United States
 Environmental Protection
 Agency
 Research and Development
 Air and Energy Engineering
 Research Laboratory
 Research Triangle Park, NC 27711
 EPA/600/SR-92/006  Feb. 1992
 Project  Summary

 Identification  and
 Characterization  of Missing or
 Unaccounted  for Area  Source
 Categories

 S. Kersteter, D. Zimmerman, R. Cawkwell, A. Chadha, B. Henning, M. Henning,
 T. Lynch, P. Marsosudiro, W. Tax, D. Winkler, and G. Woodall, Jr.
  Area source emissions of participate
 matter (TSP), sulfur dioxide (SO2), ox-
 ides of nitrogen (NO ), reactive volatile
 organic compounds (VOCs) and carbon
 monoxide (CO) are estimated annually
 by the National Air Data Branch (NADB)
 of EPA's Office of Air Quality Planning
 and Standards. Area sources include all
 mobile sources and any stationary
 sources that are too small, difficult, or
 numerous to be inventoried as point
 sources. The  NADB defines  an area
 source as an anthropogenic mobile or
 stationary source that emits less than
 100tons*peryearof TSP, SO , NOx, VOC,
 and CO.TheoriginalNationaf Emissions
 Data System (NEDS) area source meth-
 odologies and algorithms were devel-
 oped in 1973 and 1974, using 1960 cen-
 sus data, and identified 64 area source
 categories. The National Acid Precipita-
 tion Assessment Program (NAPAP) ex-
 panded the NEDS area source category
 list to 97 categories.
  Chapter 4 of Procedures for the Prepa-
 ration of Emission Inventories for Pre-
 cursors of Ozone, Volume I (EPA-450/4-
 88-021, December 1988) lists area sou rce
 categoriesto be included in a State Imple-
 mentation Plan (SIP) inventory. The list
 of area source categories to be invento-
 ried and the emissions estimation meth-
 odologies given in the SIP guidance dif-
 fer noticeably from the NEDS categories
 and  methodologies. While emissions
 sources included in NEDS and SIP in-
ventories cover a large portion of an-
thropogenic  emissions, many smaller
source categories  are not included in
either inventory. Identification, charac-
*1 ton = 907 kg.
terization, and inclusion of these cat-
egories and their emissions in the inven-
tory program will result in a more thor-
ough  and complete emissions inven-
tory.
  This report gives results of work com-
pleted under three work assignments
under EPA  Contract 68-D9-0173. The
objectives of this work were to identify
and characterize emissions sources not
currently accounted for by either the
existing NEDS or SIP area source meth-
odologies.   In all, 70 missing source
categories  were characterized, to the
extent possible, in 12 areas:
• definition/description of the category
 and activity
• process breakdown (if applicable)
• importance of the category (i.e., rea-
 son for considering the category)
• pollutants emitted
• estimate of the pollutant levels
• point/area source cutoff (i.e., does the
 category have both a point source and
 an area source component?)
• level of detail of available information
• level of detail required by users
• emission factor requirements
• regional, seasonal, or temporal char-
 acteristics
• urban or rural characteristics
• potential emissions estimation meth-
 odology
  This Project Summary was developed
by EPA's Air and Energy Engineering
Research Laboratory, Research Triangle
Park, NC, to announce key findings of
the research project that is fully docu-
mented in a separate report of the same
title (see Project Report ordering infor-
mation at back).


          Printed on Recycled Paper

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Introduction
  A mJsslngor unaccounted forsource cat-
egory is one that does not explicitly appear
on the  NEDS area source category list or
the SIP area source category list as pre-
sented in Chapter 4 of Procedures for the
Preparation of Emission Inventory for Pre-
cursors of Ozone, Volume  I  (EPA-450/4-
88-021, December 1988).  Exceptions to
this generic definition include, for example,
residential liquefied petroleum gas (LPG)
consumption, and light-duty diesel passen-
ger cars and trucks. Residential LPG  con-
sumption is not explicitly listed as a NEDS
area source category  but is accounted for
within the methodology for residential natu-
ral gas consumption. Light-duty diesel pas-
senger cars and trucks are also not explic-
itly accounted for in the  NEDS mobile
sources methodology, although diesel ve-
hicle miles traveled (VMT) and diesel fuel
consumption  are  assigned to the heavy
dutydjeselcategory. Examples of true miss-
ing or unaccounted for source categories
include cooling towers, street sweeping,
street sanding, restaurant charbroiling* op-
erations (wood- or charcoal-fired), and air-
craft cruise (inflight) operations.
  Addressing the area of missing  or
unaccounted for source categories involves
several steps:
• Identifying source categories
• data gathering and initial characterization
  of categories
• priority ranking  of characterized catego-
  ries
* more detailed. In-depth characterization
  of high ranking categories and emissions
  estimation methodology development
  This project was designed to identify and
characterize the  missing or unaccounted
for area sources. The complete effort has
been divided into phases. In all, 70 missing
or unaccounted for source categories were
identified.

Identification of Missing or
Unaccounted for Source
Categories
  Missing or unaccounted for source cat-
egories were identified by contacting vari-
ous individuals and groups, conducting lit-
erature searches, reviewing the Clean Air
Act Amendments of 1990 (CAAA)  and
Superfund Amendments and Reautho-
rization Act (SARA) Title III,  investigating
changing technologies, and reviewing other
information sources (e.g., in-house knowl-
•Ctuitmtl b usod as defined In Webster's New World
 CHcUonaryoftho American Language, Second College
 Ed»ton.Sknon4ScnusIor.lnc..N8wYorfc,NY. 1986.
edge, telephone bookyellowpages). Groups
and individuals contacted include: EPAper-
sonnel, including Regional SIP representa-
tives and other knowledgeable personnel
from the Office of Air Quality Planning and
Standards  (OAQPS), Office of  Mobile
Sources (QMS), Office of Toxic Substances
(OTS), Air  and Energy Engineering Re-
search Laboratory (AEERL), and Atmo-
spheric Research and Exposure Assess-
ment Laboratory (AREAL); state and local
agencies; NAP AP participants; Environment
Canada; trade and professional organiza-
tions; and environmental groups.
  Apartial list of missing or unaccountedfor
categories identified by this process include:
roofing activities; airport, rail yard, and ma-
rine  port support activities; charbroiling;
automobile  fires; paving or  traffic paints;
road and highway construction; and winer-
ies. Some  contacts provided information
useful for characterizing the  categories or
estimating emissions from the categories.
In addition, several contacts expressedcon-
cern about current methodologies.
  The National Technical Information Ser-
vice (NTIS) database, ChemAbstracts (us-
ing the Dialog Information Service), EPA
holdings, and Triangle university collections
were searched for reports or papers identi-
fying emissions sources not included in
NEDS or SIP methodologies. The NTIS
database was searched through the CD-
ROM system for the period  1985 through
April 1990.  General keyword identifiers
(e.g., area source, emission inventory) were
used, as well as specific category keyword
identifiers (e.g., cooling tower, pesticide air
emissions).  Approximately  135 pages of
bibliographic information with abstracts'were
reviewed. Many of the citations referred to
documentation  from the 1980 and 1985
NAPAP inventories. Ten documents were
selected  for further review. These NTIS
documents were retrieved on fiche from the
North Carolina State University public docu-
ments collection.
  No relevant citations were identified from
the EPA holdings search or an on-line title
and subject search of the Triangle Univer-
sity Bibliographic Information Service (BIS).
An initial search of ChemAbstracts (1967 to
the present) produced 60 citations and bib-
liographic citations, which were reviewed.
Relevant documents were retrieved from
the EPA/ERC Library and Duke University's
Engineering Library.
  Other information sources reviewed in-
clude annual Air and Waste  Management
Association (AWMA) (formerly Air Pollution
Control Association) proceedings, AWMA
specialty session proceedings, EPRI docu-
ments, Third Party NAPAP  review docu-
mentation, and state NAPAP review com-
ments.
  Those documents identified during the
literature search and considered useful for
this work assignment were summarized
briefly forthis report. A comment was added
after each document summary to charac-
terize the relevant source types and useful-
ness of information in the document. Docu-
ments summarized include:
• Hazardous Waste TSDF (Treatment, Stor-
  age,  and Disposal Facilities): Fugitive
  Particulate Matter Air Emissions  Guid-
  ance Document, C. Cowherd et al., EPA-
  450/3-89-019 (PB90-103250), May 1989.
• Area  Sources of VOC (Volatile Organic
  Compounds) Emissions and Their Contri-
  bution to Tropospheric Ozone Concentra-
  tions, M. Kosusko and S.L. Nolan, EPA-
  600/D-89-075 (PB89-181291), June 1989.
• Screening-Level Assessment of Airborne
  Carcinogen  Risks from Uncontrolled
  Waste Sites, T.F. Wolfinger,  JAPCA
  39:461-468, April 1989.
• Ethanol Emissions and Control for Wine
  Fermentation  Tanks,  California  Air Re-
  sources Board, ARB/ML-88-027 (PB88-
  223540), April 1989.
• Assessment of Non-Regulated Sources
  in the Seattle Area, G.M. Savage and H.
  Sharpe, Waste  Management and Re-
  search 5:1159-171,1989.
• PMJO Emission Factors  for Specialized
  Open Dust Sources, C. Cowherd and M.A.
  Grelinger, In Proceedings of the 81st An-
  nual Meeting ofAPCA, Dallas, TX, June
  19-24,1988(88-718.3).
• Evaluation of Emissions from Selected
  Uninventoried Sources in the State of
  California,  Radian  Corporation,  ARB/R-
  88-343 (PB88-215215), April 1988.
• Sources and Concentration of Chloroform
  Emissions in the South Coast Air Basin,
  Science Applications  International Cor-
  poration, ARB-R-88/344 (PB88-215678),
  April 1988.
• Updating Nontraditional VOC Source In-
  ventories, R.M. Leone, E.W. Davis, and
  A.D. Jones, In Proceedings of the 80th
  Annual Meeting ofAPCA, New York, NY,
  June 21-26, 1987 (87-58.2).
• Photochemical!/ Reactive Organic Com-
  pound Emissions  from  Consumer and
  Commercial Products, A. Jones et  al.,
  EPA-902/4-86-001 (PB88-216940), No-
  vember 1986.
• Determination of Air Toxic Emissions from
  Non-Traditional Sources in the Puget
  Sound Region, Engineering-Science,
  EPA-910/9-86-148 (PB87-123550), April
  1986.
• Air Toxics Technical Assistance for the
  State of Alaska,  R. Dickson, S. Peoples,
  and W. Oliver, EPA-910/9-87-159 (PB89-
  217897), March 1987.

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 • Effect of Wind Speed on the Atmospheric
  Levels of Particles Produced by Tradi-
  tional and Nontraditional Sources on the
  Island of Curacao,  E. Sanhueza, J.
  Romero, and E. Gijsbertha, Chemosphere
  14:91-97,1985.
  The CAAA were reviewed to  identify
 source categories not addressed in NEDS
 or the SIP  inventories,  using the  House
 version H.R.3030 (November 9, 1989;
 renumbered to House of Representatives
 Bill S.1630) and the Senate version S. 1630
 (January 23, 1990). Subsequent  to pas-
 sage of the  final law in October 1990, the
 CAM were reviewed  for any material
 changes to the identification of source cat-
 egories. Provisions in the SARA  Title III
 legislation were also examined for specific
 area source categories.
  Although  little mention of specific area
 sources of emissions was made in the CAAA,
 several  sources were identified, including:
 clean fuels;  marine vessels; urban  fugitive
 dust; residential wood  combustion; pre-
 scribed agricultural burning; prescribed sil-
 vicultural burning; rocket engine and motor
 firing and cleaning; shipbuilding and repair;
 aerospace coatings and solvent; oxygen-
 ated fuel; outer continental shelf (OCS) oil
 and gas activities; research facilities; and oil
 and gas production. Of these sources, resi-
 dential wood combustion, prescribed agri-
 cultural  and silvicultural  burning, and ma-
 rine  vessels are already included in the
 NEDS or SIP methodologies.
  Title III  of SARA (also known  as the
 Emergency Planning and Community Right-
 To-Know Act of 1986) was reviewed for any
 mention of area sources not included in
 NEDS or  SIP  inventories; however,  no
 sources were mentioned.
  Using in-house knowledge  and  experi-
 ence, several areasourcecategories (where
 changing technologies may result in emis-
 sions from source categories not currently
 included in NEDS or SIP inventories) were
 identified. Some  categories identified
through this  process include:
• ultraviolet (UV) and electron beam (EB)
  curable coatings
• clean fuels/alternate fuels
• chlorofluorocarbon (CFC) substitutes
• artificial wetlands designed to treat do-
  mestic sewage
• compressed natural gas
• pulp bleaching by ozone
• recycling activities
• drinking water ozonation
• coronal discharge
• innovative  hazardous waste destruction
  and remediation techniques
  In addition to the activities described ear-
lier, telephone book yellow  pages were
searched. These searches not only helped
 to directly identify sources not currently in
 the area source inventories, but also pro-
 vided insight to the identification process.
. Sources identified through this process in-
 clude small bakeries; fermentation  pro-
 cesses found in breweries, distilleries, and
 wineries; adhesives and glues application;
 commercial pesticide use; photocopiers and
 laser printers; and commercial charbroiling
 and deep fat frying.

 Development of Lists and
 Definitions
   Categories identified through the search
 phase were combined into a master list of
 missing/unaccounted for sources.  This list
 contains all the identified categories, re-
 gardless of their emissions potential. The
 master list was reviewed, and a preliminary
 working list was developed containing those
 categories considered  most  important  to
 characterize. The working list was submit-
 ted to  EPA for review  and was  revised
 based on the comments received. Identified
 categories were aggregated into major head-
 ings and then disaggregated  into  specific
 category listings. Definitions  were devel-
 oped for each source category.

 Characterization of Missing/
 Unaccounted for Source
 Categories
  To facilitate the characterization process
 and to ensure consistency, a template was
 developed to be  used for each category
 characterization. The template defined the
 types of information to be collected for the
 source and provided a common  format.
 Categories were characterized, to the ex-
 tent possible, in 12 areas:
 • definition/description of the category and
  activity
 • process breakdown (if applicable)
 • importance of the category  (i.e., reason
  for considering the category)
 • pollutants emitted
 • estimate of the pollutant levels
 • point/area source cutoff  (i.e.,  does the
  category have both a point source and an
  area source component?)
 • level of detail of available information
 • level of detail required by users
 • emission factor requirements
 • regional,  seasonal, or  temporal charac-
  teristics
 • urban or rural characteristics
 • potential emissions estimation methodol-
  ogy
  In all, 70 categories were characterized
for this project:
• Adhesives and Sealants - Commercial
• Adhesives and Sealants - Consumer
• Aircraft Deicing
• Aircraft Refueling
 • Airport Support Vehicles
 • Automotive Cleaners/Waxes/Polishes
 • Automotive Fluids and Fluid Leaks
 • Automotive Rustproofing/Undercoating
 • Backyard Charcoal Grills
 • Bakeries
 » Barge, Tank, Tank Truck, Rail Car, and
  Drum Cleaning
 • Breweries
 • Catastrophic/Accidental Releases - Rail
  Car, Tank Truck, and Industrial Accidents
 • Cigarette Smoke
 • Commercial Charbroiling
 • Commercial Deep Fat Frying at Restau-
  rants
 • Compressed Natural Gas Vehicles
 • Cooling Towers
 • Diesel Fuel - Evaporative Emissions from
  Service Station Operations
 • Distilleries
 • Drinking Water Treatment with Ozone
 • Extra  High Voltage (EHV) Transmission
  Lines
 • Farming Operations
 • Fireplaces
 • Grain  Grinding and Feed Preparation
 • Household Cleaners and Polishes
 • Inflight Aircraft
 • Innovative Waste Treatment Technolo-
  gies
 • Kerosene Space Heaters
 • Laminating
 • Landfill Activities - TSP
 • Landfill Methane
 • Laundry Products - Commercial and Con-
  sumer
 • Lawn Care Products
 • Mobile Sources Evaporative and Running
  Losses
 • Motor Vehicle Racing
 • Natural Gas Well Blowouts
 • Oil and Gas Production - Field Activity
 • Oil and Gas Production - Well Drilling
 • Oil Spills
 • Package Plants (Wastewater Treatment)
 • Personal  Products
 • Pesticide Application
 • Petroleum Vessel Loading and Unloading
  Losses
 • Photocopiers and Laser Printers
 • Pulp Bleaching with Ozone
 • Recycling Processes
 • Refinery Sludge Dewatering
 • Refrigerants - Leaking Coolant
 • Refrigerated Trucks
 • Refrigeration/Air Conditioning Equipment
 • Research and Testing Laboratories
 • Residential Deep Fat Frying
 • Road Construction
• Road Salting and Sanding
• Rocket Launches and Test Firings
• Sandblasting
• Silage Storage
• Small Electric Utility Boilers

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* Street Sweeping and Cleaning
• Synthetic  Organic Chemical Storage
  Tanks
• Traffic Painting
• Ultraviolet (UV) and Electron Beam (EB)
  Curable Coating
• Vehicle Lubricating
• Vehicle Repair
• Waste Incineration -  Developing Tech-
  nologies for Hazardous Waste
• Waste Oil Disposal
* Welding
• Wineries
* Wood Stoves

Characterization Activities
  Each of the 70 area source  categories
was characterized using the template. In-
formation  for the characterizations was
derived from a number of sources, many of
which had been identified during the search
phase of this project. The principal sources
of Information were available literature, in-
dustry and trade association publications
and contacts, and knowledgeable federal
and state personnel.
  Available literature was identified based
on  the original literature search and in-
cluded reference materials related to spe-
cific processes. These documents included
EPA and other government reports, journal
and conference reports, and trade associa-
tion reports and bulletins. AP-42 (Compila-
tion of AirPollutant Emission Factors, Fourth
Edition and Supplements, September 1985
through September 1991) was consulted
for emission factor data.
  Where applicable, trade associations
were  contacted for information. In  some
cases, association  contacts were able to
offer unpublished or otherwise unavailable
test reports  and clarify process descrip-
tions. If the information could be obtained
quickly, published materials were requested.
  Federal and state personnel were identi-
fied through  the category  identification
phase, guidancef romthe EPAprojectteam,
or experience with Federal Implementation
Plan (FIP), SI P, or NAPAP programs. Agen-
cies contacted included EPA/OAQPS, En-
vironment Canada, state agencies includ-
ing CARB, and regional agencies such  as
the  South Coast (California) Air Quality
Management District (SCAQMD).  These
contacts provided  process  descriptions,
emission factors and activity data,  emis-
sions estimates, and comments on a num-
ber of source categories.

Discussion of Results
  Characterization  of the 70 source cat-
egories revealed a  broad  range of source
types and availability of information sources.
Research indicates that the sources may
lack applicable emission  factors, current
activity data, or both, for the development of
emissions estimation strategies. In some
cases (e.g., backyard charcoal grilling), state
agencies such as CARB have begun to
study these sources for inclusion in state or
local inventories and can provide their re-
search results. Trade  associations may
maintain  industry  statistics, research and
testing divisions useful to source descrip-
tion, emission factor development, and ac-
tivity data identification. However, most of
the source categories lack a current emis-
sions estimation methodology adequate for
NEDS or SIP applications.
  The information presented in these char-
acterizations provides an initial overview of
the process and its emissions, an indication
and/or summary of the data available from
standard reference materials and primary
contacts, alternate methodology develop-
ment strategies,  and a basis  for ranking
these source categories for methodology
development. Once the source categories
are ranked, research directed at methodol-
ogy development  will be able to focus on
each source category individually and pro-
vide a more exhaustive search of available
resources, where warranted.
  Additional  work  on  missing  and
unaccounted for source categories may in-
volve data  gathering and analysis, mea-
surements, and other research activities.
                                                                         •&U.S. GOVERNMENT PRINTING OFFICE: 1992 - 648-080/40179

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 S. Kersieter, D. Zimmerman, R. Cawkwell, A. Chadha, B. Manning. M. Henning, T. Lynch,
   P. Marsosudiro, W. Tax, D. Winkler, andG.  Woodwall, Jr., are with Alliance Technologies
   Corp., Chapel Hill, NC 27514
 £ Sue Klmbrough is the EPA Project Officer (see below).
 Ths complete report, entitled "Identification and Characterization of Missing or Unaccounted
   for Area Source Categories," (Order No. PB92-139 377/AS; Cost: $43.00, subject to
   change) will be available only from:
         National Technical Information Service
         5285 Port Royal Road
         Springfield, VA 22161
         Telephone: 703-487-4650
 Tho EPA Project Officer can be contacted at:
         Air and Energy Engineering Research Laboratory
         U.S. Environmental Protection Agency
 	Research Tnangle Park, NC 27711
  United States
  Environmental Protection
  Agency
Center for Environmental
Research Information
Cincinnati, OH 45268
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POSTAGE & FEES PAID
         EPA
   PERMIT No. G-35
Official Business
Penalty for Private Use $300
EPA/600/SR-92/006

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