United States Environmental Protection Agency Hazardous Waste Engineering Research Laboratory Cincinnati OH 45268 Research and Development EPA/600/S2-87/003 Apr. 1987 &EPA Project Summary Use of Lined Pits for Disposal of Dilute Pesticide Waste George R. Bierman and Narinder P. S. Malik Modern agricultural practices rely heavily on the use of pesticides to sus- tain high productivity. When pesticide containers and application equipment are rinsed after use, the contaminated water requires proper disposal. At Iowa State University in Ames, Iowa, dilute pesticide rinsates have been placed in a concrete-lined pit for more than ten years. The pit contains alternating lay- ers of gravel and soil. Water evaporates from the pit surface while pesticide chemicals are adsorbed on soil parti- cles, destroyed by microorganisms or broken down chemically. Monitoring for atmospheric and ground-water con- tamination at the pit site has indicated no detectable release of pesticides to the surrounding air or water. This type of disposal facility may be appropriate for pesticide users generating 10,000 gallons or less of dilute pesticide waste annually. This report includes a review of the design criteria for lined pesticide pits and descriptions of pits currently in use around the nation. These facilities are all similar with variations in use of soil and gravel within the pit and the addi- tion of high density polyethylene liners to protect ground water from possible leakage of pit contents. Guidelines for proper siting and operation of the pit are also given. This Project Summary was devel- oped by EPA's Hazardous Waste Engi- neering Research Laboratory, Cincin- nati, OH, to announce key findings of the research project that is fully docu- mented in a separate report of the same title (see Project Report ordering infor- mation at back). Introduction The pesticide disposal facility on which the full report is based was devel- oped in the 1960s at the Horticulture De- partment of Iowa State University in Ames, Iowa. The system, called simply a "pesticide disposal pit" by its develop- ers, was created to provide a safe alter- native to the practice of disposing of waste pesticide solutions by indiscrimi- nately dumping them on unused fields or field fringes. The pits were intended to be particularly useful to farmers who generate relatively small quantities of waste pesticide solutions at any given time and for those who use a variety of pesticides on different crops. A demon- stration facility was built at Iowa State University in 1970 and has been in con- tinuous use since then. No major oper- ating nor pollution problems have oc- curred at the demonstration pit. A detailed technical report on the Iowa State Facility entitled Safe Disposal Methods for Agricultural Pesticide Wastes (No. PB 81-197584) is available through the National Technical Informa- tion Service. The pesticide disposal pit represented here is intended for use by individual farmers and others who generate 10,000 gallons or less dilute pesticide waste annually. Any pit will be subject to all applicable federal, state and local environmental laws and regulations. If the user intends to dispose of pesticide wastes that have been designated as hazardous materials under the Re- source Conservation and Recovery Act, a permit to build and operate the pit may be required. To assist in determin- ing whether or not a permit is needed, the state agencies responsible for haz- ------- I ardous waste management are listed in Appendix A in the full report. Corre- sponding federal organizations in re- gional offices are listed in Appendix B. Pit Design In the late 1960s, the Department of Horticulture at Iowa State University de- veloped a concept for disposing waste pesticide solutions. A facility based on the concept was built in 1970 at the Uni- versity's Horticulture Research Station and has been in continuous use since that time with satisfactory results. It is essentially the Iowa State design for the waste pesticide pit that is described here, with some modifications from the original. In addition, a few variations on the design that have been developed and used by others are included. The Iowa State University (ISU) Design The ISU design is a rectangular, open- top tank constructed of concrete and partially filled with alternating layers of heavy gravel and soil. See Figure 1. The pit is about three feet deep and is set into the ground so that only about the upper six inches of the walls rise above the surface of the ground. In operation, waste pesticide solutions are loaded into the pit to a depth of not more than two inches over the top gravel layer. The water evaporates and the pesticide chemicals are destroyed by bacteria and by photolytic action (depending on exposure of the liquid to sunlight). Variations On The ISU Design Numerous interested parties have ob- served the ISU pit and have reviewed the design. A few have built essentially identical pits. Others have built similar pits but have introduced their own de- sign concepts, some of which can prove to be practical and useful. At the University of Florida's Ft. Laud- erdale Agricultural Research Station, for example, variations have been intro- duced in both construction, fill material, and loading arrangement. The pit bot- tom is of concrete, poured with a six- inch curb. The walls are of concrete block, built up to a height of 36 inches above the top of the curb. The concrete block walls require special attention for positive sealing against leaks. This is ac- complished by the application of hy- draulic sealing materials and by an inte- rior liner. The liner consists of two layers of 8-mil black polyethylene. The pit is filled to a depth of 24 inches with alternating layers of gravel and soil. A pit design variation that is a major departure from the ISU concept, but is also useful is one in which a layer of soil is initially placed in the pit, then waste pesticide solutions are fed into the pit until a liquid depth of 18-24 inches above the top of the soil layer is intro- duced. In this concept, characterized by pits used at the University of Florida's Sanford Research Station and at the Agway Corporation's Farm Research Center at Tully, New York, pesticide solids settling out of the solution will be anaerobically degraded by microbial ac- tivity in the soil layer, while the water evaporates. Some photolytic degrada- tion will also take place, depending on exposure of the liquid to sunlight. Evap- . orationj-ates are.likely.to be slowerJihan in the ISU concept, because of the greater liquid depth and its resultant ability to absorb heat without increas- ing the vaporization rate. Other design features of these pits would, be similar to those of the ISU- style pits, but a principal difference is found in the loading arrangements. In the Sanford Research Station's pit, the waste pesticide solutions simply run into the pit through a pipe that pro- trudes through one end-wall at a height just above the highest anticipated liquid level. At Agway, a U-shaped, perforated Movable Roof PVC pipe (with the "U" nearly the length and width of the pit) is suspended some 15-18 inches above the liquid surface. The waste solutions are pumped into this suspended pipe and allowed to drain into the pit, with good distribution provided by the length and width of the U-shaped pipe run. Siting, Operation and Maintenance The location and maintenance of a pesticide pit can affect the facility's effi- ciency and length of useful service. If a permit is required for the pit, stringent requirements may be included for siting and operating the pit. In the absence of ..permit requirements, .the following fac- tors should be considered. Locate Pit away from Wells Locate Pit away from Residences and Property Lines Locate Pit away from Surface Water Bodies Expose Pit to Sunlight Unrestricted Air Flow Control Pit Liquid Level Equipment Wash Racks - Control Wash water Quantities Record Pit Loadings Monitor for Leaks Sump Samp/ing Riser Longitudinal Cross Section Sampling Riser -^ /- Sump Roof Rails *i f.e r> ^y T ^T^ i ' i i a '"' V" B ~H6 V J2'-0" 1 ~" £fc^ igr- s»& 6'-0" : Con I r k -r- 12 :re (W VI ?> r te 1 &m 6'-0" /- °ier J 1 :.b- h m\ 2'-0 1 r Transverse Cross Section Figure 1. The Iowa State University pesticide waste disposal pit. ------- ------- George R. Bierman andNarinder P. S. Malik are with Engineering and Economics Research. Inc.. Vienna. VA 22180. Brian A. Westfall is the EPA Project Officer (see below). The complete report, entitled "Use of Lined Pits for Disposal of Dilute Pesticide Waste," (Order No. PB 87-145 926/AS; Cost: $11.95. subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Hazardous Waste Engineering Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 Official Business Penalty for Private Use $300 EPA/600/S2-87/003 ------- |