United States Environmental Protection Agency Risk Reduction Engineering Laboratory Cincinnati, OH 45268 Research and Development EPA/600/SR-94/127 September 1994 4/EPA Project Summary Bicarbonate of Soda Blasting Technology for Aircraft Wheel Depainting Abraham S. C. Chen, Lawrence A. Smith, and Robert F. Olfenbuttel This evaluation addressed product quality, waste reduction/pollution pre- vention, and economics in replacing chemical solvent strippers with a bi- carbonate of soda blasting technology for removal of paint from aircraft wheels. The evaluation was conducted in the Paint Stripping Shop at Ellington Field, National Aeronautics and Space Administration/Lyndon B. Johnson Space Center (NASA/JSC), in Houston, TX. The evaluation used limited new test data, information from previous tests by NASA/JSC as part of their pro- gram to adopt this process as a non- destructive inspection of aircraft wheels, cost estimates for the chemi- cal stripping and bicarbonate blasting based on facility records. Because the paint being removed contained hazard- ous metal constituents, the liquid and solid wastes as well as the cloud of spray generated were evaluated for metal concentrations present and their teachability. Analyses for Cd, Cr, Cu, Pb, Mn, Ni, and Zn were made as well as total metals concentrations, pH, to- tal suspended solids, and oil and grease. The blasting technology is ef- fective for removing paint from aircraft wheels without significant damage to the anodized surface under the paint. Engineering improvements that avoid the need of respirators, reduce noise levels, and minimize water use could enhance the application. Applications that do not contain hazardous materi- als in the coating being removed could be significantly more lucrative. In com- parison to solvent depainting, this tech- nology reduced the amount of hazard- ous waste generated as well as cost savings due to reduced operating and disposal costs, resulting In a 15% re- turn on Investment in about 4 years. This Project Summary was developed by the EPA's Risk Reduction Engineer- Ing Laboratory, Cincinnati, OH, to an- nounce key findings of the research project that Is fully documented In a separate report of the same title (see Project Report ordering Information at back). Introduction The objective of the U.S. EPA's Waste Reduction Innovative Technology Evalua- tion (WRITE) Program was to evaluate, in a typical work place environment, ex- amples of prototype technologies with the potential for reducing wastes at the source or for preventing pollution. The goal of this study was to evaluate a bicarbonate of soda depainting technology that uses sodium bicarbonate-based blasting media to replace chemical solvents, such as trichloroethylene (TCE), for stripping paints from aircraft wheels. Specifically, this study evaluated (1) the effectiveness of this tech- nology, (2) the waste reduction and pollu- tion prevention potential, and (3) the economics. Bicarbonate of soda blasting is a rela- tively new process that is commercially available. Compressed air delivers sodium bicarbonate media from a pressure pot to a nozzle where the media mix with a stream of water. The media/water mixture impacts the coated surface and removes old coatings from the substrate. The wa- Printed on Recycled Paper ------- Tab/0 1. Oil and Grease. TSS, pH, and Metal Contaminants in Wastewater Collected from the Vat Parameter Oil and grease (mg/L) TSS (mg/L) pH C(f (mg/L) C/* (mg/L) Cif (mg/L) P& (mg/L) Mrf (mg/L) Ni " (mg/L) Zrf> (mg/L) Mean Concentration 49.1 253 8367 0.033 80690 1 240 1.430 0.022 0.006 5990 locaf Discharge Limit 200 365 6-10 0.2 5.0 2.0 1.5 3.0 3.0 6.0 Maximum allowable limits for grab samples. Industrial Waste Permit No 1030, City of Houston, Texas, March 10, 1989 Total metal Table 2. Total and Leachable Metals in Solid Waste that Settled to the Vat Bottom Leachable Metal (mg/L) Metal Cd Cr Cu Pb Mn Ni Zn Field Blank 0.50 0.69 1.30 1.70 0.19 0.50 1.90 Mean Concentration 2.73 14607 3297 70.87 277 0.72 281.33 Field Blank 0005 0012 0003 0019 0005 0.005 0 056 Data have been corrected with field blank. operator was measured in terms of air- borne metal concentrations. Noise levels were measured on a sound-level meter and a dosimeter. Air emissions were measured in the breathing zone of the operator and ana- lyzed for Cd, Cr, Cu, Pb, and Zn. The cloud of mist created around the blasting activity was maintained within the work area and removed by a ventilation system consisting of an exhaust hood and a rotoclone dust separator. The results of the airborne metal expo- sure study indicated that 8 hr time- weighted average (TWA) exposure to the airborne metals were below specified OSHA and American Conference of Gov- ernmental Industrial Hygienists (ACGIH) limits. Sound levels measured periodically in the operator's hearing zone during the two blasting sessions ranged from 76.8 decibels (dB) on the "A"-weighted scale (dBA) to 120.0 dBA. Dosimetry samples integrated cumulative noise exposures of 106.6 and 101.7 dBA for the first and the Mean Concentration 0.0303 22006 03927 05397 0.0023 00017 4.2840 second blasting session, respectively. These samples were based on 8-hr TWA calculated from dosimetry results recorded during the period sampled. If the actual work period were increased to a full 8 hr, the projected 8-hr TWAs would be 121.3 for the first test and 115.9 dBA for the second lest. A peak level of 146 dBA, the maximum level the dosimeter is capable of measuring, was recorded during both periods sampled. Economic Evaluation Cost comparisons were made for bicar- bonate blasting vs. chemical stripping. Blasting times to strip each wheel were measured during the test. NASA/JSC his- torical data were used to determine chemi- cal stripping times. The capital investment, operating costs and payback period were calculated according to the worksheets provided in the U.S. EPA Waste Minimi- zation Opportunity Assessment Manual. The results of the economic analysis indi- cated that a return on investment (ROI) greater than 15% (which is the cost of capital) could be obtained in 4 years, or that the payback period for NASA/JSC would be 4 years. Conclusions/Recommendations Based primarily on two depainting cycles and a previous NASA/JSC study, the bi- carbonate of soda blasting evaluation con- cludes that the blasting technology can effectively strip paint from aircraft wheels. The anodized surface damage, as a re- sult of blasting, is considered minimal. The blasting technology substantially reduced the number of man-hours required for paint stripping in comparison to chemi- cal stripping. The time saved was more than 95%. The liquid waste accumulated in the vat contained higher-than-discharge- limit Cr and could not be disposed of to the POTW. The quantity to be shipped away as hazardous waste was about 7.5 gal/T-38 aircraft wheel. The solid waste in the vat contained paint chips and debris, most of which was insoluble under the TCLP conditions. The wastewater in the rotoclone separator could be sewered with- out treatment. Although convenient for this application and within the existing local limits, the source reduction of this waste as well as reuse/recycling should be in- vestigated in greater depth. Although the exhaust ventilation system kept the heavy metal concentrations in the workspace below OSHA and NASA limits, the opportunities for source reduc- tion to minimize rotoclone wastewater should be explored. The operator of the blasting equipment was required to wear a full-face air-purify- ing respirator and protective clothing. Al- though the present test results did not make this an OSHA requirement, previ- ous testing of this system produced chrome particulate concentrations that did. The added precautions are recommended until a better understanding of the system is developed. Improved lighting for better visibility at the work surface also is rec- ommended. The noise measurements indicated that, under the conditions encountered during this study, hazardous noise exposures can result. Therefore, engineering control of noise exposure should be investigated. Hearing protection devices for all person- nel who operate or work in the vicinity of the operation should be provided with the present configuration. Evaluation of the hearing protectors used during the actual times worked during this study indicated that the protectors reduced exposures to below the OSHA and NASA permissible exposure limits. For compliance with the ------- NASA NHS/H-1845.4, work durations us- ing the blasting equipment and the hear- ing protectors assigned should not exceed 5 hr in an 8-hr work shift. NHS/IH-1845.4 requires use of both plugs and muffs when exposures equal or exceed 110 dBA. NASA Environmental Health Services (EHS) also requires all personnel who rou- tinely operate the blasting equipment to be placed in a hearing testing and evalua- tion program at the NASA/JSC clinic. The blasting technology has good po- tential for reducing waste and consequent waste disposal costs. For the application studied, this is due primarily to changing the waste from a RCRA hazardous cat- egory to a nonhazardous category. Paint stripping shops may find this technology beneficial, especially as more stringent fed- eral and local regulations are implemented for the disposal of the toxic solvent-con- taminated wastes. When no hazardous contaminants are present in the paint, elimination of all hazardous waste may be possible. The full report was submitted in fulfill- ment of Contract No. 68-CO-0003 by Battelle Memorial Institute under the spon- sorship of the U.S. Environmental Protec- tion Agency. A.S.C. Chen, LA. Smith, and P.P. Olfenbuttel are with Battelle Memorial Institute, Columbus, OH 43201-2693. Ivars Llcls is the EPA Project Officer (see below). The complete report, entitled "Bicarbonate of Soda Blasting Technology for Aircraft Wheel Depainting," (Order No. PB94-193323; Cost: $19.50, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Risk Reduction Engineering Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati, OH 45268 Official Business Penalty for Private Use $300 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 EPA/600/SR-94/127 ------- ter used dissipates the heat generated by the abrasive process, aids the paint re- moval by hydraulic action, and reduces the amount of dust in the air. As another convenience, the workers do not need to prewash or mask the surface. The dust, unlike that of plastic media, is not an ex- plosive hazard, nor is sodium bicarbonate toxic in this form. The airborne particulates generated from the stripping operation, however, can contain toxic elements from the paint being removed. The effectiveness of bicarbonate of soda blasting depends on optimizing a number of operating parameters including nozzle pressure, standoff distance, angle of im- pingement, media flow rate, water pres- sure, and traverse speed. The present study evaluated the bicar- bonate of soda blasting technology, ARMEX®/ACCUSTRIP™ (see Figure 1)*, marketed by the CDS Group (Houston, * Mention of trade names or commercial products does not constitute endorsement or recommendation for use. Texas). The evaluation was conducted at NASA/JSC's Ellington Field, which main- tains and repairs a fleet of 37 aircraft and has adopted this method for inspecting aircraft wheels. Product Quality Evaluation Although the quality of the work for this bicarbonate blasting system was based on paint removal without damage to the wheel surface that either modified metal performance or masked any cracks dur- ing inspection, an additional issue was the anodized layer below the paint. The previous method included scrub- bing and scraping that produced signifi- cant damage to the anodized layer. As an added feature of the bicarbonate blasting technology, the effect on the anodized layer was determined by inspection of the condition of the anodized layer for two cycles of depainting. A special test method was developed to qualitatively assess the anodized surface damage resulting from bicarbonate blast- Water line Figure 1. ACCUSTRIP SYSTEM™ with wet blast head. ing. The method required visual inspec- tion of the same wheel pieces after they were first stripped and after they were repainted and restripped under the same stripping conditions. The results of the inspection suggested minimal, if any, damage as a result of bicarbonate blasting. Most damage ob- served occurred in the areas around the slots, ridges, and bead rim and was attrib- uted to mechanical wear caused by tool contact and wear and tear. This study did not evaluate the effects of blasting on metal substrate damage and crack closure because the literature has already established the negligible dam- age and crack closure caused by the blast- ing. Waste Reduction and Pollution Prevention Potential Evaluation The waste reduction was measured in terms of volume reduction and pollutant reduction. Volume reduction addressed the gross wastestream such as liquid and solid wastes in the vat and wastewater in the rotoclone separator. Pollutant reduction involved individual pollutants, such as oil and grease, total suspended solids (TSS), and heavy metals, in the gross wastestream. Pollutant reduction ad- dressed the specific hazards of individual pollutants. About 30 gal of wastewater was gener- ated and collected in a vat during each of the two blasting sessions. The mean val- ues for the measured pollutants are pre- sented in Table 1. The Cr concentration did not meet the local discharge limits, so the wastewater could not be disposed of to the Publicly Owned Treatment Works (POTW). About 8 gal of solid waste settled to the bottom of the vat. Metal concentrations measured are presented in Table 2. Only a very small fraction of these metals was leachable under the Toxicity Characteris- tic Leaching Procedure (TCLP) conditions (see Table 2). TCLP requires the waste to meet limits of 1.0 mg/L Cd, 5.0 mg/L Cr, and 5.0 mg/L Pb. No regulations have been set for Cu, Mn, Ni, and Zn, The wastewater in the rotoclone separator con- tained less than detection limit of TSS and a very small amount of heavy metals, ranging from 0.005 mg/L of Cd to 0.39 mg/L of Zn. For the particular case tested, the wastewater could be sewered without treatment. Other considerations were hazards that the stripping technology might pose to workers. These included toxic airborne particulates and unsafe noise exposures. Air quality in the vicinity of the blasting ------- |