United States
             Environmental Protection
             Agency	
               Enforcement and
               Compliance Assurance
               (2224A1	
EPA-305-00-006
September 2000
&EPA
IMPLEMENTATION GUIDANCE FOR
OFF-SITE WASTE AND RECOVERY
OPERATIONS (OSWRO) NESHAP

INTERRELATIONSfflPS WITH OTHER
RELATED EPA AIR RULES
                             EPA Office of Compliance

-------
                                      Disclaimer

The Office of Air Quality Planning and Standards (OAQPS), Enforcement and Compliance
Assurance (OECA) and Region 5 Office of the U S Environmental Protection Agency have
reviewed this document and approved it for publication.

When using this document, remember that it is not legally binding and does not replace the
"National Emissions Standards for Hazardous Air Pollutants From Off-Site Waste and Recovery
Operations" (July 1, 1996, 61 FR 34158 and amended July 20, 1999, 64 FR 38949-38992) or any
state and local rules that may apply to your facility.

This document does not constitute rulemaking by the EPA and may not be relied on to create a
substantive or procedural right or benefit enforceable at law or in equity, by any person.  The EPA
may take action at variance with this document and its internal procedures.

-------
                                     Contents
Section
                                                                            Page
Tables	--.	  iv

1.0   Introduction	"...-..	1-1
   1.1 General Summary of OSWRO NESHAP	1-1
      1.1.1   What is the OSWRO NESHAP 7	.	1-1
      1.1.2   What subparts in 40 GFR part 63 apply to the OSWRO NESHAP ?	 1-1
      1.1.3   What is an off-site material as the term is applied to the OSWRO NESHAP ?  1 -2
      1.1.4   What types of facilities are potentially subject to the OSWRO NESHAP ?  . . . 1-2
      1.1.5   What are the affected sources at a facility subject to the OSWRO NESHAP ? . 1-5
      1.1.6   What are the general standards for affected sources ?  	 1-5
      1.1.7   For affected sources that use air emission controls, what are the control
             requirements ?  	........_	 1-7
      1.1.8   Where can I obtain more information about the specific OSWRO NESHAP
             requirements ?  ....	 . .		 1-7
   1.2 Additional Information About Rule Requirements	.-,..'	1-7
      1.2.1   Where can I obtain more information about the specific OSWRO NESHAP
             requirements ?	......;.,.....	 1-7
      1.2.2   If I need additional assistance, whom can I ask for help ?  . .	 1-7

2.0   Interrelation with other NESHAP				2-1
   2.1 Overlap of OSWRO NESHAP with Other NESHAP ....	2-1
      2.1.1   Why can the owner and operator of a facility be subject to both the OSWRO
             NESHAP and another NESHAP ?  .		 2-1
      2.1.2   Which NESHAP have requirements that potentially may overlap with the
             OSWRO  NESHAP?	 . ...	 .	2-2
      2.1.3   How is the OSWRO NESHAP implemented when the facility also is subject
             to another NESHAP ?	  ...	2-7
   2.2 Implementing OSWRO NESHAP In NESHAP Regulatory Overlap Situations ...... 2-7
      2.2.1   How is the OSWRO NESHAP implemented at a facility subject to another
             NESHAP when the affected source is already using air emission controls to
             comply with the other NESHAP ?  . . .			2-7
      2.2.2   How is the OSWRO NESHAP implemented at a facility subject to another
             NESHAP when the affected source is not required to use air emission controls
             under the other NESHAP ?	2-8
      2.2.3   How is the OSWRO NESHAP implemented at a facility subject to another
             NESHAP when the affected source is not regulated under the other
             NESHAP?	:	.			2-8

-------
                                Contents (continued)
Section
Page
3.0   Interrelation of OSWRO NESHAP with Relevant RCRA Regulatory Programs ..... 3-1
   3.1 Applicability of OSWRO NESHAP at RCRA Hazardous Waste Facilities .	3-1
      3.1.1   What are the "RCRA air standards" ?....•	 . . .".		3-1
      3.1.2   What is the difference between a "waste" under OSWRO NESHAP and a
             "hazardous waste" under the RCRA air standards ?'...'	3-2
      3.1.3   Why can the OSWRO NESHAP apply to facilities subject to the RCRA air
             standards ?	3-3
      3.1.4   What type of waste and recovery operations are potentially subject to the
             OSWRO NESHAP and also subject to the RCRA air standards ?	3-4
      3.1.5   Which of the RCRA air standards may apply to affected sources at a facility
             subject to the OSWRO NESHAP ?		3-6
   3.2 Applicability of OSWRO NESHAP at RCRA Used Oil Management Facilities	3-6
      3.2.1   Why can the OSWRO NESHAP apply to facilities subject to the RCRA
             used oil management rules ?		• • • 3-6
      3.2.2   What is the difference between "used oil" as defined for implementation
             of the OSWRO NESHAP and "used oil" for implementation of the RCRA
             used oil management rules ?	 3-6
      3.2.3   What type of used oil management operations regulated by RCRA are
             potentially subject to the OSWRO NESHAP ?	3-9
      3.2.4   If a used oil processing or refining operation is subject to the OSWRO
             NESHAP, how are the technical requirements of the OSWRO NESHAP
             implemented ? 	,	• •	3-9
   3.3 Comparison of OSWRO NESHAP and RCRA Air Standards Technical
       Requirements		'.	3-9
      3.3.1   How does the action level, determined under the OSWRO NESHAP, compare
             with the RCRA air standards?	 ... . ... . . .	3-9
      3.3.2   Are there affected sources which are exempted under one rule but not the
             other ?	3-12
      3.3.3   How do the technical control requirements under the OSWRO NESHAP
             compare to the technical control requirements under the RCRA air
             standards?			.'-. ........ .  . . ;.	 3-14
      3.3.4   Which technical requirements apply to an affected source when it must use
             air emission controls under both the OSWRO NESHAP and the RCRA air
             standards?	 . . .	 . .		 - . 3-20
   3.4 Permitting Considerations	-	• • 3-22
      3.4.1   What is the relationship between a facility's CAA Title V operating permit
             with the facility's RCRA Subtitle C permit ?  ....		3-22

                                Contents (continued)

-------
Section
Page
       3.4.2  How does the program policy of a "permit shield" as implemented under
             the CAA differ from the "permit-as-a-shield" policy implemented under
             RCRA ?  . . .	. .	3-23
       3.4.3  Can the sources in a facility's CAA Title V operating permit be different
             than those listed in the facility's RCRA Subtitle C permit ? . . .	3-24
                                          m

-------
                                    Tables
Number
Page
1-1    OSWRO NESHAP Subparts in 40 CFRpart 63	1-3
1-2    Waste and Recovery Operations subject to OSWRO NESHAP  	...	  1-4
1-3    OSWRO NESHAP Affected Sources	.		,	1-6
1-4    OSWRO NESHAP Air Emission Control Requirements for Affected Sources 	1-8
2-1    NESHAP Source Categories With Waste or Recovery Operations That
      Potentially May Be Subject to the OSWRO NESHAP If the Facility Receives
      Off-Site Material  	-.		• • - -	2-3
3-1    Waste or Recovery Operations Potentially Subject to OSWRO NESHAP and RCRA
      Air Standards	• •	3-5
3-2    Comparison of Affected Sources Regulated Under OSWRO NESHAP and RCRA
      Air Standards	'••	•	3-7
3-3    Comparison of Process Vent Units Regulated Under OSWRO NESHAP and RCRA
      Air Standards	• -	3-8
3-4    Comparison of 500 ppmw "Action Level" Determination Procedures Under
      OSWRO NESHAP with RCRA Air Standards		. .	3-11
3-5    Comparison of Exemptions from Using Air Emission Controls for Affected-Sources
      Managing Hazardous Waste Allowed Under OSWRO NESHAP and RCRA Air
      Standards	• • • • 3-13
3-6    Comparison of Air Emission Control Requirements Under OSWRO NESHAP with
      RCRA Hazardous Waste TSDF Standards	,.		3-16
3-7    Control Device Performance Requirements for Both the OSWRO NESHAP and
      the RCRA Air Rules	 ...	-	3-19
3-8    Equipment modifications that can be Used on Components Subject to the Equipment
      Leak Standards	 3-20
                                       IV

-------
                   1.0   INTRODUCTION AND BACKGROUND
    When developing the National Emission Standards for Hazardous Air Pollutants from
Off-Site Waste and Recovery Operations, the U.S. Environmental Protection Agency (EPA)
recognized that the potential exists for regulatory overlap with other national standards
promulgated by the Agency to meet congressional directives established under the Clean Air
Act (CAA) and Resource Conservation and Recovery Act (RCRA). Section 112(n)(7) of the
CAA voices a strong preference for consistency of National Emission  Standards for
Hazardous Air Pollutants (NESHAP) with RCRA standards, where practicable.  Similarly,
section 1006(b) of RCRA requires that the air standards be consistent with and not duplicative
of CAA standards. The provisions of the National Emission Standards for Hazardous Air
Pollutants from Off-Site Waste and Recovery Operations have been developed to minimize, if
not eliminate, regulatory overlap to the extent allowed under these different legislative acts.

    The purpose of this document is to describe the interrelationship of the National Emission
Standards for Hazardous Air Pollutants from Off-Site Waste and Recovery Operations with
other NESHAP as well as national air standards established under RCRA for hazardous waste
treatment, and disposal facilities. The remainder of this section presents a general summary of
the OSWRO NESHAP.  Section 2 discusses the interrelationship of the OSWRO NESHAP
with other NESHAP. The interrelationship of the OSWRO NESHAP with RCRA air
standards is discussed in  Section 3.
 1.1 GENERAL SUMMARY OF OSWRO NESHAP

•1.1.1 What is the "OSWRO NESHAP"?

    The "OSWRO NESHAP" is a set NESHAP applicable to certain facilities that operate
 waste management and recovery processes for materials received from off-site. These
 selected waste management and recovery operations are not subject to federal air standards
 under other NESHAP in 40 CFR parts 61  and 63; and are referred to as "off-site waste and
 recovery operations" (OSWRO) .  The OSWRO NESHAP establishs national emission
 limitations and work practice standards for hazardous air pollutants (HAP) emitted from off-
 site waste and recovery operations.
                                        1-1

-------
1.1.2 What subparts in 40 CFR part 63 apply to the OSWRO NESHAP?

    The specific provisions of the OSWRO NESHAP are established by six subparts in 40
CFR part 63 as listed in Table 1-1.  In addition, general provisions in 40 CFR 63 subpart A
are applicable to all facilities regulated under 40 CFR part 63 are applied to facilities subject to
the OSWRO NESHAP.
1.1.3  What is an off-site material as the term is applied to OSWRO NESHAP?

     An off-site material is a material that is either a -waste, used oil, or used solvent (as
these terms are defined in the rule) that contains organic HAP, and this material is not
generated at the facility but is instead  shipped or transferred to the facility from another
location. Off-site material includes any one of the following:

      •  Waste is any material generated from industrial, commercial, mining, or agricultural
         operations or from community activities which is discarded, discharged, or is being
        treated before being discarded or discharged. This definition in the OSWRO
        NESHAP is consistent with the definition of waste used for other NESHAP.

      •  Used oil is any oil refined from crude oil or any synthetic oil that has been used and
         as a result of such use is contaminated by physical or chemical impurities. This
         definition in the OSWRO NESHAP is the same definition of used oil in the RCRA
        regulation under 40 CFR 279.1.

      •  Used solvent is a mixture of aliphatic hydrocarbons or a mixture of one and two ring
        aromatic hydrocarbons that has been used as a solvent and  as a result of such use is
        contaminated by physical or chemical impurities.
1.1.4  What types of facilities are potentially subject to the OSWRO NESHAP?

     You are subject to the OSWRO NESHAP if you own or operate one of the waste or
recovery operations listed in Table 1-2 that:  1) meets the applicable qualifiers for the
operation as specified in the table; 2) receives off-site material; and 3) this operation is
located at, or is part of & major source of HAP emissions. A major source means any
stationary source or group of stationary sources within a contiguous area and under common
control that emits or has the potential to emit, considering controls, in aggregate, 10 tons or
more per year or more of any HAP or 25 tons per year or more of any combination of HAP.
                                        1-2

-------
               Table 1-1.
OSWRO NESHAP Subparts in 40 CFR part 63
40 CFR 63
Subpart DD
Subpart OO
Subpart PP
Subpart QQ
Subpart RR
Subpart VV
Subpart Title
National Emission
Standards
for Hazardous Air Pollutants
from Off-Site Waste and
Recovery Operations
National Emission
Standards
for Tanks-Level 1
National Emission
Standards 'for Containers
National Emission
Standards for Surface
Impoundments
National Emission
Standards for Individual
Drain Systems
National Emission
Standards for Oil-Water
Separators and Organic-
Water Separators
Specifies Requirements under
OSWRO NESHAP for ...
• Applicability
• Compliance dates
• General standards for affected source
• Level 2 air emission controls for tanks
• Transfer system air emission controls
• Closed vent systems and control devices
• Testing and initial compliance
• Inspections and monitoring
• Notifications, reports, and records
• Cross-referenced by Subpart DD
• Level 1 air emission controls for tanks
• Cross-referenced by Subpart DD
• Level 1 air emission controls for containers
• Level 2 air emission controls for containers
• Level 3 air emission controls for containers
• Cross-referenced by Subpart DD
• Air emission controls for surface
impoundments
• Cross-referenced by Subpart DD
• Air emission controls for individual drain
systems
• Cross-referenced by Subpart DD
• Air emission controls for oil-water separators
and organic-water separators
»
                  1-3

-------
                       Table 1-2.
Waste and Recovery Operations Subject to OSWRO NESHAP
Waste or Recovery Operation
Hazardous waste treatment, storage, and
disposal
Hazardous wastewater treatment
Other wastewater treatment
Hazardous waste recycling
Used oil processing or re-refining
Used solvent recovery
Qualifiers operation must meet for it to be
potentially subject to OSWRO NESHAP
Operation is a TSDF under either 40 CFR part
264 or part 265.
Operation is exempted from RCRA hazardous
waste permitting because the operations meet
conditions specified in 40 CFR 264.i(g)(6) or
40CFR265.1(c)(10).
Operation meets all 3 conditions:
1. Regulated under either section 402 or
307(b) of the Clean Water Act;
2. Not owned by a "state" or "municipality" as
defined by section 502(3) and 502(4),
respectively, of the Clean Water Act; and
3. Operation is the predominant activity
performed at the facility site
Operation is exempted from RCRA hazardous
waste permitting because the operations meet
conditions specified in 40 CFR 264.1 (g)(2) or
40CFR265.1(c)(6).
Operation is regulated under 40 CFR 279
subpart F
Operation is not part of a chemical, petroleum,
or other manufacturing process that is required
to use air emission controls by another subpart
of 40 CFR part 61 or 40 CFR part 63
                          1-4

-------
1.1.5  What are the affected sources at a facility subject to the OSWRO NESHAP?

     The OSWRO NESHAP applies to three groups of organic HAP emission sources that
operate in a waste or recovery operation subject to the rule: off-site material management
units,  process vents, and equipment leaks.  Table 1-3 lists the affected sources subject to the
requirements of the OSWRO NESHAP. An_ off-site material management unit means a tank,
container, surface impoundment, oil-water separator, organic-water separator, or transfer
system used to manage off-site material. A process vent means an open-ended pipe, stack, or
duct through which a gas stream containing HAP is continuously or intermittently discharged
to the atmosphere. Under the rule, a process vent is not a pressure-relief vent; a vent used as a
safety device as defined in the rule; an open-ended line or other vent that is subject to the
equipment leak control requirements under the rule; or a stack or other vent that is used to
exhaust combustion products from a boiler, furnace, process heater, incinerator, or other
combustion device. The equipment leak standards apply to each pump, compressor, agitator,
pressure relief device, sampling connection system, open-ended valve or line, valve,
connector, or instrumentation system that contains or contacts off-site material having a total
HAP concentration equal to or greater than 10 percent by weight; and the equipment
component is intended to operate for 300 hours or more during a calendar year in off-site
material service, as defined in the rule.
1.1.6  What are the general standards for affected sources?

     For an affected off-site material management unit or process vent, you must meet one
of the following alternatives:

        1. Determine that the average volatile organic hazardous air pollutant (VOHAP)
          concentration of the off-site material managed in the affected source is less than
          500 ppmw mass weighted average. The rule specifies the test protocol to be used
          for determining the VOHAP concentration, or

        2. Install and operate air emission controls, or

        3. Treat the off-site material to remove or destroy the HAP before you place the
          material in the affected source. The rule provides alternative treatment standards
          with which you may choose to comply, or

        4. Meet one of the unit-specific control requirement exemptions specified in the rule.
                                         1-5

-------
           Table 1-3.
OSWRO NESHAP Affected Sources
Source Type
Tanks
Surface impoundments
Containers
Oil/water and chemical/water
separators
Material transfer systems
Process vents
Equipment leaks
Qualifiers source must meet for it to be an affected
source subject to OSWRO NESHAP
Used for storage or treatment of off-site material
Used for storage or treatment of off-site material
Containers having a capacity > 0.1 meters3 .
(-26 gallons) and are used for storage or treatment
of off-site material
Used for treatment of off-site material
Used for transfer of off-site material
Used on any of the following off-site material
treatment processes:
• Distillation
• Fractionation
• Thin-film evaporation
• Solvent extraction
• Steam stripping
• Air stripping
Equipment components (e.g., pumps and valves)
that contain or contact off-site material having an
organic HAP concentration > 10%
              1-6

-------
1.1.7  For affected sources that use air emission controls, what are the control
      requirements?

      The control requirements for affected sources that use air emission controls are
summarized in Table 1-4.  See the applicable subpart for the affected source for the specific
control requirements that must be met.      ,
1.2 ADDITIONAL INFORMATION ABOUT RULE REQUIREMENTS

1.2.1  Where can I obtain more information about the specific OSWRO NESHAP
      requirements?

     More information about the specific OSWRO NESHAP requirements is available in the
EPA document, "The Plain Language Implementation Assistance Document for 40 CFR Part
63 Subpart DD (Off-Site Waste and Recovery Operations NESHAP)" (EPA-456/R-99-007).
An electronic version of this document can be downloaded from the Internet at
http://www.eDa.gov/ttn/uatw/ofIvvaste/rioswao.html.
1.2.2  If I need additional assistance, whom can I ask for help?

     LorenDenton
     U.S. EPA Region 5          '
     312-886-6814
                                       1-7

-------
                                           Table 1-4.
      OSWRO NESHAP Air Emission Control Requirements for Affected Sources
      Affected Source Type
            Air Emission Control Requirements
             Tanks
Required control level determined by vapor pressure of
off-site material, tank capacity, and management operation
performed in tank

Level 1 — Use either:
— Tight-fitting cover or fixed-roof
— Cover and vent to control device

Level 2 —. Use either:
—  Fixed-roof with internal floating roof
—  External floating roof
-  Cover and vent to control device
-  Pressure tank                                •
-  Locate in enclosure vented to combustion control device
      Surface impoundments
Use either:
— Floating membrane cover
— Cover and vent to control device
           Containers
Required control level determined by organic content of
off—site material, container capacity, and whether the
container is used for waste stabilization process

Level 1 — Use either:
- Container that meets DOT specifications 
- Tight-fitting cover
— Organic vapor suppression barrier

Level 2 — Use either
— Container that meets DOT specifications (a)
- Leak- tight container as tested by Method 21
- Vapor-tight container as tested by Method 27

Levels — Use either
— Cover and vent to control device -
— Place in enclosure vented to combustion control device
Notes:
       (a) A container that meets the applicable U.S. Department of Transportation (DOT)
           regulations for packaging hazardous materials for transportation under 49 CER
           parts 178 and 179.
                                               1-8

-------
                               Table 1-4.  (Concluded)
 Affected Source Type
            Air Emission Control Requirements
      Oil/water and
chemical/water separators
Use either:
- Floating roof(b)
- Fixed-roof vented to control device
— Pressurized separator
        Material
    transfer systems
Individual drain systems, use either.
- Covers, water seals, and other drain closure devices
- Continuous hard-piping
- Vent system through control device

Other transfer systems, use either
- Covers
- Continuous hard-piping
- Enclosure vented to control device
     Process vents
Standard applied to each individual affected process vent
at facility
Each affected process must be vented through a closed-
vent system to a control device
Control device must achieve >95 % control efficiency
    Equipment leaks
Implement leak detection and repair program that meets
requirements in either:
- 40 CFR 61 Subpart V             •
- 40 CFR 63 Subpart H
 Notes:
   (b)     For parts of the separator where it infeasible to use a floating roof, such as a weir
           mechanism, then use a fixed-roof vented to a control device.
                                           1-9

-------
               2.0  INTERRELATION WITH OTHER NESHAP
     This section discuses the implementation of the OSWRO NESHAP at facilities that may
also potentially be subject to compliance with other NESHAP. The applicability of the
OSWRO NESHAP to these facilities is discussed. Compliance -with the rule is discussed for
situations when a facility is subject to both the OSWRO NESHAP and another NESHAP.
2.1 OVERLAP OF OSWRO NESHAP WITH OTHER NESHAP

2.1.1  Why can the owner and operator of a facility be subject to both the OSWRO
       NESHAP and another NESHAP?

     The OSWRO NESHAP applies to six specific types of waste management or recovery
operations used to manage off-site material (as specified in the rule), and these operations are
located at, or are part of a facility that is a major source of HAP emissions.  A waste
management or recovery operation subject to the OSWRO NESHAP may be the predominate
activity (or even the only) performed at a facility (e.g., a commercial TSDF, solvent recycler,
used oil reprocessor or re-refiner).  Alternatively, this operation may be an ancillary operation
performed to support other processes at a facility. In this case, waste management and
recovery operations that meet the OSWRO NESHAP applicability criteria are sometimes
located at a chemical plant, petroleum refinery, manufacturing plant, or other facility that is
subject to another NESHAP. For example, a waste management or recovery operation
located at a chemical manufacturing plant that is subject to 40 CFR 63 subparts F, G, and H -
National Emission  Standards for Organic Hazardous Air Pollutants from the Synthetic
Organic Chemical Manufacturing Industry (referred to hereafter as the "HON") may receive
materials from another of the company's facilities for treatment.

     In developing the OSWRO NESHAP, the EPA recognized this potential for regulatory
overlap of the rule  with other NESHAP and, therefore, added provisions to the OSWRO
NESHAP to avoid duplication or overlap with standards under other NESHAP that
potentially can be applicable to the same group of affected sources. While these provisions
address many of potential overlap situations that can be anticipated, special or unique site-
specific situations do still exist where a tank, process vent, or other affected source is subject
to air emissions standards under both the OSWRO NESHAP and another NESHAP.
                                       2-1

-------
2.1.2   Which NESHAP have requirements that potentially may overlap with the
       OSWRONESHAP?

     In general, the NESHAP with requirements that potentially overlap with the OSWRO
NESHAP are those NESHAP that include provisions regulating organic HAP emissions from
wastewater treatment operations. Under certain site-specific circumstances, the applicability
of the OSWRO NESHAP to some hazardous waste management,  recycling operations, and
solvent recovery operations may overlap with another NESHAP when those units are used to
handle wastes,  used solvents, or used oil shipped to the facility site^ Table 2-1 provides a
general guide identifying which NESHAP promulgated under 40 CFR part 63 (as of April 28 ,
2000) have requirements which could potentially overlap with the OSWRO NESHAP.  This
table is not intended to be comprehensive but rather used as a guide to identify likely facilities
where other NESHAP may potentially overlap with the OSWRO NESHAP.  Due to site-
specific conditions regarding a particular type of waste management or recovery operation
handling off-site material, unique circumstances may exist for a facility overlap of the
OSWRO NESHAP with another NESHAP not indicated in the table.

     The OSWRO NESHAP contains provisions to  avoid overlap of the rule with other
NESHAP that  specifically regulate air emissions from the off-site management of wastes
containing organic HAP. The OSWRO NESHAP explicitly states under the rule applicability
that a waste is not an "off-site material" when it is transferred from a chemical manufacturing
plant, petroleum refinery, or coke by-product recovery plant subject to the National Emission
Standards for Benzene Waste Operations (40 CFR 61 subpart FF), and the owner or operator
of the facility from which the waste is transferred complies with the provisions of §61.342(f).
A similar exemption is stated in the rule for chemical manufacturing plants subject to the
process wastewater standards under National Emission Standards for Organic Hazardous Air
Pollutants from the Synthetic Organic Chemical Manufacturing Industry (see 40 CFR 63.132
through 63.147). The OSWRO NESHAP states that a waste is not an "off-site material"
when it is transferred from a facility subject to the HON and the owner or operator of the
facility from which the waste is transferred complies with the provisions  in §63.132(g).  In
both of these situations, an owner or operator complying the requirements of the applicable
NESHAP is not subject to the OSWRO NESHAP. Thus, regulatory overlap of the OSWRO
NESHAP and these other NESHAP is avoided by these applicability exemptions which have
been included in the rule.
                                        2-2

-------
 4)



3
2?;
*«

  ,
§ fa
  OT

«B

•
«2

s t>
5 Gd
O o-g
CO A


51*
ffi
CO

C
O
I
S.
o O
re >,
a I
G) O
S?
•e o
re u
.Q m
3
CO >
O
AjeAooay
)U3A|os pssp

6uiuuay-ay jo
Buisssoojd no pssn


BuipAosy
e;seyv\ snopjezBH

+U91UJE9JX
J3}BM3)S6y\/\ J31J)Q
1U31U163J 1
dQSl

CD t
• if
o co





CD
•e
re
o.
U.
O
2
•§ Jr
^> C ^^
^ 13 §
O "O ^^^
**" Q) -
^"05 CM
O O) —
o)"5 *c
Q) c P-
?5 o ^
^J ^ ^™
^ O
|§s
° CQ
W§
re
I
Q.
X
CO
UJ









^




^
^
O

CO
0
^1
3
CO










=
o
X
jC


CO
.—
w
•t^
S.
c
to
15
organic chemic
_0
'CD
.c
"c
co






^




^
v
X
LL
•S
(0
D.

CO










z~*"
o
X
CD
J—
	
CO
~
—i
•+?
32.
g
tn
"to
organic chemic
o
"CD
-C
"c
co






^




^
^

—
to
CL
co

to

to
JD
1
E
Q.

O"
CD

_
O
CO
CO
CD
vl
T3
CD
[ro
^«_i
O
CD
CD
£
o
•4-*
rocesses subjec
CL
c .
'co
•c
CD
O














—1
•c
to
Q.
co

























n batteries
CD
O
CD
O
O














^
•e
CO
CL
co

























to
CD
'o
CO
'E
_CD
o
Q














z:
•c
CO
CL
.0
co

c
CD
-*-*
CO
;N
TJ
0
c
to
E
3
"E
o
o
•o
cr
CO
CO
c.
"5
r>
o

"o
CD
CD
E
^s
E
decorative chro
T3
CO
•a
CO
X.














o
CO
CL
JO
co
























c.
0
1
CD
CO
CD
'x
o
CD
C
JD
ffi














a
•e
CO
CL
.a
3
CO






















CO
1

process cooling
CO
*L_
"to
3
T3
—














cc
•c
to
JD
CO























to
CD

distribution facil
CD
c
~0
to
CO
CD











^


co
-e
CO
CL
3
co

























o.
CO
Q.
-o
C.
CO
CL
CL














1-
•e
CO
CL
CO























CO
c:
"E
CO
CD
O
c;
CD
"o
CO
T3
_CD
"to
CD
CO
0
CO












^


ID
•c
to
CL
Jd
CO























to
c
to
CD
•0
C
to
to
CD
E
"o
Q.
CL
3
O
CD
                                 20
                                -J

-------
 •a
 cu
• S
 'o

C
O
is
<5
-0 0.
o> o
"re >,
3 S
w >
/y o
_ a>
•e o
re CD
a.*;
n <0
5S
*!
£
c
o


juSos^n

Bumusy-sy jo
Buisseoojd no pssn


BuiioAosy
31SBAA SnODJBZBU
\ N\ H H

}.U9UJ}.B3JJ[
J31BM31SBAA J3U1Q
.

JU3UJJB9JJ_
JSJBMSJSEM snopjBZBH


dQSl
ajSB/w snopjBZBH
0 W
eo
(0
•c
re
a.
a:
LL.
o

^
M *—
.— CD

3? c ®
^* 13 §
O T3 ^*
**" Q} ^~
£*"C8 CM
O O) i-m
cn"5 *c
o c o.
•re §<
O 2 *r
4, Q- °
S E °>
|Sre
wl
re
. I-
Q.
1
LU
•z.






















Subpart W





c
o
*~
o
3
•a
o
Q-
CD
-o
'E
CO
~o
n

C.
o

>>
1
oxy resins production and nor
Q.
LU




















Subpart X






















O)
"33
.£
(0
T3
CO
_CD
CO
-o
C
o
o

CO




















CD
CL
3






















irine vessel loading
Cu
2




















Subpart AA






















osphoric acid manufacturing
_f^
DL




















m
m
CD
Q.
.£2
3




















O)
,C
osphate fertilizers manufactur
J~
o_















^




Subpart CC






















troleum refineries
CD
CL
.v



















LU
LU
CD
Q.
CO






















ignetic tape manufacturing
ID
^
^

















^

O
o
•e
CO
Q.
3
co













(O
CD
^r
"o
•2


o
5
rospace manufacturing and re
CD





















Subpart HH






















and natural gas production
. T^
O




















CO
Q.
CO






















'ro
Q-
£
Q.
Ic
CO
T3
CO
D5
C
'3
J3
Q.
r~
CO
^



















Subpart JJ






















jod furniture manufacturing
.^
>




















CD
Q.
CO






















D)
C
CO
Q_
CO
O)
C
*r~
Q.




















Subpart LL




















to
"^
mary aluminum redaction plai
T~
Q-
                                                 2-4

-------
t>
 «
 s
 o
c
o
1

s&
g,s>
0) O
H o
CO CD
0)
«*-«
(fl
i
O
*£?Sn
Bumyay-ay jo
Buissaoojd no pasn
BuipAoay
a^BM snopjezEH
ViauqeaJX
jsiBMstsBMJamO
1U3U.JB3J1
ja;BMa;sBM snopjBZBH

^SBM^-BH
Sr
rr
0 CO
co
CO
-c
CO
Q.
o:
u_
o
o
is
s =°
^ *•• CO
w CO CS
o J5>—
I lJ
08*-
||8 .
«S
I
Q.
UJ
•z.













>
•c
CD
0.
JO
to
















:al resins production
S












>
•c
CD
Q-
J2
CO
















rogen fluoride production
T^
X











Subpart YY
















carbonates production
o
Q.











Subpart YY
















lic/modacrylic production
e-
o












Subpart CCC
















c/>
CD
CJ
0
CL
_J
O
X
0)
0
"Q.
0)
to











Q
Q
Q
CO
Q.
J3
3
co
















sral wool production
w
^











Ul
UJ
•e
CO
EL
CO
















ardous waste combustors
N
CO
X











O
o
CD
t:
CD
Q.
3
CO
















rmaceuticals manufacturing
CO
CL











X
X
X
CO
Q.
JO
to















-------
•8
 o>

 3
 e
 o
c
o
1
T3 °-
aj O
|&
i»>
Q) O
01 O
Q ^
•C 0
re cu
co 5
|
o


,u^s^n
Bumyay-ay jo
Buissaoojd HO Pssn

6ui|oAoay
S^SB/W snopjBZEH


^uamjE3Ji
jajBMS^SBMJSM»0

ja^EMsjsBM snopjBZEH

jasi
ajSBM snopjBZEH

M -ti
If
0 tfi
co
 ^ o
>— *— '
O T3 M
&Hs~
O O) —
Il'J-
o 2-
0)01°
O c «"
i_ " CB
h (D ra
O ^
CO ^
I'
a.
CO
LLJ





















~j?
"Z.
•e
CD
Q.
3
co
















D)

.!ir
3
t)
1
C
1
CO
CD
E>
CD

:j~
"o
Q

^











^



O
o
0
-c
CD
Q-
^a
CO

















CO

'co
CD
•c
CD
CO
CD
1^
"o
Q.

-^
QL
-3
o

5















Q_
CL
Q_
t:
CD
Q.
J2
co



















c'
O
"o
3
O
a.
CO
o
o
a.
CD
.g
"CD
"o
a.















UL
QL
•e
CD
Q.
3
CO





















£
ry aluminu
CD
T3
C
o
o
CD
CO















(—

Subpart T





















en
"55
CO
T3
CD
CD

^"»
CD
£
"~
Q.











V




>
Subpart V












_
>
0
CO


o
^
-1^
CD
S
"CD
£
cu
o

>^
o
'15
3
CL















X
X
Subpart X





















c
0
lys .product
u
__
CD
O
CD
U-
                                                     2-6

-------
2.1.3  How is the OSWRO NESHAP implemented when the facility also is subject to
       another NESHAP?

     At a facility where the owner and operator is subject to requirements under both the
OSWRO NESHAP and another NESHAP, the standards under the OSWRO NESHAP apply
only to those specific affected sources that are part of one of the waste management
operations or recovery operations regulated under the rule and used to manage off-site
material.  The OSWRO NESHAP does not apply to any other units or equipment at the
facility. For example, the standards for tanks under the OSWRO NESHAP apply only to
those tanks used to manage off-site material for the six specific types of regulated waste
management or recovery operations.  Tanks at the facility used for other processes are not
subject to standards under the OSWRO NESHAP although these tanks may be subject to
standards under the other NESHAP applicable to the facility. In addition, any tanks used as
part of one of the six specific types of regulated waste management or recovery operations
(but not used to manage off-site material, e.g., tanks used exclusively to store waste or used
solvent generated on-site at the facility) are not subject to standards under the OSWRO
NESHAP regardless of organic HAP  content.  Again, these tanks may be subject to standards
under the other NESHAP applicable to the facility. Therefore, situation may occur where a
facility is subject to the OSWRO NESHAP and another NESHAP without encountering any
direct overlap of requirements because the two rules are not applicable to the same set of
affected sources.
2.2  IMPLEMENTING OSWRO NESHAP IN REGULATORY OVERLAP
     SITUATIONS WITH OTHER NESHAP REGULATIONS.

     This section discusses the implementation of the standards under the OSWRO NESHAP
to an affected source when that source is located at a facility subject to both the OSWRO
NESHAP and another NESHAP.  Three possible regulatory overlap situations are discussed.

2.2.1   How is the OSWRO NESHAP implemented at a facility subject to another
       NESHAP when the affected source is already using air emission controls to
       comply with the other NESHAP?

     To address the regulatory overall situation at a facility where an affected source would
be required to use air emission controls under both the OSWRO NESHAP and another
NESHAP, the OSWRO NESHAP contains provisions to avoid overlapping the technical air
emission control requirements under the two NESHAP. The OSWRO NESHAP explicitly
states in § 63.683(b)(2)(i) that an off-site material management unit is not required to meet
the applicable air standards in the OSWRO NESHAP if this unit is also subject to another
subpart under 40 CFR part 61 or 40 CFR part 63, and the owner or operator is controlling the
organic HAP that are emitted from the unit in compliance with the provisions specified in the
other applicable subpart under part 61 or 63. For example, if a tank at a facility subject to
                                       2-7

-------
both the OSWRO NESHAP and the HON is used to manage an off-site material with a
VOHAP concentration greater than 500 ppmw, the owner or operator is not required to meet
tank standards under the OSWRO NESHAP as long as the tank uses air emission controls in
compliance with the provisions specified in the HON.  The same provision is applied in the
OSWRO NESHAP to process vents under § 63.683(c)(2)(i). The OSWRO NESHAP
standards for equipment leaks are directly cross-referenced to the same equipment leak
NESHAP standards also used by other NESHAP.
2.2.2   How is the OSWRO NESHAP implemented at a facility subject to another
       NESHAP when the affected source is not required to use air emission controls
       under the other NESHAP?

     Although not expected to occur commonly, the regulatory overlap situation could
possibly exist at a given facility where an affected source is used to manage an off-site
material with a VOHAP concentration greater than 500 ppmw; however this off-site material
does not meet the action level or threshold criteria used under the second NESHAP to apply
air emission controls.  In this case, a given affected source would be required to use air
emission controls under the OSWRO NESHAP but the source would not be required to use
air emission controls under the other NESHAP. For example, under the HON, the organic
HAP concentration action level used to determine which wastewater treatment units must use
air emission controls is higher than the concentration action level used for the OSWRO
NESHAP. Consequently, at a facility subject to the HON and accepting wastewater for
treatment together with its on-site wastewater, a situation could occur where the OSWRO
NESHAP requires the facility owner or operator to use air emission controls on a wastewater
treatment unit which previously had not been required to use controls under the HON. In this
case, the affected source must comply with applicable standards under the OSWRO
NESHAP.
2.2.3   How is the OSWRO NESHAP implemented at a facility subject to another
       NESHAP when the affected source is not regulated under the other NESHAP?

     The situation can occur at a facility subject to another NESHAP where a particular type
or category of affected sources is subject to standards under the OSWRO NESHAP but these
affected sources are not regulated under the other NESHAP. For example, containers and
transfer systems are types of affected sources not specifically regulated under all NESHAP.
In this case, there is no regulatory overlap, per se, since the affected sources are only
regulated by the OSWRO NESHAP. These affected source must comply with applicable
standards under the OSWRO NESHAP.
                                       2-8

-------
             3.0 INTERRELATION OF OSWRO NESHAP WITH
              RELEVANT RCRA REGULATORY PROGRAMS

     This section discuses the implementation of the OSWRO NESHAP at facilities that may
also potentially be subject to compliance with EPA regulatory programs administered under
the authority of the Subtitle.C of the Resource Recovery and Conservation Act (RCRA).  The
applicability of the OSWRO NESHAP to RCRA hazardous waste and used oil management
facilities is discussed. The technical requirements of the OSWRO NESHAP are compared to
air emission control requirements of the RCRA rules.  Compliance with the rule is discussed
for situations when a facility is subject to both the OSWRO NESHAP and the RCRA rules.
The section concludes with a discussion of facility permitting requirements under the CAA
and RCRA.
3.1  APPLICABILITY OF OSWRO NESHAP AT RCRA HAZARDOUS WASTE
     FACILITIES

3.1.1 What are the "RCRA air standards"?

     The EPA establishes rules for the management of solid wastes under authority of the
Resource Conservation and Recovery Act (RCRA). Under authority of Subtitle C of RCRA,
the EPA has established rules in 40 CFR parts 260 through 271 regulating the management of
solid wastes determined to be hazardous waste. For certain hazardous waste management
facilities subject to requirements under Subtitle C, the EPA established national standards to
control volatile organic air emissions from waste management units used to accumulate, store,
and treat hazardous wastes. These standards are referred to collectively in this document as
the "RCRA air standards".

     The RCRA air standards are established under three subparts (subparts AA, BB, and
CC) in both 40 CFR parts 264 and 265.  The RCRA air standards in 40 CFR part 264 apply
to owners and operators of RCRA permitted hazardous waste treatment, storage, and disposal
facilities (TSDF).  The standards in 40 CFR part 265 apply to owners and operators of interim
status TSDF. In addition, the RCRA air standards also apply under certain conditions
specified in the rules, to some waste management operations exempted from Subtitle C
permitting. For example, large quantity hazardous waste generators accumulating waste on-
site for less than 90-days in RCRA permit-exempted tanks and containers (commonly referred
to under the RCRA program as "90-day" tanks and containers) are subject to the applicable
RCRA air standards.
                                      3-1

-------
     The technical requirements for affected sources under the subparts AA, BB, and CC are
identical in both parts 264 and 265.  The subpartAA standards are applicable to process vents
associated with distillation, fractionation, thin-film evaporation, solvent extraction, air
stripping, and stream stripping operations that manage hazardous wastes with 10 ppmw or
greater total organic concentration.  The subpart BB standards establish requirements for
control of equipment leak emissions at TSDF.  The subpart CC standards require the use of
air emission controls on TSDF tanks, surface impoundments, and containers used to manage
hazardous waste having an average volatile organic concentration equal to or greater than
500 parts per million by weight (ppmw), as determined using the test procedures specified in
the rule.
3.1.2      What is the difference between a "waste" under the OSWRO NESHAP and a
          "hazardous waste" under the RCRA air standards?

     The term -waste is defined under the OSWRO NESHAP to mean any material generated
from industrial, commercial, mining, or agricultural operations or from community activities
than is discarded, discharged, or under treatment before being discarded or discharged.  This
definition is consistent with the definition of-waste used for other NESHAP.

     The term hazardous waste under RCRA is defined to mean a solid waste that meets the
criteria under the definition in 40 CFR 261.3. This definition encompasses many materials
that do not contain organic HAP.

     A waste under the OSWRO NESHAP may be either hazardous or nonhazardous under
the RCRA definition.  The criteria in the OSWRO NESHAP by which this waste is
determined to be an off-site material and, therefore, potentially subject to the OSWRO
NESHAP are : 1) whether the waste is generated on-site or off-site;  and 2) whether the waste
contains any of the organic HAP listed in Table 1 of 40 CFR 63 subpart DD (this table is
included as Appendix A to this guidance document). If a waste is generated on-site, then the
waste is not an off-site material regardless of whether it is also a RCRA hazardous waster or
if this waste contains organic HAP, in any quantity. Similarly, if the  waste contains no organic
HAP then the waste is not an off-site material regardless if this waste is "generated off-site or
is also a RCRA hazardous waste
                                        3-2

-------
3.1.3     Why can the OSWRO NESHAP apply to facilities subject to the RCRA air
          standards?

     The EPA established the OSWRO NESHAP and the RCRA air standards under two
separate congressionally mandated regulatory programs.  Section 112 of the Clean Air Act
directs EPA to regulate the emission of hazardous air pollutants from stationary sources by
establishing national emission standards (i.e., National Emission Standards for Hazardous Air
Pollutants or NESHAP). Section 3004(n) of RCRA directs EPA to establish standards for the
monitoring and control emissions from TSDF, as necessary to protect human health and the
environment.

     Congress included both in CAA section 112 and in RCRA section 3004(n) specific
criteria that the EPA must use to establish the air standards under each of the regulatory
programs.  However, these criteria are different under the two statutes. For example, CAA
section 112 requires that NESHAP be developed for major sources of hazardous air
pollutants based on application of Maximum Achievable Control Technology (MACT) (i.e,
the standard must be control technology-based).  In contrast, RCRA section 3004(n)
requires that RCRA air standards for TSDF be developed to achieve acceptable levels of
protection of human health (i.e, be health risk-based).   As a result of these different
regulatory approaches EPA is required to use for implementing the Congressional directives
under these environmental protection statutes, certain waste and recovery operations subject
to the OSWRO NESHAP may also be subject to complying with regulations under RCRA.

     The 1990 Amendments to the CAA recognize the potential for overlap of categories or
subcategories of air emission sources at RCRA facilities regulated by NESHAP and by RCRA
subtitle C rules. Section 112(n)(7) of the CAA specifically address this situation by directing
the EPA, to the maximum extent practicable and consistent with other provisions of section
112, to ensure that the requirements of a NESHAP are consistent with requirements under
RCRA subtitle C.   In developing the OSWRO NESHAP, the EPA identified many cases
where a facility subject to RCRA subtitle C rules managed hazardous wastes containing
organic HAP and generated off-site in waste or recovery operations exempted from the
RCRA air standards. Therefore, the EPA included applicability provisions in the OSWRO
NESHAP to control the organic HAP emissions from theses sources at RCRA facilities not
regulated by the RCRA air standards.  In response to the directive of CAA section  112(n)(7),
the EPA also added provisions to both the OSWRO NESHAP and the RCRA air standards so
that the air standards under the two rules are as consistent as practicable and do not have
duplicative requirements considering the requirements mandated by other  provisions of
section 112. However, due to certain conditions and operating practices  at some RCRA
facilities, there still exist situations of regulatory overlap by which a given waste or recovery
operation used to manage hazardous waste received from off-site is subject to air emission
control requirements under both the OSWRO NESHAP and the RCRA air standards.
                                        3-3

-------
3.1.4      What type of waste and recovery operations are potentially subject to the
          OSWRO NESHAP and also subject to the RCRA air standards?

     Table 3-1 identifies the types of waste and recovery operations potentially subject to
both the OSWRO NESHAP and the RCRA air standards.  Four of the types of waste or
recovery operations potentially regulated by the OSWRO NESHAP may be located at
facilities subject to the RCRA subtitle C: hazardous waste treatment, storage, and disposal,
operations; hazardous waste water treatment operations; hazardous waste recycling
operations; and used solvent recovery operations. Not all of these operations, however, are
subject to the RCRA air standards.  The hazardous wastewater treatment operations are
exempted from RCRA hazardous waste permitting, and therefore the RCRA air standards,
under the RCRA exemption in 40 CFR 264.1(g)(6) or 40 CFR 265.1(c)(10).  Certain
hazardous waste recycling and used solvent recovery operations may be subject to the RCRA
air standards under subparts AA and BB. When developing the RCRA air standards, the
EPA modified 40 CFR 261.6 to apply the RCRA air standards in subparts AA and BB to
exempted units used for recycling at RCRA-permitted facilities.  However, tanks, containers,
and surface impoundments (if any) at these hazardous waste recycling and used solvent
recovery operations are not subject to the RCRA air standards under subpart CC.

     Used oil processing or re-refining is not regulated under the RCRA air standards. Used
oil is regulated under RCRA as a unique material (i.e., it is not as a hazardous waste) with its
own set of standards 40 CFR part 279 - Standards for the Management of Used Oil. The
interrelationship of the OSWRO NESHAP with these standards is discusses in Section 3.2 of
this document.

     Tanks and containers exempted from RCRA hazardous waste permitting under 40 CFR
262.34(a) are still subject to the RCRA air standards. These tanks  and containers are used by
large quantity waste generators at a RCRA facility for on-site accumulation of hazardous
waste for less than 90 days (and thus commonly referred to as "90-day" tanks and containers).
Since these units cannot be used to manage hazardous waste received from off-site and still
qualify for the permit exemption under RCRA, all 90-day tanks  and containers are not subject
to the OSWRO NESHAP
                                        3-4

-------
CO
    I
    B.

   O
    cu


    O
    u
    O

    CU
    vs
    a









«J
0
£
,0
•#•»
g
in*
3
CO
Is
"£
_«
Q.





W
73
CXI
•o
C
a
•*-»
CO
L.

"*
^
O
an





•** CO
to c
> .2
CO
S3
O J?
"O |S
1°

§1
tin!
Ifiil




_o
.JU
Waste or Recovery Opera









v^
»














v^





"co
cn
o
CL
S
T3
CO
dous waste treatment, storage,
CO
N
CO
X






















•w






f)
£.
^
0
0
cn
:ardous wastewater treatment (
So
X

































"c
Other wastewater treatme





, 	 s
JO
0
"S
c
0
0
CO
•^











V









03
Hazardous waste recyclir























"o"
0
4-t
0
0
0







O3
C
'c
Used oil processing or re-ref





„ 	 ^
JO
0
"5
c
0
0
CO
\






















Used solvent recovery









^
•














^







"0"
0
-3
0
0-day tanks and containers (se
O3


0
3
O
CO
0
"co1
cn
tants (HAP) emission
o
CL
hazardous a
•5
or source
1
CO
"o
t;
CO
CL
0
JO
0
"ro
•o
0
"co
o
0
0"
JO
"cn
1
cn
c
o
"ra
0
CL
O
Waste or recover
	
"ct?

r has the potential tc
o
0
to
JC
15
o
o
o
E
o
o
0
•o
c
3
C
CO
CO
0
CO
03
3
O
3
533
"c
0
CJ
CO
c
JC
i

CO
0
o
3
0
CO
CO
o
to
source or group of st
£•
CO
c.
0
s
tn
>,
CO
03
C
CO
0
£



ibination of HAP.
ir or more of any conn
IU
0
0
CL
cn
c
o
CN
0
<
1C
CO
"o
0
0
p

CO
0
><
i_
0
CL
0
O
E
o
CO
1C
o
o
£
CO
O3
£
O)
03
CO
C
cn"
o
"c
o
o
emit considering >



air standards, under
"therefore the RCRA ;
•o
IT
CO
03
1C
•t;
E
0
CL
0
CO
CO
lazardous
j^
or
0
a:
E
o

T3
0
"S.
1
ffi
0
^
CO
03
r treatment operation
0
to
Hazardous waste
	
"cT









o

2

in
&
a:
LL
0
o
•y
O
"55
^
LL
O
o
c.
o
the RCRA exemp



RCRA-permitted
to
03
"o
8
•o
0
cn
3
~
3
0
"a.
1
m
m
T3
S
CO
-c
co
CL
JO
3
CO
_c
O)
•o
£l
CO
T3
C
*S
to
'ro
or
O
or
0
JC
"5.
CL
CO
CD
S
CN
or
LL
O
EPA modified 40
facilities.

"cT

03
f—
CM
•c
ro
CL
DL
LL
O
O
0
azardous waste). Se
JC
ro
CO
ro
"S
CO
0
CO
T3
>f standar<
V-l
"0
cn

5
O
cn

JC
0
to
0
3
nder RCRA as a unic
3
T3
0
to
3
O3
0
03
'5
•o
0
CO

~n

CN
CO
C
o
t;
0
CO
c
:andards is discusses
CO
0
cn
0
•c
SHAP with t
UJ
OSWRO
0
^
CL
JC
03
c

to
0
—

0
cn
cn
"c
3
•o
0
"a.
ainers are RCRA exe
"c
-8
•o
c
CO
J2
CL
CO
>,
CO
•o
o
O3

"o?


OSWRO NESHAP.
0
JC
_o
"o
0
Jo"
"o
c
CO
ontainers
o
•o
c
CO
03
•^
C.
_cg

CO
ci
03
"co
0"
'cn
5=
o
E
o
1
0
o
0
"cn
CO
0
O3
CO
CO
"o
c
0
T3
CO
'E
3



                                                     3-5


-------
3.1.5    Which of the RCRA air standards may apply to affected sources at a facility
        subject to the OSWRO NESHAP?

     Table 3-2 identifies which of the RCRA air standards subparts (subparts AA, BB, and
CC) may apply to affected sources at a facility that is subject to both the OSWRO NESHAP
and the RCRA rules. The series of three subparts under the RCRA air standards effectively
addresses the same set of affected sources that are regulated under the OSWRO NESHAP.

     Both the OSWRO NESHAP and RCRA air standards (under subpart AA) require the
control of air emissions from the same group of process vent sources. These processes,
typically used for waste treatment or recycling operations, are distillation processes,
fractionation processes, thin-film evaporation processes, solvent extraction processes, steam
stripping processes, and air stripping.  The definitions of each of these six treatment process
types used for implementing the OSWRO NESHAP are listed in Table 3-3.  These are the
same definitions used for the processes to implement the RCRA air standards under
subpart AA.


3.2  APPLICABILITY OF OSWRO NESHAP AT RCRA USED OIL
     MANAGEMENT FACILITIES

3.2.1    Why can the OSWRO NESHAP apply to facilities subject to the RCRA used
        oil management rules?

     In developing the OSWRO NESHAP, the EPA determined that large used oil
processing and re-refining operations can emit significant levels of organic HAP.  Used oil
processing or re-refining facilities are not subject to the RCRA air standards (i.e.,  subparts
AA, BB, and CC) . Used oil is regulated under RCRA as a unique material (i.e., it is not
regulated as a hazardous waste) with its own set  of standards under 40 CFR part 279 -
Standards for the Management of Used Oil. There are no specific requirements in 40 CFR
part 279 requiring the control of air emissions from these sources. Therefore, the EPA extend
.the applicability of the OSWRO NESHAP to include used oil processing and refining
operations.

3.2.2    What is the difference between "used oil" as defined for implementation of the
        OSWRO NESHAP and "used oil" for implementation of the RCRA used oil
        management rules?

     There is no difference in how the term "used oil" is applied for implementing the two
sets of rules. The OS WRO NESHAP adopts the same definition of used oil in the RCRA
used oil management regulations under 40 CFR  279.1.  Therefore, for applying both sets of
rules, used oil is any oil refined from crude oil or any synthetic oil that has been used and as a
result of such use is contaminated by physical or  chemical impurities.
                                        3-6

-------
"2
 es
•o


I
CO
2

-
•a
S
1
CO
 w
•*•»

—


 CUD
 o
CO

•o
 a>
 e
 o
 c.


 o

U
VJ
va
ts
^
vo
ts
CA
cs
c.
U
o
o
s
^
tn
•3
^«
R
•0
a
^«
OQ
I
y
P5

o
U
R
S4

09




g
^
e:
C.
J=
S
w




J
G
B.
S
OSWRO
NESHAP





Affected Source



\




















^





|



\




















^




CO
urface impoundmen
co


\




















-





Containers


'c?

-------
 ce
•2
CO

13
 St
 et
§
&

§
!•
O
 £
~a
 c


^
•c
ra
0.
CO
55
T3
C.
•5
(0
•a
TO
T3

(C
•*«•
CO

*^
03
CO
CD
E
CO
CO
*
Thin-film evaporation means a liquid mixture separation process or
method that uses a heating surface consisting of a large diameter
tube that may be either straight or tapered, horizontal or vertical.
Liquid is spread on the tube .wall by a rotating assembly of blades
that maintain a close clearance from the wall or actually ride on the
film of liquid on the wall.
c
o
', •
CO
o
CL
>
CD
£

r-








Q_
<£
X
co

O
cc
§
CO
0
o
03
CO
CD
E
CO
CO
Solvent extraction means a separation process or method in which
a solid or a solution is contacted with a liquid solvent (the material
and the solvent being relatively insoluble in each other) to
preferentially dissolve and transfer one or more components into the
solvent.

£-
o

o
CO
CD
"c
CD
~O
CO








Q_
<^~
X
CO
LU
0
&.
§
co .
o
o
14—
03
CO
CD
E -
CO
to
Steam stripping means a liquid mixture separation process or
method in which vaporization of the volatile components of a liquid
mixture occurs by the introduction of steam directly into the
process.


O3
_C
"CL
CL
tn
E
CO
Q)
CO

"CD .0
CD -*-'
to £
C CD
— CL
= O
03
CL^ O_
t/5 c. X
»- .2 co
"co 3=1 LLJ
s .£ ~Z.
§ |j o
*• CD >
CD *"" ^>
.C •" CO
*^~ : | . y^
CD "^ ^-
O3 = .O
£
Gas stripping means a desorption process or method used to
transfer one or more volatile components from a liquid mixture into
a gas stream either with or without the application of heat to the
liquid. Packed towers, spray towers, and bubble-cap, sieve, or
valve-type plate towers are examples of the process configurations
used for contacting the gas and a liquid



03
d
"CL
CL
'i_
In

CO
O

rt

.•§

P

1
 O
 2
 O
 2

 o
 a.

 o
U
                                                   3-8

-------
3.2.3    What type of used oil management operations regulated by RCRA are
        potentially subject to the OSWRO NESHAP?

     Not all used oil management operations regulated by RCRA are potentially subject to
the OSWRO NESHAP. The OSWRO NESHAP is potentially applicable only to those used
oil processing or refining operations that are subject to RCRA regulation under 40 CFR 279
subpart F.   Used oil management operations not subject these RCRA standards are also not
subject to the OSWRO NESHAP.  Furthermore, an used oil processing or refining operation
regulated under 40 CFR 279 subpart F is only subject to the OSWRO NESHAP if the used oil
is delivered to the facility from an off-site location and the used oil management operation is,
is located at, or is part of a. major source of hazardous air pollutants (HAP) emissions.!
3.2.4    If a used oil processing or refining operation is subject to the OSWRO
        NESHAP, how are the technical requirements of the OSWRO NESHAP
        implemented?

     The technical requirements of the OSWRO NESHAP apply to each affected source
located in used oil processing or refining operation. Under 40 CFR 279 subpart F, there are
no requirements for control of organic air emissions from used oil processing or refining
operations.  The RCRA air standards do not apply to these operations. Therefore, the
OSWRO NESHAP imposes no duplicative or conflicting requirements on those owners and
operators of used oil processing or refining operations complying with the RCRA used oil
management operations under 40 CFR 279 subpart F.
3.3  COMPARISON OF OSWRO NESHAP AND RCRA AIR STANDARDS
     TECHNICAL REQUIREMENTS

3.3.1    How does the action level determined under the OSWRO NESHAP compare
        with the RCRA Air standards?

     The OSWRO NESHAP uses a 500 ppmw action level based on the concentration of
volatile organic hazardous air pollutants (VOHAP) in the off-site material to determine which
off-site material management units and process vents must use air emission controls.
Likewise, the RCRA air standards under subpart CC uses a  500 ppmw action level on the
concentration of volatile organics (VO) in the hazardous waste to determine which tanks,
surface impoundments, and containers use air emission controls.  Consequently, for a waste
management operation subject to both the OSWRO NESHAP and the RCRA air standards
under subpart CC, the need to use air emission controls on those units used to manage a
hazardous waste that is also an off-site material is determined based on this material meeting
both of the action levels. In the development of the rules, the EPA recognized that  this
situation could occur and made the procedures for determining the 500 ppmw "action level"
                                       3-9

-------
under the OSWRO NESHAP consistent with the procedures required under the RCRA air
standards, to the extent possible under the applicable statutory requirements.

     Table 3-4 compares determination procedures for the 500 ppmw "action level" under
the OSWRO NESHAP with the procedures required under the RCRA air standards. For both
off-site material and for hazardous waste received from off-site generators, the action level
concentration is based on the composition of the material where the owner/operator accepts
position or custody of the material. The determination is made by collecting representative
samples and analyzing these samples using one of the specified test methods.  As an
alternative, both the OSWRO NESHAP and the RCRA air rules allow the use of "knowledge"
by the owner/operator to determine the VOHAP concentration of the off-site  material or the
VO concentration of the hazardous waste. The requirements for using "knowledge" for the
action level determination are the same under both rules.

     Method 305 is the compliance test method used for the OSWRO NESHAP.  This
method is designed for speciation of volatile organic hazardous air pollutants (i.e.,
identification and measurement of individual compounds). Method 305 is a "purge and trap"
method quite similar to Method 25D on the front-end sampling and purging to remove the
organic compounds from the sample.  The major difference is in the analysis where in Method
305 the purged stream undergoes separation of the individual compounds by gas
chromatography with measurement by mass spectrometry (or other appropriate means). The
concentrations of the constituents identified as HAP in  the OSWRO NESHAP are added to
obtain the total VOHAP concentration of the off-site material. It is this total VOHAP
concentration that is compared to the OSWRO NESHAP action level of 500 ppmw.

     The RCRA air standards under subpart CC use Method 25D as the  compliance test
method for measurement of the VO concentration of the collected hazardous waste samples.
Method 25D is not an individual compound speciation analysis method like Method 305 but
rather is used to provide a measure of the organic emission potential of a  material. The
method measures carbon (using a flame ionization detector) and organochlorine (by
electrolytic conductivity detector) in the material. The carbon (expressed  as methane) and the
chlorine (expressed as chloride) measurements are added together to provide an estimate of
the total VO emission potential of the waste. This VO  concentration value is  compared to the
RCRA air rules action level of 500 ppmw.

     Since Method 305 uses a speciation analysis method and the OSWRO NESHAP
specifies which chemical constituents are to be considered in the VOHAP concentration,
Method 305 measures a subset of the VO concentration measured by Method 25D.
Therefore, if an owner/operator uses Method 25D to measure the (total)  VO concentration of
an off-site material and that result indicates that the material has a VO concentration of less
than 500 ppmw, then the owner or operator can use the result of this alternative test method
to verify that the off-site material has a VOHAP concentration of less than 500 ppmw. On the
other hand, a Method 25D concentration of greater than 500 ppmw does  not automatically
                                       3-10

-------
 V)
•a
 M
 a
•e
 s
 a
*rf
CO
 o
 VI
•S
 a
 C.

 o
U







(0

re
T3
C
re
•*-*
CO
w
<
s
s








1
1
1
CO
o







Q)

C)

OS
Q.


1
•o
CD
C
'CD
T3
CO
CO
CO
•a
o
a.
E
o
o
o"
C3
CD
0
CD

to
o


CO
ca
Volatile organic hazardous air pollutants (VOHAP)
defined in the rule
*



tn

~
0
ex
E
o
o
'H
CO
Ol
S?
0










0_
£
CO
LU
Z
o
or
1
o
£
to
CO
CD

CO
CO

o
ra
Any time interval up to 1 year that the owner/ open
determines is appropriate for the material
*




T3
O

f~

1
"^

w  m M-
'C tn £ * £ 0
0 ,
-2 ^"1 o "|~g

co = •£ ^ "£ "">
°c- m p^ ^ pj ex
•5 .c "55 Or '55 o
tg or o °^ ° .2
§or J S!£.CD
IS O CO •" 03 *— t/j
I*-2 fe £ fc •§ 5
ft ll&ls
^~ -rj Q) *^ CD O O
o aj to E ^ Is ^
° ^ § <5 S c SS

>< S=T3 2= 0 J=
-§
CD ^j ca
c!5 '55 -o 5
VOHAP concentration at point-of-delivery
Applied to both RCRA hazardous wastes and non-
hazardous wastes
Applied only to wastes generated off-site and deliv
to facility. Not applied to any waste generated on-
Point where the owner/operator first accepts custo
takes possession, or assumes responsibility for a
• • . * *






£-55 -a
CD > CD
JZ JU :=

*£^ O CO
'5 t5 .2
Q. CO











|
CO
ui
"Z.
o
or
I
O
£
CO
CO
C
E
CO
CO
"to"
CD
CL
Use either:
- Direct measurement (i.e., collect & analyze sam
- Knowledge of the waste



 CD £
^ CL CD

CO "v^ o
C CD 0
co c. jr
CD 5 °
£= £- CO
.- •{? ro E
Si
' *""
                                                  5-11

-------
mean that the (OSWRO NESHAP) VOHAP concentration is greater than 500 ppmw.  The
off-site material may contain a number of organic compounds that are measured by Method
25D but are not on the list of HAP specified for consideration in the rule.

     Both rules also allow the uses of alternative analysis methods to Methods 25D and 305.
The selection of alternative methods is identical in bothjules. All of these methods are
speciation methods that require identification and measurement of individual compounds.
However, each method has been validated only for a limited number of compounds, and
multiple analyses by different methods may be required to measure all of the volatile organic
HAP present in a off-site material sample. If one of the alternative methods is used to
measure specific compounds present in an off-site material, the measured concentrations can
be corrected to values that would be measured using Method 305. This is done using
published Method 305 correction factors (f^os)-  The concentration of each individual HAP
may be "corrected" to equate to values that would be measured using Method 305 by
multiplying the measured constituent concentration by the constituent-specific adjustment
factor (fntfos)- Sum the constituent Method 305 concentrations to obtain the VOHAP
concentration for the off-site material.
3.3.2    Are there affected sources which are exempted under one rule but not the
        other?

     Both OSWRO NESHAP and the RCRA air standards include provisions which
specifically exempt certain affected sources that manage hazardous waste from having to use
air emission controls even if the waste in the unit has an organic content above the applicable
action level.  Table 3-5 compares the unit-specific exemptions potentially applicable to tanks,
surface impoundments, and containers managing hazardous waste allowed under'the OSWRO
NESHAP with the exemptions allowed under the RCRA air standards. With two exceptions
discussed below, when a tank, surface impoundment, or container qualifies for a unit-specific
exemption under the RCRA air standards it also qualifies to be exempted from using air
emission controls under the OSWRO NESHAP.

     The first exception occurs where tanks, surface impoundments, and containers managing
hazardous waste may be exempted under the OSWRO NESHAP but not the RCRA air
standards. The OSWRO NESHAP allows an owner or operator to designate one or a
combination of units managing off-site materials with a VOHAP concentration greater than
500 ppmw to be exempted from using air emission controls when these units meet the
condition that the total annual quantity of HAP contained in the off-site material placed in the
units (exempted under this provision) is less than 1 megagram per year.  To qualify for this
exemption^ the owner or operator must meet the requirements specified in the rule under 40
CFR 63.683(b)(2).  The RCRA air standards under subpart CC do not provide for a
comparable exemption. Therefore, the situation could occur at a hazardous waste TSDF also
subject to the OSWRO NESHAP where an individual tank, surface impoundment, or
                                       3-12

-------
TJ
 CJ
 en

.2
s-^
 O.

 tu
 O


 O
.to
 o
U









CD
3
K
0
TJ
c
ID
CO

s
*i
c
o
O

C
o

CO
CO
Ul
X.
Conditions for Exemption From Using









CO
•o
re
•D
c
ro
35
.b
^
^f

*.
irf








OSWRO NESHAP



Affected Unit















c
53
"S.
E
CD

O
_OJ

2
CO
Q-
E
o
o
o
Unit exempted if total annual quantity of HAP contained
in the off-site material placed in all units exempted
under this provision is less than 1 Mg/yr.
.
o
•o .
P. ^
•/operator designat
irface impoundmei
container
tu -^
c _
oj

o
CO
CO
c.
o
""S.
E
CD
CD
^_
£
.p**
15
3
D"
O „
-*- LL
CO <
CX
~ w
^ ^

° O
^ ^
CD -~,
E§
row
co O
nit exempted if either:
HAP biodegradation efficiency (RWo) for the
biological treatment process is equal to or
greater than 95%
- Total actual HAP mass removal rate (MRWo) for the
off-site material treated by the biological treatment
process is equal to or greater than the required HAP
mass removal rate (RMR) for the off-site material.
ZJ
*
^
CD
E "-
"O
C £— tD
!.E!
£ o "to >
— •*- tu co
tU T3 i; 3
O CD 	 O
tO CO to T3
1= = .2 to
rf. O) N
tn O CO
o .0-=
^ J3
CO

,0
CO
CO
c
.2
'o.
£
CD
i§
l_
£
.^*
"5
3

o ^

w ^
ex
~ CO
^ ^
c:

^ ^

c >
co O
Unit exempted if hazardous waste meets the applicable
numerical organic concentration limits specified in the
Land Disposal Restrictions under in 40 CFR 268.40.
-.
o
-t-j~ CD £
C O)j_, 	
jrface impoundme
iner used to mana
jous waste subjec
RA Land Disposa
Restrictions
y) _CO J— Q
^ g M <*•
i ° •*=

o
CO
CO
c:
o
~£.
E
0
g

£
.^*
"ro
cr
O n
•4-' LL
07 ^
c X
~ w
^ -4*
c:

L^

£ ^
co O
Unit exempted if organic hazardous constituents in the
hazardous waste have been treated by the treatment
technology established by the EPA for the hazardous
waste in 40 CFR 268.42(a), or have been removed or
destroyed by an equivalent method of treatment
approved by the EPA under 40 CFR 268.42(b).
•
o
tf &>B
CD CO CO
c c co
•o g 5
C C to
!°i
•^ll
CD 3 oj
co J5 ~ca
_ C CD
-^ O ±z
CO
CO
Q> 
**~ -1 m 'T~"
CO fc °)
CO £ J> IO
c; 3 ^
~ ^ > o5
Q. to co ja
E £ £
CD c £ §
gj _o CD o
u. "^ .2 <
•e S| £
.^ x *•* .p
"^-c ^ -°
o~'5 § ^
Or* O "O

W ^ "^ "O
C 3Z m C
•5 ^  c: co
E^ "" CD
<5?§£l
nit exempted all 3 conditions met:
- Tank located inside an enclosure vented to control
device that meets applicable requirements in 40 CFR
61 subpart FF
- Enclosure and control device began operation before
July 1, 1996
- Enclosure meets criteria in "Procedure T - Criteria for
and Verification of a Permanent or Temporary Total
Enclosure" under 40 CFR 52.741 , Appendix B.
.

"o
£ CD "CO
-^ In CD
3 !g C
-a 5 '5
- &§£
"•- O <»
"§"H£
co to 5
24. ra CO
CO

                                                        3-13

-------
container is required to use air emission controls under the RCRA air standards but is not
required under the OSWRO NESHAP to use controls. However, it is unlikely that a TSDF
owner/operator would choose to use this discretionary exemption available under the
OSWRO NESHAP for a unit that already must use air emission controls under the RCRA air
standards. There would seem to be little advantage or incentive for an owner/operator to
doing so.

     The second exception applies to a tank used for bulk feed of hazardous waste to a waste
incinerator. The OSWRO NESHAP exempts this type of tank when located in an enclosure
and vented to a control device before July 1, 1996 (and meets the other conditions listed in
Table 3-5). The RCRA air standards exempt this type of tank when located in an enclosure
and vented to a control device before November 25, 1996.  The dates are differ because the
cutoff date for either rule is determined by the date on which the exemption provision in the
applicable rule was published in the Federal Register.
3.3.3    How do the technical control requirements under the OSWRO NESHAP
        compare to the technical control requirements under the RCRA Air
        standards?

     For affected sources required to use air emission controls, Table 3-6 compares the
technical control requirements of the OSWRO NESHAP with those required under the RCRA
Air standards in subparts AA, BB, and CC by the different affected source types.

     Tanks. Surface Impoundments, and Containers. The technical requirements for tanks,
surface impoundments, and containers under the RCRA air standards in subpart CC are
essentially the same as those in the OSWRO NESHAP.  A tank, surface impoundment, or
container controlled under either set of requirements will achieve the same emission reduction
and performance level.

     Oil/water and Chemical/water Separators.   There are no specific requirements under the
RCRA Air standards as there are in the OSWRO NESHAP for oil/water and chemical/water
separators.  However, an oil/water and chemical/water separator meets the definition of a
"tank" used for applying the RCRA air standards. Therefore, these units potentially must
meet the tank standards under subpart CC.

     Material Transfer Systems.  The material transfer system control requirements under the
OSWRO NESHAP apply to any stationary system for which the predominant function is to
convey liquids or solid off-site materials from one point to another point within a waste
management operation or recovery operation conveyance of material using a container or a
self-propelled vehicle such as a front-end loader is not a transfer system under the rule). In
contrast, there are no specific requirements under the RCRA air standards for the affected
source of material transfer systems. The RCRA air standards do include a provision under
both the tank and the surface impoundment standards in subpart CC that  requires transfer of

                                       3-14

-------
hazardous waste between tanks or surface impoundments using air emission controls be
conducted using continuous hard piping or another closed system (e.g., see §264.10840).
There are no requirements under the RCRA air standards affecting the transfer of materials
into or out of containers.

     Process vents. As discussed previously in this section, both the OSWRO NESHAP and
RCRA air standards (under subpart AA) require the control of air emissions from the same
group of process vent sources.  However, there are significant differences in the application of
the process vent standards to these six process types under the OSWRO NESHAP compared
to the RCRA air standards.  The OSWRO NESHAP process vent standards apply to any of
six process types when the process is used to treat an off-site material having a VOHAP
concentration greater than 500 ppmw.  Also, the OSWRO NESHAP specifically exempts very
low flow process vents and process vents that meet the process vent flow and concentration
criteria of 6 m3/min and 20 ppmv for the vent stream.  Under the RCRA air standards the
process vent  standards are applied to the six process types when the process is used to
manage hazardous wastes with a total organic concentration of at least 10 ppmw.
                                       3-15

-------
 o
 cs
 o.

 o
u



1
0)
V) 0)
•a .i:
ft
w 2
'•?!
§s
c
0

t—












v>
"c
0
E

Q_ *-
OSWRO NESHAI
Technical Control Requ
 CO CO
SO S CO
Q. aJ *" <"
°-~o E £
co c co co
£ Sfi 1
QJ u) I •
2 = r £
4= o CD a
.= .« > ;
° CD <" *
.B .- ~



5
•

j
c 1o c: c
CO X CO C
. H- ffi • I- - .• H

5
*- r- £
° I - -
*~ "co °
S fe ro
co CD c:
CD §"'-g
Q-"ti X
^ CD
§- E m
CO 0 "
> ro w .
• Required control level determined by
material in tank, tank capacity, mana
performed in tank, and whether tank i
source.
• Tank Level 1 — Use either:
- Tight-fitting cover or fixed-roof
- Cover and vent to control device





CO
c
CO
'




3

CD
O
CD
-a
~o

"H
o
o
c
.2


(4_ f-J
• Tank Level 2 — Use either:
- Fixed-roof with internal floating roc
- External floating roof
- Cover and vent to control device
- Pressure tank
- Locate in enclosure vented to corn!



















CL
CO
LU
. o
OL
CO
O
o

to
CO
CD
E
CO
CO












• Use either:
- Floating membrane cover
- Cover and vent to control device
CO
"c
CD
E
T3
C

§_
. E •

CD
-' O
«£
ij
CO
                                            3-16

-------
 0)


 C
 o
 o
CO


CO
.a
 (0




RCRA Air Standards
Air Emission Control Requirements




ID
c
>
r~
E
0
CO
TJ
(U
Q
•2
,_
"7 D- CL 0-
ro < < <
ro -r -r -r
• Container control level applicability criteria same
OSWRO NESHAP
• Container Level 1 — Same as for OSWRO NESI
• Container Level 2 — Same as for OSWRO NESI
• Container Level 3 — Same as for OSWRO NESf
CO
% 8
„ TJ O ~
O r- i- >
C CO CL -g
CO - C _
° S "S [^ £
&> oL-M - - "- CN 0
-0 co -5 a- s- CM -c, o
T3°(0 to CO -0 0 C
 c co.c o
.c  CD "t! -~ ^ CD TJ §
o S ~J?Eo ~'i?'cb'^) "'me
TT O "*-* nT "^ *^ *~ JIT •— -r^ i Jit • -^
g^-^j c^S-^ro cJSJo ca5g
*5 QJ £ J5 o ^* 2 ff o m co -2 o ^
Q) o -^ O O O
Q:85 Olll OIIIOII
• * • •



c
[5
"c
0
O


£>
_ca
™ _
r— CD • 	
• RCRA imposes Subpart BB standards on tank at
equipment, piping and conveyance such as wast
solvent/paint collection system at a facility. The
collection system is subject to Subpart BB.
• A separator meets the definition of a "tank" used
subpart CC and must meet the tank standards










CD
U
'§
T3
"5
•£
o .
0 0
.SIS
•a ca
CD CL.
& "c  -D
O M- CD
*- O N
;_: ro o ~z:
CD C V =
-C ^3 -0 0)
.t: ca CD "S
CD 0 X CD
CD u. LL. Q.
a>
=) I 1 1
•


TJ CD
2 '§ °
.Sro 2
CO O CO
^- E CD

O -^

0
U)
E CD i-
CD u_ -Q CD
• No specific requirements for individual drain syst
other transfer systems
• Provisions under tank and surface impoundment
standards in subpart CC requires that transfer o'
hazardous waste between tanks or surface
impoundments using air emission controls must
conducted using continuous hard piping or anoth
closed system (e.g., see §264.1084(j))

in
CD
_o
TJ
2i
3
o

o
^l-'| s
1 1 • !• • i 1

0-"° 1 "S -5
tn TJ "c CD *z
. ca ™ 8 = ? °
« _.£ _ .£ o
ECO o -^ CO (-> -.
-— — .^^ en 'r~ •— - ^
CD CO Q. 3 E Q--'-'
2," "2 2 -§ ^"S
cn ^r co :£ >-> co "c
'(0 S *" m w
' i? „- § u -i,,,?!

3 CD '~ ,^ |— ; fl> '~ O
'^ O O CD m O O C
~ O O > .c O O LU
^ \ \ \ Olll

CO
£
!s ^"
S fe .
3> **--
^
CO

                                                 3-17

-------
0)
I]
o
o
(O
CO
_fl3
J2
(S




CO
*•»
V
£
«i
t- o-
TO CD

™ O
RCRAAirJ
Air Emission Cont







CO
. •*•*
c
1
(D

it
m ~5
OSWRON
Air Emission Contr




CD
a.
^~
&
H
o
to

03
To
o
8=
i •& . s
8 ^ -a
a. = °° =• a
T-, «" CN «° ' CO - '
-§ El E .•£ :'
1 -fll-l
^ .2 if .2 =ro
M_ « ';r to c:
o  ,-: to ^p '5)
g • E 5 -E S E
.2 to 5 o>- o> o>
"(3 ." "55 .0 >, ^
• Standard applied to combir
vents at facility
• Achieve either:
- Reduction of total organ
affected process vents k
- Reduction of total organ
affected process vents k
• Standard allows "emission
to achieve compliance
-s

"£ '.-'..
CD
« ro j?
co -c Si
8 §" .g

"S -D —
-»-* CD £l
CD c C
S= CD a) o
CO -1* .0 0
CO ^1 CD ^
^D to 	 ^
1 -^"S >
H > ro •§
S • S o co
2 SE! • • •
T3 £ » 1
.CD 0. y) c •
"o_ "° u) o
a. -^J ^ -5
<0 o C= CD
'E !§ > "°-
co ^"(5 -^, "o
^ ^i <~ CD i*
-2 " co o o
35 J5 LU "5 O

to
^
CD
to
(O
CD
O
0
Q.


m •-
CD 4"
• "C *~
Q- E
'ct cD
^ 
-------
     The OSWRO NESHAP are applied on an individual process vent basis and require each
affected process vent to be controlled. In, contrast, the RCRA air standards are applied on a
facility basis and require that owners or operators to reduce total organic emissions from all
affected process vents at the facility to below 1.4 kg/h (3 Ib/h) and 2.8 Mg/yr (3.1 ton/yr) or
install and operate a control device(s) that reduces total organic emissions from all affected
process vents at the facility by 95 weight percent.  If the total emissions from all affected
process vents at a the facility exceed either the daily or annual emission limitations then
controls are required; if total emissions are below  both of the emission limit criteria then no
controls are required for the process vents under subpart AA.

     For those affected process vents under either the OSWRO NESHAP required to be
vented to a control device, the technical air emission control requirements for the closed vent
system and control device are relatively consistent.  Both rules require installation and
operation of an organic recovery or destruction control device that meet certain design,
operational, and performance criteria.  The performance requirements are summarized in
Table 3-7.
                                     Table 3-7.
    Control Device Performance Requirements for both the OSWRO NESHAP and
                                RCRA Air Standards
Control Device Type
Enclosed Combustion Devices
[e.g., thermal incinerator, catalytic incinerator,
boiler, or process heater)
Organic Recovery Devices
(e.g., carbon adsorber or condenser)
Flares
Performance Requirement
• 95 % destruction efficiency
or
• 20 ppmv exit concentration
or
• minimum residence and temperature,
(e.g., 760 °C and 0.5 sec) .
• 95 % overall recovery
design and operational criteria (e.g., no
visible emissions)
     Equipment leaks.  The EPA has promulgated a number of NESHAP equipment leak
standards in 40 CFR parts 61 and 63.  The OSWRO NESHAP cross-references several of
these existing NESHAP subparts. The rule allows the owner/operator the option of
complying with the 40 CFR 61 subpart V or 40 CFR 63 subpart H.  The RCRA air standards
specifies all of equipment leak requirements in subpart BB in parts 264 and 265. The
technical requirements under the RCRA air standards in subpart BB are essentially the same as
the technical requirements in 40 CFR 61  subpart V.
                                        3-19

-------
     There are two primary techniques for reducing equipment leak emissions that form the
basis of these EPA equipment leak standards: 1) modifying or replacing existing equipment,
and 2) implementing a leak detection and repair (LDAR) program. The equipment
requirements (e.g., installing caps on open-ended lines or installing closed-loop sampling
systems) are essentially the same in all of the EPA equipment leak standards.  There are no
differences in these technical requirements between the NESHAP subparts cross-referenced
by the OSWRO NESHAP and the RCRA air standards.  Table 3-8 presents a summary of
equipment modifications that can be used for each equipment component type subject to the
equipment leak standards.
                                    Table 3-8.
            Equipment Modifications for Equipment Leak Standards
Equipment Component Type
Pumps
Compressors
Pressure relief devices
Valves
Connectors
Open-ended lines
Sampling connections
Modification
• Sealless design
• Closed-vent system
• Dual mechanical seal with barrier
fluid maintained at a higher
pressure than the pumped fluid
• Closed-vent system
• Dual mechanical seal with barrier
fluid maintained at a higher
pressure than the compressed gas
• Closed-vent system
• Rupture disk assembly
• Sealless design
• Weld together
• Blind, cap, plug, or second valve
• Closed-loop sampling
     The LDAR program is routinely administered at a facility to detect and repair equipment
that is "leaking" (i.e., emitting sufficient amounts of organics to the atmosphere to warrant
reduction of these emissions by repairing the equipment). A portable monitoring device is
used to identify equipment leaks from individual pieces of equipment. The control
effectiveness of any given LDAR program is dependent on a number of factors including leak
definition and monitoring frequency as well as initial and final leak frequencies. The EPA
equipment leak standards vary in how the LDAR program is implemented with respect to leak
definition and monitoring frequency as well as initial and final leak frequencies. Some
standards specify the leak definition (e.g.-, 10,000 ppmv) and monitoring frequency (e.g.,
                                        3-20

-------
monthly or quarterly) and others specify the final leak frequency.  The equipment leak
standards under both 40 CFR 61 subpart V and the RCRA air standards in subpart BB both
require a monthly LDAR with a leak definition of 10,000 ppmv.  In contrast, 40 CFR 63
subpart H of part 63 that has a lower leak definition for pumps and valves (e.g., 500 ppmv for
Phase II and HI) and specifies the monitoring frequency based on the leak frequency.
3.3.4    Which technical requirements apply to an affected source when it must use air
         emission controls under both the OSWRO NESHAP and the RCRA air
         standards?

     Tanks. Surface Impoundments, and Containers. The RCRA air standards under
subpart CC applicability exempt any hazardous waste management unit that the owner or
operator certifies is equipped with and operating air emission controls in accordance with the
OSWRO NESHAP (or any other applicable Clean Air Act regulation under 40 CFR part 60,
61, or 63).  It is important to note that this exemption only applies to those units using organic
air emission controls to comply with an applicable CAA regulation.

     Process Vents. The EPA amended the applicability provision of Subpart AA by adding a
new §264.1030(e) and §265.1030(d). This provision states that a process vent is not subject
to the Subpart AA standards provided the owner or operator certifies that all Subpart
AA-regulated process vents at the facility are equipped with and operating air emission
controls in accordance with the requirements of an applicable Clean Air Act regulation
codified in Part 60, 61,  or 63.

     Therefore, the Subpart AA process vent applicability exemption is only available at a
facility where each and  every process vent that would otherwise be subject to Subpart AA is
equipped with and operating air emission controls in compliance with an applicable CAA
standard under Part 60, 61, or 63. The various individual vents could be regulated under
different CAA rules as long as all vents (otherwise subject to Subpart AA) are controlled
under an applicable CAA rule.

     As with the similar exemption provisions in Subparts BB and CC, to comply with the
requirements at paragraphs §264.1030(e) or§265.1030(d) and thus qualify for the applicability
exemption, the emissions from each Subpart AA process vent must be routed through a
closed-vent system to an air emission control device.  A process vent that is in compliance
with a CAA standard under an exemption from control requirements (i.e., is not equipped
with and operating a control device) does not meet the criteria established in the provisions
paragraph §264.1030(e) or §265.1030(d) of Subpart AA.  Therefore, a unit that does not use
the required air emission controls but is in compliance with a NESHAP through an "emission
averaging" or "bubbling" provision does not qualify for the exemption.  Similarly, if the Clean
Air Act standard for the particular unit is' no control (for example, because the MACT floor
for the source category is no control and the Agency decided not to apply controls more
stringent than the floor), the exemption from the RCRA standards under §264.1030(e) or

                                        3-21

-------
§265.1030(d) of Subpart AA would not apply since the unit would not. actually be controlled
(i.e., equipped and operating air emission controls) under provisions of the MACT standard.

     To take the above example a step further, at a facility where all but one of the
Subpart AA process vents are equipped with air emission controls for compliance under CAA
rules and the one uncontrolled Subpart AA process vent is also in compliance with a CAA
regulation but is not controlled for air emissions, the facility's Subpart AA process vents do
not meet the applicability exemption criteria as stated in Subpart AA and thus are not exempt
from the rule under §264.1030(e) or §265.1030(d).

     Equipment Leaks. The amendments to the Subpart BB rules, published on December 8,
1997 (62 FR 64636-64671), revised the recordkeeping provisions of Subpart BB to eliminate
owner or operator burden caused by regulatory overlap of the various EPA equipment leak
regulations under the Clean Air Act and RCRA. The Subpart BB recordkeeping provisions in
Section 264.1064(m) and Sec. 265.1064(m) were amended to allow any equipment that
contains or contacts hazardous waste that is subject to Subpart BB and also subject to
regulations in 40 CFR Part 60, 61, or 63 to determine compliance with Subpart BB by
documentation of compliance with the relevant provisions of the Clean Air Act rules codified
under 40 CFR Part 60, Part 61, or Part 63. As noted in the preamble to these amendments,
"because compliance with Subpart BB is demonstrated through recordkeeping, this
recordkeeping revision has the effect of exempting equipment that would otherwise be subject
to Subpart BB from Subpart BB requirements, provided the equipment is operated,
monitored, and repaired in accordance with an applicable CAA standard, and appropriate
records are kept to that effect."

     Paragraph §264.1064 (m) in the recordkeeping requirements states that the owner or
operator "...may elect to determine compliance with this subpart either by documentation
pursuant to §264.1064 of this subpart [i.e., Subpart BB], or by documentation of compliance
with the regulations at 40 CFR Part 60, Part 61, or Part 63 pursuant to the relevant provisions
of the regulations at 40 CFR Part 60, Part 61, or Part 63." The corresponding Part 265
language is the same.  The objective of the amendment was to eliminate any owner or
operator burden caused by regulatory overlap. In making the revision to paragraph (m) in
§264.1064 and §265.1064 of Subpart BB, the Agency intended that, for a piece of equipment
subject to equipment leak regulations under the CAA as well as RCRA Subpart BB,
compliance with the CAA rules rather than the RCRA Subpart BB requirements would be an
adequate demonstration of compliance and in  effect eliminate the need to demonstrate
compliance under  Subpart BB of the RCRA Air Rules. Based on EPA Headquarters'
interpretation, the provisions in 40 CFR 264.1064(m) and 265.1064(m) are intended to allow
a facility owner or operator to demonstrate compliance with all of subpart BB, through
documentation of compliance with regulations under one of the specified parts of the CAA,
such as the OSWRO NESHAP. Simply put, if a facility has equipment that is subject to
relevant provisions (i.e., provisions for operating, monitoring, and repairing subpart BB
equipment) under  regulations within the specified CAA parts, that equipment is exempt from
40 CFR part 264 subpart BB and therefore no potential exists for overlap with the OSWRO

                                       3-22

-------
 NESHAP. To be eligible for the exemption provided by 40 CFR 264.1064(m) or
 265.1064(m): the relevant CAA requirements must be applicable to the subpart BB
 equipment; the relevant CAA requirements must include provisions for operation, monitoring,
 and repair of the Subpart BB equipment; the relevant CAA requirements must be codified
 within 40 CFR part 60, 61, or 63; and compliance with the relevant CAA requirements must
 be documented in the facility operating record.
3.4 FACILITY PERMITTING CONSIDERATIONS

3.4.1    What is the relationship between a facility's CAA Title V operating permit
         with the facility's RCRA Subtitle  C permit?

     A facility subject to both the OSWRO NESHAP and the RCRA air standards may be
required to have two operating permits, one permit for each of the separate regulatory
programs.  One of the OSWRO NESHAP applicability conditions is the facility is a major
source of HAP emissions. Under CAA Title V, owners and operators of facilities that are
major sources of HAP emissions are required to have an operating permit (see 40 CFR
part 70). Under RCRA subtitle C, owners and operators of TSDF that handle hazardous
waste are required to have an operating permit

     According to the EPA's Operating Permits Group of the OAQPS Information Transfer
and Program Integration Division, a Title V operating permit for a major source must be
comprehensive with respect to including all emission units and all applicable requirements that
apply to the units (see 40 CFR 70.3(c)(l)).  That is, the permit must include all "applicable
requirements" for  all emission units within the  fenceline (except for "insignificant activities")
and contain an explanation of any exemptions from otherwise "applicable requirements." An
"applicable requirement" is essentially all emission limitations and standards and other
requirements through State implementation plans (SIP), NSPS, MACT, NESHAP, and other
CAA requirements.  For example, the RCRA air emission standards are not an "applicable
requirement" under Title V because they are not CAA requirements (RCRA is a separate
statute).  The CAA standards under Part 60, 61, or 63 are applicable requirements and as such
should be included in the CAA Title V operating permit, as applicable to the facility. All
terms and conditions in the permit that are required by the CAA or applicable requirements
are federally-enforceable.  In fact, all Federally-approved rules/requirements are independently
enforceable outside of CAA permitting programs.  For example, SIP requirements become
federally-enforceable when EPA approves the SIP; NSPS, MACT, and NESHAP are
federally-enforceable as of their effective date.  Therefore, CAA requirements under 40 CFR
Parts 60,  61, or 63 are independently enforceable regardless of whether or not the
requirements have been incorporated into the facility's Title V permit. An owner or operator
with sources subject to regulations under 40 CFR Part 60, 61, or 63 must comply with the
applicable requirements of these regulations regardless of the CAA Title V permit status.

     The operating permit term is 5 years.  The requirements for permit content are described

                                        3-23

-------
in 40 CFR 70.6. Each permit must include the emission limits and standards including
operational requirements and limits that assure compliance with all applicable requirements at
the time of permit issuance.  All the terms and conditions of the permit, including any "permit
shield" granted under 40 CFR 70.6(f), remain in effect until the renewal permit has been
issued or denied. Any permit noncompliance constitutes a violation of the Act and is grounds
for enforcement action. Section 70.6(f) allows the permitting authority to include a provision
stating that compliance with the conditions of the permit shall be deemed compliance with any
applicable requirements as of the date of permit issuance provided:  (1) such applicable
requirements are included and specifically identified in the permit; or (2) the permitting
authority determines in writing that other requirements specifically identified are not
applicable to the source, and the permit includes the determination or a concise summary of it.
This means, in general, that once the applicable requirement is translated into permit terms,
the source must only comply with the Title V permit terms.
3.4.2    How does the program policy of a "permit shield" as implemented under the
         CAA differ from the "permit-as-a-shield" policy implemented under RCRA?

     The program policy of a "permit shield" as implemented under the CAA is significantly
different than the "permit-as-a-shield" policy implemented under RCRA.  The RCRA
"permit-as-a-shield" policy allows a permitted TSDF to be shielded from compliance with
regulatory requirements promulgated after the RCRA permit is issued; i.e., compliance with
the RCRA permit constitutes compliance with the RCRA program. In general, under this
policy, if a new standards is added to 40 CFR Part 264 and is not in the facility's RCRA
permit, the owner or operator is typically not required to comply with that particular standard
until the permit is reopened (most likely for renewal at the permit's expiration date) and the
requirements of the standard can be added to the facility's permit.  This is not the case under
the CAA where any "shielded" requirements must be specifically identified in the Title V
permit.  The CAA requires that the facility's  permit must be reopened to include newly
promulgated requirements if more than 3 years remain in the term of the permit. If not, the
requirements are included in the permit renewal. In either case, the facility owner or operator
must comply with any new regulations under 40 CFR part 60, 61,  or 63,  which are
independently enforceable, as of their effective date.
3.4.3    Can the sources in a facility's CAA Title V operating permit be different than
         those listed in the facility's RCRA Subtitle C permit?

     Yes. There are circumstances where a particular unit or source may be listed in a
facility's RCRA Subtitle C permit but not included or listed in the facility's CAA Title V
permit.  For example, a unit may not be listed in the Title V permit for a major source if it is
an "insignificant activity."  State permitting programs have varying definitions of "insignificant
activity." Some use a emissions threshold for HAPs (e.g., 2 tpy) and such limits should only
be subject to generally applicable requirements of the  SIP. Portable units moved onto the site

                                  .      3-24

-------
for a short period of time also may not be listed in the permit for a major source. A portable
source cannot be a major source.  In cases where a particular unit or source is not included or
listed in a facility's Title V permit, the unit is not exempt from any applicable CAA
requirements under Sections 111 and 112. As this discussion illustrates, in limited cases a
HWMU at a facility could be subject to and in compliance with a particular CAA rule but the
facility's Title V permit may not clearly identify or list the applicability of the rule.
                                         3-25

-------