svEPA
                          United States
                          Environmental Protection
                          Agency
                                     Risk Reduction
                                     Engineering Laboratory
                                     Cincinnati, OH 45268
                          Research and Development
                                     EPA/600/S-92/051   October 1992
ENVIRONMENTAL
RESEARCH   BRIEF
                      Waste Reduction Activities and Options for a
                         Remanufacturer of Automobile Radiators

                                    Kevin Gashlin and Daniel J. Watts*
Abstract
The U.S.  Environmental Protection Agency (EPA)  funded a
project with  the New Jersey  Department of Environmental
Protection and Energy (NJDEPE) to assist in conducting waste
minimization  assessments at 30 small- to medium-sized busi-
nesses in  the state of New Jersey. One of the sites selected
was a facility that remanufactures automobile radiators. The
process involves cleaning the radiator, locating and repairing
any leaks, painting, and reinstallation. A site visit was made in
1990 during which several opportunities for waste minimization
were identified.  Options  identified  include changes in the
cleaning  procedure, more efficient rinsing operations,  and
change of  paint from solvent-based to water-based. Implemen-
tation of the identified waste minimization opportunities was not
part of the program. Percent waste reduction, net annual sav-
ings, implementation costs and payback periods were estimated.

This Research Brief was developed by the Principal Investigators
and EPA's Risk Reduction  Engineering Laboratory in Cincinnati,
OH, to announce key findings of this completed assessment.


Introduction
The environmental issues facing industry today have  expanded
considerably beyond traditional concerns. Wastewater, air emis-
sions, potential soil and groundwater contamination, solid waste
disposal, and employee health and safety have become increasingly
important concerns. The management and disposal of hazardous
substances, including both process-related wastes and residues
from waste treatment, receive significant attention because of regu-
lation and economics.

As environmental issues have become more complex, the strategies
for waste management and control have become more systematic

* New Jersey Institute of Technology, Newark, NJ 07102
                         and integrated. The positive role of waste minimization and pollution
                         prevention within industrial operations at each stage of product life is
                         recognized throughout the world. An ideal goal is to manufacture
                         products while generating the least amount of waste possible.

                         The Hazardous Waste Advisement  Program (HWAP) of the Divi-
                         sion of Hazardous Waste Management, NJDEPE, is pursuing the
                         goals of waste minimization awareness and program implementation
                         in the state. HWAP, with the help of an EPA grant from the Risk
                         Reduction Engineering Laboratory, conducted an Assessment of
                         Reduction and Recycling Opportunities for Hazardous Waste (AR-
                         ROW) project. ARROW was designed to assess waste minimization
                         potential across a broad range of New Jersey industries. The
                         project targeted 30 sites to perform waste minimization assessments
                         folbwing the approach outlined in EPA's Waste Minimization Op-
                         portunity Assessment Manual (EPA/625/7-88/003). Under contract
                         to NJDEPE,  the  Hazardous Substance Management Research
                         Center at the New Jersey Institute of Technology (NJIT) assisted in
                         conducting the assessments. This research  brief presents an as-
                         sessment of the remanufacturing of automobile radiators (1 of the
                         30 assessments  performed)  and provides recommendations for
                         waste minimization options resulting from the assessment.


                         Methodology of Assessments
                         The assessment process was coordinated by a team of technical
                         staff from NJIT with experience in process operations, basic chem-
                         istry, and environmental concerns and needs. Because the EPA
                         waste minimization manual is designed to be primarily applied by
                         the inhouse staff of the facility, the degree of involvement of the
                         NJIT team varied according to the ease with which the facility staff
                         could apply the manual. In some cases, NJITs role was to provide
                         advice. In others, NJIT conducted essentially the entire evaluation.
                                                                               Printed on Recycled Paper

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The goal of the project was to encourage  participation  in the
assessment process by management and staff at the facility. To do
this, the participants were encouraged to  proceed through the
organizational steps outlined in the  manual. These steps can be
summarized as follows:

  • Obtaining corporate  commitment to  a waste minimization
    initiative
  • Organizing  a task force or similar group to carry out the
    assessment
  • Developing a policy  statement regarding waste minimiza-
    tion for issuance by corporate management
  • Establishing tentative waste reduction goals to be achieved
    by the program
  • Identifying waste-generating sites and processes
  • Conducting a detailed site  inspection
  • Developing a list  of options which may  lead to the waste
    reduction goal
  • Formally analyzing the feasibility  of the various options
  • Measuring the effectiveness of the options and continuing
    the assessment.

Not every facility was able to follow these steps as presented.  In
each case, however, the identification of  waste-generating sites and
processes, detailed site inspections, and development of options
was carried out.  Frequently, it was necessary for a high degree  of
involvement by  NJIT to accomplish these  steps. Two common
reasons for needing outside participation were a shortage of techni-
cal  staff within the company and  a need to develop an agenda for
technical action before corporate commitment and policy statements
could be obtained.

It was not a goal of the ARROW project to participate  in the
feasibility analysis or implementation steps.  However, NJIT offered
to provide advice for feasibility analysis if requested.

In each case, the NJIT team made several site visits to the facility.
Initially, visits were made to explain the EPA manual and to encourage
the facility through the organizational stages. If delays  and compli
cations  developed, the team offered assistance in the technical
review, inspections, and option development.

No  sampling or laboratory analysis was undertaken as part of these
assessments.


Facility Background
The facility refurbishes  motor vehicle radiators, both from automo-
biles and from heavier commercial vehicles.  In a real sense, this
type of facility is  in the  pollution preventbn business by extending
the useful life  and allowing  reuse of equipment  which otherwise
would find its way into the waste stream.  The process used involves
removal of the radiator from the vehicle, cleaning the radiator, finding
and repairing any leaks, painting,  and reinstallation into the vehicle
This facility  is located  in an urban  area and  employs about 20
people.


Remanufacturing Process
The remanufacturing process is conceptually simple—the radiator is
removed from the  vehicle, cleaned,  leaks detected and repaired,
painted, and reinstalled in the vehicle. These individual steps however
have potential for waste generation and each requires separate
consideration from a pollution preventbn perspective.

The removal process has potential for generation of waste streams
by capturing freon from air conditioning equipment in the vehicles
and from collecting ethylene glycol antifreeze contained in the
radiators.

The cleaning process is rigorous. The radiator is immersed in a tank
of caustic solution (typically 40% to 50 % sodium hydroxide) which is
heated to 140-200 °F. The radiator remains  in this tank, frequently
called a boil-out tank, for 15 to 60 min. The objective of this cleaning
step is  to soften or remove deposits, scale, corrosion, or other
foreign materials  from the radiator. After the cleaning, the radiator is
removed from the boil-out tank and the caustic solutbn is allowed to
drain. The radiator is then rinsed using approximately 5-10 gal of
water in a rinse tank. This rinsing is most frequently accomplished
using a flow  through  system with fresh  tap  water.  The  primary
objective of this step is to remove adhering caustb solution and any
bosened scale from the inside and outside of the radiator.

The rinsed radiator is leak tested in a test tank. Leak testing involves
hooking a compressed air line to  one end of the radiator, plugging
the other end,  and  submerging the radiator in  the test tank. Leaks
are located by  the stream  of bubbles which appear in the water and
are repaired by soldering. The soldering involves application of a flux
or muriatb acid to prepare the surface, followed by spot heating and
application of the solder. The soldering usually takes place while the
radiator is supported on a rack over the test tank.

After leak repairs are completed, the  radiator is painted using a
solvent-based  black enamel paint and reinstalled in the vehicle. The
painting is done in a spray booth.


Existing Waste Management Activities
At the time of  the assessment, the facility had questbns about its
waste management practbes and an interest in exploring pollutbn
prevention options. At the time of the assessment, the freon from the
air  conditioning system was vented to the atmosphere when  the
radiator was removed from the vehicle. Similarly, the engine coolant
was discharged to the POTW. No information  was available about
the quantity  of this  material whbh was  generated. Following  the
assessment, the freon is captured, purified  and reused  onsite.
Similarly, the antifreeze solutbn is collected and recycled. Although
these streams are  peripheral to the radiator remanufacturing,  the
changes represent advances in pollutbn prevention at the  facility.
Data to measure the impact of these changes is not yet available.

The boil-out tank generates waste whbh can be described as a
highly alkaline  sludge containing heavy metals. The usual practice is
to dump the boil-out tank when the build up of sludge on the bottom
is sufficient to interfere with the insertion of the radiator. In addition,
the supernatant liquid  from the boil-out tank  is periodically partially
discharged to the POTW. Both the sludge and  the aqueous discharge
are highly alkaline  and the metal content frequently exceeds  the
limits acceptable  for discharge. The sludge accumulates at the rate
of about 3 drums per year and is sent for land disposal. It was not
possible to determine the volume of the discharge to the POTW.

The flow through the rinse tank is estimated to be about 300 gal of
water per day.  This flow is discharged to the POTW and any sludge
which is collected in the tank is combined with the sludge from the
boil-out tank for disposal. The test tank, about 30 gal,  is dumped to
the POTW whenever it becomes  so cbudy  as to prevent easy
detectbn of leaks. The frequency of dumping  depends upon the use
of the tank, and to  a very large extent the turbidity of the test tank
depends upon the effectiveness of the preceding rinsing step. The
test tank is dumped about once each month. Any sludge in this tank
is also collected and combined with the boil-out tank sludge.

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The radiators are spray painted with solvent-based paint. Approxi-
mately 600 gal of paint at 63% solvent levels is used annually. This
means that 378 gal of solvent is released to the atmosphere. The
fitters from the  spray  booth which captured overspray were dried
and sent for disposal as non-hazardous waste.


Waste Minimization Opportunities
The type of waste currently generated by the facility, the source of
the waste, the quantity of the waste and the annual treatment and
disposal costs are given in Table 1.

Table 2 shows the opportunities for waste  minimization recom-
mended for the facility. The type of waste, the minimization opportu-
nity, the possible waste reduction and associated savings, and the
implementation cost along with the payback time are given in the
table. The quantities of waste currently generated at the facility and
possible waste reduction depend on the level of activity of the facility.

ft should be noted that the economic savings of the minimization
opportunity,  in  most  cases,  results  from the need for  less raw
material and from reduced present and future costs  associated with
waste treatment  and  disposal. It should also be  noted that the
savings given for each opportunity  reflect the savings achievable
when implementing each waste minimization opportunity indepen-
dently and do not reflect  duplication of savings that would  result
when the opportunities are implemented in a package.

The cost savings are  calculated both in terms of avoided costs of
waste disposal and recovery of any value of raw material used
again. Also, no equipment depreciation is factored into the calcula-
tions.

This facility affords two areas of opportunity for pollution preven-
tion—the painting area and the water quality and quantity manage-
ment area.

At the time of the assessment two types of options were developed
for the painting process—improve the spray procedure to reduce the
volume  of overspray  and use a water-based  paint to  paint the
remanufactured radiators. There was no water-based paint available
for this  purpose.  Since the assessment,  however,  the facility has
discovered, evaluated, and adopted for use a water-based latex
paint. The change was  not  without difficulty, however,  because
some of the customers of the business  complained that they had
received an inferior paint job because the appearance was not the
same as that of previous jobs. This was overcome through discus-
sion and education with the customers.

The water management problem is somewhat more complex. Two
types of concern are the pH of the system and the metal content of
the system. In addition there is an interest in  reducing the volume of
sludge which the remanufacturing process  generates. To a large
                                         degree reduction of the quantity of sludge  is independent of the
                                         process used because it results from the cleaning of foreign materi-
                                         als from the used radiators which are processed through the facility.

                                         One approach to reducing the boil-out tank problem is to eliminate
                                         that process entirely.  An alternative  process  called  "rodding" is
                                         essentially a manual reaming. This coupled with mechanical and
                                         spot cleaning has been used in some similar facilities in place of the
                                         boil-out tank. This alternative eliminates the boil-out and  rinse tank
                                         difficulties.

                                         If it is  decided to continue with the caustic boil-out tank  approach,
                                         then the goal should be to reduce the total water usage. One way to
                                         accomplish this is to develop a counter-flow rinsing technique which
                                         would  require the addition of at least one more  tank The objective
                                         would  be to keep as much  active chemical  in the  boil-out tank as
                                         possible.  The modification to the present procedure would involve
                                         increased attention to remove as much caustic solution as possible
                                         when  the radiator  is removed from the bath.  This would mean
                                         increased drip time to albw as much liquid as possible to drip back
                                         into the boil-out  tank. In addition, it  would be desirable to use
                                         compressed air to force out as much of the liquid as possible which
                                         may be inside the radiator.

                                         This nearly drip-free unit should  be placed in  the rinse tank and
                                         rinsed in  the usual  way. The dripping and air-forcing  procedure
                                         should be repeated here. The rinsed radiator should then be immersed
                                         in a newly added tank, which can be termed a drag-out tank for
                                         further removal  of  contaminants.  Following this step,  again  with
                                         appropriate drip time and conditions, the radiator can be placed in
                                         the leak detection tank.

                                         To make  this system most effective, the water from lightly contami-
                                         nated  tanks  would be used as make-up water for more heavily
                                         contaminated tanks. For example, because the boil-out tank is
                                         heated, water is tost through evaporation. Water from the rinse tank
                                         can be used to replace that tost water in the boil-out tank. The drag
                                         out tank water can be used to refill the rinse tank, and the leak tank
                                         can be used to refill the  drag out tank. Tap water should be used
                                         only in the leak tank. If sludge or solids appears in any of the tanks
                                         except the boil out tank, it can be removed by a simple f iltratton  prior
                                         to transferring the water to the next tank.

                                         This approach concentrates the  metals and caustic in the boil out
                                         tank and maintains relatively constant levels in the other tanks. This
                                         process eliminates much of the discharge to the POTW. In order to
                                         make this practicable, it is necessary to avoid contamination of these
                                         tanks with other materials. For example, the practice of soldering the
                                         radiators while they rest over the leak tank should be stopped.  This
                                         approach allows flux and solder to drop into the tank, contaminating
                                         the water. The  soldering should  be  done  elsewhere where  the
                                         residues can be captured and handled  more appropriately. Ideally, a
                                         non-lead  solder with the necessary  performance  characteristics
                                         should be identified and used.
  Table 1. Summary of Current Waste Generation


  Waste Generated           Source of Waste
 Alkaline Metal-Contain-
  ing Sludge
Solids from boil-out tank and
from rinse and leak tanks
  Volatile Solvents
Drying of solvent-based paint
                                   Annual Quantity
                                     Generated
 3 drums
 Aqueous Waste to POTW Flowthrough from rinse tank and        100,000 gal
                         occasional discharge from other tanks     (estimate)
378 gal
                      Annual Waste
                   Management Costs
$1,650
                                                                  30
                                                                                       (no direct
                                                                                    treatment costs)
                                                                      6U.S. GOVERNMENT PRINTING OFFICE: 1994 - 550467/80189

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 Table 2.  Summary of Recommended Waste Minimization Opportunities
 Waste Stream
 Reduced
Minimization Opportunity
   Annual Waste Reduction           Net     Implementation   Payback
    Quantity        Percent   Annual Savings      Cost      Years *
 Alkaline Metal-
 Containing Sludge
 POTW Discharge
Convert to rodding and mechan-
ical cleaning. This approach
also eliminates much discharge to
POTW.
Implement counterflow rinsing
and tank refill procedures
leading to zero discharge.
3 drums
               100
$1,650             $200          0.1
(It should be recognized that this
technique does produce solid waste
which must be managed and the approach
is highly labor intensive.)
100,000 gal     100
  30
                                                                                                    25,000
                                                                                                  (estimate)
                                 833
 Volatile Solvents
Change to water-based paints
                                                        378 gal
               100
 (This option must be considered not in light of
 current management costs, rather it should be
 compared with pretreatment costs for the entire
 POTW discharge which likely would soon be
 required for facilities of this type to remain
 in operation. This cost would be expected to
 be substantially higher than the option addressed
 here.)

  0                 0            none
(This option represents essentially no net savings
and no net cost, but is a positive pollution
prevention initiative.)
* Savings result from reduced raw materials and treatment and disposal costs when implementing each minimization opportunity independently.
Where the loss of water by evaporation from the boil-out tank is not
rapid enough to allow the levels of contaminants in the other tanks to
remain in a workable range, it may be necessary to treat the rinse
water. This may be as simple as addition of a storage/settling tank
for the  rinse water or may get more  complex depending upon
conditions at the individual facility. Monitoring of pH and acid addition
to maintain neutrality may be necessary.

When it is necessary to remove sludge from the boil-out tank, it is
suggested that the tank  contents be filtered, the  solids dried  or
compressed and the liquid returned to the tank for reuse. The solids
should be disposed of as hazardous waste, or more preferably, sent
to a secondary recovery facility to reclaim the metal values.

Regulatory Implications
There are no significant regulatory issues which would impede
the implementation of pollution prevention initiatives at this facility. In
fact, in view of the occasional exceedance of acceptable limits to the
POTW, it is likely that the facility would have to install some type of
pretreatment capability. Acceleration of identification and implemen-
                                           tation of pollution prevention practices may albw the facility to avoid
                                           the need for pretreatment by eliminating discharges to the POTW. It
                                           is expected that the process alterations to accomplish the pollution
                                           prevention approach would be substantially less costly than installation
                                           of a pretreatment capability.

                                           This  Research Brief summarizes a part of the work done under
                                           cooperative Agreement No. CR-815165 by the New Jersey Institute
                                           of Technology under the sponsorship of the New Jersey Department
                                           of Environmental Protection and Energy and the U.S. Environmental
                                           Protection Agency.  The EPA Project Officer was Mary Ann Curran.
                                           She can be reached at:

                                                   Pollution  Prevention  Research Branch
                                                   Risk Reduction  Engineering Laboratory
                                                   U.S. Environmental Protection Agency
                                                   Cincinnati, OH 45268
                                           * Mention of trade names or commercial products does not constitute endorsement
                                            or recommendation for use.
  United States
  Environmental Protection Agency
  Center for Environmental Research Information
  Cincinnati, OH 45268

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