United States Environmental Protection Agency National Risk Management Research Laboratory Cincinnati, OH 45268 Research and Development EPA/6QQ/SR-97/081 October 1997 Life Geoffrey M. Lewis and Gregory A. Keoleian The life cycle design framework was applied to photovoltaic (PV) module de- sign. The primary objective of this project was to develop and evaluate design metrics for assessing and guid- ing the improvement of PV product sys- tems. Two metrics were used to assess life cycle energy performance of a PV module: energy payback time and elec- tricity production efficiency. These metrics are based on material produc- tion, manufacturing, and transportation energies, and were evaluated for sev- eral geographic locations. An alumi- num frame is responsible for a significant fraction of the total energy invested in the module studied. Design options to reduce the energy impact of this and other components are dis- cussed. This Project Summary was developed by EPA's National Risk Management Research Laboratory, Cincinnati, OH, to announce key findings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). Introduction Interest in sustainable energy technolo- gies that are both practical and affordable has increased with growing awareness of the environmental and political conse- quences of fossil fuel and nuclear electric- ity generation. PV modules, one variety of which is the subject of this report, offer a promising alternative to our current de- pendence on nonrenewable energy tech- nologies. Photovoltaic modules convert some of the energy contained in sunlight directly into electricity without producing waste or emissions. This life cycle design project was a col- laborative effort between the University of Michigan and United Solar Systems Cor- poration (United Solar). United Solar is a joint venture between Energy Conversion Devices (ECD) of Troy, Michigan, and Canon, Inc. of Japan. ECD is a leader in the research and development of thin film amorphous silicon photovoltaic modules. Canon is known worldwide as a manufac- turer of electronic, office, and photographic equipment. The United Solar UPM-880 tandem junc- tion commercial power generation module was the product chosen for this demon- stration project. The UPM-880 is currently United Solar's standard power generation module and is the most directly compa- rable with other manufacturers' products. It employs thin film amorphous silicon as the photovoltaic material and contains two identical semiconductor junctions (hence, tandem). This module has a rated output power of 22 watts, is 119.4 x 34.3 x 3.8 centimeters in size, weighs 3.6 kilograms, and has a stabilized conversion efficiency of 5%. The UPM-880 represents a point in the development of thin film PV technology which has since been surpassed. The op- portunity to influence this technology im- provement made the UPM-880 product system a good candidate for study. United Solar is exploring innovative applications of thin film PV technology including incor- poration of PV into building materials such as standing seam metal roofing systems and roofing shingles that have the ap- ------- pearance of common asphalt shingles. Roofs, glazings, and facades all become producers of electricity in addition to per- forming their traditional structural or archi- tectural functions when thin film PV materials are used to coat building sur- faces. These building-integrated PV appli- cations are made possible in part by thin film characteristics such as ruggedness, flexibility, and low cost. Life cycle design was developed to more effectively integrate environmental consid- erations into product system design. The product system encompasses material pro- duction, parts fabrication and assembly, use, and retirement. Systems analysis based on the product life cycle offers a comprehensive approach for guiding im- provement of photovoltaics and other prod- ucts. Objectives The primary objective of this demon- stration project was to develop and apply design metrics for assessing the energy performance of photovoltaic technologies. This study was a partial application of the life cycle design methodology which also includes the assessment of waste and emissions throughout the product life cycle. The scope of this study was limited by the availability of life cycle inventory data. The two metrics discussed here are energy payback time and electricity production efficiency. The length of time required for a mod- ule to generate energy equal to the amount required to produce it from raw materials is called the energy payback time. Energy payback time is frequently used as a per- formance benchmark for renewable en- ergy technologies, particularly PV. Fossil fuel and nuclear electricity generating plants are not evaluated by energy pay- back time because they effectively never pay back. Generating losses and the on- going need for input energy (as fuel) con- spire to ensure that fossil fuel plants cannot generate as much energy as they con- sume on a primary energy basis. Electricity production efficiency is de- fined as the ratio of the total energy pro- duced by a generating system over its lifetime to the sum of energy inputs re- quired for the system's manufacture, op- eration and maintenance (including fuel), and end-of-life management. This ratio can be used to compare all types of renew- able or fossil fuel based generating tech- nologies. Product Description Over 26 different materials are used in the production of the UPM-880, 20 of which are actually incorporated into the finished product. Module production begins with a stainless steel substrate which is pro- cessed in the following steps: washing, back reflector deposition, amorphous sili- con alloy deposition, transparent conduc- tive oxide (TCO) deposition and scribing, short passivation, grid pattern printing, and cell cutting. All steps through TCO depo- sition are continuous processes. The processed substrate is laminated inside encapsulation materials which pro- vide environmental protection while allow- ing the maximum amount of light transmission to the active photovoltaic material. A sandwich of materials is as- sembled in the following order (from front to back): Tefzel (a Teflon based polymer), EVA, the processed substrate, an EVA/ polymer composite layer, and finally a gal- vanized steel backing plate (Figure 1). The steel backing plate is laminated to the material in the rest of the module by EVA, making its separation during disas- sembly nearly impossible. The steel back- ing plate and aluminum frame serve as structural components only, providing ri- gidity and mounting points for the module. Methodology Scope and Boundaries Clearly defined boundaries that constrain data gathering and analysis are critically important in comparative product system studies. Results depend directly on bound- ary definition, which also determines whether the results may be compared with those of other studies. This study included data for raw material extraction and pro- cessing (for both product and process materials), transporting processed materi- als to manufacturing facilities, manufac- turing, transporting modules to the use site, and module use. All data were deter- mined on a per module basis. Not in- cluded were data on installation or balance-of-system (BOS) components. BOS components include mounting and support structures, tracking hardware (un- less the array is fixed), wiring and termi- nals for interconnection of modules in the array, power inverters to convert the DC output of the PV module into utility-grade AC and to interface with the utility electric- ity grid, energy storage (if the array is not grid-connected), and labor for installation, operation and maintenance. Energy used for the manufacturing facility physical plant (lighting and space conditioning) and en- ergy involved in packaging and packaging materials were also not included. Data on the end-of-life phase were not collected since there is no infrastructure to deal specifically with PV modules. En- ergy required for or credited from reuse or recycling options was not considered in this study, except as discussed in the Design Implications section below. Data Collection and Analysis All energy data were considered on a per module basis and were converted to equivalent primary energy (EPE) to ac- count for losses in conversion and gen- eration. EPE makes all energy data functionally equivalent, allowing direct com- parison. For example, electric energy from the grid cannot accurately be compared to natural gas energy without taking into account production efficiencies for both electricity generation and natural gas pro- duction. Ignoring the fuel required to pro- duce electricity significantly distorts analysis. To avoid this, the United States average electricity generating efficiency ratio of 0.32 was used to convert electric- ity to EPE for this study. Materials Published data for extracting and pro- cessing raw materials (material produc- tion energy) were not available for all materials used to produce the UPM-880. Estimates were made for some materials based on discussions with industry sources. For materials manufactured by a small number of firms, energy data are usually considered proprietary. In these cases, we substituted data for similar ma- terials or processes. United Solar provided a bill of materials for the UPM-880 with all data items on a per module basis. United Solar provided data on supplier location and utilization Processed substrate EVA / polymer composite Steel backing plate Figure 1. Laminated module, edge cross section. ------- efficiency for each material as well, allow- ing a calculation of the actual amount of material incorporated into a module and the amount of waste material per module. The amount of energy expended to transport materials to United Solar facili- ties was calculated using distances deter- mined from the location data, information on transportation energy requirements in units of energy per weight-distance (Btu per ton-mile), and material weight data from the bill of materials. It was assumed that a diesel tractor trailer was used for all overland transportation and an ocean freighter was used for all overseas trans- portation. Manufacturing There are three components of manu- facturing energy: processing energy, en- ergy in process materials, and energy for transportation to the use site. Manufactur- ing process energy data were provided, on a per module basis, by United Solar. Process materials were handled by the same method discussed above for prod- uct materials. In most cases, however, data on material production energy for process materials were not readily avail- able from the literature. The amounts of process materials used per module were low relative to most product material in- puts, so process materials were assumed to contribute a negligible amount to total module energy requirements. Use Use phase data for the energy payback time calculation consist only of insolation at the module location and the module's conversion efficiency (module size is a constant, equal to 0.372m2). Insolation data, as direct normal solar radiation in watt-hours per square meter per day, were taken from the National Renewable En- ergy Laboratory's (NREL) online computer database and converted to units of kilo- watt-hours per square meter per year. Data were taken for three cities of interest: De- troit, Michigan, near United Solar and the University of Michigan; Boulder, Colorado, near NREL; and Phoenix, Arizona, a loca- tion generally considered to be an excel- lent site for PV use. These three cities approximately span the range of insola- tion available in the continental United States, from a low of around 1200 kWh/ m2/yr in Detroit to around 2000 kWh/m2/yr in Boulder to a high of around 2500 kWh/ m2/yr in Phoenix. Life Cycle Metrics Material production energy includes en- ergy for raw material extraction, process- ing, and transportation. These data were gathered in megajoules per kilogram. Be- cause material production energy data vary over a wide range, low and high values were used in separate calculations, re- sulting in two values for each energy met- ric. The energy used to transport one module worth of materials to manufactur- ing facilities was then calculated and added to the material energy. Energy data for each module manufac- turing process step were gathered on a per module basis. This energy was all in the form of electricity and was converted to equivalent primary energy as discussed above. Transport to the use site was as- sumed to be by diesel tractor trailer. Calculating energy generated by a mod- ule in use requires data for its stabilized conversion efficiency and area, along with average insolation where it will be installed. Once the energy generated by a module was known, all data necessary to calcu- late energy payback time and electricity production efficiency metrics were avail- able. Two other metrics, life cycle conversion efficiency and life cycle cost, are discussed in the full report from this project. Energy Payback Time Payback time in years was calculated by dividing the total amount of energy used to manufacture a module from raw materials, install and operate it over its lifetime, and deal with end of life disposi- tion by the amount of energy a module generates in a year using Equation 1. The variables in this equation are defined as follows: Emat = energy to extract, process, and transport raw materials to the manu- facturing facility; Efab = energy to fabricate a module from raw materials and trans- port it to the use site; Einst = energy re- quired for module installation (assumed to be 0); Eelm = energy required for any end- of-life management activity (assumed to be 0); Egen/yr = energy generated by a module in one year; and E0&m/yr = energy used annually for operation and mainte- nance (assumed to be 0). lifetime (Eelm), using Equation 2. Eiom and Eelm were assumed to be zero for this analysis; in actuality both are likely to be small numbers. Payback time + E eim -gen' (1) Electricity Production Efficiency Electricity production efficiency is cal- culated by summing the energy pro- duced by a generating system over its lifetime (Egen (lifetime)), and dividing it by the sum of the energy inputs re- quired to manufacture (Emat + Efab), in- stall, operate and maintain (Eiom, which = Einst + (module lifetime) (E0&m/yrj), and dis- pose of or reclaim it at the end of its Electricity production efficiency Egen (lifetime) Emat+Efab + Eiom + Eelm (2) Electricity production efficiency was cal- culated for the same geographic locations as payback time. Two possible module lifetimes, 10 and 25 years, were chosen to demonstrate how this variable effects the metric (the UPM-880 is currently warranted for 10 years). Electricity production efficiency is pre- sented as a ratio. A system that gener- ates more energy than is required to produce it would have an electricity pro- duction efficiency greater than unity and could be considered to be a sustainable system. Results and Discussion Life Cycle Data Energy data for production and trans- port of product materials are shown on a per module basis in Table 1, sorted from highest energy at the top to lowest at the bottom. When more than one material is required for a function, it is noted as "vari- ous" in the material column. Notice also that there are two totals at the bottom of the table, one for a standard module and one for a frameless module. This classifi- cation highlights the impact of the alumi- num frame on the energy requirements for the UPM-880. Energy required for manufacturing, con- verted to equivalent primary energy (EPE), is shown in Table 2. These data were gathered at United Solar by measuring electrical consumption of the respective machines for the amount of time neces- sary to process one module. The bulk of this energy is invested in processes that require elevated temperatures for a long period of time (encapsulation) or at greatly reduced pressure (all of the deposition steps). Life Cycle Metrics Energy Payback Time Energy payback time results are pre- sented in Table 3. Module production en- ergy summarizes the material, transport, and manufacturing energy discussed in Tables 1 and 2 for both the standard and frameless cases. Table 3 presents energy payback times in years for various loca- tions and module conversion efficiencies. Energy generated per year is calculated as the product of insolation, conversion ------- Table 1. Product Constituent Material Production Energy, in MJ Function Frame Encapsulation Substrate Backing plate Deposition materials Busbar Back reflector Grid TCO Material aluminum various stainless steel steel various various various various various Low Case 196.0 84.0 58.7 9.7 7.7 0.8 0.2 * * High Case 566.1 114.8 73.0 65.4 7.7 3.6 0.7 * * Transport 7.8 7.7 3.9 6.1 0.1 0.1 * * * % Module Mass 38.0 25.2 11.4 24.8 * * * * * Standard, total material energy Frameless, total material energy 357.1 161.1 831.4 265.4 25.5 17.7 * Negligible amount, <0.05. Standard - low energy case uses lowest reported data and assumes 70% primary / 30% secondary frame material; high uses the highest available data and assumes frame is 100% primary aluminum . Frameless - low and high cases reflect the range of values reported in the literature. Source: Appendix B in [7]. Table 2. Manufacturing Equivalent Primary Energy (EPE) Process Step EPE (MJ) % of Total Encapsulation Amorphous SI alloy deposition TCO deposition Back reflector deposition Substrate wash TCO etch Short passivation Grid pattern screen print Testing and packaging Total process energy 56.2 37.9 32.7 30.3 23.1 7.0 7.0 7.0 * 201.2 28.0 18.8 16.3 15.0 11.4 3.5 3.5 3.5 * 100.0 * Negligible amount. efficiency, and module size. Energy pay- back time in years is calculated as mod- ule production energy (in kWh) divided by energy generated per year. The conver- sion efficiency of the UPM-880 is cur- rently around 5%, but energy payback times were also calculated for a conver- sion efficiency of 8% to illustrate the effect of efficiency improvements on payback time. United Solar has produced a proto- type module with a 10% conversion effi- ciency and is currently translating this technology into production. Our methodology results in payback times higher than previously reported. Srinivas reports payback times for 5% ef- ficient amorphous silicon modules pro- duced in batch production facilities outside North America. His results ranged from 2.18 years for a frameless module to 2.6 years for a module framed with plastic and glass using an insolation level roughly equivalent to our Detroit case. Hagedorn estimates a payback time of 3.5 years for a 5% efficient module framed with plastic and glass produced in a proposed facility. Construction and material factors in both of these studies seem to indicate modules with shorter lifetimes than the UPM-880. Payback times calculated in this study should be compared with others published in the literature only if differences in the assumptions, data, and methodologies are carefully considered. Electricity Production Efficiency Electricity production efficiency results are presented in Table 4. Module produc- tion energy is identical to that noted in Table 3 and the same three locations are used, although the number under the lo- cation now represents the amount of elec- tricity generated per year by a module at 5% conversion efficiency. Energy gener- ated over a module's lifetime is the prod- uct of electricity generated per year and module lifetime. Electricity production effi- ciencies were calculated with Equation 2. Note that the high electricity production efficiency value for each case results from the low module production energy value, and vice versa, and also that values less than unity result from module production energy being greater than energy gener- ated. For comparative purposes, the United States electricity grid has an average elec- tricity production efficiency of 0.32. Design Implications Two components of the UPM-880 pho- tovoltaic module offer major opportunities for improved design: the aluminum frame and EVA encapsulant. Energy invested in the aluminum frame consists of material production energy and energy required to extrude and anodize the frame parts. Material production en- ergy can be reduced by using a higher proportion of secondary (scrap) aluminum to primary material, or by using a differ- ent, less energy intensive material. A higher proportion of secondary material might cause a decrease in the frame's surface quality, but as long as its struc- tural properties and lifetime remain unaf- fected, cosmetic imperfections should be tolerable. Use of the module in applica- tions not requiring a frame obviates the material selection process for this compo- nent and also eliminates significant en- ergy investments. Reusing the aluminum frame is another method of reducing energy investment. In the current design, the frame is easily separable and can be used on another module with minimal processing besides transportation to the production facility. The impact of reusing the frame on energy metrics is dramatic, because the frame represents between 34 and 53 percent of the total module production energy (be- tween 55 and 68 percent of total material production energy). Reusing the frame once halves its energy contribution and reusing it twice drops the energy cost to ------- Table 3. Energy Payback Time Calculations Payback Times Location and Conver. Insolation Eff., % Detroit, Ml 1 202 kWh/m2/yr Boulder, CO 1 974 kWh/m2/yr Phoenix, AZ 2480 kWh/m2/yr 5 8 5 8 5 8 Energy Gen/ Year (kWh) 22.3 35.7 36.7 58.7 46.1 73.7 Standard low 7.5 4.7 4.5 2.8 3.5 2.2 Standard high 13.4 8.4 8.1 5.1 6.4 4.0 Frame- less low 5.0 3.1 3.0 1.8 2.3 1.4 Frame- less high 6.3 3.9 3.7 2.3 2.9 1.8 Standard: module production energy is: material production + manufacture + transport = 162.2 kWh (583.8 MJ) low case; = 293.9 kWh (1058.1 MJ) high case. Frameless: module production calculated as above = 105.6 kWh (380.0 MJ) low case; = 134.5 kWh (484.3 MJ) high Table 4. Electricity Production Efficiency Calculations* Electricity Production Efficiencies Location and Generation Detroit, Ml 22.3 kWh/yr Boulder, CO 36.7 kWh/yr Phoenix, AZ 46.1 kWh/yr Module Life (yr) 10 25 10 25 10 25 Standard low 0.75 1.87 1.24 3.09 1.56 3.91 Standard high 1.33 3.33 2.23 5.57 2.83 7.07 Frameless low 1.60 3.99 2.68 6.69 3.40 8.51 Frameless high 2.01 5.03 3.39 8.49 4.33 10.83 "Assumes 5% module conversion efficiency, includes module transport energy: Detroit, 19.31 MJ; Boulder, 8.97MJ; Phoenix, 3.01 MJ. Standard: module production energy is: material production + manufacture + transport = 162.2 kWh (583.8 MJ) low case; = 293.9 kWh (1058.1 MJ) high case. Frameless: module production calculated as above = 105.6 kWh (380.0 MJ) low case; = 134.5 kWh. Table §. Energy Metrics for Frame Reuse Location and Metric Number of Uses Detroit, Ml low energy payback time (yr) high energy payback time (yr) low electricity production efficiency high electricity production efficiency Boulder, CO low energy payback time (yr) high energy payback time (yr) low electricity production efficiency high electricity production efficiency Phoenix, AZ low energy payback time (yr) high energy payback time (yr) low electricity production efficiency high electricity production efficiency 7.5 13.4 0.8 1.3 4.5 8.1 1.2 2.2 3.5 6.4 1.6 2.8 6.8 10.4 1.0 1.5 3.9 6.1 1.7 2.6 3.0 4.7 2.1 3.4 6.8 9.7 1.0 1.5 3.8 5.5 1.8 2.7 2.8 4.2 2.4 3.5 Assumes 5% module conversion efficiency; 10 year lifetime; includes transportation energy. one third of the single-use value. Table 5 contains energy metrics calculated for vari- ous levels of frame reuse. These results assume a module with 5% conversion ef- ficiency and include energy to transport the module back to the manufacturing fa- cility for each frame reuse. Transportation energy was assumed to be the same for each use of the frame; distance from the module disassembly facility to United So- lar was the same as the distance from the frame manufacturer to United Solar. The useful life of a photovoltaic module is a primary design parameter, as indi- cated in Table 4. EVA encapsulant fre- quently determines a module's useful life as it either degrades in optical quality or moisture permeability. Formulations of EVA have evolved to the point where browning is no longer the concern it once was, but moisture permeability remains a main de- terminant of module lifetime. In addition, the current formulation of EVA requires relatively high energy for lamination. A formulation with a quicker cure time and/ or a lower cure temperature would reduce this process energy requirement. The one other likely candidate for com- ponent reuse is the steel backing plate. In the current design, the backing plate is bonded to the module in the laminating press by a layer of EVA. If this layer of EVA could be deleted from the module, it would greatly facilitate disassembly and reuse or recycling of the backing plate while reducing material energy require- ments. However, our calculations revealed that eliminating one layer of EVA and re- using the steel backing plate had only an incremental effect on values of the metrics, especially compared to the effect of reus- ing the frame. Even so, deleting a layer of EVA does facilitate manufacturing and end of life management and can reduce cost. Conclusions The application of the life cycle design framework offered many useful insights for enhancing the energy performance of photovoltaic technology. Life cycle energy analysis highlighted the energy contribu- tion of individual life cycle stages, process steps, parts and components, and spe- cific materials. The project team devel- oped metrics to guide improvement of photovoltaic devices and to assess how sustainably these devices generate elec- tricity. One of these metrics, electricity pro- duction efficiency, was discussed. The metrics presented in Tables 3 and 4 demonstrate the relative significance of geographic locations with higher insola- tion and the aluminum frame. The best results are obtained with frameless appli- cations in areas of high insolation, but ------- either increased insolation or reduced mod- ule production energy are beneficial indi- vidually. For example, comparisons of standard and frameless modules indicate that the frame approximately doubles en- ergy payback time and reduces electricity production efficiency by about half. The beneficial effect of increased module life- time is also clearly demonstrated in Table 4. Electricity production efficiency is a pow- erful metric for comparing photovoltaic technology with other systems for gener- ating electricity because it puts all sys- tems on an equivalent basis. To meet a definition of sustainability, an electricity production efficiency greater than unity is necessary: this enables the device to pro- duce sufficient energy over its lifetime to at least reproduce itself (the current United States electricity grid efficiency is 0.32). All but one of the cases presented in Table 4 show efficiencies greater than unity; most are substantially higher. The energy investment in a conven- tional power plant is generally neglected in life cycle energy analysis because it is assumed to be small relative to fuel en- ergy inputs. This study shows that energy investment in the "power plant" for photo- voltaic devices is substantial relative to their energy generating capacity and can- not be neglected. A comprehensive and fair comparison of PV and conventional generating systems would involve enu- merating all terms in (2) (including any storage necessary for the PV system) and other environmental impacts such as air emissions and waste for both systems. A simple but important conclusion from Table 5 is that increasing the number of module components that can be reused and the number of times they are reused significantly improves energy metrics. Re- using the aluminum frame will yield by far the greatest improvement in energy metrics; reusing other components affects the metrics only incrementally and may not be worth additional effort from an en- ergy standpoint. Energy payback time should be a criti- cal factor in deciding whether or where to deploy photovoltaic modules, although cost is usually the sole criterion for these deci- sions. Accurate comparison between our values of this metric and other studies requires careful consideration of differ- ences in methodology or data. This study is based on actual data from an operating production facility; many other studies use theoretical calculations which tend to im- prove metrics. Photovoltaic technology development focuses primarily on increasing conver- sion efficiency and reducing cost. How- ever, energy payback time and electricity production efficiency add valuable perspec- tives for guiding photovoltaic technology development. Energy payback time can be used for strategic planning and deci- sion making when all assumptions are considered. Electricity production efficiency is a more comprehensive metric because it assesses the performance of a generat- ing system over its entire lifetime. This metric should also be used by designers for product material selection and process design. In addition, PV manufacturers, util- ity companies, policymakers, and the pub- lic should use this metric to make accurate comparisons between generating technolo- gies. The properties of amorphous silicon thin film technology seems to make it a natu- ral fit in building-integrated PV applica- tions such as glazing and sheathing materials and standing seam metal roof- ing. The full report was submitted in partial fulfillment of Cooperative Agreement num- ber CR-822998-01-0 by the National Pol- lution Prevention Center at the University of Michigan under the sponsorship of the United States Environmental Protection Agency. ------- Geoffrey M. Lewis and Gregory A. Keoleian are with the University of Michigan, Ann Arbor, Ml 48109-1115. Kenneth R. Stone is the EPA Project Officer (see below). The complete report, entitled "Life Cycle Design of Amorphous Silicon Photovol- taic Modules," (Order No. PB97-193106; Cost: $21.50, subject to change) will be available only from National Technical Information Service 5285 Port Royal Road Springfield, VA22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at National Risk Management Research Laboratory U. S. Environmental Protection Agency Cincinnati, OH 45268 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati, OH 45268 Official Business Penalty for Private Use $300 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 EPA/6QQ/SR-97/081 ------- |