United States
          Environmental Protection
          Agency, Region 1
New England
Environmental Assistance
Team
EPA-901-B-97-001
May 1997
                 Fit
                  to
              Print
An Environmental Compliance and
Pollution Prevention Manual for
New England Lithographers
                              &EPA
                              Region 1, New England

-------
Here is what some printers, trade associations, and regulators have said about Fit to
Print:


"'Fit to Print'is great -- an excellent source of vital information.  It answered a few questions that I could
never get an answer for."
       Jane Cioffi, Southington Printing Co.

"You have done a very nice job of reducing a complex, and for  many of us, an incomprehensible set of
different regulations into a readable and understandable document. It is packed with useful information."
       Michael D. Coughlin, Concord Litho Company, Inc.

"The manual is terrific and should go far in helping printers understand and comply with the EPA
regulations."
       Anthony Racco, The Hartford

"This document is a fine effort at tackling a very difficult topic, and should serve as a valuable resource
and reference document for printers who are committed to environmental compliance."
       Stig Bolgen, Printing Industries of New England

"[We were] very impressed with the thoroughness and quality of the manual.  We are certain that it will be
a big help to lithographic printers in the region."
       Richard T. Enander, Rhode Island Department of Environmental Management

"I thought the document was well done. It is well organized ... and this format will help printers
understand how environmental regulations specifically apply to  what they do."
       Paul Van Hollebeke, Vermont Agency of Natural Resources

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v0 ^^ \         UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
*  "  r\                               REGION 1
          ?                   JOHN F. KENNEDY FEDERAL BUILDING
                             BOSTON, MASSACHUSETTS 02203-0001
                                                                             OFFICE OF THE
                                       April 17  1997                     REGIONAL ADMINISTRATOR
  I am very pleased to give you Fit to Print:  An Environmental Compliance and Pollution Prevention
  Manual for New England Lithographers, produced by EPA's New England Environmental Assistance
  Team (NEEATeam). By using a variety of tools to promote industrial environmental protection ~
  education, outreach, and assistance among them — the NEEATeam has provided compliance and
  pollution prevention assistance to small and medium-sized companies in New England since 1995.
  Through their efforts, the NEEATeam has shown that sound environmental practices make good
  business sense.

  Through its Fit to Print initiative, the NEEATeam — along with its state and industry partners ~ has
  been busy generating helpful materials and sponsoring events for printers throughout New England.
  Besides this manual, the NEEATeam's Fit to Print initiative is developing compliance and pollution
  prevention workshops, technology demonstration open houses, fact  sheets, customer education
  projects to encourage "green" printing, and an evaluation of a new printing ink system.  In using these
  materials and events, we hope to help printers meet their regulatory obligations, practice pollution
  prevention and thrive economically.

  We hope this document helps you become "fit to print." Because this manual is the first of its kind
  generated by the NEEATeam, we especially welcome your comments and suggestions.  Please call
  the NEEATeam at (800) 906-3328 with any comments, suggestions or questions.
                                                              Sincerely,
                                                              John P. DeVillars
                                                              Region I Administrator
             Recycled/Recyclable • Printed with Vegetable Oil Based Inks on 100% Recycled Paper (40% Postconsumer)

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ACKNOWLEDGMENTS

The authors would like to thank the following individuals for their contributions to the development of this
manual:

CT Department of Environmental Protection: David Cherico, Glen Daraskevich, John Gove, Jim Grier,
Bob Hannon, Mike Harder, Robert Isner, Dick Mason, Joe Pulaski, Mary Sherwin, David Westcott;
ME Department of Environmental Protection: Mike Hudson, Brian Kavanah, Jim Rogers, Chris
Rushton, Ann Pistell; MA Department of Environmental Protection: John Reinhardt, Gene Romero,
William Sirull, Nancy Wrenn; MA Office of Technical Assistance for Toxic Use Reduction: George
Frantz; NH Department of Environmental Services:.Jeffrey Andrews, George Carlson, Rudy Cartier,
Max Hilgemeier, Tod Leedberg,  Mitchell Locker, Vince Perelli, Craig Wright; Rl Department of
Environmental Management: Joe Antonio, Richard Enander, Tom Epstein, Richard Girasole, Ted
Hickey, Angelo Liberti, Doug McVay,  Beverly Migliore, Terry Simpson, Gregory Yekhtikian; VT Agency of
Natural Resources: Val Colgrove, Gary Gulka, Chris Jones, Sherrie Kasten, Brian Kooiker, Christine
Thompson, Paul Van Hollebeke; Northeast Waste Management Officials' Association:  Lisa
Regenstein; Printing Industries of New England: Stig Bolen; Goldman Environmental Consultants:
Robert Fricke; Cambridge Environmental, Inc.: Robert Pojasek; Book Press, Inc.: Paul  Norcross;
Concord Litho Company, Inc.: Michael Coughlin; The Hartford: Anthony Racco; Southington Printing
Company: Jane Cioffi; Graphic Arts Technical Foundation: Gary Jones; U.S. Environmental
Protection Agency, Washington, D.C.: Doug Jamieson, David Salmon.

We would also like to recognize  the following individuals from the U.S. Environmental Protection
Agency, Region I, New England who provided valuable suggestions on improving this document:
Andrea Simpson, Lee MacMichael, Leonard Wallace, Ann Williams, and Tim Williamson. Also, we would
like to say a special thanks to: Anne Arnold, Dave  Delaney, Joan  Jouzaitis, Anne Leiby, Sally Mansur, Lisa
Papetti, and Mark Spinale, without whose expertise and commitment this manual would not have been
possible.
 This manual discusses the most significant federal and state environmental regulations that apply to
 the lithographic printing industry.  This manual is not an official EPA or state guidance document and
 should not be relied upon by the industry as a method to identify all applicable regulatory requirements
 for the following reasons: 1) Laws and regulations change; 2) Regulations that apply to a facility
 depend upon the particular processes and chemicals used -- this manual contains information that
 applies in general conditions; and 3) Laws and regulations at the federal, state, and local levels may
 differ -- please note that local requirements are not identified in the manual. This manual does not
 create any rights enforceable in litigation with the United States or the states.

 We encourage you to use this manual as part of a larger compliance effort. Take time to identify the
 universe of rules that apply to your facility by examining the regulations and requirements themselves.
 Also, use the wide range of resources that are available to assist you -- see Chapter 9 for a list of
 federal and state assistance providers who may be able to offer you additional information.

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In printing this manual, the New England Environmental Assistance Team followed the
recommendations made in this manual where possible, under the constraints made by U.S.
contracting and procurement regulations.  The following specifications were used:
Paper: 100% recycled
       30% post-consumer minimum
       70% Ib. basis weight
       no bleaching
       no coating
Cover: 100% recycled
       30% post-consumer minimum
       80% Ib. basis weight
       no bleaching
       no coating
Ink:    vegetable-based

This manual will soon be available in electronic form through a number of sources.

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                                                                             Fit to Print
                                TABLE OF CONTENTS


CHAPTER                                                                            PAGE

1.      How Can I Become "Fit To Print?" 	   1
       1.1     How Do I Comply With the Laws and Regulations That Apply to My Lithographic Print
              Shop?  	   1
       1.2     What Pollution Prevention Techniques Can I Use at My Lithographic Print Shop? ....   2
       1.3     Where Can I Get Additional Information?	    2

2.      How Can Pollution Prevention Make Me "Fit To Print?" 	   3
       2.1     What Is Prevent Pollution and How Can it Help My Print Shop?	   3
       2.2     What P2 Techniques Can I Use?	   4

3.      What Wastes Do I Generate During Printing Operations?	    9

4.      How Do I Comply With Wastewater Discharge Regulations?	   13
       4.1     Do I Know Where My Wastewater Goes?	   13
       4.2     What Do My Printing Wastewater Discharges Contain? 	   13
       4.3     What Must I Do if I Discharge to the Sewer?	   13
       4.4     What Must I Do if I Discharge to a Septic System or Other Subsurface Wastewater
              Disposal System?	   17
       4.5     What Must I Do if I Discharge to Surface Water? 	   18
       4.6     Good Environmental Management Practices	   20
       4.7     Pollution Prevention Opportunities for Wastewater Discharges	   25

5.      How Do I Comply With Hazardous Waste Regulations? 	   31
       5.1     Do I Have Hazardous Wastes at My Print Shop? 	   31
       5.2     What Is My Hazardous Waste Generator Status?	   37
       5.3     What Requirements Must Hazardous Waste Generators Meet?  	   38
       5.4     Good Environmental Management Practices	   47
       5.5     Pollution Prevention Opportunities for Hazardous Wastes  	   50

6.      How Do I Comply With Air Regulations?	   59
       6.1     Air Emissions From  Printing Operations	   59
       6.2     Calculating Air Emissions From Your Print Shop	   60
       6.3     Determining Which Regulations Apply to Your Facility	   63
       6.4     Air Pollution Permits	   70
       6.5     Good Environmental Management Practices	   71
       6.6     Pollution Prevention Opportunities for Air Emissions	   71

7.      How Should I Handle Solid Waste?  	   75
       7.1     Reduction and Recycling Opportunities for Solid Waste 	   75
       7.2     New England State Solid Waste Programs	   76

8.      How Do I Respond to Spills and Plan for Emergencies? 	   79
       8.1     Emergency Spill Reporting	   79
       8.2     Emergency Planning and Chemical Reporting	   81
       8.3     Oil Spill Prevention Control and Countermeasures  	   83
       8.4     One Plan  	   84
Table of Contents

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                                                                           Fit to Print
                       TABLE OF CONTENTS (CONTINUED)
9.      Resources	  85
       9.1     Connecticut  	  85
       9.2     Maine  	  85
       9.3     Massachusetts	  86
       9.4     New Hampshire 	  86
       9.5     Rhode Island  	  87
       9.6     Vermont  	  87
       9.7     Federal Resources in New England	  88
       9.8     OSHA	  89
       9.9     Other Sources 	  90
                                        EXHIBITS

1.      Summary of Pollution Prevention Techniques 	   5
2.      Examples of Typical Lithographic Wastes 	  10
3.      Pollutants Prohibited From Discharge to Your POTW by the Federal
       Pretreatment Regulations	  15
4.      Conditions That Make Your Shop Subject to SIU Permit Requirements  	  15
5.      Reporting Requirements for All Indirect Dischargers 	  16
6.      Sample MSDS	  32
7.      Federal Categories of Hazardous Waste Generators and Storage Time Limits Allowed	  38
8.      Sample Manifest	  43
9.      Contingency Requirements for LQGs and SQGs	  46
10.     Calculating  Your Actual VOC or HAP Emissions  	  61
11.     Calculating  Actual and Potential VOC Emissions at Ace Printing	  62
12.     List of Federal Hazardous Air Pollutants (HAPs)  	  65
                                 BACK POCKET CONTENTS
Summaries of Your State's Requirements for:

             Wastewater Discharge
             Hazardous Waste Management
             Air Emissions Control
Table of Contents

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                                                                                 Fit to Print
                      I.  How CAN  I  BECOME "FIT To PRINT?"
 As we move toward the 21st Century, printing
 shops are facing increasing pressure to
 understand the environmental consequences of
 their operations. As a New England lithographic
 printer, you should care about operating your
 shop in an environmentally sound manner for
 several reasons:

 • Your shop's use of solvents, inks, fixers,
   coatings, and other chemicals can impact the
   environment and your workers.

 • The costs of noncompliance can be high.

 • Alternatives to your current way of doing
   business may exist that could save you
   money.

 This manual is designed to help you understand
 these issues and to give you the tools to make
 appropriate changes in your processes, where
 necessary.  This manual is divided into chapters
 that tell you how to comply with the most
 significant federal environmental regulations.
 The  pocket at the end of this manual contains
 summaries of state-specific environmental
 regulations. You will also find information on
 pollution prevention, solid waste management,
 emergency planning and response, and
 resources throughout New England that are
 available to assist you. We hope that you find
 this manual useful and that it helps you become
 "Fit To  Print."
  I.I     How Do I COMPLY WITH THE
         LAWS AND REGULATIONS THAT
         APPLY To MY LITHOGRAPHIC
         PRINT SHOP?

  It is important for you to be aware of and comply
  with all environmental laws and regulations that
  apply to your print shop. These laws and
  regulations can be found at the federal, state,
  and local levels. Congress has enacted the
  federal environmental laws over the past three
  decades to protect our air, land, and water. The
  U.S. Environmental Protection Agency is
directed to write regulations that implement
these laws. In most instances, the states have
also developed regulations that are often, but not
always, based on federal regulations. By law,
state environmental regulations must be at least
as stringent as their federal counterparts; in
some cases, they are more stringent than
federal regulations.  For this reason, you should
be especially careful to determine how your
state's environmental regulations apply to your
print shop. You should become familiar with your
state environmental agency and its regulations,
and use this document to guide your inquires.

This manual discusses the most significant -
but not all of the - federal and state
environmental requirements that apply to
your print shop; local requirements are not
addressed at all. City or town water and sewer
departments, especially, will most likely have
standards of which you should be aware. You
should contact these offices directly to get the
best information on their requirements.

Here is what you should do:

• First, identify the materials you use and the
wastes you generate at your print shop.  The
information contained in Chapter 3 will help you
identify the types of wastes you generate in your
prepress, press, and postpress operations and
your housekeeping activities.  Lithographic
printing wastes can include wastes released into
the water including treated  fixer and developer;
hazardous waste, such as untreated fixer; and
releases into the air from solvents and coatings.

• Second, determine which laws and
regulations apply to your print shop in light of
the materials used and wastes generated at your
print shop. Chapters 4 through 6 highlight the
most significant federal regulatory requirements
that may apply to your print shop. The pocket at
the back of this manual includes summaries of
the major state environmental requirements that
may impact your print shop. These summaries
are not intended to replace state  regulations,
however.

• Finally, determine what other laws and
regulations apply to your processes, in
How Can I Become "Fit to Print?"

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                                                                                 Fit to Print
 addition to those that govern how you deal with
 the wastes you produce.  Chapter 8 sets forth
 many of the additional spill reporting and other
 reporting requirements to which your print shop
 may be subject.
  1.2    WHAT POLLUTION PREVENTION

        TECHNIQUES CAN I USE AT MY

        LITHOGRAPHIC PRINT SHOP?

  This manual highlights pollution prevention (P2)
  techniques that may improve your shop's
  compliance and environmental performance.
  Why should you try pollution prevention? A U.S.
  Chamber of Commerce survey of 800
  companies showed that labor and environmental
  regulations are business "growth killers" (i.e.,
  they caused businesses to raise prices and
  reduced their profitability).  So the best way to
  improve the viability of your shop is to decrease
  your regulatory burden.  And the only legal way
  to do that is to prevent pollution.  Chapter 2
  explains pollution prevention in detail and
  summarizes some of the P2 options that can be
  used in your industry.  Chapters 4 through 6
  provide examples of P2 techniques. Solid waste
  reduction techniques and resources are provided
  in Chapter 7.
commercial organizations, and non-profit groups;
we can provide written reference materials and
advise you on environmental compliance and
pollution prevention strategies; and we can give
you the recognition you deserve for practicing
pollution prevention. So, call us at 1-800-
90NEEAT. Look for our homepage on the
Internet at http://www.epa.gov/region01.  Or,
write to us at the address listed in Chapter 9.

A closing thought: You can do it!  If you can
master the fine art of printing, you can comply
with environmental regulations and prevent
pollution as many others in your industry have
done.
  1.3    WHERE CAN I GET ADDITIONAL

        INFORMATION?

  The names and telephone numbers of federal
  and state contacts are provided throughout this
  manual. If you have a question about your
  compliance obligations or about P2
  opportunities, we encourage you to call the
  contacts listed at the end of Chapter 9 and
  provided in the pocket at the end of this manual,
  as well as your local city or town agents.

  Who are "we?" Regional experts in  conjunction
  with the New England Environmental Assistance
  Team (the NEEATeam) produced this manual.
  The NEEATeam provides environmental
  compliance and pollution prevention information
  for selected regulated groups, including printers,
  throughout New England. We can help you find
  experts in federal and state  governments,
How Can I Become "Fit to Print?"

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   	Fit to Print

    2.   How CAN POLLUTION PREVENTION  MAKE ME "FIT TO PRINT?"
Pollution prevention is a simple idea: it means
you eliminate pollution before it is created by
your manufacturing processes rather than
controlling the pollution from your processes and
then treating and disposing of the wastes that
you generate.  Pollution prevention techniques
that printers can use range from merely using
chemicals in the shop more conservatively and
responsibly to making fundamental changes in
the way presses are operated and maintained.
This chapter discusses the benefits of pollution
prevention, as well as some of the techniques
that might work in your shop.
2.1    WHAT Is POLLUTION

       PREVENTION AND How CAN IT

       HELP MY PRINT SHOP?

The U.S. Environmental Protection Agency
defines pollution prevention as the use of
materials, processes, or practices that reduce or
eliminate the generation of pollutants or waste at
the source.  The direct benefits of pollution
prevention are:

•  Decreased waste management costs
•  Decreased input materials costs and energy
  consumption
•  Decreased environmental compliance costs
•  Decreased liability
•  Increased compliance
•  Increased worker safety
•  Improved corporate image.

What will these benefits mean to your printing
business?

Reductions in the cost of operating your
print shop.

The creation of waste that impacts the water,
land, or air, and the use of certain chemicals,
translates into additional dollars you  must spend.
When you generate waste, your operating costs
increase since you must pay for items, such as
hazardous waste disposal, the installation and
operation of pollution control equipment, and
permit fees. By reducing waste streams, you
can cut the cost of operating your shop. And
these cost savings should translate to lower
prices and increased profits.

For example, you purchase a petroleum-based
solvent for press cleaning, you clean your
presses with the solvent, and the remainder that
collects in drip trays becomes a hazardous
waste (because it has been mixed with inks and
other contaminants). Then, you pay someone to
dispose of the solvent in a responsible manner.
Essentially, you have paid for the solvent twice
-- once  when you bought it the first time and
again when it went out for disposal as a
hazardous waste. You would not throw out part
of a completed job, so why waste the materials
that go  into the job by using them carelessly?
Using your press wash conservatively is an
example of pollution prevention that can prevent
waste and reduce your operating costs.

A more efficient and more productive
business.

In order to maintain  compliance with
environmental regulations, you and your staff
must conduct a great number of activities.  Each
of these compliance activities costs your shop
time and money.  And, more often than not, the
cost is hidden in your shop's overhead. The
more waste you generate, the more your shop
may be regulated. So, if you spend less time on
compliance because you have less waste to
manage,  you will have more time to do what you
are supposed to do:  PRINTING.

Peace of mind.

If your workers are exposed less frequently to
hazardous materials, their health and safety will
not be as much at risk. Your employees will be
happier, and you will not need to be concerned
about their well being -- or your liability. If there
are fewer hazardous materials in your shop, your
compliance obligations will be fewer. The
environment will be cleaner. You will be
prepared for a regulator's inspection, and your
corporate image will shine. The old saying is
true: an ounce of prevention is worth a pound of
cure.
How Can Pollution Prevention Make Me "Fit to Print?"

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2.2   WHAT P2 TECHNIQUES CAN I

       USE?

This section presents an overview of pollution
prevention techniques that can be incorporated
into your prepress, press, and postpress
operations and housekeeping activities.

• Prepress operation pollution prevention
  techniques primarily involve:

  - Activities that extend the chemical and wash
    bath life
  - Activities that reduce, recover, and recycle
    the chemicals used in photo-processing
    operations
  - Activities that reduce energy and input
   material consumption
  - Activities that eliminate the need for wet
   processing operations.

• Press operation pollution prevention
  techniques incorporate:

  - Process modifications that reduce ink use at
   the press and waste ink generated
  - Equipment changes to improve solvent and
   fountain solution use
  - Use of less toxic or non-toxic inks, solvents,
   and fountain solution
  - Improvements in handling of and waste
   management practices for input materials.

• Postpress operation pollution prevention
  techniques focus on:

  - Material substitutions such as switching to
   water based  adhesives
  - Equipment modifications to make finishing
   operations more efficient.

Exhibit 1  summarizes pollution prevention
techniques for the prepress, press, and
postpress operations, as well as for
housekeeping activities. The exhibit provides a
general idea of the options available to you and
their potential benefits in your shop. Chapters 4
through 7 present detailed descriptions of each
pollution prevention technique.  It is important to
remember that not every pollution prevention
technique will work at every print shop. You
should compare and evaluate these pollution
prevention techniques to identify those that may
help you meet your pollution prevention goals.
	Fit to Print

 You will then need to try a select few to
 determine what works in your shop, but does not
 compromise the quality of your product. Some
 pollution prevention techniques are easy; some
 are more challenging. They all involve changes
 in how you do business.  When you understand
 how much it costs to comply with all the
 regulations that apply to your shop, however, we
 think you will see that changing your operations
 makes good business sense.

 Each New England state has a staff of pollution
 prevention experts who can provide additional
 information  and confidential on-site technical
 assistance,  free of charge. You should work
 with the pollution prevention office in your state,
 using this manual to guide your inquiries.
 Chapter  9 presents a list of  contacts.

 So, get going! Start today by making a
 commitment to pollution prevention, and give
 your print shop a business advantage in an
 increasingly competitive industry.
How Can Pollution Prevent/on Make Me "Fit to Print?"

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                                                                     Fit to Print
Exhibit 1. Summary of Pollution Prevention Techniques
Pollution Prevention
Technique
Benefits
Waste Reduced
Page
No.
PREPRESS
Cover Photoprocessing
Chemical Containers
Aqueous Platemaking
Extending Bath Life
Reduce
Photoprocessing
Wastewater
• Wash Water
Control
Units
• Wash Water
Recirculation Units
•Countercurrent
Washes
Silver Recovery
• On-Site
•Off-Site
Material Substitution
Electronic Imaging and
Laser Platemaking
Reduction of the amount of raw materials lost
to evaporation.
Elimination of hazardous plate developer
waste. Increased employee safety because
of reduced exposure to chemicals.
Cost savings on raw materials. Reduction in
the amount of wastewater or hazardous
waste generated. Increased employee safety
by reduction in exposure to chemicals.
Cost savings from decreased fresh water use.
Reduced wastewater discharge. Decreased
energy consumption.
Revenue from on-site recovery of silver.
Increased employee safety due to reduced
exposure to waste fixer. Cost savings from
recovery of fixer solution.
Reduction in the amount of hazardous waste,
wastewater, and solid waste generated due to
use of less hazardous or nonhazardous
materials.
Reduction in the amount of input materials
used, thereby resulting in a reduction in the
amount of waste generated. Increased
productivity because of reduced manual
labor.
Air emissions
Hazardous waste
Air emissions
Wastewater
Hazardous waste
Air emissions
Wastewater
Wastewater
Hazardous waste
Wastewater
Hazardous waste
Solid waste
Wastewater
Hazardous waste
72
53
25
25-27
27-29
29
30
How Can Pollution Prevention Make Me "Fit to Print?"

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                                                                     Fit to Print
Exhibit 1. Summary of Pollution Prevention Techniques (Continued)
Pollution Prevention
Technique
Benefits
Waste Reduced
Page
No.
PRESS
Ink Inventory Control
Improve Press
Cleaning Practices
Recycle Used Ink
Automated Press
Adjustments for
Makeready
Alternative Inks
Alternative
Fountain Solutions
Automatic Ink
Levelers and
Antiskinning Spray
Alternative
Cleaning Solutions
Reuse and Recycle
Waste Solvents
Reduce Fountain
Solution Temperature
Automatic Blanket
Cleaners
Cost savings from reductions in out-dated
materials and waste ink disposal costs.
Reductions in the amount of waste ink
generated and the amount of cleaning solvent
and towels used.
Reductions in ink use and ink disposal.
Increased quality control. Reductions in
waste paper and ink generation.
Reduction in hazardous materials used,
waste generated, hazardous waste disposal
costs, Volatile Organic Compound (VOC)
emissions, and the amount of solvent needed
to clean the equipment.
Will help meet VOC emission limitations.
Increase in indoor air quality because of
reduced emissions. Elimination of the use of
Isopropyl Alcohol (IPA) fountain solutions.
Reductions in ink use and ink disposal.
Reduced VOC emissions. Improved indoor
and regional air quality. Increased employee
safety from reduction in handling toxic
chemicals.
Reductions in the amount of new solvent
used and the quantity of waste solvent that
must be disposed.
Reductions in fountain solution losses.
Reduction in amount of waste paper and ink
generated from poor press runs. Less
evaporation of IPA.
Cost savings from decreased solvent use and
labor required for cleaning the presses.
Increased employee safety from reduced
solvent handling and exposure. Reductions
in solvent use, waste solvent generation, and
VOC emissions.
Hazardous waste
Hazardous waste
Hazardous waste
Hazardous waste
Solid waste
Hazardous waste
Air emissions
Air emissions
Hazardous waste
Solid waste
Air emissions
Hazardous waste
Air emissions
Hazardous waste
Solid waste
Hazardous waste
Air emissions
50-51
52
52
53-54
54-55
72
56
72
56
73
57
How Can Pollution Prevention Make Me "Fit to Print?"
6

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                                                                                 Fit to Print
Exhibit 1. Summary of Pollution Prevention Techniques (Continued)
Pollution Prevention
Technique
Benefits
Waste Reduced
Page
No.
POSTPRESS
Water-Based
Adhesives for Post
Press Operations
Increase Use of In-Line
Finishing
Reduction in solvent-based adhesives used.
Reduction in VOC emissions. Reduction in
waste disposal.
Reductions in labor. Increase in rate of
production.
Air emissions
Solid waste
73
75
HOUSEKEEPING
Material Handling and
Storage
Reduce Materials Used
Reuse Materials
Recycle Scrap
Solvent Sink For
Parts Cleaning
Cost savings resulting from a reduction in the
amount of raw materials discarded due to
damage or expiration.
Cost savings from decreased material
purchases. Reduction in waste generated by
printing operations.
Cost savings from reuse of materials in
printing operations and reduction in solid
waste disposal.
Cost savings from reduced waste disposal.
Reductions in environmental impacts of
landfilling or trash incineration.
Reductions in the amount of new solvent
used and the quantity of waste solvent that
must be disposed.
Hazardous waste
Solid waste
Solid waste
Solid waste
Solid waste
Hazardous waste
51
75
75
75
57
Here is how to get started:

1.      Read Chapter 3 to get a sense for the wastes you may generate.

2.      Identify your problem waste first. This will include waste that you generate in high volume, that is
       costly to dispose, that is highly toxic, or that is heavily regulated.

3.      Read the P2 suggestions in this manual and seek additional information if you need it. Talk to
       your staff, the experts listed in this manual, other printers, or your vendors.

4.      Keep an eye on results. You will want to know whether the changes are helping and how much
       money you have saved. Your shop will be proof that pollution prevention pays - you will know you
       are on the right track if your shop is clean and orderly (e.g., no towels lying around, containers are
       closed, waste management areas are neat).

5.      And last,  but definitely not least, pat yourself on the back and enjoy the advantage! The New
       England Environmental Assistance Team (the NEEATeam) has a program to provide you with the
       public recognition you deserve for a job well done. Call 1-800-90NEEAT for more information.
How Can Pollution Prevention Make Me "Fit to Print?"

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   3.  WHAT WASTES Do I GENERATE  DURING PRINTING OPERATIONS?
If you are a lithographic printer, you generate
waste.  This waste can take one of the four
forms called waste streams'.

•  Wastewater
•  Hazardous waste
•  Air emissions
•  Solid waste.

Waste will be generated throughout prepress,
press, and postpress operations, as well as
housekeeping activities.

Exhibit 2 presents examples of typical
lithographic wastes. (Note: This exhibit is not all
inclusive. Depending on the input materials
used in your shop,  your shop may generate
waste that is not listed.) Each waste is grouped
in the table according to the waste stream (i.e.,
wastewater, hazardous waste, air emissions, or
solid waste) in which it is commonly found in a
print shop. For example, used, treated fixer and
used developer are most commonly put in a
print shop's wastewater, rather than being
drummed and disposed of as a hazardous
waste.  So, you will find this waste listed in the
wastewater section of the exhibit, and you will
need to pay careful attention to Chapter 4 of this
manual in order to comply with the appropriate
regulations. Similarly, if you dispose of this
waste in drums as hazardous waste, you should
read Chapter 5 of this manual and follow those
regulations.

To identify the regulations that may impact your
shop and the pollution prevention opportunities
available follow these four steps:

1. Use Exhibit 2 as a general guide to identify
   the waste your shop generates.

2. Identify any waste generated at your shop
   that is not listed in Exhibit 2. Refer to the
   resources listed in Chapter 9 if you are not
   sure whether some aspect of your process is
   generating a waste.
3.  Determine how you currently manage each
   waste you generate by answering the
   question, "In what form or waste stream does
   this waste leave my shop?"

4.  Refer to the following chapters for information
   on regulatory compliance and pollution
   prevention for each of your shop's waste
   streams:

       • Wastewater -- Chapter 4
       • Hazardous Waste -- Chapter 5
       • Air Emissions -- Chapter 6
       • Solid Waste -- Chapter 7.
What Wastes Do I Generate During Printing Operations?

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Exhibit 2. Examples of Typical Lithographic Wastes
PREPRESS WASTE
Wastewater
• Used, treated fixers
• Used developers
• Used activators/
stabilizers
• Plate developer
• Rinse water







Hazardous Waste*
• Chrome-based
system cleaners
• Non-empty
aerosol cans
• Discarded, unused,
or outdated chemicals
• Used, untreated
fixers
• Used shop towels
contaminated with
hazardous waste**
• Proofing system
chemicals
Air Emissions
• Volatile Organic
Compounds (VOCs)
or toxics emitted
from
-Film cleaner
-Proofing systems
solvents






Solid Wastes
• Empty containers
• Developed or out-
dated film
• Out-dated materials
• Used or damaged
plates
• Used, empty aerosol
cans
• Used shop towels**




PRESS WASTE
Wastewater
• Spent fountain
solution
• Rinse water










Hazardous Wastes*
• Waste ink containing
solvents
• Waste lubricating oil
(if defined as hazardous
waste by your state)
• Used blanket or roller
wash
• Spent cleaning solvent
• Used shop towels
contaminated with
hazardous waste**
• Used parts washer
solvent
Air Emissions
• VOCs or toxics
emitted from
- Solvents from
heatset inks/ink oils
- Isopropyl alcohol
- Cleaning solvents
- Coatings
- Solvent-saturated
shop towels
- Fountain solution
additives


Solid Wastes
• Ink containers
• Used plates
• Used blankets
• Off-spec printings
• Paper wrappings
• Paper roll ends
• Unprinted paper roll
cores
• End caps
• Used shop towels**



* A waste is a "hazardous waste" if it is listed in federal or state regulations or if it exhibits hazardous characteristics.
(See Section 5.1 for the definition.) The list of hazardous waste here assumes that the waste meets one of these
criteria.
** Check with your state's hazardous waste office (see the information presented in the pocket at the end of this
manual) to help you determine whether your shop towels are hazardous.
What Wastes Do I Generate During Printing Operations?
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Exhibit 2. Examples of Typical Lithographic Wastes (continued)
POSTPRESS WASTE
Wastewater
• Water-based
inks from ink
jet operations
• Water-based
coatings
• Water-based
adhesives
Hazardous Wastes*
• Used shop towels
contaminated with
hazardous waste**




Air Emissions
• VOCs or toxics
emitted from
- Adhesives
- Coatings



Solid Wastes
• Waste paper
• Waste shipping materials
• Scrap board
• Excess adhesives
• Used shop towels**
• Non-recyclable paper
• Empty containers
HOUSEKEEPING WASTE
Wastewater
• Cleaning
wastewater










Hazardous Wastes
• Waste oil (if defined
as hazardous waste
by your state)
• Absorbent materials
used to pick up
residual oils (if defined
as hazardous waste
by your state) or
solvents
• Used shop towels
contaminated with
hazardous waste**
Air Emissions
• VOCs or toxics emitted
from
- Miscellaneous
cleaners
- Paints
- Parts washers






Solid Wastes
• Empty containers
• Used shop towels**
• Pallets









* A waste is a "hazardous waste" if it is listed in federal or state regulations or if it exhibits hazardous characteristics.
(See Section 5.1 for the definition.) The list of hazardous waste here assumes that the waste meets one of these
criteria.
** Check with your state's hazardous waste office (see the information presented in the pocket at the end of this
manual) to help you determine whether your shop towels are hazardous.
What Wastes Do I Generate During Printing Operations?
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What Wastes Do I Generate During Printing Operations?                          12

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4.  How Do I COMPLY WITH WASTEWATER DISCHARGE REGULATIONS?
The discharge of wastewater from an industrial
source, including your lithographic print shop, will
generally be covered by either the Federal Clean
Water Act or the Safe Drinking Water Act. This
chapter explains these laws and the
implementing regulations which establish the
basic framework for keeping pollution, including
toxic pollutants, out of our rivers, lakes, and
oceans.  Since the primary sources of such toxic
water pollutants are industrial facilities, the U.S.
Environmental Protection Agency (EPA) has
taken steps to regulate these facilities.
4.1    Do I KNOW WHERE MY

       WASTEWATER GOES?

You must be able to answer "yes" to this
question. Discharges to unknown locations can
harm your workers and the environment and can
expose your shop to potential liability.

Your printing wastewater most likely gets
discharged to one of three locations:

• Sewers leading to publicly owned treatment
  works (POTW). After treating the wastewater,
  the POTW discharges it to a surface water,
  such as a river, lake, or stream.
• Septic and leach field systems (and other
  subsurface disposal systems).
• Surface waters, including ponds, lakes,
  oceans, streams, wetlands, and other water
  bodies.

Federal, state, and local regulations regulate
discharges to each of these locations. To
comply with these regulations, you should have a
good understanding of where your wastewater is
being discharged and what your  wastewater
discharge contains.
4.2   WHAT Do MY PRINTING

       WASTEWATER DISCHARGES

       CONTAIN?

Now that you have identified where your
wastewater goes,  the next step is to determine
what is in it. Wastewater is commonly generated
during prepress, press, and postpress
operations.  Exhibit 2 lists lithographic wastes
(e.g., used fixer and spent fountain solution)
typically found in wastewater (see Chapter 3).
While this list is not all inclusive, it gives you a
general idea of the kinds of waste generated in
each operation that may end up in your shop's
wastewater.  For most shops, silver discharges
will be of primary concern.

After you identify the waste in the wastewater
generated by your facility, you must determine
how best to manage it according to the
regulations that apply.  Here are the steps you
should follow to responsibly manage wastewater
from your print shop:

• Follow the compliance guidelines  listed in
  Sections 4.3 through 4.5 according to where
  your wastewater is discharged.
• Comply with all  applicable federal, state, and
  local regulations, including obtaining the
  necessary permits or registrations. The pocket
  at the end of this manual contains a summary
  of your state's requirements.
• Practice good environmental management.
  (Section 4.6)
• Prevent pollution.  (Section 4.7)
4.3   WHAT MUST I Do IF I

       DISCHARGE TO THE SEWER?

If your print shop discharges wastewater into a
sewer system that leads to a municipal treatment
plant, also known as a publicly owned treatment
works, you are subject to the requirements
discussed in this section.  Sometimes, you may
hear these referred to as the requirements for
indirect discharges.  Usually, POTWs treat
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domestic household wastes using filtration and
biological treatment processes. Because certain
pollutants present in industrial discharges can
adversely affect the POTW's treatment
processes or pass through the plant directly to
surface water without receiving adequate
treatment, POTWs generally cannot handle
certain types of industrial pollutants in large
quantities.

Federal pretreatment regulations were
developed to prevent or minimize the discharge
of certain pollutants to the POTW. These
regulations, apply to all industrial facilities,
including lithographic printers, that discharge
industrial wastewater to POTWs.  Industrial
wastewater includes any sources of  non-sanitary
wastes (i.e.,  process wastewater). Because
EPA or the states often delegate the authority to
enforce these requirements to the POTWs, you
should familiarize yourself with your  POTW's
local requirements.

Two types of pretreatment requirements exist:
those for all industry (known as general
pretreatment standards) and those for specific
industries (known as categorical pretreatment
standards):

•  General pretreatment standards establish
  minimum discharge requirements for all
  industrial dischargers, including lithographic
  printers. These standards prohibit all industrial
  users from discharging specific pollutants to
  POTWs. Exhibit 3 lists the types of pollutants
  prohibited by the general pretreatment
  standards.

•  Categorical pretreatment standards apply to
  specific types or categories of industrial
  facilities or processes.  As of the date of this
  printing, such standards have not been
  established for  the printing industry.

In addition to the  general pretreatment
standards, your shop may be subject to
requirements established by your local POTW.
That is, the POTW may impose its own
wastewater discharge limits upon your industrial
discharges in order to protect its treatment plant
and to meet its own direct discharge permit
limits. Where POTW requirements are more
stringent than federal requirements, they will
apply in lieu of  the federal requirements. In all
instances, you must notify and get approval from
your POTW to discharge industrial wastewater to
the POTW.

In addition to the above, you also may need to
get a wastewater discharge permit from the local
POTW or the  state if one of the two following
conditions exist:

• Your print shop is considered a significant
  industrial user (SIU) (Exhibit 4 lists the criteria
  that would make you an SIU.)

• You are not an SIU but the POTW to which
  you discharge requires that all industrial
  dischargers, including small dischargers, have
  a permit.

(Check with your local POTW to find out if you
must obtain a permit in either situation.)

Regardless of whether a POTW issues a local
permit to your facility, you  must check with your
state environmental agency to find out if a state
permit is also  required for  a discharge to a
POTW.  Some states may have a permit
program specifically for discharges to the sewer.
Overall, even  if a POTW or the state does not
require a permit, you should  notify and obtain
approval from the POTW to discharge into the
sewer system.

If you discharge to a POTW, you may also be
required to  monitor, submit reports, and keep
records  of your industrial wastewater discharges.
Certain reporting requirements apply to all
discharges to  the POTW.  Exhibit 5 presents the
most significant of these requirements.  In
addition, if your shop must obtain a permit, as
discussed above, your facility-specific permit
may contain additional monitoring, reporting, and
recordkeeping requirements.
How Do I Comply With Wastewater Discharge Regulations?
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        Exhibit 3.  Pollutants Prohibited From Discharge to Your POTW By the
                            Federal Pretreatment Regulations

   Some of the general types of prohibited pollutants include:

   •       Pollutants that cause pass through or interference at the POTW

          Pollutants that create a fire or explosion hazard in the POTW, including waste streams with a
          closed cup flashpoint of less than 140 degrees Fahrenheit

          Pollutants that cause corrosive structural damage (i.e., any wastewater with a pH less than 5)

   •       Pollutants that are solid  or viscous and can obstruct the wastewater flow

   •       Pollutants that are released in a discharge at a flow rate or concentration that will cause
          interference at the POTW

   •       Heat in amounts that will inhibit biological activity at the POTW, and, in any case, discharges
          that will cause the temperature at the POTW to exceed 104 degrees Fahrenheit

   •       Petroleum oil, non-biodegradable cutting oil, or products of mineral oil  in amounts that will
          cause interference or pass through

   •       Pollutants that result in the presence of toxic gases, vapors, or fumes  in the POTW that may
          cause acute worker health and safety problems

   •       Any trucked or hauled pollutants,  except at discharge points designated by the POTW.

   See 40 Code of Federal Regulations Section 403.5 (40 CFR § 403.5) for a complete list.
           Exhibit 4. Conditions That Make Your Shop Subject to SIU Permit
                                       Requirements

   If your shop meets at least one of the following criteria, you should check with the local POTW or state
   to receive information about obtaining a permit:

          Discharges an average of 25,000 gallons or more per day of process wastewater (excluding
          sanitary and noncontact wastewater)

          Contributes a process waste stream that makes up 5 percent or more of the average dry
          weather hydraulic or organic capacity of the POTW treatment plant

          Is determined to have a reasonable potential for adversely affecting the POTW's operation or
          for violating any pretreatment standard or requirement

          Is subject to categorical pretreatment standards (as stated previously, none has been
          established for lithographic printers).
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Exhibit 5. Reporting Requirements For All Indirect Dischargers
Requirement*
Notify the POTW or state immediately of a wastewater discharge that could
cause problems to the POTW, including slug loading (defined as any relatively
large release of a pollutant that might not ordinarily cause a problem when
released in small quantities), spills, and unpermitted pollutants.
Notify the POTW or state of a substantial change in your shop's wastewater
discharge.
Notify the POTW, state hazardous waste authorities, and EPA Regional Waste
Management Division Director of the Office of Site Remediation and Restoration
of a hazardous waste discharge. This is a one-time written notification required
of those who discharge more than 15 kg (33 Ibs) of a hazardous waste in a
month, or, if the waste is acutely hazardous, any amount that is discharged.
Contact EPA, or see 40 CFR Part 261 , for what must be included in the written
notification. Note: A list of acutely hazardous wastes is presented in 40 CFR
§ 261.30(d) and 40 CFR § 261.33(e).
Time Frame
Immediately
Prior to the change
One-time written
notification for each
hazardous waste
discharge
 For a complete list of reporting requirements, see 40 CFR § 403.12.
How to Comply If You Discharge Wastewater
to a POTW


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4.4   WHAT MUST I Do IF I

       DISCHARGE TO A SEPTIC SYSTEM

       OR OTHER SUBSURFACE

       WASTEWATER DISPOSAL

       SYSTEM?

The Safe Drinking Water Act established the
basic framework for protecting the drinking water
of the United States. This act requires EPA to
regulate underground injection of waste fluids
through subsurface wastewater disposal
systems, such as your septic system, that
discharge waste into, or above, the underground
sources of drinking water. These regulations,
often referred to as the Underground Injection
Control (UIC) Regulations, are designed to
protect the country's drinking water supply. EPA
has authorized all six of the New England states
to implement the UIC program.

Industry and commercial businesses commonly
operate subsurface  wastewater disposal
systems. These disposal systems can include
septic systems, leach fields, leaching pits and
trenches, dry wells,  cesspools, and wastewater
disposal wells.  Subsurface disposal systems
can pose a significant threat to underground
sources of drinking water because they are
numerous, often are located near public water
supplies, and are used to dispose of a wide
range ot nonhazardous and hazardous wastes.

It is important to know what you discharge to
your subsurface wastewater disposal
system. Wastes discharged to these disposal
systems typically include liquid waste, process
wastewater, non-contact cooling water, sewage,
and storm water. Fluid wastes of this sort
commonly contain wash water, spill drainage,
and storm water from maintenance areas,
hazardous substance storage areas, processing
and manufacturing areas, and fueling areas and
are susceptible to contamination by hazardous
materials and wastes. If your wastewater
disposal system(s) is not connected to a
municipal sewer or does not discharge to a
surface water, you may be using a septic system
or other subsurface  wastewater disposal system
to dispose of your waste.
Your state regulates your subsurface wastewater
disposal system(s).  If you use a septic system
or other subsurface wastewater disposal system:

/ You may not discharge hazardous waste
  from your lithographic printing operations
  to your subsurface disposal system.
  Subsurface discharges of hazardous
  materials and wastes that render drinking
  water undrinkable or that endanger public
  health are prohibited by law. (See
  Chapter 5 to determine which of your
  printing wastes are hazardous.)

/ You must obtain a permit from your state.


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/  If your facility disposes of sewage that is
   generated by 20 or more people per day to a
   septic system or other subsurface
   wastewater disposal system, you are subject
   to DIG regulations, even if you do not
   discharge industrial wastewater to the
   disposal system. Contact your state UIC
   program to get more information about
   applicable UIC regulations. (Please refer to
   your state's requirements provided in the
   pocket at the end of this manual.)

/  You may not discharge hazardous wastes
   into your septic system or other
   subsurface wastewater disposal system.
   Discharge of hazardous waste is prohibited
   by law. If any amount of hazardous waste is
   discharged to a subsurface wastewater
   disposal system, you must stop the discharge
   and immediately notify your state UIC
   program. (Please refer to your state's
   requirements provided in the pocket at the
   end of this  manual.)
4.5   WHAT MUST I  Do IF I

       DISCHARGE To SURFACE

       WATER?

Any wastewater (excluding storm water, which is
discussed below) from your shop that is
discharged directly into surface water, including
a pond, lake, river, tributary to a river, wetland,
and ocean, requires you to apply for and obtain a
permit under the National Pollutant Discharge
Elimination System (NPDES) program. An
NPDES permit sets limits on the amounts of
pollutants that can be discharged to surface
waters. The NPDES permit system is designed
to protect the quality of the water bodies into
which wastewater is discharged.  Consequently,
stringent  limits are imposed on the amounts and
concentrations of the pollutants that may be
discharged.

NPDES Permits. The NPDES program is
implemented either by EPA or by states running
an equivalent EPA-approved program.
Therefore, your facility may be required to submit
an application and receive a permit from EPA or
the state. Please refer to Section 4.6 to
determine if you should apply to EPA or your
state for a general or individual NPDES permit.
In addition, in states where EPA is the permit-
issuing authority, the states have separate
wastewater permit requirements and issue their
own additional permits.

If your lithographic print shop is required to get
an NPDES permit, your permit will:

 • Specify the amount of pollutants that you can
  discharge, depending on either the
  wastewater treatment technology in your shop
  or on the specific water quality standards of
  the body of water to which your shop
  discharges, whichever is more protective of
  the environment.

 • Require that you routinely conduct monitoring
  and submit reports (generally on a monthly
  schedule). Such requirements are
  determined on a facility-specific basis;
  .however, some reporting requirements apply
  to all facilities.

 • Require that you maintain all monitoring
  records for at  least 3 years.

 •Contain other site-specific requirements,
  including:

        - Construction schedules
        - Best management practices
        - Whole effluent toxicity testing
        - Spill prevention  plans.

Storm Water NPDES Permits.  Certain
industrial facilities that discharge storm water
must apply for a storm water permit. You must
obtain a storm water NPDES permit if the
answer to all three of the following questions
is YES:

1.  Do you have  a storm water discharge?

The answer is YES if there is a positive
collection or conveyance system, and it
culminates at a point source (e.g., a pipe, ditch,
channel, tunnel well,  or container).  A positive
collection or conveyance system is  any type of
system that is meant to collect storm water and
remove it off-site (e.g., parking lot drains or
ditches to convey storm water off-site).
How Do I Comply With Wastewater Discharge Regulations?
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2.  Does this point source discharge to regulated
   waters?

The answer is YES if the storm water is
discharged to a surface water, or if it is
discharged to a separate storm sewer, which is
then discharged to surface waters.  Surface
water is defined broadly and includes rivers,
ponds, oceans, and wetlands.

3.  Do you conduct an industrial activity subject
   to the regulations?

As a lithographic printer, your Standard Industrial
Classification (SIC) code is 27 (or possibly 26),
so the answer is YES.  For industries in this
group, you have to ask one more question: Is
there exposure or  potential exposure of input
materials, finished products, byproducts, or
material handling equipment to storm water? If
the answer is YES to this final question and this
storm water is discharged to surface waters, you
are subject to the storm water regulations and
must obtain a storm water permit.

If you  are unsure about whether you should
answer yes to any of the above, or you are
unclear about whether you have a point source
or discharge into surface water, call one of the
resources listed at the end of this chapter.
/  Ensure that your shop meets the effluent
   limits in your NPDES permit. Conduct
   monitoring, reporting, and recordkeeping
   activities for your permitted discharges
   (wastewater and/or storm water).

/  Notify the permitting authority:

       -  Of a noncompliance that has occurred
         with your wastewater discharge that
         may endanger health or the
         environment within 24 hours of
         becoming aware of the violation and in
         writing within 5 days

       -  Of any planned physical alterations or
         additions that may affect your
         wastewater discharge at your shop as
         soon as  possible

       -  Of any planned changes in your
         wastewater discharge that may result
         in noncompliance (advance notice
         required)

       -  Of the transfer of the facility to a new
         owner as soon as possible in advance
         of the transfer.
How to Comply If You Discharge to Surface
Water

/  Apply for and obtain an NPDES permit for
   wastewater and, if applicable, for storm
   water. Contact EPA or your state regulatory
   agency to find out how to obtain an NPDES
   permit application for wastewater and/or
   storm water discharges. (Please refer to your
   state's requirements provided in the pocket at
   the end of this manual.)
How Do I Comply With Wastewater Discharge Regulations?
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4.6   GOOD ENVIRONMENTAL MANAGEMENT PRACTICES
Here are some tips on good environmental management practices that could help save you money and
improve your operations:
       • Manage silver-bearing wastewater properly. Do not put untreated fixer down the drain. Reclaim
         and recycle the silver prior to wastewater discharges (see methods described in Section 4.7).
       • If you use a silver recovery unit, operate and maintain it according to the manufacturer's
         specifications.
       • Place signs near all sinks and drains in the work area prohibiting disposal of press-cleaning
         solvents, inks, and untreated silver-bearing waste. (Remove or photocopy the sample signs
         found on the next two pages, and place above or near the sinks and drains in your shop.)
       • Properly manage wastewater discharges to septic systems.  Ensure that you have the proper
         permits. It is good practice to avoid  discharging process chemicals to your septic system.
       • Never discharge industrial wastewater to floor drains!
       • Extend the lives of photoprocessing  baths by adding replenishers and regenerators.
       • Keep process baths covered to preserve their quality and life.
       • Reduce drag-in of contaminants by using a squeegee on film between baths.  Reduce drag-out
         of solution by adding drip boards and extending drip time.
       • Use non-hazardous developers and finishers.
       • Add glass marbles to developer solution to bring the liquid level up to the brim to reduce
         oxidation.
How Do I Comply With Wastewater Discharge Regulations?                           20

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4.7   POLLUTION PREVENTION OPPORTUNITIES FOR WASTEWATER DISCHARGES

This section describes pollution prevention (P2) opportunities that can reduce wastewater discharges.
Information on whether the technique is easy or more difficult to use is included next to each listing,
followed by a description of the technique and its benefits. Each discussion provides information on the
relative cost of the technique and the waste stream that can be reduced using each technique, where
possible. For more information, please contact the individuals listed in Chapter 9.


Extending Bath Life                                                               Easy

Technique:     To reduce generation of waste and fixer solution, this P2 technique can be implemented
              with no capital expenditure and no equipment modifications by your print shop.

              You can extend the life of your fixer bath by the following activities:

                     Adding ammonium thiosulfate (hypo), which doubles the allowable concentration
                     of silver buildup in the bath.
                     Using an acid stop bath prior to the fixing bath if you do tray processing.
                     Adding acetic acid to the  fixing bath as needed to keep the pH low.
                     Changing the fixer bath solution only when it  is no longer effective,
                     rather than changing photoprocessing fixer bath solutions on a set
                     schedule. Manufacturer chemistry replenishment schedules are
                     typically conservative; therefore, you may be  discarding bath
                     solution as waste when it is still effective.

              You should discuss these options with your vendors to see what will work for your shop.

Benefits:      •      Cost savings on the purchased fixer.
                     Decrease in the volume of waste fixer solution generated.
                     Increase in employee safety because of reductions in the  number of changeouts
                     and, therefore, reductions in employee handling of and exposure to bath solution
                     chemicals.

Costs:        •      Use of these techniques can increase the chemical concentrations in your baths.
                     Thus, if you discharge wastewater to your local POTW, your NPDES permit limits
                     or treatment practices may be affected. Contact your wastewater treatment plant
                     or, if you are a direct discharger, EPA or the state, for guidance prior to making
                     these changes.


Wash Water Control Units                                                        Easy

Technique:     This P2 technique will assist you  in reducing your fresh water use  and wastewater
              generation, which in turn will result in cost savings to your print shop and decreased
              demands on the POTW to process your wastewater.  Many automatic photoprocessors
              provide a continuous flow of fresh water across the film, while others require continuous
              replenishment of a wash bath when film is processed.  A wash water control unit can be
              added to automatic photoprocessors to reduce fresh water use. A wash water control unit
              is basically an electronic valve that only turns on when film is being processed. Wall-
              mounted control units, which control the flow and temperature of the water to the wash
              bath, can be installed with any photoprocessor.
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Benefits:       •       Cost savings can be realized from decreased fresh water use and reduced
                      wastewater discharge. Here is an example to help you determine your cost
                      savings from the use of a wash water control unit:

                             ABC Photoprocessqr uses up to 2.6 gallons of wash water per
                             minute.  If the wash water were allowed to run for an 8-hour
                             period, up to 1,248 gallons of water would be  required. If running
                             water is needed for only 10 percent of the 8-hour period, a
                             control unit could reduce water consumption by up to 1,124
                             gallons.

                             Assuming a savings of up to 1,120 gallons of water per day, at a
                             cost of $1.02 per unit (1 unit is 100 ft3), a savings of up to $45 per
                             month (up to $540 per year) would be realized. Wastewater
                             discharge savings may amount up to $190 per month (up to
                             $2,280 per year), at a discharge fee of $4.25 per unit. Your
                             payback period to recover the cost of the unit  could be less than
                             1 year.

Costs:          •     A water control unit costs approximately $1,200.


Wash Water Recirculation Units                                              Moderate

Technique:     This pollution prevention technique will assist you in reducing your fresh
               water use and wastewater generation, which in turn will result in cost
               savings to your print shop and decreased demands on the POTW to
               process your wastewater. Water recirculation units can be installed to
               reuse photoprocessing wash water in film and plating processing
               equipment.

Benefits:        •       Reduces fresh water use, wastewater discharge,  and energy
                      consumption  associated with heating the wash water baths.

Costs:         •       The costs associated with installing water recirculation units vary among print
                      shops. Capital expenditures are required for:
                            The water recirculation unit (a minimum of $500)
                             Replumbing of the wash water bath system
                             Ongoing operation and maintenance.
                      Use of these techniques can increase the chemical concentrations in your baths.
                      Thus, if you discharge wastewater to your local POTW, your NPDES permit limits
                      or treatment practices may be affected. Contact your  wastewater treatment plant
                      or,  if you are a direct discharger, EPA or the state, for guidance prior to making
                      the changes.
                      Filters from the water recirculation units require disposal and may be considered
                      hazardous waste in some states (check with your state agency).

Countercurrent Washes                                                       Moderate

Technique:     This pollution prevention technique will assist you in reducing your fresh water use and
               wastewater generation, which in turn will result in cost savings to your print shop and
               decreased demands on the POTW to process your wastewater.  In tray processing,
               countercurrent washing can replace commonly used parallel tank systems.
               Countercurrent washing is done by using rinse water in the initial film wash and
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Benefits:
Costs:
introducing fresh water only at the final rinse stage when much of the contamination has
already been rinsed off the film.

       Reduces the amount of contamination in processing solutions and conserves
       water.
       Reduces the volume of fresh water used.
       Reduces the volume of wastewater generated. You can achieve dramatic
       reductions of up to 90 percent water use with this method.  Combining
       countercurrent washing and automatic controls can cut water use by 99 percent.
       Because water and sewer use rates are increasing, these techniques will yield
       short payback periods.

       The  countercurrent washing system requires more space and equipment.
       Capital expenditures are required for:
       - Equipment maintenance
       - Secondary containment to protect the shop in the event of a spill.
       Employees will need to learn proper mixing of chemistry.
Silver Recovery

Silver recovery can be performed either at your print shop or at an off-site recycling facility to reduce silver
from your wastewater and generate revenue from the recovery of this metal. This discussion highlights
four methods (three on-site and one off-site):

               On-site methods
                      Metallic replacement cartridges
                      Ion exchange and chemical precipitation
                      Electrolytic silver recovery
               Off-site methods
                      Fixer recycling.

Many printers have determined on-site recovery to be cost-effective compared to disposal costs. Reverse
osmosis is another method of silver recovery that is not discussed here because of its costs.

ON-SITE METHODS
                                                                                         Easy
Technique:     Metallic replacement cartridges -- Silver can be recovered from fixer bath solution
               through use of a metallic replacement cartridge at your print shop before the solution is
               discharged to the sewer. As wastewater passes through the cartridge, iron replaces the
               silver in solution, and the silver settles out as a solid. The metallic replacement cartridge
               must then be processed off-site to reclaim the collected silver.

               Cartridges containing  steel wool are connected to the fixer bath overflow in order to trap
               silver.  Silver concentrations can be reduced by up to 99 percent if two cartridges are
               used in series.  Cartridges must be closely monitored to determine when they are spent in
               order to prevent silver from being discharged to the sewer. Generally, a single cartridge
               treats at least 150  gallons of fixer solution.

Benefits:       •       Revenue can  be generated from the sale of silver (approximately $70 per troy
                      ounce).
                      This  method is readily available and in widespread use in the printing industry.
                      There are  no energy needs or plumbing requirements.
                      Little maintenance is required.
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Costs:         •       Capital expenditures for the initial metallic replacement cartridge hookup are
                      generally less than $50.
                      Ongoing expenses will include 1) the cost of replacement metallic cartridges at
                      approximately $50 for a 5-gallon cartridge and 2) cartridge collection and
                      processing ($75 refining fee in addition to an average $125 collection fee per 5-
                      gallon cartridge).  Cartridges cannot be reused.
                      Recovery fees may exceed revenues from silver because of the small amount of
                      silver recovered. The cost per gallon of fixer solution is estimated at $1.60.
                      The wastewater that results contains high iron concentrations.

                                                                                    Moderate
Technique:     Electrolytic silver recovery is a pollution prevention technique that can be performed at
               your printing facility to recover silver in nearly pure form from wastewater discharges.
               Two types of electrolytic silver recovery units (SRUs) use a controlled current to remove
               silver from wastewater solutions:

                      A recirculating 3RD is placed "in  line" as part of the fixer recirculating system. A
                      recirculating SRU prolongs the effectiveness of the fixer bath by filtering silver to
                      reduce its concentration and replenishing the fixer, thereby reducing the fixer
                      replenishment rate by 60 to 90 percent.

                      A terminal SRU  is connected to the overflow discharge hoses of the process.
                      Fixer solution passes through the SRU, where the silver is collected. A terminal
                      SRU may also require a backup metallic replacement cartridge in order to meet
                      applicable local  sewer use limits.

               Both types of units may have either a stationary or rotating cathode. Silver is periodically
               scraped off the cathode  and collected for pickup by a metals recycler.


Benefits:       •       Typically, recirculating SRUs remove up to 90 percent of the silver from fixer bath
                      solutions.  Revenue can be generated from sale of the silver.
                      It can minimize silver carried into the wash tank.

Costs:         •       De-silvered fixer can be reused, thereby  reducing fixer chemistry costs.
                      A rotating cathode removes more silver but requires additional maintenance
                      because it has more moving parts than a stationary cathode.
                      Capital expenditures include the purchase of an SRU and the replumbing to
                      install the unit.
                      There are operation and maintenance costs.
                      An SRU can cost between $700 and $2,000, and recycler fees vary according to
                      the monthly use of fixer.
                      pH must be closely monitored.

                                                                                 Challenging
Technique:     Ion exchange is done by passing wastewater through a number of ion-exchange resins,
               or by using a strong base-gel anion resin, to selectively remove the silver.  The resins are
               then sent off-site for silver recovery.  It is important to choose the correct resin to
               maximize efficiency of this operation.  (Ion exchange is usually a secondary or tertiary
               process, following electrolytic recovery and/or use of metallic replacement cartridges,
               because it is best for silver recovery from dilute solutions.)
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              Ion exchange can be followed by chemical precipitation, in which chemicals (e.g.,
              sulfide) are added to wastewater to precipitate silver chloride out of the solution. For this
              reason, ion exchange is cost effective for larger shops only.

Benefits:      •       Revenue can be generated from the sale of silver (approximately $70 per troy
                      ounce).
                      It can help achieve low silver concentrations in wastewater.

Costs:        •       Automated ion exchange units are only cost effective for processing large
                      amounts of wastewater, because of their high cost.  A small unit can cost $3,000
                      to $5,000.
                      The cost of chemicals for precipitation, holding tanks, and supplemental heat
                      input can make this somewhat costly.
                      Employee training or use of chemicals add other costs.

OFF-SITE METHODS
                                                                                         Easy
Technique:    Fixer recycling  can be performed at an off-site licensed recycling facility to recover silver
              from wastewater discharges. Fixer bath solution is collected at the print shop and is sent
              to a fixer recycler.  The recycler recovers the silver and, in some cases, regenerates the
              fixer.  The recycler must send the silver to a reclamation facility for processing.

Benefits:      •       Revenue can be generated from the sale of silver (approximately $70 per troy
                      ounce).
                      Cost savings can be realized from reduced fixer purchases.

Costs:        •       The cost of collecting the fixer solution and sending it to  an off-site treatment
                      facility may cost more than $2 per gallon.
Material Substitution                                                            Moderate

Technique:     By using fewer and nonhazardous input materials, you will generate less hazardous and
               nonhazardous wastes.

               Nonhazardous chemical substitutes may be available to replace hazardous chemicals
               currently used at your shop. Because many are available, you should ask your vendors to
               provide you with information about nonhazardous or less toxic chemicals.  Examples
               include:

                             Prepress chemistry that eliminates the use of formaldehyde.
                             Photographic intensifies and reducers that do not contain mercury or
                             cyanides.
                             Nonhazardous aerosols, although you should limit your use of aerosols or
                             switch to non-aerosol products, such as manual pump cans or bottles,
                             especially if they can be refilled.  (Always return defective cans to your
                             vendor.)

               Pre-sensitized plates should be used as an alternative to metal-etched plates  because
               they are nonhazardous and can be recycled for aluminum content. The pre-sensitized
               plates should be stored under the recommended  conditions to maintain effectiveness.
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               Silverless films are beginning to appear on the market. The benefit of their use is that
               they typically produce nonhazardous fixer wastes.  However, they do require a large
               capital investment in new technology. As this technology advances, they may become a
               more viable option for printers.

Benefits:       •       Reduces the volume of wastewater generated.
                      Reduces the volume of hazardous waste generated.


Electronic Imaging and  Laser Platemaking                                Challenging

Technique:     Computerized  electronic prepress systems are now available for image processing.
               Using an electronic scanner, text, photos, graphics, and layout are entered into the
               system. The copy is edited on the display monitor rather than on paper.

Benefits:       •       The reduction in the quantity of film, developing chemicals,
                      and paper used during image processing, will, in turn, reduce
                      the amount of waste film, waste paper, waste chemicals,
                      wastewater, and hazardous waste generated.
                      This technique should increase productivity because of the     ( JH
                      reduced manual labor required for image processing.

Costs:         •       This technique requires extensive research and evaluation to determine what
                      systems would be right for your operations.
                      A large capital investment is required for the purchase of the computer hardware
                      and software.  Electronic prepress systems were initially restricted to large
                      printing facilities because of the high initial capital investment. As computer
                      hardware and software prices become more reasonable, smaller printing facilities
                      will be better able to afford this technique.
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    5.   How Do I COMPLY WITH HAZARDOUS WASTE REGULATIONS?
As a printer, you produce wastes that could be
hazardous.  Therefore, it is important that you
identify and manage them properly to protect
yourself, coworkers, and others in your
community, as well as the environment.  As the
waste generator, you are responsible for all
steps in hazardous waste  management, from
generation to final disposal.

You can be held liable for any
mismanagement of your wastes, even after
they leave your facility.  So, it is important for
you to know the facts.

This chapter explains the hazardous waste law,
known as the Resource Conservation and
Recovery Act (RCRA), and its regulations which
impose many requirements on how you must
handle and dispose of the wastes you generate
in your print shop.  Sections 5.1 through 5.3
focus on the major federal requirements with
which  you must comply. In many instances, the
states impose additional and more stringent
requirements on how you handle  your wastes. It
is critical, therefore, that you review your state's
requirements provided in the pocket at the end
of this manual and contact your state
environmental agency (numbers  and addresses
are listed in the pocket at the end of this manual)
for any additional requirements.  Sections 5.4
and 5.5 present information on good
environmental management and  pollution
prevention techniques that address hazardous
waste.

Here are the steps you should follow to ensure
compliance with this law and to prevent pollution:

•  Determine whether you have hazardous waste
 at your print shop.
•  Determine your hazardous waste generator
 status.
•  Meet the eight major requirements for
 hazardous waste generators.
•  Practice good environmental management.
•  Prevent pollution from hazardous waste.
•  Determine your state's hazardous waste
 requirements.
5.1    Do I HAVE HAZARDOUS WASTES

       AT MY PRINT SHOP?

Since you are a printer, the answer will probably
be "yes."  Hazardous waste is generated during
many lithographic printing operations. The
following lists will give you an idea of the types of
waste you may be generating.  (Note: Because
each lithographic print shop is unique, this is
not all inclusive.) Exhibit 2 (see Chapter 3)
presents a profile of typical hazardous waste
generated by lithographic printing operations.

Some materials that may be familiar to you and
that may be considered hazardous wastes
depending on the state you are in include:

• Spent untreated fixer solution/silver-bearing
  photographic wastes
• Non-empty aerosol cans
• Certain discarded or unused chemicals
• Waste solvent-based inks
• Spent cleaning solvents
• Used parts washer solvent
• Solvent-contaminated rags
• Proofing system chemicals.

An important source of information about the
chemicals you use is the Material Safety Data
Sheet (MSDS). The MSDS is provided by your
chemical supplier and gjves general health and
safety information about handling these
chemicals. These MSDSs will  not provide you
with all of the answers to your environmental
questions, but they can help you identify your
hazardous waste.  Exhibit 6 provides a sample
MSDS. As you can see, properties of a
chemical, such as its pH or flashpoint, are
included on an MSDS. To ensure that your
MSDSs are current, require your vendors to
automatically supply you with an MSDS with new
products and to have anyone approving
purchases in your business ask for them from
the supplier.
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                            Exhibits. Sample MSDS
 MSDS for ISOPROPYL ALCOHOL

 1 - PRODUCT IDENTIFICATION

 PRODUCT NAME:            ISOPROPYL ALCOHOL
 FORMULA:                 CH3CHOHCH3
 FORMULA WT:              60.10
 CAS NO.:                  67-63-0
 NIOSH/RTECS NO.:           NT805000
 COMMON SYNONYMS:        2-PROPANOL; ISOPROPANOL; SEC-PROPYL ALCOHOL; IPA;
                          DIMETHYLCARBINOL
 PRODUCT CODES:           U298,5082,9080
  EFFECTIVE:               09/03/86
  REVISION #02

 PRECAUTIONARY LABELING:

  BAKER SAF-T-DATA (TM) SYSTEM
        HEALTH             - 1 SLIGHT
        FLAMMABILITY        - 3 SEVERE (FLAMMABLE)
        REACTIVITY          - 1 SLIGHT
        CONTACT           - 1 SLIGHT
  HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).

 LABORATORY PROTECTIVE EQUIPMENT:

        - SAFETY GLASSES
        • LAB COAT
        • VENT HOOD
        • PROPER GLOVES
        • CLASS B EXTINGUISHER.

 PRECAUTIONARY LABEL STATEMENTS:

        • WARNING
        • FLAMMABLE
        • CAUSES IRRITATION
        • HARMFUL IF SWALLOWED OR INHALED
        • KEEP AWAY FROM HEAT, SPARKS, FLAME
        • AVOID CONTACT WITH EYES, SKIN, CLOTHING
        • AVOID BREATHING VAPOR
        • KEEP IN TIGHTLY CLOSED CONTAINER
        • USE WITH ADEQUATE VENTILATION
        • WASH THOROUGHLY AFTER HANDLING
        • IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER
        MAY BE INEFFECTIVE
        • FLUSH SPILL AREA WITH WATER SPRAY.

 SAF-T-DATA(TM) STORAGE COLOR CODE:      RED (FLAMMABLE)
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                      Exhibit 6.  Sample MSDS (continued)

 2 - HAZARDOUS COMPONENTS

              COMPONENT              %           CAS NO.

              ISOPROPYL ALCOHOL        90-100        67-63-0


 3 - PHYSICAL DATA

 BOILING POINT:       82°C (180°F)         VAPOR PRESSURE (MM HG): 33

 MELTING POINT:      -89°C (-128°F)        VAPOR DENSITY (AIR=1): 2.1

 SPECIFIC GRAVITY:    0.79               EVAPORATION RATE: 2.83
       (H2O=1)       (BUTYL ACETATE=1)

 SOLUBILITY (H2O):           COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100

 APPEARANCE & ODOR:       COLORLESS LIQUID WITH SLIGHT ODOR OF RUBBING ALCOHOL

 4 - FIRE AND EXPLOSION HAZARD DATA

 FLASH POINT (CLOSED CUP):  12°C(53°F)           NFPA 704M RATING: 1-3-0

 FLAMMABLE LIMITS:          UPPER - 12.0%        LOWER - 2.0%

 FIRE EXTINGUISHING MEDIA:

   • USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.)

 SPECIAL FIRE-FIGHTING PROCEDURES:

  ' FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
    BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE
  • MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK
  • USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.

 UNUSUAL FIRE & EXPLOSION HAZARDS:

  - VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK
  • CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE
  • CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE.

 TOXIC GASES PRODUCED:

  CARBON MONOXIDE, CARBON DIOXIDE
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                       Exhibit 6. Sample MSDS (continued)

 5 - HEALTH HAZARD DATA

 THRESHOLD LIMIT VALUE (TLV/TWA):   980 MG/M3 (400 PPM)

 SHORT-TERM EXPOSURE LIMIT (STEL):  1225 MG/M3 (500 PPM)

 PERMISSIBLE EXPOSURE LIMIT (PEL):   980 MG/M3 (400 PPM)

 TOXICITY:     LD50 (ORAL - RAT) (MG/KG)     - 5045
              LD50 (IPR - MOUSE)  (MG/KG)    - 933
              LD50 (SKN - RABBIT) (G/KG)     -13
              LD 50 (IV - MOUSE) (MG/KG)     - 1863

 CARCINOGENICITY:    NTP: NO
                    IARC: NO
                    Z LIST: NO
                    OSHA REG:  NO

 EFFECTS OF OVEREXPOSURE:

   • INHALATION OF VAPORS MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS,
    DROWSINESS, IRRITATION OF RESPIRATORY TRACT, AND LOSS OF CONSCIOUSNESS.
   • INHALATION OF VAPORS MAY CAUSE PULMONARY EDEMA.
   •LIQUID MAY BE IRRITATING TO SKIN AND EYES. PROLONGED SKIN CONTACT MAY RESULT
    IN DERMATITIS. EYE CONTACT MAY RESULT IN TEMPORARY CORNEAL DAMAGE.
   •INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS, GASTROINTESTINAL
    IRRITATION.
   •INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.

 TARGET ORGANS

   EYES, SKIN, RESPIRATORY SYSTEM

 MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

   NONE IDENTIFIED

 ROUTES OF ENTRY

   INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT

 EMERGENCY AND FIRST AID PROCEDURES

   •CALL A PHYSICIAN
   • IF SWALLOWED, DO NOT INDUCE VOMITING
   • IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
    IF BREATHING IS DIFFICULT, GIVE OXYGEN.
   • IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST
    15 MINUTES. FLUSH SKIN WITH WATER.
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                      Exhibit 6. Sample MSDS (continued)

 6 - REACTIVITY DATA

 STABILITY:     STABLE       HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

 CONDITIONS TO AVOID:       HEAT, FLAME, OTHER SOURCES OF IGNITION

 INCOMPATIBLES:            STRONG OXIDIZING AGENTS, ALUMINUM, NITRIC ACID, SULFURIC
                          ACID, AMINES AND AMMONIA, HALOGEN ACIDS AND HALOGEN
                          COMPOUNDS

 DECOMPOSITION PRODUCTS:  CARBON MONOXIDE, CARBON DIOXIDE

 7 - SPILL AND DISPOSAL PROCEDURES

 STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE:

  • WEAR SUITABLE PROTECTIVE CLOTHING
   • SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING, OR FLAMES IN AREA
  • STOP LEAK IF YOU CAN DO SO WITHOUT RISK
  • USE WATER SPRAY TO REDUCE VAPORS
   •TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE
    INTO CONTAINER FOR LATER DISPOSAL
  • FLUSH AREA WITH WATER.

  J.T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED FOR SPILLS OF THIS
  PRODUCT.

 DISPOSAL PROCEDURE:

  DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
  ENVIRONMENTAL REGULATIONS.

 EPA HAZARDOUS WASTE NUMBER:    D001 (IGNITABLE WASTE)

 8 - PROTECTIVE EQUIPMENT

 VENTILATION:

  USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.

 RESPIRATORY PROTECTION:

  RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT
  CONCENTRATIONS UP TO 1000 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC
  VAPOR CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING
  APPARATUS IS RECOMMENDED.

 EYE/SKIN PROTECTION:

  SAFETY GOGGLES, UNIFORM, APRON, AND NEOPRENE GLOVES ARE RECOMMENDED.
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                         Exhibit 6. Sample MSDS (continued)

  9 - STORAGE AND HANDLING PRECAUTIONS

  SAF-T-DATA(TM) STORAGE COLOR CODE:       RED (FLAMMABLE)

  SPECIAL PRECAUTIONS:

    • BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID
    • KEEP CONTAINER TIGHTLY CLOSED
    • STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA.

  10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION

  DOMESTIC (D.O.T.)
  PROPER SHIPPING NAME:
  HAZARD CLASS:
  UN/NA:
  LABELS:

  INTERNATIONAL (I.M.O.)

  PROPER SHIPPING NAME:
  HAZARD CLASS:
  UN/NA:
  LABELS:
ISOPROPANOL
FLAMMABLE LIQUID
UN1219
FLAMMABLE LIQUID
ISOPROPANOL
3.2
UN1219
FLAMMABLE LIQUID
What Is Hazardous Waste?

Generally, waste is defined as:

Any solid, liquid, or contained gaseous materials
that you no longer intend to use and that you
store, dispose or recycle.

A waste is hazardous if it:

• Is listed in the  regulations
• Exhibits hazardous characteristic(s).

Each hazardous waste has a code that you must
use as you document shipment of your waste
off-site.

LISTED WASTE

A waste is considered a listed waste because it
either exhibits one of the characteristics
described below or contains any number of toxic
constituents that have been shown to be harmful
to human health and the environment. Any
nonhazardous  materials  that are
                   contaminated with listed waste are
                   considered listed waste.

                   The types of listed hazardous waste that you
                   may generate include:

                   •  Waste solvents (e.g., toluene, xylene, acetone,
                     and methyl isobutyl ketone), which are
                     classified as "F" wastes
                   •  Unused, discarded or off-specification
                     materials (e.g., unused methanol), which may
                     be classified as "U" wastes.

                   CHARACTERISTIC WASTE

                   A waste is considered characteristic because it
                   exhibits one or more of the four defined
                   hazardous characteristics, as follows:

                   •  Ignitable (D001) - Easily catches fire;
                     flashpoint is below 140° F. (See your MSDS.)
                     Please note that the terms "combustible,"
                     "flammable," and "ignitable" have different
                     definitions under other federal and state
                     regulations, so they cannot be used
                     interchangeably. An example of a D001 waste
                     is isopropyl alcohol.
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•  Corrosive (D002) - Aqueous liquids (liquids
  containing water) that easily corrode materials
  (e.g., metal drums) or human tissue and have
  a pH of less than or equal to 2 or greater than
  or equal to 12.5. An example is waste battery
  acid.

•  Reactive (D003) -- Potentially explosive or
  produces toxic gases when mixed with water,
  air, or other incompatible materials. Printers
  do not normally generate reactive wastes.

•  Toxic (D004-D043) -- If a chemical extract of
  your waste contains specific constituents, such
  as cadmium, chromium, or silver, and exceeds
  specified levels, the waste is hazardous. The
  waste code varies, depending on which
  constituents are present.  Examples include
  plate processing chemicals and waste fixer.

Hazardous waste found in the printing industry is
most likely to be ignitable or toxic.

HAZARDOUS WASTE CODES

Specific hazardous waste types have designated
waste codes. A waste code is a four-digit
classification system used by the U.S.
Environmental Protection Agency (EPA) to
identify hazardous waste on labels, shipping
papers, and other records.  All federal hazardous
waste codes begin with a letter and are followed
by numbers. All listed waste begins  with the
lettered "F," "K," "U," or "P," and all characteristic
waste begins with the letter "D."

In order to determine what the waste code is for
your hazardous waste, you need to look at the
regulations. For the sake of brevity, we have
not included copies of any regulations in this
manual.  You should call your state
environmental agency (see your state summary
page in the pocket at the end of this  manual) to
determine where you can obtain a copy of your
state's regulations. They are typically available
at your State House book store.
5.2   WHAT Is MY HAZARDOUS

       WASTE GENERATOR STATUS?

If you are a lithographic printer and your
operations cause hazardous waste to be
generated, you must now determine your
generator status.

Hazardous waste generators are divided into
different status categories, depending on the
quantity of hazardous waste generated each
month and on the total amount of hazardous
waste stored at the printing facility at any time.
The measured amount (by weight) of hazardous
waste generated at your facility per calendar
month determines which hazardous wastes
requirements and standards apply to you.

Exhibit 7 lists three federal categories of
hazardous waste generators.  This chart is
included to illustrate the federal generation rates
and storage time limits applicable to certain
generator categories. It is important to note
that states may specify different categories
than those specified in the federal
regulations  and that you must meet the
requirements specified for your state! Please
refer to your state's requirements in the
summary pages in the pocket at the end of
this manual.

To determine which category  applies to your
shop, you must count all quantities of hazardous
waste that is:

• Generated and collected at your shop prior to
  treatment or disposal
• Packaged  and transported off-site.

From Exhibit 7, you can see that it pays to be in
one of the small quantity generator categories.
There is more leeway for storage time, which will
allow you to  more cost-effectively manage your
smaller quantities of hazardous waste. Pollution
prevention can help you change your generator
status.  Section 5.5 presents pollution prevention
techniques that may work at your shop.
 How Do I Comply With Hazardous Waste Regulations!
                                         37

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                                                                             Fit to Print
Your Generator Status

Now that you have accounted for all the
hazardous waste that your print shop generates
and you have consulted your state's regulations,
you can determine your generator status.

/ My generator status is:	
Note: Because it is possible for your
generator status to change from year to year,
and even from month to month, it is very
important to keep an accurate accounting of
how much waste you have on-site at any
particular time.
Exhibit 7. Federal Categories of Hazardous Waste Generators and
Storage Time Limits Allowed
Generator Category
Conditionally Exempt
Small Quantity Generator
(CESQG)
Small Quantity Generator
(SQG)
Large Quantity Generator
(LQG)
Monthly Hazardous Waste
Generation Rate
< 220 pounds (100 kg),
< 2.2 pounds (1 kg) acute, or
< 220 pounds spill residue from
acute
> 220 pounds (100 kg) and <
2,200
pounds (1,000 kg) or
< 2.2 pounds (1 kg) acute
> 2,200 pounds (1,000 kg) or
> 2.2 pounds (1 kg) acute
Storage Time Limits
No Limit
<1 80 days or < 270 days if
waste
treatment/disposal facility is
>200
miles away
< 90 days
5.3    WHAT REQUIREMENTS MUST

       HAZARDOUS WASTE

       GENERATORS MEET?

Hazardous waste generators must comply with
eight major requirements:

• Waste identification
• EPA identification number
• Container management
• Personnel training
• Hazardous waste shipment labeling and
  placarding
• Reporting and recordkeeping requirements
• Contingency planning
• Emergency procedures and accident
  prevention.
Each requirement is explained below.  Please
ensure that you have met each requirement and
refer to your state's requirements, presented in
the pocket at the end of this manual.
1.  Waste Identification

As a generator, you must determine whether
your waste is hazardous. As explained in
Section 5.1, the MSDS for each chemical may
help you with this determination. The MSDS will
identify specific chemical properties of a
material, such as whether a material is highly
acidic or basic, whether solvents are present,
and other chemical properties, such as
ignitability (flashpoint).

/  Make a list of all the hazardous waste you
   have at your shop and determine the waste
   code for each.
How Do I Comply With Hazardous Waste Regulations!
                                       38

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/  You may know that a waste is hazardous
   because of information on a MSDS.

/  If you are not sure, you will need help. This
   may mean calling EPA or your state, a
   consultant, or a licensed transporter.  Or, you
   may need to send a sample  of your waste to a
   laboratory for them to determine if the waste is
   hazardous.
2. EPA Identification Number

If your lithographic printing facility generates
more than 100 kg (about 220 pounds or 25
gallons) of hazardous waste in any calendar
month, you must obtain an EPA identification
number. These 12-character identification
numbers are part of a national database on
hazardous waste activities. Some states also
require conditionally exempt or very small
quantity generators to have identification
numbers.  Furthermore, companies that
transport hazardous waste and facilities that
store, treat, or dispose of regulated quantities of
hazardous waste generated by lithographic
printing shops must also have  EPA identification
numbers.

How to Obtain an EPA Identification Number

/ Call or write your state hazardous waste
   management agency or EPA regional office
   and ask for a copy of EPA Form 8700-12,
   "Notification of Regulated Waste Activity."
   You will be sent a booklet containing the two-
   page form and instructions for filling it out.
   Note that a few states use a form that is
   different from the EPA form. If you contact
   your state first, you will be sent the
   appropriate form to complete.

/ Complete one copy of the form for each of
   your printing shops where you generate or
   handle hazardous waste. There is no fee
   associated with filling out this form.  Each site
   or  location will receive its own unique EPA
   identification number. You must use this
   identification number on all hazardous
   waste shipping forms.

An EPA identification number is a unique
number that applies to a particular physical
printing facility site or location. If you move
your printing facility to another location, you
must notify EPA or the state of the new
location, submit a new form, and obtain a
new EPA identification number. If hazardous
waste was previously handled at the new
location and the new location already has an
EPA identification number, that number will be
reassigned to your relocated printing facility.
3. Container Management

The following list summarizes the most
significant requirements for managing containers
of hazardous waste, regardless of their size:

/ Set aside and mark a storage area for your
   hazardous waste.  This is your designated
   on-site hazardous  waste storage area, and
   it is a collection area for your entire shop.
   The length of time  that you can store
   hazardous waste in this area depends on
   your generator category. The type of area
   and marking requirements are set by your
   state. (Please refer to your state's
   requirements provided in the pocket at the
   end of this manual.)

S Label and mark all containers of hazardous
   waste in your hazardous waste storage area.
   Clearly mark each container with the words
   "HAZARDOUS WASTE" and with the date
   the waste was first collected in that
   container. (Labels for this purpose may be
   available from the  waste hauler or  a trade
   association.) When your waste is shipped
   off-site, it is important that your transporter is
   aware of and complies with Department of
   Transportation marking  requirements for the
   truck used to haul  your waste. Further, many
   states require additional labeling, such as a
   description of the contents of the container.
   (Please refer to your state's requirements
   provided in the pocket at the end of this
   manual.)

/ You can accumulate up to 55 gallons of
   hazardous waste in properly labeled
   containers or drums  at or near the various
   parts of your shop  where the waste is
   generated. This is called satellite
   accumulation. Once 55 gallons have
   accumulated, satellite waste must  be moved
   to your designated on-site hazardous waste
   storage area prior  to shipment off-site.
How Do I Comply With Hazardous Waste Regulations'^
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/  Containers in satellite accumulation areas
   must be clearly marked with the words
   "HAZARDOUS WASTE" or with other
   wording that identifies the contents of the
   container.  Satellite waste must be moved
   within 3 days to your shop's designated on-
   Site hazardous waste storage area. The
   operator of the process that generated the
   waste is responsible for this container or
   drum as long as it is kept separate from the
   designated storage area; this operator must
   control  the waste accumulated there.

/  Mark the EPA waste code on the drum.
   Although federal regulations do not require
   marking the EPA waste code on the drum,

   most states do require marking, and it is
   highly recommended.

/  Keep containers in good condition, handle
   them carefully, and replace any leaking ones.
   If a container is in poor condition, the waste
   must be transferred to a container in good
   condition.

/  Use containers made of, or lined with,
   materials that will not react with the waste.
   Do not  store hazardous waste in a container
   if it may cause rupture, leaks,  corrosion, or
   other failure. For instance, store your fixer in
   plastic drums and your flammable liquids,
   such as solvents, in metal drums.


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4.  Personnel Training

S  If you are an LOG or an SQG of hazardous
   waste, you must train your employees on the
   procedures for properly handling hazardous
   waste, as well as on emergency procedures.
   For LQGs, the training must be formalized
   and be completed by employees within 6
   months of accepting a job involving the
   handling of hazardous waste, and you are
   required to provide annual reviews of the
   initial training.

   CESQGs or VSQGs are not required by
   federal laws to train their employees on waste
   handling or emergency preparedness, but it is
   strongly advised!

Proper waste handling can save your shop
money in waste treatment and disposal and in
lost time due to employee illness or accidents.
For information on employee training, please
contact the federal or state agencies listed in
Chapter 9 and in the pocket at the end of this
manual. It is important to note that training you
may be required to conduct by OSHA (the
Occupational Safety and Health Administration)
differs from hazardous waste management
training. Make sure you provide both types of
training to your employees.
5. Hazardous Waste Shipment Labeling and
   Placarding

When you prepare hazardous waste for
shipment, you must put the waste in properly
labeled containers that are appropriate for
transportation according to Department of
Transportation (DOT) regulations (see Chapter
9). Your transporter should be able to assist you.

If you are an SQG or LOG, you must:

/ Write the manifest document number on the
   drum label.  A blank space intended for this
   purpose is provided on hazardous waste
   labels available from label distributors.

/ Label  all drums using the 4-inch DOT warning
   labels (available from the waste hauler or a
   label distributor), which are marked with the
   proper DOT shipping name and number
   according to DOT requirements.  Usually your
   hauler will do this.
If you need additional information, you may want
to consult the requirements for packaging and
labeling hazardous wastes contained in the DOT
regulations.  To find out what the requirements
are for your specific waste, you should contact
your state transportation agency. Your state
transportation agency, your hauler, or your waste
disposal/treatment facility can help you
understand the DOT requirements.  It may be
helpful for you to create a shipping manual with
guidance for packing, shipping, and
disposal/recycling of all wastes leaving your
facility.
6. Reporting and Recordkeeping
   Requirements

Your printing facility is required to meet various
reporting and recordkeeping requirements as
part of your hazardous waste management
obligations. These requirements are
summarized below:

Uniform Hazardous Waste Manifest. The
Uniform Hazardous Waste Manifest Form (EPA
Form 8700-22) is a multi-copy shipping
document that reports the contents of the
shipment, the transport company used, and the
treatment/disposal facility receiving the wastes.
(Exhibit 8 provides a sample manifest.)

The manifest form is designed so that shipments
of hazardous waste can be tracked from the site
of generation to the final destination (i.e., from
"cradle-to-grave"). The hazardous waste
generator, the transporter, and the
treatment/disposal facility must each sign this
document and keep a copy. The waste
treatment/disposal facility also must send a copy
back to  you, so that you can be sure that your
shipment was received.

It is important that you receive a signed copy of
the manifest from the company that takes your
waste. This is your proof that the waste made it
to the final destination. If you do not receive a
signed copy of the manifest within a reasonable
period of time, you may need to file an exception
report with EPA and state environmental
agencies. (This is a situation you may never
encounter.  If you do, please contact EPA and
your state environmental agency for further
information.)  The signed copy of the  manifest is
required to be kept on file for 3 years.
How Do I Comply With Hazardous Waste Regulations'?
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You can obtain blank copies of the manifest form
from several sources.  To determine the best
source for you, use this system:

• If the state to which you are shipping your
  waste has its own manifest, use that manifest
  form (your waste transporter will know which
  manifest form is required). Contact the
  hazardous waste management agency of that
  state, your transporter, or the waste
  treatment/disposal facility to obtain manifest
  forms.

• If the state to which you are shipping your
  waste does not have its own manifest, use
  the manifest of the state in which your waste
  was generated.  Contact your transporter or
  your state hazardous waste agency for blank
  forms.

• If neither state requires a state-specific
  manifest, you may use the "general" Uniform
  Hazardous Waste Manifest (EPA Form 8700-
  22). Copies are available from some  haulers
  and waste treatment/disposal facilities, or they
  may be purchased from some commercial
  printers.

When you sign the certification on Item  16  of the
manifest form (see Exhibit 8, presented
previously), you are personally confirming that:

• The manifest is complete and accurately
  describes the shipment.
• The shipment is ready for transport.
• You have reduced the amount and hazardous
  nature of your waste to the greatest extent
  possible (within your budget constraints).

Transporters, recyclers, and waste
treatment/disposal facilities may require
additional  information. Check with them before
you prepare a hazardous waste shipment.  The
states may also have additional requirements
that must be followed.  Your hazardous waste
hauler often will be the best source for
packaging and shipping information and will help
in completing the manifest. If you have any
trouble filling out or using the manifest, ask your
waste transporter, your waste disposal/treatment
facility operator, or the appropriate contact  listed
in your state summary page provided in the
pocket at the end of this manual.
Biennial Reports.  If you are an LOG of
hazardous waste, you must submit a biennial
report (EPA Form 8700-13A) on March  1 of each
even-numbered year to the appropriate state
regulatory office. Some states impose this
requirement on SQGs.

Biennial Report applications and instructions can
be obtained from your state office (see your
state summary page in the pocket at the end of
this manual).  Copies of biennial reports must be
maintained at your shop for 3 years.

Land Disposal Restriction Notification.  Land
disposal restrictions are regulations prohibiting
the disposal of hazardous waste on land without
prior treatment of the waste.  With every
shipment of your waste off-site, you will need to
provide a notification that specifies which of the
waste you have generated is restricted from land
disposal. This notification should be attached to
your hazardous waste manifest. This form
ensures proper treatment of the waste prior to
disposal; copies of each form must be kept for 5
years.

If you plan to ship wastes off-site for recycling,
then you may not need a Land Disposal
Restriction Notification form for every shipment.
For SQGs, a "tolling agreement" can be
developed for shipments after the initial
shipment. Please contact your state for more
information on these agreements and the land
disposal restrictions.
How Do I Comply With Hazardous Waste Regulations^.
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                                                  Exhibit 8. Sample  Manifest
Please print or type.    (Form designed for use on elite (12-pitch) typewriter.)
                                                                                                   Form Approved. OMB No. 2050-0039. Expires 9-30-88
        UNIFORM HAZARDOUS
           WASTE MANIFEST
1 . Generator's US EPA ID No

 I   I   I   I   !
        Manifest
      Document No
I
                                                                                                   2  Page 1
                     Informal on  in  the  shaded  areas
                     is  not  required  by  Federal
                     law.
    3.  Generator s Name and Mailing  Address
    4   Generator's Phone (          )
                                                                                                   A. State Manifest  Document Number
                                                                                                   B. State Generator's ID
    5.  Transporter  1  Company Name
                                                                          US EPA ID Number
                                                                                                   C. State Transporter s ID
                                                                          US EPA ID Numbei
                                                                                                   D. Transporter's  Phone
                                                                                                   E. State Transporter's ID
    7.  Transporter  2 Company Name
                                                                                                   F. Transporter's  Phone
    9.  Designated  Facility  Name  and Site Address
                                                              10!
                                                                          US EPA ID Number
                                                                                                   G. State Facility's  ID
                                                                                                   H. Facility's Phone
    1 1 . US DOT Description (Including Proper Shipping Name, Hazard Class, and ID Number}
1 2. Containers

 No.     Type
                                                               13.
                                                               Total
                                                             Quantity
                                           14.
                                          Unit
                                         Wt/Vo
                                                                                                                                   Waste No.
    J.   Additional  Descriptions for  Materials  Listed  Above
                                                                                                   K. Handling Codes for Wastes Listed Above
    15. Special Handling  Instructions and Additional  Information
    16. GENERATOR'S CERTIFICATION: t hereby declare that the contents of th s consignment are fully and accurately described above by
        proper shipping name and are classified, packed, marked, and labeled, and are in all respects in proper condition for transport by highway
        according to applicable international and national government regulations.

        If I am a large quantity generator, I certify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determined to be
        economically practicable and that I have selected the practicable method of treatment, storage, or disposal currently available to me which minim zes the present and
        future threat to human health and the environment; OR, if I am a small quantity generator, I have made a good fa th effort to minimize my waste generation and select
        the best waste management method that is available to me and that I can afford.
        Printed/Typed Name
                                                                     S gnature
                                                                                                                               Month  Day   Year
      1 7. Transporter  1  Acknowledgement  of  Receipt  of  Materials
        Printed/Typed Name
                                                                     Signature
                                                                                                                               Month  Day   Year

                                                                                                                              III      I
      1 8. Transporter 2 Acknowledgement  of  Receipt of  Materials
        Printed/Typed Name
                                                                     Signature
                                                                                                                               Month  Day   Year
      1 9. Discrepancy Indication Space
     20 Facility Owner or  Operator  Certification of  receipt of hazardous materials covered  by  this  manifest except  as  noted in Item 19.
        Printed/Typed Name
                                                                     S gnature
                                                                                                                               Month  Day   Year

                                                                                                                              I  I   I  I    I  '
 EPA Form 8700-22 (Rev. 9-86) Previous editions are obsolete.
     How Do  I  Comply  With Hazardous  Waste Regulations!
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                                                                 Fit to Print
Exhibit 8. Example Manifest (continued)
Please print or type. (Form designed for use on e ite (12-pitch} typewriter.) Form Approved OMB No 20500039 Expires 9-30-9'
1
G
N
E
R
A
T
0
R
T
R
A
N
S
P
0
R
T
£
R
F
A
C
1
L
1
T
Y
UNIFORM HAZARDOUS 21. Generator's US EPA ID No Manifest
WASTE MANIFEST Document No
(Continuation Sheet)
23. Generator's Name
24. Transporter Company Name 25 US EPA ID Number
1
26 Transporter Company Name 27. US EPA ID Number
1
28. US DOT Description (Including Proper Shipping Name. Hazard Class, and ID Number}
a.
b.
c
d.
e.
i
g
h.
i.


29 Conta
No.









S. Additional Descriptions for Materials Listed Above
22 Page Informa on in the shaded
areas is not required by Federal
law
L. State Manifest Document Number
M. Stale Generator's (D
N. State Transporter's 10
O. Transporter's Phone
P. State Transporter's !D
Q. Transporter's Phone
ners
Type









30
Total
Quantity









31
Unit
Wt/Vo









R
Waste No.









T. Handling Codes far Wastes Listed Above
32. Special Handling Instructions and Additional Information
33. Transporter Acknowledgement of Receipt of Materials
Printed/Typed Name Signature
34. Transporter Acknowledgement of Receipt of Materials
Printed/Typed Name Signature
Date
Month Day Year
I I
Date
Month Day Yaai
I I
35. Discrepancy Indication Space
-PA Form 8700-22A (Rev. 9-88) Previous edition is obsolete
How Do I Comply With Hazardous Waste Regulations!
44

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                                                                              Fit to Print
Summary of Recordkeeping Requirements

EPA requires that certain records be kept on file
at your shop for 3 years.  These records are
listed below.  Included is a note where the
requirements apply to LQGs, SQGs, or both.

/  Laboratory analyses or waste profile sheets
   for determining whether wastes generated by
   your shop are hazardous [LOG, SQG]

/  Copies of all hazardous waste manifests, land
   disposal restriction notifications, and
   exception reports [LQG, SQG]
/  Copies of all Notification of Hazardous Activity
   Forms submitted to and  received from the
   state or EPA [LQG, SQG]

/  Copies of personnel training plans and
   documentation that indicates employees have
   completed the required training [LQG]

/  Copies of your shop's contingency plan [LQG]

/  Copies of your biennial report [LQG].

It is a good idea to have these documents filed
neatly in one place at your shop. State or federal
inspectors will likely ask for copies of these
documents while inspecting your shop.


7.  Contingency Planning

A contingency plan will help you look ahead and
prepare for accidents involving hazardous waste
that could possibly occur at your shop. If you are
an LQG of hazardous waste, you are required to
have a written contingency plan. If you are an
SQG of hazardous waste, you must have basic
contingency procedures in place.  Exhibit 9
presents the contingency requirements for LQGs
and SQGs.  Although a written contingency plan
is not federally required for SQGs or
conditionally exempt SQGs, it is strongly
recommended. It is also important to check with
your state and local authorities for any additional
contingency planning or emergency
preparedness requirements.
8.  Emergency Procedures and Accident
   Prevention

Emergency Procedures. Your contingency
plan, discussed in the previous section, must
contain facility-specific details on what you have
to do if you have an emergency.  Specifically:

/  In the event of a fire, explosion, or
   accidental release of hazardous waste, you
   must notify immediately the National
   Response Center if the fire, explosion, or
   other release could threaten human health
   outside your print shop or when the release
   has reached surface water. The Center
   operates a 24-hour toll free number:
   1-800-424-8802. As soon as possible, have
   the hazardous waste and any contaminated
   materials or soils cleaned up by an
   appropriately trained person.
   ANYONE WHO IS REQUIRED TO
   CALL THE NATIONAL RESPONSE
   CENTER AND DOES NOT IS
   SUBJECT TO A $10,000 FINE, A
   YEAR IN JAIL, OR BOTH.  If you are
   an owner or manager of a print shop
   and you fail to report a release, you
   may have to pay for the entire cost of
   repairing any damage, even if your
   shop was not the single or main cause
   of the damage.
As stated above, the RCRA regulations require
that emergency telephone numbers and
locations of emergency equipment be posted
near telephones. This means that next to the
telephone you must post:

/ The name, office phone number, home phone
   number, and address of your emergency
   coordinator.

/ A site plan or list of nearby:

   -  Portable fire extinguishers
   - Special extinguishing equipment (e.g., foam,
    dry chemicals)
   - Fire alarms (only if not directly connected to
    fire department)
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   - Spill control equipment (e.g., absorbent
    cotton rags)
   - Decontamination equipment (e.g., safety
    shower, eye wash fountain)
   - Water at adequate volume and pressure
    (e.g., water hoses, automatic sprinklers,
    water spray systems).

/ The telephone numbers of the fire and police
   departments.
  / Although not required, it is strongly
    recommended that you also post the
    following phone numbers by the telephone:

    - State or local emergency response teams
    - Hospital
    - Local ambulance service
    - National Response Center
    - State Department of Public Safety

  All employees who deal with hazardous waste
  must know proper waste handling and
  emergency procedures. You must appoint
  yourself or an employee to act as the emergency
  coordinator to ensure that emergency
  procedures are carried out in the event of an
  emergency.
              Exhibit 9.  Contingency Requirements for LQGs and SQGs
         LOG Contingency Plan Contents
       SQG Contingency Procedures
   Written plan required.

   The contingency plan must contain:

   •  Instructions on what to do immediately
     whenever there is a fire, explosion, or release

   •  The arrangements agreed to with local police
     and fire departments, hospitals, and state and
     local emergency response teams to provide
     emergency services

   •  The names, addresses, and telephone
     numbers of all persons qualified to act as
     emergency coordinators

   •  All emergency equipment at the shop

   •  An evacuation plan.

   Copies of the contingency plan must be
   submitted to the local police and fire
   departments, hospitals, and state and local
   emergency response teams that may be called
   upon to provide emergency services. You
   should maintain documentation showing that
   local authorities have been notified.
Basic plan required (not required to be written).

The contingency procedures include the
following:

•  You must have an emergency coordinator (an
  employee) either at the shop or on-call who is
  responsible for coordinating all emergency
  response measures.

•  You must post next to the telephone 1) the
  name and telephone number of your
  emergency coordinator, 2) the locations of the
  fire extinguishers and spill control material, and
  3) the telephone number of the fire department.

•  You must ensure that all employees who
  handle hazardous waste are thoroughly familiar
  with proper waste handling and emergency
  procedures.
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The emergency coordinator (or someone
designated by that person) must:

• Be available 24 hours a day either at the
  facility or by phone
• Know whom to call and what steps to follow in
  an emergency
• Commit company resources as necessary to
  respond to an emergency.

Because most printers are small businesses, the
owner or operator probably already performs
these functions. Therefore, it is not  intended
(nor is it likely) that you will need to hire a new
employee to fill this role.

Accident Prevention. Your shop should have
appropriate cleanup materials and emergency
communication equipment for handling
hazardous waste at your site. Some of the steps
you should take to prepare for emergencies at
your shop include the following:

/ Make sure that there  are no  floor drains near
   the area where chemicals are used that lead
   to the sewer, septic tank, or storm water
   drain.

/ Have absorbent cotton blankets or other
   absorbent materials in the area where
   hazardous materials are used or stored and
   keep them in a container marked "spill
   cleanup absorbent blankets/materials."  If a
   spill occurs, use the cotton blankets or other
   absorbent materials to absorb the spill.
/  Store hazardous waste in areas away from
   doorways.  The floor in your storage area
   should be leak-proof (e.g., concrete with an
   epoxy coating). If a doorway is nearby, a
   concrete barrier is required to prevent the
   flow of material out of the door in case of a
   large spill.

/  Provide room for emergency equipment and
   response teams to get into  any area in your
   shop in the event of an emergency.

/  If you are an LOG, you must write to local
   fire, police, and hospital officials or state or
   local emergency response teams explaining
   that you handle hazardous waste.

/  You must install and maintain emergency
   equipment (e.g., an alarm, a telephone, two-
   way portable radios, fire extinguishers, hoses,
   and automatic sprinklers) at your shop in
   hazardous waste storage areas for
   flammable and combustible liquids storage,
   so that it is immediately available to your
   employees if there is an emergency. This
   equipment must be inspected monthly.
5.4   GOOD ENVIRONMENTAL MANAGEMENT PRACTICES


How to Select a Hazardous Waste Transporter and Waste Disposal/Treatment Facility

You should choose a transporter and waste disposal/treatment facility carefully.  Even when the waste
leaves your control, your print shop remains legally responsible for the proper disposal of your waste
and any associated spills or accidents.

Before choosing a transporter or designating a facility,  check with the following sources:

       • Your state hazardous waste management agency or EPA regional office, which will be able to
         tell you whether a company has an EPA/state identification number and may know
         whether a company has had any problems.  They may also have a list of licensed
         (approved) transporters.
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        •  Your friends and colleagues in the printing business who may have used a specific hazardous
          waste transporter or disposal/treatment facility in the past.

        •  Your trade association(s), which may keep a file on companies that handle hazardous waste.

        •  Your Better Business Bureau or Chamber of Commerce to find out if any complaints have been
          registered against a transporter or facility.

After checking with these sources, contact the transporter and hazardous waste disposal/ treatment facility
directly to verify that they have an EPA/state identification number and that they can and will handle your
waste. In some states, the transporter and the designated facility may be required to have a special
permit to operate. Make sure that the transporter and waste disposal/treatment facility have the
necessary permits and insurance and that the transporter's vehicles are in good condition. You may also
want to ask them:

        •  Where the waste is going
        •  To provide information on their track record
        •  If they  have ever been cited for improper practices.

Checking sources and choosing a transporter and waste disposal/treatment facility may take some time.
You should begin checking before you open your shop or well ahead of the time you will need to ship your
waste.

Disposing of Hazardous Waste On-Site

You may not dispose of your hazardous waste on your property.

Manage Shop Towels Responsibly

Every printer uses shop towels of one sort or another. When shop towels are used to clean presses, they
become contaminated with residual ink, blanket wash, and solvents. Used shop towels can pose a threat
to human health and the environment if they are improperly managed, both in the shop and after they are
sent off for disposal or laundering. Here are some guidelines that you should follow to ensure that you are
handling, storing, and disposing of your shop towels in an environmentally responsible manner:

       1. DO NOT THROW SHOP TOWELS INTO THE TRASH.

       2. Check with  your state environmental agency to determine how towels contaminated with
          solvents and other hazardous waste are handled in your state. Each state in New England has
          different requirements; you should identify your state's requirements before you take any
          steps.

       3. Follow these best management practices for handling your shop towels in the shop before they
          are sent away for disposal or laundering:
           • Do not pour solvents on shop towels as a disposal method.

           •Collect and store shop towels in closed metal containers. Air
            drying contaminated shop towels may pose fire and health
            hazards, as well as violate hazardous waste, fire, and air
            regulations.
  PLEASE
PLACE USED
  TOWELS
     IN
CONTAINERS
 PROVIDED
           • Keep shop towel containers in a ventilated area away from other flammable materials and
            ignition sources. Do not store used shop towels on your dryer or electrical panel.
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           • Keep used shop towels away from corrosives, including haze removers, and oxidizers, such
            as stencil and emulsion removers that contain up to 100-percent sodium metaperiodate
            crystals. These substances react chemically with contaminated shop towels and can start a
            fire.

       4.  Determine which of the following management options for your shop towels are permissible
          with your state environmental agency:

           •Centrifuge  or hand/mechanically wring solvents from rented or leased shop towels, collect
            the solvents, and then manage the towels using one of the methods listed below. By
            centrifuging or wringing the solvent off the towels, the solvent can be reused in-house and/or
            reclaimed.

           •Send rented or leased solvent-contaminated shop towels to a permitted industrial laundry or
            dry cleaning facility. Industrial laundry services are available that will provide you with clean
            shop towels and launder your soiled towels.  The laundry must have the approval of its
            sewer utility to launder the shop towels. By using this method, you can eliminate the
            disposal of used shop towels as solid waste and the need for purchasing new towels.

           •Send disposable solvent-contaminated shop towels to  a permitted hazardous waste disposal
            facility, using a licensed hazardous waste transporter.

           • If permissible by your state agency,  manage towels as an industrial solid waste.

           • Send towels to an incinerator to burn for energy recovery.

Good Housekeeping

Good waste management can be thought of as simply good housekeeping practices which include:

       • Using fewer hazardous materials                        ?;
       • Reusing materials  as much as possible
       • Recycling and reclaiming waste
       • Reducing the  amount of waste you generate.

To reduce the amount of waste you generate:

       • Do not mix nonhazardous wastes with hazardous waste (e.g.,  combining nonhazardous
         cleaning agents or rags in the same container as hazardous wastes).  If you do, the
         nonhazardous waste may become subject to hazardous waste regulations and you will have
         more hazardous waste for disposal.

       • Avoid mixing different hazardous waste together, unless your waste disposal facility instructs
         you otherwise. Doing so may make recycling very difficult, if not impossible.  It may also make
         disposal more expensive.

       • Avoid spills or leaks of hazardous products. The materials used to clean up such spills or leaks
         may also become hazardous wastes.

       • Make sure the original containers of hazardous products are completely empty before you throw
         them away. Use ALL of the product - it is good business sense. For information on how to deal
         with your empty containers that once held hazardous waste refer to Section 5.3.
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       • Avoid using more of a hazardous product than you need.  For example, use no more cleaning
         solvent than you need to do the job.

       • If you drain or wring excess solvent from shop towels, reuse it for low-quality cleaning or capture
         it for proper disposal.

Reducing your hazardous waste means saving money on raw materials and reducing the costs to your
business for managing and disposing of your hazardous wastes.



5.5   POLLUTION PREVENTION OPPORTUNITIES FOR HAZARDOUS WASTES

This section describes pollution prevention (P2) opportunities that pertain to hazardous waste.
Information on whether the technique is easy or more difficult to use is included next to each listing,
followed by a description of the technique and information on its benefits.  Each discussion provides
information on the relative cost of the technique and the waste streams it can reduce, where possible.
For more information, please contact the individuals listed in Chapter 9.


Ink Inventory Control                                                               Easy

Technique:     This pollution prevention technique will reduce ink waste generated from color changes,
               press cleaning, and  poor ink management. Good operating practices focus on smart raw
               material management.

               Good operating practices and process changes to reduce waste ink include the following:

                      Use a standard ink sequence for process colors; schedule runs from lighter to
                      darker colors to decrease the need to change inks and the amount of cleaning
                      necessary.

                      Scrape as much ink as possible from the containers when disposing  of or
                      recycling ink containers.

                      Use first in first out: put new stock on shelves behind older stock.

                      Monitor ink inventory closely to assure that inks are used before their expiration
                      dates. Return unused excess inks to the manufacturer if you can.

                      Keep ink containers sealed and the contents labeled for future use. Plastic or
                      waxed paper can be placed on top of the ink to prevent oxidation (skinning).

                      Counsel customers about the environmental impacts associated with particular
                      colors, paper, or printing  method choices.

                      Ensure that  your printing  jobs represent the actual cost of
                      conducting business and disposing of hazardous waste.
                      Factor waste disposal costs into the price of your products,
                      and let the market do the rest.

                      Improve your accuracy in job estimation. Keep track of ink
                     waste generation by job,  press, and operator.
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Benefits:

Costs:
       Consult with your supplier or use a computer mixing program with a digital scale
       for mixing colors. A digital scale should also be used when measuring ink to
       improve accuracy.  You can also use software to remix and custom-formulate
       PMS colors.

       Decreases the amount of waste ink generated.

       Process changes generally require some equipment purchases and employee
       training.
Material Handling and Storage
                                                                          Easy
Technique:
This pollution prevention technique can easily be implemented at your printing shop to
avoid disposing of unused or damaged materials. The material handling and storage
activities that can be implemented as part of this technique include the following:

• Material pre-inspection
• Ordering of materials
• Proper storage
• Inventory control (first in, first out)
• Expired  materials.

Material Preinspection -- You should always inspect new materials carefully before
accepting  them. Unacceptable, damaged, or nearly expired materials should be returned
to the supplier.

Ordering  of Materials -- Minimize wastes by ordering quantities of materials that match
your needs.  When ordering input materials, such as film and photoprocessing chemicals,
avoid overstocking by ordering according to usage demands. A good unit price is
meaningless if the material goes bad on your shelf and you then have to dispose of it as
hazardous waste.

Buy the largest container that allows you to use all the contents before they go bad. This
minimizes solid waste from packaging.

If you operate a large printing shop, it may be appropriate to purchase raw materials in
large containers, preferably in returnable or refillable totes, which will eliminate or reduce
the need to clean them. If you do need to clean them, large containers take less time to
clean than several small ones. And there is less waste packaging produced by one 55-
gallon drum  than from  ten 5-gallon drums.

Proper Storage -- Chemicals that are sensitive to light and temperature should be stored
according to manufacturer's directions to prevent damage to the materials. Chemical
container labels generally list recommended storage conditions.

Paper waste can be minimized through proper handling and storage of rolls or packages
of paper.  Paper can easily absorb moisture; therefore, storing paper in an area with
controlled temperature and humidity is important.  Ideally, sheet-fed paper should be
conditioned to the  temperature and humidity of the press room for 1  day before printing.
Storage areas should be kept free of dust or other contaminants that could damage raw
materials. These areas should not be open to traffic, which increases dust and dirt.
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 Benefits:
Inventory Control - Chemical container labels list the shelf life for the material.  You
should follow these dates and keep inventories using first-in, first-out practices, which will
help you reduce the amount of materials with expired shelf lives. Also, control access to
materials that will become hazardous waste when spent by using a locked cabinet; these
materials should not be used when a nonhazardous substitute would work as well.

Expired Materials - Because expiration dates are estimated, you should perform small-
scale tests on outdated materials prior to return or disposal to determine if they are still
effective. The material may be usable, rather than becoming an expensive hazardous
waste.

        Cost savings from the decreased amount of raw materials discarded due to
        damage or expiration.
        Less solid waste from packaging, meaning lower trash disposal costs.
Improve Press Cleaning Practices
                                                                           Easy
 Technique:     This simple pollution prevention method includes reducing the amount of solvent applied
               to shop towels and the number of shop towels used to clean printing presses. Dedicating
               presses to specific colors or special inks will also decrease the number of cleanings
               required for each press.  Ink fountains should be cleaned only when a different color of
               ink is used or when the ink might dry out between  runs. Aerosol sprays are available that
               can be applied to the ink fountains to prevent drying overnight. This means that ink can
               be left in the fountain without cleaning at the end of the day.

 Benefits:       •      It reduces the amount of waste ink produced and the amount of cleaning solvent
                      and shop towels used.
                      Less labor is required to apply the spray to the ink fountains than is needed to
                      drain and clean the fountains and dispose of the waste ink.
Recycle Used Ink
                                                                           Easy
Technique:     Waste inks can be recycled on-site or through an ink recycling service. Off-site recycling,
               either by ink manufacturers or by larger printers, may be more economical for smaller
               printers. The waste ink can be reformulated into black ink and sold back to the printer.
               Whenever possible, you should manage excess ink as if it were a manufacturing
               byproduct that will be  reintroduced back into the printing process.

               If you recycle ink at your shop, separate waste ink colors and recycle lighter
               colors into darker (usually black) or specialty colors. Also, store different types
               of ink separately. Clearly mark the containers used to collect waste ink and
               prevent contamination with solvents and trash.

               Inks can also be sent  to a fuel blending service, where they are combined with other
               liquids and burned in industrial boilers or kilns. The advantage of this form of disposal is
               that it reduces the printer's exposure to litigation and cleanup costs from improperly
               landfilled inks.

Benefits:       •       This technique eliminates waste ink disposal costs.
                      It optimizes cost of purchased ink.
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Aqueous Platemaking                                                              Easy

Technique:    Aqueous platemaking processes use presensitized plates that do not require the use of
              toxic developers. Plate quality is as good as that achieved with traditional platemakers.
              Aqueous chemicals must be very clean to maintain plate quality.  You should always
              purchase the presensitized plates and aqueous developers from the same manufacturer.

Benefits:      •       It reduces pollutants in wastewater.
                      This technique will eliminate hazardous plate developer waste from your printing
                      operation. By eliminating hazardous materials used in the platemaking process,
                      you will reduce employee exposure to toxic chemicals, which increases their
                      safety.
                      If you use platemaking equipment designed to use solvent-based developers, it
                      can also accommodate aqueous chemicals and processes.

Costs:        •       A new aqueous platemaker costs from $20,000 to $30,000.
                      Aqueous chemical  life is 15 to 20 percent shorter, and chemical changeouts must
                      be  performed more frequently than with the solvent-based chemicals. Therefore,
                      chemical usage is higher.
                      Aqueous chemical costs will be less than the costs of solvent-based chemicals
                      because you use less of just one chemistry. You will also realize cost savings
                      because you will no longer be disposing of the plate- developing chemicals as
                      hazardous waste (an approximate minimum cost of $3.60 per gallon).


Automated Press Adjustments for Makeready                         Easy/Moderate

Technique:    Numerous  devices have been developed to automate press adjustments to speed up the
              makeready process. They  include:

              Web Break Detectors and Web Splicers -- A web break detector can be installed to
              detect tears in the web as it passes through a high-speed web press.  If a tear occurs, the
              detector automatically shuts down the press.  Electronic systems are available that detect
              web breaks without coming into contact with the rollers.

              Splices can be made while the paper is running at operating speed or while the paper is
              stationary.

              Automated Plate Benders - These devices were designed to prevent problems that
              occur when fitting a plate to a cylinder (e.g., plate cracking, unaligned plate bending along
              the length of the bend, and curvature of the plate  varying from that of the cylinder).

              Automated Plate Scanners -- These devices were developed for lithographic web and
              sheet-fed offset presses using microprocessor technology.  By scanning plates to
              determine the relative density of the printing image, ink fountain  keys can be pre-set to
              compensate for variations in image density.

               Automated Ink Key Setting System - Automated ink key setting is accomplished
              through scanning to determine ink density.  Ink density information is transmitted to a
               computer controlled inking system so that automatic ink adjustments are made to the ink
               profile for each ink slide position.

               Automated Registration Systems -- These devices are optical scanners and
               microprocessors used to search for registration marks.
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               Ink/Water Sensors -- These devices are used to ensure that the proper ink/water ratio is
               being used to produce a sharp dot and strong contrast without the risk of tinting. These
               sensors can be apart of an automated press control system.

Benefits:       •       These devices yield increased quality control and reductions in waste paper and
                      ink generation, as well as time.

Costs:         •       The costs of installing specific devices can be obtained from the product
                      manufacturer. Cost savings may be realized in reductions in waste paper, ink,
                      and plates generated.


Alternative Inks

The following alternative inks are available for use:

               • Vegetable-based (including soy)
               • Rubber-based (waterless printing)
               • Near-zero volatile organic compound (VOC) ink/press-wash systems
               • Ultraviolet-cured
               • Electron-beam cured.

                                                                                   Moderate
Technique:     Vegetable-based inks are common substitutes for petroleum- or solvent-based inks.
               Soy-based inks must contain a minimum of 20 percent soybean oil.  Some vegetable-
               based inks do not contain any petroleum products.

Benefits:       •       The use of vegetable-based inks can reduce VOC emissions by  50 to 99 percent.
                      Vegetable-based inks typically contain less than 1 to 20 percent  VOCs, whereas
                      petroleum-based inks contain a slightly higher percent VOCs.
                      Employee safety increases because worker hazards from VOC emissions are
                      reduced or eliminated.
                      Products  printed with vegetable-based inks are said to be more deinkable by
                      waste paper processors and produce less hazardous sludge, making them more
                      recyclable than products printed with  petroleum-based inks.

Costs:         •       Vegetable-based inks may be  harder to use, especially in high-speed or handling
                      situations.
                      Some customers may not accept such inks because they do not  yet produce very
                      high quality results in some applications.
                      They may be slightly more expensive.
                      Because their quality is improving and because of the environmental advantages
                      they offer, you should use vegetable-based inks in as many  applications as
                      possible.  The fact that you use them can also be used to your marketing
                      advantage.
                      Many colored vegetable-based inks are comparable in price to petroleum- or
                      solvent-based inks because the price is driven by the pigment and not the
                      vehicle.

                                                                                   Moderate
Technique:     Rubber-based (waterless printing) -- This pollution prevention technique describes a
               new development in lithography that eliminates the use of fountain solutions. In waterless
               printing, silicone rubber is used in place of fountain solution to repel ink from non-image
               areas of the printing plate.
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Benefits:      •       Sharper images can be created using this printing technology because inks can
                      be applied at higher densities.

Costs:        •       The inks must be maintained within narrow temperature ranges, so cooling of the
                      printing presses is often required.
                      Current plate-making methods for waterless printing are solvent-based, which
                      adds to facility VOC emissions and hazardous waste.

                                                                                   Moderate
Technique:    Near-Zero VOC Ink/Press Wash - A new ink/press wash system on the market for use
              by lithographers contains virtually no VOCs. The ink is made from a 100-percent
              vegetable oil base and, through use of special chemicals, presses can be cleaned  with a
              water-based press wash solution. Essentially, these special chemicals make the ink
              water soluble. To find out more about this new system, contact your state pollution
              prevention office or the New England Environmental Assistance Team (see Chapter 9). A
              technology demonstration on this  innovative system showed positive results, as indicated
              in the following list of benefits.

Benefits:      •       Reduces conventional press wash use and can reduce purchases of press wash.
                      Eliminates hazardous solvents in wastewater discharges.
                      Reduces hazardous waste generation and disposal.
                      Eliminates worker health risks associated with solvents containing VOCs.
                      Can reduce ink consumption.
                      Business form and check printers and job shops are excellent candidates for this
                      system.  Performs well on one-color sheet fed, raised imprint, and web presses
                      and may work on duplicators.
                      Creates potential for green marketing of your print shop.
                      Reduces VOC generation.

Costs:        •       Blanket and roller cleanup is more time consuming but is still acceptable.
                      There are potential drying problems.
                      High-quality sheet fed printers must work closely with  the manufacturer to  perfect
                      use for their shop. Other printers must be willing to experiment with this product
                      and seek support from the manufacturer.

                                                                                 Challenging
Technique:    Ultraviolet (UV)-curing inks - These inks consist of liquid prepolymers and initiators.
              When exposed to large doses of UV radiation, these compounds immediately polymerize
              into a solid.  As substitutes for solvent-based inks, UV-curing inks are particularly suitable
              for  lithographic printing on nonabsorbent substrates, such as foil and plastics. Because a
              high capital  expenditure is required to purchase the equipment, however, its use is limited
              to larger shops.

                                                                                 Challenging
Technique:    Electron-beam (EB) - curing inks - These inks are similar to UV-curing inks in that they
              contain no solvent and offer the same operational advantages. EB-curing inks are
              suitable substitutes for solvent-based inks used in lithographic printing. Because the cost
              of an EB starter system can be $1 million or more, however, its use  is limited to larger
              shops.
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Automatic Ink Levelers and Antiskinning Spray
                                                                                  Fit to Print
                                                                     Moderate
 Technique:     Automatic ink levelers work by distributing ink evenly across the ink tray and agitating the
               ink to prevent a skin from forming on the surface. These are most appropriate for large
               printing presses that are too large to spread the ink by hand. The automatic ink levelers
               reduce the amount of ink required to be in the ink tray to ensure distribution. Another
               method to prevent ink from skinning is to spray a nontoxic antiskinning agent on the ink in
               the tray.

 Benefits:       •       Reductions in ink use and associated waste ink disposal.
                      Reduction in the amount of waste paper generated due to poor press runs.

 Costs:         •       Some capital expenditure is required for installing the ink levelers. However, you
                      will probably experience cost savings from reduced loss of paper and ink in poor
                      press runs, as well as from  waste  ink disposal.
Reuse and Recycle Waste Solvent
                                                                     Moderate
Technique:
Benefits:
Costs:
By placing drip pans under presses, solvent can be collected and reused for cleaning.
Used solvent will remove most of the ink from rollers and blankets, with only a small
amount of fresh solvent needed for final cleanup.  In addition, waste solvents having one
ink color can be reused to make up the solvent content of new inks of the same color.
This pollution prevention technique will allow for a significant reduction in solvent waste
generation by reusing or recycling waste solvent.

Waste  solvents can also be recycled, although they are frequently fuel-blended.
Recycling waste solvents requires you to segregate used waste solvents from other
hazardous wastes (e.g., waste inks, fountain solutions). These waste solvents should be
handled as a hazardous waste and be recycled through a licensed off-site solvent recycler
who must have an EPA identification number. These recyclers clean, regenerate, and
sell used  solvents as recycled solvent products.

On-site distillation units are often used to reclaim solvents. Use of a distillation unit can
greatly reduce the amount of hazardous waste solvent sent off-site. (Unless you hard-pipe
waste solvent directly to a recycling unit, it gets counted as a hazardous waste
generated.) Note: On-site distillation of  flammable liquids is VERY dangerous.

       By reusing waste solvents as part  of your cleaning process, you significantly
       reduce the amount of fresh solvent needed and reduce the quantity of waste
       solvent that must be disposed of off-site.
       Recycling waste solvent also reduces the amount of hazardous waste incinerated
       or burned for energy. Both incinerators and fuel blending generate air emissions.
       Purchasing recycled solvents reduces the need for fresh solvents and promotes
       the solvent recycling industry.

       There is a hazardous sludge generated that you must manage.
       Distillation units can require some  capital investment, which varies greatly with
       the size of the  unit. A continuous  110-gallon still costs about $25,000; a 5-gallon
       batch costs about $3,000.
       You must also register recycling equipment or get a state permit. (See your
       state's summary for more information.)
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Solvent Sink For Parts Cleaning
                                                                    Moderate
Technique:    This pollution prevention technique can reduce your generation of hazardous solvent
              waste and used shop towels generated by equipment cleaning. Solvent sinks are only
              appropriate for your printing shop if parts from your presses can be easily removed and
              taken to a sink for cleaning. A solvent sink is a steel sink that parts can be placed in and
              cleaned with solvent. Solvent is supplied from a barrel and is recirculated.  The solvent
              may be filtered in the sink and used until it is dirty and no longer effective. Solvent sinks
              are generally serviced by a company that will remove and replace ineffective solvent.
              Service companies typically use recycled solvents for solvent sinks. The service
              company must be a licensed supplier and solvent recycler.

Benefits:      •       It reduces the use of fresh solvent.
                     Worker safety is improved because of reduced handling of solvent-soaked shop
                     towels to clean  press parts.

Costs:        •       Solvent sinks that are serviced by a company will cost approximately $200 per
                      month for a one-barrel sink that is changed monthly.  Note: You should negotiate
                     with your service-provider for less frequent solvent replacement (every 6 to 8
                     weeks). Service providers will want to change the solvent often, which increases
                      your hazardous waste generation rate. Solvent sinks with filtration systems start
                      at approximately $700. You should compare the cost of the solvent sink with the
                      savings associated with reducing the use of shop towels and solvents, as well as
                      with waste ink disposal costs.
Automatic Blanket Cleaners
                                                                  Challenging
Technique:
Benefits:
Costs:
This pollution prevention technique can reduce your waste solvent generation.  Automatic
blanket cleaners, which replace hand cleanup using shop towels and solvents,  have been
determined to be more efficient and use less solvent than manual cleanup.

       Increased employee safety because of reduced solvent handling and associated
       employee exposure to toxic chemicals.
       Reduced solvent use.
       Reduced waste solvent generation.
       Reduced VOC emissions.

       By using an automatic blanket cleaner, you should realize cost savings based on
       decreased solvent use and labor time required for press cleaning.
       A significant capital investment is required for an automatic blanket cleaner and
       other attachments.
       A press needs to have sufficient clearance under the blanket rollers to  allow for
       an automatic cleaner. Small presses may not have sufficient clearance.
       It is not easy to retrofit old presses for this technology.  It can also be expensive
       and not be a good return on investment.
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               6.  How Do I COMPLY WITH AIR REGULATIONS?
As a printer, you release or emit pollutants to the
air because you work with inks and solvents that
contain volatile organic compounds and toxic
vapors.  These emissions lead to the formation
of smog, and they degrade air quality. Therefore,
it is important that you comply with air pollution
control requirements and seek out methods for
reducing air emissions from your print shop in
order to  protect yourself, your co-workers, and
the quality of the air in New England. This
chapter  explains how you can meet these two
objectives.

Both the U.S. Environmental Protection Agency
(EPA) and state environmental agencies
regulate sources of air pollution.  The
requirements for most printers  in New England,
however, will most likely be regulated at the state
level. You can be held liable  for failing to
comply with federal AND state regulations,
so it is important that you comply with all the
regulations that apply to your shop. You
should also know that pollution prevention is a
smart management tool that  will benefit you in
many ways, including helping you to comply with
Clean Air Act regulations.

Here are the steps you should  follow to
responsibly manage  air emissions from your
print shop:

• Determine which products  you use that contain
  volatile organic compounds and hazardous air
  pollutants (defined  below).
• Calculate air emissions from  your shop.
• Check with your state air pollution control
  office  and determine which regulations apply to
  your shop.
• Comply with  all applicable  regulations,
  including obtaining necessary permits.
• Practice good environmental management.
• Prevent pollution.
6.1    AIR EMISSIONS FROM  PRINTING
       OPERATIONS

Air emissions from printing operations include
volatile organic compounds (VOCs) and
hazardous air pollutants (HAPs). Exhibit 2 (see
Chapter 3) lists typical air emissions generated
by lithographic printing operations. While this list
is not all inclusive, it provides a general idea of
the kinds of air emissions that your printing
operations generate.

The federal Clean Air Act is the law that
regulates air pollution in the United States. It
requires state environmental agencies to
regulate the use of VOCs because VOC
emissions lead to the formation of ground-level
ozone or smog.  VOCs are found in press wash,
parts-cleaning solvents, proofing system
solvents, fountain solutions (alcohol or its
substitutes), inks, coatings, adhesives,  and
photo- and plate- processing solutions. Press
washes can be composed of up to 100-percent
organic solvents and are a major contributor to a
facility's VOC emissions.

The Clean Air Act also identifies 189 chemicals
that are subject to regulation as HAPs.  Section
6.3 presents a list of federally  regulated HAPs.
The state in which you operate may also
regulate additional chemicals  as HAPs. (Please
see your state's requirements provided in a
pocket at the  end of this manual). On the
federal HAP list, the  most common chemicals
used by lithographers are certain glycol ethers,
which can be  found in alcohol substitutes and
cleaning solutions.

After you identify which products used at your
shop contain VOCs and/or HAPs, you must
determine the quantity of emissions generated
from the use of these products and the best way
to manage these emissions. Section 6.2
explains how  to calculate your emissions.
Section 6.3 explains the requirements you must
follow to address emissions from VOCs and
HAPs.  Section 6.4 explains the permitting
regulations. Sections 6.5 and 6.6 offer
information on good  environmental management
and pollution prevention opportunities that can
improve the efficiency of your printing
operations. The pocket at the end of this
manual contains a summary of your state's
requirements.
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6.2    CALCULATING AIR EMISSIONS

        FROM YOUR PRINT SHOP

You will need to calculate the actual amount of
VOCs and HAPs generated by your facility, as
well as your facility's potential to emit these
pollutants.  Under the Clean Air Act, your
facility's potential to emit  VOCs and HAPs is
important in determining which regulatory
requirements apply to your facility.

A facility's potential to emit is defined as the
greatest amount of emissions that could be
released by all the equipment in the facility if it
was operated 24 hours a day, 365 days a year
(its "maximum design capacity"). Pollution
control devices that reduce emissions and
restrictions  on the hours of operation are not
included in the calculation of a facility's potential
to emit unless you have a federally enforceable
permit that includes these conditions (see
Section 6.4).

You need to perform the following calculations to
determine your facility's actual and potential
VOC and HAP emissions in order to determine
which regulations apply to your facility.


A.      Determining  Your Shop's

       Actual YOC or HAP Emissions

The material balance method is suggested for
determining your actual air emissions. The basic
concept underlying the material balance method
is that the amount of material  entering a process
(like printing) is equal to the amount exiting the
process. Therefore, what you purchase as raw
material must become part of the finished
product, be  emitted to the air or water, be
disposed of as waste, or be accumulated in
inventory.

You must have the following information to use
the  material balance method to calculate
emissions:

  •  Beginning of the month inventory
  •  New purchases
  •  End of the month inventory
  •  Quantity shipped (i.e., manifested) off-site
   • Density or specific gravity of the material
   • Percentage of VOCs and HAPs in the
    material.

Material Safety Data Sheets (MSDSs) generally
provide the density or specific gravity of the
material. MSDSs also give the percentage of
VOCs or HAPs in the material (usually stated on
a weight basis). If any of this information is not
available on the MSDSs, you should contact your
vendor to obtain the necessary data. Exhibit 10
illustrates the necessary steps to calculate your
actual VOC or HAP emissions.


B.      Determining Your Facility's

        Potential YOC or HAP

        Emissions
Once you have determined your shop's actual
annual emissions, you should use this
information to determine your shop's potential to
emit VOCs or HAPs. As previously mentioned, a
facility's potential to emit is based on its
maximum design capacity (all equipment in the
shop operating 24 hours per day, 365 days per
year, or a total of 8,760 hours per year).  Also,
pollution control devices that reduce emissions
and restrictions on the hours of operation are not
included in the calculation, unless you have a
federally enforceable permit that includes these
limits. So, you should compare your facility's
actual hours of operation to the maximum design
capacity of 8,760 hours per year, using this
formula:

Potential emissions (Ibs/year) = Actual emissions
x (8,760 •=• Actual hours of operation).
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            Exhibit 10.  Calculating Your Actual VOC or HAP Emissions

 Step 1: Determine which products you purchased that contain VOCs or HAPs, using your Material
        Safety Data Sheets.

 Step 2: Determine the weight of each VOC- or HAP-containing product used in pounds.

 Step 3: For each VOC- or HAP-containing product, subtract the amount of material that your records
        show was disposed of or that remains in your shop.

 Step 4: Multiply the number from Step 3 by the VOC or HAP content of each product (usually as a
        percentage) as listed on the MSDS.

 Step 5: Add together the results from Step 4 for each VOC- or HAP-containing product used. The
        number that results is your facility's total actual VOC or HAP emissions.
Please keep in mind that your potential to emit
must account for emissions that could have
come from any unused equipment that may not
have been included in determining the facility's
actual emissions. For example, a printer may
own four presses but only have operated three
during the past year.  Emissions from three of
the presses would be used to determine the
facility's actual emissions.  But calculation of
potential emissions must include emissions from
all four presses.

In addition, according to EPA guidance,
calculations of your facility's maximum
production capacity should include the use of
coatings and inks with the highest VOC content
used in practice at your shop during the previous
2 years.
Finally, if you can document inherent physical
design limitations (e.g., your individual emissions
units require consistent and necessary
maintenance), you should contact your state to
determine whether you can reduce the number
of hours you must use in calculating your
potential to emit. Exhibit 11 provides an
example of how to  determine your facility's
actual and potential VOC emissions using a
hypothetical print shop.
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    Exhibit 11. Calculating Actual and Potential VOC Emissions at Ace Printing

       (Note: This is a hypothetical example.  The amounts assumed below will vary at your shop.)

  Step 1: Determine which products were purchased that contain VOCs:

  Bob, the owner of Ace Printing, operates three presses. He uses the following amounts of product in
  one year (VOC content and other parameters were obtained from suppliers and Material Safety Data
  Sheets):

         • Ink -- 40,000 Ibs (VOC content of 20% by weight)
         • Alcohol -- 3,000 gallons (density of 6 pounds per gallon, VOC content of  100%)
         • Press Wash -- 3,000 gallons (VOC content of 75%; specific gravity [sg] of 0.9).

         Note:  Make sure to include in your calculation all VOC-containing materials that you use,
         including adhesives; solvents used in parts cleaners; and proofing system solutions.

  Step 2: Determine the weight in pounds of each product used:

         • Ink = 40,000 Ibs
         • Alcohol = 3,000 gallons x 6 Ibs/gallon = 18,000 Ibs
         • Press Wash =  3,000 gallons x (0.9 sga x 8.34 Ibs/gallon) = 22,500 Ibs

         a Note: Specific  gravity (sg) is the density of a compound as compared to water (8.34
         pounds/gallon).  To calculate the density from a given specific gravity, multiply the specific
         gravity by 8.34 pounds per gallon.

  Step 3: Subtract the amount of material disposed of, or remaining, that can be accounted for:

         • Ink -- Assume that 1,000 Ibs of ink are disposed of in waste shipments.
           Total ink used  = 40,000 Ibs -1,000 Ibs = 39,000 Ibs.
         • Alcohol -- All alcohol is used in the operation.
           Total alcohol used = 18,000 Ibs.
         • Press Wash --  Assume that 1,000 Ibs are disposed of in shop towels. This number may be
           estimated by weighing shop towels dry and then again before laundry pickup.
           Total press wash used = 22,500 Ibs -1,000  Ibs = 21,500 Ibs.
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    Exhibit 11.  Calculating Actual and Potential VOC Emissions at Ace Printing
                                       (continued)

  Step 4: Determine the amount of VOCs used at the facility per year by multiplying the annual usage by
        the VOC fraction of the material:

        - Ink = 39,000 Ibs x 0.20 = 7,800 Ibs (Note: 20% expressed as a decimal is 0.20)
        • Alcohol = 18,000 Ibs x 1.0 = 18,000 Ibs (Note: 100% expressed as a decimal is 1.0)
        • Press Wash = 21,500 Ibs x 0.75 = 16,125 Ibs.

  Step 5: Total the actual emissions:

        • 7,800 Ibs (ink) + 18,000 Ibs (alcohol) + 16,125 Ibs (press wash) = 41,925 Ibs total
          actual VOC emissions.

  The potential emissions from Ace Printing are:

        = Actual emissions x [potential hours of operation •=• actual hours of operation]
        = 41,925 Ibs/yr x [8,760 hrs/yrb-^ 2,600 hrs/yrb]
        = 41,925 Ibs/yr x 3.37
        = 141,287.25 Ibs/yr
        = 70.6 tons per year.


        "Potential hours of operation = 24 hrs/day x 365 days/yr = 8,760 hrs/yr;
         actual hours of operation for Ace Printing = 10 hrs/day x 5 days/wk x 52 wks/yr =
         2,600 hrs/yr
6.3   DETERMINING WHICH

       REGULATIONS APPLY TO YOUR

       FACILITY

Once you have calculated your facility's actual
and potential emissions, you are ready to
determine which state and federal regulations
may apply to your facility.

A.     Major VOC Sources

A facility may be classified as a major source of
VOC emissions depending upon its potential to
emit VOCs and its location. Areas that
experience unhealthy ground-level ozone (i.e.,
smog) concentrations more than once per year
on average are designated as non-attainment
areas.  These areas are then classified as
marginal, moderate, serious, severe, or extreme,
depending upon the severity of the air quality
problem.

In most of New England, which is part of a
special area known as the Northeast Ozone
Transport Region, a major source is one with the
potential to emit 50 tons (100,000 pounds) of
VOCs or more per year.  However, for facilities
located in the southwestern portion of
Connecticut, a major source is one with the
potential to emit 25 tons (50,000 pounds) of
VOCs or more per year, because this area has
severe ground level ozone problems.
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  /  If your shop is a major source of VOCs,
     based on its potential to emit, you must
     follow the requirements listed below.

  /  If your shop is not a major source of
     VOCs, skip to Section B (Major HAP
     Sources).
 REQUIREMENTS FOR MAJOR VOC SOURCES:

 You must reduce your emissions through the
 use of Reasonably Available Control
 Technology. In some cases, states have
 established their own control levels.  EPA
 issued a draft Contrgl Techniques Guideline
 document outlining recommended levels of
 control for the offset lithographic printing
 industry in September 1993. EPA also issued
 an Alternative Control Techniques document
 in June 1994 that contains supplemental
 information. These documents may be
 obtained from state and federal environmental
 agencies.  In these two EPA guidance
 documents for offset lithographic printing shops,
 the recommended levels of control are as
 follows:

    • Heatset web -- The fountain solution
    must contain no greater than 1.6-percent
    alcohol by weight or no greater than 3.0-
    percent alcohol by weight if the solution is
    refrigerated to less than 60° F. If, however,
    the fountain solution contains no alcohol, it
    may contain up to 5.0-percent VOCs by
    weight. Also, VOC emissions from the
    press dryer exhaust vent must be reduced
    by 90 percent (by weight), or a maximum
    dryer outlet concentration of 20 ppmv  must
    be maintained, whichever is less stringent.

   • Non-heatset web - The fountain
    solution must contain no alcohol.

   •Sheet-fed -  The fountain solution
    must contain no greater than 5.0-
    percent alcohol by weight or no
    greater than 8.5-percent alcohol by
    weight if the solution is refrigerated to  below
    60° F. Alternatively, if the fountain solution
    contains no alcohol, the fountain solution
    may contain up to 5.0-percent VOCs by
    weight.
   •Cleaning solutions - You must use
    cleaning solutions with a VOC content of 30
    percent or less or cleaning solutions with a
    VOC composite partial vapor pressure less
    than 10mm Hgat20°C.

These are the EPA recommended levels of
control.  Check with your state to see whether
their requirements are more stringent and
whether a state license is needed. In addition, if
you are a major VOC source, you need to obtain
a Title V operating permit. Section 6.4 discusses
operating permits.

B.     MAJOR HAP SOURCES

If your print shop has the potential to emit 10
tons per year (20,000 pounds) of any single HAP
on the federal HAP list (see Exhibit 12) or 25
tons per year (50,000 pounds) of any
combination of HAPs on the federal HAP list, it is
considered a major source of HAPs and will
need to obtain a Title V operating permit.

Your state may regulate other pollutants in
addition to those on the federal HAPs list. Refer
to your state's requirements provided in the
pocket at the end of this manual.
 / If your shop is a major source of HAPs,
    you must obtain a Title V operating permit.
    See Section 6.4 for details, and

 / You should also review the requirements in
   Section C, New Sources or Modifications.
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            Exhibit 12. List of Federal Hazardous Air Pollutants (HAPs)

 Sec. 112 (b) List of Pollutants. -- (1) Initial List. -- The Congress establishes for purposes of this section
 a list of hazardous air pollutants as follows:
        CAS Number

        75070
        60355
        75058
        98862
        53963
        107028
        79061
        79107
        107131
        107051
        92671
        62533
        90040
        1332214
        71432
        92875
        98077
        100447
        92524
        117817
        542881
        75252
        106990
        156627
        105002	
        133062
        63252
        75150
        56235
        463581
        120809
        133904
        57749
        7782505
        79118
        532274
        108907
        510156
        67663
        107302
        126998
        1319773
        95487
Chemical Name

Acetaldehyde
Acetamide
Acetonitrile
Acetophenone
2-Acetylaminofluorene
Acrolein
Acrylamide
Acrylic acid
Acrylonitrile
Allyl chloride
4-Aminobiphenyl
Aniline
o-Anisidine
Asbestos
Benzene (including benzene from gasoline)
Benzidine
Benzotrichloride
Benzyl chloride
Biphenyl
Bis(2-ethylhexyl)phthalate (DEHP)
Bis(chloromethyl)ether
Bromoform
1,3-Butadiene
Calcium cyanamide
Caprolactam (Removed 6/6/96)
Captan
Carbaryl
Carbon disulfide
Carbon tetrachloride
Carbonyl sulfide
Catechol
Chloramben
Chlordane
Chlorine
Chloroacetic acid
2-Chloroacetophenone
Chlorobenzene
Chlorobenzilate
Chloroform
Chloromethyl methyl ether
Chloroprene
Cresols/Cresylic acid (isomers and mixture)
o-Cresol
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      Exhibit 12. List of Federal Hazardous Air Pollutants (HAPs) (continued)

        CAS Number          Chemical Name
        108394
        106445
        98828
        94757
        3547044
        334883
        132649
        96128
        84742
        106467
        91941
        111444
        542756
        62737
        111422
        121697
        64675
        119904
        60117
        119937
        79447
        68122
        57147
        131113
        77781
        534521
        51285
        121142
        123911
        122667
        106898
        106887
        140885
        100414
        51796
        75003
        106934
        107062
        107211
        151564
        75218
        96457
        75343
        50000
        76448
m-Cresol
p-Cresol
Cumene
2,4-D, salts and esters
DDE
Diazomethane
Dibenzofurans
1,2-Dibromo-3-chloropropane
Dibutylphthalate
1,4-Dichlorobenzene(p)
3,3-Dichlorobenzidene
Dichloroethyl ether (Bis(2-chloroethyl)ether)
1,3-Dichloropropene
Dichlorvos
Diethanolamine
N,N-Diethyl aniline (N,N-Dimethylaniline)
Diethyl sulfate
3,3-Dimethoxybenzidine
Dimethyl aminoazobenzene
3,3'-Dimethyl benzidine
Dimethyl carbamoyl chloride
Dimethyl formamide
1,1-Dimethyl hydrazine
Dimethyl phthalate
Dimethyl sulfate
4,6-Dinitro-o-cresol, and salts
2,4-Dinitrophenol
2,4-Dinitrotoluene
1,4-Dioxane (1,4-Diethyleneoxide)
1,2-Diphenylhydrazine
Epichlorohydrin (1 -Chloro-2,3-epoxypropane)
1,2-Epoxybutane
Ethyl acrylate
Ethyl benzene
Ethyl carbamate (Urethane)
Ethyl chloride (Chloroethane)
Ethylene dibromide (Dibromoethane)
Ethylene dichloride (1,2-Dichloroethane)
Ethylene glycol
Ethylene imine (Aziridine)
Ethylene oxide
Ethylene thiourea
Ethylidene dichloride (1,1-Dichloroethahe)
Formaldehyde
Heptachlor
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       Exhibit 12. List of Federal Hazardous Air Pollutants (HAPs) (continued)

         CAS Number         Chemical Name
         118741
         87683
         77474
         67721
         822060
         680319
         110543
         302012
         7647010
         7664393
         7783064
         123319
         78591
         58899
         108316
         67561
         72435
         74839
         74873
         71556
         78933
         60344
         74884
         108101
         624839
         80626
         1634044
         101144
         75092
         101688
         101779
         91203
         98953
         92933
         100027
         79469
         684935
         62759
         59892
         56382
         82688
         87865
         108952
         106503
         75445
         7803512
         7723140
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexamethylene-1,6-diisocyanate
Hexamethylphosphoramide
Hexane
Hydrazine
Hydrochloric acid
Hydrogen fluoride (Hydrofluoric acid)
Hydrogen sulfide
Hydroquinone
Isophorone
Lindane (all isomers)
Maleic anhydride
Methanol
Methoxychlor
Methyl bromide (Bromomethane)
Methyl chloride (Chloromethane)
Methyl chloroform (1,1,1-Trichloroethane)
Methyl ethyl ketone (2-Butanone)
Methyl hydrazine
Methyl iodide (lodomethane)
Methyl isobutyl ketone (Hexone)
Methyl isocyanate
Methyl methacrylate
Methyl tert butyl ether
4,4-Methylene  bis(2-chloroaniline)
Methylene chloride  (Dichloromethane)
Methylene diphenyl diisocyanate (MDI)
4,4'-Methylenedianiline
Naphthalene
Nitrobenzene
4-Nitrobiphenyl
4-Nitrophenol
2-Nitropropane
N-Nitroso-N-methylurea
N-Nitrosodimethylamine
N-Nitrosomorpholine
Parathion
Pentachloronitrobenzene (Quintobenzene)
Pentachlorophenol
Phenol
p-Phenylenediamine
Phosgene
Phosphine
Phosphorus
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       Exhibit 12.  List of Federal Hazardous Air Pollutants (HAPs) (continued)

         CAS Number         Chemical Name
         85449
         1336363
         1120714
         57578
         123386
         114261
         78875
         75569
         75558
         91225
         106514
         100425
         96093
         1746016
         79345
         127184
         7550450
         108883
         95807
         584849
         95534
         8001352
         120821
         79005
         79016
         95954
         88062
         121448
         1582098
         540841
         108054
         593602
         75014
         75354
         1330207
         95476
         108383
Phthalic anhydride
Polychlorinated biphenyls (Arochlors)
1,3-Propane sultone
beta-Propiolactone
Propionaldehyde
Propoxur(Baygon)
Propylene dichloride (1,2-Dichloropropane)
Propylene oxide
1,2-Propylenimine (2-Methyl aziridine)
Quinoline
Quinone
Styrene
Styrene oxide
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene (Perchloroethylene)
Titanium tetrachloride
Toluene
2,4-Toluene diamine
2,4-Toluene diisocyanate
o-Toluidine
Toxaphene (chlorinated camphene)
1,2,4-Trichlorobenzene
1,1,2-Trichloroethane
Trichloroethylene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Triethylamine
Trifluralin
2,2,4-Trimethylpentane
Vinyl acetate
Vinyl bromide
Vinyl chloride
Vinylidene chloride (1,1-Dichloroethylene)
Xylenes (isomers  and mixture)
o-Xylenes
m-Xylenes
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      Exhibit 12.  List of Federal Hazardous Air Pollutants (HAPs) (continued)

        CAS Number         Chemical Name
        106423
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
             0
                            p-Xylenes
                            Antimony Compounds
                            Arsenic Compounds (inorganic including arsine)
                            Beryllium Compounds
                            Cadmium Compounds
                            Chromium Compounds
                            Cobalt Compounds
                            Coke Oven Emissions
                            Cyanide Compounds1
                            Glycol ethers2
                            Lead Compounds
                            Manganese Compounds
                            Mercury Compounds
                            Fine mineral fibers3
                            Nickel Compounds
                            Polycyclic Organic Matter4
                            Radionuclides (including radon)5
                            Selenium Compounds
Note:
    For all listings above which contain the word 'compounds' and for glycol ethers, the following
    applies: Unless otherwise specified, these listings are defined as including any unique chemical
    substance that contains the name chemical (i.e., antimony, arsenic, etc.) as part of that chemical's
    infrastructure.
X'CN where X=H' or any other group where a formal dissociation may occur.  For example KCN or
Ca(CN)2.
Includes mono- and di-ethers or ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2) „-
OR' where n=1, 2, or 3; R=alkyl or aryl groups; R'=R ,H, or groups which, when removed, yield glycol
ethers with the structure: R-(OCH2CH)n-OH.  Polymers are excluded from the glycol category.
Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers
(or other mineral derived fibers) of average diameter 1 micrometer or less.
Includes organic compounds with more than one benzene ring, and which have a boiling point greater
than or equal to 100°C.
A type of atom which spontaneously undergoes radioactive decay.
C.     NEW SOURCES OR MODIFICATIONS

Your shop is subject to the Clean Air Act new
source review requirements if you are either a
new major source or an existing major source
with significant modifications to equipment at
your shop.
                                               New source review requires you to control your
                                               emissions to the greatest extent technically
                                               possible. In non-attainment areas and in the
                                               Ozone Transport Region, all new major sources
                                               are required to offset their emissions.  Each
                                               state's regulations define when a shop would be
                                               considered a "new" source (see your state's
                                               regulations provided in the pocket at the end of
                                               this manual).  An emissions offset is the
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reduction of emissions at an existing source to
compensate for new emissions at another
source. You can offset new emissions by buying
or trading emissions reductions from other
sources. If you are a new major source of VOC
emissions, you will definitely be subject to new
source review.  If you are a new source whose
emissions are less than major, you may still be
subject to minor new source review depending
on your state.  Most minor new source review
programs do not require offsets, but do require
the source to implement the best available
control technology.

Because you may be more likely to modify your
existing facility rather than build a new one, you
should understand the regulatory implications of
modifying your plant. You will be subject to new
source review if you undertake a significant
modification to an existing major source. A
modification to an existing major source (e.g.,
adding a press) is considered significant if it
causes emissions at your facility to exceed:

• 40 tons per year of VOCs in Maine,
  Vermont, and portions of New Hampshire
• 25 tons per year of VOCs in Connecticut,
  Rhode Island, Massachusetts, and other
  portions of New  Hampshire.

Further, each state has a federally approved
program to regulate  minor modifications and
minor new sources (see your state's regulations
provided in a pocket at the end of this manual).
    If your new shop is a major or minor new
    source or if you undertake a significant
    modification to an existing source, your
    state environmental agency will determine
    the specific control measures you must
    implement. Contact the office listed on
    your state summary page provided in the
    pocket at the end of this manual.

    You should also review the requirements
    in Section 6.4, Air Pollution Permits.
  local agencies to plan for either further
  reductions of air pollution or the maintenance
  of current air quality.
• Designate the control requirements to be used
  to reduce the emissions of certain pollutants at
  a facility.
• Identify how a facility demonstrates
  compliance with the control requirements.

Permits can take several forms, including a
permit-to-construct and a permit-to-operate. A
construction permit may be required before any
new facility can be built or before any new piece
of equipment (e.g., a printing  press) can be
installed or modified (see your state summary
page provided in a pocket at the end of this
manual). An operating permit will contain all
applicable and enforceable control  requirements
and, like all permits, will have a defined period of
effectiveness.

One type of operating permit, mandated by the
1990 Clean Air Act Amendments, is the Title V
operating permit. The  Title V operating permit
specifies all of the state and federal control
requirements, emission limits, and
recordkeeping, monitoring and reporting
requirements to which your facility is subject.

Your facility will need to obtain a Title V
operating permit if it is a major source of HAPs
or a major source of VOCs, based on your
facility's potential to emit these pollutants (see
Sections 6.3A and 6.3B).

In some states (e.g., New Hampshire,
Massachusetts, Rhode  Island, and  Maine), if you
are a major source based on your potential
emissions but your actual emissions are much
less than your source levels, you can obtain a
permit to restrict your emissions below the major
source threshold and you will  not be required to
obtain a Title V operating permit or  comply with
major new source requirements (see your state
summary provided in the pocket at  the end of
this manual).
6.4   AIR POLLUTION  PERMITS

Air permits serve three roles. They:

•  Provide an inventory of air pollution sources.
  This inventory is used by federal, state, and
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6.5   GOOD ENVIRONMENTAL MANAGEMENT PRACTICES

Here are some tips on good environmental management practices that could help you save money and
improve your operations:

       •  Document all actions you take to reduce or eliminate emissions.

       •  Keep good records of product purchases and use so you can accurately
         calculate your emissions.

       •  Do appropriate reporting and keep important records of waste disposal.

       •  Document your actual and potential VOC and HAP emissions calculations as
         well as your operating time.

       •  Educate your customers on the environmental impacts of their product
         choices.

       •  Conserve and reuse inks.

       •  Handle solvents carefully to minimize spills.

       •  Avoid use of products containing VOCs and chlorinated solvents (e.g., benzene,
         1,1,1-trichloroethylene, methylene chloride, toluene, and xylene).

       •  Choose solvents with a low VOC content or low vapor pressure or that are water-miscible when
         possible.

       •  Reuse shop towels for low quality cleaning needs in the shop prior to
         proper disposal.

       •  Use solvents conservatively by using plunger cans to dispense solvents
         with meters and using only the amount necessary. Appoint one person to
         store and distribute solvents.

       •  Do not leave shop towels out in the open; use a metal container with a lid
         that can be closed using a foot pedal.

       •  Do not leave product containers open.

       •  Switch to alcohol-free fountain solution -- today.
6.6   POLLUTION PREVENTION OPPORTUNITIES FOR AIR EMISSIONS

If you are subject to any of the requirements outlined in Sections 6.2 through 6.4, you should use pollution
prevention techniques as a means of both complying with regulations and reducing your regulatory
burden.  Even if you are not subject to any of the above requirements, you should prevent pollution where
possible in your facility because it can save you money on solvents and reduce
worker exposure to chemicals so that your facility provides a safer and more
pleasant work environment.
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This section describes pollution prevention (P2) opportunities that can limit air emissions.
Information on whether the technique is easy or more difficult to use is included next to
each listing, followed by a description of the technique and its benefits.  Each discussion
provides information on the relative cost of the technique and the waste streams that can
be reduced using each technique, where possible. For more information, please contact
the individuals listed in Chapter 9.


Cover Photoprocessing Chemical Containers                                     Easy

Technique:     This  is a simple P2 technique that can be implemented at your shop to:

                      Reduce or eliminate air emissions generated by chemical evaporation
                      Reduce purchases of virgin photoprocessing chemicals.

               Developers evaporate very quickly, while fixers evaporate at a slightly slower rate. The
               containers should always be sealed or covered to prevent evaporation.  Many print shops
               use floating lids, caps, or other devices to do this. You should also cover trays overnight if
               tray processing is done.

Benefits:       •      Your photoprocessing costs  are reduced because there is minimal loss of the
                      product through  evaporation.
                      Your working environment will be safer because of the reduction and/or
                      elimination of air emissions from the solutions.

Costs:         •      This technique may require you to purchase covers and lids. Special
                      tanks/containers can be purchased for $20 to $250.


Alternative Fountain Solution                                            Easy/Moderate

Technique:     The use of alternative fountain solution will reduce or eliminate your facility's VOC
               emissions. Fountain solutions traditionally contain isopropyl alcohol (IPA). Non-lPA
               fountain solutions that use glycol ether are typically used as a replacement for IPA.

Benefits:       •      Substitutes may help you meet VOC emission limits for your printing shop.
                      Since substitutes are used at much lower concentrations, you will  incur cost
                      savings by using less product.
                      Substitutes will improve the indoor air quality of your shop because VOC
                      emissions will be significantly reduced or eliminated.
                      Substitutes eliminate the use of highly flammable, dangerous products.

Costs:         •      Non-lPA fountain solutions cost approximately $18 to $20 per gallon, while IPA
                      solutions cost around $10 per gallon.
                      Non-lPA fountain solutions perform differently on the press than IPA solutions.
                      Generally, their operating range is smaller, and the viscosity can vary with
                      temperature resulting in inconsistent wetting.
Alternative Cleaning Solutions                                                 Moderate

Technique:     The use of alternative blanket washes and cleaners that are less toxic and flammable will
               reduce your facility's VOC emissions.  Typical press-cleaning solutions contain aliphatic
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Benefits:


Costs:
and aromatic hydrocarbons.  Alternative blanket washes, which contain mixtures of glycol
ethers and other heavier hydrocarbons, have higher flashpoints and low toxicities, which
are formulated to produce lower VOC emissions.  These glycol ether solutions clean
comparably to conventional solvents.

These alternative cleaning solutions do not evaporate as rapidly as other solvents and
may require a substantially longer drying time.  Because of the environmental and safety
benefits of these materials, however, they are gaining in popularity.  Cleanup should be
done with detergents or soap solutions wherever possible. Solvents should be used only
for cleaning up inks and oils.

Water miscible solvents are another alternative worth exploring.  They contain 100-
percent VOCs when purchased, but are cut to 50 percent with water, so at press contain
only 50 percent VOCs by content.

        The benefit of using  lower VOC solvents is the reduced VOC emissions, which
        improves indoor and regional air quality.

        Many alternative cleaning solutions require a substantially longer drying time.
        Extra time is required for cleaning presses.
Water-Based Adhesives for Postpress Operations
                                                                     Moderate
Technique:    Water-based adhesives have long been used in printing shop operations in addition to
              using solvent-based adhesives. However, an important trend in postpress
              operations is the increasing use of water-based adhesives in place of
              solvent-based adhesives, which contain toluene and methyl ethyl ketone,
              two highly toxic chemicals.

Benefits:      •       Reduces VOC and HAP emissions from solvent-based adhesives.
                      Reduces worker exposure to hazards.
Reduce Fountain Solution Temperature
                                                      Moderate/Challenging
Technique:    This P2 technique is a good operating practice that will minimize waste paper and ink
              generated from poor press runs, as well as significantly reduce VOC emissions.  Whether
              you use IPA or non-lPA fountain solution, you can maximize the efficiency of the fountain
              solutions by maintaining them at their optimum operating temperature through cooling or
              refrigeration. The optimum temperature may vary for different solutions.

              Refrigeration units can be installed for large presses. The smallest press that can
              typically accommodate a refrigeration unit is a 26-inch one-color press.

Benefits:      •       A refrigeration unit with a filtration system can significantly extend the life of non-
                      IPA fountain solutions by removing ink and paper particles. Fountain solution life
                      may be extended to months instead of days.
                      Reduced fountain solution losses.
                      Increased employee safety by reduced exposure to VOC emissions.
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Costs:         •       They do not work well in open fountains.
                      A fairly significant capital expenditure is required for the refrigeration unit and the
                      replumbing. A 5-gallon refrigeration unit costs approximately $2,400, and the
                      plumbing can cost approximately $1,000.
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                   7.  How SHOULD  I HANDLE SOLID WASTE?
Businesses across the United States generate
extremely large amounts of nonhazardous waste
daily.  In New England, incinerators and, most
often, landfills are the final destination for most
of this waste.  But many avenues exist for
diverting waste from a trash disposal facility that
may be in your community.

Solid waste reduction lowers energy
consumption and the  emission of greenhouse
gases. Recycling programs take materials out of
the waste stream that can be remanufactured
into new products, creating new businesses and
putting people to work. Industrial waste
exchanges turn one company's trash into
another company's raw materials.

This chapter describes some solid waste
reduction and recycling opportunities for
lithographers.  But because lithographic
processes differ from  one shop to next, you will
be the best source of  solid waste reduction ideas
for your shop.  To begin,  start with the ideas
listed  in Section 7.1, and then contact the
resources listed in Section 7.2.
7.I     REDUCTION AND RECYCLING

        OPPORTUNITIES FOR SOLID

        WASTE

Inefficiently managed solid waste can lead to
excessive and unnecessary expenses for your
company. The following list provides several
suggestions and resources to help you better
handle your company's solid waste.

• Reduce materials used -- You can use
  conservatively or eliminate completely a
  number of input materials to reduce solid
  wastes generated by your printing  operations.
  These materials include coatings that hinder
  recycling of paper from your shop and paper.

• Reuse materials -- While reducing the input
  materials to your printing process is the most
  effective means of pollution prevention,
  reusing materials in your printing operations
  can be an equally effective way of  reducing
c
  your solid waste stream. Try using returnable
  materials containers and returnable plastic or
  wood pallets. Check with your suppliers for
  other suggestions on how you can reuse
  materials that end up in your trash bin.

•  Recycle scrap - Many materials in a print
  shop can be recycled,  preventing them from
  ending up in the local landfill. They include
  packaging, paper (from test runs, scrap,
  waste, outdated), empty containers,
  cardboard, pallets,     	
  outdated materials
  (chemicals), plates,
  film (used or spoiled),
  and lubricating oils.
  Consult your vendors               	
  or local recycling firms
  for more ideas.

In addition, the use of in-line finishing is a
worthwhile pollution prevention technique to
reduce solid waste.  Finishing operations have
historically been labor-intensive operations,
handled either in-house or by a trade shop, and
were not integrated with the presses. Today,
equipment is available to perform almost all
major postpress operations, including cutting,
folding, perforating, trimming, and stitching in-
line.  Web presses are often linked  directly to
computer controlled in-line finishing equipment.

New to in-line finishing is demographic binding,
which is the selective assembly of a publication
based on a number of factors, such as
geographic area, family structure, income, or
personal interests.  For example, a printer can
select an advertisement to appear only in those
copies of a magazine intended for distribution in
the advertiser's selling area. Demographic
binding has proven to be a successful marketing
tool,  especially for major magazines.

This  pollution prevention technique reduces
costs by reducing the number of operators and
workers required for off-line finishing operations
by almost half, while sometimes doubling or
tripling the rate of production. It can also be
used to prepare materials for mailing by using
computers. These computers can  store and
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provide address labels, as well as address each
publication in zip code order.
7.2   NEW ENGLAND STATE SOLID

       WASTE PROGRAMS

This section provides contact numbers and
information on New England solid waste
programs.

WasteCAP

WasteCAPs are independent not-for-profit
organizations located in Maine, Massachusetts,
and New Hampshire that assist and encourage
companies to effectively drive costs out of their
operations through improved production and
solid waste management practices. WasteCAPs
conduct free, confidential, on-site waste
assessments; provide technical assistance over
the phone; and publish quarterly newsletters to
support solid waste reduction.  WasteCAPs can
also assist clients in designing or improving
recycling  programs and establishing effective
materials procurement practices. This section
lists WasteCAP contacts for the New England
states.
CONNECTICUT

Administering Agency

Connecticut Department of Environmental
Protection
79 Elm Street
Hartford, CT 06106-5127

Waste Management Bureau
Solid Waste: (860) 424-3021
Office of Pollution Prevention: (860) 424-3297

Waste Planning and Standards Bureau
Source Reduction and Recycling: (860) 424-
3365
MAINE

Administering Agency

Maine Department of Environmental Protection
State House Station 17
Augusta, ME 04333

Hazardous Materials and Solid Waste Control
Bureau
Solid Waste: (207) 289-2651
State Planning Office
State House Station 38
Augusta, ME 04333
Recycling: (207) 287-5649

WasteCAP of Maine
Maine Chamber and Business Alliance
120 Exchange Street
Portland, ME 04112
(207)774-1001
MASSACHUSETTS

Administering Agency

Massachusetts Department of Environmental
Protection
One Winter Street
Boston, MA 02108

Division of Solid Waste Management, Bureau of
Waste Prevention
Solid Waste: (617) 292-5960
Recycling:  (617)556-1021

WasteCAP of Massachusetts, Inc.
P.O. Box 763
222 Berkeley Street
Boston, MA 02117-07763
(617)236-7715
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NEW HAMPSHIRE

Administering Agency

New Hampshire Department of Environmental
Services
6 Hazen Drive
Concord, NH 03301

Waste Management Division
Solid Waste: (603)271-2900
Recycling:  (603)271-3712

WasteCAP of New Hampshire
122 North Main Street
Concord, NH 03301
(603) 224-5388


RHODE ISLAND

Administering Agency

Rhode Island Department of Environmental
Management
235 Promenade Street
Providence, Rl 02908

Office of Waste Management/Site Remediation
Solid Waste: (401)277-2797

Office of Strategic Planning and Policy
Recycling:  (401)277-3434
VERMONT

Administering Agency

Vermont Department of Environmental
Conservation
103 South Main Street
Waterbury, VT 05671

Waste Management Division
Solid Waste: (802)241-3888

Environmental Assistance Division
Recycling: (802) 241-3589
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    8.  How Do I RESPOND TO SPILLS AND PLAN FOR EMERGENCIES?
If there is a chemical or oil spill at your print
shop, you may be subject to many regulatory
requirements, depending on what spilled, how
much spilled, and where it was spilled.  It is
critical that you contain chemical and oil spills
immediately and report them to the appropriate
authorities in a timely manner.  Failure to
respond to spills appropriately could have dire
consequences for the environment in which you
and your employees live and work. The
consequences of not reporting a release when it
is required may be quite costly. And for the sake
of your community and its natural resources, you
should also comply with any additional chemical
reporting and emergency planning requirements
that may apply to your shop. It is just plain good
business sense.

Chapter 5 of this manual discusses spills of
hazardous waste covered by the Resource
Conservation and Recovery Act (RCRA) and the
associated planning requirements. If you have
developed a contingency plan and have followed
the procedures in place at your shop to address
RCRA chemical spills, you will have satisfied the
emergency planning and response requirements
for RCRA hazardous waste. Similarly, Chapter 4
discusses reporting requirements appropriate to
releases of RCRA hazardous and
nonhazardous waste to sewers and septic
systems.

Three other major laws, however, set out how
you should:

• Report spills of chemicals other than RCRA
 hazardous waste
• Report some chemicals used in your  shop
• Plan for chemical emergencies and oil spills.

The laws are the Emergency Planning and
Community  Right-to-Know Act (EPCRA), which
includes  planning, reporting, and chemical spill
requirements; the Comprehensive
Environmental Response, Compensation, and
Liability Act (CERCLA, also known as the
Superfund law), which includes requirements
concerning spills of certain chemicals; and the
Oil Pollution Act, which details oil spill planning
and response requirements. The major
requirements imposed by these laws are
described below.
8.1    EMERGENCY SPILL REPORTING

Two major laws may affect you if a chemical is
spilled in your shop. The first is CERCLA which
authorizes the U.S. Environmental Protection
Agency (EPA) to respond to releases of
hazardous substances that may endanger public
health or the environment. The second is
Subtitle III of the Superfund law Amendments,
known as EPCRA.
If you spill a CERCLA
hazardous substance or an
EPCRA extremely
hazardous substance in an
amount equal to or in
excess of the reportable
quantities, your printing
shop must immediately
notify:
• The National Response Center at (800) 424-
  8802
• Your State Emergency Contact -- See the
  contact list below
• Your Local Emergency Planning Committee
  (LEPC) -- This information is available from
  yourSERC.

You must also provide a written report on actions
taken and on any medical effects of the release
to these same organizations.

There is no penalty for making these phone calls
but there is a penalty for not making the calls.
So, do yourself a favor and make the calls if you
have any doubt about your  requirements in the
event of a spill at your print shop.

The Title III List of Lists provides the list of
CERCLA hazardous substances or EPCRA
extremely hazardous substances and the
reportable  quantities. You can obtain the List of
Lists by contacting the EPCRA Hotline at  (800)
535-0202,  the  RCRA/Superfund Hotline at (800)
424-9346,  or the EPA Chemical Emergency
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Preparedness and Prevention Office at
http://www.epa.gov/swercepp/.
New England State Emergency Contacts

CONNECTICUT

Administering Agency

Oil & Chemical Response Division
Connecticut Department of Environmental
Protection
79 Elm Street - 4th Floor
Hartford, CT 06106

• Oil & Chemical Emergency Response:
  (860) 424-3338
• General Information: (860) 424-3231


MAINE

Administering Agency

Division of Response Services
Maine Department of Environmental Protection
State House Station 17
Augusta, ME 04333

• Oil & Chemical Emergency Response (during
  business hours): (800)  482-0777
• Oil & Chemical Emergency Response (during
  non-business hours): (207) 657-3030
• General Information: (207)287-7190
 Oil & Chemical Emergency Response (during
  non-business hours): (508) 820-2121

  General Information: (617)292-5801
NEW HAMPSHIRE

Administering Agency

New Hampshire Department of Environmental
Services
P.O. Box 95
Concord, NH 03302

• Oil & Chemical Emergency Response (during
  business hours):  (603)271-3899
• Oil & Chemical Emergency Response (during
  non-business hours): (800) 346-4009
• General Information: (603)271-3503
RHODE ISLAND

Administering Agency

Rhode Island Department of Environmental
Management
235 Promenade Street
Providence, Rl 02905

•  Oil & Chemical Emergency Response (during
  business hours): (401)277-3872
•  Oil & Chemical Emergency Response (during
  non-business hours): (800) 498-1336
•  General Information:  (401)277-2234
MASSACHUSETTS

Administering Agency

Bureau of Waste Site Cleanup
Massachusetts Department of Environmental
Protection
1 Winter Street - 5th Floor
Boston, MA 02108

• Oil & Chemical Emergency Response (during
  business hours):
 - Northeast Region (Woburn) - (617) 932-7600
 - Southeast Region (Lakeville) - (508) 946-2850
 - Central Region (Worcester) - (508) 792-7653
 - Western  Region (Springfield) - (413) 784-1100
VERMONT

Administering Agency

Hazardous Materials Management Division
Vermont Department of Environmental
Conservation
Waterbury State Complex
103 South Main Street
Waterbury, VT 05676

• Oil & Chemical Emergency Response:
  (800)641-5005
• Waste Management Division: (802)241-3888
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8.2   EMERGENCY PLANNING AND

       CHEMICAL REPORTING

EPCRA is the environmental law that sets out
the primary planning and reporting requirements
for chemicals that you may use in your shop.
The purpose of EPCRA is two-fold:

•  To encourage and support emergency
  planning, by industry in coordination with state
  and local governments, for responding to
  chemical accidents

•  To provide local governments and the public
  with information about possible chemical
  hazards in  their community.

There are civil and criminal penalties for failure
to meet these obligations, and there is a citizen
suit provision of this law, so do not be caught
unaware!

It is important to note that if you eliminate
EPCRA chemicals from your operations through
pollution prevention, you will also eliminate the
associated planning and notification
requirements for your print shop.  This is an
excellent opportunity to decrease your shop's
regulatory burden through pollution prevention.

A.     Emergency Planning

/ All facilities, no matter how small, that use
   extremely hazardous substances listed under
   EPCRA in excess of certain amounts (called
   threshold planning quantities) must
   participate in emergency planning.  The
   information submitted through these
   emergency plans is used to help local
   governments respond to spills or releases
   and is made available to the public.

/ These same facilities must also appoint a
   facility emergency coordinator who must
   participate in the local emergency planning
   process.

/ Your first step to determine if these
   requirements apply to your shop is to
   determine if you use chemicals regulated
   under EPCRA and, if so, to determine what
   amounts are present at your shop.  The list of
   EPCRA chemicals and their threshold
   planning quantities is provided in the Title III
   List of Lists and is available by contacting the
   EPCRA Hotline at (800) 535-0202, the
   RCRA/Superfund Hotline at (800) 424-9346,
   or the EPA Chemical Emergency
   Preparedness and Prevention Office at
   http://www.epa.gov/swercepp. The EPCRA
   hotline can also answer questions you may
   have concerning how EPCRA may apply to
   your print shop.


B.     Hazardous Chemical

       Reporting

y  You must submit or prepare copies  of your
   print shop's Material Safety Data Sheets
   (MSDSs) or lists of all hazardous chemicals
   present at your print shop above threshold
   quantities, regardless of location or use, to
   the SERC, the LEPC, and local fire
   department.

   The threshold quantities are:

    • 500 pounds and less for extremely
    hazardous substances
    • 10,000 pounds and more for hazardous
    chemicals.

   MSDSs are available from your vendors.
   This reporting requirement is  based on the
   Occupational Safety and Health
   Administration's (OSHA) definition of a
   hazardous chemical, which is essentially any
   chemical that poses physical  or health
   hazards. As many as 500,000 products
   can fit this definition; therefore, it is highly
   likely that this reporting requirement applies
   to your shop.

/  You must also submit annual  inventories of
   these same hazardous chemicals to the
   same three organizations - the  LEPC, the
   SERC, and the local fire department. These
   inventories are due on March 1 of each year.
   Although one of two forms can be used (Tier I
   or  Tier II), most states use Tier II forms for
   reporting. Tier II forms ask for the  amounts
   and general location of specific chemicals.
   Some states  have their own form and may
   allow electronic reporting (contact your state
   office listed below).
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C.     The Toxics Release Inventory

       and  Form R Reporting

EPCRA also establishes reporting requirements
for facilities that store and manage specified
chemicals.  Facilities who must comply include
those that:

• Are classified in Standard Industrial
  Classification (SIC) codes 20 through 39
  (Manufacturing), which includes printers, and
  which meet the following criteria:

   •  Have 10 or more full-time employees; and
   •  Manufacture or process 25,000 pounds or
     more of specified chemicals or use
     quantities exceeding 10,000 pounds of
     specified chemicals.

Facilities that meet these criteria must:

/ Submit a Form R report on yearly toxic
   chemical releases to their states and EPA.
   That is, covered  facilities must estimate each
   year the total amount of the listed  chemicals
   they release into the environment  (either
   accidentally or as a result of routine
   manufacturing operations) or transport as a
   waste to another location. The reports are
   due on July 1 of  each year for releases in the
   previous calendar year.

EPA uses this information to  establish a national
Toxic Chemical Release Inventory and makes
the information available to the public and
communities through a computerized database
called the Toxic Release Inventory (TRI)
database.  This form is available from your state
EPCRA contact (see the next section).
Electronic reporting  is also available.
CONNECTICUT

Administering Agency

State Emergency Response Commission
Connecticut Department of Environmental
Protection
79 Elm Street - 4th Floor
Hartford, CT 06106-5127
(860) 424-3373

Connecticut uses the standard federal Tier II
form for reporting and requires the submission of
facility floor plans as part of its reporting
specifications. You have the option to file
electronically. Connecticut requires reporting of
any chemical spill (liquid, gaseous, and solid) to
the Department of Environmental Protection, Oil
and Chemical Response Division at (860) 424-
3338. Connecticut also requires manufacturers
that use, keep, store, or produce any hazardous
material to file a report with the local fire
marshall. Contact your local fire department for
details on these reports.
MAINE

Administering Agency

State Emergency Response Commission
Maine Emergency Management Agency
State House Station 72
Augusta, ME 04333
(207) 287-4080

Maine uses a state-specific Tier II form for
reporting and has additional state-specific facility
planning requirements. A reporting fee is
calculated based on the size of the facility and
the amount of chemicals being reported.
New England State EPCRA Contacts and
Requirements

The following sections summarize the New
England state EPCRA requirements applicable
to print shops that are more stringent and/or
different than the federal requirements. The
sections also list state EPCRA contacts.
MASSACHUSETTS

Administering Agency

State Emergency Response Commission
Massachusetts Emergency Management
Agency
400 Worcester Road
Framingham, MA 01701
(508) 820-2000
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William Panos
Massachusetts Department of Environmental
Protection
Bureau of Waste Prevention
1 Winter Street
Boston, MA 02108
(617)292-5870

Massachusetts uses a standard Tier II form with
the option of filing electronically.
NEW HAMPSHIRE

Administering Agency

State Emergency, Response Commission
Governor's Office of Emergency Management
State Office Park South
107 Pleasant Street
Concord, NH 03301
(603)271-2231

New Hampshire  uses a standard Tier II form for
reporting and requires that MSDSs be submitted
annually.
RHODE ISLAND

Administering Agency

State Emergency Response Commission
Rhode Island Emergency Management Agency
645 New London Avenue
Cranston, Rl 02920
(401)946-9996

Martha Delaney Mulcahey
Rhode Island Department of Environmental
Management
Division  of Air Resources
235 Promenade Street
Providence, Rl 02908-5767
Attn: Toxic Release Inventory
(401)277-2808

Rhode Island has state-specific facility planning
requirements, and the Tier II reporting must be
submitted electronically.
VERMONT

Administering Agency

State Emergency Response Commission
Vermont Emergency Management Agency
103 South Main Street
Waterbury, VT 05676
(802) 244-8721
(800) 347-0488

Gary Gulka
Vermont Department of Environmental
Conservation
Waste Prevention Section
103 S. Main St.
Westbury, VT 05671-0411
(802)241-3626

Vermont uses a standard Tier II form for
reporting with a reporting fee based on the size
of the facility and the amount of chemicals being
reported.
8.3   OIL SPILL PREVENTION

       CONTROL AND

       COUNTERMEASURES

The Oil Pollution Act contains requirements that
may apply to your shop in two ways:

• Any spill of oil large enough to cause a
  sheen in a body of water must be reported to
  the National Response Center at (800) 424-
  8802 and to the appropriate state oil and
  chemical emergency response number
  identified in the Section 8.1.

  These spills include releases to floor drains or
  storm drains, as well as chronic leaks from
  equipment or oil storage tanks.

• If you have a single above ground heating oil
  storage tank on your property that holds more
  than 660 gallons of oil or any number of tanks
  that hold more than 1,320 gallons of oil, you
  must have a Spill Prevention Control and
  Countermeasures (SPCC) Plan.
How Do I Respond to Spills and Plan For Emergencies?
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 Rhode Island has an Oil Pollution Control
 Regulation governing the storage of oil. For
 information on this program, call (401) 277-3872.

 New Hampshire has a Control of above ground
 Petroleum Storage Facilities rule pending. For
 information on the rule, call (603) 271-3644.
8.4   ONE PLAN

The Integrated Contingency Plan Guidance
(discussed in Chapter 5) allows you to
consolidate multiple emergency response plans
into one functional emergency response plan.
This option could save you a great deal of time
and effort. To find out more about One Plan,
contact the EPCRA Hotline at (800) 535-0202,
the RCRA/Superfund Hotline at (800) 424-9346,
or the EPA Chemical Emergency Preparedness
and Prevention Office at
http://www.epa.gov/swercepp.
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                                    9.  RESOURCES
This section presents a list of state and federal contacts that you can
call if you are seeking additional information on a particular issue or
regulation. Remember that state contacts for wastewater, hazardous
waste, and air emissions are provided in the pocket at the end of this
manual.
9.1    CONNECTICUT

State Pollution Prevention and Regulatory Assistance Contacts

Mary Sherwin                              P2 Clearinghouse & On-Site Technical Assistance:
Pollution Prevention Coordinator              Robert Brown
CT Department of Environmental Protection     ConnTAP
79 Elm Street                              50 Columbia Boulevard., 4th Floor
Hartford, CT 06106-5127                    Hartford, CT 06106
(860) 424-3297                             (860) 241-0777
Internet Address: www.state.ct.us

State Small Business Contact

Tracy Babbidge
Small Business Ombudsman
CT Department of Environmental Protection
79 Elm Street
Hartford, CT 06106-5127
(860) 424-3382



9.2   MAINE

State Pollution Prevention and Regulatory Assistance Contacts

Ann Pistell                          OR           Office of Pollution Prevention
Technical Assistance Coordinator                    1-800-789-9801
ME Department of Environmental Protection
State House Station 17
Augusta, ME 04333
(207) 287-7881
Internet Address: www.state.me.us/dep/mdephome.htm

State Small Business Contact

Brian Kavannah
Small Business Technical Assistance Coordinator
ME Department of Environmental Protection
State House Station 17
Augusta, ME 04333
(207)287-6188
In Maine: (800) 789-9802
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9.3   MASSACHUSETTS

State Pollution Prevention and Regulatory Assistance Contacts
George Frantz
Special Projects
MA Office of Technical Assistance
100 Cambridge Street, Room 2109
Boston, MA 02202
(617) 727-3260 ext. 631

P2 Clearinghouse:
Toxics Use Reduction Institute
University of Massachusetts - Lowell
One University Avenue
Lowell, MA  01854
(508) 934-3275

State Small Business Contact

George Frantz
Small Business Ombudsman
MA Office of Technical Assistance
100 Cambridge Street, Room 2109
Boston, MA 02202
(617)727-3260, ext. 631
Massachusetts Printers Partnership:
Nancy Wrenn
MA Department of Environmental Protection
Bureau of Waste Prevention
One Winter Street
Boston, MA 02108
(617)292-5584

Internet Address:
www.magnet.state.ma.us/dep/dephome.htm
9.4   NEW HAMPSHIRE

State Pollution Prevention and Regulatory Assistance Contacts
Vince Perelli
Pollution Prevention Program Manager
NH Department of Environmental Services
6 Hazen Drive
Concord, NH 03301-6509
(603)271-6460
Internet Address: www.state.nh.us

State Small Business Contact
P2 Clearinghouse:
Kathy Blake
NH Department of Environmental Services
6 Hazen Drive
Concord, NH 03301-6509
(603)271-2902
Rudy Cartier, Jr., P.E.
Small Business Technical Assistance Program & Ombudsman
NH Department of Environmental Services
64 North Main Street
Concord, NH  03301-6509
(603)271-1379
(800) 837-0656 (in-state)
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9.5   RHODE ISLAND

State Pollution Prevention and Regulatory Assistance Contacts

Richard Enander
Pollution Prevention Program Manager
Rl Department of Environmental Protection
235 Promenade Street
Providence, Rl 02908
(401)277-3434, ext. 4411
Internet Address: www.state.ri.us/pg1txt.htm

State Small Business Contact

Richard Girasole
Rl Department of Environmental Protection
Rl Pollution Prevention Program, Small Business Contact
235 Promenade Street
Providence, Rl 02908
(401)277-3434, ext. 4414



9.6   VERMONT

State Pollution Prevention and Regulatory Assistance Contacts

Gary Gulka
Waste Prevention Section Chief
VT Department of Environmental Conservation
103 South Main Street
Waterbury, VT 05671 -0404
(802)241-3626
Internet Address: www.state.vt.us/anr

On-Site Assistance Program

David Boyer
Retired Engineers and Professionals (REAP)
P.O. Box 422
Randolph, VT 05060
(802) 728-1423 or (800) 363-REAP

State Small Business Contact

Kevin Bracey
Small Business Ombudsman
VT Department of Environmental Conservation
Air Pollution Control Division
103 South Main Street
Building 3 South
Waterbury, VT 05671-0402
(802)241-3841
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                                                        Anne Leiby
                                                        New England Environmental Assistance
                                                        Team
                                                        U.S. Environmental Protection Agency,
                                                        Region 1
                                                        JFK Federal Building (SPN)
                                                        Boston, MA  02203
                                                        (617)565-4974

                                                        e-mail: leiby.anne@epamail.epa.gov
9.7   FEDERAL RESOURCES IN NEW ENGLAND

EPA Regional Lithographic Printing Contacts

Sally Mansur
New England Environmental Assistance Team
U.S. Environmental Protection Agency, Region 1
JFK Federal Building (SPN)
Boston, MA 02203
(617)565-1378
e-mail: mansur.sally@epamail.epa.gov

EPA Pollution Prevention and Regulatory
Assistance Contacts

New England Environmental
Assistance Team (NEEATeam)
U.S. Environmental Protection Agency, Region 1
JFK Federal Building
Boston, MA 02203
(800) 90-NEEAT
Internet Address: www.epa.gov/region01

       Research Library -  EPA Region I employs a full-time research librarian who can assist you with
       questions concerning solid waste. To reach the regional research librarian, call (617) 565-3282.

       WasteWise - WasteWise is an EPA program that promotes voluntary waste reduction through
       prevention, recycling, and the purchase of recycled goods. Companies that commit to a waste
       reduction receive technical assistance in achieving their waste reduction  goals.  For more
       information on the WasteWise program or other solid waste or recycling  issues, call (800) 372-
       9473.

       Tips Hotline - EPA Region  I operates a centralized environmental tip and complaint hotline for
       use by the general public. The number is (888) EPA-TIPS.

       Small Business Ombudsman -- Our Small Business Ombudsman is Dwight Peavey, who can
       be reached at (617) 565-3230.

       Environmental Leadership Program -- The  Environmental Leadership  Program is for
       companies that have a demonstrated commitment to compliance and pollution prevention.
       Participants agree to a one year project to test innovative approaches to  environmental protection.
       Call (617) 860-4ELP for information.

       Project XL (Excellence in Leadership) -- Project XL encourages tests of innovative strategies
       that achieve cleaner and cheaper environmental results than traditional regulatory approaches.
       Call Anne Kelley at (617) 565-3426.

       Energy Conservation - EPA runs the Green Lights program for companies that want to reduce
       their lighting expenses (sometimes by half) by upgrading lighting without  compromising quality.
       Call Norman Willard at (617) 565-3702.
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9.8   OSHA

The Occupational Safety and Health Act (OSHA) imposes a wide variety of important requirements on
industry, including lithographic printers. A discussion of these requirements is beyond the scope of this
manual. Because the costs of non-compliance with OSHA regulations can be quite significant, you should
ensure compliance with OSHA regulations, just as you should with environmental regulations. This
section lists the OSHA contacts in the New England states.

State OSHA Contacts
Connecticut

James P. Butler
Commissioner
Connecticut Department of Labor
200 Folly Brook Boulevard
Wethersfield, CT  06109
(806)566-5123
                 Samuel Moore
                 7(c)(1) Project Manager
                 Connecticut Department of Labor
                 200 Folly Brook Boulevard
                 Wethersfield, CT  06109
                 (806) 566-4550
Maine

Alan C. Hinsey
Director
Maine Bureau of Labor Standards
State House State #82
Augusta, ME 04333
(207) 624-6400
                 Lester Wood
                 7(c)(1) Project Manager
                 Maine Bureau of Labor Standards
                 Division of Industrial Safety
                 State House State #82
                 Augusta, ME 04333
                 (207) 624-6460
Massachusetts

Christine Morris
Secretary
Executive Office of Labor
MA Department of Labor and Industries
1 Ashburton Place, Room 2112
Boston, MA 02108
(617)727-6573
                 Joseph LaMalva
                 7(c)(1) Project Manager
                 Commonwealth of Massachusetts
                 MA Department of Labor and Industries
                 1001 Watertown Street
                 West Newton, MA 02165
                 (617)727-3982
New Hampshire

Charles E. Danielson, M.D.,
Director
NH Department of Health
and Human Services
6 Hazen Drive
Concord, NH 03301-6527
(603)271-4501
MPH
Stephen Beyer
7(c)(1) Project Manager
NH Department of Health
Division of Public Health Services
6 Hazen Drive
Concord, NH 03301-6527
(903)271-2024
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Rhode Island

Patricia A. Nolan, M.D., MPH
Director
Rl Department of Health
3 Capital Hill
Providence, Rl 02908
(401)277-2231
Vermont

Mary S. Hooper
Commissioner
Vermont Department of Labor and Industry
120 State Street
Montpelier, VT 05602
(802) 828-2288
              Marie Stoeckel
              7(c)(1) Project Manager
              Rl Department of Health
              Division of Occupational Health
              3 Capital Hill, Room 206
              Providence, Rl 02908
              (401)277-2438
              Robert McLeod
              7(c)(1) Project Manager
              Vermont Department of Labor and Industry
              National Life Building, Drawer #20
              Montpelier, VT 05602
              (802) 828-2765
9.9   OTHER SOURCES
Regional Resources

Northeast Waste Management Officials' Association (NEWMOA)
129 Portland Street, Suite 601
Boston, MA 02114
(617)367-8558
       NEWMOA offers:
- Regional list servers for printers
- CD-ROM information on P2 for printers
- P2 clearinghouse
- State referrals.
Northeast Business Environmental Network (NBEN)
56 Island Street
P.O. Box 806
Lawrence, MA 01842
(508) 557-5475
Internet Address: www.nben.org
       NBEN offers:
- Value-added networking
- Non-political atmosphere
- Online research librarian
- Partnering opportunities
- A forum for best management practices.
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PRINTING-RELATED HOME PAGE SITES ON THE INTERNET

       Printers' National Environmental Assistance Center (PNEAC) - The PNEAC is jointly
       sponsored by the Illinois Hazardous Waste Research and Information Center (HWRIC), the
       University of Wisconsin's Solid & Hazardous Waste Education Center (SHWEC), the Graphic Arts
       Technical Foundation (GATF), and Printing Industries of America (PIA). The goal of the Center is
       to provide information about the environmental impacts of printing, and effective means to achieve
       compliance with environmental regulations.

       Internet Address: www.inhs.uiuc.edu/pneac/pneac.html

       GATF Home Page -- The Graphic Arts Technical Foundation (GATF) home page provides
       information about GATF membership, workshops, products, services, NSTF scholarships, etc.

        Internet Address: www.gatf.lm.com

       PIA Home Page -- The Printing Industries of America (PIA) home page provides information
       about PIA membership and a search feature to locate local PIA members.

       Internet Address: www.printing.org

       PINE Home Page - Printing Industries of New England (PINE) offers Environmental, Safety and
       Health visits to your shop, at no cost, to assist in your understanding and compliance with federal
       and state regulations. The PINE homepage provides information about membership and other
       services.

       Internet Address: www.pine.org

       NAPL Home Page -- The National Association of Printers and Lithographers (NAPL) home  page
       describes NAPL, lists NAPL resources, equipment vendors and manufacturers, etc.

       Internet Address: www.napl.org/napl/home.html

       Envirosense: Printing P2 - This home page contains case studies, pollution prevention
       practices, regulations, and vendor information of interest to printers.

       Internet Address: www.seattle.battelle.org/es-guide/print/print.htm

       U.S. Screen Printing Institute (SPI) -- This home page lists SPI products, services, industry
       suppliers, etc.

       Internet Address: www.usscreen.com

       Craftnet Web Site -- The International Association of Printing House Craftsmen home page
       describes the Craftsmen's clubs, seminars, etc.

       Internet Address: craftnet.eas.asu.edu/welcome.html
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 VIDEO RESOURCES

       Green and Profitable National Videoconference -- A 2-hour video of the May 17, 1996, national
       videoconference explaining compliance requirements and waste prevention and pollution
       prevention techniques for lithographic printers.

       Green and Profitable Printing Video Training Series - Four video modules that explore
       practical waste reduction strategies for small and  medium lithographic printers. The fee for this
       series and accompanying viewer notes is $35, prepaid.

 Both videos can be obtained from the University of Wisconsin Extension. Contact:

 Marilyn McDole
 University of Wisconsin-Extension
 Solid & Hazardous Waste Education Center
 610 Langdon Street, Room 529
 Madison, Wl  53703
 (608)262-0910
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       MASSACHUSETTS

       As part of a pilot program called the Massachusetts Printers
       Partnership, Massachusetts has developed a workbook
       which explains environmental requirements and pollution
       prevention opportunities applicable to commercial printers.

       Massachusetts plans to incorporate the workbook
       standards into regulations in  mid-1997. The workbook, as well as the information regarding
       regulatory developments, is available at: http://www.magnet.state.ma.us/dep.

       For more information call:

                    Nancy Wrenn
                    Bureau of Waste Prevention
                    Massachusetts Department of Environmental Protection
                    (617)292-5587
Massachusetts Requirements

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