SEPA
                         United States
                         Environmental Protection
                         Agency
                                    Risk Reduction
                                    Engineering Laboratory
                                    Cincinnati, OH 45268
                         Research and Development
                                    EPA/600/S-94/013   September 1994
ENVIRONMENTAL
RESEARCH   BRIEF
                 Waste Minimization Assessment for a Manufacturer
                of Felt Tip Markers, Stamp Pads, and Rubber Cement

                               Richard J. Jendtucko*, Todd M. Thomas*,
                                       and Gwen P. Looby**
Abstract
The U.S. Environmental Protection Agency (EPA) has funded
a pilot project to assist small and medium-size manufacturers
who want to minimize their generation of waste but who lack
the expertise to do so. In an effort to assist these manufactur-
ers Waste Minimization  Assessment Centers (WMACs) were
established at selected universities and procedures  were
adapted from the  EPA  Waste Minimization  Opportunity As-
sessment Manual (EPA/625/7-88/003, July 1988). That docu-
ment has been superseded by the Facility Pollution Prevention
Guide (EPA/600/R-92/088, May 1992). The WMAC team at the
University of Tennessee performed an assessment at a plant
that manufactures  felt tip markers, stamp pads, and rubber
cement. Plastic components for  the  markers are formed in
injection molding machines.  A porous filler is  inserted into the
marker case and ink is injected into it. The endplug, nib, and
cap are added to the marker, which is then labeled and pack-
aged. The first step in stamp pad production is the injection
molding of plastic double-hinged stamp pad cases. Three types
of stamp pads are manufactured: felt, foam, and self-inking.
The pads are prepared  and inserted into the cases. Rubber
cement is manufactured by mixing synthetic rubber strips and
solvent. The team's report, detailing findings and recommenda-
tions, indicated that a large  quantity of scrap  plastic is gener-
ated by the injection molding of markers and stamp pad cases,
and that significant cost savings could be achieved by segre-
gating scrap plastic and reusing  it in subsequent production
runs.

This Research Brief was developed by the principal  investiga-
tors and EPA's Risk Reduction Engineering Laboratory, Cincin-
nati, OH, to announce  key findings of an ongoing research
* University of Tennessee, Department ol Engineering Science and Mechanics
" University City Science Center, Philadelphia, PA
                         project that is fully documented in a separate report of the
                         same title available from University City Science Center.


                         Introduction
                         The amount of waste generated by industrial plants has be-
                         come an increasingly costly problem for manufacturers and an
                         additional stress on the environment. One solution to the
                         problem  of waste generation is to reduce or eliminate the
                         waste at its source.

                         University City Science Center (Philadelphia, PA) has begun a
                         pilot  project to assist small and medium-size manufacturers
                         who want to minimize their generation of waste but who lack
                         the in-house expertise to do so. Under agreement with EPA's
                         Risk Reduction Engineering  Laboratory, the Science Center
                         has established three WMACs. This assessment was done by
                         engineering faculty and students at the University of Tennes-
                         see WMAC. The assessment teams have considerable direct
                         experience with process operations  in manufacturing plants
                         and also have the knowledge and skills needed to minimize
                         waste generation.

                         The waste minimization assessments are done for small and
                         medium-size manufacturers  at no out-of-pocket cost to the
                         client. To qualify  for the assessment, each client must fall
                         within Standard Industrial Classification Code 20-39, have gross
                         annual sales not exceeding $75 million, employ no more than
                         500 persons, and lack in-house expertise in waste minimiza-
                         tion.

                         The potential benefits of the  pilot project include minimization
                         of the amount of waste generated by  manufacturers, and
                         reduction of waste treatment and disposal costs for participat-
                         ing plants. In  addition, the project provides valuable experi-
                         ence for graduate and undergraduate_students who participate
                                                      Printed on Recycled Paper

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In the program, and a cleaner environment without more regu-
lations and higher costs for manufacturers.


Methodology of Assessments
The waste minimization assessments require several site visits
to each client served. In general, the WMACs follow the proce-
dures outlined in the EPA Waste Minimization Opportunity
Assessment Manua/(EPA/625/7-88/003, July 1988). The WMAC
staff  locate the sources of waste in the plant and identify the
current disposal  or treatment methods  and their associated
costs. They  then identify and  analyze a variety of ways to
reduce or eliminate the waste. Specific measures to  achieve
that goal are recommended and the essential supporting tech-
nological and economic information is developed. Finally, a
confidential report that details the WMAC's findings and recom-
mendations (including cost savings, implementation costs, and
payback times) is prepared for each client.


Plant Background
The plant produces several varieties of felt tip markers, stamp
pads, and rubber cement. It operates 6,120 hr/yr to produce >
2x 10* Ib/yr of product.


Manufacturing Process
Polypropylene, polystyrene, and polyethylene pellets, liquid and
powdered dyes,  and  solvents for ink mixing are the principal
raw materials used for making markers and stamp pads. Rub-
ber strips and solvents are the major raw materials required for
rubber cement manufacture.


Felt Tip Marker Production

In  order  to manufacture  felt tip markers, polypropylene and
polystyrene pellets are placed in a hopper and mixed with
colored pellets. The pellet mixtures are metered into injection
molding machines in which the three parts of the marker are
formed (the case, cap, and endplug).

The filler, a porous ink reservoir that is to be inserted into the
marker case, is  produced in a parallel  operation. Cellulose
acetate or polyester fiber is fed into a machine that stretches
and relaxes the material.  Next, cellophane is wrapped around
the filler piece, and a long cylindrical form is automatically cut
into individual pieces.

In  a third parallel operation, solvent or  water  is mixed with
appropriate dyes to make marker ink.

During final assembly of  markers, the fillers are inserted into
the molded cases, the inks are needle-injected into the fillers,
and the molded  endplugs are attached. The  next step is the
attaching of nibs (small pieces of felt that wick the ink from the
filler) in the tip of the marker body. Molded caps are snapped
into place, labels are applied to the markers, and the finished
products are packaged.

An abbreviated process flow diagram for felt tip marker produc-
tion is shown in figure 1.


Stamp Pad Production
Three types of stamp pads are manufactured by the plant: felt,
foam, and self-inking. Polystyrene pellets and black and grey
dyes are mixed together and metered into injection  molding
machines where double-hinged stamp pad cases are formed.
Felt pads are made by  layering and cutting felt and asphalt
sheets. A cloth overwrap is added and then the entire pad is
inserted into a molded case. Water-based ink  is injected into
the pad and the finished stamp pad is labeled, packaged in
cellophane, boxed, and shipped. For foam stamp pad produc-
tion, pre-cut foam pieces are dipped in water-based  ink and
passed through a wringer machine to remove excess ink. The
pad is inserted into a molded case, which is labeled, packaged
in cellophane, boxed, and shipped. Self-inking stamp pads are
manufactured by first blending dimethyl phthalate, powdered
dyes, and PVC resins in a covered tank. The mixture is poured
into individual trays, which are conveyed through a natural gas-
fired oven for curing and then air-cooled. A pad base  material
is placed in the bottom of a case and the ink-impregnated pad
is placed on top. The assembled pads are labeled, wrapped in
cellophane, boxed, and shipped.

An abbreviated process flow diagram for stamp pad production
is shown in figure 2,


Rubber Cement Production
To produce rubber cement, synthetic rubber strips and rubber
solvent are mixed together in a tank and stored in a storage
tank. The contents of the storage tank are pumped to a filler
machine  where the rubber cement is pumped into individual
bottles traveling on a conveyor. The filled bottles are capped,
packaged, and shipped to customers.


Existing Waste Management Practices
This plant already has implemented the following techniques to
manage and minimize its wastes,

  • Waste cardboard is baled and sold to a recycler.

  * Plastic waste from the injection molding machines is reground
    and sold to an outside firm for reprocessing after which it is
    returned to the plant for reuse.

  * Hydraulic oil from the injection molding machines is filtered to
    extend its useful life.

  * Liquid hazardous waste streams are segregated by primary
    component.

  * Attempts have been made in the past to recycle dimethyl
    phthalate.  However, recycling has bean discontinued be-
    cause of varying product quality and employee health con-
    cerns.

Waste Minimization Opportunities
The type of waste currently generated by the plant, the source
of the waste, the waste  management method, the quantity of
the waste, and the annual waste management cost for each
waste stream identified are given in Table 1.

Table 2 shows the opportunities for waste minimization that the
WMAC team recommended for the plant. The minimization
opportunity, the type of waste, the possible waste reduction
and associated savings, and the implementation cost along
with the simple payback time  are given  in  the table. The

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Polypropylene pellets
 polystyrene pellets

     - Color pellets
                         Mixing
                        Injection
                        molding
                          I
                         Cases
                         caps
                       endplugs
                          Nibs


                         Labels
                          Cellulose
                           acetate
                          polyester
                                                                                        Solvent, liquid dyes
                                                                                          powdered dyes
                                                                                              Resins
                                                                                     anti-foam agents
                                                                         Cellophane
                                 Stretching/relaxing
                                     cellophane
                                    overwrapping
                                                                Fillers
                                     Assembly
                                                                T
                                                           Markers shipped
                                                             to customers
                                                                            Mixing
Filtering
    f


    Ink
Figure 1.  Abbreviated process Sow diagram tor feK Up marker production.

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      Felt
    asphalt
    sheets
     Cotton
     cloth
     Water-
     based
      ink
                       Layering
                         and
                        cutting
                        Over-
                       wrapping
T
                      Insertion of
                       pad into
                         case
                         Ink
                       infection
                       Labeling,
                       wrapping,
                      packaging
                      Felt stamp
                     pads shipped
                     to customers
                       Dyes
                     Injection
                     molding
                                                 I
Polystyrene
pellets
                                                                        Molded
                                                                         cases
Pre-cut    water-
 foam     based
pieces      ink

  T      I
                               Ink
                                                      Wringing
                           Insertion of
                            pad into
                              case
                                               Mixing
   Pouring
     into
    trays
                                                                                      D/methylphthalate
                                                                                            dyes
                                                                                           resins
                                                                                                  Oven
                                                                                                 curing
                                                                         Air
                                                                       cooing
                            Labeling,
                            wrapping,
                           packaging
                                                                                               Positioning
                                                                                                 pad in
                                                                                                  case
                                                    Foam stamp
                                                    pads shaped
                                                    to customers
                                                                 Pad base
                                                                  material
                                                                                                Labeling,
                                                                                                wrapping,
                                                                                               packaging
                                                                     Sett-inking stamp pads
                                                                     shipping to customers
Figure 2. Abbreviated process flow diagram for stamp pad production.

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TğUğ 1, Summary of Current Waste Generation
Waste Stream Generated
OH-spedfication filer overwrap
Empty dye containers
Evaporated n-propyl alcohol
Excess plastic runners
Unusable filler pieces
Hydraulic oil filters
Contaminated ink alters
Hydraulic oil/detergent solution
Synthetic oil
Oil-specification markers
Off-specification markers
Scrap packaging material
Plastic scrap
Color-streaked marker
components
Ink system wash water
Plastic pellets/hydraulic oil
Ink system wash solvent
Scrap self-inking stamp pads
Wash water
n-propyl alcohol wash-out
Evaporated n-propyl alcohol
Unused inking mixture
Empty solvent containers
Scrap cellophane overwrap
Off-specification plastic cases
Off-specification felt stamp pads
Contaminated plastic floor owaring
Resins and powder dyes
Wash wetter
Waste felt inserts
Waste foam inserts
ft/bfcar cement residue
Evaporated rubber solvent
_Wastewater treatment sludge
Source of Waste
Filler machine in felt tip
marifer production
Felt tip marker and
stamp pad production
Ink mixing in felt tip
marker production
Injection molding in felt
tip marker production
Filler machine in felt tip
marker production
Filtering of hydraulic oil from
injection molding machines
Ink mixing in felt tip marker
and stamp pad production
Cleanup in felt tip marker
and stamp pad production
Air compressors
Felt tip marker production
Felt tip marker production
Felt tip marker and stamp
pad production
Color changes in injection
molding in felt tip marker
and stamp pad production
Color consistency problems
in felt tip marker production
Cleanup in felt tip marker
production
Spills in felt tip marker and
stamp pad production
Cleanup in felt tip marker
production
Improper curing of self-
inking pads
Stamp pad production
Ink mixing in stamp pad
production
Washout of ink mixer in
stamp pad production
Self-inking stamp pad
production
Stamp pad production
Packaging of stamp pads
Injection molding of stamp
pad cases
Stamp pad production
Stamp pad production
Stamp pad production
Ink mixer in stamp pad
production
Improper cutting during
stamp pad production
Poor ink transfer during
stamp pad production
Rubber cement production
Mixing of rubber cement
Onsite WWTP
Waste Management Method
Shipped K> municipal landfill
Returned to vendor for reuse
Evaporates to plant air
Ground; returned to supplier
for reprocessing
Shipped to municipal landfill
Shipped off site for incineration
Shipped to municipal landfill
Shipped off site for disposal
as hazardous waste
Shipped off site for incineration
Donated to charitable organizations
Shipped to municipal landfill
Shipped to municipal landfill
Returned to supplier for reprocessing
Ground; returned to supplier
for reprocessing
Treated onsite; sewered
Shipped to municipal landfill
Reused in black ink production
Shipped off site for disposal as
hazardous waste
Treated onsite; sewered
Shipped off site for incineration
Evaporates to plant air
Shipped off site for incineration
Returned to vendor for reuse
Shipped off site to recyder
Returned to supplier for
reprocessing
Shipped to municipal landfill
Shipped off site for disposal
as hazardous waste
Shipped off site for incineration
Treated onsite; sewered
Shipped to municipal landfill
Shipped to municipal landfill
Shipped to municipal landfill
Evaporates to plant air
Accumulating onsite in drying pond
Annual Quantity
Generated (Ib)
4,730
3,800
41,470
18,600
2,020
170
2,350
3,400
2,410
56.250
506,250
560
5,500
T65,f40
106,240
8,830
210
21,830
11,950
1,530
380
1,100
900
790
2,030
10,160
SO
50
27,890
3,750
4,500
380
15,800
N/A'
Annual Waste .
Management Cost
$500
500
16,170
1,980
1,000
2,280
1,640
10,530
8,620
90
830
500
S60
19,690
50,630
1,640
0
SS.540
5,700
2,010
150
5,540
500
420
240
500
630
560
13,290
500
500
500
o.
0'
 *  includes waste treatment, disposal, and handling costs and applicable raw material costs.
    waste is accumulating onsite; no waste was shipped off site during the past year.

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       .  Summary of Recommended Waste Minimization Opportunities
                                                                     Annual Waste Reduction
Mmmizatton Opportunity
Segregate scrap plastic from
injection molding by color and
reuse in subsequent production
runs.
Waste Stream Reduced
Excess plastic runners
Plastic scrap
Color-streaked marker
components
Quantity (Us)
9,340
3,090
81,930
Per Cent
56
56
38
Savings
$5,100'
implementation
Cost
$0
Smp/a
Payback (yr)
Immediate
Modify the self-inking stamp
 pad production process to re-
 duos pad thickness by one-half
 so thai individual pads with surface
 defects can be combined to
 produce one pad with an acceptable
 visible top surface,

improve maintenance o! injection
 molding machines to reduc
 leaking of hydraulic oil.

Filter and reuse synttietic oil
 removed from air compressors.
Scrap self-inking stamp pads
Hydraulic oil/detergent
Synthetic oil
19,650
                    90
 2,380
2,170
70
                                                    90
                                                                    20,050'
                                                                      7,370
                                                                     7,450'
                                                                                       17,400
                                                                                                        Immediate
                                                                                                          2.4
                                                                                                       immediate
   Total savings have been reduced by an annual operating cost required for implementation of this opportunity.

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quantities of waste currently generated by the plant and pos-
sible waste reduction  depend on  the  production level of the
plant. All values should be considered in that context.

It should be noted that the economic savings of the minimiza-
tion opportunity, in  most cases,  results from the  need for less
raw material and from reduced present and future costs asso-
ciated with waste treatment and disposal. Other savings not
quantifiable by this study include a wide variety of possible
future costs related to changing emissions standards, liability,
and employee health.  It also should be noted that the savings
given for each opportunity reflect the savings achievable when
implementing each waste minimization opportunity  indepen-
dently and do not reflect duplication of  savings that may result
when the opportunities are implemented in a package.


Additional Recommendations
In addition to the opportunities recommended and analyzed by
the WMAC team,  several additional measures  were consid-
ered. These measures were not analyzed  completely because
of insufficient data, minimal savings, implementation difficulty,
or a projected lengthy payback. Since one  or more of these
approaches  to  waste  reduction may,  however, increase  in
attractiveness with  changing conditions in  the plant, they were
brought to the plant's attention for future consideration.
  • Line the ink mixing tanks with Teflon inserts to minimize the
    amount of residual ink adhering to tank walls after mixing and
    draining in order to reduce the amount of washout waste
    generated during clean-up.

  • Reduce the scrap  rate in the  automated felt tip marker
    assembly line by improving the scheduling of production runs
    and maintenance of the line.

  • Utilize reusable, washable ink filters to recover resins and
    dye pigments collected during filtration following ink mixing
    and use them in production of black ink.

  • Modify the solvent-based ink mixing tanks to minimize sol-
    vent evaporative losses.

  • Purchase a sludge dryer to reduce the weight of the waste-
    water treatment sludge in order to reduce disposal costs.

This research brief summarizes part of the work done under
Cooperative Agreement No. CR-814903 by the University City
Science Center under the sponsorship of the U.S. Environmen-
tal Protection Agency.  The EPA Project  Officer  was Emma
Lou George.

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United States
Environmental Protection Agency
Center for Environmental Research Information
Cincinnati, OH 45268

Official Business
Penalty for Private Use
$300

EPA/600/S-94/013
     BULK RATE
POSTAGE & FEES PAID
         EPA
   PERMIT No. G-35

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