Nutrient Movement Through Beach Media:
                 Problems and Field Results
Application to Enhance Cleanup of Oil Contaminated Shoreline
                    Steven C. McCutcheon
                          U.S. EPA
              Environmental  Research Laboratory
                      Athens,  GA  30613
                       John R. Haines
                          U.S. EPA
            Risk Reduction Engineering Laboratory
                26 W. Martin Luther King Dr.
                   Cincinnati, Ohio 45268
                       John A. Glaser
                          U.S. EPA
           Risk  Reduction  Engineering  Laboratory
                26 W. Martin Luther King Dr.
                   Cincinnati, Ohio 45268

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INTRODUCTION                                              :

      On March 24,  1989, the  EXXON VALDEZ went aground in Prince William
Sound, Alaska, releasing approximately  11 million gallons of Prudhoe Bay crude
oil.  After learning of the magnitude of the spill, the EPA Office of Research
and Development  (ORD) convened  a meeting of nationally and internationally
recognized scientists in the  field of oil biodegradation to evaluate the
feasibility of using bioremediation to  assist in cleanup operations.
Recommendations  from the meeting urge ORD to plan and conduct a field
demonstration project to evaluate the use of fertilizers for accelerating
natural biodegradation of the spilled oil.1"6

Specific conclusions and recommendations were:

•     Oil' biodegradation in Prince William Sound waters is probably limited by
      the availability of nitrogen and  phosphorus; therefore, fertilizing the
      beaches with  these nutrients will enhance natural degradation of the
      oil.1'3-4-8

•     Past studies  have shown convincingly that the enhancement of oil
      biodegradation by nutrient addition readily occurs.  Further
      verification  of these studi.es by  laboratory experiments are unnecessary.

•     Successful bioremediation will require consideration of the engineering
      requirements  of long-term nutrient application and the physical
      agitation of  oil.

•.    Bioremediation should be applied  to residual quantities of oil, once the
      bulk oil has  been removed.

•     Treatment of  the beaches with fertilizer may not remove the black oil
      residues due  to the high molecular weight of the oil and consequent
      lower rates of biodegradation but will  reduce the ecological
      availability  of the oil.

     A detailed oil spill bioremediation research plan was then developed by
EPA ORD scientists.  The major objectives of this plan  were to:

•     Examine the occurrence and extent of natural biodegradation of oil on
      the contaminated beaches,

•     Determine the effect of nutrient  addition on the rate of biodegradation
      under field conditions.

•     Develop application methodology for long-term application of nutrients
      to contaminated beaches.


•     Develop information on the movement of nutrients in beach substrata
      (beach mechanics).

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     The importance of nutrient movement in beach strata led  to  convening  of  a
 workshop to develop study plans for hydrologic evaluation  of PWS  beaches.  The
 workshop considered the state of knowledge of water flow in  beaches.  The
 results of the workshop were presented in a report that made several
 conclusions and recommendations.   First and foremost, it was noted that  very
 little  is known about water movement  in extremely porous,  steep beaches
 typical  of PWS.  Consequently, knowledge of nutrient movement in  these beaches
 is  similarly limited.  After limited  observations on the original experimental
 beaches,  a research plan was prepared to study hydrology and nutrient movement
 in  a typical  beach in PWS.

      Items considered for study were  the extent of wave action and tidal
 influence on beach hydraulics, loss of applied nutrients to  sea water, and
 effect  of rainfall  on beach hydrology.   The results of these studies were
 designed  to provide information for application to model development of
 subsurface water flow and mixing of fresh and salt water layers in the beach
 material.

 BACKGROUND

      The  site  of the  EXXON  Valdez oil  spill  is  a harsh  and diverse environment
 with  poor accessibility.   The shoreline is  geologically young. It is composed
 largely of metamorphic rock,  and ranges from vertical  cliffs  to cobble and
 pebble  beaches.  In  some sheltered bays,  beaches were composed of  sand and
 gravel.   High-energy  beaches  are common,  with tides that vary from +4 to -1 m.
 In  some areas,  glacier and  snow melt  introduce  large amounts  of fresh water to
 nearshore  water of  the Prince William Sound.

     'The  spilled  oil  spread over an estimated 350 miles of shoreline in Prince
 William Sound.   Major contaminated shoreline areas include Knight Island,
 Eleanor Island,  Smith Island,  Green Island,  and Naked  Island.  Knight Island,
 the largest  and  one of the  most heavily polluted of these islands, has
 restricted  tidal  flushing action in some  bays and coves.

     The  oil settled  into the beach gravel  and  on rock  surfaces and the faces
 of vertical cliffs..  Contamination occurred  primarily  in the  intertidal  zone.


     The  stranded oil  was weathered with  a  loss of approximately 15% to 20% of
 the oil by  volatilization.  Volatilized  components  included  normal aliphatic
 hydrocarbons less than  12 carbon atoms  and  low  molecular weight aromatic
 hydrocarbons (benzene,  toluene,  xylene,  and  naphthalenes).  The resulting
 residue consisted of  approximately 40%  to 50% high-molecular-weight waxes  and
 asphaltenes.  On most beaches  in Prince William Sound the weathered oil  was
black and viscid rather than  brown and  mousse-like(emulsified oil).

     Beaches were physically  cleaned  by  EXXON with  a combination of flooding
 and the application of  water  under high  and  low pressure and/or high
temperature. Gross quantities  of oil were removed  from the Passage Cove
Beaches. Vacuum extraction  and physical 'skimming  were used to remove the
released oil from the water surface.  The cleaning  process partially removed

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 oil  from the surface of rocks and beaches, particularly the pools  of oil   but
 did  not effectively remove the oil trapped in and below the matrix of gravel
 and  cobble.  However, the washing process spread a thin layer of oil  over  a
 much greater surface area of rock and gravel.  The extent of physical  washing
 was  dependent upon the degree of contamination.

      To investigate bioremediation,  two test sites were chosen.  Criteria for
 the  selection of the test sites were based on the following:

       Typical shoreline of Prince William Sound; i.e.,  mixed  sand-  gravel, and
       cobblestone beaches

 •      Sufficient area with fairly uniform distribution  of sand,  gravel, and
       cobble for the test plots

 •      Protected embayment with low energy wave motion,  adequate  staging areas
       and  sufficient size to support several  test and control  plots

 •      Uniform oil  contamination

 •      Shoreline with a gradual  vertical  rise

 PASSAGE COVE PROJECT SITE

       Passage Cove is located on  the northwestern side  of Knight Island.  This
 site was originally heavily contaminated with oil  and was subjected to
 physical washing by Exxon.   Even  after physical  washing,  considerable  amounts
 of oil  remained at this site,  mostly spread  uniformly over the surface of
 rocks  and  in the beach material below the rocks.   Pools  of oil and mousse-
 like(emulsified oil)  material  were minimal on the surface.  Contamination was
 apparent to  about  50 cm below the beach  surface.   The shoreline  area and the
 designated  beaches in Passage Cove are shown  in  Figure  1.  The test site chosen
 had a  mixture of sand,  gravel,  and cobble material.  Except for  storm surges
 the wave action was generally low energy.  The calm conditions made possible
 daily  accessibility,  safety,  and  durability of the apparatus over the period
 of the  study.   The tidal  fluctuation  over the period of  the study varied from
 a high  of 4.3  m.  to'a low of -0.7 m.   This tidal  fluctuation was expected to
 dramatically affect hydraulic behavior of water  in the beach face.   As was
 typical  of  PWS  beaches,  the ground level  rose rapidly behind the beach area,
 with the exception of a small  pond directly behind the primary berm of the
 beach.   The  pond was  expected to  contribute freshwater flow to the beach area
 and moderate rapid changes  in water  level  due to  rainfall  events.

 METHODS  AND  ANALYSIS

     Hydrological  evaluation  of Kittiwake  Beach at Passage Cove, Knight Island
was implemented  through  installation  of  sample wells, instrument packages,  a
 tide gauge and  a weather  station.  Concurrently,  this beach was used to test
 the efficacy of nutrient  application  via  a sprayer using water-soluble
 fertilizer.  The orientation  of wells  installed on the beach and a  diagram of
 the instrument  packages  installed  in  the wells are shown  in Figures 2 and 3,
 respectively .  Samples of  surface and subsurface  sediments were collected for

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 oil  composition analysis about two weeks before fertilizer application, one,
 four,  and six weeks after fertilizer began.   Routine  interstitial water
 samples  for nutrient analysis were collected on the same  schedule.

 Nutrient Collection

     Nutrient samples were collected every two weeks  between August 6 and
 September 12,  1989.   Water samples were withdrawn  from each of three small
 tubes  placed alongside the major well  casing.   At  each sample location these
 sample tubes extended to.specific depths:   two feet below the beach surface,
 one  foot above the  bottom of the well,  and the bottom of  the well, respec-
 tively.

     Due to the vertical  changes in sea level  over a  tidal cycle, often a
 complete series of  nutrient samples could  not  be obtained.  Survey samples
 were collected in groups.   Groups 1 through  7  were collected August 6 and 7,
 groups 8 through 17  were collected August  20 and 21,  and  18 through 25 were
 collected September  10 and 11,  1989.   Sample sets  were collected at about
 three  hour intervals,  unless otherwise  indicated.

 Water  Samples .                   _                               '          .

     Clean 250 ml polyethylene  bottles  were  filled with water and frozen as
 soon as  possible after collection.   For each sampling period, samples were
 collected every three  hours over two  tidal cycles.  It was not feasible to
 collect  samples over 24 hour cycles due to weather conditions and the hours of
 darkness.   Salinity  and temperature data were  collected in the field concur-
 rently with  nutrient sample collection.  Samples were analyzed for ammonium,
 nitrite,  nitrate, and  phosphorous.

 Nutrient  Application

     During  the experimental  period from August 2  through  September 11, 1989
 fertilizer solution  was applied  to Kittiwake beach daily.  Seven pounds of
 triple super phosphate{0-45-0)  and 17 pounds of NH4N03(34-0-0) were dissolved
 in about  35  gallons  of seawater.   The  fertilizer solution was metered into a
 sprayer  system and distributed  over the beach  plot over a period of about an
 hour.

Meteorological  Monitoring

     Automatic  data  recorders were used to record  meteorological data,  water
conditions  in  the sample wells,  and tidal  conditions  in the bay.  The
meteorological  station was  damaged in a storm  after three weeks operation.
The well  data  recorders recorded water  depth,  salinity, and temperature.  The
tide gauge recorded  water  depth,  temperature,  and  salinity off the beach.

Oil Chemistry

     Beach samples consisted  of  either  mixed sand  and.gravel frozen in 400 ml
 I-Chem jars  or  cobblestones wrapped in  aluminum foil  and frozen.  The mixed
sand and  gravel  was  thawed  immediately  prior to the initiation of oil

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 analysis,  and  the contents were mixed thoroughly.   A weighted  100  gm  subsample
 was  removed  and  mixed thoroughly with 300 mis of methanol  in a separatory
 funnel.  The slurry was shaken for five minutes, and the methanol  was decanted
 into a  2 L separatory funnel.   The samples were similarly  re-extracted two
 times with 300 ml  of pesticide - or HPLC grade methylene chloride.  The three
 organic fractions were combined and back-extracted  with 100 ml  of  3%  aqueous
 sodium  chloride.   The phases were separated and the aqueous portion was
 extracted  with 50 ml of fresh  methylene chloride.   This aqueous extraction in
 methylene  chloride was added to the combined organic fraction.

      The combined organic fractions and 3 or 4 clean boiling chips were placed
 into a  1 L round  bottom flask  fitted with a three-ball Snyder  column.  The
 volume of  solvent was reduced  until the color was approximately the color of
 dilute weathered  oil  (ca 15 mg/2 ml methylene chloride).   The  final volume of
 the  extract  was measured with  a syringe having an appropriate  graduated
 cylinder,  and  an  aliquot was transferred to a GC autosampler vial.

      All of  the cobblestones were extracted using the same procedure
 (methanol, followed by methylene chloride),  except  that shaking was replaced
 by gentle  swirling to remove oil  from the rock surfaces.

      Gas chromatographic (GC)  analysis was accomplished with an instrument
 capable of reproducible temperature programming with a flame ionization
 detector and a reliable autosampler.  The GC conditions were:

      Column:  DB-5,  30 m X 0.25 mm, film thickness 0.25 urn
      Initial  Temperature:   45»C,   5 min.  hold
      Temperature  Rate:   3.5«C/min
    .  Final Temperature:   280»C,  60 min.  analysis
      Injector:   splitless,  1  min valve closure
      Injector Temperature:  285*C
      Injection:   2.0 01
      Detector:   FID,  350»C

      Those samples  that demonstrated significant evidence  of biodegradation
were  fractionated  to  allow separate determination of aliphatics and aromatics.
Aliquots of the sediment or oil  extracts  selected for fractionation were
 solvent exchanged  to  hexane under a stream of dry nitrogen.  A volume of 50 @1
 of hexamethyl benzene  (80 ng/01)  and 25 31  of n-decyclohexane (1 @g/(?l) was
 added to each  sample  extract prior to fractionation.  The  fractionation was
 accomplished using  a  10 mm X 23 'cm glass  column that was slurry packed (with
 hexane) with 60/200 mesh silica  gel  activated at 210 C for 24  hours.  The
aliphatic  fraction  was eluted  with 30 ml  of hexane  and the aromatic fraction
was  eluted with 45  ml  of hexane/benzene (1:1).  Aliphatic  and  aromatic
 fractions were analyzed using  the GC methods described above.

      Subsamples of  the final concentrated extract were subjected to mass
 spectral analysis  using GC/MS.   The analytical  procedure is given  in Fucus oil
 analysis protocols.

      Subsamples (5-15 ml)  of the  final  concentrated extract were also removed,
 filtered through  sodium sulfate,  and placed  in tared watch glasses.  After

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passive evaporation  of the solvent,  the oil  residue  weight was determined.

     Changes  in  oil  composition  were determined  using  three procedures:

     a.     The  branched  hydrocarbons pristane and phytane were used as
            internal  standards,  under the  assumption that they were slow to
            degrade,  and  weight  ratios of  C17:Pristane and C18:Phytane were
            calculated as indicators of biodegradation.

     b.     The  total  weight  of  all  alkanes, appearing  on the chromatograph,
            normalized to the total  residue  weight of  oil, were compared on a
            sample by  sample  basis.

     c.     Assuming  that hopane and norhopane were  not biodegraded, weight
            ratios with other identifiable hydrocarbons were calculated.

Nutrient Analysis

     Water samples taken  for  nutrient analysis were  filtered (Whatman glass
fiber filter) and then placed in 150 ml  plastic  screw  capped bottles.  The
bottles were  immediately  frozen  with a dry ice-antifreeze solution.  Water
samples taken offshore were collected with a clean bucket and subsamples were
taken for nutrient analysis.   Beach  water  samples were collected behind or in
front of an ebbing or  flooding tide,  a vacuum device capable of withdrawing
intersticial water.  The  sampler was inserted approximately 20 cm into the
mixed sand and gravel  and flushed for one  minute prior to sampling.

     Nutrient concentrations  were determined using the following standard
methods:

Nitrate--                                .    ,    '
     Nitrate was determined by reduction to  nitrite  followed by a colorimetric
assay for nitrite.  The procedure for nitrate was derived from the non-
automated technique.     Detection limits for nitrate and nitrite were
expected to be about 0.05 and 0.01 @M,  respectively.   Estimates of the
precision for the nitrate measurements  were  made at  the 20 @H level in the
samples was calculated as the mean of n determinations ±0.5 (mean/n2)  in @M.

Nitrite--
     Nitrite was determined by the Geiss reaction in an aqueous acidic
solution to form an intensely pink diazo dye with an adsorption maximum at
540-543 nm.

Ammonium--
     Ammonium was determined  by  the  Berthelot reaction by forming indophenol
blue, an intensely blue chromophore  with an  absorption maximum at
approximately 637-640  nm.  The detection limit for ammonium was expected to be
approximately 0.1 @M.12  An estimate of precision at  the 1 @M level  was
calculated as the mean of n determinations ± 0.1 (mean/n2)  in  @M.

Phosphate--
     Orthophosphate was determined as phosphomolybdic  acid,  which has an

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 absorption maximum at 880-885 nm in its reduced form in the presence  of
 antimony.12  The detection limit for phosphate was expected to be about 0.03
 @M.   An estimate of the precision  at the 3 (?M level  was calculated  as  the mean
 of n determinations ± 0.03 (mean/n )  in units  of  @M.

 Total  Kjeldahl  Nitrogen (TKN)--
      TKN was measured by heating the sample in a  sulfuric  acid solution
 containing K2SO, and HgS04 and comparing colorimetrically with  standards  and
 blanks using a  Technicon AutoAnalyzer (EPA method 365.4).

 RESULTS

      The results of the field investigation of nutrient and water movement  in
 a  typical  PWS beach were used to develop conceptual  models  and determine
 potential  effects  on bioremediation efforts in PWS .   Models of  saturated and
 unsaturated zones  of the beach were tested to determine gross circulation
 patterns of the beach.  Oil  composition changes were  used to evaluate  the
 effectiveness of nutrient addition for stimulation of biodegradation.
 Nutrient survey data were used to  follow nutrient movement  through  the body of
.the  beach  and provide estimate of  subsurface conditions and nutrient movement.
 The  first  survey conducted two days after application of fertilizer began
 showed penetration of NH4 at  1.7 to 2.3 meters below the surface  of the
 beach.   No nitrate data have  been  developed as yet for this sample  series.
 The  NH4 data varied between 3.8 and 179 uM depending on sample time and depth.
 Offshore NH4 did not exceed lOuH.   The pond behind the beach yielded NH4
 concentrations  between  0.8 and 35  uM.   The salinities of interstitial water
 varied between  0 and 18 ppt.   Open water salinities  were typically  21ppt or
 higher.  The pattern of salinity data  indicates that the sample wells
 penetrated the  zone of  saline and  fresh water mixing.   The  data present a
 complex picture of water movement  in  the beach subsurface.  Both vertical and
 horizontal  variations  in salinity  were evident^across the tidal cycle.

       The  second nutrient survey was  conducted August 20 and 21, 1989.  Both
 NH4  and N03  data were  available from  this survey.  In most  cases, the N03 was
 greater in concentration than NH4.  In  two cases NH4  exceeded N03
 concentration.   The highest nutrient  concentrations  were associated with the
 lower  salinity  values.   The lowest nutrient concentrations  were associated
 with the highest salinities.   The  offshore samples had nutrient concentra-
 tions  less than 20 uM.   NH4 concentrations varied between 0.4 and 400 uM and
 N03 concentrations varied between  0.4  and 290  uM.  Salinity values  varied
 between 2  and 21 ppt in the well'samples.   The highest salinities were
 recorded   at high  tide  and flood tide.   The lowest values were recorded on ebb
 tide and at  low tide.   With the exception of high tide,  most salinities were
 represented  as  contributions  of about  half seawater  and half freshwater
 indicating a complex vertical  and  horizontal  flow of water  under the beach.

     The third  nutrient survey was  carried out on September 10 and  11, 1989.
 Nutrient analysis  results were incomplete at this writing.  The salinity data
 recorded in  the field during  this  survey were  much lower in general than the
 earlier surveys.   This  observation  reflects an extensive period of  rainfall in
 the two weeks preceding the sample  collection.  Salinities  varied from 800
 uMho to  16ppt in the sample wells.  The field  data for this survey  do not

                                       8       x-             .       '    •'

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 permit  determination of the movement of the interface  of  fresh and salt water.

      Data  collected by the automatic recorders  in  place on KIttiwake beach
 were  also  used  to evaluate the mixing transport of nutrients. Later these data
 will  be used  to evaluated the efficacy of commercially available  models of
 groundwater flow.   The plan was to use the models  to evaluate engineering
 design  of  nutrient  application to beaches.   At this time the two best
 groundwater models have been tested.  Neither model  by  itself was adequate to
 describe the  complete movement of groundwater under the surface of the beach.

      The FEMWATER model13 was used to simulate the response  of the  beach
 groundwater surface elevations to tidal  changes.   Ignoring fluid density
 stratification  as  a first approximation,  simulations based on the point
 iterative  solution technique indicate that tidal inflows can overwhelm the
 freshwater flow near the surface of the  beach and  saltwater is pushed into the
 beach surface from the surface of the bay during late  summer conditions.  The
 depth of saltwater penetration can not be determined with the present models
 but preliminary calculations indicate that penetration of one to two meters
 (horizontal penetration into the beach)  may be  possible during the average
 tidal and  freshwater conditions occurring in August of 1989.  Penetration of
 seawater at the beach surface indicates  that freshwater fluxes are not enough
 to continually  push water through the beach  at  all  times.  However, during ebb
 tides and  at  other times fresh and brackish  water  is pushed out of the beach
 continuously.   These preliminary findings influence our understanding of how
 the beaches were oiled originally and how oil on the surface of the beach may
 continue to move  into the beach subsurface.

     Where effects of fluid density stratification  are expected is in the
magnitude  of  the penetration and the  slope of the  of the water surface under
 the beach  surface  during flood tide.  The  data on hand  do not permit resolution
 of uncertainty  with regard  to these parameters.  For example, less penetration
 than the data indicated may actually  be  occurring  (on  the order of 0.5 to 1.0
m).  The representation of  fluid mechanics is substantiated sufficiently that
 surface  penetration is occurring regularly (once a  tidal cycle except in the
case of  large freshwater flows).   Numerous observations of fairly uniform
oiling to  a depth  of several  feet tend to bear  this out.  As a result, this
offers the possibility to predict how deeply oil penetrated upon initial
oiling but additional  work  will  be necessary to make precise estimates.

     Another model,  SUTRA14, was used to determine  if  it was possible  to gain
limited  information about the density underflow of  saltwater into the beach
below the water surface.  For these calculations,  an idealized domain was
selected and the penetration of the  seawater simulated.  These calculations
are subject to  interpretation,  but at this time it  seems clear that saltwater
does not completely penetrate and underlie the beach.  This is important
because  it indicates  the dimensions of the freshwater lens under the beach.
The volume of this  lens will  influence the residence time of nutrients in the
beach.

   .  The fact that  saltwater penetrates.the  beach as a density underflow
indicates that  dispersed oil  may be pushed into the beach several  meters below
the water surface  and  may collect on  the  substrate  porous media or if
                                           \

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 sufficient  sand  is  present  to  filter the water.  As  of yet there are no
 observations  of  dispersed oil  accumulating  below the intertidal zone. Seawater
 pushed  into the  beach  mixes with  freshwater,  flows upward and moves seaward
 above the intrusion at the  toe of the beach.  There  is no back-flushing action
 of the  same seawater pushing backout the same area that it entered.  In this
 regard,  some  hydraulic pumping different from wave driven pumping is evident
 in these simulations.   Un fortunately,  if there is a filtering effect on
 dispersed oil  by this  pumping  mechanism,  there will  be less opportunity for
 nutrients to  reach  the oil.  Freshwater is  not expected to reach these low
 levels.  Any  nutrients that reach the seawater will  be diluted by mixing over
 the surface of the  embayment (Passage Cove) and will  be diluted to near
 background  concentrations.

     At  this  time,  the models  have ignored  the slope  of the beach face which
 will modify the  results significantly.   The advective nature of tides pushing
 seawater into  the beach on  a flood tide has also not  been fully incorporated.
 These alterations will  change  the upper part  of the  flow but will prevent the
 penetration of the  mixing cell  into the beach.  Density difference appears to
 drive saltwater  into the toe of the beach,  but the depth of this penetration
 is uncertain.

     Based  on  the limited success of the  preliminary  calculations first
 approximation  of the freshwater,  mixing,  and  saltwater regimes in the beach
may be similar to the  conceptual  drawing  in Figure 4.

CONCLUSIONS

 1.    Water movement,  fresh  and salt,  in  PWS  beaches  is very     complex,
     . beyond current model's ability to describe. Modifications of existing
      models or  development  of improved models is necessary.

 2.    Significant nutrient  concentrations were observed at 1.5 and
      2.3 meters depth  in beach well  samples.

 3.    Salinities from  well  samples  varied between those for open water
      and fresh water.  Model simulates  which  mechanisms affects or
      controlled salinities  but these  interpretations are pending.

 4.    There is a definite relationship  between nutrients and salinity
      that  defines  the  degree  of  mixing of nutrients  in the beach.  The
      transport  and mixing  have not been  analyzed, but clearly the spray
      irrigation system 1s  effective in delivering nutrients over the
      complete oiled profile on at  least  two  or three occasions each
      day.   This  provides an  important mechanise to put nutrients deep
      into  the beach where  other  application  awthods may be inef-
      fective.

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                               10              x        .                 -   .

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Biological Methods for Seawater  Analysis. Pergamon Press, Inc., Maxwell
House, Elmsford, New York,  1984.

 13.  G.T. Yeh, FEMWATER: A Finite Element Model of Water Flow Through
Saturated-Unsaturated  Porous Media-First Revision. Oak  Ridge National
Laboratory, Oak Ridge,  TN, pp.  258, 1987.

 14. C. Voss, A Finite-Element Simulation Model for Saturated-
Unsaturated, Fluid-Density-Dependent  Ground-Water Flow  with  Energy
Transport or Chemically Reactive Single-Species Solute  Transport. U.S.
Geological Survey, Reston, VA,  p. 409, 1984.

                               11

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                                                             90-22.5
 Raven
                                                         Guillemot
Figure 1. Schematic diagram of Passage Cove and experimental
          beaches.  Raven,control; Tern, oleophilic and granular;
          Kittiwake, water soluble; and Guillemot, oleophilic
          and granular.
                              -12

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                                                             90-22.5
                   depth
                   gauge



7





3





10



mean high tide

                                                              mean low tide
Figure 2.  Location of Wells for Beach Hydraulics Experiment at Passage Cove

                                   •13

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                                                                                90-22.5
           Strap for removal
       Aanaura sensor lor
       conauctivity ana temperature
3 PVC tubes attached to inside of
casing extending to precise locations
Sensor package rests firmly
on the bottom screen
                                                                    Aandura sensor lor pressure
                                                                    conductivity, and temperature

                                                                    6" diameter
Casing capped with
a screw-on cap
Beach Surface
             Band of screen
             excluding solids
                    Tygon luting lor
                    sample collection
                                                                        Holes or slots in
                                                                        band encircling pipe
                                                                    Screen
 Figure 3.   Cross section, of well  casing  installed in  Kittiwake
               beach.
                                     14

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                                                                   90-22.5
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