United States
                Environmental Protection
                Agency
Risk Reduction
Engineering Laboratory
Cincinnati Ohio 45268
                Research and Development
EPA/600/S2-91/044 Sept. 1991
EPA       Project  Summary
                Volumetric Leak  Detection  in
                Large  Underground  Storage
                Tanks

                James W. Starr, Richard F. Wise, and Joseph W. Maresca, Jr.
                 A set of experiments was conducted
               to determine whether volumetric leak
               detection systems presently used to
               test underground storage tanks (USTs)
               up to 38,000 L (10,000 gal) In capacity
               could meet EPA's regulatory standards
               (40 CFR  Parts 280 and 281) for tank
               tightness and automatic tank gauging
               systems when used to test tanks up to
               190,000 L (50,000 gal) In capacity. The
               experiments, conducted on two partially
               filled  190,000-L  (50,000-gal)  USTs at
               Griffiss Air Force Base in upstate New
               York during late  August 1990, showed
               that a system's  performance in large
               tanks depends primarily on the accu-
               racy of the temperature compensation,
               which is  inversely proportional to the
               volume of product in the tank. Errors
               in temperature compensation that were
               negligible in tests in small tanks were
               important in large  tanks.  The experi-
               ments suggest that volumetric systems
               now capable of meeting regulatory stan-
               dards when used  to test 30,000-  to
               38,000-L (8,000- to 10,000-gal) tanks will
               also meet these  standards when used
               to test 190,000-L (50,000-gal) tanks if
               (1) the duration of the test is increased
               from 1 or 2 h to 4 h or more to ensure
               that the vertical gradients are accurately
               measured and to reduce the ambient
               and instrumentation noise, (2) the num-
               ber of temperature sensors is increased
               from 5 to 10 or more so that the accu-
               racy of estimating the  average ther-
               mally  induced volume change in the
               layer of product surrounding each sen-
               sor increases, (3) the waiting period
               after any  addition or removal of prod-
 uct is increased from 6 to 24 h or longer
 so that the horizontal and vertical tem-
 perature gradients dissipate, (4) the av-
 erage rate of change of temperature in
 any one layer or in the tank as a whole
 is small enough to allow accurate tem-
 perature compensation, and (5) an ac-
 curate experimental estimate of the
 constants necessary for converting
 level and temperature changes to vol-
 ume is made. The experiments further
 suggest that a  multiple-test strategy Is
 required in order for such systems to
 meet the tank tightness regulatory stan-
 dard.
   This Project Summary was developed
 by EPA's Risk Reduction Engineering
 Laboratory, Cincinnati, OH, to announce
 key findings of the research project
 that Is fully documented In a separate
 report of the same title (see Project
 Report ordering Information at back).

 Introduction
  The  U.S.  Environmental  Protection
 Agency (EPA) regulation for underground
 storage tanks (USTs),  published in the
 Federal Register (40 CFR Parts 280 and
 281) on September  23, 1988, specifies
 the technical standards and a variety of
 release detection options  for minimizing
 the environmental impact of tank leakage.
 With several exceptions, the shop-as-
 sembled tanks covered  by the regulation
 range in size from small (a few  hundred
 gallons in capacity) to very large, with no
 clearly defined upper limit. (Requirements
 for large field-erected tanks have not yet
 been established). The number  of large
 tanks  (defined  here as those between
                                                                Printed on Recycled Paper

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57,000 and 190,000 L (15,000 and 50,000
gal)  in capacity) represents a small but
important portion of the total tank popula-
tion. This  number  is increasing because
of the preference  of tank owners/opera-
tors for a smaller number of larger tanks
to meet storage needs.  Many large-vol-
ume storage facilities have tanks that are
nominally  190,000 L (50,000 gal) in ca-
pacity. Unfortunately, there is not enough
information to help owners and operators
of large tanks select a testing system that
will be In compliance with the regulations.
Furthermore, it is not known whether volu-
metric tests can achieve the same level of
performance in large tanks as they do in
smaller ones.

Objectives
   The program of experiments conducted
at Griffiss Air Force Base was devised to
expand the understanding of large under-
ground storage tank behavior  as it  im-
pacts the  performance of volumetric leak
detection  testing.  This report addresses
three important questions about testing
the larger underground storage tanks  for
leaks. First, can the EPA regulatory stan-
dards be  met when volumetric methods
are used  to test tanks up to 190,000 L
(50,000 gal) in capacity?  Second, what is
the precision required of  the temperature
and level sensors and what'is the duration
of the data collection period in order for a
volumetric system to test larger tanks, par-
ticularly those that are partially filled? Third,
what are the important features of a volu-
metric system that meets or exceeds  the
regulatory performance standards?

Background
   Leak detection systems used as volu-
metric tank tightness tests on tanks cur-
rently covered by the EPA regulation (i.e.,
those up to 190,000  L   (50,000 gal) in
capacity) must be  able to detect leaks as
small as 0.38 L/h (0.10 gal/h) with a prob-
ability of  detection (PD)  of at least 0.95
and a probability  of false alarm  (PFA) of
0.05.  Leak detection  systems used  as
monthly  tests, such  as  automatic tank
gauging systems,  must be able to detect
leaks as small as 0.76 L/h (0.2 gal/h) with
a P0 of 0.95 and a PFA of 0.05. Most state
regulations, which  require that a tank tight-
ness test be done annually, are more strin-
gent than the  federal regulation. These
standards  are based on  the results of an
extensive experimental program conducted
by the American Petroleum Institute (API)
on 38,000-L (10,000-gal) tanks at retail
stations  and  by the EPA  on  30,000-L
(8,000-gal) tanks  at EPA's  Underground
Storage Tank Test Apparatus in  Edison,
NJ.
  The EPA described the important fea-
tures of a  generic volumetric tank tight-
ness system that would yield the required
level of performance in tests conducted in
overfilled and partially filled tanks. The
important features are the ones that com-
pensate for or minimize errors in the mea-
surement of volume changes not due to a
leak; these errors, which are due to ambi-
ent noise,  are not associated with leaks
and thus  occur in  both  leaking and
nonleaking tanks. Experiments  on a
30,000-L (8,000-gal) tank showed that an
array of five or more equally  spaced tem-
perature sensors, each weighted  by  the
volume of product in the layer surrounding
it, was sufficient to compensate for ther-
mally induced volume changes. This tem-
perature-sensing array  was  suitable
providing that adequate  wajting periods
were observed after any addition of prod-
uct, whether  this addition represented a
delivery to the tank or whether it consti-
tuted topping of the tank (as is required
when testing an overfilled tank). The addi-
tion of product to the  tank  produced
inhomogeneities in the temperature field
that were large enough to prevent an ac-
curate estimate of the mean rate of change
of temperature. As a means of minimizing
the effect of  these thermal  inhomo-
geneities, waiting periods of at  |east  3 h
after topping  and 4 to 6 h after a delivery
were recommended. Any addition of prod-
uct also changes the level of the liquid in
the tank and, therefore, the pressure  that
is exerted on the tank walls. This change
in pressure causes the tank to deform;
observing a waiting period before the test
allows deformation to subside, thus elimi-
nating any errors that it  might have  pro-
duced. The waiting period may have to be
as long as 12 to 18  h, depending on the
properties  of the tank and of the backfill
and  native soil surrounding it.  In tests
conducted  in overfilled tanks, there  is a
third  source  of  potential error: the tem-
perature- and/or pressure-induced expan-
sion  or contraction of any vapor trapped
in the tank. If the amount of trapped vapor
is significant, or if the  range of tempera-
ture and/or pressure changes within the
trapped vapor is great, the error can have
a detrimental impact on the test. Unfortu-
nately, it is extremely difficult to  identify
the presence of small volumes of trapped
vapor, and there is no satisfactory way to
compensate  for volume  changes due to
this phenomenon. A fourth source of po-
tential error is unique to tests conducted
in  partially filled tanks: this is  the error
produced by  evaporation or condensation
at the liquid/vapor interface and the vapor/
tank-wall interface. It is believed that the
effects of  evaporation and condensation
are usually small, but available data show
that under some air-temperature and at-
mospheric-pressure conditions they can
be large enough to produce false alarms
and missed detections. At the present time
there  is no systematic  way to determine
when  these conditions  will adversely af-
fect the test; however, any adverse ef-
fects can be minimized  through the use of
a multiple-test strategy.  The other sources
of error, which  are produced by surface
and internal  waves,  can  affect the test
results in  both  overfilled and underfilled
tanks. These can be  minimized by proper
sampling of the level and temperature data.
  For best performance, the instrumenta-
tion noise, or system  noise, should be
less than the ambient  noise. In small tanks,
whether partially filled  or overfilled, this
can be achieved. However, as the volume
or the surface area of  the product  in the
tank increases, this becomes proportion-
ately  more difficult.
  Because the  EPA  regulations (and the
recommended "important  features" of a
volumetric tank tightness test that are de-
scribed  above) are based on experiments
conducted on 30,000-L (8,000-gal) tanks,
it is unclear whether a volumetric test that
meets the EPA standard when used to
test smaller tanks  can  achieve the same
level  of performance when used to test
larger tanks. At the  present  time, there
are no experimental data that can be used
to make such an assessment, particularly
for tanks  as  large as 190,000 L (50,000
gal). Additional information about the mag-
nitude of  the noise in  large tanks  would
be required before such an assessment
could be made. Based  upon previous ex-
perimental and  analytical  work, we ex-
pected that four things would be necessary
in order for  a  volumetric leak  detection
system  to maintain the required level of
performance when used to test large tanks:
(1) more temperature sensors, (2) longer
waiting  periods after topping or after deliv-
ery of product to the tank, (3) a longer test
duration, and (4) an increase in  the preci-
sion requirements of  the temperature and
level  measurement systems.

Conclusions
   In the present study, limited-scope field
experiments  were conducted during late
August  1990 on two partially filled 190,000-
L (50,000-gal) underground storage tanks
located at Griffiss Air  Force Base  in up-
state  New York. The purpose of the ex-
periments was to  determine  whether
volumetric systems intended for 30,000-
to 38,000-L (8,000-  to 10,000-gal) tanks
could successfully be  used  with  larger
tanks. The  Griffiss tanks were 254.3 m
(77.5 ft)  long  and 320 cm  (10.5 ft) in

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diameter. A level sensor with a precision
of 0.0005 cm (0.00025 in.) and an array
of 10 submerged thermistors  spaced at
30-cm (12-in.) intervals, each thermistor
having a precision of 0.001 °C (0.002°F),
were  used  to collect the data. All experi-
ments were conducted  in  partially filled
tanks. Changes in product level were ef-
fected by shunting product from one tank
to another by means of a pump. The addi-
tion  or  removal of  product  produced
changes in  the temperature of the product
that effected volume changes of several
liters per hour or more.
  The following observations were made:
   •  Temperature fluctuations observed
     throughout the tank after approxi-
     mately 38,000 L (10,000 gal) of prod-
     uct had been added or removed were
     too great, unless at  least 4 h  had
     elapsed, to permit an accurate leak
     detection test.  (The  addition of
     38,000 L (10,000 gal) simulated a
     delivery of product to the tank.)
   •  Temperature fluctuations observed
     after the addition of approximately
     19 L (5 gal) of  product 25°C warmer
     or 8°C cooler than the in situ product
     were too great, unless 2 to 3 h  had
     elapsed, to permit an accurate leak
     detection test.  (The addition of 19 L
     (5 gal) simulated the topping of an
     overfilled tank.)
   •  The average rate of change of tem-
     perature between any two locations
     along  the long axis of the tank, as
     measured by any two thermistors at
     the same height, but distanced hori-
     zontally, was  less than  0.001 °C/h
     beginning 4 h or more after product
     additions or removals. Furthermore,
     the mean temperature  along  the
     centeriine of the tank was the same
     at  each height,  i.e., the  horizontal
     gradient was  negligible  at   the
     centeriine.
  •  A horizontal gradient  in the mean
    temperature  was observed  in  the
     mid-region of the tank in the area
     between the centeriine and the wall
    of the tank. The rate of change of
    temperature, as measured by three
    thermistors spaced at horizontal in-
    tervals of 30 cm  (12 in.), was lower
    in the  area  of the centeriine and
    higher in the area of the tank wall,
    an observation that is consistent with
    the physical process of heat transfer
    between the backfill surrounding  the
    tank and the product inside it. The
    difference  between  the  rate  of
    change of temperature measured at
    the  centeriine  of the tank and at
  locations off the centeriine was large
  enough to suggest that a single ver-
  tical  array is  not sufficient for tem-
  perature compensation unless  at
  least 18 h has elapsed since any
  product addition or removal.  Addi-
  tional  horizontally  oriented  ther-
  mistors must be  incorporated into
  the arrays to  compensate for these
  temperature changes, or  the test
  must not be started until the rate of
  change of temperature has subsided.
•  The  area  near the bottom of the
  tank exhibited the largest vertical gra-
  dient and the greatest rate of change
  of temperature. In this region, a spac-
  ing of 30 cm i(12 in.) between ther-
  mistors was 'not  adequate, in the
  experiments conducted, for correct
  temperature compensation unless at
  least 10 h had elapsed since the
  last addition or removal of product.
•  The temperature fluctuations that fol-
  lowed changes in  product level  in
  these experiments were so large that
  changes due to deformation  were
  masked. As a consequence,  none
  of  the  classical exponential  level
  changes associated with tank defor-
  mation  was observed  in these ex-
  periments.
'  Analysis of the  level data revealed
  the  presence of surface  waves
  (seiches) having periods of 2 to 10 s
  and peak-to-peak amplitudes of 1  to
  2 L. These waves were consistent
  with the fundamental and first har-
  monic of waves propagating along
  the long and short axes of the tank.
  Analysis of the temperature data re-
  vealed  the presence of  internal
  waves  having  periods of 3 to 30
  min. These subsurface waves were
  large enough to produce periodic sur-
  face waves.
  Experimental estimates of the height-
  to-volume  conversion  factor were
  within 5% of the theoretical estimates
  made with a tank chart.
  When 10 h  had elapsed after a prod-
  uct addition or removal, and ther-
  mistors spaced at 30-cm  (12-in.)
  intervals were used for thermal com-
  pensation,  the residual volume
  changes in  each of  three tests on
  nonleaking  tanks were 0.36, 0.67,
  and -0.22  L/h  (0.095, 0.177, and
  0.058 gal/h) respectively. When 2  h
  had elapsed after topping and 20  h
 after a product addition or removal,
  residual volume changes in each of
 two tests were 0.036 and -0.043 L/h
      (0.0095 and  -0.011  gal/h) respec-
      tively.  These  residual volume
      changes can be attributed to inad-
      equate  temperature  compensation.
      (There was insufficient coverage near
      the surface  of the product,  at the
      bottom of the tank, and in the area
      between the centeriine and the tank
      wall, all locations where large tem-
      perature gradients were  present.)
      The effects of  evaporation and con-
      densation within the  tank could not
      be quantified,  but their contribution
      to the residual volume changes ap-
      pears to be smaller than the errors
      in temperature compensation.
   The data collected during these experi-
 ments, combined  with theoretical  analy-
 sis, were sufficient for the  researchers to
 address each of the technical objectives
 of this study.  A summary of the key con-
 clusions of this research project are pro-
 vided below.
   Volumetric leak detection  systems
 can meet EPA's performance standards
 for testing tanks up to 190,000 L (50,000
 gal)  In capacity.  The experiments on
 190,000-L (50,000-gal) tanks suggest that
 volumetric leak detection  systems can
 meet the EPA standards for both volumet-
 ric tank testing and automatic tank gaug-
 ing. That is, they can detect leaks of 0.38
 L/h (0.10 gal/h) with a PD  of 0.95  and a
 PF/> of 0.05, which is the performance re-
 quired of tank tightness tests. (By defini-
 tion they can also meet the  requirement
 for automatic tank gauging systems, which
 is the ability to detect a leak of 0.76 L/h
 (0.20 gal/h) with a Pp of 0.95 and a PFA of
 0.05.) However, achieving this goal is very
 difficult and probably requires a multiple-
 test strategy.
  A 0.76-L/h (0.2-gal/h) leak  was detect-
 able with the thermistor array used in these
 experiments, but a smaller leak of 0.38 L/
 h  (0.1  gal/h)  could  not be  reliably de-
 tected.  However, leaks as  small as 0.38
 L/h (0.1 gal/h) were detectable if the wait-
 ing period after any addition or removal of
 product from the tank was  at least 18 h.
 After  some  analysis, this was explained
 by the fact that there was  an  insufficient
 number of thermistors at the bottom of the
 tank, near the surface of the product, and
 between the centeriine and the walls of
 the tank, areas  where either the rate of
 change of temperature or the gradient in
the rate of  change  of temperature was
 greater than  in  other parts of the tank.
 The upper portion of the layer closest to
the surface  was  influenced by  large
changes in the temperature of the vapor,
so that the  implicit assumption  that the
 rate of change of temperature varied lin-

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     early through the layer was violated. The
     thermistor closest to the surface was not
     physically centered in the layer, and the
     product surrounding it was not equally dis-
     tributed above and below  it. When the
     thermistor was too far away from the sur-
     face (e.g., 25 cm (10 in.)), the contribution
     from the surface was not properly included
     in the average. Any error  in measuring
     the average  rate of change of  tempera-
     ture was magnified by the volume of prod-
     uct in  the layer. The  error in measuring
     the average  rate of change in  tempera-
     ture was even greater in the layer of prod-
     uct  at the  bottom  of  the tank. (In
     measurements made at the bottom,  how-
     ever, the magnitude of the error decreased
     with time; in  measurements made  near
     the surface it did not.)  Although the tem-
     perature sensor is indeed centered in this
     bottom layer, the curvature of the tank is
     such that the volume of the product above
     the sensor is significantly greater than that
     below it. The average rate of change of
     temperature and the gradient in the rate
     of change of temperature were significantly
     greater here than in any other layer. While
     errors of similar magnitude in measuring
     the average  rate of change of  tempera-
     ture are present in small tanks, the vol-
     ume  of each  layer in a small tank is
     significantly less than in a large tank, par-
     ticularly  near  the  bottom.  The  largest
     source of error in measuring the average
     rate of change of temperature was due to
     horizontal gradients in the rate of change
     of temperature between the centerline of
     the tank and the wall of the tank. Better
     temperature compensation would  have
     been  achieved  if additional temperature
     sensors had been  located  near the bot-
     tom of the tank and near the product sur-
     face,  ensuring a better  estimate of the
     rate of change of temperature in the layer
     surrounding each thermistor, or if a longer
     waiting period had been  used, thus mini-
      mizing the rate of change of temperature
      in these layers and throughout the tank as
     a whole.
        The Important features  of a generic
      volumetric leak detection system that
      can meet the EPA performance  stan-
      dards have been Identified. The experi-
      ments on 190,000-L  (50,000-gal) tanks
      allowed us to identify the key feature that
      a volumetric leak detection system  used
     on larger tanks must possess in order to
      meet the EPA standard. K must have bet-
     ter temperature compensation than what
      is  deemed  sufficient  for  a 30,000- to
      38,000-L (8,000- to 10,000-gal) tank, and
      it must have longer waiting periods and a
      longer test duration. All the other features
      required for accurate detection of leaks in
small tanks are applicable equally to the
detection of leaks in large tanks.
  Five things are necessary for success-
ful temperature compensation in tanks as
large as 190,000-L (50,000-gal).  First, a
test must not be started until the horizon-
tal gradients in the  rate of change of tem-
perature between the  centerline and the
tank walls have dissipated. Second, the
number of temperature sensors must be
sufficient that the volume of product in the
layer around each sensor is not too great;
the smaller the volume in each layer, the
less likely it  is  that a temperature mea-
surement error, when summed  with mea-
surements from the  other  layers,  will
adversely affect the test. Third, the dura-
tion of the test must be bng enough that
(1) the fluctuations  in volume observed 6
h or more after any product additions or
removals can be averaged, and (2) the
precision of the temperature and level is
sufficient to detect  a leak with a specified
performance. Fourth,  a test should not
begin unless the average rate  of change
of temperature in the tank as a whole or
in any one layer is  small enough to allow
accurate temperature compensation. Fifth,
an accurate experimental estimate of the
constants necessary for converting level
and temperature changes to  volume  is
required: these constants include the co-
efficient of thermal  expansion, the volume
of product in the tank or in each layer,
and the height-to-volume conversion fac-
tor.
  How long must the  waiting period be?
In testing tanks up to  190,000  L (50,000
gal) in capacity, the length of the required
waiting period is controlled by  the gradi-
ent in  the rate of change of temperature
between the centerline and the  wall of the
tank. This  waiting  period must be suffi-
ciently long that the temperature fluctua-
tions and tank deformation associated with
a product addition or removal will have
time to subside. A waiting period of 24  h
or bnger may be required.
  The data suggest that the minimum du-
ration of a test should be at least 4 h, bng
enough that an average of the ambient
volume fluctuations can be made. Whether
4 h is sufficient depends on the resolution
and precision of the temperature and level
instrumentation.
  The spacing between thermistors in  a
190,000-L (50,000-gal) tank may need to
be as small as 15 cm (6 in.) to detect
leaks  as  small  as 0.38  L/h (0.1  gal/h),
particularly near the bottom and top of the
tank where  more dense coverage will re-
sult in  a  more accurate estimate of the
rate of change of  temperature. Since er-
rors in temperature compensation increase
as the average rate  of change of tem-
perature increases, the most direct way to
avoid errors is to wait until the average
rate of change of temperature has dimin-
ished before starting a test.
  The precision of the Instrumentation
used to measure temperature and level
changes establishes the minimum du-
ration of a test. In order for a volumetric
leak  detection system to  meet the EPA
standards, the length of a test must be
appropriate  for the precision  of the
system's instrumentatbn for temperature
and level measurement. Given a certain
level of precision, the optimum duration of
a test can be calculated. As part of the
experiments,  calculations were made to
estimate the  minimum duration of a test
conducted on a 182,000-L (48,000-gal)
tank as a function of the precision of the
temperature and level sensors,  ft was as-
sumed in the calculations that the resolu-
tion of the sensors was 2 to 3 times smaller
than the most extreme level change that
occurred over the duration of the test. The
calculations indicated that the test  dura-
tion must be at least 2 h in the case of a
level sensor having  a precision of 0.0005
cm (0.00025  in.) and a temperature sen-
sor  having  a  precision  of 0.001°C
(0.002°F). When the  instrumentation is less
precise, the test duration must be  com-
mensurately longer.  For example,  if the
level sensor had a precision of 0.0025 cm
(0.001 in.), the test would have to  be at
least 4 h long.

Recommendations
  The recommendations developed from
this research project are based on a lim-
ited set of data. The recommendations for
controlling the key sources of noise  might
be further refined if additional experiments
were conducted. We believe, however, that
additional data would not have any sub-
stantial impact on the general nature of
the recommendations made  here, and that
further refinements to these recommenda-
tions  would not materially change the ef-
fort  or cost  involved in developing or
modifying a method  of testing large tanks.
Although the experiments were limited to
tests  conducted on  partially filled tanks,
many of the conclusions are applicable to
the use of volumetric systems in overfilled
tanks as well. The recommendations that
emerged from  this research  project  fall
under two headings.

 Temperature Compensation
  The single most important cause of er-
rors in testing large tanks with volumetric
leak detection systems appears to be in-
accurate temperature compensation. Two
things are necessary for  successful tem-
perature compensation. First, the number
L.

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of temperature sensors must be sufficient
that the  volume of product in the  layer
around  each one  is  not  too great; the
smaller the volume in each layer, the less
likely it is that a measurement error, when
averaged with  measurements from the
other layers, will adversely affect  the test.
Second, a test must not be started if the
average rate of change of  temperature of
the product in the  tank as  a  whole, or
even in a single layer, is great enough to
prevent the system from detecting a leak
of given size.
  The  following  procedure is  recom-
mended for compensating for the thermal
expansion or contraction of the product:
   • Place the lowest temperature  sen-
     sor approximately 8 cm (3 in.)  from
     the  bottom of the tank and the up-
     permost sensor approximately 8 cm
     (3 in.) below the surface.
   • Space the temperature sensors at
     intervals of 15 to  30 cm (6 to 12 in.)
     or less along the vertical axis of the
     tank; space the sensors at intervals
     of 15 cm (6 in.) or less in the bottom
     46 cm (18 in.) of the tank and in the
     15 to 30 cm (6 to 12  in.) of  product
     located immediately beneath  the sur-
     face. (A 30-cm (12-in.) spacing can
     be used  if the rate  of change  of
     temperature between adjacent lay-
     ers of product throughout the entire
     tank is nearly identical.)
   •  Partition the tank into layers,  each
    . of which is centered  about  a tem-
   "• perature sensor. Then calculate the
     volume of product in each layer.
   •  Wait at least 24 h for horizontal  gra-
     dients in the rate  of change  of tem-
     perature  to  dissipate.  (These
     horizontal gradients occur between
    the centerline and the  wall of the
'    tank.) Alternatively, measure these
    horizontal gradients directly,  and do
    not attempt to compensate for tem-
    perature until they have dissipated.
    If the compensated volume rate ex-
    ceeds the threshold, continue to test
    until the  measured  volume  rate
    ceases to  decrease  and remains
    constant.
  • Using real-time measurements, wait
    for the rate of change of tempera-
    ture to diminish sufficiently that the
    maximum potential error in measur-
    ing the average rate of temperature
    for each test  is small. The  accept-
    able  rate of temperature change de-
    pends on the number of thermistors,
    the precision of each thermistor, and
    the degree of compensation that can
    be achieved with the array of ther-
       mistors. A  very conservative ap-
       proach is to incorporate the follow-
       ing analysis tests.
       -  Do not begin a test if the rate of
          change of temperature is great
          enough in any  one layer to pro-
          duce a volume change that will
          exceed the  detection  threshold.
          (When using a  threshold of 0.19
          L/h (0.05 gal/h)  in a tank contain-
          ing JP-4  fuel, this would limit the
          rate of change in temperature to
          less than 0.008°C in the largest
          layers of ,a 190,000-L (50,000-
         gal) tank divided into ten layers.)
       - Do not begin a test if the aver-
         age rate  pf  change of  tempera-
         ture throughout the tank is great
         enough  to  produce  volume
         changes  that exceed the thresh-
         old based on an average level of
         compensation to be achieved.
         (When using a threshold of 0.05
         gal/h  in a: tank containing JP-4
         fuel, this  would limit the rate of
         change  in temperature to  less
         than  0.019°C  throughout a
         190,000-L'(50,000-gal) tank if on
         average the  method is able  to
         compensate for 95% of the tem-
         perature changes.)
    •  Use the  most precise temperature
      and  level measurement  systems
      available and calibrate them  fre-
      quently  and  properly, ft is recom-
      mended that temperature  sensors
      have a precision of  0.001 °C and the
      level sensors have a precision of
      0.00025 cm (0.0001 in.).
    •  Check that all sensors function prop-
      erly during a test. If a sensor mal-
      functions,  the  test should  be
      repeated.
    •  Make sure the test is at least  4 h
      long so that ambient fluctuations will
      be properly averaged and will not
      affect the test., Longer tests may be
      required depending on the resolu-
      tion and precision of the level and
      temperature sensors.
    •  Measure the coefficient of thermal
      expansion experimentally.
    •  Determine the height-to-volume con-
      version factor used  to convert level
      measurements to volume measure-
      ments experimentally.
    •  Use a multiplexes! strategy.
Whether this temperature compensation
procedure  is sufficiently  adequate for a
volumetric leak detection  system  to meet
the EPA's regulatory standard for a tank
 tightness test  (or a  monthly monitoring
 test) will not be  known  until  an actual
 performance evaluation is conducted on a
 system that incorporates some or  all of
 these procedures.

 Evaluating a Volumetric Leak
 Detection System
   Volumetric leak detection systems that
 will  be used  on large  tanks should be
 experimentally evaluated according to the
 EPA's standard test procedure for evalu-
 ating volumetric tank tightness tests. This
 includes the performance of the system in
 terms of probability of detection and  prob-
 ability of false alarm. The primary features
 that should  be examined are the method
 of temperature compensation, the waiting
 periods, and the duration of the test. The
 results of the present study suggest that,
 when a volumetric leak detection system
 is used to test larger tanks, longer waiting
 periods, a longer test duration and better
 temperature compensation are required if
 leaks are to be detected with  reliability.
 Unfortunately, none of the existing facili-
 ties specializing in evaluations is equipped
 with 190,000-L (50,000-gal) tanks. There-
 fore, systems must be evaluated at large-
 volume  storage facilities  that   are
 operational,  and the EPA's standard test
 procedure should be modified to accom-
 modate this  type of evaluation.
  The full report was submitted in fulfill-
 ment of Contract No. 68-03-3409 by Vista
 Research, Inc., under the  sponsorship of
the U.S. Environmental Protection Agency.
                                                                                    'U.S. Government Printing Office: 1992 — 648-080/60042

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James W. Starr, Richard F. Wise, and Joseph W. Maresca, Jr., are with Vista Research,
   Inc., Mountain View, CA 94042.
Robert W. Hlllger is the EPA Project Off her, (see  below).
The complete report, entitled "Volumetric Leak Detection in Large Underground Storage
   Tanks," (Order No. PB91-227942/AS; Cost:$23.00, subject to change) will be available
   only from:
        National Technical Information Service
        5285 Port Royal Road
        Springfield,VA22161
        Telephone: 703-487-4650
The EPA Project Officer can be contacted at:
        Risk Reduction Engineering Laboratory
        U.S. Environmental Protection Agency
        Edison, NJ 08837
United States
Environmental Protection
Agency
Center for Environmental
Research Information
Cincinnati, OH 45268
      BULK RATE
POSTAGE & FEES PAID
         EPA
   PERMIT No. G-35
Official Business
Penalty for Private Use $300
EPA/600/S2-91/044

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