, United States
                      SEnvironmental^rotection
                      -Agency      .         ;
Environmental Monitoring
Systems Laboratory    '
Research Triangle Park NC 27711
                       Research and Development
EPA/600/S&-88/009D Sept. 1988
4*EPA          Project  Summary

                       Indoor  Air  Quality  in  Public
                       Buildings:   Volume  II
                       L Sheldon, H. Zelon, J. Sickles, C. Eaton, T. Hartwell, and L. Wallace
                         This report documents the second of
                       two studies of indoor air quality in public
                       buildings  carried out by the. U.S.  En-
                       vironmental Protection Agency in re-
                       sponse to public and Congressional con-
                       cern. A total of 10 buildings were studied
                       in the program. A report on the first four
                       buildings  is being published simultane-
                       ously with this report, which deals with
                       the last six buildings investigated.
                          Thfe Project Summary was developed by
                       EPA's Environmental Monitoring Systems
                       I nbomtary, Research Triangle Park, NC, to
                       announce key  findings of the research
                       project that is fully documented in a
                       separate report of the same title (see Proj-
                       ect Report ordering information at back).


                        Introduction
                          In FY 1982 and again in FY  1983, Con-
                        gress  mandated that the U.S. Environmen-
                        tal Protection Agency (EPA) carry out studies
                        of indoor air quality. Jhe studies were focus-
                        ed on volatile organic compounds (VOCs) for
                        several reasons: 1) VOCs include a number
                        of carcinogenic and  mutagenic species
                        (benzene, chloroform,  tetrachlorpethylene,
                        etc.); 2) little was known at the time about
                        human exposure to these compounds; and
                        3),methodology had recently been developed
                        to  measure  these  compounds at en-
                        vironmental  levels.  Because these com-
                        pounds were being extensively studied in
                         private, homes in EPA's ongoing Total Ex-
                         posure Assessment Methodology (TEAM)
                         Study (Wallace I987; Pellizzari 1987a,b; Han-
                         dy 1987),  the study concentrated on buildings
                         rather than homes. Buildings where people
                         spend long periods of time were selected for
                         study: schools,  homes  for the  elderly,
                         hospitals,  and office buildings.  These.
                         buildings also contain populations (children,
                         the sick  and the elderly) that may be more
                         sensitive to air pollutants.
   Two separate but closely related studies
 were carried  out.  The  first included
 measurements in four buildings (one school,
 one office building, and two homes for the
 elderly). The final report of that study, an EPA
 Research Report entitled Indoor Air Quality
 in Four Buildings, is now available (Sheldon
 et al., 1988). A separate Project Summary .
 has been written for that report.
   The second study included six buildings
 (a hospital, two office buildings, two homes
 for the elderly, and an institute for govern-
 mental studies). The final report for that study
 is entitled Indoor Air Quality in Six Buildings.
 This Project Summary refers to this second
 study only.

 Study Design
   The goals of the study were the following:

   1) Quantify a set of target VOCs, selected
      on the basis of their potential health ef-
      fects, production volume, and amena-
      bility to collection on  Tenax, in  all
      Samples.        . -  "
   2) Determine the effect of aging on the
      concentrations of VOCs within  three
      newly constructed.buildings.-
   3) Measure emissions  of VOCs  from
      building material collected from one of
      the new buildings.
   4) Measure  concentrations  of  other
      chemicals or mixtures including radon,
      formaldehyde, particles, pesticides,
      PCBs. polynuclear aromatic hydrocar-
      bons (PAHs), metals, carbon monoxide,
      nitrogen dioxide, arid asbestos.

    Six  buildings were selected for study: a
   hospital and an associated nursing home in
   Martinsburg, WV; a home for the elderly in
   Worcester,  MA;  an office building  in
   Washington, DC; another office building in
   Fairfax, VA; and an institute for governmen-
   tal studies in Cambridge, MA. The hospital,
                                                                           L)  Printed on Recycled Paper

-------
   ll I I    III III I1  ff I " I
the Worcester home for the elderly, and the
Fairfax office building were new buildings,
scheduled Jo,be..rnonitoredimmediately after
completion but before occupancy, and then
again a few months after occupancy. (Unfor-
tunately, the new hospital was not actually
monitored until almost one year after it had
been finished; therefore only two buildings
were rnpnli||ffediiwheniithey were new.) The
remaining"	three""" buildings"" 'were	existing'
buildings  ranging in age  from 3-8  years.
These buildings were monitored once only:
  Eac^rr^itoYing'Visjt lasted	three" days.
Three' 'indoor .sites" we're, selected, an
-------
Table 1.    Precision for Volatile Organic Analysis
                                                                                            o/o RSD
Compound
Aromatic Hydrocarbons
Benzene
m, p-Xy/ene
o-Xylene
Styrene
Ethylbenzene \ • .
Isopropylbenzene
n-Propylbenzene
m-Ethyltoluene
o-Ethyltoluene
1 ,2,3-Trimethylbenzene
i ,2,4-Trimethylbenzene
1,2.5-Trimethylbenzene.
Aliphatic Hydrocarbons
a-Pinene
n-Decane •
n-Undecane ;
n-Dodecane
Chlorinated Hydrocarbons
1.2-Dichloroethane,'
1.1,1-Trichloroethane
trichloroethylene
Tetrachloroethylene
p-Dichlorobenzene
Chlorobenzene
Carbon tetrachloride
o-Dichlorobenzene
Oxygenated Hydrocarbons
n-Bury/acefate
2-Ethoxyethyl acetate

: ' V
'
233
231
222
226
229
128
104
278
744 .
278
224
779

69
757
757
73

52
229
773
723
77
If
7
• f •
12


73
. 40

Mean

25 '
.17
18
28
17
17
15
.16
16
23
• 17
16

22
20
21
18

18
.21
26
16
'
29
' ••
"
28
23
,
'. 257H
Percentile

11
9
10
12
9
10
,8
,8
7
10
8
7

12 .
77,
77
70
• •
8
77
72
8
5 • •
12
7
4


, 15
12

SOTH
. Percentile

21
15
15
'21
15
15
13
14
14
• 17
14
.13

20
16
78 .-
75

75
78
. 22 •'
74
77
76
. • 74
73


24
22

75TH
• Percentile

34
22
24 ,
37
22
22
21
21
23
27
27 -
22

,28
26
27
22 -

23
25
34
21
18
17
49
. 56


36
31 '

90TH
Percentile

' 47
29
35
57
32
•30
29
29
'37
40
37
32

, 44
35 ,
39
32

37
42
49
30
23
78
706
777


47
39

  'Number of samples.
  Table 2:    Results of Distributed Volume Sampling
Chemical 	 .
n-bury/acetafe
n-dodecane
n-propyibenzenn .
1 ,3.5-trimethylbenzene
p^dichlorobenzene
a-pinene
sthylbenzene ,
tetrachloroethyiene
• tnchloroetnylene
o-xy/ene
i.1.T-trichloroethane •
isopropylbenzene
m-xy/ene
n,-undecane
o-etnyltoluene
1 . 2, 3-1 rimet hylbenzene ,
? .2.4-tnmethylbenzene -
•n-decane . -
m-emyfto/uene
o-cresol
1 ,2-dichloroethane
N
65
63
95
108
67
59
210 •
112
" ~ 94
197
207
. 779 •
276
727
• •• ' ,272
208
200
730
/96
74
43
Mean3
2.25 •
22.84
7.55
2.67
7.77
8.70
2.59
7.74 ,
1.85
2.80 .
4.45
0.76
6.56 .
' 77.25
0.66'
' 0.99 ,
3.00'
70.27
2.58
7.07
2.58
SO6
0.03
0.32
0.02
0.04 ,
0.03
0.29
0.08 ..
0.05
0.05
0.075
0.72
0.03
0.24
. 6.47
0.025
• 0.04
0.77
0.49 ,
0.76
0.06
0.77
RSD(%f
7
7"
7
7
2
3
'3
3
: 3
3
3
4
.4
•4
4
4 '
4
5
6
6
-7
chemicals—a set of 10 aromatic and aliphatic
VOCs—were identical in both of the new
buildings studied, indicating that the findings
may be generally true for  many buildings.
The materials emitting these chemicals at the
highest rates were surface coatings such as
adhesives, caulking,  and paints; wall  and
floor coverings such as molding, linoleum tile,
and carpet; and miscellaneous other mater-
ials such as telephone cables. Structural
materials such as brick and mineral board
had few organic emissions. Surprisingly
-however, some solvent-based materials such
as linoleum tile cement and joint compound
and some other materials such as ceiling tile
and plastic laminates also had no detectable
 emissions of the target compounds. These
 findings confirm the findings of the earlie
 EPA study (Sheldon  1988; Wallace 1985) o
 emissions from 19 building materials.
    Because building renovations utilize man\
 of ,the same materials (adhesives, paints

-------
Tfblt 2, (Continued)
i 1 1 1 ii
Chemical • ,
stynme
chlofQbenzene
ocKchhtobwizane
2-$t!tioxyBthytacetate
benzene
cirbon tetrachronde 	 	 	 ;
bromxliChlofomethane
m-cftsol

ii
N
203 .
7
4
50
215
" 19 	
3
41

Mean3
1.26
7.76
7.77 •
3.53
2.68
0.87 '.'
0.98
5.35

II I I *
SD"
	 O'.ii '•"
0.12
0.025
0.36
0.35
0.12
0.24
1.66

RSD(%f
9
10
10
10
13
15
24
31
*M«*fj of tfw three geometric moans tor the three sampling volumes.
* Sumdard deviation of tin three geometric means
8 Aftifivt standard deviation




' I



carpets, etc.) that cause elevated VOC con-
centrations in new buildings, it appears possi-
ble that similar elevated concentrations will
occur in buildings that are being renovated
or refurbished.
Two types of health effects may be
associated with the elevated concentrations
of organic gases and particles reported here.
First, chronic health effects, including cancer.
may be caused by long-term exposure to
trichloroethylene, tetrachloroethylene, carbon
tetrachloride, and p-dichlorobenzene are
animal carcinogens and therefore possible
human carcinogens. The elevated particle
t*W» 3.    Mean Indoor Concentration of Volatile Organic Compounds for all Monitoring Trips
if*
                                                                        Mean Indoor Concentration (ng/L)
Martlnsburg,



Coumpound
Aromatic Hydrocarbons
Bonzeno
nvXyfene
b-Xytene
* 	
Styrene
Ethytbenzene
Isopropytbenzene
tn-EthyttokmrrB
o-Etnyttoiuene
1,2,3-Trimethytbeftzene
1,2,4'Trimethfybenzene
1,3,5-Trrmeijylbenzefie
Aliphatic Hydrocarbons
Cffin^)e " 	 ' 	
n-Decana
n-Un, 1-Tnchloroethane
Trichtomathykne
Tairachtoroethylane
p&chtorobenzene
i i in i i
Oxygenated Hydrocarbons
1 III
n-Butylacetate
2~£thoxyethyl acetate
WV
Fairfax, VA
Washington.
Worcester, MA DC
Nursing0
Hospital (Newf
Tnp 1
(7/84)

7.55
6.88
3.05
7.00
7.94
0.37
WD
7.77
WD
0.63
	 1.48
ND

ND
3.65
3.31
ND

Hill i
2.06
	 498
105
WD
WD
||

III 1
WD
7.37
Tnp 2
(10/84)

2.73
3.73
0.92
7.07
7.07
NDd
ND
0.86
ND
0.43
0.98
ND

ND
2.73
7.96
WD

i
7.49
4.50
WD
WD
ND


ND
ND
Tnp 3
(8/85)

2.88
9.91
3.07
1.33
2.88
0.33
ND
1.48
0.66
0.76
1.82
0.75

ND
2.71
2.34
ND

I
22Y
75,54
ND
1.79
6.61


ND
ND
Office (NewjP
Trip 1
(1/85)

2.74
41.53
78.40
2.52
57.26
3.94
5.00
27.47
8.89
75.70
73.57
76.97

74.73
436.38
270.80
752.69

J
WD
72.54
WD
WD
ND


ND
ND
Trip 2
(4/85)

- 4.95
15.05
3.67
2.87
5.37
0.67
"7.73
5.57
2.08
2.97
7.27
2.75

24.64
75.24
33.93
23.74

(ihl 	 I'ii1:, '
4.57
38,85
7.93
7.64
2.64

'
6.34'
2.76
Home (New)
Trip 1
(4/85)

1.70
23.80
8.92
2.99
7.90
2.27
2.99
12.38
4.01
5.32
73.95
6.83'

' 5.79
68.27
68.57
37.42

:,, <;il ; , '!'!!,|i'ii|;'||, ': "!'
WD
4,03
2.58
7.73
2.77
*

WD
9.58
Top 2
(8/85)

2.44
5.33
2.07
1.27
2.15
0.33
0.70
2.62
0.73
0.72
-2.52
0.92

WD
3.87
3.48
WD

•,; ',, 	 i', , , • li'ij'iiiii.
WD
7,76
0.57
0.96
0.62


7.22
ND
Office
(Old)
Trip 1
(8/84)

5.61
27.11
9.28
2.36
10.15
0.79
1.22
6.07
1.60 '
1.80
6.28
1.83

ND
2.26
2.85-
ND

„ '"" '„,'.»" ' ,||l , »'
ND
40.98
0.61
3.97
0.60
• '''it

2.63
7.67
Cambridge,
MA
Office/
School
(Old)
Trip 1
(2/85)

4.50
8.72
3.43
1.32
2.69
0.36
0.56
2.62
0.74
7.06
2.80
7.74

2.65
5.98
6.77
2.23


WD
70.69
70.89
4.77
ND


1.48
, ND
Martinsburg, WV
Nursing
Home (Old)
Trip 1
(7/84)

3 13
2.95
0.99
1.19
0.97
ND
ND
0.90
ND
0.79
0.98
ND

ND
1.87
ND
ND

•I. , .
WD
3.09 •
; WD
0.99 ,
WD


Wo
WD
"Buttdmg compkttd -34 weeks before first monitoring trip.
"BuMtng competed -1 week before erst monitoring trip.
c8uttoWifl compiled -4 weeks before first monitoring trip.
*B*tow tfw cpjtr\!ifable limit.

-------
Table 4. Concentration Data for Volatile Organ/OS Summarized by Compound 'Class
• ; Concentration (ng/L) '

i
Hospitals
Hospital (New)
Trip 1 (7/84)
Trip 2 (10/84)
Trip 3 (8/85)
Offices
Office (New;
Trip.1 (1/85)
Trip.2(4/85) .
Office (Old)
Trip 1 (8/84)
Office/School (Old)
_ Tnp 7 (2/85)

Completion
(Weeks)

-34
-48
-1.Sy
.-1
14
~iy
~2y :
Aromatic
Hydrocarbons
Indoor

18
11
' 26
270
54
74
30
Outdoor

5.4
5.1
6.2
16
.' .13
'50.
12
In/Out
Ratio

. 3.3
2.2
4.2
17
4.2
• 1*
2.5
Aliphatic
Hydrocarbons .
.Indoor

7.0
' 4.7
5.1
810
98
5.7
18
Outdoor In/Out'
Ratio

ND3 -"
ND —
ND —
ND —
ND -
ND -
ND —
Chlorinated
• Hydrocarbdns
Indoor

8.7
. 6.0
26
. 13
56
46
26
Outdoor

3.7
5.3
3.2
1.0
3.0
8.1
3.7
In/Out
Ratio

2.2
1.1
8.1
13
19
5.6
7.0
Oxygenated
Hydrocarbons '• •
Indoor

1.3
ND
ND
NO
8.5
4.3
' 1.5
Outdoor In/Out
Ratio

ND —
.• ND -
ND —
/-
NO -
ND —
ND —
ND • —
Indoor

34
21
57
11~00
220
130
75
Total
Outdoor

9.1
.10
9.4
17
16
58
16

In/Out
Ratio

3.7
2.1
6.1
65,
14
2.2
4.6
Hom.es
Nursing Home (New)
Trip 1(4/85)
Trip 2 (8/85)
Nursing Home (Old)
Trip , '7/84;
-4
-23-
- 8 y
93
,22
72
8.5
77 .
7.8
. 77
7.3
7.5
773
7.3
7.9
ND ' ' ,— -
ND —
"ND —
9.9
3.9
4.7
2.8 ,
2.5
7.3
3.5
7.6
3.2
9.6 .
• 7.2
ND
, ND
ND
ND
— 286
— 34
— 78
77
20
26
"Below the quantifiable limit.
"Not calculated
 Table 5.    Summary of Emission Results
                                         Emmission Rate foglm'h)
Aliphatic and
. Oxygenated
Aliphatic
Sample3 Hydrocarbons

Cove adhesive
Latex caulk
Latex paint (Glidden)
Carpet adhesive
Black rubber molding
Small diameter telephone
cable
Vinyl cove molding
Linoleum tile
Large diameter telephone
cable
Carpet
Vinyl edge molding
Particle board
Polystyrene 'foam
insulation
Tar paper
Primer/adhesive
Latex paint (Bruning)
Water repellant
mineral board

d
252
111 '
136
24

• 33
31 •
6.0

74
27
• 78 . • '.
27

0.79
3.2
1 3.6
-

7.7
Aromatic. .
Hydrocarbons
a
380
52 •
98
78

26
74 • • '. •
QC
OO .- "
-
2U .
9.4
7*
.1

20
.3,1
o c —
2.5
3.2
'
0.43
Halogenated
Hydrocarbons
a .
5.2
,86
.0 ,
6.88
.
0.62
4.0

4.3

0.41
• > 0. 74

7.4




••

All
Target
Compounds
>5000
637
- 249
234
103
60
v.v
46
45

38
36
30
'28

-22
6.3
6.7
3.2

7.5

loadings associated with the smoking areas
of these buildings supplements earlier work
(Repace 1980, Spengler 1985) indicating in-
creased exposure to, environmental tobacco
smoke (ETS), a probable human carcinogen,
in these buildings, which house children, the
sick and the elderly. Risk assessments have
been carried out for VOCs (Wallace, 1986;
Tancrede, 1987)  and for ETS (Repace and
Lowrey, 1985; NAS, 1986) in the home en-
vironment and have concluded that risks are
considerably greater for these chemicals in
indoor air than in outdoor air or (except for
chloroform)  'in  drinking water.  The  risks
associated with the type of buildings studied
here would be proportional to the amount of
time spent in them.              ..-'.-
  ' The second type of health effect is acute,
consisting of eye, nose and throat irritation,
headaches,  neurotoxic symptoms  such as
depression, irritability, and forgetfulness, and
 general malaise—a group of symptoms often
 described as  "Sick  Building  Syndrome"
 (SBS). Although the cause or causes of SBS
 are unknown, several hypotheses implicate
 low-level concentrations of VOCs as a possi-
 ble cause (Berglund, 1982; Molhave, 1984).

-------
    Ttblt 5     (Continued)
                                            {EmmissK>ri Rate r


'
Sample*
CftffWM biOCk
PVCppe
Duet insulation
T'®ated mefa* roofing
Unihane sealant
Fioefgtass insulation
Cxfeoor mnsral board
Interior mineral board
Ceiling '*
fletf clay brick
Plastic laminate
PfaslfC outlet povsf
Aliphatic and
Oxygenated
Aliphatic
Hydrocarbons
„
.
073
.
.
.
.
.
.
.
,
-


Aromatic
Hydrocarbons
0.39
Q53 	
0.75
0.79
0.73
0.08
0.03

"


•
1 	 , 	 •

Halogenateo
Hydrocarbons
0 15

.
0.06
-

-
-
- "
-
,
. -

All
Target
Compounds
0 54
053
0.2S
0,25
0.13
0.80
0.03
-

-
• -
-
   .Jotfit compound
   " twroteum trie cement
    *£irmston rate tor cov» *dhestves if,a mmimurri, value, sample was_pverjoadedjt is estimated'that cove adhesive'
    is one ot the htgriest emitters ctfVo/aMe organics	%	•	,	
    'Wo dtlfCMW» emutsmns              "                           .
«llLi	It, i	•
iili1
	UllLl-Zrt
       . ,11 n


1
p
ft



U
(.


Hi
Carpet


>



LA



JL


t
iJ


|j
. i
Linoleum
Tile

Ii4- 1
^UlVjiUjL^U.j
i'i	ii	i1 . !:;«:i', ,,i"-;fiOO   ,,,,'000  	750O  ,  ,	2000
                    Scanfltumber
                                 Vinyl
                                 Cove
                                 Molding
                                                      ;,5oo	rogohii7i,ii|i;750o	• 2000 _,
                                                              'Scan Number _ '    ,      ^
                                                                           Vinyl
                                                                           Edge
                                                                       '   . Molding
             BOO     7000    7500    2000.
                    Scan Number
                                                      500tOOO7500     2000
                                                              Scan Number
     ii               • •   	';,, «"    !',::»' ,-i .••           i mi     i      hi
    Figure 1.    CC/MS chromatograms of emissions samples collected from interior exposure
                 building  materials during headspace experiments ('designates the external
                 standard).
Conclusions
   The measurement method  employee '•./
VOCs (sampling on Tenax sorbem followed
by GC-MS analysis! was shown to have good
precision for nearly all target c.ompounas
Sampling  at  .three  different  flow  rates
("distributed volume" sampling) detected no
artifact formation or other sampling problems  •
   Many volatile organic compounds are at
higher concentrations in buildings than out-
doors. The sources of these elevated indoor
air concentrations include surface-coatings.
wall and floor coverings, and other building
materials. Emission rates-, ranged  up  to
several thousand /ig/m2/h.
   Concentrations of individual aromatic and
aliphatic compounds such as xylenes and
decane were elevated over outdoor levels by
factors  of  100 or more  in  the two  new
bujjdings studied. The time to reach concen-
trations comparable with outdoor levels was
estimated to be several months.
   Concentrations of respirable participates
were  elevated in smoking areas  of some
buildings. 	           "  .'   '    •

Recommendations
  This study of six buildings and its earlier
companion  study of four buildings has in-
dicated that concentrations of certain target
VOCs are elevated in buildings due to emis-
sions from certain building materials. Only
ten buildings were  monitored and only 50
building materials were tested for emissions.
Many more buildings  of various  types
(hospitals,  enclosed shopping  malls,  etc.)
where people spend a considerable fraction
of their time should be monitored before it
will be, possible to  estimate the frequency
distribution  Of VOC concentrations in such
'buildings. Many more  building materials
should be tested to determine their rates of
emission of chemicals of concern before a
trustworthy estimate of the range of emission
rates can be achieved.'
   Future   studies  need   not   employ
"distributed  volume"  sampling  on  all
samples, although limited distributed volume
sampling could be employed  to assure that
sampling problems were 'not  occurring.

References
   Berglund. B., Berglund. U.. Johansson. I.
and Lindvall. T. (1984) "Mobile laboratory for-,
sensory air quality  studies in non-industrial
environments" in Berglund.  B. Lindvall. T.
and Sundell, J. eds. Indoor Air: Sensory and
Hyperreactlvity Reactions to Sick Buildings.
 Volume 3, pp. 467-472. Swedish Council for
 Building Research, Stockholm. Sweden.
   Berglund, B., Berglund.; U.  and Engen, T.
 (1987) "Do 'Sick Buildings' Affect Human Per-
 formance? How Should One Assess Them?"

-------
                           l-11'r-rnv
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     5OG
               ,000    " 1500     2000
               Scan Number
                        Black   ,
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                        Molding
                                              500
                                        7000     7500    2000
                                        Scan Number
                                                                      Particle
                                                                      Board
   500 -   7000'     7500    2000

            Scan Number
                           Plastic
                           Outlet
                           Cover
                                                  500     1000     1500    2000
                                                          Scan Number
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        500
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                                                 500     7000     7500    2000
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                                                                     Plastic
                                                                     Laminate
       500     7000       7500    2000
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                                                   5OO    7000      7500    2000
                                                           Scan Number
figure 1.    (Continued)
m Indoor Air '87: Proceedings of the 4th In-
ternational Conference on Indoor Air Quali-
ty and Climate. 'August 17-21. 1987. Vol. 2. pp.
477-481. Institute for Water. Soil,  and Air
Hygiene. W. Berlin.               ,
  Berglund. B.. Berglund. U.. Lindvall. T. and
Nicander-Bredberg. H. (1982) "Dlfactory and
chemical characterization  of  indoor  air—
Towards 'a psychophysical model for air quali-
ty," Environ. Int. 8: 327-332.    .            '
   Handy, R.W.. et a/.. (1987) The  Total Ex-
posure Assessment Methodology (TEAM)
Study:  Standard  Operating  Procedures.
Volume IV, US Environmental Protection
Agency, EPA/600/6-87/002d, Washington, DC.
   Molhave, L., Bach, B. and Pederson, O.F.
(1984) "Human reactions during controlled '
exposures  to low concentrations of organic
gases and vapours known as normal indoor   ,
air pollutants" in Berglund, B. Lindvall. T. and
 Sundell, J. eds.  Indoor  Air,:  Sensory and
 Hyperreactivity Reactions to Sick Buildings;
 Volume 3,  pp. 431-436. Swedish Council for
 Building Research, Stockholm, Sweden.
   National Academy of ^ciences.Kigse) En-
 vironmental Tobacco Smoke: Measuring Ex-
 posures and Assessing Health Effects, Na-
 tional Academy Press, Washington, DC.
    Pellizzari, E;D., Perritt, R.,  Hartwell, T.D.,
 Michael, L.C., Whitmore, R., Handy, R.W.,
 Smith, Q, and Zelon, H. (1987) The Total Ex-
 posure Assessment Methodology (TEAM)
 Studv: Elizabeth and Bayorne, New Jersey; ',-
 Devils Lake, North Dakota, and Greensboro,
 North Carolina, Volume II, US Environmen-
 tal Protection Agency, EPA/600/6-87/002b.
 Washington, DC.
    Pellizzari, E.D., Perritt, R., Hartwell, T.D.,
  Michael,  L.C. Whitmore, R., Handy, R.W.,
  Smith, D, and Zelon, H. (1987) The Total Ex-
  posure Assessment Methodology (TEAM)
  Study: Selected Communities in Northern
  and Southern California, Volume III, US En-
  vironmental Protection  Agency,  EPA/60D7-
  6-87/002C, Washington, DC.
     Repace,,J.L. and Lowrey,  A.H. (1980) "In-
  door air pollution tobaccp smoke, and public
   health" Science 208: 895-914.
     Repace, J. L. and Lowrey, A.H: (1985) "A
   Quantitative Estimate of Nonsmokers' Lung
   Cancer Risk from Passive Smoking" Environ.
   Int.  11 3-22.
 '   Sheldon, L.S.. Handy, R. W., Hartwell, T.D.,
   Whitmore, R.W., Zelon, H.S., and Pellizzari,,
   E.D., (1988) Indoor -Air Quality in Public
   Buildings: Volume I, US EPA. Washington,
   DC.                             -
     Spengler,  J.D., Treitman, R.D., Tosteson,
   T.D., Mage,  D.T, and Soczak,  M.L., (1985)
    ''Personal Exposures  to  Respirable Par'
   ticulates and Implications  for  Ambient Air
    Quality  Standards  and  Health  Effects
    Research," Enwron.Sc/. 4:347-353.

-------
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                                                  500       7000    7500    2000
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Flgurt 2,    GC/MS chromatograms of emissions samples  collected from solvent  based
            bfiilding materials  during  headspace experiments  ("designates  the  external
'  .,         standard).
  Spicer, C. W., et at (1986) "Intercompanson
of Sampling Techniques for Toxic Organic
Compounds in Indoor Air," Hochheiser, S.
and Jayanti, R.K.M., Eds. in Proceedings of
the 1986 EPA-APCA Symposium on Meas-
urement  of Toxic Air Pollutants.  USEPA
600/9-86-013; Air Pollution Control Associa-
tion, Pittsburgh, PA.
  Tancrede, M., Wilson,  R., Zeise, L.. and
Crouch,  E.A.C.  (1987) "The  Carcinogenic
Risk of Some Organic Vapors Indoors:  A
Theoretical  Survey"  Atmos Environ
21:2187-2205.
  Wallace,  L. A., Pellizzari. E.D.. Leaderer.
B. R, Zelon, H. and Sheldon. L. (1985) "Emis-,
sions of Volatile Organic Compounds from
Building Materials and Consumer Products"
Atmos Em. 21:385-393.
  Wallace,  Lance A. (1986) "Cancer Risks
from Organic Chemicals in the Home" in En-
vironmental risk management—Is Analysis
Useful?, Proceedings of  an APCA Interna-
tional Specialty Conference, pp. 14-24. Air
Pollution Control Association, Pittsburgh. PA.
SP-55.
  Wallace,  L. (1987a)  The Total Exposure
Assessment Methodology (TEAM)  Study:
Summary and Analysis,  Volume I, US En-
vironmental Protection Agency, EPA/600/-
6-87/002a, Washington, DC.
  Wallace,  L. (1987b)  "Emission Rates of
Volatile Organic Compounds from Building
Materials and  Surface Coatings"  in  Pro-
ceedings of the 1987 EPA/APCA Symposium
on Measurement of Toxic and Related Air
Pollutants, pp. 115-122. Air Pollution Control
Association, Pittsburgh, PA.
  Wallace, L.. Jungers, R.. Sheldon.  L.. and
Pellizzari,  E.  (1987c)  "Volatile  Organic
Chemicals in 10 Public-Access Buildings" in
Indoor Air '87: Proceedings of the 4th Inter-
national Conference on Indoor Air  Quality
and Climate. Auqust 17-21. 1987. Vol. 2. pp
188-192.  Institute ;or Water.  Soil, and Air
Hygiene, W. Berlin.

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Figure 2.    (Continued!  .   -        .       ' '    '    .


Tab/e6    Average A,r Exchange Measurements for Field Monitoring Trips
                                        Air Exchange Rate (Changes/h) ± S.D.
Location
New Buildings ,
'Office
.Nursing Home
Trip
3 •
1
2

Overall
0.44 ± 0172.'
0.60 ±0.08
0.30 ±0.70
' 0.54 ± 0.74 ,
Day
0.50 ± 0.72
0.58 ± 0.08
0.38 ± 0.07
0.65 ± 0.70
Night
0.95 ± 0.64
0.08 ± 0.08
0.37 ± 0.08
0.67 ± 0.08
0.27 ± 0.03
0.43 + 0.08
we
 Old Buildings


 Off/ce

-OfficeSScr.00,
.0.44 ±0,79


 0.50. ± 1.10;
0.49 ±0.14-.

0.57 ± 0.08


a54±a33
0.39 ± 0.23

0.45 ± 0.08

0.35 ± 0.79
    •L-Shrtdon. H. Zelon. J.. Sickles, C Eafon.a^^a^e,, ar£ ^Research
      Triangle Institute, Research Triangle Park. NC 27709.





      be available only from:                  ;
             National Technical Information Service
             5285 Port Royal Road
             Springfield. VA22161
             Telephone: 703-487-4650
     The EPA Project Officer can be contacted at:
             Environmental Monitoring Systems Laboratory
             U.S. Environmental Protection Agency
             Research Triangle Park, NC 27711

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