vvEPA
                        United States
                        Environmental Protection
                        Agency
                        Research and Development
                                   Risk Reduction
                                   Engineering Laboratory
                                   Cincinnati, OH 45268
                                   EPA/600/S-92/056  October 1992
ENVIRONMENTAL
RESEARCH   BRIEF
                     Waste Reduction Activities and Options for a
                     Laminator of Paper and Cardboard Packages
                                   Hanna Saqa and Daniel J. Watts*
Abstract
The U.S. Environmental Protection Agency (EPA) funded a
project with the New Jersey Department of Environmental
Protection and Energy (NJDEPE) to assist in conducting waste
minimization assessments at 30 small- to medium-sized busi-
nesses in the state of New Jersey. One of the sites selected
was a facility that laminates paper and cardboard substrates
which are  used for packaging purposes. The lamination is
accomplished by application of a liquid laminate to the surface
of the substrate followed by curing.  The facility  also applies
metallic coatings to similar substrates by transfer from mylar
films. A site visit was made in 1990  during which several
opportunities for waste minimization  were identified. Options
identified included changing to UV curing for laminates and
onsite distillation and reuse of solvents. Implementation of the
identified waste minimization opportunities was not pan" of the
program. Percent waste  reduction, net annual savings, imple-
mentation costs and payback periods were estimated.

This Research Brief was developed by the Principal Investiga-
tors and EPA's Risk Reduction Engineering Laboratory in Cin-
cinnati, OH, to announce key findings  of this completed as-
sessment.


Introduction
The environmental issues facing industry today have expanded
considerably beyond traditional concerns. Wastewater, air
emissions, potential soil and groundwater contamination, solid
waste disposal, and employee health and safety have become
increasingly important concerns. The management and dis-
posal of hazardous substances, including both process-related
* New Jersey Institute of Technology, Newark, NJ 07102
                        wastes and residues from waste treatment, receive significant
                        attention because of regulation and economics.

                        As environmental issues have become more  complex, the
                        strategies for waste management and control  have become
                        more systematic and integrated. The positive  role of waste
                        minimization and pollution prevention within industrial operations
                        at each stage of product life  is  recognized throughout the
                        world. An ideal goal is to manufacture products while generat-
                        ing the least amount of waste possible.

                        The Hazardous Waste Advisement Program (HWAP) of the
                        Division of Hazardous Waste Management, NJDEPE, is pursu-
                        ing the goals of waste minimization awareness and program
                        implementation in the state. HWAP, with the help of an EPA
                        grant from the Risk Reduction Engineering Laboratory, con-
                        ducted an Assessment of Reduction and Recycling Opportuni-
                        ties  for Hazardous Waste (ARROW) project.  ARROW was
                        designed to assess waste minimization  potential  across  a
                        broad range of New Jersey industries. The project targeted 30
                        sites to perform waste minimization assessments following the
                        approach outlined in EPA's Waste Minimization Opportunity
                        Assessment Manual (EPA/625/7-88/003). Under contract to
                        NJDEPE, the Hazardous Substance  Management  Research
                        Center at the New Jersey Institute of Technology (NJIT) assisted
                        in conducting the assessments. This  research  brief presents
                        an assessment of the  lamination of paper and cardboard
                        substrates which  are used to make packaging (1  of the 30
                        assessments  performed)  and provides recommendations for
                        waste minimization options resulting from the assessment.


                        Methodology of Assessments
                        The assessment process was coordinated by a team of techni-
                        cal  staff from NJIT with experience  in process operations,
                        basic chemistry, and environmental concerns and needs. Be-
                                                                          ,..C> Printed on Recycled Paper

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  cause the EPA waste minimization manual is designed to be
  primarily applied by the inhouse staff of the facility, the degree
  of involvement of the NJIT team varied according to the ease
  with which the facility staff could apply the manual. In some
  cases,  NJIPs role was to provide advice.  In  others,  NJIT
  conducted essentially the entire evaluation.

  The goal  of the  project was to encourage participation in the
  assessment process by management and staff at the facility.
  To do this, the participants were encouraged to proceed through
  the organizational  steps outlined  in the  manual. These steps
  can be summarized as follows:

   • Obtaining corporate commitment to a waste minimization
     initiative
   • Organizing a task force or similar group to carry out the
     assessment
   • Developing a policy statement regarding waste minimiza-
     tion for issuance by corporate management
   • Establishing tentative waste reduction goals to be achieved
     by the program
   • Identifying waste-generating sites and processes
   • Conducting a detailed site inspection
   • Devebping a list of options which may lead to the waste
     reduction goal
   • Formally analyzing the feasibility of the various options
   • Measuring the effectiveness of the options and continuing
     the assessment.

 Not every  facility was able to follow these steps as presented.
 In  each case,  however, the identification  of waste-generating
 sites and processes, detailed site inspections, and development
 of options  was carried out. Frequently, it was necessary for a
 high degree of involvement by NJIT to accomplish these steps.
 Two common reasons for needing outside participation were a
 shortage of technical staff within the company  and a need to
 develop an agenda for technical action before corporate com-
 mitment and policy statements could be obtained.

 It was not a goal of the ARROW project  to participate in the
 feasibility  analysis  or  implementation  steps. However, NJIT
 offered to provide advice for feasibility analysis if requested.

 In each  case, the NJIT team made several site visits to the
 facility.  Initially, visits were made to explain the EPA manual
 and to encourage the facility through the organizational stages.
 If delays and complications developed, the team offered assis-
 tance in the technical review, inspections,  and option develop-
 ment.

 No sampling or laboratory analysis was undertaken as part of
 these assessments.


 Facility Background
 The facility is a  manufacturer  of oil-based  and water-based
 paints sold for general purpose use.  In addition, the company
 produces painting supplies such as spackle and caulking com-
 pound. The company purchases solvents, pigments, and addi-
 tives and blends them in the proper formulation to create their
 product line. The  materials are then packaged. In order to
 maintain  quality and product consistency,  it is necessary to
 clean the mixing and filling equipment to prevent contamination.

 The facility  is located in an urban area and empbys about 125
 people. This particular  facility has been in operation  for more
than 50 years. Substantive pollution prevention concepts have
 already been introduced  into the operations of  this facility,
 including distillation and reuse of waste solvents.


 Manufacturing Process
 The production of oil-based paints is accomplished by combining
 and blending the required raw  materials such as pigments,
 resins, co-solvents,  and additives with the paint solvents such
 as toluene or xylene to achieve the required product specifica-
 tion. When color or production changes are made, the tanks
 and equipment are  washed with solvents. The  finished prod-
 ucts are packaged and prepared  for shipment from the facility.

 The production of latex or water-based paints is similar except
 that different types of raw materials are used  in production and
 that the solvent used is water. As in the oil-based productbn,
 color or production changes require washing of the tanks and
 equipment, in this case with water. The finished products are
 packaged and prepared for shipment from the facility.

 The facility  also  produces other types of  products for the
 painting industry including  spackling compounds and  caulking
 materials. The production process for these types of materials
 are similar—raw  materials are  purchased,  formulated,  and
 blended according to specifications, packaged, and  shipped
 from the facility. The major difference is that these products are
 solids rather than liquid, so the use of solvents and equipment
 cleaning needs are substantially different. At the request of the
 facility, this assessment focussed on the paint manufacturing
 area.


 Existing Waste Management Activities
 The company has already instituted a  program of pollution
 prevention. This  is perhaps best  illustrated by the addition of
 distillation equipment for recovery and reuse of waste solvents.
 The current waste management  activities at  the facility dem-
 onstrate an awareness of pollution prevention concepts.

 For the oil-based paints, the first identified waste stream is the
 waste  solvent used in  the washing  of the  equipment.  This
 waste stream which contains paint pigments and other additives
 is generated at  a rate  of about  1100 gal/wk. The stream is
 distilled onsite in  a  300-gal capacity still. The  still bottoms,
 about 110 gal/wk, is a very dry material which  is sent offsrte for
 disposal as hazardous waste. Any filters or dust collectors
 used to filter batches of paint are  collected, dried and sent out
 for disposal as nonhazardous waste based upon their lack of
 content of hazardous material. VOCs from evaporating solvent
 is another waste stream  but the volume could not be estimated.

 For the water-based  paints, the first identified waste stream is
 the washings from cleaning the equipment between batches.
 This wash water contains pigments and other additives and in
 many ways can be  considered to  be very dilute  paint.  The
 wash waters are segregated by color in  55-gal drums  prior to
 onsite  processing. The  individual drums are  combined in a
 1000-gal tank and a polymeric flocculent is added to  remove
the solids. The flocculated mixture is passed  through  a drum
filter, the solids are removed and dried  and the liquid is  dis-
charged to a POTW. The approximately 1500 Ib/wk of dried
solid, is  sent offsite for disposal as nonhazardous waste.  Any
filters or dust collectors used to  filter batches of this  type  of
paint are collected, dried and sent out for disposal as nonhaz-
ardous waste. They are  maintained separately from the similar
materials from the oil-based paint productbn.

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Waste Minimization Opportunities
The type of waste  currently generated  by the facility,  the
source of the waste, the quantity of the waste and the annual
treatment and disposal costs are given in Table 1.

Table 2 shows the opportunities for waste minimization recom-
mended for the facility. The type  of  waste, the minimization
opportunity, the possible waste reduction and associated sav-
ings, and the implementation cost along with the payback time
are given  in the table. The quantities of waste currently gener-
ated at the facility and possible waste  reduction depend on the
level of activity of the facility.

It should be noted that the economic savings of the minimiza-
tion opportunity, in most cases, results from the need for less
raw material and from reduced present and future costs asso-
ciated with waste treatment and disposal. It should  also be
noted that the savings  given for each opportunity reflect the
savings achievable when implementing each waste minimization
opportunity  independently and do not reflect  duplication of
savings  that  would result when the opportunities  are imple-
mented  in a  package. Also, no  equipment  depreciation is
factored into the calculations.

The two  major options  for pollution prevention at  this facility
consist of completion of the move toward UV coatings and
away from solvent-based coatings. This effort is complicated
by customer demands  and  specifications  which require  the
continued use of solvent-based  laminates. Continued  educa-
tional efforts and perhaps improved  performance  of  the  UV
coatings may be required to  change this situation.

Because cleaning of the equipment will still be required after
changing to UV coating laminates, it  is recommended that a
* Mention of trade names or commercial products does not constitute endorsement
 or recommendation for use.
                                       single solvent, ideally one with relatively low toxicity, be se-
                                       lected for this purpose. That solvent should be segregated and
                                       a distillation capability obtained for the facility to allow recycling
                                       and reuse. This will create another waste stream,  the still
                                       bottoms, but the volume of that stream will be substantially less
                                       than the total volume of the washings.

                                       The practice of using washing solution as makeup or thinner
                                       solvent for application of new batches should be continued and
                                       expanded where possible. Additionally, care should be taken to
                                       keep containers of volatile solvents covered when not in use.
                                       This will reduce the amount  which  evaporates into the atmo-
                                       sphere.


                                       Regulatory  Implications
                                       There are no significant regulatory issues which would impede
                                       the implementation of additional pollution prevention initiatives
                                       at this facility. Increased regulatory attention to air quality may
                                       spur the development of  additional types  of UV coatings for
                                       lamination purposes, addressing some of the performance and
                                       appearance concerns of clients who insist upon solvent-based
                                       lamination. A need remains for an outlet for the residual mylar
                                       film. This may  not be a regulatory issue, but increased atten-
                                       tion to solid waste disposal may  develop new options for
                                       material of this type

                                       This Research  Brief summarizes a part of the work done under
                                       cooperative Agreement No.  CR-815165 by the  New Jersey
                                       Institute of  Technology under the  sponsorship  of the  New
                                       Jersey  Department of Environmental Protection  and Energy
                                       and the U.S. Environmental Protection Agency. The EPA Project
                                       Officer was Mary Ann Curran. She can be reached at:

                                               Pollution Prevention  Research Branch
                                               Risk Reduction Engineering Laboratory
                                               U.S. Environmental Protection Agency
                                               Cincinnati, OH 45268
 Table 1.  Summary of Current Waste Generation
 Waste Generated
   Source of Waste
 Mixed Organic Solvents   Washing of equipment used to
                       apply coating to stock
 Volatile Solvents


 Metallized Mylar Film
Solvents driven off from
solvent-based coatings

Excess from stamping operation
Annual Quantity
  Generated
 40 drums


  > 1000 gal


  Variable
  (Estimated 2000 Ib)
  Annual Waste
Management Costs
                                                          $4,000
(Cost of operating thermal
oxidation system)

65/ton
                                                                     *U.S. GOVERNMENT PRINTING OFFICE: MM - S50-M7/WISI

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Table 2.   Summary of Recommended Waste Minimization Opportunities

Waste Generated       Minimization Opportunity
Washing Solvents
Acquire distillation capability
to allow recycle and reuse of
solvent
                                                   40 drums
                                                                           Implementation  Payback

Volatile Solvents

Complete changeover to UV
laminates
Quantity Percent
> 1000 gal 100
Annual Savings
Cost of operation
of thermal oxidizer
Cost
$0
Years '
immed
100     $4000
        (However a still bottoms waste
        stream will be created.)
                                                                                                     5000
                                                                                           1.2
* Savings result from reduced raw material and treatment and disposal costs when implementing each minimization opportunity independently.
   United States
   Environmental Protection Agency
   Center for Environmental Research Information
   Cincinnati, OH 45268

   Official Business
   Penalty for Private Use
   $300

   EPA/600/S-92/056
                                                                              BULK RATE
                                                                        POSTAGE & FEES PAID
                                                                                  EPA
                                                                           PERMIT No. G-35

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