United States Environmental Protection Agency National Risk Management Research Laboratory Cincinnati, OH 45268 Research and Development EPA/600/SR-97/083 September 1997 &EPA Project Summary Utilizing Low Volatile Organic Content Exterior Coatings for Wood Furniture Paul B. Kranz, James E. Stadelmaier and Thomas F. Stanczyk Abstract This report provides an evaluation of commercially viable source reduction techniques implemented by a manu- facturer of wood chairs, bar stools and settees in various styles ranging from classic American to European contem- porary. As federal EPA regulations became more stringent for volatile organic com- pound (VOC) emissions in the wood- working industry, the Dinaire Corpora- tion began testing alternative formula- tions employed as waterborne finishes, sealers and topcoats. In an effort to minimize costly investments in air emis- sion control equipment, the company examined and implemented a number of source reduction techniques that dic- tated modifications to raw material for- mulations as well as equipment needed to appiy and cure surface finishes. By phasing in low VOC, water-based formulations in conjunction with high- volume low-pressure spray systems, an ultraviolet curing system and proce- dural modifications, Dinaire was able to show reductions in the quantities of hazardous waste as well as the overall loadings of volatile organic compounds released as hazardous air pollutants. The reductions in air emission load- ings negated the need for costly im- provements in air emission control equipment. The Project Summary was developed by the National Risk Management Re- search Laboratory's Sustainable Tech- nology Division, Cincinnati, OH to an- nounce the key findings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). introduction The process of finishing wood house- hold furniture generally employs a num- ber of operations, such as; glue sizing or bleaching, cleaning/stripping, coating, dry- ing, sanding, rubbing/buffing, equipment cleaning and repair touch-up. These op- erations will provide household furniture with a pleasing appearance, a feeling of smoothness and the protection of the wood. The finishing process typically yields: • volatile organic compound (VOC) emissions, including hazardous air pollutants such as xylene and tolu- ene • liquid waste comprising of spent stains, wash coats, fillers, various sealers, discarded solvent and waste- water generated from paint overspray abatement systems • solid wastes including overspray sol- ids, solvent-laden residues, rags and wood dust and scrap The Dinaire Corporation is a manufac- turer of wood furniture products, primarily dinette sets. In an effort to minimize vola- tile organic compound emissions as well as hazardous waste, the company under- took a program to identify and test alter- native low-VOC waterborne finishing for- mulations that would be economically ad- vantageous in terms of minimizing expen- ditures associated with the proper man- agement of hazardous waste and the con- trol of hazardous air pollutants. Printed on Recycled Paper ------- Taking into account the variable prod- uct line and quality specifications, Dinaire was challenged in its quest to identify and implement alternative stains and coating formulations containing reduced loadings of volatile organic compounds character- ized as hazardous air pollutants. The company's operations complicated the evaluations since two facilities were in- volved in the manufacturing operations and ihe equipment needed to apply the sur- face finishes was not uniform at each fa- cility. Quality issues did pose some barri- ers to implementing, on a company-wide scale, alternative low VOC, waterborne coatings. Low-VOC, waterborne sealants and coatings were identified for wood furni- ture, however, the conversion dictated in- vestments in new equipment for applying the formulations and curing the finished products. The purpose of this project was to analyze and document the applicability, adequacy and advantages of finishing the surfaces of wood furniture with low-VOC, waterborne coatings. The analysis factor in the findings, observations and recom- mendations of the Pollution Prevention Op- portunity Assessments published by Sci- ence Applications International Corpora- tion under EPA contract 68D0068, Pollu- tion Prevention Initiative within the Great Lakes Basin. The technical and economic analysis also summarized some of the findings of Dinaire's alternative formula- tion evaluations. This project was completed under the terms of the Erie County WRITE Program as a joint effort by Dinaire Corporation located in Buffalo, NY; Erie County De- partment of Environment and Planning, Buffalo, NY, Recra Environmental, Inc., Amherst, New York; and the USEPA Of- fice of Research and Development, Cin- cinnati, OH. Procedure The Dinaire Corporation employs a sys- tematic approach to manufacturing and assembling wood furniture at its two facili- ties located at Gruner Rd. and Ohio St. The Gruner Rd. facility manufacturers table tops, whereas the Ohio St. facility manu- facturers chairs. The surface finishes on the tables and chairs must conform to required quality specifications, including color. Wood used in the manufacture of Dinaire's products is cut into desired shapes and sizes either by automatic ma- chinery or manually with hand held power tools. To produce wood materials of the desired size and physical properties, lami- nated wood is designed and produced at Dinaire's facilities. The laminates are made by taking strips of wood and gluing them together. The adhesive bonding of the laminated wood is cured at room tem- perature yielding emissions comprising of fumes from the glue and dust particulates from the wood cutting operations. The goals established by the Gruner Rd. facility dealt with the identification of low-VOC, waterborne coats for table tops that would assist Dinaire in complying with federal and state regulations governing hazardous air pollutants emitted from wood furniture operations. To achieve this goal, the company defined the following equip- ment specifications: • Venjakob double head spray system • Denibber-180 grit • Venjakob surface cleaner • Venjakob dual eight-gun carousel spray machine equipped with 1.8 Kremlin air-assisted, airless spray gun • Venjakob triple head, brush wiping machine • the Superfici dual 200-watt lamp ul- traviolet (UV) modular curing unit During the course of Dinaire's evalua- tions, table tops were finished using the Venjakob automatic spray equipment. This equipment utilizes high-volume, low-pressure spray guns. All of the table tops are UV cured. In their assessment of equipment modifications, Dinaire was able to confirm commercial applications for UV cured coatings on wood substrates. The expanded use of UV curing was accom- plished as a result of technological ad- vances involving the development of high- molecular weight, low-viscosity res- ins. The goals established by the Ohio St. facility dealt with the identification and use of a low-VOC, waterborne self-sealing top- coat for the final coat and a low-VOC, waterborne self-sealing topcoat for the sec- ond coat of sealer. To'"achieve this goal, the following equipment specifications were identified. • Accuspray HVLP Stain Guns #10 air cap, #51 tip • Enviro-Sealer Guns, Binks BBR HVLP, #95-P air cap, #91, top 12 oz. fluid delivery (45 sec.), 8 to 10 Ibs. atomizing air, 9/16( minimum air hose, 2.5 wet mil thickness • Accuspray HVLP waterborne lacquer gun • Devilbiss JGA 501 spray gun and Binks BBR HVLP 95-P air cap, #94 tip for acrylic basecoat. Results and Discussions The evaluations that were undertaken by Dinaire took into account a number of environmental as well as economic and productivity interests. In comparison to fin- ishing processes employing solvent-based formulations, Dinaire was able to show a number of advantages to low-VOC, waterborne formulations as long as qual- ity specifications were adequately ad- dressed. Based on the diverse operating requirements, the company's evaluations generated positive results summarized herein. Procedural and Equipment Modifications With the alternatives that were speci- fied and tested, the table top operations utilize a low-VOC, waterbased finish that is UV cured. These operations also utilize a solventbased, high-solids formulation that is utilized as a top coat. The equipment supplied by Venjakob applies coatings to exact wet mil thickness (2.5-3.0). Any overspray is recovered and reused as a sealant. Between each application step, table tops are UV cured. In selecting UV-curing equipment, Dinaire had to weigh the following factors: • The process does not lend itself well to simple hand-spray applications; as such the UV equipment necessitates investments in automated systems. • The selected UV system requires "line of sight" radiation; as such three-di- mensional pieces will be difficult to finish and applications by design will generally involve flat-top components. • Since most wood finishing is done for aesthetic and design functions, fin- ishing adjustments may have to be made often to address changes in custom specifications. • The cost of the UV processor is com- paratively high, however; investments appear justified based on predefined improvements in productivity. • Extra care must be used when utiliz- ing UV to ensure workplace safety as a result of ozone formation. Constant ventilation will be required to remove the ozone and heat formed, and main- tain the ideal operating temperatures on the terminals, the neck and the radiation surface. • While the dry film thickness applied with high-solids UV-cured coatings does improve the utilization of top coatings, improvements in transfer application efficiency must be consid- ered. • Unlike most other industrial finishing applications, wood finishes almost al- ways require a multi-step system ap- plied over a natural variable substrate. ------- As such variable colors, glosses and open-pore finishes may be difficult to achieve with a UV system. • The UV-curable coatings are not com- patible with oil-based stains, such as linseed oil. As such, a UV coating would prevent complete curing. • The conversion to UV-curable coat- ings would not eliminate the use of formulations with minimal solvent con- tent. The formulations applied to the table tops would still need to be prop- erly managed. The company's investment in the UV- curing system factored in the following advantages: • High solid coatings formulations can be effectively applied with variable product specifications, reducing the VOC loadings of the applied coat- ings. • Because of the high-solids content of coatings, the company can achieve high-film thicknesses with significantly fewer coats and pro- cess steps that are comparatively attained with low-solids, conven- tional coatings. • Because the polymer is completely cross-linked, the film's properties, in terms of surface scratch resistance and chemical resistance, are as high or higher than films that have been chemically cross-linked with external catalysts. • UV coatings generally cure within as little as one to two seconds of expo- sure to UV light yielding the benefit of high production throughput as a re- sult of the fast cure cycle. • The extremely fast cure rates allow for short ovens and conveyor sys- tems; as such the facility does not have to allocate valuaBfe pfaht "space for coatings to cure in storage. • Although a detailed energy conserva- tion analysis had not been completed, the company noted that the UV sys- tem consumes less energy than gas- fired curing ovens. The installation of HVLP spray guns improved the transfer efficiencies of high-solids, water based formulations re- ducing the wet film thickness for ulti- mate coating. In addition to reducing overspray emis- sions, the improvements in transfer effi- ciency have resulted in as much as a 50% reduction in the use of coating mate- rials. To optimize the benefits of HVLP spray equipment, the company continues to investigate productivity gains attributed to improvements in transfer efficiency. For example, Dinaire is able to stain 12 chairs with each gallon of stain using automated HVLP spray guns, whereas 5-7 chairs were stained with each gallon of stain prior to the transfer efficiency improve- ments. As the facility has converted to high- volume, low-pressure HVLP spray guns, procedural changes and up- grades have been made with the chair finishing operations resulting in a re- duction in the number of solvent based coatings, as well as fugitive air emis- sions from the spray booths. With em- ployee training, excessive overspray has also been minimized. In addition, the con- sumption of solvents in the various formu- lations has been reduced. "Prior to implementing'a spray system, the compan/s operations involved dip- ping and hand-wiping coatings. This change reduced the generation of waste rags containing solvents, thus reducing employee exposure to fumes while allow- ing for higher production rates. Quality Issues Quality issues did pose some major bar- riers to implementing an alternative finish- ing system utilizing a low-VOC water-borne formulation. During the evaluation phase, the company documented problems, such as raising of wood grains, yellowing of stains after prolinged sunlight, inconsis- tencies in stain quality, and quantities of select formulations contained unaccept- able concentrations of formaldehyde. These problems were eventually dealt with; however, the company ultimately had to change suppliers and impose proce- dural modifications for operators and in- ventory managment to ensure adherence to plant quality controls. Environmental , The changes implemented by the com- pany resulted in a number of environmen- tal benefits. These improvements assisted the company in their efforts to minimize capital investments dictated by regulatory standards governing the control of haz- ardous air pollutants from the wood furni- ture finishing operations. The combined changes in operations and formulations showed: • 80-90% reduction in the costs associ- ated with managing hazardous waste • significant reductions in the VOC con- tent of materials used as sealants and topcoats • reduction in waste overspray attrib- uted to both the use of low-VOC, waterborne formulations and improve- ments in transfer efficiency attain- able with HVLP spray applications of high-solids coatings • reduction in energy consumed with UV-cured formulations In comparison to the old operations, reliant on low-solid content solvent-based coatings, the topcoat overspray can be recovered and reused as sealant. The company is attempting to recover stain overspray; however, reuse opportunities are limited due to inconsistencies in the recovered stain quality. During the company's period of evalu- ation, the operations were able to phase in low-VOC waterborne stains and high- solids coatings. These new formulations assisted the company in reducing the loadings of volatile organic compounds emitted as air emissions. Operations can yield a finished product in 2 to 3 steps ensuring 2.5 to S.Omil finish at each appli- cation, in comparison to the old opera- tions which required as many as 4 to 5 procedural steps resulting in 1.4 to 2.1 mil finish. A number of the modifications selected by the company can be categorized as source control techniques, which contrib- ute to the reduction in the generated quan- tities of hazardous waste. During the evalu- ation period, the quantities of ignitable waste (D001) were reduced by greater than 95%. Economic The fixed cost for the project including the purchase and installation of the HVLP guns and Superfici UV curing unit was calculated to be $50,740. Annual opera- tion and maintenance costs were assumed to be $1,000 for the economic analysis supplementing this project. The Net Present Value (NPV) for the project was determined by factoring in the equipment purchase NPV, tax savings on depreciation NPV, and savings on vari- able costs NPV. Since the substitution of low-VOC coatings for solvent coatings was only partially implemented by Dinaire, as- sumptions on the economic impact from a complete substitution had to be made. Based on these assumptions, the project provided a positive net present value and a payback period of 2.68 years. Once fully implemented, the low-VOC coating alternatives will improve the overall eco- nomics of the project. Some of miscellaneous savings attrib- uted to the changes: • average cost per gallon of low-VOC stains approximately 5.5% lower than the cost per gallon of solvent stain ------- • total cost of disposing of hazardous waste generated by the Ohio St. fa- cility reduced from $17,925 in 1990 to $765 in 1994 • total cost of disposing of hazardous waste generated at Gruner Rd. re- duced from $15,785 in 1990, to $8,050 in 1994 Conclusion The decision by Dinaire Corporation to phase in lowVOC water based stains and high-solid content topcoats has provided a number of benefits justifying ongoing investment in the company's strategy to minimize reliance on all solvent-based stains and topcoats associated with wood furniture finishing operations. Despite various quality issues, Dinaire was able to achieve customer specifica- tions; however, inventory management, proper equipment controls, and operator training were all important elements to sustaining the changes. Investments in a modular ultraviolet (UV) curing system resulted in significant gains in productivity. The fast curing cycle trans- lates into greater product throughput and control over product quality. The improvements in spray transfer efficiency as well as the conversion to high-solids coatings resulted in better utilization of resources, including costly finishes, energy, and labor. With HVLP spray guns, the stain utilization was im- proved 40-70%, significantly reducing air emissions attributed to overspray and solvent use. In addition to improving productivity and resource utilization, the investments in the new finishing operations helped Dinaire comply with air regulations and, in doing so, avoided capital-intensive air abatement control equipment. By reducing exposure to solvent-laden stains and topcoats, work place safety and environment was improved. The risks posed by the company's reliance on sol- vent based formulations have been mini- mized to a level that can be better con- trolled. The reduced reliance on hazard- ous air pollutants has also minimized dis- carded oversprays posing environmental compliance issues. In terms of positive economic impact, the changes provided a good net present value and a payback that has the poten- tial to improve with full implementation of the low VOC strategy. With implementa- tion of these changes, economic savings were recognized in terms of better re- source utilization, including, energy, labor and raw materials, reduced disposal charges for hazardous waste, reduced charges for stains and coatings used in operations, reduced costs for controlling overspray, and reduced costs for control- ling emissions of hazardous air pollutants in relation to applicable regulations. The full report was submitted in fulfillment of CR-816762 Erie County Department of Environment and Planning under the sponsorship of the U.S. EPA. PaulKranz is with Erie County Department of Environment and Planning, Buffalo, NY 14202. James E. Stadelmaierand Thomas F. Stanczykis with Recra Environmental, Inc., Amherst, NY 14228. Paul R Paul Randall is the EPA Project Officer (see below). The complete report, entitled "Utilizing Low Volatile Organic Content Exterior Coatings for Wood Furniture," (Order No. PB98-100415; Cost: $21.50, subjectto change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Sustainable Technology Division National Risk Management Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 United States Environmental Protection Agency Center for Environmental Research Information (G-72) Cincinnati, OH 45268 Official Business Penalty for Private Use $300 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 EPA/600/SR-97/083 ------- |