United States Environmental Protection Agency Industrial Environmental Research Laboratory Research Triangle Park NC 27711 Research and Development EPA-600/S8-81 -017 Dec. 1981 Project Summary Limestone FGD Scrubbers: User's Handbook D. S. Henzel, B. A. Laseke, E. 0. Smith, and D. O. Swenson Among the many available processes for desulfurizing flue gas from utility boilers, the limestone wet scrubbing process is widely used and is gaining increasing acceptance as technologi- cal advances are developed. The Lime- stone FGD Scrubbers: User's Hand- book is intended for use by utility project managers and project engineers. It provides guidance in selecting, installing, and operating a limestone FGO system, covering all phases from inception of the project through design, procurement, operation, and maintenance. The Handbook gives detailed accounts of utility experience with operational limestone scrubbing systems. It also describes in detail numerous optional process features and recent innovative modifications that enhance the efficiency of the system. This Project Summary was devel- oped by EPA's Industrial Environ- mental Research Laboratory, Research Triangle Park, NC, to announce key findings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). Introduction Flue gas desulf urization (FGD) systems are widely used by utilities to comply with current limitations on emissions of sulfur dioxide (SOz) from power plant boilers. Among the available FGD processes, wet limestone scrubbing has met widespread acceptance: about 63 percent of the systems now operational, under construction, or planned use limestone as the absorption reagent. Because substantial increases in FGD usage are projected for the next several years, there is need for an instructive handbook that deals on a practical level with the major aspects of limestone scrubbing. The User's Handbook there- fore is designed to provide guidance for utility project managers, engineers, and others involved in selecting, procuring, installing, and operating a limestone scrubbing system. The Handbook is based in part on current, well-proven engineering/ management practices and in part on the records and experience of utilities with operational limestone systems. Since 1972 the operation of prototype scrubbers at the EPA/TVA Shawnee test facility has generated a large amount of data on limestone scrubber design, performance, operating param- eters, and reliability. The Handbook incorporates practical guidance based on these data and on experience gained at-the Shawnee facility. Figure 1 shows an FGD project coordination scheme, from inception of the project through design, procurement, operation, and maintenance of the system. This scheme also provides the basis for the structure of the Handbook. The Basic Process and Optional Process Features The basic limestone process handles boiler flue gas from which fly ash has been removed by treatment in a particu- late collection device such as an electrostatic precipitator or a fabric filter. The flue gas is brought into ------- Assignment of Limestone FGD Project Overall System Design • Power Plant Considerations • Design Basis • Material and Energy Balances • System Configuration Options • Computerized Design Guides Equipment Design Scrubber Modules Limestone Slurry Preparation Liquid Flow Equipment Flue Gas Flow Equipment Sludge Processing Equipment Process Control and Instrumentation Procurement • Prebid Considerations • Preparation of Specifications • Evaluation of Proposals • Engineering Design, Installation, Startup, and Testing Operation and Maintenance Standard Operations Initial Operations System Startup and Shutdown System Upsets Preventive Maintenance Programs Unscheduled Maintenance Figure 1. FGD project coordination sequence. contact with the limestone slurry in a simple scrubber tower. Chemical re- action of limestone with SOa in the flue gas produces waste solids, which must be removed continuously from the scrubbing loop. These waste solids are concentrated in a thickener and then dewatered in a vacuum filter to produce a filter "cake," which is mixed with fly .ash. The resulting stabilized mixture is then transported to a landfill. The limestone scrubbing system is called a "throwaway" process because the product sludge is disposed of rather than regenerated to recover sulfur. The limestone FGD process has been enhanced with the advent of recent technology improvements, which provide options to the basic limestone process. The capabilities of these optional process features are being verified by current commercial experience. Among these features are: • Useofapresaturatortocoolthehot flue gas. • Installation of a venturi scrubber ahead of the main scrubber module. • Operation of a combination scrub- ber (venturi/spray) with a charged particulate scrubber. • Placement of an additional tank in the process flow, a "two-loop" system. • Operation of a two-loop system with a single scrubber module. • Forced oxidation of the scrubber sludge. • Use of chemical additives. Although the utility management staff does not perform detailed system design, their informed decisions con- cerning the system are prerequisite to effective dealings with architectural/ engineering consultants and with FGO system suppliers. The Handbook presents a systematic approach to managerial decision-making through discussion of process and equipment options. Among the major design considera- tions are those related to the power plant: coal properties and supply, steam generator design, power demand, factors related to the power plant site, and environmental regulations. The primary factors serving as the design basis are those that determine the size and configuration of the FGD system: flow rate, composition, pressure, and temperature of the flue gas from the boiler. These parameters, together with the pollutant removal requirements, reagent stoichiometric ratio, and com- positions of the limestone and makeup water, provide the basis for FGD system design. After determination of the major design basis and material/energy factors, several system configuration options must be considered. Most critical among these are the options for (1) particulate removal (separate versus integral), (2) location of the flue gas fan, (3) flue gas bypass (versus no bypass), (4) reheat (versus no reheat), and (5) sludge disposal. Redundancy and system flexibility, which are closely interrelated, are needed to some extent in every limestone FGD system. They are dis- cussed as options because decisions must be made as to the degree of redundancy and flexibility to be incor- porated into the system design. Three major computer programs are available for use in the planning and operational stages of a limestone FGD project. The TVA Lime/Limestone Scrubbing Computer Model is structured to generate a complete conceptual design package for either a lime or limestone scrubbing system, together with a breakdown of cost requirements. The PEDCo Flue Gas Desulfurization Information System is an ongoing survey of design, performance, and process data on operational FGD systems in the United States. The Bechtel- Modified Radian Equilibrium program gives simplified equations for calculation of gypsum saturation levels as an index of scaling potential. The FGD System A substantial portion of the Handbook gives detailed descriptions of key components of the FGD system including materials of construction and process control. Major emphasis is on equipment items that most strongly affect the operation and performance of a lime- stone FGD system: the scrubber, mist eliminator, reheater, and fans, together with equipment used in slurry prepara- tion and sludge treatment. Each of these major equipment items is presented in a similar format: first, a description of the unit and its function, followed by discussion of the basic equipment types, including major design variations. Then follows a review of the principal design considerations, and finally a brief survey of actual applications in operational systems in the U.S. Table 1, showing the basic types of scrubbers available for use in a limestone FGD system, exemplifies the Handbook's treatment in discussions of the scrubber and of individual components; it lists generic and specific types and identifies common trade names. These descrip- tions are then, used throughout the technical discussion of each component, as exemplified in Table 2, which concerns gas velocities through the scrubber. Details of the key parameters in operational and planned systems, together with accounts of on-line operational experience, provide a basis for assessment and decision by the project utility staff. •' ------- Table. 1 Basic Scrubber Types for Commercial Limestone FGD Systems Generic type Specific type Trade or common name Venturi Variable-throat/bottom-entry liquid distribution disk Variable-throat/side-movable blades Variable-throat/side-movable blocks Variable-throat/vertically adjustable rod decks Variable-throat/adjustable drum Spray Open/countercurrent spray Open/crosscurrent spray Tray Sieve tray Packed Static bed Mobile bed Rod deck Grid Combination Spray/packed Venturi/spray Flooded-disk scrubber Rod scrubber Radial flow venturi Vertical spray tower Horizontal spray chamber Marble-bed scrubber Turbulent contact absorber fTCAJ Ventri-sorber Table 2. Limestone Scrubber Design Gas Velocities Gas velocity, ft/s* Operational Planned Scrubber type Venturi Variable-throat/side-movable blocks VariaNe-throat/vertically adjustable rod decks Spray Open/countercurrent Open/ crosscurrent Tray Sieve Packed Static bed Mobile bed Rod deck Grid Combination Spray/packed No.' 2 1 2 1 2 1 2 1 1 2 Range 90-130 80 10 22 10-15 31 13-15 13 12 7-10 Avg. /Vo.b Range Avg. 110 80 10 3 8-10 9 22 2 22 22 13 31 14 13 12 81 10 10 required capital investment and annual operating costs. After selection of the successful bidder, the utility project management staff coordinates the activities of suppliers and architectural/ engineering consultants in detailed engineering design, fabrication, instal- lation, startup, and testing. Operation and Maintenance Reliable operation of the limestone scrubbing system is achieved by ad- herence to a sound program of operation and maintenance. The Handbook pro- vides guidance for standard operating practices, routine start-up and shut down, and system upsets. It outline procedures for preventive and erne1 gency maintenance and gives guideliru on scrubber unit staffing. 'Multiply ft/s by 0.3048 to convert to m/s. "The number of systems for which design scrubber L/G is known. Procurement of the System Procurement planning involves defi- nition of the scope of supply, allocation of procurement packages among poten- tial bidders, and selection of bidders. Specifications are then prepared in three categories: (1) bidding require- ments, which inform the bidders re- garding the information required, proposal format, number of copies, and similar requirements; (2) contract requirements, consisting of contract regulations and provisions for bonds, guarantees, and payments; and (3) technical requirements, which constitute a full and detailed statement of the utility's requirements for chemical and engineering parameters of the FGD system. Proposals are evaluated in terms of technical, commercial, and economic factors, the latter including details of ------- D. S. Henzel and B. A. Laseke are with PEDCo Environmental. Inc.. Cincinnati. OH. 45246; E. O. Smith andD. 0. Swenson are with Black and Veatch. Kansas City. MO 64114. Robert H. Borgwardt is the EPA Project Officer (see below). The complete report, entitled "Limestone FGD Scrubbers: User's Handbook." (Order No. PB 82-106 212; Cost: $37.50, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield. VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Industrial Environmental Research Laboratory U.S. Environmental Protection Agency Research Triangle Park. NC 27711 U.S. GOVERNMENT PRINTING OFFICE; 1981 — 599-017/7410 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 Postage and Fees Paid Environmental Protection Agency EPA 335 Official Business Penalty for Private Use $300 ------- |