WATER POLLUTION
PERFORMANCE EVALUATION STUDY 40
(WP040)
INSTRUCTION PACKAGE
******************
PLEASE READ ALL INSTRUCTIONS CAREFULLY
BEFORE ANALYZING SAMPLES
IMMEDIATELY UPON RECEIPT OF SAMPLES, CHECK
FOR BREAKAGE AND CORRECTNESS OF SETS
SHIPPED; SEE LIST OF REQUESTED SETS
ON THE BOTTOM OF THE REPORT FORM LABEL.
SAMPLE REPLACEMENT TAKES AT LEAST
2 TO 3 WEEKS
******************
PLEASE NOTE THERE IS ONLY
ONE CONCENTRATION PER ANALYSE
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: ! WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY #40
: ; f.\ ,;., TABLE OF CONTENTS
SUJBij[EgI SET PAGE(S)
Instructions (General and Reporting) 3
Trage Metal 1-35-6
; . . and 1-5
Mineral 1-5 7
":'"' pH ''' ' ":;S ' ' : 1-4 9
;.' , Nutrient' "' ' " " ' ' ' ''"'" 1-2 11
Demand l-l 13
Polychlorinated Biphenyls in Water O 15
Polychlorinated Biphenyls in Transformer Oil O 17
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; Chlorinated Pesticide '" _ ^ , ' ' "! O is
Volatile Halocarbons O 21
Volatile Aromatics O 23
(.; ' ' '' - " iiiiii '' ' "". '"'ii ., i , "i , "' "
Total Cyanide 1-3 25
Non-filterableResidue (Total Suspended Solids) 1-1 27
Oil & Grease 1-2 29
Total Phenolics 1-3 3l
Total Residual Chlorine 1-4 33
Material Safety Data Sheets 35-60
General Instructions for Reporting Results 61-84
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY #40
GENERAL INSTRUCTIONS
Treat each PE study sample the same way you would treat a
routine sample, i.e., usual analyst, usual analytical sys-
tem, usual procedures, etc.
For each analyte you report, provide results of a single
analysis, as would be done with a routine sample.
« To request replacements for broken and/or missing ampuls,
FAX your request to Terry Bundy at ManTech (919) 406-2246
(your EPA assigned lab code must be included on all sample
requests) using the form attached to the cover letter for
this mailing; to obtain answers to questions, call your
regional or state coordinator (see list attached to your
cover letter).
Read instructions carefully before opening ampuls.
For best results, ampul solutions and reagent water should
be at room temperature (near 20° Centigrade) when used.
Amber-colored total residual chlorine ampuls as well as the
clear cyanide ampuls should be stored away from light until
the analyst is ready to use them.
Open ampuls cautiously to avoid cuts or flying glass. A
suggested procedure is to wrap the ampul in cloth or a thick
paper towel and snap off the ampul top at the narrow part of
the neck.
Unless otherwise stated, samples need not be filtered.
Use only Class A volumetrics.
"Reagent water" is equivalent to Type II Reagent Water as
specified in ANSI/ASTM Standard D 1193-91.
(PAGE 4 IS BLANK)
WP040
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
TRACE METAL SAMPLES
Two ampuls containing 5% nitric acid (v/v) are provided to
prepare two separate samples.
SAMPLE PREPARATION
To prepare sample 1, fill a 1-L volumetric flask approx-
imately 3/4 full with reagent water, pipet 10.0 mL (which con-
tains 0.5 mL of concentrated nitric acid) of ampul 1 and 1.0 mL
of trace-metal-grade concentrated nitric acid into the flask,
dilute to volume with reagent water, and mix well. To prepare
sample 2, repeat the procedure using ampul 2. The resulting
samples should be analyzed for the following analytes at levels
within the stated concentration ranges.
Sample 1
Analyte
Aluminum
Arsenic
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Mercury
Nickel
Selenium
Vanadium
Zinc
Concentration,
micrograms per
liter (jUg/L)
after dilution
<50,00
<2000
<2000
<2000
<2000
<2000
<4000
<4000
<4000
<60
<4000
<4000
<11000
<4000
Sample 2
Analyte
Antimony
Beryllium
Molybdenum
Silver
Strontium
Thallium
Titanium
Concentration,
micrograms per
liter (jig/L)
after dilution
<2000
<2000
<1000
<2000
<500
<2000
<500
Continued on other side of sheet.
WP040
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Notes:
Samples, standards and reagent water blanks should all have
the same acid matrix. The solution resulting from the above
dilution will contain 0.15% v/v nitric acid; additional or
different acids may be used as appropriate for analytical
procedures or to match standards.
Mercury is present as a mixture of organic and inorganic
forms. If a cold vapor method is used, an aliquot of the
sample must be digested before analysis for mercury.
However, digestion of this sample for any other metal
analysis in unnecessary.
Chromium should be determined only as total chromium. When
chromium is analyzed by direct air-acetylene AA, use of
matrix modifiers or the less sensitive oxidizing flame may
be necessary to control interfering ions. Preferably, use a
fuel-rich nitrous oxide-acetylene flame for best results.
Some analytes may occur at concentrations that are too low
! for determination with simple direct AA and must be deter-
m^ned ^jth .^CP/ furnace AA, or AA after chelatipn extraction
(where approved) to produce reportable results.
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With some methods (such as colorimetric chromium method
3i°OD fjcom Reference 74), preparatory extraction may be
required to remove relatively high concentrations of inter-
ferences before analysis .
' i " '"i;: ; ' ' " if ' "i;'1 ., ' i, ....... . '
Because many analysts will use atomic absorption or induc-
tively coupled plasma spectrometry, multiple aspirations or
measurements may be obtained to determine an analyte concen-
tration, as with routine samples .
Report results as micrograms per liter with three figures.
l£ AA is used, specify which method (i.e., air-acetylene,
nitrous oxide -acetylene, platform or non-platform) was used.
' ' ':: ;,," , ''.' ' "' ": '' ...... '' ' '' ' '' ',"",:;' . WP040
Ampuls contain 5% nitric acid.
CORROSiyE/pXIpIZER - TOXIC - SEVERE IRRITANT
Material Safety Data Sheets are attached
immediately following the sample preparation instructions.
END OF INSTRUCTIONS FOR TRACE METALS
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
MINERAL #1
Two ampuls containing reagent-water solutions are provided
to prepare one sample. The contents of ampuls 1A and IB are used
to prepare a sample for determination of total alkalinity,
specific conductance, total dissolved solids, hardness, calcium,
magnesium, sodium, potassium, chloride, fluoride, and sulfate.
SAMPLE PREPARATION
To prepare sample 1, fill a 1-L volumetric flask approxi-
mately 3/4 full with reagent water, pipet 10.0 mL from each of
ampuls 1A and IB into the flask, dilute to volume with reagent
water, and mix well.
NOTES:
Instructions for pH analysis have been moved to page 9 of
these sample preparation instructions.
Solutions in ampuls were preserved by autoclaving the sealed
ampuls. Because the preservative treatment is not effective
after ampuls are opened, open ampuls just before analysis.
Determine alkalinity and specific conductance first. If
calcium, magnesium, and hardness are not to be determined
during the day the sample was prepared, acidify (pH <2) an
aliquot of the freshly prepared sample with nitric acid for
later analysis.- For other determinations, the sample is
stable for at least a month if adequately stoppered and
cooled to 4°C.
Total alkalinity results may be biased if a blank correction
is not applied. To compensate for the 980 mL of reagent
water used to dilute the 20 mL of ampul contents, titrate an
aliquot of reagent water (using the same volume as used for
your sample analyses) from the same source as that used to
dilute ampul solutions and subtract 98% of the required
titrant from the titrant measured for each sample.
Report results using the units specified on the data report-
ing form to three figures.
WP040
END OF INSTRUCTIONS FOR MINERALS
(PAGE 8 IS BLANK)
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
pH SAMPLE
SAMPLE PREPARATION
To prepare the pH sample, pour the contents of the pH ampul
directly into a ^50-mL beaker; do not dilute before determining
pH.
NOTES:
We acknowledge that, ideally: 1) the strong memory effects
of the calibrating buffers are removed by allowing the
electrode(s) to soak in some of the sample prior to
analysis, and 2) laboratories should be able to use their
entire routine analytical procedures in performance
evaluation studies. However, there are practical limits to
the amount of pH sample we can provide to you in our
studies.
Therfore, we propose that you soak your electode(s) in
distilled water to remove the memory effect of the
calibration buffers before you analyze our pH sample as
directed in the study instructions. We believe this
adjustment to your normal procedure is reasonable, effective
and should not adversely affect your chances of successful
performance.
If you cannot produce a valid pH measurement from your
analytical system using a sample of 20 mL (or 40 mL using
the contents of an additional ampul which is available upon
request), your analytical system is beyond the scope of this
study. For example, systems for continuous pH measurement
may require a minimum sample size which is incompatible with
the current study design. If your pH system is incompatible
with the study design, you should discuss this with your
state/regional study coordinator.
WP040
END OF INSTRUCTIONS FOR pH
(PAGE 10 IS BLANK)
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11
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
NUTRIENT SAMPLES
Two ampuls containing reagent-water solutions are provided
to prepare two separate samples. Sample 1 will contain inorganic
nitrogen and phosphorus and may be analyzed for ammonia nitrogen,
nitrate nitrogen, and orthophosphate phosphorus. Sample 2 will
contain organically-bound forms and may be analyzed for total
Kjeldahl nitrogen and total phosphorus. When prepared according
to instructions, samples will contain <50 mg/L of each nutrient.
SAMPLE PREPARATION
To prepare sample 1, fill a 1-L volumetric flask approxi-
mately 3/4 full with ammonia-free, reagent water, pipet 10.0 mL
of ampul 1 solution into the flask, dilute to volume with reagent
water, and mix well. To prepare sample 2, repeat the procedure
with ampul 2.
NOTES:
Solutions in ampuls were preserved by autoclaving the sealed
ampuls. Because this preservative treatment is not effec-
tive after ampuls are opened, open ampuls just before analy-
sis .
If a solution is not to be analyzed within two days after
preparation, preserve a sample aliquot with 0.2 mL of con-
centrated sulfuric acid per 100 mL of sample (pH,<2) and
store at 4°C until just before analysis. Analyze the pre-
served sample as soon as possible within the maximum 28-day
holding time.
Report results as milligrams per liter with three figures.
END OF INSTRUCTIONS FOR NUTRIENTS
(PAGE 12 IS BLANK)
WP040
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
DEMAND SAMPLES
One ampul containing reagent-water solution is provided to
prepare one sample. The sample may be analyzed to determine 5-
day biochemical oxygen demand (BOD), 5-day carbonaceous BOD
(CBOD), chemical oxygen demand (COD), and total organic carbon
(TOG).
SAMPLE PREPARATION
To prepare the sample, fill a 1-L volumetric flask approxi-
mately 3/4 full with reagent water, pipet 20.0 'mL from the ampul
into the flask, dilute to volume with reagent water, and mix
well. The sample is ready for analysis to determine 5-day BOD,
5-day CBOD, COD and TOC. Each measured value should be <300
mg/L.
NOTES:
The ampul contains about 21 mL of solution; if clean dry
pipets are used, this is sufficient to prepare the sample.
More ampuls may be requested if both 5-day BOD and 5-day
CBOD are to be determined. If an additional sample is
needed, complete the "Request for Sample Replacement" sheet
attached to the cover memorandum and submit as directed.
The solution in this ampul was preserved by autoclaving the
sealed ampul. Because this preservative treatment is not
effective after the ampul is opened, open the ampul just
before analysis.
Begin the BOD and/or CBOD as soon as possible after sample
preparation. If cooled to 4°C, the maximum holding time for
these analyses is 48 hours. If COD and/or TOC cannot be
analyzed within your usual holding time after sample
preparation, an aliquot should be preserved (pH <2) using
0.2 mL of concentrated sulfuric acid per 100 mL (or an
equivalent amount of another acid which is compatible with
your chosen methods). This acid preserved portion should be
stored at 4°C and analyzed as soon as possible within the
28-day maximum holding time.
5-day BOD and 5-day CBOD: For proper oxygen depletion, the
sample should be tested in a dilution series such as 4%, 8%,
and 16%. Use a natural surface water, diluted domestic
sewage, or commercially available seeds for seeded dilution
water and avoid entrainment of air. For a 5-day CBOD, the
use of a nitrifying inhibitor is recommended.
Continued on other side of sheet WP040
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:: ;: 14
NOTES, continued
Be sure to determine the "blank" BOD of your seeded dilution
-water so that the proper seed correction can be made (See
STANDARD METHODS, 17th edition, Page 5-6).
Report results as milligrams per liter with three figures.
END OF INSTRUCTIONS FOR DEMAND
WP040
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15
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
POLYCHLORINATED BIPHENYLS IN WATER
Two ampuls containing acetone solutions of polychlorinated
biphenyls (PCBs) as Aroclor mixtures are provided to prepare two
separate samples.
SAMPLE PREPARATION
To prepare sample 1, add approximately 1 L of reagent water
to a 2-L separatory funnel, pipet 1.0 mL of the ampul 1 solution
into the separatory funnel, and mix well. To prepare sample 2,
repeat the above procedure using ampul 2.
NOTES:
Identify the Aroclor(s) by specific commercial formulation
number(s) and measure the concentration(s).
For calculations, assume initial sample volume was 1000 mL.
Report results as micrograms per liter with three figures.
WP040
Ampul solutions contain acetone.
FLAMMABLE LIQUID - IRRITANT
Material Safety Data Sheets are attached
immediately following the sample preparation instructions,
END OF INSTRUCTIONS FOR PCBs IN WATER
(PAGE 16 IS BLANK)
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17
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
PCBs IN TRANSFORMER OIL
Two ampuls containing transformer oil contaminated with
polychlorinated biphenyls (PCBs) as Aroclor mixtures are provided
to prepare two separate samples.
SAMPLE PREPARATION
To prepare sample 1, weigh a clean, dry 100-mL volumetric
flask to the nearest 0.1 mg. Transfer approximately 1 g of the
material in ampul 1 into the volumetric flask, reweigh the flask
to the nearest 0.1 mg, and calculate the weight difference.
Dilute the sample aliquot to volume with pesticide-grade hexane,
and mix well. Transfer the remainder of the material from ampul
1 to a teflon-lined screw-cap vial and store for future use. To
prepare sample 2, repeat the procedure using ampul 2.
NOTES:
Identify the Aroclor(s) by specific commercial formulation
number(s) and measure the concentration(s).
Report results as milligrams per kilogram of oil with three
figures.
WP040
Ampuls contain Shell Diala (R) oil AX.
TOXIC & IRRITANT TO SKIN
Material Safety Data Sheets are attached
immediately following the sample preparation instructions,
END OF INSTRUCTIONS FOR PCBs IN TRANSFORMER OIL
(PAGE 18 IS BLANK)
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
CHLORINATED PESTICIDE SAMPLES
Two ampuls containing acetone solutions of chlorinated
pesticides are provided to prepare two separate samples. The
sample prepared from ampul 1 may be analyzed for aldrin,
dieldrin, ODD, DDE, DDT, heptachlor, and heptachlor epoxide; the
sample prepared from ampul 2 may be analyzed for (total) chlor-
dane.
SAMPLE PREPARATION
To prepare sample 1, add approximately 1 L of reagent water
to a 2-L separatory funnel. Pipet 1.0 mL of solution from ampul
1 to the separatory funnel, and mix well. To prepare sample 2,
repeat the above procedure using ampul 2.
NOTES:
For calculations, assume that the initial sample volume was
1000 mL.
Report results as micrograms per liter with three figures.
WP040
Ampuls contain acetone.
FLAMMABLE LIQUID - IRRITANT
Material Safety Data Sheets are attached
immediately following the sample preparation instructions,
END OF INSTRUCTIONS FOR CHLORINATED PESTICIDES
(PAGE 20 IS BLANK)
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21
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
VOLATILE HALOCARBON SAMPLES
One ampul containing a methanol solution of volatile halo-
genated organic compounds is provided to prepare one sample. The
sample may be analyzed for up to 11 halogenated organic com-
pounds .
SAMPLE PREPARATION
To prepare the sample, fill a 100-mL volumetric flask to
volume with carbon-filtered reagent water. Using a 25- to 50-jiL
syringe, withdraw 25 jitL from ampul 1 immediately after opening
the ampul and adjust syringe contents to 20 uL. Quickly inject
the 20-ptL aliquot into the reagent water in the expanded volume
of the flask; remove the needle as quickly as possible after
injection. Mix the sample by inverting the flask three times
only (excessive shaking results in loss of volatiles) and
analyze immediately.
NOTES:
Report results as micrograms per liter with three figures.
WP040
Ampuls contain methanol.
FLAMMABLE LIQUID - TOXIC/IRRITANT
Material Safety Data Sheets are attached
immediately following the sample preparation instructions
END OF INSTRUCTIONS FOR VOLATILE HALOCARBONS
(PAGE 22 IS BLANK)
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23
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
VOLATILE AROMATICS SAMPLES
One ampul containing a methanol solution of volatile aromat-
ic compounds is provided to prepare one sample. The sample is to
be analyzed for up to six aromatics.
SAMPLE PREPARATION
To prepare the sample, fill a 100-mL volumetric flask to
volume with carbon-filtered reagent water at room temprature.
With a 25- to 50-/iL syringe, withdraw 25 ^iL from ampul 1 immedi-
ately after opening the ampul, and adjust syringe contents to 20
/iL. Quickly inject the 20 /zL aliquot into the reagent water in
the expanded volume of the flask; remove the needle as quickly as
possible after injection. Mix the sample by inverting the flask
three times only (excessive shaking results in loss of volatiles)
and analyze immediately.
NOTES:
Report results as micrograms per liter with three figures.
WP040
Ampuls contain methanol.
FLAMMABLE - TOXIC/IRRITANT
Material Safety Data Sheets are attached
immediately following the sample preparation instructions.
END OF INSTRUCTIONS FOR VOLATILE AROMATICS
(PAGE 24 IS BLANK)
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US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
CYANIDE SAMPLES
One ampul containing a reagent-water solution is provided to
prepare one sample.
SAMPLE PREPARATION
To prepare the sample, fill a 1-L volumetric flask approximately
3/4 full with reagent water and add 1 mL of IN NaOH. Pipet 10.0
mL of the solution from the ampul into the flask, dilute to
volume with reagent water, and mix well.
NOTES:
CAUTION: The sample should be analyzed as soon as possible
after opening and diluting.
The cyanide concentration will be <2 mg/L.
To prevent a concentration change, the ampul and, even more
importantly, the prepared sample should not be exposed to
sunlight or other ultraviolet light any longer than neces-
sary. Therefore, perform the analysis immediately after
sample preparation.
The specified addition of 1 mL of 1 normal sodium hydroxide
is only a recommended minimum to prevent the loss of
cyanide. If another amount, or even another base (such as
KOH) is part of the analyst's "normal routine", it is
his/her option to change the recommendation.
Since all the cyanide is present in soluble forms,
filtration of the sample is not necessary, however, the
sample will require distillation.
The presence of a precipitate in the ampul is not a problem,
unless it is blue in color.
Report results as milligrams per liter with three figures.
END OF INSTRUCTIONS FOR CYANIDE
(PAGE 26 IS BLANK)
WP.04.0 ,
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27
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
NON-FILTERABLE RESIDUE (TOTAL SUSPENDED SOLIDS) SAMPLES
One vial containing homogeneously mixed solids is provided
to prepare one sample.
SAMPLE PREPARATION
To prepare the sample, fill a 1-L volumetric flask about 3/4
full with reagent water. Soon after opening and without drying,
weigh 500 mg of solids from the vial and quantitatively transfer
to the volumetric flask using a glass funnel and wash bottle
filled with reagent water. After rinsing the glass funnel
thoroughly and removing it, dilute flask contents to volume with
additional reagent water (see notes) and mix by inverting the
flask 10 times. Let the sample flask stand for 10 min and invert
again 10 times. Immediately after the second set of inversions,
rapidly measure a 500-mL aliquot into a graduated cylinder by
repetitively mixing and pouring so as not to allow solids to
settle in the flask before the transfer is complete. Filter this
500-mL aliquot and determine the non-filterable residue (total
suspended solids) according to the chosen method.
NOTES:
Do not dry the vial contents prior to weighing the 500 mg of
mixed solids. Weigh the solids as received without any
preparatory action.
If a significant portion of the weighed (500 mg) solids
fails to disperse evenly and stubbornly floats on the
surface, add a few drops of diluted detergent to the
partially filled sample preparation flask. For example,
dissolve approximately 10 mL of detergent in 100 mL of
reagent water and mix. Then add 2 drops of this diluted
detergent to the sample preparation flask, mix, observe, and
repeat (if necessary) the 2 drop additions until the
suspended sample appears to be dispersed evenly. Choose a
detergent which will rinse clean from the gooch crucible and
filter pad without leaving a measurable residue requiring a
blank subtraction. Possible conveniently accessible choices
might be Triton-X-100, or any house-hold liquid dish-washing
detergent void of insoluble ingredients. If your detergent
fails to disperse the solids evenly, request a new ampul.
Continued on other side of sheet
WP040
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CAUTION: The analysis should be performed soon after the
500 mL aliquot is obtained.
Report results as milligrams per liter with three figures,
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Ampuls contain NaCl.
IRRITANT
Material Safety Data Sheets are attached
immediately following the sample preparation instructions,
END OF INSTRUCTIONS FOR NON-FILTERABLE RESIDUE
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29
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
OIL AND GREASE SAMPLES
One ampul containing a solution of oil and grease in n-
propanol and glycerol is provided to prepare one sample.
SAMPLE PREPARATION
To prepare the sample, add 994 mL of reagent water and 5 mL
of 1:1 hydrochloric acid into a 2-L separatory funnel and mix.
Pipet 1.0 mL of the ampul solution into the separatory funnel and
mix well. Analyze the sample using whatever analytical method
you most often use on routine samples. Note that data produced
using hexane for extraction must be reported in a different place
on the report form than data produced using freon for extraction.
NOTES:
To avoid a concentration change, the sample must be analyzed
soon after the ampul has been opened.
The sample should be analyzed with an approved gravimetric
method, because it is not suitable for an infrared method.
For calculations, assume that initial sample volume was 1000
mL.
Report results as milligrams per liter with three figures.
WP040
Ampuls contain n-propanol (flammable liquid)
and glycerol (irritant)
Material Safety Data Sheets are attached
immediately following the sample preparation instructions,
END OF INSTRUCTIONS FOR OIL AND GREASE
(PAGE 30 IS BLANK)
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11F
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31
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
TOTAL PHENOLICS SAMPLES
One ampul containing a reagent-water solution is provided to
prepare one sample.
SAMPLE PREPARATION
To prepare the sample, fill a 1-L volumetric flask approxi-
mately 3/4 full with reagent water. Pipet 10.0 mL from the ampul
into the flask, dilute to volume with reagent water, and mix
well. Analyze the sample using a 4AAP method ONLY.
Notes:
In each sample, the resulting total phenolic concentration
will be <6 mg/L.
The solution in the ampul was preserved by autoclaving the
sealed ampul. Because this preservative treatment is not
effective after the ampul is opened, open the ampul just
before analysis.
Do not report phenolic results determined with GC/MS, be-
cause GC/MS data are not equivalent to data obtained with
the 4AAP methods.
Report results as milligrams per liter with three figures.
END OF INSTRUCTIONS FOR TOTAL PHENOLICS
(PAGE 32 IS BLANK)
WP040
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33
US ENVIRONMENTAL PROTECTION AGENCY
WATER POLLUTION LABORATORY PERFORMANCE EVALUATION STUDY 40
TOTAL RESIDUAL CHLORINE SAMPLES
One ampul containing a reagent-water solution is provided to
prepare one sample.
SAMPLE PREPARATION
To prepare the sample, fill a 1-L volumetric flask approximately
3/4 full with chlorine-free, reagent water. Pipet 10.0 mL from
the ampul into the volumetric flask, dilute to 'volume with
reagent water, and mix well.
NOTES:
In this sample, the resulting concentration of total residu-
al chlorine will be <6 mg/L.
To prevent a concentration change, the ampul and prepared
sample should not be exposed to sunlight or other strong
light or agitation any longer than necessary. Therefore,
perform the analysis immediately after sample preparation.
Report results as milligrams per liter with three figures.
END OF INSTRUCTIONS FOR TOTAL RESIDUAL CHLORINE
(PAGE 34 IS BLANK)
WP040
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iCIO. N1TROSYU ^PCHtORlTI; MTIYL ?WCHLOSATI ?Ulrt lEWENfj WTASSIUM
T-svnonoij suuTJtic ACIO ?tus NTASSIIW eiofsojant ^w>*ocsuuyasc ACIO
(CAftO'S ACIO): TKIOOICUYCOC PUW KTOfiOCCN
SECTION IJJ -
OATA S/10 SEI JtCTJC« 3t
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fUUWASU UU
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SrtCIAL ?I« rtCHTim
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UNUSUAL Fltt *» IXHOSION HA2AftO$i
XOOCJUTC fXnOSION K1ZAAO VHDf YA>O« IS UPCSO TO
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HICX CCHCtXTJIiTIONS 0« MOUNCtO OtfflSWf Wf ClUSt KtiOiOil. OI22IHCSJ
IJIITATIOM O/ HtS t ICJMJUTOit TI*Ct. W5J W ITJtXTX. 4 NAICOStS.
IYI CtJNTACT WWC$ SIVCIC IWITATION; »IM COKTACT >UT C1USI MI«J IRRJ
CSWCtNflUTIONS Of 30.000 FM 1« tXHtatATILT OW«WOU5 70 tUl 1 MC1LTM
CMCXCCMa AMD f I«1T AID rftOCCBACSs
M£0iaL usxsTUttf rc« AIL cises of ovtjtcx/osuxt.
SXINS VIJH VtTM 10AF AM VATC*.
rrfSi iweotATay VASH JKJJWUCW.T
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li
,: ''i1!
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JM3ICATOXS: STASILin JTHtl
COM3IT10MS TO AVOID:
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(KlTV TC 4VOIO):
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OR
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sowscrs t
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VAST? ois^csjit xrrvco:
TO It MRfOSXCO IN CCWLlJlNCZ VI7X ALL' CJRStVT ICCtl. STATt." *
-------
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JtCtlCK till- IMCIAl MOTtCTlON
CSMUTOIT
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VITK AXT USC OF THIS IKfOWUTlCH. '
M57£: HA 08 M/A OEMJTtS WT-AYA1USL£ C« NCN-l?H.ICiSLt
-------
-------
Shell
MATERIAL SAFETY DATA SHEET
MSOS Nuwesai >> w.oja-s tu( i
am*
ii^
SHELL- 7l3«473-94ei CHEMTREC: 100*424-8300
O
SHELL 713-241-4S1S
KA2AJS RAT1N5
UAH «a
not i
. 4
and shrorft h**fth effect! f«fw to *M fOieuuien kt StstJoft 0
NAM
^
f
wrrvic (sfi see
Oil.
SCCTION. IX-A- MODUCT/JNOfttOIlNT
W~ *
» snai ouu OIL AX MIXTVRI 100
1 SOLVENT 1CFINEO KYO«Ot«AT£D MIDDLE DISTRUTE <4?43-4|>? CO-100
2 $£Yt«LY KYJftQTHEATSO UOXT KXPKTHEN3C &ISTHUTI t47O.S3-| o-O
9 RUTTUTW HYOROXY TOLUtMt UI-J1-O 10 HLA8, JUT >S WLA«, IAT- WT 4VAIUILI
BASEO lff»« CATA AVAIU8LC TO SKILL. CC«f>OWCNT 3 JH TK1S MO&UCT IS «7 HA2AS50US UWJJJ OJKi HliA»D
11 10. 1200).
IKPORXATIOH
TKf HSAUTH EFffCTS KiOTED HLBV ARE CONSISTSN? WITH RfCUIflEKtKTS UN2E8 TKi CSMA KA2ASO t9X«UWCATJ3N
S7AN&ABO (21 CFt 18 19.1200).
EYt CCNTACT
ftASCD ON tSSexTtALLY SJKJUt KOOUCT TfStlWO >.?COUCT IS PRESUMID 70 1C M5NIMI7ATINC TO TX( fYES.
SICXK earner .
At» M IMIMTULLV stxtuui ^fcoewer TESTIMC PBOOUCT is MIJUKED TO n $IIS«TLY IMITATING TO TKI
SKIN. FWUJNOte AWO BEJ>EATEO CONTACT HAT *CSVLT IN VARIOUS SKIN DISOaDUi |uCH A$ &EMUTIT1S,
M OIL ACKX.
ItftfLATUM
xwauTiflM or VAW«$ (CENESUTEO AT MIW TE«PE»ATva£s CW.Y) o» OIL K:ST IUY uusi A HUB
0^ TKI WCOUS KCKSfUKES OF THS UP«ft >JS>lRATeftf TRACT.
2W01STIOH
ISTIBH Of MDOUCT KAY ft£SUlT !M VCKlTlMj ASHftATIOM (8RCATH1HO tt VCUITM IWTO TH£ LUNflS) KJST
AVOIDED AS IVEM SHALl OUAWTITIES KAY RESULT 1M ASPIRATION ^NeWONITIS.
-------
SICKS Ji SYWTOKS
IMITATION AJ WTED MOVE. AJFIlATICN FNtV-CNlTIS MAT 1C IVIOCKIO IT COUCHJWS. LABORCO
AM3--CYAMHI3 (ILUISH $XIN)J IN J|Vt«I CASES DEATH MAT OCCUR.
*. ifl ..... !«! ..... ^ f" .' '. ,jl ....... ill T , ' ""i;:1' - ' /. ' J - " ''"' '' > '"'
AfiOUYATtD MEDICAL CONDITiONS
PREEXISTING SKJH AM) l£S>lUTOaT OIS860e«S IUT tf AGCBAVATtO IT CX«SU8| TO TWI1 PRODUCT.
j ' . Vj
1 ________ . ..... jilZlZHl [[[
' /I _______ OCOfrATICKU. EXPOSURE LIMITS
OSKA ' ACGIH ......
TLV/TVA
5 MC/M3- 10
OIL HIST. MINERAL ______
SECTION V - ------- -------- EXEJWOJCY AND FIRST AID PROCEDURES
«»*>« *»«*i*»«5;y«»'»»"»^ ***"" »**»*** « ».**»« *»»»*» WWM.^^ »»
FLUSH-tYES VITH VATER; IF -IRRnATlOH OCCURS, GET MEDICAL ATTCHTION. - ----
'«;'; ' ' ' ;, , ..... ' ' ' '' , , . ;!.
REMOVt COMTAiUNATEO CLOTHING/SHOES AW VIH EXCESS FROM SXlM. . JIUSH SKIM VJTH VATER. fOUOV IT
VASHJKW WITH SOAP AND VATE». IF IRRITATIOM OCCURS. CCT- MEDICAL ATTENTION.
,, J;1;'1 ; '': . . , . ;, , , . : ....... :.V , ,
*X}WA1ATXOM "'"**""""
itEkovc VICTIM TO FRESH AIR ANO PROVWE OXYCEN IF BREATHING is DIFFICULT. CET MEDICAL ATTENTION.
INOCSTION
00 NOT INDUCE VOMITING.--: IF VCMITJNG OCCURS SPONTANEOUSLY. KEEP KEAO BELOV HIPS TO PREVENT
ASPIJtATION OF-LIOUIO INTO THE LUNGS. GET KEDICAL ATTENTION.
NOT« TO PHTSXCJAU
IF MORf THAN 2.0--ML PER KG HAS IEW INGESTED AND VOMITING HAS NOT OCCURRED. EMESIS SHOUU) IE
i»*octi:wifH SUPERVISIOH.- KEEP VICTIM-S KEAO BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH
*$ I.OSS OF CAG REFLEX. CONVULSIONS Ot UNCOKSCIOUSNESS OCCUR BEFORE EMESIS. GASTRIC UVACE USING A
OJFrtD ENOOTRACHIAL TUBE SHOULD £ CONSIDERED.
riMtl»W*»*i *«WMMW^ * » <*»*. %*.»»*»
^ » m, mvm m an-y-ii IT "" *<»»»»»»«»»»»«*"» ^ **_«.»« »^»»»»*»*»».»»»,, ^ »*» * o.»
StCTlOH VI S«PBL£XEXTAL HEALTH INFORXATIO*
HOHt IDENTIFIED.
'$ECTIO«VX1 FKTSICA1. DATA
B02LXNO POINT: >3CO
.{DEO F)
MEVTINO POINT:, .-«O (POUR POINT)
(DEO f)
SPECIFIC GRAVITY: O.883
(H20M)
SOLUBILITY:
(IN VATER)
NEGLIGIBLE
EVAPORATION RATE (N-BUTYL ACETATE t): NOT AVAILABLE
VAPOR FRESSURE: NOT AVAILABLE
(KH HC)'
-------
PAS«
000*: VH|T{ UOUIO. SLICXT MTl>woCi»tON OW5»
SECTION VIII F1«C AND EXPLOSION HAZARDS
FLASH POINT AND METHOD: PUWXAJLI LIMITS A VOLUME IN AI*
a»S-J10 016 I (COC) LOV£R: N/AVA UPP£«: N/AVA
eXTIHCUISHING MEDIA
USC WATER FOG. FOAM, 08Y CUBICAL OR C02. 00 MOT USE A SI9£CT $Ta£i* Of WATER. PRODUCT VILI flOAT
AND CAM 1C IEIGNITEO ON SUIUCE 0? VATER.
SPECIAL riM riGHTIM ^ROaDURCS AND PRECAUTIONS
ItATIRIAl ₯IU NOT §UtN UNUSS ^8|K|AT|0. 00 MOT CNTCB CONf INEO f I8C-$nCC WITHOUT FW.L 8WX£i CtAI
(MtLKtT WITH fACf SMIIL8. IU»CC« COATS. CCOVtS ANO »U8SCt tOOTS). INCUUOINC a MSlTIVE-PBCSSUtt
NIOSH-APMOVtO SCtf-CONTAlKro e»CATHIN6 APPARATUS. COOL flftt tXPOSIO CONTAIM£RS VITX VATI1
SECTION « _
STABILITY: STABLE KA2A600US POLY«8I2ATICN: VJLt MOT OCCUR
CONOITIOKS AND KATERIALS TO AVOID:
AVOID HCAT. OPEN fU«S. AND CXIOI21NG KATERUuS.
KA2AMOOS KCCWOSITION PWOOCTS
THERMAL t>£CO«PO$ITION MOOOCTS ARE HIGHLY 0£P£«>ENT ON THE COMBUSTION CONOITIONS. A COMPLEX
MIXTURE Of AIMORWC MLtO. LlOL"e. PARTICULATES ANO CASES WILL EVOLVE VMEM THIS KATEIUL UNO£2SC£S
PYROLTSIS Ot COMBUSTION. CABSC* MONOXIDE AMD OTHER UNlOENTIfUO ORCANIC COMPOWOS MAY BE fORMO
UPON COK6USTIOM.
SECTIOM X CHPLOYEC PROTECTION *
HESPIRATORY PROTECT10M
If EXPOSURE KAY OR OOES EtC££D OCCUPATIONAL EX«>OSUHE LIMITS (SECTION IV) USE A NIOSH-APPROVED
RESPIRATOR TO PREVENT OVE*£XPOSURE. IN ACCORD WITH M C« 1S10.13* USE EITHER AN
ATHOSPKERE-SUPPLYINC RESPIRATOR OR AN AIB-fHJRIfYING RESPIRATOR tOR ORGANIC VAPORS AND PARTICULATES.
PROTECTIVE CLOTHXNO
WEAfi CHEMICAL-RESISTANT GLOVES AMO OTHER PROTECTIVE CLOTHINC AS REQUIRED TO MINIMIZE SKIN COMTicT
NO SPECIAL EYE PROTECTION IS ROUTINELY NECESSARY. TEST DATA FROM PUBLISHED LITERATURE AND/OR
AJ« CLOTHING MANUFACTURERS INDICATE THE BEST PROTECTION IS PROVIDED BY HITRILE GLOVES '
SECTION « ENV1RJOKMEWTAJ. PROTECTION
SPItL OK LEAK PROCEDURES
RAV SURM ALTHOUGH NOT READILY IGNITA8LE. USE CAUTIOUS UUOGMENT VHE« CLEANING UP LARGE «?«LL$ «
LASiE SPILLt WEAR H£> :*ATOR AND PROTECTIVE CLOTHING AS APPROPRIATE. $WT Oft SOURCE OP LEAK
IF SAfE TO f: W. DIKE. *-0 CONTAIN. R£»40VE WITH VACUUM TRUCKS 08 PUMP TO STORAGE SAL VICE VESSELS
SOAK OP RE£ Jl WITH AN ADSORBENT SVCM AS CLAY. SAND. 08 OTHEB SUITABLE MATERIALS: DIS-OSE Bf
PROPERLY. FL-SH AREA WITH VATE8 TO REMOVE TRACE RESIDUE. « SMALL SPILLS TAKE UP VITM AW
ABSORBENT KAURIAL AND DISPOSE Of PROPERLY. ^ l **
VASTE DISPOSAL
PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE VITH LOCAL REGULATIONS.
ENVIRONMENTAL HAZARDS
THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN VATER ACT. SPILLS ENTER1M3 (A)
SURFACE VATCRS OR (B) ANY VATER COURSES OR SEVERS ENTERING/LEADING TO SURFACE VATERS THAT CAU5T I
SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER. SOO-424-IC02.
-------
KAMI; $*ltL CUc>iA; Oit
PACE 4
SCCTION XI!
SPECIAL PRECAUTION*
MINIMIZE SKIN CCNTACT. VASH V1TH SOAP IX) V1TIB ICFQOC UT1NC. OBlNKlNC. JlOcINC 08 USING TOUET
FACILITIES. LAUNDER CONTAMINATED ClOTMlMJ iEFOBC REUSE. >80«»Cfll.T OI$>0$C 0' CCNTitUmTIO
A*TICLtS. INCLU01NG SKIS. THAT CAWQT £ OCCOMTAMIM/.TCO.
SECTION XXXX
TRANSPORTATION REQUIREMENTS
DEPARTMENT OF TBANSPORTAT10N CLASSIFJCATION: WOT HArABOOUS IT 0.0.T. RCCUVATIONS
' ' ' "
SECTION XIV
OTKCA KECUUkTOftY CONTROLS
THE CCWOKENTS OF THIS ?BCOOCT ARE LISTED ON THE EPA-TSCA iNVENTOat OF CHEMJCAl SUBSTANCES.
THE INFORMATION CONTAINED HEREIN is BASED CN THE DAT* AVAILABLE TO vs A>O is BELIEVED TO BE
^WEVli. iHELL MAKES MJ VARRAMTY. EXPRESSED OR IMP'.IJO REGARDING THE ACCURACY OF THESE DATA OR THE
RESULTS TO SE OBTAINED FfiOM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR. INOUSY FROM THE
USE OF THE PRODUCT DESCRIBED HEREIN.
DATE PflEPAfi£D:JULY 25. ISIS
BE SAFE
READ "PUR' PRODUCT
SA/ETt XHfOWaTieH ...AM) PASS XT ON
(PRODUCT LIABILITY LAW
REQUIRES IT)
OOHN'P. SEPESI
SHELL OIL COMPANY
PRODUCT SAFETY AND COMPLIANCE
P. 0. MX 4320
HpySTON. TX 77210
;,! itulilj ..{Mi
-------
MATERIAL SAFItY DATA S H f f T
n-HOu* CKERCINCY THIPHONE (201) i$t«2ui
CHEMTREC * (100) Ut-tJOO NATIONAL RESPONSE CENTER f (800)
N3660 -01 NITRIC ACID ,iet, ,
EFFECTIVE: 10/01/15 ISSUED: oi/»m
«»««««*««»««««««»«*«««»«» '*»««s*.««*saB*««»x»****tflta*»tc«i« »'«*/**
SECTION I - PRODUCT IDENTIFICATION »»««.
PRODUCT NAMES NITRIC ACIO """»"«""»««.«.«..,.,.
FORMULA! HN03
FORMULA WT: *3,0l
CAS N0.» 07697-37-2
NIOSH/RTECS NO.: QU5775000
COMMON SYNONYMS: HYDROGEN NITRATE
PRODUCT COOES: ^801,9602,9598,9606,5371,9597,9600,51l3i96l6,9605,UQ\
PRECAUTIONARY LABELLING
HEALTH - 3 (POISON)
. FUHHABIUTY - 0
REACTIVITY - 3 (OXIOUER)
CONTACT - A (CORROSIVE)
LABORATORY PROTECTIVE EQUIPMENT
OGGLES SHIELD! LAB COAT C APRON? VENT HOOD! PROPER CLOVES
PRECAUTIONARY LABEL STATEMENTS
POISON DANCER
STRONG DXIDUE* - CONTACT WITH OTHER MATERIAL MAY CAUS6 FIRE
LIQUID AND VAPOR CAUSE SEVERE BURNS - KAY BE FATAL If SWALLOwEO
HARMFUL IF IHHAIEO AND MAY CAUSE DELAYED LUW INJURY
SPHLACE HAY CAUSE FIRE OR LIBERATE DANGEROUS
-------
'. t . '.; N A f E A 1 A L J A f E"? Y"" 0' A ....... T' A ..... J M E £ 'f ......
2S-HOUA EMERGENCY TELEPHONE -- <20l) is'f-2151
CKEftTREC » (800) *2*'*J03 RATIONAL RESPONSE CENTER (100) V24-M02
, , , ,..,, . , , ,, ». ^ . ,,,, , ,
NJ6&0 "01 NITRIC ACIO f AC , j
EFFECTIVES 10/01/15 I5SU60: 01/23/86
'
* «
««««*««*S"» = =*« = :
$OLUBILITY(H20): COMPLETE (IN ALL PROPORTIONS) X VOLATILE* BY VOLUME: 100
C OOOR: COLORLESS LIQUID, WITH CHOKING ODOR.
SECTION IV - FIRE AND EXPLOSIOM HAZARD DATA
N/A NFPA 70*M RATING: 3-0-0 OXY
IRE 6XT iNC'U t SHIHC MEDIA
WATER SPRAY.
f IKE-FIGHTING PROCEDURES
lFICHflRS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE HOOE
Mi CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE VATER
JO KEEP FIRE-EXPOSED CONTAINERS COOL.
FIRE t EXPLOSION HAZARDS
OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
SECTION V -HEALTH HAZARD DATA
10XIC CASES PRODUCED
NITROGEN OXIDES
THRESHOLD LIMlt VALUE (TLV/TWA): 5 M6/H3 ( 2 PPM)
SHORT-TEP EXPOSURE LIMIT (STEL): 10 HG/K3( 4
............ EFFECTS OF OyiREXPOSURE .................................
LiOUlD KAY CAUSE SEVERE BURNS tO SKIN AND EYES.
INHALATION OF VAPORS KAY CAUSE SEVERE. IRRITATION OF THE RESPIRATORY SYSTEM
iV I ;,,,.,, .j^HAIIfioN IF YAPORS KAY CAUSE COUGHINS, CHEST PAINS f DIFFICULTY MEATHINS
: i;;':l ..... > ' , OR UNCONSCIOUSNESS.
KAY ftE FATAL.
EMERGENCY AND FIRST AID PROCEDURES
CALt, A PHYSICIAW.
IF Spllblll, t>S NOT INDUCi VOMITINGS IF CONSCIOUS, GIVE WATER, MILK, OR
KILK OF MAGNESIA.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, CIYE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FO
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
WASH CLOTHING BEFORE *E~US£.
CONTINUED ON PAGES 3
-------
K A T C A l A L SAFETY DATA inter
24-HOUR EMERGENCY TELEPHONE (201) 139-2131
CHEHTREC * MOO) *2*-9300 --NATIONAL RESPONSE CENTER f (800)
NJ660 -01 NITRIC ACID
EFFECTIVE: 10/01/85 ISSUED: Ol/23/l6
SECTION vi - REACTIVITY om
«»x;««««szsxz*«ssixes«xzs«ax«*a»«xcxx«xx««s«««»t««tt«»t«»xexxx«B«8Bx»»*xax««i»«j
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL HOT occui
CONDITIONS TO AVOID: HEATf LIGHT
INCOHPATIBLES: STRONG BASES* COMBUSTIBLE MATERIALS,
STRONG REDUCING ACENTS
DECOMPOSITION PRODUCTS: OX106S OF NITROGEN
SECTION VII - SPILL AND DISPOSAL PROCEDURES
rssmri«a»r xxxxxxxx = = ***<>xazz = :zxz:xz
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. $TO
LEAK IF YOU CAN 00 SO WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL W
SODA ASH OR LIME. WITH CLEAN SHOVELt CAREFULLY PLACE MATERIAL INTO CLEA1,
DRY CONTAINER AND COVER} REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER,
KEEP COMBUSTIBLES (WOOD* PAP£R» OIL* ETC.) AWAY FROM SPILLED MATERIAL.
J« T. BAKER NEUTRASORB(R) OR NEUTRASOL(R) -LOW NA*» ACID NEUTRALIZERS
ARE RECOMMENDED FOR SPILLS OF THIS PRODUCT.
DISPOSAL PROCEDURE
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE* AND LOCAL
ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER* 0002* 0003 (CORROSIVEt REACTIVE WASTE)
* = ***S***S**«»****C*****'*»S*a*S«'**«S**S
SECTION VIII - PROTECTIVE EQUIPMENT
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEET
TLV REQUIREMENTS.
RESPIRATORY PROTECTION: RESPIRATORY 'PROTECTION REQUIRED IP AIRBORNE
CONCENTRATION EXCEEDS TLV* AT CONCENTRATIONS UP
TO 100 PPMt A CHEMICAL CARTRIDGE RESPIRATOR VITH
ACID CARTRIDGE IS RECOMMENDED, ABOVE THIS LEVEL.
A SELF-CONTAINED BREATHING APPARATUS IS ADVISED*
EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD* UHIFORH*
PROTECTIVE SUIT* ACID-RESISTANT GLOVES ARE
RECOMMENDED*
SECTION IX - STORAGE AND HANDLING PRECAUTIONS
x- s
-AF-T-DATA(TM) STORAGE COLOR CODE* YELLOW
SPECIAL PRECAUTIONS
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAHMARL5
CONTINUED ON PAGE: %
-------
« l.f I A I At S A f | T Y 0 A T A $ H I f T
7V-HOIM EMERGENCY TELEPHONE - Uol) I51-M31
CH£HTR|C t (l|pMi^-9300 NATIONAL RESPpNSI ||NTfi * (400-) 424-||0.f
N3440 -01
fFFiCtfVE: 10/01/1$
NITRIC AC 10
tit t »tt
*
H IX - STORAGE AN? HANDLING PRfCAUTSpMS (CONTINUED)
IYir«1|lS«««''«« ««««««'« a' «1ut««««m*tl««««««1t,»«»iit..,,,t.
CpMBUSTISLJ MATERIALS. *"*'*" ."
' i| *» « »*»«>«««*«*«««sxx«xm«S5«x, «.«».,, 8, ,l,,,t,,tjtai
I "TRANSPORTATION DATA AHO AOOITIOHAL INFORMATIOM *Si
S**«««s««««*«*««»«»U»LlCAno£S IT ?«
THE USER'S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF THIS lNFOR>U??il In.
THE ADOPTION OF «C1SSARY SAFETY PRECAUTIONS. WE RESERVE THE RI6HT ?J I|S?ce°*
SAFETY OATA SHEETS PERIODICALLY AS NEW INFORMATION BECOMES AVAIuIfr
III I ...... "l" /;'';', "i; ' ; :."/; . ..... {:, >; . ':, j _ . ; :i ' ..... ', ", ' ,'^f' .! 1*1
LAST PACE" "" ...... , ...... . ............ ' ....... '"'" '
,!!",,. ,,,,'i!"i. "!;'» TS
111, ":
'..Jll'i /',
-------
U/H/H
OATA
SfCTION 1 NAME A*0 «X»LJCT
Mint AND iOO'CSS CXCXICAL MjMigl: M
-------
IUTOIAL
OATA
].!<
scene* vui- SMCIAL MOTCCTION INFORMATION
MOTfCTtON:
AI*-SUmtlO »US*. 00 HOT 8fi£ATH| VAPOH.
VENTILATION LOCAL:
PiOVIDt AOEOUATt SCNEJUL MCCVUNICAC LHQ LOCAL CmiUST VfNTlUTION.
VtKTIUTICM MCOUNICAC:
M/4
OTHll
DO HOT GIT IH CTtS 0« ON CLOTH1HQ. fiCt SHHU) IUT 1C NCCCSSHT
MOTCCf iyi
SArtTt .......... «tovti
tYt
SAFETY COOCttJ
SECTION IX SPECIAL
KANOtlHC AND STORAC! PRECAUTIONS:
Ktlf CONTAlMIl TIGHTLY CLOSED. M3 JWOKIWC Off FLARES. STORC IN A
VELL-VENT1UTEO A»£A. AVAY fRCM SOURCES OP IGNITION. AVOID >90LCW3£0
0« «C^EATIO CONTACT WITH SXIN. If INGESTED. CAM CAUSC
CAWOT IE KAOC NON-POISONOUS.
SECTION X - OTHER
704:
1 ;;: "i - '"Wi!,! ^
1 3 0
HEALTH FUKXA8ILITY REACTIVITY
THE STATEMENTS CONTAINED HEREIN ARC OFFERED FOR INfORMATION PURPOSES ONLY.
VE KIKE MO VAJUUHTIES. EXPRESS Oft IMPLIED. AM} ASSUME NO LIABILITY IN CONNECTION
USE OF , THIS INFORMATION. ......... ................... ,, ' ......... , ........ ' ........................ .......................... , .................. ........ , ............. i;
NOTE: KA OR N/A DEMOTES NOT-AVAILABLE OR NCN-JU>PLICABLC
I IS
-------
UATE3UL iA/fTY DATA SKTT J.|i»
SECTION » HULTH KA7AIO OATA.
OSXA STO-HR: TV* 300 MM TX01: ORL>HM(L. A8SORH WITH SAM>.
VASTC DISPOSAL MCTHOOt
TO BE FEJtrOAMCO IN COMPLIANCE VITH ALL CURRENT LOCAL. STATE. AX»
FEDERAL RECULATIONS.
-------
;'ili'!i!|| I1 ,;!:> ,', i! >," t'lilii
-------
Mallinckrodt
Effacclva Date: 08-07-85
IDENTIFICATION:
SODIUM
Mittrla! Sifitv Pata
Kalllnctrodc Inc.
SeUnca Product* Dlvliton
P.O. Box M
Partt, lUncucky
taarj«ncy Telephone Nuobtr
j: S«lc
Foraul* CAS No.: 7647-1A-5
(Uztrdous Injredientt:
lion*.
Molecular Veljht: SS.44
Cheatcal For»uU: HaCl
PRECAUTIONARY
A« p»rc of good Induicrial «nd p«r«on«l hyjltna «nd »*fity proc«dur«. avoid «11
uiinecusary expoiure to the cheateal ub*tanc* and Iniuri proapt renovsl froa skin.
yet and clothlnf.
SEE S£C?10H 5.
DOT lldi»rd Claai: Hoc Regulatad
A|. [.r trance : Chlte crytCalllne.
SECTION
Odur:
Odo.less.
Solubility: 36j/100cc wat«r 8
Point: K13*C (257S'K)
PoJnt: 801'C (1474T)
S(>rclfle Gravity: 2.16
(6»T)
Vapor Denalcy fAlr-l):Ho Interval io<
fouitd.
Vapor Pretaur* (a** IJg) : 1.0 $ Ifci'C
(1589'F)
Evaporation Rate :Ho Inforaatlou (i..n
-------
fire
loo.
fir*:
SECTION
NoC considered to be a fir* hatird.
Ciploiton:
fit* Extinguishing Media:
Hoc considered to be an explosion hazard
,;;! ;;,' 'i . i i
Us* any aeans suitable for extinguishing surrounding
fir*.
II II I II
I
Special Inforoatlon:
if i; is -rfj
In th* avent of a fir*. wear full protective
clothlnj and HIOSH-approved «lfconciined breaching
apparatus with full faceplcc* oparaCcd In th*
pressure deaand or other poslclv* pressure nod*.
:i ;,
Stablltcy:
tf4zardpu< Decorapotltlon
Products:
SECTION ?
Stable undar ordinary condition* of use and icorag*.
Vhen heatad to abov* 80l*C (U74*F) 1C
-------
1nfor»Mlt.n.
Inhalation:
SFCTIOK
Inhalation of dust «av cause «lld irritation to ucous
(branes, noit and throat. Synptoac «ay Include
coughing, drynes*. and *or« throat.
InjeitIon:
Very larga dosas can causa vonjtlnj, diarrhea, and
prostration. Dehydration and congestion occur In MUSI
Intarnal orpns Hyperterlc salt solutions cm produce
violent tnfTaeviatory reactloni In the festrointestliiAl
tract.
Skin Contact:
Not cxp«ctad to b« A haalth hazard.
Eye Contact:
Kay cause Irritation.
Chronic Exposure:
Ho inforoatlon fout»d.
Aggravation of
Fre-exictlng Conditions:
Ko Inforaatlon found.
FIRST AID
Inhalation:
Remove to fraah «lr. Cet vedlcal attention for any
breathing difficulty.
Ingest I on:
Skin Exposure:
If Urge aaounts were 'svalloved, jet »edlcal advice
Wash expotad area vlth soap and vitar. Cet eedtcal
advlct if irritation develops.
Eye Exposure:
Wash thoroughly with running water. Cet medical advice
if irritation develops.
C. TOXICiTY DATA
(UTECS. 19«2)
Oral rat IJ>50: 3000 ngAg-
Reproductive effect* cited.
-------
n>a»ur»a
Airborne Exposure I. (alts:
SECTION $
Mont established
Ventilation Systea:
In general, dilution ventilation Is satisfactory
health hazard control (or this substance. However. If
conditions of us* createdlsconfort to the worker, a
local exhaust tyrtea should be considered.
1 ,r,i,l!' V'li'l I '» ''ill " '"I!1 '
fejonel Respirators:
(NIOSU Approved)
,1 '"I"1 'I,,, ' " . ,!,.« 'V ,! ! I,, if I1 '!' ' I' 'i.":», , '!| .,.,',, !! , , M. Hi; :,.:i,!. . , ' ' ! ,i , .
Tor conditions of use where exposure to the dust Is
Apparent, a dust/atsc respirator aay be worn. For
energencies, a self-contained breathing apparatus nay
be necessary.
Skin Protection:
Eye Protection:
Vear protective gloves and clean body-covering
clothing.
Use chenlcal safety goggles. Contact lenses should
not be worn when working with this naterlal.
Maintain eye wash fountain and quick-drench facilities
in work area.
Information SICT1QH 7.
Keep in a tightly closed container, stored in a cool, dry. ventilated area.
Protect against physical daaage.
«*«**«****«*<
The Information cohtTiried herein is provided in good faith and is believed to
be correct as of the date hereof. However. Hallinckrodt. Inc. Bakes no repre-
sentation *3 to the comprehensiveness or accuracy of the inforvation. It is
expected that Individuals receiving the inforoation will exercise their in*
dependent judgment in determining its appropriatenesa for a particular
purpose. Accordingly, Hall inckrodt. Inc. will not be responsible for daoagea
of any kind, resulting from the use of err reliance upon such information.
NO BEmSENTATlOHS. OR WARRANTIES. EITHER EXPRESS OR IMPLIED, OF
MEftaiAKtABILlTY. FITHESS TOR A PARTICULAR PURPOSE OR OF AMY OTHER
NATURE ARE MADE HEREUHOER WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR TO THE PRODUCT TO VHICl! THE INFORMATION REFERS.
-------
MATERIAL SAFETY DATA SHEET
EM SCIENCE _w
A Division of EH Industries
P.O. BOX-70
48O Democrat Bd.
Gibbstovn, N.J. 08027
_..NGLE
CINCINNATI,
45246
RX DRIVE
'reparation Date
>atS Sent to Cus
nformation Phon
i OCT
: Nov
Huab<>r!
NFPA HAZARD RATINGS
Health ....: l
Reactivity : o
Flamaabillty ...: 3
Special Harirds.: K/A
" ~~ SECTION I
Catalog Huaber(s)i PX1815
X1824
Chemical Kaae....i pro
DOT
DOT
-N/A
11 - HAZARDOUS JLNGKJblUILNTJ
rdistaaces to fignition: source;andrflash,back*j
'>' ' «-"'^ '"** ' *' ''
ic^al _
.fro*
, incoordlna
Medical Cond. Aq
Routes of Entr
carcinogenloit
atlon appea
Emergency tips
SJUnj valh. _,
Eyes: iMtediat
Inhalation]
_ wwwwww
to eyes
con
[estlon or
LD50: 1870
;e, and throat
ation: headache, nausea, dizziness,
ratea by Bxps Data not available.
I Inhalation* iAoestion or
.I See Comments. Section it»
le aaterlal is notltisted 4s a cancer
#i t ? . «»
^5fY y^ph soap/water
f fTfish thprou|hly,vith yater for at 1
[ toTfoesh aifi §ive artificial respi
,r-£T"- or skin contact.
ection X; If no Infora-
a cancer causing agent
. 15,,.-
on if
- KKAll'JLVJLTK UATA '
M8D8-PHS15 Page I i 01
:ii7s:£££^:s:££^^
-------
ability*(.«.««.«)
nditlo&« to AYoid .....i
"l"t!l/Krw4lSp iia"
!xl 8!K?
taxardous
lasardous
YES
ot surfaces
Wat
Ox
s», Hal .
Data not
COx
collect on absorbent
with
, Strong oxidizers
cur«nt
«.*« j.j ^fi^fJtw*.viii - fcreyiAK JMOTKCTiUN INi'OKHATlOH
'££*&£&?'J&?irfiI°&.J?2£'Sli25' *5°t«ctlve clothing,
l?^!t£E«1eluat* v!3ln;So?frrai In an appr^
^^.SSi^f Si?X«»^(NS9^enei_Nitrile or eouivalentJ sh
e worn |S |rS?e|t(SSf§r|SStag|trile or ^^alent) should be
Safety glasses with side shield!
Is »ust be worn at all tiaes
Handling t storage *...«
-Keep'contalner closed
Stor§ in cool. well-v<
< and oxldlzers
ri-tgratory anlaals -..,-^.w^v.^
Bjutagenic effects and cause.tuoors
'". ; "''' :":'ii.,!' Xi" ' "J'SlI" 'li * v" !' " 'it I , ", ,.i,i!!' '' -' " if'',! , ' ,. ", JIV'Jiiji. '' |^ . . »
k I* "*--*';!
History....
N/A ss Not available:
86
;. ' . i *"!''!*!'' ii* i , "t ( r"
it i '.
": ' ,.. , ' ' ,'ks'DJ3-?zi8l5 Page it 02
eo~tw «< -« *»« **u. *.
-------
J.TBaker
34 Houf Efixirgwy T«i>pNy* - (201) 859-2151
Ch4mu»< I (*00) 424-IXXJ
H«IIoojl *«lfx>«w C«nl«f 8 OOP] 124-JJOJ
SAFETY DAT.
C«3S -OS
Effective: 04/15/87
Glycerol, Anhydrous
SECTION I - PRODUCT IDENTIFICATION
P«ge
Issued.1 11/03
Product Hatne:
Formula:
Glycerol, Anhydrous
HOCH2CHOHCH2OH
Formula Bt: 92.10
CAS Mo.: S6-81-S
NIOSH/RTECS Ho . : HA80S0006
Common Synonyms: 1,2,3-Propanetriol; Glycerin; Glycyl Alcoho
Product Codes: 2141,2135,H?78,213S
PRECAUTIONARY LABELLING
SQF-T-DQTft Sstem
gjCHT SLJOff
Laboratory Protective Equipment
Kfcrrart
IOC
canter
surwr
Precautionary Label Statements
CAUTION!
HAY CAUSE IRRITATION
HAY BE HARMFUL IF SUALLOUED
During use avoid contact uith eyes, skin, clothing. Uaah thoroughly
handling. Uhen not in use keep in tiohtlu «O0«.,* M~»,.--._ tou9niy
keep in tightly closed container.
Storage Color Codes Orange (general storage)
SECTIOH II - HAZARDOUS COMPONENTS
"***'"**mummmmmmmmm*mmmmBmmmm
Cotnponent
, Anhydrous
1 CftS Ma
90-100 5S-S1-5
Boiling Point:
SECTIOH III - PHYSICAL DATA
' m m*mmmm m m m m m m m m »
290«C ( 55VF)
.
"
Ccntir.ued on Pace: 2
0 0 0 X5
-------
O»mU»C I (100) 424-1)00
C«ntif f (100 I2UM2
c" n Mn "i.;
CM33S -05 Glycerol, Anhydrous
. ........ ........
SECTION in - "PHYSICAL DATA
..... ill I . ' >! ' ! . ,|i ',:'"},; ill!
"I!1'"'! ' " ., n. . -, i | -. : ', '. ' 1)1*111
Point: 18'C< 64*F) U«por Density(air-l): 3.1
Gravity: 1.26 Evaporation Rat.:
0): Complete (in all proportions) t Volatiles by Uoluae: 0
Appoar&nce & Odor: Clear, colorless, odorless syrupy liquid.
I ; J I r. " I|E§WH,' iv':- "FIRE,, AND EXPLOSION "HAZARD DATA""*"""
I || ." ,; iBHi I, itL i, Ji /»! .:,-" '&. :. Hut1 i,,i',,! ?: ,!, !,.,'!' , ; .. " i" , , , tii' ,s'. :!"!; in i "i , ., .ran "..!! ', . - « * ">. ,,',H, , s , ,, , n ',, .
Fl*»h PoInC tciose| Cup): i39»C ( 390«F> HFPA 704H ValYng"" Y-Y-Y"
FlAiwmabio Liaits: Upper - N/A \ Lower - 0.9 %
I I \'\ I, Iljij!.'![;:' .,;.;' 'I; .1 '''If -:; ;.;i, ..t' '" £:""'" , I -. "' ii «"» '"..S ; I ' "''' is!" ' I " » ,,J '?! ' , '' \ ' ":> ,, '7 '*:;; *:!! i: 'i -.'ill
Fire Extinguishing Media
Us* extinguishing oedia'appropriate for surrounding fire.
I I i .' ijj'i; ,;, III 11111 "':' 1 ' i .', ' . 'iii ti': >>' :, ."''ji,'1 'i ' ;": '.' ins' ,,!' :;' ;: ' ,,. : :, < ""lluli1 ' '», *n''\i,i'
Special Fire-rightirxy Procedures
Firefighters nhould wear proper protective equipment and self-contained
breathing apparatus with full facepiece operated in positive pressure «ode
linn i i i in I i n in H '!,» r>:''' ' .« h ; 'h 'in: ;i; >n jiiii',:
Tire t Explosion
Contact with strong oxidisers may cause fire or explosion.
Toxic Gases Produced
carbon monoxide, carbon dioxide*, acrolein
mmmmm^^mirmmmmmmBmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmm*
"SECTION 'v'- HiEALTH"HA3AKo"DATA" "*"
Limit Ualue (TLy/TUA): 10 »g/m3 (
Toxiciiy: LD5Q (oral-rat) (g/kg) - 12.6
:' ,, (| ' LDSfl (ipr-»>ouse) (»g/kg) -".'63
" "", ' ,,i U>so {s"cu-"rat) (»g/Tcg)
LD (iv-rai)
Carcinogenieity: NTP: No IARC: Ho 2 List: No OSHA reg: Ns
jcl, ,i;i' .i;,! P ill ; i,"" , .' ' i" "|l" >' " ' " -7i ';>.,' '. ' '. ;"> ' "' i : ' . i,"1 ' , iiiiSM1 .-i,1';
of OverexoDsure
Jnl>«l*,Ji9"S °* vapors my cause coughing and difficult breathing.
Contact with skin or eyes *>ay cause irritation.
Prolonged skin conta'ct way cause dermatitis.
1 *. I.; ! ii""1"!: , I1 ' !,'. ,;i '; t; ;V- 1 3 / :; '. '" ! , ji' 'i,'. ' .. .,'' _ _
Continued en Face : 3 (J (j
mi iijftu ;;; ,, , ,,,, ,, , ||| ' 'S": :'' ' a '! i1 ' ,\»"' '",!,, M ,'. "I ,!,; . , ^\: ' ' a', i" !.: , ' ', '" ' ,' ,
-------
Ktftxut
f (100) 424-1)00
C«nl«r I (IOC)
C4836 -OS
Effective: 04/15/87
Glyccrol, Anhydrous
^«VWV>>VWBVMI
SECTIOH U - HEALTH HAZARD DATA (Continued)
Pages 3
Issued: ll.'Q9/88
Ingestion may cause headache, nausea, vomiting, gastrointestinal
irritation, convulsions, and unconsciousness.
Target Organs
eyes, skin, mucous membranes
Medical Conditions Cenerallu Aggravated By
Nona Identified
Bootes Of EntrtJ
eye contact, skin contact, inhalation, ingestion
Emergency and First flid Procedures
INCESTIOhU
INHALATION:
If sualloued and the person is conscious, immediately give
large amounts of water. Get medical attention.
If a person breathes in large amounts, move the exposed
person .to fresh air. Get medical attention.
EYE CONTACT: Immediately flush with plenty of water for at least IS
minutes. Get medical attention.
SKIN COMTfiCT: Immediately wash with plenty of soap and uater for at least
IS minutes.
SECTION UI - REACTIVITY DATA ...
Stability: Stable Hazardous Polymerization: Uill not occur
Incompatibles: strong oxidizing agents, strong acids, strong bases
Decomposition Products: carbon monoxide, carbon dioxide, acrolein
SECTION VII - SPILL AMD DISPOSAL PROCEDURES -------
Steps to be tafcen in the event of a spill or disc-harp^
Wear suitable protective clothing. Take up with sand or other noncom-
but-tible absorbent material and place into container for later disposal.
Flush spill area with water.
piaposal Procedurq
Dispose in accordance with all applicable federal, state, and local
environmental regulations.
SECTION UIIX - INDUSTRIAL PROTECTIVE EQUIPHENT """"
i?entilaticn: Use general or local exhaust ventilation to meet
TLU requirements.
Heapirciery Protection: Respiratory protection required if airborne
concentration exceeds TLU. At concentrations
3
above 10 mg/m , a dust/sist respirator i«
Co-it irced :r ricet £
-------
'ir1'"!, i*' ' 'in1' "'I "i' Kiii'1 ii1 "' ,i' ,i:i,.;'"' iiw :f , ; :i' , it,!1 ';," J"" i' w J '"ii: *i nlh.: -i i i n n in i n i v n i in inn i n i
24 Hour CrofQtnqr TdtpNx* - (2Ct) 15
CfemiiK f (IOC) 424.1)00
'SHEET
G483S -P Glycerol, ftnhydrou* f49-: 4
Eff«ciiv«J 04/1S/87 Issued: 11/89/88
« "*' i
SECTICM UIII - INDUSTRIAL PROfECTIUE EQUIPHDIT (Conlinoe<|)
( ^W(
?l< . , f; ..":. , ,..: a?; " " .
' T>rftetfHft"T T6^^AL C T . H . 0 . )
Proper Shipping Name Chenicals, n.o.s. (Non-regulated)
..«.!.»«..*» I,*.* -»**'--»»---».»
» Hot Applicable or Hot Available
, , ,, , , , ...... ..... . . . ....... , ..... ,
Th* information published in this Material Safety Data Sheet has been compiled
from our experience and data presented in various technical publications. It is
th* user's responsibility to determine the suitability of this information for
|h^i adoption of necessary safety precautions. Ue reserve the right to revise
*-%f»ri»l Safety Data Sheets periodically as new information becomes available.
J. T. faker Inc. makes no warranty or representation about the accuracy or
completeness nor fitness for purpose of the information contained herein.
1988 J.T. BAKER INC.
-TRADEMARKS OF J.T. BAKER INC.
-------
US Environmental Protection Agency
Water Pollution Laboratory Performance Evaluation Study 40
GENERAL INSTRUCTIONS FOR REPORTING RESULTS
REPORTING INSTRUCTIONS
Your seven-character EPA lab identification code is shown on the
label affixed to page 1 of the data reporting form. This is a
permanent number that was assigned by the USEPA the first time your
lab participated in a performance evaluation study and must be
entered at the top of each page of the data report form. Make any
necessary changes to the name/address information on the label.
Along with each analytical result, report the two-digit code for
the analytical method used to obtain that result in the column
marked "MC" (see analyte/method list). When code 99 is used to
indicate that an "other" method was used, the method must be
described briefly on a separate sheet attached to the report form.
Do not submit a written copy of an "other" method to EPA. If
atomic absorption was used, indicate whether it was an air-
acetylene, nitrous oxide-acetylene, platform, or non-platform
method..
Type or clearly print analytical results in the column marked
"Quantity" using specified units in the appropriate blocks (right
justify results) on the forms provided.
Do not enter dashes or other characters in place of a value. If an
analyte is not detected, either leave the appropriate reporting
area blank or report your detection limit along with a less than
(<) symbol. Do not use less than or greater than (>) symbols if
they can be avoided.
A decimal point requires a separate block.
Report all results to three figures.
Except for methods such as for trace metals analyses in which
multiple aspirations or measurements are routinely used to
determine a concentration, report results of a single determi-
nation, not an average of multiple determinations.
Data not reported according to instructions included in this
package will not be evaluated.
Provide any notes or comments on a separate sheet of paper attached
to the report form.
NERL-CI
598
-------
: ' US Environmental Protection Agency
lll!l" , ; " i " » i'1'11 l|'";l ','" i' ' ll!l1 ,'1!1 '' ' ' ' :i' 'i1',; " "" ,'i ll!i ' 'I! r ' ' .I ' ' , "
GENERAL INSTRUCTIONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
'".: (Continued)
!!.. -^' . if ;':;,. Methpd
Analyte '
.!< I 'llil I'"' I'1 I1'! "IF , ' ' '
Trace Metals:
Aluminum
I !' Ii I'!., . .1 .,,.. , 1
ir'uil III'1 ". ' " i.i1.'
ll'11"11 ' '
i'1 ;' i"' I
"' .1,1 'V 1 . ' . ''
i'Y , ''"i1 ",,T', V
': ' ,' 1' ' :,'",:" ,, "' ..".,..
', ;;; ,:;,,' :'1'1'' ,,:j,, -="'
"
1' ' , ,1 1
""1," , II. ''.
Antimony
": £;; ::.
,,,, lll»ll,ljlll ll'l
,!'"'! '!!! " ' ' " ' ", '
, ' :"! ' '.".
Arsenic
u
j,"i;|!j>l'i|
Code
13 ',
14
ill ll
15
26
1
27
28
29
i'i,=31
""ii3,.
56
",99 ,'
nil i
13 ' "
14
15 _
"2"3
2,4 ...
Ife '
99
14
15
"16
,1"7
'"'"I"!",1
20
21
22
29
31
,,,'hr
32
^
45
"46
it
ReJF
R19
R24
,,,''-
R24
R89
R89
R89
R89
R25
R79
R80
O
R24
.'. R?4
R19
R89
R89
R89
O
R19
R24
R24
R24
R89
R89
R89
R89
R25
R25
R25
1 nil ' '
R79
R79
' " '
-Method
- 200.7
... - 202.1
- 202.2
- 3 HID
'" i: , ,» , : , i ' "r ; ; ,,' , ,,
; r 3.113B
- 3500D
- 3120B
- D4190-82 (88)
, - ,1-3051-85
- AES0029
ther
T ':
« , !!!i i . i!|i; ' 1 ' ,
- 204.1
- 204.2
- 200.7
" -' 3'lilB
- 3113B
-' 3i20B
ther
- 200.7
- 206.2
- 206.3
- 206.4
. ',
- 3114B4d
- 3113B '
- 3120B
- 3500C
- D2972-88A
- D2972-88B
- D2972-88C
- 1-3062-85
- 1-3060-85
Description
Inductively Coupled Plasma (ICP)
Atomic Absorption (AA) :
Direct aspiration unless
otherwise noted
AA; Furnace
AA ' ' '!""1'.
AA; Furnace
Eriochrome Cyanine R
ICP
Direct Current Plasma (DCP)
AA
DCP
IH ;,, , , il jll,,;,; ,_, 1' , ' , . ,,,!' '. , , I.' !
AA ' ' ' ' '
AA; Furnace
ICP
AA ' ' ' :"'"
AA; Furnace
ICP ' '.',..'
ICP
AA; Furnace
AA; Gaseous hydride
Silver biethyl-
dithiocarbamate
1' 'i » ;in"""llll! ' ' , ' "., "" ih
A|^.; Gaseous hydride
AA; Furnace
ICP
Silver biethyl-
",(, i I",. "I"
dithiocarbamate
Silver Di ethyl -
dithiocarbamate
AA; Gaseous hydride
AA; Furnace
AA; Gaseous hydride
Silver Diethyl-
PI ' " ii,1 "i, , ,, iii,/ " , *
dithiocarbamate
99
Other
-------
US Environmental Protection Agency
(Continued)
Method
Analyte Code
Beryllium 13
14
15
26
27
28
29
31
32
33
43
56
99
Cadmium 13
14
15
20
21
22
23
24
35
36
37
38
39
44
45
46
52
55
56
99
Ref . -Method
R19 - 200.7
R24 - 210.1
R24 - 210.2
R89 - 3111D
R89 - 3113B
R89 - 3120B
R89 - 3500D
R25 - D3645-84A(88)
R25 - D4190-82 (88)
R25 - D3645-88B
R79 - 1-3095-85
R80 - AES0029
Other
R19 - 200.7
R24 - 213.1
R24 - 213.2
R89 - 3111B
R89 - 3111C
R89 - 3113B
R89 - 3120B
R89 - 3500D
R25 - D3557-90A
R25 - D3557-90B
R25 - D4190-82 (88)
R25 - D3557-90C
R25 - D3557-90D
R79 - 1-3135-85
R79 - 1-3136-85
R79 - 1-1472-85
R8 - p. 37
R81 - 974.27
R80 - AES0029
Other
Description
ICP
AA
AA; Furnace
AA
AA; Furnace
ICP
Aluminon
AA
DCP
AA; Furnace
AA
DCP
ICP
AA
AA; Furnace
AA
AA; Chelation-extraction
AA; Furnace
ICP
Dithizone
AA
AA; Chelation-extraction
DCP
Voltametry
AA; Furnace
AA
AA
ICP
AA
AA
DCP
-------
US Environmental Protection Agency
ill, GEI3ERAL INSTRUCTIONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
- - (Continued)
Method
Anal yt'e Code
Chromium 13
".. .' ' ''..'" ' 14
'; 15
Ji.; " "i,;J 16
'''I , , '. ' , '!i 20
21
" ' ' ; "'' '22
'' '' ' ' ' 23
24
, , 35
if !!"'' ;1 . 1,1'! i 36
- ' ' '""; "' 38
;;,:': ., , 44,"",' ',
55
56
99
Cobalt 13
14
, 15
! " 'i ' , ni O C
,,' ' « £t+J
;:'" ' , 26
:.,. . , , . 27
;. '28
"I! .. 34
,:,;; 35
36
i ,37
T, 44
!"' . ' 1 "
'!' " ,!! 51
56
: ' 99
Ref .
R19
R24
R24
R24
R89
R89
R89
R89
R89
R2.5
R25
~R25
IJ79
R81
R80
-Method
- 200.7
- 218.1
- 218.2
- 218.3
- 3111B
- 3111C
- 3113B
- 3120B
- 3500D
- D1687-92B
- 04190-82(88)
"'- lpl687-92C "",""
- 1-3236-85
- 974.27
- AES0029
Description
, ICP i
AA
AA; Furnace
AA; Chelation-extraction
AA
AA; Chelation-extraction
AA; Furnace
ICP
Diphenylcarbazide
AAi
DCP'' """"l" '"" " ' ' ' """:":l"""'
AA; Furnace
AA '" " ' ' ' , "
AA
DCP
Other
R19
R24
R24
.R89
R89
R89
R89
R25
R25
R25
R25
~R79
R8
R80
- 200.7
- 219.1
- 219.2
"- 3111B
- 3111C
-. 3113B
- 3120B
- D3558-90A
- D3558-90B
- D4190-82 (88) '
: D3558-90C
"-!'- 32 3 9- 8 5 ,
- p. 37.
- AES0029
ICP
AA
AA; Furnace
AA,,' '.. "", ' ' , ' '. . ' ','","'
AA; Chelation-extraction
AA; Furnace
ICP
AA
AA; Chelation-extraction
DCP
AA; Furnace
AA" I '
'"AA!
DCP '
Other
-------
US Environmental Protection Agency
Method
Analyte Code
Copper 13
14
15
20
21
22
27
28
29
30
35
36
37
39
44
45
52
54
56
57
99
Iron 13
14
15
20
21
22
27
28
30
36
37
38
39
43
53
56
57
99
(Continued)
Ref . -Method
R19 - 200.7
R24 - 220.1
R24 - 220.2
R89 - 3111B
R89 - 3111C
R89 - 3113B
R89 - 3120B
R89 - 3500D
R89' - 3500E
R25 - D1688-90C
R25 - D1688-84A(88)
R25 - D1688-90A
R25 - D1688-90B
R25 - D4190-82(88)
R79 - 1-3271-85
R79 - 1-3270-85
R8 - p. 37
R41 - 8506
R81 - 974.27
R80 - AES0029
Other
R19 - 200.7
R24 - 236.1
R24 - 236.2
R89 - 3111B
R89 - 3111C
R89 - 3113B
R89 - 3120B
R89 - 3500D
R25 - D1068-90C
R25 - D1068-90A
R25 - D1068-90B
R25 - D1068-90D
R25 - D4190-82 (88)
R79 - 1-3381-85
R44 - 8008
R81 - 974.27
R80 - AES0029
Other
Description
ICP
AA
AA; Furnace
AA
AA; Chelation-extraction
AA; Furnace
ICP
Neocuproine
Bicinchoninate
AA; Furnace
Neocuproine
AA
AA; Chelation-extraction
DCP
AA
AA
AA
Bicinchoninate
AA
DCP
ICP
AA
AA; Furnace
AA
.AA; Chelation-extraction
AA; Furnace
ICP
Phenanthroline
AA; Furnace
AA
AA; Chelation-extraction
Phenanthrol ine
DCP
AA
Phenanthroline
AA
DCP
-------
US Environmental Protection Agency
!
Analyte
Lead
,' ',. i , . .: , .,.
i, '!: ;,
=i ;, ;!'
:;;,': '"
I, ,,
!r,l, " ..... 1
,: '..',
Manganese
i, '
.i'.,.
u
"'I'
.fii1.: , ..' '
,
:, ,.
1 i
Mercury
I
Method
Code
13
>:' 14
15
.... .,', ' '-20
".' ",'I ' "21 ",
i! ilii, , ',,.,,'" "
22
23
"" ' 2,4
:"35 ; ' .'.
,36,,,',
37
38
39
' ' " .43
56
57' '";"
' "99
13
: '.';« 14'
15
20
21
22
28
29
35
36
37
38
'';;.; ";' 43
"' ,:;r:'! !, 54"' ' ' !"
... - ...i ...
'.;',:; 56
"" 57"
58
"I , 9.9
is
'; 14
"'-: 23
' , ,;;:,; ;.. 33
':'"' ' 43
51
99
(Continued)
Ref . -Method
R19 - 200.7
R24 - 239.1
R24 - 239.2
R89 - 3111B ;
"';R89 - "Miic ,""' ;
i " ' ' i1: , i ," ''" I1
R89 - 3113B
R89 - 3120B
R89 - 3500D
R25 - D3559-90A
R25 - D3559-9QB
R25 - D4190-82(88)
R25 - D3559-9bC
R25 - D3559-90D
R79 - 1-3399-85
R81 -974. 27
R8d - AES0029
Other
R19 - 200.7
R24 - 243.1
R24 - 243.2
R89 - 3111B
R89 - 3 11 1C
R89 - 3113B
R89 - 3 12 OB
R89 - 3500D
R25 - D858-90A
R25 - D858-90B
R25 - D4190-82 (88)
R25 - D858-90C
R79 - 1-3454-85
R4.1 -' 8034 ' , '
, ii , ... ' , ; . .
R81 - 974.27
R81 - 920.203
R80 - AES0029
Other
R24 - 245.1
R24" - 24;5.2
R89 - 3112B
R25 - D3223-91
R79 - 1-3462-85
R81 - 977.22
Other
^ *-* *-* "..«. j-*j.\. j. \^j-i j-iw j. j. \-u.i u j. i*r±.f j.j^n^
Description
ICP^ | i ^ |
AA
AA; Furnace
'I),!,:: \\ ! ' . JiTPil illn" .''I! ', ,,,''., . ..! .in h Ir'lli,!,.'1 ," .'Mi 1 'i
AA
AA; ;"chelat"i"on-extra.ction'
AA; Furnace
ICP
Dithizone
AA "
AA; Chelation-extraction
DCP
Voltametery
AA; Furnace
AA ':" " '"" "" ' ":" " ' : "":'! : ":
AA
"' , ' . ' j'l1' 'l!!:!.. " '" "' , '"'" '... ' "';.' 11 . :" '. . , if:" ».
DCP
ICP
AA
AA; Furnace
AA , , , :,n
AA; Chelation-extraction
AA; Furnace
icp;
Persulfate
AA
AA; Chelation-extraction
DCP
AA; Furnace
AA
j. . i1-:,".! , . Mi '" ' . ' :": ' ; :» i -..*
Periodate (pp. 2-113 and
2-117)
AA
Persulfate
DCP
.
Manual Cold Vapor
Automated Cold Vapor
Manual Cold Vapor '.
Manual Cold Vapor
Manual Cold Vapor
Manual Cold Vapor
'ill. 'ill." . '" ,"' < 'I'lllll
lijii'l 'Si" ." ' il "Ml
..iliiii;;,: i 'i. ''
-------
US Environmental Protection Agency
(Continued)
Method
Analyte Code
Molybdenum ' 13
14
15
23
24
25
42
52
99
Nickel 13
14
15
20
21
22
27
28
34
35
36
37
43
52
99
Selenium 12
13
25
26
27
32
43
99
Re f .-Method
R19 - 200.7
R24 - 246.1
R24 - 246.2
R89 - 3111D
R89 - 3113B
R89 - 3120B
R79 - 1-3490-85
R80 - AES0029
Other
R19 - 200.7
R24 - 249.1
R24 - 249.2
R89 - 3111E
R89 - 3111C
R89 - 3113B
R89 - 3120B
R89 - 3500D
R25 - D1886-90A
R25 - D1886-90B
R25 - D4190-82 (88)
R25 - D1886-90C
R79 - 1-3499-85
R80 - AES0029
Other
R19 - 200.7
R24 - 270.2
R89 - 3113B
R89 - 3114B
R89 - 3120B
R25 - D3859-88A
R79 - 1-3667-85
Other
Description
ICP
AA
AA; Furnace
AA
AA; Furnace
ICP
AA
DCP
ICP
AA
AA; Furnace
AA
AA; Chelation-extraction
AA; Furnace
ICP
Heptoxime
AA
AA; Chelation-extraction
DCP
AA; Furnace
AA
DCP
ICP
AA ; Furnace
AA; Furnace
AA; Gaseous hydride
ICP
AA; Gaseous -hydride
AA; Gaseous hydride
-------
1" !"" , " Q
, ,'., ; O
' '
%
f
., ii 111 US Environmental Protection Agency
: i! GENERAL INSTRUCTIONS FOR REPORTING RESULTS ' IN WATER POLLUTION STUDIES
; , ,; '' '' ' ' " ' ;";;...
1 :!:;,:,'' "i"; '': ':;"!::; :"' ' Method
Nil!!;,' '.[ ''Analyte ' '"" Code'
;,; liji ' ;: ..Silver 13
' ';!' "I'l "Msi; "' 1 15 ...
;. K ir[ !.'' ' 1" i Ili! '20
111::::;,1!' "I; ;: :' ,1- .' ""'"' : "HI ^ '"''
:. !- '1'i '< ' ill : ' ' . if' '23 ' "
Vf ' T! H I3;,! , '':, '. ' Si '4,3
t< fir ii : . ,'K.i' ' "..-' ,'M |52""
;;,.!,, ! , " i' M|| ; ' '" , ' "' ' ,* '!, ' 5Y
i i," 1 !' :':! , «i l'1 ' , !r ' . 'lili
. ; . ... ;....;, , .;.,,,,, ;, QQ
!::: :!!:! " '; *' "Strontium 99
i '(M :,i in "' ill I'l'' . i. " . if " I1 "H1" i, . .
:ri'"'ij' '1. I' "" i nUillf. " hfi,1 L , " ii, liilivll !, ' I
" ''' -1"11"'1 'Thallium 13
"'; i,:" ' '»' ":"' ;""' . " ''."'.' ,'= .14
, , ,n , T r-
'" G'lilP ,, lit I1'1" ' '"i'1' »i, Mil -1--3
,:,, '!'," : ..':'" , ';:"!;! , '. ' '*;! 23
;;; ;?!.'" , ;( '«' , iii'i; [, ' /'',; :;. Jfi ''..
j;j||pj! i; .I'T.itanlum " .' '..,. .'13
""":i!'' ':.!! '. "', , !.J! : : '", *',; ,23
: , .:: ,57
" ";: : ":" ',:,:,:'"' , ',;;,; '99
,, , ,, . ,, Vanadium ,.,. 13
,;,.,": : .[ ..." ":", , .14
',;,;;, "; ": ,; ' 'is "
;;;' ' " ;:: ... . " !26
27
1 ' :, ".; , , ' i, '28
'.;.'' . '33
: i ! lii" ' , , '. 57
;;, ':'. :; :,:::;; ' 99
(Continued)
: .i . >' ' .: . ' :,.
Ref . -Method
R19 - 200.7
'R24 , - 2721 1
,',,R24 - 2 7 2 . 2 h
'..I ]R£9. - 3111B ' ' '',.
R89' -..3.113B,;..
' R89";"- 312.66 ,'
R79 - 1-3720-85
, R8 - p. 37
R81 - 974127
R80 - AES0029
. .. . 1,1 S ' ! , ' . .' '" : '
Other
Other
"''i1', ' '""'il, ,:, I1 ';;'''' ' , "' ' i '"
R19 - 200.7
',", ',"_ R24, -' 279.1 '
R24 - 279.2
R89 - 3 12 OB
..,' V| ( '"other ' '..,, .. ,,.'
R24. -, 283. 1,"
R2.4... - 283, 2
R89 - 31liD:
R80 - AES0029
Other
R19 - 200.7
R24 - 286.1 ,
R24 - 286.2
R89 - 3111D ,
RP9, - 3 12 OB
R89 - 3500D
R25 "- D4190-82(88)
R80 - AESOQ29
Other
i , ,11,,!' ' if L "i::1 '!'!,, ,; i , ii: " PL i in1,,,
1 , , ,, , n ,
Description
ICP
:.y." '':"' ' ; ,. , ' ' ,; , i" , ; ; ioi t
AA
"'" i ,'',!" i ; ' ,' i ' - ;' ' i1 >; ', ' - = , ::i in 4 '
,AA; Furnace
'AA.. " ' '.'"" ' /'. ' ' , , "";", ' """"1 T,'
AA; Che 1 at ioia- extract ion
,AA; ' Furnace
ICP'
AA '.
AA
' i, ,i f '',',!' ' " , ' :M ,,. "j! , :,:':", l ill,
AA ,
DCP
"'"l j!!" ' '' ' ' ' " |l'1"" ' "'' '"
i 'n ' i '' ' " h , t" it1 " "''i'l"'!1 1 ,:« i
T ,,: ,,i ipl,1, ,,,'« , ' , - ' ' ,'»,,,' ,,i|l!l i 1 W,' 1
ICP
AA
AA; Furnace
""'' :' , :m,;i' ' ; , ' IM ,,; "'in:, i, i',,1;
AA ..
ic'p"
1 '! !''!,, ' , , , ' , , ' ''i , ' "null' 1 ' , '
.AA,, ',, ' , ' " ' \ " ' ','
AA; Furnace
AA
DCP'
. in ,' ,, ir, . i , ,
,ICP
AA
AA; Furnace
,AA ' "
ICP
Gallic Acid
DCP" \ ii
DQP " ,",,,'" ' ',, ,', ' ,' i,',' "1 "',
,
'. ,1
"',,:I
' ' ini
,, ,1; ' /"I
'iilll'
, ".J
; .'li
:-' ,"i '
, ' in
, 11
, 'ii
1 < HI
' ".111
';" Ill
,'', "II
" Lin
,,,,, , ,
ill If
'Hit
-------
US Environmental Protection Agency
(Continued)
Method
Analyte
Zinc
Minerals :
Specific
Conductance
Total Dissolved
Solids (TDS)
Code
13
14
15
20
21
22
27
28
34
35
36
43
52
54
55
57
99
12
23
32
43
53
99
12
23
42
99
Ref . -Method
R19 - 200.7
R24 - 289.1
R24 - 289.2
R89 - 3111B
R89 - 3111C
R89 - 3500F
R89 - 3120B
R89 - 3500E
R25 - D1691-90B
R25 - D1691-90A
R25 - D4190-82(88)
R79 - 1-3900-85
R8 - p. 37
R41 - 8009
R81 - 974.27
R80 - AES0029
Other
R24 - 120.1
R89 - 2510B
R25 - D1125-91A
R79 - 1-1780-85
R81 - 973.40
Other
R24 - 160.1
R89 - 2540C
R79 - 1-1750-85
Other
Description
TCP
AA
AA; Furnace
AA
AA; Chelation-extraction
Zincon
ICP
Dithizone
AA; Chelation-extraction
AA
DCP
AA
AA
Zincon (pp. 2-231 and 2-333)
AA
DCP
Wheatstone Bridge
Wheatstone Bridge
Wheatstone Bridge
Wheatstone Bridge
Wheatstone Bridge
Glass Fiber Filtration,
180°C
Glass Fiber Filtration,
180°C
Glass Fiber Filtration,
180°C
-------
10
US Environmental Protection Agency
INSTRUCTIONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
~"; ',.: , ;;'";;'- ' ' '' ' \ (Continued)
Method
tS
Code
Ref.-Method
Descrintion
Total Hardness
(as CaCOj)
i, lit,:;
'il il!lll'|i!l,
Hil III.1-
H ',
17 -
4 ',
2,4
14 R24 - 130.1 Automated colorimetric
15 "R24" -' 130.2 EDTA
16 R24 - 215.1 + 242.1 AA (Sum of Ca and Mg as
: : " , : '," '.; : '. '".'. .:' ' ' carbonates)
R2l,i, T ,i2Qp''.'7 ", "'" " ' IQP ',(?w" pf -99- and'Mg'as'
,,,, , , ",,,,'',, , , ., , carbpnates)
- 2340'C ' " '"'" EDTA "" ' '"'"
"" " '"','' "I'Si ,|i" "'T,'8"'1!'""' "'i ','. H 'if1 ' i »"!' " ""',' "'Si! ',' . .'|!||i!i|iij,'1': ' ,! 1,1,,'" ",; "\\ ' , ' :\','
'-, 311 IB ,",'" "' AA,(sum of Ca and Mg as
jriaillll, "iii "1 '' "; " 'M |:|",:,, ,|, iiiui: nil1" "' ,':,;' I""1.' ,1!,, ' ,,,i ' , 11 ' ' '' ' , ,," fill ",, " ^ ,,"l I,.1"' 'ml '" ,1,,,'H" ' ' ! , '
'"ilJIIji'l ,1,11" ;1 "ii1 HILrif ,, "'rVi '''''i'HI!' , ""M1 i1 '"''V''"'! ' |, " ir ' '' ',,;"," f~> ia "V*T~»~i7n 3 t" O G 1
, i|'! ' ,:;,';,i , ," i,'i,;11 ,,,;':"i , " ", ;, ' ', ,,li ' , l!i : ' ,: , ;' OCL.L J.'OJ.lCLUCtO I
tcfjj ij1;,,, -.I i;*!!,;!,!!!',!,!:,!;'.j'ij'ilii ti.\: ,*. 'h;r-rM.-:Jf" .'"'S .i1'1':" i1;;,: j" \ '<'; ;,. ,:; '! MH. »", '''"'., "'i~"-» ',"
r-1 26 R89 - 312OB ICP (sum of Ca and Mg as
I ' "'.'" ,'""", =" ,,";;' ',,, ', ,' ;;, carbonates)
'^ 33 "FR25 - pil26-86(92) EDTA' ^'^ "" , ' ", ,', ,^,
34 R25 - D511-88B AA (sum of Ca and Mg as
-jj :,,, ,;l;, 3, _,, .i, ;',I, " , ";"','' ;;;; ,car^pnates_)
,.= 44 ' " "R79 - 1-1338-85' EDTA' "^
45 R79 - 1-3152 + AA (sum of Ca and Mg as
1 " ' "' '" ''' ' ": 3447-85 carbonates)
v 53 R81, - ,973.,526 ^ ,EOTA ,,_, ,
':":- 99 " Other " ' ' """" " " ' ' '
Calcium
:'f!|':,, ; fi ,-Lf ::;'!"i'\,;,,'"
: ;;/':';! Magnesium
12
13
14
11 I 25"
26
27
34
35
43
:Z! 52"
99
I '
12
13
li'i 25,,
:::: 26
::::: 27
34
=i' 43
::::54
..I 55
99
R19 -
R8 9
,,,^i«
R25
R25
R79
R80
200-7
iis'.'i'"" ' '"
215.2
311 IB
35 bop
312 OB
D511-92B
D511-92A
1-3152-85
AES0029
Other
R19
R24
R89
R89
R89
R25
R79
R81
R80
200.7
242.1
3111B
3500D
3120B
D511-92B
1-3447-85
974.27
AES0029
ICP
AA
EDTA
AA"
EDTA
ic'p
AA
EDTA
AA
DCP
ICP
AA
AA
Gravimetric
ICP
AA
AA
AA
DCP
Other
-------
11
US Environmental Protection Agency
Analyte
Sodium
Potassium
Total
Alkalinity
(as CaCO3)
Chloride
Method
Code
12
13
25
26
27
43
54
55
99
12
13
21
25
26
27
43
53
99
13
14
23
33
44
45
53
, 99
13
14
15
27
28
29
36
37
46
47
48
49
53
99
(Continued)
Ref . -Method
R19 - 200.7
R24 - 273.1
R89 - 3111B
R89 - 3500D
R89 - 3120B
R79 - 1-3735-85
R81 - 973.54
R80 - AES0029
Other
R19 - 200.7
R24 - 258.1
R3 - 317B
R89 - 3111B
R89 - 3500D
R89 - 3120B
R79 - 1-3630-85
R81 - 973.53
Other
R24 - 310.1
R24 - 310.2
R89 - 2320B
R25 - D1067-92
R79 - 1-1030-85
R79 - 1-2030-85
R81 - 973.43
Other
R24 - 325.3
R24 - 325.1
R24 - 325.2
R89 - 4500B
R89 - 4500C
R89 - 4500E
R25 - D512-89B
R25 - D512-89A
R79 - 1-1183-85
R79 - 1-1184-85
R79 - 1-1187-85
R79 - 1-2187-85
R81 - 973.51
Other
J -L. V-/ -I-J.N Vfj-a. J. JM.V .1. WJ_tXJ W X -L. WJ.V ___MJ -L \J f^-f Jj ' '>Z?
Description
ICP
AA
AA
Flame Photometric
ICP
AA
AA
DCP
ICP
AA
Cobalt initrite
AA
Flame Photometric
ICP
AA
AA
Manual Tit rat ion
Automated Titration
Manual Titration
Manual Titration
Manual Titration
Automated Titration
Manual Titration
Mercuric Nitrate
Automated Ferri cyanide
Automated Ferricyanide
Silver Nitrate
Mercuric Nitrate
Automated Ferricyanide
Silver Nitrate
Mercuric Nitrate
Silver Nitrate
Mercuric Nitrate
Manual Ferricyanide
Automated Ferricyanide
Mercuric Nitrate
-------
f
12
!:;;|ij I; .- US Environmental Protection Agency
' '''' " "
' '' \JQiimVCVU JJ^.g^JV'-'W.i. J-WJ.1
; ill , ' ': , i' ,'
Method
Arialytc Code
Fluoride 14
'III ' ' ' 15
" 1 1 ';',' 16
., .:. M 20'
11 21
2:2
33
34
' ' 45
'" -" '99
i ' , i ,...
Sulfate 14
15
1 ' ' . ,
16
,;-;. . ;:;=:, Y , ,: . ;
: '' ' ' 25
26
27
r 34
.'i "'""55
.-"' ' .'* ' !"' ' 99
i i, " '.,. , " ' |;." »M i J ,
Nutrients :
::,!;;;"' "' J.S /'"''. ,;;;,,; ,7'"''- , j*j. . ";:' .'' .'-';".,
Ammonfa', 14
^.s Nitrogen 15
"I ,;;"" , , ,' "... ""I 16
''li.r. 1". 1 ' ' '"' -. .--.i7
20
21
" !" ,,',"22 '""
23
1 24
,! , ".'-' ',!.!"." 32
- : :r.p. .' ,, i 33
''. i> ': , "' I.'.1., I'iiii 44
- i'1 r; !< '". , ):;« J..1"". '-
l'"ii . ' " " :;'' « «! 45
1 i fill1:! .. . ' ' 'i1'!,!!!, :»'
ii: ':' ' .( S3
: ""'' ' ' '= "' 5"4
1 1, i 'I'l! Jli1 ' ' I" '' ''"Mlif" ' III, , i
99
; (Continued)
Ref . -Method
R24 - 340.1
R24 - 340.2
R241 - 340.3
R89 - 4500C
R89" - 4500D
R89 - 4500E
R25 - Dll79-80A(88)
R25 - D117?-80B(88)
R79 - 1-4327-85
Other
f ' ;
R24 - 375.3
R24 - 375.4
R24 - 375.1
,,;'"! ' ' ' , . : ,
R33 - 426C
R89 - 4500C
R89 - 4500D
R25 - D516-90
R81 - 925.54
Other
"i; ; '."": ' : / "
-J." '" "|; ; .' '. '. .".
R24 - 350.2
R24 - 350.3
'".R24. - 350/1'
R24 - 350.2
R89 - 4500C
R89 - 4500E
:-R|§" _ 450 OH"
R89 - 4500G
R89 - 4500F
R25 - D1426-89A
R25 - D1426-89B
R79 - I -3520 -85
R79 - 1-4523-85
R40 - '3'79"-'75WE
R81 - 973.49
Other
Description
SPADNS
Manual Electrode
Automated Complexone
.Manual Electrode
SPADNS :
Automated Complexone
SPADNS
Manual Electrode
Automated Electrode
. , j H i ,,; , . ' '
Gravimetric
Turbi dime trie
Automated Colorimeter
(barium chloranilate)
Turbi dimetric
Gravimetric
Gravimetric
Turbidimetric
Gravimetric
, , s '" .;, '( , ' : ", :..
'\i: iiiill,1- I,/ " ' ., :!' 1 '" -
Titration
Electrode
Automated Phenate
Nesslerization
Nesslerization
Titration
Automated Phenate
Electrode
Electrode
Nesslerization
Electrode
Nesslerization
" Automated* "Phenate "'
Ill"' I1 '-'i!'' "ll'lillt II", '"' ... ,''!,' Hi, "lilh , '''
Automated Electrode
Nesslerization
''',!!'' ' ' ' ''J!'1
"
' "I 1,,' ,''
' ' ,M| , .', ' ''" 'i ; "i:1"* i ,»! ':!" '"Ill
" "1 '" !: 1 Gil! " . : Ml
..s »' -"fii ;, i' . '-:ii
; ,* "'!nxiliii ; iii""ij| M I'l j ' ../ill
1 II
'
-------
13
US Environmental Protection Agency
GENERAL INSTRUCTIONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
(Continued)
Method
Analyte
Code
Ref.-Method
Description
Nitrate,
as Nitrogen
Orthophosphate,
as P
15
16
17
18
20
21
22
27
35
36
43
52
54
99
13
14
15
25
26
33
43
54
55
99
R24 - 352.1
R24 - 353.1*
R24
R24
R89
R89
R89
353.2*
353.3*
4500E*
4500F*
4500H*
R3 - 419D
R25 - D3867-90A*
R25 - D3867-90B*
R79 - 1-4545-85*
R8 - p. 28
R81 - 973.50
Other
R24 - 365.1
R24 - 365.2
R24
R89
R89
R25
R79
365.3
4500F
4500E
D515-88A
1-4601-85
R81 - 973.56
R81 - 973.55
Other
Brucine Sulfate
Automated Hydrazine
Reduction
Automated Cadmium Reduction
Cadmium Reduction
Cadmium Reduction
Automated Cadmium Reduction
Automated Hydrazine
Reduction
Brucine Sulfate
Automated Cadmium Reduction
Cadmium Reduction
Automated Camium Reduction
Brucine Sulfate
Brucine Sulfate
Automated Ascorbic Acid
Reduction
Manual Ascorbic Acid
Reduction
Manual Two Reagent
Automated Ascorbic Acid
Reduction
Manual Ascorbic Acid
Reduction
Manual Ascorbic Acid
Reduction
Automated Ascorbic Acid
Reduction
Automated Ascorbic Acid
Reduction
Manual Ascorbic Acid
Reduction
Normally, use of these methods for nitrate would require a prior analysis of
nitrite and subtraction of the nitrite results to get an estimate for nitrate,
however, WP study samples do not contain any nitrite.
-------
14
:pS Environmental .Protection Agency
, 1
".., " ' Method
Analyte Code
Kjeldahl 14
Nitrogen 15
',""", , 16
;"': * i
|,i ' 17
i;'1 is
"!:' ' .. 19
J' : , h 34
'; : 35
36
-, i |37
i. , 42'
53
70
71
72
ii
73
, ,:',, ' , "74
75
''"' ' ';' 76
77
:,: .
" " '.. ' 78
' f" ' /',, 99
Ref .
R24
R24
R24
; ,' i.:. ". .:
R24
R24
R24"
R2 5
R25
iR25
R25
.
.. R26
R81
R89
R89
R89
R89
R8 9
'R89',
1 ''
R89
"""' " ,,r '!!''
R89
"' ' "" '
R89
: (Continued)
1 i
-Method
- 351.3
- 351.4
- 351.2
, . i
- 351.3
- 351,3
- 351.1 !
- D3590-89A
- D3590-89A
- P3590-89A
- D359d-89B
-' 1-4551-78
- 973.48
- 4500H
- 4500B+E
- 4500B+C
- 4500B+F
- 4500B+G
-""45'6bC+E"
- 4500C
'.'
- 4500C+F
1 , ' H,, !' , », ' 1,1 " "
- 4500C+G
11111 ' , '.'I'1: ..... ' :: " ' V1
Description
Nesslerization
Potentiometric
Semi -automated Block
Digestion
Titration
Electrode
Automated. Phenate
Titration
Nesslerization, ,
Potentiometric
Semi -automated Block
Digestion
Automated Phenate
Titration
Automated Phenate
Macro Digestion + Titration
Macro Digestion +
, 'ii, ,,:J iiiii",! ' i'1]1'!, "in ,, / 'iiii, , r , , ' , i : , ,
-------
>
15
« US Environmental Protection Agency
GENERAL INSTRUCTIONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
(Continued)
Method
Analyte Code
Total 13
Phosphorus ,
as P 14
15
16
26
27
33
34
43
54
55
99
Ref .
R24
R24
R24
R24
R89
R89
R25
R25
R79
R81
R81
-Method
- 365.2
- 365.3
- 365.1
- 365.4
- 4500E
- 4500F
- D515-88A
- D515-88B
- 1-4600-85
- 973.56
- 973.55
Description
Manual Ascorbic Acid
Reduction
Man. Ascorbic Acid Reduction
(2 reagents)
Automated Ascorbic Acid
Reduction
Semi -automated Block
Digestion
Manual Ascorbic Acid
Reduction
Automated Ascorbic Acid
Reduction
Manual Ascorbic Acid
Reduction
Semi -automated Block
Digestion
Automated Ascorbic Acid
Reduction
Automated Ascorbic Acid
Reduction
Manual Ascorbic Acid
Reduction
Other
-------
16
, ' ;US Environmental Protection Agency
' !<';,
"i!:1"
JV.niiiipi ~ eaffiifljBguBi .j,i ,,-- , i , 7ir,r
i ' i
Method
Analyte
Demands :
Chemical
Oxygen
Demancl (COD)
,,K , ,, ,; '" ,: ,:"
*
: " , r ' , .'> "
',
; ' ; if ;; , -
Tot-af = - " '
Organic
Carbon (TOG) "'
,. if' " ' Hi! 'r "! V;,: ;; :>j|
;: ;,:. '. ,'' , ' ;;;
A ' ! ' : ,:,
; 11:;'iii \ ' 'i,,, j
i"1'!; , ' i" , fii
" " :'s
Biochemical
Oxygen Demand
(5 day BOD)
Carbonaceous BOD
I ii
' i -!
Code
12
13
14
15
23
24
33
34
45
46
47
52
54
55
56
99
12"L :
23
24
25
32
33
42
52
99
11
12
24
25
42
51
53
99
22
99
" ! :: (Continued)
Ref . -Method
R24 - 410.1
R24 - 410.2
":R24 _- 410. 3 '
R24 - 410.4
R89 - 5220C
R89 - 5220D
R25 - D1252-88A
R25 - D1252-88B
R79 - 1-3560-85
R79 - 1-3562-85
R79 - 1-3561-85
R8 - p. 17
R41 - 8000
R42 - p. 1
R81 - 973 .46
Other
" R24 ,- 415.1 ;
R89 - 5310B
R89 '- 5310C
R89 "- 5310D ' "
R25 - D2579-85A
",^2S"|- D2579-85B
8,83. - P- 14
R81 '-' 973 .4 7
Other
R24 -' 405 '.1
R24 - 405.1
R89 - 5210B
R89 - 5210B
Ri6 - 1-1578-78
R8 - p. 17
R8l - 973:44
Other
R89 - 5210B
Other
'' ; , . . i:1 ; ' ;." . , . =,-,; : ,
Description
' ." :,,. ". : ",:,", i ;
bichromate Reflux
Dichromate Reflux
bichromate" Reflux
Spectrbphotometric
Dichromate Reflux
Spectrophotometric
Dichromate Reflux
Spe c t r opho t ome trie
bichromate Reflux
bichromate Reflux
Spectrophotometric
Dichromate Reflux
Spectrophotometric
Spectrophotometric
bichromate Reflux
,:. . -," \ :. ' : :: : :
Combustion or oxidation
Combustion or oxidation
Combustion or oxidation
Combustion or oxidation
Combustion or oxidation
Combustion or oxidation
Combust ion/ Infrared
Combustion or oxidation
«!l * i1 '" ,:|V" ", ' ' ,, ' " '". !: '»: , f ,i'' 1,
Winkler (Azide Modification)
Electrode
Winkler (Azide Modification)
Electrode
Winkler (Azide Modification)
Winkler (Azide Modification)
Winkler (Azide Modification)
Carbonaceous BOD
-------
17
US Environmental Protection Agency
GENERAL INSTRUCTIONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
(Continued)
Method
Analyte
Organic s :
PCB ' s in a
water matrix
PCB ' s in
transformer oil
Aldrin
DDD
DDE
DDT
Heptachlor
Dieldrin
Code
16
17
18
21
99
11
31
99
' 16
17
18
24
25
26
33
43
99
16
17
18
24
25
26
43
99
Ref . -Method
R54 - 608
R54 - 625
R46 - p. 43
R89 - 6410B
Other
R61 - p. 1
R62 - D4059-86
Other
R54 - 608
R54 - 625
R46 - p. 7
R89 - 6630B
R89 - 6630C
R89 - 6410B
R25 - D3086-90
R82 - p. 30
Other
R54 - 608
R54 - 625
R46 - p. 7
R89 - 6630B
R89 - 6630C
R89 - 6410B
R82 - p. 30
Other
Description
GC
GC/MS
GC
GC/MS
GC
GC
GC
GC/MS
GC
GC
GC
GC/MS
GC
GC
GC
GC/MS
GC
GC
GC
GC/MS
GC
-------
18
(In::
ill:..:
US Environmental Protection Agency
; : (Continued)
Method
Analyte"
Hepfcachlor
Epoxide
" '!
1 ,. ,,!
. ,:,
Chlordane
.' . si ;
'": ' ' ,
,' .'. :. '
Bromodichloro-
} methane
Brqmofqrin
1^2 Dichloro-
e thane
Dibromochloro-
me thane
Code
16
17
18
18
24
25
ii! 26
33
'], 43
:-=' 99
'il'ili,,1'
16
,:;:; 17
' "18
vffii ' 24
25
.'.- 26
;::: 33
99
13
., 14
16
21
22
99
Ref . -Method
R54 - 608
R54 - 625
R46 - p. 7
R47 - p. S73
R89 - 6630B
R89 - 6630C
R89 - 6410B
R25 - D3086-90
., R8,2 - p. 30
Other
.R54 - 608
R54 - 625
R46 - p. 7
R89 - 663 OB
R89 - 6630C
R89 - 641 OB
R25 - D3086-90
Other
R54 - 624
R54 - 601
R54 - 1624
R89 - 6210B
R89 - 6230B
Other
Description
GC
GC/MS
GC
GC '
GC /
GC
GC/MS .
GC
GC
- ?: :-.- . :.i:/i|
GC
GC/MS
GC
GC
GC
GC/MS
GC
"' " ~ :; ,;,.*'!
GC/MS
GC
GC/MS
GC/MS
GC
1,1,1 Trichloroethane
Trichloroethene
Carbon tetra-
chlorlde
i ' ,i
13
""'"" 14
15
16
V; 21
'' 22
99
R54 - 624
R54 - 601
R46 - p. 130
R54 - 1624
R89 - 62 3 OB
R89 - 6410B
Other
GC/MS
' GC
GC
GC/MS
GC
GC/MS
-------
19
US Environmental Protection Agency
(Continued)
Method
Analvte
Chloroform
Tetrachloroethene
Methylene Chloride
Chlorobenzene
Benzene
Ethylbenzene
Toluene
Code
13
14
- 15
16
21
22
99
13
14
15
16
21
99
11
12
13
15
16
21
22
23
99
11 .
12
16
21
22
99
Ref . -Method
R54 - 624
R54 - 601
R46 - p. 130
R54 - 1624
R89 - 6210B
R89 - 6230B
Other
R54 - 624
R54 - 601
R46 - p. 13.0.
R54 - 1624
R89 - 6230B
Other
R54 - 601
R54 - 602
R54 - 624
R46 - p. 130
R54 - 1624
R89 - 6210B
R89 - 6220B
R89 - 6230B
Other
R54 - 602
R54 - 624
R54 - 1624
R89 - 6210B
R89 - 6220B
Other
Description
GC/MS
GC
GC
GC/MS
GC/MS '
GC
GC/MS
GC
GC
GC/MS
GC
GC
GC
GC/MS
GC
GC/MS
GC/MS
GC
GC
GC
GC/MS
GC/MS
GC/MS
GC
-------
20
US Environmental Protection Agency
GENESAL_Il?STJ5IICr;EONS FOR REPORTING RESULTS IN WATER POLLUTION STUDIES
(Continued)
Method
Analyte Code
1,2 dichlorobenzene
1,3 dichlorobenzene
"I;! I1' , ' ':
. . , :«, ' i F!!«
i .":i, |i
1,4 dichlorobenzene
' j f , , , : ,",,, 1,1
;.] ; i
''.': , n
, , ,, ' ,,fl
; f ' ' .i; ' I
111111 ' ''"'
i; !:" ''"'i' "< ' '"'""»
it ' i . ,,,:' i
Total Cyanide
, ;, '
. " '"' |
:' - ' ii' J
1 ,;,; 1 'l' ' .. ll
1 ,':,
,,, l 'v " , '
j; .i'. :'. ' f, : in
i '"I, i in i ,, ; ,11, i
Non- f i 1 terable
Residue
(Total Suspended
11 Solids)",, ; ' ;
11
12
13
14
15
17
99
11
12
13
14
15
17
21
22
23
99
13
14
25
26
34
43
1
51
99
12
24
42
99
Ref . -Method
R54 - 601
R54 - 602
R54 - 612
R54 - 624
R54 - 625
R54 - 1625
Other
R54 - 601
R54 - 602
R54 - 612
R54 - 624
R54 - 625
R54 - 1625
R89 - 641 OB
R89 - 6220B
R89 - 623 OB
Other
R24 - 335.2
R24 - 335.3
R89 - 4500D
R89 - 4500E
R25 - D2Q36-91A
R79 - 1-3300-85
R8 - p. 22
Other
R24 - 160.2
R89 - 2540D
R79 - 1-3765-85
Other
Description
GC
GC
.' , . . ,
GC
GC/MS
GC/MS
GC/MS
GC
GC
GC
GC/MS
GC/MS
GC/MS
GC/MS
GC
,GC . ".'. '" ' ";"
1:-.,' :- ^ .' .i.L! ' ' ' , " ' ,.'
Manual Spectrophotometric
Automated Spect ro-
il t photometric
Titrimetric ,
Manual Spectrophotometric
Manual Spectrophotometric
'JH[ ".,]], , ||!">11-:!«II f: .' 1' "! ' . . ' ,J
Manual Spectrophotometric
Titration or Colorimetric
Glass fiber 103° to 105°C
Glass fiber 103° to 105°C
Glass fiber 103° to 105°C
-------
21
US Environmental Protection Agency
Analyte
Oil and
pH
Method
Code
Grease 12
13
23
99
12
23
32
33
43
52
54
99
(Continued)
Ref . -Method
R24 - 413.1
R102 - 1664
R89 - 5520B
Other
R24 - 150.1
R89 - 4500B
R25 - D1293-84A(90)
R25 - D1293-84B(90)
R79 - 1-1586-85
R43 - p. 1
R81 - 973.41
Other
Description
Freon Extraction/Gravimetric
Hexane Extraction/
Gravimetric
Freon Extraction/Gravimetric
Electrode
Electrode
Electrode
Electrode
Electrode
Automated Electrode
Electrode
Total Phenolics
11
12
R24 - 420.1
R24 - 420.2
21
R3 - 510A + 510B
Manual 4-AAP with
distillation
Automated 4-AAP
with distillation
(with the manual
distillation in
420.1)
Manual 4-AAP with
distillation
and chloroform extraction
22
99
Total Residual 11
Chlorine 12
13
.14
15
16
20
26
27
28
29
31
51
99
R3 - 510A + 510C
Other
R24
R24
R24
R24
R24
R24
R89
R89
R89
R89
R89
R25
R49
- 330.1
- 330.2
- 330.3
- 330.4
- 330.5
- 330.2
- 4500B
- 4500C
- 4500D
- 4500F
- 4500G
- D1253-86(92)
- P- 1
Manual 4-AAP with
distillation
Titrimetric - amperometric
Back- starch end point
lodometric
DPD-FAS
Spectrophotometric, DPD
Back-amperometric end point
lodometric
Back- starch end point
Titrimetric - amperometric
DPD - FAS
Spectrophotometric, DPD
Titrimetric - amperometric
Electrode
Other
-------
1 "? '".', .I1"1.* 1', flXl J1 ''.I!
'
22
METHOD REFERENCES
.ill
S3. "Standard Methods for the Examination of Water and. Waste Water," 14th ed.,
/! ',, 1^76. ^Available from the American Public Health Association,
"'. 1015 18th Street, N.W., Washington, DC 20036.
R8. American National Standards on Photographic Processing Effluents,
1 ' April 2, 1975 ". Available from ANSI, 1430 Broadway^ New York, NY 10018.
R19. "Inductively Coupled Plasma-Atomic Emission Spectrometric Method for Trace
Element Analysis of Water and Wastes," Appendix C, 40 CFR, Part 136.
R24. "Methods of Chemical Analysis of Water and Wastes." U.S. Environmental
Protection Agency, NERL, Cincinnati, OH 45268, March, 1983
;.; .. (EPA-6pO/4-79-020) . Available from ORD Publications, CERI, EPA, Cincinnati,
OH"11 '45268. "'"" "
R2S. Annual Book of ASTM Standards, Volumes 11.01 and 11.02 for Water, merican
Society for Testing and Materials, 1916 Race Street, Philadelphia, PA
i ' . I1,11 ,|",'l , ' JilH ^ i " ' . '"' ' ' ' IH ' '!, ',.,','» '' ' . J "'" '" :!"!, ! 1,1" I I ,11' ,'!'
'«' ; '19103.
:f : ?" : rj:" i' '" , :' v : .-. ' . ' .. ',..":.;. :'J- !"K\ 1B|
1+ ': , -I', ll I . ' ' ; ' ' , . ' i... J '! ;-i ,. i.;!* I J i|IK
R26. Techniques of Water-Resources Investigation of the U.S. Geological Survey,
! Chapter A-l, "Methods for Determination of Inorganic Substances in Water and
Fluvial Sediments," Book 5, 1979, Stock #024-001-03177-9.Available from "
:. Superintendent of Documents, U.S. Government Printing Office, Washington,
\. . . D.C. 20402. "'"" '"' ,' " "" . ' : " . , \ _ / \ " "r '^^ri ^
.I,1 '-: <: ', , "'. ' 'iif "" ' . r : ' ; ." , ' " ' v"!- , "j«,i ; - '' if ," , . ... '..''i,1 " .. .tiiiiu k i
:;R33,. Standard M^th^ds for Examination pf Water and Wastewater. 15th ed., 1981.
Available from the American Public Health Association, 1015 18th Street,
N.W., Washington, D.C. 20036.
R34. "Official Methpds, of Analysis of the Association of Official Analytical
" Chemists" Methods Manual, 14th ed., 1985. Available from the AOAC, 2200
Wilson Blvd., Suite 400, Arlington, VA 22201-3301. (703) 522-3032.
:,',: ' ' " 'I' ;;:"'"! ' .'nJ'1"1 ^ , i» , , ' ' y ' , i,1:,, ' IM i : i ' ' " '!' ?l1" ! ''"
R40. Ammonia, Automated Electrode Method, Industrial Method Number 379-75WE,
dated February 19, 1976, Bran & Luebbe (Technicon) AutoAnalyzer II, Bran &
Luebbe Analyzing Technologies, Inc., Elmsford, NY10523.
R41. Hach Handbookof Water Analysis, 1979, Hach Chemical Company,
P.O. Box 389, Loveland, CO 8Q537.
R42. COD Method, Oceanography International Corporation, 512 West Loop, P.O. Box
2980, College Station, TX 77840
-------
23
R43. Hydrogen Ion (pH) Automated Electrode Method, Industrial Method Number
378-75WA, October, 1976, Bran & Luebbe (Technicon) AutoAnalyzer II,
Bran & Luebbe Analyzing Technologies, Inc., Elmsford, NY 10523.
R44. Iron, 1,10-Phenanthroline Method, Method 8008, 1980, Hach Chemical Company,
P.O. Box 389, Loveland, CO 80537.
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' i;i|: ; »,.; " ' »! If -:! ' ! .", "'iilWili,, :l! . ' ' " ' ' ' 'iI',,, ' ' ' , "jj11; 1'
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A-US. GOVERNMENT PRINTING OFFICE: 1998 -«SO-070/«X>32
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