United States
Environmental Protection
Agency
Industrial Environmental Research
Laboratory
Research Triangle Park NC 27711
Research and Development
EPA-600/S8-81 -017  Dec. 1981
Project  Summary
Limestone  FGD   Scrubbers:
User's  Handbook

D. S. Henzel, B. A. Laseke, E. 0. Smith, and D. O. Swenson
  Among the many available processes
for desulfurizing flue gas from utility
boilers, the limestone wet scrubbing
process is widely used and is gaining
increasing acceptance as technologi-
cal advances are developed. The Lime-
stone FGD  Scrubbers: User's  Hand-
book  is intended for use by utility
project managers and project engineers.
It provides guidance in selecting,
installing, and operating a limestone
FGO system, covering all phases from
inception of the project through
design, procurement, operation, and
maintenance. The Handbook gives
detailed accounts of utility experience
with operational limestone scrubbing
systems.  It also describes in  detail
numerous optional process  features
and recent  innovative modifications
that enhance  the efficiency of the
system.
  This Project Summary was devel-
oped  by EPA's Industrial Environ-
mental Research Laboratory, Research
Triangle Park, NC, to announce key
findings of the research project that is
fully documented in a separate report
of the same title (see Project Report
ordering information at back).

Introduction
  Flue gas desulf urization (FGD) systems
are widely used by utilities to comply
with current limitations on emissions of
sulfur  dioxide (SOz) from power plant
boilers. Among the  available FGD
processes, wet limestone scrubbing has
met widespread acceptance: about 63
percent of the systems now operational,
under  construction,  or planned use
limestone as the absorption reagent.
Because substantial increases in FGD
usage are projected for the next several
years, there is need for an instructive
handbook that deals on a practical level
with the  major aspects of limestone
scrubbing. The User's Handbook there-
fore is designed to provide guidance for
utility project managers, engineers, and
others involved in selecting, procuring,
installing, and operating a limestone
scrubbing system.
  The Handbook is based  in part on
current,  well-proven engineering/
management practices and in part on
the records and experience of utilities
with operational limestone systems.
Since 1972 the operation of prototype
scrubbers at the EPA/TVA Shawnee
test facility  has  generated a large
amount of data on limestone scrubber
design, performance, operating param-
eters, and reliability. The Handbook
incorporates practical  guidance based
on these data and on experience gained
at-the Shawnee facility.
  Figure  1  shows an FGD project
coordination scheme, from inception of
the project through design, procurement,
operation, and maintenance of the
system. This scheme also provides the
basis for the structure of the Handbook.

The Basic Process and Optional
Process Features
  The basic limestone process handles
boiler flue gas from which fly ash has
been removed by treatment in a particu-
late collection device such as an
electrostatic  precipitator or a fabric
filter. The flue gas is brought into

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Assignment of Limestone FGD Project
Overall System Design

• Power Plant Considerations
• Design Basis
• Material and Energy Balances
• System Configuration Options
• Computerized Design Guides
Equipment Design
  Scrubber Modules
  Limestone Slurry Preparation
  Liquid Flow Equipment
  Flue Gas Flow Equipment
  Sludge Processing Equipment
  Process Control and Instrumentation
Procurement

• Prebid Considerations
• Preparation of Specifications
• Evaluation of Proposals
• Engineering Design, Installation,
  Startup, and Testing
 Operation and Maintenance
   Standard Operations
   Initial Operations
   System Startup and Shutdown
   System Upsets
   Preventive Maintenance Programs
   Unscheduled Maintenance
Figure 1.     FGD project coordination
             sequence.
contact with the limestone slurry in a
simple  scrubber tower. Chemical re-
action of limestone with SOa in the flue
gas produces waste solids, which must
be  removed continuously from the
scrubbing loop. These waste solids are
concentrated in a  thickener and then
dewatered in a vacuum filter to produce
a filter "cake," which is mixed with fly
.ash. The resulting stabilized mixture is
then transported  to  a landfill. The
limestone scrubbing system is called a
"throwaway" process because the
product sludge is  disposed of  rather
than regenerated to recover sulfur.
  The limestone FGD process has been
enhanced with the  advent of recent
technology improvements, which provide
options to the basic limestone process.
The capabilities  of these  optional
process features are being verified by
current commercial experience. Among
these features are:
  • Useofapresaturatortocoolthehot
     flue gas.
  • Installation of a venturi scrubber
     ahead of the main scrubber module.
  • Operation of a combination scrub-
     ber (venturi/spray) with a charged
     particulate scrubber.
  • Placement of an additional tank in
     the  process  flow, a "two-loop"
     system.
  • Operation of  a  two-loop system
     with a single scrubber module.
  • Forced  oxidation of the scrubber
     sludge.
  • Use of chemical additives.
  Although the utility management
staff does not perform detailed system
design, their informed decisions con-
cerning the system are prerequisite to
effective  dealings  with architectural/
engineering consultants and with FGO
system  suppliers.  The  Handbook
presents a systematic approach to
managerial  decision-making through
discussion  of process and equipment
options.
  Among the major design considera-
tions are those related to the power
plant: coal properties and supply, steam
generator  design, power demand,
factors related to the power plant site,
and environmental regulations.
  The primary factors serving as  the
design  basis are those that determine
the size and configuration of the FGD
system: flow rate, composition, pressure,
and temperature of the flue gas from the
boiler. These parameters, together with
the pollutant removal requirements,
reagent stoichiometric ratio, and com-
positions of the limestone and makeup
water, provide the basis for FGD system
design.
  After determination of the major
design  basis  and material/energy
factors, several system  configuration
options  must be  considered.  Most
critical  among these are the options for
(1) particulate removal (separate versus
integral), (2) location of the flue gas fan,
(3) flue gas bypass (versus no bypass),
(4)  reheat (versus  no reheat), and  (5)
sludge disposal. Redundancy and system
flexibility, which are closely interrelated,
are needed to some extent in  every
limestone FGD system. They are dis-
cussed as  options because  decisions
must  be made as  to the  degree  of
redundancy and flexibility to be incor-
porated into the system design.
  Three major computer programs are
available for use in the  planning and
operational stages of a limestone FGD
project.  The  TVA  Lime/Limestone
Scrubbing Computer Model is structured
to generate a complete conceptual
design package for either  a lime  or
limestone scrubbing system, together
with a breakdown of cost requirements.
The PEDCo Flue Gas Desulfurization
Information System  is an ongoing
survey of design,  performance, and
process data on operational FGD systems
in the United  States. The Bechtel-
Modified Radian Equilibrium program
gives simplified equations for calculation
of gypsum saturation levels as an index
of scaling potential.
The FGD System
  A substantial portion of the Handbook
gives detailed descriptions  of  key
components of the FGD system including
materials of construction  and process
control. Major emphasis is on equipment
items that most  strongly affect  the
operation and performance of a lime-
stone FGD system: the scrubber, mist
eliminator, reheater, and fans, together
with equipment used in slurry prepara-
tion and sludge treatment. Each of these
major equipment items is presented in a
similar format: first, a description of the
unit and  its function, followed by
discussion of the  basic  equipment
types, including major design variations.
Then follows a review of the principal
design considerations, and  finally  a
brief survey of  actual applications in
operational systems in the  U.S.
  Table  1, showing  the basic types of
scrubbers available for use in a limestone
FGD system, exemplifies the Handbook's
treatment in discussions of the scrubber
and  of individual  components; it lists
generic and specific types and identifies
common  trade names. These descrip-
tions are then, used throughout  the
technical discussion of each component,
as  exemplified in Table 2,  which
concerns gas velocities through  the
scrubber. Details of the key parameters
in operational and  planned  systems,
together with  accounts  of on-line
operational experience, provide a basis
for  assessment and decision  by  the
project utility staff.                 •'

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 Table. 1    Basic Scrubber Types for Commercial Limestone FGD Systems
  Generic type
Specific type
Trade or common name
  Venturi        Variable-throat/bottom-entry
                 liquid distribution disk
                Variable-throat/side-movable blades
                Variable-throat/side-movable blocks
                Variable-throat/vertically adjustable
                 rod decks
                Variable-throat/adjustable drum
  Spray         Open/countercurrent spray
                Open/crosscurrent spray
  Tray           Sieve tray
  Packed        Static bed
                Mobile bed

                Rod deck
                Grid
  Combination   Spray/packed
                Venturi/spray                	
                        Flooded-disk scrubber
                        Rod scrubber

                        Radial flow venturi
                        Vertical spray tower
                        Horizontal spray chamber


                        Marble-bed scrubber
                        Turbulent contact
                         absorber fTCAJ
                        Ventri-sorber
 Table 2.    Limestone Scrubber Design Gas Velocities

                                             Gas velocity, ft/s*
Operational Planned
Scrubber type
Venturi
Variable-throat/side-movable
blocks
VariaNe-throat/vertically
adjustable rod decks
Spray
Open/countercurrent
Open/ crosscurrent
Tray
Sieve
Packed
Static bed
Mobile bed
Rod deck
Grid
Combination
Spray/packed
No.'


2

1

2
1

2

1
2
1
1

2
Range


90-130

80

10
22

10-15

31
13-15
13
12

7-10
Avg. /Vo.b Range Avg.


110

80

10 3 8-10 9
22 2 22 22

13

31
14
13
12

81 10 10
required capital investment and annual
operating costs. After selection of the
successful bidder, the utility project
management staff  coordinates the
activities of suppliers and architectural/
engineering  consultants  in  detailed
engineering design, fabrication, instal-
lation, startup, and testing.

Operation and Maintenance
  Reliable operation  of the limestone
scrubbing  system  is achieved by ad-
herence to a sound program of operation
and maintenance. The Handbook pro-
vides guidance for standard operating
practices,  routine  start-up and shut
down, and system upsets. It  outline
procedures for preventive and erne1
gency maintenance and gives guideliru
on scrubber unit staffing.
'Multiply ft/s by 0.3048 to convert to m/s.
"The number of systems for which design scrubber L/G is known.
Procurement of the System
  Procurement planning involves defi-
nition of the scope of supply, allocation
of procurement packages among poten-
tial bidders, and selection of bidders.
  Specifications are  then prepared in
three categories: (1) bidding  require-
ments,  which inform the bidders re-
garding the  information required,
proposal format, number of copies, and
similar requirements; (2) contract
            requirements, consisting of contract
            regulations and provisions for bonds,
            guarantees, and  payments; and (3)
            technical requirements, which constitute
            a  full  and  detailed statement of the
            utility's requirements for chemical and
            engineering parameters of the FGD
            system.
              Proposals are evaluated in terms of
            technical,  commercial,  and  economic
            factors, the latter  including  details  of

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      D. S. Henzel and B. A. Laseke are with PEDCo Environmental. Inc.. Cincinnati.
        OH. 45246; E. O. Smith andD. 0. Swenson are with Black and Veatch. Kansas
        City. MO 64114.
      Robert H. Borgwardt is the EPA Project Officer (see below).
      The complete  report, entitled "Limestone FGD Scrubbers: User's Handbook."
        (Order No. PB 82-106 212; Cost: $37.50, subject to change) will be available
        only from:
              National Technical Information Service
              5285 Port Royal Road
              Springfield. VA 22161
               Telephone: 703-487-4650
      The EPA Project Officer can be contacted at:
              Industrial Environmental Research Laboratory
              U.S. Environmental Protection Agency
              Research Triangle Park. NC 27711
     U.S. GOVERNMENT PRINTING OFFICE; 1981 — 599-017/7410
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Postage and
Fees Paid
Environmental
Protection
Agency
EPA 335
Official Business
Penalty for Private Use $300

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