.6
 53.2
 55.9

 60.8
113.3
158.4
162.8

 32.0
 46.3

 31.1

 65.0
                                                                               C -C
                                                                                          o(C -C )
-12.0
-20.2
-24.8
-24.0

 -9.3
-17.3
-23.7
-23.2

 -1.4
 -2.2

 -4.6
18.9
24.5
25.1
25.5

26.0
45.5
68.5
67.2

16.6
22.1

12.1
Neucral-
ImpingemRnt
Combinacion
                  44
                         0.76
              3.14
                            -10.0
                                                62.9
Note:   Estimated concentrations  for one case hour were zero according to COMPLEX II  (Class F,T),  Neutral
       and  the Neutral-Impingement combination models.  Consequently, geometric statistics were computed
       over 44 case hours for  these models,  instead of over 45 case hours, as in the other statistics.
 *The Turner objective scheme  is used to determine the hourly stability class.
**PFM was run for case-hours  in which H ^ Hcrit + 5 m.
                                                210

-------
     On the basis of the lognormal statistics, the Neutral model best
estimates the highest observed_concentration each hour (in the sense that it
                              r\   __ f\    O
gives the smallest values of £  = e  + cr£).  It shows a slight bias toward
overestimation (m  = 0.97).  The Neutral-Impingement hybrid, the Impingement
                 O
model, and COMPLEX I (class D)'follow closely in performance with mean biases
of 0.66 to 0.76.  These are the only models in the test group that, on
average over at least 44 test cases, estimate the highest observed
concentration to within a factor of 2.  A second group of models has a bias
factor of about 0.4.  This group includes COMPLEX I (class E, F, and
appropriate stability class), and COMPLEX II (class D).
     Model ranking mostly depends on the magnitude of m (e) because s
                                                       o             &
(or cr£) shows less variability among the models.  The models that show
the largest biases are in increasing order:  the Valley model, mg = 0.29;
Valley centerline, m  = 0.28; COMPLEX II (class E), mg = 0.23; COMPLEX II
(appropriate stability class), m  = 0.16; and finally COMPLEX II (class F),
                                O
m  = 0.13.
 g
     The  relative performance of COMPLEX I and COMPLEX II indicates that
1-hour average calculated maximum concentrations at CCB are overestimated by
greater margins when:
      e     22.5°  sector averaging  is  not  used,  and
      e     stable plume configuration is  used.
 The best combination includes  22.5°  sector  averaging  and  a  0.5  plume  path
 coefficient  (COMPLEX I,  class  D),  but  it  is not  clear if  best performance  is
 due primarily to the difference  between class  E  and class D dispersion
 coefficients or to the difference  in plume  trajectory assumptions  (partial
 lift rather  than impingement).  For  example, it  is possible that the  use of
 class E plume spread coefficients  in combination with the 0.5 path
 coefficient  might yield m  value closer to  unity, but this  has  not been
                          &
 explored.
      A similar picture of relative model  performance  emerges if the
 (untransformed) concentration errors are  assumed to  be normally distributed.
 Mean residuals and standard deviations of the residuals between calculated
 and observed maximum concentrations  are plotted  in Figure 76.   The models
 with the smallest mean residuals are Neutral, Neutral/Impingement, COMPLEX I
                                   211

-------
       8.0'
       7.0-

       6.0-

       s.e-
 mg
      3.6-
      a.e-
       1.0-
        .7
COMPLEX II (Class F)

  * COMPLEX II
    (Appropriate Stability Class)
                                                          COMPLEX II (Class E)
                            Valley (Centerline) A
                                               Valley
                                                   ^COMPLEX I (Class F)
                                   COMPLEX I (Class E) ^ * COMPLEX I (Appropriate Stability
                                                    COMPLEX II        Class'
                                                     (Class D)
                                                  A COMPLEX I (Class D)
                                                      A Impingement
                                                  * Neutral/Impingement
                                                 Neutral
          .7
                   1.0
                                     2.0
                                                3.0
                                                        -4.6    5.0  6.0  7.0 8.0   18.
   Figure 75.    Relative performance  of models tested with  45 case  hours
                  of data from  CCB with model performance based on ratios of
                  maximum calculated and observed hourly SFg  concentrations.
Note:   mg  and s.g  are the  geometric mean and geometric  standard deviation
        of  the ratio Co/Cp.
                                           212

-------
 flax Co - Hex Cp
                     i Neutral
          COMPLEX I (Class D).
  -38.8-
                Valleys
                   Neutral/Impingement
                   * Impingement
               COMPLEX I (Class F)
              £ A COMPLEX I (Appropriate Stability Class)
                 A COMPLEX II (Class D)
                       COMPLEX I (Class E)
  -se.e-
                                          Valley (Centerline)
                                                        COMPLEX II (Class E)
 -iae.0-
  -159.e-
                                             COMPLEX II (Appropriate Stability Class) t

                                                         COMPLEX II (Class F) .
  -189. .9
               —r—
                69.e
                                            "T
                                                                    isa.'s
                                                                        Co - Res Cp)
Figure 76.
Relative performance  of models tested with 45 case  hours  of
data from  CCB with model performance based on residuals of
maximum calculated and observed  hourly  SF6 concentrations.
                                          213

-------
  -S.0-
                  • Neutral
                              > COMPLEX II (Class D)
                       * COMPLEX I (Class D)
 -15.9-
                                               * COMPLEX II (Class E)
 -ae.e-
                             > COMPLEX I (Class E)
                                                  COMPLEX II (Appropriate Stability Class)
 -as.e-
                             A COMPLEX I (Appropriate Stability Class)
                             * COMPLEX I (Class F)
                                                     'COMPLEX II
                                                       (Class F)
                                         49.9
                                                           69.9
                                                              99.9


                                                       alCo - Cp)
Figure 77.
Relative performance of models tested with 45 case hours  of
data  at CCB  with model performance based  on residuals of
calculated and observed hourly SFg concentrations at all
samplers.
                                       214

-------
(class D), and Impingement.  (The Neutral model underestimates maximum
concentrations on the average, but it still exhibits the best performance in
terms of e2.  The next best model is COMPLEX I (class D).)  Those with
the largest mean residuals are Valley centerline and COMPLEX II (stable
classes).  Valley, COMPLEX I (stable classes), and COMPLEX II (class D) are
grouped not far from the relatively better models.
     A different relative ordering is foundjvhen paired residuals from all
                                           2
sampling points are evaluated in terms of e  (see Figure 77).  The
Neutral model is again nearest to a zero mean residual.  COMPLEX II (class D)
now ranks ahead of COMPLEX I (class D), COMPLEX II (class E) is virtually
tied with COMPLEX I (class E), and COMPLEX II (class F) is poorer than
COMPLEX  I (class F).  The Valley and Impingement model results are not
presented because they estimate only the maximum concentration.
     The relative performances of COMPLEX I and COMPLEX II become clearer
when added  importance is attached to the standard deviation of the residuals
(a ).  COMPLEX I results show uniformly smaller CT£ values than do
COMPLEX  II  results.  Therefore, the mean residuals for COMPLEX II are
probably closer to zero than the corresponding COMPLEX I residuals because
underestimates and overestimates tend to balance.  This interpretation is
consistent  with the fact that COMPLEX I is a sector-averaged model, whereas
COMPLEX  II  is a narrow  plume model.
     PFM performance was not included in the foregoing comparisons because it
was run  for only  23 of  the 45 test cases.  Instead, PFM is separately
compared against  the Neutral model and against the COMPLEX models for  those
23 case  hours during which the release height was equal to or greater than
H     plus  5 m.   Table  48 presents the residual statistics for this
  crit
comparison  and these results are displayed in Figures  78 to  80.
      PFM ranks about the same as COMPLEX II (class D)  and COMPLEX I  (stable
classes) in estimating  the maximum concentrations, both with and without  the
log transformation.  Its bias  (m  ) is 0.68.   The  only  models with a  bias
closer to unity are Neutral  (m  = 1.03) and COMPLEX  I, class D (mg = 1.10).
Point-by-point residual analysis  (see Figure  80)  shows PFM  (class D) to have
                                                        2
the smallest mean residual,  but  its mean square error  (£  )  is not as
small  as that  for the Neutral model.
                                   215

-------
              tfl1
                                  \D co  in  co
                                  r-4 CM  i-l  i-l
                                                  oo  oo  f-  co
                                                  i-l  CM  CO  CO
                                                                                  O" 05
                                                                                  B  -
 Al
                                     co  in  co
                                                  CM  vO  CT\  CO
 CO
 es
 SB
CO
                                  co  in co
                                                        CO  vO
                                                                                  3 -u
                                                                                  II) CO
                                                                                  S5 B
                                            a)   u 41
                                            i-l     -o
                                            o   o o
                                                                                  60 to
O
             U
                                  i-l  O  «-»
                                                                                  N JS

                                                                                  0) Ol
CO
M
CA
                                  vo  co  m
                                  CM  CM  CM
                                                  CM  CM  CM  CO
                                                                                  o o
                  o o
                                     O  O
                                                                                  B cu co
                                                                                  O 3 O
                                                                              E    u co
                                     CO  CO  CO
                                  CM  CM  c*g
                                                 co co  co  co
                                                 CM CM  CM  CM
                                                                             U    4J 4J 4J
                                                                             CO    C « q)
OO
                                                                                  0) -r( O

sin
                                                       *
                                                          a
                                                    888
                                                                             01   U  O
                                                                             B   m  <1) B
                                                                             >-i   W  DO-i-l
                                           216

-------
    is.e


     8.6

     7.9

     6.0-


     5.0-


     4.0-



     3.0-
mg
     a.e-
     1.0H
COMPLEX II (Class F)
       COMPLEX II
       (Appropriate Stability Class)
COMPLEX II (Class E)
                                           * PFM (Class E)

                            COMPLEX I (Class F) * COMPLEX I (Class E)
                           COMPLEX II (Class D) A ^ * COMPLEX I (Appropriate Stability Class)
                                          * PFM (Class D)
                                            Neutral
                                            * COMPLEX I (Class D)
      .7
        .7       1.0                a.e        3.0     4.6    s.e   e.e  7.0 8.0

Note: rrig and sg are the geometric standard deviation of the ratio Co/Cp.
  Figure 78.    Relative  performance of models  tested with  23 hours case
                 hours (release height  > Hcr^t)  of data at CCB with model
                 performance based on ratios of  maximum calculated and
                 observed  hourly  SF^ concentrations.
                                         217

-------
n«x Co - n«x
   10.8
  -ie.0-
  -30.0-
  -50.0-
  -70.0-
  -90.0-
                       A Neutral
COMPLEX I (Class F)
                                    * COMPLEX I (Class D)
                                PFM (Class D)
                                    A COMPLEX I (Appropriate Stability Class)
                                     *• COMPLEX II (Class D)
                                           * COMPLEX I (Class E)
                                         . PFM (Class E)
                                                         COMPLEX II (Class E)
                                                          ^ COMPLEX II
                                                          (Appropriate Stability Class)
                                                                  i COMPLEX II
                                                                   (Class F)
 -ne.0
       .0
                    30.0
                                   40.0
                                                 60.0
                                                   80.0


                                                      Hcrit)  of data at CCB with model  performance
               based on residuals of maximum calculated and observed
               hourly SF,  concentrations.
                                        218

-------
     Co -
   -3.©-
   -e.e-
   -9.0-
  -15.8-
  -18.0-
                  Neutral
PFM (Class D)

      A PFM (Class E)
* COMPLEX II (Class D)
                                                  COMPLEX II (Class E)
                                  COMPLEX I (Class D)
                       COMPLEX II
                       (Appropriate Stability Class)
                            A COMPLEX II (Class F)
               COMPLEX I
               (Appropriate Stabil ity Class) •
      A COMPLEX I (Class E)
                                   COMPLEX I (Class F)
                                  ae.e
                                                 30.0
                                                                           - Cp)
Figure 80.    Relative performance  of models tested with 23 case hours
               (release height > Hcrit) of data at CCB with model performance
               based  on residuals of calculated and observed hourly SFg
               concentrations  at all samplers.
                                        219

-------
     Figures 78 through 80 also show that the models  perform better  on  the
subset of case hours during which the release was above Hcrit than they do
on the entire 45-hour set.  For example, only the COMPLEX II (stable)
computations overestimate maximum observed concentrations by more than  a
factor of 2.  Furthermore, the COMPLEX II estimates provide a marginally
better description of the overall distribution of concentrations than the
COMPLEX  I estimates.  This suggests that the flow was generally steadier when
the release was above Hcrit, and, consequently, that nonsector-averaged
models tend to do as well or better than sector-averaged models in describing
plume spread over 1-hour periods for this class of flow.  This is best
demonstrated with PG class D dispersion  rates.
     Model performance may also be addressed by quantifying  the uncertainty
in model estimates  in  terms of confidence intervals  computed  from the error
statistics  (mean and standard  deviation).  One approach  to computing
confidence  intervals is  described  in Appendix C.
      The evaluations of  model  performance presented  above  show  that there is
clearly  room for  improving the reliability of Gaussian models intended  for
use in complex terrain settings.   ERT's plans for further  development  of
models with data  from  the experiments  at CCB are presented in the next
 section.
                                    220

-------
                                  SECTION 6
                     CONCLUSIONS AND EECOMMENDATIONS FOR
                       FURTHER ANALYSIS  AND  DEVELOPMENT

6.1  Accomplishments in Overview

     The Cinder Cone Butte study, the initial field study in EPA's continuing
program to develop and validate reliable dispersion models for applications
in complex terrain, has achieved its stated objectives (Holzworth 1980) of
providing both a set of visual observations of smoke plumes interacting with
an isolated terrain feature in generally stably stratified flows and a
detailed data base of meteorological and tracer measurements with which to
develop appropriate models for these interactions.
     The field program has verified the basic concepts of the experimental
design.  The flexibility provided by the release of gaseous and visible
tracers from mobile cranes allowed experiments to be run cost-effectively
under various meteorological conditions.  The study has also demonstrated the
value of a meteorological data-handling system that collects, processes, and
displays information to guide the experiments in real time.
     Moreover, the CCB study has confirmed the utility and effectiveness of
scaled physical modeling within the overall program.  The general features of
the flows visualized at CCB replicated the flows produced at the Fluid
Modeling Facility, thereby verifying that to a very useful extent, the
essential physics of stably stratified flows over complex terrain features
can be reduced to the laboratory scale in order to examine particular flow
conditions and to guide experimental design.
     For example, during the design of the CCB field study, information
derived from experiments in the FMF's stably stratified water tank was
valuable in siting the 150 m tower outside the perturbing influences of the
butte.  Pictures of dye streaklines in tank experiments were the primary
                                     221

-------
basis for choosing the array of sampler locations on CCB and for relocating
some samplers in response to meteorological forecasts.   In addition,  a series
of quantitative laboratory experiments provided important support for the
Hunt-Snyder critical streamline height, which in turn was the basis for
positioning the heights of tracer releases in response to computed Froude
numbers during the field experiments.
     Laboratory modeling of case hours from the CCB experiments is continuing
at the FMF to aid in the interpretation of the field observations.  The
detailed fluid modeling study of one case hour is reported in Appendix B.
This study shows the influence on hourly averaged concentrations of the use
of sequential 5-minute flow data instead of hourly averaged flow data.
Before any general conclusions may be deduced, however, additional data from
both physical and mathematical models should be obtained for other case
hours, and results of sequential simulations should be compared with hourly
averaged results as well as with field data.  Although laboratory fluid
modeling cannot simulate the real world exactly (because of differences in
scales and intensity of turbulence, differences in wind and temperature
profiles, and lack of meander in the laboratory flows, as well as for other
reasons), it is nonetheless a valuable adjunct to field experiments; as
Holzworth (1980) states, "by allowing the controlled variation of independent
variables, laboratory experiments will provide deeper  insight and
understanding of the fundamental physics."
     The CCB field program has provided a detailed, reliable data archive
with which to evaluate the accuracy of the present generation of complex
terrain models as well as to develop more reliable models.  The data archive
includes the following:

     •    meteorological measurements,
     •    observations of the patterns of tracer concentrations on the butte,
     •    lidar-derived  plume sections, and
     •    photographic evidence.

     The edited  data  archive  is  unique  in its  detailed and reliable
documentation of stable  flow and dispersion  near an isolated hill.  Moreover,
                                   222

-------
in addition to its quantitative content, this data base also has important
qualitative value:  many of the photographs clearly demonstrate that plumes
interact with elevated terrain features in a complicated variety of ways
under stable flow conditions and that the simple impingement description used
in some current dispersion models may not be in accord with the behavior of
plumes.
     Substantial progress has also been made in developing improved
dispersion models for projecting ground-level concentrations on complex
terrain from elevated point sources in stably stratified flows.  We have
developed new statistical techniques for evaluating the performance of air
quality models and have applied these techniques to current complex terrain
models.  Preliminary new models have been constructed that incorporate some
on-site turbulence data and only the simplest sort of field observations
that is, the two distinct regimes of plumes released above or below the
dividing streamline height.  Even these first attempts at more physically
realistic models  show better performance than current models.  The
evaluations of the performance of these preliminary models point to the need
for  further development of complex terrain models of known reliability and
demonstrated applicability for regulatory use.
     Of course, the results of these evaluations cannot be simply applied to
other  sites with  different scales, such as power plants near mountains, or to
different  sorts of terrain elements, such as bluffs, ridges, or mesas where
the  potential  for blocking of  the flow  is greater and where the dividing
streamline height is  related to  the  flow characteristics in a different way.
The  data base  of  the  CCB  field study cannot  be  used  to address all  these
problems directly—nor was  the experiment  intended to address them.  Other
field  experiments must  be designed and  performed  for these  purposes, as the
EPA's  program  has recognized.
      We have  only begun to exploit the  data  gathered at  CCB, however.   We
anticipate that because  of the good  quality  of  the meteorological  and tracer
measurements,  these  data contain valuable  information on the characteristics
of the flow over  the  butte and on the effects  of  both 5-minute  and  1-hour
 turbulence on the observed patterns  of  tracer  gases.  This  information  will
 lead to an improved  understanding of transport  and diffusion around the
                                   223

-------
butte—which will, in turn, point the way to better models of these
processes.  The remainder of this report summarizes comparative performance
evaluations of the several models tested (Section 6.2) and presents
recommendations for further analysis of CCB data and further model
development with this data base (Section 6.3).

6.2  Comparative Model Performance Evaluations

     Valley, COMPLEX I, COMPLEX II, and PFM computations of 1-hour average
SF, concentrations were compared with measured SF- concentrations from as
  b                                              o
many as 45 experiment case hours in the CCB data archive.  Two new
experimental models were also evaluated with the same data.  This evaluation
serves to document how well each of these models performed with the CCB data,
in both an absolute and a relative sense.
     The Valley model is a screening algorithm intended for estimating the
highest expected 24-hour average concentration of pollutants released from
large point sources in complex terrain.  It is based upon a univariate
Gaussian plume formula incorporating 22.5° horizontal sector averaging and
postulated worst—case meteorology leading to stable impingement situations.
The comparison of Valley with CCB SF  tracer concentrations only tests how
well the model simulates 1—hour average concentration estimates at CCB, not
the way the Valley model is used in regulatory practice for estimating
24—hour average concentrations by persisting the assumed worst—case
meteorology for six hours.
     In 39 of the 45 test case hours, the concentration maximums were
overestimated by Valley, and in four of the case hours, maximum
concentrations were appreciably underestimated.  The mean ratio (over all
45 hours) of the Valley model estimate to the observed concentration is 5.3
and the geometric mean ratio is 3.4.
     The four cases in which Valley underestimated peak observed values may
be "explainable" by the scale of the CCB experiment.  The Valley model and
its assumed worst-case meteorological conditions are supposed to apply to
real sources in complex terrain, where source heights and transport distances
are generally much larger than the source-terrain geometry of the CCB
                                     224

-------
          -   But during the experiments, wind speeds at release heights were
frequently less than 2.5 in/sec, and as the plume approached the impingement
point, CT  was at times significantly smaller than the 10 m plume
        2
centerline stand-off distance assumed by the model.  This phenomenon is
associated,  of course, with the small scale of the CCB experiment.  For most
regulatory applications of the Valley model, cr  is large by comparison to
                                              z
the 10 m stand-off distance, and therefore the model concentration estimates
usually correspond closely to maximum plume centerline values.
     Unlike Valley, COMPLEX I, COMPLEX II, and PFM are sequential air quality
models.  These models are intended to produce 1-hour concentration estimates
using on-site meteorology.  COMPLEX I and COMPLEX II were tested with
45 experiment case hours, and PFM was tested with 23 of these hours in which
the SF, tracer was released at least 5 m above the critical dividing
      6
streamline height.  The 1-hour average meteorology used to drive these models
was estimated for the tracer release height.  No "tuning" of the model inputs
was done to improve the performance of these models.
     COMPLEX I was found to overestimate in the mean when peak observed
concentrations were compared to peak modeled concentrations (regardless of
location) and when the hourly stability class was derived from the Turner
scheme.  The mean of  the ratios of the peak modeled to peak observed
concentrations is 5.3 and the geometric mean is 2.6, both nearly the same as
Valley.
     COMPLEX II was also found to overestimate maximum observed
concentrations when the hourly stability class was derived from the Turner
scheme.  The mean of  the ratios of peak concentrations is 14.4, and the
geometric mean is 6.3.  Therefore, COMPLEX I, with the constant sector
averaging to simulate crosswind diffusion, appears to do a better job of
estimating the magnitude of peak hourly concentrations at CCB than COMPLEX II.
     Additional evaluations of the COMPLEX models were made by fixing the
stability class for all test hours.  Each model was run x^ith stability
classes D, E, and F in turn.  Note that both COMPLEX I and COMPLEX II include
the following default values for plume path coefficients as functions of
stability class.  For stability class D the plume path coefficient is 0.5.
For stability classes E and F, the plume path coefficients is 0.0, and full
                                    225

-------
surface reflection (doubling of concentrations) is assumed.  The COMPLEX I
and COMPLEX II model runs were made with these default values.
     Both models overestimated peak concentrations on the average but the
bias toward overestimation decreased as the stability class was changed from
F to D.  However, the scatter in the data (as characterized by the standard
deviation of the residual CT(C -C )) was not significantly affected.
     These models performed better, however, on the subset of hours in which
the tracer was released above the dividing streamline height of the flow.
The overall bias toward overestimation was reduced, and the scatter in the
data was also reduced, although it remained large.  Again, COMPLEX I
performed better than COMPLEX II.
     PFM was compared with COMPLEX I and COMPLEX  II using Turner a  and
a  values for PG stability classes D and E on the same subset of hours.
 z
PFM appears to offer some improvement over COMPLEX II, particularly for
stability class E (when COMPLEX II adopts the Valley model stable impingement
plume path).  PFM does not appear to offer improvement over COMPLEX I.
     Two new experimental models were also tested and compared with COMPLEX I
and COMPLEX II.  The Neutral model is similar to  COMPLEX  II (class D).  Like
COMPLEX II, it uses a 0.5 plume path coefficient  for neutral stability, but
unlike COMPLEX II, it uses on-site turbulence intensities to calculate
dispersion coefficients.  The Impingement model also uses on-site turbulence
data.  It estimates the maximum 1-hour concentration for  a plume that
impinges upon the terrain and then passes around  the sides of the terrain
feature.
     The Neutral model performs better than  the other models evaluated in
terms of mean bias and offers an improvement  in terms of  the standard
deviation of residuals over all the data, but no  improvement in the standard
deviation of the residuals of peak concentrations.
     A hybrid model that combines the Neutral model  (for  cases in which the
tracer is released above the critical dividing streamline) and the
Impingement model  (for cases in which the tracer  is  released below) was
disappointing—both the bias and  standard deviation  of the residuals
increased over those  obtained when  the Neutral model alone was used for all
hours.
                                     226

-------
     It appears that the use of oil-site turbulence data does, to some extent,
improve model performance at CCB and that the use of horizontal sector
averaging over 22.5° (in lieu of turbulence data) to describe effective
crossplume spread over an hour is more helpful than the use of the CF
inferred from the Turner surface stability class.  For this data base,
however, none of the models tested to date yielded precise estimates.

6.3  Recommendations for Further Research

     Although the CCB f i,eld program" has provided good visual and quantitative
data on the interactions of stable plumes with an isolated hill, much remains
to be done to achieve the goal of practical, easily comprehensible, and
reliable dispersion models applicable to stable flows in complex terrain and
transferable to other sites.  This section describes the research and
development we plan to perform with the data already obtained from the CCB
experiments.  We expect  that substantial progress toward the program's goal
will result from these efforts.
     The key to successful modeling of observed tracer concentrations at CCB
lies in relating the meteorological data to the observed behavior of the
visible plume.  Over the course of the field program, smoke  plumes exhibited
a wide range of shapes,  dimensions, and trajectories as they passed near the
hill.
     A dominant feature  of plume trajectories at  CCB is the  sensitivity of
plume path in the horizontal to small changes in wind direction or source
position.  As the stability of  the atmosphere increased and  the mean wind
speed decreased, the plume rested on one side of  the hill  or the other but
spent very little time  in between.  During experiment hours  in which  the mean
wind was directed toward the center of the hill,  the plume generally  swept
quickly across  the  hill, coming to rest  on alternate sides of  the hill in
turn.  This  behavior is  consistent with  the notion  of flow beneath the
critical dividing streamline.
     For periods of weaker  thermal  stratification or greater wind  speed at
source height,  horizontal  trajectories were  steadier and  the plumes  rose over
part of  CCB  for significant  periods during  some hours.  At times,  in passing
                                    227

-------
over the crest of the hill, plumes appeared to shrink in vertical extent, and
gave at least the visual impression they were not in contact with the
surface.  This behavior is consistent with the notion of flow above the
critical dividing streamline.
     Often, however, the distinction between these two conceptual
descriptions was not well defined in the visual appearance of the plumes.
The appearance of the plumes varied from hour to hour and quite often varied
a great deal during the course of one hour.  Sometimes the plume was very
wide and flat; at other times, it was a well-collimated "pencil beam"; and
undulations, waves, and even spiraling pulsations were occasionally
observed.  For initially narrow plumes, some increase in spread upwind of the
hill was often noted if the plume was transported toward the center of the
hill, but no such spread was seen if the plume curved around the side.  This
suggests that the hill influenced at least locally the upwind flow field and
turbulence levels.
     The model comparison and evaluation studies described in this report
underscore the importance of these qualitative plume features.  Models that
employed unaltered  PG a  and cr  values did least well because
horizontal meander  over time scales of 10 minutes to an hour often produced
plume spread much larger than that described by the stable (class E and F)
a  curves.  Horizontal sector averaging improved model performance, but a
 y
fixed sector width  is not applicable to all stable-flow plume phenomena or to
all source-terrain  geometries.  A model that uses on-site turbulence data to
estimate plume size performed better than  similar models that use PG  sigmas
with or without  sector averaging.  Yet although on-site turbulence data
contain information about  plume spread and meander, the use  of  such data also
introduces new sources of uncertainty  into the modeled concentration
estimates.  Systematic errors in meteorological instrumentation, for  example,
produce errors in modeled a   estimates.   It is therefore essential to
correct the data for documented deficiencies  in order to take fuller
advantage  of  the data's  ability to characterize observed plume  behavior.
      The development  of  mathematical models incorporating the effects  of
these  phenomena  will  require further analysis of  the  CCB data base.   This
analysis will involve  refinements  of  the  data base,  identification and
                                   228

-------
 formulation of model components  for describing  important  transport  and
 dispersion phenomena, testing and evaluation of new model formulations, and
 continued improvement arid refinement of these formulations.

      Refinement of the Meteorological Data

      Refining the meteorological data will include adjusting wind and
 turbulence data to account for non-cosirie response characteristics of the
 propeller anemometers.   The knowledge and use of these kinds of adjustments
 is especially important for evaluating model performance.
      As noted earlier,  the values of mean wind derived at CCB from,the
 propeller anemometers often disagreed with corresponding values derived from
 the cup-and-vane anemometers.   Where the source of the discrepancy is
 obvious—misalignment of the instrument on the tower or a seized propeller,
 for example—the anemometer data can be corrected (or deleted) on the basis
 of the  information at hand.   But other sources  of discrepancy arise  from
 differences  in the way  the two  kinds  of systems  respond to winds at  various
 angles  of incidence,  differences in  the way they react to the same levels  of
 turbulence intensity, or for kindred  reasons.   In a few cases,  the
 discrepancies  in mean wind speed may  be so large that  winds derived  from
 propeller systems  could  imply H     >H, whereas  winds  from cups  could      :
 imply Hcrit 
-------
     Identification and Testing of Model Components

     Aided by observational evidence, we will continue to develop and test
model components such as flow-field, turbulent diffusion, boundary-layer, and
wake components.  These components will individually undergo sensitivity
tests, refinements, and calibrations until their theoretical formulations are
as consistent as possible with the observations.  The tests will serve to
define acceptable ranges for parameters and to permit a structured tuning of
the complete model with observed tracer concentrations.  (Tuned models will
be evaluated with a data set separate from that used to adjust model
parameters.)
     Observational evidence will be assembled from a "learning" subset of the
CCB data to support additional case study analyses.  The analyses done to
date have been performed largely without the benefit of correlative CCB
data—nephelometer, sonde, lidar, sampling mast concentrations, and
photographs—that could help in quantifying plume transport and diffusion
phenomena.  The purpose of continuing case study analyses is to delineate
these phenomena as well as possible using all available information
(including cae hours of near-zero tracer concentrations), so that we can
understand the evolution of the measured 1-hour tracer concentration
distributions within the resolution of the 5-minute average meteorological
data and the 10-minute average tracer data in the CCB data base.
     The 5-minute meteorological data base is essential to our understanding
of the CCB experiments.  Many of the theoretical descriptions of plume
behavior near terrain are linked to notions about streamline patterns.
These, in turn, depend critically upon the spatial and temporal variability
in wind speed and wind direction.  It has been shown, for example, that the
mean wind field used in the models exerts a critical influence on the
inferred flow regime (H < H  lt, H > Hcrl(.) and especially on the
magnitudes and locations of the maximum concentrations.  It is therefore
important to seek ways to infer the time-dependent structure of the flow
field from supporting short-term data.
     One suggested approach to this task is to construct the streamlines at
CCB implied by the 10 m and 30 m potential temperature data on the butte,
                                    230

-------
taking as a working assumption that streamlines are constrained to travel
along surfaces of constant potential temperature, at least during fairly
steady-state periods.  The streamlines thus derived could be used to
determine from what elevations, in the approach flow over the plain, air
parcels over the butte appear to originate.  (Leeward 10 m temperatures may
be contaminated by heat exchange with the butte surface, but this could be
checked by comparing windward and leeward temperatures.)  These implied
streamlines could then be compared to estimates of one or more candidate flow
models.
     The short-term data will prove' valuable in other ways as well.  We have
not begun to explore the wealth of information that could be extracted from
time series of the mean wind and turbulence fields or from their
autocorrelations and cross-correlations in time and space.  Spectral analyses
of these data may lead to a better understanding of stable boundary layer
processes, to new insight into the mechanics of plume meander and turbulent
growth at CCB, and to more successful algorithms for relating small-scale
turbulence to large-scale flow characteristics.
     Supplementary data akin to those in the 5-minute and 10-minute average
data base will be obtained in simulated flows set up in EPA1s towing tank.
These data will help to refine, extend, arid test model components.  For
example, to explore further the use of the CCB potential temperature data as
a quantitative indication of streamline patterns, it would also be worthwhile
to simulate these same flow situations in the towing tank in order to
ascertain how well the laboratory model describes the flow fields inferred
from the observed temperature fields.  We recognize that it may be difficult
or impractical to set up in the towing tank the corresponding nonuniform
density gradient; however, if even an approximate correspondence in the
profile of N(z) can be established, the experiments could be very instructive.
     Another example of such testing of model components is the analysis of
how plume deformation and plume growth effects combine during stable
impingement conditions.  To help distinguish these effects, we suggest
performing a series of towing tank experiments to simulate case hours of
strongly stable plume impingement.  The purpose of these runs would be to
observe and record the lateral and vertical growth of the plume as it
                                    231

-------
approaches the butte in a nonturbulent flow—that is, to estimate the pattern
of plume growth resulting from flow distortion only.  Where possible, the
plume dimensions estimated from the tank experiments could be compared with
the CCB photographs and lidar results.  Because the tank flows would be
almost entirely nonturbulent, the  (scaled) laboratory plume should be smaller
than the plume observed at CCB.  If initial plume dimensions can be ignored
or readily accounted for, any relative differences found in the plume's
crosswind or vertical spread would measure the additional plume dispersion
caused by local small—scale turbulence or drainage winds.
     The quantitative correspondence cannot be taken at face value because of
essential differences between flows in the laboratory model experiment and
the prototype flow at CCB—differences in surface boundary layer
characteristics, in hill roughness, in profiles of temperature (density) and
winds in the approach flow, in steadiness of the flow, and so forth.  At
least qualitatively, however, any significant differences in plume dimensions
should suggest the relative magnitude of distortion and diffusion processes
at CCB under impingement conditions.

     Evaluation of Models

     Models formulated and adjusted by means of the learning data set must be
evaluated on a test data set.  Individual case hours within this data set
should be studied in the same detail as is done for the learning set, so that
sufficient data are available to run the models and so that enough
familiarity with the data is obtained to gauge the expected imprecision in
model estimates.
     Model performance will be primarily gauged by comparing estimated tracer
concentrations to observed concentrations.  Where possible, we will test
individual model components to assess the adequacy of the components that
make up the model (as well as the adequacy of the model as a whole) and to
identify important deficiencies.  Residuals between observed and modeled
variables will be analyzed in accordance with the methods presented in
Section 5.  Efforts will also be made to include a broader range of
statistical tests consistent with recommendations of the AMS Workshop on
Dispersion Model Performance (Fox 1981).
                                    232

-------
     Improvement and Refinement of Model Formulations

     Model formulation and testing is viewed as an iterative process.  First
attempts, such as those described in Section 4, are made to investigate the
scope of the problem and to set a model performance mark to be exceeded by
more refined approaches.  It is our intent to develop and evaluate a number
of models over the course of this project and to assemble a hierarchy of
modeling techniques, accuracies, and data needs.
     The data needs are especially critical.  For practical use in various
regulatory applications, complex terrain models will not always have
available as much research-grade meteorological data as that gathered at
CCB.  The range of turbulence measurements available at CCB—for example, the
5-minute average and 1-hour average winds and turbulence intensities at
16 locations from the propeller anemometers—might represent a monitoring
program for a critical siting study planned well in advance of the model
application.  However, the CCB data base may yield useful information for
estimating turbulence statistics (such as O  or Cf ) or other
important features that govern flow (such as N(z)) entirely from surface and
low-level measurements.  If such empirical formulae are found and understood
within a sound theoretical framework, perhaps they can be generalized for
testing in full-scale plume-terrain geometries under different meteorological
conditions.  It is therefore suggested that such relationships in the CCB
data base be explored and their possible utility evaluated for routine
operational use in improved complex terrain models.
     As an example of areas in which a hierarchy of modeling approaches may
be studied, consider two major elements of the transport and dispersion
process, plume transport or flow and plume diffusion or spread.  Several
models evaluated in Section 5 use simple empirical terrain adjustments to the
plume height above the ground  to siimilate flow distortion and use the
standard PG coefficient for plume spread.  One of the new models also uses a
simple terrain adjustment but  uses on-site turbulence data instead of the PG
sigmas to estimate plume spread.  The new model therefore represents a step
in the hierarchy toward more refined models that require additional  on-site
data.
                                    233

-------
     A hierarchy of approaches to the flow and diffusion, components of a
complex terrain air quality dispersion model is suggested below.  We do not
want to imply, however, that the full hierarchy would have to be pursued to
develop an adequate complex terrain model.

     •    Flow Module Component

     1)   Empirical terrain adjustment:  An empirical terrain correction
          factor is incorporated into a straight-line Gaussian air quality
          model.   (The "half-height" correction is an example.)
     2)   Simple potential flow:  The flow is assumed to be inviscid and
          stratification is ignored.  Potential flow theory is used to
          calculate the flow around a terrain feature.
     3)   Stratification adjustment to potential flow:  An empirical
          adjustment is made to potential flow to ensure that streamline
          deflections become more horizontal with increasing stratification.
          For small stratification, the adjustment factor becomes inoperative.
     4)   Linearized inviscid flow:  The flow is assumed to be inviscid, but
          density  stratification is included.  The resulting momentum
          equation may be  solved if it is assumed that  the hill is  so  small
          that  the boundary condition  for vertical velocity may be  applied at
          the surface of the plain  (z  = 0) rather than  at the hill's surface
          (z -  z(x,y)).  In principle, this approximation allows  the flow
          field to be computed  for  arbitrary hill shapes.
     5)   Numerical solutions:   In  this approach, the momentum equation is
          solved by numerical methods.  Turbulence is modeled with  any one of
          the several approximations available.

     •   Dispersion Module  Component

     1)   Sigma curves:   Here,  the  plume  spread  is estimated with stability
          classification schemes.   It  is  also  assumed  that  the  hill does not
          affect turbulence.
                                   234

-------
2)   Turbulence data:  Again, turbulence is assumed to be unaffected by
     the hill;  however, the sigmas are estimated from measurements of
     turbulence intensity.
3)   Terrain-modified sigmas:  Turbulence intensities over the hill are
     modified by empirical factors based on simple theories (such as
     rapid distortion theorjr) or from turbulence data from the tower on
     the butte.
4)   Turbulence models:  Here, the evolution of turbulence is estimated
     from models of turbulence.  An example of this would be the k-e
     model suggested by Launder and Spalding (1972).
                                235

-------
                                  REFERENCES
 Bass,  A. 1980.  Towing Tank Studies in Support of Field Experiments at
      Cinder Cone Butte, Idaho.  Phase II:  Plume Behavior with Froude Number
     and Incident Wind Direction.  Environmental Research and Technology
      Inc., Concord, MA.

 Bass,  A., D.G. Strimaitis, and B.A. Egan 1981.  Potential Flow Model
     for Gaussian Plume Interaction with Simple Terrain Features.
     EPA-600/54-81-008.  U.S. Environmental Protection Agency, Research
     Triangle Park, NC.

 Box, G.E.P.,  W.G. Hunter,  and J.S.  Hunter 1978.  Statistics for
     Experimenters:  An Introduction to Design, Data Analysis, and Model
     Building.New York:John Wiley & Sons.
Budney,  L.J.  1977.   Guidelines for Air Quality Maintenance Planning
     and Analysis.   Volume 10 (revised):   Procedures for Evaluating Air
     Quality  Impact  of  New Stationary Sources.  EPA-450/4-77-001 (OAQPS
     No.  1.2-029R).   U.S.  Environmental Protection Agency,  Research Triangle
     Park, NC.

Burt, E.W. 1977.  Valley Model User's Guide.   EPA-450/2-77-018.
     U.S. Environmental Protection Agency,  Research Triangle  Park,  NC.

Csanady,  G.T. 1973.   Turbulent Diffusion  in the Environment.
     D. Reidel, Dordrecht-Holland.

Drazin,  P.G. 1961..   On the Steady Flow of  a  Fluid of  Variable Density
     Past an Obstacle.  Tellus 13:   239-251.

Egan, B.A. 1975.  Turbulent Diffusion in  Complex Terrain.   Lectures  on
     Air  Pollution and Environmental  Impact Analyses.  American
     Meteorological Society, Boston,  MA.

Fox, D.G. 1981.  Judging Air Quality  Model  Performance.  A  Summary of
     the AMS Workshop on Dispersion Model Performance, Woods Hole, MA,
     September 1980.  AMS Bulletin  62;  599-609.

Holzworth, G.C. 1980.  The EPA Program  for Dispersion Model
     Development for Sources in Complex Terrain.   Second Joint Conference on
     Applications of Air Pollution Meteorology, New Orleans, LA.  American
     Meteorological Society, Boston, MA.
                                     236

-------
Horst, T.W. 1973.  Corrections for Response Errors in a Three-
     Component Propeller Anemometer.  J. Appl. Meteorol. 12; 716-725.

Hovind, E.L., M.W. Edelstein, and V.C. Sutherland 1979.  Workshop on
     Atmospheric Dispersion Models in Complex Terrain.  EPA-600/9-79-041.
     U.S. Environmental Protection Agency, Research Triangle Park, NC.

Hunt, J.C.R. and R.J. Mulhearn 1973.  Turbulent Dispersion from
     Sources near Two-Dimensional Obstacles.  J. Fluid Mech. 61; 245-274.

Hunt, J.C.R. and J.S. Puttock, and W.H. Snyder 1979.  Turbulent
     Diffusion from a Point Source in Stratified and Neutral Flows around a
     Three-Dimensional Hill (Part I - Diffusion Equation Analysis).  Atmos.
     Environ. 13: 1227-1239.

Hunt, J.C.R. and W.H. Snyder 1978.  Flow Structure and Turbulent
     Diffusion around a Three-Dimensional Hill. (Part II - Surface
     Concentrations Due to Upstream Sources - unpublished manuscript).

Hunt, J.C.R. and W.H. Snyder 1980.  Experiments on Stably and
     Neutrally Stratified Flow over a Model Three-Dimensional Hill.
     J. Fluid Mech. 96; 671-704.

Isaacs, R.G., A. Bass, and B.A. Egan 1979.  Application of Potential
     Flow Theory to a Gaussian Point Source Diffusion Model in Complex
     Terrain.  Fourth Symposium on Turbulence, Diffusion, and Air Pollution,
     Reno, NV.  American Meteorological Society, Boston, MA.

Izumi, Y., Barad, M.L. 1970.  Wind Speeds as Measured by Cup and Sonic
     Anemometers and Influenced by Tower Structure.  J. Appl. Meteorol.
     £: 851-6.

Launder, B.E. and D.B. Spaulding 1972.  Lectures in Mathematical
     Models of Turbulence.  New York:  Academic Press.

Maggs, R.J., P.L. Joynes, A.J. Davies, and  J.E. Lovelock 1971.  The
     Electron-Capture Detector - A New Mode of Operation.  Anal. Chem. 43;
     1966-1971.

Milne-Thompson,  L.M. 1968.  Theoretical Hydrodynamics.  New York:  The
     MacMillan  Company.

Papoulis, A. 1965.   Probability, Random Variables,  and  Stochastic
      Processes.   New York: McGraw Hill Book Company

Snyder,  W.H. 1980a.  Towing  Tank Studies  in Support  of  Field
     Experiments at  Cinder Cone  Butte, Idaho.   Phase  III; Verification of
     Formula for Prediction  of Dividing Streamline  Height.  U.S.
     Environmental  Protection Agency,  Research Triangle Park, NC.
                                   237

-------
Snyder, W.H. 1980b.  Towing Tank Studies in Support of Field
     Experiments at Cinder Cone Butte, Idaho.  Phase I: Influence of Hill on
     Wind Field at the Meteorological Tower Site.  U.S. Environmental
     Protection Agency, Research Triangle Park, NC.

Strimaitis, D.G., J.S. Scire, and A. Bass 1981.  COMPLEX/PFM.  Air Quality
     Model User's Guide.  Final Draft Report, EPA Contract No. 68-02-2759.
     Environmental Research & Technology, Inc., Concord, MA.

Van Ulden, A.P. 1978.  Simple Estimates for Vertical Diffusion From
     Sources near the Ground.  Atmos. Environ. 12; 2125-2129.

Yanskey, G.R., E.H. Markee, Jr., and A.P. Richter 1966.  Climatography
     of the National Reactor Testing Station.  Report  IDO-12048.
     U.S. Atomic Energy Commission.
                                   238

-------
                   APPENDIX A



SUMMARY OF TRACER DATA ANALYZED FOR TESTS 201-218
                        239

-------
   TABLE A-l.   CASE 201  (10/16/80 - 1700-2500)
No. 1—Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL

Hour
1
2
3
4
5
6
7
8
TOTAL
SFg CF-^Br
11
11
3
13
8
11
10
6
73
TABLE A-2. CASE 202
No. 1-Hour Ave Samples
SF6 CF_3l£
14
19
24
23
23
22
24
20
169
SJ.6
70
82
39
54
31
14
2
0
292
(10/17/80 -
No. 10-Min
SF6
113
136
56
46
21
23
9
0
404
CFjjBr








1700-2500)
Ave Samples
CF3Br






•

                                                     Total

                                                       81
                                                       93
                                                       42
                                                       57
                                                       49
                                                       25
                                                       12
                                                      	6
                                                      365
                                                     Total

                                                      127
                                                      155
                                                       80
                                                       69
                                                       44
                                                       45
                                                       33
                                                       20
                                                      573
                        240

-------
TABLE A-3.   CASE 203 (10/20/80 - 0000-0800)
Hour
1
2
3
4
5
6
7
8
TOTAL
Hour
1
2
3
4
5
6
7
8
TOTAL
No. 1-Hour Ave Samples
SFg CF3Br
1
21
20
2
9
7
3
16
79
'TABLE A^. CASE 204
No. 1-Hour Ave Samples
SF6 CF3Br
32
33
12
26
29
28
32
30
222
No. 10-Min Ave Samples
57
67
49
29
55
64
49
70
440
(10/21/80 - 0000-0800)
No. 10-Min Ave Samples
SFfc CF3Br
53
66
47
61
51
72
74
83
507
                                                   Total

                                                     58
                                                     88
                                                     69
                                                     31
                                                     64
                                                     71
                                                     52
                                                     86
                                                    519
                                                   Total

                                                     85
                                                     99
                                                     59
                                                     87
                                                     80
                                                    100
                                                    106
                                                    113
                                                    729
                     241

-------
   TABLE A-5.    CASE 205 (10/23/80 - 0000-0800)
Hour
1
2
3
4
5
6
7
8
TOTAL
No. 1-Hour Ave Samples
SF6 CF3Br
20
12
29
31
33
35
33
32
225
No. 10-Min Ave Samples
SF6 CF3Br
6
11
41
78
69
70
69
78
422
Total
26
23
70
109
102
105
102
110
647
   TABLE A-6.   CASE 206  (10/24/80 - 0000-0800)
No. 1—Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6 CF3Br
1
33
34
34
30
29
31
36
228
SF6 CF3I
11
78
62
58
58
57
62
60
446
Jr Tota]
12
111
96
92
88
86
93
96
674
                       242

-------
   TABLE A-7.   CASE 207  (10/25/80 - 0000-0800)
No. 1-Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL

SF6
2
31
30
25
2
3
30
27
150
TABLE A-8
CF3Br







CASE 208
No. 1-Hour Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
15
15
28
33
4
35
3
40
173
CF3Br
2
2
11
15
1
17
0
16
64
SF.6
5
65
55
75
63
66
72
68
469
(10/27/80 -
No. 10-Min
Si6
63
72
69
73
38
60
19
67
461
GF3Br








1700-2500)
Ave Samples
CF3Br
6
14
16
21
15
28
14
29
143
                                                     Total

                                                        7
                                                       96
                                                       85
                                                       100
                                                       65
                                                       69
                                                       102
                                                       95
                                                       619
                                                     Total

                                                       86
                                                      103
                                                      124
                                                      142
                                                       58
                                                      140 •
                                                       36
                                                      152
                                                      841
                        243

-------
   TABLE A-9.   CASE  209  (10/28/80 -  1700-2500)
No. 1-Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SFfi CF3E
L 	 n i- n — —* —
46
49
48
1
3
3
48
42
240
•T SFft CF-^Br
78
65
78
2
5
6
65
69
368
Total
124
114
126
3
8
9
113
111
608
   TABLE  A-10.   CASE 210  (10/30/80  -  0000-0800)
No.  1-Hour  Ave Samples
 No.  10-Min  Ave  Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF.6
39
31
42
35
3
43
43
15
251
CF3Br
9
15
22
15
1
22
19
6
109
SF6
73
83
60
74
23
84
65
9
471
CF3Br
11
17
15
13
0
15
16
2
89
TotaJ
132
146
139
137
27
164
143
32
920
                        244

-------
           TABLE A-ll.  CASE  211 (10/31/80 - 0000-0800)
        No. 1-Hour Ave Samples
                           No.  10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
40
35
31
36
42
34
34
39
291
CF3Br
20'
18
17
19 -"
21
16
20
18
149
SF6
90
70
63
76
82
78
72
65
596
CEjBr
26
13
4
11
5
4
8
10
81
Total
176
136
115
142
150
132
134
132
1,117
           TABLE A-12.  CASE 212 (11/2/80 - 1700-2500)
No. 1-Hour Ave Samples
                                   No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
11
10
17
1
8
18
20
_JL
86
S£6 CF3*
37
34
25
0
3
42
53
8
202
5r Tota!
48
44
42
1
11
60
73
9
288
                                245

-------
   TABLE A-13.  CASE 213 (11/4/80 - 0000-0800)
No. 1-Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL

SF6
3
3
4
29
43
47
42
45
216
TABLE A- 14
CF-^Br
1
1
2
10
13
12
10
13
62
. CASE 214
No. 1-Hour Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
0
26
38
36
42
7
41
43
233
CFjBr
0
8
11
9
3
1
15
14
61
SF6
4
2
0
41
84
75
82
64
352
(11/5/80
CF^Br
0
0
0
27
28
9
15
14
93
- 0200-1000)
No. 10-Min Ave Samples
SF6
0
81
80
65
75
0
89
88
478
CF3Br
0
32
35
36
24
0
33
34
194
                                                     Total

                                                        8
                                                        6
                                                        6
                                                      107
                                                      168
                                                      143
                                                      149
                                                      136
                                                      723
                                                     Total

                                                        0
                                                      147
                                                      164
                                                      146
                                                      144
                                                        8
                                                      178
                                                      179
                                                      966
                        246

-------
   TABLE A-15.  CASE 215  (11/6/80 - 0000-0800)
No. 1-Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
45
47
43
50
46
46
1
0
278
TABLE A-16.
CFjjBr
9
11
11
2
16
15
0
0
64
p A C T7 O 1 A
, V^r\Oi-j «£JLQ
No. 1-Hour Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
52
47
54
48
57
51
53
6
368
CF3Br
15
14
14
11
15
13
14
2
98
S£6
83
94
96
103
97
94
0
0
567
(11/9/80 -
CF^Br
75
56
53
0
80
77
0
0
341
0000-0800)
No. 10-Min Ave Samples
SFfi
94
97
89
92
103
107
105
0
693
CF3Br
16
14
30
28
34
26
19
0
167
                                                     Total

                                                      212
                                                      208
                                                      203
                                                      155
                                                      239
                                                      232
                                                        1
                                                        0
                                                    1,250
                                                     Total

                                                      177
                                                      172
                                                      187
                                                      179
                                                      209
                                                      197
                                                      191
                                                    	14
                                                    1,326
                       247

-------
   TABLE A-17.  CASE 217  (11/10/80 - 0200-1000)
No. 1-Hour Ave Samples
No. 10-Min Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
50
50
52
1
48
45
49
44
339
TABLE A-18
CF3Br
8
10
8
0
15
15
21
18
95
. CASE 218
No. 1-Hour Ave Samples
Hour
1
2
3
4
5
6
7
8
TOTAL
SF6
50
45
44
50
49
44
51
49
382
CF3Br
6
12
7
8
13
7
9
12
74
SF6
96
95
89
5
97
97
102
83
664
(11/12/80
CFjBr
0
0
5
0
15
24
26
18
88
- 0200-1000)
Total
154
155
154
6
175
181
198
163
1,186
No. 10-Min Ave Samples
SF6
65
95
92
105
103
95
87
71
713
CF3Br
10
21
30
31
32
26
9
10
169
Total
131
173
173
194
197
172
156
142
1,338
                        248

-------
             APPENDIX B
LABORATORY SIMULATION OF STABLE PLUME
  DISPERSION OVER CINDER CONE BUTTE
                 249

-------
                 LABORATORY SIMULATION OF  STABLE PLUME

                    DISPERSION  OVER  CINDER  CONE BUTTE



                       Comparison with Field Data
                                   by
                           William H. Snyder*
                                  and
                         Robert E. Lawson, Jr.*
                   Meteorology and Assessment Division
               Environmental Sciences Research Laboratory
                  U.S. Environmental Protection Agency
                   Research Triangle Park, NC  27711
                                 May 1981
*0n assignment from National Oceanic and Atmospheric Administration,
 U.S. Department of Commerce.
                                   250

-------
                                  INTRODUCTION

     The  purpose  of  this  series of  experiments was  to duplicate,  in the labora-
 tory,  the field experiments  performed by Environmental Research and Technology,
 Inc. (ERT) at Cinder Cone Butte,  Idaho.  In particular, one hour  (0500-0600)
 of case 206 was modeled.  As case 206 was representative of very  stable atmo-
 spheric conditions, the Fluid Modeling Facility towing tank was selected as
 the proper facility for these experiments.  Measurements made during the towing
 tank experiments  included ground level concentration, vertical distributions of
 concentration at  selected points, plume dispersion  in the absence of the hill,
 and visual observations of plume characteristics and trajectories.  In the
 following pages,  the conduct of this study is described (not necessarily in
 chronological  order)  along with some observations in regard to the correlation
of field and laboratory data.
                                     251

-------
                         SUMMARY OF FIELD OBSERVATIONS
Meteorological Data
     The field meteorological data has been summarized in a separate data report
(Cinder Cone Butte Meteorological Data, Lawson, March 1981), but there are seve-
ral points of interest which require further explanation.  A considerable portion
of the meteorological data was missing due to failure of the instruments or data
collection system.  At the 40 m-level  (which is the level nearest the source
height), only the westerly component of wind speed was available.  This was over-
come to some extent by assuming  a wind direction of 122°.  The southerly wind
component and hence the mean wind speed were then calculated.  Since no informa-
tion was available to indicate the distribution of wind direction at this level,
the frequency distribution of wind directions at the  source  height was assumed
to be  the same  as that at the 80 m-level.  Where temperature data was missing,
it was possible in some cases to interpolate between  data  for the previous
time  period  and data  for  the following time period  in order  to obtain a  reason-
able  estimate  for the missing data point.  The  values of HC  reported by  ERT and
 summarized  in  the above mentioned report  were  revised using  the  estimated wind
 speeds at the  40 m-level  and some interpolated  temperatures. This  resulted
 in an increase in the average  value  of HC from about 34 m  to about  41 m.
 Figures 1  and  2 show the  mean  wind speed  and  temperature profiles for  the  one
 hour period.  Table 1 provides  a listing  of the newly computed  values  of HC  for
 each 5-minute period within the hour.  Figure 3 shows the  variation of wind
 direction at the 80 m-level  during the hour.   Note the slight shift in wind
 direction during the hour.   The mean wind direction  (derived from the mean
 westerly and southerly wind speeds) is 122.3°.  In Figure 4, an admittedly
 crude attempt was made to determine the frequency distribution of wind direction.
 As noted, this distribution is  for the 80 m-level.  Although the number of data
 points used to form this distribution was small, the bimodality of the distri-
 bution is apparent, with the main peak occurring around 121° and a secondary
 one near 125.5°.  Similar plots were  produced for HC as shown in Figures 5 and
 6.  There appears to be  no  systematic trend in HC and the distribution shows a
 single peak around 41 m.
                                       252

-------
     No analysis of the remaining meteorological tower data was attempted as
most of the data was reported as missing.  The lower-level winds, as indicated
by the instruments at the 2 and 10 m elevations, appeared to be decoupled
from the upper level winds.

Concentration Data

     Field concentration data for case 206 were acquired using sulfur hexa-   ,
fluoride (SFg) as a tracer source, the concentrations being reported in parts
per trillion.  The SFg was released at a rate of 0.063 grams/second from a
height of 35 m.  The source was reportedly located at 122°/597 m from the hill
center but examination of photographs of the source and maps of the road on
which the source was known to be located indicated a more likely position to
be 124.6°/597 m.  This alteration of the source coordinates was supported by
ERT.
     As both the  source  height  and meteorological tower data were referenced
to local ground level, these  heights were adjusted to reference all measure-
ments  to the base of the hill.  Careful  examination of the  topographic maps
showed the met  tower to  be located at an elevation of 941 m (3087 ft), while
the  source was  located at an  elevation of 939 m (3081 ft).  The met tower was
thus  3.9 m and  the  source 5.8 m lower than  the  base of the  hill.  This then
means  that the  source  height  relative to the  base of the  hill  was 29.2 ms and
all  H  values  calculated from met  tower  data  should be reduced by 3.9 m  in
order to maintain comparability relative to the hill.  Although  the source
 height used  in  the  model is  shown  as  31  m,  the  1.8 m difference  was deemed
 insignificant  in  relation to  the errors  in  estimating elevations  from the
 topographic  maps.
      Figure  7  shows the  one-hour average concentration distribution over the
 hill.  The wind direction indicated on  this plot is  from 122°.  The distribu-
 tion is  seen to favor the northeast side of the hill with the  axis  of the
 distribution on a southeast-northwest line.  The maximum concentration  is
 located  in the east draw near the 30 m elevation contour.  There is a  rather
 tight concentration gradient along the southwest side  of the distribution  with
 the tightest gradient being directly between  the two peaks.
      Although not plotted, there were several 10-minute average concentration

                                     253

-------
samples available.  These samples were used to form one-hour averages for com-
parison with the data plotted in Figure 7.  The resulting one-hour averages
were in good agreement with data from the one-hour average samplers.
     Sampler location 60X (FMF sample port 34) showed an anomalously low
value (15 ppt) and is believed to be in error.

Slides
     Several 35 mm slides of the case 206 field experiments were available for
analysis.  While  it was not possible to obtain quantitative data from these
slides, several qualitative observations were made.  The plume was initially
observed to split with a portion traveling around the north side of the hill
and the remainder traveling through the draw and over the hill.  Approximately
half-way through  the  hour the plume trajectory was directly through the draw.
There was some evidence that the plume was being downwashed on the upwind  side
of the hill.  The slides indicate that the  area of  peak surface concentration
may have been at  a  somewhat greater elevation  («\, 50  m contour) than  indicated
by the concentration  data.  The  fact  that the  plume  was  initially observed to
split  around  the  north butte and later traveled directly through the  draw  is
in apparent contradiction to the reported 80  m wind  directions.   It  should
be noted that the travel time  from  the source to the hill was  on the  order of
6 minutes  and this  must  be  taken into account when  comparing observations  with
met  data.
      The  slides  were also  used to  visually  confirm the  location and release
 height of the source.
                                      254

-------
                           EXPERIMENTAL DETAILS

Model Speci f i ca11ons

     The model was constructed of acrylic plastic by a vacuum forming tech-
nique.  The nominal model scale was 1:640; after fabrication, the model  scale
was determined to be 1:647 horizontal  and 1:694 vertical  (model  height =
14.4 cm).  The model was mounted on a  circular platform (1.7 m dia.)  which
was inserted into a circular, recessed cutout in a 2.5 m square baseplate to
allow for rotation to various wind directions.  The baseplate provided an
upstream fetch of about 0.7 m and a downstream fetch of about 0.2 m;  its
width was 3 cm less than the width of the towing tank (2.5 m).  Both  baseplate
and model were covered with small gravel (average diameter on the order of
2 mm) in order to simulate surface roughness.  The gravel  size was chosen by
application of Jensen's criterion (Snyder, 1981),
                                om
                                op
                                         n
With a prototype z   ^ 5-8 cm, then z
where e is the grain size, e
U*z /v > 2.5.  Assuming U^/U
         * 0.07-0.12 mm, and since z
2-3 mm.  To be aerodynamica'lly rough,
                                                                        /30,
                                0.045, and a tow speed of 10 cm/sec, the
value of U*z /v is on the order of 0.5.  In spite of this small  value of
roughness Reynolds number., the boundary layer on the baseplate approaching
the hill was visually observed to be turbulent, albeit quite thin (^ 2 cm).
Under the strongly stratified flows, the surface flow on the hill itself was
not observed to be turbulent.
     Sample ports were located on the model at the same locations as in the
field study although port identification numbers were altered for more efficient
data processing.  The ports projected approximately 2 mm above the surface
                                     255

-------
roughness, except for the mast mounted samplers, which were scaled in height
in proportion to their field counterparts.  The ports were fabricated from
0.24 cm O.D. brass tubing with equal lengths of vinyl tubing leading from the
ports to the sampling system.
     The source was simulated with a 0.32 cm I.D. brass tube with the upper
portion bent over such that the tracer dye was released parallel to the
approach flow.
     The tracer dye was a mixture of concentrated blue food dye (Warner
Oenkinson No. 393), towing-tank water drawn through the stack, and small
amounts of either saturated salt water or alcohol.  The diluent (salt water
or alcohol and towing-tank water) was mixed in such proportions that the
final mixture - 1 part concentrated dye with 10 parts diluent - was neutrally
buoyant.  The emission rate of tracer dye was nominally 190 cc/min, the exact
rate being determined each tow.
     0, 30,  60, and 90 m  contour lines were added to  the model  to aid in
Visualization and photography.  Index marks were placed around  the periphery
to aid  in aligning both source and  model  in relation  to the desired wind
direction.
Stratification  of Towin£ Tajik

     The  water  channel was  stratified  using layers  of salt water  as  described
by Hunt,  et al_ (1978).   Linear stratification  was used to  simulate  the  potential
temperature profile  derived  from Figure  2.  The sharp gradient  near the
surface was ignored  as  it translates  to  a layer of  only 1.4 cm  depth and
cannot, for practical  reasons, be  maintained  in the water channel.   This appears
justified because,  as  mentioned  earlier, the  surface winds in the field were
decoupled from the higher level  winds.
      As successive experiments lead to erosion of the density profile near
 the surface, it was  necessary after each two  to three tows to siphon 3 to 6
 centimeters of water from the surface layer and to  add the same volume of
 saturated salt water to the bottom.  This had the effect of restoring the
 original  linear profile to the surface.
      The dye tracer used as the effluent also discolored the water after two
 to three tows; hence, in conjunction with the siphoning process, the water was
 chlorinated to bleach out the residual dye.  The chlorine treatment was followed
                                      256

-------
by dechlorination with sodium thlosulfate to insure that tracer samples were not
also bleached out.
     The density profile and water quality were checked each day prior to
initiating a series of tows.  A typical density profile is shown as Figure 8.

Photography

     Photographic records of each test were made using 35 mm cameras.  One
camera was used to photograph a plan view of the model while a second was used
to record a side view.  In addition to these still photos, 16 mm movies were
made of each tow.  A polaroid-back Graflex camera was used to provide black-
and-white photos for immediate evaluation and comparison.  A list of available
photographic records is seen in Table 2,

Colorimetric Technique for Concentration Measurements

     The technique used for measuring concentrations is conceptually very
simple.  Samples were withdrawn through the sample ports via a vacuum system
which deposited each port sample in a separate test tube.  The contents of
each tube were then analyzed for concentration using a Brinkman PC-600 color-
imeter.  The PC-600 utilizes a fiber-optic probe with fixed path length which
is simply dipped  into the contents of each tube.  The output of the instrument
is a voltage which is related to the opacity of the solution being tested.  This
voltage is sampled by computer and converted to concentration in percent dye.
The conversion from voltage to'concentration utilizes a calibration curve
formed by recording the output voltage vs. concentration for 12 "standards"
which consist of  accurately known dilutions of the same dye used for the tracer
source.  A "Beer's Law" type of curve  is then best-fit to the standards for
use in converting the voltage from the unknown sample into a dye concentration.
Although the instrument required some  care in use, frequent checks of the
calibration showed excellent repeatability.  A typical calibration curve is
shown in Figure 9.
                                     257

-------
Procedure Followed

     The sequence of events leading to a daily series of tows was as  follows;


     1.  Measure density profile.

     2.  If density profile is not linear, then siphon from surface
         to restore the profile and add an equal volume of brine
         at the bottom of the channel to restore the original depth.

     3.  Withdraw a sufficient quantity of water through the stack
         to mix the dye tracer.  Mix the dye, diluent water, and
         alcohol such that the effluent specific gravity is the
         same as that.at the source height.

     4.  Use program IMPINGE to determine, from the density
         profile, the tow speed appropriate to the desired HC.

     5.  Place one drop of sodium thiosulfate solution in each
         sample test tube to insure that any residual chlorine
         does not affect the sample concentration.

     6.  Check and/or adjust the source flow rate and the
         sample flow rate.  Check vacuum seals on sampling
         device.

     7.  Check that all cameras and lights are ready - also
         check alignment of stack vs. wind direction.

     8.  Set desired tow speed on carriage controller and
         check timer used to monitor actual tow speed.

     9.  Initiate tow, monitoring source flow rate and sample
         time during the tow - sampling is initiated only
         after the starting transient has decayed and conditions
         are stabilized.

     10.  After the tow, record all pertinent data immediately,
         then remove the sample  test tubes and proceed with
         analysis of samples.

     11.  At the end of each day's experiments, or more frequently
         if necessary, chlorinate the water to  remove the  residual
         dye - this must be followed by dechlorination and a check
         of the density profile.
 A total  of 41  tows  was  made.   A  summary list  showing  all  tests conducted is

 provided in Table 3 along with remarks  on  visual  observations made after each

 tow.
                                     258

-------
Observations of Erratic
                                    ti  PUni
     The only erratic behavior observed during the entire series of tests was
a tendency for the plume to be deflected slightly toward the north side of the
hill during the last 1/3 of the tow.  This was not observed during the tests
with the flat baseplate9 rather some slight horizontal meandering of the plume
was observed.  No tests were conducted to investigate this phenomenon as it
did not appear to be significantly affecting the concentration measurements.

Flat Baseplate Measurements

     The last nine tows were conducted with the model hill removed and a flat
disk inserted in its place.  The disk was coated with gravel of the same size
as  that on the model and was equipped with a cross-rake of sampling ports.
The rake was mounted at three locations during the experiments , corresponding
to  model distances of 48.5, 91 .4, and 134.2 cm and full-scale distances
of  314, 591, and 868 m downwind from the source.  Samples were drawn from the
cross-rake using the vacuum sampling system and similarly analyzed for dye
concentration.  The resulting measurements provided  an  indication of concentra-
tion in  the  absence of the hill and estimates of  the vertical and horizontal
spread of the plume.

Conversion of Model Concentrations  to  Field Concentrations

     Model concentrations  were  recorded  in percent of dye  by volume, these
 values  then  being  converted  to  nonditnenslonal form by, the. foil owing equation:

                                    x  = CUH2  s
                                         Q

 where  x is  the  nondlmensional  concentration,  U  is the tow speed,  H  is  the
 hill  height, and Q is  the effluent flow rate.   These nonditnensional  concentra-
 tion values  were then  used to convert the model  concentrations to their field
 equivalents  as  follows:

                            xmodel   =  xfield 9
                                      259

-------
                so
                and
Cf =
Field concentrations were reported in parts-per-trillion (ppt)  of SFg which
has a density of 6.5 grams/liter at 20°C and 760 mm Hg.   The height of  the
hill, H-, was TOO m, and the wind speed at the source height was 1.3 m/s.
Making the substitutions,
                   C(ppt) =
                               (.063 gm/s)(l
                                                        12
                           ppt)x
                                   (6.5 gm/A)(1.3 m/s)(100 m)2
                           = 746 X.


 Thus,  conversion  of nondimensional model  concentrations to equivalent field
 concentrations  in ppt is  simply a  matter  of multiplying by 746.  Note that
 the conversion  factor is  inversely proportional  to wind speed and,  since the
 wind speed data near the  source height was missing,  this  value was  estimated
 from the wind profile as  was previously discussed.
                                      260

-------
                    PRESENTATION AND DISCUSSION OF RESULTS
Dispersion in the Absence pf_ the.
     Nine tows were made to characterize plume dispersion in the absence of
the hill.  During each tows lateral and vertical concentration profiles were
measured in one cross-section (one downwind distance).  Tests were conducted
at three towing speeds, corresponding to H  values of 24, 44 and 60 ms and
                                          C»
lateral and vertical concentration profiles were measured at downwind distances
corresponding to 314, 591, and 868 m.  Typical profiles are shown in Figures
10 and 11.  These results (as well as the remainder of data to be presented) are
displayed in terms of full scale equivalents.  "Best-fit" Gaussian profiles are
also displayed; it may be observed that the concentration distributions are
very close to Gaussian in shape.
     Standard deviations of horizontal and vertical plume widths are shown in
Figure 12.  As the average effluent flow speed was 40 cm/s, the effluent was
emitted as a turbulent jet; the jet was visually observed to expand rapidly
initially both in the vertical and horizontal directions.  Horizontal growth
continued at a slower rate, but vertical growth approached zero, with a hint
of plume collapse (negative growth) further downwind.  These qualitative
observations are substantiated by the growth curves displayed in Figure 12.
Neither horizontal nor vertical plume widths appear to be strongly affected by
the towing speed.
     Figure 13 shows the variation of plume centerline concentration versus
downwind distance.  Table 4 summarizes the plume statistics in the absence of
the hill.
     Let us address the correspondence between  these  laboratory measurements
in the absence of the hill and the field plume  behavior.  The field plume was
generated by a thermal fogger suspended from a  crane.  Because of the  rapid
mixing of the jet in the wake of  the fogger, and because the fogger was free
to rotate about a vertical axis,  ERT  (Strimaitis,  1981)  has estimated  virtual
                                      261

-------
plume widths of a   * 2 m and a   = 3 m.   When the field plume was observed
"missing" the hill under strongly stable conditions, it was frequently described
as looking like a "piece of yarn", i.e.,  a long, reasonably straight plume with
slightly ruffled edges and near-zero growth.  Hence, for short time periods
(*> 5 min), the plume dimensions may be very roughly estimated as az = 5 m and
a  s 15 m.  The laboratory values shown in Table 4 and Figure 12 are comparable
to these estimated, short-term field values.
     On the other hand, plume meander, as was immediately apparent in the field,
was obviously lacking in the laboratory simulations.  Also lacking were the  low
frequency fluctuations in wind speed (or H ).  Since adequate field measurements
                                          \f
of plume dimensions and concentrations as functions of averaging time were un-
available at this time, it was not possible to draw firmer conclusions concern-
ing the relationship between laboratory and field measurements of plume behavior
in the absence of the hill.  However, some elementary attempts at simulating
the fluctuating wind speed and direction in the presence of the hill were made
(see next section).

Concentration Patterns on the Butte

     A total of 32 tows with the model of Cinder Cone Butte in place was made,
representing different source locations (by mistake), wind directions and wind
speeds.  A summary of all tows is given in Table 3.  A map of port numbers is
provided in Figure 14 for later reference and a cross-reference list to ERT
sampler locations is given in Table 5.  In Figure 14, the precise port location
is the lower left corner of the dot matrix from which the number is configured.
     The first 9 tows were preliminary in nature; only the highlights will be
described here.
     Figure 15 shows top and side views of the plume diffusing over the hill
during Tow 8.  The source height Hg was 31 m, the dividing streamline
height H  was 38 m, and the wind direction was 122°.  Under these conditions,
        \f
the flow was observed to be limited in vertical travel such that the plume
passed around and between the two peaks, but did not surmount them.
     Tows 1 and 2 were done approximately 2 hours apart under ostensibly
identical conditions for the purpose of testing repeatability.  The two con-
centration distributions may be compared by examination of Figure 16.  The
                                      262

-------
one-digit numbers on these maps are relative concentrations (same scaling
factor on both maps).  The decimal points associated with the numbers are
located at the sampler locations.  Care should be exercised in reading the
maps, i.e., if the number is to the left of the decimal point, the relative
concentration is a whole number; if to the right, a fractional number.  (These
numbers are truncated, not rounded.)  Also, 100 samples were collected during
each tow.  If no number appears at a port location, it is because a visual
inspection of the contents of the sample collection test tube revealed no
dye, and  the sample  was not analyzed,  if the sample was analyzed and the
relative  concentration was found  to be less than 0.1,  then a 0 appears on the
map  (sampler location is  at the  bottom center of the zero).
     Figure 17 compares the concentrations from the two tows on  a scatter
diagram.   Except  for one  obvious  outlier  (which is unexplained at this point),
concentrations generally  match  to within  10 to 2Q% of  each other without any
obvious bias over the range from 0.02 Cmx to Cmx, and  is considered  excellent
repeatability.   The obvious departures at the  very low concentrations  is most
likely due to  slight secondary flows  in  the towing tank.
     Tows 7  and  8 were  also done for  the purpose of  testing  repeatability,
but in this  case, two  high speed tows  and a twenty-four  hour delay occurred
 between the two; the density  profile  was not  restored  by skimming as was
 usual, so that the two  profiles differed somewhat,  as  shown  in  Figure 18.
 Note that the towing speeds  differed  between  the two tows  (see  Table 3)  such
 that H  was the same,  according to Hunt's formula  (Snyder, 1980):
       \f
                                        V
      The scatter diagram for tows 7 and 8 is shown in Figure 19, where it may
 be observed that the scatter is very much larger than in the previous compar-
 ison.  Variations between the two tows do not appear to have significant bias,
 but are typically factors of 3 to 5 apart.  The conclusion that may be drawn
 from this  test, then,  is that the precise shape of the density profile is
 quite  important in  determining the concentration distribution, i.e., a gross
 characterization of the stability (such as  by specifying HC alone) is clearly
                                     263

-------
not sufficient.
  Figure 20 shows a 3 x 6 matrix of concentration distributions,  covering
all combinations of three wind directions (117°, 122°,  and 127°)  and six
values of HC (24, 31, 38, 44, 49 and 60 m).   Concentration isopleths have
been drawn by eye so that the distributions  can be more readily comprehended.
Several points are to be noted from this figure.  First, at the wind direction
of 122°, as H  increased from 24 to 60 m, the location  of the maximum shifted
from the downwind side of the hill to the top and finally to the upwind side.
The crosswind width of the distributions increased as H  increased,  but the
value of the maximum concentration changed relatively little (less than a
factor of 2).  At H  = 60 m, the maximum surface concentration was located at
                   c
nearly the same elevation as the source.  Second, changes of only ±5° in wind
direction had dramatic effects on the distributions, moving the locations  of
the maximum concentrations from the north skirt of the  hill at a wind direc-
tion of 127°, to the centerline at 122°, then to the south skirt at 117°.
Again, the values of the maximum concentrations changed relatively little  with
changes in H  and/or wind direction, although the values of the maximums
            c
were noticeably less at 127°.  Third, for centerline winds (122°), the shapes
of the distributions change substantially with changes  in H , whereas for  off-
                                                           C
axis winds (117° or 127°), the distributions are, for practical purposes,  indep-
endent of H .  Unfortunately, very few field samplers were located within  the
areas of maximum concentration for the off-axis winds.   During this hour,  only
two samplers were working within the 1600 ppt SFg contour on the south side of
the hill.  Finally, it is noteworthy that the maximum surface concentration was
1/2 to 2/3 of the plume centerline concentration in the absence of the hill
(cf., Figure 13).
     A scatter diagram comparing concentration distributions measured in
three of these tows (11,12, and 13) with field distributions is presented  in
Figure 21.  There is one obviously suspicious field measurement point (port 34;
ERT sampler location 60X; see Figure 14 for sampler location and Figure 7  for
field concentration distribution).  Ignoring that, it is generally apparent
that maximum model concentrations were much higher than maximum field concen-
trations (by factors of 3 to 10) and low model concentrations were much lower
than low field values; there were many ports on the model where zero-concen-
trations were observed, whereas in the field, all the samplers showed at least
a trace concentration.  It is impossible, of course, to show these points
                                     264

-------
properly on the logarithmic scatter diagram of Figure 21; they are Indicated,  .
however, by the hand-drawn points on the bottom of the figure.
     As mentioned earlier, low-frequency fluctuations in wind speed and
direction as observed in the field were obviously lacking in the towing tank.
This is almost certainly the explanation for the discrepancies between the
model and field data of Figure 21,,  The previous series of 18 tows was done in
an attempt to determine whether a superposition of concentration patterns from
tows done at a series of discrete wind speeds (various H 's) and wind directions
                                                        C
could be used to simulate field conditions with continuous distributions of
wind speed and direction.  As mentioned earlier, however* the 40 sn-level winds
were lacking, so that proper choices for particular wind speeds and directions
to simulate and superpose were difficult to make.  The particular choices for
the previous series of tows (122° ±5° and 24 m < HC < 60 m) were made on an
ad hoc basis after studying the field photographs of plume behavior and
available meteorological data at other levels on the tower.
     The first attempt at superposition is shown in Figure 22.  It was con-
structed as the simple arithmetic average of the distributions from each of
the 18 tows.  Figure 23S a scatter plot of resulting model concentrations
versus field concentrations, showed a marked improvement over the previous
single-tow comparisons.  The highest model concentrations here are within a
factor of 2 of the highest field values.  Whereas the low model concentrations
are still lower than the low field values, there were no zero-model-concentra-
tion values.  The indication for improving the correspondence iss therefore,
an even larger series of towss although particular choices to be made for
other wind speeds and/or directions are not immediately obvious.
     Three points on the scatter plot of Figure 23 deserve discussion.  The
two points marked 49 and 61 (port numbers) were the only two operating  field
samplers on the south side of the hill, and both of them indicated quite small
values of concentration.  Evidently the choice of the 117° wind direction was
a poor one; it created the lobe of the concentration distribution around the
south  side of the butte.   In an attempt to improve the correspondence,  the
6 tows  at the 117° wind  direction were eliminated from the superposition; this
process  reduced model concentrations at these two points to only a factor of
2 higher than the observed field  values.  However, it increased nearly  all
remaining concentrations  by approximately 50%; such a simple  solution is
                                    265

-------
therefore not sufficient.
    The point marked 31 on the scatter plot was located at the 25 m elevation,
i.e., 5 m lower than the source; it happens to be the location of the highest
concentration measured during this hour in the field.  This may at first appear
anomalous.  However, Hunt and Venkatram (private communication) have reported
similar observations during other very stable periods.  Hunt has further pos-
tulated as a possible mechanism a vortex roll-up on the windward side of the
hill and has done some preliminary calculations showing that such vortex roll-
up is plausibly due to shear in the approach flow.  Vortex roll-up was not
observed on the windward side of the CCB model, as shear in the approach flow
was absent.  Such vortex roll-up has been observed in the towing tank, however,
on model hills of much steeper slope (Hunt and Snyder, 1980).
    Other combinations and superpositions from this set of 18 tows were
attempted, but the superposition of the entire set (Figures 22 and 23) appeared
to yield the best results.
    Five additional tows were made, 3 at 120° and 2 at 125.5°, so that super-
positions could be made on the basis of the  probability distribution of HC and
the bimodal distribution of wind direction at the 80 m-level  (Figures 6 and 4,
respectively).  Various combinations of distributions including those from these
5 tows were made, using uniform as well as weighted averaging.  None of these
superpositions were as successful as those shown  in Figures 22 and 23.
    Figures 24 and 25  show the variation of  maximum surface concentration with
H   and wind direction, respectively.  No systematic variation of Cmx with HC
is  observed, but there is a definite tendency for the maximum concentration to
peak around a wind direction of 120°.  It  is also to  be noted that the maxi-
mum surface concentration at this wind direction  is approximately equal to
the plume centerline concentration in the  absence of  the  hill.
                                        266

-------
                               CONCLUSIONS
1.  Repeatability of the concentration distributions in the towing tank was
good.  Under ostensibly identical conditions, concentrations can be matched
to within 10 to 20% upon successive tows.

2.  Gross stability classifications are not sufficient for characterizing
concentration distributions.  It appears that the detailed shape of the
density profile is quite important in determining concentrations on a point-
by-point basis.  However, such a gross classification would appear to be
reasonable for predicting the values of maximums as well as ranges of values
of concentration (but not locations).

3.  Surface concentration distributions around the hill are extremely sensi-
tive to changes in wind direction under stable conditions.  In these exper-
iments, 24 m < H, < 60 m, the location of the maximum concentration shifted
                c
through an angle of approximately 60° (looking from the source) with a shift
of only 10° in wind direction.
4.  The value of the maximum surface concentration changed relatively little
with changes in wind direction or wind speed; over the entire range of
24 m £ H  £ 60 m and 117° <_ e <_ 127°, the maximum changed by only a factor
of 3.5.
5.  For "on-axis" wind directions (i.e., plume aimed directly toward hill
center), the location of the maximum surface concentration moved from the lee
side to the windward side as HC increased from 24 to 60 m.  The value of the
maximum surface concentration changed by only a factor of 1.5 over this same
range of Hr.
          v»
                                    267

-------
6.  For "off-axis" wind directions (on the order of ±5°), the locations and
values of the maximum surface concentrations are, for practical  purposes,
Independent of HC.

7.  Because of the absence of low frequency fluctuations In wind speed and
direction in the tank, the concentration distributions observed in the tank
were exceedingly narrow; maximum concentrations were 5 to 10 times larger than
those observed in the field.

8.  An ad hoc attempt was made to simulate the low frequency wind fluctuations
by superposing concentration patterns from tows done at a series of discrete
wind speeds and wind directions.  This attempt was moderately successful in
that 80% of the model concentrations were within a factor of 2.5 of the field
concentrations.  The highest model concentrations were a factor of 2.5 larger
than field values.  The  points where the model showed concentrations lower
than field values were located on the extreme edges of the distributions,
indicating that tows at  very slightly different  wind directions could  have
brought  these  points in-line.

9.  The  ad  hoc attempt was  made  because of  malfunctions  in the measurement
system at  the  40-m level (closest to  plume  elevation),  so  that a  detailed
analysis of  80-m  level winds was made.  Additional  tows  were made on  the basis
of the frequency  distribution  of wind directions at the  80-m level.   Several
superpositions on this  basis yielded  results less  satisfactory  than did  the
ad hoc attempt.   Frequency distributions  of wind speed  and direction  at. plume
 elevation  are evidently essential in  order to improve performance of  the model.

 10.  For "on-axis" winds in the model,  maximum surface concentrations approached
 those at the centerline of the plume in the absence of the hill,  i.e., Cmx =  aCQ,
 where 0.5 <. a <.!.  However, because of the extreme sensitivity of  the location
 of maximum concentration to wind direction, the plume is "smeared"  broadly
 across the hill  surface as the wind direction changes by only a few degrees.
 Hence, short term (-v5 min) in the field may be expected to approach CQ; larger
 term averages H hr) may be expected to be reduced by factors of 5 to 10 (or
 more depending, of course, on the magnitudes of au and OQ).
                                      268

-------
                                REFERENCES
Hunt, J.C.R. and Snyder, W.H., 1980: Experiments on Stably and Neutrally
Stratified Flow over a Model Three-Dimensional Hill, J. Fluid Mech.s v. 96,
pt. 4, p. 671-704.

Hunt, J.C.R., Snyders W.H., and Lawson, R.E. Jr., 1978:  Flow Structure and
Turbulent Diffusion around a Three-Dimensional Hill: Fluid Modeling Study on
Effects of Stratification: Part I:-,Flow Structures Envir. Prot. Agcy. Rpt. No.
EPA 600/4-78-041, Res. Tri. Pk.9 NC.

Snydera W.H., 1980: Towing Tank Studies in Support of Field Experiments at
Cinder Cone Butte, Idaho; Phase III: Verification of Formula for Prediction
of Dividing Streamline Height, Rpt. to Envir. Res. & Tech., Aug. 29S 12p.

Snyder, W.H., 1981: Guideline for Fluid Modeling of Atmospheric Diffusion,
Envir. Prot. Agcy. Rpt. No. EPA-450/4-81-004, Res. Tri. Pk., NC, 200p.

Strimaitis, D.6., 1981: private communication.
                                    269

-------
TABLE 1:  VALUE OF HC DURING EACH 5-MINUTE PERIOD OF THE HOUR 0500-0600
           TIME
           (END)
 FIVE-MINUTE

PERIOD NUMBER
 Hc
(m)
            0505
            0510
            0515
            0520
            0525
            0530
            0535
            0540
            0545
            0550
            0555
            0600
      1
      2
      3
      4
      5
      6
      7
      8
      9
     10
     11
     12
40.
38.
42.
42,
40,
38,
38.8
40.
44.
40.
40.3
40.7
.2
.5
.3
          Average HC = 40.8
  m
                   =  1.7 m
          Note:  H   was calculated assuming a hill height of 100 m.
                 These values are referenced to local ground level.
                                  270

-------
           TABLE 2.  PHOTOGRAPHIC RECORDS AVAILABLE
TYPE OF RECORD
16 mm motion picture film
35 mm color prints
35 mm color prints
Polaroid b & w prints
LOCATION AND EXPERIMENTS RECORDED
    all tows - plan view only
    all tows - plan view
    all tows - side view
    tows 10-41 - plan view only
                              271

-------
TABLE  3.     SCHEDULE  OF  TOWS
                                                                                           DENSITY

                                                                                           PROFILE I
                                                               source at 597 in/122' very
                                                               little dye reaching south
                                                               peak need to check field
                                                               repeat of tow Jl to check
                                                               adjusted source height to
                                                               correct for differences
                                                               In local  around level
                                                               slight roll-up on windward
                                                                side of model  - may be effect
                                                                source location changed to
                                                                ran two high speed tows fc
                                                                JCRH following this  tow
                                                                repeatability check
                                                                effluent released 1sok1nat1cally. 41
                                                       97 4      source location moved to 597 ml   4
                                                                124.6', plume splits around
                                                                north butte       	
                                                                 a little more dye getting
                                                                 plume goes primarily
                                                                 through (over?) the draw
                                                                 very little dye through the
                                                                  saddle - most splits around
                                                                     iged wind direction  to 127
                                                                  ... of plume goes around the
                                                                  north butte  - max * 30 m
                                                                  contour
                                                                  not very different from
                                                                  previous tow
                                                                  Klume doesn't go over hill  -
                                                                  plume very thin at top of
                                                                  hill, not reaching top of
                                                                  masts
                                                                   no plume over the  north peak
                                                                   large wake with uniformly
                                                                   low concentration
                                                                   changed wind direction  to 117
                               272

-------
TABLE 3.  SCHEDULE OF TOWS (continued)
TOW I
DATE
1981
23
4/22
24
4/22
25
4/22
26
4/23
27
4/23
28
4/29
29
4/30
30
5/1
31
5/1
32
5/4
33
5/11
34
5/12
35
5/12
36
37
5/13
38
5/13
39
5/15
40
5/15
41
5/15
FILE * e
CCBRD . degrees
23 117
24 117
25 117
26 117
27 117
28 120
29 120
30 120
31 125.5
32 125.5
Sfci D
11 13 °
37 (z) 0
38 (y)
39 (z) 0
40 (y)
41 (z) 0
42 (y)
43 {z) 0
44 (y)
45 (z) 0
46 (y)
47 (z) 0
48 (y)
49 (z) 0
50 (y)
"s
ni
(cm)
(43S,
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
(4.5)
31
<4.5)
Hc
..<«)
60
(8.64)
24
(3.5)
38
(5.51)
44
(6.4)
49
(7.06)
38
(5.51)
31
(4.5)
31
(4.5)
38
(5.51)
31
(4.5)
24
(3.5)
60
(8.64)
44
(6.4)
24
(3.5)
60
(8.64)
44
(6.4)
24
(3.5) .
60
(8.64)
44
(6.4)
TOM
SPEED
cm/sec
8.49
14.13
11.85
11.33
10.31
12.87_
13.87
13.61
11.86
12.98
14.47
7.89
10.85
15.25
7.87
11.28
14.84
7.49
10.85
EFFLUENT
RATE
cc/n1n
191.9
194.7
193.4
193.7
194.6
194.5
195.1
200.0
195.2
192.6
194.5
198.1
198.2
196.8
196.4
195.9
192.8
194.7
192.5
SAMPLE
TIDE
sec
142.4
100.2
114.4
106.1
119.2
110.9
96.2
99.1
106.3
104.6
105.2
156.3
124.5
95.8
154.8
118.3
97.3
153.0
117.9
DENSITY
REMARKS PROFILE t
	 CCBRS.
plume goes around south side
of hill - large uniform wake
small portion of plume went
over top of Mil
very similar to tow #24 -
slight wisp over draw about
2/3 of way down the channel
mostly around south side -
but, about 2/3 of way down
the channel got some around
north side and draw
very similar to previous tow
some shift about 2/3 of way
down the channel
changed wind direction to 120*
plume splitting around both
peaks similar to higher HC


changed wind direction to
125.5°
plume spreads mostly around
north butte - occasionally
. goes over north butte - get
shift 2/3 of way down channel
model removed and flat base-
plate Installed with cross
rake 48.5 cm from source
observe no- shift of plums
centerllne during the tow

moved cross rake downstream
to 91.4 cm from source
toward end of tow» plume
centerllne wavers a bit

moved cross rake downstream
to 134.2 cm from source
toward end of tow, plume
centerllne wavers a bit
last tow for case 206
53
53
53
55
55
56
58
59
59
60
61
63
63
64
64
64
65
65
65
                273

-------
TABLE 4.  SUMMARY OF FLAT BASEPLATE MEASUREMENTS
X
(m)
313.8
313.8
313.8
591.4
591.4
591.4
868.3
868.3
868.3
Hc
(m)
24
44
60
24
44
60
24
44
60
°z
(m)
4.8
5.0
4.5
4.7
4.0
3.8
4.6
3.8
3.7
oy
(m)
' 7.3
8.7
9.4
11.7
13.4
13.7
11.2
13.7
14.5
Cz
max
(ppt)
25,350
21,026
15,658
19,758
17,894
14,912
21,996
17,074
14,688
cy
max
(ppt)
24,978
20,504
15,881
16,925
14,166
13,719
21,250
14,912
13,644
                        274

-------
TABLE 5.  LOCATION OF SAMPLERS ON CINDER CONE BUTTE
FMF
PORT
i
2
3
4
5
6
7

9
10
11
12
13

15
16
17
IB
19
za
Zl
ZZ
Z3
24
23
Z6
Z7
ZB
23
38
31
32
33
34
35
36
37
38
39
4B

42
43
44
45
46
47
48
43
3B
51
32
33
34
33
36
37
38
33
6B
61
62
63
64
63
66
67
68
69
70
71
72
73
74
73.
76
77
78
79
80
81
82
83
84
83
86
87
88
89
90
31
52
93
94
95
?O
97
98
99
ERT
PORT
37.
37.
37.

37.
37.
37.
37.
37.
37.
37.
37.
37.
34.
31.
31.
31,
31.
31.
31.
Z9,
ZB,
ZB.
27,
Z6,
26,
Z6,
63,
62,
60.
6O,
68
60,
SO,
60.
60,
60.
60.
38,
38
57
57
37
57
57
56
56
56
33
33
55
35
33
34
33
33
39
39
33
39
39
39
33
39
39
33
43
45
43
4B
48
48
48
48
48
30
64
64
65
67
67
67
67
67
67
67
67
67
67
69
69
7B
7B
7D
72
72
73
73
74
01 083
0200E1
83000
84000
05808
85BBO
07083
B988B
1BB0B
11800
12000
20080
26380
10BBB
9000O
.9603O
.07000
.03003
,26000
,83003
.B4B0B
.Z6BBB
. 1 1O00
.03BBB
.03088
. 03B00
.06000
,03000
. B3B3B
. B3B3B
. 84038
.2ZOOO
.230BB
.24BBO
.23083
.26000
.81880
.82000
.08000
.B7OOO
. Z5000
.26880
.96080
. 13000
.30380
.03308
.04008
.85800
.B30BB
. 13B00
.96BBO
. Z6B0B
.90000
.04800
.03000
. 04BOB
.21088
.01000
.BZBBB
.03000
.03000
.07000
. 1Z000
. 17000
. 1B0B8
. Z3BBB
. 243B0
.07080
. 10383
. 1Z0BB
. BZ000
. 03338
.03838
. 07B3O
. 10000
.87830
.83BBO
. 10033
.03000
.01080
.B2BB0
. 84080
.83000
. B6BB3
. 13330
.23000
. 24000
.23000
.26000
.B700B
.26080
.88080
.26008
.rr'jrT
. 2^-yoFi
. ?4ODE3
. loono
. 118015
.830^3
** 74.84083
ANGLE
, DEC.
8.
8.
8.
B,
B,
3,
8,
8,
8,
8.
'6
8
8
38
32
S3
33
33
53
33
68
71
73
83
30
90
90
98
103
1ZD
1ZO
128
120
1ZO
1Z8
12B
1ZO
120
135
137
143
143
143
143
147
150
158
130
138
138
138
139
133
163
171
173
1B7
187
187
187
187
187
187
187
187
187
Z3Z
Z3Z
232
Z33
233
233
233
233
Z33
278
277
277
283
300
3BB
388
300
38B
388
300
300
380
3BB
315
313
3Z2
322
333
338
330
343
343
333
333
.88008
, 00800
.00800
, OOOOO
, 83088
.80000
,88800
. 88888
.BBBBB
.00000
.880013
. BBBBB
.88800
.08800
.000O0
.OOOOO
.88300
. OOOOO
.88000
.00800
. BOBBB
. 08BBB
.80880
.800B8
. 03000
.OO00B
.0OO00
. BBBBB
.00880
.00000
.00000
. 000B8
. BBBOB
.00300
.00000
. BBB38
.00003
.BB888
. 000B0
.BBBBB
.0000B
.00080
.80000
.88000
.80000
. 00000
.00000
.00888
. 00000
.08000
.08030
.00BO8
.00888
.BBBBB
.00000
.O0000
.00300
.BBBBB
.00008
.BBBBB
.00800
.08888
.00000
.80000
.0000O
.88080
.00000
.00000
.BBBBB
.00000
. BBBB0
. OBBBB
.BBBBB
.BBBBB
.00000
.BBBBB
.03008
. 33300
.00000
.00008
.00000
.00000
.00333
.BBBB8
. 00000
.BBBBO
. BB000
.00000
.BBBBO
.00333
.BBBBB
.00300
.00800
.oonoo
.00308
.88800
. eoeoo
. O8O30
. 00800
.8BB0O
51B.
449.
391.
3BS.
275.
2sn.
227.
177.
154.
I 7"? ,
lif.
193.
19.
1415,
146,
1S4,
200,
134,
107,
246,
187,
420
73
. 260
360
20B
142.
315
190
362
297
Z33
164
124
94
43
318
418
195
243
327
148
165
165
162
255
198
86
250
284
2O4
163
196
3B1
139
Z60
37
310
411
348
Z91
231
113
IBB
• 130
77
107
Z24
138
63
411
3Z7
Z5B
211
130
238
282
133
252
510
416
343
311
284
230
247
178
130
54
ZOO
3Z5
151
IBB
Z7C.
Z8S
21 1
1Z7
183
31B
197
R
m
08880
30008
00003
DB80I.1
8BBB0
08000
001)0(5
00883
08008
B0QOO
.80000
.80008
.08000
. 300FI8
. OOOOO
. OOOOO
. B8OOB
.03008
,00000
.00083
.80003
.OOBBB
.OBBBB
.BBBBB
.83308
. B8000
. 0B800
. 30800
. BBBBO
.30000
. 800OO
.08888
.00080
. 33000
. BU000
.BOBBB
.80008
.08880
.08883
.00080
.00080
.00000
.osaae
.80088
.00800
. 8B8U3
.BBBBB
.00003
. 83B08
. 80888
. 0300B
.BBBBB
. BBBBB
.00833
. BBBBB
. 38883
.BBBBB
. BBBBB
.BBBBB
.00008
. OBBOO
.30000
.BBOOO
.BBBBB
.BBBBB
. BBBBB
.BBBBB
.BBBBB
.3B3B8
. 00000
.00000
. 00003
. BOBBB
.00000
.B000O
.00800
.33000
.00000
. B0BBB
.BBBBB
.BB0BB
.B3BB8
.80808
.03888
.8BB8B
.83388
.80000
.88080
.BBBBB
.BBBBB
.BBBOO
.BBBBB
. OBBBB
, onono
. DOOWJ
.BOBOB
. ooooo
. ooooo
. BBOOO
. BBOOO


78.
62.
54.
'42.
3B.
34.
31 ,
?4,
21 ,
16,
11
26
2
73
115
122
139
122
85
196
173
337
72
258
368
208
142
311
1B3
313
257
ZB3
142
107
81
37
44!
355
137
163
196
.84
99
33
88
127
3B
42
S3
76
76
33
78
77
21
31
-4
-62
-5B
-42
-35
-30
-14
-21
-18
-9
-a.4
-176
-124
-60
-396
-315
-249
-203
-144
-238
-279
-157
-243
-441
-368
-237
-269
-245
-133
-213
-154
-112
-46
-141
-2Z9
-92
-66
-124
-106
-73
-32
-Z7
-37
-Z4
X
m
.37845
.48886
.41681
.86541
.27269
,73333
. 59237
.63378
.43271
.37916
.2730-3
.86847
.64429
.08816
.84976
.93007
.7Z736
.39007
.43414
. 46463
. 38338
. 11826
. 44438
.06213
.08838
.08800
.08888
.9343B
.32571
.50034
. 28886
.51543
.02779
. 38686
. 486 1 7
.23839
.67173
. 06946
. 88587
.67863
.79282
.25346
.23873
.29873
.23871
.49866
.99895
.33355
.65815
.41852
.41832
. 1Z974
.23896
.98236
. 74343
. 68423
.50343
. 15722
.33141
.41317
.46618
.59118
.81584
.93784
.28154
.3B45Z
.31778
.31372
.38562
.83330
.93664
.83864
.Z0356
.81833
.88928
.80088
.83764
.81464
.41258
.66986
.26404
.84462
. 33200
.94348
. 18445
.90677
. 15144
. 5825 1
.76584
.41337
.80679
.36336
. 43035
. C44B6
. 75923
. B3334
.F!68 3 4
. 17461
.77516
.00350


505.
444.
387.
305.
272.
247.
224.
175.
15J.
l?n .
ea.
131 .
is.
126.
89.
92.
128.
92.
64.
14B.
7B.
136.
13.
31.
-0.
-0.
-8.
-43.
-43.
-181.
-148.
-117.
-82.
-62.
-47.
-21.
-255.
-205.
-137.
-175.
-261.
-111.
-131.
-131.
-135.
-228.
-171.
-74.
-231 .
-183.
-183.
-154.
-182.
-238.
-137.
-258.
-36.
-3B6,
-407.
-345.
-288,
-243,
-114.
-178.
-143.
-76,
-65,
-137,
-97.
-15,
-186.
-84,
-66
-54
-38
0
34
19
65.
255,
208,
171
155
142
115
123
63,
65
27
141.
229
118
85
24?
?6'1
195
122
181
3(17
19^
y
m
B3671
63034
19479
00256
32T7B
567^ •*
7SBU5
27745
SB 128
81271
21172
12173
81589
43963
88633
67324
36265
67324
39482
84637
B5B33
73743
41 113
68313
08135
8B378
08033
B4081
1764B
00138
50122
5B097
00067
00331
00039
58818
00209
00163
68668
52583
15580
B0348
77545
77545
86517
83728
,47365
,47845
.79653
. 14631
. 14631
.041 14
,38221
,74420
,28883
,86223
.72417
,19312
.93513
.40576
.83069
. 12883
. 14271
.65816
.88173
. 42533
.87438
.98651
.27334
.38435
.37038
.63043
.77264
.68863
.82130
.88267
.37834
.37332
.22526
.00542
.80441
.50363
.50330
.OB3B1
.00244
.50262
,80183
.08138
.80057
.42316
.81262
.33082
. 18632
. 0ZH33
. '4887
.6368?
.67301
. 42239
.63965
.53194
                          275

-------
150
                      3     li     5      6      7     8     9
                         HERN HIND  SPEED  (M/S)
         Figure  1.  Average Wind Speed Profile, 0500-0600.
                             276

-------
150
100  -
                          TEMPERHTURE  .(DEC  C]
           Fiqure 2. Average Temperature  Profile, 0500-0600
                            277

-------
     130
     125 --•
UJ
LU
cc
CD
UJ
a
o
t—>
h-
CJ
UJ
a:

a

a
     115 -
     110
                               FIVE-MINUTE  PERIOD
    Figure 3.  Variation of 80 m Wind Direction During the Hour.
                                 278

-------
                   CM
                   CM
                   Lf)

                   CM
"







B


f


-








1


1
\
\
\










I
1







1
1
I
t

i






\
-




\
\




\
j

i —


CO
CM
r—


CM
CM
OJ
r—
0
f-"


r~~
CO
                          ©
                                           O

                                           OJ
                                           o


                                           c
                                           o
                                           •t~"


                                           13
                                           {/I
                                           •i —
                                           O


                                           I

                                           O)
                                            OJ
                                            I
CD
          279

-------
o
     25
                                                                 15
                             FIVE-MINUTE  PERIOD
                                                     0600
            Figure 5.  Variation of H  During the  Hour.
                                   w
                               280

-------
            I

            I

           I

           I
    \
                 IT)
                      o
                 oo
CM
*d-
                        o
                  o
                  en
                  oo
                  CO
                  oo
                  oo
                                     q-
                                      o
                                      -Q
                                      •r-


                                      4J
                                      to
                                      •i—
                                      Q
                                      c:
                                      O)

                                      C3"
                                      OJ

                                      U_
                                      VJO

                                      I
                                      O)
o
              281

-------
Figure 7.  One-Hour-Average SFg Concentrations from Field Data.
                             282

-------
    110
    100 -
     90 -
UJ
                      1.05             1.1            1.15
                                SPECIFIC GRRVITY
1.2
         Figure 8.  Typical  Density Profile  in  Towing Tank.
                               283

-------
o
t^t
H-
a:
tr
i_
2:
at
o

LU
>-
Q
     .01 -
    .001 -•
   .0001
                     A  Standards

                     —  Best-fit Beer's Law
               A      .2     .3'   .U     .5     . S     .7     .8     .9    1

                                      VQLTPGE ",:	". :.  	  ,,"   • '.:	  :
                     Figure  9.  Colorimeter Calibration  Curve
                                 284

-------
      100
      90 -1
      80 --
      70 -•
      60 -
      50
      140 -
      30 --
      20 -•
       10 -•
5000
                            10000       15000      20000

                                CONCENTRflTION  IPPT]
3000U
Figure 10.  Vertical distributions of  plumes  over flat baseplate 48.5 cm
            (314 m) downwind of  source.
                                  285

-------
   30000
   25000
   20000
D_
 a:
 LU
 CD
 CJ
    15000
    10000 +
    5000 -•
                                            tM]
Figure 11.   Horizontal distributions  of plumes over flat baseplate
             48.5  cm (314 m) downwind  of source.
                                                                        80
                                  286

-------
      20
      is
a-     10  -•
tn
       0  -
                                             CENTER ! M  I i M I Ml i i  M M
                                               OF
                                              HILL
         0    100    200    300    liOO    500    600    700    300    900    1000
              Figure 12.  Plume Widths  in  the Absence of the Hill
                                   287

-------
       3UUGO  -
       25COO --
    Q-
    O
    i—t
    h—

    F ^0000 -f
    U4
    CJ
   CJ
      15000 -•
      10000
            0     100   200    300    100    500    600

                                        X      (M3
700  - SOO .   903    1000
Figure 13. Concentration vs. downwind  distance in the absence  of the hill
           Open  points from vertical distributions; closed  points  from
           horizontal  distributions.
                                     288

-------
                  XV	_-^-,;-..^-	


EPF1
  INDFR  CONE     FLUID
u J- IN V nnuir?         MODELING
     I [JHnlu         SECTION
        Figure 14.  Sampling Port Location Map.
                    289

-------
Figure 15.  Side and Top Views of Model  during  Tow 8.



                             290

-------
Figure 16.  Concentration Distributions from Tows 1 (top) and 2 (bottom)
                                  291

-------
    100000
     10000 -
  D_
  D_
  OC
  OC
  (—
  2
  LLJ
  O
  2:
  Q
  O

  OJ

  IS
  to
  h-
1000
        100
                          100
                          A
                                   1000           10000

                          TOW 1  CONCENTRfl'TIQN  tPPT)
                                                                        100000
Figure 17. Scatter  Diagram Showing Repeatability Between  Successive Tows,
                                    292

-------
o
LlJ
C3
J. iU -


1 n n -









8r! -




~> n
1



RTl




•rr




M-lTf






— — •






























Eg..-





















i
i.
.

















,



































1
i —

























"3




























T — — '




















































	 l






















^]
=a 	
































i — -















	 ITT





































1.

















.




































15












. iM










































1 	 —





























































tJ















































_ — _,
	 -1
	 i










1
!
	 J
1




s






J






j


"









"I

i
	 1

	 1
— — • r
1.
                               SPECIFIC GRRVITT
     Figure 18.  Density Profiles for Tows 7 and 8.
                                293

-------
    100000
        10
           10
100             1000           10000
      TQH 7 CQNCEHTRflTIQN  (PPT)
                                                                      100000
Figure 19.  Scatter Diagram Showing  Effects of Change in Shape of Density Profile.
                                   294

-------
      TOW 24
     24 m; 0 = 117°
                           TOW 22
                         31 m; 0 = 117°
                                TOW 25
                          Hc = 38 m; e »  117°
                       /
H. =
 TOW 12
24 m; 0 « 122*
       TOW 11
H  = 31  m; 0 = 122°
 c
      TOW 10
H. = 38 m; 0 = 122C
      TOW 18
Hc = 24 m; 0 = 127{
                           TOW 19
                    H  = 31  m; 0 =  127°
                     C
                                TOW  17
                               38 m; 0 -  127°
   Figure 20:   Concentration  Distributions  Resulting from TOWS at
               3 Wind Directions  and  6  Values of H  ; H  = 31 m.
                                                 C   S
                                  295

-------
      TOW
f-L « 44 m; e - 117'
- 49 m; 0 - 117C
                                 23
   = 60 m;  e * 117'
H  = 44 m; G = 122{
  49 m; e « 122C
      TOW 13
H, = 61 m; 0 - 122C
      TOW 20
     44 m; G - 127C
    TOW 21
= 49 m; 6 = 127'
      TOW 16
H  = 60 m; 0 • 127e
   Figure 20:  (continued)
                                   296

-------
   10000 +<
Q_
D_
CL
tr
LLJ
o
2:
D
O
UJ
a
a
2:
    1000 -•
                                                  !      A  11
                                                 I""--	'D  12
                                                  i      O  13
     100 -
                            100         9        1.000

                            FIELD CONCENTRflTION  (PPTJ
10000
Figure 21.  Scatter Diagram Comparing  Concentration Distributions from
            3 Individual Tows with  Field  Distributions.
                                297

-------
             200M
Figure 22.  Concentration Distribution  from Superposition of 18 Tows.
                                298

-------
   10000
Q_
Q_
cr
01
D
o
UJ
a
    1000
     100 - -
     10
                            100                  100D

                            FIELD  CONCENTRRTIQN  IPP'T)
10000
       Figure 23.   Scatter Diagram Comparing Superposition of
                   Concentration Distributions from 18 Tows with
                   Field Distributions.
                                 299

-------
20000
                                                  Wind Direction
                                                A117   degrees
                                                I]120   degrees
                                                O122   degrees
                                                0 125.5 degrees
                                                A127   degrees
                                 Hr     CM)
        Figure 24. Variation of Maximum Concentration with H
                               300

-------
    20000
   15000
i—
Q_
Q-
CC
cc
t—
CJ
CD
O
X
CC
   10000
    sooo
A  Hc=24m
D  Hc=31tn
O  Hc=38m
0  Hc=44m
                            120                  125

                            WIND DIRECTION  (DEGREES]
                130
 Figure 25. Variation of Maximum Concentration with  Wind  Direction.
                                   301

-------
                                 APPENDIX C
                     USE OF MODEL PERFORMANCE STATISTICS

     The model tests discussed in Section 5 are based on the following
hypothesized relationship between an observation C  and the corresponding
model estimate C :
                           e (x2)
                                                 (1)
where x, are known model inputs, and x« are unknown variables.  Recall
that because x? is unknown, the estimate C  can be  associated with an
infinite ensemble of possible observations.  This ensemble is in effect
described by the distribution of the residuals £.
     To understand how the statistics of e can be used to link model
estimates with observations, the following questions might be asked:
     1)   Given a model estimate C  , what is the probability that the
          corresponding observation C  will exceed a specified
          concentration C ?
                         s
     2)   Given an estimate C  , what fraction of corresponding
          observations are expected to lie within a factor of 2 of the
          modeled  concentration?
     To answer these questions assume that e is normally distributed with
zero mean.  Then the sample variance of e is given by
           1  N
           J-  v
           N 1-1

-------
where N is the number of observations.  It can be readily shown that
CC   - C  )/S follows a Student-t distribution with N degrees of
  oi    pi
freedom.*
     To answer Question I, we construct the following t-statistic, t^
          (C  -
                                       (3)
The probability Pr(t > t  ) can be readily obtained from statistical
tables.  For example, consider the standard deviation of the residuals
associated with log-transformed concentrations
     S = In
                                          1/2
                                       (4a)
The log-transformation of concentrations allows us to restate  Question 1
as:  What is the probability  that the observed concentration CQ will
exceed x times the predicted  concentration  C  ?  Let us  take x  = 2 and
s  =2.5 for N = 45  so that t  becomes
 e                            r
          ln(xC  )  -  In  C
               p	p _  In  2
                                       (4b)
             In s
In 2.5
                                      0.76
 From tables, we  find  Pr  (t>tr> -  26%.
      This  calculation immediately allows us  to  answer  Question  2.   Because
 the  t-distribution  is symmetric,  we  expect 26%  of  the  observations  to be
 less than  one-half  the estimated  concentration  and 26% to  be  greater than
 twice the  estimated concentration.   Therefore,  48% of  the  observations  are
 expected to lie  within a factor of 2 of the  estimate.
 *See  Box,  G.E.P., W.G.  Hunter,  and  J.S.  Hunter  1978.   Statistics  for  Experi-
 ments;  An  Introduction  to  Design,  Data Analysis,  and Model  Building.   New
 York: John  Wiley &  Sons.
                                     303

-------
     We can also estimate confidence intervals for the model calculations.
Specifically, we can express the (1 - Y) confidence interval for the ratio
C /C  as follows:
 o  p
                     
-------
                                  TECHNICAL REPORT DATA
                           (Please read Instructions on the reverse before completing)
1. REPORT NO.
   EPA-600/3-82-036
                                                          3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
   EPA COMPLEX TERRAIN  MODEL DEVELOPMENT
   First Milestone  Report -  1981
                                                          B. REPORT DATE

                                                             April 1982
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
   T. F. Lavery, A. Bass,  D.  G.  Strimaitis, A. Venkatram,
   B. R. Greene. P. J.  Drivas.  and B. A. Eoan	
                                                          8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS

   Environmental Research  & Technology,  Inc.
   696 Virginia Road
   Concord, Massachusetts  01742
             10. PROGRAM ELEMENT NO.

               CABN1D/01-0566 (FY-82)
             11. CONTRACT/GRANT NO.

               68-02-3421 .
12. SPONSORING AGENCY NAME AND ADDRESS
   Environmental Sciences Research  Laboratory - RTP, NC
   Office of Research and Development
   U.S.  Environmental Protection  Agency
   Research Triangle Park, North  Carolina 27711
             13. TYPE OF REPORT AND PERIOD COVERED
               Interim 6/80-12/81	
             14. SPONSORING AGENCY CODE
               EPA/600/09
15. SUPPLEMENTARY NOTES
16. ABSTRACT
        The U.S. Environmental  Protection Agency is sponsoring the Complex Terrain
   Model Development  program,  a multi-year integrated  program to develop and validate
   practical plume dispersion  models of known reliability  and accuracy for simulating
   one-hour average ground-level  concentrations downwind of elevated sources during
   stable atmospheric  conditions in complex terrain.   The  first major component of the
   Complex Terrain Model  Development program was a field study conducted during the
   fall of 1980 at Cinder Cone Butte, a roughly axisymmetric, isolated 100-meter-tall
   hill located in the broad Snake River Basin near Boise,  Idaho.   The field program
   consisted of ten flow  visualization experiments and eighteen multi-hour tracer gas
   experiments conducted  during stable flow conditions.

        This report presents an overview of the Cinder Cone Butte field program and
   the results of the  modeling analyses completed through  June 1,  1981.  The objec-
   tives of this phase of the  modeling program were to begin the development of new
   dispersion models  using the Cinder Cone Butte data  base and to compare their
   performance with existing complex terrain dispersion models.
17.
                               KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS  C.  COSATI Field/Group
13. DISTRIBUTION STATEMENT
                        RELEASE TO PUBLIC
                                              19. SECURITY CLASS (ThisReport)

                                                    UNCLASSIFIED
                                                                        21. NO. OF PAGES
                                327
                                             20. SECURITY CLASS (This page)

                                                    UNCLASSIFIED
                                                                        22. PRICE
EPA Form 2220-1 (9-73)
                                           305

-------

-------