United States
                   Environmental Protection
                   Agency
National Exposure
Research Laboratory
Research Triangle Park, NC 27711
                   Research and Development
EPA/600/SR-97/034   July 1997
&EPA        Project Summary

                   Field  and  Laboratory
                   Evaluations  of  a  Real-Time
                   PAH  Analyzer
                   Mukund Ramamurthi and Jane C. Chuang
                    This study is a continuation of a pre-
                   vious evaluation of a real-time analyzer
                   for polycyclic aromatic hydrocarbons
                   (PAH) in air. The  responses of the  in-
                   strument, Gossen PAS Models 10001
                   and  10021,  were  evaluated  for vapor
                   versus particle phase PAH, and for
                   variations in the environmental condi-
                   tions of temperature and humidity. The
                   noise and ozone  levels produced dur-
                   ing operation were measured. In addi-
                   tion, a cigarette smoke generator was
                   developed for use in field evaluations
                   of the analyzer. The particle transmis-
                   sion efficiency was also measured for
                   a range of particle sizes below 1 |am.
                    In general, the  PAS responded only
                   to PAH in the particulate phase. Small
                   responses to vapor-phase PAH in two
                   experiments were found to be associ-
                   ated with adsorption of the test PAH
                   on particle  surfaces. Small and insig-
                   nificant ozone levels  were  measured
                   within a few inches of the instrument.
                   Its noise output was below the NC-35
                   criterion, except in the frequency range
                   1000 to 3000 Hz,  where the noise ap-
                   proached NC-40. Temperature and hu-
                   midity did not affect the response of
                   the PAS to aerosols that were equili-
                   brated at the test  temperature.
                    The particle transmission  efficiency
                   through the PAS was determined  for a
                   range of aerosols 0.034 to 0.32 |am. Large
                   particle losses below 0.10 um were iden-
                   tified. A modified sampling configura-
                   tion was developed, which increased the
                   particle transmission efficiency  to
                   greater than 90%  over the entire size
 spectrum, without having deleterious
 effects on the performance of the ana-
 lyzer.
   This Project Summary was developed
 by EPA's National Exposure Research
 Laboratory, Research Triangle Park, NC,
 to announce  key findings of the  re-
 search project that is fully documented
 in a separate report of the same title
 (see Project Report ordering informa-
 tion at back).

 Introduction
  The  PAH analyzers evaluated in this
 study were a  Model PAS 10001 Photo-
 electric Aerosol Analyzer, manufactured
 by Gossen, GmbH (Erlangen, Germany)
 and two of a  newer version,  Model PAS
 10021,  purchased  from  EcoChem Tech-
 nologies, Inc.  (West Hills, CA). The PAH
 analyzers are  based  on the principle of
 photoelectric ionization of PAH adsorbed
 on the surface of aerosol particles. Their
 operation is discussed in detail in the re-
 port on the first phase of this study (Re-
 port  on Work Assignment  13, Contract
 68-DO-0007).
  The earlier evaluation showed the PAS
 provides a real-time (< 5 s) response that
 correlates  with indoor  fine  particulate-
 phase PAH (< 2.5 u.m) and does not re-
 spond to two-ring PAH vapors.  The  re-
 sults suggested that the PAS had poten-
 tial for screening and  semiquantitative
 measurement of human exposure to air-
 borne PAH in  ambient and indoor air, and
 for indicating  activities that may lead to
 PAH exposures.

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  The  following objectives were estab-
lished for this follow-on study to (1) deter-
mine whether the PAS responds to a num-
ber of different two- to four-ring PAH va-
pors, (2)  measure the noise and ozone
output of the PAS, (3) develop a cigarette
smoke generator  capable of  use in field
evaluations of the  PAS, (4) determine the
effects of temperature  and  humidity  on
the PAS  operation,  (5)  investigate  the
transmission  of aerosol particles through
the PAS and modify it,   if necessary, to
improve this transmission, (6)  investigate
the response of the PAS  to aerosols that
do not contain PAH, and (7) compare the
PAS measurements with  PAH concentra-
tions obtained by  integrated air sampling
followed by GC/MS analysis.

Results and Conclusions
  The  PAH analyzer did not respond to
two- to four-ring  PAH  vapors,  including
naphthalene,  1-methylnaphthalene, chloro-
naphthalene,  phenanthrene, and fluoran-
thene. A small  signal, 0.008  pA, was ob-
served  for pyrene vapor at 3 ppb, when 50
to 60 particles/cc were also present in the
chamber. This  response  was most likely
due to condensation of pyrene on the sur-
faces of the particles.
  The PAS noise  level was generally be-
low the criterion of NC-35, except at fre-
quencies of  1000, 2000,  and 4000  Hz,
where the noise level was close to NC-40.
These sound  levels are between the  noise
levels  typically encountered  in private
homes and large offices. The operation of
the PAS did not  increase indoor ozone
levels significantly.
  The cigarette smoke generator that was
designed and fabricated is capable of pro-
viding field verifications of the performance
of the PAH analyzer. Despite the inherent
variability in the cigarette combustion pro-
cess, the  smoke generator elicits a rea-
sonably characteristic frequency distribu-
tion of PAS responses during a cigarette
test. Parameters that characterize this fre-
quency distribution can then be compared
with nominal ranges to verify operation in
the field. Additionally, the PAS  response
was well correlated with the particle  num-
ber concentration  of the cigarette smoke.
  Elevated or depressed temperature and
humidity operating conditions do not  have
a significant impact  on  the response of
the  PAS to  a cigarette smoke aerosol
equilibrated at the test temperature.
  The response of the PAS, operating at
typical  room  conditions, does  increase
slightly,  relative to particle  number  con-
centration, as  the temperature  of the
sampled air increases. Although  a mecha-
nism for this  insignificant increase is not
established, it appears likely that  as the
aerosol  temperature increases, the effi-
ciency of ionization of the surface PAH is
enhanced,  requiring  less energy for the
photoionization process.
  Aerosol  transmission  efficiency test
showed that the PAS, in its original de-
sign configuration, had significant particle
losses  in  the  silicone tubing and in the
electrofilter, particularly  at  particle  sizes
< 0.1  urn  diameter, where  the transmis-
sion  efficiency was  < 70%. A modified
configuration, consisting of bypassing the
electrofilter and using stainless steel tub-
ing, provided transmission efficiency > 90%
for all test  aerosols,  ranging in monodis-
perse size  from 0.034 to 0.32 |im. Field
trials in various indoor microenvironments
indicated no deleterious effects on overall
analyzer performance as a result of the
modified design configuration. Under typi-
cal indoor conditions  in both smoking and
nonsmoking environments, an  improve-
ment in the sensitivity of the analyzer was
also observed.
  The  PAS response to  non-PAH test
aerosols, normalized  to aerosol  number
concentration, was very small and propor-
tional to  particle surface area for sodium
chloride,  ammonium  sulfate, and  phthalic
anhydride aerosols generated from drying
nebulized water solutions  of the respec-
tive compounds. When the phthalic anhy-
dride  and  dioctyl  phthalate  were  nebu-
lized from isopropyl alcohol, the PAS re-
sponse was much smaller and only weakly
proportional to particle surface area. The
results suggest  that the weak PAS re-
sponse to non-PAH aerosols arises from
impurities in the solvents used to gener-
ate the nebulized droplets.
  In eight homes, fine particle PAH con-
centrations  in  indoor air,  measured from
integrated sampling and GC/MS analysis,
ranged from 27 to 120 ng/m3  These mea-
sured PAH concentrations were within one-
fifth to two times the total fine particle
PAH concentrations  estimated from  the
PAS response, using  a conversion  factor
of 3000 ng/m3  per pA of electrometer sig-
nal.

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     Mukund Ramamurthi and Jane C. Chuang are with Battelle, Columbus OH 43201-
       2693.
     Nancy K. Wilson is the EPA Project Officer (see below).
     The complete report, entitled "Field and Laboratory Evaluations of a  Real-Time
       PAH Analyzer," (Order No. PB97-176 838; Cost: $28.00, subject to change) will
       be available only from:
             National Technical Information Service
             5285 Port Royal Road
             Springfield, VA 22161
             Telephone: 703-487-4650
     The EPA Project Officer can be contacted at:
             National Exposure Research Laboratory
             U. S. Environmental Protection Agency
             Research  Triangle Park, NC 27711
United States
Environmental Protection Agency
Center for Environmental Research Information
Cincinnati, OH 45268

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