SEPA United States Environmental Protection Agency Risk Reduction Engineering Laboratory Cincinnati, OH 45268 Research and Development EPA/600/S-94/013 September 1994 ENVIRONMENTAL RESEARCH BRIEF Waste Minimization Assessment for a Manufacturer of Felt Tip Markers, Stamp Pads, and Rubber Cement Richard J. Jendtucko*, Todd M. Thomas*, and Gwen P. Looby** Abstract The U.S. Environmental Protection Agency (EPA) has funded a pilot project to assist small and medium-size manufacturers who want to minimize their generation of waste but who lack the expertise to do so. In an effort to assist these manufactur- ers Waste Minimization Assessment Centers (WMACs) were established at selected universities and procedures were adapted from the EPA Waste Minimization Opportunity As- sessment Manual (EPA/625/7-88/003, July 1988). That docu- ment has been superseded by the Facility Pollution Prevention Guide (EPA/600/R-92/088, May 1992). The WMAC team at the University of Tennessee performed an assessment at a plant that manufactures felt tip markers, stamp pads, and rubber cement. Plastic components for the markers are formed in injection molding machines. A porous filler is inserted into the marker case and ink is injected into it. The endplug, nib, and cap are added to the marker, which is then labeled and pack- aged. The first step in stamp pad production is the injection molding of plastic double-hinged stamp pad cases. Three types of stamp pads are manufactured: felt, foam, and self-inking. The pads are prepared and inserted into the cases. Rubber cement is manufactured by mixing synthetic rubber strips and solvent. The team's report, detailing findings and recommenda- tions, indicated that a large quantity of scrap plastic is gener- ated by the injection molding of markers and stamp pad cases, and that significant cost savings could be achieved by segre- gating scrap plastic and reusing it in subsequent production runs. This Research Brief was developed by the principal investiga- tors and EPA's Risk Reduction Engineering Laboratory, Cincin- nati, OH, to announce key findings of an ongoing research * University of Tennessee, Department ol Engineering Science and Mechanics " University City Science Center, Philadelphia, PA project that is fully documented in a separate report of the same title available from University City Science Center. Introduction The amount of waste generated by industrial plants has be- come an increasingly costly problem for manufacturers and an additional stress on the environment. One solution to the problem of waste generation is to reduce or eliminate the waste at its source. University City Science Center (Philadelphia, PA) has begun a pilot project to assist small and medium-size manufacturers who want to minimize their generation of waste but who lack the in-house expertise to do so. Under agreement with EPA's Risk Reduction Engineering Laboratory, the Science Center has established three WMACs. This assessment was done by engineering faculty and students at the University of Tennes- see WMAC. The assessment teams have considerable direct experience with process operations in manufacturing plants and also have the knowledge and skills needed to minimize waste generation. The waste minimization assessments are done for small and medium-size manufacturers at no out-of-pocket cost to the client. To qualify for the assessment, each client must fall within Standard Industrial Classification Code 20-39, have gross annual sales not exceeding $75 million, employ no more than 500 persons, and lack in-house expertise in waste minimiza- tion. The potential benefits of the pilot project include minimization of the amount of waste generated by manufacturers, and reduction of waste treatment and disposal costs for participat- ing plants. In addition, the project provides valuable experi- ence for graduate and undergraduate_students who participate Printed on Recycled Paper ------- In the program, and a cleaner environment without more regu- lations and higher costs for manufacturers. Methodology of Assessments The waste minimization assessments require several site visits to each client served. In general, the WMACs follow the proce- dures outlined in the EPA Waste Minimization Opportunity Assessment Manua/(EPA/625/7-88/003, July 1988). The WMAC staff locate the sources of waste in the plant and identify the current disposal or treatment methods and their associated costs. They then identify and analyze a variety of ways to reduce or eliminate the waste. Specific measures to achieve that goal are recommended and the essential supporting tech- nological and economic information is developed. Finally, a confidential report that details the WMAC's findings and recom- mendations (including cost savings, implementation costs, and payback times) is prepared for each client. Plant Background The plant produces several varieties of felt tip markers, stamp pads, and rubber cement. It operates 6,120 hr/yr to produce > 2x 10* Ib/yr of product. Manufacturing Process Polypropylene, polystyrene, and polyethylene pellets, liquid and powdered dyes, and solvents for ink mixing are the principal raw materials used for making markers and stamp pads. Rub- ber strips and solvents are the major raw materials required for rubber cement manufacture. Felt Tip Marker Production In order to manufacture felt tip markers, polypropylene and polystyrene pellets are placed in a hopper and mixed with colored pellets. The pellet mixtures are metered into injection molding machines in which the three parts of the marker are formed (the case, cap, and endplug). The filler, a porous ink reservoir that is to be inserted into the marker case, is produced in a parallel operation. Cellulose acetate or polyester fiber is fed into a machine that stretches and relaxes the material. Next, cellophane is wrapped around the filler piece, and a long cylindrical form is automatically cut into individual pieces. In a third parallel operation, solvent or water is mixed with appropriate dyes to make marker ink. During final assembly of markers, the fillers are inserted into the molded cases, the inks are needle-injected into the fillers, and the molded endplugs are attached. The next step is the attaching of nibs (small pieces of felt that wick the ink from the filler) in the tip of the marker body. Molded caps are snapped into place, labels are applied to the markers, and the finished products are packaged. An abbreviated process flow diagram for felt tip marker produc- tion is shown in figure 1. Stamp Pad Production Three types of stamp pads are manufactured by the plant: felt, foam, and self-inking. Polystyrene pellets and black and grey dyes are mixed together and metered into injection molding machines where double-hinged stamp pad cases are formed. Felt pads are made by layering and cutting felt and asphalt sheets. A cloth overwrap is added and then the entire pad is inserted into a molded case. Water-based ink is injected into the pad and the finished stamp pad is labeled, packaged in cellophane, boxed, and shipped. For foam stamp pad produc- tion, pre-cut foam pieces are dipped in water-based ink and passed through a wringer machine to remove excess ink. The pad is inserted into a molded case, which is labeled, packaged in cellophane, boxed, and shipped. Self-inking stamp pads are manufactured by first blending dimethyl phthalate, powdered dyes, and PVC resins in a covered tank. The mixture is poured into individual trays, which are conveyed through a natural gas- fired oven for curing and then air-cooled. A pad base material is placed in the bottom of a case and the ink-impregnated pad is placed on top. The assembled pads are labeled, wrapped in cellophane, boxed, and shipped. An abbreviated process flow diagram for stamp pad production is shown in figure 2, Rubber Cement Production To produce rubber cement, synthetic rubber strips and rubber solvent are mixed together in a tank and stored in a storage tank. The contents of the storage tank are pumped to a filler machine where the rubber cement is pumped into individual bottles traveling on a conveyor. The filled bottles are capped, packaged, and shipped to customers. Existing Waste Management Practices This plant already has implemented the following techniques to manage and minimize its wastes, Waste cardboard is baled and sold to a recycler. * Plastic waste from the injection molding machines is reground and sold to an outside firm for reprocessing after which it is returned to the plant for reuse. * Hydraulic oil from the injection molding machines is filtered to extend its useful life. * Liquid hazardous waste streams are segregated by primary component. * Attempts have been made in the past to recycle dimethyl phthalate. However, recycling has bean discontinued be- cause of varying product quality and employee health con- cerns. Waste Minimization Opportunities The type of waste currently generated by the plant, the source of the waste, the waste management method, the quantity of the waste, and the annual waste management cost for each waste stream identified are given in Table 1. Table 2 shows the opportunities for waste minimization that the WMAC team recommended for the plant. The minimization opportunity, the type of waste, the possible waste reduction and associated savings, and the implementation cost along with the simple payback time are given in the table. The ------- Polypropylene pellets polystyrene pellets - Color pellets Mixing Injection molding I Cases caps endplugs Nibs Labels Cellulose acetate polyester Solvent, liquid dyes powdered dyes Resins anti-foam agents Cellophane Stretching/relaxing cellophane overwrapping Fillers Assembly T Markers shipped to customers Mixing Filtering f Ink Figure 1. Abbreviated process Sow diagram tor feK Up marker production. ------- Felt asphalt sheets Cotton cloth Water- based ink Layering and cutting Over- wrapping T Insertion of pad into case Ink infection Labeling, wrapping, packaging Felt stamp pads shipped to customers Dyes Injection molding I Polystyrene pellets Molded cases Pre-cut water- foam based pieces ink T I Ink Wringing Insertion of pad into case Mixing Pouring into trays D/methylphthalate dyes resins Oven curing Air cooing Labeling, wrapping, packaging Positioning pad in case Foam stamp pads shaped to customers Pad base material Labeling, wrapping, packaging Sett-inking stamp pads shipping to customers Figure 2. Abbreviated process flow diagram for stamp pad production. ------- TğUğ 1, Summary of Current Waste Generation Waste Stream Generated OH-spedfication filer overwrap Empty dye containers Evaporated n-propyl alcohol Excess plastic runners Unusable filler pieces Hydraulic oil filters Contaminated ink alters Hydraulic oil/detergent solution Synthetic oil Oil-specification markers Off-specification markers Scrap packaging material Plastic scrap Color-streaked marker components Ink system wash water Plastic pellets/hydraulic oil Ink system wash solvent Scrap self-inking stamp pads Wash water n-propyl alcohol wash-out Evaporated n-propyl alcohol Unused inking mixture Empty solvent containers Scrap cellophane overwrap Off-specification plastic cases Off-specification felt stamp pads Contaminated plastic floor owaring Resins and powder dyes Wash wetter Waste felt inserts Waste foam inserts ft/bfcar cement residue Evaporated rubber solvent _Wastewater treatment sludge Source of Waste Filler machine in felt tip marifer production Felt tip marker and stamp pad production Ink mixing in felt tip marker production Injection molding in felt tip marker production Filler machine in felt tip marker production Filtering of hydraulic oil from injection molding machines Ink mixing in felt tip marker and stamp pad production Cleanup in felt tip marker and stamp pad production Air compressors Felt tip marker production Felt tip marker production Felt tip marker and stamp pad production Color changes in injection molding in felt tip marker and stamp pad production Color consistency problems in felt tip marker production Cleanup in felt tip marker production Spills in felt tip marker and stamp pad production Cleanup in felt tip marker production Improper curing of self- inking pads Stamp pad production Ink mixing in stamp pad production Washout of ink mixer in stamp pad production Self-inking stamp pad production Stamp pad production Packaging of stamp pads Injection molding of stamp pad cases Stamp pad production Stamp pad production Stamp pad production Ink mixer in stamp pad production Improper cutting during stamp pad production Poor ink transfer during stamp pad production Rubber cement production Mixing of rubber cement Onsite WWTP Waste Management Method Shipped K> municipal landfill Returned to vendor for reuse Evaporates to plant air Ground; returned to supplier for reprocessing Shipped to municipal landfill Shipped off site for incineration Shipped to municipal landfill Shipped off site for disposal as hazardous waste Shipped off site for incineration Donated to charitable organizations Shipped to municipal landfill Shipped to municipal landfill Returned to supplier for reprocessing Ground; returned to supplier for reprocessing Treated onsite; sewered Shipped to municipal landfill Reused in black ink production Shipped off site for disposal as hazardous waste Treated onsite; sewered Shipped off site for incineration Evaporates to plant air Shipped off site for incineration Returned to vendor for reuse Shipped off site to recyder Returned to supplier for reprocessing Shipped to municipal landfill Shipped off site for disposal as hazardous waste Shipped off site for incineration Treated onsite; sewered Shipped to municipal landfill Shipped to municipal landfill Shipped to municipal landfill Evaporates to plant air Accumulating onsite in drying pond Annual Quantity Generated (Ib) 4,730 3,800 41,470 18,600 2,020 170 2,350 3,400 2,410 56.250 506,250 560 5,500 T65,f40 106,240 8,830 210 21,830 11,950 1,530 380 1,100 900 790 2,030 10,160 SO 50 27,890 3,750 4,500 380 15,800 N/A' Annual Waste . Management Cost $500 500 16,170 1,980 1,000 2,280 1,640 10,530 8,620 90 830 500 S60 19,690 50,630 1,640 0 SS.540 5,700 2,010 150 5,540 500 420 240 500 630 560 13,290 500 500 500 o. 0' * includes waste treatment, disposal, and handling costs and applicable raw material costs. waste is accumulating onsite; no waste was shipped off site during the past year. ------- . Summary of Recommended Waste Minimization Opportunities Annual Waste Reduction Mmmizatton Opportunity Segregate scrap plastic from injection molding by color and reuse in subsequent production runs. Waste Stream Reduced Excess plastic runners Plastic scrap Color-streaked marker components Quantity (Us) 9,340 3,090 81,930 Per Cent 56 56 38 Savings $5,100' implementation Cost $0 Smp/a Payback (yr) Immediate Modify the self-inking stamp pad production process to re- duos pad thickness by one-half so thai individual pads with surface defects can be combined to produce one pad with an acceptable visible top surface, improve maintenance o! injection molding machines to reduc leaking of hydraulic oil. Filter and reuse synttietic oil removed from air compressors. Scrap self-inking stamp pads Hydraulic oil/detergent Synthetic oil 19,650 90 2,380 2,170 70 90 20,050' 7,370 7,450' 17,400 Immediate 2.4 immediate Total savings have been reduced by an annual operating cost required for implementation of this opportunity. ------- quantities of waste currently generated by the plant and pos- sible waste reduction depend on the production level of the plant. All values should be considered in that context. It should be noted that the economic savings of the minimiza- tion opportunity, in most cases, results from the need for less raw material and from reduced present and future costs asso- ciated with waste treatment and disposal. Other savings not quantifiable by this study include a wide variety of possible future costs related to changing emissions standards, liability, and employee health. It also should be noted that the savings given for each opportunity reflect the savings achievable when implementing each waste minimization opportunity indepen- dently and do not reflect duplication of savings that may result when the opportunities are implemented in a package. Additional Recommendations In addition to the opportunities recommended and analyzed by the WMAC team, several additional measures were consid- ered. These measures were not analyzed completely because of insufficient data, minimal savings, implementation difficulty, or a projected lengthy payback. Since one or more of these approaches to waste reduction may, however, increase in attractiveness with changing conditions in the plant, they were brought to the plant's attention for future consideration. Line the ink mixing tanks with Teflon inserts to minimize the amount of residual ink adhering to tank walls after mixing and draining in order to reduce the amount of washout waste generated during clean-up. Reduce the scrap rate in the automated felt tip marker assembly line by improving the scheduling of production runs and maintenance of the line. Utilize reusable, washable ink filters to recover resins and dye pigments collected during filtration following ink mixing and use them in production of black ink. Modify the solvent-based ink mixing tanks to minimize sol- vent evaporative losses. Purchase a sludge dryer to reduce the weight of the waste- water treatment sludge in order to reduce disposal costs. This research brief summarizes part of the work done under Cooperative Agreement No. CR-814903 by the University City Science Center under the sponsorship of the U.S. Environmen- tal Protection Agency. The EPA Project Officer was Emma Lou George. ------- United States Environmental Protection Agency Center for Environmental Research Information Cincinnati, OH 45268 Official Business Penalty for Private Use $300 EPA/600/S-94/013 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 ------- |