United States Environmental Protection Agency Research and Development Air and Energy Engineering Research Laboratory Research Triangle Park, NC 27711 EP/V600/SR-94/218 Project Summary Soil Radon Potential Mapping of Twelve Counties in North-Central Florida Kirk K. Nielson, Rodger B. Holt, and Vern C. Rogers This report describes the approach methods, and detailed data used to pre- pare soil radon potential maps of twelve counties in North-Central Florida. The maps were developed under the Florida Radon Research Program to provide a scientific basis for implementing radon-protective building construction standards in areas of elevated risk and avoiding unnecessary regulations in areas of low radon risk. Calculated soil radon potentials re- flect geographic variations by model- ing the potentials as the rate of radon entry into a reference house that Is successively modeled on the soils in each radon map region. Individual soil profile properties are defined by hori- zon from county soil survey data Ra- don source properties are defined from aeroradiometric data and from soil ra- dium and radon emanation measure- ments. Calculated rates of radon entry into the reference house are grouped into tiers for display on radon potential maps. Comparison of the calculated radon entry rates with indoor radon data yields a geometric standard de- viation of 2.1 and indicates that the reference house is consistent with the aggregate properties of the Florida houses in the comparison. This Project Summary was developed by EPA's Air and Energy Engineering Research Laboratory, Research Tri- angle Park, NC, to announce key find- ings of the research project that is fully documented in a separate report of the same title (see Project Report ordering Information at back). Introduction Soil radon potential maps are being de- veloped for Alachua, Citrus, Clay, Duval Flagler, Lake, Levy, Marion, Nassau' Putnam, St. Johns, and Volusia counties in Florida. They are designed to show from soil and geological features the ar- eas that have different levels of radon potential. The maps are being developed under the Florida Radon Research Pro- gram to provide a scientific basis for imple- menting radon-protective building construc- tion standards where they are needed and to avoid the cost of unnecessary imple- mentation where they are not needed. Soil radon potentials are defined for mapping purposes as the calculated annual-average rate of radon entry from soils into a reference house. They are calculated to represent geographic radon sourcia distributions, minimizing the influ- ences of house and occupant variations temporal variations, and political and insti- tutional boundaries (city, county, etc.). The mapping approach consists of Definition of radon map polygons (geographic areas on a radon map) from existing soil and geologic maps. Definition of the soil profiles asso- ciated with each radon map poly- gon and their associated radon gen- eration and transport properties. Calculation of numeric soil radon potentials for individual soil profiles and an area-weighted average to represent each radon map polygon. a. b. c. Printed on Recycled Paper ------- d Grouping map units with similar ra- don potentials and plotting the ra- don map polygons by color-coded radon potential tiers. Radon map polygons ^redefined by tho digital intersection of STATSGO soil map units with digitized surface-geology map units. The intersections to def.ne the polygons were performed with a geo- maphic information system under Arclnfo format at the University d Florida GeoPlan Center. The STATSGO soil maps defined 29 units in Alachua County, 13 in Citrus County, 14 in Clay and Duval counties, 13 in Flagler County, 16 in Lake County. 21 in Levy County, 20 in Marion County, 11 in Nassau County, 20 in Putnam County, 18 in St. Johns County, and 21 in Volus.a County. The map units occurred in mul- tiple polygon areas in each county, rang- ing from about 40 to 120 polygons per county. When intersected by geology poly- gons, the number of map polygons was approximately doubled. Soil profiles in each polygon were de- fined from county soil sunwdate comi- piled at the University of Florida Soil and Water Science Department for each hori- zon in each of several profiles. The data included horizon depth and thickness, den- sity, textural analyses and classifications, water drainage characteristics, high water table depths and durations, and related physical properties. Radon Entry Modeling Soil radon potentials were defined to eliminate house and occupant variables by using a hypothetical "reference house with invariant properties, including indoor pressure, ventilation rate, slab and foun- dation design and attributes, and other reference conditions. The reference house was modeled as if it were located on each of the soil profiles that made up the land areas of each map polygon to reflect the average differences and variabilities in ra- don potential between and within the map polygons. The annual-average rates of ra- don entry into the reference house were modeled using complete, multiphase ra- don generation and transport equations. They characterize indoor radon entry by both diffusion (concentration-driven) and advection (with pressure-driven air flow). The soil radon entry modeling for the reference house utilized detailed soil pro- file data defined by county soil survey analyses and surface geology data. The detailed soil profiles analyzed with the ref- erence house for each location included individual radon source and transport prop- erties of each soil horizon. The reference housa was defined with the approximate characteristics of Florida slab-on-grade single-family dwellings. It consisted of an 8 6 x 16.5m rectangular structure with a perimeter shrinkage crack between the floating floor slab and the stem walls. The indoor pressure, house ventilation rate. floor slab properties, and other house char- acteristics were based on typical values measured in Florida houses. The radon entry modeling represented soil moisture profiles under the reference house by an annualized distribution that was defined from the reported high water table depths and durations. Since the map calculations utilized a fixed set of house and foundation charac- teristics and considered only vertical varia- tions in radon source and transport prop- ertiesMhe 2-dimensionaURAdon-Emana-- tion and TRansport into Dwellings (RAETRAD) model was used to develop a more efficient, 1-dimensional algorithm that gave equivalent results for the refer- ence house. The specialized radon poten- tial cartography algorithm was named RnMAP and was shown to approximate the reference-house RAETRAD analyses within about 5%. Most of this difference resulted from the finite-difference math- ematics in RAETRAD compared to ana- lytical radon calculations in RnMAP. The 1 -dimensional radon generation and trans- port calculations in RnMAP define the sub-slab radon concentration, from which radon entry rates are computed with em- pirical functions for radon diffusion through the intact floor slab and for diffusive and advective transport through floor cracks. The empirical functions, fitted to the sub-slab soil properties, also define the coupling of the soil region to the reference-house slab properties based on corresponding RAETRAD calculations. Radon Source and Transport Parameters , Radon potentials of each map polygon were calculated from the radon source and transport properties of the soil pro- files comprising the polygon region. Ra- don source properties were estimated from National Uranium Resource Evaluation (NURE) aeroradiometric data for shallow horizons (0 to 2 or 2.5m). and from geo- logical classifications of the soils for deep horizons (to 5m depth). The NURE data were averaged [to obtain a geometric mean and geometric standard deviation (GSD)1 for each polygon from data in an flight-line segments within the polygon, and were converted from equivalent uranium concentrations to corresponding radium concentrations for the model calcutalions. Polygons not intersected by NURE flight lines were represented by the geometric mean and GSD of all NURE data for their geological classification in the county. The NURE flight-line data were partitioned digi- tally into map polygon segments with the same geographic information system used to define the map polygons. Radon amanation coefficients for each of the NURE-based radium concentrations were defined from a measured trend of increasing emanation with radium concen- tration. The trend had the form E » 0 15Ra + 0.20 for radium levels below 23 pCi g-1 and remained constant at 0 50-0.55 for higher radium levels. The trend was based on emanation measure- ments from over 200 samples from the twelve counties. Most of the samples were from University of Florida soil-survey ar, chives and corresponded to the soils used to develop the STATSGO soil maps The remainder were from U.S. Geological Sur- vey borings. To attain adequate precision at low radium concentrations, the radon emanation measurements utilized a new effluent technique that is described and validated in the full report. Deep-soil radium concentrations were defined from surface geology classifica- tions and radium measurements in a larger qroup of over 600 soil samples. These included the samples used for emanation measurements plus additional samples from the same sources. Radon transport properties were esti- mated from soil profile physical data com- piled for each STATSGO soil map unit. The radon transport properties (radon dif- fusion coefficients and air permeabilities) were calculated from empirical correlations with soil horizon water contents, porosi- ties, and particle sizes. Soil horizon water contents were calculated from their height above the water table using soil water drainage data. Steady-state water balance calculations indicated that for water tabes - in the 5m or shallower range, sub-slab soil water contents were well-approximated by the soil drainage-curve moisture at a matric potential that was equal to the dis- tance above the water table. Water drain- aqe data compiled for each soil horizon in each soil profile therefore were directly interpolated from the horizon-to-water-tab e distance to estimate soil moistures Field measurements of near-surface soil water matric potentials at 46 locations in Central Florida confirmed the range of matric po- tentials being used. Calculation of Soil Radon Potentials Soil radon potentials were computed Dy mathematically modeling the reference ------- house as if it were located on each soil profile of each of the radon map poly- gons. The RnMAP calculations used the specific radon source and radon transport properties of the horizons in each soil profile. The radon potentials were calcu- lated as the rate of radon entry into the reference house in annual units (mCi y1) to emphasize the long-term average na- ture of the radon potential estimates. Radon potentials were calculated for each of several soil profiles in each poly- gon, at each of two or three seasonal water table depths. They then were aver- aged seasonally to obtain annual-average radon potentials, which in turn were aver- aged over the different profiles to repre- sent each polygon. Radon potentials also were calculated for both low- and high-radium geology, and the applicable geologic classification was used afterward to select the appropriate values to repre- sent each polygon. Separate radon potentials were calcu- lated for the estimated median of the dis- tribution in each polygon and also for ra- don potentials corresponding to the 75, 90, and 95% confidence limits. The confi- dence limits were based on the geometric means and GSDs of radium computed from the NURE data distributions in each polygon and also on the varied properties of the different soil profiles that comprised the polygon. Production and Interpretation of the Radon Maps The resulting radon potentials were par- titioned into seven tiers of similar numeri- cal values for display on the radon poten- tial maps. The tiers corresponded to the <0.4, 0.4-1, 1-2, 2-3, 3-6, 6-12. and >12 mCi y1 levels of radon potential. This set of tiers provided suitable ranges for using a uniform tier scale on all of the radon potential maps. Map polygons were col- ored according to the appropriate tier clas- sification for intuitive visual interpretation. However the numerical values of the ra- don potentials for each map polygon are presented in the report for more quantita- tive map interpretations. A radon potential of 3 mCi y1 corresponds to approximately 3.9 pCi L1 in the reference house. Separate maps were plotted for the me- dian, 75, 90, and 95% confidence limits of radon potentials to give a better perspec- tive of radon potentials in a given polygon (region). Regions with low potentials on both the median and higher-confidence-limit maps exhibit reasonable assurance of hav- ing minimal indoor radon risk. Regions with high radon potentials on the median and higher-confidence-limit maps conversely have a relatively high probability of el- evated indoor radon levels. Regions with low median radon potentials but high pd- tentials for higher confidence limits are heterogeneous (low median; high GSD) arid may have generally low radon poten- tials but occasional to frequent anomalies with high radon potential. Special consid- erations may be needed to define radon-protective building needs in these areas. The calculated soil radon potentials ware compared with 804 indoor radon mea- surements in the twelve counties from the state-wide land-based radon survey. The comparison was consistent with the reference-house indoor radon accumula- tion rate of 1.3 pCi L1 per mCi y1 of soil radon potential and with an ambient out- door radon concentration of approximately 0.3 pCi L-'. The GSD between measured indoor radon levels and those predicted from the maps was 2.08, which is the approximate level of precision associated with the calculated soil radon potentials. The total variation among measured in- door radon levels was partitioned to esti- mate a house variability of GSD=3.7, com- pared to soil variability on the order of GSD=2.2 to 2.4. Uncertainties are much higher in predicting an indoor radon level for a particular house than for predicting the median level in the reference house for a given polygon. ------- K Wfe/son, R Holt, and V. Rogers are with Rogers and Associates Engineering ' Corp., Salt Lake City, UT 84110-0330. changa) will be available only from National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at Air and Energy Engineering Research Laboratory U S. Environmental Protection Agency Research Triangle Park, NC 27711 United States Environmental Protection Agency Center tor Environmental Research Information Cincinnati, OH 45268 Official Business Penalty for Private Use $300 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 EPA/600/SR-94/218 ------- |