FOULING OF FINE PORE DIFFUSED AERATORS:
          AN INTERPLANT COMPARISON
                      by

         C. Robert Baillod and Kevin Hopkins
          Michigan Technological University
            Houghton, Michigan 49931
        Cooperative Agreement No. CR812167
                 Project Officer

               Richard C. Brenner
Water and Hazardous Waste Treatment Research Division
        Risk Reduction Engineering Laboratory
              Cincinnati, Ohio 45268
   RISK REDUCTION ENGINEERING LABORATORY
    OFFICE OF RESEARCH AND DEVELOPMENT
   U.S. ENVIRONMENTAL PROTECTION AGENCY
            CINCINNATI, OHIO 45268

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                                        DISCLAIMER
   Development of the information in this report has been funded in part by the U.S. Environmental
Protection Agency under Cooperative Agreement No. CR812167 by the American Society of Civil
Engineers. The report has been subjected to Agency peer and administrative review and approved for
publication as an EPA document. Mention of trade names or commercial products does not constitute
endorsement or recommendation for use.

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                                          FOREWORD
    Today's rapidly developing and changing technologies and industrial products and practices frequently
carry with them the increased generation of materials that, if improperly dealt with, can threaten both
public health and the environment. The U.S. Environmental Protection Agency (EPA) is'Charged by
Congress with protecting the Nation's land, air, and water resources.  Under a mandate pf national
environmental laws, the Agency strives to                                         :
formulate and  implement actions leading to a compatible balance between human activities and the ability
of natural systems to support and nurture life. These laws direct EPA to perform  research to define our
environmental problems, measure the impacts, and search for solutions.              *

    The Risk Reduction Engineering Laboratory is responsible for planning, implementing, and managing
research, development, and demonstration programs to provide an authoritative, defensible engineering
basis in support of the policies, programs, and regulations of EPA with respect to drinking water,
wastewater, pesticides, toxic substances, solid and hazardous wastes, and Superfund-related activities.
This publication is one of the products of that research and provides a vital communication link between
the researcher and the user community.                                           i

    As part of these activities, an EPA cooperative agreement was awarded to the American Society of
Civil Engineers (ASCE) in 1985 to evaluate the existing data base on fine pore diffused aeration systems
in both clean and process waters, conduct field studies at a number of municipal wastewater treatment
facilities employing fine pore aeration, and prepare a comprehensive design manual on the subject. This
manual, entitled "Design Manual - Fine Pore Aeration Systems," was completed in September 1989 and
is available through EPA's Center for Environmental Research Information, Cincinnati, Ohio 45268 (EPA
Report No. EPA/625-1-89/023).  The field studies, carried out as contracts under the ASCE cooperative
agreement, were designed to produce reliable information on the performance and operational
requirements of fine pore devices under process conditions.  These studies resulted in 16 separate
contractor reports and provided critical input to the design manual.  This report summarizes the results of
one of the 16 field studies.                                                       :
                E. Timothy Oppelt, Director
                Risk Reduction Engineering Laboratory
                                                 in

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                                           PREFACE
    In 1985, the U.S. Environmental Protection Agency funded Cooperative Research Agreement
CR812167 with the American Society of Civil Engineers to evaluate the existing data base on fine pore
diffused aeration systems in both clean and process waters, conduct field studies at a number of
municipal wastewater treatment facilities employing fine pore diffused aeration, and prepare a
comprehensive design manual on the subject. This manual, entitled "Design Manual - Fine  Pore Aeration
Systems," was published in September 1989 (EPA Report No. EPA/725/1-89/023) and js available from
the EPA Center for Environmental Research Information, Cincinnati, OH 45268.      ;

    As part of this project, contracts were awarded under the cooperative research agreement to conduct
16 field studies to provide technical input to the Design Manual. Each of these field studies resulted in a
contractor report. In addition to quality assurance/quality control (QA/QC) data that may be  included in
these reports, comprehensive QA/QC information is contained in the Design Manual. A listing of these
reports is presented below.  All of the reports are available from the National Technical;Information
Service, 5285 Port Royal Road, Springfield, VA 22161 (Telephone: 703-487-4650).

1.     "Fine Pore Diffuser System Evaluation for the Green Bay Metropolitan Sewerage District"
       (EPA/600/R-94/093) by J.J. Marx

2.     "Oxygen Transfer Efficiency Surveys at the Jones Island Treatment  Plants, 1985-1988"
       (EPA/600/R-94/094) by R. Warriner

3.     "Fine Pore Diffuser Fouling:  The Los Angeles Studies" (EPA/600/R-94/095) by; M.K. Stenstrom
       and G. Masutani                                                        j.

4.     "Oxygen Transfer Studies at  the Madison Metropolitan Sewerage District Facilities"
       (EPA/600/R-94/096) by W.C. Boyle, A. Craven, W. Danley, and M. Rieth

5.     "Long Term  Performance Characteristics of Fine Pore Ceramic Diffusers at Monroe, Wisconsin"
       (EPA/600/R-94/097) by D.T.  Redmon, L. Ewing, H. Melcer, and G.V. Ellefson  j

6.     "Case History of Fine Pore Diffuser Retrofit at Ridgewood, New Jersey" (EPA/600/R-94/098) by
       J.A. Mueller and P.O. Saurer                                             [

7.     "Oxygen Transfer Efficiency Surveys at the South Shore Wastewater Treatment Plant, 1985-
       1987'(EPA/600/R-94/099) by R. Warriner

8.      "Fine Pore Diffuser Case History for Frankenmuth, Michigan" (EPA/600/R-94/100) by T.A.
       Allbaugh and S.J. Kang


                                                iv

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9.      "Off-gas Analysis Results and Fine Pore Retrofit Information for Glastonbury, Connecticut"
        (EPA/600/R-94/101) by R.G. Gilbert and R.C. Sullivan                        \

10.     "Off-Gas Analysis Results and Fine Pore Retrofit Case History for Hartford, Connecticut"
        (EPA/600/R-94/105) by R.G. Gilbert and R.C. Sullivan                        !

11.     The Measurement and Control of Fouling  in Fine Pore Diffuser Systems" (EPA/600/R-94/102) by
        E.L Bamhart and M. Collins                                              \

12.     "Fouling of Fine Pore Diffused Aerators: An Interplant Comparison" (EPA/600/R-94/103) by C.R.
        Baillod and K. Hopkins

13.     "Case History Report on Milwaukee Ceramic Plate Aeration Facilities" (EPA/600/R-94/106) by
        L.A. Ernest                                                         '     j

14.     "Survey and Evaluation of Porous Polyethylene Media Fine Bubble Tube and Disk Aerators"
        (EPA/600/R-94/104) by D.H. Houck                                        !

15.     "Investigations into Biofouling Phenomena  in Fine Pore Aeration Devices" (EPA/600/R-94/107) by
        W. Jansen, J.W. Costerton, and H. Melcer                                  !

16.     "Characterization of Clean and Fouled Perforated Membrane Diffusers" (EPA/600/R-94/108) by
        Ewing Engineering Co.

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                                           ABSTRACT
   There has been increasing interest in fine pore aeration systems, along with concern about diffuser
fouling and the subsequent loss of aeration efficiency. The objective of this study was to
assess the
relative fouling tendency of fine bubble diffusers at nine activated sludge treatment plants. A secondary
objective was to relate fouling to mixed liquor and process parameters. A standardized diffuser test
header containing four removable diffusers was installed at each of the participating plants.  Diffusers
were periodically removed and tested for oxygen transfer efficiency (OTE), bubble release vacuum (BRV),
dynamic wet pressure (DWP), foulant accumulation, and increase in OTE after acid cleaning.

   The results of this study showed that an increase in BRV was generally accompanied'by a decrease
in oxygen transfer efficiency, an accumulation of foulant, and an increase in DWP loss through the
diffuser.  The plants were classified according to their degree of fouling (as measured by BRV). The
classifications were:  heavily fouling, moderately fouling, fouling, and lightly fouling. The secondary
objective was to relate fouling tendency to process parameters.  Observations at individual plants
suggested that high organic loads enhanced fouling, although interplant comparison suggested a weak
association between fouling and organic load.                                       i

   This report was submitted in partial fulfillment of Cooperative Agreement No. CR812167 by the
American Society of Civil Engineers under subcontract to Michigan Technological University under the
partial  sponsorship of the U.S. Environmental Protection Agency. The work reported herein was
conducted over the period of 1986-1988.
                                                 VI

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                                              CONTENTS
Foreword	i...	   iii
Preface	   iv
Abstract	   vi
Figures	I	  viii
Tables	i	   ix
Acknowledgments	;	   x

      1.  Introduction	;	   1
      2.  Methods and Approach	',	    2
             Plan of Study	;	    2
             Diffuser Test Header	    2
             Measurements	;	    5
             Coordination	    7
      3.  Plant Descriptions	    8
             Frankenmuth, Michigan	,	    9
             Green Bay, Wisconsin	.;	   10
             Jones Island west Plant, Milwaukee, Wisconsin	   11
             Madison, Wisconsin	   12
             Monroe, Wisconsin	.'	   13
             North Texas, Piano, Texas	;	   14
             Portage Lake, Hancock, Michigan	.j	   14
             South Shore Plant, Milwaukee, Wisconsin	....'	   15
             Whittier Narrows Plant, Los Angeles, California	   16
      4.  Results	  18
             Data Directory	   20
             Diffuser test Header Behavior During Study	;	   20
             Comparative Analysis of Fouling After 12 to 16 Months	.;	   22
             Discussion	  26
      5.  Conclusions	i	  31
         References	  32
         Appendices
             A.  Diffuser Foulant Characteristics	   33
             B.  Influent and Plant Process Conditions During Study	,	   41
             C.  Description of Methods	   45

                                               vii

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                                  FIGURES
Number
                                                                          Page
  1     Sketch of test header and accessories	i	    3
  2     Sketch of test header and pressure monitoring box .  .  .!	    4
  3     Frankenmuth plan sketch of Cells 1-6	  .  .l	    9
  4     Green Bay Plant plan sketch of Tank 4	i	10
  5     Jones Island West Plant plan sketch of Tank 6	i	11
  6     Madison Plant plan sketch of Unit 3 (Tanks  22,  23 and  24)  ....   12
  7     Monroe Plant plan sketch of Tank 2	'.	13
  8     North Texas Plant plan sketch of Tank One	•	14
  9     Portage Lake Plant plan sketch of Unit 2	15
 10     South Shore Plant plan sketch of Tank 9	16
 11     WMttier Narrows Plant plan sketch	i	17
 12     Trends in bubble release vacuum 	'	   21
 13     Trends in dynamic wet pressure	i	23
 14     Relationship between BRV and fouling factor	'.-....   25
 15     Relationship between BRV and SRT	j.  .         27
 16     Relationship between BRV and F/M	'	28
 17     Relationship between BRV and percent volatile  in  foulant   <  .  .  .   29
                                    viu

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                                 TABLES
 1     Characteristics of participating plants ........ .....   8
 2     Frankenmuth Plant process summary ..... ...... '.****   9
 3     Green Bay Plant process summary ............ I.'.*.*.**  10
 4     Jones Island West Plant process summary ........ <..!!!  ll
 5     Madison Plant process summary ............. .  ! ! " '  12
 6     Monroe Plant process summary  ........... !!!!'*'  13
 7     Portage Lake Plant process summary  .  . ........ !  ! ! !    15
 8     South Shore Plant process summary ........... :.  . . . !  is
 9     Whlttier Narrows Plant process summary  ........ '!!!!!  17
10     Portage Lake Plant summary of dlffuser fouling  .  . .  . .      *    19
11     Portage Lake Plant foulant characteristics  ...... .  . ! ! !  19
12     Portage Lake Influent and process characteristics
         during the study  . .  .  .  ...........  . .  . i .....  20
13     Comparison of dlffuser characteristics and plant
         operating data  .  . .............  ....;.....  24
                                    IX

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                               ACKNOWLEDGMENTS                 ;

                                                               !
    Significant effort on the part of the professional staff at the various
wastewater treatment plants examined 1n this study was required' to coordinate
the field studies and to supply operating data.  Contributions of the
following Individuals are gratefully acknowledged: Lee Hauswlrth at the
Portage Lake plant, Michael Plerner, David Schauer, and Jack Boiex at the Green
Bay plant, Paul Nehm at the Madison plant, Read Warrlner at the! Milwaukee
Jones Island and South Shore Plants, Jerry Elllfson at the Monroe Plant, Dan
Geyer at the Frankenmuth Plant, M1ke Stenstrum at the Wh1tt1er Narrows Plant,
and Ed Barnhart at the North Texas Plant.                      ;

    This study utilized dlffuser cleaning data collected by oth^r
Investigators working on the EPA - ASCE Fine Bubble Diffused Aeration Design
Manual Project.  Such data and Information contributed by David; Redmon and
Lloyd Ewlng of Ewlng Engineering and William Boyle of the University of
Wisconsin are gratefully acknowledged.                          <

   This work could not have been completed without the efforts of several
students at Michigan Tech.   The contributions of Janette Lutz and Ronald Mauno
are especially acknowledged.

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                                   SECTION 1                    ;

                                  INTRODUCTION


      The activated sludge process is the most widely used method  for secondary
 wastewater treatment in the United States,  and its popularity is  increasing.
 Provision of oxygen to the active organisms through aeration is'the most .
 energy intensive aspect of activated sludge process operation and consumes  60%
 to 80% of the total energy requirements in  wastewater treatment.   Moreover,
 the performance of the biological  treatment system is intimately  linked  to  the
 proper functioning of the aeration system.
                                                                i

      Contemporary interest in  effective and economical  wastewater treatment
 systems has  resulted in an emphasis  on  more cost-effective aeration systems.
 Fine pore aeration systems,  while  not a new technology,  have the  potential to
 achieve energy savings in wastewater treatment.   One perceived problem with
 these systems is the uncertainty  involved in estimating  their maintenance
 costs.   In operation,  the fine pore  aeration devices can become fouled or
 covered by a  biophysical  foulant  or  slime,  and this condition has been
 associated with severely reduced aeration efficiency (Boyle  and Redmon,  1983).
 (U.S.  Environmental  Protection Agency,  1985).  To  effectively exploit the
 advantages of fine pore diffused aeration equipment,  design  and operating
 engineers need information  not only  on  clean and process  water performance,
 but  also  on fouling tendency and cleaning costs.

      In  recognition of this  need,  the American Society of Civil Engineers
 (ASCE)  and the U.S.  Environmental  Protection Agency (EPA)  entered into a
 cooperative agreement  to  develop design  Information  on fine  pore1  diffused
 aeration.  This  effort Included a  significant emphasis on  plant-scale field
 studies conducted  to fill gaps 1n  knowledge  relative  to  fouling and cleaning
 of fine pore  air diffusers.  One aspect  of  this effort, and  the subject of
 this  report,  was focused  on  comparing the relative  fouling tendencies observed
 at the  various wastewater treatment plants  participating  in  the ASCE-EPA
 project.  The  objective  of this study, therefore,  was to assess the relative
 fouling tendency of fine bubble diffusers at  the participating  activated
 sludge plants.  This information was useful   in interpreting  the hesults of
 other related  studies  being  conducted at  these plants.  A  secondary objective
was to  relate  fouling  to mixed liquor and process parameters.   i

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                                   SECTION 2

                              METHODS AND APPROACH
 PLAN OF STUDY
      The general  approach relied upon Installation  of a  standardized  dlffuser
 test header in each of the nine participating  activated  sludge  plants.
 Properties  of the dlffusers and accumulated  foulant were monitored  over  a
 period of approximately 16 months.   At the same  time,  Information on
 wastewater  and process operating conditions  was  collected.  Comparisons
 between the plants were then made to indicate  the relative  fouliing  tendencies.
 In  addition,  the  data  were examined  for possible association  of fouling
 tendency with wastewater characteristics and process loading  parameters.
 Additional  studies related to  the significance of blofllms  1n the dlffuser
 fouling phenomenon were conducted on the dlffuser test header stones  removed
 at  the 12 to  16 month  interval.   The results of  these  studies are presented
 elsewhere (Costerton,  1988).                                    i
DIFFUSER TEST HEADER                                            i

     A  standardized,  Instrumented and  removable test header containing  four
San1ta1re 0.22 m.  (9  in.) disk diffusers was Installed in each  of the nine
participating activated sludge plants.  The test header was attached to a
removable downcomer,  and Instrumented  so that air flow could belmeasured and
controlled.  Figure 1 shows the test header and Its accessories!  The section
of  the  header feeding Dlffuser 1 was separated from the sect1on:of the header
feeding Dlffusers 2,  3, and 4.  This was because the stone in Dlffuser 1 was
replaced at four month Intervals and was expected to have less  resistance to
air flow than the older stones in the other dlffusers.  Consequently, to
maintain a constant air rate to each dlffuser, the air flow to Diffuser 1 was
independent of the common header feeding Diffusers 2, 3 and 4.  !

     Figure 2 1s a schematic of the pressure monitoring box and,and associated
tubing connected to a single diffuser.  Quick disconnect fittings and valves
were employed so- that selected color coded tubes could be connected to the
pressure monitoring box.   Pressure taps into the header and dlffuser plenums
allowed measurement of the pressure differential across the orifice.   Air flow
was determined from a calibration curve developed for this orifice.    For
example, a pressure differential  of 10 cm.  (4.0 in.) across the orifice
indicated an air flow of 1.7 m3/hr (1.0 cfm) to the diffuser.   The air bubble
pipe terminated at the level of the diffuser so that  pressure drop across the
dlffuser was equal  to the differential pressure between the plenum and the
bubble pipe.  This 1s known as the dynamic  wet pressure (DWP).  i

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     PRESSURE  LINES TO DIFFUSERS:
PURGE LINE
                                                   PRESSURE
                                                   MONITORING
                                                   BOX
                                                    AIR SUPPLY FROM
                                                    EXISTING SOURCE
                 DIFFUSER #2,
                            \
     DIFFUSER  #\    AIR SUPPLY
BUBBLER TUBE


         . DIFFUSER  #3
               .DIFFUSER #4
         Figure  1.   Sketch of  test header and accessories.

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BUBBLER  PIPE
                    O
                    o
                    o
                                           DWP
                                                        o
                                                    AIR TO

                                                    BUBBLE PIPE
                                                       LOW-DOWN
                                         ORIFICE
                                        PLENUM
                                    HEADER
                              PLENUM •'
DIFFUSER
Figure 2.    Sketch of  test header  and  pressure monitoring box,

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      The test headers were  installed so that the dlffusers were at a depth of
 approximately 1.5 m. (5.0 ft.) and at a position in the tank which was
 meaningful for the assessment of fouling.  The prescribed position was at the
 end of the first grid (in a tapered system), or at the quarter point of a plug
 flow tank, or anywhere in a completely mixed tank.  When plant conditions made
 it impractical to install the pilot header at the prescribed position, the
 header was installed closer to the feed point.                  ;


 MEASUREMENTS                                                    '•
                                                                 •
      The diffuser study at each plant was conducted over a period of roughly
 16 months starting from the date of the test header installation.  The study
 period was divided into phases, with each phase approximately four months
 long.   Because of scheduling problems, the length of study at each plant was
 not always 16 months and the phases were not always four months  |in length.

 Air Rates and Pressure Drops                                    i

     Air rates were  controlled at approximately 1.0 scfm per diffuser.   This
 was accomplished by  measuring  and adjusting  the flow rate at weekly intervals.
 At the same time,  the dynamic  wet pressure was recorded.   The procedure  was
 straight-forward and consisted of connecting the appropriate color-coded tubes
 to the pressure  monitoring box,  reading  the  desired pressure differential,
 and, if necessary, adjusting the air flow rate to the  diffuser.  i
                                                                 i

     At the conclusion  of each 4 month phase,  dynamic  wet pressures were
 measured at air  rates of 1.0,  2.0 and  2.5 scfm,  and the  test header was  lifted
 from the tank for  removal  and  characterization of stones.        i

 Diffuser Characterization Schedule                               I

     The diffuser  removal  and  characterization schedule was  designed so  that
 the stones  removed reflected both the  incremental and  cumulative  effects  of
 fouling.  Thus,  at the  conclusion of each  phase  except the first|,  two  stones
 were removed,  one which  had  operated only  the  previous four  months,  and  one
 which  had operated since  the beginning of  the  study.  Normally, a  routine
 characterization was  performed on each stone  removed.  A  special • cleaning
 characterization was  performed on stones  removed  at  the 12 to  16 month
 intervals.  This was  accomplished by the  schedule described  below.

     At  the conclusion of  the  fourth month,  the diffuser  stone in  Position 1
 was removed and  replaced by  a  new stone. The  removed stone was subjected  to a
 routine  laboratory characterization  for dynamic wet pressure  (DWP),  bubble
 release  vacuum (BRV), foulant  analysis, and  flow  profile.    At the  eighth
 month,  the  stone in Position 1 was again  removed  and replaced, and  the stone
 in  Position 2 was removed.   The  Position 2 air outlet was plugged.   A routine
 characterization was  performed on both stones.   At the twelfth month, the
 diffuser in Position  1 was again  removed and  replaced, and the stone in
 position 3 was removed and the outlet was plugged.  A routine characterization
was normally performed on both removed stones.   Finally, at the;sixteenth
month,  the stones in  Positions 1  and 4 were  removed.  A special cleaning

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 characterization was performed on these stones.   This consisted of a routine
 characterization for DWP, BRV, flow profile,  and foulant analysis plus
 measurement of oxygen transfer efficiency before and after acid cleaning the
 stone.   Certain stones removed at the 12 to 16 month periods  were also studied
 to explore the influence of biofilm formation on fouling (Costerton, 1988)

 Routine Diffuser Characterization                              ',
                                         - ,                      i
      A  routine diffuser characterization included the following;

    Foulant Analysis:   This consisted of scraping the foulant  off  the
    surface and analyzing for the weight of dry solids per unit  area, volatile
    and  non-volatile  content, and acid solubility.               i

    Bubble  Release Vacuum:   This  was measured  by  applying a vacuum to a point
    on the  working surface of a thoroughly wetted diffuser stone!and  measuring
    the   vacuum required to withdraw bubbles at the  specified  flux rate from
    the  point  in question.   A large  number of  points  were sampled  to  obtain a
    distribution of BRV values and these were  averaged to obtain the  BRV values
    reported in this  study.   The  BRV parameter is sensitive to the the
    effective  pore diameter at any point on the surface of the stone.

    Dynamic Wet Pressure:   The dynamic wet pressure  (DWP)  test measured the*
    pressure differential  across  the diffusers while  operating 1n  a   submerged
    condition.   The DWP was  measured in  situ during operation  of'the  test
    header  as  well  as  in the laboratory  during characterization.    Normally,
    the  DWP was reported at  air rates  of 1  and 2  SCFM.  However, some of the
    DWP  tests  were reported  at other air rates, and this  required  interpolation
    to obtain  the  DWP  corresponding  to the  1 and  2 SCFM.

    Gas  Flow Profile:   The  gas flow  profile  test  measured  the  rate of air
    captured in three  concentric  circular areas centered  over  the  diffuser
    stone.   This was used  to quantitate  the  uniformity  of  air  release  across
    the  surface of the  stone.                                    ;

     Details  of the routine  diffuser  characterization  procedure are given in
Appendix   C.   Normally,  this  characterization was performed under the general
supervision of William C. Boyle at  the  University of Wisconsin.

Special  Cleaning  Characterization.                              j

    Diffusers  from the  fourth  phase  of the  study were subjected to a  special
cleaning characterization.   This  consisted of a  routine characterization plus
laboratory  OTE measurement  in  clean water before and after cleaning.  Cleaning
was accomplished  by hosing,  acid application,  and hosing  (Milwaukee Method).
In addition, the  foulant ash was analyzed for elemental composition by energy
dispersive  spectroscopy.  Details of  this characterization are described in
Appendix  C.   Normally, this  characterization  was performed undeV the
supervision of David Redmon at the  Ewing Engineering Laboratoryiin Milwaukee.

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 Plant Operating  Data.                                           !

 Throughout  the study, operating data were collected by personnel at each
 participating plant.  This  Information  Included  Influent and primary effluent
 wastewater  characteristics, final effluent characteristics, and process
 information such as food/microorganism  ratio, and sludge age.   !


 COORDINATION                                                    \
                                                                I

     The diffuser. test header was installed at the participating plants as
 part; of other studies supported by the ASCE-EPA Fine Bubble Diffused Aeration
 Design Project.  The investigators responsible for the various s'tudies were
 responsible for collection of the test header operating data and for removal
and shipment of the stones for characterization.  C. Robert BaiVlod of
Michigan Technological  University was responsible for coordinating the
diffuser test header studies and compiling and analyzing the data obtained
from the various  plants.                                         l

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                                 SECTION 3                     ,
                                                               i
                             PLANT DESCRIPTIONS

     Nine municipal activated sludge plants participated in the interplant
fouling comparison.  Table I lists the plants along with the wastewater
characteristics and typical operating conditions.  The data from certain
plants, such as Green Bay, and Madison were more complete than the data from
other plants such as Whittier Narrows and North Texas.  Appendix B summarizes
the wastewater characteristics and operating conditions experienced at each
plant during the fouling study.                                !

Plant
Frankenmuth
Green Bay '
Jones Island
Madison
Monroe
North Texas
Portage Lake
South Shore
Whittier
Narrows
TABLE 1.
Average
Flow *
(MGD)
1.47
40.0
58.9
13.2
2.2
14.0
2.3
98.0
12.5
CHARACTERISTICS
Annual
BODS *
(mg/L)
:====== = =
652
375
278
87
418
100
150
100
96
SRT
(d)
15.9
2.5
4.0
11.0
8.0
10.0
10.0
7.9
2.3
OF PARTICIPATING PLANTS
Process
Configuration
= s ss a: s =s= s ss =3 ==a ss =2=
CS
CS
C
C
SF
SF
CS
SF
C
* Flow and BODS values are for primary effluent except
used fine screening and Portage Lake, which used only
CS =• Contact Stabilization C = Conventional SF =
** 1 MGD = 3785 mVd
IndustM.
% Flow
45
30
11
6
17
NA
< 5
6
NA
==========
for Jones
course scr
Step Feec


Jl Contribution
% BOD8
71
50
38
38
50
NA
< 5
18
NA
5SSS








Island, which
•eening.

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FRANKENMUTH, MICHIGAN
     This 5,560 m'/d  (1.47 MGD) contact stabilization  plant Includes four
aeration tanks, or  cells.   The plant receives a  substantial  Industrial load
consisting primarily  of brewery waste.  The plant  recycles  effluent from an
anaerobic dlgestor  and filtrate from vacuum filters  into  the primary
sedimentation  tanks.   Table 2 summarizes the wastewater characteristics, and
Figure 3 shows a  plan view of the aeration tanks.

                  TABLE 2.   FRANKENMUTH PLANT PROCESS SUMMARY
Location: Frankenmuth,  Michigan
Average Primary  Effluent Characteristics:
     Dally Flow:   5,560 rnVd (1.47 MGD)
     BOD8:  652  mg/L
     TSS:  310 mg/L
     NHS:  10.9  mg/1      pH:  7.0
     Temperature:  20 °C
Major Industrial Contributors:   brewery and restaurants
     Fraction of Flow:   0.45
     Fraction of BOD8:   0.71
Primary Treatment:  sedimentation
Typical SRT:  15 days
Tank Dimensions  (each cell,  L x W x D)
                                13.4 m  (94  ft)  x  6.7 m (22 ft)
                                x 5.01 m  (16.4  ft)
j RAS
          Primary
         Effluent
-»
->

CEL
CEL
-\
L 2
L I
/



CEL
/
CEL
/
L 3
\
L 4
\
CELL 6
CELL 5
/S
                                             Mixed Liquor
                                             
-------
GREEN BAY, WISCONSIN                                              ,•

     This plant  consists of 4 parallel  contact stabilization processes,  each
of which Includes  an aeration and reaeratlon tank.  The plant ha|s  a  thermal
sludge conditioning system and recycles the thermal sludge conditioning  liquor
to the activated sludge process.  Filtrate  from the sludge filters 1s also
recycled to  the  activated sludge process.   Typical wastewater and  process
characteristics  are given 1n Table 3.   Figure 4 1s a plan view of  the contact
and reaeratlon tanks of quadrant 4 showing  the location of the dlffuser  test
header.                                                            I

                   TABLE 3.  GREEN BAY  PLANT PROCESS SUMMARY      j

Location: Green  Bay, Wisconsin                                    ' .
Average Combined Influent Characteristics *:
     Daily Flow:  151,000 mVd (40 MGD)
     BOD8:   375  mg/L
     TSS:  224 mg/L
     NH9:  26 mg/L
     pH:  7.0
     Temperature:   25 °C
Thermal Sludge Conditioning Liquor and Sludge Filtrate:
     Average Daily Flow:  1,890 m3/d  (0.5 MGD)
     Average BOD8:  7000 mg/L
     Average TSS:   3400 mg/L
Major Industrial Contributors: paper mills
     Fraction of Flow:  0.30
     Fraction of BOD,:  0.50
Primary Treatment:  sedimentation
Typical SRT: 2.5 days
Tank Dimensions  (L x W x D):  74 m  (245 ft) x 22 m  (74 ft) x 6.4 m (21 ft)
3j3IMaiMaiWaim«B3::BMMMMMMai:m«aMMV« »aM3B»at«« 3S»aiaiSB«»»«»"«i««»»««
* Primary effluent and mill waste.                                !
       Primary  \J/.
      Effluent-
                           REAERATIDN TANK 4
                             AERATION TANK 4
                                        New
                                        location
                                                       RAS
Mixed Liquor

-------
JONIES ISLAND WEST PLANT, MILWAUKEE, WISCONSIN                  i

     The Jones Island West Plant Includes 2 batteries of 12 aeration tanks
each located north and south of the secondary clarlflers.   Each tank consists
of two passes.  The test header was Installed 1n the first pass ;of Tank 6.
Screened sewage 1s combined with recycled sludge before 1t flows  Into the
aeration tanks.  The plant recycles vacuum filter filtrate and scrubber water
from dryers back Into  the activated sludge process.  Characteristics of the
combined recycle flows and plant Influent are listed 1n Table 4.;   Figure 5
shows a plan view of Tank 6.                                   I


              TABLE 4.  JONES ISLAND WEST PLANT PROCESS SUMMARY
^9(g3BMM:3VIB3B3S33MaRVmMMMnMMMMMMHMMSMBMMHMM9M3iMXfl
Location:  Milwaukee, Wisconsin
Average Screened Influent Characteristics *:
     Dally Flow:  222,940 mVd (58.9 MGD)
     BOD9:  278 mg/L
     TSS:  232 mg/L
     TKN:  32 mg/L
     pH:  7.3
     Temperature:  18 °C
Major Industrial Contributors:  breweries, food processors, tanneries
     Fraction of Flow:  0.11
     Fraction of BODS:  0.38
Primary Treatment:  fine screening
Typical SRT:  4 days
Tank Dimensions (each pass, L x W x D):  67.7 m (222 ft) x 6.7 m (22 ft)
                                         x 4.6 m (15 ft)

 * Includes recycle flows
      Mixed  Liquor
     (-to  clarlfler)

       Mixed  Liquor



| 
-------
MADISON, WISCONSIN  .                                            j
                                                                i
     This  151,000 m*/d  (40  MGD)  activated sludge plant 1s divided Into two
sub-plants, East and West.   The  West Plant,  1n turn, 1s divided Into Units 3
and 4.  Each unit Includes  1 three-pass  aeration tank, and the test header was
placed 1n  the first pass  (labeled  Tank 24)  of Unit 3.   The plant normally runs
at a relatively high SRT  and produces a  nitrified effluent.  Table 4 lists
some of the plants Influent and  process  characteristics prior tp the test
header Installation, and  Figure  5  1s a plan  view of the Unit 3.;
                   TABLE  5.  MADISON PLANT PROCESS SUMMARY,
Location:  Madison, Wisconsin
Average Primary Effluent Characteristics:
     Dally Flow (West Plant):   50,000 m*/d  (13.2 MGD)
     BOD9:  87 mg/L
     TSS:  67 mg/L
     NH,:  15 mg/L
     pH:  7.8
                   16 °C
     Temperature
Major Industrial Contributors
     Fraction of Flow:  0.06
     Fraction of BOD8:  0.15
Primary Treatment: sedimentation
Typical SRT:  11 days
Tank Dimensions (each pass, L x W x  D)
                               meat  and  cheese processors
                                          80.8  m (265 ft)  x 9.2 m (30 ft)
                                          x  5.1 m (16.7  ft)
                                       Approximate location of test iheader
     Primary
    Effluent
             t
             RAS
                             POOOI
                                         TANK 24
                     £
                                         TANK 23
                                         TANK 22
                                                                ^1 Mixed
                                                                : Liquor
                                                                ;
-------
MONROE, WISCONSIN

     This  is an 8,330 m*/d (2.2 MGD) plant that Includes an aerated  in-line
equalization basin  between the primary clarlflers and the aerat1:on tanks.  The
equalization basin  was  1n  operation during most of the study.  T,here are 3
two-pass aeration tanks, and  the test header was Installed at the end of the
first pass  In Tank  2.   Influent 1s fed step-wise along the first pass.  The
plant receives a significant  Industrial  load consisting primarily of soluble
cheese processing and brewing wastes.  Characteristics of total waste load 1s
given in Table 6 and a  plan view of the aeration basin which contained the
test header is given in Figure 7.
                    TABLE  6.   MONROE PLANT PROCESS SUMMARY
Location:  Monroe, Wisconsin                                     !
Average Raw Influent Characteristics:                            I
     Dally Flow:  8,330 m'/d  (2.2 MGD)
     BOOB:  418 mg/L
     TSS:  212 mg/L
     TKN or NHS:  NA
     pH :  NA
     Temperature:  NA                                            ;
Major Industrial Contributors:   breweries and dairy and food processors
     Fraction of Flow:  0.17                                     '.
     Fraction of BOD8:  0.50                                     i
Primary Treatment:  sedimentation plus  aerated, In-line flow equalization
Typical SRT:  8 days
Tank Dimensions (each pass, L x  W x D):   31.1 m (102 ft) x 7.6 m (25 ft)
                                          x 3.9 m (12.8 ft)
   Mixed Liquor
  
-------
 NORTH TEXAS PLANT, PLANO, TEXAS                                i

      This 53,000 m'/d (14 MGD) treatment plant 1s located near Piano,  Texas
 and: 1s a combined trickling filter and activated sludge plant. !Lack of
 Information on the division of flow between the trickling filter and activated
 sludge portions of the plant hampered Interpretation  of the  plant operating
 data.  Figure 7 shows a plan view of the tank containing the test header.
                            RAS
       Mixed  Liquor
       (to clarlfier)
                  c
                  cu
                  3
                  £
                  Q-
                  Ld
                  £

                  Q_
                                                   TANK #1
                                                Catwalk
Approximate
location of
test  header
Figure 8.  North Texas Plant plan sketch of Tank One.            i


PORTAGE LAKE PLANT, HANCOCK, MICHIGAN                           '
                                                                i
     This contact stabilization plant consists of two  separate circular
modular units, each of which includes a contact tank,  reaeratloni tank,
clarlfier, and aerobic sludge dlgestor.  Both units were 1n operation during
the study.  This plant receives a relatively low strength and low temperature
influent, with almost no Industrial  contribution to the  waste load.   Table  7
summarizes typical  Influent and process conditions for the plant; and Figure 9
is a plan view of Unit 2, which contained the test header.      i
                                       14

-------
                  TABLE 7.  PORTAGE LAKE PLANT  PROCESS SUMMARY
Location:   Hancock,  Michigan
Average  Raw Influent Characteristics:
      Dally  Flow:   8,700 mVd (2.3 MGD)
      BOD,:   150 mg/L
      TSS:   110  mg/1
      NH3 or TKN:   NA
      pH:  7.4
      Temperature:   16 °C
Major Industrial  Contributors:  none
Primary  Treatment:  coarse screening and preaeratlon
Fraction of Flow  Treated by Aeration Basin Studied:   0.50
Typical  SRT: 10 days
Tank  Dimensions:   Diameter of Clar1f1er: 11.9 m  (39  ft)
                   Diameter each unit: 30 m (98.4  ft)
                   Depth: 4.6 m (15 ft)
                Primary
               Effluent
      Approximate location
      of test header
                          Activated
                          Sludge ft- VAS
                                      WAS
Secondary
Effluent
                                                      Aeration Tank Volunei 340 n3
Figure 9.  Portage  Lake  Plant plan sketch of Unit 2.
SOUTH SHORE PLANT, MILWAUKEE,  WISCONSIN                          i

     This plant has  28 single-pass aeration tanks.  Primary  effluent is fed at
the head and step-wise along both sides of each tank.  The test header was
located in Tank 9, approximately 27 m. (90 ft.) from the  head  of;the tank.
Typical primary effluent and process characteristics are  given lij Table 8, and
Figure 10 shows a plan view of Tank 9.                           i
                                        15

-------
                  TABLE 8.  SOUTH SHORE PLANT PROCESS SUMMARY
 Location:   Milwaukee,  Wisconsin                                 i
 Average Primary Effluent Characteristics:                       •
      Dally Flow:   371,000 mVd (98 MGD)                         \
      BODS:   100 mg/L
      TSS:   72 mg/L
      TKN:   29 mg-N/L                                            j
      pH:   7.7                                    -             •  i
      Temperature:   15  °C                                        ;
 Major Industrial Contributors:  glue processors, food processors, and machine
 industries                                                       \
      Fraction of Flow:   0.06                                    ;
      Fraction of BODS:   0.18
 Primary Treatment:   sedimentation                               i
 Typical SRT:   7.9  days                                           j
 Tank  Dimensions (each  pass,  L  x W x D):  113 m (370 ft) x 9.1 m (30 ft)
                                          4.6 m (15 ft)           I
    Primary
   Effluent
           t
           RAS
Primary
Effluent
1
Primary
Effluent

/^BBBO TANK * 4
/ t
t

                   ; Mixed
                   i Liquor
                   ; 
-------
               TABLE 9.  WHITTIER NARROWS PLANT PROCESS SUMMARY
Location:  Los Angeles, California
Average Primary Effluent Characteristics:
     Dally Flow:  47,300 mVd (12.5 MGD)
     BOD,:  96 mg/L
     TSS:  95 mg/1
     NH3 or TKN:  NA
     pH:  NA
     Temperature:  25 °C
Major Industrial Contributors: NA
Primary Treatment: sedimentation
Typical SRT:  2.5 days
Primary . .
Effluent /
\
r— >
^
s*
Tank
Tank
Tank
fff*m
3
2
1 ,
^ Mixed Liquor
— ... ^> ^ J.Q j-^pif jer)
^ '
	 	 	 DA
-------
                                  SECTION 4

                                   RESULTS
DATA DIRECTORY
     The reduced data are presented 1n three tables for each participating
plant.  These tables are titled:                                i

    IPlarvt Name) Summary of Dlffuser Fouling                    i
                                                                i
    These tables 11st the date,  elapsed time (time the characterized stone
    resided in the tank), field  and laboratory DWP, laboratory BRY,  flow
    profile (fraction of air flow collected in outer annular are'a),  and
    fouling factor (SOTE of a fouled stone divided by the SOTE of a  new
    stone).  Table 10 is a summary of diffuser fouling for the Portage Lake
    Plant and is given here for  illustration.   Corresponding tables  for the
    other participating plants are given in Appendix A (Tables Al, A3, A5, A7,
    A9,  All,  and A13).                                          i
                                                                i

    (Plant Name) Foulant Characteristics

    These tables list the date,  elapsed time (time the characterized stone
    resided in the tank), dry foulant accumulation expressed as mg/sq.cm,
    percent ash in the dry foulant,  percent of the ash which wasi solubilized
    by hydrochloric add, and percentages  of silicon,  calcium,  and iron
    measured  in the ash during a cleaning  characterization.   Table 11  shows
    the  foulant characteristics  for  the Portage Lake  Plant and  1s given  here
    for  illustration.   Corresponding tables for the other participating  plants
    are  given  in Appendix A (Tables  A2,  A4,  A6, A8, A10, A12,  and A14).

    (Plant  Name)  Influent and Process  Characteristics  During thei Study

    These  tables begin with the  date and elapsed time  followed  by Influent and
    process characteristics.   Table  12  shows the influent and process
    characteristics  for the Portage  Lake Plant.  In these tables; the  elapsed
    time  refers  to  the Incremental time  prior  to the  listed  date.  In  Table
    12,  for example,  the  date  1/14/87  appears with  elapsed timesiof  4.0  and
    8.4 months.   The  influent  and  process data listed  for the 4.0 month
    elapsed time  pertain  to the  incremental 4.0 month  period preceding
    'L/14/87.   Likewise,  the data  listed  for the 8.4 month elapsed time pertain
    to the  cumulative  8.4 month  period preceding 1/14/87.  The  cumulative
    period  spans  the  time between  the beginning of  the  study and!the listed
    date.  Corresponding  tables  for  the other participating  plants are given
                                                                i
                                      18                        '

-------
 in Appendix B (Tables Bl, 82,  B3,  B4,  B5, B6, and B7).     '.





       TABLE 10.  PORTAGE LAKE  PLANT  SUMMARY OF DIFFUSER FOULING


DATE
=============
NEW DIFFUSER
9/10/86
1/14/87
1/14/87
5/21/87
5/21/87
8/3/87
ELAPSED
TIME

MONTHS
=============
0.0
4.4
4.0
8.4
4.2
12.7
15.2
FLD OWP
1n
111
9 1 SCFM 9
=============
5.0
5.5
6.0
7.6
9.0
12.0
8.0
LAB DWP,

1 SCFM 9
============
5.0
8.9
6.5
7.5
6.4
7.5
NA
1n

2 SCFM
:======:
5.6
10.5
9.0
9.5
9.4
9.6
NA
DDW
DKV
In
========
5.3
14.8
13.5
18.3
13.0
19.9
18.1
FLOW ;
DDAC TIC
PROFILE
OUT/TOT
i
==33S3SS— 333=2
0.80 '•
0.50
0.70 :
0.80
0.70
0.90
NA :
FOULING
t A/^TrtQ
FACTOR

.============
NA
NA
NA
NA
NA
0.833
NA
TEST HEADER INSTALLED: APRIL 29, 1986
      TABLE  11.   PORTAGE LAKE PLANT FOULANT  CHARACTERISTICS
DATE
NEW DIFFUSER
9/10/86
1/14/87
1/14/87
5/21/87
5/21/87
8/3/87
ELAPSED
TIME
MONTHS
0.0
4.4
4.0
8.4
4.2
12.7
15.2
MG/SQ.CM
0
22
NIL
4
3
2
NA
% ASH
NA
85
NA
78
88
65
NA
% Ac SOL ASH
NA
NA
NA
9.7
15.0
13.8
NA
%Si ASH
NA
NA
NA
NA
NA
16.4
NA
!
%Ca ASH
NA
:NA
NA
;NA
NA
'3.5
NA
%Fe ASH
NA
NA
NA
NA
NA
13.4
NA
                                     19

-------
TABLE 12.  PORTAGE LAKE  INFLUENT  AND PROCESS CHARACTERISTICS DURING THE STUDY

                             RAW INFLUENT                    PROCESS CONDITIONS
DATE
9/10/86
1/14/87
1/14/87
5/21/87
5/21/87
8/3/87

ELAPSED
TIME (mo)
4.4
4.0
8.4
4.2
12.7
15.2

FLOW
(MGD)
0.89
1.20
1.05
1.16
1.08
1.08

BOD,
(mg/L)
122
155
139
166
148
144

TSS
(mg/L)
107
109
108
120
112
112

BOD
Loading
(lb/1000
75.5
129.2
101.1
133.6
111.1
108.0

TSS pH
Loading
ft»-d)
66.2 7.4
91.1 7.4
78.7 7.4
96.8 7.6
84.3 7.4
84.3 7.4

MLVSS
1028
1463
1246
1964
1485
1514

SRT
(d)
7.7
9.4
8.5
8.7
8.6
8.5

F/M
i
0.23
0.28
0.25
0.22
0.24
0.24

DO
(mg/L)
3.5
3.0
3.2
** 3.0
** 3.2
** 2.9

TEMP
(C)
17
16
16
12
15
15

  TEST HEADER INSTALLED ON APRIL 29,1986
    * Unit 2 only
   ** DO measurements were not taken from April  9 - June 14, 1987.
  *** 1 MOD = 3785 m*/d
 DIFFUSER  TEST HEADER BEHAVIOR DURING STUDY

 Bubble Release Vacuum Trends                                     \
                                                                 •  i

      BRV  data for the participating plants are plotted versus  time  in  Figure
 12.  A general  upward trend 1s evident for the more heavily  fouljing plants
 such as Jones Island and Frankenmuth, whereas a relatively constant pattern 1s
 shown for the more lightly fouling plants such as Madison and  Monroe.   The
 data suggest  that the pl-ants can be grouped as follows:          !

     Heavily Fouling Plants:  Jones Island and Frankenmuth.       •
     BRV values  increased rapidly to more than 100 cm (40 1n) of  water  by the
     12th  month.  These plants also tended to show high foulant  accumulation
     with  Jones  Island accumulating over 150 mg/cm2 1n 13.6 months and
     Frankenmuth  accumulating 95 mg/cm2 in 5.3 months.
                                                                   i
     Moderately  Fouling Plants:  Green Bay, North Texas, and  Whittier Narrows.
     BRV values  increased gradually but perceptibly to more than  50  cm  (20 In)
     of water  by  the 12th month.

     Fouling Plants:  South Shore and Portage Lake.
     BRV values  increased somewhat but to less than 50 cm (20 in) of water by
     the 12th  month.   Foulant accumulations were less than 25 mg/cm2  over 12
     months                                                        ;
                                         20

-------

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-------
     Lightly Fouling Plants:  Madison and Monroe.
     BRV values Increased to about 25 cm (10 1n) of water and then remained
     relatively constant.  Foulant accumulations were variable but generally
     less than 10 mg/cma over 12 months.

 Dyn6im1 c Wet Pressure Trends                                     I

      Dynamic wet pressure (DWP) data are plotted 1n Figure  13.  A general
 upward  trend is suggested with the plants judged to be more susceptible to
 fouling generally showing higher values for DWP.  The exception to this
 observation is the Jones Island plant which exhibited an average DWP  even
 though  1t was shown to be an extremely fouling plant by BRV and foul ant
 accumulation.

 Cumulative Versus Incremental  Fouling                           |

      The schedule of dlffuser removal  and characterization  was  planned  so  that
 incremental  fouling over four month periods might be distinguished from
 cumulative fouling over the entire study period.  Consequently,  many  data
 points  are shown at the four month time period in Figures 12 and 13.  These
 represent the various stones removed from Position 1 on the test header at
 four  month intervals.   Based on these  limited  data,  no consistent seasonal or
 incremental  trend is evident.   Hence,  more attention was focusedi on the stones
 1n  the  fouled condition after  a cumulative period of 12 to  16 months.
                                                                 i

 COMPARATIVE  ANALYSIS OF FOULING AFTER  12 TO 16 MONTHS           !

      Table 13 is  derived  from  the  Tables in Appendices  A and B  and compares
 the characteristics  of  the  fouled  diffusers after an  elapsed time  of
 approximately 12  to  16  months  along  with selected plant operating  parameters
 during  the elapsed  time period.  Since  this was  a relatively uncontrolled
 study,  care  must  be  used  in  Inferring  cause and  effect  relationships  from
 these data.   Nevertheless,  it  1s useful  to  examine these data for  reasonable
 associations.                                                    i
                                                                 i
 Relationship between  Fouling Factor  and  BRV                     |

     Figure  14 shows  the  relationship between  BRV and  fouling factor, computed
 from SOTE measurements made on  clean and  fouled  stones.  SeveraliSOTE
measurements were also made on  stones after  add  cleaning and,  in  nearly all
 cases,  the stones were  restored  to within 5% of  the SOTE for a new  stone.

     Figure  14 shows that the fouling factor 1s  reasonably well  correlated
with BRV  (correlation coefficient -.- 0.88).  This is understandable as it was
shown earlier that the plants which  accumulated  the most foulant!had the
highest BRV  values.  The heavily fouling and moderately fouling plants showed
fouling factors ranging from about 0.55  to 0.74 whereas the  fouling and
lightly fouling plants showed fouling factors  ranging from 0.83 to 0.99.
Based upon these data and reasoning, BRV can be accepted as a measure of
fouling.                                                         i


                                       22                        !

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 Relationship between BRV and Loading Parameters                i
                                                                i

      It 1s interesting to explore the association between fouling,  as measured
 by BRV, and activated sludge loading, as  measured by the Food/Ml'cro-organism
 ratio (F/M) or solids retention time (SRT).   Here,  F/M 1s expressed as mass  of
 5 day BOD fed/day per unit mass of mixed  liquor volatile suspended  solids
 (MLVSS),  and SRT is determined as the mass of MLVSS 1n Inventory!  divided by
 the mass  of MLVSS wasted per day.  Figure 15  shows  the relationship between
 BRV and SRT, and Figure 16 shows the corresponding  relationship between BRV
 and F/M.   In each case, an understandable association  1s weakly suggested  by
 the lines of best fit.   However, the correlation coefficients  are low (-0.52
 for BRV vs.  SRT,  and 0.24 for BRV vs. F/M).   In both associations,  the Jones
 Island and Frankenmuth  plants appear to behave differently than the other
 plants.   The DWP/BRV ratio given in Table 13  also Indicates different dlffuser
 behavior  at the  Jones Island and Frankenmuth  plants.   Both the DWP  and BRV
 tests measure bubble release pressure, and for a new stone the average DWP/BRV
 ratio will  be close to  1.0.   As the stone becomes fouled,  this ratio  will  be
 less than 1.0.   The DWP/BRV ratio for the Jones Island and Frankenmuth plants
 at  12 months are  0.13 and 0.33,  respectfully.   These are the lowest ratios
 among the nine plants studied,  thus supporting the  conclusion  that  these are
 the heavily fouling plants.                                     ,

 Relationship between BRV and Percent Volatlles In Foulant       !

      Figure  17 explores the  relationship  between  BRV and percent  volatile
 solids  (100% - ash%)  in the  foul ant.   Based on these data,  1t  appears that
 foulant high  in  inorganic as.h  and low 1n  organics 1s conducive to deleterious
 fouling.   It  appears  that a  foulant low 1n organics  Is  a necessary, but not
 sufficient  condition  for deleterious  fouling.
                                                                i

 DISCUSSION        ,                                              i

      The  reasons  for  the  robust  fouling observed  at  the Jones  Island  and
 Frankenmuth plants  are  not entirely  clear.  A  possible  contributing factor is
 that  Jones  Island was receiving  an  undetermined amount  of additional waste
activated  sludge  by  tank  truck  from  the South  Shore plant.  Th1s!could have
provided  inorganic  partlculates  to  the foulant matrix.  The Frankenmuth waste
contained the highest BOD5 concentration  (652 mg/1, much of which 1s  soluble)
and  industrial contribution  (71%  of BODB)  of the participating plants, and
this appears  to have  stimulated  fouling.  Another possible contributing factor
was the location of the  test headers at the head of the tanks.   Both Jones
Island and Frankenmuth  had their  test headers placed, within a few meters of
the Inlet.  The combination of the each plant's waste characteristics and
locating the  headers at  the tank  inlets may have contributed to the heavy
diffuser fouling.                                               \

     Previous studies (EPA, 1985)(Reith, 1985) have observed severe fouling
problems at the Madison and Monroe plants.  Yet, in this interplant
comparison, both plants showed only light  fouling tendencies.   Likely
contributing factors to the lessened fouling  tendency at Monroe are  the
incorporation of aerated  In-line equalization and the addition  of ammonia  to

                                       26

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improve the nutrient balance.  The aerated equalization basin following
primary, treatment greatly reduced the soluble BODB load on the lactivated
sludge process (Baillod, 1988).  Earlier fouling at the Madison plant appears
to have been associated with heavy loadings of dairy waste.    !
                                      30

-------
                                   SECTION  5

                                  CONCLUSIONS
     The  objective  of  this  study was  to assess  the  relative fouling tendency
 of  fine bubble  dlffusers at nine municipal activated sludge planits
 participating in  comprehensive  studies related  to fouling and cleaning of fine
 bubble diffusers.   The  results  showed that an Increase  in average bubble
 release vacuum  (BRV) was generally accompanied  by a decrease in ioxygen
 transfer  efficiency, an accumulation of foulant, and an  increase 1n the
 dynamic wet pressure (DWP)  loss through the diffuser.  Based on ithese results,
 the participating plants were classified as:                    I
                                                                i           •
 Heavily Fouling :   Jones Island West and Frankenmuth, characterized by BRV
 values increasing to more than  100 cm (40 in) of water and foulant
 accumulation greater than 100 mg/cm2 over period of one year,   i

 Moderately Fouling;  Green  Bay, North Texas, and Whittier Narrows,
 characterized by BRV values  increasing to more  than 50 cm (20 1ri) of water
 over one year.                                                  !
                                                                i
 Fouling;  South Shore and Portage Lake, characterized by BRV values
 increasing to less  than 50  cm (20 1n) of water and foulant accumulations less
 than 25 mg/cm2 over one year.                                .   .

 Lightly Fouling;  Madison and Monroe, characterized by BRV values increasing
 to about 25 cm (10  in)  of water and remaining relatively constant along with
 foulant accumulations generally less than 10 mg/cm2 over one year.

     A secondary objective was to relate fouling tendency to process
parameters.  Observations at individual  plants suggested that high organic
 loads enhance fouling.   However, interplant comparisons suggested a weak
association between fouling and organic load.  Thus, it appears that other
plant and waste specific factors in addition to organic load also Influence
fouling.                                                         ;
                                       31

-------
                                  REFERENCES

Boyle, W.C. and D.T. Redmon, "Biological Fouling of Fine Bubble Dlffusers:
State-of-Art", Jour. Env. Engr. Div. ASCE, 109(5):991-1005, 1983.

U.S. Environmental Protection Agency, "Summary Report:  Fine Pore (Fine
Bubble) Aeration Systems", EPA/625/8-85/010, 1985.

Costerton, J.W., "Investigations into Biofouling Phenomena 1n Fine Pore
Aeration Devices", Draft Report Submitted to ASCE/EPA Fine Pore^Aeration
Project Committee, Cooperative Agreement No. 812167, March, 1988.

Dan'ly, W.B., "Biological Fouling of Fine Bubble Dlffusers - Phase I", M.S.
Independent Study Report, Civil and Environmental Engineering Department,
University of Wisconsin, Madison, 1984.                         \

Reith, M.G., "Effects of Biological  Fouling on the Oxygen Transfer Efficiency
of Fine Bubble Diffusers", M.S. Thesis, University of Wisconsin-Madison, 1985.

BaiUlod, C.R., "Oxygen Utilization in Activated Sludge Plants:   Simulation and
Model Calibration", Final Report, U.S. Environmental Protection Agency, Water
Engineering Research Laboratory, Cooperative Agreement CR813162-01-2, 1988.
                                       32

-------
                                    APPENDIX A

                       DIFFUSER  FOULANT CHARACTERISTICS


                  TABLE Al.   FRANKENMUTH PLANT SUMMARY OF DIFFUSER FOULING !
                ELAPSED    FLD  DWP        LAB DWP,  1n               FLOW       FOULING
                 TIME        1n	_     BRV   PROFILE !     FACTOR
  DATE          MONTHS    0 1 SCFM    @ 1 SCFM  @ 2 SCFM       1n   OUT/TOT i
 10/7/87         5.3         NA          17.3      27.1      20.2    0.50  '        NA

 5/20/88        12.8         NA          19.0      42.0      57.3     NA   '      0.737

TEST HEADER INSTALLED:  APRIL 28,   1987


                                                                         i
                  TABLE A2.   FRANKENMUTH PLANT FOULANT CHARACTERISTICS
                  ELAPSED
                  TIME                                                   i
 °ATE             MONTHS   MG/SQ.CM   % ASH  % Ac SOL ASH   %S1 ASH   %Ca  ASH   %Fe ASH

10/7/87         •  5.3        95        95        32.0        21.0      4J8       8.6

5/20/88           12.8        96        89         NA          NA         NA        NA
                                         33

-------
TABLE A3.   GREEN BAY PLANT SUMMARY OF DIFFUSER FOULING
— — 'saasiataisasa
DATE
10/18/86
2/24/87
2/24/87
6/19/87
6/19/87
8/3/87
10/27/87
10/27/87
TEST HEADER

==============

DATE
10/18/86
2/24/87
2/24/87
(5/19/87
(5/19/87
8/3/87
10/27/87
ELAPSED
TIME
MONTHS
4.6
4.1
8.8
3.9
12.6
14.0
4.2
2.8
INSTALLED JUN
TABLE
ELAPSED
TIME
MONTHS
4.6
4.1
8.8
3.9
12.6
14.0
4.2
FLD DWP
In
III
@ 1 SCFM
NA
5.5
11.5
12.5
25.0
14.5
9.0
5.5
IE 1, 1986
A4. GREEN
===========

MG/SQ.CM
13
10
63
NA
NA
30
33
LAB DWP, 1n . FLOW
® 1 SCFM ® 2 SCFM In OUT/TOT
10.1 14.0 15.0 0.53 !
10.5 13.3 16.5 0.48 ;
11.0 17.7 20.0 0.54 :
NA NA NA NA i
NA NA NA NA |
15.0 34.0 24'.8 NA :
15.8 22.7 13.9 0.64 |
NA NA NA NA i
i
BAY PLANT FOULANT CHARACTERISTICS \
==========================3=================

% ASH % Ac SOL ASH %S1 ASH %Ca ASH
90 14.0 11.6 17.8
88 49.0 8.7 17.9
88 51.0 4.9 16.4
NA NA NA NA
NA NA NA NA
92 37.6 NA fjlA
94 29.0 13.1 12.6
FOULING
FACTOR
NA
NA
NA
NA
NA
0.714
NA
NA


=========

%Fe ASH
6.7
6.7
6.2
NA
NA
NA
8.4
                       34

-------
               TABLETS.  JONES ISLAND WEST PLANT SUMMARY OF DIFFUSER  FOULING
 DATE

10/20/86

3/6/87

3/6/87

8/5/87
                 ELAPSED    FLD DWP        LAB DWP,  1n
                  TIME        1n       	
                 MONTHS    @ 1 SCFM    @ 1  SCFM  @ 2 SCFM
                  4.1

                  4.5

                  8.5

                 13.6
           14.1

           24.0

           23.4

           NA
             13.0

             10.8

             8.7

             10.0
            26.9

            20.3

            16.9

            19.8
                                                   FLOW  |
                                           BRV   PROFILE
                                             In   OUT/TOT
                                                   FOULING
                                                   FACTOR
           19.0    0.78  :         NA

           34.9    0.65  ]         NA

           43.0    0.79           NA

           75.7     NA         0.555
TEST HEADER  INSTALLED: JUNE 18, 1986
                 TABLE A6.  JONES ISLAND WEST PLANT FOULANT CHARACTERISTICS
 DATE
ELAPSED
 TIME                                                    ;
MONTHS   MG/SQ.CM   % ASH   % Ac SOL ASH   %S1 ASH   %Ca ASH   %Fe ASH
10/20/86

3/6/87

3/6/87

8/5/87
 4.1

 4.5

 8.5

13.6
100

 26

107

152
90

86

87

86
 4.0

33.1

21.6

 NA
                                                              14.9

                                                              18.0

                                                              11.7

                                                              9.3
io.i

111. 9

 7.8
 i
 8.1
 7.3

 6.6

 9.3

14.2
                                            35

-------
TABLE A7.  MADISON PLANT SUMMARY OF DIFFUSER FOULING


DATE
1/14/87
4/23/87

4/23/87
8/6/87
8/6/87
TEST HEADER


DATE
1/14/87
4/23/87
4/23/87
8/6/87
8/6/87
ELAPSED
TIME
MONTHS
4.7
3.3

7.9
4.0
12.0
FLD DWP
1n
@ 1 SCFM
3.2
5.2

9.8
NA
NA
LAB DWP, 1n


@ 1 SCFM 9 2 SCFM
5.7 6.7
5.4 6.1

8.6 11.3
NA NA
6.2 8.0
FLOW ! FOULING
BRV PROFILE FACTOR
1n OUT/TOT
12.4 0.50 \ NA
7.7 0.55 ! NA
. i
9.3 0.53 i NA
8.4 NA : NA
9.3 NA 0.989
INSTALLED: AUGUST 25, 1986 |
i
TABLE
ELAPSED
TIME
MONTHS
4.7
3.3
7.9
4.0
12.0
A8. MADISON

MG/SQ.CM !
7
5
8
NA
7
PLANT FOULANT CHARACTERISTICS :
' «

1 ASH % Ac SOL ASH
50 41.5
58 39.4
56 41.7
NA NA
48 NA

%S1 ASH %Ca|ASH %Fe ASH
10.3 16.3 4.2
5.3 11.9 2.7
11.1 9.6 2.6
i
NA NA NA
NA NA NA
                       36

-------
                    TABLE A9. MONROE PLANT SUMMARY OF DIFFUSER FOULING



DATE
12/4/86
3/9/87
3/9/87
7/10/87
:=========i:s==:3=
ELAPSED
TIME

MONTHS
4.5
3.5
8.0
12.0
FLD DWP
1n

@ 1 SCFM
NA
NA
NA
NA
LAB DWP


@ 1 SCFM @
7.2
5.2
6.5
6.9
, In


2 SCFM
8.2
6.6
8.8
8.1

QD I/

1n
8.1
7.8
8.2
9.3
FLOW '

PROFILE!
OUT/TOT;
NA ;
NA
NA j
NA
FOULING

FACTOR

NA
NA
NA
0.976
TEST HEADER INSTALLED: JULY 9, 1986
                    TABLE A10.   MONROE PLANT FOULANT CHARACTERISTICS


DATE
12/4/86
3/9/87
3/9/87
7/10/87
ELAPSED
TIME
MONTHS
4.5
3.5
8.0
12.0


MG/SQ.CM
50
13
81
2.6


% ASH
75
45
73
45


% Ac SOL ASH
NA
NA
NA
NA


%S1 ASH
NA
NA
NA
NA
l

%Ca !ASH
HA
NA
NA
NA
«

%Fe ASH
NA
NA
NA
NA
                                            37

-------
               , TABLE All. NORTH TEXAS PLANT SUMMARY OF DIFFUSER FOULING



DATE
5/12/86
7/86
11/86
7/87
7/87
ELAPSED
TIME

MONTHS
4.4
7
11
3
18
FLD DWP
In

9 1 SCFM
NA
NA
NA
NA
NA
LAB DWP,


« 1 SCFM 0
11.0
11.9
12.4
8.7
37.0
1n


2 SCFM
14.0
13.7
15.8
9.1
40.5

QDW

1n
27.4
14.3
21.4
9.5
40.7
FLOW '<

KKUr IL&
OUT/TOT,
0.7
0.6
0.6 i
0.6
0.5
FOULING

FACTOR

NA
NA
NA
NA
NA
TEST HEADER INSTALLED:  DECEMBER 30,  1985
                 TABLE A12.   NORTH TEXAS  PLANT  FOULANT CHARACTERISTICS
ELAPSED

DATE
5/12/86
7/86
11/86
7/87
7/87
TIME
MONTHS
4.4
7
11
3
18

MG/SQ.CM
42
8
29
0.2
18

% ASH
95
94
96
77
88

% Ac SOL
NA
20.0
9.5
NA
40.3

ASH %S1 ASH
NA
20.4
20.7
11.7
22.8

%Ca ASH
NA
19.2
16.8
I
8.3
0.5

%Fe ASH
NA
3.3
3.5
2.1
2.3
                                          38

-------
TABLE A13.  SOUTH SHORE PLANT SUMMARY OF DIFFUSER FOULING
DATE
10/21/86
3/6/87
3/6/87
8/5/87
TEST HEADER

DATE
10/21/86
3/6/87
3/6/87
8/5/87
ELAPSED FLD DWP LAB DWP, In FLOW1 FOULING
MONTHS @ 1 SCFM ® 1 SCFM @ 2 SCFM In OUT/TOT
4-3 7.6 7.6 9.0 10.2 0.21 ! NA
I
4.5 9.8 10.1 12.5 12.3 0.65! NA
8.8 11.9 10.6 14.1 19.6 0.63 NA
13.7 NA 11.5 16.0 18.0 NA 0.994
INSTALLED: JUNE 13, 1986
I
TABLE A14. SOUTH SHORE PLANT FOULANT CHARACTERISTICS \
ELAPSED
TIME
MONTHS MG/SQ.CM % ASH % Ac SOL ASH %S1 ASH %Ca| ASH %Fe ASH
4.3 6 87 NA 10.9 10.0 10.2
4-5 5 86 50.0 10.6 11.8 9.9
8-8 7 67 44.0 7.8 8.3 8.1
13.7 23 76 NA 4.7 10.2 1.3
                          39

-------
                TABLE_A15.  WHITTIER NARROWS PLANT SUMMARY OF DIFFUSER FOULING
                  ELAPSED    FLD DWP        LAB DWP, 1n                FLOW !      FOULING
                   TIME        1n       	     BRV   PROFILED      FACTOR
    DATE          MONTHS    9 1 SCFM    9 1 SCFM  9 2 SCFM      1n   OUT/TOT
  ====================================================3==»=«»=======s======3=aaa==,i-=a=-==.«=
   6/28/88        * 9.6         NA         12.1      21.9       25.0     NA  :       0.896
 TEST HEADER  INSTALLED:  AUGUST 22,  1986
 * Data  Is for a dlffuser stone Installed on 9/9/87
                TABLE A16.  WHITTIER  NARROWS  PLANT  FOULANT CHARACTERISTICS
                   ELAPSED
                    TIME
  DATE             MONTHS   MG/SQ.CM   % ASH   % Ac SOL ASH   SI  ASH    %Ca ASH   %Fe ASH
6/28/87             9.6        NA        NA          NA           NA         NA
NA
                                            40

-------
                                        APPENDIX B

                INFLUENT AND PLANT PROCESS CONDITIONS DURING STUDY



          TABLE 81.  FRANKENMUTH  INFLUENT AND PROCESS CHARACTERISTICS  DURING THE STUDY
                                                                           I

                              PRIMARY EFFLUENT                      PROCESS^ CONDITIONS
DATE


10/7/87
*5/20/88
ELAPSED
TIME (mo)

5.0
12.8
FLOW
(MGD)

1.36
1.38
BOD,
(mg/L)

653
526
TSS
(mg/L)

322
253
BOD TSS
Loading Loading
(lb/1000 ft»-d)
116.7 57.4
95.5 46.2
PH


6.4
6.9
MLVSS
(mg/L)

4877
4720
SRT
(d)

23.6
21.8
F/M
(1/d)

0;29
0.24
DO
(mg/L)

0.97
1.03
TEMP
(C)

26.8
22.0
 TEST HEADER INSTALLED ON APRIL 28, 1987
 *Est1mated
        TABLE B2.  JONES ISLAND INFLUENT AND PROCESS CHARACTERISTICS DURING THE STUDY
                              PRIMARY  EFFLUENT
                                                                    PROCESS CONDITIONS
DATE ELAPSED
TIME (mo)

10/20/86 4.1
3/6/87 4.5
3/6/87 8.5
8/5/87 *13.6
FLOW
(MGD)

4.65
4.60
3.83
3.74
BOD,
(mg/L)

220
208
245
253
TSS
(mg/L)

NA
NA
NA
NA
BOD
Loading
(lb/1000
58.1
54.3
53.5
53.8
TSS
Loading
ft'-d)
NA
NA
NA
NA
PH


7.7-6.9
7.7-6.8
9.4-6.8
9.4-6.8
MLVSS
(mg/L)

1470
1443
1653
1636
SRT
(d)

3.4
3.4
3.7
3.6
! F/M
(1/d)

0.64
0.61
0.52
io.53
DO
(mg/L)

0.6
1.6
1.2
0.9
TEMP '
(C)

19.8
14.2
16.7
17.0
TEST HEADER  INSTALLED ON JUNE 18,  1986
                                              41

-------
            TABLE B3.  GREEN BAY  INFLUENT AND PROCESS CHARACTERISTICS DURING THE!STUDY


                         COMBINED MILL WASTE AND 'PRIMARY EFFLUENT        PROCESS  CONDITIONS
DATE ELAPSED
TIME (mo)

10/18/86 4.6
2/24/87 4.1
2/24/87 8.8
6/19/87 3.9
6/19/87 12.6
8/3/87 14.0
10/27/87 4.2
FLOW
(MGD)

18.8
14.3
16.4
14.2
15.7
15.5
13.5
BOD,
(mg/L)

396
467
433
402
424
417
371
TSS
(mg/L)

220
242
228
224
227
223
167
BOD
Loading
(lb/1000
168.6
151.1
160.4
129.2
150.4
146.1 '
113.6
' TSS
Loading
ft'-d)
93.6
78.6
84.9
71.8
80.5
78.0
51.2
pH


7.1
7.2
7.2
NA
7.2
7.2
6.9
MLVSS
(mg/L)

1881
2320
2174
1890
2060
2003
1513
SRT
(d)

2.7
3.1
2.9
3.1
3.0
3.1
3.8
F/M
(1/d)
:
0.53
0.47
i
0.51
0.46
0.49
0.48
0.38
DO
(mg/L)

ISSSS3S
1.6
2.2
1.9
2.2
2.0
2.0
2.0
TEMP
(C)

28
20
24
23
24
24
28
 TEST HEADER INSTALLED ON JUNE 1,  1986                                         ;
  *  pH data was not available for June  and July of  1986 and March, May, June and October of
      1987.                                                                     :
 **  MLVSS was  only measured one day out of each month during the study (1 to 3 samples per
      sample day).   Data  was not available for June, July and August of 1986.
           TABLE B4.  MADISON  INFLUENT AND PROCESS CHARACTERISTICS DURING THE STUDY
                               PRIMARY EFFLUENT
                                                                    PROCESS CONDITIONS
 =========
DATE


====3l = = =
1/14/87
4/23/87
4/23787
8/6/87
8/6/87
ELAPSED
TIME (mo)

= ======33=
FLOW
(MGD)

=*====: ====s====aj===
4.7
3.3
7.9
3.0
11.0
11.6
10.7
11.3
10.8
11.2
BOD,
(mg/L)

=«==S5SJ
83
83
90
99
92
TSS
(mg/L)

=======
67
67
67
68
67
===555====:
BOD
Loading
TSS pH
Loading
(lb/1000 fts-d)
a=s_0==!_==
20.0
18.7
21.2
22.5
21.2
MLVSS
(mg/L)

==.====.==== ====== ====&—
16.2 *
15.0 *
15.6 *
15.6 *
15.6 *
1851
1944
1895
1641
1826
SRT
(d)


18.5
18.5
18.5
15.8
17.7
F/M
(1/d)


0.11
0.11
0.11
0.14
0.12
DO
(mg/L)


**
**
**
**
**
TEMP
(C)


18
14
16
20
17
TEST HEADER INSTALLED ON AUGUST 25,  1986
 * Average pH during the study was 7.6 (range:  7.4-7.7)
** Average DO during the study was 2.0 mg/L (range:  0.7-4.9 mg/L)
                                               42

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              TABLE 85.   MONROE INFLUENT AND PROCESS CHARACTERISTICS  DURING  THE STUDY

                            EQUILIZATION BASIN EFFLUENT                  PROCESS CONDITIONS
E ELAPSED
TIME (mo)

FLOW
(MGD)

BOD, TSS
(mg/L) (mg/L)

BOD
Loading
(lb/1000
TSS
Loading
ft'-d)
PH


                                                                  MLVSS  SRT    F/M    DO   TEMP
                                                                  (mg/L)  (d)  ; (1/d)  (mg/L)  (C)
121/4/86
3/9/87
3/9/87
7/10/87
4.5
3.5
8.0
12.0
2.30
2.35
2.17
2.17
**290
**285
**283
273
104
103
120
140
85.5
85.5
78.6
75.5
30.6
30.9
33.3
38.9
8.9-6.9
8.8-7.0
8.9-7.2
9.0-7.2
1230
1150
1281
1361
6.3
5.8
- 7.5
7.4
\ 0.38
j 0.42
0.35
; 0.32
2.8 19/23
2.7 18/22
*3.4 *15/19
*3.7 *16/20
 TEST HEADER  INSTALLED ON JULY 9, 1986
 * DO and temperature data was not available for February, March, and April of |l987.
 ** Primary effluent                                                           !
 SRT's were estimated.
           TABLE 86.  SOUTH SHORE INFLUENT AND PROCESS CHARACTERISTICS DURING THE STUDY
                               PRIMARY EFFLUENT
                                                                       PROCESS CONDITIONS
DATE   ELAPSED
      TIME (mo)
 FLOW   BOD,
(MGD)
 TSS     BOD      TSS
(mg/L) Loading  Loading
        (lb/1000 ft"-d)
                                                            PH
 MLVSS  SRT :  F/M    DO   TEMP
(mg/L)  (d) ;(l/d) (mg/L)   (C)
10/21/86
3/13/87
3/15/87
8/15/87
4.3
4.5
8.8
*13.7
6.00
6.20
5.51
5.69
74
77
90
90
NA
NA
NA
NA
22.5
23.7
25.0
25.8
NA
NA
NA
NA
7.9-7.6
7.9-7.6
8.1-7.4
8.1-6.8
1164 6.1
1165 6.0
1207 6.1
1140 5.8
i0.31
|0.33
!0.33
;0.36
1.3
0.9
1.1
1.1
18.4
13.4
15.9
15.9
TEST HEADER INSTALLED ON JUNE 13,  1986
                                               43

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      TABLE 87.  WHITTIER NARROWS INFLUENT AND PROCESS CHARACTERISTICS DURING THE STUDY
                               PRIMARY EFFLUENT
                                                                       PROCESS CONDITIONS
  DATE   ELAPSED
        TIME (mo)
 FLOW   BOD.    TSS     BOD       TSS    pH
(mVd) (mg/L)  (mg/L)  Loading    Loading
                      (lb/1000  ft'-d)
 MLVSS  SRT    F/M    DO   TEMP
(mg/L)  (d)   (1/d)  (mg/L)   (C)
 1/1/87      9.6    4.54   97    95    28.7     28.1      NA    682   2.2   0.67   2.0    24.4
TEST HEADER INSTALLED ON AUGUST 22,  1987
                                              44

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                                  APPENDIX C
                            DESCRIPTION OF METHODS
FOULANT ANALYSIS
     An Important aspect of the characterization of the fouled cMffusers was
the analysis of the nature of the foulant on the dlffuser.  Theiprocedure for
foulant analysis 1s given below:
       1.  Specify a certain area on the surface of a dlffuser disc.
       2.  Scrape the materials off the surface, divide and put them  Into two
          vials«                                               '
                                                               i
       3.  Place each vial's contents 1n a tared evaporation dish.
       4.  Measure the wet weight.
       5.  Dry at 105°C for > 1 hour (To constant weight).       ',
       6.  Cool,  desiccate, and  weigh for total  solids.           \
       7.  Put the dishes  into  furnace,  firing  them at  550°C fori20
          minutes.                                              ,
       8.  Cool,  desiccate  and  weigh  the  dishes  for fixed solids.'
       9.  Take one dish content  for metallic 1on analysis.  Place 1n a
          vial.                                                 i
     10. Add approximately  10 ml of 14% HC1 to  the other dish and stir
         gently  until the formation of gas bubbles ceases.
     11. Centrifuge the solution at 20,000 rpm  for 15 minutes. Decant
         the upper portion, add deionized water into the tube centrifuge
         again and decant. Repeat once more for a total of thre;e decants.
     12. Repeat the steps 5, 6, and 9 using the centrlfuged solids.
         Compare the results with those of the non-acidified foulant.
                                     45

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 BUBBLE RELEASE VACUUM

      The bubble release vacuum,  as Indicated by the name,  1s a measure of the
 vacuum 1n Inches of water gauge, required to emit bubbles  from a localized
 point on the surface of a thoroughly wetted porous dlffuser element.  The  test
 provides a means of determining  the effective pore diameter at any point  on
 the surface of a ceramic dlffuser, and is an Important  measure 6f the relative
 fouling among plants.   The test  apparatus consists of a probe, manometer,
 vacuum source, and rotameter as  shown 1n  Figure C.I.            j

      A brief description of the  BRV testing procedure is llsted'below.  Danly
 (1984) more thoroughly describes the test procedure.            I

      1.   If the dlffuser 1s new, immerse  1t 1n tap water until  wetted.
          Remove from water just  prior to  test and let drain by gravity  for not
          more than 30  minutes.   Keep diffuser in a horizontal  plain while
          draining.  Do not soak  fouled dlffusers.
                                                                I
      2.   Set BRV flow  rate.                                     !

      3.   Apply probe to BRV test location.   The water surface  will  rise 1n
          the probe while bubbles are released at the dlffuser  surface.  If the
          water level becomes  too high,  discard excess water by a  quick  lateral
          and upward movement  of  the  probe.   If water level  1s  too low, apply
          additional  water onto the dlffuser adjacent to  the probe.  This  1s
          especially useful  when  testing fouled dlffusers.

      4.   Equilibrium has been reached  when  the rate of  rise of water  in the
          probe equals  the rate of  rise  1n  the  manometer  (inches ;water gauge).
          If  time  to reach equilibrium  is  excessive, it may  be  reduced by
          operating the  by-pass valve momentarily.  The  flux rate  increases
          dramatically when  the by-pass valve  1s  open.  The  large  suction
          force will  pull  foulant off a dirty  dlffuser.   Because Ithe loss of
          foulant may effect test results, the  by-pass valve  should be used
          judiciously.                                           :
                                                                i
                                                                i
      5.   At  equilibrium,  read and  record  the manometer reading and the height
          of water  in the  probe.  BRV equals  the manometer reading less the
          height of water  1n the probe.                          !

      6.   Repeat steps 3  through 5  for all  test  locations.
                                                                i

DYNAMIC WET PRESSURE                                            i
                                                                i

     The dynamic wet pressure, DWP, 1s the pressure differentials across the
diffusion element when operating in a submerged condition,  and is expressed in
inches of water gauge.    In the dynamic wet pressure test, most of the pressure
differential is due to the force or pressure required to form bubbles against
the force of surface tension and only a small fraction of the total pressure
gradient  is required to overcome frictlonal resistance.          |
                                      46

-------
     DWP and BRV test both measure bubble release pressure.  DWP measures 1t
for the whole dlffuser while BRV gives a distribution of pressure. For a new
stone, the average DWP/BRV ratio 1s close to 1.0.  As a stone fouls, the
average BRV for the 12 points tested on the top surface becomes greater than
DWP.  The average DWP/BRV ratio becomes less than 1.0.         '

    Laboratory DWP was measured each time a stone was removed from the test
header.  The equipment required for measuring DWP 1n the lab Includes an air
source, rotameter, In-line mercury manometer, thermometer, dlffuser plenum
with standard orifice, water-filled manometer and aquarium.  The test set-up
looks very much like Figure C.2 without manometer A and the bubbler.  The
water-filled manometer (manometer B 1n Figure C.2) 1s tapped Into the plenum
at one end and open to atmosphere at the other end.   The water »1n the aquarium
1s high enough so the dlffuser was covered with water.         i

     The following 1s a brief description of the DWP test.  Consult Danly
(1984) for more Information on the test.

     1.  The aquarium should be filled with tap water so there will be
         several  cm.  (1n.) of water over the dlffuser.  If this 1s done the
         day before testing,  the water will  warm to  room temperature.

     2.  New diffusers should be wetted the same as  for the BRV test.  Do ndt
         soak fouled  dlffusers.

     3.  Place dlffuser securely 1n plenum.

     4.  Hold plenum  over aquarium and turn  air on.   This  allows water
         entrained  1n  the dlffuser to  drain  into the tank  and not on the
         floor.   If the dlffuser 1s fouled,  do  not turn air flow any higher
         than its  operating  air  flow rate.                      \

     5.   Place plenum  in  aquarium.   Adjust  air  flow  to minimum suggested rate
         of  0.85 mVhr/dome  (0.5 scfm/dome).  Visually inspect the flow
         profile.   If  the dlffuser is  not mounted  correctly,  coarse bubbling
         will  be  evident.   If this  is  the case,  take plenum outiof the
         aquarium and  reseat  the dlffuser.                      '

     6.   Adjust air flow  to maximum allowable rate for the  test'being
         time  for excess  water to be driven  out  of stone.   When'testing  fouled
         diffusers, dp not exceed the  operating  air  flow rate.  !
                                                               i
     7.   Perform a  DWP profile.   This  is done by checking DWP  at  three or
        more air flows.   Typical air  flows  are  36.6,  73.2,  109i7,  146.3-
        m'/hr/m"  (2,  4,  6, and  8 scfm/ft2).  A  bucket  catch may  be  performed
         to  check air  flow rate.   In line pressure and  temperature  readings
        are  taken  so  air  flow rates can be  translated  to standard  conditions.

    8.  After the  last DWP reading, turn the air flow  to almost  zero.
        Measure the static head  over  the dlffuser.   The static ihead is
        subtracted from DWP manometer  readings  to give  true DWP|  readings.


                                     47                        :      .

-------
I
-j
BRV
PROBE
   DIFFUSER
                 BY-PASS  _ VALVE
                         •o-
                MANOMETER
                                                    CO
                                                      VACUUM
                                                      SOURCE
                                          ROTAMETER
          Figure C.I.   BRV  test apparatus.
                                           AIR  SOURCE
  ~\ '  •  •   •
   V'    '  -. '  '
   \   •••'...
                                              AIR FLOW CONTROL
                                                  :( ORIFICE
                     HEADER
Figure C.2.   Laboratory DWP  test apparatus.
                          48

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      9.   Correct  air  flow  data  to  standard conditions.  Regress DWP  (y) on
          air flow (x).   The  correlation  coefficient  should be close  to 1.0.


 GAS  FLOW PROFILE  TEST                                          ;

      The gas flow profile  test  uses quantitative techniques to evaluate the
 uniformity  of air release  across the surface of ceramic dlffusers, while
 operating,  rather than appraising  uniformity by visual means.  This  1s
 accomplished by testing  the  element at an air rate which 1s approximately
 equal  to 36.6 mVhr/ma (2.0  scfm/ft2), or at the recommended design  rate, with
 anywhere from 5.1 - 20.3 cm.  (2 -  8 1n.) of water over 1t.      i

      The rate of  air  release  from  selected areas 1s measured by Displacing
 water from  an inverted container and recording the rate of displacement of
 water with  a stopwatch.  By  combining the container area and the rate of air
 discharge,  a flux rate,  expressed  as m3/hr/m2, or other convenient units, can
 be calculated.  By comparing  the flux rate of the selected area ;read1ngs with
 one  another,  a quantitative measure or graphical representation of the profile
 can  be generated.

      Flux rate Is  determined  by measuring the displacement of water by the
 rising gas  stream from a vessel Inverted over the diffuser.  The vessel must
 first  be filled with water, covered and deftly Inverted so that the mouth of
 the  vessel  1s just submerged.   Captured gas volume 1s measured over a time of
 a few  seconds taking care  so  that  the captured volume 1s recorded at
 atmospheric  pressure, i.e. equal water surface levels Inside and outside of
 the  Inverted  vessel.  The  flow  rate 1s determined by dividing the captured
 volume by the time Interval.  The  flux rate Is defined as flow rate divided by
 the  area of  the capture  vessel.  A flow profile for a typical  diffuser
 requires flow measurements on each of three concentric circles as shown 1n
 Figure C.3.   Flow  rates  for the annular areas are determined by difference.
                                                                i
     These measurements are made by using three vessels,  each with a different
 surface  capture area.  The large,  13.5 liter vessel  captures the entire flow.
 The  two  liter vessel captures all but the periphery flow,  whereas the 1000 ml
 graduated cylinder captures the flow around the washer.   By subtraction,  flux
 rates are obtained for the outer, middle and Inner areas  of the diffuser.
 These  flux rates are then compared to the average flux rate for the diffuser.


 HOSE-ACID-HOSE CLEANING  (MILWAUKEE METHOD)                       ;

     This method has been used at the Milwaukee wastewater treatment plants
 for many years.   A high pressure water jet  1s applied to  the diffuser surface
 followed by acid spraying and hosing.   The  rationale is  to first hose off  the
easily removable foulant  so that the applied acid can solubH1ze; the inorganic
precipitate inside the pores of the diffuser.  A second  hosing 1s then
performed to remove the solubilized foulant and residual  acid.    The materials
 needed for this  method are:  high or low pressure water  hosing equipment,  add
 spray applicator  (Hudson  Add Sprayer or equivalent)  and  50% by volume of  18

                                                                i •
                                      49

-------
   1000 ml GRADUATED
   CYLINDER
Figure  C.3.  Diffuser  air flow  profile
                      50

-------
Baume Inhibited  muriatic add. This 1s equivalent to a 14% HC1  solution.  The
procedure 1s given  below:
                                                              i
     1.   Clean dlffuser by high pressure or low pressure hosing'with the air
         on  at approximately 1.7 mVhr (1 cfm) per dlffuser.    ;

     2.   Apply approximately 50 ml of 14% HC1  to the surface of; the dlffuser
         using the  spray applicator.  No air should be applied to the dlffuser
         during  the add application period.

     3.   Let add remain on the dlffuser for 30 minutes.  Turn air on 5
         minutes.                                              :

     4.   Hose the dlffuser again for one minute or so  to  remove all  the
         residual add.
                                   51

-------