&EPA
           United States
           Environmental Protection
           Agency
           Office of Exploratory
           Research
           Washington DC 20460
EPA-600/6-84-004
September 1984
           Research and Development
Institutional
Responses to
Contamination of
Ground Water
Used for Public
Water Supplies:
           Implications for
           EPA R&D Programs

-------

-------
                                                                   EPA-600/6-84-004
                                                                   September 1984
~  ;,                   INSTITUTIONAL RESPONSES  TO CONTAMINATION
fg                 OF GROUND WATER  USED  FOR PUBLIC WATER SUPPLIES:
#•                        IMPLICATIONS FOR EPA  R&D PROGRAMS   ;  ;
                                      FSNAl. REPORT
                                       Submitted  To:

                          EPA Office of Research and Development
                                  Contract No. 68-02-3718

                            Project Manager:   Dr. Marvin Rogul
                          Director of Scientific Assessment Staff
                                       Prepared By:

                                     ICF Incorporated
                              1850 K Street,  N.W., Suite 950
                                  Washington, D.C.  20006

                           Project Director:   Theodore R. Breton
                          Principal Analyst:   Steven N.  Payne
                               OFFICE OF EXPLORATORY RESEARCH
                             OFFICE OF RESEARCH AND DEVELOPMENT
                            U.S. ENVIRONMENTAL PROTECTION AGENCY
                                    WASHINGTON, DC 20460

-------
                      NOTICE

This document has been reviewed in accordance with
U.S. Environmental Protection Agency policy and
approved for publication.  Mention of trade names
or commercial products does not constitute endorse
ment or recommendation for use.
bfc.
 %
                        11

-------
                            TABLE OF CONTENTS
                             ,  '
                                                                          Page
EXECUTIVE SUMMARY
  I.  INTRODUCTION ---- ......... ........................... .............    I~1
         Background on Organic Contamination of Ground Water ...........    1-1
         Purpose of Study . . . . ................... ! .......................    1"^
         Outline of Report .............................................    I~4-

 II .  METHODOLOGY ...................... . ...............................   J1'1
         Initial Survey ................ ..... ...........................   II-l
         Case Selection ................................................   II-3
         Study Procedure ..... ............ ..............................   II -7

III.  ANALYSIS OF CASES ... ................... .................. • .......  IH-1
         Organic Contaminants Detected  .................................  III-2
         Sources of Contamination ......................................  Ill -4
         Discovery of Ground-Water Contamination .......................  III-5
         Prevention of Ground-Water Contamination ......................  III-6
         Actions Taken in Response to Contamination  ....................  III-7
         Health Guidelines .......... ........ . ..... .....................  111-10

 IV.  GROUND-WATER CONTAMINATION RESEARCH AND.  DEVELOPMENT NEEDS ... .....   IV- 1
         .Analytical Procedures for Monitoring  Contaminants  ... ..........   IV- 1
         Determination of the Extent and Source of Contamination ....... •  IV-5
         Engineering Control Technologies  ..............................   IV-6
         Aquifer Management Technologies ........ . ..... .................   IV-8
         Health Effects  ................................................   IV-10
         Other Needs  ...... .............................................  IV-12
   V.   CONCLUSIONS
 APPENDICES
          A:   INITIAL SURVEY RESULTS  ....................................   A-l
          B:   SAMPLE INTERVIEW QUESTIONS  ............................ ....   B-l
          C:   COMPLETE CASE STUDIES .....................................   C-l
          D:   LIST OF CONTACTS FOR EACH CASE  ............................   D-l
                                       111

-------

-------
                            EXECUTIVE SUMMARY     .                .;




    The objectives of this ground-water assessment for the EPA Office of


Research and Development are threefold.  The first objective is to improve


EPA's understanding of problems faced by the states and municipalities in


ensuring that ground-water is safe for drinking.  The second objective is to


provide guidance to EPA in setting research and development priorities in


ground-water and drinking water areas.  The final objective is to present the


data on the original and final sets of ground-water contamination cases


examined, with source lists for contacts at each organization dealing with the


problem.  These objectives reflect revisions made in the work plan which


originally called for a mini-assessment of trends in ground-water pollution.


    The scope of this assessment was defined to include public water systems
                                      •'       '    "=,.,..,

with confirmed drinking water contamination from synthetic organic chemicals


in ground-water.  A preliminary list of municipalities with ground-water


contamination problems was developed to select a group of cases for in-depth


analysis.  These cases, chosen with the assistance of regional EPA and state
                      . • •  •  ;    . -•    •...-•:-• •., ... ;."  -if ' -t,  •:	-  •' •.     •'.-,...; ,

officials, were studied through site visits and extensive telephone interviews.






CONTAMINATION TRENDS


    Several distinct patterns of ground-water problems became apparent.  Eighty


percent of the cases involved trichloroethylene, detected at levels as high as


5,700 ppb in public wells.  Tetrachloroethylene, trichlorpethane, and other


volatile halogenated organic compounds were detected less frequently, and at


lower levels.  The major sources of these organic solvents were military con-


tractors or airports, followed closely by plating industries, electronics

-------
                                   E-2
industries, and chemical waste handlers/landfills.   Leaking underground  tanks
or improper disposal of solvents were identified as the most common point
sources of pollution.  It is important to note that a large number of other
cases of ground-water contamination are likely to exist but have not been
discovered or made public due to the same fears and uncertainties exhibited  by
public officials in the cases studied.
»*-
 *
PATTERNS OF  INSTITUTIONAL RESPONSE
    Several patterns of institutional response also became apparent.   In a
typical case, organic-contaminated drinking water was discovered accidentally
or by state officials testing suspected or random sites.  The local water
utility usually closed the contaminated wells immediately and invoked conser-
vation measures or purchased water to replace lost capacity.  At this point
the state  and technical consultants joined in investigations to determine the
source of  contamination and to restore long-term water supplies.  In the major-
ity of cases, new or recompleted wells were selected as a long-term water
source, rather  than water treatment or aquifer rehabilitation.
    In a typical case, the local water authorities would be working with t'.ie
county health or environmental department, the state health department and
environmental agency, and regional EPA officials.  The capabilities of state
agencies,  which often took the lead in resolving ground-water contamination
cases, varied widely.  The State of New York, for  example, has studied
organics  in ground water extensively, while Washington barely has enough staff
or funding to conduct any investigations  at all.   Several states, such as
Arizona,  have set up their own versions of Superfund  (CERCLA) to attempt to
respond  to hazardous waste problems.  The Department  of Defense has also

-------
                                   E-3
become  involved in a significant number of cases-through-programs such"as the




Air Force's Installation Restoration Program.             /;,;•-    -     ,:









RESEARCH AND DEVELOPMENT NEEDS •,            .      t     -:  ;  ,




    The major technical deficiency encountered was a paucity of information on




the health effects of organics in drinking water and a lack of consistent




health guidelines.  Evaluating.the hazards of keeping contaminated'wells in




service, informing the public, and designing treatment techniques were-all




made difficult by weaknesses in health data and- inconsistencies,•in recom-




mended allowable levels of contamination.-    . . :.    :     .




    Testing and monitoring techniques appeared adequate in most cases.




Research on more comprehensive and less expensive methods of analysis would,




however, aid in the detection and resolution of organics contamination cases,




as would standardized protocols for monitoring.   Tracing the sources of organ-




ics in ground water proved to be a more serious  problem.   Several investiga-




tions were limited by costly drilling techniques,  the complicated data require-




ments for ground-water modeling,  or an overall lack of institutional coordina-




tion.  Many regions also face a shortage of qualified hydro/geological person-




nel to carry out extensive subsurface studies.




    The state-of-the-art of treatment techniques  to remove organics from drink-




ing water was generally not a limiting factor, and either EPA or  engineering




consultants had enough knowledge to install a pilot plant and design an effec-




tive treatment plant.   Aeration techniques were  usually selected  although




little is known about the levels  of air contamination due to  aeration.   The




major constraints  in designing treatment methods  are the  uncertainties in

-------
                                   E-4
specifications for allowable effluent levels of organics, not the efficacy of




removal technologies.



    In conclusion, most municipalities examined in this study handled the




problem of organic chemicals in their ground water fairly well, but more work




is needed to improve several areas of response.  The most critical R&D need




for states and municipalities is in health effects research, followed by estab-




lishment of consistent guidelines or standards for organics in drinking water.




The dissemination of technical information on detection, analysis, and




engineering control techniques is also necessary to help local and state offi-




cials to make informed decisions on resolving problems with organic contami-




nants in ground water.

-------
                            I.   INTRODUCTION




    This study was commissioned by EPA to investigate trends,in cases of


ground-water contamination and to evaluate research and development needs of


municipalities with contaminated ground-water supplies.  This  section presents


background information on the growing problem of organic contaminants in


ground-water sources used for drinking water supplies, elaborates on the pur-


pose of this investigation and outlines the content of the report that follows,
                                            \>   •         .    " -  '        ' " ;





BACKGROUND INFORMATION ON GROUND WATER CONTAMINATION


    Ground water is a vast but vulnerable natural resource.  About 25 percent


of all fresh water used in this country comes from ground-water sources,  and


somewhat over 50 percent of the U.S.  population relies on ground water,  often
            . •'     '          '     -  •  •          -    •'   - •  ' .      >'   ,  ;  ,' '

untreated, as a primary source of drinking water.1  Ground-water use is


proportionately higher for small water utilities and in rural  areas, where


over,90 percent of the population is  dependent upon public or,  more often,


private wells for drinking water.2 Considering the fact that  over 20


trillion gallons of ground water are  withdrawn annually, one might suspect


that the nation is facing a problem with the quantity of the ground-water


resource.   Except for arid regions in the West, however, natural recharge is
1  U.S. Environmental Protection Agency,  Office of  Drinking Water, "

Planning Workkshop to Develop  Recommendations for a Ground Water 'Protection

 Strategy:  Appendices,  Washington,  B.C.   U.S.  Government  Printing Office,
1980 p. IV-1.                           '                        '


2  Murray, C.E., and Reeves,  E.B.,  Estimated  Use of Water in  the  United

States in  1975,  Geological Survey,'Circular 765, Arlington, VA, USGS,  1977
p. 20.

-------
                                   1-2
usually ten times as large as withdrawal, and overall ground-water quantity is

not a problem.

    The current problem associated with ground-water supplies is with quality,

not quantity.  Although ground water had always been considered a secure,

pristine resource, recent discoveries indicate that contamination from various

sources is a problem in many locations.  One potentially serious trend becoming

evident is that many instances of ground-water contamination are associated

with organic chemicals.  The earlier national organics monitoring programs

focused attention on trihalomethanes in surface-water systems, and as recently

as four or five years ago, ground water was still thought, by most, to be

relatively secure from organics contamination.

    Three major national studies by EPA  from 1975 through 1979 showed that a

number of volatile chlorinated hydrocarbons -(besides trihalomethanes) were

frequently found  in ground water.3,'*,5  More recent studies, focusing

more on ground water, such as the Ground Water Supply Survey, the Community

Water Supply  Survey, and the Rural Water Survey  confirmed earlier reports that

several organic  chemicals associated with  solvents, especially trichloroethy-

 lene and tetrachloroethylene, were present in  a  significant  number of water
 3  Symons,  J.M.  et,al.,  "National Organic Reconnaissance Survey for
 Halogenated Organics," Journal  of the  American Water Works Association,
 67:234 (1975).

 4  U.S.  Environmental Protection Agency,  "Organic Chemicals in Drinking
 Water,"  Washington,  D.C.  1978.

 5  Information on the National  Organics Screening Program (NOSP) provided by
 the Criteria and Standards Division, Office of Drinking Water, U.S.
 Environmental Protection Agency, Washington, D.C.

-------
                                    1-3
systems using ground water.6  The  occurence of organic cheraicMsriri drinking

water from ground-water sources has  been recognized as^ •a^poteritially' serious

health hazard.           .           ,     ,.     ,...,•;   .-'•_•._-.,  . ;. .'V-,.; ••.•  .

    EPA has reacted to requests for  assistance by states and t,'O:its congres-

sional mandate to .carry out the Safe Drinking Water Act and other {Statutes in

a number of ways.  One major program is  regulatory in nature,., .to set:standards

and guidelines to protect the public health .and to restrict. \t;he,.use- and dis-

posal of chemicals and hazardous wastes.v  A recent survey .showed that  EPA

drinking water research and development  assistance was ,thel,highest .priority

request from the States.7  In support of the regulatory role and to provide

technical assistance to municipalities,  states, and Regions with concerns

about organics in ground water, EPA  has  developed-.a .ground-water .resear.ch

program.   .               ,        ;       ......... -•;,, , -; •.  .. •      ,,.•:

    The EPA drinking water research  plan recognizes, that th$,;l-arges,t areas of

ignorance in the drinking water field are rela.ted to the measurement,  assess-
                                             .     -     - * f "-..'.
ment, chronic health effects, and  treatment of trace organics in ground water.

This study was initiated to investigate  trends in cases of ground-water contam-

ination and to comment on the needs  of States and municipalities in studying

and resolving local cases of drinking water problems caused by contaminated

ground water.
6  Coniglio, W.A., Miller, K.,  and  MacKeever,  D.  "The Occurrence of Volatile
Organics in Drinking Water,"  U.S. Environmental Protection Agency, Office of
Drinking Water, briefing paper, March 6,  1980,  p.  10.

7  U.S. Environmental Protection Agency,  Office of Research and Development
"Decision Unit Analysis - Drinking  Water,"  prepared for the Office of
Management and Budget, 1982,  p. 1.

-------
                                   1-4
PURPOSE OF  STUDY

    Orginally, this study was intended to be a mini-assessment of trends in

ground-water pollution.   Early discussions between the Office of Research and

Development and ICF Incorporated centered around a proposed work plan to

characterize the current extent of ground-water contamination, project trends

in ground-water contamination, assess the potential health hazards associated

with these trends, and to identify policy implications, information gaps, and

research needs.  After ICF presented its detailed work plan for the mini-

assessment, ORD decided that the available data were inadequate to fully

support the type of inquiry initially sought and that a change in study

emphasis was mandatory.   The background research and investigations preceeding

this decision are not presented in this report.

    The scope of the effort was changed to provide a narrower but more

in-depth study.  The main tasks of the revised work plan were to:

         •   identify cases of drinking water contamination associated with
             ground-water' contamination;

         •   contact the local and state organizations involved to determine
             the facts of each case, institutional responses, and any difficul-
             ties encountered;

         •   organize the findings to permit others to derive insights on
             preferred methods in technical areas such as detection, analysis,
             monitoring, or treatment; and

         •   use the data to derive suggestions for EPA research needs.

The procedures used to perform these tasks are described in the section

entitled Methodology.
OUTLINE OF REPORT

    The remainder of this report is organized into sections addressing the

methodology  employed, characteristics of the cases analyzer!, research and

-------
                                   1-5
development needs, and conclusions on trends in organic contamination of ground


water.  The methodology section describes the procedure used to identify water


systems with contaminated ground water and to select the cases studied in


depth.  The analysis section describes various technical and organizational


aspects of the case studies, as well as problems commonly encountered.  The


section on ground-water R&D discusses the areas of assistance most frequently


requested by municipalities and states with ground-water problems and outlines
                       •^

these areas in a format consistent with EPA's Drinking Water and Ground Water


Research Plans.


    Several important components of this report are included as Appendices.


These include the results of the initial survey of water systems, the complete


case studies (the subject of most of the effort expended in this assessment)


and a list of contacts at every agency involved in each case.  The last two


items, especially, will be valuable for follow-up studies on specific technical


topics.      ,  :  -    ,    _

-------

-------
   ........           ,     j(    II,. ., METHODOLOGY    . _;	 ,   ,,  ......


    Since the data available on ground-water contamination are inadequate to

support a statistically-based inquiry, the case study method was ~chosen to gain

an in-depth understanding of the problems involved in responding to ground-

water contamination.  Briefly, the general approach in the project was to:

   ,   .   •   Compile data on cases of drinking water problems associated
             with ground-water contamination;

         •   .Select .a cross-section of cases for in-depth analysis, involving
             site visits and phone interviews;

         •   Contact the key individuals in the selected group of cases to
             obtain detailed information on how the water utility discovered
             and dealt with the problem;

         •   Identify common patterns of problems and responses; and

         •   Make suggestions on research and program needs to EPA, based on
             the findings of the cases studied in depth.


'A more detailed explanation of the methodology is presented below.
 INITIAL INVESTIGATION

    In compiling data on cases of drinking water contamination, an effort was

 made to investigate those cases considered significant by .state and local

 authorities.  State public health agencies were contacted to identify instances

 of drinking water problems caused by actual or potential ground-water contami-

 nation.  The data compiled on each case included location, contaminants iden-

 tified, and a brief description, if possible, of the extent of the problem and

 any action taken.  Over one hundred cases in the ten.regions were identified

-------
                                   II-2
in this step.   Several criteria were established to narrow the scope of  the

investigation.   Those cases that clearly did not include public systems,  those

that involved only inorganic contaminants (including heavy metals),  or those

which were known to be actively involved in lawsuits were screened out.

Seventy-seven cases passed this screen and were considered for the final

analysis.  A review of the cases indicates the following characteristics:

         •   Geography:  The 77 sites identified were concentrated in
             areas of high population density, indicative of more frequent
             contamination as well as more intensive water testing:
                        Region

                           1
                           2
                           3
                           4
                           5
                           6
                           7
                           8
                           9
                          10
                               Total
No. of Sites Identified

         .4
         27
          7
          8
         12
          1
          3

          9
          6

         77
             Contaminant:   Some cases involved more than one contaminant.
             The preliminary data collection effort yielded the following con-
             tamination pattern:
             Contaminant

             Trichloroethylene  (TCE)
             Unspecified  "Organic"
             Tetrachloroethylene
             Unspecified  "Solvents"
             PCB
             Trichloroethane  (TCA)
             Toluene
             Dichloroethylene (DCE)
             Acetone
             Dibromochloropropane  (DBCP)
             Phenols
             Benzene
         No.  of Cases Identified

                 39
                 17
                  9
                  6
                  6
                  5
                  4
                  3
                  2
                  2
                  2
                  2

-------
                                   II-3
             If the cases  identified as unspecified "organics" or "solvents"
             are attributed to TCE (the preliminary investigation 'indicates
             this is likely),  then 81 percent of the seventy-seven cases
             involve TCE.   Nineteen contaminants identified only once are not
             listed above.   One possible fault with the table above is that
             some officials might have confused TCE with' TCA. "

             Source of contamination:  Where the source was'identified,
             almost half of the cases were associated with landfills or waste
             dumps.  Another twenty to thirty percent were linlced to industrial
             sites.  A smaller proportion of cases were linked to buried  pipe
             or tanks and septic systems.'

             Magnitude of problem:   The populations affected ranged from
             less than 1,000 persons to over. 400-,000.  Mos,t water systems
             affected appeared to be in the range of 2,500 to SO'OdO customers.

             Action taken:   In cases where responses to contaminated
             drinking water were reported, over half of the systems qjosed
             down one or more wells.  Roughly fifteen to twenty percent either
             changed supplies or purchased water, and about ten percent of
             those systems  that reported taking action implemented'granular
             activated carbon (GAG) treatment, aeration, or other advanced
             treatment methods.                               ' '' '  '  ' '' '
CASE SELECTION                                       ' ''    '""  "'

    Site characteristics such as location,  contaminants, source of contami-

nants, magnitude of the problem, and action taken were considered to assemble

an intermediate group of cases representative of the whole.   Regional EPA and

state drinking water officials were then contacted for.assistance in selecting

the final group of cases for site visits and interviews.  In some instances,

the cases they suggested for analysis involved a more serious problem or had

received more publicity than a "typical" case, so an effort  was made to balance

the relatively controversial cases with more ordinary ones.   The regional and

state officials identified those cases where knowledgeable local officials were

actually available for detailed interviews.  The cases .selected for study dif-

fer from a truly representative sample in that the information about how each

-------
                                   II-4
community detected and responded to its drinking water problem was  readily

available.

    Since the final set of cases was selected on the basis of several general

criteria, rather than"chosen randomly, statistical measures of the study

results are inappropriate.  The field experience and in-depth examination of a

small number of cases, however, provide an understanding of typical problems

and responses from which general inferences can be drawn.

    Budget constraints dictated that only a limited number of cases could be

investigated in depth.  A two-tiered approach was proposed to study as many

cases as  possible while allowing in-depth analysis.  Two sets of cases were

selected:  a group of seven cases  designated for site visits and a group of

eight cases studied through extensive  telephone  interviews.  The more compli-

cated cases, listed in Exhibit  II-l, were selected  for site visits because

numerous  officials had to be  contacted to trace .the decision-making process.

The second group  of cases,  listed  in  Exhibit II-2,  were  more  clear-cut  so that

telephone interviews were usually  adequate.  The following table displays the

distribution of those  cases  investigated in-depth by  Region  and state.


 DISTRIBUTION OF CASE STUDIES
 EPA Region

          I
         II

        III
         IV
          V
         IX
 Totals
      State

Massachusetts
New Jersey
New York
Pennsylvania
Florida
Indiana
Michigan
Minnesota
Arizona
California
Washington

     11
Site  Visits   Telephone  Interviews   Total Cases
    1
    1

    1
    1
    1
1
1
2
1
1

1
1
 1
 2
 3
 1
 1
 1
 2
 1
 1
 1
 1

15

-------
                             II-5
CO
H

co
^
"O




C
o

•P
ID
E
I_
O
c>-
C


_
CO
C
0

*J

•a
•o
<





CD >
C to 0
to 3 C

CO C 2-
co a O
— Ci-
TS -P
(U CO C
O.C- o
E 4J —
3 — • ] *
a,— ra
d- i.
— to
— O CO
0 <-
>0 —

T3 » CO
0 C. .p
•P O to
CO P C •
C Q.— to
— CD E
E O O CD
to <- -P —
P 0 .a
C -PT3 O
O C to 1-'
O — .C Q,







E
0

n
o
s_
a.

ti-
O

•P
c
0
P
X
UJ







1 CD
CJO
0
0 >>
CO
>>e

._ e;
> CD
CO —
CD £1
C O
(_
co a.

— * •
0T3 O>
5 CD C
, •* 4_>._
ro to "o
C (0
t>_ — CD
o E s-
CO Q.
t- 4J 10

u





10
4J
c
(0
c

E
(0
.p
c
o
0





CD
JZ —
P >5
CD 4J
15
— n
>,
0->>
0 S-
1- CO
a—
O -P
« t-
— CD
1 P
•«
•O — '
>>«-
»J= CD
bj JJ JZ
O CD -P
1- E CD




•o
(!)
T3
T3 •
CO "D
C
T3 CO
C E
TO CD
•a
S-
CD -P
•P CD
CO 0
3= E

•P O
J= p
01
3 10
O —
!_ —
.Q (D
>
C
> >
O CD
1— C



O
P

03
3
•o

T3
CD
CO
O

CJ •
C
U) O
« ._
— -P
CD CO
> C

1^ E
CO
Ct- JJ
o c
o
•=»• o

CD
C
CD

a> >>
C£
CD +J
— a>
XO
r: t-
•P O
0 —
or:
!- 0
o —
— i-
r:i-
o
COOJ
£_ »
4-) T-
03 -
HT-
4J
C
0
>
CD
!_
a.

o
P

•a
03
w
3-

.— .
— CD
0 E
> =

t--a
o
4JC,_
Q.O
0
OTD
!- CO
CD 0
P.i-
C Q.
— U)

a>
._

•a
—
0
—
(«.

—
_
0
>

4->
w
0
01
i_
CO •
— T3
0
u> -p
" O
>>CD
•P Q-
— 4_
O CO









01
O
O
>

!_
0
x:
4J
o

^
Ul
o
1- -
•a
0
as >

— o
0 a>
>'>
0
> -P
o o
0 C
U3
— .E
-a 0
— _
>>J2
— o
— i-
03 Q.
*i
C *
0 "0
•O 0
— . Ul
O O
o —
<.o






Ul
— ;
—
0
>

—
CO
a.
— ,
o •
— •a
c 0
3 4J
E.co
c
C| 	 ,
0, E
'CO
«+ .p
— c
CO O
X O




U)
0
o
>

•p
c
0
1_
0
C|-
Q_
• ••
T3

C
0
>
0
C/3
en
D
O 1 •
— 3 E
! 	 0
nj co —
> >J3
.0 o
•a s-'
C C Q.
to —
0.
0-0 JT
O 0 -P -
!- >
3—01
O O C
w > —
C W
	 CO
CO 0 -
— 0 i-
S_ S- 4J •
4J to
U) T3
3 U3 C
•D 0 tO
C —
— O Ol
C C
.,00 —
x: ai-p
1— to to
0
1 U
— £-
0 3
— O
C CO
3 i-
E 0 O
	 3
C O to
. 0 en e

•p - 1
O T3 T3
3.0 0
•a to jj
o o o
. ! 	 0
Q.C3 Ci-
1 d.
r: « co
en—
	 s. E
x: 0 0 0
>«--
0 —^3
> — 3 O
— ro CT s-
U. CLtO Q.





















LU
o
1-
C 0
o o
— S-T3
-P 3 C
to O to
!- tO
•P Dl '
	 C
— CO, —
c, 	 . s-
t- 0
^ *J:4->
CJ1 t/3 —
3 3 C •
OT3 O 0
!- C E 0
r:— c
•p r: co
»*j j->
•a s — w
005 —
Q-> «
E 0 en to
3 CO,C.,tO
Q. —
E -P a.
w i- to 3
— 0 !- . 1
P 0 C
— to a. to
— O.0
000 —
3: -P o O



•o i
0 —
c e
> CO CO
O -P c-
1 C 0
i_ O Ct-
o o —
•P 3
c» >> CT
0 — to
> JZ
C cnX
	 0
JT-— .
C4- Q.
O to E
— o •
— OT3
- >, 0
0 -P K+i
> — -a o
— 0 0
0 — 4J C_
C P CO C4-
O 3 C tO









0
C
CO
J=
p
0
0
£_
0

.c
o
.^
s_
>-


c
•_

T3
0
• >

0
>
c
..—
.
CO 03
C O
• 0 «-
— 3
•P O
to to
N
— en
• c c
to —
,cn-P
,.£- C
•o —
0
>5Q.
c c
to —
•Z. a.


1 E
C 0 •
0 -P-O
owe
c >>co
1 0 to E
- O 0
>-a
-C 0
OlC 4.
, — 0
JT •>£
- T3 E
.C 0 3
4-3 tO U3
-•;— o
S — -P
O 0
t/> 0
	 03 E
,.— c
0 O -P
: f — 0
•P C
o eo c
> i- CO
1— -P O
0
c
0
_
>>0
c. c
J-> 0
0 —
0 >>
s-r:
O -P
— 0
£ 0
0 !-
to O

•P.C
0 0

Q
i -. 1
UJ CM
0 ."
Hi-







Y—
1

	
H
m
—
X
X
UJ
UJ
H

CO
CD
0
Q tO
UJ CO
— O
Q
p
^~
CO
CO
LJ
co
<^
O

a.
Q.
JZ
c
5
o
1-

>j
— CO
CO
o o
— o
ace
0
cc
0"
0
o

c
.CD

O


^
U
>

- c
o

cr
0
tr
i.
CO
jr
j£

UJ


x
0
0
O

0
— i
4J
4-1
CO
m



X


c
o

CT
0
en
                                                     0
                                                     to
                                                     O
                                                     -5

                                                     C
                                                     CO
                                                     co
•a
o

-------






















































CM
1

„_

CO
X
X
UJ









































CO
s

C£
UJ
1-
UJ
z
o
X


CO
0
UJ

._
— J

CO
10
UJ
CO
s





c
o
4J
CO
t.
ft-
c


ft
c
0
4->
T3
•c

r* .
0 >>
<- CO
co re
0 t-
CO 0
•a
0 C
> 3
C —
0 a.
4-> Q.
X 3
0 CO-

^ c_
•a 0
0 4J
CO CO
O 3:
0 3:
0
CO C
— 5_
0 O
3: &-







0

o

ex
ft-
O
c
0
4:
u





ft
o
fe^*D
O 0
CO P
o
O10
Cft-
— ft-
>>CO
a«-
a0
3 P
CO CO
CO
— CO
0 C
a- 4J





CO
4J
C
CO
c
E
CO
4-
C
c
CJ











0
c
CO
X
0
Q

UJ











a
c
c
c.












0 <
s S


•^
„ t—
o
Cft-
o-o
.- 0
O CQ
0
<£.




B
T3
0
O —
P —
•a'Z.
0T3
a.
e 01
3 C
a—
0
— .a
0 —

0
Contaminated
waste, new w




^
__
Q.
Q.
3
CO
i-
0
i
ft-
0
•a •
.- 0
-C 4J
4-> O
1 0
Cft-
O co



0
c
CO
.c
p 0
0 C
20
«-
0 >>
J= p
O 0
— o
c- i-
P O

»jr
UJ O
o —
h-Q




-5
Z
,_
v '
o

C

c_
— CO

s:
C P
0 3
•- O
D CO
0
K.

,
o

!_
CO
0
0
en
CO
0
CO
3
*-"O
•o 0
0 P
— C
— 0
L 0
•a —
a.
0
3= 0
0 —
Z P



^
"O •
0 CO
p-a
co c
C CO
— E
E 0
COT3
p
O CO
O 0
a.
CO
— 0
0 0
ON 4->
O
ft- C
O C
CO
co O



0
C
0

^j
.C
p
0
o
0

u
CO
t_
0



-^
z

^
t_
co
a.


O

c:
0
•o
<-
CO
O

II-6
0

^
•a —
0 <-
CO"O
3
C —
O 0
•e*
CO 3:
O 0
C
•a
0 —
*-> —
CO P
> c
— 3
Granular act
tempo rari ly
.
•a
0
CO 10
- o
.3- —

p 0
o-a
i- O
4J P
CO
— -a
a co
0 CO
4J —
CO —
:*
O 0
0
0 '-
C J=
O 4J



CO
O
«
C
CO
O)

o
0
•5
o

uT
o










J.
z

^

CO
p
CO
0






4-J •
JTT3
010
3 —
O —
i- 10
n P
CO
•o c
to
0 0
01 4-1
CO CO
o X
E to
Increased pu
water. GAG

0
c
o

i. •,
O UJ
ft- O ft-
1- O
CO
— ft- 0 0
— O CO C
0 30
d 7 of 50 w
sive levels
closed beca
chloroethyl
0 CO CO
CO 0 — i-
O O— P
— X 0 0
O 0 > P
0
c
0
r:
p
0
o
S—
o

.c
o
2
p
0
h-

•K
UJ
o





CO ^
C P
CO —

— 00-
co P -.
C 3 0

— 0 CO
— Q. t- -O
— 0 CO
JZ P C
C P CO CO
O 5- IS— J
— O
0 Z
0
o:

0

3

1 Q.
0 Q.
4-> 0
C 0
•— v*
•a u
0
— T3
ft- 0
•_ — —
P— •
C — T3
0 ! 	
T3TD 0
CO CD —
05-3:
O O
(- -P E
3 ao
o 0 *-
co o ft-
0
c •
o 0
-a «-
0-a 3
— 0 CO
!- P O
3 to —
^5 C O
•^
E E co
O CO 4->
!_ 4J —
4- C
OT3
UJ O 0
O O
H- >,!-
— o
0 >
to ~o
0 0 C
oi.cz to
CO
CO C —
0 CO 0
-IP 3:















UJ
o









u.
J=
u
CO
> 0

C 0
0 5-
.- 0
0
cc



i
—
P
CO
0
c
01
c
0
.O

-
Q.
a.
3
CO
c.
0
4-3
CO •
0
0 CO
Z 01

1
»—
£
CO
p
c
0
o

{—
0
ft_
source aqui
•a
0 0
— P
O CO
CO C
0
c
0
JZ
p
0
o
^*
o

o
a
CM
*
f~
uTto
o —
h-0










=
•>
^^
0

CO
c o
O -P
— 0
0
C£



CO
c.
0
PT3
O 0 •
C ft- 0
C O
CO <- <-
003
 CO
T3 Ol
0 C i-
CO— 0
O >^£ P
— O CO
O O 3:
•~
co 3-
— -D"C
0 c
3: 10 s-
E 0
4J 0 ft-
CO 13
1- >>
O P 0
3: 0 C
0 O
CO S E


|
T3 C
c o
CO O
CO 0
— £-
— CO
0
> CO
^"
6 municipa 1
private wel
lated.
t
ft- X—
0 C E
CO CO
m s P










CO
O
O
CO
3
O
's.
>






z
2

^
C
o
p
£2
cn
•~

m
CD
z


-------
                                   II-7
STUDY PROCEDURE




    The first step in investigating the final set of cases was to identify the




lead agency responsible for coordinating actions taken in response to each




case of organics in ground water.  Interviews with officials at the lead agency




were followed by contacts with other organizations involved in particular




aspects of the problem.  Often, the interviews would trace two different paths




of response to the contamination problem:  the local and health agencies




concerned with supplying safe drinking water, and the state environmental and




EPA offices responsible for finding and halting the source of contamination.




As many as eight agencies were contacted in the course of a single case study.




    Both the site visits and the extensive telephone interviews were structured




around a general set of questions.  The interview format was tailored to each




case and each agency involved to maximize the amount of detailed information




gathered and to avoid redundant questioning.  The use of interviewers know-




ledgeable about municipalities' problems with organics in drinking water




allowed some flexibility in studying each case and eliminated the need for a




formal, more limited interview methodology.




    A sample set of questions, included as Appendix B, shows the type of infor-




mation typically gathered.  The sample questions are divided into categories




including general information,about the contamination problem, how the-




organics in drinking water were detected, how the scope of the problem was




evaluated, and what actions were taken in response.  This list of questions




was developed to guide the interviewers.  It was not used in a survey context.

-------

-------
                         III.  ANALYSIS OF CASES


    A case study was written on each of the ground-water contamination inci-

dents investigated through site visits and telephone interviews.   The full

description of each case is included in Appendix C.  The. description of the

cases studied through site visits are of course more detailed than those

studied through telephone interviews, but both types are organized in the'fol-

lowing format.
         Summary
         Discovery of the Contamination Problem
         Actions to Protect Water Quality
         Current Status                     •
         Institutional Involvement
         Health Guidelines
         Conclusions
The case studies provide useful accounts of the chronology of events, the fac-

tors contributing to decision-making, and the problems encountered in response

to each incident of organics in ground water used for public drinking water

supplies.  The overall progression of events and organizational responsibili-

ties in the cases should be helpful in, explaining how a typical contamination

problem is handled;  A detailed source list of over eighty persons contacted

for information on the cases is included as Appendix D.

    To allow examination of trends and problems in particular aspects of

ground-water contamination cases, the important factors in each case were also

broken out horizontally.  Topic areas addressed include the contaminants •

involved, usual sources of ground-water contamination, the means by which con-

tamination was detected, whether aquifer contamination could have been pre-

-------
                                  III-2
vented, actions taken in response to contamination, and a comparison of various

state health guidelines.  Section IV contains an in-depth discussion of the

technical problems encountered in ground-water contamination cases.
Organic  Contaminants Detected

    The scope of this study was limited to cases of drinking water contamina-

tion caused by organic chemicals in ground water.  In both the preliminary

data collection effort and the final set of case studies, trichloroethylene

was, by far, the most prevalent synthetic organic compound present in ground-

water supplies.  The preliminary survey indicated that fifty to eighty percent

of the cases screened involved trichloroethylene, often in conjunction with

other organics.  In the 15 in-depth studies, eighty percent of the sample

cases involved trichloroethylene; other organics were present in greater than

trace amounts as indicated below.
                                              Highest Level Detected
                                Occurrences   .    in  Public Well
   Trichloroethylene
   Tetrachloroethylene
   1,1,1 trichloroethane
   1,2 dichloroethane
   1,1 dichloroethylene
   cis-1,2 dichloroethylene
   trans-1,2 dichloroethylene
12
 7
 5
 3
5,700 ppb
  375 ppb
1,500 ppb
   12 ppb

   79 ppb
    Single incidents of contamination by vinyl chloride,  methyl tertiary butyl

ether, diisopropyl ether, phallates and dioxane were also noted.   Several

associated or degradation compounds often present at lower levels than the

"primary" organic contaminants were not always reported,  on the assumption

that they would also be controlled by whatever means was  chosen to control the

"primary" contaminants.

-------
                                   III-3
    As shown, trichloroethylene was, by  far, the most ubiquitous  contaminant


 reported.  The  insights gained through the case studies  indicate  that  the


 majority of contaminants reported generally as "organics"  or  "solvents"


 probably are trichloro'ethylene, with trichloroethane or  tetrachloroethylene


 being the other most prevalent compounds.


    Trichloroethylene  (TCE) seems to have become the "reference standard"  for


 organic compounds  in ground-water contamination, although  other studies have


 mentioned that  1,1,1 trichloroethane is  the compound most  often detected in

                                !
 certain states.  Several offices reported that the presence of TCE  is  generally


 used as an indicator for more hazardous  compounds usually  found in  much lower


 concentrations, such as 1,2 dichloroethane.


    It also should be noted that levels  of organic contamination  in industrial


•or private wells were usually higher than in public wells.  This  occurs because


 the industrial  wells are closer to the contamination site  and because  the  more


 numerous private wells are usually completed in shallower, more vulnerable


 aquifers.  Most states have regulations  mandating an undeveloped  zone  around


 public wells, but  private wells have traditionally been  less  protected.


 Additionally, private wells are more common in the older parts of municipal


 areas, where medium to heavy industry has often been operating (and using


 organic solvents)  for many years, than in the newer suburbs.


    In the cases studied, it would not be unreasonable to  state that at least


 five to ten private wells were known to  be contaminated  for every municipal


 well contaminated  by organics.  Although fewer persons in  municipal  areas  rely


 on private supplies than on public drinking water, the degree of  contamination


 is usually significantly higher.  For this reason and since the option of


 connecting to public water is usually available in municipal  areas,  steps  to

-------
                                   III-4
 protect  private well  owners  should be  considered when organics contamination

 Is  detected  at public wells.  The County Health Departments have usually super-

 vised  testing of private wells, while  State Health Departments oversee public

 water  supplies.
Sources of Contamination

    Several definite trends were observed in the sources of organics contribut-

ing to  ground-water contamination in the final set of sites studied.  The table

below displays the frequency of occurrence for five categories of sources.

Note that  some sites were contaminated by more than one source.

               Confirmed or Suspected Source            Cases
            Airport/military base or contractor
            Plating industries
            Electronic industries
            Landfills/chemical waste handlers
            Other industrial
5
4
3
3
3
In all cases where a source was confirmed, either the use or disposal of sol-

vents or degreasers was mentioned as the cause of ground-water contamination.

    The list above suggests the type of industries that should be investigated

for potentially hazardous organics use and disposal practices.  In the experi-

ence of several state officials, wherever TCE has been used in any significant

quantity, a problem exists.  More specific point sources that were found in

follow-up investigations at the above sites were leaking underground storage

tanks, dry well/pump disposal of used solvents,  and chemical tank or barrel

rinse areas.  No contamination incidents were reported as the result of one

isolated spill, but many cases were reported where continuous disposal took
                                                      '               ''  s~
place over several years.

-------
                                  III-5
    In the dozen cases where a point source was identified,.actions.were taken

to eliminate that source.   The organics still contained in the unsaturated

zone remain in many cases  as non-point sources, contributing to contamination

in the saturated aquifer zone with every major .rainstorm.   Above-ground ...

sources, however, have been controlled and are in most cases being strictly

monitored.                        .r           ,



Discovery of Ground-Water  Contamination      ..........

    The presence of organic compounds in drinking water wells was discovered

by a wide variety of methods in the cases 'studied.  The following table shows

how many contamination incidents were detected by each of, five methods.

             Method  of Discovery of Organics         Number of Cases

             State/County Monitoring Program   ..        ,       4   ,  .•
             Contamination Suspected         '                  4
             Accidental Testing      .                        ,,4
             Testing for Trihalomethanes                       2
             Federal Monitoring Program                        1


    The federal monitoring programs have turned up many cases of organics

contamination nation-wide, but these programs were usually involved only

indirectly, by heightening awareness of potential ground-water quality

problems, in the cases examined in this study.  Several incidents of organics

contamination discussed in this report were discovered by state monitoring

programs, and many more are likely to be discovered as more states begin .

testing public water supplies.  Budget constraints and limited laboratory

capacities are major factors hindering state monitoring programs.

    Somewhat surprisingly,. in several of the water systems studied, synthetic

organics were discovered while testing for .trihalomethanes.  Trihalomethanes

-------
                                  III-6
are rarely found,in well water supplies due to the lack of organic 'precursors




(humic and fulvic acids) in ground water and less frequent chlorination.  The




four water systems that were suspected of containing organics were tested




because of taste and o.dor complaints or because organics were detected in




nearby industrial wells or ground-water supplies.




    In four of the fifteen cases studied, contamination of public water




supplies by synthetic organic compounds was not particularly suspected.  The




thought that over twenty-five percent of these cases of ground-water contami-




nation were discovered accidentally is not a comforting one.  Unfortunately,




no data were available on the frequency of negative test results which could




be used to estimate nation-wide trends in contamination.









Prevention of Ground Water Contamination




    In few of the cases studied could a simple action have prevented aquifer




contamination, since the organics release was not usually confined to a single




point source.  The cases with leaking buried solvent tanks, Vero Beach and the




Great Oaks Water Company, however,  could have been easily prevented,  if the




leaks had been detected either by some simple accounting of the amount of




solvent delivered,  used, and stored or by occasional pressure tests on the




tank systems.  The gasoline tank leak in Rockaway Township that spilled




thousands of gallons could also have been prevented by either of these methods.




    The majority of the cases studied involved the use of thousands of gallons




of solvents/degreasers over a five  to twenty,year period.   Several of these




sites even halted most operations ten or more years ago, but the organics are




still present in ground water in high enough concentrations to cause  concern.




Of equal concern is the length of time that people in some areas had  been

-------
                                  III-7
drinking organics-laden water.   Avoiding problems of this magnitude would have




te'qUlffed a complete change-over in handling and disposal methods for chemicals




many years ago, rather than any simple preventative steps.









Actions Taken in  Response to Contamination




    Actions taken in response to the discovery of organic contaminants in




drinking water range from Glen Cove's closing wells to Rockaway Township's




installation of granular activated carbon adsorption contactors and a packed




tower aeration column.  Table III-l displays the immediate, short-term, and




long-term actions taken by each system to provide high-quality drinking water




to their customers.




    The typical response on the part of a water system was to confirm the




initial tests that showed the presence of organics, notify the appropriate.




state health or environmental agency, and close the wells showing any signifi-




cant amounts (with the definition of 'significant' varying from 0 to 75 ppb)




of contamination.  The next step was usually to notify the public of the




problem and meet with county and state health, state environmental, and any




regional agencies with jurisdiction over water quality to plan a coordinated




response.  By this time, the system might have had to purchase water (at rates




ranging from 2 to 5 times normal costs) from neighboring interconnected




systems, or implement water use restrictions.




    In an ideal response, investigations to trace and control the source of




contamination would parallel studies of alternatives for supplying uncontami-




nated water.  These alternatives would usually include drilling new wells or




providing treatment by carbon adsorption or an aeration technique.  Two impor-




tant, factors enter this decision:  the cost and availability of new well sites

-------
                                              III-8
                           to
                           0,    o
                                          0}
                                          >
                                                    a,
                                                          «
                                                      Ol
                                                      c

                                                      c
                                                      c
                                                      CO
                                                                O
                                                                z
                  a)

            I    2
                           I
                                          o   o
                                     o   —   —
                                                O
                                          0   —    0
                                                     o
                                                     —    o
                                                 O
                                                z
                                                                                              O
                                                                                             z
   CO 0)
   I- 6
   O •"->
_ Q.CO
O E CD
  . CD t-
     "


5



*   <-
CD   01
                            O
                           Z
                                1    <
                                                                     OJ

                                                                    .a
                            0)
                                 o
                                z
                                                                                                   O
                                                                                                   Z
                                                                01

                                                                -Q
                                                                                         .4J
                                                                                         O
                    _
                 ces
                       £
                                           03
                                           >
                                            0
                                           >
                                                                                                    
O O.T3
   O.CD


Ct7> O
Q3   Q3

o t- c
t_ CD t

03 «•
O. to
                            o
                            VO
                                                 OJ
                                                 OS
                                                                          o   o
                                                                          o  • o\
CD
<
O
u

o

z

u

o

o
I-

tn
LU
V>
Z
o
a.
V)
UJ
cc
             T3
             03
             m
                                 g
O
o
cc
                                       I
                                                 o
                                                 o
                                                           c
                                                           c
                                                           CD
                                                           a.
                                                                                     C
                                                                                     O
                                                                       0>
                                                           t!   2
                                                                0)
                                                                >
                                                                            c
                                                                            o
                                                                            to
                                                                            o
                                                                          .  3
                                                                                     •o
                                                                                      o
                                                                                      o
                                                                                    •3

-------
                                  III-9
and the required quality of the treated water.   Since no single numbers, have

been widely accepted as reasonably safe and attainable levels of contamination,

systems often opted for the more certain choice:  a new source of water.  An

engineering contractor usually designed the treatment system or placed the new

wells.  Except for the companies doing business in carbon systems, most

consultants have preferred aeration technologies when drinking, water treatment

is the chosen alternative.                       -    .    '     ;

    The investigations into the source(s) of contamination usually involved

sampling private wells and drilling monitoring wells to determine the extent

and magnitude of organics in ground water., • A consulting engineering firm was

often used for this step although .the. state agencies or EPA occasionally pro-

vided investigative teams.  A scenario frequently observed was the investigator

tracing the contaminant plume toward a particular industrial sitej but not

being able to conclusively prove responsibility for the contamination.  In

only three of the'fifteen cases studied did the suspected- culprit cooperate

willingly and aid on-site surface or drilling investigations to trace the

source.  In a few cases no real progress has been made, but some progress has

been made in most cases, as shown in,the following table.


                                     Investigations         Investigations
                                     Concluded            Continuing

  No Success in Tracing Sourcce           -'...-.
  One Source Suspected         .           2                     3
  One Source Confirmed                    4                     -
  More than One Source Suspected          2                     4
  More than One Source Confirmed

-------
                                  Ill-10
Health Guidelines




    The lack of detailed information on the health effects of organic chemicals




in drinking water and the corresponding lack of consistent guidelines were the




major problems faced -by the states and municipalities in dealing with ground-




water contamination cases.  Only a few states, such as New York, have gone




beyond reviewing the array of health effects numbers published at one time or




another in the Federal Register.  Table III-2 shows the variety of concen-




trations allowable at certain risk and exposure levels for trichloroethylene,




the organic most often detected and used as an indicator of contamination.




Not only do health officials have a lack of confidence in this type of risk




estimation, but they also have a variety of methods for applying the




information.  Consequently, as shown in Table III-3, the maximum contaminant




levels recommended in state guidelines for trichloroethylene range from 0 to



75 ppb.




    The implications of the uncertainties and inconsistencies in health guide-




lines for organic chemicals found in ground water are major.  Most obviously,




customers of some water utilities are subject to higher toxic and carcinogenic




risks than others.  Secondly, the health guideline levels greatly affect



actions taken and expenses incurred in protecting water quality.  If all the




cases studied had been subject to a recommended TCE limit of 75 ppb, half would




not have had to take action besides closing a few wells, and five or six water




supply crises would have been averted (although public pressure might have




forced stricter measures).  Thirdly, because of the uncertainties in health




guidelines and the possibility of a standard being set, water operators were




afraid to take assertive actions, and they were especially hesitant to install




engineering control technologies to reduce contaminant levels, for fear of

-------
                                 Ill-11
TABLE 111-2

TOXICITY  AND  CARCINOGENIC. RISK GUIDELINES
FOR TRICHLOROETHYLENE
              EPA Suggested  No Adverse Reponse Levels  (SNARLs)

        Length of Exposure      Concentration  in  Drinking Water tppb)
              One-Day                           2000
              Ten-Day                            200
              Chronic            "       '•' • ••"    75 "•
                Drinking Water  Exposure for Carcinogic Risk

                                 Concentration  in-Drinking Water Cug/1)

   Projected  Upper Limit        National Academy          EPA  Carcinogen
Excess Lifetime  Cancer Risk    of Sciences (NAS)     Assessment Group  (CAG)

  1 in 10,000    (10~4)   .•'•'•      450                      280
  1 in .100,000    (10"S)       ,  ;        45   ,    :-  ,   ,           28  ;.
  1 in 1,000,000 (10"S)  "                4.5         '"             2.8
Assuming;  Lifetime  exposure (70 years)  by 70 kg adult/ consumption' 6'f 2  litres
           of water  per day.

-------
                                  111-12
TABLE 111-3

SUMMARY  OF STATE GUIDELINES FOR
TRICHLOROETHYLENE IN DRINKING WATER
    State

Massachusetts

New Jersey


New York



Pennsylvania


Florida

Indiana

Michigan


Minnesota

Arizona

California


Washington
    Locatiorv

Bedford

Rockaway Township
S. Bunswick Township

Garden City Park WD
Glen Cove
Vestal

North Penn. Water
  Authority

Vero Beach

Elkhart

Battle Creek
Petoskey

New Brighton

Tucson

Great Oaks Water
  Company

Lakewood WD
          Recommended Maximum
       Contaminant Levels for  TCE

                 75 ppb

any single VOC-50 ppb, total VOCs 100 ppb
                 33 ppb

any single VOC-50ppb,  total VOCs 100 ppb
any single VOC-SOppb,  total VOCs 100 ppb
any single VOC-SOppb,  total VOCs 100 ppb
originally 4.5 ppb,  now 75 ppb

               0.00  ppm

originally 75 ppb, now 45 ppb

minimizing exposure  suggested (0 ppb)
minimizing exposure  suggested (20 ppb)

                 27  ppb


                 5  ppb


                 5  ppb

no guidelines, handled case-by-case

-------
                                  111-13
over- or under-designing.   The officials contacted were confident in the capa-




bility of treatment technologies to remove organics from drinking water, but




were uncertain about what removal efficiencies to specify.




    In short, the lack of consistent health guidelines is the major obstacle




to state and municipal officials responding to organic contamination of' ground




water used as a drinking water source.  Many different interpretations of




health effects information by state officials have confused local water systems




and caused great public concern.  Section IV elaborates on the need for




additional  health effects research.

-------

-------
                   IV.   GROUND-WATER CONTAMINATION
                    '    RESEARCH AND DEVELOPMENT


    An important objective  of  this  study was to  identify research needs

relating to the detection and  control  of organics  in ground water, particularly

in aquifers used for public water supplies.  This  section discusses research

needs either mentioned by the  municipalities or  state  organizations or  inferred

from the case studies.   The discussion is  organized into five  technical and one

general area.  The areas discussed are the following:


         ••  Analytical Procedures for Monitoring Contaminants
         •   Determination  of  the Extent and Source of Contamination
         •  ' .'Engineering Control Technologies
         •   Aquifer Management Technologies
         •   Health Effects
         •   Other Needs


These topics were defined to parallel the areas'addressed  in EPA ground water

research plans.



ANALYTICAL  PROCEDURES FOR MONITORING CONTAMINANTS

     The analysis, of how the presence  of organic contaminants in ground water

was actually detected  in the  cases studied, discussed on page III-5,  provides

some interesting insights.  Only one  of the fifteen cases was detected through

a federal  monitoring program, while six cases were detected either accidentally

or during  voluntary (not required) testing  for  trihalomethanes.  Many water

utility officials,  especially in the  Northeast, were  in favor of broadening

mandatory testing programs for  organics in  ground water.  'These officials were

 generally of the opinion that many of their neighboring systems had problems

 with organics  but either were afraid  to test  in the first place because of the

-------
                                    IV-2
 potential cost of treatment, or had tested and found, organics but chose not to

 report the test results to the State water quality "agency or the public.
         *'
    The following breakdown shows the laboratories finally used for the major-

 ity of the analytical work in each case:
                     Primary Laboratory

                          EPA
                          State
                          County
                          Private
Cases

 2  -
 6
 2
 5
                                                     15
    The quality of EPA labwork was generally reported as quite good but delays

in performing analysis were common.  As a result, if EPA labs were used, it

usually meant that no other alternatives were available or affordable.  In

several cases, municipalities switched from public to private labs for faster

turn-around;  The State laboratories were also reported to be consistently

competent, but in every case, personnel, equipment, or budgetary constraints

slowed response time and limited the number of analyses that could be per-

formed.  At Battle Creek, for example, the state health department pould only

spare a dozen sample bottles every two weeks, so it took many months to deter-

mine how many private wells near the public wellfield were also contaminated.

Nassau County, New York was the only county studied with organics analysis

capability.  Since more people live in Nassau County than in several states

and since ground water is relied upon almost exclusively for public supplies,

it is not surprising that the County Health Department has had the capacity

not only to handle virtually all the water quality testing, but to revise and

improve several EPA laboratory methods.

-------
                                   IV-3
    All but one of the water systems that turned to private labs for organics

analyses faulted the quality of at least one lab used.  Especially in the cases

detected from 1978 to 1980, reproduceability of test results was poor.  Analyz-

ing and reporting extremely low concentrations of organics was also a weak

area.  Water systems often ended up "shopping around" to find good quality

analytical services at a reasonable cost.  Fortunately, laboratories performing

organics analyses have improved over the past several years, and most of the

water systems are satisfied with the quality of recent test results.  Split

samples are usually taken as a quality control measure.  Sampling procedures

are not regarded as a technical weakness.

    Monitoring of water supplies after an incident of contamination has been

discovered is generally not a problem area.  Once the municipalities studied

detected the presence of organics in their water, frequent monitoring was

always instituted to maintain water quality.  Three factors usually-influenced

the decision to monitor -frequently:  the personal responsibilities felt by

water officials, recommendations from the state health agencies, or public

concern over the potential health hazards.             '

    In the areas of testing, sampling, and monitoring, several needs were

voiced.  The first general request was for more funding for equipment and

qualified .personnel.  The second set of  requests was organized along more

technical lines, summarized in the following points.


         •   A one-time nation-wide program of sampling finished ground water
             for organics should be instituted, with priority given to water
             systems located near large-scale users of industrial solvents.
             Michigan, for .example,  has begun a state-wide survey, beginning
             with the most vulnerable systems in each district, with sampling
             priorities set by the district engineers familiar with local
             problems.  The national monitoring surveys already performed

-------
                       IV-4
 should be  analyzed to  isolate common factors involved in organic
 contamination of ground water, so that priority sampling can
 begin.                               .

 Several water officials mentioned a need for revised sampling
 and testing procedures to include more organics.  Current standard
 methods'are viewed as  time-consuming and expensive, although
 generally  adequate, but they need to be simultaneously expanded
 and streamlined.
The development of a general screening method for organics was
suggested as a valuable tool by the director of the Michigan
Department of Health laboratories arid others.

A frequently heard complaint concerned the reporting of trace
amounts of organics.  EPA was requested to standardize a policy
regarding lower detectable limits to avoid reports of "suspected
trace amounts" of a particular contaminant that might not actually
be present, complicating investigative efforts and further
upsetting the public.  Reports of organics present below detecta-
ble limits are felt to be unfairly slanted towards implying the
presence of a chemical.  Research in this -area must be associated
with the health effects of various organics found in ground water.

The water utilities who -used private laboratories want to see
expanded laboratory certification programs.  Even state labs could
often improve.quality assurance programs, although most appeared
to be very conscientious about professional standards.
Sampling procedures were reported as adequate in most cases,
but several officials thought that the "trace amounts" of chemi-
cals occasionally reported from analysis were due to cross-conta-
mination during sampling or to ubiquitous compounds present in
the laboratory.

Other minor problems with sampling, especially the difficulty
in sampling for volatile organics in deep wells, were brought up
as problems, some of. which could be remedied by well design.

Searching for abandoned wells was a problem in about a third of
the cases studied.  The potential of abandoned wells as hidden
sources of contamination, as perforations through confining clay
beds, or as additional data sources for aquifer sampling was men-
tioned several times.  The basins containing the Lakewood and
Great Oaks water systems, for example,  are estimated to contain
over 5,000 and 9,000 wells, respectively, but no one knows the
exact numbers or locations.                     .

-------
                                   IV-5
DETERMINATION OF THE EXTENT AND  SOURCE  OF CONTAMINATION




    Several technical topics are addressed under the above heading, including




methods for determining the transport and fate of organic contaminants and




characterizing the hydrological/geological features of the saturated and




unsaturated zones.  For purveyors of ground water, these topics are important




in both determining the local extent of contamination (necessary for choosing




locations for new wells) and for planning measures to-prevent the migration of




organics to other production wells.  These topics are also critical in tracing




plumes of contaminants back to their sources.




    As discussed earlier, most of the utilities studied had difficulties in




outlining the extent of contamination and tracing the source'.  The cost of




putting down monitoring wells in some regions is very expensive, limiting the




number of data points available for decision-making.   The relative lack of




information on the transport and fate of chemicals in the subsurface also




hindered investigations.  Several utilities,  such as  the towns of Vestal and




Bedford, described their ground-water investigations  as  "basic" or "textbook,"




but most faced technical and/or budget constraints.   In  several cases,  such as




Lakewood,  Petoskey,  and Lansdale (North Penn Water Authority), anomalies in




the local geology severely complicated efforts to outline the extent and trace




the source of organics contamination.




    The municipalities studied usually had a ground-water consulting firm,  or




occasionally the state water quality agency,  conduct  the actual investigations




to determine the extent and source of contamination,  and therefore were not




directly involved in the technical aspects.   Several  general  areas where the




utilities  or their consultants did request more research and  information are




summarized in the following points.

-------
                                  IV-6
            The most frequent request for research was on the transport,
            detention, and degradation properties of various organic chemicals
            in both the saturated and unsaturated zones.  Existing information
            is, at best, fragmentary, and predictions of the mobility and
            transformation of organic contaminants in ground water are not
            nearly as accurate as predictions for inorganic compounds.

            Of .particular interest are the degradation products, in indus-
            trial processes and subsurface, of ubiquitious organics such as
            trichloroethylene and trichloroethane.  Ground-water investigators
            have a definite need for data relating organic compounds found in
            low or trace concentrations to those found at higher concentra-
            tions, especially to-confirm or deny conjectures that only one
            source of contamination is involved.

            Several ground-water specialists stressed a need to design sub-
            surface sampling investigations around predictive ground-water
            flow and transport models, rather than to apply models to existing
            data.  The consultants interviewed claimed they occasionally used
            in-house models, but the time and expense involved in verifying
            the predictive capabilities of most models were often better spent
            on pump tests and other forms of data collection.  No state agen-
            cies involved in determining the extent and source of contaminants
            in ground water reported using models to predict the behavior of
            pollutants in ground water.

            Both the parties conducting contamination source investigations
            and the suspected contaminators asked for the development of
            standard methods for monitoring well placement  and sampling to
            support or deny charges of polluting an aquifer.  "Standard,
            accepted practices"  are required for credible data when munici-
            palities have to go  to court to recover damages  from alleged
            sources.

            The capability to conclusively  identify  a compound  found  in
            ground water  as emanating  from  a particular source, by  some type
            of "chemical  finger-printing" method, was one area  of R&D
            requested by  a few organizations.   No one knew  much about the
            technology, but most thought  it would save  investigative  and
            legal  time  and money,  especially in cases such  as the Tucson
            Airport problem, where more  than one  source is  now  suspected.
ENGINEERING CONTROL TECHNOLOGIES

    Although only one of the water utilities studied had implemented a"full-

scale treatment plant, most officials agreed that engineering control techno-

logies were fairly well advanced.  In all the cases studied, treatment to

-------
                                    IV-7
 remove organic compounds from drinking water was at,least considered, and one




 or two systems may yet install treatment plants.  B,etween, the consulting




 engineers and the lead agency handling each case, enough basic technical infor-




 mation was usually available.  These sources credited EPA for performing some




 very useful research in the field.




     By coincidence, at two of the cases studied EPA pilot projects are being




 conducted.  At Glen Cove, New York, pilot studies are being conducted at one




 contaminated well to compare removal efficiences of resin and granular acti-




 vated carbon adsorption and air-stripping techniques.   Work is also .being




 carried out to test regeneration methods and the effectiveness of regenerated




 adsorption media.  At the North Penn Water Authority in Lansdale, Pennsylvania,




 a pilot study of in-well aeration techniques is in progress.   The potential of




 this technology was discovered when samples of organic-contaminated water were




 air-lifted out of wells and found to have reduced levels of volatile organics.




     Three types of comments were received about the state of research on engi-




 neering control technologies.   The first was a request for updated cost infor-




 mation and the publication of more technical data on the major.methods of




 removing organic solvents,  mainly granular activated carbon (GAG) adsorption




 and packed-tower aeration processes.   The second request was  for more field




 work and demonstration projects on the techniques already proved in the




 laboratory.   This type of research is necessary to provide design information,




 costing,  and actual removal efficiencies under field conditions.




     The third research-related request was for a decision on  the levels  of




 contaminants allowable in drinking water so that design specifications can  be




 set.   Engineers are afraid  of  under-  or over-designing-treatment plants,  in




•the face  of  uncertainties about what  level of  organics  removal must be

-------
                                   IV-8
obtained to meet health standards.   This belief is certainly one reason why




more water treatment systems have not been installed.   The only beneficiaries




of this -uncertainty are lessors of temporary treatment systems.




    To reiterate, local and state water officials feel that engineering control




technologies have been fairly well proven and only require updated process




costs and some field demonstrations.  The majority of water system operators




contemplating treatment are leaning towards some type of packed-tower air-




stripping to remove volatile organic compounds.  One significant problem is




the  lack of solid standards or guidelines for organics, which hinder design




specifications.  Overall, better dissemination of information on technical




research and on  the GAG and aeration systems currently in use  is needed.
 AQUIFER MANAGEMENT TECHNOLOGIES




     Several  technical  areas,  categorized here  as  "aquifer management technolo-




 gies" and separate from the  treatment methods  generally  referred to as engi-




 neering control technologies,  were  also discussed by  the officials contacted




 in the cases studies.   Some  type of aquifer  management was  considered in about




 one third of the cases studied.   The technologies discussed here deal with




 aquifer rehabilitation or with shifting the  plume or  zone of contamination.




     Aquifer rehabilitation,  including  restoration of  both the saturated and




 unsaturated zones, involves  two technologies:   either in-situ or surface treat-




 ment of the contaminated water and purging the unsaturated  area of contamina-




 tion, combined with removal of the source of contamination.  This  type  of




 remedial action, although expensive, is  sometimes necessary.  The  third techno-




 logy under this category involves designing pumping patterns or injection




 strategies to keep the contaminant plume away from production wells.   In most

-------
                                    IV -9
of the cases studied, the water  utility pumped contaminated wells to'waste to




keep brganics from migrating  to  uncontaminated wells.  "      ••.•.•-.•...'•  ?•:. :•.--..




    A definite need exists  for research on aquifer rehabilitation"' technologies.




At ten of the sites studied,  production wells  are or were being pumped to- waste




(only three water,systems or  industries treated the contaminated water before




discharge), but no plans for  reinjection have  been approved^ and no'work has




been planned 'to purge the unsaturated  zone.  The present literature reflects




only a recent interest in this' country in restoring water" quality in the'




aquifer, so specific needs  cannot be 'easily addressed.   Frbrrf'ther c'ases-studied,




only the general need for more research'on this' topic' can !be reported.'  A major




reclamation project, however, is being planned at the Tucson Airport site that



should provide useful data.      ' '   '     '>••'•   '  .:   •..,;. .:/.  .. .  -.,- .._ < •-•




    As mentioned, two-thirds  of  the systems-studied" decided'to pump contami-




nated production or mentoring wells to wa'ste,  usually to prevent 'migrataon of




the contaminant plume rather  than to restore the aquifer'.- -''Plans to reinject




treated water were considered at four  or five  sites,  but rej'ected by EPA or




the lead agency because of  the fear of altering aquifer flow patterns'-and fur-




ther dispersing the contaminant  plume.  'At Battle Creek a s;tudy'by USGS'




investigated the possibility  of  injecting water between the'city's  well field




and the source of contamination  to create a  mounding effect to prevent :further




migration of contaminants toward the-well field;         ••••'.'•'




    In summary, although decisions to  pump contaminated wells"to waste are




rarely controversial since  current practices are not'being changed-  the-7 tied-




sions are often made after  considerable'delay'and without sufficient informa-




tion.  Few experts seem to  have  enough confidence in injection and'monitoring




techniques to reinject treated water.   Enough  interest  has been expressed,

-------
                                   IV-10
however, by the states and municipalities to justify increasing research on




aquifer management technologies beyond hazardous waste site cleanup and preven-




tion.  Information on the costs of aquifer rehabilitation techniques relative




to other alternatives for restoring water supplies is especially needed.
HEALTH EFFECTS




    More than any other area, health effects research was unanimously suggested




as the topic on which municipalities, states, and the Regions most desperately




need EPA assistance.  Only the federal government, and possibly a few states,




have the capability to carry out the toxicity and carcinogenicity studies




required to provide the data for determining the relative hazards of various




contaminants at different levels of concentration.   In making decisions about




ground water quality  solely to protect public health, optimum choices simply




.cannot be  made  if the major criterion,  is  unknown.




    First  and  foremost, water  agencies need more information on the  acute  and




 chronic health effects of the  most common organic  contaminants.  Realizing that




 some  of this  research is  completed or  in progress,  the next need that must be




 met is reporting the  results  on two levels.  The major effort  at distributing




 health effects information  should be concentrated  on the usual  technical




 reports  intended for  scientists and health specialists to assist  in their  deci-




 sion-making responsibilities.   The second level of reported results needs  to




 be in a version that  the general public can understand.   The misinformation




 and misconceptions common to most of the cases studied created many difficul-




 ties for  local officials who often were not able to explain to citizens what




 the health effects of drinking contaminated water might be.  In support of




 regulatory development and to assist officials in the field, the completion of

-------
                                    IV-11
health, effects research,  especially on the organics"prevalent in ground water,




is essential.  The need;to  then  provide understandable .information to the




public must be emphasized:'  <   ./   .          . ,           ; •;-•>  ; •,-,  -, ,




    A somewhat surprising finding of'-this' study-is that'.the majority of .the




dozens of local and state water  quality and health officials interviewed1were




in favor of nation-wide standards for  the volatile organic compounds most fre-




quently encountered.   In  a  dramatic turnabout since the proposal "'of • .maxoLmum




contaminant levels for trihalom'ethanes, almost all those/involved in the case




studies favored standards for  organics, for: several reasons. 'The two reasons




heard most often were  to  protect the' public'health as much' as possible, and to




finally be able to supply-'water  designated as ''safe", by the^federal.government,




for the comfort-of water  officials and especially to.'satisfy the public's




concerns.              -•.-•.•'iis-  ....;•.v;   •...,.•  ,; ;.....  '    ,  ( •.-....•  -.-;; •• t.,: ,..,-...




    In about half of the  cases studied, the existing SNARLs;-by. EPA- or the




estimated increased carcinogenic risk  levels determined by. MAS were not under-




stood.  The difference between the SNARLs and risk level numbers was one-of




the problems:  many systems did  not differentiate between the two .sets o,f num-




bers proposed for several organics,  and even used them, interchangeably.  In




the New Jersey cases,  a wide, range of  "health numbers"-were recommended to




different municipalities.   In  the-Elkhart,! case,  every agency invoIved had their




own number, each of which had  been published somewhere, for. .allowable .levels




of trichloroethylene in drinking water.,  It is. imperative that a .consistent




policy for carcinogenic risk assessment-be.developed -and that a consistent set




of health advisories on the most common organics  be issued under this,policy.




   • Whether nation-wide maximum  contaminant,levels (MCLs) are issued for




organic compounds in drinking  water or not,  recommended maximum contaminant

-------
                                   IV-12
levels (RMCLs) and supporting Wealth effects information are necessary for




municipalities to plan a response to organic contamination in ground-water




supplies and for the states to provide a basis for regulatory decisions.   The




fact that the need for consistent health effects information was the highest




priority request in the cases studied in this report must be underscored.
OTHER NEEDS




    Across the technical areas discussed above, several general requests were




made related to EPA research and development.  The three broad areas where




assistance would be helpful were in reducing the costs of dealing with organics




in ground water, disseminating more technical  information, and in providing




more trained expertise.  Advances in these general areas would improve overall




response to the ground-water contamination problem.




    First of all, cheaper  analytical methods,  less costly drilling and moni-




toring techniques, and more efficient and economic treatment technologies are




items  that everyone in the ground-water  field  would, of course, like to see.




The need  for cheaper, more efficient methods is hard to dispute.




    Equally important and  more  easily attainable  is the goal of improving the




transfer  of technical information.  The  major  sources  of technical  information




on topics  related to ground-water  contamination,  for the municipal water




systems  studied,  were the  state health and  environmental  agencies,  EPA  program




 staff, ground-water  consultants, and technical journals  and  conferences.  No




water officials contacted  mentioned the  EPA Clearinghouse for  Ground Water




 Models or the Ground Water Information Center  as  sources  used  for information.




 One of the primary sources in EPA of  technical and health effects information




 was through the Office of Drinking Water's  Criteria and Standards Division,

-------
                                   IV-13
which was found helpful in several of the cases.  Several ground-water consult-




ing firms have organized successful conferences to educate state and local




personnel about methods of detecting, monitoring, and resolving problems with




contamination of ground-water supplies.   This type of conference seems highly




valuable, and EPA should consider supporting similar programs.   However it is




accomplished, improving the transfer of technical information should be a high




priority.




    Especially in the state agencies and Regional offices, the lack of quali-




fied personnel was identified as a common problem.  The few-toxicologists and




hydrogeolegists employed by the health,  water, and environmental agencies are -




spread very thinly.  Where laboratory facilities for organics analysis are




available, qualified technicians often are not available, or are severely over-




loaded due to the drastic recent increases in sampling.  Traditional engineer-




ing training in water and waste water treatment is proving to be insufficient




as new health hazards (carcinogens) are turning up in water sources formerly




considered pristine.  Some type of updated training in the skills required to




deal with ground-water contamination would be an interim solution to a problem




that over time must be addressed on a broader scale.

-------

-------
                                V.   CONCLUSIONS

       The majority of effort in this .study was„ concentrated.,,qn .gathering, infor-
   mation for detailed, studies of ground-water,,contamination cases. .The  full
   case studies should be a valuable resource for those, setting research,and pro-
   gram priorities in the field of ground  water.   An analysis of; characteristics
,.  common to most of the cases .provides  insights  about pptenfia^, £rends ;-in ground-
 . . water .contamination..            	     ,.,,.,,,... ,..   .« ,-„„-.,  .,...,
    - '  -        •   • •           •- •   '• -	.•'...-..  ..-,. ..:.....) .•:,-. - ...,-..t..-4 .;.,'.>•,.
       Organic solvents were, by far,  the  most frequently, discovered contaminants,
 ,  with trichloroethylene reported as  the  mos.t ubiquitous, organic,  c.pmpoun'd .  .
   detected, appearing in eighty percent of  the cases,,^TrichJLpro.et^y.lene  is  becom-
   ing the indicator compound for monitoring and  treating^organics j.n drinking
   water.  State, monitoring .programs and.testing  initiated,by suspicions  of  con-
   tamination  from likely, sites, originally., led to., the, detection- of .the  contami-
   nants in the  majority of contamination  incidents studied,, .but ferity  percent of
   the ca^es were discovered accidentally  or while .Resting for.  trihalgmethanes.
   In terms of Identifying high-priority sites, privatei .andj  military aerospace
   industries  and airports were most frequently assppiate.d with ^organic ^contami-
   nation  incidents, followed, by  landfills, and che.mical waste,handlers,,.rrelectronic
   companies,  and plating  industries..  , Specific-.point-'Sources were u.sual.ly above
   ground  or ,buried  solvent tanks,  solvent baths,.or old,disposal.wells.or dump
   areas.                                        	:  ....   ...  ........  ;  , „  .  ... ,
       The case  studies  explain,  in detail,  the specific,actions taken  in
   response to the detection of  organic chemicals in drinking .water.supplies.
   Overall, most municipalities  responded.fairly .well .to the, si-feuation,: ^d no

-------
                                   V-2
major mistakes were made, but some problems were common.  The most frequently




encountered problem was a lack of understandable information on the health




effects of the organic compounds detected.  Decisions on water supply alterna-




tives and treatment options were very difficult to make without solid health




guidelines, so most systems simply closed the contaminated wells and looked




for new wells.




    The second part of this study focussed on the research needs of states and




municipalities confronted with organic chemical contamination of ground-water




supplies.  The research needs discussed by the water, environmental, and health




agencies were usually very general, but a few deficiencies in technical infor-




mation were commonly mentioned.




    By far, the major obstacle in choosing alternative responses to the problem




of organics in ground water was the paucity of health effects information and




guidelines.  Requests for increased research and dissemination of information




on the health effects of common organic compounds were virtually unanimous.




Testing, sampling, and monitoring were technical areas with fewer weaknesses.




Engineering control technologies for removing organics from drinking water were




considered to be fairly well advanced, although more field demonstrations wore




requested.  Aquifer management techniques also need more refinement before




rehabilitation of aquifers will be commonly accepted.  Few specific research




needs other than those discussed above were mentioned by the state and




municipal officials contacted.




    Finally, the in-depth case studies, data on incidents of ground-water con-




tamination, and source lists of the persons contacted at the many agencies




involved in these cases provide a firm basis for further investigations.  This




report is intended to provide  insights about the common problems and research

-------
                                   V-3
needs of states and municipalities dealing with ground-water contamination.




As Such, it presents the necessary information to examine particular aspects



of the problem in greater'detail.

-------

-------
                    APPENDICES
APPENDIX A:  Initial Survey Results

APPENDIX B:  Sample Interview.Questions

APPENDIX C:  Complete Case Studies

             Bedford, MA
             Rockaway Township,  NJ
             South Brunswick, NJ
             Garden City Park,  NY
             Glen Cove,  NY
             Vestal, NY
             North Penn  Water Authority,  Lansdale,  PA
             Vero Beach, FL
             Elkhart, IN
             Battle Creek, MI
             New Brighton, MN
             Tucson, AZ
             Great Oaks  Water Company, San Jose,  CA
             Lakewood, WA

APPENDIX D:  List of Contacts for Each Case

-------

-------
      APPENDIX A'




INITIAL SURVEY RESULTS

-------
                                                           A-2
8
                           CO
                           c
                           c
                           o
                           o

                           §
                            o
                           o
                            o
                            u
                            a
                             
 •a
  c
  3
  O
  13 —
   CD  a.
   •u  o.
   O  3
   CD  t/)
   (».
   a-  t-
   co  cu
      jj
   to  co
    O.C

   V£>  O
                                                                    •a
                                                                     (D
                                                                     ro >>
             o


             CD
                                                                     O t- CD OT3
                                                                   . <- CO C P
                                                                  OD 3 (DO     to
                                                                  t— Q.C    T3  —
                                                                  ON          CO  ~~
                                                                  ,- c a-   -.c  eu
                                                                     m    OJ     3:
                                                                     	  _: CD  C-
                                                                    > P  O —  CD  to

                                                                   CD T3 ti- —  CO  —
                                                                   >  t-     C —
                                                                   O  O  S-  3     CD

                                                                   WO  P  E  > OUJ
                                                                   —  CD  CO  O  O — O
                                                                   OCO  3:  CJ P Ol—
                       •a
                        0)
                       CD
                                      to >,
                                      C C
                                    I  — CO
                                    o co a.
                                    3 aiE
                                   c/) co o
                                         o
                                     • p
                                    cu	•
                                    c/l  3 CO
                                    co  to  to

                                       CO  Q.
                                    •a —  to
                                    c    —
                                    3 — -a
                                    <~  3
                                    C- tt_ CD
                                    Q) CO 4J
                                    o. to to
                                    3 CD CO
                                    W5 O >
                                                                                                     I
                                                                                                     Q.P
                                                                                                     3 CO
                                                                                                     to.C
                                 3 Q.S  >>
                                 0.3     P
                                    to   ^—
                                 O	
                                 p 3: —  co
                                    (/)  CD  3
                                 p     3:  a
                                 o o  o
                                                   o
                                                   a.
                                                   c
                                                   o
                                                   E
                                                   CO

                                                   c
                                                   O
                                                   O
                                                        c
                                                        3
                                                        O
a.
a.
3
to

P >>
CO —
J= CL
•p a.
   3
to to

— t_
 0) CD
                                     c c
                                     C—  I-  P
                                     O     O  CO

                                        c
                                     0—3  —
                                     .P.C  a  —
                                         O     CD
                                     •O  CO  <-  >
                                      CO  CD  O  O
                                     .C-Ci-_l

                                      (A  CO E P
                                      t-  p ra o
                                      a)  c CD CD
                                      to  co s- tt-
                                      3  C P<>-
                                        — to co
                                      — EC
                                      — CO > O
                                      CO 4J O P
                                       CDOT3 —
                                       4J     CD.IB

                                       >>; = -
                                       L — to  C
                                       a.  a.— =>
                                                    -a
                                                     CD
                                                     c
                                                     o
                                                                              E
                                                                              E
                                                                              O
                                                                              o
                                                     c/>  c
                                                         CD
                                                                      CD
                                                                      C
                                                                      UJ
                                                                      o
                                                                      I-
                                                                                                        to
                                                                                                        o
                                                                               O  X
                                                                               Q.J3
                                                                               0)
                                                                               1-T3
                                                                                  CD
                                                                               to  P
                                                                               CD  O
                                                                               (A  CD
                                                                               CO  O.
                                                                               O  X
                                                                                  CD

                                                                               O  to
                                                                               O CD
                                                                               ZCC
                                                                   CO
                                                                   O
                                                                   o
                                                                   z
      CD
      to








h-
3
u
1—
a
z
z
o
o
CU
,_
CO

s

C/}
c.
o

o
o


0.
Id
—
_
^
•a
c
CO


.2: .2:
S. CD
CO-
CO
— Ol
CO 3
t- CO
3Z
Ci.
•o
C
CO
— I


c
CO
a.
E
0
O
UJ C
z —
< s
s: £
I—
u
c/>
3


I
O3
0)
£
•a
 0}
CO
*
                                                                                                   LJ
                                                                                                   CC
                                                                                                   2
                                                                 
                                                                                                             >,
                                                                                                          CO C/?
                                                                                z
                                                                                o
                                                                                2:
                                                                                o:
                                                                                UJ
                                                                    Q
                                                                    O
                                                                    X

-------
                                     A-3
o
UJ
c:

5 c
•••
j
3 O CO
E — E
C 0
3 CO —
oin
: o2 •
Q.
13
3 CO 0
: JZ E
> o
i-CO
J r-
T—
3
3 -T3'
C 00-
to to E
0 O CO
JZ — t-
= V> 0 01
3 O
tv. 0 £_
i On a.

O Ol
• -P c

- OT3 P
) O CO CO
J O JZ 0
3 .- P

»— ^~ t.
r 0
:  CO —
.C -P
>> CO
0O\ 0
tOC\J 4J
1 • £.
i 0 * s_
, ~5 to CO
0 —
^ 13 3
0) — cn
z: o 0
— (_
C,- JJ
o to jr
0 01
•P Q.3
C 0
013 <-
O CO JZ
!- JZ 4J
0
D.I-T3
CO 0
CM !~ .'
. ^0
^t to >,
•P 0
In 1980-81
contaminan
state disc

















Ul
CO
o;
Ul
2
^



















CO
—

0


^
0
C

,o

4J
.-o
0
• —
'I.
Cl


.
•a
'affecte
CO


0
CO
a
0
'c
3
S
CO




0
C
0
JZ
0
0
Tetrachlor

















0
CO
-o
c
0
*£

























0
•o
—
to

3
0
•o
0
to
CO
0
c.
o
c
—•


ffected.
CO

CO
I
CO 0
a to.
— CO
O.C
— o
c <-
So.







Ul
o
i-

















c
CO
CO
u.



























.
T3
0
CO
O
Q.
O
&_
Q.
-
0
^

^
0
T3
0
to
O
— *
O

0
CO
Q.
0
C
3
s:





0
c
0
s:
Trichloroe

















CO
CO
s









































T3
0
CO.
O
—
o

0
CO
_Q.
O
•c
,-3.-
2:





0
c
0
jr
.P
Trichloroe

















C-
0
•a
E
CO "
O



1
i. •
013 f-
E 0 C 0
0— O -P
— fl —
T3 CO t- Ji-
0 lr> CO 1t-
I- to O
CO C .C
	 "O-O
O 0 —
0 p AJ .
T3 -'CO Q.E
>>> !- 0
>, 0 — O -P
.p C P CO CO
— 0 o n x
O Ol CO CO CO


—

0

c
T3 CO

— I_
JZ 0
1— C.
0

O —
co >> •
o a
r- 0 •.
(_
TJ Q.
0 O
to to
O —
0— ,
T3
to
0
0) ..
— U 0
CO CO T3
5.5 Z;
0 E 0
— CO —
C 4J JZ
3 C 0 ,
E 0
0 0.
CO C
I- .CO
O -P -P
CO CD
CM— E





0
C
0
4J
Trichloroe

















1 -
CO ,
O '
o
C£
*
Q.
3

C
CO
0

O

o:

p '
c
CO

•w ,
^ ';
• c
o •
Q'

















.
•o
0
p
ontamina
O:

to ,'•
0
;.IO
Ti)
(0






c.
,0
. JZ
Trichloroe



to
0
4J

CO


0) -P
C CO
0 *-
to . o
^ 3

0
X 0
c =
4J' tO
CO
0 <
— .. a.
a. ' ui






to
«.
^
0

O) •
c-a
— 0

o —
•P CO
— a
c to
0 C
S —


to


0 0

a.
O 0
0 -P
a. co

o —
o c-
O QL

CO >)
3 t-
O CO
n E

^
nation.
r DW. P
•— o •

(0
•CO
0 f
O OJ
^ CO
S3;-
.. CO :
.C 0
.0 !.
> CO' '
'O. —





0
C
0 0
— c
>>CO
JZ X
a 0
Trich'loroe
Toluene, H







a.
>j"~

t- tO 4J
;0 C C
'Q.S 3
000

a.
c o
00 —
v— 4J 4J
s 	 c
0 — 'CO
'Q.E^-
£ co.P
Q
^f
S
O

T3 r- a
• Ci- 3
n ro
<^ c
C- C CO
0 O 0
a. 	
3 -P O
to o
0 O
0 CO -P

J3 C
— . o
to 0 —
tO 4J 4J
o— o
Q- to CO


S
•Q
to
0 !-
•P O

to

*- 0
CO Cj-
0 —
C 3
O"
to O
— CO
0 T3
S 0
.p
— CO
CO C
a.—
O CO
._.4J .
c c
30
: E-o
c ;
• p
c
' O tO ••
— 0
f' E
'-. CO Q. ;
: c jz . .
r o to
-• o c -
^ ':* • ;
•« S-S .'
01-





13
0
CO
C
PCB, Chlor
Solvents
i
'•. c
. O'
,« E H-...
0 «-,
P eo -a
•— U.,t_ eo >>
C/3 '0 0 p
^H Q.4J C
= O U. to 3
•P C03 E O
10—3 3O
! 	 ,_
0 Q- E 0. C
3: i- co
^ CO *t 0
o E tj-"a o
o i- - — o
r- to 0 O
r 'c 0 a
CO 0'0 0. —
- CO-Q.S-JZ
< O CO U_ tO
uio

E
'0

n
o
t!
f^

. oi --
tC

•^O
••C •'• ;
?ro.

-«»
pit

€^-

•a
 -

CO '-P
C C
contami
Re's i del
O) '-•
— c

ivate we
trucked
f-'/
Q)
I|



LJ CD
O C
f- 0
0) O
c<
CD
3 -
— 03
O C
Benzene, Ti
Ethylbenzel










Q-.!


to-
c-

o
)-
Cv
O"'
to .
o
CO
-5


^


W

Q. _

f-
O>

->
Q


0
JZ


£» J,
O f

^ ' '
•p • ~

o • :"
tO T3
a 0
CO P
'00
0
•: 014-
:-. c Ct. L
— CO r"-
1 a r.-
S CO
--, § !_
• a 0 • 'i
/ s
O 4J
to '
• T3 3
r i- 0 7
• • +J O
-io '•
CD -i
X c»





0 J
0 C*
0 C 0
C 0.—
ro — >,
JZ >,J: .
p cr .p .
Trichloroe
Dichloroetl
Trichloroe


^ :







_y '«


' ^ ' '•

C •

-.• E •..
CO •
_• j;
': 3 ".
o .-•
*


0

«

0
^

O •
4J 0

•pn
JZ CO
Ol —

O CO
•P CO

C -P
0 0
p

C Cl

E 0


C -P
O CO
o c

to 0
O P
C CO
CO
s 	
o

p ^
to o
O -Q
p
ss.ting; i
t closed
•P O


fi regulai
anera 1 ly
Island. •'.'
oiaf •.
3 Ol
O CO C
£_ — o
4J 0
^ ^
0

0 to 0
> 0 —
o on
O t— O
to 3 I-
— 00.
•a to
Ul
to — O
E coi-
Many probh
to industr
Widespread

















:*

-------
                                                                       A-4
                                •o
                                01
                             t- t_
                             CO 13
                             C-
                             O —
                             a—
                             E O
                             01 >
                             4J

                             •o 01
                             01 c
                             CO
                             3 —
                             < C
                             0 3
                                                                                             01
                                                                                             01
                                            e
                                            a  •
                                               c
                                            <-  o
                                            o —


c


g
01

£2
0
(_
a •
c
<- o
0 —

If
C C
01 U
01 CO
.Q
O
T3O
CO O •
c. - to
N CD
01 CM O
13 P
— C CO
OOP
— O
p-o a
to 01 '
01 to Cw
0. 3 O
— »
«!-T3
13 P 01
01 CO P
— 01 C
_ t- CD

!_ 01 01

ID O.
— to E

01
f 5- 10
01 C
> P O
CD CO —
Z > P
0

13
c to
CO —

I-'ai
0) >
p
CO >
> 01
c •
P 13
f "Q C^
CT 01 CO
3-D E
OT3 01
CD CO-O
— 01
   3
Z C
o —

o c
UJ O
ceo
                             •a
                             01
                             o
                             o
                       •a    CD
                        01    a.
                        to    —
                        o    o
                                                                   01

                                                                   CO
                                                                   01
                                                                   u
                                                                   c
                                           •a
                                            01
                                            to
                                            o

                                            o

                                            to
               01
               ca
               o
           T3
            01
            to
            O
                                •a
                                01
                 •a
                  01
                  to
                  o

      c
      3


      01
      01
3   w
 u    o
                        c
                        3
      01
      c
      o
a

o
3   a'  °~
 u    o    o
      c
      3
            C
            3
            E
                                                                   C
                                                                   3
                                                                   E
                                                                   01 CO
                                                                   — o
                                                       01
                                                       o
                                                       c
                                        •a
                                        01
                                        to
                                        o

                                        o

                                        to
CD
a
                                                        01  to
                                                       — o
                                                 •a
                                                  01

                                                  CO
                                                .  c

                                              IB
                                               CO  CD
                                               O  P
                                              —  C
                                               O  O
                                                  o
                                               to
                                              —  to

                                               01 —

                                               *£
                                               01
                                               p  01
                                               CO  P
                                               >  CO
CLt-
   a.

roo
   in
  «vo
                                                    — 01
                                                    01 J=
           —  c
            CD  CD
            a.
           .—  CD
            O  P
           —  CD
            C  E
            3 —
            E  P
               to
           CM Ul
                                                                                                      0!
                                                                                                      a.
                       01
                       01



                       o
                       c
                       c
c

'i
                                                                                                      c
                                                                                                      o
               ca

               c
            Cl- CO
            O E
               01
            CO *O
                                                                           c
                                                                           o
                       CO
                       p
                       c
                       o
                       o
                                  •o
                                   01
                                                                                                                 4-
                                                                                                                 o
                                                                                                                             o >,
                                                          a
                                                          o
                                                          CD
                                                          a.

                                                         o
                                                         o
                                                         o
                                                                                                                                                 P 01
                                                                                                                                                 CO P
—
s a
a.
to 3
CD to.

i_ 3:
010
CO
CD
X01
C !-
CO CO
a.
E<4-
0 0
O
65
O

•^
01 P
to 3
O O

0 ID

CO *
— -o
— c
01 CD
^ —•

X 0
— o
c/i c£
\Q


3
O •
J33j


£_
• O

o
— !-
P 01
C04-

— 3
E a-
CO U
P CO
c
o c
o o

3: >,
O —
01
13 <-
01
E co
L. CD
*— • (—
Cl- CO
c
o c
CJ —
13 01
01 P
•U CO
CD P
— CO
3
0.1-
O CO
a co
z


•— •

CO O
01
.c —

C CD

c-
3: o
O >0

                                                                   >>P O
                                                                   .C 01 —

                                                                   CD t- O
                                                                   o o —
                                                                   {	£_
                        C
                        CO
                        at
                                                  C31    C31   Ol
                                            — O
                                            C. mi-
                                            o t-  .
                                            — P »—
                                            (- CD  .
                                            I—I—«-
                                             -C
                                            01 CD
                                          -C-C
                                         01  01 P
                                         C— 01
                                         01  >>0
                                        — .c t-
                                         >>P O
                                        .C  CD —

                                         01  t- o
                                         00 —
                                         £	C-


                                        —  O
                                        J^  CO f—
                                         o  <-   -
                                        —  Pl-
                                         S-  01   -
                                        I—1-<-
                                                                               01
                                                                               c
                                                                               01
                                                                     J= C
                                                                      P 01
                                                                      01 —
                                                                      o >»

                                                                      O P
                                                                     — CD
                                                                     -C O
                                                                      O !-

                                                                     IS
                                                                     I—x:
                                                                         o
                                                                     CM CO
                                                                       * £_
                                                                                                      01
                                                                                                      c
                                                                                                      CD
                                                                                                      01
                                                                                                      o
                                                                                                      ^
                                                                                                      0!
                                                                                                      Q-
                                                                                                                          m
                                                                                                                          o
                                                                                                                          >



^*
•a
0
3
C

P
C
O
u


i£


3:
UJ
z

p
c
3
O
u


fZ
o
2
ca

•»
P

0
o

•a
c
UJ

>1
p
c
3
O
o

01
g
o
o
<-
ca

«

CD
p
to
01
>
*
X
c
3
O
o

c
o
4J
^
3
U.

^
c
3:
O
4J
to
C
£
0
-3
C
3
O
O

C
o
p
to
01
c

>
3

^
CD

C
o
•o
01

CD
0
>>
p
C
3
O
O


CD
C
p
3
a.

^
£—
01
4J
to

01
t-
CQ










«





to
c
01
01
3
cr
%
c
3
0
U

•a
c
CO

o
o
a.

*
c
!-
0}
Ci-
tt-
3
(/}










P>
C
3
O
O

3
CO
CO
to
CO

                                                                               c
                                                                               3
                                                                               O
                                                                               u
                                                                               3
                                                                               

CO


4J
CO
£_
S

o
o

~

to

<
Q_
UJ
>
CO

CD
ca



_
—
ft—
•a
c
CD
_J

CO

>
CD
p
CO
CO


—

..-
CI-
TS
c
CO
-J
01 >.
CTI ca
CO CO
a.
JZ i.
p 03
01 P
CO to

•ao

O

-------
             A-5
            o
           
                  a
                  3
                 CO
           -a
           •a
           <
CD a>
o c
fl) O

>>
a.
a.
• 3
y> •
• T3
3- CD
O -P
0
4- 0
0<4-
4.
4J CO
C
CD 05
O —

0) CD
Q.>
' O '0)
CO JJ
CO


c

c.

— 4J
^ CD
O
(A CO
— u.
— ^*-
03
> 03
O
CD t-
4J 3
CO O
> -  s-
    CD
•O'E
 03-3
 U1Z
 U)   •

— 13
—  CD
 CD  «
 >  O

CO  O
                           CD—.
                           «  e
                           O  CO

                           o  c
                               o
                           —  o
> o «
      0)
— 0) CO
CO •	
a— i-
— E a
o    t-
                               3,


                            O "O
                            <-  CO
                            oo
                           —     d)
                           J=   -C
                            O  O CD


                            «-  C >>
                           1-  0) .C
                               (A 4J
                           r-  t. OS
                             -< O
                  LJ
                  O
                               C J=
                             -CO O
                               .
                            O 4J t-
                            a. 0)1-
                            c
                            3

-------
                                                               A-6
          c
          o
         •a
         T)
                    •a
                     £
                     CD

                     o
                     o
                    .00
                     or-
            CD    VO
            to    h-
            IS    O\
            O CD i-
               4J
            13 IB C
            CO 4J —
            JtO
            O    4J

            —  • 3
            oa- to

               ON IS
            to f— —
            IS
            C. CD-0
               U CD
                      -r-       Ul (04-
                     =  1
                       U.
                    •o    ox>
                     c  co < CD
                     IB  O1O —
                        IS    —
                     (-a   is
                     co  e   -4J
                    •U  3 IA IO
                     IB  a.— c

                       T3 CD
                    «  CD 5 E
                    C  10    CD
                     OIIB 13 4J
                     3  CD O 10
                     O  t- O >»
                    CO  O OllA
               f	
               O\ >

            IB    O» S-
               C C  O

          .  CD ,   4J  IB
            Ul 4J IB  <-
            O at —  co
            — CD •"•>  Q.
            O 3 O  O
               CTCJl
            — CD CO —
            — S. c —

            4- CO O W
            •a jj 4J T3
            C IS IB  C
            IB'4J 4J  IB
            _l to CO —
               O    C
              —    IS
              — I —
              .0.0  a.
               3 3
               ato  a.

               IB >» I
                  c  c
               5 IS  IS
               o a. CD
               C E —
                  o  o
              — o
              —    o> •
                     c<
              4-  ..-Q.
              T5 j: 4JU1
               C £- 4J
               IS IB — O
              -i as 4J
         o
         c
S
a:
         c
         o
         X
         Ul
         c
         o
         t_
         o
 CD   •
 L-  1A
 O —
 C  CD

    CD
•o —
 CD
 (A  CD
=>  U

   •a
  .  CD
13  1-
 CD
4J  O
 O 4J
 CD
6-  C
fc-  o
IB —
   4J
 IATJ
   C
 O IB

— C
£> O

a. 40
         c
         o
        o
                                a
                                a
                                3
                                13
                                CO
 cr
 o   •
 IB CD

•O CX
 CO O
 4J CD
 IB a.
 c

•i§
 ISO
 JJ   ^
 CO
 oo
(J--
            CD
            C
            IS  CD
           C.  C
           •"  IB
            ur:
            O  4J
            t.  CD
            O  E
           —  o
           .c  s-
            O  3

           aw

           CMS
             -o





CO
_
^
S

CD
4J
IS
>

L.
Q.
cn
c
c
CO
>
CO
IA

CD
(A
O
O

o
4J

13
IB
X


0 C
CD
to —
— >»
coc
> 4J
CD CO
— 0
t.
CD O
> —
— x:
to o
to is •
CO t-
CJ 4J
x co
CD 4J


                                      ^2
                                      IS  CX
                                      CD

                                         O

                                     con
 C 4J
— c  •
   IB CD
 01	
 C Q. Q.
      O
 OI4J CD
 <- c a.
 is .co
j= eo
 O 4JO
 IA IB ITl
— , CD
IS    4J
C CD IS
   O
   O

 IA' >,
 01—
 c a.
— a
 i- 3
 a. co
 to

 to CD  •
 IB 4J CO
   IB —
 Ol^? Q.
 C.    O
— > CD
 cncD a.

 is >o

 o iso
 IA CO  1

•ao i
      o
a
s
                                              O              C
                                              C     CD CD


                                              10    —^
                                              CO,    >>4J
                                              (A    JZ CD
                                              IS    -WO
                                              O     CO t-

                                              IA     I	
                    Ul
                    o
                                OJT
                               —  O
                               .C  IS
                                O  <-
                                                                     JJ >  CO
                                                                     C CT3
                                                                     O IB —
                                                                     OQ  >
                                      CD
                                      C
                                      CD
                                     CD
                                     C
                                     CD
                                     3



                                     £
                                                                    0
T3T3T-
 
 E 01'-
 CB C CD
4J — (A
C <-
O Q.O
O CO 4-»
                                                 I
                                                 o
                                                 CO
                                                            ca
                                                            o
                                                                                               CD


                                                                                              a:
                                                                           C  IS
                                                                           CD  CX
                                                                          r:  E
                                                                           01 o
                                                                           coo
                                                               < co

                                                               O (S

                                                               c

                                                                  CO
                                                               Ol-
                                                                                               IB—
                                                                                              .CO
O IA

13
CD CO
4JJ£
IB IB
C 4J
— C
E —
IB
4-> t-
C IS
O CO
o c
                                                                                                            o
                                                                                                            o
                                                                                                            o
                                         01
                                         c
                                         IS
                                        4->  •
                                         C 01
                                         o —
                                         o a.
                                           o
                                                                                                                        •o
                                                                                                                        CD
                                                                                         O
                                                                                         a.
                                                                                                                        C
                                                                                                                        O
c
o
U

o

c
                                                                                                                                 o
                                                                                                                                 a.
by
on
                                                                                                                                S       c
                                                                                                                                a
                                                            4-
                                                            o
                 CD
                 4J
                 L.
                 O
                 Q.
                 CD
                                                                                                                                         C
                                                                                                                                         CO
                                                                                                                                         13
                          CD
                          C
                          IB
                          13
                                                                                                             C
                                                                                                             CD
                                                                                                            £
                                                            IB
                                                            O
                                                                                                                               .S
                                                         E
                                                         IS
                                                         4J
                                                         C
                                                         o
                                                         U
              UJ
              Ul
              a
o
en
c —
CO IB —
IB-Jb-
S 13
IB «C
	 IB
CO CD-J
a >
IS.X
.t. CO
aio ffi

IA
IB 13 >>
CJ C S
IB S-

co
z










^

z
>
Q
>
05
Z

Ul
a.



is

c >,
IS 4->

_. ^

to x:
C 4J
C 3
CD<
a.
c.
C. CD

^- IS
OS
z
*
                                                                                o >>

                                                                                IS C

                                                                                !>- O
                                                                                3O
                                                                                CO
                                                — 4-1

                                                n-ca
                                                •a
                                                 c   -
                                                 is a.

                                                   .C
                                                 IS (A
                                                                                C 0
                                                                                isl-
                                                                                              L
                                                                                              1-
                          3 a.
                         a —

                          CD (A
                          C C
                          IB >
                         •a o
                                                                                                            —  ex

                                                                                                            13 JT
                             01-
                             a
                             013

                            co  is
                             i   i-
                                                                                                            o
                                                                                                            a:
                                                                                                    o
                                                                                                    en


-------
                                                     A-7
UJ
ce
c
o

^J
CO
e
t.
o

c


«.
CO
c
o

4J
._
n
•o

03
O
t.
3
O
tn

03
XI >>
S3

— C
3 O
O —

to co


3 0
X)4-
c
4J 	
03
03
E
03

XI


Q.

t_
03
4J
CO
3

o
c

c

S-
o

Ct.
o

4-3
C
03
4-1
X.
UJ
4.
O

c
o

4-9
a


0
en
03
0
to c
03
— 03
— -a
a.—
n ^
3 0
tn i- .
a.

OT3 •

4^ 3
O O
a>x:
ci- cn
4-
co E
CO
4-> t-
O O1


o a
•a
o>
to c

03 4J
— tn
XI 03
04,
a i- .

X*~3
C ca

y


> tn
03 E
4J 03
CO —
4J .a
to o
4J Q.
3





cn
4-3
C
ca
c

E
CO

C
c
c





0 X
x: —
01 a
3 a.
O 3
<- tn
r:
4J t- .
03 CM
tn 4J co
E co O\
03 Sr-.

XI 03 t-'

1-3X1
Q.4J E
3 0)
X<>- •"
c a
ca th. 03
E O03






























•
•o
03

CO
O
o


to
w
c
CO
c

e
CO
4J
c •
o
o

4-
o

03
O
i. .
3 <-
0 03
tO 4J
ca
03 5

oin
c 03

to co
03
0 t-
Zl—

to
•a
e
3
o
a
E to
0 C3
o —
c
!- CO


— O
3
tO 03
1 —
O —
C 4J
CO CO

S- O
0>






























4J
c
CO
o —
— •a
— CO
XI t-
= cn ,
a
C
*g
"BTJ
^t

•U jJ ,

Q^
CO
— O
>c\l
o .

CO
03 — 03
E— i-
3 03 CO

a —
Xco
4J — CO
c ao
co aa
C 3 W
— to —
E T3
CO *-
4J 0) E
C 4J O
O CO t_
o St^

o

X
o
h-


to
4,
C
03


OO
too.

0 «

c —
CO CO
01 4J
S- 03
OS
1 03
s- a.
o —
4, CU
to

•UXi
CO
•o
•a 03
0 C
4J ^
CO O
o
— J£ 4J
Ctt
03 CO CO
C3 4J i-
t- 0
3 03 <-
O Dl—
U5 CO <







1
C
o
o

• >»

a
a.
3
tn
s.
03
4J
CO
S •
•o
U 03
— tn
— 0
XI —
3 0
a.

^
• 03 .
OD >
^-
a\ o
t- C
o
•a
03 -a
t_ 03
.03 4J
> CO
o c
o —
to E
— CO
a 4,





03
T3

£-
O

x:
o

_
^j
C
»
^


UJ
o
H
                                                           c
                                                           o
                                                          •a
                                                          X!
                                                           3   '
                                                           to

                                                           t_   .
                                                           CO
                                                          XI   •
                                                           can
                                                          —  os
                                                           CO  4J
                                                          E  co
                                                                   c o tn
                                                                   03 I- 03
                                                                  •o ao
                                                                         o
                                                                      4J 3
                                                                   o o to
                                                                   4J 03
                                                                      ^- CO
                                                                   tn '-
                                                                   C OT3
                                                                   O O 03

                                                                   4->n —
                                                                   U C CO
                                                                   < CO O
                                                                    a.
                                                                    E
                                                                    0)

                                                                   O
                                                                   o
                                                                   o
                               4-  iJ

                                   CO

                               —  o

                               •Q.—
                                3<
                                to

                               2  03
                               a  c
                                   4J
                                03  —
                                •U CO
                                O <-
                                03 Q-
i.
o
x>
E
3
C

ca
c
03
4J
CO
•e
x:
w
to
4J
C
CO
c

E
CO

c
o
o •
to

- . _
tn 03
S ^
— 03

CO

CO —
£_ 1.
03 a
—
E
CO

E

tt- -
OTJ
03 03
C —

O
0 —
4J 03
C i
x:
•D CO
03 03
T3 —
C CO
u —

X
03 C •
O 03
tO 4J O
CO to t.
x: os 3
<- o
03 a. tn
E
— o —
a. a
03 a
03 0 3
4J C tO
CO 03
x: 3 i-
o— o
                                                           03
                                                           •a

                                                           CUJ
                                                           COO
                                                           XI-
                                                           o

                                                             .0)
                                                           en
                                                           3 —

                                                           E O
                                                           •03    UJ
                                                           co—    O
                                                                                  O
                                                                                  o
                                               03
                                              x;
                                                        to
                                                        o

                                                        c
                                                        CO
                                                        01
                                                                   t- (-.
                                                                   4J O

                                                                   tn

                                                                   co —
                                                                   •o Q.
                                                                      Q.
                                                                   1A 3
                                                                   J- tn
                                                            CO
                                                        o  S
                                                        IA"
                                                        i^-n
                                                            03
                                                         03  a.
                                                         u  o
                                                         i—
                                                         3  03

                                                         tn'o3
                                                           n

                                                         o  X
                                                         CO 03
                                                         C C   .

                                                        'i E
                                                         CO O   '

                                                         Cft-   •
                                                         o   —
                                                        •C3 03  E-
                                                            E  co

                                                        g«X
                                                                                                       03
                                                                                                       C
                                                                                                       03
                                                         03

                                                         s-
                                                         O


                                                         t
                                                         03
                                                         Q-
                                                                   UJ


                                                                   S
                                                                                 X!
                                                                                 3
                                                                                 a.
                                                                                                                     •a
                                                                                                                     03
                                                                                                                     O
                                                                                                                     Q.
                                                                                                                     03
                                                                       to
                                                                       E
                                                                       03

                                                                       XI

                                                                       g
                                                                       a.
                                                           c
                                                           CO
                                                           4J
                                                           O.
                                                           03
                                                                                  at
                                                                                  c
                                                                                  o
                                                                                                                      CJ1
                                                                                                                      c
                                                           3
                                                           O
                                                           U
                                                           o

                                                           to
                                                           E
                                                           03

                                                           XI
                                                           O
                                                                                           3
                                                                                           tn

                                                                                           ca
                                                                                                                               c
                                                                                                                              o
                           03 O    CO
                           — CO    4->
                           d- 03    05
                           — CO

                           03 —    	
               o;
               o
                           a -u
                              £-
                           •W O
CO C
> O
co to

   U
  • CO
tO-3
_ O,

  o

 *
         x:
         u
         CO
         03
         ca

03       E

t-   ';   CO
3       O-
o
Xi       4->
—       tn
O       03
                                                                                   03
                                                                                to —
                                                                                03 —


                                                                                tn c
                                                                                   o
                                                                                °~5
                                                                               LJS
                                                       XJ
                                                        C
                                                                                           CO
                                                                                           1A
                                                                                                       03
                                                                                                       t/3
                                                                                                       E
                                                                                                       3
                                                                                  O
                                                                                  a:
                                                                                  o
                                                                                  z
x
t-
                                                                    o
                                                                    to

-------
                                                           -A-8
  c
  o
 E

 O
C.
 c
 •o
 •a
 o
 t.
 a.
 o
 c
^£
 C
ft.

O
 C
 CD
X
UJ
De
                                    c
                                 — o   •
                                 — >  CD
                                   a.—
                                t-    Q.
                                o  o

                                a   o
                                CDTJ
                                O  CDTJ
                                '	CO
                                CD— CD

                                c  t! a
                               — TJ to
                                                     c- i
                                                     CO O
                                                       3 CO
                                                       01S
                                                       en
                                                       c c
                                                    3
                                                    TJ O1CD
                                                       C C
                                                    T>"~ CO
                                                    C 43 SI
                                                    3 10 43

                                                    O CD CD
                                                    U. 43 E
      to
   ft- O
   O i-
      43
   CD CD
   too.
   3
   CO C
   O —
   CD
   a to
      O!
   13 C
   (D —
   43 TJ
   « C
   (D —
   I-ft-
$
o  •
o —
to —
                                                                                — c
                                                                                 CO CO

                                                                                 c
                                                                                 CD CO

                                                                                H«.
                                                                                 O CO
                                                                                 U CD
                                                                                < C
   to
   E
TJ CD
 CD —
 En
 <- O
 o <.
ft- Q.
 i.
 CD I.
 O. CD

 O143
 c o  •

43 C C
 to CD 3
 CD.C O
                                                                                                                               CD
                                                                                                                          «O1O
                                                                                                                         T3 C t-

                                                                                                                         CD— 3
                                                                                                                         tO-Q O
                                                                                                                         O C CO
                                                                                                                               0!
                                                                                                                         0)  L.  43

                                                                                                                         —  O  CO
                                                                                                                                          O)
                                                                                                                                          C

                                                                                                                                          a.

                                                                                                                                          3
                                                                                                                                         •a
               >>aj a.
               3. --

               •Q « tO C
C O 43 43
— to —
itf CD 3 >
— TJ
I 	 c CD
0 E— <-
ft- co

	 c .
— eo co 3:
CDC a
c t- (-
— CO O

E 43
CD— t-3:
— > CDO

0 10— C
< 	 CO O
a <-

ao . o 43
to t-._
— CO CD 10
co a> o JT
.
TJ
CD
43
O
CD
t_
ft.
CO

T)
CD

ft-

^
_
CD
>
43
to
CD
a>
i.
CO

              u— u   —
              0 w 0) C —
                       o  E
                     [)•— O    CO
                     lia,   y

                              o
.C
J=
43
CO
CD
s:
CD
to
0
a.
o
o
CO
o
in
CM
CD
to
o
jC
'43

ft-
O


c
o
43
CO
c
E
CO
43
C
o
o
t
since
unknown

CD O
to o
0 !-
O O
OT
4J

C >,
CO 43
O —
"ected.
ir commun
•*- U
ft- ft-
CO
2
— Q
CDft-
> 0
— CD
CO O
ac-
— 3
o o
'— to
c
3 CD
E —
0
T— (fl










_. .

0)
>
—
CO
a.
0
c
3
E

CD
C
O







.
•a
0)
CD

O

S3
3
a.
c
to
—
CD
>
to .
— O
— 43 tO
CD CO
0) tO 43 .
CO >

— CO 3
t- j^
a. to
t- ,
CD >,
.to —
,T> 3 a.
CD a
to— 3
o — to
— CD
o ^ —
' CO
to CD a.

— co o >,

'-so
— 0--E CO
CO Q.
a o co
— ; • 43 o.
013
	 CD Q.T3
C 43 3 CD
3 O 43
E CD Jf'~.
. C_ 0 E
CO .c
o
• c

a> as
4J Q)
ra rt
con tarn in.
CE but di
[__
(A
— 

- O t-
— w
A a
•3 — , .-
Q.OJ
fO
C|_ 4J* .
'O C CO
03 —
CNJ EO
'I
,
                                                                                                                             C
                                                                                                                       iTl  • CO
                                                                                                                          XJE
                                                                                                                          CD

                                                                                                                       -•a co  •
                                                                                                                       CD CXI
                                                                                                                       43—0
                                                                                                                       CO £ 43
                                                                                                                       C CO CO  .
                                                                                                                       — 43 CT3
                                                                                                                       E C— CD
                                                                                                                       CO O  E 43
                                                                                                                       43 O  CO CO
                                                                                                                       C    43 C
                                                                                                                       O 43  C —
                                                                                                                       O C  O E
                                                                                                                          CO  O CO
                                                                                                                       CO —    43
                                                                                                                       — a.j£ c
                                                                                                                       —    t- o
                                                                                                                       CD C  CO O
                                                                                                                       > o  a.
                                                                                                                         —    to
                                                                                                                       — 43  I	
                                                                                                                       CO —  CD —
                                                                                                                       Q.C— CD
                                                                                                                       — 3 — i
                                                                                                                       O S  CO


                                                                                                                       C CO 43 CO

                                                                                                                       E 4J 43 43
                                                                                                                          CO  CO C
                                                                                                                      \O      CD
                                                                                                                          tf) tO TJ
                                                                                                                      Ci	

                                                                                                                       O	CO
                                                                                                                          CD CD CD
                                                                                                                      in i > t-
                                                                                                                                          CD
                                                                                                                                          43
                                                                                                                                          i.
                                                                                                                                          a.
                                                                                                                                         4-
                                                                                                                                         o
                                                                                                                                         CD
                                                                                                                                         a

                                                                                                                                         3
                                                                                                                                         C

                                                                                                                                         •o
                                                                                                                                         c
                                                                                                                                         >>
                                                                                                                                         43
                                                                                                                                         C
                                                                                                                                         3
                                                                                                                                         o-a
                                                                                                                                         o CD
                                             Ct.
                                             o
'I
                                                      0)
                                                      c
                                                      CD
                                                    .43
                                                   r- CD
                                                             CD
                                                             C
                                                             CD


                                                             X
                                             §   G°       2
                                             m       o       i
                                             i      -..c       o
                                             O   L4j  O       —
                                             O   O—       t.
                                             a-   i-a       i-
                CD-
               JZ
               43
               O
                                                                                              CD
                                                                                           I  C
                                                                                          CM  CO,
                                                                                            •>J=
                                                                                          t— 43
                                                                                           I  CD
                                                                                          OT  O
                                                                                          —  £.
                                                                                          •O  O
                                                                                          UJ O  :
                                                                                          o —
                                                                                          KQ--
                                                                                                     o
                                                                                                      I-
                                                                                                     CM
                                                                                                     CO

                                                                                                     o
                                                                                                                         UJ
                                                                                                                         o
                                                                                                                         t-
          CO S
             CD >>
            JZ 43
            U C
                3
             O O
            — o
             CO
            U 0)
                                                                                                                                        CO
                                                                                                                                       TJ
                                                                                                                                     CD^£
                                                                                                                                      1 CO

                                                                                                                                     OT°


                                                                                                                                        CD
                             UJ

                             *
                                            O    M

                                            5    S
                                            O    CD
                                            —   CL
                                            S..  *
X

O

CD

"fl
                                                                       •    CD
                                                                           ax

                                                                     o   o
                                                                     o
                                                                     N    CD
                                                                     
-------
                     A-9
                         CO  £-
                         0)  03
                         c  >
                       •  O4-  •

                        — .x: a
                         n c «
                        JZ CD CO
>T3
   CD
Z 3
o c

CJ4J
LJ C
o: o
   o
                        •a
                        o>
                        to
                       , 3
                       ' CD
                        a
—  s
CO  CO
Q.4J
—  C
O  O

c°
a- oj
i- «
                        Ct- CO
                        o o
                                            •a
                                             a
                                             
-------
          A-10
s
a:
               TO
               C
               =>
               c
               o
               o
               a.
               a.
               3
               — C     (0
               .a o.     4J
               3~     c
               Q.-U     O
                 TO     O
               C CT
               	     OS
                       4.
                       O
               m
               N
               c
                       o
                       c
              0)
             ,.3
              o-
          X   ffl
          ^   §.
          *   J
          LJ   _
          Z   <

-------
                              A-ll
         o
         <4-
         c
o
Ul
a:
         t_
         o ,
         X
         UJ
         •u
         a
               C
               O
                    • c
                     3
                     E

                     o
                     •o
                     CD
                      a
                      3
 E     to
 CO     C
 4-1    —
 C    —
 O     CD
 O     Q.
 o    w c
— .   00
 C    3-0
 CO    T3 C
 O*   O CO
 I-    t-.Q
 O    a- CO
                                     I
                                    ul
                                 CD —
                                 o-a
                                 c

                                 w CD
                                    4J
                                 E n
                  0 O C
                  — O O
                  .a _;._
                   w) O O>
                   O !	
                  0-<4- i>  ,
                        cfl
                     W 0)
                    • c >
                   c o c
                   o	
                  — T3
                  4J CO S-
                   co i- o
                   C O1T3
                  — Q.C
                  CO)  •
                  O *J •)->
                  O IS O
                                             ca
                                           >    -u
                                          T3T3 O
                                          CU Q) CD
                                          S-.C4-
                                          CD CO <*-
                                                               CO
                                                         O CD
                                                         O W
                                                         C 0) >>
                                                         O 0) CO
 CO
 c in   •
— je  01
 E—  C
 co = —
 •W CO  3
 CO  C
 O    —
 o c  a
   —  c
—     o
— T5  O
 CD 0!
 > -H  C
   co  O
 CD 3 —
 E •>->  -U
 O —  ra
CO trt  CTJ
         C
         CO
         c
         o
         o
 c.
 o     
•*i    *>
       §0
       3
      TJ
—     O
 CO     i-
 !-    O.
 CD

 CD    ._
tf>    O
                                                         CU
                                                        •a
                                          U] t/1
                                          O w
                                          — c
                                          C 0)
                                          CO >
         CO
         CJ
                  0.
                  E

                  O >>



                  ±"
                  O w
                     CO

                  CO C
                  W CO
                                 CO

                                 s:
                                                     Sr
                                                     UJUJ

-------
           A-12
      ra
      c
      o
      T3
      •o
                    4J
                    C
                    o
                    o
                    CL
                    a.
                    3
                    3
                    a
           c
           o
        a
            re 3
            CO O
            E —
            CB —
            ua
            in 3

            w
              SI
            O -P
      O.E
        
— o

•a c
c to
re 01
   £_
O O

C 01
CO C
to —
I- >
re —
   o

•u c
   CO
 CO 4J
•E C
 O 0)
 — 13
 n —

 sg
                             a
                       o

                       c
            o
            o
            <
            K.

            3
            o
            C3
                     <

                     o
               §
              •ce.
               o
               z
                        <
                        z
                        <

-------
                                                                    A-13-
           c
           o
          •O
          T)
          O
          C
         C
         03
         X
         LJ
§       I
—  •     4J
O
UJ
a:
03 03
O CO
re o
Q. a
CO O
0 I-
c. a •
CD C
< CB re
•P —
E co a.
O -P
C-OT u
*-• c
. 03
CD • E
c re
>>co 03
re — t-
S C3-4J

.

a)

«j

c
i

c
OJ *

o
a
a>
w

.

Q)
-P
CO
CD
L.
1

C
CO
•p

U
4J
Q.
Q)

re
c
...
E
re
c
o
o

—
—
0


—
re
a

0

c
3
E


CO
z
0
^

0
4J
re

•—
&_
a

o
CM
1.
o
t—

o
CO
o

c
— c
0
13 .C
0 ^
c
0T3
a0
0 <-
03 0
cc >
o
0
• CO •
T3 —
00
CO
0
0 C
co re
— res'
0 X
? *O H~
0
— we.
a o o
a— !>-
— a
o 01
— c c
C 0 —
3 C. C
E W 0
VOT3 «-
1 C U
IA re to-
I
0

c
3
3:
o

Ct.
o


-a
3

CO



•o
0
CO
o
o
CO
~
0
>


n
a.

o

c
3
e
O 5

H* 3
                                               I


                                               !_
                                               O
                                               0
                                              a

                                              o
                                              •a
                                              0
                                 a co
                                 a—

                                 o 0


                                 3 C
                                 E O
                                                                0

                                                                t
                                                                3
                                                                O
3
•0
C
T3
0
O CO
0 3
O

o c
o re
.3-
•a
•a 03
03 C
> 0
<- a.
03 o
CO 0
j= ' •
0 >
"~ O
.c c
^

^ c
0 re
cos .
0 C
— o
o • —
CO 4J
co 03 re
_._ !_
~* -P 4J ~
03 •— -^

4.
— cr) •
ra>- c
Q. O

O— s.

C 0 0
•3 —
- 0 4J
0\ 0 —



1
c c
03 O

J
CO
•0 CD
0 >
c
0 !-'
Q.O) ,
0 *>
0 CO*.
*- >

0 4J
!_ C
0 0 •
>E
0
T3 0
0 re
to —
0 0.
— 0
U i-

C 0
0.C
03 4J
.a
•a
•a o
re <-
JZ 03 •
> 0
•P O O
CD O 4J

w — : -a
•o 0
to P
— co re
— re c
> S
•P re
                                                                                       c
                                                                                       0
                                                                           o
                                                                           re
                                                                             o
                                                                           to o\   •
                                                                           CO    CO
                                                                           re J->  t_

                                                                           d c  «-
                                                                             —  3
                                                                          •a co w
                                                                           C13 O1O
                                                                           co re  co
                                                                           O   c,.
                                                                           Q.4J 3
                                                                           p- c
                                                                           <- 3 re
                                                                          Q- co £
                                                                                      C
                                                                                      o
contam
we
va
                                                                                      !_

                                                                                      Q.
de
                                      -a P
                                         co
                                      o re
                                      to to   .
                                      c 3  to
                                      re o  c
                                      — T3  o
                                      as- —
                                         re «
                                      >>N  re
                                      4J co —
                                      C £  3
                                      3    01
                                      O d  03
                                      o 3  e  .
                                .01       01

                                 as-    — -a
                                 t- o—  P c
                                ^C 41  CD  CO TO
                                 P CO—  !_
                                       *-  03 'ai
                                •a o  -P  a. c
                                 03 4-1  CO  O —
                                 O.    3  O !-
                                 E c-a  o o
                                3 O  C    W
                                 p.	to —  .
                                   4J    — C OL
                               . to re       o 3
                                — i.  .  03 E
                                   •P  !_ 0  . c

                                -  • 53 i-.c re
                                — — > D t» CD
                               , CD — CD O •'	
                                3: c»- to co ^ o
O —
4J —
1 0
i c-a >
C— 0 CO
3 !-_ oj
^ 	 4J
CT3 3 0 re
O 0 CT> >
— Ol 0 —
w re s 	 t-
re e co a.
c re to Q.
— •00— •
E — o •
ca .C C — CM .
•P J-> CO CCOT5
C— Q.3O\ 03
0 CO E E-r- 4J
O 0 O CO
SZ C30 >,0
vo re 4J
• 0 Or- E
••a 010 i !.

to re ~ • — p
Oil . co !_ TO
— O co 03 ex -^
O +3 4J ^
CO O — 4J
— P 0 CO O10
— eft. c 01
0 0 0 t- •>-
> -a -a — w o
— 0 tO 4->
— to c .c 0. '
re 0 4J 4J 4>t3
ace: t- 03
— — 4J Ol Ol
o a re c t.
"""" * "*~ Z3
C C DlS 0 ,
3 — CO O» W
e 03 — c c'
*J "D 4J Q) 03
QJ t- 3 0)-Q C
C Q)— (D c £
O O O 4-> ZS O











£.
0)
4J
CO
Ol
c

-p
w
0)
4J

•P
C
03
E
*>
L.
CO
a
CD
•o
J=
4J
CO
Q)
.C
0)
J-»
CO
4-1
CO




^
_
J^ "

— -Q
•C Q)

W O

, <^_
>><*-
w ca
— , O)
._ c.
4J \CD
D1*-

-Q> D
03 D-
C-CO
5
O X
1 0)
c-
O Q.
W £
to O
03O
C
Zi
O -P
CO
— c

0'i
>s
03 c
C 0
0 0
ed
po
                                                                                        CO

                                                                                        0

                                                                                       J3
                                                                                        O
on
                                                                                                                                                   c
                                                                                                                                                   o
                                                                                                                                                   o
                                                                                                                                                   c
                                                                                                                                                   CO
        C
        o
        o
                   Q-

                   O   UJ
                   CD   O
                   Q   I-
                                o
                                H-
                                                 Ld
                                                 O
                        o
                        CO
                        a
 ui
 o
ca
o
  o

  !_

  O
 —D
  re
  E

  O
                   Ol
                   c
Z    CO    O
O    3    CO
N    *-    b
—    -P    3
                                   C
                                   03
                                   o
                                   .c
                               o
                               o
                                                      <
                                                      o
                                                             >,
                                                             CD
.a
 re
P

 c
            c  •
            re'
           05
                                                                                    o
                                                                                    o
 re co
 I. 03
 re —
 — j->
 O c
    3
 CO O
 4JO
 C
 re re
 Wa
    CD
  «E
-O CD
 OS —
 4J<
 re
ET3

,c re
 re
tn
        o
        -3

      ' C
        re
        ui
S

-------
                                                                 A-14
 •a
 •o
 <
o

s
cc
         o
         c
 .X
  c
         X
        LJ
c_
o
        c
        o
        03
        a
        c
        a
c
o
u
                    •o
                     OS

                     tl
                     3
                    a c
                    0) ra
                    — -u

                    .. 0)
                    03 O)
                    Ora

                    a o
                    o -u
                    t/3 to
                   T3
                    0)
                    o
                    to
                   o
                   JJ
                   ra
                   •a
                   ID
                   CO
                   o
            O.


            O
                                                                          0) a>
                                                                          > o
                                                                         — i_
                                                                          O 3
                                                                          > o  .
                                                                          c w c
                                                                         —    o
                                                                            01—
                                                                          CO C 4J
                                                                          a>— ra
                                                                         — u C
                                                                          o c —

                                                                          m o ra
                                                                          Ol Q.-P
                                                                          re c c
                                                                           — a
                                                                         >>Q.O
                                                                         C
                                                                         10 C 4-
                                                                         E— O
                                           O
                                           C
                                           c
                                           ra
                                           c
                                           03
                                           E
                                          •a
                                           ID
                                   03
                                   a:
                            §
                           T3
                            C
                            ra  •
                           J3 4J
                            ra c
                              03
                           — E
                           "~ -H
                            a) ra
                            ;* 03
                          >;*>   —
                          *>      ra
                          — a.   Q.
                          CO   —
                          3—   O
                          E 03   —
                          S >   C
                          O j


O
c


03
—

a.
a.
3
CO
i

c
o


0
03
W
c>»


C
O
—

ra
c

E
ra
4-9
C
o
o


1
1 —
c co a. .
O 03 03
o t- 01
03 CO
C-T3 —
ra c —
01 —
— e s.
•a E-D
01 O
JJ O £_
CO 01 O
03 S.

4J 01
0 C 4J '
0 01 01
CO E >>
4-> CO
O ra o
a.—
•W 01 —
c.-oa
03 3
O *~ Q.
!- 4J
01— O
a. ro *J •
03 —
OX Q.—
.3" 3 03
^^ ^

«T3 o >>
— 01 O U

01 ra c
> C M 3
•~ i * g:
0 E C E
vo ra ai o
r~ 4J ^ y


•
•a
01

co ra
01 C
o —
3 <0
o "
« c
o
— o
ra
<- 01


01 o
CO U
cn<-
c ra
— 01
> a
	 Q.
o ra

c i-
— 01

E —
03 3
— cr
J3 O
o ra

a. ra
E
01 O
CTO
^- ra
roh-


^ 4-i
*— ^3
(U O










^
a>
w
o

o

c
o

-u .
CO "O
•u ea
c E
0} Q)
o-a
c
o t-
b 0
E
£: E

._ 05
(—
4J
J= 0)

— E
>

« o


Q) 03
^ o

O 1
i O
1— C


                                                                                                                                        CO
                                                                                                                                        03
                                                                                                                                              3
                                                                                                                                              O
                                                                                                                                              •a
                                                                                                                                       N
                                                                                                                                       ra
                                                                                                                                              I
                           c—
                           ffl 03
                          HO-
                                          c —
                                          03 (0
                                         1-0
                                  cot    o en
                                 — o   — o
                  ra
                  u
                           ao
                           Q)._
                          coca
                                          0.0
                                          a> —
                                                    o
                                                    a
                                            Ul    CO

                                            g    5
                                            i-    C
                                            01    ra
                                            E    tn
                                            3    !.
                                            z    o
                                                                                    01
                                                                                  01 C
                                                                                  C 03
                                                                                  O —
                                                                          4J Q3

                                                                          01 O
                                                                          O s-
                                                                         c.  o
                                                                          o —
                                                                          ra o
                                                                              o 01  N
                                                                              l-Hr-
                                                                                                                                             o
                                                                                                                                             o
                                                                                                                                        3: oiw
                                                                                                                                           c-
                                                                                                                                        13
            o    c.
            X    3
            <    03

            S    3
                          c
                          3

                    =   8
                    o
                    o    o
                    LU    C
                    ce    ra
                    o   -I
                                 o
                                 o
                                a:
CO

§
E
O
O
ra
                                                                     •a
                                                                      o
                                                                      o

                                                                     I
                                                                                                                                        3 c uu
                                                                                                                                        o —
                                                                                                                                        s- <- c
                                                                                                                                        OQO

                                                                                                                                           I  I
                                                                                                                                            o
                                                                                                                                            o

-------
                              APPENDIX B




                       SAMPLE SURVEY QUESTIONS






A.  GENERAL INFORMATION ABOUT  CONTAMINATION PROBLEM






    1.   When was  contamination discovered?






    2.   What contaminant levels are involved?






    3.   What is the  likely source of contamination?






    4.   How extensive is ground-water contamination?






    5.   How many  wells are currently or potentially affected?






    6.   What has  been/is being done?






    7.   What was  the chronology of' events and  who  has been  involved?



         •  Water  utility






         •  Municipal government






         •  County health department






         •  State  health department






         •  State  EPA






         •  Regional EPA






         •  Industry






         •  Consultants

-------
                                  B-2
B.  GENERAL INFORMATION ABOUT THE WATER  SYSTEM
    1.  How many persons are served by the water system?
    2.   Is the system public or private?
    3.  What percent of supply is  from ground water?
   4.  What treatment methods  are used?
   5.  How many wells,  what capacity?
   6.  What are total production capacity, average production, peak demand?

-------
                                   B-3
C.  DETECTION OF ORGANiCS



    .1.  How was the problem originally discovered?



     2.  When was the problem first suspected?



     3:  Who initiated testing for organics?



     4.  When was contamination by organics confirmed?



     5.  What organics were tested for?



     6.  What organics were detected, in what concentration, in how many wells?



     7.  How long might problem have existed?



     8.. Are any other problems suspected?



     9.  Might nearby untested sites also be contaminated?



    10.  How much did testing cost?



    11.  Who bore the costs?



    12.  Did the required expense delay the decision to test?



    13.  Who performed the tests?


                              X
    14.  How were they selected?



    15.  Were the service, turn-around time, test quality, and reports
         satisfactory?



    16.  How confident are you of the results?

-------
                                   B-4
C.  DETECTION OF ORGANICS  (Continued)        .         ;      ,



    17.   What local,  state or  regional  organizations were involved in
         detecting organics in the ground water, and what roles did they play?



    18.   Did any industry representatives or consultants become involved?


    19.   What action was  initiated on the basis of test results?


    20.   What organizations were notified?


    21.   Was the public notified?  How?
    22.
Would better technical information,  equipment,  or  training have been
helpful?
    23.
In retrospect, what were the major problems  in detecting organic
contamination?         •                   . •  •   •   .  "  •
    24.  General comments.

-------
                                  BrS
D.  EVALUATING SCOPE OF CONTAMINATION PROBLEM-         .


     1.   What actions  were  taken to determine  the scope of the problem?


     2.   What testing  or monitoring programs were considered?
     3.   If such programs were  set up, give details on frequency, location,
         etc.                                   .           •
     4.   How far is  the  source of contamination from affected wells?


     5.   What is the soil type?



     6.   Do you have any indication that the contamination is spreading?


     7.   What is. the depth  and areal extent of the aquifer?


     8.   How long has the source been contaminating ground water?


     9.   Are other wells threatened?  •



    10.   What other  waste dumps, landfills, or industrial sites are nearby?


    11.   Do you expect any  more of the same or other contamination to occur in
         the future?



    12.   Who was contacted  for assistance in this stage?


    13.   Who had responsibility for this stage?


    14.  .What local,  state, or regional organizations became involved in
         evaluating  the  scope of the contamination problem, and what roles did
         they play?

-------
                                   B-6
D.  EVALUATING SCOPE OF CONTAMINATION PROBLEM (-Continued)


    15.   Did any industry representatives or consultants become involved?


    16.   What did follow-up  testing  and/or monitoring and/or other actions
         cost?


    17.   Who bore the costs?                                  •. •.


    18.   Did you feel sufficiently informed as to what to look for?


    19.   Were testing techniques, equipment, technical expertise, timing, or
         costs constraints at  this stage?


    20.   Was the public  involved in  evaluating the scope of contamination?
         How?


    21.   Were government officials involved?  How?


    22.   Do you feel  the scope of the contamination problem was adequately
         determined?   With what certainty?


    23.   General comments.           ..   ''   •

-------
                                   •B-7
E.  RESPONSE TO PROBLEM


     1,   What action was finally taken?         -;   •-••"  -


     2.   What options were considered?


     3.   What factors seemed important?
                      \    \

     4.   What parties were consulted in arriving at a decision?
     5.  What other state,  local, or regional organizations eventually became
         involved in responding to the drinking water problem, and what roles
         did they play?
     6.  Did any industry representatives or consultants become involved?


     7.  What health information was considered?


     8.  Were SNARLs used in choosing a response?


     9.  Were they understandable?
    10.  Did state or.municipality have any applicable regulations or
         guidelines?
    11..  Would regulations (MCLs) rather than guidelines (SNARLs) be helpful
         in deciding on treatment?
    12.  How were potential changes in regulation considered?


    13.  Was the time frame of response critical?


    14.  What was the final cost of resolving the problem?


    15.  What alternatives for funding were examined?

-------
                                   B-8
E.  RESPONSE TO PROBLEM (Continued)    .


    16.   Who bore the costs?          ,     '       , .  ••  • •



    17.   Were technical  expertise, treatment technologies, or information on
         health effects  constraints to decision-making?


    18.   Was the public  involved in responding to the problem?  How?


    19.   Were government officials involved?  How?


    20.   Are you satisfied with the resolution of the problem?


    21.   In  retrospect, where could more assistance have been helpful?


    22.   What  were the major problems in responding to the problem?


    23.   General  comments.

-------
                              APPENDIX C


                          CASE STUDY REPORTS


                        Case                                            Page

BEDFORD,  MASSACHUSETTS	 C-l
ROCKAWAY  TOWNSHIP, NEW JERSEY	 C-7
SOUTH BRUNSWICK TOWNSHIP, NEW JERSEY	 C-18
GARDEN CITY PARK WATER DISTRICT, NEW YORK		 C-24
GLEN COVE,  NEW YORK  	 C-32
VESTAL, NEW YORK			 c-42
NORTH PENNSYLVANIA WATER AUTHORITY,  LANSDALE, PA .	 C-48
VERO BEACH,  FLORIDA	 c-55
ELKHART,  INDIANA	.	 c-61
BATTLE CREEK, MICHIGAN .,..	 C-70
PETOSKEY, MICHIGAN	. .  . .	:	 C-81
NEW. BRIGHTON, MINNESOTA	'.'...	 C-88
TUCSON, ARIZONA	•	 c-97
GREAT OAKS  WATER COMPANY, SAN JOSE,  CALIFORNIA  		 C-lll
LAKEWOOD, WASHINGTON	 c-121
                     FORMAT  FOR CASE STUDY REPORTS



                  SUMMARY

                  BACKGROUND INFORMATION

                  DISCOVERY OF CONTAMINATION  PROBLEM

                  ACTIONS TO PROTECT WATER  QUALITY

                  CURRENT STATUS

                  INSTITUTIONAL INVOLVEMENT

                  HEALTH GUIDELINES

                  CONCLUSIONS

-------
                                  C-ii
                            ABBREVIATIONS






 DBCP:   dibromochloropropane




  DCE:   dichloroethylene




 DIPE:   diisopropyl ether




  GAG:   granular activated carbon




 MERL:   EPA Municipal Environmental Research Laoratory




 MTBE:   methyl tertiary butyl ether




  NAS:   National Academy of Science




  PCE:   tetrachloroethylene




SNARL:   "Suggested No Adverse Reaction Level"




  TCA:   trichloroethane




  TCE:   trichloroethylene




  VOC:   volatile organic compound
                                UNITS






  gpra:    gallons  per minute




  mgd:    million  gallons  per day




 mg/1:    milligrams  per liter




  ppb:    parts  per billion




 Vg/1:    micrograms  per liter (roughly equivalent to ppb)

-------
                           CASE STUDY REPORTS


                             TOWN OF BEDFORD
                              MASSACHUSETTS


SUMMARY

    Over the past several years, the Town of Bedford has experienced a substan-

tial water supply shortage as local growth has surpassed the municipal water

system's capacity.  The shortage was  seriously compounded when two  synthetic

organic compounds were accidentially discovered in the finished water.   Four

of nine wells were found to be contaminated with trichloroethylene  (500 ppb)

and trichloroethane as well as dioxane (2100 ppb).   The State then  recommended

closing the wells.

    Bedford responded to the crisis in several other ways as well.   Water use

bans, changes in water charge rate structure,  and purchases  of water from

neighboring systems were the short-term measures employed.   Efforts  directed

toward long-term resolution of the problem included acceleration of  an ambit-

ious exploration and development program for new wells and investigations into

halting the discharge and leaching of contaminants  from the  industrial  source.

Bedford is currently testing new wells but still will not be able to meet water

demands for several years.



BACKGROUND

    The Town of Bedford supplies water to a residential population of approxi-

mately 11,000 residents and a total employment population of about 24,000.

Bedford's water comes from two sources:   indigenous  wells and external  connec-

tions.  Nine wells supplied about 75  percent of the  town's water  requirements,

-------
                                   C-2
with the balance purchased from neighboring systems.   Unfortunately,  the four




wells that became contaminated with volatile organic  chemicals provided almost




two-thirds of the indigenous supply.  Average daily demands are about 1,75 MGD,




with correspondingly higher summer peaks.









DISCOVERY OF THE CONTAMINATION PROBLEM




    The discovery of organic chemicals in Bedford's drinking water was com-




pletely accidental.  In May 1978, an engineer who lived in Bedford tested his




water as preparation for a paper he was writing.  Relatively high levels of




organics showed up in his test, so he called town officials.  When the town




became aware of the problem, officials closed the wells and notified the state




Department of Environmental Quality Engineering (DEQE).  DEQE tested the water




to  confirm the presence of organics and agreed with the decision to close the




wells on June 2, 1978.  Besides 500 ppb of trichloroethylene and 2100 ppb




dioxane, the DEQE analysis showed that dichloroethane, bromodichloromethane,




and traces of chloroform were present in four of Bedford's nine wells.
 ACTIONS  TO  PROTECT WATER QUALITY




     Massachusetts  generally  follows  the EPA  SNARLs  for allowable levels of




 organic contaminants  in drinking water supplies.  When dioxane was found, DEQE




 called EPA for more information.   EPA suggested  a maximum contaminant level of




 20 ppb for dioxane.  Based on the  guidelines,  DEQE  and the Board of Health




 recommended closing well Nos.  3, 7,  8, and 9.




     Besides closing the contaminated wells,  Bedford took several other measures




 to combat the problem.   To reduce  water consumption the town  instituted water




 bans such as those used previously during  summer months.  Bedford  also changed

-------
the price structure for drinking water from, a flat rate to an ascending block




rate, which discourages use.                          -




    To meet existing water demands Bedford made arrangements to purchase water




from several neighboring interconnected water systems.  This solution is only




temporary because purchasing the water at retail is quite expensive  ($1,400-




1,600/day) and several of the neighboring systems are experiencing water




quality problems themselves.               ,




    The Town of Bedford expects to spend $3 to 4 million on an exploration and




resource development program .to replace and expand the municipal water supply.




Another $1.2 million is expected to be spent on treatment and filtration to




remove iron and manganese.   The long-term plan must now provide about 1 MGD to




meet current restricted demands and may have to provide, as much as another 4




MGD to meet expected 1990 demands.  A study by Bedford's consulting engineers




has identified several potential sites for new wells.  The two most promising




sites may provide enough water for short-term demands, but high levels of iron




and manganese have required expensive treatment technologies.  The search for




new water supplies is continuing.




    In the fall of 1978, Bedford contracted with a consulting firm, Camp,




Dresser, and McKee (COM), to determine the extent and magnitude of aquifer con-




tamination,  pinpoint the source(s), and outline actions the town.could take.




Several of the industries suspected of causing the contamination also hired




their own consultants.




    The COM report, which cost Bedford $130,000, recommended three general




courses of action:  a-program to flush the..aquifer,  investigations into treat-




ment methods,  and development of alternative water supplies.   A plan to pump




three contaminated wells to waste in the Shawsheen River was  eventually




approved by the Massachusetts Department of Environmental Quality  Engineering

-------
                                   C-4
and EPA, but pumping has not yet started.   Treatment methods to control the




levels of organics in drinking water have not been extensively investigated.




Developing alternative water supplies has been made a high priority, and a




major program in that area is continuing, as discussed previously.




    Efforts to pinpoint the source('s) and define the extent of contamination




have had mixed results.  The town and DEQE have been successful in isolating




several point sources.  Programs of test well drilling and sampling have pro-




vided information to develop subsurface descriptions of lenses of contamina-




tion associated with various industrial sites.  The source of dioxane was not




difficult to trace since only one firm in the watershed used the  chemical.  In




most cases, actions to  prevent  further contamination and continued monitoring




have generally been adopted, and litigation has been undertaken by the town




against the alleged contaminating companies to assign  legal responsibility for




remedial measures.  In  a few other  cases, multiple  sources  have confused  the




situation and  emphasized the vulnerability of the  aquifer to  accidental contam-




ination.
 CURRENT STATUS



     At present, Bedford is still involved in litigation against an allegea con-




 taminator.   The affected wells remain closed.   A NPDES permit was  received to




 pump contaminated water to the Shawsheen River, but pumping operations have




 not yet begun.  The Shawsheen River well field has been rehabilitated to clean




 out iron and manganese deposits, bringing the wells back up to original capac-




 ity.  At the Concord River site, three new wells have been drilled, but the




 treatment plant to remove exessive levels of iron and manganese has not.been




 completed.

-------
                                   C-5
 INSTITUTIONAL  INVOLVEMENT




    The Massachusetts Department of Environmental Quality Engineering, the




 agency with primacy over drinking water in the state has been the nominal lead




 agency in the Bedford case.  DEQE has a good staff of hydrologists, geologists,




 and engineers supplemented by a toxicologist and an analytical laboratory.  A




 recently approved bond issue has given DEQE $10 million for funding investiga-




 tions and remedial actions at contamination sites.  Financially, the state is




 now very well equipped to deal with organics problems.




    The Town of Bedford has also been very active in the contamination case,




 assisting in the preliminary industrial survey and contracting with COM to




 trace the sources of the volatile organics and dioxane.   According to the




 state, the Bedford case was fairly straightforward,  but  the town's budget




 constraints hindered efforts to find and control the sources.




    The other major actor in resolving Bedford's organics contamination prob-




 lem was Camp,  Dresser,  and McKee,  the town's water consultants.   The only real




 difficulty COM had during their sampling and monitoring  well program was with




 inconsistent analytical results from various labs.   This situation changed as




 the labs  improved quality control,  although some analytical testing was shifted



 to the state labs.









 HEALTH  GUIDELINES




   •Although the Massachusetts  Department  of Health  has  some jurisdiction over




water systems,  the Department of Environmental  Quality Engineering has  been




 awarded primacy for the state's drinking water  program and  wields  the overall




 authority.   As  mentioned above, DEQE  usually uses  the  EPA SNARLs as  a basis  for




 allowable  levels of organics in water supplies.  At  75 ppb  for trichloroethy-

-------
                                   C-6
lene and somewhere between 300 and 1000 for trichloroethane, the SNARLs are




considerably higher than the health guidelines in most states.




    A DEQE offical stated, however, that although the state has urged several




water systems to place previously-contaminated wells back into service, no




water utility is willing to take responsibility for pumping even relatively




low levels of organics into the water system.  In more than one case, wells




with total organics levels below 10 ppb are still not being used.









CONCLUSIONS




    Although the Bedford  incident  is presently considered to be a relatively




straightforward, basic case,  in  1978 it was not viewed as such.  At that time,,




few persons had had much  experience in dealing with organics  in ground water,




and no  EPA guidelines were available.  Where  standard procedures for  sampling.,




drilling, and analytical  work are  now generally accepted, little guidance  was




then  available.  EPA's recommended techniques generally  have  been considered




as good in terms of quality  control and  legally-defensible  data, but  time




consuming.




    Several  technical  and policy areas have remained as  weak  points.   One  tech-




nical problem  is  that  while  plenty of  information was avilable on-trihalomet-




hane  and volatile organic removal techniques, COM was unable  to find any




methods for  removing dioxane from water.   Research to develop treatment techni-




 ques  for various  classes  of  related  compounds was suggested as one  area where




 EPA assistance is critical.   Officials indicated there is a need for greater




 consistency between regions  in terms  of acceptable aquifer cleanup  techniques,




 improved health effects information,  and better coordination at the EPA




 regional office,  where frequent turnovers hindered progress in the Bedford




 case.

-------
                                    C-7  ,
                             ROCKAWAY TOWNSHIP
                        MORRIS COUNTY, NEW JERSEY


 SUMMARY

    During their own testing in November  1979, Rockaway Township health offic-

 ials discovered trichloroethylene-in the  municipal water system.  The contam-

 ination was traced to one well, which was eventually pumped through aeration

 to waste to keep the TCE from spreading to other nearby wells.  When other

 organics, namely diisopropyl ether and methyl tertiary butyl ether showed up

 in the course of increased monitoring at  the two remaining wells, a water

 emergency was declared.  Township officials then obtained an emergency appro-

 priation to have carbon adsorption units  installed.  The adsorption units

 removed most of the organics, but the granular activated carbon (GAG) had to

 be replaced almost monthly, rather than every six to nine months as originally

 estimated.  Rockaway Township,  therefore, designed and installed a packed

 column air stripping unit that  removes over ninety percent of the problem

 organics.                         '     '   .     -   .  .   .



 BACKGROUND

    Rockaway Township is located along Interstate  Route 80 in Morris  County in

North Central North Jersey.   The Township has  a population of about 20,000

people,  most of which is supplied potable water from municipal .water  supply

systems.   Approximately half of the Township population is  served by  a ground-

water supply system owned and operated by the  Township.  The remainder of the

population is served by water suppliers  in adjoining municipalities or by indi-

vidual wells.   A ban on new septic systems has  effectively  halted new construc-

tion in 'the Township.

-------
                                   C-8
    Rockaway's ground-water supply system consists  of  three wells, located

about 80 feet from each other as shown in Figure 1.  The  individual capacities

of the three wells are:
                         Well No.  4:     350 gpra
                         Well No.  6:     550 gpm
                         Well No.  7:   1,000 gpm
When the wells are pumping simultaneously,  the combined capacity of  the  system

is about 2.0 mgd because of head constraints.   Each well is  approximately  100

to 200 feet deep and taps an unconsolidated, glacial deposit.   Historically,

the Township's ground-water supply has exhibited very good quality and required

only disinfection prior to pumping into the distribution system.
DETECTION OF THE CONTAMINATION PROBLEM

    In November 1979, trichloroethylene (TCE) was detected in Well Nos.  4 and

6.  Township officials initiated the testing because of articles they had read

in professional journals warning of growing problems with synthetic organics in

ground-water supplies.  The Health Department consequently sampled the finished

water and sent the samples to their contracting laboratory for a standard VOC

scan.  Follow-up samples sent to the EPA labs at Edison, New Jersey confirmed

that both wells had consistently high levels of TCE:  50 to 100 ug/1 in Well

No. 4 and 170 to 220 ug/1 in Well No. 6.  Both wells are located at the east

end of the  well field, nearest to the suspected source of contamination, which

is about 1,600 feet east of the wells as shown on Figure 1.

-------
                                                    C-9
                                                                                                Approximate
                                                                                                Suspected Source
                                                                                                of Ice Contamination
           	7   /

Figure  1.    Location of Rockway Wells.

-------
                                   C-10
    The New Jersey ,State Department of Environmental Protection (NJDEP) has




set "action levels" at 50 ppb for a single VOC and 100 ppb for total  VOCs.




The New Jersey action levels are the same as those for New York.   New York has




probably spent more time and money on investigating the effects of organics  in




drinking water than any other state.



    Below the action levels, no action is required on the part of the water




system.  Above these levels, the system is required only to notify the NJDEP.




If VOC concentrations exceed the action levels, NJDEP will recommend whether




the water supply should be taken out of service, taking into consideration the




size and importance of the potential disruption in relation to the remainder




of a municipality's water supply.
 ACTIONS TO PROTECT WATER QUALITY



    .Since TCE levels  in-Wells Nos. 4 and 6 were considerably higher than the




 state's  maximum  recommended  levels, township officials quickly took the two




 wells  out of service.  The Health Department then began looking for the source




 of contamination and  researching  the possible health effects of trichloroethy-




 lene.  At the same time,  officials started  inquiries into treatment methods




 for removing the TCE.



     EPA  Region  II was contacted for  assistance, but was not  able to offer much




 help.  Region  II did  eventually tell Township officials that the Rockaway con-




 tamination  problem would be  put on the Superfund  "Priority List" and  therefore




 be eligible for financial assistance,  but  this  information was  incorrect.  The




 Township also  contacted EPA  Region  III officials  who did  provide an explana-




 tion of applicable regulations and  guidelines  and useful  information  on trich-




 loroethylene in drinking water.

-------
                                   C-ll
     By  early  1980, the Health Department had  investigated testing  laboratories




 and  had selected one of the  less expensive  labs to test the  samples still being




 collected.  Continuing tests soon showed that contamination  was spreading to




 the  remaining good well.  To keep TCE  levels  low in Well No. 7y Well No. 6 was




 pumped  to waste in an adjacent brook,  preventing the contaminant plume from




 migrating westward.                                                 .




     By  the summer of 1980, water usage restrictions were in  place  and the




 Health  Department was engaged in discussions with the suspected industrial




 source,  a company that used TCE.  The  source initially suspected-was identi-




 fied by the Health Department as about the only company in the Township that




 used TCE.  The plant site also was upgradient from the Township well field.




 In cooperation with NJDEP, the Township convinced the suspect company to drill




 five test wells, one of which was on the far side of the plant site from the




 wells.  This particular well showed the greatest levels of TCE, 'in effect




 exonerating the company as the main source and leading the search beyond the




 political border of Rockaway Township to another industrial site.




     The site currently suspected is a federal facility built in the 1940s.




 The  federal facility is a factory which reached full production in the 1950s




 and  1960s and used,TCE baths to clean parts used in fabricating rocket engines.




 Since Rockaway Township has no jurisdiction,outside its political boundaries,




 the matter has been turned over to the state for investigation'and enforcement.




 Investigations into the source of TCE extended through the summer of 1980.




    During this time the Township began to consider alternatives for dealing




with the TCE contamination problem;   Three main alternatives  were suggested:






         • drilling a new well in the western portion of the  Township;

-------
                                   C-12
         • purchasing water from the neighboring municipality of Dover;  or
         • treating the contaminated wells.


The first option would have required several years to investigate potential

well sites and install a new well with sufficient capacity and quality.   The

second option would have required a contract, possibly a long-term commitment,

to purchase water at a higher price than the Township could supply from their

wells.  Interconnecting pipelines and meters would also have had to be con-

structed to implement this option.  The treatment options considered included

both aeration and GAG adsorption.

    As these alternatives were being considered, the Township began to receive

taste and odor complaints about  its drinking water.  In October 1980, the TCE

problem was compounded by the discovery of diisopropyl ether  (DIPE) and methyl

tertiary butyl ether  (MTBE)  in Well No. 7  at concentrations of  70 to 100 ug/1

and 25 to 40 ug/1,  respectively.  The taste  and  odor threshold  concentrations

for these compounds are between  5 and 15 ug/1, explaining the numerous com-

plaints  from water  customers.

    The  TCE problem became  less  important  as the Health Department scrambled

to deal  with the new crisis. At first, the  Township had no  idea where the

ethers were coming  from.  A Shell Oil Company  gas  station  1,500 feet upgrad-

ient  soon became a  prime  suspect for two  reasons.   When Health  Department

officials noticed a drilling rig onsite,  they  went to  the  station to  ask why

Shell was drilling.  While there, they  spoke with police officers  who mentioned

that they had staked out  the station for  several months  to apprehend  the cul-

 prit Shell suspected of stealing 50 gallons of gasoline  nightly.   After at

 least 6,000 gallons were lost,  Shell began to  suspect  that a leaking  tank was

 the culprit.   Shell notified the New Jersey Department of  Environmental

-------
                                   C-13
Protection (NJDEP) Spill Control group and began investigative drilling.  NJDEP



reportedly failed to notify the Township or the Bureau of Potable Waters'


Groundwater Resource section.                             .    ,     ,



    The Township also had reason to suspect the gas station as the source of
        /

the ethers due to some detective work at EPA headquarters.  When-the Health



Department, baffled by the appearance of more organic contaminants, called the


head of the Criteria and Standards Division in the Office of Drinking Water


Supply (ODWS), he had his staff perform a literature search on the two



ethers.  This effort turned up the fact that the methyl tertiary butyl ether


was a proprietary gasoline additive used only by Shell.  Throughout their


efforts .to resolve the various contamination problems^



Township officials have stated that ODWS was extremely responsive.



    Shell drilled about fifteen monitoring wells to determine the extent of



aquifer contamination.  Faced with their own information and evidence gathered



by the NJDEP Groundwater Monitoring and Enforcement group, Shell-agreed to pay


for the hydrogeological work.


    Meanwhile, although little health information on the new contaminants was


available, the Mayor declared a water emergency when the ethers were discovered


and went immediately to the Township Council with the engineering and health


staff for an emergency appropriation of funds to install a treatment system.


At that time residents were advised not to drink the water and were instructed


where to obtain water for drinking.  The Township was very' prompt and open in


notifying the public.  Health Department staff spent the weekend following the


announcement at a phone bank, answering more than 1,000 calls per day for


several days.                                               .

-------
                                   C-14
    The Township had already discussed GAG adsorption with the Calgon Corpora-




tion.  When the water emergency was declared, officials had little choice but




to choose a GAG adsorption system as the optimum treatment method for a range




of organics and as the most expedient solution to the problem.  After some




negotiations with Calgon, the Township was able to purchase (rather than make




the usual leasing arrangement) a GAG system on very advantageous terms.  Within




three weeks, two 20,000 Ib. GAG contactor tanks were installed and the system




was put on line.  The system cost was estimated at $200,000.




    Based on the TCE levels initially detected in the wells, the carbon was




expected to last six to eight months before regeneration was necessary.  After




three months of operation, however, the DIPE concentration in the contactor




effluent was 14 ug/1, MTBE was at 23 ug/1, and TCE was not detected.  With the




ethers "saturating" the carbon and breaking through earlier than expected, it




became necessary for the township to replace the carbon every two months,




rather than every six or nine months.  By the end of 1981, the carbon was being




replaced at a rate of about once every four to six weeks, at a cost of $32,000




per change.  The Township negotiated, with Shell to pay for the carbon.




    Because of the replacement expenses due to the quick breakthrough of the




ether compounds, the Township began to investigate aeration techniques as




pretreatment to the GAG adsorption system.  Officials at ODWS suggested they




contact the EPA Cincinnati Municipal Environmental Research Laboratory (MERL)




for help in conducting pilot studies.  Pilot-scale tests were conducted at the




well site using a packed-column aeration process, and test results  indicated




that adequate removal of organics could be achieved using aeration.  Shell




sent an engineer to help design a treatment installation and agreed to pay for




an aeration facility.  'Consequently, a packed column was fabricated on

-------
                                     C-15
  site  and put  on  line  in December  1981  at  a  reported  cost  of  $375,000  for the



  1.7 mgd  tower.









  CURRENT STATUS





     Currently, both aeration and GAG adsorption are used  for VOC removal.  As




  expected, the life of the carbon has been prolonged by reducing the influent




  ether levels to the GAG contactors.  Removal efficiencies for DIPE have usually




  been greater than 99 percent, while about 95 percent of the MTBE and virtually




  all of the TCE are removed.   At the time of this report (November 1982) the




 carbon on line when the aeration system was installed is still in place.  The




 raw water still is pumped through the packed column to the contactor tanks  and




 then to the distribution system,  but Township and Shell officials feel the




 adsorption step is unnecessary at  this  point and are  considering taking the




 tanks  off. line. . The Township will maintain  the capacity to bring carbon




 adsorption back on-line  quickly in anticipation of the arrival  of the  major



 part of the ether plume.





    The cost of service  to water customers has  increased  from $0.27/thousand




 gallons to $0.48/thousand gallons with  the addition of GAG treatment and




 aeration.  This figure is estimated  to  drop to  $0.40/thousand gallons  after



 the well  pumps are restaged.









 INSTITUTIONAL  INVOLVEMENT




    The Township Engineer and Rockaway Township Health Department organized




 and carried out a response to the contamination problems with the help of




 several other agencies.  The Township, however, took the lead in dealing with




trichloroethylene and ethers  in their drinking water.   For a relatively small




body with no previous  experience with similar problems, the Health Department

-------
                                   C-16
and others played an extremely active role in researching the situation and

evaluating alternative solutions.  Although officials felt they were often in

over their heads and had to operate continually in  crisis mode,  their

responses were rapid, and little effort was spared to protect public health.

    Briefly, the roles taken by other agencies in the Rockaway Township ground

water contamination case were as follows:
             U.S.  Environmental Protection  Agency (EPA).  At  least four
             groups in EPA were involved in the Rockaway Township case.
             Region II and Region III were both contacted for assistance, but
             Region III was more helpful, even though New Jersey is located in
             Region II.  The experiences of other regions indicate that this
             might simply have been the result of contacting the wrong person
             at Region II, or that Region III has had more experience in
             dealing with this type of problem since state programs in Region
             III are not as established as those of, for example, New York.

             The Office of Drinking Water Supply in Washington, and partic-
             ularly Dr. Cotruvo, was credited with being very helpful in pro-
             viding information on the contaminants detected in the Township's
             water.  Similarly, researchers at the Municipal Environmental
             Research Laboratory were quick to provide technical assistance in
             evaluating and testing various organics removal techniques.

             New Jersey Department of Environmental Protection (NJDEP).
             Three sections of DEP had some involvement in the Rockaway
             Township case.  Most helpful was the  Groundwater Monitoring and
             Enforcement group, who came out and helped trace the gasoline
             spill.  This group's work established the evidence used to prove.
             that  Shell was unquestionably  the source of ethers in Rockaway
             water.  The State's Bureau  of  Potable Water followed the  Rockaway
             Township  incident, but did  not actually become  involved except to
             verify  one  set of  test results.  The  Spill Control group  at NJDEP
              apparently  made  a  major blunder in not notifying the Township or
              state ground water group of the Shell gasoline  leak.

              New Jersey State  Health Department.  Rockaway Township
              officials  stated that  the  state toxicologist was very helpful  in
              supplying and interpreting health  information.  The toxicolo-
              gist 's  quick response  was  appreciated since the Township  was
              under fire to explain  the  health hazards  associated with  TCE  and
              the ethers  to the public.

-------
                                    C-17 '
 HEALTH  GUIDELINES                              -




    The health  guidelines  for  drinking water quality recommended by the State




 of  New Jersey  (a maximum of  50 ppb  of  any one organic or 100  ppb of 'totaT




 prganics) have  already been  outlined.   The guidelines parallel  those drawn up




 by  the New York State Department  of Health.   Some  other  municipalities  in New




 Jersey have  reportedly been  given different- recommended  "maximum .contaminant




 levels, however, so the health guidelines  do not appear  t6 be: firmly-estab-



 lished.                             .-'•.'           ''-.."•• '.-.-• i •...••








 CONCLUSIONS




    Rockaway Township officials eventually handled their organics contamination




 problem very, well.  With a minimum  of  outside assistance, the Township  removed




 the immediate health hazard, tracked down  the sources of contamination,




 designed and installed two treatment systems, -and  negotiated ah agreement  for




 one responsible party to pay for  treatment.   Health Department'officials




 believe that the state and federal  agencies  should act only as  technical and




 scientific resources whenever the local government has enough resources to



 take the lead.




    In agreement with this view point, the local officials feel!that their big-




 gest weakness in dealing with .the prganics contamination was a  lack of informa-




 tion oft health effects.   They call  for some useful, consistent numbers to guide




 them in protecting public health.   Township officials believe that testing and



 reporting requirements would turn up quite a  few local water systems with




 organics- levels in the 25-50 ppb range, as well ,as some-wells with over 50 ppb




which have not been tested thus, far because of the desire to avoid the poten-



 tial long-term costs of having to... treat contaminated water.

-------
                                   C-18
                        SOUTH  BRUNSWICK TOWNSHIP
                      MIDDLESEX COUNTY, NEW JERSEY


SUMMARY

    The accidental discovery of trichloroethane in a South  Brunswick Township

water well in 1977 began one of the first cases of organics contamination  in

New Jersey public water supplies.   South Brunswick Township Well  No. 11, which

supplied one-third of the Water Department's capacity, was  closed when  tests

showed 400 to 500 ppb of trichloroethane (TCA).

    The Township responded by hiring a ground-water consulting firm to  trace

the source of contamination.  Geraghty & Miller drilled  a  series  of monitoring

wells that traced the contaminant plume towards an IBM plant.   When notified,

IBM voluntarily drilled their own wells, installed an air-stripping tower,  and

began pumping out the contaminated water.  After two summers of dangerously

low water supplies, South Brunswick eventually installed a new well to  restores

capacity.  The Township also began pumping Well No. 11 to  the sewer system and

cut back on nearby pumpage to prevent further migration of the plume.   IBM ha,si

reimbursed the Township $1 million for expenses incurred.



BACKGROUND

    South Brunswick Township is located in Middlesex County, New Jersey,  at

the south end of the New York-Newark-Elizabeth sprawl.  When the contamination

incident was discovered, the Township Water Department was supplying water to

about  18,000 persons with three wells.  The Township wells are screened from

about  80 to 100 feet and tap the lower, but not completely confined,  aquifer.

Average demands are about 2.5 MGD, with summer peaks near 4.25 MGD.  Several

heavy  manufacturing and chemical industries are located in the Township.

-------
                                    C-19
 DISCOVERY OF THE CONTAMINATION PROBLEM            ;:i




     In September of 1977,  the  New  Jersey-Department  of  Environmental  Protec-




 tion XNJDEP) tested South  Brunswick's  water  as part  of  a  state-wide program.




 No organics were detected  at that  time..  In'December, a local-company that had




 found trichloroethylene  (TCE)  in.chlorine gas cylinders it used'warned other




 chlorine users  to check  their  supplies.   When the South Brunswick-water was




 sampled,  the analysis confirmed that both finished and  raw water had  TCE.'




 Since this result was highly curious,  another, analysis  was run that showed •




 that the organic detected-was  actually 400 ppb of trichloroethane (JTCA), not




 TCE,  and that the chlorine feeder had  nothing to do with the newly.Adetected




 chemicals..  Levels  of tetrachloroethylene near 150 ppb'were, found.later.








 ACTIONS TO PROTECT  WATER QUALITY




     The  first step  taken by the Township was to close the-contaminated ,well.




 Four  hundred parts per billion of trichloroethane was riot a borderline case in



 terms of health guidelines, so officials acted quickly to remove Well No.  11




 from  service.   A new well at the other end of the township was not completed




 until two years later, so South Brunswick experienced;several water crises



 during the summers.   One of the two remaining wells  also went out of service




 periodically for repairs, .further complicating matters.  Fortunately,,  the




 Township has 5.5 million gallons  of storage  (more than a .peak day's  demand)



which helped a  great deal during  the shortage.




    The second  step  taken by the  Township  was to  hire a  giroundTwater rconsul-



 tant, Geraghty  & Miller,   Geraghty  & Miller performed a  two-phase  investiga-




tion, including studying potential  sources, sampling .existing wells, and

-------
                                   C-20
drilling monitoring wells.  The final report indicated that the TCA plume




extended from an IBM facility seven-tenths of a mile to South Brunswick Well




No. 11.



    On the basis of this information, the Township went to IBM and negotiated




a plan of action. IBM did more work to define the plume and drilled seven pro-




duction wells off-site to pump out the contaminated water.  The point source




on IBM property was found to be a leaking buried tank.  Geraghty & Miller




estimated 500 to 1000 gallons of TCA had leaked.  About 1 MGD of contaminated




ground water is now being drawn out of the aquifer and pumped through an air-




stripping tower.  The treated water is discharged to a ditch or sprayed on a




field to recharge the aquifer.  Plans for injection wells are under considera-




tion to recharge the aquifer and create a mounding effect which should halt the




spread of contaminated ground water toward South Brunswick wells.1




    One year after the problem was discovered, monitoring wells indicated that:




the plume was mig'rating toward the remaining two South Brunswick wells.  Well




No. 11 was reactivated and pumped to the sewage system to halt the spread.




When the new well came on line a year later, the Township switched one of the




original wells to back-up capacity to reduce withdrawals near the contaminated




zone.  Well No.  11  is being pumped to waste at  0.85 MGD, which is upsetting




local  officials  who are sensitive to the  fact that their  aquifer is threatened




not only by organics  and  salt water  intrusion but also by oversubscription.
 CURRENT STATUS



     For the short term,  at least,  the South Brunswick Township Water Department




 is in a relatively comfortable position.   With the new  well,  they have  ample




 capacity even if a third of their  supply is lost.   Moreover,  as  a result  of




 various ground-water investigations,  there are now almost 300 monitoring  wells

-------
                                    C-21
 in the Township,  about one per acre.   This  measure of security and the "early-




 warning" wells drilled by IBM around  the South Brunswick production wells  have




 taken the pressure off the Township.   IBM has  also followed through on their




 "good-neighbor" policy and reimbursed South Brunswick for roughly $1 million.




     Besides  the multi-million dollar  five-year abatement program  at the South




 Brunswick facility,  IBM put in monitoring wells  at all their manufacturing




 facilities nationwide.   Several other problem  sites were discovered..  IBM  has




 a highly-trained  crew  assigned to work on contamination  incidents,  and a South




 Brunswick officials  says  that IBM now has the  best analytical  laboratory in



 the  State of New  Jersey.





     Another  industrial  source was discovered, during the  ground-water  investiga-




 tions  in South Brunswick.   A  contaminated plume  from this source was heading




 for  Well No. 12.  The  industry, Mideast Aluminum,  put in their own monitoring




 wells  and eventually began  pumping out the contaminated water and running it •




 through  aeration.  The plume  has retreated and now is confined under the plant.




     Although the  immediate  supply problems have been resolved,  the long-term




 security of the South Brunswick water supply remains uncertain due to potential




 contamination  from unknown sites,  salt water intrusion, and over-subscription.








 INSTITUTIONAL  INVOLVEMENT




    Five years ago, even in New Jersey, water authorities had not  had much




 experience with organic chemicals  in ground-water supplies.   Since the discov-




 ery of the South Brunswick case, much knowledge has been  gained about organic




 contamination of drinking water, but the first  few cases  were definitely learn-



 ing experiences.




    South Brunswick Township handled the situation well,  especially in negoti-




ating with IBM rather than threatening legal action.   Township  officials empha-

-------
                                   C-22
sized the fact that cooperative efforts were much more productive than antagon-


istic efforts.  Fortunately, the Township was able to bear the financial burden


until reimbursed by IBM.


    IBM, in this case as in others„ cooperated completely with efforts to solve


the contamination problem, although they never .actually admitted complicity in


the contamination problem.  Their nation-wide program to investigate ground-


water contamination associated with their manufacturing operations is an


example to other chemical users and producers.
                                    »

    The New Jersey Department of Environmental Protection (NJDEP) did not pro-


vide any financial assistance to South Brunswick, but did offer help with any


litigation the Township should undertake.  The state geologist was very help-


ful in advising on hydrogeologic investigations.  The local Board of Health


never really became involved.


    EPA provided some technical assistance to the Township.  Cincinnati Labor-'


atory personnel set up their portable pilot plant at the contaminated South


Brunswick well.  Several treatment technologies, including granular activated


carbon and resin adsorption as well as aeration, were demonstrated.
HEALTH GUIDELINES


    The New Jersey Department of Environmental Protection set a recommended


maximum of 33 ppb for trichloroethane in South Brunswick drinking water.   The


source of this number remains a mystery, especially since neighboring Rocky


Hill was told that 100 ppb was acceptable and since 50 ppb of any single


organic was suggested to Rockaway Township.  Standard State of New Jersey


policy limits any single organic to 50 ppb and total organics to 100 ppb.

-------
                                   C-23
CONCLUSIONS

    The cooperation between IBM and the township has led to a satisfactory

solution to the problem of contaminated ground water.   The threat to public

health was removed soon after it was discovered, a new water source was

located, and efforts continue to clean up the aquifer.  The Township is  content

with the resolution of the problem and now has quite a few defenses to warn of
                 \
future contamination incidents.

    Township officials maintain that their biggest problem in the TCA case was

with testing.  For quite a while they could riot find three labs to agree on

the contents of the same sample.  This situation has improved greatly since

1977.

-------
                                   C-24
                   GARDEN  CITY  PARK WATER  DISTRICT,
                                NEW YORK


 SUMMARY

    The Garden City Park Water District was notified by the Nassau County

 Health Department in late 1977 that tetrachloroethylene had been found in the

 water supply.  One well was closed in November of that year when two successive

 tests showed contaminant levels of 76 and 84 ug/1.  Since one-fourth of the

 water system was already restricted due to excessive levels of nitrates, the

 tetrachloroethylene problem became very serious when two more wells had to be

 closed in April and June of 1981.  As short-term measures, the Water District

 purchased water from neighboring systems and imposed sprinkling restrictions.

 Conservation efforts and the addition of a new well allowed Garden City Park

 to operate through the summer of 1982 without purchasing water.   Plans to blend

water from different wells to allowable nitrate levels and to start a pilot

plant for organic removal testing have been approved by the Health Department

to restore short-term capacity, but long-term plans to meet water demands are

uncertain.



 BACKGROUND

    The Garden City Park Water District serves a  population of about 24,000 in

a three mile square area located in the southwestern portion of  the Town of

North Hempstead,  Nassau County, New York.   Formerly a dairy-farming region,

the service area is now largely residential,  with some light industry and

commercial establishments.   The Water District is served by the  Nassau County

public sewer system.

-------
                                   C-25
    At the time the organic problem was discovered,  the Water District had nine




Wells scattered throughout the service area.   A new well came on line in early




1982.  All wells but Nos.  1 and 2 pump directly into the distribution system




after chlorination and treatment with caustic soda.   Well No. 6 also has poly-




phosphate added.  Well No. 9 is equipped with a nitrate treatment plant con-




sisting of an ion exchange resin bed which is continuously regenerated through




a closed loop, using salt  as the regenerate.   Mechanical problems have kept the




equipment out of service several times.  Waste brine and rinse water are dis-




charged to the county sewer system, a procedure approved by special permit.




Because of high operating costs, this well is used only during peak periods.




    Total well capacity was about 14.5 mgd before the organics problem was dis-




covered, with over a third of that restricted due to nitrates.  The Water Dis-




trict operates 2.5 million gallons of elevated storage to handle peak demands.




Peak summer demands are near 6.4 mgd, with average winter demands only 2.2 mgd.








DISCOVERY OF THE CONTAMINATION PROBLEM




    Between 1975 and 1977, the US EPA conducted surveys to characterize the




organic chemical contamination of the nations'  drinking water systems.  Alerted




by the preliminary reports on these surveys and the discovery of contaminated




wells near the Grumman Aerospace Corporation facility in Bethpage, the New York




State Department of'Health organized a cooperative effort with Nassau County




officials to sample and analyze water from community wells.  Beginning in 1976,




wells were tested for six synthetic organic chemicals:  1,1,2-trichloroethy-




lene, trifluorotrichloroethane, tetrachloroethylene, chloroform, carbon tetra-




chloride, and 1,1,1-trichloroethane.  By the end of April 1978, 372 community




water system wells had been tested:  tetrachloroethylene and 1,1,2-trichloro-

-------
                                   C-26
ethylene were found in 15 percent and 13 percent,  respectively,  of those




sampled.




  '  Tetrachloroethylene was found in Garden City Park Water District's  Well  No.




5 in November 1977 during the initial testing program.  State Health Depart-




ment guidelines limit any single organic contaminant to 50 ug/1, and total con-




taminants to 100 ug/1.  Concentrations of 76 and 84 ug/1 were detected, so the




Water District complied with Nassau County's request to remove the well from




service.  The Nassau County Health Department (NCHD) requires annual testing




for the six compounds .listed in the paragraph above and requires notification




if the individual maximum contaminant levels (50 ug/1) are exceeded. Testing




at Garden City Park in 1981 showed levels of tetrachloroethylene over 50 ug/1




in well No. 4.  £fter well No. 4 was taken out of service, levels of tetra-




chloroethylene in nearby well No. 6 climbed rapidly until that well also had




to be closed.  One set of tests was performed by the NCHD, and the other by




the Water District's consultants, Holzmacher, McLendon, & Murrell, P.C.




(H2M).  After these wells were closed, the Water District was left with only




3,680 gpm of unrestricted capacity, only about three-quarters of the capacity




necessary for a peak day, even at 100% operation.








ACTIONS TO PROTECT WATER QUALITY




    The immediate action taken by the Water District to protect their customers




from the health hazards of contaminated water was in all cases to close the




wells classified as "restricted".  The Nassau County Health Department  has




drawn up a comprehensive "Policy Statement on Use of Public Supply Wells Con-




taminated by Organic Chemicals" that explains testing, monitoring and reporting




requirements and water quality guidelines.  Details of this document are dis-




cussed  in the Glen Cove case study.

-------
                                   C-27
    The Water Districts' consulting engineers, H2M, have made several sugges-




tions for improving both the short-terra and long-term available supply.  The




short-term options proposed relate principally to blending well water of




acceptable quality with well water which exceeds standards to deliver a product




water to the distribution network that meets the applicable standards or guide-




lines.  The County has approved the blending technique for reducing nitrate




levels, and a project to blend wells 1 and 2 into the 1.5 million gallon tank




at the well site is nearing completion.  The County has restated its opposition




to blending to reduce organic levels, taking the position that there is no




"safe" level of a carcinogen in a water supply and proposing conservation mea-




sures and the purchase of water before organic-contaminated water is used for




drinking.  In 1981, the Water District purchased 142 million gallons from the




neighboring'Albertson Water District, one of six interconnected systems.




    H2M has "also suggested several long-term programs•to remedy the curtailed



supply of water, -agreeing that expected growth in consumption as well as cur-




rent demands must be met.  The consultants approach the long term objectives




in two ways:  installing a new water supply, or treating water at an existing




well(s).   The Health Department has urged Garden City Park to "vigorously pur-




sue selection of a site for a new well", but recognizes the lack of an ideal




location for a new well.  Any new wells would have to be drilled in the north




end of the Water District to avoid the contamination problems apparent in wells




in other locations.  Tapping a different aquifer may provide a solution.  The




minimum short-term resolution to the water supply shortage was estimated by




H2M to cost $355,000, with the full program to increase supply estimated at



$1,530,000.




    With nitrate levels apparently declining and organic levels increasing,



H2M suggests that treatment methods should focus on organics removal.   They

-------
                                   C-28
mention that carbon adsorption, synthetic resin adsorption,  and air stripping




have been used to control tetrachloroethylene,  and propose a countercurrent




packed tower air stripper as the most cost-effective technology.   The Health




Department agreed with H2M that Garden City Park should set up a pilot plant




at Well No. 6 to test removal efficiences and to develop design parameters  for




that well and another potential site.  H2M has decided that they have enough




technical information.to design and install a packed tower air-stripping plant




without setting up a pilot plant, and plan a 1200 gpm (1.7 mgd) installation




at well No. 6.




    The restored capacity from Well No. 6 should meet short-term needs but  not




long-term demands.  The Water District has contracted with a private firm,




Ecolotrol, to plan a pilot biological denitrification plant on Well No. 1 or




2.  The Water District believes that enough of the organics might be removed




by the plant to meet both the nitrate standard and the tetrachloroethylene




guideline.  If so, a 2.5 mgd biological denitrification plant may be installed




to meet long-term water demands.
CURRENT STATUS




    The County Health Department has recently begun drilling monitoring wells




to identify the source(s) of the organics discovered in Garden City Park Water




District wells five years ago.  Several landfills are suspected, but none have




been positively linked to the tetrachloroethylene in Water District wells.




    Conservation measures will be in effect to reduce water demands until the




air-stripping plant is installed.  The plant is expected to be completed in




late 1983.  In the summer of 1983, work should begin on the biological denitri'



fication pilot plant designed by Ecolotrol.  In the meantime, Water District

-------
                                   C-29
officals are still investigating the possibility of using wells with tetra-

chlorpethylene levels slightly over the 50,ppb'Health Department guideline.



INSTITUTIONAL INVOLVEMENT

    the organizations involved in the Garden City Park organics contamination

problem are the following:

           Garden City Park Water District
           Nassau County Department of Health
           New York State Department of Health
           New York State Department of Environmental,Conservation
           u.s. EPA                        .-  ,    •  -              --•••:-
           Holzmacher, McLendon and Murrell, P.C.  (H2M)
           Ecolotrol                        ,


    The Garden City Park Water District is directed by a Board of Commissioners

and operated by the office of the Supertendent.   The Water District  relies on

the County for health information and on a private consulting firm,  H2M,  for

technical and planning expertise.

    The Nassau County Department of Health administers  the basic State programs

in addition to programs initiated by the County.   The Department of  Health is

a large organization with a relatively large staff assigned to drinking water

problems.   The County Health Department has  its  own laboratory and specialists

to carry out programs that most other municipalities would have to relegate to

state authorities.   Since Nassau County was  the  location of New York State's

first detected cases of organics contamination in  ground water,  the  Department

of Health has extensive experience in dealing  with contamination problems.

   .The New York State Department of Health  is the organization that carried

out the first studies of organics in ground-water  supplies  on Long Island.

The State Department of Health has been involved in the Garden City  Park  case

only indirectly,  through the County Department of  Health.   The State developed

-------
                                   C-30
the Interim Guidelines that address organic contamination and has analyzed the




available medical and technical information to assist the counties with ques-




tioliS bn health effects and treatment alternatives.  A summary of information,




as well as the results of several organics surveys, is presented in an excel-




lent comprehensive report entitled "Organic Chemicals and Drinking Water",



revised in April 1981.




    The Department of Environmental Conservation and EPA were not active in the




Garden City park organics case.  The Water District's consulting engineers,




H2M, have played a major role in evaluating alternatives to secure a sufficient




water supply and in planning treatment methods.  Ecolotrol has been involved




with the specialized planning for a biological denitrification pilot plant.
HEALTH GUIDELINES




    The Nassau County Department of Health administers the state health guide-




lines and regulations affecting community and non-community water supplies.




The New York State Department of Health Interim Guidelines for organic chem-




icals specify that the level of benzene or of vinyl chloride shall not exceed




5 ug/1 and that the level of any other single synthetic organic chemical con-




taminant shall not exceed 50 ug/1.  Ground-water source community systems are



required to monitor eighteen organic constituents, including six halogenated




organics:  1,1,2-trichloroethylene, trifluorotrichloroethane, tetrachloroethy-



lene, chloroform, carbon tetrachloride, and 1,1,1-trichloroethane.




    The Interim Guidelines were adopted by the State Department of Health on




January 13, 1977 and modified on February 25, 1980 as a direct consequence of




detecting these organic contaminants in ground water.  Concerns raised over




the hazards associated with long-term consumption of these potential carcin-



ogens prompted the State to take action.

-------
                                   C-31
CONCLUSIONS                              :




    The Garden City Park case involved only  a  few  government organizations,




biit Still touched on many technical topics.  Although the County  is drilling




several monitoring wells, no real progress has been made in conclusively ident-



ifying the source of contamination.  Conservation  measures, more  so than water




purchases, were credited with avoiding severe  water shortages when wells were




closed.  Finally and perhaps most importantly, the consulting engineers hired



by the Water District had enough confidence  in their own expertise and informa-



tion from other projects to proceed with installing a full-scale  packed column



air stripper to remove the tetrachloroethylene found in ground-water  supplies.

-------
                                    C-32
                             CITY OF GLEN COVE
                         NASSAU COUNTY, NEW YORK


 SUMMARY

     The Nassau County Health Department (NCHD) tested the City of  Glen Cove's

 Water in the summer of 1977 for organic compounds.   Their analysis indicated

 that four of Glen Cove's wells contained trichloroethylene (TCE) and tetra-

 chloroethylene above New York.State's maximum allowable  limits  of  50 ug/1 for

 any one organic contaminant and a total allowable  limit  of 100  ug/1 for all

 such compounds.  The Health Department subsequently  restricted  the use of

 those wells.

     The City,  faced with the loss of  half of  its water supply, was forced to

 purchase water from neighboring systems  as  well as to implement conservation

 measures that  summer.   One  of  two wells  being  developed  at the time the con-

 tamination was discovered was-then put on line, allowing water demands to be

 met.   To further  augment their'reduced supply, the City retained an engineer-

 ing consulting firm to  study the  situation.  The firm found that no existing

 treatment  technology was capable  of treating large volumes of water containing

 trichloroethylene and tetrachloroethylene and helped the City secure an EPA

 research grant  to test  several possible treatment methods with pilot studies

 at  one well field.  The first two phases of this study are complete,  and  the

 third phase is  currently in progress.



 BACKGROUND

    The City of Glen Cove is located in northern Nassau County,  New York on

Long Island Sound.  The City supplies  water to a population of about 27,000

with an average demand of 4.14 mgd and a peak demand  of 7.72 mgd in 1981.

-------
                                   C-33
 When the  organics problem was  first noticed  in  1977,  the  City was  operating




 seven wells  drawing  from intervals between 160  and  300  feet  deep.  The  only




 treatment applied to the raw water is  chlorination, with  polyphosphate  and




 sodium  hydroxide added  as corrosion control  agents.   Glen Cove  is  mainly a




 residential  area, with  some light industry and  commercial establishments in




 the center of town.








 DISCOVERY OF THE CONTAMINATION PROBLEM




     Organic  chemical contamination of  the ground water  in Nassau County was




 first discovered in  October 1975 at two Grumman Aerospace Corporation wells  in




 Bethpage, thirteen miles from  Glen Cove.  This  discovery  by  the State Health




 Department and the detection of VOCs in eleven  adjacent public  and industrial




 wells led to the establishment of an extensive  program  to sample all public




•wells.




     Sampling for volatile halogenated  organic chemicals began in late 1976 in




 southeastern Nassau  County.  At that time, samples  from public  wells were




 routinely tested for eight such compounds:   trichloroethylene,  tetrachloro-




 ethylene, trifluorotrichloroethane, 1,1,1-trichloroethane, chloroform,  bromo-




 dichloromethane, carbon tetrachloride,  and 1,1,2-trichloroethane.  Limited




 testing for  vinyl chloride, 1,2-dichloroethylene, methylene  chloride, bromo-




 form and the non-halogenated compounds benzene  and  toluene was  also carried




 out. The samples collected were analyzed by the U.S. EPA, New  York State




 Department of Health, Nassau County Department  of Health, and various




 consultants'  laboratories.




     In  early 1977, the  State Health Department  developed  "interim  guidelines"




 to assist the Department in evaluating data  and controlling  the use of  public

-------
                                    C-34
 supply wells.   The guidelines limited vinyl chloride to  5  ug/1  (micrograms




 per liter),  other organic chemicals to 50 ug/1,  and the combined level  of  all




 Organic chemicals to 100 ug/1.   These guidelines were based on a toxicological




 study in progress by the National Academy of Science which  relied primarily on




 extrapolation  of animal data and were predicated on a lifetime human exposure




 (70 years) to  drinking water (2  liters/day)  which would cause one additional



 cancer death per year.in 100,000 to one million  persons.




     The Nassau County Department of Health sampled  the Glen Cove  municipal




 wells in the summer of 1977.  Four wells  (Numbers 22,  1-S,  20, and 21) were




 placed in the  "restricted" category and closed due  to organic contamination,




 mainly by trichloroethylene  (as  high as 300  ug/1) and tetrachloroethylene  (as



 high as 375  ug/1).
ACTIONS TO PROTECT WATER QUALITY




    The decision to close the contaminated wells was the first action taken to



protect public health.  The Nassau County guidelines for organics in drinking




water are very clear and detailed, so closing the wells was not an arbitrary



decision.




    Faced with the loss of about half of the municipal water supply capacity,




Glen Cove also had to implement conservation measures and purchase water.   The



City entered into contracts with the Sea Cliff Water Division to supply 0.70




mgd and with the Locust Valley Water District for 0.25 mgd to meet the summer




demand in 1977.  Conservation measures were credited with significantly



reducing demand and minimizing the shortage.




    By the summer of 1978, two factors, the closing of a industrial customer




with a water demand of 1 mgd and the opening of a new 2 mgd well,  allowed  even

-------
                                   C-35
summer demands to be met,  although another smaller well (No.  2-S) was closed




in August 1978 due to measured tetrachloroethylene concentrations in consecu-




tive satoples of 73 and 84 ug/1.




    Two efforts initiated in 1977 and 1978 were directed towards ensuring the




long-term availability of safe drinking water.  Beginning in 1977, the Nassau




County Health Department began investigations into the source(s) of Glen Cove's




organic contamination problem.  One study was conducted to identify local




industries that used the halogenated organic solvents.  Another study surveyed




residences and commercial establishments, such as dry cleaners, to update




knowledge of organic chemical usage and disposal practices in the vicinity of




the contaminated wells.  The other main line of investigation concentrated on




methods of treating the water, rather than on isolating the source.  The City




and their consulting engineers entered into discussions with U.S. EPA that




resulted in a research grant to test several possible treatment methods at the



Glen Cove site.




    The first study to identify sources of contamination was carried out by




NCHD in June to December 1977.  Over one hundred inspections/surveys were made




of commercial/industrial sites near the Carney Street and Seamens Road well




fields.  This study concluded that no waste disposal practices were found at




that time which could account for the extent of contamination at the Carney




Street or Seamans Road wells.  The contamination problem was therefore attri-




buted, to past disposal practices, perhaps as recent as the early 1970s.  The




Health Department recommended exploring the feasibility of purging the contam-




inated ground water as well as changing water supply practices.  The difficul-




ties in testing for dichloromethane, a suspected contaminant, were noted.

-------
                                   C-36
    The  second study by the Nassau County Health Department was conducted to




 find the source of contamination of the Seamen Road wells.  This study looked




 more closely  at drycleaners and unsewered residences in the area, as well as




 several  commercial buildings and a distant  (2,000 feet from wells) landfill.




 The NCHD concluded that the one remaining drycleaner was a potential source and




 ordered  several changes at the facility.  The report also recommended connect-




 ing all  unsewered residences and continuing the investigation with subsurface




 exploration techniques.  Finally, the Health Department proposed a specific




 program  of observation well construction and sampling.  No hydrologic/geologic



 studies  of this type have been carried out to date.




    In an effort to treat the contaminated water, rather than to find the




 source,  the City retained the consulting engineering firm of Nebolsine Kohlmann




Ruggiero Engineers, P.C. (NKRE) to design a feasible and economical treatment



 system.  Through consultation with the U.S.-EPA's Drinking Water Research




Division, Municipal Environmental Research Laboratory (MERL), Cincinnati, it




was determined that no existing treatment technology was capable of treating




 large volumes of water containing these organic contaminants.  After prelim-




 inary tests of the Carney Street wells, discussions and negotiations between




the City, NKRE,  and the U.S.  EPA resulted in a research grant (later a cooper-




 ative agreement)  funded by the U.S.  EPA to test several possible treatment



methods at the Glen Cove site.




    Phase I of the pilot project,  begun in March 1979,  tested counter-current



diffused aeration and adsorption using resins.   Phase II of the project began




at the conclusion of Phase I,  after  modifications to the pilot plant equipment




 (including changes in resin-testing  column size,  installation of activated

-------
                                   C-37
carbon towers, adaptations for a larger steam supply,  and installation of a

packed aeration tower and a cooling tower for air stripping)  were completed.

    Tile data developed during the two phases of testing showed that the most

efficient system to reduce organic contamination to low levels was one using

aeration followed by adsorption on resin.  This approach allows treatment by

aeration to efficiently strip all contaminants, significantly lowering the

well water contamination levels, and then polishes the water  with resin,

thereby reducing regeneration requirements and extending the  length of service

time for the resins.  The pilot project has shown that the target contaminant

level is an important consideration in interpreting the data  or determining

the cost of treatment, and the effluent -quality mandated affects the design

parameters, length of service time for adsorbents and  the overall system costs.

Phase III of the pilot project is in progress.   The following table shows the

estimated cost ranges for the"three systems tested:


ESTIMATED COSTS FOR FULL-SCALE INSTALLATION
(Thousands of Dollars)
       System             Capital Costs

       Diffused Aeration     228-471
       Packed Column
         Aeration

       Resin
477-684
308-953
 Annual Operating Costs

122-342
($0.19-0.33/thousand gallons)

130-378
($0.21-0.36/thousand gallons)

 77-228
($0.12-0.22/thousand gallons)
CURRENT STATUS

    According to the Health Department,  the Glen Cove  site  is no  longer con-

sidered a "hotspot"  in terms of organic  contamination.  Since new wells have

come on line, the present capacity is  sufficient to meet water demands, and

-------
  " ""'*   »                    '.  ',             •        !

 little, further action is planned.  The City and NKRE are examining the possi-
    4f  ; '                   •••?•..     ;,

     "                    °     '  •**'* !
 bility'pf getting  a grant for a demonstration plant based on pilot project
     '_,: f. •           :   .     '•' '   *• v "•'.., ',. •

 results, but the outcome of their efforts  is uncertain.  Glen Cove does not



 seem  interested in following up on the problem, as long as immediate water



 demands can be met.







 INSTITUTIONAL INVOLVEMENT



    The Nassau County Health Department has been the lead agency in dealing



with volatile organics in the Glen Cove water supply.  The Health Department,



mostly through the Bureau of Public Water  Supply, initiated the organics test-



 ing program in 1977 that discovered the problems with Glen Cove's drinking



water.  NCHD is responsible for administering the New York State Health Depart-



ment Guidelines for organics in drinking water.  In that capacity, the depart-



ment classified Glen Cove wells into "restricted," "reserve," and "unre-



stricted" categories, with specific suggestions to the City as to approved use


of each category.



    The Nassau County Health Department also planned and carried out two resi-



dential/industrial surveys in the Glen Cove area, in an inconclusive effort to



find sources of contamination.  With a complete laboratory facility capable of



testing for volatile halogenated and non-halogenated compounds, the Department



offers strong technical support to testing and monitoring programs.  In addi-



tion to providing technical assistance, NCHD reviews proposed alternatives for



alleviating water shortages due to organic contamination.



    Since the County has  had over a dozen water systems with serious organics



problems, the large staff and years of experience that NCHD can apply to cases



of drinking water contamination is a definite advantage.  Several other organ-



izations that have been involved to a lesser extent in the Glen Cove case:

-------
                                   C-39
             U.S.  Environmental Protection Agency (EPA).   The  federal
             government has been involved only in two aspects of the Glen Cove
             contamination problem.  EPA research into the health effects of
             various organics was used by the New York State Health Department
             to set the guidelines used by Nassau County to recommend.that
             wells be closed.  EPA is also involved in funding the pilot tests
             at Glen Cove to compare and establish design ^parameters for '-•
             aeration, resin adsorption, and granular activated carbon adsorp-
             tion treatment techniques.

             New York State Health Department.  The State Health Depart-
             ment has been involved in the Glen Cove case' only indirectly.
             The State, however, deserves mention for'its studies of organics
             and drinking water.  At present, the NYSHD guidelines on organics
             in drinking water are being reviewed.  Recommendations on stan-
             dards for organics, rather than the present guidelines, are
             expected to be proposed in late 1982.

             New York Department of Environmental Conservation.   The  .
             Department of Environmental Conservation has responsibility in
             New York under the State Pollution Discharge Elimination System
             and Water Classification System to protect tjie water resources of
             the state, including ground water.  DEC has conducted a state-
             wide survey of organic chemical use, storage and disposal  which
             has been used in Nassau County to identify potential sources  of
             ground water contamination.

             City of Glen Cove.  The City  of  Glen Cove has played a rather
             passive role in resolving the problem of organics in its drinking
             water supply.  Officials stated that once new wells  restored  the
             City's capacity to meet immediate demands,  it reportedly became
             someone else's responsibility to investigate the source and extent
             of contamination.   Consequently,  Glen Cove now has no major plans
             to investigate the problem.  Their consulting engineers are con-
             cluding the pilot tests at a Glen Cove well site, but unless
             federal money becomes  available,  no further action is .expected.
HEALTH GUIDELINES

    The State of New York first announced guidelines  for synthetic organic

chemicals in public water supplies in January 1977.   These guidelines  specify

that the level of benzene or vinyl chloride shall not exceed 5  ug/1, that the

level of any other single synthetic organic chemical  shall not  exceed  50 ug/1,

and the combined total for such contaminants shall not exceed 100  ug/1.  The

State Health Department has extensively researched methods of estimating .risks

-------
                                  C-40
from organic chemicals and has reviewed many strategies for managing synthetic

organic contaminants  in  drinking water, but has kept the 50 ug/1 guideline  for

single synthetic organics.  By Health Department references, 50 ug/1 corre-

sponds to a wide range of risk levels, as shown in the following table for  some

common organics.
MAS PROJECTED LIFETIME CANCER  RISKS FOR
INDICATED DRINKING WATER  CONCENTRATIONS
                             Concentrations  Corresponding to Risk Levels
     Compound

Carbon Tetrachloride
Chloroform
Dibromoethane
Tetrachloroethylene
Trichloroethane
Trichloroethylene
Vinyl Chloride
1 x 10
                                        -4
1 x 10
                  -5
1 x 10
                  -6
450.0
29.0
48.0
220.0
46.0
460.0
110.0
45.0
2.9
4.8
22.0
4.6
46.0
11.0
4.5
0.29
0.48
2.20
0.46
4.6
1.10
                             (all concentrations  in.parts-per-billion)
Note that the risk levels for the "allowable"  50  ug/1 of trichloroethane and

the "allowable" 5 ug/1 of vinyl chloride differ by one  and a half orders of

magnitude.  Despite this apparent inconsistency,  the State of New York has the

most extensive program for dealing with origanic  chemicals in drinking water
                                i
of any state investigated in this survey.  The Nassau County Policy

Statement on  Use of Public Supply Wells  Contaminated  by Organic Chemicals

is one of the most comprehensive documents on the subject produced by county

government.
 CONCLUSIONS

    The  Glen Cove contamination case differs from most others examined in

 several  respects.  First, the presence of organics was detected and a response

-------
                                   C-41
was made under a well-funded, well-organized County Health Department program.




Second, no hydrogeological study was made to determine the source of contamina^




tion.  This kept Glen Cove from finding a responsible (i.e.,  liable) party and




from being certain of halting the source of contamination.  Third,  a pilot pro-




ject has generated quite a bit of information on treatment technologies  that




can be extremely useful to Glen Cove or other water systems with similar prob-




lems.  The value of this data should not be overlooked.

-------
                                  C-42
                                 VESTAL
                                NEW YORK
SUMMARY

    Random sampling of New York water  supplies by  the State Health Department

discovered high levels of trichloroethane in a well  operated by the Town of

Vestal Water District No. 1.   The state came back  and sampled  all of Vestal's

wells and found another, in District No. 4,  contaminated with  trichloroethane

and tetrachloroethylene.  Both wells were shut  down in  the spring of  1980.

    District No. 4 faced a water shortage that  summer and installed a portable

granular activated carbon unit on the contaminated well until  a new well  came

on line.  The State assisted in tracking down the suspected source of contam-

ination, a chemical company less than 300 feet from the well.  The Town of

Vestal  and the  State  are currently involved in litigation against the company.

    Water District No.  1 experienced-no major supply disruptions,  but it was

 feared  that  the contamination would spread to the two remaining wells in the

 district.  The  well  is  now pumped to waste to prevent migration of the organ-

 ics,  and a private contractor  is performing  a study to pinpoint the source.

 EPA recently sent investigators to  the site  to evaluate  the case for Superfund

 assistance.
 BACKGROUND

     The Town of Vestal is located in Broome County in south-central New York

 State.  Vestal supplies water to 27,300 persons,  including 11,000  at  the  State

 University at Binghampton.  The water system is divided into nine  Water Dis-

 tricts, supplied by a total of eight wells.  The wells tap into a  moderately

-------
                                   C-43
vulnerable aquifer at about 140 feet.   The deep bed of  gravel below the soil



level allows rapid percolation.







DISCOVERY OF THE CONTAMINATION PROBLEM



    In 1978, through one of the national water supply sampling  programs, EPA



randomly selected a Vestal well, No.  1-1, for organics  analysis.   The  samples



were delivered to the Cincinnati lab where they set on  a shelf, unrefrigerated,



for a year or two.  When the samples were tested,  some  organics were detected,



but although the results were published, they were dismissed as inaccurate



because of poor handling procedures.   In the spring of  1980, the New York State



Department of Environmental Conservation (DEC) sampled  ground water at nearby



Endicott and, on a fluke, collected a sample from a Vestal well.



    The results of organics analysis on that sample from Well No. 1-1  showed



over 1500 ppb of 1,1,1 trichloroethane.  The state came back and resampled  all



Vestal wells.  This confirmation round of testing confirmed, the results  in
  .  , . * < ••       '                                    O


Well No. 1-1 and also revealed that Water District No.  4 well No.' 2 had  300



ppb of 1,1,1 trichloroethane and tetrachloroethylene.






ACTIONS TO PROTECT WATER QUALITY



    The first step taken to protect water quality was to close  the contaminated



wells.  State Department of Health guidelines are quite specific in recommend-



 ing that water with greater than 50 ppb of a single organic (except vinyl



 chloride, which has a 5 ppb limit) or  100 ppb of total organics should not  be



 used for drinking.



    The two wells were contaminated by different sources.  Well No.  1-1  was



 pumped to waste in the Susquehanna River to prevent the spread of contamina-

-------
                                   C-44
tion to the other two wells in District 1, located about 1500 feet downgrad-




ient.  Levels of contamination have dropped from 1700 ppb to about 200 ppb.




    The Town hired a local consultant to trace the source of contamination in




District 1.  So far, a considerable amount of drilling- and many flow tests have




determined the general direction of plume travel, but no source has been defin-




itely identified.  Vestal requested assistance from DEC for further investiga-




tions.  EPA contractors were recently sent to the site to evaluate the case




for Superfund aid.  The EPA team reportedly copied the existing documentation




in Town files and did no on-site investigations.  Vestal has spent over




$100,000 investigating the source of contamination.




    Closing Well No. 4-2 severely restricted water supplies in that district




of the Vestal water system.  The Town put a portable GAG unit on the well to




help meet  summer water demands.  When a well aready under construction came on




line, No.  4-2 was taken off GAG and pumped to the Susquehanna.  Trichloroethane




levels have dropped from 200 ppb down to  50 or  100 ppb.



    The DEC came  in to trace the source of contamination in Well No. 4-2, cur-




iously enough with State Department of Transportation  funding.  An obvious




source, a  chemical company located 370 feet from the well,  was soon identified.




Apparently the  company had obtained a permit from DEC  to rinse chemical barrels




on a gravel pad behind the building.  The Town  of Vestal and the New York




Attorney General are  currently involved  in litigation, against the  company.
 CURRENT STATUS



     Investigations in Vestal District No.  1 are still continuing while the




 resolution of the problem in District No.  4 is somewhere in the court system.

-------
                                   C-45
The Town is running out of money to finance further investigations and must




find either the responsible party or another funding source.   Even if Vestal




is approved for Superfund monies, the funding probably will not be available




for a year or two.    .








INSTITUTIONAL INVOLVEMENT             -




    The roles of the various agencies involved in the ground-water contamina-




tion cases at Vestal have already been outlined.   The Town of Vestal has played




an active role in finding alternate sources of drinking water and in tracing




the sources of contamination.   The current town engineer was  hired just two




months before the contamination was detected, but he and his  staff responded




well at the time and have gone ahead in making contingency plans in case the




problem worsens.  Extensive research and several national ground-water confer-




ences have provided useful information for making .decisions on treatment and



other technical responses.




    The New York State Departments of Healtn and Environmental Conservation




assisted in testing well water and tracing the sources of organics.   New York




has,a fairly well established state program for dealing with organic contamina-



tion, described in the Glen Cove case study.




    EPA Region II has been involved indirectly.   The regional office provided




some health information to the town, through DEC, and the hazardous  waste sites




branch recently sent in a team of contractors to briefly investigate the case



for Superfund consideration.                         .




    Several other organizations have been involved peripherally.   Roy Martin




Consultants and other local firms have assisted in placing the new wells and




tracing the sources of contamination, especially in Well No.  1-1.   Calgon and

-------
                                   C-46
the American Water Works Associaion have provided information on treatment

alternatives.  The local media was involved in the case, but reportedly criti-

cized the water officials rather than distributing the few known facts of the

problem.  The County Health Department also hindered the investigation by the

Town of Vestal.  Finally, a local citizen and student group organized to lobby

for no allowable levels of contamination has generated some political pressure.



HEALTH GUIDELINES

    The New York State guidelines recommending less than 50 mg/1 of any single

organic chemical and  less than  100 mg/1 for total organics are described in

detail in the  case study of Glen Cove.  Although the New York program for

organics in drinking  water is one of the country's most established, questions

as to what levels of  various organics will be acceptable in even the near

•future complicate decision-making.  Water officials do  not seem to have much

confidence in  the permanence of these guidelines and hesitate to take actions

based solely on the present numbers.  For example, a treatment plant cannot be

designed without performance specifications,  and the fear of designing an

 installation and then having the  applicable  standard change  is a very real
                 i
problem.



 CONCLUSIONS

     After a slow start in detecting the trichloroethane and tetrachloroethylene

 problems in Vestal drinking water,  due in part to handling delays  at EPA's  busy

 Cincinnati labs, the town acted decisively in removing the contaminated wells

 from service.   Fortunately,  a new well was already being developed that was

 capable of replacing the closed wells.   Vestal and the Department  of Environ-

-------
                                   C-47
mental Conservation then proceeded with efforts to find the sources of organ-




ics.  One source has been found and the Town is continuing its search for the




other.



    As in many other cases, the lack of understandable information on the




health, effects of the synthetic organics was a major problem in responding to




the situation.  Town officials felt that there were not enough regulations or




standards as to what levels of contamination were "safe," "acceptable," or




"allowed" in drinking water.  Vestal could have contracted to have a treatment




system installed, if. necessary, but not with assurances that the system would




both  meet any  applicable  standards and protect,, public health as much as




feasible.   A related problem was  in dealing with the media, which  soon became




a major  source of irritation.  The Town simply did^not have the answers about




the potential  health hazards that the newspapers wanted,  and the media saw




this  weakness  as  a  cover-up.



  - Another problem is  the cost  of  investigative  efforts.  Vestal  has spent




 over  $100,000  in one  district  and is  already running out  of  funds  to  continue




work.  The  possibility  of Superfund monies  becoming available would be helpful,




 but a lack  of information surrounding EPA's evaluations  and the delays  expected




 before funds  are actually committed have kept local officals  cautious about




 depending on government aid.

-------
                                  C-48
                   NORTH  PENNSYLVANIA WATER AUTHORITY
                         LANSDALE, PENNSYLVANIA
SUMMARY

    In response to requests  by water  customers, the North Pennsylanvla Water

Authority (NPWA) tested its  wells  in  1979  for organic chemicals.  Of the

system's 51 wells, seven were found to have trichloroethylene and one had

tetrachloroethylene,  or perchloroethylene  (PCE).  All eight wells were closed,

effectively reducing  the system's  supply by about one-third.

    The NPWA's short-term response was to  purchase water from a neighboring

water company and to  increase pumpage from the  remaining wells to make up for

lost capacity.  The Water Authority then worked with EPA Region III and the

Pennsylvania Department of Environmental Resources  (DER) to trace the source

of contamination.  This task proved to be  difficult due to aquifer heterogene-

ities and the large number of potential sources soon discovered.  Eventually,

only one well was definitely tied  to  a single source of contamination.  A

number of local industries have contributed to  finding and halting sources of

contamination.

    The NPWA began treating  some well water with granular activated carbon

adsorption in 1981.  Other treatment  technologies,  including an in-well aera-

tion project, are also being tested.
BACKGROUND

    The North Pennsylvania Water Authority is the major water utility for

eastern Montgomery County, located in southeastern Pennsylvania.  NPWA is a

non-profit utility, governed by an elected Board of Directors,  serving seven

townships and municipalities.  The Authority has 51 wells  capable of supplying

-------
                                   C-49
5.2 MGD,  but usually only 30 to 35  wells  are required to  be  in  service.  The




production wells are scattered all  over the service area.  Some, of the very




old wells are in the shallow aquifer at about 120 feet, while the new wells,




generally in the lower aquifer, are as deep as 300 feet.








DISCOVERY OF THE CONTAMINATION PROBLEM




    When a very large trichloroethylene (TCE) spill in nearby Collegeville




contaminated the local water supply, officials at the North Pennsylvania Water




Authority became curious about the quality of their own water sources.   In




July  1979,  the Authority tested the water and found levels of, TCE from 1 to




400 ppb  in  seven wells.  One other well showed significant levels of perchloro-




ethylene.   Other chlorinated hydrocarbons such as 1,1,1 trichloroethane and




cis-1,2  dichloroethylene were  also detected  in smaller amounts.




nated wells were scattered  at  various  locations around the" service area.
The contami-
 ACTIONS TO  PROTECT WATER QUALITY



     The eight  wells  found to be contaminated were  immediately closed down.




 The Water Authority  referred to the  NAS  1  in 106 increased cancer risk level




 of 4.5 ppb for TCE in taking this  action,  although the  State of Pennsylvania




 does not yet have primacy under the  Safe Drinking  Water Act and had no official




 response levels for  organics  in water supplies.  About  one-third of the NPWA




 supply capacity was  lost when the  wells  were closed,  although the difference




 was quickly made up by purchasing  water  from the neighboring Keystone Water




 Company.  Keystone gets its water  from a surface source, and complaints about




 taste and odor problems as well  as questions  about the wisdom of  exchanging

-------
                                   C-50
TCE risks for THM risks often associated with surface water supplies have




caused NPWA officials to minimize use of Keystone water.




    The Pennsylvania Department of Environmental Resources and EPA Region III




became involved in tracing the sources of volatile organics and in evaluating




treatment alternatives.  NPWA, with DER and EPA assistance, has put quite a




bit of effort into locating the sources of contamination.  Although the old




industrial area in the middle of Lansdale had several suspected sources, a




newly developed area with more recent activity was picked first for pump tests




and periodic sampling to isolate sources of organics.  Deep industrial wells




and more shallow monitoring wells were used to define the contaminant plumes.




NPWA carried out investigations through the summer of 1982, and a group of




industries with potential TCE problems, organized as the North Penn Water




Resources Group, sponsored investigations in 1982.  The Water Authority and




EPA have stressed a positive .approach to resolving the organics problem,




rather than threatening the industries with legal action, and have received




excellent cooperation  from the industries.



    Only one contaminated well was definitely  linked to  a single  industrial




source.  Another well  was found to be contaminated by six different  sources.




The multitude  of sources and  fractured rock geology made investigations diffi-




cult,  especially in  downtown  Lansdale.   Several  clean-up actions  were  taken  on




industrial  sites found to be  contaminated by organics used  as  solvents or




degreasers.  One very  heavily contaminated site  was  excavated  and the  dirt




hauled away.   At several sites, the  contaminated soil was  dug  up  and spread




over  the ground to volatize the synthetic organics present.  Other industries




improved chemical drum storage facilities, replaced  leaking TCE tanks, or




installed  other measures to  control  organic  discharges.

-------
                                   C-51
    In,the meantime,  efforts, were underway to treat the contaminated well




water.  Shortly .after the wells were originally closed, .several were put back




on line and pumped to the wastewater treatment plant to prevent localized  TCE




plumes from spreading to clean wells.  In November 1981, a 100 gpm granular




Motivated carbon plant was installed at one well,  at a cost of $70,000, to




return a portion of that well's capacity to service.  Officials from the EPA




Municipal Environmental Research Lab in Cincinnati tested the effectiveness of




their portable packed aeration tower on one well in 1982.  The Water Authority




and EPA have also entered into a cooperative agreement for $90,000 to test new




in-well aeration techniques.  This two-year project is in the preliminary




stages of design, although laboratory facilities with a gas chromatograph  have




already been installed for organics analysis.  Operating expenses for the  lab




are estimated at $70,000 per year.  North Perm's total costs thus far have




totalled over $500,000, and average water bills have increased by $0.50 per



month. -.       .                               ,








CURRENT STATUS




    Recently, some previously-closed wells have been put back on line to  reduce




the amount of water purchased from the Keystone Water Company,  Although  the




4.5 ppb risk level was originally discussed, DER is now speaking in terms  of




75 ppb, the number used as the long-term Suggested No Adverse Response Level,




as an acceptable level for TCE.  NPWA has only put wells back on line with TCE



levels,less than 5 or 10 ppb.








INSTITUTIONAL INVOLVEMENT




    The Water Authority, Department of Environmental Resources, and EPA worked




together on most aspects of the contamination problem around Lansdale.

-------
                                   C-52
Although DER was inundated with requests for assistance with chemical contami-




nation incidents in 1979, the Department still managed to respond to North




Penn's contamination problem.  Several EPA officials from the Region III office




and the MERL center in Cincinnati provided assistance in several stages of




tracing and controlling organics in the drinking water supply.  Both EPA and




the American Water Works Association provided research grants to test VOC




removal techniques.  .



    The North Penn Water Resources Group, the organization of industries formed




to deal with the TCE problem, has been very cooperative in allowing and assist-




ing investigations on and off plant sites.  Most, if not all, of these firms




have probably contributed to ground-water contamination in the area, but the




group still deserves credit for facilitating investigations.  The success of




this positive effort is  largely due to NPWA's decision to emphasize cleanup




efforts rather than determination of culpability.



    Several engineering  and ground-water consulting firms have been involved




in the North Penn case.  Until the Water Authority equipped its own labora-




tory, a private lab was  also used for organics analyses.
 HEALTH  GUIDELINES



     As  mentioned previously, the State of Pennsylvania has not been given pri-




 macy under  the  Safe Drinking Water Act and therefore has no program to deal




 with organic  chemicals  in  drinking water supplies.  For lack of better informa-




 tion, the Department of Environmental Regulation  initially proposed the NAS





 10"6 increased  cancer risk level of  4.5 ppb  for TCE.  Now the DER  is using




 the Suggested No Adverse Response Level  (SNARL) of  75 ppb for chronic exposure




 to TCE.

-------
                                   C-53
CONCLUSIONS




    Several aspects of the North Penn Water Authority case,are fairly unusual.




First of all, the utility was fortunate that lost production capacity could be




made up easily,  even if at considerable expense,  considering the prevalence of




ebtttaMination sites throughout the service area.   Second, the lack of a state




drinking water program eliminated one agency usually,involved in ground-water




cases.  Finally, the degree of cooperation between the Water Authority and the




group of local industries using TCE has rarely-been observed elsewhere.




    Several aspects of the North Penn case are common to many other cases.




The public "outrage" and intense media coverage hindered careful, deliberate




response to the problem.  In retrospect, NPWA officials feel that the decision




to install a GAG adsorption plant as small as 100 gpm may have been too hasty.




The major shortcoming that kept the public upset and complicated planning was




the lack of understandable, consistent information on the health effects of



organics in drinking water.




    Informing the public about the detection of potential carcinogens in their




drinking water caused an "incredible amount of panic."  With several sets of




health numbers for TCE being tossed around, and no solid information that the




public could relate to, confusion was rampant.  Local officials needed one




"official" number for acceptable levels of TCE both to calm the public and to




use as a goal in designing water treatment methods.  The Water Authority has




made great efforts to keep the media informed of progress in the case, and the



initial furor has largely ceased.




    Local officials also mentioned a need for more technical information.




Improved knowledge of the transport of chemicals through soil, rock, and the

-------
                                   C-54
water table is needed to better predict leaching, subsurface travel, and reten-




tion of various organic compounds.  More information on'site cleanup proced-




ures, such as the relative merits of landfill disposal, impermeable liners,




forced leaching, soil aeration, etc.. was requested.



    Finally, in another health-related topic, the tradeoffs in abandoning a




ground-water supply contaminated with low levels of TCE for a surface water




source contaminated with trihalomethanes need to be evaluated.  The lack of a




consistent basis for making this type of comparison has long been a problem.

-------
                                   C-S5
                                VERO  BEACH
                                  FLORIDA


SUMMARY

    Trichloroethylene and related volatile organics were accidentally disco'v-

ired in Vero Beach's drinking water when the water supply was tested for tri-

halomethanes in 1978.  The City traced the contaminants back to ,one well near

the airport.  After the well was closed, an investigation around,the airport

'area revealed that Piper Aircraft had a buried tank of TCE that was leaking.

    Once the suspected source was identified, test holes .were drilled around

the tank that confirmed that very high levels of TCE were present.  After dis-

cussions between the City, Piper, and Florida Department of Environmental Regu-

lation (DER), a dewatering well was drilled to prevent the acquifer contamina-

tion from spreading to other wells.  After a major delay, a NPDES permit was

finally, approved to discharge the water from this well to a canal.

    Vero Beach never experienced a serious water shortage because of the closed

"well, but new wells have since been drilled to supplement the City's supply.

Local officials feel that they and Piper could have handled the problem as well

and much more rapidly without interference from the State and EPA.



BACKGROUND

    The City of Vero Beach is located on the Atlantic coast of central Florida.

The City supplies water to about 21,000 customers at a normal rate of 7 to 8

MGD.  About twenty relatively shallow wells are used by the. City.   The combina-

tion of very sandy soil and a high water table make ground-water supplies very

vulnerable to contamination from surface spills as well as intrusion by salt

-------
                                   C-56
water if wells are pumped at high rates.   Vero  Beach  treats  its water with




coarse filtration and a lime softening process  before distribution.








DISCOVERY OF THE CONTAMINATION PROBLEM



    In 1978, a researcher for the Harper-Branch Research Foundation tested




Vero Beach's finished water for trihalomethanes.  The results  of  that  analysis




showed that very low levels of total trihalomethanes  were present,  but that




another halogenated organic, trichloroethylene, was present at a  level of 68




ppb.  The  city backtracked through the water distribution system  and found




that one well, production well No. 15 located on Vero Beach Airport property,




was the source of TCE  in the drinking water system.
 ACTIONS TO  PROTECT WATER QUALITY



     The concentration of TCE  in the contaminated well was 900 ppb.  Based on




 health information from Harper-Branch  and the Water Department, Vero Beach




 decided to close down the  well.



     With the immediate threat to  drinking water quality removed, the City




 began looking at potential sources of  contamination on the airport grounds.




 Very quickly they learned that Piper Aircraft had  a buried tank for TCE.



 Piper pressure-tested the tank and found a  leak  in a  corroded below-ground




 pipe fitting.  After Piper drained the tank to prevent any more of the solvent




 from leaking out, shallow (12-15  feet  deep) well points were put  down around




 the tank to determine the extent  of contamination. High  levels of TCE were




 found to be fairly widespread, indicating that  the tank had  been  leaking for




 some time.

-------
                                   C-57
    After discussions with Florida DER and the City's consulting engineers,  Gee




& Jenson, Piper drilled a 60 foot deep interceptor well near the tank site.




Samples from that well had over 10,000 ppb of trichloroethylene.  The City




applied to the state for a NPDES permit to pump the well to waste in a nearby




drainage canal to prevent the spread of contamination to other wells.  The




State approved of the pumping plan, but EPA refused the permit until a base-




line study of the discharge area was completed, since the effects of TCE




getting into the salt water environment were unknown.  The study cost Vero




Beach quite a bit and the delay allowed the contaminant to migrate further.




    In February 1982, after more than a year's delay, the Florida Department




of Environmental Regulation authorized emergency pumping of the Piper well,




with some treatment, because the contamination had spread to other wells.




Eventually a consent agreement was developed by EPA and DER, requiring an




analysis of the results of the treatment process used before discharging 'the



contaminated water, an evaluation of other treatment alternatives, establish-




ment of a monitoring program, and a hydrological evaluation.  The NPDES permit




was finally approved with Piper Aircraft listed as the discharger.




    Piper had put in water lines from the purge well to the canal and had Gee




& Jensen design a treatment method.  Gee and Jensen settled on an aeration




technique through spray nozzles to remove the volatile TCE.  In reviewing




alternate treatment techniques, the following options and cost estimates were




considered:

-------
                                   C-58
                  Treatment Technology                 '    Estimated Cost
      Air Stripping
        (a) upgrade spray discharge system                 $   9,500
        (b) design aeration tower                          $  26,400-52,800
      Synthetic Resin Adsorption                           $  62,000
      Steam Stripping                                      $350,000
      Solvent Extraction                                   $555,000
      Activated Carbon Adsorption                          $810,000


Levels of trichloroethylene in the Piper well were around 7000 to 8000 ppb  in

August 1981 and have declined to 400 ppb fourteen months later.  The air

stripping process currently in use has approximately a 70 percent removal

efficiency.  About 0.25 MGD is being pumped from Piper's purge well.  TCE

levels at the end of the discharge spillway were less than 3 ppb.

    At the time that the organic contamination was discovered, Vero Beach was

in the process of drilling two new production wells.  While the City never

experienced serious water supply disruptions, a total of eight wells have

since been drilled to satisfy current demand as well as projections of future

growth.  There are some problems with drilling in the area 'in  that  isolated

spots of contamination by various  chemicals are occasionally encountered.



CURRENT STATUS

     At  present,  levels  of  trichloroethylene  in the  abandoned Vero Beach produc-

tion well  are down to trace amounts.  Apparently, the contaminant plume has

moved past that well and the purge well is preventing the  residual  contamina-

tion at the tank site from migrating towards  the  production well.   City wells

 are still being monitored for organics  and Gee &  Jensen are  still sampling and

 testing water at several points from the purge well,  through the spray nozzle

 discharge, and down the canal.   Trichloroethylene levels a short distance  down

 the canal from the discharge spillway are below the detectable limit.

-------
                                  C-59
INSTITUTIONAL INVOLVEMENT                                                ,



    The City of Vero Beach and Piper Aircraft,  in a rare  example  of government/




business cooperation, worked together to resolve the problem.   Once it became




clear that Piper was at fault, the company became very cooperative in cleaning




lip the spill.  Technical assistance from the Harper-Branch Research Foundation,




a private, non-profit organization, was instrumental in detecting the original




problem and carrying out the response.  Harper-Branch was generally  in  charge




of testing and monitoring programs.  The City's consulting engineers, Gee &




Jensen, designed and tested the treatment method for discharged water.   The




State of Florida became involved only in approving a permit to discharge purged




water to the drainage canal.  The state DER tentatively approved the NPDES per-




mit, but EPA Region  IV officials became quite upset at the request and orgin-




ally would not  allow a discharge of TCE greater than 0 ppb.  The agreement




finally worked  out with DER  allowed up to  1000 ppb of trichloroethylene to be




present in  canal water several hundred meters downstream  from the discharge




spillway.           •








 HEALTH  GUIDELINES



     The Department  of Environmental Regulation  finally imposed a maximum  allow-




 able level for TCE  in drinking water of 0.00 mg/1.   In response  to earlier




 requests from Vero  Beach, the DER merely sent  the City a copy  of a Federal




 Register which discussed EPA's approach to setting health standards.  Appar-




 ently., DER later adopted the policy of limiting public  exposure  to potential




 .carcinogens as much as possible.

-------
                                   C-60
CONCLUSIONS




    The case of organic contamination in ground water at Vero Beach is somewhat




unusual ih that the City and the organization that caused the contamination




worked together to resolve the problem, without assistance from the state




health" and enviromental agencies or EPA.  In fact, Vero Beach officials claim




they could have resolved the problem equally as well and much more rapidly




without the state and EPA becoming involved.  Frequent and confusing personnel




turnovers at the EPA Region IV office and the lack of knowledge about the




effects of TCE in a saltwater environment were sources of irritation to local




officials.  Although individual contacts proved helpful, the slow pace of




bureaucratic response was difficult for local officals, highly concerned with




a potentially serious ground-water problem, to understand.




    A major reason for the Region's slow response was the lack of information




available on the environmental and health effects of trichloroethylene and the




other organics present in the ground water.  Region IV simply had not had much




experience with this type of problem.  The NPDES process also seems inadequate




for emergency pumping to purge aquifers of contaminants.  The dichotomy




between justifying industrial discharges versus efforts to prevent the spread




of potential carcinogens to public wells should be recognized.




    The testing, monitoring, and treatment design aspects of the Vero Beach




case were handled competently by a private research foundation and the City's




consulting engineering firm.  The state agencies  involved, however, were not




able to provide useful information to  the City, partly  due to their relative




inexperience with the health effects and control methods associated with




organic chemicals in ground-water supplies.

-------
                                  C-61
                          ELKHART WATER WORKS
                             ELKHART,  INDIANA


SUMMARY

    The Elkhart Water Works  was  one  of a  thousand  community water supplies

sampled by EPA in a nation-wide  ground-water program  concluded  in 1982.  In

April 1981 Elkhart was told  that 94  ppb of trichloroethylene had been found in

the city's finished water.   Followup well-by-well  sampling resulted  in several

wells being closed, leaving  Elkhart  with  insufficient capacity  for a normal

summer.                              .     '                   .     '   .

    More well tests, samples from observation wells drilled by  the Water Works

for EPA, and a study by the Water Works'  consulting engineers.outlined the con-

taminant plume and suspected sources by the Spring of 1982. At present, two

interceptor wells between the sources and the main well field  are being  pumped

to waste to purge the aquifer and keep the contaminants from migrating  into

the well field's*zone of influence.  No significant change in contaminant

 levels has been  observed, and Water Works officials are planning another study

 to conclusively  identify the source so remedial actions can be taken.



 BACKGROUND

     The Elkhart Water Works is  a public  utility,  managed by a board of trustees

 under the Indiana Public Service Commission,  that supplies the majority of

 water consumed in Elkhart,  Indiana.  The Water Works  has 12,600 accounts  for

 approximately 36,000 people in  this city of 41,000.   The  remainder  of the popu-

 lation is served by private or  subdivision wells.

-------
                                   C-62
    Elkhart's water supply comes from three well fields.  The North Main Street




Well Field has 15 wells, each with an average depth of over 50 feet and rated




at dbbtlt 1 mgd each.  The Bower Street Well Field on the west side of town has




two wells 70 feet deep and one well 135 feet deep, with a total design capacity




of 4.5 mgd.  The newest supply, the South Well Field, was put into service in




1966.  South Well Field has three wells, each 100 feet deep with a combined




design capacity of 3 mgd.  Several of Elkhart's wells have been placed on




reserve, due to high iron levels or other problems.  With all wells pumping,




maximum capacity is near 20 mgd, three-quarters of which is from the North




Main Street Well Field.  Peak demands at North Main Street are in the range of




12 to 14 mgd, with off-season lows near 5 mgd.  The Water Works operates a 6.5




million gallon storage system, with 2.5 million gallons of that total elevated.




    The United States Geological Survey completed a three-year study of north-




western 'Elkhart County in 1981 to define the general flow and quality .of water




in the outwash system, to determine if a proposed well field near the Municipal




Airport (northwest of the city) would draw leachate from an industrial land-




fill, and to define the areal extent of ground-water contamination at an east-




side industrial park and landfill.  The hydrologic portion of the study




reported that the outwash aquifers underlying the region are mainly composed




of sand and gravel and are separated by a thick silt and clay bed.  The satu-




rated thickness of these deposits averages 175 feet and ranges from 85 to 500




feet.  Under most of Elkhart, the silt and clay bed confines the underlying




aquifer.  Average hydraulic conductivities of the sand, and the sand and




gravel, are 80 and 400 feet per day, respectively.  Regional ground-water flow




is toward the St. Joseph River.  The sand and gravel soil has been described



as "highly vulnerable."

-------
                                   C-63
    The USGS investigation discovered that ground-water  quality had,  as
expected, been degraded in some areas near Elkhart  by liquid and solid waste
disposal practices.   Volatile organic compounds  have been detected in residen-
tial wells near an industrial area in east Elkhart.   The landfill on  the  north-
w§St Side was closed because leachate penetrated the shallow aquifer,  uncon-
fined at that point.


DISCOVERY OF THE CONTAMINATION PROBLEM
    Through preliminary reports of the USGS study described above,  Elkhart
officials had reason to suspect volatile organics might  be present in drinking
water.  In April 1981 EPA Region V notified the  Water Works that Elkhart  was
on the list of 1,000 community water systems due to be tested for organics.
When test results came back in May, EPA informed Elkhart that the finished
water from the North Main Street plant contained 94 ppb  of trichloroethylene.
More samples .were then taken to confirm early tests.   The results of  these
follow-up analyses showed 57 ppb in the finished water and 270 ppb in the most
heavily contaminated well, Well E.  As much as 880  ppb of trichloroethylene
has been detected in observation holes and closed production wells since.

  •   . •            •                         "  /
ACTION TO PROTECT WATER.QUALITY
    In Elkhart, as in most cities faced with organics in their drinking water
supplies, the short-term action taken to protect water quality was to close
contaminated wells.   Here, however, confusion over  the allowable levels of TCE
made the decision to close wells less clear-cut. The Indiana State Board of
.Health (ISBH) thought that 75 ppb (EPA's Suggested  No Adverse Response Level)
was allowable while EPA wavered between 45 and 4.5  ppb (the National  Academy of

-------
                                   C-64
Science estimated 1 in 106 and 1 in 107 increased cancer risk levels).
When the contamination problem was discovered, the Water Works took a conserva-
tive approach and immediately closed down the wells that showed significant
amounts of TCE.  In May 1981 water from one well contained 270 ppb TCE, so the
definition of  'significant' was not critical.  Since then, wells with as low
as 17 ppb TCE have been closed to keep the quality of the finished water as
high as possible.  Water  from the North Main Street plant now contains less
than 1.5 ppb, but officials are not certain that they could always meet an EPA
standard of  4.5 ppb  for trichloroethylene.
    One month  after  trichloroethylene was discovered in water from the North
Main Street  plant, the Water Works, under the  supervision of  an EPA Region V
hydrologist, drilled five 2-inch  observation holes generally  upgradient of the
well  field.  These 30 feet deep holes  were to  determine the direction  the  con-
 tamination was coming from.   Test results  in early July showed high  contamina-
 tion levels  (several hundred parts per billion of TCE)  in observation  wells
 east of the well field.   The observation holes and production wells  continued
 to be sampled every two weeks to provide data for planning further efforts.
     After EPA's initial involvement,  the Indiana State Board of Health took
 over as the nominal lead government agency.   The ISBH continued sampling and
 organized several meetings with the agencies and suspected industrial sources
 involved.
     In the  spring of 1982, the water utility hired Canonie Environmental to
 determine the extent of  the trichloroethylene contamination.  Under Canonie's
 supervision, the Water Works drilled eighteen more observation wells.  Most of
 the wells were east of the North Main  Street plant, around the suspected indus-
 trial sources.  The suspected  sources, the Excel  and DuraKool companies, both

-------
                                   C-65
 used TCE  in plating  operations.   Canonie  sampled  all the wells  installed up to




 that point in March  and was  able  to  outline  the areal  extent  of the plume




 faltly Conclusively, since the wells were relatively close  together.   Begin-




 ning in May 1982,  all water  samples  were  sent to  a private  lab, since  the  ISBH




 lab cduld not provide the rapid turnaround time required.




     At the conclusion of their study, Canonie presented several alternatives




 to the Water Works Board. One alternative was to install  a north-south slurry




 wall between the source and  well  field,  a four hundred foot'long barrier




 extending south to Christiana Creek.  On the east side of  the slurry wall,




 interceptor wells would be placed to draw out the contaminated water.   A  second




 alternative was to install interceptor wells on  the western edge of the indus-




 trial sites, irrigate to leach out the organics,  and pump  the interceptors to




 waste in the creek.



     The Board, in consultation with EPA, the State, and the companies, decided




 to put two  interceptor wells on the western edge of the DuraKool property.




' When Elkhart went to install the wells, however,  DuraKool  would not let any




 drilling take place until the Water Works released DuraKool from any liability




 in the contamination case.  Water Works officials balked at this request and




 placed, the  wells  directly across North Main Street on the eastern edge of the




 North Main  well field.



      After protracted negotiations,  the Water Works obtained a  NPDES permit




 from the  State to discharge water from the  interceptor wells to Christiana




 Creek.  The state allowed discharges containing  up to 500 ppb  of trichloro-




 ethylene  on the condition that some progress  towards  reducing  these levels be




 made within nine  months.  The utility began pumping to the Creek in August




  1982,  at  a rate of  about 4  mgd.  Some field tests  of  simple  air-stripping

-------
                                   C-66
methods, such as discharging the contaminated water through perforated plastic

pipe, have been shown to reduce TCE concentrations in the effluent by as much

as 40 percent, but the outfall presently runs directly into the Creek.  The

concentration of TCE in the effluent has varied around 300 ppb.

    the State Board of Health has strongly recommended that the source of con-

tamination be |ocated and removed.  The ISBH told Elkhart that they should

consider air stripper and granular activated carbon treatment methods, as well.

Elkhart experimented with rudimentary air-stripping, as described above, and

contacted Calgon for information on portable GAG units, should the need arise.

The state itself has become involved in on-site inspections and soil  sampling

on Excel and DuraKool property.
 CURRENT STATUS

     The Elkhart Water Works  is  now. assuming that  some  remedial  action must be

 taken,  since concentrations  of  TCE' in the interceptor  wells have not, declined..

 One factor that may force action is the ISBH NPDES permit, which requires

 Elkhart to show in early 1983 that effluent levels in  water pumped to

 Christiana Creek have declined.  The. Board of Health has warned as recently  as

 October 1982 that it objectives in the Elkhart case are to:


     1)   determine the extent of the contamination problem;
     2)   determine the need for emergency remedial actions;
     3)   identify the responsible parties;
     4)   solicit proposals for permanently remedying the situation;
     5)   work out a plan with the parties involved to pay for remedial action;
          and
     6)   begin remedial actions as soon as possible.


     The Water Works has asked Canonie Environmental to submit a proposal for

 more work to pinpoint the source(s) of contamination.   At the same time,

-------
                                   C-67
Elkhart is looking for more witnesses employed by the companies  suspected of
dumping the chemicals.  The water utility has spent about $150,000 thus far on
the problem and, in the absence of government funding, must find the source of
contamination to shift liability and the costs of clean-up to that party.
Comprehensive on-site clean-up efforts could easily cost several million
dollars.   In the meantime, Elkhart is spending $1,200-1,400 per month on
electricity to  pump the interceptor wells, and $1,500 per month on  laboratory
fees.
    Despite  local  efforts,  the water supply  for  Elkhart  is still  restricted.
 If the summer  of  1983 is  accompanied by normal water demands, the Water  Works
 will be very hard-pressed to meet those demands.  One option for  increasing
 water supply is to accelerate existing plans for the new well field on the
 northwest side of the city, but officials are still uncertain whether demands
 could be met.

 INSTITUTIONAL  INVOLVEMENT.
     A number of parties were  involved in different aspects of the Elkhart
 ground-water contamination  case.  The USGS was  one of the first  agenices to
 become  involved,  when their investigation of ground water in Elkhart County
 discovered  two areas where waste disposal practices  had contaminated ground
 water.   A national EPA survey of community  water systems then  detected  the
 prganics in the  North Main Street well field.
      After EPA's  initial  involvement, the City Water works  and  the  Indiana State
  Board of Health directed efforts to find the source and to prevent the further
  spread of contamination.  The ISBH dealt with the suspected industries very
  firmly and has insisted the industries take major actions soon to resolve the
  problem.  The Water Works  capably managed the  initial investigation and hired

-------
                                   C-68
a ground-water consulting firm, Canonie Environmental, to trace the source and




to present alternatives to the state for securing a safe water supply.
HEALTH GUIDELINES




    The Indiana State Board of Health generally passes on EPA information with-




out much interpretation.  In the Elkhart case, the ISBH was initially recom-




mending a maximum allowable level of 75 ppb for TCE (the level of the EPA SNARL




for chronic exposure) but has reportedly been suggesting a limit of 45 ppb (the




 concentration at which the NAS estimates a 1 in 10s increased cancer risk).




The confusion surrounding the meanings of these items and what is truly "safe"




has. complicated the decision-making process immensely.
CONCLUSIONS




    The case of organic contamination at the North Main Street well field in



Elkhart has been a troublesome one.  Although the wells found to be contami-




nated were immediately closed, and finished water quality (averaging 1-2 ppb



TCE) is now being very carefully monitored, several problems still exist.




Ground-water investigations have not yet conclusively implicated the suspected




industrial sources.  One of the sources has closed down local operations and




may be hard to prosecute.  Success in pumping out the contaminated zone of the




aquifer to waste has been slow and it appears it will take quite a while to




reduce TCE levels in local ground water.  The City's capacity to supply water




remains drastically reduced and next summer could bring dangerously low water




levels.  On top of these problems, the Water Works is running out of money to



continue investigations.




    Water Works officials feel that they should not be responsible for paying




for investigative and remedial actions and would like to see the state or

-------
                                   C-69
federal government assist financially,.  Technical assistance requested on the




case was for more health effects information, improved subsurface monitoring




methods, and research on aquifer management technologies to direct the move-




ment of the contaminant plume away from the remaining production wells.

-------
                                   C-70
                          CITY OF BATTLE CREEK
                                MICHIGAN
SUMMARY

    In 1981 sampling of private wells near a Battle Creek landfill  accidentally

Uncovered the presence of organic contaminants in the municipal water  system.

After the city notified the state of the problem, the Department  of Natural

Resources applied to EPA for assistance.  While EPA conducted a preliminary

investigation, the city pumped the two most heavily contaminated  wells to

waste.  Eighteen of thirty municipal wells eventually had to  be closed,  in

accordance with Michigan Department of Public Health recommendations that no

organics-contaminated water be supplied to the public.   The County  Health

Department found that over 80 private wells between the public wellfield and

the suspected industrial sources were significantly contaminated  by as many as

seven volatile organic chemicals.

    The wells pumping to waste were shut down recently when a USGS  report

showed that increased pumpage was drawing contaminated ground water toward the

wellfield.  Meanwhile the demand for municipal water has increased  due to the

discovery of various organics in several cereal manufacturers' wells (and the

subsequent closures of the wells), which has heightened the severity of the

water supply shortage.  Efforts to supplement the water supply through treat-

ment or alternate sources have been of secondary importance relative to locat-

ing the source(s) of contamination and establishing legal liability.  The situ-

ation at Battle Creek remains one of the potentially most serious organics con-

tamination cases in the Midwest.

-------
                                   C-71
 BACKGROUND




     The  City  of  Battle  Creek owns.and operates one wellfield  located  in the




 northwest portion of  the City.  The Verona wellfield  supplies water to the




 City of  Battle Creek, an industrial park, and parts of  four townships.  The




 total population served is  slightly over 50,000 persons.   Several major break-




 fast cereal maufacturers also obtain their potable and  production water from




 the  city system.  These manufacturers and other industries are  located south




 of the wellfield, beginning several hundred yards down  the valley.  A railroad




 yard crosses  northeast  through  the industrial complex to  the wellfield.




 Between  the wellfield and the industrial complex lies a residential section of.




 100  to 150 older homes.  These  residences obtain water  from .relatively shallow



 private  wells.                    ..,'.' -  • .  -...-.




     The  Verona wellfield, which borders on the Battle Creek River, has four




 production wells on the west side of the river and 30 on  the east (see Figure



 BC1).  Most of the municipal wells tap the Marshall sandstone formation at




 depths of 100 to 160  feet.  Residential wells in the  area generally tap the




 upper Marshall formation and the overlying glacial deposits, .only 20  to 60




 feet deep.  Some of the municipal wells drawing from  the  Marshall formation




 are  capable of yielding several thousand gallons per  minute.  Battle  Creek had




 thirteen wells that could consistently yield 1,000 gpm  each.  These and other




...wells can be  pumped at  high rates without significant drawdown.  Depending on




 seasonal demand, pumping from the Verona field ranges from 7,000 to 12,000




 gpm. The annual average is .about 9,000 gpm.  Of this total, about 5,000 to



 6,000 gpm is  currently  pumped to just two industries.




     Ground water in the immediate area generally flows  towards  Battle Creek




 River, except, at Verona wellfield where flow is towards the production wells

-------
                                   C-72
being pumped.  At peak summer periods (when withdrawals are as. high as  12,000




gpnO, water is drawn to the wellfield from several thousand feet away.   During




these periods, water is drawn to the wellfield from strata underlying the




industrial sites.  In winter, when withdrawals are normally 7,000 gpm,  the




Zone of influence is smaller, and the east-west divide between water flowing




to the wellfield and water under the industrial sites flowing to the river




shifts northward, reducing the movement of water under the industrial sites to




the wellfield.








DISCOVERY OF THE  CONTAMINATION  PROBLEM



     In August 1981, the Calhoun County Health Department took water samples




from residences with  private wells  in the northwest part of the  city.  The




sampling was undertaken in response to  complaints  of taste and odor problems




 in wells near the Cereal  City  Landfill, 'several  miles  from the Verona well-




 field.   When the test results  came  back from the state labs,  county officials




 notified one residence, a rectory,  that volatile organic  chemicals had  been




 discovered in the well water and  that the residence  should consider hooking  up




 to city water.  The minister informed the county that  his .water was not from a




 well, but from the municipal system.



     The health department took more samples to confirm the preliminary find-




 ings.  When the results  showed that low levels of organics were indeed present




 in municipal water, they notified the city of the problem.  The city immedi-




 ately began testing through the distribution system and at the Verona wells.




 These September 1981 tests showed that ten wells had some degree of organics




 contamination.  Plant tap water contained 10 ppb of cis-1,2 dichloroethylene,




 4 ppb of trichloroethylene, and smaller amounts, of dichloroethane, perchloro-

-------
                                   C-73
ethylene,  and trichloroethane.   Individual well samples showed levels as  high




as 12 ppb for dichloroethane,  91 ppb for trichloroethane,  66 ppb for dichloro-




ethylene,  26 ppb for trichloroethylene,  and 44 ppb for perchloroethylene.








ACTIONS TO PROTECT WATER QUALITY




    The position of the State of Michigan .Director'of'Public Health is that




every effort should be made to limit the amounts of organics in drinking water.




Consequently, the ten Battle Creek wells that showed any contamination (over 1




ppb, defined for these purposes as the detectable limit) were closed.  The




Director's position was formalized in a December 1981 letter that presented




the state policy on organics and public health.  In that letter, the director




underscores the frustration of having to make such an important decision on




the basis of incomplete information, and opts for the most;conservative choice.




    Besides closing the contaminated wells, other short-term responses to the




discovery of organics in Battle Creek's water included continued weekly testing




of city wells,  initiation of a program by  the county to sample nearby private




wells, and notification of the public about the organics problem and associated




health risks.   Since  levels of contamination appeared highest in wells on the




southeastern edge  of  the wellfield, city  and state officials assumed the con-




tamination was  moving from the southeast  towards the northwest.  To keep the




contamination.from spreading  further  into the wellfield, the two most heavily




contaminated wells, Nos. 32 and  35, were  pumped to waste in the river.   Contin-




ued monitoring has led  to eight  more  wells being  closed, leaving only twelve




wells (capable of  9,150 gpm,  less  than  half of the city's  previous production




 capacity)  in service.

-------
                                   C-74
    Simultaneous testing by the Calhoun County Health Department began turning

up private wells south of the wellfield with organics contamination.  The

following table compares levels in public wells with levels  in private wells

for the seven organic chemicals detected.  Since laboratory  limitations  (all


                  MAXIMUM LEVELS  OF ORGANIC CHEMICALS
                              IN WELL WATER
          Contaminant
Concentration in
City Wells (30)
     (ppb)
    Concentration in
Private Wells (over 100)
         (ppb)
perchloroethylene
trichloroethylene
cis-1,2 dichloroethylene
1,1 dichloroethylene
1,1,1 trichloroethane
1,1 dichloroethane
1,2 dichloroethane
44
34
79
5
99
12
3
230
657
3,900
38
43
149
325
 organics tests  for the city and county were run by the State Department of
                           a
 Public Health)  allowed the county to test only a dozen or so wells at any one

 time, it took several months to find that a large number of wells were

 seriously  contaminated.   One year later, some wells still had not been tested.

     The County  has developed' three  form  letters to notify residents with con-

 taminated  wells;  these explain that the  well water should not be used for

 drinking,  should not be  used for cooking or drinking, or should not be used

 for bathing,  cooking, or drinking,  depending on the degree of contamination.

 In all  cases, private well owners are  now told where they can pick up city

 water for  household  use.  One  of the companies suspected of  causing the ground-

 water problem has agreed to buy  $5000  worth of bottled water for residents with

 contaminated wells.

-------
                                   C-75
    In November 1981,  the Michigan Department of Natural Resources (DNR) pre-

pared an emergency action plan to obtain EPA assistance on the suspected con-

tamination sites.  The plan contained a site summary, site status, and emer-

gency action plan.  In late December EPA agreed to provide a response to the

tiMR plan.  •'•                  ,                                ,

  ,  The first, phase of the EPA response was handled by a Technical Assistance

Team  (TAT) from EPA's contractor, Ecology & Environment,, Inc.  The TAT drilled

15 wells near the wellfield and both upgradient and downgradient from the sus-

pected sources.  Water and soil samples were collected and analyzed.  The
                                                          l
results of the TAT .investigation indicated that three sites could have contri-

buted to the organics problem in Battle Creek .ground water; an industrial sol-
                                                              I
vent  reclamation  facility that handled large quantities of the; substances in

question, a railroad yard and former maintenance facilities where degreasers

were  used,  and a  landfill located one mile south of the wellfield.  The TAT

study was limited to a $25,000 budget but was sufficient to place Battle Creek

on  the Superfund  national priority  list, allowing EPA to provide  additional

assistance.        .                                     .  .

     By February  1982, the agencies  involved  in  the Battle Creek case had been

organized into a Task Force under the guidance  of the state Department  of

Public Health (DPH) Regional  Engineer's  office.  The following organizations

 are represented  on the Task Force:

          •    Michigan Department of Public Health  (DPH)     .
    •     , •    Michigan Department of Natural  Resources  (DNR)
          •    U.S. Geological  Survey (USGS)
          •    U.S. EPA, Region V, Office of Superfund
          •    Calhoun County Health Department.
          •    City of Battle Creek
          •    Kellogg Company                  .
          •    General Foods  Corporation (Post)
          •    Ralston Purina Company
          •    Michigan Department of Commerce

-------
                                   C-76
The Task Force was set up to coordinate activities directed towards defining




the source and extent of the problem and, subsequently, controlling the con-




tamination problem.



    The cereal companies are on the Task Force because of their concerns about




using contaminated water in their manufacturing processes.  Several of the




cereal companies' wells showed low levels of organics.  To keep their product




as "wholesome" as possible, they switched over to city water in February 1982.




The increased demand severely taxed the already reduced capacity of the Battle




Creek system.  In the previous year, the City had completed a new $4.5 million




high capacity pumping station that was to provide enough capacity for an esti-




mated 20 years of  local growth.  When Kellogg and General Foods switched to




city water, they increased base demand by 4,000 to 5,000 gpm, roughly doubling




the amount of water the City had to supply.  The capacity deemed sufficient




for 20 years of growth was used up in one month.  Besides straining the City s




water supply capacity, the increased pumpage drew more water from the contami-




nation zone towards the wellfield.



    In the summer, while the DNR and EPA were concluding  site  investigations,




the City  of Battle Creek contracted with USGS for some ground-water modeling




studies of the  six by six  square mile  area  around the wellfield.  The $32,000




study  concluded that  shifting pumpage  patterns would not  prevent migration  of




contaminants toward  the Verona  field.   In fact,  simulations  showed that with-




drawing  2,000  gpm at  Well  Nos.  32  and  35 near the south  edge of the  field was




compounding  rather than  alleviating migration towards wells.   Battle Creek,




therefore,  stopped pumping the  wells to waste  in August  1982.



     The City also began designing  an additional  high service system  to  supply




 customers.   The USGS report was relied upon to provide the background basin

-------
                                   C-77
information required to place additional high-capacity city wells.  In other


efforts, the County represented the townships in, negotiations with the Depart-
                                             '-- ' .   '-'•  '   f, i   •'. > •

rtient of Commerce to secure funding to extend City water mains to the affected


private homes.


    In the fall of 1982, the City and a national ground-water consulting firm


sponsored a conference in Battle Creek on volatile organic compounds in ground


water., Over sixty state and local government and industry representatives


attended.  All reports indicated that the conference was highly successful in


providing technical information and a basic education in ground-water contami-


nation.





CURRENT  STATUS


    In October 1982, EPA Region V Superfund officials met with the three sus-


pect companies to work out a plan of remedial.action.  By the end of November,


EPA wanted the companies, singly or collectively,  to agree to take responsibil-


ity for further efforts, to undertake a feasibility study,  and to outline the


scope of work for permanent remedial measures.   The companies suspected of


causing the organics contamination are not expected to comply willingly,  since


none have been proven guilty of contaminating Battle Creek's drinking water.


    The Michigan DNR and EPA are handling negotiations with' the suspect com-


panies.  The two agencies are also expected to begin evaluating treatment


alternatives.   The Michigan DPH is keeping a close watch on the situation and


searching for more health information.  Ca'lhoun County is negotiating with the


State Department of Commerce to extend water mains to the owners of contami-


nated private wells.  The county Health Department is also  still sampling pre-


viously untested private wells.   The next steps in resolving the Battle Creek

-------
                                   C-78
water crisis will depend on the outcome of additional hydrogeological investi-

gations by the EPA Field Investigation Team and legal discussions.
 INSTITUTIONAL INVOLVEMENT

    the lead agency in the Battle Creek organics case has been the Michigan

 Department of Public Health.  Officials in the DPH office of Water Supply

 direct the Task Force.of  local, county, and state government and industry

 representatives.   Since the discovery of organics in drinking water supplies

 for Battle Creek  and  several  other  municipalities, DPH has  initiated a state-

 wide sampling program for public  water  systems.  The laboratory  in Lansing is

 the only DPH facility in  the  state  capable  of testing for halogenated and nori-

 halogenated organic compounds.   Severe  budget cutbacks  in Michigan have  forced

 all of the state's branch labs  to close.

     Several of the agencies in the Task Force have been more heavily involved

 in tracing the source of contamination and assuring a high quality drinking

 water product than others.  The roles of the major agencies have been as

 follows:


          •   Michigan  Department  of Natural Resources.
              The  DNR has  been the  primary state agency involved with site
               surveys, hydrogeological  investigations, and  industrial discus-
               sions to  find the source  of and clean up the  assorted organics in
               ground  water.   DNR  has a  drilling rig and a hydro/geo staff cap-
               able of aquifer studies,  but  again, budget cutbacks have slowed
               responses to water  quality problems.

               U.S. Geological Survey                              .
               The study USGS  performed  for  the City was quick and thorough.   In
               the course  of the study,  the  USGS determined  ground water  flow
               patterns and rates  and made suggestions on pumpage patterns to
               minimize drawing contaminated water  to the Verona  wellfield.
               Several dozen observation wells drilled by USGS (in  addition to
               wells drilled by the EPA TAT) are  still  available  for  sampling  to
               monitor the position of the contamination plume over time.

-------
                                  C-79
            U.S.  EPA
            EPA Region V has been a major participant in resolving the problem
            at Battle Creek, mainly through their Superfund Office.  The
            Technical Assistant Team study, completed last spring, and the
            Field Investigation Team work, still in progress, are .the two main
            efforts to determine the source(s) and extent of the organics in
            ground water.  The Office of Superfund is also involved in
            negotiations with the suspected sources to set up and ascertain
            funding guarantees for remedial actions on the industrial sites
            and possibly at the City wellfield.

            Calhoun County Health  Department
            The County Health Department has worked closely with DPH to
            sample private wells that might be contaminated by organic com-
            pounds,  jSince August 1981, the county has tested over 120 wells,
            mostly in the residential area south of the Verona wellfield.
            About two-thirds of the wells tested have proven to be contami-
            nated with at least one of the compounds previously mentioned.
            The Health Department would like to do more sampling, but this
            effort is constrained by limited laboratory capacity at Michigan
            DPH.                                              .  '  .  .

            City of Battle Creek
            The City has been  involved in most of the work done so far to
            find the source of and  a solution for the contamination problem,
            and has worked  especially closely with DPH.  EPA and Michigan DNR
            have been working more  closely with each other, rather than with
            the city, although the  Task Force has been effective  in bridging
            communications  gaps between the agencies.

            Battle  Creek has not had to spend a large amount of the Water
            Department budget  on the organics problem, but the situation has
            been  very time-consuming.  Since the state lab has provided all
            the analytical  work, the US6S  project and small  changes in the
            water system have  been  the only direct expenses  incurred.  Still,
            the organics problem is using enough resources to require rate
             increases  in the near  future,  especially if the  City  has to pay
             for new wells  or major  system upgrading.
HEALTH GUIDELINES

    As discussed earlier, Michigan has no "action levels," per se,  for respond-

ing to organics in drinking water.  Instead,  the Department of Public Health

considers each case individually and makes, recommendations to limit human

exposure to potential carcinogens as much as  possible.   In the case of Battle

-------
                                   C-80
Creek, every well that showed contamination by organics was closed,  since some

of the lost capacity could be made up by increasing pumpage from other wells.,

It is doubtful, however, that normal summer demands can be met by the existing

number of wells.  In other organics cases in Michigan, such as Petoskey, sole

supplies have not been closed since alternative sources were not available.

    Department of Public Health officials would welcome more information on

the health risks associated with various organics in drinking water, but

express hesitation at accepting a federal standard, preferring to have more

discretion in protecting water quality.
 CONCLUSIONS

    The Task Force members  are proceeding  relatively smoothly towards resolving

 the problems of various  organics  in Battle Creek wells.   Several strengths and

 weaknesses  in response to the problem are  noted below:


          •    Qualified,  concerned assistance was available to the  City  from
              the State of Michigan.

          •    Some communication lapses between agencies hindered progress,
              but formation of the Task Force improved coordination.

          •    Severe State budget cutbacks  have limited organics analysis
              capabilities.  Private wells  that may be severely  contaminated
              still have not yet been tested.

          «    With seven VOCs present in Battle Creek wells and  three sources
              suspected,  investigative efforts have become very  complicated.

          •    An educational conference on volatile organics in  ground water
              was sponsored by a private ground-water consulting firm.  Many
              local, state, and industry representatives attended and spoke
              very highly of the value of this type of meeting.

          •   Delays in  Superfund investigative efforts have mildly frus-
              trated local officals who need a solution to their problem soon.

-------
                                    C-81
                             CITY  OF PETOSKEY
                                 MICHIGAN


 SUMMARY

     During  testing  for trihalomethanes in the City of Petoskey's water supply,

 tirichloroethylene and cis-1,2 dichloroethylene were found at concentrations of

 45  ppb  and  20 ppb,  respectively.   Since the city has only one well, located on

 the Lake Michigan shoreline, the source could not be closed down.  The State

 Department  of Public Health  and Department of Natural Resources have been

 following the case  closely since 1981 to isolate the source of contamination

 and locate  a new water supply.  At present, contaminant levels have declined

 somewhat but well drilling has not yet found a new supply capable of sustain-

 ing the pumping rate required.



 BACKGROUND                                -

    The City of Petoskey is a small .community located on the Lake Michigan

 shore in the Northwestern Lower Peninsula.   The entire water supply for the

 City comes  from one large infiltration well 50 feet from the Little Traverse

 Bay shoreline; a cone-shaped pit about 36 feet wide and 17  feet deep.   The

well is capable of providing 3,000  gpm (4.3 mgd) without noticeable drawdown.

Average daily demands are about 1.4 mgd,  with summer peaks  (due to resort

customers)  near 2.1  mgd.   The raw water is  fairly  soft  and  low  in iron,  as

might be expected of lake water.  Chlorination and  fluoridation  are the  only

treatments  applied to the raw water before  it  is pumped  into the  distribution

system.

    One well has  provided a sufficient supply of water for the  10,000 persons

served in the City and parts  of  adjacent  townships.  For the past  several

-------
                                   C-82
years, however, the Michigan Department of Public Health (DPH)  has been urging




the city to install another well because of the vulnerability of the pit well




in the City and because state policy recommends at least two sources of water




to maintain a reliable supply.  Petoskey has directed a ground-water consultant




to begin looking for a suitable location for a new well.









DISCOVERY OF THE CONTAMINATION  PROBLEM




    On August  12,  1981 a water sample was collected from the Petoskey water




system for trihaloraethane  (THM) analysis.  The sample was collected by DPH in




response to an inquiry by  the local health department director.  Although the




finished water received chlorination, it had not been sampled previously




because the source was technically defined as ground water and the water




system was small enough to be excluded  from EPA  monitoring requirements.




    As expected', the THM levels were  low.  The analysis performed by the state




laboratory, however, showed  the presence of two  other" organic compounds, tri-




chloroethylene (TCE) at 12 ppb and dichloroethylene at  7 ppb.  DPH notified




the city manager and water superintendent of the sampling results and the




significance  of the organic  compounds.  Five more samples were collected at




various points in  the water  system in early September.  The  table below shows




the results  of the analysis  of those  samples.
Compound
cis-1,2 dichloroethylene
trichloroethylene
1,1 dichloroethylene
DPW
Garage
11
19
ND
City
Hall
23
38
ND
Lockwood
Hospital
21
35
ND
Plant Tap Plant Tap
(New Pump) (Old Pump
7 27
12 45
ND >1

-------
                                    C-83
 All samples  showed the presence  of  some  THMs,  but  total  trihalomethanes were




 at levels  of 18  ppb or less.   The results  of the plant tap  sample  from the old




 pump station were  confirmed using mass spectroscopy.  Selected samples were




 analyzed using a full  VOC  scan.  No other  organics showed up at significant




 levels,  although low concentrations of phallates were noted.  Continued




 testing  over the past  year has indicated that  organics levels are  declining



 slightly.









 ACTIONS  TO  PROTECT WATER  QUALITY




     The  normal response in Michigan to detection of organic contaminants in a




 public well  is to  close down the well.  The State has no "action levels" set




 for organics,  but  suggests that  the levels of organic chemicals in drinking




 water be limited as much as possible.  In some cases, wells showing 1 ppb of




 TCE have been  closed.  At  Petoskey,  the city only has one well,  and the pre-




 sence of 20 ppb of TCE in  the water system was deemed less hazardous to public




 health than closing down the City's  entire water supply.   No other water sys-




 tems are close enough to Petoskey to make an intersystem connection feasible.




     City officials met with their consulting engineers and the local health




 officer  on September 16, 1982 to discuss  a response to the problem.  They




 decided  it was necessary to inform the public of the presence of  the organics




 in drinking water and issued a press release explaining what was  known about




the problem.   Continued sampling was planned,  including raw water samples  and




plant tap samples to ensure that contamination was  not being introduced by the




chlorine or fluorine feed systems.   The City used an  independent  laboratory



for their followup  analyses.

-------
                                   O84
    Results of additional testing showed that levels of trichloroethylene and


dichloroethylene were consistently twice as high in samples from the old pump


station as from the new pump stations.   The intakes for each station are only


several feet apart in the well.  The majority of pumpage has since been shifted


to the new pump station to lower the amounts of organics sent to the distribu-


tion system.


    At the September meeting, the City also authorized their engineers to pro-


ceed with developing specifications for a test well located 1/2 mile southwest


of the City.  The proposed site for the new water source had been reviewed and


approved for test well drilling.  A 2" hole drilled on that site hit an aquifer


at 240 feet that appeared to have sufficient quantity.  The severe winter


slowed drilling operations, so it was not until March 1982 that a 6" test well


was completed.  Test pumping showed that nitrates were consistently present.
                 «

The results of several analyses indicated that 6 to 7 mg/1 of nitrates were


present, uncomfortably close to the drinking water, standard of 10 mg/1.


    Because of the nitrate problem, the search for a new city well was expanded


to several other sites,  and some test holes were drilled.  No other location,


however, has proved to yield as high a flow rate of water  as the first, and


the city  is uncertain about what to do next.


    Shortly after the contamination problem was discovered, the Michigan


Department of Natural Resources  (DNR) became  involved  in investigating the


source of the organics.   A  site visit to a small manufacturing  firm 500  feet


from  the  well and subsequent soil  samples  at  that  site tentatively implicated


that  firm as the source.  The  DNR  sent  in  a drilling  crew  to establish ground


water flows and outline  the contamination  zone.  In drilling six monitoring

-------
                                   C-85
wells, three different ground-water flow directions were noted.  Although water




levels were the same in all wells, it was very difficult to pump much water out




of the rock for analysis.  In short, investigative efforts have been stymied by




unusual hydrogeologic conditions along the shoreline.




    the above ground investigations by DNR on the plant site have been more




successful.  In the spring of 1982, officials from the DNR field office came




on site and had barrels of hazardous wastes removed.   An area of contaminated




soil was also excavated.  The excavation was covered with an impermeable liner




and then backfilled.  The purpose of the liner is to prevent more substances




from leaching into the ground-water table.   The owners of the manufacturing




plant have been cooperative in assisting cleanup efforts.








CURRENT STATUS




    Presently, the City of Petoskey is still trying to find a satisfactory site




•for a new> secure well.   The city and state have spent over $200,000 thus  far




on the case.  The Michigan Department of Public Health is still assisting  the




City in finding a new source,  and has recently met with the City's engineers




to authorize more test wells.   The Petoskey City Council has been under pres-




sure from the press and the public to show  progress in resolving the contamina-




tion problem.   Finally,  DNR has slackened efforts to  trace the source of con-




tamination through hydrogeologic studies.   Thus far,  the state has not been



able to make a solid case against the suspected source.








INSTITUTIONAL INVOLVEMENTS




    As in most cases,  institutional response to the detection of organics  in




Petoskey's well was  focused in two areas.   The Michigan Department of Public

-------
                                   C-86
Health had been urging Petoskey to find a new well,  and accelerated efforts to




find a new drinking water source once the old well was  found to  be  contami-




nated.  The Department of Natural Resources directed efforts to  find and con-




trol the source of contamination, including drilling monitoring  wells near the




production well and suspected source and conducting  a hazardous  waste excava-




tion and removal project on the industrial sites.








HEALTH GUIDELINES



    The Director of Public Health in Michigan recommends that public exposure




to potential carcinogens be limited as much as possible, promoting a no-thres-




hold-level policy.  In a situation such as that at Battle Creek, where lost




water  production from contaminated wells can be mostly made up by increasing




pumpage  from clear wells, this policy means that  any well showing organics




contamination  should be closed.  At Petoskey, however, where the City depends




on one well for its entire water supply, the potential hazards of closing that




well  are greater than the risks  associated with keeping the well open.  The




only  option in this case was  to  notify the public and  accelerate the search




 for alternate  supplies.








 CONCLUSIONS



     The Petoskey  case was the only situation studied in which a well defined




 as contaminated was still being used.   Present  trichloroethylene levels  are




 around 20 ppb, a  concentration that would be quite  acceptable in New York,




 where the state guidelines  limit a single VOC to  50 ppb.   Local and state




 officials expressed a need for more health effects  information  to  get  a better




 idea of the health risks faced by Petoskey residents.

-------
                                   C-87
    Another stumbling block in resolving the Petoskey case was the difficulty




with drilling and monitoring along the lakefront.  The shallow rock and unusual




hydrology have stalled efforts to trace the trichloroethylene and dichloroethy-




lene found in the City's well back to the source.  Although responsibility has




not been proven, the industry suspected of being the source has cooperated with



surface cleanup plans.

-------
                                   O88
                              NEW BRIGHTON
                                MINNESOTA
SUMMARY

    In July 1981, the City of New Brighton was  notified by the  Minnesota

Department of Health that trichloroethylene and other,  related  organic  solvents

had been identified in most of the city's wells.   The city discontinued use of

the most heavily contaminated wells and increased pumpage from  the uncontami-

nated wells, supplemented as needed by water from mildly contaminated wells.

The public was notified of the problem and sprinkling restrictions were

announced to keep demand down during peak-use summer months.  ...A request for

Superfund assistance in developing new water supplies was turned down,  but the

city began a program of recompleting wells in deeper intervals  anyway,  at a

fairly large expense.  At present, the previously "clean" wells are picking up

traces of contamination, but the newly-completed wells- appear free of organics,

and should be able to meet immediate demands.  Efforts to trace the source of

contamination have centered around the Twin City Army Ammunition Plant, and

the Army has begun on-site investigations.
 BACKGROUND

    The City of New Brighton is a suburb on the north side of Minneapolis,

 Minnesota.  The Department of Public Works has a total of eight fairly deep

 (around 400 feet) wells serving 23,500 of the city's residents.  At the time

 organic contamination was discovered, average daily demand was about 2.5 MGD

 with  summer peaks running around 6 to 7 MGD.  Only six of the eight wells were

 on line at that time, since one well was down for repairs and the oldest well

 was used  only  as a standby supply.

-------
                                   C-89
 DISCOVERY OF THE  CONTAMINATION  PROBLEM




     By  early  1981, the Minnesota Pollution Control Agency (MPCA) had set up a




 strike  force  unit to  identify and investigate hazardous waste dump sites.




 Acting  on a tip  about past disposal practices at the Twin Cities Army Aramuni-




 tibn Plant (referred to as the "arsenal"), MPCA sampled private wells around




 the  arsenal in July.  When a variety of organic chemicals in well water were




 identified in this testing, the Pollution Control Agency immediately notified




 the  Minnesota Department of Health (MDH), the agency with jurisdiction over



 public water  supplies.




     The Department of Health sampled public wells in the area and discovered




 the  contamination to be fairly widespread.   The water supplies for the City of




 New  Brighton, two other municipalities,  the arsenal and a trailer park were




 found to be contaminated, as were several hundred private wells near the




 arsenal.  Trichloroethylene, trichloroethane, dichloroethylene, and dichloro-



 ethane were the contaminants detected most frequently.   Of the New Brighton




 wells, four had TCE concentrations between 150 and 200  ppb,  two had concen-




 trations from 5 to 10 ppb,  and two wells showed no traces of contamination.




 One of the originally uncontaminated wells  has since shown 20-30 ppb of TCE,



 leaving the city with only  one clean well.








ACTIONS TO  PROTECT WATER  QUALITY




    The Department of Health took a second  set of  samples tp confirm the




 initial results and notified New Brighton.   In discussions with the  city, MDH




 interpreted the health risks of  the  moderately high levels of organics  found




 in the city wells and outlined possible  options  to reduce the risk to public




health.   The  Department of  Health used both the  EPA Suggested No Adverse

-------
                                   C-90
Response Levels (SNARLS) and the HAS increased cancer risk estimates in




explaining the situation to city officials.  Minnesota had not had a similar




case of gross contamination by VOCs before, but the state reacted quickly in




setting a zero-exposure goal to reduce exposure to potential carcinogens as




mtlch as possible.



    The short-term control method was to close the most heavily contaminated




wells.  The City established a pumping scheme to bring contaminated wells on




line only when water demands required, in reverse order by the degree of con-




tamination.  This temporary solution a-llowed base (winter) demands to be met,




but still meant that contaminated wells would have to be used in the summer.




The other immediate action taken was to notify the public of the problem.  The




City hand-delivered letters to all  its customers explaining the problem and




possible health effects.  Shortly thereafter, the press and television media




grabbed the story and put out enough misinformation to make it difficult for




the City and MDH to keep the situation under control.



    The State  outlined  three long-term control options that New Brighton could




take,  basically treatment to remove the organics, new well construction to  find




an uncontaminated source, or connection to an  adjacent municipal water system.




Since the  adjacent system, the  City of Minneapolis, had a history  of taste  and




odor  complaints with  its surface water system, and since treatment was not




thought to be  .a  complete solution,  the City opted for  a well  construction




program.



    With  the  assistance of the  Pollution  Control Agency, New  Brighton  applied




 to EPA for Superfund  money to  recomplete  two existing  wells into  deeper, clean




 formations,  at a cost of  $500,000.  The November 1981  application for  funds to




 develop an alternative source  by deepening existing  fcells was denied because

-------
                                    C-91
 the site  did not  meet  criteria  for .an immediate  removal.   An EPA Technical




 Assistance  Team and  a  Field  Investigation Team have  studied the site.




     The City proceeded without  EPA assistance to have the  two most heavily con-




 taminated wells recompleted  in  a deeper  (1000 feet)  aquifer in September  1981.




 The State required strict quality control measures,  including special casing,




 to  eliminate the  possiblity  of  contaminants migrating to previously-clean zones




 along the well  bore.   Cross-contamination of clean aquifers by aquifers carry-




 ing organic chemicals  is often  a major concern when  monitoring or production




 wells are drilled through more  than one  aquifer.  One of the two recompleted




 wells came  on line in  the summer of 1982 and the other was to follow shortly.




 In  the. meantime,  the City imposed and enforced strict sprinkling bans to  keep




 summer demands  low.  On five occasions, water emergencies were declared.




 Samples taken in  the distribution system when the city was forced to put  a




 contaminated well on line occasionally reached 10 to 15 ppb of trichloroethy-



 lene.




    The Minnesota Pollution Control Agency has been the agency most involved




 in  tracing the  source of contamination and has been following an investigation




program estimated to cost over  $500,000.   The MPCA sampled local wells and




 found that high concentrations of organics were present in wells on one side




of  the arsenal  (the side nearest the New Brighton well field)  and that no




organics were present in wells on the other three sides.   With some EPA




Superfund money for off-site well drilling,  MPCA defined the extent of contami-




nation more  closely.   These data and information on TCE and solvents  use at




the arsenal were used to persuade the Army to do an on-site study.   Officials




at the arsenal originally balked,  but became cooperative after political




pressure was applied by the local Congressional  delegation. Monitoring wells

-------
                                   C-92
have now been drilled in Phase I of the Installation Restoration Program




sponsored by the Department of Defense.



    EPA offered the assistance of a Field Investigation Team in January 1982.




The FIT examined four other potential sources of contamination between New




Brighton and the arsenal, drilled and sampled eighteen monitoring wells,




sampled 150 existing wells surrounding the arsenal, and started a surface-water




sampling program.  The investigation showed that the direction of ground-water




flow was from the arsenal toward New Brighton and that the zone of contamina-




tion was highest on the downgradient side of the facility.  One other site, a




solvent recycler, had high levels of organics nearby, and the owner has begun




investigations on-site in response to  a request by MPCA.
 CURRENT STATUS



     Efforts  are currently proceeding  on two  fronts  in the New Brighton case.




 The Minnesota Department  of Health is still  working with the City to develop




 alternative  sources of drinking water.  Towards  that end, the second of two




 recompleted  wells is expected to come on  line soon  and  a new drilling program




 is planned.   By the summer of 1983, the City hopes  to drill three new deep




 wells, bringing the total of good wells to six,  capable of meeting  even summer




 demands.  Voters in New Brighton passed a $2.6 million  bond issue for further




 well construction in the November 1982 election. MDH performed the background




 work and well site surveys required to locate the new wells.



     In terms of tracing the source, the Minnesota Pollution Control Agency  is




 continuing to gather evidence on the source of the  organics showing up  in




 local wells.  The DPH is engaged in discussions  with the arsenal to determine




 culpability and work out some cleanup agreement.

-------
                                    C-93
 INSTITUTIONAL INVOLVEMENT




     The agencies involved in resolving the organics problem are split into' two




 groups.  On one side,  the City of New Brighton and Minnesota Department of




 Health have the goal of protecting the public health by providing safe drink-




 ing water.   Working in complementary fields,  the Minnesota Pollution Control




 Agency and EPA are  charged with removing the  threat to  health by identifying



 and halting the -source of contamination.




     The City of New Brighton is handling the  problem internally,  without hir-




 ing a consulting engineering firm.   Good communication  with the  state  agencies




 has allowed the City to make reasonably informed decisions,  and  the  City has




 made strong efforts  to protect  the  quality of water distributed  to its  resi-




 dents.   The City and DPH originally shared organics  analyses  expenses,  but New



 Brighton now contracts  with  a private  lab.




     The state agencies  are facing budget  reductions but still have been respon-



 sive to New Brighton's  problems.  The Department of Health  is the lead  agency




 on  drinking water quality issues.  MDH has a  capable but small staff knowledge-




 able about  organics  and ground water.  With the discovery of several organic




 problems in state ground water, however, the Department is being severely taxed




 to  respond  and  cannot handle much more.  Laboratory capacity is especially




 limited.  MDH has contacted EPA Region V several times for information but has



 generally relied on internal resources.




    The Minnesota Pollution Control Agency has been the lead agency involved




 in determining the extent and source of the north Minneapolis area organics




problem.  Relations  between MPCA and MDH are reported to be good.  Since the




Pollution Control Agency also has a fairly limited budget,  agency policy has




been generally to identify the party responsible for contamination incidents

-------
                                   C-94
and turn over further investigations and expenses to the responsible party.




MPCA has spent many weeks preparing requests for EPA to provide assistance  in




emergency and remedial measures.




    EPA involvement in the New Brighton case has mainly been through the




Reglbn V office, except for headquarters involvement in Superfund decisions.




State officials say that the Region V office has been very helpful in respond-




ing to the New Brighton area problem.  EPA headquarters has been reportedly




less helpful in supplying information.








HEALTH GUIDELINES



    The Minnesota Department of Health reportedly uses a 1 in 10s increased




cancer risk level concentration of 27 ppb as the guideline for trichloroethy-




lene.  TCE is usually used as the indicator organic.  The EPA Cancer Assessment




Group (GAG) did estimate that a 1 in 10s increased risk would be associated




with 20 ppb, but no other health department interviewed used the GAG figures




to set guidelines and no other department mentioned a 27 ppb guideline.  The




source, therefore, of the health guideline numbers reported for Minnesota is




uncertain.
 CONCLUSIONS



    The main points of the New Brighton case of ground-water contamination by




 organic solvents   can be summarized as follows:






          •   Widespread contamination, potentially a very serious problem.




          *   Department of Defense involvement slowed response.



          •   State performed  reasonably well but has no established program.




          0   Lack of health information is  a problem.

-------
                                    C-95
          •    Media involvement  complicated  the  situation.

          •    No  EPA funds  for immediate  removals,  although some  Superfund
              money has been made  available.


     State officials believe that  the whole  investigation around .the Twin City

 Army Ammunition  Plant was  hampered by the fact  that the arsenal  is a  federal

 facility  and  that  EPA was  very  leery of  getting involved in a conflict with

 the  Department of  Defense.  According to the National Contingency Plan,

 Defense is responsible for dealing with  hazardous waste problems on their own

 property, but responsibility for  off-site migration of contaminants seems to

 be an unresolved issue.  The Army apparently took the position in this case

 that their responsibility  ended at their property boundary.  Although another

 small source may have contributed to the problem of organic  chemicals in the

 local ground water,  it does appear that the arsenal was the  primary source.

 This premise has not been proven  absolutely, given the difficulties in tracing

 subsurface flows of chemicals that are becoming fairly ubiquitous.

     Another difficulty faced by state officials was in obtaining a commitment

 from EPA to spend Superfund monies on remedial or emergency  actions.   The

 Pollution Control Agency has submitted at least three applications for long-

 term relief, emergency actions (planned removal request),  and initial remedial

 measures,  none of which have been approved.   DCA officials  have not understood

why the decisions have been made against them.   Along the same lines,  the state

has wondered why EPA has  been so hesitant in the New Brighton case to fund

 alternative water supplies.

    An issue related to Superfund decisions  is  the lack of  health effects

 information or standards  for organics  in drinking water.  On one side of this

problem,  the City was unable to  convince the media that the levels of organics

-------
                                   C-9.6
present were not extremely hazardous.  On the other hand, the state was unable




to convince EPA that TCE levels varying from 1 to 150 ppb were serious enough




to require emergency action to supply an alternate water supply.  The lack of




a "hard" number on which to base decisions on protecting public health also




makes it difficult to recover damages from polluters.




    Overall, some measure of certainty in response would have been helpful in




resolving several aspects of the New Brighton case.  It was difficult to decide




on closing wells without solid health guidelines.  Quite a bit of effort was




expended to obtain EPA Superfund assistance without knowing whether such




assistance would be forthcoming.  The responsibility of the Army in cleaning up




the organics problem is still under negotiation.  The failure of all parties




involved to coordinate a broad investigation of the total area of contamina-




tion, now estimated to be 18 square miles, was also due to uncertainties about




funding and each party's degree of responsibility, although the State was in




favor of such a study.  The delays caused by these uncertainties have caused




the health risk to remain and have allowed the organic plume to migrate




further, contaminating another New Brighton well and placing the water supply




of the next municipality downgradient in jeopardy.

-------
                                    C-97
                            CITY OF TUCSON
                          PIMA COUNTY, ARIZONA


 SUMMARY

     Prompted by a state-wide surface impoundment study, EPA undertook a field

 investigation of certain  uncontrolled hazardous waste sites in Arizona early

 in  1981.  The investigation of the Hughes facility, the number one potential

 source of contamination,  near Tucson Airport revealed the presence of various

 contaminants in wells at  and near the facility.  The results of further sampl-

 ing  showed 77 ppb of trichloroethylene in one Tucson Water Department well,

 leading to the closure of that well.  Continued monitoring has revealed

 organic contaminants in eight other public wells, five of which have been

 closed.  Tucson's water production capacity has not yet been significantly

 affected.

     Soil borings and downgradient monitoring wells have been used to verify

 suspected disposal areas and determine migration of the contamination plume.

 Preliminary government efforts  were concentrated on plume identification  and

waste.stream/source studies on  the assumption that a detailed hydrogeologic

 study contracted by Hughes would be available,  but Hughes refused to release

 the report until the summer of  1982.   Some  activity on treatment  research and

 clean-up alternatives has  begun since the Air Force announced a $3 million

 commitment to treat water  from  the contaminated wells.   Previous  estimates of

total clean-up costs ranged up  to $20 million.   The  ongoing  search to

positively identify contamination sites has  been expanded from just  the Hughes

facility to the  Tucson Airport  area  as a whole.

-------
                                   C-98
BACKGROUND




    The City of Tucson Water Department is one of the largest public water




suppliers in the state.  Tucson Water operates over 240 wells, with the number




in service at any one time dependent upon demand.  The annual average demand




is about 70 mgd, with winter lows of 50 mgd and summer peaks near 150 mgd.




The City of Tucson only consumes about 15 percent of the base demand.  Seventy




percent is used for irrigation and the remainder is consumed in copper mining




operations south of the city.




    A typical Tucson water well is about 800 feet deep.  The upper regional




aquifer begins 100 to 150 feet below ground level ,and is roughly 100 feet




thick.  A tight clay zone separates the upper aquifer from the lower, another




100 feet down.  Most wells are screened at both intervals, but the majority of




water produced is from the upper zone since the lower zone is less permeable.




Tucson water-well fields are -scattered over a large part of the Tucson Basin.




    Tucson International Airport is located about five miles south of the




center of the city.  U.S. Air Force Plant No. 44, operated by Hughes Aircraft,,




Missile Systems Group, is on the south edge of airport property about one mile




east of Nogales Highway.  The facility is spread over approximately two square




miles.  Of nearly a hundred structures, the main building (#801) is the source




of most of the liquid effluents and general industrial wastes.  Various metal




finishing and electroplating operations are performed in this building and




others.




    Land use near the Hughes facility is principally medium to heavy industrial




manufacturing sparsely situated on large parcels of extremely flat, arid  land.




The area immediately surrounding the airport to the south and west was




reportedly used- by up to six aircraft manufacturing and retrofitting operations




from World War II to the Korean War.  Approximately one mile west of Building

-------
                                    C-99
 801 and one-half mile from currently-used wastewater impoundments-,  low-income




 single family residences  border  Nogales  Highway.  Trailers  and  small mobile




 home pS£ks  are common along Nogales  Highway,  south of the airport.  Most of




 these residences rely on  deep  200-600  foot municipal and domestic wells




 drilled adjacent to  the highway.









 DISCOVERY OF THE CONTAMINATION PROBLEM




     In December 1979,  the Arizona Department  of Health Services  (ADHS) com-




 pleted a state-wide  assessment of surface  impoundment  sites.  Along with eval-




 uating the potential  for  ground-water  pollution by percolation and infiltration




 from surface waste impoundments  in the state, the report ranked the major sites




 for  further investigation.  Air Force  Plant No. 44, operated by Hughes




 Aircraft, was highest  on  the list, having  reportedly caused the contamination




 of.nearby wells with  chromium, cadmium, and arsenic.   Tucson Water Depart-




 ment's Well SC-7, located  about one mile west of the Hughes facility,  had




 exceeded the EPA Drinking Water Standard for chromium on at least three



 occasions since  1975.




    On the basis of the ADHS study,  EPA Region IX selected the Hughes  facility




 for further investigation under the Uncontrolled Hazardous  Waste Site  Investi-




 gation Program.  An extensive amount of background information was  gathered




 before EPA's Field Investigation Team went on site on March 5,  1981 to  collect




water samples and examine the facility.  This information included  well logs,




previous ground-water quality analyses, aerial photographs,  and other official




documents relating to the plant's operation.   A special effort  was  made to




analyze historical chemical usage and waste disposal  practices.

-------
                                   C-100
    EPA's consultants conducting the on-site investigation (Ecology and Envir-




onment, Inc.) found three Hughes wells contaminated with trichloroethylene;




one as high as 4,600 ppb.  At the same time, Tucson Water Well SC-7, on the




far side of Nogales Highway and one mile west of the most heavily contaminated




Hughes well, yielded 77 ppb TCE.  These samples were taken during the first




week of March 1981.  The test results came back two months later.  Since the




state had no action levels for VOCs, they and Tucson officials spent several




days looking for references.  The same action levels used by the State of




California were adopted temporarily and SC-7 was closed on May 12.




    A follow-up investigation May 26-28 involved gathering some on-site soil




samples and samples from previously inaccessible Hughes wells in addition to




ten municipal and private wells north and west of the facility.  One additional




Tucson well  (C-62) was found to be contaminated and subsequently closed on




June 29.  The presence of TCE and chromium  in wells operated by Hughes was




confirmed  (as high  as 13,000 ppb TCE) at that time.  As more wells  have been




sampled  in  successively wider circles, water from  four more Tucson  wells has




been  found  to contain significant amounts  (over 5 ppb) of TCE and have been




closed.  The most  recent  closure of  an active well was November  1981, but test-




 ing has  continued.   All  of  the  wells  contaminated  lie in a swath stretching to




the northwest  from the Hughes  facility,  although it  is unlikely  that Hughes is




 the only source responsible.








 ACTIONS TO PROTECT DRINKING WATER QUALITY



    As discussed above,  Arizona had no  policy  for  dealing with volatile




 organics in ground water in 1981.   Historically, Tucson has  had  very good

-------
                                    C-101
 water from deep, ancient aquifers.  EPA had even used Tucson water as a base-

 line for naturally-occurring organics, so officials were caught off-guard when

 a serious contamination problem was discovered.  '

     The state tentatively established an action level of 5 ppb for trichloro-

 ethylene, the same level suggested by the State of California.   Five parts per

 billion is roughly the NAS'  1 in 10s  increased cancer risk level;  the concen-

 tration at which one additional case  of cancer per million people  consuming 2

 liters  of water per day over a 70 year lifetime  may be expected.   Six Tucson

 water wells were taken out of service for exceeding this  guideline.   ADHS

 released the  final  Guidelines for TCE in Public Water Supplies in March

 1982, discussed later  in this  case  study.

    After the analytical results  from water and  soil  samples taken by E&E

 during the May follow-up investigation were reviewed/ some  long-term  planning

 began.  'In September 1981 interagency meetings were held  to define the scope,

 tasks, and.areas of responsibility  for investigating  and  removing the threat

 to Tucson's water.  Ecology  and Environment's  Interim Composite  Report on

 Intergovernmental  Agency Activities,  submitted to  EPA Region IX, contains  a

 framework of tasks and subtasks, reproduced here as Exhibit 1,  and a chronology

of major investigative events, reproduced here as Exhibit 2.  These exhibits

outline each study activity,  agency responsible, and planned and actual dates

of accomplishment.  The government agencies most heavily involved in planning

and carrying out the work plan have been:


         •   U.S. Environmental Protection Agency (EPA)

             --  Region IX,  San Francisco
             --  Ecology and  Environment, Inc.

-------
                                               C-102
 CO
  I
 •31
 cs
  I
 o\
•H
 CO
 Cd
 Cd
 CJ
 o
 CO
 CJ

 H
 O


 Cu
 O

•fd

 §
 CJ
 CO







e>J
CO
en
r~^









j I
00
CT*
^^













































CJ
o
Oi
Cd
CO
1
=
1

1
CM
1
CQ
Cd
Fu
§
-5
o
Cd
ca
£„
o
z
EH
CJ
0





U
Z
Cd
^
Cd
>J
aa
M
CO
z
o
CM
CO
Cd
CCi





















>i
'-t
-1
>
H
^
















X

X X X X X X X


XX X X X X X


X X X X X X


X XXX




P O
d r4 U 01 O*
3 oi oi 4J 3
a 4J 4-i co to pa u
-.. co co cu 3 --. O
IJ 3 3 — I M 4J
01 -u M B OI cj
4JfiTJfi4JO4JCO
COO-rlOCO W CO l-l
3 cn E M 3 O 3 4J
O JC 0 T3 3 fi
C3U3BEHBO
OEHCOfHM^-OCJ
ca ^^. *. — *^. o 03
aJ o ctf fi cci cd O* O ^a;
3 3 3 oi 3 ^fl 3 3 CM
O EH £3) ^ Q cd CQ EH cd
*********
03
01 >>
CO -H 4J
CJ U «H
• rl 4J >.rH
4J 03 4-1 CO
to to 3 -rt 3
rH -H -O rH O"
01 l-l C CO X
> >> Q) M 3 rH -O
OI 60 4J O* CO 3
rJ O U U CJ 4-1
rH CO O rH -r4 CO
MO U «4-l (0 E
01 OI tO CJ CU rH
4J CJ .C 4-1 -H jC CO
CD CJ 01 B CJ CJ
3 01 00 01 -r4
CJ CO f^J TJ *fi rH CO

•H U-4 tO u-4 CQ O J3

tO 3 3 J-i C M O
>H UCOIHCXQJgJOOt
C^ CO O ^J 4J M U fjl
3 J3 ra M tn
CO O CO O O OBSrH
>» -H >W O
rJ l-l BUH4-I BOUHU-IJ^
, B -r< ea. B e -H -H
O'HB-HOlEOcfltOO
tlrHCU-H BOIOIrHrHTJ
rv^ CUOICU *CUCJ^^O
Q3aa — caacdcdcj
£C <£ CQ O C-^CdpL^U^C








^*

X
X

X




















u u
-O TJ
•H -H
e E
•s-s
CO CO

B S

&£ >*&
•K ,*













4J rH
<4H tO
CO B
U -iH
a cu
CO

CO

U-l O
o
4-1 O
ca
4J fi
OI O
P -H
Q* 4-1
OI l-l
fi o.
— Cu
M


















X


X X


X X



'






w

0 CJ
3 3
n CQ
« «








td

01
to
>> 3
.C T3
P. fi
co ca
M^
O rH
>• 4J CO
Q O U

EH Cu >-i
CO O
t-< 4J
Cd CO to
CJ -r4 -H
OS l-l X
£3 01
O < «H
CO O
^•» y-i
SOB
•3 a
Cd tfl >r4
OS *r4 4J
EH 03 co
CO r*» 3
rH rH
Cd CO CO
H fi >
co -a! Cd
3 < <0
M















X


X


X



CJ
3
CQ
Cd

Cd

I-i
O

CJ
CO
I-i
4-1
B
0
O

^
CM
td
•K











01
4-1
CO
CO
3
*rj
• r4
rH
O
CU CO
U
•H IW
4-1 O
O
CO B
r4 O
CU .H
rH CO
CO N
•H -H
l-l l-l
4-1 OI
Indus
Charact
o










X
X

X

X


X








t
CO
OI
• H

4-1
CO
3
•fi
rH
O
§ ,

Cd Cd Cd

td td td
•K * *
CO
cu
•f-l
l-l
4J
03
3

fi
M

^i
O
<4-l 4J rH
IH to
4J CO C
OI »J -H
00 Q Cu
-a
3 1
M
4_l

o
M «W U-l
EH O O
CJ B fi
MOO
CU -H -r4
M 4J £»
EH to (0
Z B B
Cd -H -H
a E e
M IJ >-l
OI OI
Cd 4J 4-1
§ 01 01
S a ta
M




X
X
X
X

X
X
X



















































to
rH
(—1
OI
03
00 rH
B rH
•rt 01
4J S
CO
•H 3
* £
Cd Z
• •
— t>»





XXX
XXX
XXX
XXX

XXX
XXX
X

X

X


X


X


X






4J
J-i J-t T3
O O *H
4J AJ £j
0 0 43
to td u
I-i M CO
4-1 JJ
c; e c
o o  '
M
0
a.
OI
at
14-1
O
C
o
• H
4J
Prepara
CM






























































>,
CJ
fi
o>
00
CO
13
CO
ai
rH
dicates
c
M

-------
C-103
c.
K
<
C£
H-
£
—
:/
2!
^
Xi
^3
^











CO
d
_|
5
b
g
*
CO


















01
01
r>
•f-l
4-1
cd
d
M
CO
U
1-1
O.
3
d
cd
reatment/Cle
^
M







Cd
c£)
Cd
""«s»
CJ
§•
CQ
•te

0
^4
cd
CO
CO

">;
•a
3
4-1
01
CO
en
cd
o «-*
^ o
.Literature
.Evaluation
< m









w
c<3
Cd
^S^
'g
PQ
•K



,— 1
cd
^
o
CO
Vl
CO
•a
'H
t-H
0
CO
d
1 .Extractio
option





Cd
td
Cd

O
o-
3:
CQ

CJ
3:
P3
4C









cd
01
0
ex
CO
•H
^
2. Treatment
options





jj
CU
4J
cd


d
o
01
a
3
£-4
•K









M
(U
cd
3:
4_l
0
.Development
CJ



















e
ca

eo
0
M
Oi
ement
eo
cd
d
.2
tl
CO
en
CO



«
Cd
CJ
O"
i^S
CQ
i^^
O

CQ
•x^
Oi
Cd
-K


r-«
O
•M
4-1
cd
4J
d
CU
e
O)
r-l
a, 01
S 
•H
•a 4J
d cd
.Selection a
of altern
a













o
O
Q
•K







..^
CU
3 c^-
co -a
CU
rH U
cd cj
CJ cd
CO -i-l P.
H eo e
CJ 0 -H
O-i O 01
1 I p" '
01 O
.03 T3 f.
H -H 3:
>J O. •






















e>-
13
0)













CJ
a
a
•K




CO
4J
01
O
CJ

y J3
Cd 4-1
CX r-l
S cd
•r-l CU
EH

CO
4-1
CO
>J
cd
3
o
33
*
04



o
Evaluation
PQ













ss
Cd
•JC
Q
3

Cd 01
33 Q
•
(-1
!•»
                                                                  C r-l
                                                                  O  O
                                                                 O  M
                                                                     4J
                                                             «-<  >>  C
                                                              O 4-»  O
                                                              J-l -fl CJ
                                                              4-1 r-l
                                                              C  CO  CU
                                                              O  3  CO
                                                             cj o*  cd
                                                                     -•  >
                                                              3  3 -H
                                                             pa  « Q
                                                                                 o
                                                                                 d
                                                                                 CO
                                                                                 oo
         c
         o
 >  d
 4-1  M  O
 la  O  I-
 aj i— i  -^i
 a.  o  >
 (U  CJ   d
a Cd  Cd
                                                              I
                                                                     I   I    I    I
                                                                 I
                                                                CJ
                                                             o o- CJ os  cd  <
                                                             3 3: Q 3  u3  o-
                                                             B3 CQ Q Q  Cd  Cd

-------
                                        C-104-
                        :TARLE 2.1 CHRONOLOGY OF MAJOR INVESTIGATIVE EVENTS
   DATE
              ACTIVITY DESCRIPTION
                                                                        AGENCY PARTICIPATION
3/3 - 5/31



4/15/81


5/26 - 28/81
5/18/81


7/17-11/2/81
7/17/81-
4/8/82

9/8-10/81
9/22-23/81



11/81


1/12-31/32





1/25-2/8/82
Site inspection of Hughes' Aircraft/USAF Plant # 44;
11 water samples collected from onsite and offsite
municipal,  industrial, and private wells

Draft preliminary site inspection report submitted
to Hughes Aircraft Co..for comment

Followup investigation of Tucson Airport area; 14
water samples collected from onsite and offsite
wells; onsite wellsresampled plus Credit Union well
and Hughes  Hell #2; 3 soil samples collected from
former waste water impoundments; .ADHS collects
duplicates  of offsite wells

HAC critique of draft preliminary report received
and draft report revised; .report released 6/29/81

A total of 93 water samples from 52 municipal and
private wells. Sample collection dates 7/17, 7/20,
8/3, 8/11,  8/12, 8/24, 9/2, 9/16, 9/30, 11/2.

Distribution system sampling (ave. 7 samples/sel)
Shallow soil.borings; 22 samples collected in
areas selected by ADHS in over 8 sections rang-
ing from drainage ditches south of Irvington Road
to various areas on HAC property.  Report
TSC14-2(81)177 issued by EPA on 1/8/82

Inter-agency coordination meetings; develop con-
ceptual tasks and assign responsibilities;
establish reporting framework

Well Inventoryi  historical water quality data
search; water level measurements

6 soil borings to 150' in five separate locations
(TAA fire fighting training area, HAC FACO dump,
 HAC abandoned  metal precipitate pits, HAC aban-
 donned wastewater impoundment,.TAA landfill )j
115 samples collected

Tucson Airport Authority welV'tflO aquifer test;
abandoned  well reactivated, pumped for 2 weeks,
and periodically sampled.  Duplicate samples
collected for ADHS BWQ and EPA/E&E by TW; 15
sets of samples collected.
EPA/E&E; TW
EPA
                                                                     EPA/E&E; TW; ADHS
EPA/E&E
                                                                     ADHS BWC; ADHS BWQ
                                                                     TW; ADHS BWQ
                                                                     .ADHS/BWC;  EPA;  EPA/E&E
EPA: EPA/E&E;  ADHS; AzAG;
TW; flzDWR


DWR; TW  •
 ADHS  BWC
                                                                      TW;  EPA/E&E

-------
                                          C-105
    DATE
                ACTIVITY  DESCRIPTION
                                                                          AGENCY PARTICIPATION
 3/P-5/8?
 3/15-18/82
3/15/82



t/13-6/1/82


i/10-14/82
71/82


1/82
  Tucson Airport  Authority wells  tfl.and #5 aquifer
  tests; abandoned wells  reactivated,  pumped 1-2 days
  each;  7 samples collected at TAA  #1;  9 samples
  collected  at TAA'#5 plus blank  from  distribution
  system.

  Attempted  monitoring well installation;  revised
  scope  of work resulted  in collection  of  3  water
  samples  and 8 soil samples collected  from  3  lo-
  cations  (TAA landfill,  drainage ditch  at entrance
  to Tucson  Aviation Center off Nogales  Highway,
  drainage ditch  immediately south of Warner Prop. Co.
  Tucson Aviation Ctr.)

  RCRA 3007 information requests  sent to Airport Area
  industries  for waste practice  investigation; re-
  sponses received circa  4/10/82

 Aquifer testing; B-102,  SC-7, B-85, B-101,  B-87,
 C-64, C-62, B-103                               '

  ntermediate depth soil  borings; 59 samples-
  ollected in 23  soiling  borings  at a depth
  f approximately 15 feet; 5 general areas
  elected  on basis of historical  alleged
  ources  of  disposal.

  ughes Aircraft/Hargis & Montgomery hydrogeological
  tudy made  available to  EPA

5 monitoring wells scheduled for installation;
Coordination with San Xavier Indain Reservation
Gates Learjet,- and Hughes Aircraft.  Phase  II
monitoring wells pending results..
                                                                       TW;  EPA/E&E;  EPA
                                                                      ADHS/BWC; EPA; CPA/E&E
 EPA
TW
                                                                      EPA/E&E
EPA
                                                                     EPA; EPA/E&E
              FP?/F*F'   r Enviro™ental  Protection Agency, Region IX,  San Francisco, CA
                     ^  A°-°9y & EnVir°nment' Inc. Field Investigation Team
                       "  £H20na Apartment of Health Services/Bureau  of Waste Control
                                            °f HeaUh S-V>C"/B-eau  of Water Quality
                  .
              DWR -  Arizona  Department  of Water Resources
              AzAG - Arizona 'Attorney General    •

-------
                                   C-106
             Arizona Department of Health Services  (ADHS)



             --  Bureau of Water Quality

             —  Bureau of Waste !Control



             City of Tucson Water Department



             Arizona Department of Water.Resources
CURRENT  STATUS



    Since June 1982, developments have occurred on several fronts.   Hughes



finally released the hydrogeologic report prepared by their consultants,  after



EPA negotiated and filed suit for the information.  EPA directed the construc-



tion of five monitoring wells on Indian land west of Nogales Highway.   The



county health department became active in the case.  The major development was



announced by the Air Force in October.  In a lengthy press release, the Air



Force stated its intention to spend $3 mill-ion under its Installation



Restoration Program (IRP) to clean up the Tucson aquifer.  Previous estimates
    a


of the cost of clean-up had ranged up to $20 million.



    After major negotiations, the Air Force committed itself to a plan to pump



contaminated ground water to a treatment plant capable of removing the subject



organics.  One and a half million dollars has been allocated for redesigning



and replacing pumps and pipes and making other alterations at Hughes' treat-



ment plant to allow pumping at 450 gpm.  Another $1.2 million has been allo-



cated for drilling 15 reclamation wells "spread strategically within the zone



of contamination."  The cost of booster pumps and 35,000 feet of pipelines are



included in that figure.  The final $300,000 has been approved for designing' &



treatment system.  These remedial actions are to be  implemented when EPA's



efforts to define the extent of the contamination plume are complete.  EPA has



already spent over $500,000 on the case.

-------
                                   0107
    In the same press release, the Air Force verified that contamination

migrating off-site had forced Tucson to close Well SC-7.   The Air Force was

not involved in early discussions on the contamination problem but has now

stated that "the contaminants .. . were used by Hughes in it's operations at the

plant (and) percolated through the soil from waste treatment ponds."



INSTITUTIONAL INVOLVEMENT

    The responsibilities and participation of the major government agencies

involved in the Tucson ground water problem have been as  follows:


         •   U.S.  Environmental  Protection Agency  (EPA).  EPA has been
             directly involved in every step of detecting and resolving the
             problem.  The state-wide surface impoundment assessment by ADHS
             that uncovered the problem was largely funded by EPA, as is ADHS
             itself.   EPA's uncontrolled hazardous waste  site program was
             responsible for confirming the presence of TCE and other
             contaminants.  Region IX personnel and their main contractor.
             Ecology and Environment, Inc., haye been heavily involved in
             hydrogeological studies, waste stream/source analysis,  plume
             identification and treatment/clean-up research.

         •   Arizona Department  of Health  Services  (ADHS).   Despite
             budget cutbacks and  organizational changes,  ADHS has  played a
             major role in the Tucson case.  ADHS is the  regulatory agency
             with primary responsibility for ground-water protection,  safe
             drinking water and control of hazardous wastes in Arizona.
             Therefore, when the  contamination problem was discovered,  EPA
             reportedly asked ADHS to take the lead in the case,  also for the
             purpose of avoiding  intergovernmental conflicts.   Since then,
             ADHS has coordinated all local,  state,  and federal TCE-related
             activities.

             This responsibility  has been a major drain oh health  department
             resources.  Since the state had no contingency plan for dealing
             with a ground-water  contamination incident as serious as  that
             discovered in Tucson, funding and manpower had to be  borrowed
             from existing programs, causing other services to be  cut  back.
             Reorganizations have shifted responsibility  back and  forth
             between safe drinking water,  hazardous  waste, and ground-water
             protection (a group  that was  scheduled to be phased out in 1981)
             programs.   A special group was recently set  up to manage  the
             continuing investigations and implementation of  remedial actions

-------
                      C-108
in the TCE problem areas as well as to oversee the utilization of
monies obtained under the CERCLA and Arizona's Water Quality
Assurance Revolving Fund (WQARF).

The Water Quality Assurance Revolving Fund is Arizona's version
of Superfund, set up by the state legislature in response to the
discovery of trichloroethylene and other contaminants in Tucson
area wells.  The monies in the WQARF can be used to assist in the
clean-up or removal of contaminants from ground water or as state
matching funds against federal remedial actions related to ground-^
water problems.  The WQARF was funded to $500,000 in 1982, with
half of that, the maximum allowable for one site, already
committed to the Tucson case.

City of Tucson Water Department.   Tucson Water,  the agency
most directly affected by the discovery of organics in the Tucson
aquifer, had not only the funding but the technical expertise to
respond to the problem.  Since the water department still had
ample capacity after the well closings, it was in no hurry to
resolve the contamination problem if in doing so, water
department funds would be expended.  On the contrary, Tucson
Water chose to limit.their involvement and see if a federal or
state source could be found to fund investigative and remedial
actions.  Tucson Water expenditures on the case were generally
related to pump tests and sample collection.  Although the State
had to struggle to come up with $50,000 for emergency drilling,
Tucson Water reportedly had several times 'that amount available
in one of several program budgets.

These facts are not intended in any way to put the blame on
Tucson Water for not responding as quickly as possible, but to
point out a dilemma that is not unique to this case.  As long as
the water system could still meet demand and  as long as no
immediate threat to other wells was obvious,  there was no
incentive for  the department to rush in and spend their own money
when other funding sources could be exploited.  Some
clarification  of EPA policy on reimbursement  for  funds already
expended might have speeded the department's  response.

Pima  County Health Department.  In the summer of 1982, the
county health  department became involved  in the organics issue
since it was brought up as a highly publicized, politicized
health hazard.  Pima County began an extensive search  for private
wells near the airport that had not yet been  tested  and handled
sample collection  for the  state.

The county went one step  further due to the  interest  aroused by
publicity  on the case.  At a public hearing  in September  1982,
monitoring requirements  for  all public and semi-public water
systems  in the county were proposed.   In  the  form of  a County
Ordinance, this proposal would  require annual testing  by  each

-------
                                   C-109
             system for volatile organics.   In addition to the cost  burden  on
             small system operators  (some of which supply only 5  to  10
             customers), enforcement of the ordinance would be difficult.

             Arizona Department of  Water Resouces (ADWR) .  The Department
             of Water Resources is another agency involved in the coordination
             and planning of meetings.   As the state  agency responsible  for
             keeping track of the quantity of water resources, ADWR  assisted
             the overall effort by conducting a well  inventory and providing
             historical water quality data and water  level measurements.
             Drilling logs and well  specifications have also been helpful in
             developing an idea of the previously-unstudied hydrogeology of
             many problem areas.
HEALTH GUIDELINES

    As previously discussed, the health hazards posed by organic chemicals

found in Tucson's water forced ADHS to adopt temporary guidelines for TCE which

were finalized in March 1982.  ADHS is currently re-evaluating the guidelines

issued in March to address the issue of TCE risk relative to other hazards,

such as the trihaloraethanes prevalent in surface-water" supplies near Phoenix.



CONCLUSIONS

    As might be expected of a "potentially disastrous" contamination problem

involving a large number of actors, the response to trichloroethylene and

other organics detected in wells near Hughes has not proceeded perfectly.

Some difficulties raised by officials involved in the investigation are noted

below:


         •   Hughes' refusal to release the hydrogeological information
             collected by their consultant, Hargis and Montgomery, slowed
             investigative efforts, reduced the possibility of a coordinated
             response, and caused undue friction.

-------
                                   C-110
         •   The uncertainties and time involved in getting the Tucson
             Airport Area on EPA's Interim Priority Superfund (CERCLA) List
             delayed investigative efforts and caused several steps of the
             workplan to be eliminated due to funding constraints.

         *   Tucson Water Department had the necessary resources but
             expended no great effort in response because it hoped to obtain
             EPA funds.

         •   ADHS was caught unprepared and had to fight budget cutbacks,
             public pressure, and a lack of technical expertise to respond.


These problems served to slow but not stop progress on the case.  In the end,

the Air Force came through with funding from a Department of Defense IRP grant.

This and Superfund monies have caused Hughes and the government health agencies

to increase their respective levels of effort towards resolving the problem.

    Several other difficulties unrelated to the amount of money spent in Tucson

remain.  Health effects information on the contaminants detected is incomplete

and not easily understood by the public.  In a state such as Arizona, the

health department does not have the resources required to conduct health

research and must depend on the federal government.  Similarly, many states do

not have the expertise required to set guidelines or regulations for carcino-

gens and again must rely on more capable agencies, although even EPA has yet

to decide on regulations for some synthetic organic compounds.

    Another weakness is in knowledge of the transport and decomposition of

organics in the soil and ground-water environments.  Local officials did not

have much faith in the ability of existing models to predict plume movement.

Some type of chemical finger-printing was also mentioned as a technology that

would help to positively identify sources of contamination.

-------
                                   C-11,1
                      GREAT OAKS WATER COMPANY,
                        SAN JOSE,  CALIFORNIA


SUMMARY

    The Great Oaks Water Company (GOWC)  in San Jose was  notified by Fairchild

in December 1981 that trichloroethane had been found in  wells  on Fairchild's

plant site.  A nearby GOWC well was then tested for volatile organics.  When

the test results showed the well water was contaminated  by 5,700 ppb of, tri-

chloroethane, the well was taken out of  service.   Fairchild, GOWC,  and  the

half-dozen agencies with jurisdiction over health and water issues  then began

meeting to determine the extent of contamination and resolve the problem.

    Soil borings and monitoring wells have outlined the  area of contamination

around a leaking waste solvent tank on Fairchild property, and the  firm has

been pumping the contaminated GOWC well  through carbon-packed  bottles to waste

to keep the trichloroethane from migrating to other wells.  The water company

had enough capacity to meet demands during the relatively cool summer of 1982

but is concerned about other down-gradient wells becoming contaminated.  Great

Oaks is also concerned about its reputation and solvency in the face of several

lawsuits alleging damages to public health.



BACKGROUND

    The Great Oaks Water Company is an investor-owned utility  regulated by the

California Public Utilities Commission.   The company was founded in 1959 to

provide water to an unserviced area in South San Jose, and has grown rapidly

with the development of the local electronics industry;  now serving an  esti-

mated 70,000 persons through 16,000 connections.   GOWC prides  itself on pro-

-------
                                   C-112
viding excellent service to the community at very reasonable rates,  arrived at




through careful planning and budgeting.




    Before the contamination problem was discovered, GOWG was operating 13




wells.  An average daily demand would be about 10-12 mgd, with summer peaks as




high as 19 mgd.  The water company has a 1.5 million gallon elevated storage




tank for peak leveling and fire protection, but the widely dispersed wells




pump directly into the distribution system so localized pressure drops can




occur when a well is taken out of service.








DISCOVERY OF CONTAMINATION



    In November of 1981, a Fairchild crew noticed discolored soil and smelled




solvent fumes while excavating near the south-west corner of the South San Jose




plant for a new underground storage tank.  Fairchild did some soil borings and




tested an on-site well shortly thereafter to determine the source of the




apparent leak.  Great Oaks Water Company officials noticed the drilling activ




ity,  since the plant site was directly across the street from their offices,




but knew nothing of the problem until  Fairchild  informed them on December 4




that  trichloroethane had been found in a Fairchild well one hundred feet from




the plant.   Since the notification was given  late on a Friday afternoon, the




President of GOWC wasn't able to contact  state officials for advice on how to




proceed until the following Monday.  On that  day, Fairchild1s consultants




 (EMCON) tested GOWC Well No.  13 and the domestic water supply in the Fairchild



plant.  The plant's water  showed only  0.7  ppb of trichloroethane, but Well No.




 13 showed 5,700 ppb of  trichloroethane.




     At this point  it  is  interesting to note that in 1980 the State Department




 of Health  Services had  conducted a study  of volatile halocarbon contamination

-------
                                   C-113
 in four  ground-water basins.  Trichloroethylene  and tetrachloroethylene were




 chosen as  indicators of  contamination because of their widespread use and dis-




 persion's ease  and  sensitivity of  analysis, environmental persistence (resis-




 tence  to degradation)  and high mobility.  Of 183 wells sampled in the Santa




 dlaM  Valley,  only three wells showed any traces of TCE or PCE contamination




.and none of  these  tested over 1.0 ppb.  Great Oaks Water Company Well No. 13




 was sampled  and  scheduled for TCE/PCE and purgeable organics analysis, but the




 sample was apparently  lost, as no results were ever reported.  Results for




 Well No. 13  could  have either alerted officials  to the contamination problem




 considerably earlier or  established a base date  at which the contaminant plume



 had not  reached  the well.








 ACTIONS TO  PROTECT  WATER QUALITY




     Closing  the  contaminated well was the. first  short-term step in protecting




 the quality  of water delivered to Great Oaks' customers.  Since the concentra-



 tion of  trichloroethane  in Well No. 13 was almost twenty times as high as




 California's 'Action Level' (discussed later), the need for this action was




 not questioned.  Organizing working groups to trace the source and to plan




 remedial actions was another effort undertaken shortly after the contamination



 was discovered.




     Beginning  in December 1981, the water and health agencies with either




 responsibility for or  an interest in the problem began meeting at least every




 other  week.  The purpose of the meetings was to  plan monitoring and long-term




 clean-up actions,  as well as to report individual progress.  At first,  some




 officials were confident that the entire problem would be resolved within




 three  months,  but  more cautious voices have proved correct as no comprehensive

-------
                                   C-114
plan for remedial action has emerged as of eleven months after the leak was




discovered.  The organizations usually represented at the meetings have been




the Great Oaks Water Company, Fairchild, the Santa Clara County Health Depart-




ment, the Santa Clara Valley Water District, the Regional Water.Quality Control




Board, the State Department of Health Services, and various consultants.




    When the contamination problem was discovered, Fairchild's consultant was




EMCON.  EMCON drilled about eight monitoring wells on-site in an initial




attempt to define the area of contamination.  After it became apparent that




the scope of the problem was expanding, Woodward-Clyde Consultants were com-




missioned by Fairchild to define the plume and suggest clean-up measures.




Also in early 1982, Fairchild paid to have one GOWC well (No.  4)  deepened to




increase production capacity, at a cost of about $30,000.




    Woodward-Clyde took soil borings or drilled monitoring wells  at 23 loca-




tions on Fairchild property and constructed another 19 monitoring wells down-




gradient from the property.  Eight private wells in the area were also sampled.




In January Woodward-Clyde had decided that Well No. 13 had to be  pumped to




waste to halt the spread of the plume to other wells, and later set up a row




of monitoring wells as an early-warning system for other GOWC production wells.




Their report "Hydrogeologic Studies at Fairchild Camera and Instrument Corpora-




tion, MOS Facility" was finished in May 1982 and reportedly cost  Fairchild




about $500,000.   The Woodward-Clyde report seemed to explain the  hydrogeologic




characteristics  of the region and define the areal extent of the  TCA plume




fairly well, but no suggestions were made for cleaning-up the source.  The




report apparently did include a contingency plan for responding if the tri-



chloroethane moved past the contaminated GOWC well.

-------
                                   C-115
    Fairchild designed and had installed an unusual system for removing the




trichloroethane from Well No. 13 water before pumping it to waste.  The con-




taminated well is now pumped through isolated GOWC lines to a filtration system




on the Fairchild site.  About 1,700 gpm of contaminated water is pumped through




750 to 800 individual carbon bottles connected in parallel, each tank treating




slightly more than 2 gpm.  The Regional Water Quality Control Board has




approved a maximum effluent1 concentration of 30 ppb for water dumped to a storm




drain on-site.  Fairchild also had several large carbon contactor tanks




installed in June and July of 1982 to remove or'ganics from water pumped from a




purge well near the leak site.  Because of very high influent concentrations




(over 10,000 ppb), the tanks are currently treating only a tenth of their




total design capacity of 2,000 gpm.  Fairchild is reportedly spending $5,000




to $6,000 per day on carbon replacement alone.




    At present, after extensive evaluation, Fairchild has selected another con-




sulting firm, Canonie Environmental, to continue working on the aquifer contam-




ination problem.   Fairchild has been thinking recently about removing the




organics from contaminated water by an air-stripper process, but nobody seems




to know what levels of trichloroethane are safe in air.   The Air Resources




Control Board would have responsibility for the necessary emissions standards,




but the characteristics of the substance and the legal definition of "source"




are still uncertain.  The questions associated with transferring a potential



carcinogen from one medium to another have yet to be resolved.








CURRENT  STATUS




    At present, the extent of trichloroethane in South San Jose ground water




has been fairly well defined.  Great Oaks water supplies are sufficient for

-------
                                   C-116
the short-terra, and it appears that Fairchild will be involved in cleaning up




the contamination.  GOWC has probably the most-often tested water in the




country, with Fairchild and IBM running organic analyses weekly.   IBM has been




spending about $6 to 8 thousand per month on testing and GOWC has been spending




ail eqtial amount.  Fairchild's expenses have been even higher.  The overall




situation seems fairly well in hand, but some problems remain.




    Some local residents are dissatisfied with official responses to the




problem.  Articles in the local press (viewed as "sensationalist reporting" by




local officials) have aroused public interest in the trichloroethane problem




to a "hysterical" pitch.  One point of contention is that Fairchild did not




notify the public of the trichloroethane leak until after a newspaper printed




the story a month after Well No. 13 was closed.  Local and state officials




maintain that notification was postponed while the extent of the health hazard




was being studied, and that the contaminated well had been closed down immedi-




ately regardless of notification.  One lawsuit has been filed over this




alleged negligence.




    Another point of contention is the failure of state and  local government




to set standards for organic chemicals and to follow through on enforcement of




these standards.  A class action suit has been filed by 150 people against the




Regional Water Quality Control Board, the State Department of Health Services,




the City of San Jose, the Santa Clara Valley Water District  and others alleg-




ing negligence in protecting public health.




    Most recently, in May 1982, a multi-million dollar lawsuit was filed by




eight South San Jose couples claiming,they have been harmed by the contamina-




tion.  Led by  a mother of a child with a congenital birth defect, the group




brought suit against Fairchild and GOWC.  Prompted by public outcry, the State




Department of  Health Services announced in late September a  study to investi-

-------
                                   C-117
gate possible links between the contaminated well and birth defects in one

neighborhood.  The study, which could cost up to $100,000, should be concluded

by September 1983.                                              ,            ,



iNltltUTIONAL INVOLVEMENT

    Several of the mild organizational conflicts and the perceived lack of

progress encountered in responding to the organics  problem in Great Oaks Water

Company wells were due to the myriad of overlapping jurisdictions  in the State

of California,   The following summary attempts  to explain the mandate and

involvement of each organization:


         •    Regional  Water Quality Control  Board (RWQCB).  The RWQCB was
             officially the lead agency in the  Great Oaks case.  As  the agency
             with overall responsibility for water quality in the  state,  the
             RWQCB was looked to for direction.   Unfortunately,  for  some
             reason, the Board was  slow to "react to  the  problem  in South San
             Jose,  and several of the other  agencies  became frustrated  at
             constant  delays.  Relations  were smoothed out  somewhat  in  the
             work groups.

         •    State  Department of  Health Services (DHS).  California DHS
             is  charged with protecting  the  health of the public and therefore
             has  jurisdiction  over  public water  supply wfells.  Two DHS  groups
             the  Sanitary Engineering Branch and the Hazardous Waste Manage- '
             ment Division have been  involved in the  Great  Oaks case    The
             primary role of DHS has  been in administering  drinking water
             standards  and monitoring requirements.   DHS has also provided
             information on the health effects of various organics found in
             water  systems.  Of the state  agencies,  DHS  is probably best
             equipped to serve as a clearinghouse for health information.  The
             Department  doesn t have  a toxicologist or a huge staff, but they
             do try to keep abreast of developments  in health research and
             occasionally go to EPA for assistance in answering complicated
             requests.

        •    Santa  Clara Valley Water District (SCVWD).  The SCVWD is  in
             charge of water conservation and flood  control in the Valley
            The Water District operates surface reservoirs and artificial
             recharge basins as the local agency for surface and ground-water
             supplies.   Although the SCVWD does  have ordinance and revenue
            S^r'x." Usually relies on the less-cumbersome authority of the
            KWQOB when enforcement actions are  necessary.  In the  GOWC case
            the^Water  District sits in on meetings  and reviews proposals for
            exploration and remedial measures.   As  the custodian of  all well

-------
                      C-118
logs in the Valley and the body most familiar with ground-water
flows, the SCVWD must approve any well drilling activity.   In
this capacity, the Water District rejected a plan to pump  out,
clean-up, and reinject contaminated water on the grounds that
until the contamination area was defined, changes in flow
patterns might disperse the plume.

Santa Clara County Health Department (SCCHD).   In
California, the County Health Departments are responsible  for
enforcing SDWA monitoring requirements and water quality stan-
dards for small, semi-private and private water systems.   When
Fairchild announced it had discovered the trichloroethane  prob-
lem, it was the Santa Clara County Health Department that  checked
the nearby small community systems for organic contamination.
Over a hundred samples were taken, but no nearby wells were found
to be contaminated.  The County is quite concerned about the
threats posed to over 5,000 private wells.  The SCCHD role in the
Great Oaks case has been to supplement the State Health Depart-
ment by taking responsibility for the small community systems,  as
well as to participate in the planning meetings with the rest of
the agencies.

Great Oaks Water Company  (GOWC).  As discussed earlier, the
GOWC is a medium-sized investor-owned utility.  As such, the
Water Company is subject to Public Utilities Commission rules and
must meet all the same Health Department water quality standards
as the public (municipal) water systems.  A major difference is
that a private utility isn't eligible for public grant money for
defining and cleaning up a contamination problem.

U.S.  Environmental Protection Agency (EPA).   The Region IX
EPA office in San Francisco and the headquarters Office of Drink-
ing Water, Criteria and Standards Division have been involved in
the Great Oaks case.  Region IX has had  little to do with the
case except to answer occasional  questions from DHS.  Region IX
has not assisted the local agencies.  The director of the
Criteria and Standards Division of the Office of Drinking Water
at headquarters and his staff have reportedly been helpful in
supplying health information.

Consulting  Firms.   At least four consulting firms have been
working on various aspects of ground-water contamination  in the
Great Oaks Water Company service  area.   Fairchild has had EMCON,
Woodward-Clyde Consultants, and Canonie  Environmental working oix-
and off-site.  IBM has hired Brown &  Caldwell as part of  their
rapid response to a potential contamination problem  near  their
facility.               .'•.,.'                         :

-------
                                   C-119
HEALTH GUIDELINES                                       -.-.>..




    The California Department of Health Services has recommended a set of




 Action Levels" for organic chemical compounds found in domestic water sup-




plies.  These guidelines are essentially the EPA SNARLs.  The Action Levels




ar6 generally set at the carcinogenic risk levels where a 1 in 1,000,000 excess




lifetime cancer risk is estimated, although some variances up to the 1 in




100,000 risk level are allowed if alternate water supplies are not available.




DHS plans to expand the list of Action Levels as more information becomes




available from EPA or as major incidents of contamination force the issue.








CONCLUSIONS




    In addition to complaints from consumers and lawsuits over past practices,




the problem presently affecting local officials is that nothing has been done




to clean up the source or the aquifer and no actions have been approved for the




near future.  This concerns water and health officials who are worried about




continuing contamination and the potential of the contamination plume spread-




ing to other wells.  They believe that the difficulties caused by the involve-




ment of so many agencies, the defensive attitude of the industrial source, and




the failure of the lead agency to act decisively have slowed responses to the




problem to the point that no resolution is in sight, a far cry from early




predictions that the problem could be cleared up in three months.




    According to most officials interviewed, the major weaknesses in dealing




with the trichloroethane problem were related to health information and guide-




lines.  The need for EPA to continue research on the health effects of organics




and to then promulgate standards (rather than loose guidelines) based on that

-------
                                   C-120
health information and an assessment of risks was voiced frequently.  Other




topics suggested for research were the detention and transport of organic




chemicals in the subsurface and ground-water environments.  Less expensive




testing and monitoring techniques were also called for, but the major area




where EPA assistance was thought necessary was in performing health research,




distributing health effects information in a form understandable by the public,



and establishing enforceable standards.

-------
                                   C-121
                       LAKEWOOD WATER DISTRICT

                      PIERCE COUNTY, WASHINGTON





SUMMARY



    The Tacoma-Pierce County Health Department (TPCHD)  and the State Department



of Social and Health Services (DSHS) conducted a survey of surface  and ground-



water quality in late 1980.   Traces  of organic chemicals appeared in a sample



taken from a Lakewood Water District well.   Followup sampling by DSHS and EPA



Region X confirmed that relatively high levels of 1,2 trans-dichloroethylene,



trichloro.ethy lene, and tetrachloroethylene  were present in two adjacent



Lakew.ood wells.



    EPA took the lead in a two-phase approach to the problem.   The  first  phase



consisted of an immediate 'health response (closing the contaminated wells) and
                                                               I


planning meetings with the agencies involved to coordinate efforts  in determin-



ing the extent of contamination.  In the second phase,  the EPA, state and local



health departments, state Department of Ecology, Lakewood Water District, and



the Air Force met to identify the source and discuss corrective actions.



    The Water District lost about one-tenth of its production capacity when



the two wells were closed in August 1981.  In addition to problems  with low



water pressure in that corner of the District, summer demands were  difficult



to meet, so sprinkling restrictions had to  be implemented. .A new,  deeper well



was drilled to augment water supplies, but  that effort only produced a dry



hole.  The Water District and other local agencies have admitted that nothing



could have been done without EPA1s technical and financial assistance, but are



disappointed at the slow pace of progress in the case.

-------
                                   0122
BACKGROUND



    Pierce County is located at the southeastern end of Puget Sound in western




Washington State.  It is roughly 1,790 square miles in area and extends from




Puget Sound to the crest of the Cascade Mountains Range, a distance of about




75 Biles.  Most of the County's 501,000 people live in central Pierce County,




primarily in the cities of Tacoma and Puyallup and the unincorporated areas




surrounding Tacoma, including Lakewood.



    The highest density residential and commercial growth has occurred in




central Pierce County, primarily in the area south of the City of Puyallup and




in the communities of Lakewood, Parkland and Spanaway, all south of Tacoma.




Developmental pressures in the Lakewood area have been heightened by the




expanded use of nearby McChord Air Force Base and Fort Lewis since World War




II.  Nearly all  growth in unincorporated Pierce  County has occurred without




'the benefit of public"sewer  systems.   Community  storm water  drainage systems




are  also virtually absent outside  of  cities, making storm water injection




through  drain wells  commonplace  in many areas.   Only one major protected



 surface-water source exists  in the county,  that  serving the  majority of needs?




 for  the  City  of  Tacoma.  Drinking  water for most areas  of  developing Pierce




 County has been  supplied by many small public  and private  water systems




 tapping  underlying ground-water  aquifers.



     The  geology  of the Pierce County area is an important  factor  in ground-




 water studies.   The region is crossed by  several well-defined channels cut by




 glacial  meltwater streams  which left substantial deposits  of coarse sands  and




 gravel known as  the Steilacoom gravels.   Several of these channels are the




 ancestral tributaries of the Lakewood area drainage basin known as Clover  and




 Chambers Creek.   Due to the high velocity and erosional effects of these

-------
                                   C-123
meltwater streams, and to glacial anomalies in the local geology,  the normally




protective glacial till layers are absent in some areas, permitting rapid




recharge through the overlying highly permeable Steilacoom gravels.  The uncon-




solidated glacial drift and alluvium underlying the area contain aquifers of




very high porosity and permeability that yield high flow rates of water.  The




highly permeable gravels and steep gradient make rapid transport of ground-




water contaminants a serious problem.




    The Lakewood Water District draws all of its water from these highly per-




meable aquifers, using 25 wells screened at intervals varying from 110 to 800




feet deep.  The Water District serves over 40,000 persons in a twenty square




mile area southwest of Tacoma.  Wide variations in demand are due primarily to




lawn sprinkling in this mostly-residential area:  average demands  are near 6




mgd,.with summer averages of 15 to 18 mgd and the peak 1982 demand at 22 mgd.




    Most of the Lakewood wells are pumped directly into the distribution sys-



tem,,, although the Water District does have a small amount of storage capacity.




Some of the wells receive chlorination,  and all are sampled weekly for



bacteria, a concern in this unsewered area.








DISCOVERY  OF THE CONTAMINATION PROBLEM




    In response to growing concerns about the effects of rapid development on




ground-water quality, DSHS directed a study 'in 1980 to investigate the extent




of aquifer contamination in the Clover Creek-Chambers Creek Basin.   The study




was designed to document ground-water quality, identify any trends in ground-




water quality related to development, and recommend areas for further study.




The analysis of existing data showed that a significant problem did exist

-------
                                   C-124
and recommended a. comprehensive survey of water quality be made as  soon as

possible.

    ThS comprehensive survey began in November 1980 and .was concluded in

February 1981.  The Department of Social and Health Services performed the

survey, with the aid of the Tacoma-Pierce County Health Department.  EPA agreed

to assist by running organics analyses on 24 samples collected throughout the

basin.  Lakewood Water District Well No. H-l was selected for analysis partly

to satisfy geographical diversity and partly for its proximity to McChord Air

Force Base.

    The  results of the February tests came back later in the spring, showing

that  1,2 trans-dichloroethylene, trichloroethylene, and tetrachloroethylene

were present  in Well No. H-l.  Follow-up sampling by EPA and DSHS in July and

August confirmed that H-l and H-2, a nearby well in the same production zone,

were both contaminated.  The the results of those tests were as follows:


HIGHER LEVELS OF CONTAMINANTS DETECTED
(ppb)

                                               Well #1      Well #2

              1,2 trans-dichloroethylene          37           138
              trichloroethylene                      7           18
              tetrachloroethylene                  29           138


ACTIONS TO  PROTECT WATER QUALITY

     Since the levels  of contamination in both wells exceeded the NAS  contami-

nant level  for a 1 in 100,000  increased cancer risk by as  much as  600  percent,

 immediate  action was  necessary.   The following account of responses  to the

 discovery  of VOC contamination is taken partly from a paper presented at the

 AWWA 1982  Annual Meeting by William A.  Mullen (Region X Drinking Water Program

 Chief) and others.                       '

-------
                                   C-125
    The Water District, State Departments of Health and Ecology, Tacoma-Pierce




County Health Department, EPA, and the U.S.  Air Force formed a work group to




deVelbp and implement an action plan.  The action plan was broken down into




three phases:  removing the health threat, determining the source of contamina-




tldfi*. and taking remedial measures to restore,or replace Lakewood's water



supply.                            •




    In the first phase, concurrent with the planning process, several actions




were taken immediately.  The Water District voluntarily removed the wells from




service in mid-August and notified its customers regarding the problem.   A




sampling program was begun to assure that contaminated water had been flushed




from the system, and nearby homeowners with private wells were urged to contact




the Tacoma-Pierce County Health Department so that sampling could be arranged.




Those Wells, along with other public water supply wells in the area, were




sampled by EPA to ensure that any public health threat had been eliminated.



Wells on McChord Air Force Base were sampled jointly by EPA and the Air Force. <




    In the second phase of the EPA investigation, beginning in November 1981,




a number of monitoring wells were drilled to determine the source of contamina-




tion.  Ten shallow (28 to 35 feet) interactive wells were drilled by EPA from




November to February around the contaminated Lakewood wells.  These wells,




drilled at a total cost of about $10,000, showed some contamination in the




upper aquifer, but at concentrations an order of magnitude lower than those in



H-l and H-2.  Pump testing of the two Lakewood wells, however, showed there




was some interconnection, possibly through a poorly-cased well bore, between



the two aquifers.

-------
                                   C-126
    In January 1982 the hypothesis that the upper aquifer was the carrier of




contamination was abandoned,  and efforts were concentrated on the lower




aquifer.  By this time the Water District was becoming frustrated with the




apparent lack of progress and therefore contracted for a deep multilevel well




near H-2 with their own money, rather than waiting for authorization through




EPA and EPA's contractor, Ecology and Environment (E&E), Inc.  EPA provided




technical assistance on this well and did the testing, which showed the




highest contamination at a depth of 90 feet.



    The information gathered from the multilevel well was used to design a




deeper drilling program.  Beginning in June 1982, a series of deep holes have




been drilled around H-l and H-2 in an effort to trace the flow of contaminants




in the deeper aquifer (below 90 feet).  A cable tool rig has been used for




these test holes because it is much more controllable and provides better




samples than an air rotary rig.  The seventh deep well has just, been completed,




and EPA officials expect the next well to confirm their suspicions that the




contaminant plume is flowing from a source  in the direction of nearby McChord




Air Force Base.  To date, only about $36,000 has been spent on the 10 shallow




wells, one multilevel well, and seven deep  monitoring wells.




    As the above activities were proceeding, the Air Force carried out some




investigations on-base.  The Air Force  and  EPA checked the eight wells on




McChord Air Force Base  after organics were  discovered in H-l and H-2, but




found only trace levels.   In addition,  quarterly surface-water sampling has




not shown organics  concentrations higher than allowed by the Base's NPDES




discharge permit.   Most other  investigations on the Base have been related to




the Air Force's  Installation Restoration Program.

-------
                                   C-127
    The Installation Restoration Program (IRP) is essentially the Air Force's




version of Superfund.  IRP is a four-phase program targeted at identification




of potential waste storage areas through to the final restoration of any dump




sites which may require clean-up.  Phase I, a detailed analysis of records,




including a history of operations, the geological and hydrological conditions




which may contribute to migration of pollutants off installations, and a search




of ecological files for evidence of any environmental effects resulting from




contamination, was completed by CH2M and Hill in July 1982 and made public.




Phase II, a field survey of the installation, consisting of soil and water




sampling to confirm the presence of specific migrating pollutants, was begun




shortly thereafter by JRB Associates.  The first two phases are estimated -to




cost the Air Force $370,000.  Phase III and IV, containment and remedial




actions, will depend on the findings of Phase II.  Based on preliminary




findings, the Headquarters Air Force Engineering and Services Center program



directors have moved McChord from below number fifty to about number twelve  on




"the list" of installation priority sites.  Some of these actions were accele-




rated when a local congressman, in his efforts to find a culprit in the




Lakewood incident, initiated a congressional investigation into the case last



spring.








CURRENT STATUS




    The second of three phases to resolve the Lakewood problem is currently  in




progress.  The immediate health hazard has been removed, and EPA is optimistic




that drilling efforts in October and November will all but pin down the source




of contamination.  Phase three, remedial action to ensure that Lakewood Water

-------
                                   C-128
District has a safe long-term supply,  will likely take quite a while,  based on

the quantity of VOCs already pulled out of the- production wells and the fact

that increasing concentrations have been reported in some wells.
INSTITUTIONAL INVOLVEMENT

    At least a half dozen organizations have been directly involved in resolv-

ing the problem of organic compounds in Lakewood Water District's ground-water

supply.  The 'round-table' approach, to planning and decision-making has

attempted to take advantage of expertise held by each group.  The following

briefly describes the role of each organization in the Lakewood case.


         •   U.S.  Environmental Protection Agency (EPA).  The  Drinking
             Water Programs Branch of EPA's Region X in Seattle has been the
             lead agency  in coordinating a response to the Lakewood contamina-
             tion problem.  Other agencies have stated that they simply could
             not have handled the problem without technical and financial
             assistance from EPA.  In terms of technical assistance, EPA.or
             EPA's contractor ran the organics analyses that originally-
             discovered the problem, performed further sampling in confirma-
             tion, drilled the shallow monitoring wells, supervised the multi-
             level well,  and is now drilling a series of deep wells that are
             expected to  pinpoint the source of contamination.  Since the
             state and county have no capacity for laboratory analyses of
             organics, EPA has generally been responsible for all testing.

             For technical information, EPA officials in Seattle have con-
             tacted  EPA headquarters, various consulting firms with experience
             in hydrogeology, and personal sources at other Regional Offices.
             For health  information, the Seattle office has usually turned to
             the Office of Drinking Water  at headquarters in Washington, D.C.
             Professional journals and water industry conferences have also
             been  credited as valuable sources of  information for those
             organizations with  enough personnel and resources to keep up with
             current events.

          •  State Department of Social and  Health Services (DSHS).  The
             Department  of Social  and  Health Services is responsible  for the
             quality of  water  distributed  to the public.  In this  capacity, it
             deals with  water  utilities  on sampling  and  compliance  require-
             ments  and provides  information on treatment.   Although DSHS is
              the primary health  agency in  the State  of Washington,  it  has not

-------
                      C-129
established a program to deal with contamination of ground-water
sources and has no plans to establish any guidelines for organics
in drinking water.  In the absence of any state program for
responding to VOC contamination,  DSHS has handled each incident
individually, referring to the EPA Office of Drinking Water's
"Guidelines in Response to Contamination Detected in Groundwater
Supply Survey" and to other agencies for suggestions on how to
proceed.

The Department of Social and Health Services is handicapped in
dealing with problems such as organics in the Lakewood wells for
several reasons.  First of all, there seems to be some confusion
at the state level as to who exactly is responsible for this new
type of problem.  Some coordination in the roles of DSHS and the
Department of Ecology would be helpful.  Secondly, the state has
been hardhit by budget cuts and has not looked favorably on
expanding health  service related activities.  Finally, DSHS has a
shortage of personnel qualified'to deal with organics or ground
water.  The civil engineers traditionally concerned with conven-
tional water or wastewater treatment just have not been trained
in hydrogeology or toxicology, and the state has no lab space  for
organics analysis.

Department of Ecology  (DoE) .  The State of Washington
Department  of  Ecology is more concerned with the resource  aspects
of ground-water  contamination than  the health  effects.   In the
Lakewood  case, DoE' was  involved  in  the debate  over local growth
and  land use planning that "prompted the  DSHS study ('with the
cooperation of DoE and Tacoma-Pierce County Health Department) of
ground-water quality.   Because of jurisdictional conflicts,
 including one over the Commencement Bay  Superfund  site,  and  the
 commitment of a large share of resources elsewhere, DoE has  not
played a major role  in the Lakewood contamination  problem.  The
 Department of Ecology has,.however, assisted in the initial
 ground-water basin study and in surface  surveys of potential
 sources of organic contaminants.

 Tacoma-Pierce County  Health  Department (TPCHD) .  Under an
 agreement with DSHS, the local health department has responsibil-
 ity over some small water and sewer systems.   Without the finan-
 cial or technical resources to do any complicated testing, how-
 ever, the Tacoma-Pierce County Health Department has been unable
 to take much responsibility over ground-water issues.

 The Health Department has been heavily involved in several
 aspects of the Lakewood case.  The TPCHD helped the State select
 well sites for sampling in the initial ground-water basin study.
 Health Department officials urged DSHS to recommend closing the
 Lakewood Water District's contaminated wells early, after the
 first round of testing.  More recently, the department has been
 conducting historical  surveys into the use and disposal of

-------
                                   C-130
             organic compounds in the Tacoma-Pierce County area.   This
             information is being used to gain insight as  to potential  con-
             tamination sites as well as to aid in the development of a com-
             prehensive land use policy.

             Since the Tacoma-Pierce'County Health Department could not afford      *
             to do any drilling or even organics scans, they credit EPA for
             making any progress in the case possible.  At the same time,
             TPCHD was mildly critical of the slowness of  response and  several
             lapses in communications between themselves and the  federal
             organizations.
                                                         \
         •   United States Air Force (USAF).  The Air Force and Army have
             maintained large installations south of Tacoma since before World
             War II.  McChord Air Force Base property, beginning  several
             hundred yards from the contaminated Lakewood  wells,  consists  of
             over 1,000 acres on which live about 6,500 people associated  with
             the Base's flying mission.

             McChord Air Force Base was the immediate suspect when the  tri-
             chloroethylene, tetrachloroethylene, and dichloroethylene  (com-
             pounds often associated with aircraft-type degreasers) were dis-
             covered at H-l and H-2.  As of September 1982, no evidence has
             conclusively implicated or exonerated the Air Force  as the source
             of the volatile organics.  Under the USAF Installation Restora-
             tion Project (described previously), Base personnel  and their
             consultants carried out an extensive study of organics use and
             disposal practices.

         •   Lakewood Water District.   The Lakewood Water District's main
             concern in the organics contamination case has been  with finding  ,
             a suitable location for a new production well.  After extensive
             studies, one deep well was drilled a mile downgradient of  the
             contaminated wells.  Continuous monitoring showed no detectable
             organics as drilling passed through the aquifer level contami-
             nated at Well No.s H-l and H-2.   Lakewood has not taken a  signi-
             ficant role in tracing the source of contamination.


HEALTH GUIDELINES

    As mentioned earlier, the State of Washington has not  set guidelines for
                                                                                   f
volatile organics in drinking water.  The EPA SNARLs are therefore the  only

real guidance the health agencies have in responding to cases of  contamina-

tion.  The obvious difficulty with this approach is that the SNARLs document

can be interpreted in many ways.  Lakewood Wells H-l and H-2 contained  over

200 ppb of each of the organics detected, well over the maximum recommended

-------
                                   C-131
concentrations other states suggest (usually on the order of 5 to 50 ppb).


For this reason the health agencies were unanimous in recommending that the



wells be taken out of service.


    If circumstances had differed, the response might have been less predict-


able.  An EPA official in Seattle thought a standard should be set at a risk


level between I/10s and 1/107 excess cases of cancer, roughly equivalent


to a TCE level between 4.5 and 0.45 ppb.  An Air Force'official said he would


be concerned if over 10 ppb of TCE showed up in his wells, a risk level between


1/105 and 1/106.  Most state guidelines recommend using water with no more


than 5 to 50 ppb of TCE, depending on the availability of alternate supplies.


The Lakewood Water District Superintendent did not seem to think that a 1 in


4,000 risk  level of excess lifetime cancer risks was excessive.,  All parties


involved called for someone, usually an agency with higher authority, to set
                                                               I

some defensible guidelines.






CONCLUSIONS


     The response  to the discovery of trichloroethylene,  tetrachloroethylene,


 and dichloroethylene  in Lakewood Water  District wells was  slowed by a  lack  of


 financial  resources,  little  previous  experience with VOCs  in ground water,  and


 the regional attitude that resource contamination is an East Coast  problem,


 not a Washington problem.   Overall,  the organizations - involved were fairly


 well organized and responded to the best of their abilities.  Several


 weaknesses, however,  were highlighted by officials working on the case:




          •   Health effects information still contains  lots of unknowns  and

              needs to be improved;

-------
                                   C-132
             Some type of public education effort would be helpful to
             explain the magnitude of risks in understandable terms;

             Streamlined funding and response mechanisms would eliminate
             frustration over delays perceived by the public as
             unresponsiveness to the problem;

             A clearinghouse for information on treatment options and other
             technical aspects should be set up and publicized;

             A lack of qualified hydrologist/geologist professionals
             requires present staff to be spread thin at times;

             Some type of inhouse or external peer review process for study
             plans would help if the response was rapid;

             Some standard well placement and monitoring procedures would be
             a good fallback;

             Communication between the levels of government involved in
             organics contamination cases needs to be improved;

             The federal government needs to recognize that in most cases,
             local governments cannot shoulder this type of burden.
To reiterates better health information and clear guidelines are the two most

critical areas where research efforts should be concentrated.  Other areas

where assistance would be helpful are drilling and monitoring, and hydrogeo-

logical investigations, in general.

-------
                              APPENDIX D


                           LIST OF CONTACTS

                      GROUND-WATER CASE  STUDIES
PHONE  INTERVIEWS

    Bedford, Massachusetts
         EPA Region I  - Eliot Thomas

         Town of Bedford  - Steve Daly, Town,Administrator

         Massachusetts Water Pollution Control Office

         Massachusetts Department of Environmental
           Quality Engineering  - Jerry McCall

         Camp,  Dresser, McKee - Donna D'Amore

    Garden City Park, New York
         Water District Superintendent - John Mirando
              Assistant Superintendent - John Guarino

         Nassau County Health Department - Frank Padar

         N.C.H.D. Bureau  of Water Supply -
           Michael Alarcon, Director

         New York Bureau  of Public Water Supply
           Protection - John Orndorff, Director

    Vestal, New York
         Town Engineer -  Tom Goettle

         Consultant - Ray or John Martin

         New York Department of Environmental
           Conservation - Mike  Marchie

         New York Department of Health - Jim McCarthy

         New York Bureau  of Public Water Supply
           Protection - John Orndorff, Director
(617)  223-6688

(617)  275-1111




(617)  292-5500

(617)  742-5151
(516) 746-3194
(516) 746-3194

(516) 535-3324
(516) 535-3323


(518) 474-5577


(607) 748-1514

(607) 724-3226
(518) 474-5577

-------
                                   D-2
PHONE  INTERVIEWS  (Continued)

    North Pennsylvania Water Authority,  Pennsylvania
         North Pennsylvania Water Authority -
           Harry Borchers,  Executive Manager

         North Pennsylvania Water Authority -
           Judy Wright

         EPA Region III  - Bob Ranowski, Karen  Dewald

    Vero Beach, Florida
         Lab Supervisor  - John TenEyck

         EPA Region IV -  Mark McClanahan,  Toxicologist

         Florida Department of Environmental
           Regulation -  Glen Dykes
           (also William Bostwick, Fred Huttner,
             Mickey Bryant)
(215)  855-3617


(215)  885-3617

(215)  597-9873


(305)  562-5124

(404)  881-3781


(904)  488-3601
         Harper-Branch Research Foundation - Dr.  Tsen Wang -(305)  567-7196
    New Brighton, Minnesota
         City Engineer - Les Proper
         .Minnesota Department of Health - Gary Englund,
           Chief, Water Supply Section
         Minnesota Department of Health - Dick Clark,
           Supervisor, Engineering Unit

         Minnesota Pollution Control Agency - Steve Lee

    Petoskey, Michigan
         City Manager - Steven Hoffner

         Public Works Superintendent - Frank McCune

         MDPH - District Engineer - Tim Benton

         MDPH - Public Water Supply Division
           Jim Cleland

         Michigan Department of Natural Resources -
           Dan Cummins, Geologist

         Petoskey Water Superintendent - Pete Adams

         District Health Office - Dr. Brian Young
(612) 633-1533

(612) 296-5330

(612) 623-5227

(612) 297-2720


(616) 347-4105

(616) 347-4105

(517) 373-1376


(517) 373-1376


(517) 373-2508

(616) 347-5550

(616) 347-6014

-------
                                  D-3
PHONE  INTERVIEWS  (Continued)

  - South Brunswick, New Jersey
         Public Works -  Larry Merk

         Township Health Officer  - Robert Harris

         IBM " Chaim  Luria

         New Jersey DEP  Geologist -  Bill Altoff

         New Jersey Bureau of Potable Water  -
           Barker Hamill

         Geraghty-Miller - Erhardt Werth


SITE  VISITS

    Glen Cove,  New  York
         Director, Public Works - Joe Hurley

         Superintendent  - Anthony Caruso

         Nassau County Department of Health  - Don Myott,
           Frank Padar

         Nassau County Bureau of  Water  Supply -
           Mike Alarcon

         New York Bureau of Public Water Supply
           Protection -  John Orndorff,  Director

         Nebolsine, Kohlmann, Ruggiero  Engineers -
           Dominic Ruggiero

    Rockaway Township, New Jersey
         Health Department - Richard Christie

      .   Township Engineer - Ron  McKinnon

         Water Superintendent - Donald  Tyrone

         Township Attorney - Rich Sirota

         New Jersey DEP  - Joe McKulka

         New Jersey Bureau of Potable Water  -Barker Hamill
(201)  329-4000

(201)  329-4000

(201)  329-7704

(609)  292-0668


(609)  292-5550

(516)  921-6060
(516)  676-2000

(516)  676-2000


(516)  535-3323


(516)  535-3324


(518)  474-5577


(212)  695-6800


(201)  627-7200

(201)  627-7200

(201)  627-7200

(201)  539-1313

(609)  292-0577

(609)  292-5550

-------
                                   D-4
SITE  VISITS (Continued)

    Elkhart, Indiana
         Water Works Manager - Mike Terlep

         State Board of Health - Arnold Viere
                               - Jim Traylor
(219)  295-2400

(317)  633-0210
         City Engineer - Bruce Carter

         EPA Region V - Michael Strimbu

         Canonie Environmental - Roberto 'Rob1  Weiss Malik

    Battle Creek, Michigan
         Michigan DPH - Water Supply Division - Jim Cleland

         Michigan DPH - District Engineer - Rick Wirsing

         Michigan DNR - Bill Iverson, Section Chief

         EPA Region V - Steve Ostrodka

         City Utilities Engineer - Larry Osborn

         Calhoun County Health Department - Ted Havens

    Lakewood, Washington
         EPA Region X - Bill Mullen, Section Chief

         EPA Region X - Fred Wolfe, Hydrologist

         Washington Department of Social and Health
            Services - Bob James

         Tacoma-Pierce County Health Department -
            Derek Sandison

          Lakewood Water District, Superintendent -
            Wayne Dunbar

         Washington Department of Ecology - Jim Oberlander,
            Will Abercrombie
(219) 295-2400

(313) 886-6202

(219) 926-8651


(517) 373-1376

(517) 373-1376

(517) 373-8147

(321) 886-7571

(616) 966-3421

(616) 966-1241


(206) 442-4092

(206) 442-0691


(206) 464-7671
 (206) 588-4423
          United States Air Force  -
            Captain Lindsay Waterhouse

-------
                                  D-5
SITE VISITS (Continued)

    San Jose, California
         Great  Oaks  Water Co.  -  Ken  Krajeyski

         Regional Water Quality  Control  Board -
         •  Peter Johnson

         Santa Clara County Health Department -
           Steve Brooks

         Santa Clara Valley Water District - Tom Iwamura

         Fairchild - Larry Amen

         California Health Department (DHS),
           Engineer - Cliff Bowen

         EPA Region IX - Nate Lau, California

    Tucson, Arizona
         Water Department - Tom Jefferson

         Water Department - Bruce Johnson,
           Chief Hydrolegist

         City of Tucson - T.J. Harrison, Attorney

         EPA Region IX - George Wilson,  Arizona

         EPA Region IX - Harry Seraydarian, Toxics
           Division

         Arizona Department of Health Services -
           Pamela Beilke, DEH

         Arizona Department of Water Resources -
           Ed Nemecek
(408)  227-9540


(415)  464-4270


(408)  279-6060

(408)  265-2600

(415)  962-5011


(415)  540-2153

(415)  974-


(602)  791-4761


(602)  791-4761

(602)  791-4221

(415)  974-8274


(415)  974-7460


(602)  255-1134
         Consultant  - Ecology & Environment - Dave Buecker  (415) 777-2811
         United States Air Force - Charles Alfred,
            Environmental Program Manager

         Hughes Aircraft - Donald Ellerman, Legal Counsel
                         - Edward K. Spaulding, Manager,
                           Environmental Health and Safety
Wright-Patterson
Air Force Base
 (602)  746-6000

-------

-------